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Home My WebLink AboutNC0038377_J15050632 Report_20150902+ DUKE Analytical Laboratory 1 of55 ENERGY Order Number: Project Name: Customer Name(s): Customer Address: Lab Contact: Report Authorized By: (Signature) Program Comments: 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone:980-875-5245 Fax:980-875-4349 Order Summary Report J15050632 MAYO STEAM - AB GW ASSESSMENT SOIL Tim Hunsucker, Jerry Wylie, Kathy Webb, John Toepfer Margaret Galvin -Karr MXG4644 (101 161) 2015.06.19 13:52:27 Ef�ERGY-04'00' Margaret Galvin -Karr Phone: 980-875-5219 Date: Please contact the Program Manager (Margaret Galvin -Karr) with any questions regarding this report. Data Flags & Calculations: 6/18/2015 Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Sample ID's & Descriptions: 2 of 55 Sample ID Plant/Station 2015015768 2015015769 2015015770 3 Total Samples Collection Date and Time Collected By Sample Description MAYO STEAM 19-May-15 2:15 PM illegible ABMW-3EB MAYO STEAM 20-May-15 3:20 PM illegible ABMW-3SEB MAYO STEAM 20-May-15 2:15 PM illegible ABMW-3S(51.0-53.0) 3 of 55 Technical Validation Review Checklist: COC and .pdf report are in agreement with sample totals Yes No and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. ❑ Yes❑ No All laboratory QA/QC requirements are acceptable.❑ Yes ❑ No Report Sections Included: U Job Summary Report ❑ Sample Identification n Technical Validation of Data Package ❑ Analytical Laboratory Certificate of Analysis ❑ Analytical Laboratory QC Report Reviewed By: Date: Sub -contracted Laboratory Results ❑ Customer Specific Data Sheets, Reports, & Documentation ❑ Customer Database Entries 0 Chain of Custody [I/0] Electronic Data Deliverable (EDD) Sent Separately Certificate of Laboratory Analysis 4 of 55 This report shall not be reproduced, except in full. Order # J15050632 Site: ABMW-3EB Collection Date: 19-May-15 2:15 PM Analyte Result Units Qualifiers RDL DF METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Sample #: 2015015768 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Certificate of Laboratory Analysis 5 of 55 This report shall not be reproduced, except in full. Order # J15050632 Site: ABMW-3SEB Collection Date: 20-May-15 3:20 PM Analyte Result Units Qualifiers RDL DF METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Sample #: 2015015769 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050632 Site: ABMW-3S(51.0-53.0) Collection Date: 20-Mav-15 2:15 PM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 6 of 55 Sample #: 2015015770 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kic&fie. Suite 100 Huntersville, INC 28078 (704)875-9092 June 15, 2015 Program Manager Duke Energy 13339 Hagers Ferry Road Bldg.7405 MG30A2 Huntersville, NC 28078 RE: Project: J 15050632 Pace Project No.: 92251236 Dear Program Manager: Enclosed are the analytical results for sample(s) received by the laboratory on May 22, 2015. The results relate only to the samples included in this report. Results reported herein conform to the most current TN standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Herring kevin.herring@pacelabs.com HORIZON Database Administrator Enclosures cc: Marge Galvin -Karr, Duke Energy Program Manager, Duke Energy Mary Ann Ogle, Duke Energy Rodney Wilke, Duke Energy p«FO REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, lqe� �� without the written consent of Pace Analytical Services, Inc.. BRAT, Page 1 of 48 lacmnalyfica( www.pacelabs.com Pace Analytical Services, Inc. 9800 Kinfb6ge. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15050632 Pace Project No.: 92251236 Minnesota Certification IDs 1700 Elm Street SE Suite 200, Minneapolis, MN 55414 A21-A Certification #: 2926.01 Alaska Certification #: UST-078 Alaska Certification #MN00064 Alabama Certification #40770 Arizona Certification #: AZ-0014 Arkansas Certification #: 88-0680 California Certification #: 01155CA Colorado Certification #Pace Connecticut Certification #: PH-0256 EPA Region 8 Certification #: 8TMS-L Florida/NELAP Certification #: E87605 Guam Certification #:14-008r Georgia Certification #: 959 Georgia EPD #: Pace Idaho Certification #: MN00064 Hawaii Certification #MN00064 Illinois Certification #: 200011 Indiana Certification#C-MN-01 Iowa Certification #: 368 Kansas Certification #: E-10167 Kentucky Dept of Envi. Protection - DW #90062 Kentucky Dept of Envi. Protection - WW #:90062 Louisiana DEQ Certification #: 3086 Louisiana DHH #: LA140001 Maine Certification #: 2013011 Maryland Certification #: 322 Michigan DEPH Certification #: 9909 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification #: 41320 Connecticut Certification #: PH-0216 Delaware Certification: FL NELAC Reciprocity Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Massachusetts Certification #: M-FL1264 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Green Bay Certification IDs 1241 Bellevue Street, Green Bay, WI 54302 Florida/NELAP Certification #: E87948 Illinois Certification #: 200050 Kentucky Certification #: 82 Louisiana Certification #: 04168 Minnesota Certification #: 055-999-334 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 CERTIFICATIONS Minnesota Certification #: 027-053-137 Mississippi Certification #: Pace Montana Certification #: MT0092 Nevada Certification #: MN_00064 Nebraska Certification #: Pace New Jersey Certification #: MN-002 New York Certification #: 11647 North Carolina Certification #: 530 North Carolina State Public Health #: 27700 North Dakota Certification #: R-036 Ohio EPA#: 4150 Ohio VAP Certification #: CL101 Oklahoma Certification #: 9507 Oregon Certification #: MN200001 Oregon Certification #: MN300001 Pennsylvania Certification #: 68-00563 Puerto Rico Certification Saipan (CNMI) #:MP0003 South Carolina #:74003001 Texas Certification #: T104704192 Tennessee Certification #: 02818 Utah Certification #: MN000642013-4 Virginia DGS Certification #: 251 Virginia/VELAP Certification #: Pace Washington Certification #: C486 West Virginia Certification #: 382 West Virginia DHHR #:9952C Wisconsin Certification #: 999407970 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 Nevada Certification: FL NELAC Reciprocity New Hampshire Certification #: 2958 New Jersey Certification #: FL765 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FLO1264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 Washington Certification #: C955 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity North Dakota Certification #: R-150 South Carolina Certification #: 83006001 Texas Certification #: T104704529-14-1 US Dept of Agriculture #: S-76505 Wisconsin Certification #: 405132750 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 2 of 48 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kigc&y&ie. