NC0038377_J15050409 Report_20150902

+ DUKE Analytical Laboratory 1 of43
ENERGY
Order Number:
Project Name:
Customer Name(s):
Customer Address:
Lab Contact:
Report Authorized By:
(Signature)
Program Comments:
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone:[phone] Fax:[phone]
Order Summary Report
J15050409
MAYO STEAM - AB GW ASSESSMENT SOIL
Tim Hunsucker, Jerry Wylie, Kathy Webb, John Toepfer
Margaret Galvin -Karr Phone: [phone]
MXG.06.30 8:1 :5
R Y, 2015.06.3008:10:54-04'00' Date:
Margaret Galvin -Karr
Please contact the Program Manager (Margaret Galvin -Karr) with any questions regarding this report.
Data Flags & Calculations:
6/30/2015
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Sample ID's & Descriptions:
Sample ID Plant/Station
2015014671 MAYO STEAM
2015014672 MAYO STEAM
2 Total Samples
Collection
Date and Time Collected By
09-May-15 2:16 PM
09-May-15 2:30 PM
Erin Black
Erin Black
2 of 43
Sample Description
MW-15-EB
MW-15(05.-1.0)

3 of 43
Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals Yes No
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits. ❑ Yes❑ No
All laboratory QA/QC requirements are acceptable.❑ Yes ❑ No
Report Sections Included:
U Job Summary Report
❑ Sample Identification
n Technical Validation of Data Package
❑ Analytical Laboratory Certificate of Analysis
❑ Analytical Laboratory QC Report
Sub -contracted Laboratory Results
❑ Customer Specific Data Sheets, Reports, & Documentation
❑ Customer Database Entries
66 Chain of Custody
[I/0] Electronic Data Deliverable (EDD) Sent Separately
Reviewed By: Margaret Galvin -Karr Date: 6/30/2015

Certificate of Laboratory Analysis 4of43
This report shall not be reproduced, except in full.
Order # J15050409
Site: MW-15-EB
Collection Date: 09-May-15 2:16 PM
Analyte Result Units Qualifiers RDL DF
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Sample #: 2015014671
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15050409
Site: MW-15(05.-1.0)
Collection Date: 09-May-15 2:30 PM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
-- Additional Information --
Mercury in EB run out of hold time. MG-K 6/30/2015
5 of 43
Sample #: 2015014672
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kig%y4ftie. Suite 100
Huntersville, INC 28078
[phone]
June 29, 2015
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg.7405 MG30A2
Huntersville, NC 28078
RE: Project: J 15050409
Pace Project No.: 92250201
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on May 15, 2015. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TN standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc: Marge Galvin -Karr, Duke Energy
Program Manager, Duke Energy
Mary Ann Ogle, Duke Energy
Rodney Wilke, Duke Energy
p«FO
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
lqe� ��� without the written consent of Pace Analytical Services, Inc..
BRAT,
Page 1 of 37

lacmnalyfica(
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kir cwhe. Suite 100
Huntersville, NC 28078
[phone]
Project: J15050409
Pace Project No.: 92250201
Minnesota Certification IDs
1700 Elm Street SE Suite 200, Minneapolis, MN 55414
A21-A Certification #: 2926.01
Alaska Certification #: UST-078
Alaska Certification #MN00064
Alabama Certification #40770
Arizona Certification #: AZ-0014
Arkansas Certification #: 88-0680
California Certification #: 01155CA
Colorado Certification #Pace
Connecticut Certification #: PH-0256
EPA Region 8 Certification #: 8TMS-L
Florida/NELAP Certification #: E87605
Guam Certification #:14-008r
Georgia Certification #: 959
Georgia EPD #: Pace
Idaho Certification #: MN00064
Hawaii Certification #MN00064
Illinois Certification #: 200011
Indiana Certification#C-MN-01
Iowa Certification #: 368
Kansas Certification #: E-10167
Kentucky Dept of Envi. Protection - DW #90062
Kentucky Dept of Envi. Protection - WW #:90062
Louisiana DEQ Certification #: 3086
Louisiana DHH #: LA140001
Maine Certification #: 2013011
Maryland Certification #: 322
Michigan DEPH Certification #: 9909
Ormond Beach Certification IDs
8 East Tower Circle, Ormond Beach, FL 32174
Alabama Certification #: 41320
Connecticut Certification #: PH-0216
Delaware Certification: FL NELAC Reciprocity
Florida Certification #: E83079
Georgia Certification #: 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification #: 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383
Kentucky Certification #: 90050
Louisiana Certification #: FL NELAC Reciprocity
Louisiana Environmental Certificate #: 05007
Maryland Certification: #346
Massachusetts Certification #: M-FL1264
Michigan Certification #: 9911
Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236
Green Bay Certification IDs
1241 Bellevue Street, Green Bay, WI 54302
Florida/NELAP Certification #: E87948
Illinois Certification #: 200050
Kentucky Certification #: 82
Louisiana Certification #: 04168
Minnesota Certification #: 055-999-334
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
CERTIFICATIONS
Minnesota Certification #: 027-053-137
Mississippi Certification #: Pace
Montana Certification #: MT0092
Nevada Certification #: MN_00064
Nebraska Certification #: Pace
New Jersey Certification #: MN-002
New York Certification #: 11647
North Carolina Certification #: 530
North Carolina State Public Health #: 27700
North Dakota Certification #: R-036
Ohio EPA#: 4150
Ohio VAP Certification #: CL101
Oklahoma Certification #: 9507
Oregon Certification #: MN200001
Oregon Certification #: MN300001
Pennsylvania Certification #: 68-00563
Puerto Rico Certification
Saipan (CNMI) #:MP0003
South Carolina #:74003001
Texas Certification #: T104704192
Tennessee Certification #: 02818
Utah Certification #: MN000642013-4
Virginia DGS Certification #: 251
Virginia/VELAP Certification #: Pace
Washington Certification #: C486
West Virginia Certification #: 382
West Virginia DHHR #:9952C
Wisconsin Certification #: 999407970
Montana Certification #: Cert 0074
Nebraska Certification: NE-OS-28-14
Nevada Certification: FL NELAC Reciprocity
New Hampshire Certification #: 2958
New Jersey Certification #: FL765
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FLO1264
South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
Washington Certification #: C955
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
North Dakota Certification #: R-150
South Carolina Certification #: 83006001
Texas Certification #: T104704529-14-1
US Dept of Agriculture #: S-76505
Wisconsin Certification #: 405132750
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 2 of 37

