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Home My WebLink AboutNC0038377_J15050346 report_20150902Analytical Lab + DUKE Analytical Laboratory Page 1of97 ENERGY Order Number: Project Name: Customer Name(s): Customer Address: Lab Contact: Report Authorized By: (Signature) Program Comments: 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone:980-875-5245 Fax:980-875-4349 Order Summary Report J15050346 MAYO STEAM - AB GW ASSESSMENT SURFACE Tim Hunsucker, Jerry Wylie, Kathy Webb, John Toepfer Mary Ann Ogle Phone: 980-875-5274 �n O Mary Ann Ogle ✓5 2015.06.02 09:41:12 -04'00' Date: Mary Ann Ogle Please contact the Program Manager (Mary Ann Ogle) with any questions regarding this report. Data Flags & Calculations: 5/28/2015 Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Sample ID's & Descriptions: Collection Sample ID Plant/Station Date and Time Collected By Sample Description 2015014486 MAYO STEAM 12-May-15 3:10 PM illegible S-02 2015014487 MAYO STEAM 12-May-15 12:10 PM illegible S-05 2015014488 MAYO STEAM 12-May-15 2:25 PM illegible S-03 2015014489 MAYO STEAM 13-May-15 5:00 PM illegible S-08 2015014490 MAYO STEAM 13-May-15 4:00 PM illegible S-06 2015014491 MAYO STEAM 13-May-15 2:10 PM illegible SW-REF1 2015014492 MAYO STEAM 12-May-15 4:15 PM illegible S-01 2015014493 MAYO STEAM 13-May-15 10:55 AM illegible S-02B 2015014494 MAYO STEAM 13-May-15 11:15 AM illegible S-02B Dup 2015014495 MAYO STEAM 13-May-15 10:20 AM illegible S-04 2015014496 MAYO STEAM 13-May-15 12:45 PM illegible SW-CB2 2015014498 MAYO STEAM 13-May-15 6:45 PM illegible FIELD BLANK 2015014504 MAYO STEAM Trip Blank 2015014505 MAYO STEAM 13-May-15 6:45 PM illegible Filter Blank 2015014506 MAYO STEAM 13-May-15 11:40 AM illegible SW-CB1 15 Total Samples Analytical Lab Page 2 of 97 Analytical Lab Page 3 of 97 Technical Validation Review Checklist: COC and .pdf report are in agreement with sample totals Yes No and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. ❑ Yes❑ No All laboratory QA/QC requirements are acceptable.❑ Yes ❑ No Report Sections Included: U Job Summary Report ❑ Sample Identification n Technical Validation of Data Package ❑ Analytical Laboratory Certificate of Analysis ❑ Analytical Laboratory QC Report Sub -contracted Laboratory Results ❑ Customer Specific Data Sheets, Reports, & Documentation ❑ Customer Database Entries d❑ Chain of Custody [I/0] Electronic Data Deliverable (EDD) Sent Separately Reviewed By: Peggy Kendall Date: 5/28/2015 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050346 Site: S-02 Collection Date: 12-May-15 3:10 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.042 mg-N/L 0.01 INORGANIC IONS BY IC Chloride 73 mg/L 1 Sulfate 33 mg/L 1 MERCURY IN WATER - (Analysis Performed by Shealy Labs) Vendor Parameter Complete DISSOLVED METALS BY ICP Aluminum (AI) 0.006 mg/L 0.005 Barium (Ba) 0.125 mg/L 0.005 Boron (B) 1.64 mg/L 0.05 Iron (Fe) 3.00 mg/L 0.01 Manganese (Mn) 3.40 mg/L 0.005 Strontium (Sr) 0.557 mg/L 0.005 Zinc (Zn) 0.012 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 29.8 mg/L 0.01 Magnesium (Mg) 13.3 mg/L 0.005 Potassium (K) 2.52 mg/L 0.1 Sodium (Na) 20.8 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.012 mg/L 0.005 Barium (Ba) 0.130 mg/L 0.005 Boron (B) 1.65 mg/L 0.05 Iron (Fe) 3.10 mg/L 0.01 Manganese (Mn) 3.32 mg/L 0.005 Strontium (Sr) 0.558 mg/L 0.005 Zinc (Zn) 0.011 mg/L 0.005 Analytical Lab Page 4 of 97 Sample #: 2015014486 Matrix: GW_WW DF Method Analysis Date/Time Analyst Vendor Method V_SHEALY 1 EPA 353.2 05/14/2015 14:19 LSTARL1 10 EPA 300.0 05/19/2015 09:20 BGN9034 10 EPA 300.0 05/19/2015 09:20 BGN9034 Vendor Method V_SHEALY 1 EPA 200.7 05/15/2015 10:49 MHALL3 1 EPA 200.7 05/15/2015 10:49 MHALL3 1 EPA 200.7 05/15/2015 10:49 MHALL3 1 EPA 200.7 05/15/2015 10:49 MHALL3 1 EPA 200.7 05/15/2015 10:49 MHALL3 1 EPA 200.7 05/15/2015 10:49 MHALL3 1 EPA 200.7 05/15/2015 10:49 MHALL3 1 EPA 200.7 05/15/2015 12:59 MHALL3 1 EPA 200.7 05/15/2015 12:59 MHALL3 1 EPA 200.7 05/15/2015 12:59 MHALL3 1 EPA 200.7 05/15/2015 12:59 MHALL3 1 EPA 200.7 05/18/2015 10:17 MHALL3 1 EPA 200.7 05/18/2015 10:17 MHALL3 1 EPA 200.7 05/18/2015 10:17 MHALL3 1 EPA 200.7 05/18/2015 10:17 MHALL3 1 EPA 200.7 05/18/2015 10:17 MHALL3 1 EPA 200.7 05/18/2015 10:17 MHALL3 1 EPA 200.7 05/18/2015 10:17 MHALL3 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050346 Site: S-02 Collection Date: 12-May-15 3:10 PM Analyte Result DISSOLVED METALS BY ICP-MS Antimony (Sb) < 1 Arsenic (As) < 1 Beryllium (Be) < 1 Cadmium (Cd) < 1 Chromium (Cr) < 1 Cobalt (Co) 10.2 Copper (Cu) < 1 Lead (Pb) < 1 Molybdenum (Mo) < 1 Nickel (Ni) 1.76 Selenium (Se) < 1 Thallium (TI) Low Level < 0.2 Vanadium (V) Low Level < 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 Arsenic (As) < 1 Beryllium (Be) < 1 Cadmium (Cd) < 1 Chromium (Cr) < 1 Cobalt (Co) 9.09 Copper (Cu) < 1 Lead (Pb) < 1 Molybdenum (Mo) < 1 Nickel (Ni) 1.98 Selenium (Se) < 1 Thallium (TI) Low Level < 0.2 Vanadium (V) Low Level < 0.3 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4) Complete SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 330 Total Carbon TOC 1.3 TOTAL SUSPENDED SOLIDS TSS < 5 Analytical Lab Page 5 of 97 Sample #: 2015014486 Matrix: GW_WW Units Qualifiers RDL DF Method Analysis Date/Time Analyst ug/L 1 1 EPA 200.8 05/28/2015 11:28 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 11:28 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 11:28 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 11:28 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 11:28 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 11:28 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 11:28 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 11:28 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 11:28 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 11:28 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 11:28 DJSULL1 ug/L 0.2 1 EPA 200.8 05/28/2015 11:28 DJSULL1 ug/L 0.3 1 EPA 200.8 05/28/2015 11:28 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 13:44 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 13:44 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 13:44 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 13:44 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 13:44 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 13:44 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 13:44 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 13:44 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 13:44 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 13:44 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 13:44 DJSULL1 ug/L 0.2 1 EPA 200.8 05/19/2015 13:44 DJSULL1 ug/L 0.3 1 EPA 200.8 05/19/2015 13:44 DJSULL1 Vendor Method V SHEALY Vendor Method V_ELE1 mg/L 25 1 SM2540C 05/14/201514:55 AGIBBS5 mg/L 0.1 1 SM5310C/EPA9060A 05/19/201511:50 GHUTCHI mg/L 5 1 SM2540D 05/14/201511:38 AGIBBS5 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050346 Site: S-05 Collection Date: 12-May-15 12:10 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.081 mg-N/L 0.01 INORGANIC IONS BY IC Chloride 71 mg/L 1 Sulfate 46 mg/L 1 MERCURY IN WATER - (Analysis Performed by Shealy Labs) Vendor Parameter Complete DISSOLVED METALS BY ICP Aluminum (AI) 0.018 mg/L 0.005 Barium (Ba) 0.063 mg/L 0.005 Boron (B) 1.74 mg/L 0.05 Iron (Fe) 0.023 mg/L 0.01 Manganese (Mn) 0.017 mg/L 0.005 Strontium (Sr) 0.240 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 38.1 mg/L 0.01 Magnesium (Mg) 13.9 mg/L 0.005 Potassium (K) 5.46 mg/L 0.1 Sodium (Na) 11.2 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.109 mg/L 0.005 Barium (Ba) 0.068 mg/L 0.005 Boron (B) 1.79 mg/L 0.05 Iron (Fe) 0.112 mg/L 0.01 Manganese (Mn) 0.079 mg/L 0.005 Strontium (Sr) 0.248 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 Analytical Lab Page 6 of 97 Sample #: 2015014487 Matrix: GW_WW DF Method Analysis Date/Time Analyst Vendor Method V_SHEALY 1 EPA 353.2 05/14/2015 14:20 LSTARL1 10 EPA 300.0 05/18/2015 20:06 BGN9034 10 EPA 300.0 05/18/2015 20:06 BGN9034 Vendor Method V_SHEALY 1 EPA 200.7 05/15/2015 10:37 MHALL3 1 EPA 200.7 05/15/2015 10:37 MHALL3 1 EPA 200.7 05/15/2015 10:37 MHALL3 1 EPA 200.7 05/15/2015 10:37 MHALL3 1 EPA 200.7 05/15/2015 10:37 MHALL3 1 EPA 200.7 05/15/2015 10:37 MHALL3 1 EPA 200.7 05/15/2015 10:37 MHALL3 1 EPA 200.7 05/15/2015 13:03 MHALL3 1 EPA 200.7 05/15/2015 13:03 MHALL3 1 EPA 200.7 05/15/2015 13:03 MHALL3 1 EPA 200.7 05/15/2015 13:03 MHALL3 1 EPA 200.7 05/18/2015 10:21 MHALL3 1 EPA 200.7 05/18/2015 10:21 MHALL3 1 EPA 200.7 05/18/2015 10:21 MHALL3 1 EPA 200.7 05/18/2015 10:21 MHALL3 1 EPA 200.7 05/18/2015 10:21 MHALL3 1 EPA 200.7 05/18/2015 10:21 MHALL3 1 EPA 200.7 05/18/2015 10:21 MHALL3 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050346 Site: S-05 Collection Date: 12-May-15 12:10 PM Analyte Result DISSOLVED METALS BY ICP-MS Antimony (Sb) < 1 Arsenic (As) 2.47 Beryllium (Be) < 1 Cadmium (Cd) < 1 Chromium (Cr) < 1 Cobalt (Co) < 1 Copper(Cu) 1.69 Lead (Pb) < 1 Molybdenum (Mo) 12.7 Nickel (Ni) < 1 Selenium (Se) < 1 Thallium (TI) Low Level < 0.2 Vanadium (V) Low Level 1.37 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 Arsenic (As) 2.72 Beryllium (Be) < 1 Cadmium (Cd) < 1 Chromium (Cr) < 1 Cobalt (Co) < 1 Copper(Cu) 1.93 Lead (Pb) < 1 Molybdenum (Mo) 11.8 Nickel (Ni) < 1 Selenium (Se) < 1 Thallium (TI) Low Level < 0.2 Vanadium (V) Low Level 1.43 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4) Complete SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 320 Total Carbon TOC 6.1 TOTAL SUSPENDED SOLIDS TSS 9.0 Analytical Lab Page 7 of 97 Sample #: 2015014487 Matrix: GW_WW Units Qualifiers RDL DF Method Analysis Date/Time Analyst ug/L 1 1 EPA 200.8 05/28/2015 11:33 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 11:33 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 11:33 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 11:33 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 11:33 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 11:33 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 11:33 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 11:33 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 11:33 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 11:33 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 11:33 DJSULL1 ug/L 0.2 1 EPA 200.8 05/28/2015 11:33 DJSULL1 ug/L 0.3 1 EPA 200.8 05/28/2015 11:33 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 13:58 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 13:58 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 13:58 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 13:58 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 13:58 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 13:58 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 13:58 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 13:58 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 13:58 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 13:58 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 13:58 DJSULL1 ug/L 0.2 1 EPA 200.8 05/19/2015 13:58 DJSULL1 ug/L 0.3 1 EPA 200.8 05/19/2015 13:58 DJSULL1 Vendor Method V SHEALY Vendor Method V_ELE1 mg/L 25 1 SM2540C 05/14/201514:55 AGIBBS5 mg/L 0.1 1 SM5310C/EPA9060A 05/19/201511:50 GHUTCHI mg/L 5 1 SM2540D 05/14/201511:38 AGIBBS5 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050346 Site: S-03 Collection Date: 12-May-15 2:25 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.039 mg-N/L 0.01 INORGANIC IONS BY IC Chloride 58 mg/L 1 Sulfate 29 mg/L 1 MERCURY IN WATER - (Analysis Performed by Shealy Labs) Vendor Parameter Complete DISSOLVED METALS BY ICP Aluminum (AI) 0.007 mg/L 0.005 Barium (Ba) 0.061 mg/L 0.005 Boron (B) 1.24 mg/L 0.05 Iron (Fe) 0.213 mg/L 0.01 Manganese (Mn) 1.14 mg/L 0.005 Strontium (Sr) 0.438 mg/L 0.005 Zinc (Zn) 0.007 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 26.2 mg/L 0.01 Magnesium (Mg) 10.2 mg/L 0.005 Potassium (K) 2.12 mg/L 0.1 Sodium (Na) 24.0 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.060 mg/L 0.005 Barium (Ba) 0.064 mg/L 0.005 Boron (B) 1.25 mg/L 0.05 Iron (Fe) 0.381 mg/L 0.01 Manganese (Mn) 1.17 mg/L 0.005 Strontium (Sr) 0.446 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 Analytical Lab Page 8 of 97 Sample #: 2015014488 Matrix: GW_WW DF Method Analysis Date/Time Analyst Vendor Method V_SHEALY 1 EPA 353.2 05/14/2015 14:21 LSTARL1 10 EPA 300.0 05/18/2015 20:55 BGN9034 10 EPA 300.0 05/18/2015 20:55 BGN9034 Vendor Method V_SHEALY 1 EPA 200.7 05/15/2015 10:52 MHALL3 1 EPA 200.7 05/15/2015 10:52 MHALL3 1 EPA 200.7 05/15/2015 10:52 MHALL3 1 EPA 200.7 05/15/2015 10:52 MHALL3 1 EPA 200.7 05/15/2015 10:52 MHALL3 1 EPA 200.7 05/15/2015 10:52 MHALL3 1 EPA 200.7 05/15/2015 10:52 MHALL3 1 EPA 200.7 05/15/2015 13:07 MHALL3 1 EPA 200.7 05/15/2015 13:07 MHALL3 1 EPA 200.7 05/15/2015 13:07 MHALL3 1 EPA 200.7 05/15/2015 13:07 MHALL3 1 EPA 200.7 05/18/2015 10:24 MHALL3 1 EPA 200.7 05/18/2015 10:24 MHALL3 1 EPA 200.7 05/18/2015 10:24 