NC0038377_J15050018 Report_20150902

+ DUKE Analytical Laboratory 1 of36
ENERGY
Order Number:
Project Name:
Customer Name(s):
Customer Address:
Lab Contact:
Report Authorized By:
(Signature)
Program Comments:
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone:[phone] Fax:[phone]
Order Summary Report
J15050018
MAYO STEAM - AB GW ASSESSMENT SOIL
Tim Hunsucker, Jerry Wylie, Kathy Webb, John Toepfer
Margaret Galvin -Karr
MXG4644(101161)
u G42k',G_Y�- 015.06.01 10:19:16
04'00'
Margaret Galvin -Karr
Phone: [phone]
Date:
Please contact the Program Manager (Margaret Galvin -Karr) with any questions regarding this report.
Data Flags & Calculations:
5/28/2015
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Sample ID's & Descriptions:
2 of 36
Collection
Sample ID Plant/Station Date and Time Collected By
2015012958 MAYO STEAM 28-Apr-15 1:00 PM illegible
1 Total Samples
Sample Description
MW-12D(88.5-90.0)

3 of 36
Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals Yes No
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits. ❑ Yes❑ No
All laboratory QA/QC requirements are acceptable.❑ Yes ❑ No
Report Sections Included:
U Job Summary Report
❑ Sample Identification
n Technical Validation of Data Package
❑ Analytical Laboratory Certificate of Analysis
❑ Analytical Laboratory QC Report
Reviewed By: Date:
Sub -contracted Laboratory Results
❑ Customer Specific Data Sheets, Reports, & Documentation
❑ Customer Database Entries
0 Chain of Custody
[I/0] Electronic Data Deliverable (EDD) Sent Separately

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15050018
Site: MW-12D(88.5-90.0)
Collection Date: 28-Apr-15 1:00 PM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
4 of 36
Sample #: 2015012958
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kigc&ykie. Suite 100
Huntersville, INC 28078
[phone]
May 27, 2015
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg.7405 MG30A2
Huntersville, NC 28078
RE: Project: J 15050018
Pace Project No.: 92247909
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on May 01, 2015. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TN standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc: Marge Galvin -Karr, Duke Energy
Program Manager, Duke Energy
Rodney Wilke, Duke Energy
p«FO
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
lqe� ��� without the written consent of Pace Analytical Services, Inc..
BRAT,
Page 1 of 30

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kigc&ykie. Suite 100
Huntersville, NC 28078
[phone]
Project: J15050018
Pace Project No.: 92247909
Ormond Beach Certification IDs
8 East Tower Circle, Ormond Beach, FL 32174
Alabama Certification #: 41320
Connecticut Certification M PH-0216
Delaware Certification: FL NELAC Reciprocity
Florida Certification #: E83079
Georgia Certification #: 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification #: 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383
Kentucky Certification #: 90050
Louisiana Certification #: FL NELAC Reciprocity
Louisiana Environmental Certificate M 05007
Maryland Certification: #346
Massachusetts Certification #: M-FL1264
Michigan Certification #: 9911
Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236
Green Bay Certification IDs
1241 Bellevue Street, Green Bay, WI 54302
Florida/NELAP Certification #: E87948
Illinois Certification #: 200050
Kentucky Certification #: 82
Louisiana Certification #: 04168
Minnesota Certification #: 055-999-334
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification M E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
CERTIFICATIONS
Montana Certification #: Cert 0074
Nebraska Certification: NE-OS-28-14
Nevada Certification: FL NELAC Reciprocity
New Hampshire Certification #: 2958
New Jersey Certification #: FL765
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
Pennsylvania Certification #: 68-00547
Puerto Rico Certification M FLO1264
South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
Washington Certification #: C955
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
North Dakota Certification #: R-150
South Carolina Certification #: 83006001
Texas Certification #: T104704529-14-1
US Dept of Agriculture #: S-76505
Wisconsin Certification #: 405132750
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
West Virginia Certification M 356
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 2 of 30

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kic&fie. Suite 100
Huntersville, NC 28078
[phone]
Project: J15050018
Pace Project No.: 92247909
Lab ID Sample ID
SAMPLE SUMMARY
Matrix Date Collected Date Received
92247909001 2015012958 Solid 04/28/1513:00 05/01/1512:57
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 3 of 30

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kigg8yke. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
J15050018
92247909
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92247909001
2015012958
EPA 6010
TAP
16
PASI-0
EPA 6020
DRS
8
PASI-O
EPA 7471
CKJ
1
PASI-O
ASTM D2974-87
MLO
1
PASI-O
EPA 9045
MLS
1
PASI-A
EPA 9056
KHC
2
PASI-O
EPA 9056
KHC
1
PASI-O
EPA 9060
TJJ
6
PASI-G
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 4 of 30