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kig%y4fte. Suite 100
Huntersville, NC 28078
[phone]
Project: J15050409
Pace Project No.: 92250201
Asheville Certification IDs
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
CERTIFICATIONS
West Virginia Certification #: 356
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 3 of 37

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kig%y4ftie. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE SUMMARY
Project: J15050409
Pace Project No.: 92250201
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92250201001
92250201002
2015014671
2015014672
Water
Solid
05/09/1514:16
05/09/1514:30
05/15/1513:00
05/15/1513:00
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 4 of 37

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 ffli698f4ft" Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
J15050409
92250201
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92250201001
2015014671
EPA 6020A
RJS
24
PASI-M
EPA 7470A
LMW
1
PASI-M
92250201002
2015014672
EPA 6010
CKJ
16
PASI-0
EPA 6020
DRS
8
PASI-O
EPA 7471
CKJ
1
PASI-O
ASTM D2974-87
MLO
1
PASI-O
EPA 9045
MLS
1
PASI-A
EPA 9056
AIS
2
PASI-O
EPA 9056
AIS
1
PASI-O
EPA 9060
TJJ
6
PASI-G
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 5 of 37

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 ffiini c&fie. Suite 100
Huntersville, NC 28078
[phone]
SUMMARY OF DETECTION
Project:
Pace Project No.:
J15050409
92250201
Lab Sample ID
Client Sample ID
Method
Parameters
Result
Units
Report Limit
Analyzed Qualifiers
92250201001
2015014671
EPA 6020A
Chromium
0.47J
ug/L
0.50
06/26/15 11:46
EPA 6020A
Nickel
0.20J
ug/L
0.50
06/26/15 11:46
92250201002
2015014672
EPA 6010
Aluminum
8440
mg/kg
30.9
05/27/15 21:55
EPA 6010
Barium
64.6
mg/kg
3.1
05/27/15 21:55
EPA 6010
Beryllium
0.24J
mg/kg
0.31
05/27/15 21:55
EPA 6010
Calcium
451
mg/kg
155
05/27/15 21:55
EPA 6010
Chromium
10.4
mg/kg
1.5
05/27/15 21:55
EPA 6010
Copper
12.5
mg/kg
1.5
05/27/15 21:55
EPA 6010
Iron
15600
mg/kg
12.4
05/27/15 21:55
EPA 6010
Magnesium
3760
mg/kg
155
05/27/15 21:55
EPA 6010
Manganese
108
mg/kg
1.5
05/27/15 21:55
EPA 6010
Nickel
1.3J
mg/kg
1.5
05/27/15 21:55
EPA 6010
Potassium
1370
mg/kg
309
05/27/15 21:55
EPA 6010
Strontium
11.2
mg/kg
3.1
05/27/15 21:55
EPA 6010
Zinc
18.9
mg/kg
6.2
05/27/15 21:55
EPA 6020
Cobalt
3.9J
mg/kg
6.2
05/27/15 17:24
EPA 6020
Lead
4.7J
mg/kg
6.2
05/27/15 17:24
EPA 6020
Vanadium
27.1
mg/kg
6.2
05/27/15 17:24
EPA 7471
Mercury
0.0056J
mg/kg
0.010
05/26/15 20:45
ASTM D2974-87
Percent Moisture
19.4
%
0.10
06/02/15 10:59
EPA 9045
pH at 25 Degrees C
5.2
Std. Units
0.10
05/27/15 11:20
EPA 9060
Total Organic Carbon
1210
mg/kg
740
06/02/15 15:56
EPA 9060
Total Organic Carbon
1710
mg/kg
747
06/02/15 16:02
EPA 9060
Total Organic Carbon
1460
mg/kg
745
06/02/15 16:07
EPA 9060
Total Organic Carbon
2900
mg/kg
738
06/02/15 16:13
EPA 9060
Mean Total Organic Carbon
1820
mg/kg
742
06/02/15 15:56
EPA 9060
RSD%
41.2
%
06/02/15 15:56 1g
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 6 of 37

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 ffli298 W' Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15050409
Pace Project No.: 92250201
Method: EPA 6010
Description: 6010 MET ICP
Client: Duke Energy
Date: June 29, 2015
General Information:
1 sample was analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below or on the
chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 3050 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
QC Batch: MPRP/24322
CH: The continuing calibration for this compound is outside of Pace Analytical acceptance limits. The results may be biased high.
• BLANK (Lab ID: 1223174)
• Sodium
• LCS (Lab ID: 1223175)
• Sodium
• MS (Lab ID: 1223176)
• Sodium
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: MPRP/24322
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92250205001
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1223176)
• Aluminum
• Barium
• Calcium
• Copper
• Iron
• Magnesium
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 7 of 37

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 ffli998 W' Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15050409
Pace Project No.: 92250201
Method: EPA 6010
Description: 6010 MET ICP
Client: Duke Energy
Date: June 29, 2015
QC Batch: MPRP/24322
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92250205001
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• Manganese
• Potassium
• Strontium
• MSD (Lab ID: 1223177)
• Aluminum
• Barium
• Calcium
• Copper
• Iron
• Magnesium
• Manganese
• Potassium
• Strontium
R1: RPD value was outside control limits.
• MSD (Lab ID: 1223177)
• Calcium
Additional Comments:
Batch Comments:
Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
• QC Batch: ICP / 14866
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 8 of 37

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 ffli4c8f4W' Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15050409
Pace Project No.: 92250201
Method: EPA 6020
Description: 6020 MET ICPMS
Client: Duke Energy
Date: June 29, 2015
General Information:
1 sample was analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below or on the
chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 3050 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: MPRP/24323
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92250205001
M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
• MS (Lab ID: 1223180)
• Antimony
• Cobalt
• Vanadium
• MSD (Lab ID: 1223181)
• Antimony
• Arsenic
• Cobalt
• Lead
• Selenium
• Vanadium
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 9 of 37

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 ffli998f4ft" Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15050409
Pace Project No.: 92250201
Method: EPA 6020
Description: 6020 MET ICPMS
Client: Duke Energy
Date: June 29, 2015
Analyte Comments:
QC Batch: MPRP/24323
N2: The lab does not hold TNI accreditation for this parameter.
•2015014672 (Lab ID:92250201002)
• Antimony
• BLANK (Lab ID: 1223178)
• Antimony
• LCS (Lab ID: 1223179)
• Antimony
• MS (Lab ID: 1223180)
• Antimony
• MSD (Lab ID: 1223181)
• Antimony
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 10 of 37