MHALL3 1 EPA 200.7 05/18/2015 10:24 MHALL3 1 EPA 200.7 05/18/2015 10:24 MHALL3 1 EPA 200.7 05/18/2015 10:24 MHALL3 1 EPA 200.7 05/18/2015 10:24 MHALL3 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050346 Site: S-03 Collection Date: 12-May-15 2:25 PM Analyte Result DISSOLVED METALS BY ICP-MS Antimony (Sb) < 1 Arsenic (As) < 1 Beryllium (Be) < 1 Cadmium (Cd) < 1 Chromium (Cr) < 1 Cobalt (Co) 1.82 Copper (Cu) < 1 Lead (Pb) < 1 Molybdenum (Mo) < 1 Nickel (Ni) < 1 Selenium (Se) < 1 Thallium (TI) Low Level < 0.2 Vanadium (V) Low Level < 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 Arsenic (As) < 1 Beryllium (Be) < 1 Cadmium (Cd) < 1 Chromium (Cr) < 1 Cobalt (Co) 1.75 Copper (Cu) < 1 Lead (Pb) < 1 Molybdenum (Mo) < 1 Nickel (Ni) < 1 Selenium (Se) < 1 Thallium (TI) Low Level < 0.2 Vanadium (V) Low Level < 0.3 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4) Complete SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 240 Total Carbon TOC 2.0 TOTAL SUSPENDED SOLIDS TSS 9.0 Analytical Lab Page 9 of 97 Sample #: 2015014488 Matrix: GW_WW Units Qualifiers RDL DF Method Analysis Date/Time Analyst ug/L 1 1 EPA 200.8 05/28/2015 11:37 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 11:37 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 11:37 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 11:37 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 11:37 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 11:37 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 11:37 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 11:37 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 11:37 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 11:37 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 11:37 DJSULL1 ug/L 0.2 1 EPA 200.8 05/28/2015 11:37 DJSULL1 ug/L 0.3 1 EPA 200.8 05/28/2015 11:37 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 14:02 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 14:02 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 14:02 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 14:02 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 14:02 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 14:02 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 14:02 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 14:02 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 14:02 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 14:02 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 14:02 DJSULL1 ug/L 0.2 1 EPA 200.8 05/19/2015 14:02 DJSULL1 ug/L 0.3 1 EPA 200.8 05/19/2015 14:02 DJSULL1 Vendor Method V SHEALY Vendor Method V_ELE1 mg/L 25 1 SM2540C 05/14/201514:55 AGIBBS5 mg/L 0.1 1 SM5310C/EPA9060A 05/19/201511:50 GHUTCHI mg/L 5 1 SM2540D 05/14/201511:38 AGIBBS5 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050346 Site: S-08 Collection Date: 13-May-15 5:00 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.095 mg-N/L 0.01 INORGANIC IONS BY IC Chloride 94 mg/L 1 Sulfate 53 mg/L 1 MERCURY IN WATER - (Analysis Performed by Shealy Labs) Vendor Parameter Complete DISSOLVED METALS BY ICP Aluminum (AI) 0.016 mg/L 0.005 Barium (Ba) 0.101 mg/L 0.005 Boron (B) 1.88 mg/L 0.05 Iron (Fe) 0.064 mg/L 0.01 Manganese (Mn) 0.657 mg/L 0.005 Strontium (Sr) 0.661 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 35.5 mg/L 0.01 Magnesium (Mg) 17.5 mg/L 0.005 Potassium (K) 3.35 mg/L 0.1 Sodium (Na) 21.0 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 2.73 mg/L 0.005 Barium (Ba) 0.198 mg/L 0.005 Boron (B) 1.86 mg/L 0.05 Iron (Fe) 6.19 mg/L 0.01 Manganese (Mn) 2.79 mg/L 0.005 Strontium (Sr) 0.691 mg/L 0.005 Zinc (Zn) 0.024 mg/L 0.005 Analytical Lab Page 10 of 97 Sample #: 2015014489 Matrix: GW_WW DF Method Analysis Date/Time Analyst Vendor Method V_SHEALY 1 EPA 353.2 05/14/2015 14:27 LSTARL1 10 EPA 300.0 05/18/2015 21:11 BGN9034 10 EPA 300.0 05/18/2015 21:11 BGN9034 Vendor Method V_SHEALY 1 EPA 200.7 05/15/2015 10:56 MHALL3 1 EPA 200.7 05/15/2015 10:56 MHALL3 1 EPA 200.7 05/15/2015 10:56 MHALL3 1 EPA 200.7 05/15/2015 10:56 MHALL3 1 EPA 200.7 05/15/2015 10:56 MHALL3 1 EPA 200.7 05/15/2015 10:56 MHALL3 1 EPA 200.7 05/15/2015 10:56 MHALL3 1 EPA 200.7 05/15/2015 13:11 MHALL3 1 EPA 200.7 05/15/2015 13:11 MHALL3 1 EPA 200.7 05/15/2015 13:11 MHALL3 1 EPA 200.7 05/15/2015 13:11 MHALL3 1 EPA 200.7 05/18/2015 10:28 MHALL3 1 EPA 200.7 05/18/2015 10:28 MHALL3 1 EPA 200.7 05/18/2015 10:28 MHALL3 1 EPA 200.7 05/18/2015 10:28 MHALL3 1 EPA 200.7 05/18/2015 10:28 MHALL3 1 EPA 200.7 05/18/2015 10:28 MHALL3 1 EPA 200.7 05/18/2015 10:28 MHALL3 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050346 Site: S-08 Collection Date: 13-May-15 5:00 PM Analyte Result DISSOLVED METALS BY ICP-MS Antimony (Sb) < 1 Arsenic (As) < 1 Beryllium (Be) < 1 Cadmium (Cd) < 1 Chromium (Cr) < 1 Cobalt (Co) 1.18 Copper (Cu) < 1 Lead (Pb) < 1 Molybdenum (Mo) < 1 Nickel (Ni) < 1 Selenium (Se) < 1 Thallium (TI) Low Level < 0.2 Vanadium (V) Low Level < 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 Arsenic (As) < 1 Beryllium (Be) < 1 Cadmium (Cd) < 1 Chromium (Cr) 2.81 Cobalt (Co) 15.3 Copper (Cu) 4.22 Lead (Pb) 2.95 Molybdenum (Mo) < 1 Nickel (Ni) 4.25 Selenium (Se) < 1 Thallium (TI) Low Level < 0.2 Vanadium (V) Low Level 5.19 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4) Complete SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 410 Total Carbon TOC 2.7 TOTAL SUSPENDED SOLIDS TSS 420 Analytical Lab Page 11 of 97 Sample #: 2015014489 Matrix: GW_WW Units Qualifiers RDL DF Method Analysis Date/Time Analyst ug/L 1 1 EPA 200.8 05/28/2015 11:42 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 11:42 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 11:42 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 11:42 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 11:42 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 11:42 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 11:42 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 11:42 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 11:42 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 11:42 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 11:42 DJSULL1 ug/L 0.2 1 EPA 200.8 05/28/2015 11:42 DJSULL1 ug/L 0.3 1 EPA 200.8 05/28/2015 11:42 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 14:07 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 14:07 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 14:07 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 14:07 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 14:07 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 14:07 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 14:07 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 14:07 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 14:07 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 14:07 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 14:07 DJSULL1 ug/L 0.2 1 EPA 200.8 05/19/2015 14:07 DJSULL1 ug/L 0.3 1 EPA 200.8 05/19/2015 14:07 DJSULL1 Vendor Method V SHEALY Vendor Method V_ELE1 mg/L 25 1 SM2540C 05/14/201514:55 AGIBBS5 mg/L 0.1 1 SM5310C/EPA9060A 05/19/201511:50 GHUTCHI mg/L 5 1 SM2540D 05/14/201511:38 AGIBBS5 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050346 Site: S-06 Collection Date: 13-May-15 4:00 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.121 mg-N/L 0.01 INORGANIC IONS BY IC Chloride 9.6 mg/L 1 Sulfate 4.4 mg/L 0.1 MERCURY IN WATER - (Analysis Performed by Shealy Labs) Vendor Parameter Complete DISSOLVED METALS BY ICP Aluminum (AI) 0.073 mg/L 0.005 Barium (Ba) 0.032 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 0.422 mg/L 0.01 Manganese (Mn) 0.616 mg/L 0.005 Strontium (Sr) 0.099 mg/L 0.005 Zinc (Zn) 0.016 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 13.7 mg/L 0.01 Magnesium (Mg) 4.99 mg/L 0.005 Potassium (K) 1.85 mg/L 0.1 Sodium (Na) 13.0 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 1.14 mg/L 0.005 Barium (Ba) 0.042 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 3.17 mg/L 0.01 Manganese (Mn) 0.670 mg/L 0.005 Strontium (Sr) 0.103 mg/L 0.005 Zinc (Zn) 0.009 mg/L 0.005 Analytical Lab Page 12 of 97 Sample #: 2015014490 Matrix: GW_WW DF Method Analysis Date/Time Analyst Vendor Method V_SHEALY 1 EPA 353.2 05/14/2015 14:31 LSTARL1 10 EPA 300.0 05/19/2015 00:20 BGN9034 1 EPA 300.0 05/19/2015 00:20 BGN9034 Vendor Method V_SHEALY 1 EPA 200.7 05/15/2015 11:00 MHALL3 1 EPA 200.7 05/15/2015 11:00 MHALL3 1 EPA 200.7 05/15/2015 11:00 MHALL3 1 EPA 200.7 05/15/2015 11:00 MHALL3 1 EPA 200.7 05/15/2015 11:00 MHALL3 1 EPA 200.7 05/15/2015 11:00 MHALL3 1 EPA 200.7 05/15/2015 11:00 MHALL3 1 EPA 200.7 05/15/2015 13:15 MHALL3 1 EPA 200.7 05/15/2015 13:15 MHALL3 1 EPA 200.7 05/15/2015 13:15 MHALL3 1 EPA 200.7 05/15/2015 13:15 MHALL3 1 EPA 200.7 05/18/2015 10:32 MHALL3 1 EPA 200.7 05/18/2015 10:32 MHALL3 1 EPA 200.7 05/18/2015 10:32 MHALL3 1 EPA 200.7 05/18/2015 10:32 MHALL3 1 EPA 200.7 05/18/2015 10:32 MHALL3 1 EPA 200.7 05/18/2015 10:32 MHALL3 1 EPA 200.7 05/18/2015 10:32 MHALL3 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050346 Site: S-06 Collection Date: 13-May-15 4:00 PM Analyte Result DISSOLVED METALS BY ICP-MS Antimony (Sb) < 1 Arsenic (As) < 1 Beryllium (Be) < 1 Cadmium (Cd) < 1 Chromium (Cr) < 1 Cobalt (Co) < 1 Copper (Cu) 1.02 Lead (Pb) < 1 Molybdenum (Mo) < 1 Nickel (Ni) < 1 Selenium (Se) < 1 Thallium (TI) Low Level < 0.2 Vanadium (V) Low Level 0.588 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 Arsenic (As) < 1 Beryllium (Be) < 1 Cadmium (Cd) < 1 Chromium (Cr) < 1 Cobalt (Co) 1.29 Copper (Cu) 1.21 Lead (Pb) < 1 Molybdenum (Mo) < 1 Nickel (Ni) < 1 Selenium (Se) < 1 Thallium (TI) Low Level < 0.2 Vanadium (V) Low Level 2.75 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4) Complete SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 140 Total Carbon TOC 4.2 TOTAL SUSPENDED SOLIDS TSS 65 Analytical Lab Page 13 of 97 Sample #: 2015014490 Matrix: GW_WW Units Qualifiers RDL DF Method Analysis Date/Time Analyst ug/L 1 1 EPA 200.8 05/28/2015 11:47 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 11:47 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 11:47 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 11:47 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 11:47 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 11:47 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 11:47 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 11:47 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 11:47 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 11:47 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 11:47 DJSULL1 ug/L 0.2 1 EPA 200.8 05/28/2015 11:47 DJSULL1 ug/L 0.3 1 EPA 200.8 05/28/2015 11:47 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 14:11 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 14:11 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 14:11 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 14:11 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 14:11 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 14:11 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 14:11 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 14:11 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 14:11 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 14:11 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 14:11 DJSULL1 ug/L 0.2 1 EPA 200.8 05/19/2015 14:11 DJSULL1 ug/L 0.3 1 EPA 200.8 05/19/2015 14:11 DJSULL1 Vendor Method V SHEALY Vendor Method V_ELE1 mg/L 25 1 SM2540C 05/14/201514:55 AGIBBS5 mg/L 0.1 1 SM5310C/EPA9060A 05/19/201511:50 GHUTCHI mg/L 5 1 SM2540D 05/14/201511:38 AGIBBS5 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050346 Site: SW-REF1 Collection Date: 13-May-15 2:10 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.058 mg-N/L 0.01 INORGANIC IONS BY IC Chloride 6.0 mg/L 0.1 Sulfate 1.8 mg/L 0.1 MERCURY IN WATER - (Analysis Performed by Shealy Labs) Vendor Parameter Complete DISSOLVED METALS BY ICP Aluminum (AI) 0.023 mg/L 0.005 Barium (Ba) 0.031 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 0.785 mg/L 0.01 Manganese (Mn) 0.315 mg/L 0.005 Strontium (Sr) 0.073 mg/L 0.005 Zinc (Zn) 0.016 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 8.24 mg/L 0.01 Magnesium (Mg) 3.60 mg/L 0.005 Potassium (K) 1.68 mg/L 0.1 Sodium (Na) 8.84 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.111 mg/L 0.005 Barium (Ba) 0.034 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 2.66 mg/L 0.01 Manganese (Mn) 0.338 mg/L 0.005 Strontium (Sr) 0.074 mg/L 0.005 Zinc (Zn) 0.007 mg/L 0.005 Analytical Lab Page 14 of 97 Sample #: 2015014491 Matrix: GW_WW DF Method Analysis Date/Time Analyst Vendor Method V_SHEALY 1 EPA 353.2 05/14/2015 14:32 LSTARL1 1 EPA 300.0 05/19/2015 00:37 BGN9034 1 EPA 300.0 05/19/2015 00:37 BGN9034 Vendor Method V_SHEALY 1 EPA 200.7 05/15/2015 11:04 MHALL3 1 EPA 200.7 05/15/2015 11:04 MHALL3 1 EPA 200.7 05/15/2015 11:04 MHALL3 1 EPA 200.7 05/15/2015 11:04 MHALL3 1 EPA 200.7 