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Home My WebLink AboutNC0038377_J15050212 Report_20150902+ DUKE Analytical Laboratory 1 of60 ENERGY Order Number: Project Name: Customer Name(s): Customer Address: Lab Contact: Report Authorized By: (Signature) Program Comments: 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone:980-875-5245 Fax:980-875-4349 Order Summary Report J15050212 MAYO STEAM - AB GW ASSESSMENT SOIL Tim Hunsucker, Jerry Wylie, Kathy Webb, John Toepfer Margaret Galvin -Karr MXG4644 (101161) ye �� 2015.06.10 06:40:34 -04'00' Margaret Galvin -Karr Phone: 980-875-5219 Date: Please contact the Program Manager (Margaret Galvin -Karr) with any questions regarding this report. Data Flags & Calculations: 6/9/2015 Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Sample ID's & Descriptions: 2 of 60 Collection Sample ID Plant/Station Date and Time Collected By Sample Description 2015013898 MAYO STEAM 07-May-15 11:50 AM Erin Black SB-7-EB 2015013900 MAYO STEAM 07-May-15 12:20 PM Erin Black SB-7 (1.0-2.0) 2015013901 MAYO STEAM 07-May-15 12:45 PM Erin Black SB-7 (4.5-7.5) 3 Total Samples 3 of 60 Technical Validation Review Checklist: COC and .pdf report are in agreement with sample totals Yes No and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. ❑ Yes❑ No All laboratory QA/QC requirements are acceptable.❑ Yes ❑ No Report Sections Included: U Job Summary Report ❑ Sample Identification n Technical Validation of Data Package ❑ Analytical Laboratory Certificate of Analysis ❑ Analytical Laboratory QC Report Reviewed By: Date: Sub -contracted Laboratory Results ❑ Customer Specific Data Sheets, Reports, & Documentation ❑ Customer Database Entries 0 Chain of Custody [I/0] Electronic Data Deliverable (EDD) Sent Separately Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050212 Site: SB-7-EB Collection Date: 07-May-15 11:50 AM Analyte Result Units Qualifiers RDL DF METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Sample #: 2015013898 Matrix: SOIL 4 of 60 Method Analysis Date/Time Analyst Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050212 Site: SB-7 (1.0-2.0) Collection Date: 07-Mav-15 12:20 PM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 5 of 60 Sample #: 2015013900 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050212 Site: SB-7 (4.5-7.5) Collection Date: 07-Mav-15 12:45 PM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 6 of 60 Sample #: 2015013901 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kic&fie. Suite 100 Huntersville, INC 28078 (704)875-9092 June 04, 2015 Program Manager Duke Energy 13339 Hagers Ferry Road Bldg.7405 MG30A2 Huntersville, NC 28078 RE: Project: J 15050212 Pace Project No.: 92249061 Dear Program Manager: Enclosed are the analytical results for sample(s) received by the laboratory on May 08, 2015. The results relate only to the samples included in this report. Results reported herein conform to the most current TN standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Herring kevin.herring@pacelabs.com HORIZON Database Administrator Enclosures cc: Marge Galvin -Karr, Duke Energy Program Manager, Duke Energy Mary Ann Ogle, Duke Energy Rodney Wilke, Duke Energy p«FO REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, lqe� �� without the written consent of Pace Analytical Services, Inc.. BRAT, Page 1 of 53 lacmnalyfica( www.pacelabs.com Pace Analytical Services, Inc. 9800 Kinfke. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15050212 Pace Project No.: 92249061 Minnesota Certification IDs 1700 Elm Street SE Suite 200, Minneapolis, MN 55414 A21-A Certification #: 2926.01 Alaska Certification #: UST-078 Alaska Certification #MN00064 Alabama Certification #40770 Arizona Certification #: AZ-0014 Arkansas Certification #: 88-0680 California Certification #: 01155CA Colorado Certification #Pace Connecticut Certification #: PH-0256 EPA Region 8 Certification #: 8TMS-L Florida/NELAP Certification #: E87605 Guam Certification #:14-008r Georgia Certification #: 959 Georgia EPD #: Pace Idaho Certification #: MN00064 Hawaii Certification #MN00064 Illinois Certification #: 200011 Indiana Certification#C-MN-01 Iowa Certification #: 368 Kansas Certification #: E-10167 Kentucky Dept of Envi. Protection - DW #90062 Kentucky Dept of Envi. Protection - WW #:90062 Louisiana DEQ Certification #: 3086 Louisiana DHH #: LA140001 Maine Certification #: 2013011 Maryland Certification #: 322 Michigan DEPH Certification #: 9909 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification #: 41320 Connecticut Certification #: PH-0216 Delaware Certification: FL NELAC Reciprocity Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Massachusetts Certification #: M-FL1264 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Green Bay Certification IDs 1241 Bellevue Street, Green Bay, WI 54302 Florida/NELAP Certification #: E87948 Illinois Certification #: 200050 Kentucky Certification #: 82 Louisiana Certification #: 04168 Minnesota Certification #: 055-999-334 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 CERTIFICATIONS Minnesota Certification #: 027-053-137 Mississippi Certification #: Pace Montana Certification #: MT0092 Nevada Certification #: MN_00064 Nebraska Certification #: Pace New Jersey Certification #: MN-002 New York Certification #: 11647 North Carolina Certification #: 530 North Carolina State Public Health #: 27700 North Dakota Certification #: R-036 Ohio EPA#: 4150 Ohio VAP Certification #: CL101 Oklahoma Certification #: 9507 Oregon Certification #: MN200001 Oregon Certification #: MN300001 Pennsylvania Certification #: 68-00563 Puerto Rico Certification Saipan (CNMI) #:MP0003 South Carolina #:74003001 Texas Certification #: T104704192 Tennessee Certification #: 02818 Utah Certification #: MN000642013-4 Virginia DGS Certification #: 251 Virginia/VELAP Certification #: Pace Washington Certification #: C486 West Virginia Certification #: 382 West Virginia DHHR #:9952C Wisconsin Certification #: 999407970 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 Nevada Certification: FL NELAC Reciprocity New Hampshire Certification #: 2958 New Jersey Certification #: FL765 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FLO1264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 Washington Certification #: C955 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity North Dakota Certification #: R-150 South Carolina Certification #: 83006001 Texas Certification #: T104704529-14-1 US Dept of Agriculture #: S-76505 Wisconsin Certification #: 405132750 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 2 of 53 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kig,8y&e. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15050212 Pace Project No.: 92249061 Asheville Certification IDs North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 CERTIFICATIONS West Virginia Certification #: 356 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 3 of 53 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ff�i�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: J15050212 Pace Project No.: 92249061 Lab ID Sample ID Matrix Date Collected Date Received 92249061001 2015013898 Water 05/07/1511:50 05/08/15 11:55 92249061002 2015013900 Solid 05/07/1512:20 05/08/15 11:55 92249061003 2015013901 Solid 05/07/1512:45 05/08/15 11:55 92249061004 2015013900 SPLP Water 05/07/15 12:20 05/08/15 11:55 92249061005 2015013901 SPLP Water 05/07/15 12:45 05/08/15 11:55 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 4 of 53 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 fflinl c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: J15050212 92249061 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92249061001 2015013898 EPA 6020A RJS 24 PASI-M EPA 7470A DM 1 PASI-M 92249061002 2015013900 EPA 6010 CKJ 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 MLO 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 300.0 AES2 1 PASI-A EPA 353.2 DMN 1 PASI-A SM 4500-CI-E SER 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92249061003 2015013901 EPA 6010 CKJ 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 MLO 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 300.0 AES2 1 PASI-A EPA 353.2 DMN 1 PASI-A SM 4500-CI-E SER 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92249061004 2015013900 SPLP EPA 6020A TT3 24 PASI-M EPA 7470A DM 1 PASI-M 92249061005 2015013901 SPLP EPA 6020A TT3 24 PASI-M EPA 7470A DM 1 PASI-M REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 5 of 53 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffli�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15050212 