NC0038377_J15040671 Report_20150902

+ DUKE Analytical Laboratory 1 of98
ENERGY
Order Number:
Project Name:
Customer Name(s):
Customer Address:
Lab Contact:
Report Authorized By:
(Signature)
Program Comments:
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone:[phone] Fax:[phone]
Order Summary Report
J15040671
MAYO STEAM - AB GW ASSESSMENT SOIL
Tim Hunsucker, Jerry Wylie, Kathy Webb, John Toepfer
Margaret Galvin -Karr
MXG4644 (101161)
f RGY - 015.06.16 10:27:15
04'00'
Margaret Galvin -Karr
Phone: [phone]
Date:
Please contact the Program Manager (Margaret Galvin -Karr) with any questions regarding this report.
Data Flags & Calculations:
6/16/2015
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Sample ID's & Descriptions:
Sample ID Plant/Station
Collection
Date and Time
Collected By
2 of 98
Sample Description
2015012319
MAYO STEAM
23-Apr-15 12:15 PM
Synterra
MW-07BR-EB
2015012320
MAYO STEAM
23-Apr-15 12:30 PM
Synterra
MW-07BR (1.0-2.0)
2015012321
MAYO STEAM
26-Apr-15 3:30 PM
Synterra
MW-12D-EB
2015012322
MAYO STEAM
26-Apr-15 3:45 PM
Synterra
MW-12D (1.0-2.0)
2015012323
MAYO STEAM
25-Apr-15 1:40 PM
Synterra
MW-16-EB
2015012324
MAYO STEAM
25-Apr-15 2:10 PM
Synterra
MW-16BR (1.0-2.0)
2015012325
MAYO STEAM
25-Apr-15 5:30 PM
Synterra
MW-16BR (33.0-35.0)
2015012326
MAYO STEAM
26-Apr-15 9:00 AM
Synterra
MW-16BR (23.0-24.0)
2015012327
MAYO STEAM
26-Apr-15 3:50 PM
Synterra
MW-16BR (54.5-55.5)
2015012328
MAYO STEAM
27-Apr-15 8:30 AM
Synterra
MW-12D (25.0-26.0)
2015012329
MAYO STEAM
27-Apr-15 8:45 AM
Synterra
MW-12D (34.0-35.0)
11 Total Samples

3 of 98
Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals Yes No
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits. ❑ Yes❑ No
All laboratory QA/QC requirements are acceptable.❑ Yes ❑ No
Report Sections Included:
U Job Summary Report
❑ Sample Identification
n Technical Validation of Data Package
❑ Analytical Laboratory Certificate of Analysis
❑ Analytical Laboratory QC Report
Reviewed By: Date:
Sub -contracted Laboratory Results
❑ Customer Specific Data Sheets, Reports, & Documentation
❑ Customer Database Entries
0 Chain of Custody
[I/0] Electronic Data Deliverable (EDD) Sent Separately

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15040671
Site: MW-07BR-EB
Collection Date: 23-Apr-15 12:15 PM
Analyte Result Units Qualifiers RDL DF
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Sample #: 2015012319
Matrix: SOIL
4 of 98
Method Analysis Date/Time Analyst
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15040671
Site: MW-07BR (1.0-2.0)
Collection Date: 23-Apr-15 12:30 PM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
5 of 98
Sample #: 2015012320
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis 6 of 98
This report shall not be reproduced, except in full.
Order # J15040671
Site: MW-12D-EB
Collection Date: 26-Apr-15 3:30 PM
Analyte Result Units Qualifiers RDL DF
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Sample #: 2015012321
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15040671
Site: MW-12D (1.0-2.0)
Collection Date: 26-Apr-15 3:45 PM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
7 of 98
Sample #: 2015012322
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis 8 of 98
This report shall not be reproduced, except in full.