05/15/2015 11:04 MHALL3 1 EPA 200.7 05/15/2015 11:04 MHALL3 1 EPA 200.7 05/15/2015 11:04 MHALL3 1 EPA 200.7 05/15/2015 12:48 MHALL3 1 EPA 200.7 05/15/2015 12:48 MHALL3 1 EPA 200.7 05/15/2015 12:48 MHALL3 1 EPA 200.7 05/15/2015 12:48 MHALL3 1 EPA 200.7 05/18/2015 10:36 MHALL3 1 EPA 200.7 05/18/2015 10:36 MHALL3 1 EPA 200.7 05/18/2015 10:36 MHALL3 1 EPA 200.7 05/18/2015 10:36 MHALL3 1 EPA 200.7 05/18/2015 10:36 MHALL3 1 EPA 200.7 05/18/2015 10:36 MHALL3 1 EPA 200.7 05/18/2015 10:36 MHALL3 Certificate of LaboratoryAnalysis Analytical Lab y Page 15 of 97 This report shall not be reproduced, except in full. Order # J15050346 Site: SW-REF1 Sample #: 2015014491 Collection Date: 13-May-15 2:10 PM Matrix: GW_WW Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst DISSOLVED METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 1 EPA 200.8 05/28/2015 11:51 DJSULL1 Arsenic (As) < 1 ug/L 1 1 EPA 200.8 05/28/2015 11:51 DJSULL1 Beryllium (Be) < 1 ug/L 1 1 EPA 200.8 05/28/2015 11:51 DJSULL1 Cadmium (Cd) < 1 ug/L 1 1 EPA 200.8 05/28/2015 11:51 DJSULL1 Chromium (Cr) < 1 ug/L 1 1 EPA 200.8 05/28/2015 11:51 DJSULL1 Cobalt (Co) < 1 ug/L 1 1 EPA 200.8 05/28/2015 11:51 DJSULL1 Copper (Cu) 1.17 ug/L 1 1 EPA 200.8 05/28/2015 11:51 DJSULL1 Lead (Pb) < 1 ug/L 1 1 EPA 200.8 05/28/2015 11:51 DJSULL1 Molybdenum (Mo) < 1 ug/L 1 1 EPA 200.8 05/28/2015 11:51 DJSULL1 Nickel (Ni) < 1 ug/L 1 1 EPA 200.8 05/28/2015 11:51 DJSULL1 Selenium (Se) < 1 ug/L 1 1 EPA 200.8 05/28/2015 11:51 DJSULL1 Thallium (TI) Low Level < 0.2 ug/L 0.2 1 EPA 200.8 05/28/2015 11:51 DJSULL1 Vanadium (V) Low Level 0.451 ug/L 0.3 1 EPA 200.8 05/28/2015 11:51 DJSULL1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 1 EPA 200.8 05/19/2015 14:16 DJSULL1 Arsenic (As) < 1 ug/L 1 1 EPA 200.8 05/19/2015 14:16 DJSULL1 Beryllium (Be) < 1 ug/L 1 1 EPA 200.8 05/19/2015 14:16 DJSULL1 Cadmium (Cd) < 1 ug/L 1 1 EPA 200.8 05/19/2015 14:16 DJSULL1 Chromium (Cr) < 1 ug/L 1 1 EPA 200.8 05/19/2015 14:16 DJSULL1 Cobalt (Co) < 1 ug/L 1 1 EPA 200.8 05/19/2015 14:16 DJSULL1 Copper (Cu) < 1 ug/L 1 1 EPA 200.8 05/19/2015 14:16 DJSULL1 Lead (Pb) < 1 ug/L 1 1 EPA 200.8 05/19/2015 14:16 DJSULL1 Molybdenum (Mo) < 1 ug/L 1 1 EPA 200.8 05/19/2015 14:16 DJSULL1 Nickel (Ni) < 1 ug/L 1 1 EPA 200.8 05/19/2015 14:16 DJSULL1 Selenium (Se) < 1 ug/L 1 1 EPA 200.8 05/19/2015 14:16 DJSULL1 Thallium (TI) Low Level < 0.2 ug/L 0.2 1 EPA 200.8 05/19/2015 14:16 DJSULL1 Vanadium (V) Low Level 1.09 ug/L 0.3 1 EPA 200.8 05/19/2015 14:16 DJSULL1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4) Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 120 mg/L 25 1 SM2540C 05/14/201514:55 AGIBBS5 Total Carbon TOC 4.5 mg/L 0.1 1 SM5310C/EPA9060A 05/19/201511:50 GHUTCHI TOTAL SUSPENDED SOLIDS TSS 5.0 mg/L 5 1 SM2540D 05/14/201511:38 AGIBBS5 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050346 Site: S-01 Collection Date: 12-May-15 4:15 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.018 mg-N/L 0.01 INORGANIC IONS BY IC Chloride 54 mg/L 1 Sulfate 39 mg/L 1 MERCURY IN WATER - (Analysis Performed by Shealy Labs) Vendor Parameter Complete DISSOLVED METALS BY ICP Aluminum (AI) 0.020 mg/L 0.005 Barium (Ba) 0.131 mg/L 0.005 Boron (B) 1.56 mg/L 0.05 Iron (Fe) 15.1 mg/L 0.01 Manganese (Mn) 3.36 mg/L 0.005 Strontium (Sr) 0.340 mg/L 0.005 Zinc (Zn) 0.006 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 21.5 mg/L 0.01 Magnesium (Mg) 8.16 mg/L 0.005 Potassium (K) 1.63 mg/L 0.1 Sodium (Na) 35.7 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.198 mg/L 0.005 Barium (Ba) 0.142 mg/L 0.005 Boron (B) 1.56 mg/L 0.05 Iron (Fe) 22.0 mg/L 0.01 Manganese (Mn) 3.37 mg/L 0.005 Strontium (Sr) 0.346 mg/L 0.005 Zinc (Zn) 0.016 mg/L 0.005 Analytical Lab Page 16 of 97 Sample #: 2015014492 Matrix: GW_WW DF Method Analysis Date/Time Analyst Vendor Method V_SHEALY 1 EPA 353.2 05/14/2015 14:33 LSTARL1 10 EPA 300.0 05/18/2015 22:09 BGN9034 10 EPA 300.0 05/18/2015 22:09 BGN9034 Vendor Method V_SHEALY 1 EPA 200.7 05/15/2015 11:08 MHALL3 1 EPA 200.7 05/15/2015 11:08 MHALL3 1 EPA 200.7 05/15/2015 11:08 MHALL3 1 EPA 200.7 05/15/2015 11:08 MHALL3 1 EPA 200.7 05/15/2015 11:08 MHALL3 1 EPA 200.7 05/15/2015 11:08 MHALL3 1 EPA 200.7 05/15/2015 11:08 MHALL3 1 EPA 200.7 05/15/2015 13:18 MHALL3 1 EPA 200.7 05/15/2015 13:18 MHALL3 1 EPA 200.7 05/15/2015 13:18 MHALL3 1 EPA 200.7 05/15/2015 13:18 MHALL3 1 EPA 200.7 05/18/2015 10:40 MHALL3 1 EPA 200.7 05/18/2015 10:40 MHALL3 1 EPA 200.7 05/18/2015 10:40 MHALL3 1 EPA 200.7 05/18/2015 10:40 MHALL3 1 EPA 200.7 05/18/2015 10:40 MHALL3 1 EPA 200.7 05/18/2015 10:40 MHALL3 1 EPA 200.7 05/18/2015 10:40 MHALL3 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050346 Site: S-01 Collection Date: 12-May-15 4:15 PM Analyte Result DISSOLVED METALS BY ICP-MS Antimony (Sb) < 1 Arsenic (As) 2.06 Beryllium (Be) < 1 Cadmium (Cd) < 1 Chromium (Cr) < 1 Cobalt (Co) 7.88 Copper (Cu) < 1 Lead (Pb) < 1 Molybdenum (Mo) < 1 Nickel (Ni) < 1 Selenium (Se) < 1 Thallium (TI) Low Level < 0.2 Vanadium (V) Low Level < 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 Arsenic (As) 3.45 Beryllium (Be) < 1 Cadmium (Cd) < 1 Chromium (Cr) < 1 Cobalt (Co) 8.05 Copper (Cu) < 1 Lead (Pb) < 1 Molybdenum (Mo) < 1 Nickel (Ni) 1.21 Selenium (Se) < 1 Thallium (TI) Low Level < 0.2 Vanadium (V) Low Level 0.450 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4) Complete SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 260 Total Carbon TOC 1.5 TOTAL SUSPENDED SOLIDS TSS 95 Analytical Lab Page 17 of 97 Sample #: 2015014492 Matrix: GW_WW Units Qualifiers RDL DF Method Analysis Date/Time Analyst ug/L 1 1 EPA 200.8 05/28/2015 12:09 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 12:09 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 12:09 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 12:09 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 12:09 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 12:09 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 12:09 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 12:09 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 12:09 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 12:09 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 12:09 DJSULL1 ug/L 0.2 1 EPA 200.8 05/28/2015 12:09 DJSULL1 ug/L 0.3 1 EPA 200.8 05/28/2015 12:09 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 14:20 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 14:20 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 14:20 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 14:20 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 14:20 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 14:20 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 14:20 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 14:20 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 14:20 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 14:20 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 14:20 DJSULL1 ug/L 0.2 1 EPA 200.8 05/19/2015 14:20 DJSULL1 ug/L 0.3 1 EPA 200.8 05/19/2015 14:20 DJSULL1 Vendor Method V SHEALY Vendor Method V_ELE1 mg/L 25 1 SM2540C 05/14/201514:55 AGIBBS5 mg/L 0.1 1 SM5310C/EPA9060A 05/19/201511:50 GHUTCHI mg/L 5 1 SM2540D 05/14/201511:38 AGIBBS5 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050346 Site: S-02B Collection Date: 13-May-15 10:55 AM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.033 mg-N/L 0.01 INORGANIC IONS BY IC Chloride 79 mg/L 1 Sulfate 36 mg/L 1 MERCURY IN WATER - (Analysis Performed by Shealy Labs) Vendor Parameter Complete DISSOLVED METALS BY ICP Aluminum (AI) 0.007 mg/L 0.005 Barium (Ba) 0.130 mg/L 0.005 Boron (B) 1.64 mg/L 0.05 Iron (Fe) 3.20 mg/L 0.01 Manganese (Mn) 3.25 mg/L 0.005 Strontium (Sr) 0.552 mg/L 0.005 Zinc (Zn) 0.013 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 30.0 mg/L 0.01 Magnesium (Mg) 13.6 mg/L 0.005 Potassium (K) 2.53 mg/L 0.1 Sodium (Na) 21.0 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.036 mg/L 0.005 Barium (Ba) 0.135 mg/L 0.005 Boron (B) 1.64 mg/L 0.05 Iron (Fe) 3.59 mg/L 0.01 Manganese (Mn) 3.28 mg/L 0.005 Strontium (Sr) 0.563 mg/L 0.005 Zinc (Zn) 0.010 mg/L 0.005 Analytical Lab Page 18 of 97 Sample #: 2015014493 Matrix: GW_WW DF Method Analysis Date/Time Analyst Vendor Method V_SHEALY 1 EPA 353.2 05/14/2015 14:34 LSTARL1 10 EPA 300.0 05/18/2015 22:25 BGN9034 10 EPA 300.0 05/18/2015 22:25 BGN9034 Vendor Method V_SHEALY 1 EPA 200.7 05/15/2015 11:11 MHALL3 1 EPA 200.7 05/15/2015 11:11 MHALL3 1 EPA 200.7 05/15/2015 11:11 MHALL3 1 EPA 200.7 05/15/2015 11:11 MHALL3 1 EPA 200.7 05/15/2015 11:11 MHALL3 1 EPA 200.7 05/15/2015 11:11 MHALL3 1 EPA 200.7 05/15/2015 11:11 MHALL3 1 EPA 200.7 05/15/2015 13:22 MHALL3 1 EPA 200.7 05/15/2015 13:22 MHALL3 1 EPA 200.7 05/15/2015 13:22 MHALL3 1 EPA 200.7 05/15/2015 13:22 MHALL3 1 EPA 200.7 05/18/2015 10:43 MHALL3 1 EPA 200.7 05/18/2015 10:43 MHALL3 1 EPA 200.7 05/18/2015 10:43 MHALL3 1 EPA 200.7 05/18/2015 10:43 MHALL3 1 EPA 200.7 05/18/2015 10:43 MHALL3 1 EPA 200.7 05/18/2015 10:43 MHALL3 1 EPA 200.7 05/18/2015 10:43 MHALL3 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050346 Site: S-02B Collection Date: 13-May-15 10:55 AM Analyte Result DISSOLVED METALS BY ICP-MS Antimony (Sb) < 1 Arsenic (As) < 1 Beryllium (Be) < 1 Cadmium (Cd) < 1 Chromium (Cr) < 1 Cobalt (Co) 10.9 Copper (Cu) 5.02 Lead (Pb) < 1 Molybdenum (Mo) < 1 Nickel (Ni) 1.77 Selenium (Se) < 1 Thallium (TI) Low Level < 0.2 Vanadium (V) Low Level < 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 Arsenic (As) < 1 Beryllium (Be) < 1 Cadmium (Cd) < 1 Chromium (Cr) < 1 Cobalt (Co) 10.1 Copper (Cu) < 1 Lead (Pb) < 1 Molybdenum (Mo) < 1 Nickel (Ni) 2.04 Selenium (Se) < 1 Thallium (TI) Low Level < 0.2 Vanadium (V) Low Level < 0.3 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4) Complete SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 280 Total Carbon TOC 1.2 TOTAL SUSPENDED SOLIDS TSS 6.0 Analytical Lab Page 19 of 97 Sample #: 2015014493 Matrix: GW_WW Units Qualifiers RDL DF Method Analysis Date/Time Analyst ug/L 1 1 EPA 200.8 05/28/2015 12:27 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 12:27 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 12:27 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 12:27 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 12:27 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 12:27 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 12:27 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 12:27 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 12:27 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 12:27 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 12:27 DJSULL1 ug/L 0.2 1 EPA 200.8 05/28/2015 12:27 DJSULL1 ug/L 0.3 1 EPA 200.8 05/28/2015 12:27 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 14:25 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 14:25 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 14:25 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 14:25 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 14:25 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 14:25 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 14:25 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 14:25 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 14:25 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 14:25 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 14:25 DJSULL1 ug/L 0.2 1 EPA 200.8 05/19/2015 14:25 DJSULL1 ug/L 0.3 1 EPA 200.8 05/19/2015 14:25 DJSULL1 Vendor Method V SHEALY Vendor Method V_ELE1 mg/L 25 1 SM2540C 05/14/201514:55 AGIBBS5 mg/L 0.1 1 SM5310C/EPA9060A 05/19/201511:50 GHUTCHI mg/L 5 1 SM2540D 05/14/201511:38 AGIBBS5 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050346 Site: S-02B Dup Collection Date: 13-May-15 11:15 AM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.035 mg-N/L 0.01 INORGANIC IONS BY IC Chloride 79 mg/L 1 Sulfate 35 mg/L 1 MERCURY IN WATER - (Analysis Performed by Shealy Labs) Vendor Parameter Complete DISSOLVED METALS BY ICP Aluminum (AI) 0.006 mg/L 0.005 Barium (Ba) 0.130 mg/L 0.005 Boron (B) 1.63 mg/L 0.05 Iron (Fe) 3.15 mg/L 0.01 Manganese (Mn) 3.25 mg/L 0.005 Strontium (Sr) 0.552 mg/L 0.005 Zinc (Zn) 0.010 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 30.0 mg/L 0.01 Magnesium (Mg) 13.5 mg/L 0.005 Potassium (K) 2.53 mg/L 0.1 Sodium (Na) 21.0 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.024 mg/L 0.005 Barium (Ba) 0.133 mg/L 0.005 Boron (B) 1.63 mg/L 0.05 Iron (Fe) 3.33 mg/L 0.01 Manganese (Mn) 3.28 mg/L 0.005 Strontium (Sr) 0.559 mg/L 0.005 Zinc (Zn) 0.010 mg/L 0.005 Analytical Lab Page 20 of 97 Sample #: 2015014494 Matrix: GW_WW DF Method Analysis Date/Time Analyst Vendor Method V_SHEALY 1 EPA 353.2 05/14/2015 14:35 LSTARL1 10 EPA 300.0 05/18/2015 22:42 BGN9034 10 EPA 300.0 05/18/2015 22:42 BGN9034 Vendor Method V_SHEALY 1 EPA 200.7 05/15/2015 11:15 MHALL3 1 EPA 200.7 05/15/2015 11:15 MHALL3 1 EPA 200.7 05/15/2015 11:15 MHALL3 1 EPA 200.7 05/15/2015 11:15 MHALL3 1 EPA 200.7 05/15/2015 11:15 MHALL3 1 EPA 