Pace Project No.: 92249061 Lab Sample ID Client Sample ID Method Parameters SUMMARY OF DETECTION Result Units Report Limit Analyzed 92249061001 2015013898 EPA 6020A Aluminum 20.5 ug/L 10.0 05/18/15 13:55 EPA 6020A Barium 0.35 ug/L 0.30 05/18/15 13:55 EPA 6020A Calcium 337 ug/L 40.0 05/18/15 13:55 EPA 6020A Chromium 2.2 ug/L 0.50 05/18/15 13:55 EPA 6020A Copper 0.67J ug/L 1.0 05/18/15 13:55 EPA 6020A Iron 105 ug/L 50.0 05/18/15 13:55 EPA 6020A Magnesium 5.9J ug/L 10.0 05/18/15 13:55 EPA 6020A Manganese 1.3 ug/L 0.50 05/18/15 13:55 EPA 6020A Molybdenum 19.3 ug/L 0.50 05/18/15 13:55 EPA 6020A Nickel 0.35J ug/L 0.50 05/18/15 13:55 EPA 6020A Potassium 48.1 J ug/L 50.0 05/18/15 13:55 EPA 6020A Sodium 16.9J ug/L 50.0 05/18/15 13:55 EPA 6020A Strontium 0.68 ug/L 0.50 05/18/15 13:55 EPA 6020A Zinc 2.5J ug/L 5.0 05/18/15 13:55 92249061002 2015013900 EPA 6010 Aluminum 9000 mg/kg 29.1 05/22/15 18:54 EPA 6010 Barium 68.8 mg/kg 2.9 05/22/15 18:54 EPA 6010 Beryllium 0.46 mg/kg 0.29 05/22/15 18:54 EPA 6010 Calcium 301 mg/kg 145 05/22/15 18:54 EPA 6010 Chromium 11.4 mg/kg 1.5 05/22/15 18:54 EPA 6010 Copper 7.7 mg/kg 1.5 05/22/15 18:54 EPA 6010 Iron 9460 mg/kg 11.6 05/22/15 18:54 EPA 6010 Magnesium 1110 mg/kg 145 05/22/15 18:54 EPA 6010 Manganese 693 mg/kg 1.5 05/22/15 18:54 EPA 6010 Nickel 4.2 mg/kg 1.5 05/22/15 18:54 EPA 6010 Potassium 534 mg/kg 291 05/22/15 18:54 EPA 6010 Strontium 5.7 mg/kg 2.9 05/22/15 18:54 EPA 6010 Zinc 21.4 mg/kg 5.8 05/22/15 18:54 EPA 6020 Cobalt 5.9 mg/kg 5.8 05/22/15 19:48 EPA 6020 Lead 5AJ mg/kg 5.8 05/22/15 19:48 EPA 6020 Vanadium 17.6 mg/kg 5.8 05/22/15 19:48 EPA7471 Mercury 0.037 mg/kg 0.0096 05/21/1513:02 ASTM D2974-87 Percent Moisture 13.0 % 0.10 05/20/15 10:34 EPA 9045 pH at 25 Degrees C 5.1 Std. Units 0.10 05/18/15 15:45 EPA 300.0 Sulfate 5.2 mg/L 2.3 05/22/15 18:08 EPA 353.2 Nitrogen, Nitrate 0.31 mg/L 0.23 05/28/15 20:31 EPA 9060 Total Organic Carbon 1650 mg/kg 686 06/02/15 16:19 EPA 9060 Total Organic Carbon 1600 mg/kg 694 06/02/15 16:25 EPA 9060 Total Organic Carbon 1620 mg/kg 694 06/02/15 16:30 EPA 9060 Total Organic Carbon 1570 mg/kg 690 06/02/15 16:36 EPA 9060 Mean Total Organic Carbon 1610 mg/kg 691 06/02/15 16:19 EPA 9060 RSD% 2.2 % 06/02/15 16:19 92249061003 2015013901 EPA 6010 Aluminum 2020 mg/kg 30.0 05/22/15 19:06 EPA 6010 Barium 15.5 mg/kg 3.0 05/22/15 19:06 EPA 6010 Beryllium 0.21J mg/kg 0.30 05/22/15 19:06 REPORT OF LABORATORY ANALYSIS M1 M1 M1 M1 M6 M6 B H1 Qualifiers This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 6 of 53 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffli�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15050212 Pace Project No.: 92249061 Lab Sample ID Client Sample ID Method Parameters SUMMARY OF DETECTION Result Units Report Limit Analyzed Qualifiers 92249061003 2015013901 EPA 6010 Calcium 154 mg/kg 150 05/22/15 19:06 EPA 6010 Chromium 8.2 mg/kg 1.5 05/22/15 19:06 EPA 6010 Copper 4.4 mg/kg 1.5 05/22/15 19:06 EPA 6010 Iron 6040 mg/kg 12.0 05/22/15 19:06 EPA 6010 Magnesium 387 mg/kg 150 05/22/15 19:06 EPA 6010 Manganese 226 mg/kg 1.5 05/22/15 19:06 EPA 6010 Nickel 1 AJ mg/kg 1.5 05/22/15 19:06 EPA 6010 Potassium 266J mg/kg 300 05/22/15 19:06 EPA 6010 Strontium 2.9J mg/kg 3.0 05/22/15 19:06 EPA 6010 Zinc 6.5 mg/kg 6.0 05/22/15 19:06 EPA 6020 Vanadium 8.2 mg/kg 6.0 05/22/15 19:55 EPA7471 Mercury 0.011 mg/kg 0.0092 05/21/1513:09 ASTM D2974-87 Percent Moisture 17.2 % 0.10 05/20/15 10:34 EPA 9045 pH at 25 Degrees C 6.4 Std. Units 0.10 05/18/15 15:45 EPA 300.0 Sulfate 5.7 mg/L 2.4 05/22/15 18:21 B EPA 353.2 Nitrogen, Nitrate 0.29 mg/L 0.24 05/28/15 20:33 H1 EPA 9060 Total Organic Carbon 922 mg/kg 722 06/02/15 16:54 EPA 9060 Total Organic Carbon 918 mg/kg 722 06/02/15 16:59 EPA 9060 Total Organic Carbon 963 mg/kg 728 06/02/15 17:05 EPA 9060 Total Organic Carbon 736 mg/kg 723 06/02/15 17:12 EPA 9060 Mean Total Organic Carbon 885 mg/kg 724 06/02/15 16:54 EPA 9060 RSD% 11.4 % 06/02/15 16:54 92249061004 2015013900 SPLP EPA 6020A Aluminum 133 ug/L 10.0 05/28/15 18:01 EPA 6020A Barium 126 ug/L 0.30 05/28/15 18:01 EPA 6020A Boron 77.5 ug/L 5.0 05/28/15 18:01 EPA 6020A Calcium 870 ug/L 40.0 05/28/15 18:01 EPA 6020A Chromium 0.37J ug/L 0.50 05/28/15 18:01 EPA 6020A Copper 0.85J ug/L 1.0 05/28/15 18:01 EPA 6020A Iron 61.7 ug/L 50.0 05/28/15 18:01 EPA 6020A Lead 0.054J ug/L 0.10 05/28/15 18:01 EPA 6020A Magnesium 270 ug/L 10.0 05/28/15 18:01 EPA 6020A Manganese 9.3 ug/L 0.50 05/28/15 18:01 EPA 6020A Nickel 0.35J ug/L 0.50 05/28/15 18:01 EPA 6020A Potassium 318 ug/L 50.0 05/28/15 18:01 EPA 6020A Sodium 1410 ug/L 50.0 05/28/15 18:01 EPA 6020A Strontium 16.8 ug/L 0.50 05/28/15 18:01 EPA 6020A Zinc 60.6 ug/L 5.0 05/28/15 18:01 92249061005 2015013901 SPLP EPA 6020A Aluminum 18200 ug/L 10.0 05/28/15 18:24 EPA 6020A Arsenic 2.0 ug/L 0.50 05/28/15 18:24 EPA 6020A Barium 252 ug/L 0.30 05/28/15 18:24 EPA 6020A Beryllium 0.66 ug/L 0.20 05/28/15 18:24 EPA 6020A Boron 63.7 ug/L 5.0 05/28/15 18:24 EPA 6020A Cadmium 0.028J ug/L 0.080 05/28/15 18:24 EPA 6020A Calcium 1890 ug/L 40.0 05/28/15 18:24 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 7 of 53 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 fflic&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Project: J15050212 Pace Project No.: 92249061 Lab Sample ID Client Sample ID Method Parameters Result Units 92249061005 2015013901 SPLP EPA 6020A Chromium 19.9 ug/L EPA 6020A Cobalt 4.5 ug/L EPA 6020A Copper 15.3 ug/L EPA 6020A Iron 17300 ug/L EPA 6020A Lead 5.7 ug/L EPA 6020A Magnesium 1920 ug/L EPA 6020A Manganese 491 ug/L EPA 6020A Molybdenum 1.1 ug/L EPA 6020A Nickel 9.5 ug/L EPA 6020A Potassium 1820 ug/L EPA 6020A Selenium 0.24J ug/L EPA 6020A Sodium 2270 ug/L EPA 6020A Strontium 34.2 ug/L EPA 6020A Thallium 0.12 ug/L EPA 6020A Vanadium 32.0 ug/L EPA 6020A Zinc 92.3 ug/L REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Report Limit Analyzed Qualifiers 0.50 05/28/1518:24 0.50 05/28/1518:24 1.0 05/28/1518:24 50.0 05/28/1518:24 0.10 05/28/1518:24 10.0 05/28/1518:24 2.5 05/29/15 08:01 0.50 05/28/1518:24 0.50 05/28/1518:24 50.0 05/28/1518:24 0.50 05/28/1518:24 50.0 05/28/1518:24 0.50 05/28/1518:24 0.10 05/28/1518:24 1.0 05/28/1518:24 5.0 05/28/1518:24 Page 8 of 53 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffli�c&)e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15050212 Pace Project No.: 92249061 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: June 04, 2015 General Information: 2 samples were analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/24249 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92249061002 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1218699) • Aluminum • Barium • Iron • Manganese • MSD (Lab ID: 1218700) • Aluminum • Barium • Iron • Manganese Additional Comments: Batch Comments: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. • QC Batch: ICP / 14828 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 9 of 53 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffli�c&)e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15050212 Pace Project No.: 92249061 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: June 04, 2015 General Information: 2 samples were analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/24250 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92249061002 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • MS (Lab ID: 1218705) • Antimony • Arsenic • Selenium • Vanadium • MSD (Lab ID: 1218706) • Antimony • Arsenic • Lead • Selenium • Thallium • Vanadium Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 10 of 53 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffiic&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15050212 Pace Project No.: 92249061 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: June 04, 2015 Batch Comments: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. • QC Batch: ICPM / 9829 Analyte Comments: QC Batch: MPRP/24250 N2: The lab does not hold TNI accreditation for this parameter. •2015013900 (Lab ID:92249061002) • Antimony •2015013901 (Lab ID:92249061003) • Antimony • BLANK (Lab ID: 1218703) • Antimony • LCS (Lab ID: 1218704) • Antimony • MS (Lab ID: 1218705) • Antimony • MSD (Lab ID: 1218706) • Antimony REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 11 of 53 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffligc&)e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15050212 Pace Project No.: 92249061 Method: EPA 6020A Description: 6020A MET ICPMS Client: Duke Energy Date: June 04, 2015 General Information: 3 samples were analyzed for EPA 6020A. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3020 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/54425 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92249061001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1966605) • Aluminum • MSD (Lab ID: 1966606) • Aluminum QC Batch: MPRP/54657 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92250515004 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1975922) • Aluminum • Calcium • Iron • Magnesium • Manganese REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 12 of 53 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kiigc&y&e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15050212 Pace Project No.: 92249061 Method: EPA 6020A Description: 6020A MET ICPMS Client: Duke Energy Date: June 04, 2015 QC Batch: MPRP/54657 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92250515004 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MSD (Lab ID: 1975923) • Aluminum • Calcium • Iron • Magnesium • Manganese • Sodium Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 13 of 53 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KP�c&)e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15050212 Pace Project No.: 92249061 Method: EPA 7470A Description: 7470A Mercury Client: Duke Energy Date: June 04, 2015 General Information: 3 samples were analyzed for EPA 7470A. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7470A with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 14 of 53 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K�nic&)e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15050212 Pace Project No.: 92249061 Method: EPA 7471 Description: 7471 Mercury Client: Duke Energy Date: June 04, 2015 General Information: 2 samples were analyzed for EPA 7471. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7471 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 15 of 53 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KP�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15050212 Pace Project No.: 92249061 Method: EPA 9045 Description: 9045 pH Soil Client: Duke Energy Date: June 04, 2015 General Information: 2 samples were analyzed for EPA 9045. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Duplicate Sample: All duplicate sample results were within method acceptance criteria with any exceptions noted below. QC Batch: WET/37491 D6: The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits. • DUP (Lab ID: 1460370) • pH at 25 Degrees C Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 16 of 53 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KP�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15050212 Pace Project No.: 92249061 Method: EPA 300.0 Description: 300.0 IC Anions, SPLP Client: Duke Energy Date: June 04, 2015 General Information: 2 samples were analyzed for EPA 300.0. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. QC Batch: WETA/23020 B: Analyte was detected in the associated method blank. • BLANK for HBN 264920 [WETA/230 (Lab ID: 1465540) • Sulfate Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 17 of 53 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KPc&)e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15050212 Pace Project No.: 92249061 Method: EPA 353.2 Description: 353.2 Nitrogen, NO2/NO3, SPLP Client: Duke Energy Date: June 04, 2015 General Information: 2 samples were analyzed for EPA 353.2. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 1-11: Analysis conducted outside the EPA method holding time. •2015013900 (Lab ID:92249061002) •2015013901 (Lab ID:92249061003) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 18 of 53 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KP�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15050212 Pace Project No.: 92249061 Method: SM 4500-CI-E Description: 4500 Chloride, SPLP Client: Duke Energy Date: June 04, 2015 General Information: 2 samples were analyzed for SM 4500-CI-E. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: WETA/23132 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92249061003,92249703005 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1472685) • Chloride • MSD (Lab ID: 1472686) • Chloride Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 19 of 53 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K��c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15050212 Pace Project No.: 92249061 Method: EPA 9056 Description: 9056 IC Anions Client: Duke Energy Date: June 04, 2015 General Information: 2 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/46476 DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015013900 (Lab ID:92249061002) • Chloride •2015013901 (Lab ID:92249061003) • Chloride • Sulfate REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 20 of 53 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K�c&)e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15050212 Pace Project No.: 92249061 Method: EPA 9056 Description: 9056 IC Anions 48hr Client: Duke Energy Date: June 04, 2015 General Information: 2 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 1-13: Sample was received or analysis requested beyond the recognized method holding time. •2015013900 (Lab ID:92249061002) •2015013901 (Lab ID:92249061003) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 21 of 53 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KPgc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15050212 Pace Project No.: 92249061 Method: EPA 9060 Description: Total Organic Carbon Quad Client: Duke Energy Date: June 04, 2015 General Information: 2 samples were analyzed for EPA 9060. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: This data package has been reviewed for quality and completeness and is approved for release. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 22 of 53 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K��c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15050212 Pace Project No.: 92249061 Sample: 2015013898 Lab ID: 92249061001 Collected: 05/07/15 11:50 Received: 05/08/15 11:55 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;I➢ZI7c\�i,I=11 l[99�� 6? Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470A Mercury Mercury Date: 06/04/2015 03:07 PM Analytical Method: EPA 6020A Preparation Method: EPA 3020 20.5 ug/L 10.0 3.0 1 05/15/1510:17 05/18/1513:55 7429-90-5 ND ug/L 0.50 0.15 1 05/15/1510:17 05/18/1513:55 7440-36-0 ND ug/L 0.50 0.11 1 05/15/1510:17 05/18/1513:55 7440-38-2 0.35 ug/L 0.30 0.081 1 05/15/1510:17 05/18/1513:55 7440-39-3 ND ug/L 0.20 0.067 1 05/15/1510:17 05/18/1513:55 7440-41-7 ND ug/L 5.0 1.1 1 05/15/1510:17 05/18/1513:55 7440-42-8 ND ug/L 0.080 0.024 1 05/15/1510:17 05/18/1513:55 7440-43-9 337 ug/L 40.0 16.0 1 05/15/1510:17 05/18/1513:55 7440-70-2 2.2 ug/L 0.50 0.17 1 05/15/1510:17 05/18/1513:55 7440-47-3 ND ug/L 0.50 0.13 1 05/15/1510:17 05/18/1513:55 7440-48-4 0.67J ug/L 1.0 0.21 1 05/15/1510:17 05/18/1513:55 7440-50-8 105 ug/L 50.0 13.7 1 05/15/1510:17 05/18/1513:55 7439-89-6 ND ug/L 0.10 0.046 1 05/15/1510:17 05/18/1513:55 7439-92-1 5.9J ug/L 10.0 3.2 1 05/15/1510:17 05/18/1513:55 7439-95-4 1.3 ug/L 0.50 0.24 1 05/15/1510:17 05/18/1513:55 7439-96-5 19.3 ug/L 0.50 0.094 1 05/15/1510:17 05/18/1513:55 7439-98-7 0.35J ug/L 0.50 0.16 1 05/15/1510:17 05/18/1513:55 7440-02-0 48.1J ug/L 50.0 11.7 1 05/15/1510:17 05/18/1513:55 7440-09-7 ND ug/L 0.50 0.20 1 05/15/1510:17 05/18/1513:55 7782-49-2 16.9J ug/L 50.0 16.3 1 05/15/1510:17 05/18/1513:55 7440-23-5 0.68 ug/L 0.50 0.13 1 05/15/1510:17 05/18/1513:55 7440-24-6 ND ug/L 0.10 0.015 1 05/15/1510:17 05/18/1513:55 7440-28-0 ND ug/L 1.0 0.28 1 05/15/1510:17 05/18/1513:55 7440-62-2 2.5J ug/L 5.0 2.4 1 05/15/1510:17 05/18/1513:55 7440-66-6 Analytical Method: EPA 7470A Preparation Method: EPA 7470A ND ug/L 0.20 0.022 1 05/15/15 09:10 05/15/15 10:58 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 23 of 53 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K3�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15050212 Pace Project No.: 92249061 Sample: 2015013900 Lab ID: 92249061002 Collected: 05/07/15 12:20 Received: 05/08/15 11:55 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Aluminum Barium Beryllium Boron Calcium Chromium Copper Iron Magnesium Manganese Molybdenum Nickel Potassium Sodium Strontium Zinc 6020 MET ICPMS Antimony Arsenic Cadmium Cobalt Lead Selenium Thallium Vanadium 7471 Mercury Mercury Percent Moisture Percent Moisture 9045 pH Soil pH at 25 Degrees C 300.0 IC Anions, SPLP Sulfate 353.2 Nitrogen, NO2/NO3, SPLP Nitrogen, Nitrate 4500 Chloride, SPLP Chloride Date: 06/04/2015 03:07 PM Analytical