Order # J15040671
Site: MW-16-EB
Collection Date: 25-Apr-15 1:40 PM
Analyte Result Units Qualifiers RDL DF
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Sample #: 2015012323
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15040671
Site: MW-16BR (1.0-2.0)
Collection Date: 25-Apr-15 2:10 PM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
9 of 98
Sample #: 2015012324
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15040671
Site: MW-16BR (33.0-35.0)
Collection Date: 25-Apr-15 5:30 PM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
SPLP LEACHATE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
10 of 98
Sample #: 2015012325
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15040671
Site: MW-16BR (23.0-24.0)
Collection Date: 26-Apr-15 9:00 AM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
SPLP LEACHATE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
11 of 98
Sample #: 2015012326
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15040671
Site: MW-16BR (54.5-55.5)
Collection Date: 26-Apr-15 3:50 PM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
12 of 98
Sample #: 2015012327
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15040671
Site: MW-12D (25.0-26.0)
Collection Date: 27-Apr-15 8:30 AM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
SPLP LEACHATE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
13 of 98
Sample #: 2015012328
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15040671
Site: MW-12D (34.0-35.0)
Collection Date: 27-Apr-15 8:45 AM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
SPLP LEACHATE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
14 of 98
Sample #: 2015012329
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
-- Additional Information --
SPLP sulfate blank is 3.1 mg/L. Sample results at or near this level. Results are suspect. M. Galvin -Karr 6/15/2015.

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 f igc&y fie. Suite 100
Huntersville, INC 28078
[phone]
June 15, 2015
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg.7405 MG30A2
Huntersville, NC 28078
RE: Project: J 15040671
Pace Project No.: 92247383
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on April 28, 2015. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TN standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc: Marge Galvin -Karr, Duke Energy
Program Manager, Duke Energy
Mary Ann Ogle, Duke Energy
Rodney Wilke, Duke Energy
p«FO
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
lqe� ��� without the written consent of Pace Analytical Services, Inc..
BRAT,
Page 1 of 82

lacmnalyfica(
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kiinf0e. Suite 100
Huntersville, NC 28078
[phone]
Project: J15040671
Pace Project No.: 92247383
Minnesota Certification IDs
1700 Elm Street SE Suite 200, Minneapolis, MN 55414
A21-A Certification #: 2926.01
Alaska Certification #: UST-078
Alaska Certification #MN00064
Alabama Certification #40770
Arizona Certification #: AZ-0014
Arkansas Certification #: 88-0680
California Certification #: 01155CA