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15050632 Pace Project No.: 92251236 Asheville Certification IDs North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 CERTIFICATIONS West Virginia Certification #: 356 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 3 of 48 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ff�i�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: J15050632 Pace Project No.: 92251236 Lab ID Sample ID Matrix Date Collected Date Received 92251236001 2015015768 Water 05/19/1514:15 05/22/1514:40 92251236002 2015015769 Water 05/20/1515:20 05/22/1514:40 92251236003 2015015770 Solid 05/20/1514:15 05/22/1514:40 92251236004 2015015770 SPLP Water 05/20/15 14:15 05/22/15 14:40 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 4 of 48 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 fflinl c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: J15050632 92251236 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92251236001 2015015768 EPA 6020A RJS 24 PASI-M EPA 7470A JDD 1 PASI-M 92251236002 2015015769 EPA 6020A RJS 24 PASI-M EPA 7470A JDD 1 PASI-M 92251236003 2015015770 EPA 6010 CKJ 17 PASI-0 EPA 6020 CRT 7 PASI-O EPA 7471 CRT 1 PASI-O ASTM D2974-87 MLO 1 PASI-O EPA 9045 MAB 1 PASI-A EPA 300.0 AES2 1 PASI-A EPA 353.2 DMN 1 PASI-A SM 4500-CI-E SER 1 PASI-A EPA 9056 CMB 2 PASI-O EPA 9056 CMB 1 PASI-O EPA 9060 TJJ 6 PASI-G 92251236004 2015015770 SPLP EPA 6020A TT3 24 PASI-M EPA 7470A LMW 1 PASI-M REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 5 of 48 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffli�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15050632 Pace Project No.: 92251236 Lab Sample ID Client Sample ID Method Parameters SUMMARY OF DETECTION Result Units Report Limit Analyzed 92251236001 2015015768 EPA 6020A Aluminum 18.1 ug/L 10.0 05/29/15 18:03 EPA 6020A Barium 0.70 ug/L 0.30 05/29/15 18:03 EPA 6020A Calcium 134 ug/L 40.0 05/29/15 18:03 EPA 6020A Chromium 1.2 ug/L 0.50 05/29/15 18:03 EPA 6020A Cobalt 3.3 ug/L 0.50 05/29/15 18:03 EPA 6020A Iron 186 ug/L 50.0 05/29/15 18:03 EPA 6020A Lead 0.070J ug/L 0.10 05/29/15 18:03 EPA 6020A Magnesium 9.91 ug/L 10.0 05/29/15 18:03 EPA 6020A Manganese 7.0 ug/L 0.50 05/29/15 18:03 EPA 6020A Molybdenum 0.27J ug/L 0.50 05/29/15 18:03 EPA 6020A Potassium 29.3J ug/L 50.0 05/29/15 18:03 EPA 6020A Strontium 0.16J ug/L 0.50 05/29/15 18:03 EPA 6020A Zinc 3.6J ug/L 5.0 05/29/15 18:03 92251236002 2015015769 EPA 6020A Aluminum 41.7 ug/L 10.0 05/29/15 18:41 EPA 6020A Barium 1.5 ug/L 0.30 05/29/15 18:41 EPA 6020A Boron 2.3J ug/L 5.0 05/29/15 18:41 EPA 6020A Calcium 298 ug/L 40.0 05/29/15 18:41 EPA 6020A Chromium 2.1 ug/L 0.50 05/29/15 18:41 EPA 6020A Cobalt 61.1 ug/L 0.50 05/29/15 18:41 EPA 6020A Copper 1.1 ug/L 1.0 05/29/15 18:41 EPA 6020A Iron 321 ug/L 50.0 05/29/15 18:41 EPA 6020A Magnesium 59.5 ug/L 10.0 05/29/15 18:41 EPA 6020A Manganese 9.9 ug/L 0.50 05/29/15 18:41 EPA 6020A Molybdenum 0.32J ug/L 0.50 05/29/15 18:41 EPA 6020A Nickel 0.64 ug/L 0.50 05/29/15 18:41 EPA 6020A Potassium 90.1 ug/L 50.0 05/29/15 18:41 EPA 6020A Sodium 182 ug/L 50.0 05/29/15 18:41 EPA 6020A Strontium 0.80 ug/L 0.50 05/29/15 18:41 EPA 6020A Zinc 5.2 ug/L 5.0 05/29/15 18:41 92251236003 2015015770 EPA 6010 Aluminum 10600 mg/kg 34.0 06/04/15 01:35 EPA 6010 Barium 56.1 mg/kg 3.4 06/04/15 01:35 EPA 6010 Beryllium 0.90 mg/kg 0.34 06/04/15 01:35 EPA 6010 Chromium 1.3J mg/kg 1.7 06/04/15 01:35 EPA 6010 Copper 9.0 mg/kg 1.7 06/04/15 01:35 EPA 6010 Iron 16900 mg/kg 13.6 06/04/15 01:35 EPA 6010 Magnesium 4210 mg/kg 170 06/04/15 01:35 EPA 6010 Manganese 319 mg/kg 1.7 06/04/15 01:35 EPA 6010 Potassium 2980 mg/kg 340 06/04/15 01:35 EPA 6010 Strontium 3.3J mg/kg 3.4 06/04/15 01:35 EPA 6010 Zinc 27.7 mg/kg 6.8 06/04/15 01:35 EPA 6020 Cobalt 6.6J mg/kg 6.8 06/03/15 19:56 EPA 6020 Vanadium 28.8 mg/kg 6.8 06/03/15 19:56 EPA 7471 Mercury 0.021 mg/kg 0.010 06/03/15 18:18 ASTM D2974-87 Percent Moisture 24.6 % 0.10 06/05/15 09:17 REPORT OF LABORATORY ANALYSIS Qualifiers This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 6 of 48 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffii�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15050632 Pace Project No.: 92251236 Lab Sample ID Method 92251236003 EPA 9045 EPA 300.0 EPA 9060 92251236004 EPA 6020A EPA 6020A EPA 6020A EPA 6020A EPA 6020A EPA 6020A EPA 6020A EPA 6020A EPA 6020A EPA 6020A EPA 6020A EPA 6020A EPA 6020A EPA 6020A EPA 6020A EPA 6020A EPA 6020A EPA 6020A Client Sample ID Parameters 2015015770 pH at 25 Degrees C Sulfate RSD% 2015015770 SPLP Aluminum Arsenic Barium Boron Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Nickel Potassium Sodium Strontium Vanadium Zinc SUMMARY OF DETECTION Result Units Report Limit Analyzed Qualifiers 5.9 Std. Units 3.0 mg/L 1.6 % 268 ug/L 0.17J ug/L 80.2 ug/L 85.6 ug/L 170 ug/L 0.55 ug/L 0.15J ug/L 0.54J ug/L 95.1 ug/L 0.072J ug/L 40.8 ug/L 4.8 ug/L 0.18J ug/L 102 ug/L 1870 ug/L 3.2 ug/L 0.61 J ug/L 56.7 ug/L REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. 0.10 06/03/1512:00 H1 2.7 06/10/1510:13 B 06/12/15 09:11 10.0 06/10/1516:09 0.50 06/10/1516:09 0.30 06/10/1516:09 5.0 06/10/1516:09 40.0 06/10/1516:09 0.50 06/10/1516:09 0.50 06/10/1516:09 1.0 06/10/1516:09 50.0 06/10/1516:09 0.10 06/10/1516:09 10.0 06/10/1516:09 0.50 06/10/1516:09 0.50 06/10/1516:09 50.0 06/10/1516:09 50.0 06/10/1516:09 0.50 06/10/1516:09 1.0 06/10/1516:09 5.0 06/10/1516:09 Page 7 of 48 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 fflic&)e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15050632 Pace Project No.: 92251236 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: June 15, 2015 General Information: 1 sample was analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/24465 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92251157007 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1229849) • Aluminum • Iron • Manganese • MSD (Lab ID: 1229850) • Aluminum • Iron Additional Comments: Batch Comments: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. • QC Batch: ICP / 14943 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 8 of 48 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffli�c&)e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15050632 Pace Project No.: 92251236 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: June 15, 2015 General Information: 1 sample was analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/24466 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92251157007 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • MS (Lab ID: 1229856) • Arsenic • Thallium • MSD (Lab ID: 1229857) • Thallium Additional Comments: Batch Comments: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. • QC Batch: ICPM / 9902 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 9 of 48 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffii�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15050632 Pace Project No.: 92251236 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: June 15, 2015 Analyte Comments: QC Batch: MPRP/24466 N2: The lab does not hold TNI accreditation for this parameter. •2015015770 (Lab ID:92251236003) • Antimony • BLANK (Lab ID: 1229854) • Antimony • LCS (Lab ID: 1229855) • Antimony • MS (Lab ID: 1229856) • Antimony • MSD (Lab ID: 1229857) • Antimony REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 10 of 48 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 fflic&)e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15050632 Pace Project No.: 92251236 Method: EPA 6020A Description: 6020A MET ICPMS Client: Duke Energy Date: June 15, 2015 General Information: 3 samples were analyzed for EPA 6020A. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3020 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/54700 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92251147009 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1977700) • Boron • MSD (Lab ID: 1977701) • Boron QC Batch: MPRP/55041 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92253352007 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1989780) • Aluminum • MSD (Lab ID: 1989781) • Aluminum Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 11 of 48 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffligc&)e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15050632 Pace Project No.: 92251236 Method: EPA 7470A Description: 7470A Mercury Client: Duke Energy Date: June 15, 2015 General Information: 3 samples were analyzed for EPA 7470A. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7470A with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 12 of 48 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffli�c&)e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15050632 Pace Project No.: 92251236 Method: EPA 7471 Description: 7471 Mercury Client: Duke Energy Date: June 15, 2015 General Information: 1 sample was analyzed for EPA 7471. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7471 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 13 of 48 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KP�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15050632 Pace Project No.: 92251236 Method: EPA 9045 Description: 9045 pH Soil Client: Duke Energy Date: June 15, 2015 General Information: 1 sample was analyzed for EPA 9045. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 1-11: Analysis conducted outside the EPA method holding time. •2015015770 (Lab ID:92251236003) Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Duplicate Sample: All duplicate sample results were within method acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 14 of 48 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K�nlc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15050632 Pace Project No.: 92251236 Method: EPA 300.0 Description: 300.0 IC Anions, SPLP Client: Duke Energy Date: June 15, 2015 General Information: 1 sample was analyzed for EPA 300.0. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. QC Batch: WETA/23222 B: Analyte was detected in the associated method blank. • BLANK for HBN 267287 [WETA/232 (Lab ID: 1479817) • Sulfate Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 15 of 48 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KP�c&)e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15050632 Pace Project No.: 92251236 Method: EPA 353.2 Description: 353.2 Nitrogen, NO2/NO3, SPLP Client: Duke Energy Date: June 15, 2015 General Information: 1 sample was analyzed for EPA 353.2. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 1-11: Analysis conducted outside the EPA method holding time. •2015015770 (Lab ID:92251236003) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 16 of 48 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KP�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15050632 Pace Project No.: 92251236 Method: SM 4500-CI-E Description: 4500 Chloride, SPLP Client: Duke Energy Date: June 15, 2015 General Information: 1 sample was analyzed for SM 4500-CI-E. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 17 of 48 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KPc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15050632 Pace Project No.: 92251236 Method: EPA 9056 Description: 9056 IC Anions Client: Duke Energy Date: June 15, 2015 General Information: 1 sample was analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/46803 DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015015770 (Lab ID:92251236003) • Chloride • Sulfate REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 18 of 48 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KP�c&)e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15050632 Pace Project No.: 92251236 Method: EPA 9056 Description: 9056 IC Anions 48hr Client: Duke Energy Date: June 15, 2015 General Information: 1 sample was analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 113: Sample was received or analysis requested beyond the recognized method holding time. •2015015770 (Lab ID:92251236003) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/46804 DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015015770 (Lab ID:92251236003) • Nitrate as N REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 19 of 48 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K��c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15050632 Pace Project No.: 92251236 Method: EPA 9060 Description: Total Organic Carbon Quad Client: Duke Energy Date: June 15, 2015 General Information: 1 sample was analyzed for EPA 9060. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: This data package has been reviewed for quality and completeness and is approved for release. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 20 of 48 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15050632 Pace Project No.: 92251236 Sample: 2015015768 Lab ID: 92251236001 Collected: 05/19/15 14:15 Received: 05/22/15 14:40 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;I➢ZI7c\��,I=11a Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470A Mercury Mercury Date: 06/15/2015 01:39 PM Analytical Method: EPA 6020A Preparation Method: EPA 3020 18.1 ug/L 10.0 3.0 1 05/28/15 21:12 05/29/15 18:03 7429-90-5 ND ug/L 0.50 0.15 1 05/28/15 21:12 05/29/15 18:03 7440-36-0 ND ug/L 0.50 0.11 1 05/28/15 21:12 05/29/15 18:03 7440-38-2 0.70 ug/L 0.30 0.081 1 05/28/15 21:12 05/29/15 18:03 7440-39-3 ND ug/L 0.20 0.067 1 05/28/15 21:12 05/29/15 18:03 7440-41-7 ND ug/L 5.0 1.1 1 05/28/15 21:12 05/29/15 18:03 7440-42-8 ND ug/L 0.080 0.024 1 05/28/15 21:12 05/29/15 18:03 7440-43-9 134 ug/L 40.0 16.0 1 05/28/15 21:12 05/29/15 18:03 7440-70-2 1.2 ug/L 0.50 0.17 1 05/28/15 21:12 05/29/15 18:03 7440-47-3 3.3 ug/L 0.50 0.13 1 05/28/15 21:12 05/29/15 18:03 7440-48-4 ND ug/L 1.0 0.21 1 05/28/15 21:12 05/29/15 18:03 7440-50-8 186 ug/L 50.0 13.7 1 05/28/15 21:12 05/29/15 18:03 7439-89-6 0.070J ug/L 0.10 0.046 1 05/28/15 21:12 05/29/15 18:03 7439-92-1 9.91 ug/L 10.0 3.2 1 05/28/15 21:12 05/29/15 18:03 7439-95-4 7.0 ug/L 0.50 0.24 1 05/28/15 21:12 05/29/15 18:03 7439-96-5 0.27J ug/L 0.50 0.094 1 05/28/15 21:12 05/29/15 18:03 7439-98-7 ND ug/L 0.50 0.16 1 05/28/15 21:12 05/29/15 18:03 7440-02-0 29.3J ug/L 50.0 11.7 1 05/28/15 21:12 05/29/15 18:03 7440-09-7 ND ug/L 0.50 0.20 1 05/28/15 21:12 05/29/15 18:03 7782-49-2 ND ug/L 50.0 16.3 1 05/28/15 21:12 05/29/15 18:03 7440-23-5 0.16J ug/L 0.50 0.13 1 05/28/15 21:12 05/29/15 18:03 7440-24-6 ND ug/L 0.10 0.015 1 05/28/15 21:12 05/29/15 18:03 7440-28-0 ND ug/L 1.0 0.28 1 05/28/15 21:12 05/29/15 18:03 7440-62-2 3.6J ug/L 5.0 2.4 1 05/28/15 21:12 05/29/15 18:03 7440-66-6 Analytical Method: EPA 7470A Preparation Method: EPA 7470A ND ug/L 0.20 0.022 1 05/30/1510:30 06/01/1519:57 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 21 of 48 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KPgc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15050632 Pace Project No.: 92251236 Sample: 2015015769 Lab ID: 92251236002 Collected: 05/20/15 15:20 Received: 05/22/15 14:40 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;I➢ZI7c\�i,I=11 l[99�� 6? Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470A Mercury Mercury Date: 06/15/2015 01:39 PM Analytical Method: EPA 6020A Preparation Method: EPA 3020 41.7 ug/L 10.0 3.0 1 05/28/15 21:12 05/29/15 18:41 7429-90-5 ND ug/L 0.50 0.15 1 05/28/15 21:12 05/29/15 18:41 7440-36-0 ND ug/L 0.50 0.11 1 05/28/15 21:12 05/29/15 18:41 7440-38-2 1.5 ug/L 0.30 0.081 1 05/28/15 21:12 05/29/15 18:41 7440-39-3 ND ug/L 0.20 0.067 1 05/28/15 21:12 05/29/15 18:41 7440-41-7 2.3J ug/L 5.0 1.1 1 05/28/15 21:12 05/29/15 18:41 7440-42-8 ND ug/L 0.080 0.024 1 05/28/15 21:12 05/29/15 18:41 7440-43-9 298 ug/L 40.0 16.0 1 05/28/15 21:12 05/29/15 18:41 7440-70-2 2.1 ug/L 0.50 0.17 1 05/28/15 21:12 05/29/15 18:41 7440-47-3 61.1 ug/L 0.50 0.13 1 05/28/15 21:12 05/29/15 18:41 7440-48-4 1.1 ug/L 1.0 0.21 1 05/28/15 21:12 05/29/15 18:41 7440-50-8 321 ug/L 50.0 13.7 1 05/28/15 21:12 05/29/15 18:41 7439-89-6 ND ug/L 0.10 0.046 1 05/28/15 21:12 05/29/15 18:41 7439-92-1 59.5 ug/L 10.0 3.2 1 05/28/15 21:12 05/29/15 18:41 7439-95-4 9.9 ug/L 0.50 0.24 1 05/28/15 21:12 05/29/15 18:41 7439-96-5 0.32J ug/L 0.50 0.094 1 05/28/15 21:12 05/29/15 18:41 7439-98-7 0.64 ug/L 0.50 0.16 1 05/28/15 21:12 05/29/15 18:41 7440-02-0 90.1 ug/L 50.0 11.7 1 05/28/15 21:12 05/29/15 18:41 7440-09-7 ND ug/L 0.50 0.20 1 05/28/15 21:12 05/29/15 18:41 7782-49-2 182 ug/L 50.0 16.3 1 05/28/15 21:12 05/29/15 18:41 7440-23-5 0.80 ug/L 0.50 0.13 1 05/28/15 21:12 05/29/15 18:41 7440-24-6 ND ug/L 0.10 0.015 1 05/28/15 21:12 05/29/15 18:41 7440-28-0 ND ug/L 1.0 0.28 1 05/28/15 21:12 05/29/15 18:41 7440-62-2 5.2 ug/L 5.0 2.4 1 05/28/15 21:12 05/29/15 18:41 7440-66-6 Analytical Method: EPA 7470A Preparation Method: EPA 7470A ND ug/L 0.20 0.022 1 05/30/15 10:30 06/01/15 20:04 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 22 of 48 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K��c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15050632 Pace Project No.: 92251236 Sample: 2015015770 Lab ID: 92251236003 Collected: 05/20/15 14:15 Received: 05/22/15 14:40 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 10600 mg/kg 34.0 17.0 5 06/02/15 20:20 06/04/15 01:35 7429-90-5 Barium 56.1 mg/kg 3.4 1.7 5 06/02/15 20:20 06/04/15 01:35 7440-39-3 Beryllium 0.90 mg/kg 0.34 0.17 5 06/02/15 20:20 06/04/15 01:35 7440-41-7 Boron ND mg/kg 17.0 8.5 5 06/02/15 20:20 06/04/15 01:35 7440-42-8 Calcium ND mg/kg 170 84.9 5 06/02/15 20:20 06/04/15 01:35 7440-70-2 Chromium 1.3J mg/kg 1.7 0.85 5 06/02/15 20:20 06/04/15 01:35 7440-47-3 Copper 9.0 mg/kg 1.7 0.85 5 06/02/15 20:20 06/04/15 01:35 7440-50-8 Iron 16900 mg/kg 13.6 6.8 5 06/02/15 20:20 06/04/15 01:35 7439-89-6 Magnesium 4210 mg/kg 170 84.9 5 06/02/15 20:20 06/04/15 01:35 7439-95-4 Manganese 319 mg/kg 1.7 0.85 5 06/02/15 20:20 06/04/15 01:35 7439-96-5 Molybdenum ND mg/kg 3.4 1.7 5 06/02/15 20:20 06/04/15 01:35 7439-98-7 Nickel ND mg/kg 1.7 0.85 5 06/02/15 20:20 06/04/15 01:35 7440-02-0 Potassium 2980 mg/kg 340 170 5 06/02/15 20:20 06/04/15 01:35 7440-09-7 Selenium ND mg/kg 5.1 2.5 5 06/02/15 20:20 06/04/15 01:35 7782-49-2 Sodium ND mg/kg 340 170 5 06/02/15 20:20 06/04/15 01:35 7440-23-5 Strontium 3.3J mg/kg 3.4 1.7 5 06/02/15 20:20 06/04/15 01:35 7440-24-6 Zinc 27.7 mg/kg 6.8 3.4 5 06/02/15 20:20 06/04/15 01:35 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 6.8 3.4 100 06/02/15 20:20 06/03/15 19:56 7440-36-0 N2 Arsenic ND mg/kg 6.8 3.4 100 06/02/15 20:20 06/03/15 19:56 7440-38-2 Cadmium ND mg/kg 0.81 0.41 100 06/02/15 20:20 06/03/15 19:56 7440-43-9 Cobalt 6.6J mg/kg 6.8 3.4 100 06/02/15 20:20 06/03/15 19:56 7440-48-4 Lead ND mg/kg 6.8 3.4 100 06/02/15 20:20 06/03/15 19:56 7439-92-1 Thallium ND mg/kg 6.8 3.4 100 06/02/15 20:20 06/03/15 19:56 7440-28-0 Vanadium 28.8 mg/kg 6.8 3.4 100 06/02/15 20:20 06/03/15 19:56 7440-62-2 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury 0.021 mg/kg 0.010 0.0052 1 06/02/15 20:30 06/03/15 18:18 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 24.6 % 0.10 0.10 1 06/05/15 09:17 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 5.9 Std. Units 0.10 0.10 1 06/03/15 12:00 H1 300.0 IC Anions, SPLP Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 05/28/15 04:30 Sulfate 3.0 mg/L 2.7 1.3 1 06/10/1510:13 14808-79-8 B 353.2 Nitrogen, NO2/NO3, SPLP Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 05/28/15 04:30 Nitrogen, Nitrate ND mg/L 0.27 0.27 1 06/09/15 17:53 H1 4500 Chloride, SPLP Analytical Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 05/28/15 04:30 Chloride ND mg/L 6.6 3.3 1 06/06/15 07:37 16887-00-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/15/2015 01:39 PM without the written consent of Pace Analytical Services, Inc.. Page 23 of 48 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K��c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15050632 Pace Project No.: 92251236 Sample: 2015015770 Lab ID: 92251236003 Collected: 05/20/15 14:15 Received: 05/22/15 14:40 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 338 169 5 05/29/1515:01 16887-00-6 D3 Sulfate ND mg/kg 338 169 5 05/29/1515:01 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 33.8 16.9 5 05/29/15 15:01 14797-55-8 D3,1-13 Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon ND mg/kg 789 395 1 06/12/15 09:11 7440-44-0 Total Organic Carbon ND mg/kg 795 398 1 06/12/15 09:17 7440-44-0 Total Organic Carbon ND mg/kg 801 400 1 06/12/15 09:22 7440-44-0 Total Organic Carbon ND mg/kg 792 396 1 06/12/15 09:28 7440-44-0 Mean Total Organic Carbon ND mg/kg 794 397 1 06/12/15 09:11 7440-44-0 Surrogates RSD% 1.6 % 1 06/12/15 09:11 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/15/2015 01:39 PM without the written consent of Pace Analytical Services, Inc.. Page 24 of 48 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K3nlc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15050632 Pace Project No.: 92251236 Sample: 2015015770 SPLP Lab ID: 92251236004 Collected: 05/20/15 14:15 Received: 05/22/15 14:40 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;T➢Z17c\�iil=11 a Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470A Mercury Mercury Date: 06/15/2015 01:39 PM Analytical Method: EPA 6020A Preparation Method: EPA 3020 268 ug/L 10.0 3.0 1 06/10/1511:32 06/10/1516:09 7429-90-5 ND ug/L 0.50 0.15 1 06/10/1511:32 06/10/1516:09 7440-36-0 0.17J ug/L 0.50 0.11 1 06/10/1511:32 06/10/1516:09 7440-38-2 80.2 ug/L 0.30 0.081 1 06/10/1511:32 06/10/1516:09 7440-39-3 ND ug/L 0.20 0.067 1 06/10/1511:32 06/10/1516:09 7440-41-7 85.6 ug/L 5.0 1.1 1 06/10/1511:32 06/10/1516:09 7440-42-8 ND ug/L 0.080 0.024 1 06/10/1511:32 06/10/1516:09 7440-43-9 170 ug/L 40.0 16.0 1 06/10/1511:32 06/10/1516:09 7440-70-2 0.55 ug/L 0.50 0.17 1 06/10/1511:32 06/10/1516:09 7440-47-3 0.15J ug/L 0.50 0.13 1 06/10/1511:32 06/10/1516:09 7440-48-4 0.54J ug/L 1.0 0.21 1 06/10/1511:32 06/10/1516:09 7440-50-8 95.1 ug/L 50.0 13.7 1 06/10/1511:32 06/10/1516:09 7439-89-6 0.072J ug/L 0.10 0.046 1 06/10/1511:32 06/10/1516:09 7439-92-1 40.8 ug/L 10.0 3.2 1 06/10/1511:32 06/10/1516:09 7439-95-4 4.8 ug/L 0.50 0.24 1 06/10/1511:32 06/10/1516:09 7439-96-5 ND ug/L 0.50 0.094 1 06/10/1511:32 06/10/1516:09 7439-98-7 0.18J ug/L 0.50 0.16 1 06/10/1511:32 06/10/1516:09 7440-02-0 102 ug/L 50.0 11.7 1 06/10/1511:32 06/10/1516:09 7440-09-7 ND ug/L 0.50 0.20 1 06/10/1511:32 06/10/1516:09 7782-49-2 1870 ug/L 50.0 16.3 1 06/10/1511:32 06/10/1516:09 7440-23-5 3.2 ug/L 0.50 0.13 1 06/10/1511:32 06/10/1516:09 7440-24-6 ND ug/L 0.10 0.015 1 06/10/1511:32 06/10/1516:09 7440-28-0 0.61J ug/L 1.0 0.28 1 06/10/1511:32 06/10/1516:09 7440-62-2 56.7 ug/L 5.0 2.4 1 06/10/1511:32 06/10/1516:09 7440-66-6 Analytical Method: EPA 7470A Preparation Method: EPA 7470A ND ug/L 0.20 0.022 1 06/10/1510:30 06/10/1515:00 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 25 of 48 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K��c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050632 Pace Project No.: 92251236 QC Batch: MERP/13678 Analysis Method: EPA 7470A QC Batch Method: EPA 7470A Analysis Description: 7470A Mercury Water Associated Lab Samples: 92251236001, 92251236002 METHOD BLANK: 1977493 Matrix: Water Associated Lab Samples: 92251236001, 92251236002 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury ug/L ND 0.20 06/01/1519:52 LABORATORY CONTROL SAMPLE: 1977494 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 5 4.8 96 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1977495 1977496 MS MSD 92251236001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 5 5 5.0 5.0 100 99 80-120 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/15/2015 01:39 PM without the written consent of Pace Analytical Services, Inc.. Page 26 of 48 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050632 Pace Project No.: 92251236 QC Batch: MERP/13814 Analysis Method: EPA 7470A QC Batch Method: EPA 7470A Analysis Description: 7470A Mercury Water Associated Lab Samples: 92251236004 METHOD BLANK: 1989756 Matrix: Water Associated Lab Samples: 92251236004 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury ug/L ND 0.20 06/10/1514:06 LABORATORY CONTROL SAMPLE: 1989757 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 5 5.0 100 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1989758 1989759 MS MSD 92253195001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 5 5 5.5 5.3 110 106 80-120 4 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/15/2015 01:39 PM without the written consent of Pace Analytical Services, Inc.. Page 27 of 48 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050632 Pace Project No.: 92251236 QC Batch: MERP/5803 Analysis Method: EPA 7471 QC Batch Method: EPA 7471 Analysis Description: 7471 Mercury Associated Lab Samples: 92251236003 METHOD BLANK: 1229879 Matrix: Solid Associated Lab Samples: 92251236003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury mg/kg ND 0.0080 06/03/1517:24 LABORATORY CONTROL SAMPLE: 1229880 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury mg/kg .082 0.081 98 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1229881 1229882 MS MSD 92251157007 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury mg/kg ND .142 .144 0.15 0.15 101 102 80-120 3 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/15/2015 01:39 PM without the written consent of Pace Analytical Services, Inc.. Page 28 of 48 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K��c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050632 Pace Project No.: 92251236 QC Batch: MPRP/24465 Analysis Method: EPA 6010 QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid Associated Lab Samples: 92251236003 METHOD BLANK: 1229847 Associated Lab Samples: 92251236003 Parameter Units Aluminum mg/kg Barium mg/kg Beryllium mg/kg Boron mg/kg Calcium mg/kg Chromium mg/kg Copper mg/kg Iron mg/kg Magnesium mg/kg Manganese mg/kg Molybdenum mg/kg Nickel mg/kg Potassium mg/kg Selenium mg/kg Sodium mg/kg Strontium mg/kg Zinc mg/kg Matrix: Solid Blank Result Reporting Limit Analyzed ND 5.0 06/03/15 23:37 ND 0.50 06/03/15 23:37 ND 0.050 06/03/15 23:37 ND 2.5 06/03/15 23:37 ND 25.0 06/03/15 23:37 ND 0.25 06/03/15 23:37 ND 0.25 06/03/15 23:37 ND 2.0 06/03/15 23:37 ND 25.0 06/03/15 23:37 ND 0.25 06/03/15 23:37 ND 0.50 06/03/15 23:37 ND 0.25 06/03/15 23:37 ND 49.9 06/03/15 23:37 ND 0.75 06/03/15 23:37 ND 49.9 06/03/15 23:37 ND 0.50 06/03/15 23:37 ND 1.0 06/03/15 23:37 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 1229848 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Aluminum mg/kg 127 112 88 80-120 Barium mg/kg 12.7 11.4 90 80-120 Beryllium mg/kg 1.3 1.1 89 80-120 Boron mg/kg 127 113 89 80-120 Calcium mg/kg 635 571 90 80-120 Chromium mg/kg 12.7 11.3 89 80-120 Copper mg/kg 12.7 11.1 88 80-120 Iron mg/kg 127 111 87 80-120 Magnesium mg/kg 635 567 89 80-120 Manganese mg/kg 12.7 11.4 89 80-120 Molybdenum mg/kg 12.7 11.1 87 80-120 Nickel mg/kg 12.7 11.4 89 80-120 Potassium mg/kg 635 557 88 80-120 Selenium mg/kg 12.7 10.6 84 80-120 Sodium mg/kg 635 572 90 80-120 Strontium mg/kg 12.7 11.1 87 80-120 Zinc mg/kg 63.5 56.0 88 80-120 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/15/2015 01:39 PM without the written consent of Pace Analytical Services, Inc.. Page 29 of 48 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K��c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050632 Pace Project No.: 92251236 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1229849 1229850 MS MSD 92251157007 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum mg/kg 1950 231 228 2290 2720 149 341 75-125 17 20 M1 Barium mg/kg 38.2 23.1 22.8 56.5 63.7 79 112 75-125 12 20 Beryllium mg/kg 0.43J 2.31 2.31 2.4 2.6 84 95 75-125 10 20 Boron mg/kg ND 231 228 202 219 85 93 75-125 8 20 Calcium mg/kg 957 1150 1140 1940 2280 85 116 75-125 16 20 Chromium mg/kg 4.3 23.1 22.8 23.4 26.3 83 97 75-125 12 20 Copper mg/kg 4.8 23.1 22.8 24.2 26.7 84 96 75-125 10 20 Iron mg/kg 2770 231 228 2360 2800 -176 15 75-125 17 20 M1 Magnesium mg/kg 160J 1150 1140 1160 1290 87 99 75-125 11 20 Manganese mg/kg 15.6 23.1 22.8 32.6 37.1 74 94 75-125 13 20 M1 Molybdenum mg/kg 4.9 23.1 22.8 23.8 25.9 82 92 75-125 8 20 Nickel mg/kg 4.4 23.1 22.8 24.6 27.3 87 100 75-125 11 20 Potassium mg/kg ND 1150 1140 1180 1280 87 98 75-125 9 20 Selenium mg/kg ND 23.1 22.8 18.4 20.5 80 90 75-125 10 20 Sodium mg/kg ND 1150 1140 1140 1160 92 95 75-125 2 20 Strontium mg/kg 29.7 23.1 22.8 48.0 56.4 79 117 75-125 16 20 Zinc mg/kg ND 115 114 101 111 85 95 75-125 9 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/15/2015 01:39 PM without the written consent of Pace Analytical Services, Inc.. Page 30 of 48 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050632 Pace Project No.: 92251236 QC Batch: MPRP/24466 Analysis Method: EPA 6020 QC Batch Method: EPA 3050 Analysis Description: 6020 MET SOLID Associated Lab Samples: 92251236003 METHOD BLANK: 1229854 Matrix: Solid Associated Lab Samples: 92251236003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Antimony mg/kg ND 0.051 06/03/1518:24 N2 Arsenic mg/kg ND 0.051 06/03/1518:24 Cadmium mg/kg ND 0.0061 06/03/1518:24 Cobalt mg/kg ND 0.051 06/03/1518:24 Lead mg/kg ND 0.051 06/03/1518:24 Thallium mg/kg ND 0.051 06/03/1518:24 Vanadium mg/kg ND 0.051 06/03/1518:24 LABORATORY CONTROL SAMPLE: Parameter 1229855 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Antimony mg/kg 2.5 2.4 93 80-120 N2 Arsenic mg/kg 2.5 2.4 95 80-120 Cadmium mg/kg .25 0.22 87 80-120 Cobalt mg/kg 2.5 2.4 94 80-120 Lead mg/kg 2.5 2.3 90 80-120 Thallium mg/kg 2.5 2.4 92 80-120 Vanadium mg/kg 2.5 2.4 93 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1229856 1229857 MS MSD 92251157007 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qua] Antimony mg/kg ND 4.45 4.63 ND ND 88 76 75-125 20 N2 Arsenic mg/kg 13.2 4.45 4.63 16.5 17.0 73 82 75-125 3 20 M6 Cadmium mg/kg ND .445 .463 ND ND 102 100 75-125 20 Cobalt mg/kg ND 4.45 4.63 6.2J 5.6J 99 82 75-125 20 Lead mg/kg ND 4.45 4.63 5.2J 4.8J 93 82 75-125 20 Thallium mg/kg ND 4.45 4.63 ND ND 64 63 75-125 20 M6 Vanadium mg/kg 4.8J 4.45 