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kigc&ykie. Suite 100
Huntersville, NC 28078
[phone]
Project: J15050018
Pace Project No.: 92247909
Lab Sample ID
Method
Client Sample ID
Parameters
92247909001
2015012958
EPA 6010
Aluminum
EPA 6010
Barium
EPA 6010
Beryllium
EPA 6010
Calcium
EPA 6010
Chromium
EPA 6010
Copper
EPA 6010
Iron
EPA 6010
Magnesium
EPA 6010
Manganese
EPA 6010
Molybdenum
EPA 6010
Nickel
EPA 6010
Potassium
EPA 6010
Strontium
EPA 6010
Zinc
EPA 6020
Cadmium
EPA 6020
Cobalt
EPA 6020
Lead
EPA 6020
Vanadium
ASTM D2974-87
Percent Moisture
EPA 9045
pH at 25 Degrees C
EPA 9060
Total Organic Carbon
EPA 9060
Total Organic Carbon
EPA 9060
Total Organic Carbon
EPA 9060
Mean Total Organic Carbon
EPA 9060
RSD%
SUMMARY OF DETECTION
Result
Units
Report Limit
Analyzed Qualifiers
17400
mg/kg
28.1
05/10/1517:46
179
mg/kg
2.8
05/10/1517:46
1.5
mg/kg
0.28
05/10/1517:46
2870
mg/kg
140
05/10/1517:46
141
mg/kg
1.4
05/10/1517:46
11.2
mg/kg
1.4
05/10/1517:46
31500
mg/kg
11.2
05/10/1517:46
15200
mg/kg
140
05/10/1517:46
2820
mg/kg
2.8
05/11/1512:51 D4
3.3
mg/kg
2.8
05/10/1517:46
75.3
mg/kg
1.4
05/10/1517:46
7650
mg/kg
281
05/10/1517:46
24.4
mg/kg
2.8
05/10/1517:46
195
mg/kg
5.6
05/10/1517:46
0.49J
mg/kg
0.67
05/13/1511:54
19.9
mg/kg
5.6
05/13/1511:54
8.0
mg/kg
5.6
05/13/1511:54
50.1
mg/kg
5.6
05/13/1511:54
11.6
%
0.10
05/11/1510:33
7.3
Std. Units
0.10
05/06/15 13:00
377J
mg/kg
677
05/26/1513:05
383J
mg/kg
685
05/26/1513:17
346J
mg/kg
672
05/26/1513:22
356J
mg/kg
679
05/26/1513:05
8.3
%
05/26/1513:05
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 5 of 30

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 f i6'8yke. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15050018
Pace Project No.: 92247909
Method: EPA 6010
Description: 6010 MET ICP
Client: Duke Energy
Date: May 27, 2015
General Information:
1 sample was analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 3050 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: MPRP/24040
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92247834001
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1208607)
• Aluminum
• Iron
• MSD (Lab ID: 1208608)
• Aluminum
• Iron
• Manganese
Additional Comments:
Batch Comments:
Samples in this batch were diluted due to the presence of high levels of non -target analytes or other matrix interference.
• QC Batch: ICP / 14693
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 6 of 30

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 f inlc&yke. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15050018
Pace Project No.: 92247909
Method: EPA 6010
Description: 6010 MET ICP
Client: Duke Energy
Date: May 27, 2015
Analyte Comments:
QC Batch: MPRP/24040
D4: Sample was diluted due to the presence of high levels of target analytes.
•2015012958 (Lab ID:92247909001)
• Manganese
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 7 of 30

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 f iQ'8yke. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15050018
Pace Project No.: 92247909
Method: EPA 6020
Description: 6020 MET ICPMS
Client: Duke Energy
Date: May 27, 2015
General Information:
1 sample was analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 3050 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: MPRP/24041
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92247834001
M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
• MS (Lab ID: 1208613)
• Antimony
• Cadmium
• Cobalt
• Vanadium
• MSD (Lab ID: 1208614)
• Antimony
• Cobalt
• Lead
• Selenium
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 8 of 30

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 f ig'8yke. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15050018
Pace Project No.: 92247909
Method: EPA 6020
Description: 6020 MET ICPMS
Client: Duke Energy
Date: May 27, 2015
Batch Comments:
Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
• QC Batch: ICPM / 9756
Analyte Comments:
QC Batch: MPRP/24041
N2: The lab does not hold TNI accreditation for this parameter.
•2015012958 (Lab ID:92247909001)
• Antimony
• BLANK (Lab ID: 1208611)
• Antimony
• LCS (Lab ID: 1208612)
• Antimony
• MS (Lab ID: 1208613)
• Antimony
• MSD (Lab ID: 1208614)
• Antimony
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 9 of 30

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 ffli '8yke. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15050018
Pace Project No.: 92247909
Method: EPA 7471
Description: 7471 Mercury
Client: Duke Energy
Date: May 27, 2015
General Information:
1 sample was analyzed for EPA 7471. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 7471 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 10 of 30

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 f ig'8yke. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15050018
Pace Project No.: 92247909
Method: EPA 9045
Description: 9045 pH Soil
Client: Duke Energy
Date: May 27, 2015
General Information:
1 sample was analyzed for EPA 9045. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
QC Batch: WET/37238
D& The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits.
• DUP (Lab ID: 1450002)
• pH at 25 Degrees C
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 11 of 30

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 ffli '8yke. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15050018
Pace Project No.: 92247909
Method: EPA 9056
Description: 9056 IC Anions
Client: Duke Energy
Date: May 27, 2015
General Information:
1 sample was analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
Analyte Comments:
QC Batch: WETA/46118
DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
•2015012958 (Lab ID:92247909001)
• Chloride
• Sulfate
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 12 of 30