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 ffli 98f4ft" Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15050409
Pace Project No.: 92250201
Method: EPA 6020A
Description: 6020A MET ICPMS
Client: Duke Energy
Date: June 29, 2015
General Information:
1 sample was analyzed for EPA 6020A. All samples were received in acceptable condition with any exceptions noted below or on the
chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 3020 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: MPRP/55423
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92254832007
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 2002625)
• Aluminum
• MSD (Lab ID: 2002626)
• Aluminum
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 11 of 37

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 ffli998f4ft" Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15050409
Pace Project No.: 92250201
Method: EPA 7470A
Description: 7470A Mercury
Client: Duke Energy
Date: June 29, 2015
General Information:
1 sample was analyzed for EPA 7470A. All samples were received in acceptable condition with any exceptions noted below or on the
chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
1­13: Sample was received or analysis requested beyond the recognized method holding time.
•2015014671 (Lab ID:92250201001)
Sample Preparation:
The samples were prepared in accordance with EPA 7470A with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 12 of 37

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 ffli 98f4ft" Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15050409
Pace Project No.: 92250201
Method: EPA 7471
Description: 7471 Mercury
Client: Duke Energy
Date: June 29, 2015
General Information:
1 sample was analyzed for EPA 7471. All samples were received in acceptable condition with any exceptions noted below or on the
chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 7471 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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PROJECT NARRATIVE
Project: J15050409
Pace Project No.: 92250201
Method: EPA 9045
Description: 9045 pH Soil
Client: Duke Energy
Date: June 29, 2015
General Information:
1 sample was analyzed for EPA 9045. All samples were received in acceptable condition with any exceptions noted below or on the
chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
QC Batch: WET/37661
D6: The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits.
• DUP (Lab ID: 1467400)
• pH at 25 Degrees C
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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PROJECT NARRATIVE
Project: J15050409
Pace Project No.: 92250201
Method: EPA 9056
Description: 9056 IC Anions
Client: Duke Energy
Date: June 29, 2015
General Information:
1 sample was analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below or on the
chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
Analyte Comments:
QC Batch: WETA/46586
D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
•2015014672 (Lab ID:92250201002)
• Chloride
• Sulfate
REPORT OF LABORATORY ANALYSIS
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[phone]
PROJECT NARRATIVE
Project: J15050409
Pace Project No.: 92250201
Method: EPA 9056
Description: 9056 IC Anions 48hr
Client: Duke Energy
Date: June 29, 2015
General Information:
1 sample was analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below or on the
chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
1­13: Sample was received or analysis requested beyond the recognized method holding time.
•2015014672 (Lab ID:92250201002)
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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PROJECT NARRATIVE
Project: J15050409
Pace Project No.: 92250201
Method: EPA 9060
Description: Total Organic Carbon Quad
Client: Duke Energy
Date: June 29, 2015
General Information:
1 sample was analyzed for EPA 9060. All samples were received in acceptable condition with any exceptions noted below or on the
chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
Analyte Comments:
QC Batch: WETA/28762
1g: % RSD > 40
•2015014672 (Lab ID:92250201002)
• RSD%
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: J15050409
Pace Project No.: 92250201
Sample: 2015014671 Lab ID: 92250201001 Collected: 05/09/15 14:16 Received: 05/15/15 13:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
;I➢ZI7c\�i,I=11 l[99�� 6?
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Sodium
Strontium
Thallium
Vanadium
Zinc
7470A Mercury
Mercury
Date: 06/29/2015 03:48 PM
Analytical Method: EPA 6020A Preparation Method: EPA 3020
ND
ug/L
10.0
3.0
1
06/23/15 06:46
06/26/15 11:46
7429-90-5
ND
ug/L
0.50
0.15
1
06/23/15 06:46
06/26/15 11:46
7440-36-0
ND
ug/L
0.50
0.11
1
06/23/15 06:46
06/26/15 11:46
7440-38-2
ND
ug/L
0.30
0.081
1
06/23/15 06:46
06/26/15 11:46
7440-39-3
ND
ug/L
0.20
0.067
1
06/23/15 06:46
06/26/15 11:46
7440-41-7
ND
ug/L
5.0
1.1
1
06/23/15 06:46
06/26/15 11:46
7440-42-8
ND
ug/L
0.080
0.024
1
06/23/15 06:46
06/26/15 11:46
7440-43-9
ND
ug/L
40.0
16.0
1
06/23/15 06:46
06/26/15 11:46
7440-70-2
0.47J
ug/L
0.50
0.17
1
06/23/15 06:46
06/26/15 11:46
7440-47-3
ND
ug/L
0.50
0.13
1
06/23/15 06:46
06/26/15 11:46
7440-48-4
ND
ug/L
1.0
0.21
1
06/23/15 06:46
06/26/15 11:46
7440-50-8
ND
ug/L
50.0
13.7
1
06/23/15 06:46
06/26/15 11:46
7439-89-6
ND
ug/L
0.10
0.046
1
06/23/15 06:46
06/26/15 11:46
7439-92-1
ND
ug/L
10.0
3.2
1
06/23/15 06:46
06/26/15 11:46
7439-95-4
ND
ug/L
0.50
0.24
1
06/23/15 06:46
06/26/15 11:46
7439-96-5
ND
ug/L
0.50
0.094
1
06/23/15 06:46
06/26/15 11:46
7439-98-7
0.20J
ug/L
0.50
0.16
1
06/23/15 06:46
06/26/15 11:46
7440-02-0
ND
ug/L
50.0
11.7
1
06/23/15 06:46
06/26/15 11:46
7440-09-7
ND
ug/L
0.50
0.20
1
06/23/15 06:46
06/26/15 11:46
7782-49-2
ND
ug/L
50.0
16.3
1
06/23/15 06:46
06/26/15 11:46
7440-23-5
ND
ug/L
0.50
0.13
1
06/23/15 06:46
06/26/15 11:46
7440-24-6
ND
ug/L
0.10
0.015
1
06/23/15 06:46
06/26/15 11:46
7440-28-0
ND
ug/L
1.0
0.28
1
06/23/15 06:46
06/27/15 10:02
7440-62-2
ND
ug/L
5.0
2.4
1
06/23/15 06:46
06/26/15 11:46
7440-66-6
Analytical Method: EPA 7470A Preparation Method: EPA 7470A
ND ug/L 0.20 0.022 1 06/21/15 15:05 06/21/15 20:46 7439-97-6 H3
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: J15050409
Pace Project No.: 92250201
Sample: 2015014672
Lab ID:
92250201002 Collected:
05/09/15 14:30
Received: 05/15/15 13:00 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample
size and any dilutions.
Report
Parameters
Results
Units Limit
MDL
DF
Prepared
Analyzed
CAS No.
Qual
6010 MET ICP
Analytical
Method: EPA 6010
Preparation
Method: EPA
3050
Aluminum
8440
mg/kg
30.9
15.5
5
05/26/15 10:30
05/27/15 21:55
7429-90-5
Barium
64.6
mg/kg
3.1
1.5
5
05/26/15 10:30
05/27/15 21:55
7440-39-3
Beryllium
0.24J
mg/kg
0.31
0.15
5
05/26/15 10:30
05/27/15 21:55
7440-41-7
Boron
ND
mg/kg
15.5
7.7
5
05/26/15 10:30
05/27/15 21:55
7440-42-8
Calcium
451
mg/kg
155
77.4
5
05/26/15 10:30
05/27/15 21:55
7440-70-2
Chromium
10.4
mg/kg
1.5
0.77
5
05/26/15 10:30
05/27/15 21:55
7440-47-3
Copper
12.5
mg/kg
1.5
0.77
5
05/26/15 10:30
05/27/15 21:55
7440-50-8
Iron
15600
mg/kg
12.4
6.2
5
05/26/15 10:30
05/27/15 21:55
7439-89-6
Magnesium
3760
mg/kg
155
77.4
5
05/26/15 10:30
05/27/15 21:55
7439-95-4
Manganese
108
mg/kg
1.5
0.77