200.7 05/15/2015 11:15 MHALL3 1 EPA 200.7 05/15/2015 11:15 MHALL3 1 EPA 200.7 05/15/2015 13:26 MHALL3 1 EPA 200.7 05/15/2015 13:26 MHALL3 1 EPA 200.7 05/15/2015 13:26 MHALL3 1 EPA 200.7 05/15/2015 13:26 MHALL3 1 EPA 200.7 05/18/2015 10:55 MHALL3 1 EPA 200.7 05/18/2015 10:55 MHALL3 1 EPA 200.7 05/18/2015 10:55 MHALL3 1 EPA 200.7 05/18/2015 10:55 MHALL3 1 EPA 200.7 05/18/2015 10:55 MHALL3 1 EPA 200.7 05/18/2015 10:55 MHALL3 1 EPA 200.7 05/18/2015 10:55 MHALL3 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050346 Site: S-02B Dup Collection Date: 13-May-15 11:15 AM Analyte Result DISSOLVED METALS BY ICP-MS Antimony (Sb) < 1 Arsenic (As) < 1 Beryllium (Be) < 1 Cadmium (Cd) < 1 Chromium (Cr) < 1 Cobalt (Co) 10.8 Copper (Cu) < 1 Lead (Pb) < 1 Molybdenum (Mo) < 1 Nickel (Ni) 1.82 Selenium (Se) < 1 Thallium (TI) Low Level < 0.2 Vanadium (V) Low Level < 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 Arsenic (As) < 1 Beryllium (Be) < 1 Cadmium (Cd) < 1 Chromium (Cr) < 1 Cobalt (Co) 10.1 Copper (Cu) < 1 Lead (Pb) < 1 Molybdenum (Mo) < 1 Nickel (Ni) 1.68 Selenium (Se) < 1 Thallium (TI) Low Level < 0.2 Vanadium (V) Low Level < 0.3 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4) Complete SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 330 Total Carbon TOC 1.3 TOTAL SUSPENDED SOLIDS TSS 5.0 Analytical Lab Page 21 of 97 Sample #: 2015014494 Matrix: GW_WW Units Qualifiers RDL DF Method Analysis Date/Time Analyst ug/L 1 1 EPA 200.8 05/28/2015 12:32 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 12:32 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 12:32 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 12:32 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 12:32 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 12:32 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 12:32 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 12:32 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 12:32 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 12:32 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 12:32 DJSULL1 ug/L 0.2 1 EPA 200.8 05/28/2015 12:32 DJSULL1 ug/L 0.3 1 EPA 200.8 05/28/2015 12:32 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 14:30 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 14:30 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 14:30 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 14:30 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 14:30 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 14:30 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 14:30 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 14:30 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 14:30 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 14:30 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 14:30 DJSULL1 ug/L 0.2 1 EPA 200.8 05/19/2015 14:30 DJSULL1 ug/L 0.3 1 EPA 200.8 05/19/2015 14:30 DJSULL1 Vendor Method V SHEALY Vendor Method V_ELE1 mg/L 25 1 SM2540C 05/14/201514:55 AGIBBS5 mg/L 0.1 1 SM5310C/EPA9060A 05/19/201511:50 GHUTCHI mg/L 5 1 SM2540D 05/14/201511:38 AGIBBS5 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050346 Site: S-04 Collection Date: 13-May-15 10:20 AM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) < 0.01 mg-N/L 0.01 INORGANIC IONS BY IC Chloride 49 mg/L 1 Sulfate 35 mg/L 1 MERCURY IN WATER - (Analysis Performed by Shealy Labs) Vendor Parameter Complete DISSOLVED METALS BY ICP Aluminum (AI) 0.010 mg/L 0.005 Barium (Ba) 0.136 mg/L 0.005 Boron (B) 1.30 mg/L 0.05 Iron (Fe) 7.45 mg/L R1 0.01 Manganese (Mn) 3.52 mg/L 0.005 Strontium (Sr) 0.301 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 21.2 mg/L 0.01 Magnesium (Mg) 7.95 mg/L 0.005 Potassium (K) 1.65 mg/L 0.1 Sodium (Na) 34.6 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.034 mg/L 0.005 Barium (Ba) 0.148 mg/L 0.005 Boron (B) 1.34 mg/L 0.05 Iron (Fe) 11.4 mg/L 0.01 Manganese (Mn) 3.62 mg/L 0.005 Strontium (Sr) 0.313 mg/L 0.005 Zinc (Zn) 0.007 mg/L 0.005 Analytical Lab Page 22 of 97 Sample #: 2015014495 Matrix: GW_WW DF Method Analysis Date/Time Analyst Vendor Method V_SHEALY 1 EPA 353.2 05/14/2015 14:37 LSTARL1 10 EPA 300.0 05/18/2015 22:58 BGN9034 10 EPA 300.0 05/18/2015 22:58 BGN9034 Vendor Method V_SHEALY 1 EPA 200.7 05/15/2015 12:14 MHALL3 1 EPA 200.7 05/15/2015 12:14 MHALL3 1 EPA 200.7 05/15/2015 12:14 MHALL3 1 EPA 200.7 05/15/2015 12:14 MHALL3 1 EPA 200.7 05/15/2015 12:14 MHALL3 1 EPA 200.7 05/15/2015 12:14 MHALL3 1 EPA 200.7 05/15/2015 12:14 MHALL3 1 EPA 200.7 05/15/2015 13:30 MHALL3 1 EPA 200.7 05/15/2015 13:30 MHALL3 1 EPA 200.7 05/15/2015 13:30 MHALL3 1 EPA 200.7 05/15/2015 13:30 MHALL3 1 EPA 200.7 05/18/2015 11:06 MHALL3 1 EPA 200.7 05/18/2015 11:06 MHALL3 1 EPA 200.7 05/18/2015 11:06 MHALL3 1 EPA 200.7 05/18/2015 11:06 MHALL3 1 EPA 200.7 05/18/2015 11:06 MHALL3 1 EPA 200.7 05/18/2015 11:06 MHALL3 1 EPA 200.7 05/18/2015 11:06 MHALL3 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050346 Site: S-04 Collection Date: 13-May-15 10:20 AM Analyte Result DISSOLVED METALS BY ICP-MS Antimony (Sb) < 1 Arsenic (As) < 1 Beryllium (Be) < 1 Cadmium (Cd) < 1 Chromium (Cr) < 1 Cobalt (Co) 8.75 Copper (Cu) < 1 Lead (Pb) < 1 Molybdenum (Mo) < 1 Nickel (Ni) < 1 Selenium (Se) < 1 Thallium (TI) Low Level < 0.2 Vanadium (V) Low Level < 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 Arsenic (As) 1.40 Beryllium (Be) < 1 Cadmium (Cd) < 1 Chromium (Cr) < 1 Cobalt (Co) 8.23 Copper (Cu) < 1 Lead (Pb) < 1 Molybdenum (Mo) < 1 Nickel (Ni) 1.10 Selenium (Se) < 1 Thallium (TI) Low Level < 0.2 Vanadium (V) Low Level < 0.3 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4) Complete SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 240 Total Carbon TOC 1.4 TOTAL SUSPENDED SOLIDS TSS 28 Analytical Lab Page 23 of 97 Sample #: 2015014495 Matrix: GW_WW Units Qualifiers RDL DF Method Analysis Date/Time Analyst ug/L 1 1 EPA 200.8 05/28/2015 12:36 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 12:36 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 12:36 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 12:36 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 12:36 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 12:36 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 12:36 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 12:36 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 12:36 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 12:36 DJSULL1 ug/L 1 1 EPA 200.8 05/28/2015 12:36 DJSULL1 ug/L 0.2 1 EPA 200.8 05/28/2015 12:36 DJSULL1 ug/L 0.3 1 EPA 200.8 05/28/2015 12:36 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 14:48 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 14:48 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 14:48 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 14:48 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 14:48 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 14:48 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 14:48 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 14:48 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 14:48 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 14:48 DJSULL1 ug/L 1 1 EPA 200.8 05/19/2015 14:48 DJSULL1 ug/L 0.2 1 EPA 200.8 05/19/2015 14:48 DJSULL1 ug/L 0.3 1 EPA 200.8 05/19/2015 14:48 DJSULL1 Vendor Method V SHEALY Vendor Method V_ELE1 mg/L 25 1 SM2540C 05/14/201514:55 AGIBBS5 mg/L 0.1 1 SM5310C/EPA9060A 05/19/201511:50 GHUTCHI mg/L 5 1 SM2540D 05/14/201511:38 AGIBBS5 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050346 Site: SW-CB2 Collection Date: 13-May-15 12:45 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.052 mg-N/L 0.01 INORGANIC IONS BY IC Chloride 26 mg/L 1 Sulfate 5.0 mg/L 0.1 MERCURY IN WATER - (Analysis Performed by Shealy Labs) Vendor Parameter Complete DISSOLVED METALS BY ICP Aluminum (AI) 0.038 mg/L 0.005 Barium (Ba) 0.084 mg/L 0.005 Boron (B) 0.448 mg/L 0.05 Iron (Fe) 2.13 mg/L 0.01 Manganese (Mn) 8.24 mg/L 0.005 Strontium (Sr) 0.213 mg/L 0.005 Zinc (Zn) 0.008 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 16.9 mg/L 0.01 Magnesium (Mg) 6.57 mg/L 0.005 Potassium (K) 2.25 mg/L 0.1 Sodium (Na) 13.7 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.148 mg/L 0.005 Barium (Ba) 0.089 mg/L 0.005 Boron (B) 0.455 mg/L 0.05 Iron (Fe) 4.16 mg/L 0.01 Manganese (Mn) 8.33 mg/L 0.005 Strontium (Sr) 0.217 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 Analytical Lab Page 24 of 97 Sample #: 2015014496 Matrix: GW_WW DF Method Analysis Date/Time Analyst Vendor Method V_SHEALY 1 EPA 353.2 05/14/2015 14:38 LSTARL1 10 EPA 300.0 05/19/2015 01:59 BGN9034 1 EPA 300.0 05/19/2015 01:59 BGN9034 Vendor Method V_SHEALY 1 EPA 200.7 05/15/2015 12:10 MHALL3 1 EPA 200.7 05/15/2015 12:10 MHALL3 1 EPA 200.7 05/15/2015 12:10 MHALL3 1 EPA 200.7 05/15/2015 12:10 MHALL3 1 EPA 200.7 05/15/2015 12:10 MHALL3 1 EPA 200.7 05/15/2015 12:10 MHALL3 1 EPA 200.7 05/15/2015 12:10 MHALL3 1 EPA 200.7 05/15/2015 13:41 MHALL3 1 EPA 200.7 05/15/2015 13:41 MHALL3 1 EPA 200.7 05/15/2015 13:41 MHALL3 1 EPA 200.7 05/15/2015 13:41 MHALL3 1 EPA 200.7 05/18/2015 11:10 MHALL3 1 EPA 200.7 05/18/2015 11:10 MHALL3 1 EPA 200.7 05/18/2015 11:10 MHALL3 1 EPA 200.7 05/18/2015 11:10 MHALL3 1 EPA 200.7 05/18/2015 11:10 MHALL3 1 EPA 200.7 05/18/2015 11:10 MHALL3 1 EPA 200.7 05/18/2015 11:10 MHALL3 Certificate of LaboratoryAnalysis Analytical Lab y Page 25 of 97 This report shall not be reproduced, except in full. Order # J15050346 Site: SW-CB2 Sample #: 2015014496 Collection Date: 13-May-15 12:45 PM Matrix: GW_WW Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst DISSOLVED METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 1 EPA 200.8 05/28/2015 12:41 DJSULL1 Arsenic (As) < 1 ug/L 1 1 EPA 200.8 05/28/2015 12:41 DJSULL1 Beryllium (Be) < 1 ug/L 1 1 EPA 200.8 05/28/2015 12:41 DJSULL1 Cadmium (Cd) < 1 ug/L 1 1 EPA 200.8 05/28/2015 12:41 DJSULL1 Chromium (Cr) < 1 ug/L 1 1 EPA 200.8 05/28/2015 12:41 DJSULL1 Cobalt (Co) 2.71 ug/L 1 1 EPA 200.8 05/28/2015 12:41 DJSULL1 Copper (Cu) < 1 ug/L 1 1 EPA 200.8 05/28/2015 12:41 DJSULL1 Lead (Pb) < 1 ug/L 1 1 EPA 200.8 05/28/2015 12:41 DJSULL1 Molybdenum (Mo) < 1 ug/L 1 1 EPA 200.8 05/28/2015 12:41 DJSULL1 Nickel (Ni) < 1 ug/L 1 1 EPA 200.8 05/28/2015 12:41 DJSULL1 Selenium (Se) < 1 ug/L 1 1 EPA 200.8 05/28/2015 12:41 DJSULL1 Thallium (TI) Low Level < 0.2 ug/L 0.2 1 EPA 200.8 05/28/2015 12:41 DJSULL1 Vanadium (V) Low Level 0.397 ug/L 0.3 1 EPA 200.8 05/28/2015 12:41 DJSULL1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 1 EPA 200.8 05/19/2015 15:02 DJSULL1 Arsenic (As) 1.06 ug/L 1 1 EPA 200.8 05/19/2015 15:02 DJSULL1 Beryllium (Be) < 1 ug/L 1 1 EPA 200.8 05/19/2015 15:02 DJSULL1 Cadmium (Cd) < 1 ug/L 1 1 EPA 200.8 05/19/2015 15:02 DJSULL1 Chromium (Cr) < 1 ug/L 1 1 EPA 200.8 05/19/2015 15:02 DJSULL1 Cobalt (Co) 2.73 ug/L 1 1 EPA 200.8 05/19/2015 15:02 DJSULL1 Copper (Cu) < 1 ug/L 1 1 EPA 200.8 05/19/2015 15:02 DJSULL1 Lead (Pb) < 1 ug/L 1 1 EPA 200.8 05/19/2015 15:02 DJSULL1 Molybdenum (Mo) < 1 ug/L 1 1 EPA 200.8 05/19/2015 15:02 DJSULL1 Nickel (Ni) < 1 ug/L 1 1 EPA 200.8 05/19/2015 15:02 DJSULL1 Selenium (Se) < 1 ug/L 1 1 EPA 200.8 05/19/2015 15:02 DJSULL1 Thallium (TI) Low Level < 0.2 ug/L 0.2 1 EPA 200.8 05/19/2015 15:02 DJSULL1 Vanadium (V) Low Level 0.811 ug/L 0.3 1 EPA 200.8 05/19/2015 15:02 DJSULL1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4) Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 170 mg/L 25 1 SM2540C 05/14/201514:55 AGIBBS5 Total Carbon TOC 7.8 mg/L 0.1 1 SM5310C/EPA9060A 05/19/201511:50 GHUTCHI TOTAL SUSPENDED SOLIDS TSS 30 mg/L 5 1 SM2540D 05/15/2015 08:13 AGIBBS5 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050346 Site: FIELD BLANK Collection Date: 13-May-15 6:45 PM Analyte Result Units Qualifiers RDL DF MERCURY IN WATER - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Sample #: Matrix: 2015014498 GW_WW Analytical Lab Page 26 of 97 Method Analysis Date/Time Analyst Vendor Method V_SHEALY Certificate of LaboratoryAnalysis Analytical Lab y Page 27 of 97 This report shall not be reproduced, except in full. Order # J15050346 Site: Trip Blank Collection Date: Analyte Result Units Qualifiers RDL DF MERCURY IN WATER - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Sample #: 2015014504 Matrix: GW WW Method Analysis Date/Time Analyst Vendor Method V_SHEALY Site: Filter Blank Collection Date: 13-May-15 6:45 PM Analyte DISSOLVED METALS BY ICP Aluminum (AI) Barium (Ba) Boron (B) Iron (Fe) Manganese (Mn) Strontium (Sr) Zinc (Zn) DISSOLVED METALS BY ICP-MS Antimony (Sb) Arsenic (As) Beryllium (Be) Cadmium (Cd) Chromium (Cr) Cobalt (Co) Copper (Cu) Lead (Pb) Molybdenum (Mo) Nickel (Ni) Selenium (Se) Thallium (TI) Low Level Vanadium (V) Low Level Certificate of LaboratoryAnalysis Analytical Lab y Page 28 of 97 This report shall not be reproduced, except in full. Order # J15050346 Sample #: 2015014505 Matrix: GW WW Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst < 0.005 mg/L 0.005 1 EPA 200.7 05/15/2015 11:42 MHALL3 < 0.005 mg/L 0.005 1 EPA 