Colorado Certification #Pace
Connecticut Certification #: PH-0256
EPA Region 8 Certification #: 8TMS-L
Florida/NELAP Certification #: E87605
Guam Certification #:14-008r
Georgia Certification #: 959
Georgia EPD #: Pace
Idaho Certification #: MN00064
Hawaii Certification #MN00064
Illinois Certification #: 200011
Indiana Certification#C-MN-01
Iowa Certification #: 368
Kansas Certification #: E-10167
Kentucky Dept of Envi. Protection - DW #90062
Kentucky Dept of Envi. Protection - WW #:90062
Louisiana DEQ Certification #: 3086
Louisiana DHH #: LA140001
Maine Certification #: 2013011
Maryland Certification #: 322
Michigan DEPH Certification #: 9909
Ormond Beach Certification IDs
8 East Tower Circle, Ormond Beach, FL 32174
Alabama Certification #: 41320
Connecticut Certification #: PH-0216
Delaware Certification: FL NELAC Reciprocity
Florida Certification #: E83079
Georgia Certification #: 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification #: 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383
Kentucky Certification #: 90050
Louisiana Certification #: FL NELAC Reciprocity
Louisiana Environmental Certificate #: 05007
Maryland Certification: #346
Massachusetts Certification #: M-FL1264
Michigan Certification #: 9911
Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236
Green Bay Certification IDs
1241 Bellevue Street, Green Bay, WI 54302
Florida/NELAP Certification #: E87948
Illinois Certification #: 200050
Kentucky Certification #: 82
Louisiana Certification #: 04168
Minnesota Certification #: 055-999-334
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
CERTIFICATIONS
Minnesota Certification #: 027-053-137
Mississippi Certification #: Pace
Montana Certification #: MT0092
Nevada Certification #: MN_00064
Nebraska Certification #: Pace
New Jersey Certification #: MN-002
New York Certification #: 11647
North Carolina Certification #: 530
North Carolina State Public Health #: 27700
North Dakota Certification #: R-036
Ohio EPA#: 4150
Ohio VAP Certification #: CL101
Oklahoma Certification #: 9507
Oregon Certification #: MN200001
Oregon Certification #: MN300001
Pennsylvania Certification #: 68-00563
Puerto Rico Certification
Saipan (CNMI) #:MP0003
South Carolina #:74003001
Texas Certification #: T104704192
Tennessee Certification #: 02818
Utah Certification #: MN000642013-4
Virginia DGS Certification #: 251
Virginia/VELAP Certification #: Pace
Washington Certification #: C486
West Virginia Certification #: 382
West Virginia DHHR #:9952C
Wisconsin Certification #: 999407970
Montana Certification #: Cert 0074
Nebraska Certification: NE-OS-28-14
Nevada Certification: FL NELAC Reciprocity
New Hampshire Certification #: 2958
New Jersey Certification #: FL765
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FLO1264
South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
Washington Certification #: C955
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
North Dakota Certification #: R-150
South Carolina Certification #: 83006001
Texas Certification #: T104704529-14-1
US Dept of Agriculture #: S-76505