4.63 10 8AJ 114 76 75-125 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/15/2015 01:39 PM without the written consent of Pace Analytical Services, Inc.. Page 31 of 48 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K�gc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050632 Pace Project No.: 92251236 QC Batch: MPRP/54700 Analysis Method: EPA 6020A QC Batch Method: EPA 3020 Analysis Description: 6020A Water UPD4 Associated Lab Samples: 92251236001, 92251236002 METHOD BLANK: 1977698 Associated Lab Samples: 92251236001, 92251236002 Parameter Units Aluminum ug/L Antimony ug/L Arsenic ug/L Barium ug/L Beryllium ug/L Boron ug/L Cadmium ug/L Calcium ug/L Chromium ug/L Cobalt ug/L Copper ug/L Iron ug/L Lead ug/L Magnesium ug/L Manganese ug/L Molybdenum ug/L Nickel ug/L Potassium ug/L Selenium ug/L Sodium ug/L Strontium ug/L Thallium ug/L Vanadium ug/L Zinc ug/L Matrix: Water Blank Result Reporting Limit Analyzed ND 10.0 05/29/1516:47 ND 0.50 05/29/1516:47 ND 0.50 05/29/1516:47 ND 0.30 05/29/1516:47 ND 0.20 05/29/1516:47 ND 5.0 05/29/1516:47 ND 0.080 05/29/1516:47 ND 40.0 05/29/1516:47 ND 0.50 05/29/1516:47 ND 0.50 05/29/1516:47 ND 1.0 05/29/1516:47 ND 50.0 05/29/1516:47 ND 0.10 05/29/1516:47 ND 10.0 05/29/1516:47 ND 0.50 05/29/1516:47 ND 0.50 05/29/1516:47 ND 0.50 05/29/1516:47 ND 50.0 05/29/1516:47 ND 0.50 05/29/1516:47 ND 50.0 05/29/1516:47 ND 0.50 05/29/1516:47 ND 0.10 05/29/1516:47 ND 1.0 05/29/1516:47 ND 5.0 05/29/1516:47 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 1977699 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Aluminum ug/L 80 85.4 107 80-120 Antimony ug/L 80 78.9 99 80-120 Arsenic ug/L 80 79.8 100 80-120 Barium ug/L 80 79.2 99 80-120 Beryllium ug/L 80 77.9 97 80-120 Boron ug/L 80 81.4 102 80-120 Cadmium ug/L 80 81.2 102 80-120 Calcium ug/L 1000 1020 102 80-120 Chromium ug/L 80 81.9 102 80-120 Cobalt ug/L 80 79.1 99 80-120 Copper ug/L 80 82.4 103 80-120 Iron ug/L 1000 1020 102 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/15/2015 01:39 PM without the written consent of Pace Analytical Services, Inc.. Page 32 of 48 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K��c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050632 Pace Project No.: 92251236 LABORATORY CONTROL SAMPLE: 1977699 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Lead ug/L 80 77.4 97 80-120 Magnesium ug/L 1000 1030 103 80-120 Manganese ug/L 80 83.1 104 80-120 Molybdenum ug/L 80 79.8 100 80-120 Nickel ug/L 80 81.4 102 80-120 Potassium ug/L 1000 1010 101 80-120 Selenium ug/L 80 80.3 100 80-120 Sodium ug/L 1000 975 97 80-120 Strontium ug/L 80 79.5 99 80-120 Thallium ug/L 80 79.0 99 80-120 Vanadium ug/L 80 81.7 102 80-120 Zinc ug/L 80 83.0 104 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1977700 1977701 MS MSD 92251147009 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum ug/L 230 80 80 317 320 109 112 75-125 1 20 Antimony ug/L ND 80 80 80.4 80.8 100 101 75-125 0 20 Arsenic ug/L ND 80 80 81.4 81.4 102 102 75-125 0 20 Barium ug/L 3.5 80 80 83.5 83.9 100 101 75-125 0 20 Beryllium ug/L ND 80 80 80.8 79.0 101 99 75-125 2 20 Boron ug/L 39.5 80 80 84.1 84.4 56 56 75-125 0 20 M1 Cadmium ug/L ND 80 80 83.0 82.3 104 103 75-125 1 20 Calcium ug/L 229 1000 1000 1270 1250 104 102 75-125 2 20 Chromium ug/L ND 80 80 82.0 83.4 102 104 75-125 2 20 Cobalt ug/L ND 80 80 80.4 80.6 100 101 75-125 0 20 Copper ug/L 2.1 80 80 85.6 85.8 104 105 75-125 0 20 Iron ug/L 138 1000 1000 1160 1170 102 104 75-125 1 20 Lead ug/L 0.37 80 80 80.3 80.0 100 99 75-125 0 20 Magnesium ug/L 20.5 1000 1000 1070 1070 105 105 75-125 0 20 Manganese ug/L 15.1 80 80 98.9 99.4 105 105 75-125 0 20 Molybdenum ug/L ND 80 80 80.9 81.7 101 102 75-125 1 20 Nickel ug/L ND 80 80 81.5 82.9 101 103 75-125 2 20 Potassium ug/L 51.5 1000 1000 1070 1070 101 102 75-125 1 20 Selenium ug/L ND 80 80 82.2 78.4 103 98 75-125 5 20 Sodium ug/L ND 1000 1000 1020 1000 98 96 75-125 1 20 Strontium ug/L 2.2 80 80 82.7 82.9 101 101 75-125 0 20 Thallium ug/L ND 80 80 83.8 83.8 105 105 75-125 0 20 Vanadium ug/L ND 80 80 82.6 83.3 103 104 75-125 1 20 Zinc ug/L ND 80 80 84.0 88.6 100 106 75-125 5 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/15/2015 01:39 PM without the written consent of Pace Analytical Services, Inc.. Page 33 of 48 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050632 Pace Project No.: 92251236 QC Batch: MPRP/55041 Analysis Method: EPA 6020A QC Batch Method: EPA 3020 Analysis Description: 6020A Water UPD4 Associated Lab Samples: 92251236004 METHOD BLANK: 1989137 Associated Lab Samples: 92251236004 Parameter Units Matrix: Blank Result Water Reporting Limit Analyzed Qualifiers Aluminum ug/L ND 10.0 06/10/1515:28 Antimony ug/L ND 0.50 06/10/1515:28 Arsenic ug/L ND 0.50 06/10/1515:28 Barium ug/L ND 0.30 06/10/1515:28 Beryllium ug/L ND 0.20 06/10/1515:28 Boron ug/L ND 5.0 06/10/1515:28 Cadmium ug/L ND 0.080 06/10/1515:28 Calcium ug/L ND 40.0 06/10/1515:28 Chromium ug/L ND 0.50 06/10/1515:28 Cobalt ug/L ND 0.50 06/10/1515:28 Copper ug/L ND 1.0 06/10/1515:28 Iron ug/L ND 50.0 06/10/1515:28 Lead ug/L ND 0.10 06/10/1515:28 Magnesium ug/L ND 10.0 06/10/1515:28 Manganese ug/L ND 0.50 06/10/1515:28 Molybdenum ug/L 0.13J 0.50 06/10/1515:28 Nickel ug/L ND 0.50 06/10/1515:28 Potassium ug/L ND 50.0 06/10/1515:28 Selenium ug/L ND 0.50 06/10/1515:28 Sodium ug/L ND 50.0 06/10/1515:28 Strontium ug/L ND 0.50 06/10/1515:28 Thallium ug/L ND 0.10 06/10/1515:28 Vanadium ug/L ND 1.0 06/10/1515:28 Zinc ug/L ND 5.0 06/10/1515:28 LABORATORY CONTROL SAMPLE: Parameter 1989138 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Aluminum ug/L 80 76.9 96 80-120 Antimony ug/L 80 77.3 97 80-120 Arsenic ug/L 80 78.2 98 80-120 Barium ug/L 80 81.9 102 80-120 Beryllium ug/L 80 81.7 102 80-120 Boron ug/L 80 79.6 99 80-120 Cadmium ug/L 80 79.1 99 80-120 Calcium ug/L 1000 985 98 80-120 Chromium ug/L 80 79.9 100 80-120 Cobalt ug/L 80 84.7 106 80-120 Copper ug/L 80 81.5 102 80-120 Iron ug/L 1000 1040 104 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/15/2015 01:39 PM without the written consent of Pace Analytical Services, Inc.. Page 34 of 48 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 1inic&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050632 Pace Project No.: 92251236 LABORATORY CONTROL SAMPLE: 1989138 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Lead ug/L 80 79.9 100 80-120 Magnesium ug/L 1000 989 99 80-120 Manganese ug/L 80 75.8 95 80-120 Molybdenum ug/L 80 77.7 97 80-120 Nickel ug/L 80 79.3 99 80-120 Potassium ug/L 1000 932 93 80-120 Selenium ug/L 80 78.9 99 80-120 Sodium ug/L 1000 1030 103 80-120 Strontium ug/L 80 76.1 95 80-120 Thallium ug/L 80 84.7 106 80-120 Vanadium ug/L 80 77.6 97 80-120 Zinc ug/L 80 81.3 102 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1989780 1989781 MS MSD 92253352007 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum ug/L 37.2 80 80 146 145 136 135 75-125 1 20 M1 Antimony ug/L ND 80 80 78.6 78.8 98 98 75-125 0 20 Arsenic ug/L ND 80 80 81.5 81.7 102 102 75-125 0 20 Barium ug/L 0.67 80 80 77.2 78.9 96 98 75-125 2 20 Beryllium ug/L ND 80 80 83.8 82.9 105 104 75-125 1 20 Boron ug/L 1AJ 80 80 76.5 80.3 94 99 75-125 5 20 Cadmium ug/L ND 80 80 78.8 81.1 99 101 75-125 3 20 Calcium ug/L 162 1000 1000 1100 1200 94 104 75-125 8 20 Chromium ug/L 0.33J 80 80 78.7 81.2 98 101 75-125 3 20 Cobalt ug/L ND 80 80 79.0 79.9 99 100 75-125 1 20 Copper ug/L 