Method: EPA 6010 Preparation Method: EPA 3050 9000 mg/kg 29.1 14.5 5 05/20/1514:45 05/22/1518:54 7429-90-5 M1 68.8 mg/kg 2.9 1.5 5 05/20/1514:45 05/22/1518:54 7440-39-3 M1 0.46 mg/kg 0.29 0.15 5 05/20/1514:45 05/22/1518:54 7440-41-7 ND mg/kg 14.5 7.3 5 05/20/1514:45 05/22/1518:54 7440-42-8 301 mg/kg 145 72.7 5 05/20/1514:45 05/22/1518:54 7440-70-2 11.4 mg/kg 1.5 0.73 5 05/20/1514:45 05/22/1518:54 7440-47-3 7.7 mg/kg 1.5 0.73 5 05/20/1514:45 05/22/1518:54 7440-50-8 9460 mg/kg 11.6 5.8 5 05/20/1514:45 05/22/1518:54 7439-89-6 M1 1110 mg/kg 145 72.7 5 05/20/1514:45 05/22/1518:54 7439-95-4 693 mg/kg 1.5 0.73 5 05/20/1514:45 05/22/1518:54 7439-96-5 M1 ND mg/kg 2.9 1.5 5 05/20/1514:45 05/22/1518:54 7439-98-7 4.2 mg/kg 1.5 0.73 5 05/20/1514:45 05/22/1518:54 7440-02-0 534 mg/kg 291 145 5 05/20/1514:45 05/22/1518:54 7440-09-7 ND mg/kg 291 145 5 05/20/1514:45 05/22/1518:54 7440-23-5 5.7 mg/kg 2.9 1.5 5 05/20/1514:45 05/22/1518:54 7440-24-6 21.4 mg/kg 5.8 2.9 5 05/20/1514:45 05/22/1518:54 7440-66-6 Analytical Method: EPA 6020 Preparation Method: EPA 3050 ND mg/kg 5.8 2.9 100 05/20/1514:45 05/22/1519:48 7440-36-0 M6,N2 ND mg/kg 5.8 2.9 100 05/20/1514:45 05/22/1519:48 7440-38-2 M6 ND mg/kg 0.70 0.35 100 05/20/1514:45 05/22/1519:48 7440-43-9 5.9 mg/kg 5.8 2.9 100 05/20/1514:45 05/22/1519:48 7440-48-4 5AJ mg/kg 5.8 2.9 100 05/20/1514:45 05/22/1519:48 7439-92-1 M6 ND mg/kg 5.8 2.9 100 05/20/1514:45 05/22/1519:48 7782-49-2 M6 ND mg/kg 5.8 2.9 100 05/20/1514:45 05/22/1519:48 7440-28-0 M6 17.6 mg/kg 5.8 2.9 100 05/20/1514:45 05/22/1519:48 7440-62-2 M6 Analytical Method: EPA 7471 Preparation Method: EPA 7471 0.037 mg/kg 0.0096 0.0048 1 05/20/1514:50 05/21/1513:02 7439-97-6 Analytical Method: ASTM D2974-87 13.0 % 0.10 0.10 1 05/20/1510:34 Analytical Method: EPA 9045 5.1 Std. Units 0.10 0.10 1 05/18/15 15:45 Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 05/14/15 03:45 5.2 mg/L 2.3 1.1 1 05/22/1518:08 14808-79-8 B Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 05/14/15 03:45 0.31 mg/L 0.23 0.23 1 05/28/15 20:31 H1 Analytical Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 05/14/15 03:45 ND mg/L 5.7 2.9 1 05/21/15 05:26 16887-00-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 24 of 53 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K�n�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15050212 Pace Project No.: 92249061 Sample: 2015013900 Lab ID: 92249061002 Collected: 05/07/15 12:20 Received: 05/08/15 11:55 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 286 143 5 05/16/1518:57 16887-00-6 D3 Sulfate ND mg/kg 286 143 5 05/16/1518:57 14808-79-8 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 28.6 14.3 5 05/16/15 18:57 14797-55-8 H3 Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 1650 mg/kg 686 343 1 06/02/15 16:19 7440-44-0 Total Organic Carbon 1600 mg/kg 694 347 1 06/02/15 16:25 7440-44-0 Total Organic Carbon 1620 mg/kg 694 347 1 06/02/15 16:30 7440-44-0 Total Organic Carbon 1570 mg/kg 690 345 1 06/02/15 16:36 7440-44-0 Mean Total Organic Carbon 1610 mg/kg 691 345 1 06/02/15 16:19 7440-44-0 Surrogates RSD% 2.2 % 1 06/02/15 16:19 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2015 03:07 PM without the written consent of Pace Analytical Services, Inc.. Page 25 of 53 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K3�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15050212 Pace Project No.: 92249061 Sample: 2015013901 Lab ID: 92249061003 Collected: 05/07/15 12:45 Received: 05/08/15 11:55 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Aluminum Barium Beryllium Boron Calcium Chromium Copper Iron Magnesium Manganese Molybdenum Nickel Potassium Sodium Strontium Zinc 6020 MET ICPMS Antimony Arsenic Cadmium Cobalt Lead Selenium Thallium Vanadium 7471 Mercury Mercury Percent Moisture Percent Moisture 9045 pH Soil pH at 25 Degrees C 300.0 IC Anions, SPLP Sulfate 353.2 Nitrogen, NO2/NO3, SPLP Nitrogen, Nitrate 4500 Chloride, SPLP Chloride Date: 06/04/2015 03:07 PM Analytical Method: EPA 6010 Preparation Method: EPA 3050 2020 mg/kg 30.0 15.0 5 05/20/1514:45 05/22/1519:06 7429-90-5 15.5 mg/kg 3.0 1.5 5 05/20/1514:45 05/22/1519:06 7440-39-3 0.21J mg/kg 0.30 0.15 5 05/20/1514:45 05/22/1519:06 7440-41-7 ND mg/kg 15.0 7.5 5 05/20/1514:45 05/22/1519:06 7440-42-8 154 mg/kg 150 75.0 5 05/20/1514:45 05/22/1519:06 7440-70-2 8.2 mg/kg 1.5 0.75 5 05/20/1514:45 05/22/1519:06 7440-47-3 4.4 mg/kg 1.5 0.75 5 05/20/1514:45 05/22/1519:06 7440-50-8 6040 mg/kg 12.0 6.0 5 05/20/1514:45 05/22/1519:06 7439-89-6 387 mg/kg 150 75.0 5 05/20/1514:45 05/22/1519:06 7439-95-4 226 mg/kg 1.5 0.75 5 05/20/1514:45 05/22/1519:06 7439-96-5 ND mg/kg 3.0 1.5 5 05/20/1514:45 05/22/1519:06 7439-98-7 1.4J mg/kg 1.5 0.75 5 05/20/1514:45 05/22/1519:06 7440-02-0 266J mg/kg 300 150 5 05/20/1514:45 05/22/1519:06 7440-09-7 ND mg/kg 300 150 5 05/20/1514:45 05/22/1519:06 7440-23-5 2.9J mg/kg 3.0 1.5 5 05/20/1514:45 05/22/1519:06 7440-24-6 6.5 mg/kg 6.0 3.0 5 05/20/1514:45 05/22/1519:06 7440-66-6 Analytical Method: EPA 6020 Preparation Method: EPA 3050 ND mg/kg 6.0 3.0 100 05/20/1514:45 05/22/1519:55 7440-36-0 ND mg/kg 6.0 3.0 100 05/20/1514:45 05/22/1519:55 7440-38-2 ND mg/kg 0.72 0.36 100 05/20/1514:45 05/22/1519:55 7440-43-9 ND mg/kg 6.0 3.0 100 05/20/1514:45 05/22/1519:55 7440-48-4 ND mg/kg 6.0 3.0 100 05/20/1514:45 05/22/1519:55 7439-92-1 ND mg/kg 6.0 3.0 100 05/20/1514:45 05/22/1519:55 7782-49-2 ND mg/kg 6.0 3.0 100 05/20/1514:45 05/22/1519:55 7440-28-0 8.2 mg/kg 6.0 3.0 100 05/20/1514:45 05/22/1519:55 7440-62-2 Analytical Method: EPA 7471 Preparation Method: EPA 7471 0.011 mg/kg 0.0092 0.0046 1 05/20/1514:50 05/21/1513:09 7439-97-6 Analytical Method: ASTM D2974-87 17.2 % 0.10 0.10 1 05/20/1510:34 Analytical Method: EPA 9045 6.4 Std. Units 0.10 0.10 1 05/18/15 15:45 N2 Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 05/14/15 03:45 5.7 mg/L 2.4 1.2 1 05/22/1518:21 14808-79-8 B Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 05/14/15 03:45 0.29 mg/L 0.24 0.24 1 05/28/15 20:33 H1 Analytical Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 05/14/15 03:45 ND mg/L 6.0 3.0 1 06/04/15 06:41 16887-00-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 26 of 53 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15050212 Pace Project No.: 92249061 Sample: 2015013901 Lab ID: 92249061003 Collected: 05/07/15 12:45 Received: 05/08/15 11:55 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 300 150 5 05/16/15 20:01 16887-00-6 D3 Sulfate ND mg/kg 300 150 5 05/16/15 20:01 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 30.0 15.0 5 05/16/15 20:01 14797-55-8 H3 Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 922 mg/kg 722 361 1 06/02/15 16:54 7440-44-0 Total Organic Carbon 918 mg/kg 722 361 1 06/02/15 16:59 7440-44-0 Total Organic Carbon 963 mg/kg 728 364 1 06/02/15 17:05 7440-44-0 Total Organic Carbon 736 mg/kg 723 361 1 06/02/15 17:12 7440-44-0 Mean Total Organic Carbon 885 mg/kg 724 362 1 06/02/15 16:54 7440-44-0 Surrogates RSD% 11.4 % 1 06/02/15 16:54 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2015 03:07 PM without the written consent of Pace Analytical Services, Inc.. Page 27 of 53 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K3c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15050212 Pace Project No.: 92249061 Sample: 2015013900 SPLP Lab ID: 92249061004 Collected: 05/07/15 12:20 Received: 05/08/15 11:55 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;T➢Z17c\�iil=11 a Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470A Mercury Mercury Date: 06/04/2015 03:07 PM Analytical Method: EPA 6020A Preparation Method: EPA 3020 133 ug/L 10.0 3.0 1 05/28/1510:26 05/28/1518:01 7429-90-5 ND ug/L 0.50 0.15 1 05/28/1510:26 05/28/1518:01 7440-36-0 ND ug/L 0.50 0.11 1 05/28/1510:26 05/28/1518:01 7440-38-2 126 ug/L 0.30 0.081 1 05/28/1510:26 05/28/1518:01 7440-39-3 ND ug/L 0.20 0.067 1 05/28/1510:26 05/28/1518:01 7440-41-7 77.5 ug/L 5.0 1.1 1 05/28/1510:26 05/28/1518:01 7440-42-8 ND ug/L 0.080 0.024 1 05/28/1510:26 05/28/1518:01 7440-43-9 870 ug/L 40.0 16.0 1 05/28/1510:26 05/28/1518:01 7440-70-2 0.37J ug/L 0.50 0.17 1 05/28/1510:26 05/28/1518:01 7440-47-3 ND ug/L 0.50 0.13 1 05/28/1510:26 05/28/1518:01 7440-48-4 0.85J ug/L 1.0 0.21 1 05/28/1510:26 05/28/1518:01 7440-50-8 61.7 ug/L 50.0 13.7 1 05/28/1510:26 05/28/1518:01 7439-89-6 0.054J ug/L 0.10 0.046 1 05/28/1510:26 05/28/1518:01 7439-92-1 270 ug/L 10.0 3.2 1 05/28/1510:26 05/28/1518:01 7439-95-4 9.3 ug/L 0.50 0.24 1 05/28/1510:26 05/28/1518:01 7439-96-5 ND ug/L 0.50 0.094 1 05/28/1510:26 05/28/1518:01 7439-98-7 0.35J ug/L 0.50 0.16 1 05/28/1510:26 05/28/1518:01 7440-02-0 318 ug/L 