Wisconsin Certification #: 405132750
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 2 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 ff�ic&� �e. Suite 100
Huntersville, NC 28078
[phone]
Project: J15040671
Pace Project No.: 92247383
Asheville Certification IDs
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
CERTIFICATIONS
West Virginia Certification #: 356
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 3 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 %%yfte. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE SUMMARY
Project: J15040671
Pace Project No.: 92247383
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92247383001
2015012319
Water
04/23/1512:15
04/28/15 14:30
92247383002
2015012320
Solid
04/23/1512:30
04/28/15 14:30
92247383003
2015012321
Water
04/26/1515:30
04/28/15 14:30
92247383004
2015012322
Solid
04/26/1515:45
04/28/15 14:30
92247383005
2015012323
Water
04/25/1513:40
04/28/15 14:30
92247383006
2015012324
Solid
04/25/1514:10
04/28/15 14:30
92247383007
2015012325
Solid
04/25/1517:30
04/28/15 14:30
92247383008
2015012326
Solid
04/26/15 09:00
04/28/15 14:30
92247383009
2015012327
Solid
04/26/1515:50
04/28/15 14:30
92247383010
2015012328
Solid
04/27/15 08:30
04/28/15 14:30
92247383011
2015012329
Solid
04/27/15 08:45
04/28/15 14:30
92247383012
2015012325 SPLP
Water
04/25/15 17:30
04/28/15 14:30
92247383013
2015012326 SPLP
Water
04/26/15 09:00
04/28/15 14:30
92247383014
2015012328 SPLP
Water
04/27/15 08:30
04/28/15 14:30
92247383015
2015012329 SPLP
Water
04/27/15 08:45
04/28/15 14:30
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 4 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 ffli ,8yftie. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
J15040671
92247383
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92247383001
2015012319
EPA 6020A
RJS
24
PASI-M
EPA 7470A
JDD
1
PASI-M
92247383002
2015012320
EPA 6010
CKJ
16
PASI-0
EPA 6020
DRS
8
PASI-O
EPA 7471
CKJ
1
PASI-O
ASTM D2974-87
MLO
1
PASI-O
EPA 9045
MLS
1
PASI-A
EPA 9056
AIS
2
PASI-O
EPA 9056
AIS
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92247383003
2015012321
EPA 6020A
RJS
24
PASI-M
EPA 7470A
JDD
1
PASI-M
92247383004
2015012322
EPA 6010
CKJ
16
PASI-0
EPA 6020
DRS
8
PASI-O
EPA 7471
CKJ
1
PASI-O
ASTM D2974-87
MLO
1
PASI-O
EPA 9045
MLS
1
PASI-A
EPA 9056
AIS
2
PASI-O
EPA 9056
AIS
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92247383005
2015012323
EPA 6020A
RJS
24
PASI-M
EPA 7470A
JDD
1
PASI-M
92247383006
2015012324
EPA 6010
CKJ
16
PASI-0
EPA 6020
DRS
8
PASI-O
EPA 7471
CKJ
1
PASI-O
ASTM D2974-87
MLO
1
PASI-O
EPA 9045
MLS
1
PASI-A
EPA 9056
AIS
2
PASI-O
EPA 9056
AIS
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92247383007
2015012325
EPA 6010
CKJ
16
PASI-0
EPA 6020
DRS
8
PASI-O
EPA 7471
CKJ
1
PASI-O
ASTM D2974-87
MLO
1
PASI-O
EPA 9045
MLS
1
PASI-A
EPA 300.0
AES2
1
PASI-A
EPA 353.2
DMN
1
PASI-A
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 5 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 KPi %Yfte. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project: J15040671