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 fflic&)e. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15050018
Pace Project No.: 92247909
Method: EPA 9056
Description: 9056 IC Anions 48hr
Client: Duke Energy
Date: May 27, 2015
General Information:
1 sample was analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
1-13: Sample was received or analysis requested beyond the recognized method holding time.
•2015012958 (Lab ID:92247909001)
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 13 of 30

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 ffli '8yke. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15050018
Pace Project No.: 92247909
Method: EPA 9060
Description: Total Organic Carbon Quad
Client: Duke Energy
Date: May 27, 2015
General Information:
1 sample was analyzed for EPA 9060. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 14 of 30

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 ffli ,8yke. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15050018
Pace Project No.: 92247909
Sample: 2015012958
Lab ID:
92247909001 Collected:
04/28/15 13:00
Received: 05/01/15 12:57 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample
size and any dilutions.
Report
Parameters
Results
Units Limit
MDL
DF
Prepared
Analyzed
CAS No.
Qual
6010 MET ICP
Analytical
Method: EPA 6010
Preparation
Method: EPA
3050
Aluminum
17400
mg/kg
28.1
14.0
5
05/09/15 09:34
05/10/15 17:46
7429-90-5
Barium
179
mg/kg
2.8
1.4
5
05/09/15 09:34
05/10/15 17:46
7440-39-3
Beryllium
1.5
mg/kg
0.28
0.14
5
05/09/15 09:34
05/10/15 17:46
7440-41-7
Boron
ND
mg/kg
14.0
7.0
5
05/09/15 09:34
05/10/15 17:46
7440-42-8
Calcium
2870
mg/kg
140
70.2
5
05/09/15 09:34
05/10/15 17:46
7440-70-2
Chromium
141
mg/kg
1.4
0.70
5
05/09/15 09:34
05/10/15 17:46
7440-47-3
Copper
11.2
mg/kg
1.4
0.70
5
05/09/15 09:34
05/10/15 17:46
7440-50-8
Iron
31500
mg/kg
11.2
5.6
5
05/09/15 09:34
05/10/15 17:46
7439-89-6
Magnesium
15200
mg/kg
140
70.2
5
05/09/15 09:34
05/10/15 17:46
7439-95-4
Manganese
2820
mg/kg
2.8
1.4
10
05/09/15 09:34
05/11/15 12:51
7439-96-5
D4
Molybdenum
3.3
mg/kg
2.8
1.4
5
05/09/15 09:34
05/10/15 17:46
7439-98-7
Nickel
75.3
mg/kg
1.4
0.70
5
05/09/15 09:34
05/10/15 17:46
7440-02-0
Potassium
7650
mg/kg
281
140
5
05/09/15 09:34
05/10/15 17:46
7440-09-7
Sodium
ND
mg/kg
281
140
5
05/09/15 09:34
05/10/15 17:46
7440-23-5
Strontium
24.4
mg/kg
2.8
1.4
5
05/09/15 09:34
05/10/15 17:46
7440-24-6
Zinc
195
mg/kg
5.6
2.8
5
05/09/15 09:34
05/10/15 17:46
7440-66-6
6020 MET ICPMS
Analytical
Method: EPA 6020
Preparation
Method: EPA
3050
Antimony
ND
mg/kg
5.6
2.8
100
05/09/15 09:34
05/13/15 11:54
7440-36-0
N2
Arsenic
ND
mg/kg
5.6
2.8
100
05/09/15 09:34
05/13/15 11:54
7440-38-2
Cadmium
0.49J
mg/kg
0.67
0.34
100
05/09/15 09:34
05/13/15 11:54
7440-43-9
Cobalt
19.9
mg/kg
5.6
2.8
100
05/09/15 09:34
05/13/15 11:54
7440-48-4
Lead
8.0
mg/kg
5.6
2.8
100
05/09/15 09:34
05/13/15 11:54
7439-92-1
Selenium
ND
mg/kg
5.6
2.8
100
05/09/15 09:34
05/13/15 11:54
7782-49-2
Thallium
ND
mg/kg
5.6
2.8
100
05/09/15 09:34
05/13/15 11:54
7440-28-0
Vanadium
50.1
mg/kg
5.6
2.8
100
05/09/15 09:34
05/13/15 11:54
7440-62-2
7471 Mercury
Analytical
Method: EPA 7471
Preparation
Method: EPA
7471
Mercury
ND
mg/kg 0.0092
0.0046
1
05/09/15 09:41
05/09/15 18:03
7439-97-6
Percent Moisture
Analytical
Method: ASTM D2974-87
Percent Moisture
11.6
%
0.10
0.10
1
05/11/15 10:33
9045 pH Soil
Analytical
Method: EPA 9045
pH at 25 Degrees C
7.3
Std. Units
0.10
0.10
1
05/06/15 13:00
9056 IC Anions
Analytical
Method: EPA 9056
Chloride
ND
mg/kg
278
139
5
05/06/1511:27
16887-00-6
D3
Sulfate
ND
mg/kg
278
139
5
05/06/1511:27
14808-79-8
D3
9056 IC Anions 48hr
Analytical
Method: EPA 9056
Nitrate as N
ND
mg/kg
27.8
13.9
5
05/06/15 11:27
14797-55-8
H3
Date: 05/27/2015 02:42 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 15 of 30