200.7 05/15/2015 11:42 MHALL3 < 0.05 mg/L 0.05 1 EPA 200.7 05/15/2015 11:42 MHALL3 < 0.01 mg/L 0.01 1 EPA 200.7 05/15/2015 11:42 MHALL3 < 0.005 mg/L 0.005 1 EPA 200.7 05/15/2015 11:42 MHALL3 < 0.005 mg/L 0.005 1 EPA 200.7 05/15/2015 11:42 MHALL3 < 0.005 mg/L 0.005 1 EPA 200.7 05/15/2015 11:42 MHALL3 < 1 ug/L 1 1 EPA 200.8 05/28/2015 12:23 DJSULL1 < 1 ug/L 1 1 EPA 200.8 05/28/2015 12:23 DJSULL1 < 1 ug/L 1 1 EPA 200.8 05/28/2015 12:23 DJSULL1 < 1 ug/L 1 1 EPA 200.8 05/28/2015 12:23 DJSULL1 < 1 ug/L 1 1 EPA 200.8 05/28/2015 12:23 DJSULL1 < 1 ug/L 1 1 EPA 200.8 05/28/2015 12:23 DJSULL1 < 1 ug/L 1 1 EPA 200.8 05/28/2015 12:23 DJSULL1 < 1 ug/L 1 1 EPA 200.8 05/28/2015 12:23 DJSULL1 < 1 ug/L 1 1 EPA 200.8 05/28/2015 12:23 DJSULL1 < 1 ug/L 1 1 EPA 200.8 05/28/2015 12:23 DJSULL1 < 1 ug/L 1 1 EPA 200.8 05/28/2015 12:23 DJSULL1 < 0.2 ug/L 0.2 1 EPA 200.8 05/28/2015 12:23 DJSULL1 < 0.3 ug/L 0.3 1 EPA 200.8 05/28/2015 12:23 DJSULL1 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050346 Site: SW-CB1 Collection Date: 13-May-15 11:40 AM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.625 mg-N/L 0.01 INORGANIC IONS BY IC Chloride 58 mg/L 1 Sulfate 30 mg/L 1 MERCURY IN WATER - (Analysis Performed by Shealy Labs) Vendor Parameter Complete DISSOLVED METALS BY ICP Aluminum (AI) 0.009 mg/L 0.005 Barium (Ba) 0.085 mg/L 0.005 Boron (B) 1.14 mg/L 0.05 Iron (Fe) 1.60 mg/L 0.01 Manganese (Mn) 2.10 mg/L 0.005 Strontium (Sr) 0.411 mg/L 0.005 Zinc (Zn) 0.012 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 25.5 mg/L 0.01 Magnesium (Mg) 9.98 mg/L 0.005 Potassium (K) 2.09 mg/L 0.1 Sodium (Na) 23.1 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.965 mg/L 0.005 Barium (Ba) 0.101 mg/L 0.005 Boron (B) 1.15 mg/L 0.05 Iron (Fe) 4.32 mg/L 0.01 Manganese (Mn) 2.35 mg/L 0.005 Strontium (Sr) 0.425 mg/L 0.005 Zinc (Zn) 0.013 mg/L 0.005 Analytical Lab Page 29 of 97 Sample #: 2015014506 Matrix: GW_WW DF Method Analysis Date/Time Analyst Vendor Method V_SHEALY 1 EPA 353.2 05/14/2015 14:39 LSTARL1 10 EPA 300.0 05/20/2015 18:34 BGN9034 10 EPA 300.0 05/20/2015 18:34 BGN9034 Vendor Method V_SHEALY 1 EPA 200.7 05/15/2015 11:46 MHALL3 1 EPA 200.7 05/15/2015 11:46 MHALL3 1 EPA 200.7 05/15/2015 11:46 MHALL3 1 EPA 200.7 05/15/2015 11:46 MHALL3 1 EPA 200.7 05/15/2015 11:46 MHALL3 1 EPA 200.7 05/15/2015 11:46 MHALL3 1 EPA 200.7 05/15/2015 11:46 MHALL3 1 EPA 200.7 05/15/2015 13:53 MHALL3 1 EPA 200.7 05/15/2015 13:53 MHALL3 1 EPA 200.7 05/15/2015 13:53 MHALL3 1 EPA 200.7 05/15/2015 13:53 MHALL3 1 EPA 200.7 05/18/2015 11:14 MHALL3 1 EPA 200.7 05/18/2015 11:14 MHALL3 1 EPA 200.7 05/18/2015 11:14 MHALL3 1 EPA 200.7 05/18/2015 11:14 MHALL3 1 EPA 200.7 05/18/2015 11:14 MHALL3 1 EPA 200.7 05/18/2015 11:14 MHALL3 1 EPA 200.7 05/18/2015 11:14 MHALL3 Certificate of LaboratoryAnalysis Analytical Lab y Page 30 of 97 This report shall not be reproduced, except in full. Order # J15050346 Site: SW-CB1 Sample #: 2015014506 Collection Date: 13-May-15 11:40 AM Matrix: GW_WW Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst DISSOLVED METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 1 EPA 200.8 05/28/2015 12:46 DJSULL1 Arsenic (As) < 1 ug/L 1 1 EPA 200.8 05/28/2015 12:46 DJSULL1 Beryllium (Be) < 1 ug/L 1 1 EPA 200.8 05/28/2015 12:46 DJSULL1 Cadmium (Cd) < 1 ug/L 1 1 EPA 200.8 05/28/2015 12:46 DJSULL1 Chromium (Cr) < 1 ug/L 1 1 EPA 200.8 05/28/2015 12:46 DJSULL1 Cobalt (Co) 3.05 ug/L 1 1 EPA 200.8 05/28/2015 12:46 DJSULL1 Copper (Cu) < 1 ug/L 1 1 EPA 200.8 05/28/2015 12:46 DJSULL1 Lead (Pb) < 1 ug/L 1 1 EPA 200.8 05/28/2015 12:46 DJSULL1 Molybdenum (Mo) < 1 ug/L 1 1 EPA 200.8 05/28/2015 12:46 DJSULL1 Nickel (Ni) < 1 ug/L 1 1 EPA 200.8 05/28/2015 12:46 DJSULL1 Selenium (Se) < 1 ug/L 1 1 EPA 200.8 05/28/2015 12:46 DJSULL1 Thallium (TI) Low Level < 0.2 ug/L 0.2 1 EPA 200.8 05/28/2015 12:46 DJSULL1 Vanadium (V) Low Level < 0.3 ug/L 0.3 1 EPA 200.8 05/28/2015 12:46 DJSULL1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 1 EPA 200.8 05/19/2015 15:06 DJSULL1 Arsenic (As) < 1 ug/L 1 1 EPA 200.8 05/19/2015 15:06 DJSULL1 Beryllium (Be) < 1 ug/L 1 1 EPA 200.8 05/19/2015 15:06 DJSULL1 Cadmium (Cd) < 1 ug/L 1 1 EPA 200.8 05/19/2015 15:06 DJSULL1 Chromium (Cr) 1.25 ug/L 1 1 EPA 200.8 05/19/2015 15:06 DJSULL1 Cobalt (Co) 4.20 ug/L 1 1 EPA 200.8 05/19/2015 15:06 DJSULL1 Copper (Cu) 1.65 ug/L 1 1 EPA 200.8 05/19/2015 15:06 DJSULL1 Lead (Pb) < 1 ug/L 1 1 EPA 200.8 05/19/2015 15:06 DJSULL1 Molybdenum (Mo) < 1 ug/L 1 1 EPA 200.8 05/19/2015 15:06 DJSULL1 Nickel (Ni) 1.52 ug/L 1 1 EPA 200.8 05/19/2015 15:06 DJSULL1 Selenium (Se) < 1 ug/L 1 1 EPA 200.8 05/19/2015 15:06 DJSULL1 Thallium (TI) Low Level < 0.2 ug/L 0.2 1 EPA 200.8 05/19/2015 15:06 DJSULL1 Vanadium (V) Low Level 1.83 ug/L 0.3 1 EPA 200.8 05/19/2015 15:06 DJSULL1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4) Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 220 mg/L 25 1 SM2540C 05/14/201514:55 AGIBBS5 Total Carbon TOC 2.8 mg/L 0.1 1 SM5310C/EPA9060A 05/19/201511:50 GHUTCHI TOTAL SUSPENDED SOLIDS TSS 49 mg/L 5 1 SM2540D 05/15/2015 08:13 AGIBBS5 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050346 Site: SW-CB1 Collection Date: 13-May-15 11:40 AM Analyte SamDle #: 2015014506 Matrix: GW_WW Analytical Lab Page 31 of 97 Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst Qualifiers: R1 Relative Percent Difference exceeded method acceptance limits, see additional notes. -- Additional Information -- R1 - Iron % RPD > 20% in the MS/MSD of this sample (21 %). Matrix interference from the sample concentration is suspected. All other QC recoveries were within the limits. Analytical Lab Page 32 of 97 Element One Inc. 6319-D Carolina Beach Rd. Wilmington, INIC 28412 Phone: 910 793-0128 Fax: 910 792-6853 e1lab@e1lab.com REPORT OF ANALYSES Duke Energy May 29, 2015 Laboratory Services Client Project Name AB GW Assessment water Mayo Steam 13339 Hagers Ferry Road Bid. MG03A Client Project Number J15050346 Huntersville, NC 28078 PO Number Sample Matrix Sample Type Grab Date Received 05/14/2015 Date Analyzed 05/15/2015 Method SM 4500 S2- D Time Received 1635 Delivered by FedEx Received by JRC eOne ID Duke Energy ID Parameter Result Unit Dil DL Date Time Sampled Sampled 24764-1 S-02 Sulfide < 0.1 mg/L 1 0.1 05/12/15 1510 24764-2 S-05 Sulfide < 0.1 mg/L 1 0.1 05/12/15 1210 24764-3* S-03 Sulfide < 0.5 mg/L 5 0.1 05/12/15 1425 24764-4* S-08 Sulfide < 0.5 mg/L 5 0.1 05/13/15 1700 24764-5* S-06 Sulfide < 0.5 mg/L 5 0.1 05/13/15 1600 24764-6 SW-REF1 Sulfide < 0.1 mg/L 1 0.1 05/13/15 1410 24764-7 S-01 Sulfide < 0.1 mg/L 1 0.1 05/12/15 1615 24764-8 S-02B Sulfide < 0.1 mg/L 1 0.1 05/13/15 1055 *Sample spike recovery outside of QA limits of 85-115%; dilution necessary to meet laboratory QA limits. Rev. 05.21.15 was to correct the time sampled for sample S-08. Rev. 05.29.15 was to correct an entry error. All samples were analyzed within hold -time. Ken gmiN, Laboratory Director 24764 Duke Report Packet Rev. 05.29.15 Compiled byl—&-s— NC Certifications: DW 37788 and DWQ DENR 604 Analytical Lab Page 33 of 97 Elernent One 9nc. 6319-D Carolina Beach Rd. Wilmington, NC 28412 Phone: 910 793-0128 Fax: 910 792-6853 110 F- 41 b e a W—C a .com rsk-�hmrr%ntOne REPORT OF ANALYSES Duke Energy May 29, 2015 Laboratory Services Client Project Name AB GW Assessment water Mayo Steam 13339 Hagers Ferry Road Bld. MG03A Client Project Number J15050346 Huntersville, NC 28078 PO Number Sample Matrix Sample Type Grab Date Received 05/14/2015 Date Analyzed 05/15/2015 Method SM 4500 S2- D Time Received 1635 Delivered by FedEx Received by JRC eOne ID Duke Energy ID Parameter Result Unit Dil DL Date Time Sampled Sampled 24764-9 S-02B Dup Sulfide < 0.1 mg/L 1 0.1 05/13/15 1115 24764-10 S-04 Sulfide < 0.1 mg/L 1 0.1 05/13/15 1020 24764-11 SW-CB2 Sulfide < 0.1 mg/L 1 0.1 05/13/15 1245 24764-12"" SW-CB1 Sulfide < 1.0 mg/L 10 0.1 05/13/15 1140 *Sample spike recovery outside of QA limits of 85-115%; dilution necessary to meet laboratory QA limits. "Sample spike recovery outside of QA limits of 85-115%; dilution necessary. Unable to meet laboratory QA limits. Rev. 05.29.15 was to correct an entry error. All samples were analyzed within hold -time. — (4 /;�W� Ken Smith, Laboratory Director 24764 Duke Report Packet Rev. 05.29.15 Compiled by_V__I_J NC Certifications: DW 37788 and DWQ DENR 604 Analytical Lab Page 34 of 97 9 06 Cn �.j Z1 Q �i Zi O U W C O H N M U U. Z Q S U v rwlyuo� pt101 e e o 0 0 0 0 0 0 0 0 0 0 0 C Nsinew � o OMoIBQ '�a 8 l V z gas) sinew � a aQ° b 2 IV n O ¢ O o YYY �3 •►mom d� 7 (61UOW813jnS w S i op"l S punonuinl pailssp IA11849 A ala1IPul asaold :tueLodwl'�ewo�sn� 8 8 Gl*uognO . puogiTala .,s r r ... _..�.► 'Rllul1h41'0 s g 1141N ... � �, -OIWVN'001 J Vl i g g '4OS'I0 8 i i E w ARs49A It[I i b Heal ~ SM'SS, — H I Q d i 0E 8 q.0 x €I 4qE •Awo� 2 I 'FI CS } ' rJ F > ee qW M I O g$ O �n 1 K ass Cn O �1 an° �II� S7 do' ac y a� IN V G1 _ _ E p = p r._._._.r_ i N d m q' S CL o a 9 L V1 �If a� is qq ku a - e b at N i Y fs6' o Eqq a 1 a CO. oa�• Sea m 4j a O t LL LLIv1 t7 ��3 i 3 b N 1` i E S ' o a a U) i �a 1 4 z H O r i 1LU tu O W W bs i Ip W W W. Qs ? or J I a • c � ', i •SAY ��11 1�f� e ernentOne SAMPLE SUBMISSION FORM TAT 7 BD Hold Time Expiration 05.19.15 @ 1210 Client: Duke Energy LIMS No J15050346 Project ID Mao m Analytical Lab IYage��+/ lL04 Analysis Due Date 05.20.15 Report Due Date 05.22.15 Date Rec: 05.14.15 Time Rec: 1635 Rec By J RC H >9 Yes No Temp<_ 6°C Yes No Ref. Method: SM4500 S2 D If No, Record �_� If No, Record a7d111 IC IuC1.L11116dLIVII Ol VVIIGGLIVII 1111VIII14LIVII Lab ID Client ID Collection Date Collection Time Analysis Requested 1 S-02 05/12/15 1510 Sulfide 2 S-05 05/12/15 1210 Sulfide 3 S-03 05/12/15 1425 Sulfide 4 S-08 05/13/15 1200 Sulfide 5 S-06 05/13/15 1600 Sulfide 6 SW-REF1 05/13/15 1410 Sulfide 7 S-01 05/12/15 1615 Sulfide 8 S-026 — /15 1055 Sulfide 9 S-02B Dup _05113 05/13/15 _1115 Sulfide 10 S-04 05/13/15 1020 Sulfide 11 SW-CB2 05/13/15 1245 Sulfide 12 SW-CB1 05/13/15 1140 Sulfide NOTE for Sulfide The MS/MSD spike should approximate 2 to 3 times the sample concentration. If no sulfide detected at 100 pg/L spike the sample to render the final spike concentration at - 500 pg/L Lab Communications All AB Groundwater Assessment jobs need a RL of 0.1 SS Page 1 of 1 Prep By /Date lG-ss-6 15 SS by Labeled By / Date s 5/14/201 :37:29 PM ID Verification By /Date _ 1 Analytical Lab Page 36 of 97 METHOD: SM 4500 S2- D ELEMENT ONE ELEMENT ASSAY: Sulfide Spectrophotometer Wave Length 664 UNITS OF ANSWER u /mL DETECTION LIMIT u 1.000 CLIENT: Duke SPK LEVELjqM 5 Lab ID# 24769/764/768/770/713 MAX ALIQUOT 05.15.15 Na2S•9H2O Lot # STANDARD conc(ppm) 800 40721 Cal Std Lot: WC2-80-5 1300 QC Std Lot: WC2-80-6 KLS Page 1 of 4 STD ABSORPTION Y 10.00 Date: X Time Analysis Begun 10 Time Analysis Ended Analyst: Y X ug STD SOLUTION STD 0.8w ABS o,00 _ - - - --- - -- . -- -- ----- 0.00 1.00 2.50 5.00 7.50 10.00 0.000 0800 0.098 Y 0400 .439-iso 0.232 0.300 .,M 0.439 01M a00° 0.64 0.785 00 z.ao 460 6M a.ao 10.00 1200 x Sloe 0.079327473 Correlation 0.997397391 SAMPLE I.D. SAMP ABS ug PER ALIQUOT ALI in mL ANALYZED PREP VOL in mL ALI in mL TAKEN RESULTS u /mL LESS THAN % SPK REC SPIKE LEVEL 0.0 0.00 10 10 10 < 0 1.0 0.097 0.7588 10 10 10 < 76% 1.0 2.5 0.24 2.6614 10 10 10 0.266 106% 2.5 5 0.45 5.4554 10 10 10 0.546 109% 5.0 7.5 0.661 8.2627 10 10 10 0.826 110% 7.5 10.00 0.815 10.3116 10 10 10 1.031 103% 10.00 24769-1 0.007 -0.4387 10 10 10 24769-1 du 0.002 -0.5052 10 10 10 < 0 1,: ,; NA 24769-1 s k 0.365 4.3245 10 10 10 0.432 86% 5.0 24769-2 0.008 -0.4254 10 10 10 < 24769-2 s k 0.346 4.0717 10 10 10 0.407 81 % 5.0 24769-3 0.006 -0.4520 10 10 10 24769-3 spk 0.406 4.8700 10 10 10 0.487 97% 5.0 247694 0.002 -0.5052 10 10 10 0:1' 24769-4 s k 0.438 5.2957 10 10 10 0.530 106% 5.0 24769-5 0.143 1.3708 10 10 10 37 24769-5 s k 0.542 6.6794 10 10 10 0.668 106% 5.0 24769-6 0.004 -0.4786 10 10 10 : < 0,1r_ �, a 24769-6 s k 0.452 5.4820 10 10 10 0.548 110% 5.0 24769-7 0.299 3.4463 10 10 10 0,345' 24769-7 s k 0.719 9.0344 10 10 10 0.903 112% 5.0 24769-8 0.001 -0.5185 10 10 10 "< 0.1� .. 