50.0 11.7 1 05/28/1510:26 05/28/1518:01 7440-09-7 ND ug/L 0.50 0.20 1 05/28/1510:26 05/28/1518:01 7782-49-2 1410 ug/L 50.0 16.3 1 05/28/1510:26 05/28/1518:01 7440-23-5 16.8 ug/L 0.50 0.13 1 05/28/1510:26 05/28/1518:01 7440-24-6 ND ug/L 0.10 0.015 1 05/28/1510:26 05/28/1518:01 7440-28-0 ND ug/L 1.0 0.28 1 05/28/1510:26 05/28/1518:01 7440-62-2 60.6 ug/L 5.0 2.4 1 05/28/1510:26 05/28/1518:01 7440-66-6 Analytical Method: EPA 7470A Preparation Method: EPA 7470A ND ug/L 0.20 0.022 1 05/30/1510:30 06/01/1513:38 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 28 of 53 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K3�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15050212 Pace Project No.: 92249061 Sample: 2015013901 SPLP Lab ID: 92249061005 Collected: 05/07/15 12:45 Received: 05/08/15 11:55 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;T➢Z17c\�iil=11 a Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470A Mercury Mercury Date: 06/04/2015 03:07 PM Analytical Method: EPA 6020A Preparation Method: EPA 3020 18200 ug/L 10.0 3.0 1 05/28/1510:26 05/28/1518:24 7429-90-5 ND ug/L 0.50 0.15 1 05/28/1510:26 05/28/1518:24 7440-36-0 2.0 ug/L 0.50 0.11 1 05/28/1510:26 05/28/1518:24 7440-38-2 252 ug/L 0.30 0.081 1 05/28/1510:26 05/28/1518:24 7440-39-3 0.66 ug/L 0.20 0.067 1 05/28/1510:26 05/28/1518:24 7440-41-7 63.7 ug/L 5.0 1.1 1 05/28/1510:26 05/28/1518:24 7440-42-8 0.028J ug/L 0.080 0.024 1 05/28/1510:26 05/28/1518:24 7440-43-9 1890 ug/L 40.0 16.0 1 05/28/1510:26 05/28/1518:24 7440-70-2 19.9 ug/L 0.50 0.17 1 05/28/1510:26 05/28/1518:24 7440-47-3 4.5 ug/L 0.50 0.13 1 05/28/1510:26 05/28/1518:24 7440-48-4 15.3 ug/L 1.0 0.21 1 05/28/1510:26 05/28/1518:24 7440-50-8 17300 ug/L 50.0 13.7 1 05/28/1510:26 05/28/1518:24 7439-89-6 5.7 ug/L 0.10 0.046 1 05/28/1510:26 05/28/1518:24 7439-92-1 1920 ug/L 10.0 3.2 1 05/28/1510:26 05/28/1518:24 7439-95-4 491 ug/L 2.5 1.2 5 05/28/15 10:26 05/29/15 08:01 7439-96-5 1.1 ug/L 0.50 0.094 1 05/28/1510:26 05/28/1518:24 7439-98-7 9.5 ug/L 0.50 0.16 1 05/28/1510:26 05/28/1518:24 7440-02-0 1820 ug/L 50.0 11.7 1 05/28/1510:26 05/28/1518:24 7440-09-7 0.24J ug/L 0.50 0.20 1 05/28/1510:26 05/28/1518:24 7782-49-2 2270 ug/L 50.0 16.3 1 05/28/1510:26 05/28/1518:24 7440-23-5 34.2 ug/L 0.50 0.13 1 05/28/1510:26 05/28/1518:24 7440-24-6 0.12 ug/L 0.10 0.015 1 05/28/1510:26 05/28/1518:24 7440-28-0 32.0 ug/L 1.0 0.28 1 05/28/1510:26 05/28/1518:24 7440-62-2 92.3 ug/L 5.0 2.4 1 05/28/1510:26 05/28/1518:24 7440-66-6 Analytical Method: EPA 7470A Preparation Method: EPA 7470A ND ug/L 0.20 0.022 1 05/30/1510:30 06/01/1513:41 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 29 of 53 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K��c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050212 Pace Project No.: 92249061 QC Batch: MERP/13557 Analysis Method: EPA 7470A QC Batch Method: EPA 7470A Analysis Description: 7470A Mercury Water Associated Lab Samples: 92249061001 METHOD BLANK: 1966620 Matrix: Water Associated Lab Samples: 92249061001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury ug/L ND 0.20 05/15/1510:43 LABORATORY CONTROL SAMPLE: 1966621 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 5 4.9 98 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1966707 1966708 MS MSD 92249477011 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 5 5 4.7 4.8 94 97 80-120 3 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2015 03:07 PM without the written consent of Pace Analytical Services, Inc.. Page 30 of 53 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050212 Pace Project No.: 92249061 QC Batch: MERP/13677 Analysis Method: EPA 7470A QC Batch Method: EPA 7470A Analysis Description: 7470A Mercury Water Associated Lab Samples: 92249061004, 92249061005 METHOD BLANK: 1977489 Matrix: Water Associated Lab Samples: 92249061004, 92249061005 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury ug/L ND 0.20 06/01/1513:04 LABORATORY CONTROL SAMPLE: 1977490 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 5 5.0 99 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1980282 1980283 MS MSD 92251147009 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 5 5 5.2 5.1 103 102 80-120 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2015 03:07 PM without the written consent of Pace Analytical Services, Inc.. Page 31 of 53 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K�gc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050212 Pace Project No.: 92249061 QC Batch: MERP/5748 Analysis Method: EPA 7471 QC Batch Method: EPA 7471 Analysis Description: 7471 Mercury Associated Lab Samples: 92249061002, 92249061003 METHOD BLANK: 1218709 Matrix: Solid Associated Lab Samples: 92249061002, 92249061003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury mg/kg ND 0.0081 05/21/1512:58 LABORATORY CONTROL SAMPLE: 1218710 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury mg/kg .08 0.080 100 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1218711 1218712 MS MSD 92249061002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury mg/kg 0.037 .0954 .0943 0.13 0.12 94 86 80-120 7 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2015 03:07 PM without the written consent of Pace Analytical Services, Inc.. Page 32 of 53 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K��c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050212 Pace Project No.: 92249061 QC Batch: MPRP/24249 Analysis Method: EPA 6010 QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid Associated Lab Samples: 92249061002, 92249061003 METHOD BLANK: 1218697 Associated Lab Samples: 92249061002, 92249061003 Parameter Units Aluminum mg/kg Barium mg/kg Beryllium mg/kg Boron mg/kg Calcium mg/kg Chromium mg/kg Copper mg/kg Iron mg/kg Magnesium mg/kg Manganese mg/kg Molybdenum mg/kg Nickel mg/kg Potassium mg/kg Sodium mg/kg Strontium mg/kg Zinc mg/kg Matrix: Solid Blank Result Reporting Limit Analyzed ND 5.1 05/22/1518:46 ND 0.51 05/22/1518:46 ND 0.051 05/22/1518:46 ND 2.5 05/22/1518:46 ND 25.5 05/22/1518:46 ND 0.25 05/22/1518:46 ND 0.25 05/22/1518:46 ND 2.0 05/22/1518:46 ND 25.5 05/22/1518:46 ND 0.25 05/22/1518:46 ND 0.51 05/22/1518:46 ND 0.25 05/22/1518:46 ND 50.9 05/22/1518:46 ND 50.9 05/22/1518:46 ND 0.51 05/22/1518:46 ND 1.0 05/22/1518:46 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 1218698 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Aluminum mg/kg 130 131 101 80-120 Barium mg/kg 13 13.2 102 80-120 Beryllium mg/kg 1.3 1.3 103 80-120 Boron mg/kg 130 131 101 80-120 Calcium mg/kg 649 653 101 80-120 Chromium mg/kg 13 13.2 102 80-120 Copper mg/kg 13 12.9 100 80-120 Iron mg/kg 130 131 101 80-120 Magnesium mg/kg 649 649 100 80-120 Manganese mg/kg 13 13.1 101 80-120 Molybdenum mg/kg 13 12.8 98 80-120 Nickel mg/kg 13 13.0 101 80-120 Potassium mg/kg 649 635 98 80-120 Sodium mg/kg 649 671 104 80-120 Strontium mg/kg 13 12.8 99 80-120 Zinc mg/kg 64.9 65.7 101 80-120 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2015 03:07 PM without the written consent of Pace Analytical Services, Inc.. Page 33 of 53 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050212 Pace Project No.: 92249061 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1218699 1218700 MS MSD 92249061002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum mg/kg 9000 149 151 13700 13800 3150 3180 75-125 0 20 M1 Barium mg/kg 68.8 14.9 15.1 90.2 88.7 142 133 75-125 2 20 M1 Beryllium mg/kg 0.46 1.49 1.49 1.8 1.9 92 95 75-125 2 20 Boron mg/kg ND 149 151 128 132 84 87 75-125 3 20 Calcium mg/kg 301 749 751 1080 1080 104 104 75-125 0 20 Chromium mg/kg 11.4 14.9 15.1 26.1 27.9 98 110 75-125 7 20 Copper mg/kg 7.7 14.9 15.1 22.0 22.8 96 100 75-125 3 20 Iron mg/kg 9460 149 151 10000 10500 384 687 75-125 4 20 M1 Magnesium mg/kg 1110 749 751 1890 1900 104 105 75-125 0 20 Manganese mg/kg 693 14.9 15.1 665 729 -182 241 75-125 9 20 M1 Molybdenum mg/kg ND 14.9 15.1 12.1 12.7 79 82 75-125 4 20 Nickel mg/kg 4.2 14.9 15.1 19.2 19.5 100 102 75-125 2 20 Potassium mg/kg 534 749 751 1380 1410 113 116 75-125 2 20 Sodium mg/kg ND 749 751 754 704 93 87 75-125 7 20 Strontium mg/kg 5.7 14.9 15.1 21.2 21.3 103 104 75-125 0 20 Zinc mg/kg 21.4 74.9 75.1 94.7 96.7 98 100 75-125 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2015 03:07 PM without the written consent of Pace Analytical Services, Inc.. Page 34 of 53 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 1inlc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050212 Pace Project No.: 92249061 QC Batch: MPRP/24250 Analysis Method: EPA 6020 QC Batch Method: EPA 3050 Analysis Description: 6020 MET SOLID Associated Lab