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 KPi ,8ykie. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15050018
Pace Project No.: 92247909
Sample: 2015012958
Lab ID:
92247909001
Collected:
04/28/15 13:00
Received: 05/01/15 12:57 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample
size and any dilutions.
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared Analyzed
CAS No. Qual
Total Organic Carbon Quad
Analytical
Method: EPA 9060
Total Organic Carbon
377J
mg/kg
677
338
1
05/26/15 13:05
7440-44-0
Total Organic Carbon
ND
mg/kg
682
341
1
05/26/15 13:10
7440-44-0
Total Organic Carbon
383J
mg/kg
685
343
1
05/26/15 13:17
7440-44-0
Total Organic Carbon
346J
mg/kg
672
336
1
05/26/15 13:22
7440-44-0
Mean Total Organic Carbon
356J
mg/kg
679
339
1
05/26/15 13:05
7440-44-0
Surrogates
RSD%
8.3
%
1
05/26/15 13:05
Date: 05/27/2015 02:42 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 16 of 30

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 tf�T igykie. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15050018
Pace Project No.: 92247909
QC Batch: MERP/5697
Analysis Method: EPA 7471
QC Batch Method: EPA 7471
Analysis Description: 7471 Mercury
Associated Lab Samples: 92247909001
METHOD BLANK: 1208617
Matrix: Solid
Associated Lab Samples: 92247909001
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Mercury mg/kg
ND 0.0082
05/09/1517:09
LABORATORY CONTROL SAMPLE: 1208618
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Mercury mg/kg
.083 0.083
100 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1208619 1208620
MS MSD
92247834001
Spike Spike MS
MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec Limits RPD RPD Qual
Mercury mg/kg 0.018
.079 .077 0.098
0.097 101 102 80-120 2 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/27/2015 02:42 PM without the written consent of Pace Analytical Services, Inc..
Page 17 of 30

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 KQ igyk.. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15050018
Pace Project No.: 92247909
QC Batch: MPRP/24040 Analysis Method: EPA 6010
QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid
Associated Lab Samples: 92247909001
METHOD BLANK: 1208605
Associated Lab Samples: 92247909001
Parameter
Units
Aluminum
mg/kg
Barium
mg/kg
Beryllium
mg/kg
Boron
mg/kg
Calcium
mg/kg
Chromium
mg/kg
Copper
mg/kg
Iron
mg/kg
Magnesium
mg/kg
Manganese
mg/kg
Molybdenum
mg/kg
Nickel
mg/kg
Potassium
mg/kg
Sodium
mg/kg
Strontium
mg/kg
Zinc
mg/kg
Matrix: Solid
Blank
Result
Reporting
Limit
Analyzed
ND
5.1
05/10/1515:56
ND
0.51
05/10/1515:56
ND
0.051
05/10/1515:56
ND
2.6
05/10/1515:56
ND
25.6
05/10/1515:56
ND
0.26
05/10/1515:56
ND
0.26
05/10/1515:56
ND
2.0
05/10/1515:56
ND
25.6
05/10/1515:56
ND
0.26
05/10/1515:56
ND
0.51
05/10/1515:56
ND
0.26
05/10/1515:56
ND
51.1
05/10/1515:56
ND
51.1
05/10/1515:56
ND
0.51
05/10/1515:56
ND
1.0
05/10/1515:56
Qualifiers
LABORATORY CONTROL SAMPLE:
Parameter
1208606
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
Aluminum
mg/kg
130
139
107
80-120
Barium
mg/kg
13
13.9
106
80-120
Beryllium
mg/kg
1.3
1.4
105
80-120
Boron
mg/kg
130
133
102
80-120
Calcium
mg/kg
651
699
107
80-120
Chromium
mg/kg
13
13.1
101
80-120
Copper
mg/kg
13
13.0
100
80-120
Iron
mg/kg
130
138
106
80-120
Magnesium
mg/kg
651
682
105
80-120
Manganese
mg/kg
13
13.5
103
80-120
Molybdenum
mg/kg
13
13.3
102
80-120
Nickel
mg/kg
13
13.7
105
80-120
Potassium
mg/kg
651
675
104
80-120
Sodium
mg/kg
651
708
109
80-120
Strontium
mg/kg
13
13.7
105
80-120
Zinc
mg/kg
65.1
68.9
106
80-120
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/27/2015 02:42 PM without the written consent of Pace Analytical Services, Inc..
Page 18 of 30