Pace Project No.: 92247383
Lab ID
Sample ID
Method
Analysts
Analytes
Reported
Laboratory
SM 4500-CI-E
SER
1
PASI-A
EPA 9056
AIS
2
PASI-O
EPA 9056
AIS
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92247383008
2015012326
EPA 6010
CKJ
16
PASI-0
EPA 6020
DRS
8
PASI-O
EPA 7471
CKJ
1
PASI-O
ASTM D2974-87
MLO
1
PASI-O
EPA 9045
MAB
1
PASI-A
EPA 300.0
AES2
1
PASI-A
EPA 353.2
DMN
1
PASI-A
SM 4500-CI-E
SER
1
PASI-A
EPA 9056
AIS
2
PASI-O
EPA 9056
AIS
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92247383009
2015012327
EPA 6010
CKJ
16
PASI-0
EPA 6020
DRS
8
PASI-O
EPA 7471
CKJ
1
PASI-O
ASTM D2974-87
MLO
1
PASI-O
EPA 9045
MAB
1
PASI-A
EPA 9056
AIS
2
PASI-O
EPA 9056
AIS
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92247383010
2015012328
EPA 6010
CKJ
16
PASI-0
EPA 6020
DRS
8
PASI-O
EPA 7471
CKJ
1
PASI-O
ASTM D2974-87
MLO
1
PASI-O
EPA 9045
MAB
1
PASI-A
EPA 300.0
AES2
1
PASI-A
EPA 353.2
DMN
1
PASI-A
SM 4500-CI-E
SER
1
PASI-A
EPA 9056
AIS
2
PASI-O
EPA 9056
AIS
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92247383011
2015012329
EPA 6010
CKJ
16
PASI-0
EPA 6020
DRS
8
PASI-O
EPA 7471
CKJ
1
PASI-O
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 6 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 �n%yfte. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project: J15040671
Pace Project No.: 92247383
Lab ID
Sample ID
Method
Analysts
Analytes
Reported
Laboratory
ASTM D2974-87
MLO
1
PASI-O
EPA 9045
MAB
1
PASI-A
EPA 300.0
AES2
1
PASI-A
EPA 353.2
DMN
1
PASI-A
SM 4500-CI-E
SER
1
PASI-A
EPA 9056
AIS
2
PASI-O
EPA 9056
AIS
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92247383012
2015012325 SPLP
EPA 6020A
RJS
24
PASI-M
EPA 7470A
DM
1
PASI-M
92247383013
2015012326 SPLP
EPA 6020A
RJS
24
PASI-M
EPA 7470A
DM
1
PASI-M
92247383014
2015012328 SPLP
EPA 6020A
RJS
24
PASI-M
EPA 7470A
DM
1
PASI-M
92247383015
2015012329 SPLP
EPA 6020A
RJS
24
PASI-M
EPA 7470A
DM
1
PASI-M
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 7 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 1P2,8y ft.. Suite 100
Huntersville, NC 28078
[phone]
Project: J15040671
Pace Project No.: 92247383
Lab Sample ID Client Sample ID
Method Parameters
SUMMARY OF DETECTION
Result Units Report Limit Analyzed
92247383001
2015012319
EPA 6020A
Aluminum
7.6J
ug/L
10.0
05/06/15 09:10
EPA 6020A
Barium
0.22J
ug/L
0.30
05/05/15 14:46
EPA 6020A
Calcium
68.7
ug/L
40.0
05/05/15 14:46
EPA 6020A
Chromium
1.3
ug/L
0.50
05/05/15 14:46
EPA 6020A
Cobalt
0.50J
ug/L
0.50
05/05/15 14:46
EPA 6020A
Copper
0.74J
ug/L
1.0
05/05/15 14:46
EPA 6020A
Iron
166
ug/L
50.0
05/05/15 14:46
EPA 6020A
Magnesium
19.0
ug/L
10.0
05/05/15 14:46
EPA 6020A
Manganese
2.7
ug/L
0.50
05/05/15 14:46
EPA 6020A
Molybdenum
0.32J
ug/L
0.50
05/05/15 14:46
EPA 6020A
Nickel
0.36J
ug/L
0.50
05/05/15 14:46
EPA 6020A
Strontium
0.26J
ug/L
0.50
05/05/15 14:46
EPA 6020A
Zinc
4.9J
ug/L
5.0
05/05/15 14:46
92247383002
2015012320
EPA 6010
Aluminum
3080
mg/kg
25.5
05/07/15 10:38
EPA 6010
Barium
21.5
mg/kg
2.6
05/07/15 10:38
EPA 6010
Beryllium
0.29
mg/kg
0.26
05/07/15 10:38
EPA 6010
Calcium
68.5J
mg/kg
128