5
05/26/15 10:30
05/27/15 21:55
7439-96-5
Molybdenum
ND
mg/kg
3.1
1.5
5
05/26/15 10:30
05/27/15 21:55
7439-98-7
Nickel
1.3J
mg/kg
1.5
0.77
5
05/26/15 10:30
05/27/15 21:55
7440-02-0
Potassium
1370
mg/kg
309
155
5
05/26/15 10:30
05/27/15 21:55
7440-09-7
Sodium
ND
mg/kg
309
155
5
05/26/15 10:30
05/27/15 21:55
7440-23-5
Strontium
11.2
mg/kg
3.1
1.5
5
05/26/15 10:30
05/27/15 21:55
7440-24-6
Zinc
18.9
mg/kg
6.2
3.1
5
05/26/15 10:30
05/27/15 21:55
7440-66-6
6020 MET ICPMS
Analytical
Method: EPA 6020
Preparation
Method: EPA
3050
Antimony
ND
mg/kg
6.2
3.1
100
05/26/15 10:30
05/27/1517:24
7440-36-0
N2
Arsenic
ND
mg/kg
6.2
3.1
100
05/26/15 10:30
05/27/1517:24
7440-38-2
Cadmium
ND
mg/kg
0.74
0.37
100
05/26/15 10:30
05/27/1517:24
7440-43-9
Cobalt
3.9J
mg/kg
6.2
3.1
100
05/26/15 10:30
05/27/1517:24
7440-48-4
Lead
4.7J
mg/kg
6.2
3.1
100
05/26/15 10:30
05/27/1517:24
7439-92-1
Selenium
ND
mg/kg
6.2
3.1
100
05/26/15 10:30
05/27/1517:24
7782-49-2
Thallium
ND
mg/kg
6.2
3.1
100
05/26/15 10:30
05/27/1517:24
7440-28-0
Vanadium
27.1
mg/kg
6.2
3.1
100
05/26/15 10:30
05/27/1517:24
7440-62-2
7471 Mercury
Analytical
Method: EPA 7471
Preparation
Method: EPA
7471
Mercury
0.0056J
mg/kg 0.010
0.0051
1
05/26/15 10:30
05/26/15 20:45
7439-97-6
Percent Moisture
Analytical
Method: ASTM D2974-87
Percent Moisture
19.4
%
0.10
0.10
1
06/02/15 10:59
9045 pH Soil
Analytical
Method: EPA 9045
pH at 25 Degrees C
5.2
Std. Units
0.10
0.10
1
05/27/15 11:20
9056 IC Anions
Analytical
Method: EPA 9056
Chloride
ND
mg/kg
305
153
5
05/21/15 01:29
16887-00-6
D3,M1
Sulfate
ND
mg/kg
305
153
5
05/21/15 01:29
14808-79-8
D3
9056 IC Anions 48hr
Analytical
Method: EPA 9056
Nitrate as N
ND
mg/kg
30.5
15.3
5
05/21/15 01:29
14797-55-8
H3
Date: 06/29/2015 03:48 PM
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: J15050409
Pace Project No.: 92250201
Sample: 2015014672
Lab ID:
92250201002
Collected:
05/09/15
14:30
Received: 05/15/15 13:00 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample
size and any dilutions.
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared Analyzed
CAS No. Qual
Total Organic Carbon Quad
Analytical Method: EPA 9060
Total Organic Carbon
1210
mg/kg
740
370
1
06/02/15 15:56
7440-44-0
Total Organic Carbon
1710
mg/kg
747
373
1
06/02/15 16:02
7440-44-0
Total Organic Carbon
1460
mg/kg
745
372
1
06/02/15 16:07
7440-44-0
Total Organic Carbon
2900
mg/kg
738
369
1
06/02/15 16:13
7440-44-0
Mean Total Organic Carbon
1820
mg/kg
742
371
1
06/02/15 15:56
7440-44-0
Surrogates
RSD%
41.2
%
1
06/02/15 15:56
1g
Date: 06/29/2015 03:48 PM
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: J15050409
Pace Project No.: 92250201
QC Batch: MERP/13956 Analysis Method: EPA 7470A
QC Batch Method: EPA 7470A Analysis Description: 7470A Mercury Water
Associated Lab Samples: 92250201001
METHOD BLANK: 2001526 Matrix: Water
Associated Lab Samples: 92250201001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Mercury ug/L ND 0.20 06/21/15 20:42
LABORATORY CONTROL SAMPLE: 2001527
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Mercury ug/L 5 5.4 109 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2001528 2001529
MS MSD
92254629012 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Mercury ug/L ND 5 5 4.9 5.0 98 100 80-120 1 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 06/29/2015 03:48 PM without the written consent of Pace Analytical Services, Inc..
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QUALITY CONTROL DATA
Project: J15050409
Pace Project No.: 92250201
QC Batch: MERP/5767
Analysis Method: EPA 7471
QC Batch Method: EPA 7471
Analysis Description: 7471 Mercury
Associated Lab Samples: 92250201002
METHOD BLANK: 1223182
Matrix: Solid
Associated Lab Samples: 92250201002
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Mercury mg/kg
ND 0.0080
05/26/1519:53
LABORATORY CONTROL SAMPLE: 1223183
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Mercury mg/kg
.08 0.075
94 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1223184 1223185
MS MSD
92250205001
Spike Spike MS
MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec Limits RPD RPD Qual
Mercury mg/kg 0.036
.0935 .0901 0.13
0.11 98 82 80-120 15 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: J15050409
Pace Project No.: 92250201
QC Batch: MPRP/24322 Analysis Method: EPA 6010
QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid
Associated Lab Samples: 92250201002
METHOD BLANK: 1223174
Associated Lab Samples: 92250201002
Parameter
Units
Aluminum
mg/kg
Barium
mg/kg
Beryllium
mg/kg
Boron
mg/kg
Calcium
mg/kg
Chromium
mg/kg
Copper
mg/kg
Iron
mg/kg
Magnesium
mg/kg
Manganese
mg/kg
Molybdenum
mg/kg
Nickel
mg/kg
Potassium
mg/kg
Sodium
mg/kg
Strontium
mg/kg
Zinc
mg/kg
Matrix: Solid
Blank
Result
Reporting
Limit
Analyzed Qualifiers
ND
4.9
05/27/15 20:02
ND
0.49
05/27/15 20:02
ND
0.049
05/27/15 20:02
ND
2.5
05/27/15 20:02
ND
24.5
05/27/15 20:02
ND
0.25
05/27/15 20:02
ND
0.25
05/27/15 20:02
ND
2.0
05/27/15 20:02
ND
24.5
05/27/15 20:02
ND
0.25
05/27/15 20:02
ND
0.49
05/27/15 20:02
ND
0.25
05/27/15 20:02
ND
49.1
05/27/15 20:02
ND
49.1
05/27/15 20:02 CH
ND
0.49
05/27/15 20:02
ND
0.98
05/27/15 20:02
LABORATORY CONTROL SAMPLE:
Parameter
1223175
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
Aluminum
mg/kg
125
135
108
80-120
Barium
mg/kg
12.5
13.5
108
80-120
Beryllium
mg/kg
1.3
1.3
101
80-120
Boron
mg/kg
125
121
97
80-120
Calcium
mg/kg
626
670
107
80-120
Chromium
mg/kg
12.5
11.6
93
80-120
Copper
mg/kg
12.5
12.1
96
80-120
Iron
mg/kg
125
131
105
80-120
Magnesium
mg/kg
626
625
100
80-120
Manganese
mg/kg
12.5
12.3
98
80-120
Molybdenum
mg/kg
12.5
12.7
101
80-120
Nickel
mg/kg
12.5
12.9
103
80-120
Potassium
mg/kg
626
656
105
80-120
Sodium
mg/kg
626
717
115
80-120 CH
Strontium
mg/kg
12.5
13.6
109
80-120
Zinc
mg/kg
62.6
64.3
103
80-120
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 06/29/2015 03:48 PM without the written consent of Pace Analytical Services, Inc..
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QUALITY CONTROL DATA
Project: J15050409
Pace Project No.: 92250201
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
1223176
1223177
MS
MSD
92250205001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Aluminum
mg/kg
9300
137
141
12600
13400
2430
2870
75-125
6
20 M1
Barium
mg/kg
68.9
13.7
14.1
93.6
109
181
285
75-125
15
20 M1
Beryllium
mg/kg
0.31
1.37
1.37
1.7
1.8
103
105
75-125
4
20
Boron
mg/kg
15.9
137
141
142
149
92
94
75-125
5
20
Calcium
mg/kg
8110
682
707
15200
11400
1040
461
75-125
29
20 M1,R1
Chromium
mg/kg
13.8
13.7
14.1
30.7
31.3
124
124
75-125
2
20
Copper
mg/kg
28.5
13.7
14.1
48.2
51.7
145
164
75-125
7
20 M1
Iron
mg/kg
17200
137
141
20100
20300
2100
2180
75-125
1
20 M1
Magnesium
mg/kg
3240
682
707
4770
4880
223
232
75-125
2
20 M1
Manganese
mg/kg
405
13.7
14.1
475
505
512
711
75-125
6
20 M1
Molybdenum
mg/kg
ND
13.7
14.1
10.6
11.0
75
76
75-125
4
20
Nickel
mg/kg
6.0
13.7
14.1
21.6
22.7
114
118
75-125
5
20
Potassium
mg/kg
506
682
707
1380
1400
128
127
75-125
2
20 M1
Sodium
mg/kg
ND
682
707
939
950
125
122
75-125
1
20 CH
Strontium
mg/kg
31.8
13.7
14.1
54.8
56.1
168
171
75-125
2
20 M1
Zinc
mg/kg
22.5
68.2
70.7
97.5
102
110
112
75-125
4
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/29/2015 03:48 PM without the written consent of Pace Analytical Services, Inc..
Page 24 of 37