24769-8 s k 0.438 5.2957 10 10 10 0.530 106% 5.0 Blank 0 0.0000 10 10 10 1 < QC 0.444 5.3755 10 10 10 1 0.538 108% 5.0 Submitted for QA/QC- Date: 5.15.15 By: (Print) KLS 'gn): Analytical Lab Page 37 of 97 METHOD: SM 4500 S2- D ELEMENT ASSAY: Sulfide CLIENT: Duke Lab ID# 24769/764/768/7701713 Date: 05.15.15 Time Analysis Begun 800 Time Analysis Ended 1300 Analyst: KLS ug STD STD SOLUTION ABS 0.00 0.000 1.00 0.098 2.50 0.232 5.00 0.439 7.50 0.64 10.00 0.785 Wave Length 664 Na2S•9H2O Lot # 40721 Page 2 of 4 X ELEMENT ONE SPK LEYELLUM 5 MAX ALIQUOT 10.00 STANDARD conc(ppm) X Cal Std Lot: WC2-80-5 10 QC Std Lot: WC2-80-6 Sloe 0.079327473 Correlation 0.997397391 SAMPLE I.D. SAMP ABS ug PER ALIQUOT ALI in mL ANALYZED PREP VOL in mL ALI in mL TAKEN RESULTS u /mL LESS THAN % SPK REC SPIKE LEVEL 24770-1 0.00 0.0000 10 10' 10 24770-1 dup 0,001 -0.5185 10 10 10 < 0.1'. , NA 24770-1 s k 0.389 4.6438 10 10 10 0.464 93% 5.0 24770-2 0.004 -0.4786 10 10 10 < 0.1 24770-2 s k 0.448 5.4288 10 10 10 0.543 109% 5.0 24770-3 0.028 -0.1593 ' 10 10 10 24770-3 s k 0.435 5.2558 10 10 10 0.526 105% 5.0 24770-4 0 0.0000 10 10 10< 24770-4 s k 0.44 5.3223 10 10 10 0.532 106% 5.0 24768-1 0.001 -0.5185 10 10 10 <'.0.1'` 24768-1 s k 0.423 5.0961 10 1 10 10 0.510 102% 5.0 24768-2 0.001 -0.5185 10 10 10 < 0: 24768-2 s k 0.426 5.1361 10 10 10 0.514 103% 5.0 24768-3 0.001 -0.5185 10 10 10 <6,1`` " 24768-3 s k 0.399 1 4.7768 10 10 10 0.478 96% 5.0 24768-4 0.003 -0.4919 10 10 10 24768-4 s k 0.377 4.4841 10 10 10 0.448 90% 5.0 24768-5 0.003 -0,4919 10 10 10 24768-5 s k 0.443 5.3622 10 10 10 0.536 107% 5.0 Blank 0 0.0000 10 10 10 < QC 0.442 5.3489 10 10 10 0.535 107% 5.0 Submitted for Q QC- Date: 5.15.15 By: (Print) KLS i Analytical Lab Page 38 of 97 METHOD: SM 4500 S2- D ELEMENT ASSAY: Sulfide CLIENT: Duke Lab ID# 24769/764/768/770/713 Date: 105.15.15 Time Analysis Begun 1800 Time Analysis Ended 11300 X Y ug STD STD SOLUTION ABS 0.00 0.000 1.00 0,098 2.50 0.232 5.00 0.439 7.50 0.64 10.00 0,785 ELEMENT ONE Spectrophotometer Wave Length 664 UNITS OF ANSWER DETECTION LIMIT u SPK LEVEL CuM Na2S•9H2O Lot # 40721 Page 3 of 4 MAX ALIQUOT STANDARD conc(ppm) Cal Std Lot: WC2-80-5 QC Std Lot: WC2-80-6 ISTDABSORPTION 0.000 110* OBW Y 0./00 AW 0.200 0100 0.000 X 10 Y 2 50 I -,00 0 os UD 200 4D0 000 8.00 1000 12M x Sloe 0.079327473 Correlation 0.997397391 SAMPLE I.D. SAMP ABS ug PER ALIQUOT ALI in mL ANALYZED PREP VOL in mL ALI in mL TAKEN RESULTS ug/mL LESS THAN % SPK REC SPIKE LEVEL 24764-1 0.00 0.0000 10 10 10! 24764-1 du 0.001 -0.5185 10 10 10 <.0'1, - NA 24764-1 s k 0.409 4.9099 10 10 10 0,491 98% 5.0 24764-2 0 0.0000 10 10 10 <.0.T 24764-2 s k 0.44 5.3223 10 10 10 0.532 106% 5.0 24764-3 0 0.0000 10 10 10 < 24764-3 s k 0.345 4.0584 10 10 10 0.406 81 % 5.0 24764-4 0.033 -0.0927 10 10 10 < 24764-4 s k 0.343 4.0318 10 10 10 0.403 81 % 5.0 24764-5 0.027 -0.1726 10 10 10 < 24764-5 s k 0.307 3.5528 10 10 10 0.355 71 % 5.0 234764-6 0.004 -0.4786 10 10 10 <, 0.1; . 24764-6 s k 0.442 5.3489 10 10 10 0.535 107% 5.0 24764-7 0.062 0.2931 10 10 10 24764-7 s k 0.391 4.6704 10 10 10 0.467 93% 5.0 24764-8 0 0.0000 10 10 10 24764-8 s k 0.411 4.9365 10 10 10 0.494 99% 5.0 24764-9 0.001 -0.5185 10 10 10 24764-9 s k 0.37 4.3910 10 10 10 0.439 88% 5.0 24764-10 0.004 -0.4786 10 10 10 <�O. I;;s` , 24764-10 s k 0.365 4.3245 10 10 10 0.432 86% 5.0 24764-11 0.004 -0.4786 10 10 10 24764-11 spk 0.368 4.3644 10 10 10 0.436 87% 5.0 24764-12 0.008 -0.4254 10 10 10 < 24764-12 s k 0.319 3.7124 10 10 10 0.371 74% 5.0 Blank 0 0.0000 10 10 10 < QC 0.442 5.3489 10 10 10 0.535 107% 5.0 Submitted for QA/(;C- Date: 5.15.15 By: (Print) KLS ign): ___..,_ Analytical Lab Page 39 of 97 METHOD: SM 4500 S2- D ELEMENT ONE ELEMENT ASSAY: Sulfide Spectrophotometer Wave Length 664 UNITS OF ANSWER u /ml- DETECTION LIMIT u 1.000 CLIENT: Duke SPK LEVELLUM 5 Lab ID# 24769/764/768/770/713 Na2S•9H2O Lot # 40721 Page 4 of 4 MAX ALIQUOT 10.00 Date: 05.15.15 STANDARD conc(ppm) X Time Analysis Begun 800 ICal Std Lot: WC2-80-5 10 Time Analysis Ended 1300 JQC Std Lot: WC2-80-6 Analyst: KLS STD ABSORPTION Y ug STD SOLUTION 0.00 1.00 2.50 5.00 7.50 10.00 Y STD ABS 0.000 0.098 0.232 0.439 0.64 0.785 X 30 il- s a n Fnx. Sloe 0.079327473 Correlation 0.997397391 SAMPLE I.D. SAMP ABS ug PER ALIQUOT ALI in mL ANALYZED PREP VOL in mL ALI in mL TAKEN RESULTS u /mL LESS THAN % SPK REC SPIKE LEVEL 24769-2 0.00 -0.5052 10 10 5 < 24769-2 spk 0.323 3.7657 10 10 5 0.753 75% 5.0 24764-3 0.005 -0.4653 10 10 5 < 24764-3 s k 0.349 4.1116 10 10 5 0.822 82% 5.0 24764-4 0.017 -0.3056 10 10 5 < 24764-4 spk 0.352 4.1515 10 10 5 0.830 83% 5.0 24764-5 0.005 -0.4653 10 1 10 5 < 24764-5 s k 0.345 4.0584 10 10 5 0.812 81 % 5.0 24764-12 0.032 -0.1060 10 10 5 < 24764-12 s k 0.331 3.8721 10 10 5 0.774 77% 5.0 24769-2 0.00 -0.5052 10 10 2 24769-2 spk 0.364 4.3112 10 10 2 2.156 86% 5.0 24764-3 0.005 -0.4653 10 10 2 24764-3 spk 0.362 4.2845 10 10 2 2.142 86% 5.0 24764-4 0.005 -0.4653 10 10 2 24764-4 s k 0.364 4.3112 10 10 2 2.156 86% 5.0 24764-5 0.007 -0.4387 10 10 2 24764-5 spk 0.365 4.3245 10 10 2 2.162 86% 5.0 24764-12 0.005 -0.4653 10 10 2 < 24764-12 spk 0.332 3.8854 10 10 2 1.943 78% 5.0 24764-12 0.003 -0.4919 10 10 1 24764-12 spk 0.347 4.0850 10 10 1 4,085 82% 5.0 24713 0.006 -0.4520 10 10 1 < 24713 spk 0.302 3.4863 10 10 1 3.486 70% 5.0 24713 0.004 -0.4786 10 10 0.5 24713 s k 0.344 4.0451 10 10 0.5 8.090 81 % 5.0 Blank 0 1 0.0000 10 10 10 < QC 0.44 5.3223 10 10 10 0.532 106% 5.0 Submitted for QA/QC- Date: 5.15.15 By: (Print) KLS7776"-sig ): SHEALY ENVIRONMENTAL SERVICES, INC. Report of Analysis Duke Energy 13339 Hagers Ferry Rd Bldg 7405 Huntersville, NC 28078 Attention: Mary Ann Ogle Project Name: AB GW Assessment Water - Roxboro Project Number:J15050346 Lot Number:QE14045 Date Completed:05/21/2015 Grant Wilton Project Manager This report shall not be reproduced, except in its entirety, without the written approval of Shealy Environmental Services, Inc. The following non -paginated documents are considered part of this report: Chain of Custody Record and Sample Receipt Checklist. *QE14045* Shealy Environmental Services, Inc. Page: 1 of 43 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. SC DHEC No: 32010 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative Duke Energy Lot Number: QE14045 Project Name: AB GW Assessment Water - Roxboro Project Number: J15050346 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the Shealy Environmental Services, Inc. ("Shealy") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPS), and Shealy policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below. If you have any questions regarding this report please contact the Shealy Project Manager listed on the cover page Shealy Environmental Services, Inc. Page: 2 of 43 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. Sample Summary Duke Energy Lot Number: QE14045 Project Name: AB GW Assessment Water - Roxboro Project Number: J15050346 Sample Number Sample ID Matrix Date Sampled Date Received 001 2015014486 Aqueous 05/12/20151510 05/14/2015 002 2015014487 Aqueous 05/12/20151210 05/14/2015 003 2015014488 Aqueous 05/12/20151425 05/14/2015 004 2015014489 Aqueous 05/13/20151700 05/14/2015 005 2015014490 Aqueous 05/13/20151600 05/14/2015 006 2015014491 Aqueous 05/13/20151410 05/14/2015 007 2015014492 Aqueous 05/12/20151615 05/14/2015 008 2015014493 Aqueous 05/13/20151055 05/14/2015 009 2015014494 Aqueous 05/13/20151115 05/14/2015 010 2015014495 Aqueous 05/13/20151020 05/14/2015 011 2015014496 Aqueous 05/13/20151245 05/14/2015 012 2015014498 Aqueous 05/13/20151845 05/14/2015 013 2015014504 Aqueous 05/13/2015 05/14/2015 015 2015014506 Aqueous 05/13/20151140 05/14/2015 (14 samples) Shealy Environmental Services, Inc. Page: 3 of 43 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. Executive Summary Duke Energy Lot Number: QE14045 Project Name: AB GW Assessment Water - Roxboro Project Number: J15050346 Sample Sample ID Matrix Parameter Method Result Q Units Page 001 2015014486 Aqueous Alkalinity SM 2320B- 39 mg/L 6 001 2015014486 Aqueous Bicarbonate Alkalinity SM 2320B- 39 mg/L 6 001 2015014486 Aqueous Methane RSK - 175 12 ug/L 7 001 2015014486 Aqueous Mercury (CVAFS) 1631E 1.18 ng/L 8 002 2015014487 Aqueous Alkalinity SM 2320B- 28 mg/L 9 002 2015014487 Aqueous Bicarbonate Alkalinity SM 2320B- 28 mg/L 9 002 2015014487 Aqueous Mercury (CVAFS) 1631E 0.896 ng/L 11 003 2015014488 Aqueous Alkalinity SM 2320B- 46 mg/L 12 003 2015014488 Aqueous Bicarbonate Alkalinity SM 2320B- 46 mg/L 12 003 2015014488 Aqueous Methane RSK - 175 10 ug/L 13 003 2015014488 Aqueous Mercury (CVAFS) 1631E 3.94 ng/L 14 004 2015014489 Aqueous Alkalinity SM 2320B- 13 mg/L 15 004 2015014489 Aqueous Bicarbonate Alkalinity SM 2320B- 13 mg/L 15 004 2015014489 Aqueous Mercury (CVAFS) 1631E 8.00 ng/L 17 005 2015014490 Aqueous Alkalinity SM 2320B- 59 mg/L 18 005 2015014490 Aqueous Bicarbonate Alkalinity SM 2320B- 59 mg/L 18 005 2015014490 Aqueous Methane RSK - 175 140 ug/L 19 005 2015014490 Aqueous Mercury (CVAFS) 1631E 4.00 ng/L 20 006 2015014491 Aqueous Alkalinity SM 2320B- 41 mg/L 21 006 2015014491 Aqueous Bicarbonate Alkalinity SM 2320B- 41 mg/L 21 006 2015014491 Aqueous Methane RSK - 175 35 ug/L 22 006 2015014491 Aqueous Mercury (CVAFS) 1631E 2.00 ng/L 23 007 2015014492 Aqueous Alkalinity SM 2320B- 68 mg/L 24 007 2015014492 Aqueous Bicarbonate Alkalinity SM 2320B- 68 mg/L 24 007 2015014492 Aqueous Methane RSK - 175 89 ug/L 25 008 2015014493 Aqueous Alkalinity SM 2320B- 36 mg/L 27 008 2015014493 Aqueous Bicarbonate Alkalinity SM 2320B- 36 mg/L 27 008 2015014493 Aqueous Methane RSK - 175 15 ug/L 28 008 2015014493 Aqueous Mercury (CVAFS) 1631E 1.45 ng/L 29 009 2015014494 Aqueous Alkalinity SM 2320B- 36 mg/L 30 009 2015014494 Aqueous Bicarbonate Alkalinity SM 2320B- 36 mg/L 30 009 2015014494 Aqueous Methane RSK - 175 15 ug/L 31 009 2015014494 Aqueous Mercury (CVAFS) 1631E 0.685 ng/L 32 010 2015014495 Aqueous Alkalinity SM 2320B- 58 mg/L 33 010 2015014495 Aqueous Bicarbonate Alkalinity SM 2320B- 58 mg/L 33 010 2015014495 Aqueous Methane RSK - 175 38 ug/L 34 011 2015014496 Aqueous Alkalinity SM 2320B- 63 mg/L 36 011 2015014496 Aqueous Bicarbonate Alkalinity SM 2320B- 63 mg/L 36 011 2015014496 Aqueous Methane RSK - 175 250 ug/L 37 011 2015014496 Aqueous Mercury (CVAFS) 1631E 3.3 ng/L 38 015 2015014506 Aqueous Alkalinity SM 2320B- 47 mg/L 41 015 2015014506 Aqueous Bicarbonate Alkalinity SM 2320B- 47 mg/L 41 015 2015014506 Aqueous Methane RSK - 175 120 ug/L 42 Shealy Environmental Services, Inc. Page: 4 of 43 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Executive Summary (Continued) Lot Number: QE14045 Sample Sample ID Matrix Parameter Method Result Q Units Page 015 2015014506 Aqueous Mercury (CVAFS) 1631E 5.95 ng/L 43 (44 detections) Shealy Environmental Services, Inc. Page: 5 of 43 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals Client: Duke Energy Laboratory ID: QE14045-001 Description: 2015014486 Matrix: Aqueous Date Sampled:05/12/2015 1510 Project Name: AB GW Assessment Water - Date Received:05/14/2015 Project Number: J15050346 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 05/15/2015 1100 HMA 75006 1 (Bicarbonate ) SM 2320B-2011 1 05/15/2015 1100 HMA 1 (Carbonate Al) SM 2320B-2011 1 05/15/2015 1100 HMA CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 39 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 39 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 6 of 43 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane Client: Duke Energy Laboratory ID: QE14045-001 Description: 2015014486 Matrix: Aqueous Date Sampled:05/12/2015 1510 Project Name: AB GW Assessment Water - Date Received:05/14/2015 Project Number: J15050346 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 05/18/2015 1053 DCS 75194 CAS Analytical Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 12 10 ug/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 7 of 43 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Mercury (CVAFS) Client: Duke Energy Laboratory ID: QE14045-001 Description: 2015014486 Matrix: Aqueous Date Sampled:05/12/2015 1510 Project Name: AB GW Assessment Water - Date Received:05/14/2015 Project Number: J15050346 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 1631 E 1 05/19/2015 1130 COH 05/15/2015 1701 74984 CAS Analytical Parameter Number Method Result Q PQL Units Run Mercury (CVAFS) 7439-97-6 1631E 1.18 0.500 ng/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 8 of 43 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals Client: Duke Energy Laboratory ID: QE14045-002 Description: 2015014487 Matrix: Aqueous Date Sampled:05/12/2015 1210 Project Name: AB GW Assessment Water - Date Received:05/14/2015 Project Number: J15050346 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 05/15/2015 1119 HMA 75006 1 (Bicarbonate ) SM 2320B-2011 1 05/15/2015 1119 HMA 1 (Carbonate Al) SM 2320B-2011 1 05/15/2015 1119 HMA CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 28 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 28 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 9 of 43 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane Client: Duke Energy Laboratory ID: QE14045-002 Description: 2015014487 Matrix: Aqueous Date Sampled:05/12/2015 1210 Project Name: AB GW Assessment Water - Date Received:05/14/2015 Project Number: J15050346 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 05/18/2015 1115 DCS 75194 CAS Analytical Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 10 ug/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 10 of 43 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Mercury (CVAFS) Client: Duke Energy Laboratory ID: QE14045-002 Description: 2015014487 Matrix: Aqueous Date Sampled:05/12/2015 1210 Project Name: AB GW Assessment Water - Date Received:05/14/2015 Project Number: J15050346 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 1631 E 1 05/19/2015 1144 COH 05/15/2015 1701 74984 CAS Analytical Parameter Number Method Result Q PQL Units Run Mercury (CVAFS) 7439-97-6 1631E 0.896 0.500 