05/07/15 10:38
EPA 6010
Chromium
4.1
mg/kg
1.3
05/07/15 10:38
EPA 6010
Copper
7.0
mg/kg
1.3
05/07/15 10:38
EPA 6010
Iron
7320
mg/kg
10.2
05/07/15 10:38
EPA 6010
Magnesium
437
mg/kg
128
05/07/15 10:38
EPA 6010
Manganese
27.7
mg/kg
1.3
05/07/15 10:38
EPA 6010
Nickel
0.68J
mg/kg
1.3
05/07/15 10:38
EPA 6010
Potassium
315
mg/kg
255
05/07/15 10:38
EPA 6010
Strontium
2.OJ
mg/kg
2.6
05/07/15 10:38
EPA 6010
Zinc
7.0
mg/kg
5.1
05/07/15 10:38
EPA 6020
Lead
5.4
mg/kg
5.1
05/06/15 17:54
EPA 6020
Vanadium
12.8
mg/kg
5.1
05/06/15 17:54
EPA 7471
Mercury
0.0073J
mg/kg
0.0086
05/07/15 13:57
ASTM D2974-87
Percent Moisture
2.8
%
0.10
05/13/15 10:29
EPA 9045
pH at 25 Degrees C
5.6
Std. Units
0.10
04/29/15 14:50
EPA 9060
Total Organic Carbon
485J
mg/kg
613
05/18/15 09:33
EPA 9060
Total Organic Carbon
418J
mg/kg
618
05/18/15 09:38
EPA 9060
Total Organic Carbon
383J
mg/kg
612
05/18/15 09:45
EPA 9060
Total Organic Carbon
394J
mg/kg
623
05/18/15 09:51
EPA 9060
Mean Total Organic Carbon
420J
mg/kg
617
05/18/15 09:33
EPA 9060
RSD%
10.8
%
05/18/15 09:33
92247383003
2015012321
EPA 6020A
Aluminum
64.1
ug/L
10.0
05/06/15 09:52
EPA 6020A
Barium
1.1
ug/L
0.30
05/05/15 14:51
EPA 6020A
Boron
7.3
ug/L
5.0
05/05/15 14:51
EPA 6020A
Calcium
971
ug/L
40.0
05/05/15 14:51
EPA 6020A
Chromium
1.8
ug/L
0.50
05/05/15 14:51
EPA 6020A
Cobalt
7.6
ug/L
0.50
05/05/15 14:51
EPA 6020A
Copper
1.3
ug/L
1.0
05/05/15 14:51
REPORT OF LABORATORY ANALYSIS
Qualifiers
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 8 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 KPiS%yfte. Suite 100
Huntersville, NC 28078
[phone]
Project: J15040671
Pace Project No.: 92247383
Lab Sample ID Client Sample ID
Method Parameters
SUMMARY OF DETECTION
Result Units Report Limit Analyzed
92247383003
2015012321
EPA 6020A
Iron
663
ug/L
50.0
05/05/15 14:51
EPA 6020A
Lead
0.38
ug/L
0.10
05/05/15 14:51
EPA 6020A
Magnesium
39.8
ug/L
10.0
05/05/15 14:51
EPA 6020A
Manganese
14.3
ug/L
0.50
05/05/15 14:51
EPA 6020A
Molybdenum
0.21J
ug/L
0.50
05/05/15 14:51
EPA 6020A
Nickel
0.68
ug/L
0.50
05/05/15 14:51
EPA 6020A
Potassium
22.OJ
ug/L
50.0
05/05/15 14:51
EPA 6020A
Sodium
20.OJ
ug/L
50.0
05/05/15 14:51
EPA 6020A
Strontium
1.7
ug/L
0.50
05/05/15 14:51
EPA 6020A
Zinc
9.0
ug/L
5.0
05/05/15 14:51
92247383004
2015012322
EPA 6010
Aluminum
11000
mg/kg
29.9
05/07/15 10:42
EPA 6010
Barium
19.6
mg/kg
3.0
05/07/15 10:42
EPA 6010
Boron
27.4
mg/kg
15.0
05/07/15 10:42
EPA 6010
Chromium
43.6
mg/kg
1.5
05/07/15 10:42
EPA 6010
Copper
12.4
mg/kg
1.5
05/07/15 10:42
EPA 6010
Iron
31200
mg/kg
12.0
05/07/15 10:42
EPA 6010
Magnesium
139J
mg/kg
150
05/07/15 10:42
EPA 6010
Manganese
22.1
mg/kg
1.5
05/07/15 10:42
EPA 6010
Nickel
0.83J
mg/kg
1.5
05/07/15 10:42
EPA 6010
Potassium
182J
mg/kg
299
05/07/15 10:42
EPA 6010
Zinc
5.2J
mg/kg
6.0
05/07/15 10:42
EPA 6020
Arsenic
3.6J
mg/kg
6.0
05/06/15 17:56
EPA 6020
Lead
6.8
mg/kg
6.0
05/06/15 17:56
EPA 6020
Vanadium
61.0
mg/kg
6.0
05/06/15 17:56
EPA 7471
Mercury
0.036
mg/kg
0.0093
05/07/15 13:59
ASTM D2974-87
Percent Moisture
17.5
%
0.10
05/13/15 10:29
EPA 9045
pH at 25 Degrees C
4.9