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 WWW- Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15050409
Pace Project No.: 92250201
QC Batch: MPRP/24323 Analysis Method: EPA 6020
QC Batch Method: EPA 3050 Analysis Description: 6020 MET SOLID
Associated Lab Samples: 92250201002
METHOD BLANK: 1223178
Matrix:
Solid
Associated Lab Samples: 92250201002
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Antimony
mg/kg
ND
0.051
05/27/1515:48 N2
Arsenic
mg/kg
ND
0.051
05/27/1515:48
Cadmium
mg/kg
ND
0.0061
05/27/1515:48
Cobalt
mg/kg
ND
0.051
05/27/1515:48
Lead
mg/kg
ND
0.051
05/27/1515:48
Selenium
mg/kg
ND
0.051
05/27/1515:48
Thallium
mg/kg
ND
0.051
05/27/1515:48
Vanadium
mg/kg
ND
0.051
05/27/1515:48
LABORATORY CONTROL SAMPLE: 1223179
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits
Qualifiers
Antimony
mg/kg
2.6
2.5
97
80-120
N2
Arsenic
mg/kg
2.6
2.6
102
80-120
Cadmium
mg/kg
.26
0.25
97
80-120
Cobalt
mg/kg
2.6
2.5
98
80-120
Lead
mg/kg
2.6
2.6
101
80-120
Selenium
mg/kg
2.6
2.7
106
80-120
Thallium
mg/kg
2.6
2.6
100
80-120
Vanadium
mg/kg
2.6
2.5
99
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1223180
1223181
MS
MSD
92250205001
Spike
Spike
MS
MSD
MS MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec % Rec
Limits
RPD RPD Qual
Antimony
mg/kg
ND
2.97
2.74
ND
ND
42
22
75-125
20 M6, N2
Arsenic
mg/kg
ND
2.97
2.74
4.5J
3.7J
90
67
75-125
20 M6
Cadmium
mg/kg
ND
.297
.274
ND
ND
102
99
75-125
20
Cobalt
mg/kg
13.5
2.97
2.74
18.6
18.8
170
189
75-125
1 20 M6
Lead
mg/kg
3.5J
2.97
2.74
7.2
7.5
123
146
75-125
5 20 M6
Selenium
mg/kg
ND
2.97
2.74
5.OJ
4AJ
82
66
75-125
20 M6
Thallium
mg/kg
ND
2.97
2.74
3.OJ
ND
81
77
75-125
20
Vanadium
mg/kg
60.5
2.97
2.74
76.0
76.0
521
561
75-125
0 20 M6
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/29/2015 03:48 PM without the written consent of Pace Analytical Services, Inc..
Page 25 of 37