Samples: 92249061002, 92249061003 METHOD BLANK: 1218703 Matrix: Solid Associated Lab Samples: 92249061002, 92249061003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Antimony mg/kg ND 0.051 05/22/1519:44 N2 Arsenic mg/kg ND 0.051 05/22/1519:44 Cadmium mg/kg ND 0.0061 05/22/1519:44 Cobalt mg/kg ND 0.051 05/22/1519:44 Lead mg/kg ND 0.051 05/22/1519:44 Selenium mg/kg ND 0.051 05/22/1519:44 Thallium mg/kg ND 0.051 05/22/1519:44 Vanadium mg/kg ND 0.051 05/22/1519:44 LABORATORY CONTROL SAMPLE: 1218704 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Antimony mg/kg 2.5 2.5 102 80-120 N2 Arsenic mg/kg 2.5 2.6 103 80-120 Cadmium mg/kg .25 0.25 100 80-120 Cobalt mg/kg 2.5 2.5 102 80-120 Lead mg/kg 2.5 2.5 101 80-120 Selenium mg/kg 2.5 2.5 101 80-120 Thallium mg/kg 2.5 2.5 103 80-120 Vanadium mg/kg 2.5 2.5 101 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1218705 1218706 MS MSD 92249061002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony mg/kg ND 2.87 2.87 ND ND 63 52 75-125 20 M6, N2 Arsenic mg/kg ND 2.87 2.87 3.3J 3.OJ 68 55 75-125 20 M6 Cadmium mg/kg ND .287 .287 ND ND 112 80 75-125 20 Cobalt mg/kg 5.9 2.87 2.87 8.8 8.2 101 79 75-125 7 20 Lead mg/kg 5AJ 2.87 2.87 8.0 7.4 93 69 75-125 8 20 M6 Selenium mg/kg ND 2.87 2.87 3.1J 3.OJ 29 27 75-125 20 M6 Thallium mg/kg ND 2.87 2.87 2.9J ND 85 74 75-125 20 M6 Vanadium mg/kg 17.6 2.87 2.87 19.7 17.9 74 11 75-125 9 20 M6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2015 03:07 PM without the written consent of Pace Analytical Services, Inc.. Page 35 of 53 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050212 Pace Project No.: 92249061 QC Batch: MPRP/54425 Analysis Method: EPA 6020A QC Batch Method: EPA 3020 Analysis Description: 6020A Water UPD4 Associated Lab Samples: 92249061001 METHOD BLANK: 1966603 Associated Lab Samples: 92249061001 Parameter Units Aluminum ug/L Antimony ug/L Arsenic ug/L Barium ug/L Beryllium ug/L Boron ug/L Cadmium ug/L Calcium ug/L Chromium ug/L Cobalt ug/L Copper ug/L Iron ug/L Lead ug/L Magnesium ug/L Manganese ug/L Molybdenum ug/L Nickel ug/L Potassium ug/L Selenium ug/L Sodium ug/L Strontium ug/L Thallium ug/L Vanadium ug/L Zinc ug/L Matrix: Water Blank Result Reporting Limit Analyzed ND 10.0 05/18/1513:36 ND 0.50 05/18/1513:36 ND 0.50 05/18/1513:36 ND 0.30 05/18/1513:36 ND 0.20 05/18/1513:36 ND 5.0 05/18/1513:36 ND 0.080 05/18/1513:36 ND 40.0 05/18/1513:36 ND 0.50 05/18/1513:36 ND 0.50 05/18/1513:36 ND 1.0 05/18/1513:36 ND 50.0 05/18/1513:36 ND 0.10 05/18/1513:36 ND 10.0 05/18/1513:36 ND 0.50 05/18/1513:36 ND 0.50 05/18/1513:36 ND 0.50 05/18/1513:36 ND 50.0 05/18/1513:36 ND 0.50 05/18/1513:36 ND 50.0 05/18/1513:36 ND 0.50 05/18/1513:36 ND 0.10 05/18/1513:36 ND 1.0 05/18/1513:36 ND 5.0 05/18/1513:36 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 1966604 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Aluminum ug/L 80 75.6 94 80-120 Antimony ug/L 80 77.8 97 80-120 Arsenic ug/L 80 76.4 96 80-120 Barium ug/L 80 76.0 95 80-120 Beryllium ug/L 80 76.9 96 80-120 Boron ug/L 80 73.1 91 80-120 Cadmium ug/L 80 77.0 96 80-120 Calcium ug/L 1000 1020 102 80-120 Chromium ug/L 80 77.4 97 80-120 Cobalt ug/L 80 75.8 95 80-120 Copper ug/L 80 75.6 95 80-120 Iron ug/L 1000 951 95 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2015 03:07 PM without the written consent of Pace Analytical Services, Inc.. Page 36 of 53 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 I� %fir&e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050212 Pace Project No.: 92249061 LABORATORY CONTROL SAMPLE: 1966604 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Lead ug/L 80 78.2 98 80-120 Magnesium ug/L 1000 927 93 80-120 Manganese ug/L 80 76.8 96 80-120 Molybdenum ug/L 80 77.0 96 80-120 Nickel ug/L 80 76.5 96 80-120 Potassium ug/L 1000 954 95 80-120 Selenium ug/L 80 73.8 92 80-120 Sodium ug/L 1000 926 93 80-120 Strontium ug/L 80 76.4 96 80-120 Thallium ug/L 80 80.4 100 80-120 Vanadium ug/L 80 76.9 96 80-120 Zinc ug/L 80 75.6 95 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1966605 1966606 MS MSD 92249061001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum ug/L 20.5 80 80 124 129 130 136 75-125 4 20 M1 Antimony ug/L ND 80 80 77.0 76.7 96 96 75-125 0 20 Arsenic ug/L ND 80 80 76.1 75.0 95 94 75-125 2 20 Barium ug/L 0.35 80 80 74.2 74.6 92 93 75-125 1 20 Beryllium ug/L ND 80 80 77.9 76.9 97 96 75-125 1 20 Boron ug/L ND 80 80 71.9 77.2 89 96 75-125 7 20 Cadmium ug/L ND 80 80 76.2 76.2 95 95 75-125 0 20 Calcium ug/L 337 1000 1000 1370 1330 103 99 75-125 3 20 Chromium ug/L 2.2 80 80 78.8 79.1 96 96 75-125 0 20 Cobalt ug/L ND 80 80 75.4 75.2 94 94 75-125 0 20 Copper ug/L 0.67J 80 80 76.3 76.6 95 95 75-125 0 20 Iron ug/L 105 1000 1000 1060 1060 95 95 75-125 0 20 Lead ug/L ND 80 80 77.5 77.6 97 97 75-125 0 20 Magnesium ug/L 5.91 1000 1000 994 966 99 96 75-125 3 20 Manganese ug/L 1.3 80 80 77.1 77.4 95 95 75-125 0 20 Molybdenum ug/L 19.3 80 80 95.0 94.4 95 94 75-125 1 20 Nickel ug/L 0.35J 80 80 77.0 76.8 96 96 75-125 0 20 Potassium ug/L 48.1J 1000 1000 989 974 94 93 75-125 2 20 Selenium ug/L ND 80 80 74.5 72.4 93 90 75-125 3 20 Sodium ug/L 16.9J 1000 1000 915 950 90 93 75-125 4 20 Strontium ug/L 0.68 80 80 76.0 76.8 94 95 75-125 1 20 Thallium ug/L ND 80 80 79.5 79.8 99 100 75-125 0 20 Vanadium ug/L ND 80 80 75.9 76.6 95 95 75-125 1 20 Zinc ug/L 2.5J 80 80 77.2 76.5 93 92 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2015 03:07 PM without the written consent of Pace Analytical Services, Inc.. Page 37 of 53 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Iic&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050212 Pace Project No.: 92249061 QC Batch: MPRP/54657 Analysis Method: EPA 6020A QC Batch Method: EPA 3020 Analysis Description: 6020A Water UPD4 Associated Lab Samples: 92249061004, 92249061005 METHOD BLANK: 1975920 Associated Lab Samples: 92249061004, 92249061005 Parameter Units Aluminum ug/L Antimony ug/L Arsenic ug/L Barium ug/L Beryllium ug/L Boron ug/L Cadmium ug/L Calcium ug/L Chromium ug/L Cobalt ug/L Copper ug/L Iron ug/L Lead ug/L Magnesium ug/L Manganese ug/L Molybdenum ug/L Nickel ug/L Potassium ug/L Selenium ug/L Sodium ug/L Strontium ug/L Thallium ug/L Vanadium ug/L Zinc ug/L Matrix: Water Blank Result Reporting Limit Analyzed ND 10.0 05/29/15 07:58 ND 0.50 05/29/15 07:58 ND 0.50 05/29/15 07:58 ND 0.30 05/29/15 07:58 ND 0.20 05/29/15 07:58 ND 5.0 05/29/15 07:58 ND 0.080 05/29/15 07:58 ND 40.0 05/29/15 07:58 ND 0.50 05/29/15 07:58 ND 0.50 05/29/15 07:58 ND 1.0 05/29/15 07:58 ND 50.0 05/29/15 07:58 ND 0.10 05/29/15 07:58 ND 10.0 05/29/15 07:58 ND 0.50 05/29/15 07:58 ND 0.50 05/29/15 07:58 ND 0.50 05/29/15 07:58 ND 50.0 05/29/15 07:58 ND 0.50 05/29/15 07:58 ND 50.0 05/29/15 07:58 ND 0.50 05/29/15 07:58 ND 0.10 05/29/15 07:58 ND 1.0 05/29/15 07:58 ND 5.0 05/29/15 07:58 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 1975921 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Aluminum ug/L 80 80.8 101 80-120 Antimony ug/L 80 80.3 100 80-120 Arsenic ug/L 80 80.1 100 80-120 Barium ug/L 80 79.6 99 80-120 Beryllium ug/L 80 84.4 106 80-120 Boron ug/L 80 83.7 105 80-120 Cadmium ug/L 80 82.2 103 80-120 Calcium ug/L 1000 943 94 80-120 Chromium ug/L 80 83.7 105 80-120 Cobalt ug/L 80 82.3 103 80-120 Copper ug/L 80 86.3 108 80-120 Iron ug/L 1000 1040 104 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2015 03:07 PM without the written consent of Pace Analytical Services, Inc.. Page 38 of 53 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050212 Pace Project No.: 92249061 LABORATORY CONTROL SAMPLE: 1975921 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Lead ug/L 80 82.5 103 80-120 Magnesium ug/L 1000 1010 101 80-120 Manganese ug/L 80 84.4 106 80-120 Molybdenum ug/L 80 81.3 102 80-120 Nickel ug/L 80 83.2 104 80-120 Potassium ug/L 1000 1010 101 80-120 Selenium ug/L 80 81.6 102 80-120 Sodium ug/L 1000 996 100 80-120 Strontium ug/L 80 80.4 100 80-120 Thallium ug/L 80 83.4 104 80-120 Vanadium ug/L 80 82.4 103 80-120 Zinc ug/L 80 83.0 104 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1975922 1975923 MS MSD 92250515004 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum ug/L 4980 80 80 6650 6480 2090 1880 75-125 3 20 M1 Antimony ug/L ND 80 80 78.3 76.8 98 96 75-125 2 20 Arsenic ug/L 0.31J 80 80 80.2 78.7 100 98 75-125 2 20 Barium ug/L 14.4 80 80 95.1 94.3 101 100 75-125 1 20 Beryllium ug/L ND 80 80 85.5 84.7 107 106 75-125 1 20 Boron ug/L ND 80 80 88.7 86.7 110 107 75-125 2 20 Cadmium ug/L ND 80 80 83.0 83.4 104 104 75-125 0 20 Calcium ug/L 4220 1000 1000 6590 6550 236 233 75-125 1 20 M1 Chromium ug/L 80.3 80 80 168 166 109 107 75-125 1 20 