0.951 80 80 82.2 83.6 102 103 75-125 2 20 Iron ug/L 61.6 1000 1000 1130 1170 107 111 75-125 3 20 Lead ug/L 0.10 80 80 78.4 79.9 98 100 75-125 2 20 Magnesium ug/L 28.0 1000 1000 1010 1030 98 100 75-125 2 20 Manganese ug/L 1.9 80 80 76.6 79.4 93 97 75-125 4 20 Molybdenum ug/L 0.0951 80 80 78.6 78.9 98 99 75-125 0 20 Nickel ug/L 0.17J 80 80 79.8 80.3 100 100 75-125 1 20 Potassium ug/L 22.2J 1000 1000 1010 1030 99 100 75-125 1 20 Selenium ug/L ND 80 80 83.2 82.2 104 103 75-125 1 20 Sodium ug/L 48.7J 1000 1000 940 955 89 91 75-125 2 20 Strontium ug/L 0.94 80 80 77.4 78.9 96 97 75-125 2 20 Thallium ug/L ND 80 80 84.1 85.3 105 107 75-125 1 20 Vanadium ug/L ND 80 80 76.5 78.9 95 98 75-125 3 20 Zinc ug/L 8.1 80 80 89.3 88.9 102 101 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/15/2015 01:39 PM without the written consent of Pace Analytical Services, Inc.. Page 35 of 48 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050632 Pace Project No.: 92251236 QC Batch: PMST/3618 Analysis Method: ASTM D2974-87 QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture Associated Lab Samples: 92251236003 SAMPLE DUPLICATE: 1233279 92250709001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 16.0 15.4 4 10 SAMPLE DUPLICATE: 1233280 92250709013 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 27.6 26.5 4 10 SAMPLE DUPLICATE: 1233281 35190598001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 23.7 3 10 SAMPLE DUPLICATE: 1233282 35190619004 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 4.2 4.1 2 10 SAMPLE DUPLICATE: 1233283 35191337002 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 3.8 4.4 15 10 D6 SAMPLE DUPLICATE: 1233284 35191350005 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 24.2 18.4 27 10 D6 SAMPLE DUPLICATE: 1233285 35191350014 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 12.1 13.3 9 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/15/2015 01:39 PM without the written consent of Pace Analytical Services, Inc.. Page 36 of 48 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050632 Pace Project No.: 92251236 QC Batch: WET/37801 Analysis Method: EPA 9045 QC Batch Method: EPA 9045 Analysis Description: 9045 pH Associated Lab Samples: 92251236003 SAMPLE DUPLICATE: 1472050 Parameter pH at 25 Degrees C SAMPLE DUPLICATE: 1472051 Parameter pH at 25 Degrees C 92251251005 Dup Max Units Result Result RPD RPD Qualifiers Std. Units 6.8 6.9 2 10 H3 92251242018 Dup Max Units Result Result RPD RPD Qualifiers Std. Units 5.5 5.5 1 10 H3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/15/2015 01:39 PM without the written consent of Pace Analytical Services, Inc.. Page 37 of 48 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Iic&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050632 Pace Project No.: 92251236 QC Batch: WETA/23222 Analysis Method: EPA 300.0 QC Batch Method: EPA 300.0 Analysis Description: 300.0 IC Anions Associated Lab Samples: 92251236003 METHOD BLANK: 1479817 Matrix: Water Associated Lab Samples: 92251236003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Sulfate mg/L 3.2 2.0 06/09/15 22:29 LABORATORY CONTROL SAMPLE: 1479818 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfate mg/L 20 19.1 96 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1479819 1479820 MS MSD 92251132016 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfate mg/L 8.0 31.9 31.9 38.7 37.8 96 93 2 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/15/2015 01:39 PM without the written consent of Pace Analytical Services, Inc.. Page 38 of 48 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050632 Pace Project No.: 92251236 QC Batch: WETA/23223 Analysis Method: EPA 353.2 QC Batch Method: EPA 353.2 Analysis Description: 353.2 Nitrate + Nitrite, Unpres. Associated Lab Samples: 92251236003 METHOD BLANK: 1480060 Matrix: Water Associated Lab Samples: 92251236003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, Nitrate mg/L 0.18 0.020 06/09/15 17:32 Z2 LABORATORY CONTROL SAMPLE: 1480061 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Nitrate mg/L 2.5 2.4 96 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1480062 1480063 MS MSD 92250709003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Nitrate mg/L ND 3.6 3.6 3.6 3.6 93 93 90-110 0 10 H1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1480064 1480065 MS MSD 92250709005 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Nitrate mg/L ND 3.5 3.5 3.4 3.4 92 92 90-110 0 10 H1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/15/2015 01:39 PM without the written consent of Pace Analytical Services, Inc.. Page 39 of 48 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050632 Pace Project No.: 92251236 QC Batch: WETA/23153 Analysis Method: SM 4500-CI-E QC Batch Method: SM 4500-CI-E Analysis Description: 4500 Chloride Associated Lab Samples: 92251236003 METHOD BLANK: 1474736 Matrix: Water Associated Lab Samples: 92251236003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/L ND 1.0 06/06/15 07:23 LABORATORY CONTROL SAMPLE: 1474737 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloride mg/L 20 19.9 100 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1474738 1474739 MS MSD 92250515002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride mg/L ND 23.8 23.8 24.3 24.2 92 92 90-110 0 10 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1474762 1474763 MS MSD 92250709003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride mg/L ND 28.8 28.8 27.1 26.9 91 90 90-110 1 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/15/2015 01:39 PM without the written consent of Pace Analytical Services, Inc.. Page 40 of 48 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Iic&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050632 Pace Project No.: 92251236 QC Batch: WETA/46803 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92251236003 METHOD BLANK: 1226976 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/kg ND 49.5 05/29/15 06:56 Sulfate mg/kg ND 49.5 05/29/15 06:56 LABORATORY CONTROL SAMPLE: 1226977 Parameter Units Chloride mg/kg Sulfate mg/kg MATRIX SPIKE SAMPLE: 1226979 Parameter Units Chloride mg/kg Sulfate mg/kg SAMPLE DUPLICATE: 1226978 Parameter Chloride Sulfate Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 499 489 98 80-120 499 478 96 80-120 92251251005 Spike MS MS % Rec Result Conc. Result % Rec Limits Qualifiers ND 526 474 90 80-120 H1 ND 526 508 84 80-120 H1 92251251005 Dup Units Result Result mg/kg ND ND mg/kg ND ND Max RPD RPD Qualifiers 20 H1 20 H1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/15/2015 01:39 PM without the written consent of Pace Analytical Services, Inc.. Page 41 of 48 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Iigc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050632 Pace Project No.: 92251236 QC Batch: WETA/46804 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92251236003 METHOD BLANK: 1226986 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrate as N mg/kg ND 5.0 05/29/15 06:56 LABORATORY CONTROL SAMPLE: 1226987 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg 49.9 48.4 97 80-120 MATRIX SPIKE SAMPLE: 1226989 92251251005 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg ND 52.6 48.1 92 80-120 H3 SAMPLE DUPLICATE: 1226988 92251251005 Dup Max Parameter Units Result Result RPD RPD Qualifiers Nitrate as N mg/kg ND ND 20 