aceAnaiXical
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Pace Analytical Services, Inc.
9800 tSini98f4ft" Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15050409
Pace Project No.: 92250201
QC Batch: MPRP/55423 Analysis Method: EPA 6020A
QC Batch Method: EPA 3020 Analysis Description: 6020A Water UPD4
Associated Lab Samples: 92250201001
METHOD BLANK: 2002623
Associated Lab Samples: 92250201001
Parameter
Units
Aluminum
ug/L
Antimony
ug/L
Arsenic
ug/L
Barium
ug/L
Beryllium
ug/L
Boron
ug/L
Cadmium
ug/L
Calcium
ug/L
Chromium
ug/L
Cobalt
ug/L
Copper
ug/L
Iron
ug/L
Lead
ug/L
Magnesium
ug/L
Manganese
ug/L
Molybdenum
ug/L
Nickel
ug/L
Potassium
ug/L
Selenium
ug/L
Sodium
ug/L
Strontium
ug/L
Thallium
ug/L
Vanadium
ug/L
Zinc
ug/L
Matrix: Water
Blank
Result
Reporting
Limit
Analyzed
ND
10.0
06/26/1511:41
ND
0.50
06/26/1511:41
ND
0.50
06/26/1511:41
ND
0.30
06/26/1511:41
ND
0.20
06/26/1511:41
ND
5.0
06/26/1511:41
ND
0.080
06/26/1511:41
ND
40.0
06/26/1511:41
ND
0.50
06/26/1511:41
ND
0.50
06/26/1511:41
ND
1.0
06/26/1511:41
ND
50.0
06/26/1511:41
ND
0.10
06/26/1511:41
ND
10.0
06/26/1511:41
ND
0.50
06/26/1511:41
ND
0.50
06/26/1511:41
ND
0.50
06/26/1511:41
ND
50.0
06/26/1511:41
ND
0.50
06/26/1511:41
ND
50.0
06/26/1511:41
ND
0.50
06/26/1511:41
ND
0.10
06/26/1511:41
ND
1.0
06/27/15 09:08
ND
5.0
06/26/1511:41
Qualifiers
LABORATORY CONTROL SAMPLE:
Parameter
2002624
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
Aluminum
ug/L
80
80.2
100
80-120
Antimony
ug/L
80
78.1
98
80-120
Arsenic
ug/L
80
79.6
100
80-120
Barium
ug/L
80
78.6
98
80-120
Beryllium
ug/L
80
80.7
101
80-120
Boron
ug/L
80
79.2
99
80-120
Cadmium
ug/L
80
79.4
99
80-120
Calcium
ug/L
1000
983
98
80-120
Chromium
ug/L
80
79.5
99
80-120
Cobalt
ug/L
80
79.8
100
80-120
Copper
ug/L
80
78.1
98
80-120
Iron
ug/L
1000
1000
100
80-120
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/29/2015 03:48 PM without the written consent of Pace Analytical Services, Inc..
Page 26 of 37

aceAnaiXical
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Pace Analytical Services, Inc.
9800 IS298f4ft" Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15050409
Pace Project No.: 92250201
LABORATORY CONTROL SAMPLE:
2002624
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits
Qualifiers
Lead
ug/L
80
79.8
100
80-120
Magnesium
ug/L
1000
978
98
80-120
Manganese
ug/L
80
79.7
100
80-120
Molybdenum
ug/L
80
78.8
99
80-120
Nickel
ug/L
80
80.9
101
80-120
Potassium
ug/L
1000
963
96
80-120
Selenium
ug/L
80
80.5
101
80-120
Sodium
ug/L
1000
975
97
80-120
Strontium
ug/L
80
78.8
99
80-120
Thallium
ug/L
80
79.5
99
80-120
Vanadium
ug/L
80
80.2
100
80-120
Zinc
ug/L
80
80.2
100
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
2002625
2002626
MS
MSD
92254832007
Spike
Spike
MS
MSD
MS MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec % Rec
Limits
RPD
RPD Qual
Aluminum
ug/L
132
80
80
578
479
558
434
75-125
19
20 M1
Antimony
ug/L
ND
80
80
77.6
79.5
97
99
75-125
2
20
Arsenic
ug/L
ND
80
80
79.8
80.2
100
100
75-125
1
20
Barium
ug/L
0.60
80
80
78.7
79.9
98
99
75-125
1
20
Beryllium
ug/L
ND
80
80
82.8
83.2
103
104
75-125
1
20
Boron
ug/L
ND
80
80
84.1
84.3
104
105
75-125
0
20
Cadmium
ug/L
ND
80
80
79.4
79.8
99
100
75-125
1
20
Calcium
ug/L
34.3J
1000
1000
1020
1080
99
104
75-125
5
20
Chromium
ug/L
0.31J
80
80
79.4
81.1
99
101
75-125
2
20
Cobalt
ug/L
ND
80
80
80.0
80.6
100
101
75-125
1
20
Copper
ug/L
0.26J
80
80
78.6
79.3
98
99
75-125
1
20
Iron
ug/L
296
1000
1000
1380
1350
108
105
75-125
2
20
Lead
ug/L
0.42
80
80
81.4
81.7
101
102
75-125
0
20
Magnesium
ug/L
13.5
1000
1000
986
1030
97
101
75-125
4
20
Manganese
ug/L
3.3
80
80
83.6
83.7
100
101
75-125
0
20
Molybdenum
ug/L
ND
80
80
78.1
79.4
98
99
75-125
2
20
Nickel
ug/L
0.46J
80
80
81.0
82.6
101
103
75-125
2
20
Potassium
ug/L
24.7J
1000
1000
990
1010
97
99
75-125
2
20
Selenium
ug/L
ND
80
80
80.7
79.2
101
99
75-125
2
20
Sodium
ug/L
ND
1000
1000
1000
1010
99
100
75-125
1
20
Strontium
ug/L
ND
80
80
79.1
80.2
99
100
75-125
1
20
Thallium
ug/L
ND
80
80
81.6
81.9
102
102
75-125
0
20
Vanadium
ug/L
0.36J
80
80
81.8
80.6
102
100
75-125
1
20
Zinc
ug/L
16.9
80
80
97.5
98.3
101
102
75-125
1
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/29/2015 03:48 PM without the written consent of Pace Analytical Services, Inc..
Page 27 of 37