Cobalt ug/L 2.9 80 80 87.6 86.8 106 105 75-125 1 20 Copper ug/L 12.2 80 80 99.7 98.0 109 107 75-125 2 20 Iron ug/L 15800 1000 1000 18800 18400 291 259 75-125 2 20 M1 Lead ug/L 0.39 80 80 83.4 83.5 104 104 75-125 0 20 Magnesium ug/L 2050 1000 1000 3850 3800 179 175 75-125 1 20 M1 Manganese ug/L 163 80 80 280 276 146 141 75-125 1 20 M1 Molybdenum ug/L 14.4 80 80 96.4 95.3 103 101 75-125 1 20 Nickel ug/L 5.7 80 80 90.4 88.5 106 103 75-125 2 20 Potassium ug/L 395 1000 1000 1460 1420 106 103 75-125 2 20 Selenium ug/L ND 80 80 81.9 81.2 102 101 75-125 1 20 Sodium ug/L 903 1000 1000 2140 2430 124 153 75-125 12 20 M1 Strontium ug/L 29.7 80 80 121 118 114 111 75-125 2 20 Thallium ug/L ND 80 80 85.0 84.4 106 106 75-125 1 20 Vanadium ug/L 15.3 80 80 105 104 112 111 75-125 1 20 Zinc ug/L 9.7 80 80 94.0 91.4 105 102 75-125 3 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2015 03:07 PM without the written consent of Pace Analytical Services, Inc.. Page 39 of 53 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050212 Pace Project No.: 92249061 QC Batch: PMST/3581 Analysis Method: ASTM D2974-87 QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture Associated Lab Samples: 92249061002, 92249061003 SAMPLE DUPLICATE: 1218747 92248767001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 17.1 19.4 12 10 D6 SAMPLE DUPLICATE: 1218748 92249477001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 10.9 10.5 4 10 SAMPLE DUPLICATE: 1218749 92249077002 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 25.4 24.9 2 10 SAMPLE DUPLICATE: 1218750 92249681005 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 31.1 30.5 2 10 SAMPLE DUPLICATE: 1218751 92249710007 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 29.6 28.1 5 10 SAMPLE DUPLICATE: 1218752 92249710016 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 4.3 4.8 9 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2015 03:07 PM without the written consent of Pace Analytical Services, Inc.. Page 40 of 53 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Iic&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050212 Pace Project No.: 92249061 QC Batch: WET/37491 Analysis Method: EPA 9045 QC Batch Method: EPA 9045 Analysis Description: 9045 pH Associated Lab Samples: 92249061002, 92249061003 SAMPLE DUPLICATE: 1460370 92249101011 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 6.5 6.7 3 10 D6 SAMPLE DUPLICATE: 1460371 Parameter pH at 25 Degrees C 92249077002 Dup Units Result Result Std. Units 5.5 5.5 Max RPD RPD Qualifiers 0 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2015 03:07 PM without the written consent of Pace Analytical Services, Inc.. Page 41 of 53 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Iigc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050212 Pace Project No.: 92249061 QC Batch: WETA/23020 Analysis Method: EPA 300.0 QC Batch Method: EPA 300.0 Analysis Description: 300.0 IC Anions Associated Lab Samples: 92249061002, 92249061003 METHOD BLANK: 1465540 Matrix: Water Associated Lab Samples: 92249061002, 92249061003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Sulfate mg/L 3.1 2.0 05/22/1512:56 LABORATORY CONTROL SAMPLE: 1465541 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfate mg/L 20 19.7 99 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1465542 1465543 MS MSD 92248135006 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfate mg/L 12.6 31.9 31.9 45.6 45.8 104 104 0 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1465544 1465545 MS MSD 92248773012 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfate mg/L 5.4 25.3 25.3 30.6 30.7 99 100 0 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2015 03:07 PM without the written consent of Pace Analytical Services, Inc.. Page 42 of 53 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050212 Pace Project No.: 92249061 QC Batch: WETA/23082 Analysis Method: EPA 353.2 QC Batch Method: EPA 353.2 Analysis Description: 353.2 Nitrate + Nitrite, Unpres. Associated Lab Samples: 92249061002, 92249061003 METHOD BLANK: 1470182 Matrix: Water Associated Lab Samples: 92249061002, 92249061003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, Nitrate mg/L 0.14 0.020 05/28/15 20:01 Z2 LABORATORY CONTROL SAMPLE: 1470183 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Nitrate mg/L 2.5 2.5 100 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1470184 1470185 MS MSD 92248135006 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Nitrate mg/L 0.39 4 4 4.2 4.2 97 95 90-110 1 10 H1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1470186 1470187 MS MSD 92248135012 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Nitrate mg/L 0.31 3.1 3.1 3.3 3.3 98 98 90-110 0 10 H1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2015 03:07 PM without the written consent of Pace Analytical Services, Inc.. Page 43 of 53 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050212 Pace Project No.: 92249061 QC Batch: WETA/23009 Analysis Method: SM 4500-CI-E QC Batch Method: SM 4500-CI-E Analysis Description: 4500 Chloride Associated Lab Samples: 92249061002 METHOD BLANK: 1464494 Matrix: Water Associated Lab Samples: 92249061002 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/L ND 1.0 05/21/15 05:11 LABORATORY CONTROL SAMPLE: 1464495 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloride mg/L 20 19.9 99 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1464496 1464497 MS MSD 92248135006 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride mg/L ND 31.9 31.9 33.1 32.7 101 100 90-110 1 10 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1464498 1464499 MS MSD 92248773012 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride mg/L ND 25.3 25.3 24.9 25.0 97 97 90-110 0 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2015 03:07 PM without the written consent of Pace Analytical Services, Inc.. Page 44 of 53 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 1j nl c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050212 Pace Project No.: 92249061 QC Batch: WETA/23132 Analysis Method: SM 4500-CI-E QC Batch Method: SM 4500-CI-E Analysis Description: 4500 Chloride Associated Lab Samples: 92249061003 METHOD BLANK: 1472681 Matrix: Water Associated Lab Samples: 92249061003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/L ND 1.0 06/04/15 06:39 LABORATORY CONTROL SAMPLE: 1472682 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloride mg/L 20 21.0 105 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1472683 1472684 MS MSD 92249061003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride mg/L ND 24.2 24.2 27.1 27.1 109 110 90-110 0 10 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1472685 1472686 MS MSD 92249703005 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride mg/L ND 20 20 23.1 23.3 114 115 90-110 1 10 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2015 03:07 PM without the written consent of Pace Analytical Services, Inc.. Page 45 of 53 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050212 Pace Project No.: 92249061 QC Batch: WETA/46476 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92249061002, 92249061003 METHOD BLANK: 1216279 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/kg ND 49.8 05/16/1517:10 Sulfate mg/kg ND 49.8 05/16/1517:10 LABORATORY CONTROL SAMPLE: 1216280 Parameter Units Chloride mg/kg Sulfate mg/kg MATRIX SPIKE SAMPLE: 1216282 Parameter Units Chloride mg/kg Sulfate mg/kg SAMPLE DUPLICATE: 1216281 Parameter Chloride Sulfate Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 495 482 97 80-120 495 482 97 80-120 92249061002 Spike MS MS % Rec Result Conc. Result % Rec Limits Qualifiers ND 567 534 94 80-120 ND 567 606 90 80-120 92249061002 Dup Units Result Result mg/kg ND ND mg/kg ND ND Max RPD RPD Qualifiers 20 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2015 03:07 PM without the written consent of Pace Analytical Services, Inc.. Page 46 of 53 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050212 Pace Project No.: 92249061 QC Batch: WETA/46475 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92249061002, 92249061003 METHOD BLANK: 1216275 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrate as N mg/kg ND 5.0 05/16/15 17:10 LABORATORY CONTROL SAMPLE: 1216276 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg 49.5 48.8 99 80-120 MATRIX SPIKE SAMPLE: 1216278 92249061002 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg ND 56.7 55.6 98 80-120 H3 SAMPLE DUPLICATE: 1216277 92249061002 Dup Max Parameter Units Result Result RPD RPD Qualifiers Nitrate as N mg/kg ND ND 20 