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 KS igyk.. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15050018
Pace Project No.: 92247909
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
1208607
1208608
MS
MSD
92247834001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Aluminum
mg/kg
2530
119
130
3690
4030
969
1150
75-125
9
20 M1
Barium
mg/kg
27.2
11.9
13
40.6
42.9
112
120
75-125
5
20
Beryllium
mg/kg
0.181
1.2
1.3
1.4
1.4
99
92
75-125
1
20
Boron
mg/kg
ND
119
130
110
109
90
83
75-125
0
20
Calcium
mg/kg
470
595
649
1100
1140
106
104
75-125
4
20
Chromium
mg/kg
4.3
11.9
13
16.2
16.5
100
94
75-125
2
20
Copper
mg/kg
3.4
11.9
13
15.0
15.5
98
93
75-125
3
20
Iron
mg/kg
4750
119
130
4950
5440
161
527
75-125
9
20 M1
Magnesium
mg/kg
349
595
649
975
1010
105
101
75-125
3
20
Manganese
mg/kg
180
11.9
13
195
206
122
195
75-125
5
20 M1
Molybdenum
mg/kg
ND
11.9
13
10.9
11.0
88
81
75-125
1
20
Nickel
mg/kg
1.7
11.9
13
13.8
14.0
102
95
75-125
2
20
Potassium
mg/kg
135J
595
649
706
717
96
90
75-125
2
20
Sodium
mg/kg
ND
595
649
644
672
99
95
75-125
4
20
Strontium
mg/kg
4.2
11.9
13
16.4
16.9
102
97
75-125
3
20
Zinc
mg/kg
22.0
59.5
64.9
87.1
87.0
109
100
75-125
0
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/27/2015 02:42 PM without the written consent of Pace Analytical Services, Inc..
Page 19 of 30

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 K4,8yk.. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15050018
Pace Project No.: 92247909
QC Batch: MPRP/24041 Analysis Method: EPA 6020
QC Batch Method: EPA 3050 Analysis Description: 6020 MET SOLID
Associated Lab Samples: 92247909001
METHOD BLANK: 1208611
Matrix:
Solid
Associated Lab Samples: 92247909001
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Antimony
mg/kg
ND
0.053
05/11/1512:09 N2
Arsenic
mg/kg
ND
0.053
05/11/1512:09
Cadmium
mg/kg
ND
0.0063
05/11/1512:09
Cobalt
mg/kg
ND
0.053
05/11/1512:09
Lead
mg/kg
ND
0.053
05/11/1512:09
Selenium
mg/kg
ND
0.053
05/11/1512:09
Thallium
mg/kg
ND
0.053
05/11/1512:09
Vanadium
mg/kg
ND
0.053
05/12/1517:01 CU
LABORATORY CONTROL SAMPLE: 1208612
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits
Qualifiers
Antimony
mg/kg
2.6
2.7
101
80-120
N2
Arsenic
mg/kg
2.6
2.7
102
80-120
Cadmium
mg/kg
.26
0.27
101
80-120
Cobalt
mg/kg
2.6
2.7
104
80-120
Lead
mg/kg
2.6
2.7
104
80-120
Selenium
mg/kg
2.6
2.7
101
80-120
Thallium
mg/kg
2.6
2.7
104
80-120
Vanadium
mg/kg
2.6
2.6
100
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1208613
1208614
MS
MSD
92247834001
Spike
Spike
MS
MSD
MS MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec % Rec
Limits
RPD RPD Qual
Antimony
mg/kg
ND
2.6
2.6
ND
ND
60
61
75-125
20 M6, N2
Arsenic
mg/kg
ND
2.6
2.6
3.5J
3.3J
88
87
75-125
20
Cadmium
mg/kg
ND
.26
.26
ND
ND
60
83
75-125
20 M6
Cobalt
mg/kg
3.3J
2.6
2.6
6.7
6.6
130
129
75-125
2 20 M6
Lead
mg/kg
3.6J
2.6
2.6
6.9
6.9
125
128
75-125
1 20 M6
Selenium
mg/kg
ND
2.6
2.6
3.2J
ND
92
55
75-125
20 M6
Thallium
mg/kg
ND
2.6
2.6
ND
ND
91
93
75-125
20
Vanadium
mg/kg
8.5
2.6
2.6
12.1
11.5
136
119
75-125
5 20 M6
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/27/2015 02:42 PM without the written consent of Pace Analytical Services, Inc..
Page 20 of 30

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 KP�c&fie. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15050018
Pace Project No.: 92247909
QC Batch: PMST/3544
Analysis Method:
ASTM
D2974-87
QC Batch Method: ASTM D2974-87
Analysis Description:
Dry Weight/Percent Moisture
Associated Lab Samples: 92247909001
SAMPLE DUPLICATE: 1209474
35185070001
Dup
Max
Parameter
Units
Result
Result
RPD
RPD
Qualifiers
Percent Moisture
%
99.5
99.2
0
10
SAMPLE DUPLICATE: 1209476
92247911001
Dup
Max
Parameter
Units
Result
Result
RPD
RPD
Qualifiers
Percent Moisture
%
25.9
26.6
2
10
SAMPLE DUPLICATE: 1209477
92247911010
Dup
Max
Parameter
Units
Result
Result
RPD
RPD
Qualifiers
Percent Moisture
%
28.8
29.0
1
10
SAMPLE DUPLICATE: 1209478
35186853004
Dup
Max
Parameter
Units
Result
Result
RPD
RPD
Qualifiers
Percent Moisture
%
18.1
19.0
5
10
SAMPLE DUPLICATE: 1209479
35187478002
Dup
Max
Parameter
Units
Result
Result
RPD
RPD
Qualifiers
Percent Moisture
%
8.1
8.5
5
10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/27/2015 02:42 PM without the written consent of Pace Analytical Services, Inc.. Page 21 of 30