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 lSS98f4W- Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15050409
Pace Project No.: 92250201
QC Batch: PMST/3609
Analysis Method:
ASTM
D2974-87
QC Batch Method: ASTM D2974-87
Analysis Description:
Dry Weight/Percent Moisture
Associated Lab Samples: 92250201002
SAMPLE DUPLICATE: 1229602
92250201002
Dup
Max
Parameter
Units
Result
Result
RPD
RPD
Qualifiers
Percent Moisture
%
19.4
18.7
4
10
SAMPLE DUPLICATE: 1229603
35190185002
Dup
Max
Parameter
Units
Result
Result
RPD
RPD
Qualifiers
Percent Moisture
%
8.6
7.4
15
10 D6
SAMPLE DUPLICATE: 1229604
35190195001
Dup
Max
Parameter
Units
Result
Result
RPD
RPD
Qualifiers
Percent Moisture
%
2.3
2.0
11
10 D6
SAMPLE DUPLICATE: 1229605
35190544023
Dup
Max
Parameter
Units
Result
Result
RPD
RPD
Qualifiers
Percent Moisture
%
5.9
6.3
6
10
SAMPLE DUPLICATE: 1229606
35190544041
Dup
Max
Parameter
Units
Result
Result
RPD
RPD
Qualifiers
Percent Moisture
%
5.7
5.1
11
10 D6
SAMPLE DUPLICATE: 1229607
35190704003
Dup
Max
Parameter
Units
Result
Result
RPD
RPD
Qualifiers
Percent Moisture
%
19.3
12.9
40
10 D6
SAMPLE DUPLICATE: 1229608
35190704011
Dup
Max
Parameter
Units
Result
Result
RPD
RPD
Qualifiers
Percent Moisture
%
21.0
22.6
7
10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 06/29/2015 03:48 PM without the written consent of Pace Analytical Services, Inc.. Page 28 of 37

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Pace Analytical Services, Inc.
9800 WWW- Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15050409
Pace Project No.: 92250201
QC Batch: WET/37661 Analysis Method: EPA 9045
QC Batch Method: EPA 9045 Analysis Description: 9045 pH
Associated Lab Samples: 92250201002
SAMPLE DUPLICATE: 1467399
Parameter
pH at 25 Degrees C
SAMPLE DUPLICATE: 1467400
Parameter
pH at 25 Degrees C
92250201002 Dup Max
Units Result Result RPD RPD Qualifiers
Std. Units 5.2 5.3 1 10
92250205001 Dup Max
Units Result Result RPD RPD Qualifiers
Std. Units 6.5 6.7 3 10 D6
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 06/29/2015 03:48 PM without the written consent of Pace Analytical Services, Inc.. Page 29 of 37

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Pace Analytical Services, Inc.
9800 WWW- Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15050409
Pace Project No.: 92250201
QC Batch: WETA/46586 Analysis Method: EPA 9056
QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions
Associated Lab Samples: 92250201002
METHOD BLANK: 1219552 Matrix: Solid
Associated Lab Samples:
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Chloride mg/kg ND 50.5 05/21/15 00:24
Sulfate mg/kg ND 50.5 05/21/15 00:24
LABORATORY CONTROL SAMPLE:
1219553
Parameter
Units
Chloride
mg/kg
Sulfate
mg/kg
MATRIX SPIKE SAMPLE:
1219555
Parameter
Units
Chloride
mg/kg
Sulfate
mg/kg
SAMPLE DUPLICATE: 1219554
Parameter
Chloride
Sulfate
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
497 468 94 80-120
497 462 93 80-120
92250201002 Spike MS MS % Rec
Result Conc. Result % Rec Limits Qualifiers
ND 619 545 72 80-120 M 1
ND 619 583 80 80-120
92250201002 Dup
Units Result Result
mg/kg ND ND
mg/kg ND ND
Max
RPD RPD Qualifiers
20
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/29/2015 03:48 PM without the written consent of Pace Analytical Services, Inc.. Page 30 of 37

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 WWW- Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15050409
Pace Project No.: 92250201
QC Batch: WETA/46587
Analysis Method:
EPA 9056
QC Batch Method: EPA 9056
Analysis Description:
9056 IC Anions
Associated Lab Samples: 92250201002
METHOD BLANK: 1219557
Matrix: Solid
Associated Lab Samples:
Blank Reporting
Parameter
Units
Result Limit
Analyzed
Qualifiers
Nitrate as N
mg/kg
ND 5.1
05/21/15 00:24
LABORATORY CONTROL SAMPLE:
1219558
Spike LCS
LCS
% Rec
Parameter
Units
Conc. Result
% Rec
Limits
Qualifiers
Nitrate as N
mg/kg
49.7 47.3
95
80-120
MATRIX SPIKE SAMPLE:
1219560
92250201002 Spike
MS
MS
% Rec
Parameter
Units
Result Conc.
Result
% Rec
Limits Qualifiers
Nitrate as N
mg/kg
ND 61.9
55.3
89 80-120 H3
SAMPLE DUPLICATE: 1219559
92250201002 Dup
Max
Parameter
Units
Result Result
RPD
RPD
Qualifiers
Nitrate as N
mg/kg
ND ND
20 H3
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 06/29/2015 03:48 PM without the written consent of Pace Analytical Services, Inc.. Page 31 of 37