H3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2015 03:07 PM without the written consent of Pace Analytical Services, Inc.. Page 47 of 53 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Ijc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050212 Pace Project No.: 92249061 QC Batch: WETA/28762 Analysis Method: EPA 9060 QC Batch Method: EPA 9060 Analysis Description: 9060 TOC Average Associated Lab Samples: 92249061002, 92249061003 METHOD BLANK: 1167261 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mean Total Organic Carbon mg/kg ND 600 06/02/15 07:26 LABORATORY CONTROL SAMPLE: 1167262 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mean Total Organic Carbon mg/kg 120000 114000 95 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1167263 1167264 MS MSD 92249703006 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg ND 5990 6000 4820 4980 77 79 50-150 3 30 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1167265 1167266 MS MSD 92249703007 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg ND 6030 6010 5110 5550 81 89 50-150 8 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2015 03:07 PM without the written consent of Pace Analytical Services, Inc.. Page 48 of 53 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: J15050212 Pace Project No.: 92249061 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TN -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-G Pace Analytical Services - Green Bay PASI-M Pace Analytical Services - Minneapolis PASI-O Pace Analytical Services - Ormond Beach BATCH QUALIFIERS Batch: ICP/14828 Ill Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. Batch: ICPM/9829 III Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. ANALYTE QUALIFIERS B Analyte was detected in the associated method blank. D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. D6 The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits. H1 Analysis conducted outside the EPA method holding time. H3 Sample was received or analysis requested beyond the recognized method holding time. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2015 03:07 PM without the written consent of Pace Analytical Services, Inc.. Page 49 of 53 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, INC 28078 (704)875-9092 QUALIFIERS Project: J15050212 Pace Project No.: 92249061 ANALYTE QUALIFIERS M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. N2 The lab does not hold TIN accreditation for this parameter. Z2 Analyte present in the associated method blank above the detection limit. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2015 03:07 PM without the written consent of Pace Analytical Services, Inc.. Page 50 of 53 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Ijc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: J15050212 Pace Project No.: 92249061 Lab ID Sample ID QC Batch Method QC Batch Analytical Method 92249061002 2015013900 EPA 3050 MPRP/24249 EPA 6010 92249061003 2015013901 EPA 3050 MPRP/24249 EPA 6010 92249061002 2015013900 EPA 3050 MPRP/24250 EPA 6020 92249061003 2015013901 EPA 3050 MPRP/24250 EPA 6020 92249061001 2015013898 EPA 3020 MPRP/54425 EPA 6020A 92249061004 2015013900 SPLP EPA 3020 MPRP/54657 EPA 6020A 92249061005 2015013901 SPLP EPA 3020 MPRP/54657 EPA 6020A 92249061001 2015013898 EPA 7470A MERP/13557 EPA 7470A 92249061004 2015013900 SPLP EPA 7470A MERP/13677 EPA 7470A 92249061005 2015013901 SPLP EPA 7470A MERP/13677 EPA 7470A 92249061002 2015013900 EPA 7471 MERP/5748 EPA 7471 92249061003 2015013901 EPA 7471 MERP/5748 EPA 7471 92249061002 2015013900 ASTM D2974-87 PMST/3581 92249061003 2015013901 ASTM D2974-87 PMST/3581 92249061002 2015013900 EPA 9045 WET/37491 92249061003 2015013901 EPA 9045 WET/37491 92249061002 2015013900 EPA300.0 WETA/23020 92249061003 2015013901 EPA 300.0 WETA/23020 92249061002 2015013900 EPA 353.2 WETA/23082 92249061003 2015013901 EPA 353.2 WETA/23082 92249061002 2015013900 SM 4500-CI-E WETA/23009 92249061003 2015013901 SM 4500-CI-E WETA/23132 92249061002 2015013900 EPA 9056 WETA/46476 92249061003 2015013901 EPA 9056 WETA/46476 92249061002 2015013900 EPA 9056 WETA/46475 92249061003 2015013901 EPA 9056 WETA/46475 92249061002 2015013900 EPA 9060 WETA/28762 92249061002 2015013900 EPA 9060 WETA/28763 92249061003 2015013901 EPA 9060 WETA/28762 92249061003 2015013901 EPA 9060 WETA/28763 Date: 06/04/2015 03:07 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Analytical Batch ICP/14828 ICP/14828 ICPM/9829 ICPM/9829 ICPM/24315 ICPM/24494 ICPM/24494 MERC/15737 MERC/15927 MERC/15927 MERC/5735 MERC/5735 Page 51 of 53 „t. aceAnalytica/” Client Name: V VI uocument Name: uocumenE mevisea: oepternuel - LU 1-F Sample, Condition td on Recei t SCUR Pa e 1 of 2 Document Number: Issuing Authoritp of so F-CHR-CS-003-rev.15 Pace Huntersvilie Quality Office Courier: [] Fed Ex ❑ UPS[] USPS❑ Client❑ Commercial❑ Pace Other Custody Seal on Cooler/Box Present: ❑ yes ❑ no Seals intact: ❑ yes Q no Packing Material: ❑ Bubble VDp Bubble Bags [] None ❑ Other Thermometer Used: IR Gun 1 01 Type of Ice: `Wet Blue None L Samples on ice, cooling process has begun Temp Correction Factor T1401 No Correction Corrected Cooler Temp.; °C Temp should be above freezing to 6°C Biological =Dateandals_o person e: amintng g' Tissue is Frozen: Yes No NIA'-r Comments: Chain of Custody Present: }Yes ❑No ❑NIA 1. ' Chain of Custody Filled Out: ElYes ❑No ONIA 2. Chain of Custody Relinquished: E(Yes ❑No ❑NIA 3. Sampler Name & Signature on COC: QYes [IN, ❑NIA 4. Samples Arrived within Hold Time: DYes ❑No ❑NIA 5. Short Hold Time Analysis (<72hr): Dyes PNo ❑NIA 6. Rush Turn Around Time Requested: ❑Yes Ulho ❑NIA 7. Sufficient Volume: PYes ❑No DNIA $, Correct Containers Used: -Pace Containers Used: DYes ❑No DYes C]No ©NIA ❑NIA 9. Containers Intact: Oyes ❑No ❑NIA 10. Filtered volume received for Dissolved tests ©Yes ❑No QhIA 11. Sample Labels match COC: -Includes dateltime11D1Analysis Matrix: OYea []No ❑NIA 12, All containers needing preservation have been checked. All containers needing preservation are found to be in compliance with EPA recommendation. exceptions: VOA, coliform, TOC, O&G, WN-DRO (water) ❑Yes ❑No Dyes ONO ❑Yes 0 No PIVIA R/N/A 13. Samples checked for dechlorination: []Yes ❑No 0N/A 14. Headspace in VOA Vials (>6mm): ❑Yes ❑rso 1111NrA 15. Trip Blank Present: Trip Blank Custody Seals Present Pace Trip Blank Lot # (if purchased): ❑Yes ❑No ❑Yes CJNo LIMA NIA 16. Client Notification/ Resolution: Field Data Required? Y N Person Contacted: Dateil'ime: Comments/ Resolution: SCURF Review: �� Date:�/!', tr�H(S— Note: SRF R@view: Date: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office ( Le out of hold, incorrect preservative, out of temp, incorrect containers) WO#:92249061 1111111111111111111111 92249061 Page 52 of 53 sjaweluDo Jo 9 Jplolw _ z I I 8 O<uO J �Z 41 C a or) ` �Zr 0 • !l i I w � 0 m - I z I N a .aj I 5 (7bOliA"IdN'd I I I I Ssaoov) I " ; p per zo a - Z easel I i g S alll!oeds;uewlpeg - — — — — — — — — — — I � c I P S ICY (3OVd) SAO za g- Z N 01 c suoluv pue I lYl ! a Sjel,sw leloi d'}dS LA, I e a �.r. 10 0 ; .�� N .e'er zo y - OOi I I t- �y .(ram. AC j (Bovd) per zo g - I, IJ U u} I ed [q ! •� O a `Suo!ua ` SIS3eW leloi IN aa! 69a_ i {I ax_c 0 j� Tc ` SGAlIYr— C u dwopu c m <I \ m� C L Q JII O E p _ -Ij Jr Op O H 1 ` a N LLJ kA ._.._...._.._. • o 0 LLiu i o r`/�I ! ! I E 0 . VI � I � \�\ o- � ' LL C7 4 1 O ®� V r7,t nl R u- f ' a � � •� (�/ 1 I t 1 I n 3 IL 0 I A n "•{ v -. I @ n cr`�ml tar �I��I,,IrQ Pd� l u CrtS E Ia4� I .� n 7 LLl fair 13--I ° F a. O U 6r a r fn VY "'S 4'] Z3 L) / e e� co m z Y 1 C a I i I vi e d o W If FI I I ! ! I I a c� I 4 nD aIRkLU U-1 Q r' ILIbu of ellwnll�'udddd oie alalwoz. of jowop 3 ..._. �. T. c 3 rc , a I I I E I 1 � w1 N b i .1.. `.l. _. _.. 1. •. J.. ��._.I_..1-. _.1.�. �..�.. •... 1. _. �•.1.._ ._-L _.. Q (n �' eia;6wo�lcnw s0wwolcn� `.. _.. _.• � �.... ^� ,� Page 53 CHAIN OF CUSTODY RECORD AND ANALYSIS R_EQUE_ST F+[�RM �^ Arlalytirad Laboratory Servicon i M ' " ` " _ ._.�_�._._._._._._._.. _ I L8' borate hire Only Yr � rM�uc Fey +aewl F E f� r wit: SOIL 'I� i„/ Y. df rWul6cnisl■Y! M. C. 2d67B I liwwd,7 laaw� iaA P18Tb�si6 y Njos ¢ �I I PTp�t NNW �IPha+�iiv rJa �- - �}! �arher,— AB Groundwater Assessment • SnA PACE ccew-1' 3]Gll�dt 41Fa, Na. f.. P4 11.42081 A8 CW I-11y50a SVnterre EDD Y Mc sa i DISTRIplJMN C3 _ —a ORIGINAL Ira LAB, Y Ci7PY it) (.-I I . N'1 i _ NP�ESi Plan) — p HfV41AIF )�1LV�flllti LO djl!1W}Myb lkAtl: EI!'ilb: flPin,l a:ipyv I elexj, ,MMMS urwr - — aW wlei f]' Ir11P.a..o la _ -. - SrJ itlll t fi R�Irooi4�e. 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