ng/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 11 of 43 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals Client: Duke Energy Laboratory ID: QE14045-003 Description: 2015014488 Matrix: Aqueous Date Sampled:05/12/2015 1425 Project Name: AB GW Assessment Water - Date Received:05/14/2015 Project Number: J15050346 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 05/15/2015 1125 HMA 75006 1 (Bicarbonate ) SM 2320B-2011 1 05/15/2015 1125 HMA 1 (Carbonate Al) SM 2320B-2011 1 05/15/2015 1125 HMA CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 46 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 46 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 12 of 43 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane Client: Duke Energy Laboratory ID: QE14045-003 Description: 2015014488 Matrix: Aqueous Date Sampled:05/12/2015 1425 Project Name: AB GW Assessment Water - Date Received:05/14/2015 Project Number: J15050346 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 05/18/2015 1130 DCS 75194 CAS Analytical Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 10 10 ug/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 13 of 43 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Mercury (CVAFS) Client: Duke Energy Laboratory ID: QE14045-003 Description: 2015014488 Matrix: Aqueous Date Sampled:05/12/2015 1425 Project Name: AB GW Assessment Water - Date Received:05/14/2015 Project Number: J15050346 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 1631 E 1 05/19/2015 1158 COH 05/15/2015 1701 74984 CAS Analytical Parameter Number Method Result Q PQL Units Run Mercury (CVAFS) 7439-97-6 1631E 3.94 0.500 ng/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 14 of 43 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals Client: Duke Energy Laboratory ID: QE14045-004 Description: 2015014489 Matrix: Aqueous Date Sampled:05/13/2015 1700 Project Name: AB GW Assessment Water - Date Received:05/14/2015 Project Number: J15050346 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 05/15/2015 1130 HMA 75006 1 (Bicarbonate ) SM 2320B-2011 1 05/15/2015 1130 HMA 1 (Carbonate Al) SM 2320B-2011 1 05/15/2015 1130 HMA CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 13 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 13 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 15 of 43 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane Client: Duke Energy Laboratory ID: QE14045-004 Description: 2015014489 Matrix: Aqueous Date Sampled:05/13/2015 1700 Project Name: AB GW Assessment Water - Date Received:05/14/2015 Project Number: J15050346 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 05/18/2015 1140 DCS 75194 CAS Analytical Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 10 ug/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 16 of 43 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Mercury (CVAFS) Client: Duke Energy Laboratory ID: QE14045-004 Description: 2015014489 Matrix: Aqueous Date Sampled:05/13/2015 1700 Project Name: AB GW Assessment Water - Date Received:05/14/2015 Project Number: J15050346 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 1631 E 1 05/19/2015 1202 COH 05/15/2015 1701 74984 CAS Analytical Parameter Number Method Result Q PQL Units Run Mercury (CVAFS) 7439-97-6 1631E 8.00 0.500 ng/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 17 of 43 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals Client: Duke Energy Laboratory ID: QE14045-005 Description: 2015014490 Matrix: Aqueous Date Sampled:05/13/2015 1600 Project Name: AB GW Assessment Water - Date Received:05/14/2015 Project Number: J15050346 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 05/15/2015 1135 HMA 75006 1 (Bicarbonate ) SM 2320B-2011 1 05/15/2015 1135 HMA 1 (Carbonate Al) SM 2320B-2011 1 05/15/2015 1135 HMA CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 59 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 59 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 18 of 43 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane Client: Duke Energy Laboratory ID: QE14045-005 Description: 2015014490 Matrix: Aqueous Date Sampled:05/13/2015 1600 Project Name: AB GW Assessment Water - Date Received:05/14/2015 Project Number: J15050346 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 05/18/2015 1156 DCS 75194 CAS Analytical Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 140 10 ug/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 19 of 43 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Mercury (CVAFS) Client: Duke Energy Laboratory ID: QE14045-005 Description: 2015014490 Matrix: Aqueous Date Sampled:05/13/2015 1600 Project Name: AB GW Assessment Water - Date Received:05/14/2015 Project Number: J15050346 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 1631 E 1 05/19/2015 1207 COH 05/15/2015 1701 74984 CAS Analytical Parameter Number Method Result Q PQL Units Run Mercury (CVAFS) 7439-97-6 1631E 4.00 0.500 ng/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 20 of 43 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals Client: Duke Energy Laboratory ID: QE14045-006 Description: 2015014491 Matrix: Aqueous Date Sampled:05/13/2015 1410 Project Name: AB GW Assessment Water - Date Received:05/14/2015 Project Number: J15050346 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 05/15/2015 1141 HMA 75006 1 (Bicarbonate ) SM 2320B-2011 1 05/15/2015 1141 HMA 1 (Carbonate Al) SM 2320B-2011 1 05/15/2015 1141 HMA CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 41 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 41 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 21 of 43 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane Client: Duke Energy Laboratory ID: QE14045-006 Description: 2015014491 Matrix: Aqueous Date Sampled:05/13/2015 1410 Project Name: AB GW Assessment Water - Date Received:05/14/2015 Project Number: J15050346 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 05/18/2015 1206 DCS 75194 CAS Analytical Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 35 10 ug/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 22 of 43 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Mercury (CVAFS) Client: Duke Energy Laboratory ID: QE14045-006 Description: 2015014491 Matrix: Aqueous Date Sampled:05/13/2015 1410 Project Name: AB GW Assessment Water - Date Received:05/14/2015 Project Number: J15050346 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 1631 E 1 05/19/2015 1212 COH 05/15/2015 1701 74984 CAS Analytical Parameter Number Method Result Q PQL Units Run Mercury (CVAFS) 7439-97-6 1631E 2.00 0.500 ng/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 23 of 43 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals Client: Duke Energy Laboratory ID: QE14045-007 Description: 2015014492 Matrix: Aqueous Date Sampled:05/12/2015 1615 Project Name: AB GW Assessment Water - Date Received:05/14/2015 Project Number: J15050346 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 05/15/2015 1146 HMA 75006 1 (Bicarbonate ) SM 2320B-2011 1 05/15/2015 1146 HMA 1 (Carbonate Al) SM 2320B-2011 1 05/15/2015 1146 HMA CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 68 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 68 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 24 of 43 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane Client: Duke Energy Laboratory ID: QE14045-007 Description: 2015014492 Matrix: Aqueous Date Sampled:05/12/2015 1615 Project Name: AB GW Assessment Water - Date Received:05/14/2015 Project Number: J15050346 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 05/18/2015 1217 DCS 75194 CAS Analytical Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 89 10 ug/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 25 of 43 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Mercury (CVAFS) Client: Duke Energy Laboratory ID: QE14045-007 Description: 2015014492 Matrix: Aqueous Date Sampled:05/12/2015 1615 Project Name: AB GW Assessment Water - Date Received:05/14/2015 Project Number: J15050346 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 1631 E 1 05/19/2015 1217 COH 05/15/2015 1701 74984 CAS Analytical Parameter Number Method Result Q PQL Units Run Mercury(CVAFS) 7439-97-6 1631E ND 0.500 ng/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 26 of 43 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals Client: Duke Energy Laboratory ID: QE14045-008 Description: 2015014493 Matrix: Aqueous Date Sampled:05/13/2015 1055 Project Name: AB GW Assessment Water - Date Received:05/14/2015 Project Number: J15050346 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 05/15/2015 1207 HMA 75006 1 (Bicarbonate ) SM 2320B-2011 1 05/15/2015 1207 HMA 1 (Carbonate Al) SM 2320B-2011 1 05/15/2015 1207 HMA CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 36 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 36 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 27 of 43 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane Client: Duke Energy Laboratory ID: QE14045-008 Description: 2015014493 Matrix: Aqueous Date Sampled:05/13/2015 1055 Project Name: AB GW Assessment Water - Date Received:05/14/2015 Project Number: J15050346 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 05/18/2015 1227 DCS 75194 CAS Analytical Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 15 10 ug/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 28 of 43 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Mercury (CVAFS) Client: Duke Energy Laboratory ID: QE14045-008 Description: 2015014493 Matrix: Aqueous Date Sampled:05/13/2015 1055 Project Name: AB GW Assessment Water - Date Received:05/14/2015 Project Number: J15050346 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 1631 E 1 05/19/2015 1221 COH 05/15/2015 1701 74984 CAS Analytical Parameter Number Method Result Q PQL Units Run Mercury (CVAFS) 7439-97-6 1631E 1.45 0.500 ng/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 29 of 43 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals Client: Duke Energy Laboratory ID: QE14045-009 Description: 2015014494 Matrix: Aqueous Date Sampled:05/13/2015 1115 Project Name: AB GW Assessment Water - Date Received:05/14/2015 Project Number: J15050346 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 05/15/2015 1213 HMA 75006 1 (Bicarbonate ) SM 2320B-2011 1 05/15/2015 1213 HMA 1 (Carbonate Al) SM 2320B-2011 1 05/15/2015 1213 HMA CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 36 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 36 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 30 of 43 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane Client: Duke Energy Laboratory ID: QE14045-009 Description: 2015014494 Matrix: Aqueous Date Sampled:05/13/2015 1115 Project Name: AB GW Assessment Water - Date Received:05/14/2015 Project Number: J15050346 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 05/18/2015 1312 DCS 75194 CAS Analytical Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 15 10 ug/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 31 of 43 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Mercury (CVAFS) Client: Duke Energy Laboratory ID: QE14045-009 Description: 2015014494 Matrix: Aqueous Date Sampled:05/13/2015 1115 Project Name: AB GW Assessment Water - Date Received:05/14/2015 Project Number: J15050346 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 1631 E 1 05/19/2015 1226 COH 05/15/2015 1701 74984 CAS Analytical Parameter Number Method Result Q PQL Units Run Mercury (CVAFS) 7439-97-6 1631E 0.685 0.500 ng/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 32 of 43 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals Client: Duke Energy Laboratory ID: QE14045-010 Description: 2015014495 Matrix: Aqueous Date Sampled:05/13/2015 1020 Project Name: AB GW Assessment Water - Date Received:05/14/2015 Project Number: J15050346 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 05/15/2015 1218 HMA 75006 1 (Bicarbonate ) SM 2320B-2011 1 05/15/2015 1218 HMA 1 (Carbonate Al) SM 2320B-2011 1 05/15/2015 1218 HMA CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 58 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 58 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 33 of 43 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane Client: Duke Energy Laboratory ID: QE14045-010 Description: 2015014495 Matrix: Aqueous Date Sampled:05/13/2015 1020 Project Name: AB GW Assessment Water - Date Received:05/14/2015 Project Number: J15050346 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 05/18/2015 1324 DCS 75194 CAS Analytical Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 38 10 ug/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 34 of 43 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Mercury (CVAFS) Client: Duke Energy Laboratory ID: QE14045-010 Description: 2015014495 Matrix: Aqueous Date Sampled:05/13/2015 1020 Project Name: AB GW Assessment Water - Date Received:05/14/2015 Project Number: J15050346 