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 l� ' i re. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15050409
Pace Project No.: 92250201
QC Batch: WETA/28762
Analysis Method: EPA 9060
QC Batch Method: EPA 9060
Analysis Description: 9060 TOC Average
Associated Lab Samples: 92250201002
METHOD BLANK: 1167261
Matrix: Solid
Associated Lab Samples:
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Mean Total Organic Carbon mg/kg
ND 600
06/02/15 07:26
LABORATORY CONTROL SAMPLE: 1167262
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Mean Total Organic Carbon mg/kg
120000 114000
95 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1167263 1167264
MS MSD
92249703006
Spike Spike MS
MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec Limits RPD RPD Qual
Mean Total Organic Carbon mg/kg ND
5990 6000 4820
4980 77 79 50-150 3 30
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1167265 1167266
MS MSD
92249703007 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Mean Total Organic Carbon mg/kg ND 6030 6010 5110 5550 81 89 50-150 8 30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 06/29/2015 03:48 PM without the written consent of Pace Analytical Services, Inc..
Page 32 of 37

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Pace Analytical Services, Inc.
9800 WWW' Suite 100
Huntersville, NC 28078
[phone]
QUALIFIERS
Project: J15050409
Pace Project No.: 92250201
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
LABORATORIES
PASI-A
Pace Analytical Services - Asheville
PASI-G
Pace Analytical Services - Green Bay
PASI-M
Pace Analytical Services - Minneapolis
PASI-O
Pace Analytical Services - Ormond Beach
BATCH QUALIFIERS
Batch: ICP/14866
Ill Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
ANALYTE QUALIFIERS
1g %RSD>40
CH The continuing calibration for this compound is outside of Pace Analytical acceptance limits. The results may be biased
high.
D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
D6 The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits.
H3 Sample was received or analysis requested beyond the recognized method holding time.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
N2 The lab does not hold TN accreditation for this parameter.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/29/2015 03:48 PM without the written consent of Pace Analytical Services, Inc.. Page 33 of 37

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 WWW- Suite 100
Huntersville, INC 28078
[phone]
QUALIFIERS
Project: J15050409
Pace Project No.: 92250201
ANALYTE QUALIFIERS
R1 RPD value was outside control limits.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/29/2015 03:48 PM without the written consent of Pace Analytical Services, Inc.. Page 34 of 37

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 W698f4ft" Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: J15050409
Pace Project No.: 92250201
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
92250201002
2015014672
EPA 3050
MPRP/24322
EPA 6010
92250201002
2015014672
EPA 3050
MPRP/24323
EPA 6020
92250201001
2015014671
EPA 3020
MPRP/55423
EPA 6020A
92250201001
2015014671
EPA 7470A
MERP/13956
EPA 7470A
92250201002
2015014672
EPA 7471
MERP/5767
EPA 7471
92250201002
2015014672
ASTM D2974-87
PMST/3609
92250201002
2015014672
EPA 9045
WET/37661
92250201002
2015014672
EPA 9056
WETA/46586
92250201002
2015014672
EPA 9056
WETA/46587
92250201002
2015014672
EPA 9060
WETA/28762
92250201002
2015014672
EPA 9060
WETA/28763
Date: 06/29/2015 03:48 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Analytical
Batch
ICP/14866
ICPM/9853
ICPM/24991
MERC/16232
MERC/5752
Page 35 of 37

�eQI1rIalytical �
i
Sample Condition Upon Receipt SCUR V v Page 1 of 2
Document Number: Issuing Authority:
F-CHR-CS-003-rev.15 Pace Huntersville Quality OVfice 43
Client Name: cA Kz. r% n (If
Courier: ❑ Fed Ex ❑ UPS❑ USPS❑ Client❑ emmercial❑ Pac Other r 3 r,
Custody Seal on Cooler/Box Present: ❑ yes no Seals intact: El yes [] no 0og i t
Packing Material: ❑ Bubble VDp �BubbleBags ❑ None ❑ Other
Thermometer Used: IR Gun 1401�Type of Ice: e% Blue None Samples on ice, cooling process has begun
Temp Correction Factor T1401 No Correction
Biological Tissue is Frozen: Yes No 1A Date and Initials of person examining
Corrected Cooler Temp.: 'G g contentsi) (' 5
Temp should be above freezing to 6°C Comments:
Chain of Custody Present: es ❑ o QNIA 1.
Chain of Custody Filled Out: es o ❑NrA 2,
Chain of Custody Relinquished: es ❑ ❑NIA 3.
Sampler Name & Signature on COC: Elp &LO ❑NIA 4.
Samples Arrived within Hold Time: Wes ONO PNIA 5.
Short Hold Time Analysis (<72hr): Oyes QN IA 6.
Rush Turn Around Time Requested: Dyes o ❑NIA 7.
Sufficient Volume: 0,4yflNo ❑NIA 8,
Correct Containers Used: dyes ONO P<NIA 9.
-Pace Containers Used:
❑Yes o
❑NIA
Containers Intact:
ErYes ONo
❑NIA
Filtered volume received for Dissolved tests
Dyes No
O 01A
11.
Sample Labels match COC:
es ONO
ON/A
12,
-Includes date/time/lD1Analysis Matrix:
All containers needing preservation have been checked.
No
❑NIA
13.
All containers needing preservatlon are found to be in
��yesONO
❑NIA
compliance with EPA recommendation.
Dyes ❑t�O
exceptions: VOA, col{form, TOC, O&G,1M-DRO (water)
Samples checked for dechlorination:
QYes ❑No
IA
14.
Headspace in VOA Vials ( >6mm):
OYes ❑No
NrA
15.
Trip Blank Present:
Dyes DNo
NIA
16.
Trip Blank Custody Seals Present
❑Yes ONO
N/A
Pace Trip.Blank.Lot #_(it_purchased): I
Client Notification/ Resolution: Field Data Required? Y I N
Person Contacted: Date/Time:
Comments/ Resolution:
SCURF Review: �itri'�%a Date: 15-/,'�"K 1 Place label here
SRF Review: I —I IDate: I yzf d W ® ' 9225®2Q1
Note: Whenever there is a discrepancy affecting North Carolina compliance
samples, a copy of this form will be sent to the North Carolina DEHNR
Certification office ( Le out of hold, incorrect preservative, out of temp, 92250201
incorrect containers)
Page 36 of 37

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Page 37 of 37

CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM
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ClshmIT)OP
Te-t-ai-li: Al, Sb, Al%. Els, Be, 6, Cd, Ca, CF. CO, Cu, Fal, Pb, Mg, Mn, Mu, N
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