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 K��c&fie. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15050018
Pace Project No.: 92247909
QC Batch: WET/37238 Analysis Method: EPA 9045
QC Batch Method: EPA 9045 Analysis Description: 9045 pH
Associated Lab Samples: 92247909001
SAMPLE DUPLICATE: 1450001
Parameter
pH at 25 Degrees C
SAMPLE DUPLICATE: 1450002
Parameter
pH at 25 Degrees C
92248135013 Dup Max
Units Result Result RPD RPD Qualifiers
Std. Units 7.1 7.2 0 10
92247913005 Dup Max
Units Result Result RPD RPD Qualifiers
Std. Units 5.0 5.0 2 10 D6
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/27/2015 02:42 PM without the written consent of Pace Analytical Services, Inc.. Page 22 of 30

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 K�c&fie. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15050018
Pace Project No.: 92247909
QC Batch: WETA/46118 Analysis Method: EPA 9056
QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions
Associated Lab Samples: 92247909001
METHOD BLANK: 1204695 Matrix: Solid
Associated Lab Samples:
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Chloride mg/kg ND 50.0 05/06/1510:44
Sulfate mg/kg ND 50.0 05/06/1510:44
LABORATORY CONTROL SAMPLE:
1204696
Parameter
Units
Chloride
mg/kg
Sulfate
mg/kg
MATRIX SPIKE SAMPLE:
1204698
Parameter
Units
Chloride
mg/kg
Sulfate
mg/kg
SAMPLE DUPLICATE: 1204697
Parameter
Chloride
Sulfate
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
491 453 92 80-120
491 450 92 80-120
92247909001 Spike MS MS % Rec
Result Conc. Result % Rec Limits Qualifiers
ND 561 492 88 80-120
ND 561 513 92 80-120
92247909001 Dup
Units Result Result
mg/kg ND ND
mg/kg ND ND
Max
RPD RPD Qualifiers
20 D3
20 D3
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/27/2015 02:42 PM without the written consent of Pace Analytical Services, Inc.. Page 23 of 30

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 KPgc&fie. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15050018
Pace Project No.: 92247909
QC Batch: WETA/46117
Analysis Method:
EPA 9056
QC Batch Method: EPA 9056
Analysis Description:
9056 IC Anions
Associated Lab Samples: 92247909001
METHOD BLANK: 1204691
Matrix: Solid
Associated Lab Samples:
Blank Reporting
Parameter
Units
Result Limit
Analyzed
Qualifiers
Nitrate as N
mg/kg
ND 5.0
05/06/15 10:44
LABORATORY CONTROL SAMPLE:
1204692
Spike LCS
LCS
% Rec
Parameter
Units
Conc. Result
% Rec
Limits
Qualifiers
Nitrate as N
mg/kg
49.1 46.2
94
80-120
MATRIX SPIKE SAMPLE:
1204694
92247909001 Spike
MS
MS
% Rec
Parameter
Units
Result Conc.
Result
% Rec
Limits Qualifiers
Nitrate as N
mg/kg
ND 56.1
49.9
89 80-120 H3
SAMPLE DUPLICATE: 1204693
92247909001 Dup
Max
Parameter
Units
Result Result
RPD
RPD
Qualifiers
Nitrate as N
mg/kg
ND ND
20 H3
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/27/2015 02:42 PM without the written consent of Pace Analytical Services, Inc.. Page 24 of 30

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 K��c&fie. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15050018
Pace Project No.: 92247909
QC Batch: WETA/28613
Analysis Method: EPA 9060
QC Batch Method: EPA 9060
Analysis Description: 9060 TOC Average
Associated Lab Samples: 92247909001
METHOD BLANK: 1161513
Matrix: Solid
Associated Lab Samples:
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Mean Total Organic Carbon mg/kg
ND 600
05/26/15 08:34
LABORATORY CONTROL SAMPLE: 1161514
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Mean Total Organic Carbon mg/kg
120000 130000
108 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1161515 1161516
MS MSD
92247835016
Spike Spike MS
MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec Limits RPD RPD Qual
Mean Total Organic Carbon mg/kg 2750
7410 7410 10300
10900 101 110 50-150 6 30
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1161527 1161528
MS MSD
92248424001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Mean Total Organic Carbon mg/kg 50700 60900 60900 113000 106000 102 91 50-150 6 30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/27/2015 02:42 PM without the written consent of Pace Analytical Services, Inc..
Page 25 of 30

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 %'8yke. Suite 100
Huntersville, NC 28078
[phone]
QUALIFIERS
Project: J15050018
Pace Project No.: 92247909
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
LABORATORIES
PASI-A Pace Analytical Services - Asheville
PASI-G Pace Analytical Services - Green Bay
PASI-O Pace Analytical Services - Ormond Beach
BATCH QUALIFIERS
Batch: ICP/14693
Ill Samples in this batch were diluted due to the presence of high levels of non -target analytes or other matrix interference.
Batch: ICPM/9756
Ill Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
ANALYTE QUALIFIERS
CU The continuing calibration for this compound is outside of Pace Analytical acceptance limits. Analyte presence below
reporting limits in associated samples. Results unaffected by high bias.
D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
D4 Sample was diluted due to the presence of high levels of target analytes.
D6 The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits.
H3 Sample was received or analysis requested beyond the recognized method holding time.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/27/2015 02:42 PM without the written consent of Pace Analytical Services, Inc.. Page 26 of 30