H3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/15/2015 01:39 PM without the written consent of Pace Analytical Services, Inc.. Page 42 of 48 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050632 Pace Project No.: 92251236 QC Batch: WETA/28987 Analysis Method: EPA 9060 QC Batch Method: EPA 9060 Analysis Description: 9060 TOC Average Associated Lab Samples: 92251236003 METHOD BLANK: 1173951 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mean Total Organic Carbon mg/kg ND 600 06/12/15 08:04 LABORATORY CONTROL SAMPLE: 1173952 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mean Total Organic Carbon mg/kg 120000 105000 87 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1173953 1173954 MS MSD 92251236003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg ND 7920 7920 6890 7800 83 95 50-150 12 30 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1173955 1173956 MS MSD 92251877001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg 772J 7830 7800 7660 7620 88 88 50-150 1 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/15/2015 01:39 PM without the written consent of Pace Analytical Services, Inc.. Page 43 of 48 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: J15050632 Pace Project No.: 92251236 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TN -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-G Pace Analytical Services - Green Bay PASI-M Pace Analytical Services - Minneapolis PASI-O Pace Analytical Services - Ormond Beach BATCH QUALIFIERS Batch: ICP/14943 Ill Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. Batch: ICPM/9902 III Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. ANALYTE QUALIFIERS B Analyte was detected in the associated method blank. D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. D6 The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits. H1 Analysis conducted outside the EPA method holding time. H3 Sample was received or analysis requested beyond the recognized method holding time. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/15/2015 01:39 PM without the written consent of Pace Analytical Services, Inc.. Page 44 of 48 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 1j nl c&fie. Suite 100 Huntersville, INC 28078 (704)875-9092 QUALIFIERS Project: J15050632 Pace Project No.: 92251236 ANALYTE QUALIFIERS M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. N2 The lab does not hold TIN accreditation for this parameter. Z2 Analyte present in the associated method blank above the detection limit. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/15/2015 01:39 PM without the written consent of Pace Analytical Services, Inc.. Page 45 of 48 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: J15050632 Pace Project No.: 92251236 Lab ID Sample ID QC Batch Method QC Batch Analytical Method 92251236003 2015015770 EPA 3050 MPRP/24465 EPA 6010 92251236003 2015015770 EPA 3050 MPRP/24466 EPA 6020 92251236001 2015015768 EPA 3020 MPRP/54700 EPA 6020A 92251236002 2015015769 EPA 3020 MPRP/54700 EPA 6020A 92251236004 2015015770 SPLP EPA 3020 MPRP/55041 EPA 6020A 92251236001 2015015768 EPA 7470A MERP/13678 EPA 7470A 92251236002 2015015769 EPA 7470A MERP/13678 EPA 7470A 92251236004 2015015770 SPLP EPA 7470A MERP/13814 EPA 7470A 92251236003 2015015770 EPA 7471 MERP/5803 EPA 7471 92251236003 2015015770 ASTM D2974-87 PMST/3618 92251236003 2015015770 EPA 9045 WET/37801 92251236003 2015015770 EPA 300.0 WETA/23222 92251236003 2015015770 EPA 353.2 WETA/23223 92251236003 2015015770 SM 4500-CI-E WETA/23153 92251236003 2015015770 EPA 9056 WETA/46803 92251236003 2015015770 EPA 9056 WETA/46804 92251236003 2015015770 EPA 9060 WETA/28987 92251236003 2015015770 EPA 9060 WETA/28988 Date: 06/15/2015 01:39 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Analytical Batch ICP/14943 ICPM/9902 ICPM/24507 ICPM/24507 ICPM/24738 MERC/15926 MERC/15926 MERC/16086 MERC/5790 Page 46 of 48 �-Illcekla[Xical- I le Condition Upon Recei Document Number: F-CHR•CS-003-rev.16 Page 1 of 2* Issuing Authority: Pace Huntersville Quality ct+5 Client Name: iUt Page 2 of 2 is for Internal Use Only Courier: ❑ Fed Ex ElUPS❑ USPS❑ Client❑ ommercial❑ (ace Other Custody Seal on Cooler/Box Present; ❑ yes U no Seals intact: ❑ yes ❑ no Packing Material: ❑ Bubble VDp ❑ Bubble Bags ❑ None ❑ Other g, Thermometer Used: IR Gun T1401 Type of Ice: (W- et 1 Blue None qi amples on ice, cooling process has begun Temp Correction Factor T1401 No Correction —1-11 Corrected Cooler Temp.: r`� ° 0 °C Temp should be above freezing to 6°C Biological Tissue is Frozen: Yes Comments: NO NIA, Date and Initl is 3 p�rson��min pg contents: ) Chaih of Custody Present: Yes ❑No 0N1A 1. Chain of Custody Filled Out: Z ©No ❑NIA 2. Chain of Custody Relinquished: ®es No ❑NIA 3. Sampler Name & Signature on COC: "es ONo ❑NIA 4. Samples Arrived within Hold Time: es ❑No ❑NIA 5. Short Hold Time Analysis (<72hr): ❑Yes Pflo ❑NIA 6. Rush Turn Around Time Requested: ❑Yes o ❑NIA 7. Sufficient Volume: 9 es ONO ❑NIA $, Correct Containers Used: -Pace Containers Used: YeS/10No Qa ! ❑No ❑NIA ❑NIA 9. Containers Intact: V es ONO ❑NIA 10. Filtered volume received for Dissolved tests Oyes ONO �rA 11, Sample Labels match COC: -includes date/time/ID/Analysis Matrix: eves ONO ❑NIA 12. All containers needing preservation have been checked. All containers needing preservation are found to be in compliance with EPA recommendation. exceptions: VOA, coliform, TOC, O&G, 4VI-DRO (water) es G3Yes ❑Yes ❑No ONO ONO El NIA El NIA 13. Samples checked for dechlorination: lives ONO ❑NIA 14. Headspace in VOA Vials( >6mm): ❑Yes ❑No ANIA 15. Trip Blank Present: Trip Blank Custody Seals Present Pace Trip -Blank Lot # (if purchased): - ❑Yes ❑Yes ONO ONO T&A NIA 16. Client Notification/ Resolution: Field Data Required? Y 1 N Person Contacted: Date/Time: Comments/ Resolution: SCURF Review: Date: 15[�GtS SRF Review: L4 Date: ZLe G Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (Le out of hold, incorrect preservative, out of temp, incorrect containers) WOq:92251236 1111111111111111111111 92251236 Page 47 of 48 w o j p a Customer to complete appropriate columns to right m n a v (b�y o � m n I r Imo] n (b 0 0 1 J l i I I I c Q �� g 7 9 a I I� M, I I'{� N 9 I � 'u ^ n �I l ( °c a a IV 7 n' 0 D o a Guslomnr must Canialele a a O N o ut� Ai; wrD iYa't u? c rb ucr r (A C a 9 n ff � I I ! "Coma. ��A� leGrata Roo Total Metals , Anio pH ' t - 8 oz jar (PACE) %% Sp r /C/,S r l TOC 1 - 4 oz jar I i (PACE) i i f SPLP - Total Metals and Anions 1 2 - 8 oz jars (PACE) Sediment specific tests 2 - 8 oz jar (ACCESS R I ? I ANALYTICAL) d0Total k of Containers w ea 4of5 R c M % J6..�� M Oo C a 3 G� Y v no I I 1 a a > t N 1 � N H i r„Wamrr N 0 m O?-i d o $�°moo Sr 0 I re�3 u e � I�Nn�m Q lip n -n j i ------------- r 4 _ i j 0 n g iX n I Pmf rn 3e Y j47 j � i 1 0 I 00 N I la N 1 m �> a n tsa S n 3 I� z = 2 ± 3 r n, r I n rj� Fri 4 N i al m u � a Q 01-1 pAp L5 � •Gj-n iv 5 n r' i II m j 5 ( I I i i � z r N 1 'x Z rl 00 QC)° ro o — > 5 n'I z> v Page 48 of 48 0 _ _ _ _ CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM 1 1 _._. Analyticmi Lahorat�oFy SurAcetT 'i i - - - P - - _._.-.---._._._llnalp ical Labo�rato _ Ube- -- i i 1i 1. r� iy wler� L ac� 93;�39 Ne€pre Fiel'y Rd I i_3 oi- � 'f 6rm M M min9 From �. Irs 4/ 1 j3: Hxm*oreNIW. N. Q `29M I I��'99� "[sage S Teme .. '? 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