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 1631 E 1 05/19/2015 1231 COH 05/15/2015 1701 74984 CAS Analytical Parameter Number Method Result Q PQL Units Run Mercury(CVAFS) 7439-97-6 1631E ND 0.500 ng/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 35 of 43 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals Client: Duke Energy Laboratory ID: QE14045-011 Description: 2015014496 Matrix: Aqueous Date Sampled:05/13/2015 1245 Project Name: AB GW Assessment Water - Date Received:05/14/2015 Project Number: J15050346 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 05/15/2015 1224 HMA 75006 1 (Bicarbonate ) SM 2320B-2011 1 05/15/2015 1224 HMA 1 (Carbonate Al) SM 2320B-2011 1 05/15/2015 1224 HMA CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 63 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 63 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 36 of 43 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane Client: Duke Energy Laboratory ID: QE14045-011 Description: 2015014496 Matrix: Aqueous Date Sampled:05/13/2015 1245 Project Name: AB GW Assessment Water - Date Received:05/14/2015 Project Number: J15050346 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 05/18/2015 1409 DCS 75194 CAS Analytical Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 250 10 ug/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 37 of 43 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Mercury (CVAFS) Client: Duke Energy Laboratory ID: QE14045-011 Description: 2015014496 Matrix: Aqueous Date Sampled:05/13/2015 1245 Project Name: AB GW Assessment Water - Date Received:05/14/2015 Project Number: J15050346 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 1631 E 1 05/19/2015 1235 COH 05/15/2015 1701 74984 CAS Analytical Parameter Number Method Result Q PQL Units Run Mercury (CVAFS) 7439-97-6 1631E 3.3 0.500 ng/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 38 of 43 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Mercury (CVAFS) Client: Duke Energy Laboratory ID: QE14045-012 Description: 2015014498 Matrix: Aqueous Date Sampled:05/13/2015 1845 Project Name: AB GW Assessment Water - Date Received:05/14/2015 Project Number: J15050346 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 1631 E 1 05/19/2015 1240 COH 05/15/2015 1701 74984 CAS Analytical Parameter Number Method Result Q PQL Units Run Mercury(CVAFS) 7439-97-6 1631E ND 0.500 ng/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 39 of 43 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Mercury (CVAFS) Client: Duke Energy Laboratory ID: QE14045-013 Description: 2015014504 Matrix: Aqueous Date Sampled:05/13/2015 Project Name: AB GW Assessment Water - Date Received:05/14/2015 Project Number: J15050346 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 1631 E 1 05/19/2015 1254 COH 05/15/2015 1701 74984 CAS Analytical Parameter Number Method Result Q PQL Units Run Mercury(CVAFS) 7439-97-6 1631E ND 0.500 ng/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 40 of 43 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals Client: Duke Energy Laboratory ID: QE14045-015 Description: 2015014506 Matrix: Aqueous Date Sampled:05/13/2015 1140 Project Name: AB GW Assessment Water - Date Received:05/14/2015 Project Number: J15050346 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 05/15/2015 1229 HMA 75006 1 (Bicarbonate ) SM 2320B-2011 1 05/15/2015 1229 HMA 1 (Carbonate Al) SM 2320B-2011 1 05/15/2015 1229 HMA CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 47 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 47 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 41 of 43 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane Client: Duke Energy Laboratory ID: QE14045-015 Description: 2015014506 Matrix: Aqueous Date Sampled:05/13/2015 1140 Project Name: AB GW Assessment Water - Date Received:05/14/2015 Project Number: J15050346 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 05/18/2015 1425 DCS 75194 CAS Analytical Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 120 10 ug/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 42 of 43 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Mercury (CVAFS) Client: Duke Energy Laboratory ID: QE14045-015 Description: 2015014506 Matrix: Aqueous Date Sampled:05/13/2015 1140 Project Name: AB GW Assessment Water - Date Received:05/14/2015 Project Number: J15050346 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 1631 E 1 05/19/2015 1259 COH 05/15/2015 1701 74984 CAS Analytical Parameter Number Method Result Q PQL Units Run Mercury (CVAFS) 7439-97-6 1631E 5.95 0.500 ng/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 43 of 43 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 QC Summary Shealy Environmental Services, Inc. QC Data for Lot Number: QE14045 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals - Ii Sample ID: QQ75006-001 Matrix: Aqueous Batch: 75006 Analytical Method: SM 2320B-2011 Parameter Result Q Dil PQL Units Analysis Date Alkalinity ND 1 10 mg/L 05/15/20151049 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QE14045 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals - LCS Sample ID: QQ75006-002 Matrix: Aqueous Batch: 75006 Analytical Method: SM 2320B-2011 Spike Amount Result % Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Alkalinity 100 91 1 91 90-110 05/15/20151054 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QE14045 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals - MS Sample ID: QE14045-001MS Matrix: Aqueous Batch: 75006 Analytical Method: SM 2320B-2011 Sample Spike Amount Amount Result % Rec Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Alkalinity 39 100 120 1 82 70-130 05/15/20151107 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QE14045 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals - MSD Sample ID: QE14045-001MD Matrix: Aqueous Batch: 75006 Analytical Method: SM 2320B-2011 Sample Spike Amount Amount Result % Rec % RPD Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date Alkalinity 39 100 120 1 84 2.1 70-130 20 05/15/20151114 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QE14045 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane - MB Sample ID: QQ75194-001 Matrix: Aqueous Batch: 75194 Analytical Method: RSK - 175 Parameter Result Q Dil PQL Units Analysis Date Methane ND 1 10 ug/L 05/18/20151022 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QE14045 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane - LCS Sample ID: QQ75194-002 Matrix: Aqueous Batch: 75194 Analytical Method: RSK - 175 Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Methane 150 120 1 82 70-130 05/18/2015 0951 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QE14045 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane - LCSD Sample ID: QQ75194-003 Matrix: Aqueous Batch: 75194 Analytical Method: RSK - 175 Spike Amount Result % Rec % RPD Parameter (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date Methane 150 120 1 80 2.5 70-130 30 05/18/20151001 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QE14045 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Mercury (CVAFS) - MB Sample ID: QQ74984-001 Matrix: Aqueous Batch:74984 Prep Method: 1631E Analytical Method: 1631E Prep Date: 05/15/2015 1701 Parameter Result Q Dil PQL Units Analysis Date Mercury (CVAFS) ND 1 0.500 ng/L 05/19/2015 1102 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QE14045 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Mercury (CVAFS) - LCS Sample ID: QQ74984-002 Matrix: Aqueous Batch:74984 Prep Method: 1631E Analytical Method: 1631E Prep Date: 05/15/2015 1701 Spike Amount Result % Rec Parameter (ng/L) (ng/L) Q Dil % Rec Limit Analysis Date Mercury (CVAFS) 5.00 5.65 1 113 75-125 05/19/2015 1107 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QE14045 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Mercury (CVAFS) - MS Sample ID: QE14045-001MS Matrix: Aqueous Batch:74984 Prep Method: 1631E Analytical Method: 1631E Prep Date: 05/15/2015 1701 Sample Spike Amount Amount Result % Rec Parameter (ng/L) (ng/L) (ng/L) Q Dil % Rec Limit Analysis Date Mercury (CVAFS) 1.18 5.00 6.23 1 101 71-125 05/19/2015 1135 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QE14045 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Mercury (CVAFS) - MSD Sample ID: QE14045-001MD Matrix: Aqueous Batch:74984 Prep Method: 1631E Analytical Method: 1631E Prep Date: 05/15/2015 1701 Sample Spike Amount Amount Result % Rec % RPD Parameter (ng/L) (ng/L) (ng/L) Q Dil % Rec % RPD Limit Limit Analysis Date Mercury (CVAFS) 1.18 5.00 6.32 1 103 1.4 71-125 24 05/19/2015 1139 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QE14045 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. W u 1 �? fl 3 A.5 �1ig ROM M I 19 •}a+iMM `:OL rg6 ha — rTJ i t el. wlwl� am I_ M I 4M co CD ;E C; t Ir V,x i IS C3 C I'I� i 1 I 7 g e a i e r:g :II'- ■NICIIIII■■ ■E MENOMONEE will I�. IRIND UNKIND Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. Shndr Environmimmill Sorvcc«, Page 1 of t Db0'=01V NWnbs-r, F-0.0-016 R-i;plam Date: I We14 Ravision Number'. 17 i F#%ti�a Dau; W3WI.5 mpie receipt Checklist ( RQ Cooler Inspected by/date: Lot #= Means, of receipt: ❑ SESI ❑ C ent ❑ ITS ❑ FedEx ❑ Airbo na Exp a0thcr Yes �?01 1. Wev vostody suls pymew an the cooler? 'es " ,c NA2. If cu tad seals were resent were th ntc iud ualraltri7 Cooler I VOTigival temperature upon r J L- 1'C Mmthod: empei tore nk A, 1M4cthod of coolant, — et Ice 3. If tezn Yes No ❑ NA [] Phi nnti (For ono imtned tceipVDcrived (corrected) tarnperahire upon reaeipi: . dC 1 1 11C J l VC; inst Bottles IR Gun ID,. IR Gun C=ectio+n Factor- 4 . zi T El Blue Tce Q lee El Mont of any owler exceeded 6.01C, warns Project Manager aotific,6 led by( phnrle, note (circle one), other: ers received via commercial courier. Phis are to bin notified tei . Yes ❑'L NO ❑ NA 4, Is tbq- mwercial comher'a pacidrig al`glip attachcd iu ibis form? yft 7du ❑ S, Vcrc pipper custody prooedw s (xeli 1Frectiv wed? Yes ❑ No I t�I. v. 5a' e s�� les relinquished by elierit tci uommcrcial couricr? yes No ❑ 6, W= , le TDs listed nn the C CSC`? Yes No ❑ 7. W ere le IDs listed on A am le containers? i N;s Nc I A. Waq wn 4, W a", collection lelcOon Jose & lime listed on the C c? yC5 No ❑ date & time liged ea all ham is containen? yes No ❑ 10 - Did all �ontkner lahel information(ID, date, time) ag= with the cocr Yc-5 No [3 1 l .Were is to be erformed listed on the ]C' z No ❑ 12. Did all sam les arrivv in -die proper c tainers for each teat' Yes NO ❑ 13. Did all ntaincrs arrive in or_t'd condition (unbroken, lids on, etc)? Yes Na © 14. Was a atc sans lac volume available? Yes No [ 1 S. Were a comes I sample rra4,Givcd witbiu �/2 the holding time or='l,,3 hears, whichever fust? La ics unntaiacrs missin ? Yes No [je- 16. wcere 41V Yes ❑ No 17. Were ere an e!Emsq samples not listed on COC"? Yes ❑ No ®" I4 1$. Wcra< blcs , mnt > . ea -size" `J"or 6mtn in diam r ;n an VQ.� vials" Yes [] No ❑ NA [2- 19. Were a I metals, O&GIH 'immient same les received gat a1 pH of <2? Ycs No 1q Zit, W= a I cyanide &ncVor sulfide sal les received at a pH >127 Yes ❑ No❑ NA 2l . Werc a residua l applicable NH3,�TKN!cyanideiphenol (~ ,2mg+L) samples free of uhlorinc? Y-s ❑ No NA 2'_'. Were 011=ion tiemp=turcs doomnented on the COC= for �C 8uIn ios? Yes E) No 0 NA Eq- II_ Wcre Q Cic... corr iem remarke�umgts (i.t. rcquenM ditutions, SD designdion5, mUy transcribed fTCaril the CC into the or rwn.ent segttca Ln LLM511 'ics ❑ No 24. Was th quote number used taken fi ni the container lintel? Sample Prexervatiion (Mii9 Lt by mm cted for any sa>zriplm;(s) incorr+eet.lypreserved or with lteadt4o=) Samplers) amordin l y in sample receiviFig with 'Were rmeivcd iilwoT ectly preserved anal were adjusted }SO4,HNC ,HCl,Na()H uqitljg SR # Saru lc(s) were reorived with bubbles >6 mm in diameter. Sam lc(s) wcm. received with TRI_' >0.2 m 'L (Ir ni is No SC: Drinking Water Project Sample(s) Saul le sl 14= not rEceived Sa le labels applied h -, met; . poR verified to be- 2 by Date. at a pH of <rt and were aditlsttd acoordingly usin SR# Verifaud ley' Dante., Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 - ------- C-HAtN0FCL)ST0D RECORD AND ANALYSIS LZDuke EfmwW DMks E 0 M ;j;t, �-Ff . ........... AnatVfical LoWrawry AmMiftlukbo P-1 of Cuom* a IA)40 "M.. Rd -N�� N.C. J�pg 34(4.' 1 S'Ampas 1.49 M4 FT34"t i -ftm� I[a rl ................ FA I- laso4maoll , e rn e n t 1 T� PO 1142133 SHEALY p 0 1142089 GPS L.allon - amprra iold Stank (i faafnple) Trip flank (Mllmy) f 'ReF Man k Qifdayp EPI - f V Wl RY 1 4y Or—n&d B, 1-1� Fikmfflon(U45 E-Lr:MEMFS by lep_va fg": Air, 80, CCL CO, at. Cu, ELEMENTS by PCP fMW�; M. 8*� g, Fe,Mm at. Zmg, M. pl). SP... S, I I JLL,h, I " Mp UrlCLr tw%&Glvnd M*tW& -, miq nmtmlx ICP, No. ' L A"W" CA. My, K, N. :QUEST FORM Synterra EDD (METFUM1110N OR10,1NAL In I FL C.. a-Wo W)IW MP13EB D"Www— u&-r RVKLV*M— COC REV DAI E 112212015 .............. Requ*51cd Tuffraround '-.I Ul*s —4 Zfs *01W AbAP `Add. Gost'Oddl P;oy