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 �nlc&yke. Suite 100
Huntersville, INC 28078
[phone]
QUALIFIERS
Project: J15050018
Pace Project No.: 92247909
ANALYTE QUALIFIERS
N2 The lab does not hold TIN accreditation for this parameter.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/27/2015 02:42 PM without the written consent of Pace Analytical Services, Inc.. Page 27 of 30

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 t 2'8yk.. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: J15050018
Pace Project No.: 92247909
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
92247909001
2015012958
EPA 3050
MPRP/24040
EPA 6010
92247909001
2015012958
EPA 3050
MPRP/24041
EPA 6020
92247909001
2015012958
EPA 7471
MERP/5697
EPA 7471
92247909001
2015012958
ASTM D2974-87
PMST/3544
92247909001
2015012958
EPA 9045
WET/37238
92247909001
2015012958
EPA 9056
WETA/46118
92247909001
2015012958
EPA 9056
WETA/46117
92247909001
2015012958
EPA 9060
WETA/28613
92247909001
2015012958
EPA 9060
WETA/28614
Date: 05/27/2015 02:42 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Analytical
Batch
ICP/14693
ICPM/9756
MERC/5684
Page 28 of 30

(Siouleluoo loomooul
SOSO z6
'dLual;o lno 'adder JosaJd loaJJooul 'pioq;o lno a•l) aolj© ucwv.jA?�D
21NHB0 ewloJe0 glJON aql of lugs eq IIIM wlo} slgl jo Ildoo a 'soldLues
ll 4 I I
gousildwoo eulloJe0 quoN 6ulloap AouedaJoslp a sl aJagl IOAauagM :aloN
// onm
606LVZZ6 1
_cc•+j1��
:sled
:glad
AA
:nnainalrl dUS
:MOIAO-d juno5
:uoilnlos98 /sluawwo0
:awl jjaleo :p913elu00 U09Jad
N 1 A 4pannb98 eleCI plolj :uoi;nlosaa /ual;eall ON W0110
'96
V/r q
tllN9
ONE]
ONE]
GOAD
SaA❑
:(pesegoJnd;i) # lol Nuels dial. aced
luasaJd sleaS dpolsno Jluelq duj.
:luasaJd Nuelq diii
'9�
viNKl
ONO sgh❑
:(ww9e ) slelA VOA ul aoedspeaH
'tr4
b'IN 9
ONO
SSA❑
:u011eupolgo9p Jo; peNoag3 saldweS
£ F
v!N❑
VINN/
ON
ONE]
oN❑
saA❑
saA❑
saA❑
(,alum) oMG-!M'0'80'301'wJol!Soo 'y0A mo!ldom
'uoilepuauJUJooaJ yd3 Um gouelldwoo
ui aq of puno; aJe uoilTamaseid bu!peau sJauieluoo ila
•pa>loago uaaq aAeq uoilemosoid 6uipeou siouleluoo IIV
'Zl
a/N❑
ONO
S
:xlaleA si9Aleuyl(]llawillalep sopni3ul-
:000 golew slage-1 oldweS
l (
v/ z
ONCI
saA❑
S;Sal paAIOSS!Q JO; paA1939J awnlOA paJallld
'0
IN
ONE]
SaA
:13elul SJ2ulelU00
6
VINE]
b!N❑
ON sa
N❑ SO
:pain sJa IWOO a3ed-
:pass sieuleluoD ioeil00
g
b4N❑
ONO
s9A GI
:ewnloA luoio!jjnS
L
dIN❑
o
s ❑
:pa;sanbaa owll punoJy uJnl gsnU
9
VINE]
ONn
saA❑
:(JiIZZ>) sisl(leuy awll p10H luogS
'9
d/N❑
oN❑
SO A
:awil PIOH u1411M paAiJJV saldweS
17
VINE]
ONE]
S A
:000 uo ainleu6iS V aweN JaldweS
E
VINE]
ONE) s6A
:pagsinbuilo�j Apolsn0;o uleg0
Z
VINE]
ONE] SA
:1n0 pallid Jtpolsn0;o uieg0
4
7IND
ONE]
s
:luasaJd XPOMD10 uleg0
SJUGIU00
Sululw ut 2)PM'Pi slel}lul pue owa
:s;uawwo0
!N oN saA :uazoJd si anssil leol6o1018
0.9 01 BulzaaJ) aAoge eq pinogs dwal
•dwa1 as oo a O
�. •1 0 P �aaJJp
u VI{./W.jjvo `HIV PUYkd. ...4-2 .,..,y.. •,...,v ... -.L
un6aq seq ssaooJd Buil000'aol uo sold uleg auoN ants :aol jo odA.L l,otq j un0 ail :posn Ja}awowxag j,
JaglO ❑ auoN ❑ ]q ❑ d❑1 elggns ❑ :lelJOWIN GulJlaed
ou ❑ say(❑ :13elul sleas ou �SOA ❑ :luasaJd x091181003 uo leas Apo;sn0
JaglO ❑Iei3Jawwo 1ua110 ❑SdSfl ❑Sdfl ❑ xipad ❑ :Jalano0
&
2 0 :9WEN Iu9110
eoL40 l!leni) all!AsaalunH aoed 94•A01-£OO-SO-UH3-A l
:41!Joglny 6uinssl :JagwnN luawnoolj
Z to � a ed -In9S # looeu uo n uoillpuoo al ages ploglAmtrVast� .—.
t,LOZ '7.7 Jagwaldas :p9S!A9U luawnoo❑ :9w6N luawnoop
Page 29'of 30

`1—
V�Nz4 k�Fti,
`m3;
siaweluoo ao # leloloTj
-
Q o z
1= o w;
U 1:
J 5co
0 4�i
0
f ?1
._._ _. _v�FJk'"
w
i
a
z
zi86
a
g
(-IVOIlA-IVNV
ss30Od)
3
.rer zo g - z sissi
I
p ffi
a!j!oeds auaw!peS
s
(3o'dd) sJef zo g-
c
Suoluv puE
? _
0
sleIaW le)ol - didS
k E
N
Jul zo p- 4 Doi
f
I
OJD
0
(33'dd) ref zo g • 6
ra
Hd
rvy
'suolud ' SWIM Idol
O
-z F-
eal betl
4eJ0c1
Cr
ci n c s sl(le Vol
dwo�u
�
Z
E
N
rm
` 8
C
O
e
o0 '
se
a r o
0
p
3
1J J !
c--i I
n ;
O
U
i/7 w
U
N
m
M
............
I
C
v rn n
5 sRa
! o
n D
°c c
[7
Q
c i w
QQ �I
a
A o Ali!
C
n O
E
S
I
W
d
liJ
o
O
I!
o a
z m
r.
L
o 6
4uj
Z E
I
a
LU
E p c
q 9
P
—
E
E
LU
f)
�
Jy6u
of auwnl
oo alAGAde
vI
Lau
...�.._..
'
..T.._
_
� �
G
0
dlm
3
I
0 of 36,
0
O
"p
A l
a
E x
3
o
�
o
r
3
7Q+
�p
N h
m
} N
W y
V V
flj :E
R
za
fn w
m
.m
Zs
L
a
�a
3 u
f
C1 m
Q
�V
N
a
la a
V a�
vUrn
m
ro
i
1
a�
1
N �
'G Q
m
m �
�
a
sr
_. a�A iuc� 1i 7::,laiu al5 nj
Page 30 of 30

CIAAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM
Laborgadto Use Only
L Tcw I NC
- a " � " "" � �` � �` i r-- work poftr — _K-
fa, DUKE MLO Code MGOJAL2 j BulbOing 74AB) ; i umm: S01 L to,__
J31W 5� sosbuib CH—
HW@m gamy Rd I I ---
HwnlumvWba, itC- 2W70 1 Laggbd By c5b, a
�90 ENERGY, 19800 B75--5245 i NPI
AjapLE pRoaRAw GfiKffliJVWa1w-
- -----------
13pr,0<.4 r4pMw AB GFoLpridwatw Assessment - SOP
PACE
PO 1142081
AB GW
bmwi-,* WIN: Gjrrkq�v ID I 7"aCaft
g1pji.1cy HT 0
63 opo."Ing MR:
When spucflk 49cc~jIng ois t— sklabWlkhod Wo 4 ni)l indkMad mb*Vd
Fnwd jh& folMwing; 11 FarrierM&rrg,�r MquounRi" ID 1111 S 14CCOM14PO NEIds mbriv'J. OF
21 Pnwrr coviect ac-zowhiiij fOrgorldfl4i UFLif AfId PrOC685 Ill.
LAO USE ONLY
ILgib 10 "'Sarriple Description or ID
L
Vb W�kp-- LZ b - fa
77L-
WATER I EQUIPMENT BLANK (I PER DAY
til
Ati, k1a, Be, 13, Cd, C-16 Cr, CO. Cur Fe, Pb, Mg, 0
113viai%iotvalives whAFq tpSod Must tw
at1dwi wilhon IS mirik4l*s nf sample
14 Ccllectiur4 IrifoirMatioll
- =21-1!9u; Do
Ln
-9
0 io
4 W,
a,
fo
Go
I
CJ
I"
';k
Lu
e
[L
12 0,
G
-4
Sr, 71, V, Zn' I&rcwy, pH
irftte Size DIsirlibLnWrL ReduX Poterithol
Syr""RA tft
DISTRIBUT10",
()lzi(;i MAI Lu LAB.
COPY 1c1 CL R. M
"Requested Turnaround
14 Duyh
'? L3,3ys
Q Hr

MW-12BR Equipwnt Blank
Total Met -&Is 9 TOC
*called these sample 128R, Total Metals, TOC, & SPLP
wed to be re-labled Mau'- IN Total Metal, TOC, & SPLP
Total Metals &TOC
W12-18
4/26/2015
15:30
MW-12BR(1.0-2.0)
4/2612015
15,45
MW-12BR(25.N6.01
4/17/2015
8,30
M1r'Vr-12BR(34.0-36.01
4/27/2D15
8:45
MW-12BR(88.5-90,01!
4/2812015
13 DO
Redox, &Mineral Assay
Kd, Redox, & Mineral Assay
HFO, Redox, Wineral Amy
MW428R(50&515)
4126/2015 17:15
MW-12BR(88,5,90,D)
4/2812015 13:00
MW-12BR(96.0-97.51
412812015 13:15
,Its .s 0t S