Std. Units
0.10
04/29/15 14:50
EPA 9060
Total Organic Carbon
848
mg/kg
724
05/20/15 11:04
EPA 9060
Total Organic Carbon
979
mg/kg
725
05/20/15 11:10
EPA 9060
Total Organic Carbon
1460
mg/kg
730
05/20/15 11:16
EPA 9060
Total Organic Carbon
1170
mg/kg
726
05/20/15 11:23
EPA 9060
Mean Total Organic Carbon
1110
mg/kg
726
05/20/15 11:04
EPA 9060
RSD%
23.7
%
05/20/15 11:04
92247383005
2015012323
EPA 6020A
Aluminum
13.5
ug/L
10.0
05/06/15 09:57
EPA 6020A
Barium
0.30
ug/L
0.30
05/05/15 14:56
EPA 6020A
Calcium
65.9
ug/L
40.0
05/05/15 14:56
EPA 6020A
Chromium
0.58
ug/L
0.50
05/05/15 14:56
EPA 6020A
Cobalt
1.0
ug/L
0.50
05/05/15 14:56
EPA 6020A
Copper
0.44J
ug/L
1.0
05/05/15 14:56
EPA 6020A
Iron
96.7
ug/L
50.0
05/05/15 14:56
EPA 6020A
Magnesium
14.2
ug/L
10.0
05/05/15 14:56
EPA 6020A
Manganese
1.7
ug/L
0.50
05/05/15 14:56
EPA 6020A
Molybdenum
0.14J
ug/L
0.50
05/05/15 14:56
EPA 6020A
Strontium
0.15J
ug/L
0.50
05/05/15 14:56
REPORT OF LABORATORY ANALYSIS
Qualifiers
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 9 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 1P4,8y ft.. Suite 100
Huntersville, NC 28078
[phone]
Project: J15040671
Pace Project No.: 92247383
Lab Sample ID Client Sample ID
Method Parameters
SUMMARY OF DETECTION
Result Units Report Limit Analyzed
92247383006
2015012324
EPA 6010
Aluminum
5360
mg/kg
32.4
05/07/15 10:59
EPA 6010
Barium
95.4
mg/kg
3.2
05/07/15 10:59
EPA 6010
Beryllium
0.40
mg/kg
0.32
05/07/15 10:59
EPA 6010
Calcium
253
mg/kg
162
05/07/15 10:59
EPA 6010
Chromium
7.6
mg/kg
1.6
05/07/15 10:59
EPA 6010
Copper
4.3
mg/kg
1.6
05/07/15 10:59
EPA 6010
Iron
7710
mg/kg
12.9
05/07/15 10:59
EPA 6010
Magnesium
454
mg/kg
162
05/07/15 10:59
EPA 6010
Manganese
1250
mg/kg
1.6
05/07/15 10:59
EPA 6010
Nickel
1.9
mg/kg
1.6
05/07/15 10:59
EPA 6010
Potassium
254J
mg/kg
324
05/07/15 10:59
EPA 6010
Strontium
3.2J
mg/kg
3.2
05/07/15 10:59
EPA 6010
Zinc
10.4
mg/kg
6.5
05/07/15 10:59
EPA 6020
Cobalt
6.OJ
mg/kg
6.5
05/06/15 18:06
EPA 6020
Lead
6.3J
mg/kg
6.5
05/06/15 18:06
EPA 6020
Vanadium
17.3
mg/kg
6.5
05/06/15 18:06
EPA 7471
Mercury
0.012
mg/kg
0.011
05/07/15 14:02
ASTM D2974-87
Percent Moisture
24.9
%
0.10
05/13/15 10:29
EPA 9045
pH at 25 Degrees C
5.1
Std. Units
0.10
04/29/15 14:50
EPA 9060
Total Organic Carbon
2880
mg/kg
800
05/20/15 12:17
EPA 9060
Total Organic Carbon
3740
mg/kg
796
05/20/15 12:24
EPA 9060
Total Organic Carbon
3380
mg/kg
804
05/20/15 12:29
EPA 9060
Total Organic Carbon
3410
mg/kg
801
05/20/15 12:34
EPA 9060
Mean Total Organic Carbon
3350
mg/kg
800
05/20/15 12:17
EPA 9060
RSD%
10.6
%
05/20/15 12:17
92247383007
2015012325
EPA 6010
Aluminum
9030
mg/kg
37.6
05/07/15 11:04
EPA 6010
Barium
131
mg/kg
3.8
05/07/15 11:04
EPA 6010
Beryllium
0.36J
mg/kg
0.38
05/07/15 11:04
EPA 6010
Boron
16.8J
mg/kg
18.8
05/07/15 11:04
EPA 6010
Calcium
4470
mg/kg
188
05/07/15 11:04
EPA 6010
Chromium
9.2
mg/kg
1.9
05/07/15 11:04
EPA 6010
Copper
126
mg/kg
1.9
05/07/15 11:04
EPA 6010
Iron
19100
mg/kg
15.0
05/07/15 11:04
EPA 6010
Magnesium
5220
mg/kg
188
05/07/15 11:04
EPA 6010
Manganese
1630
mg/kg
1.9
05/07/15 11:04
EPA 6010
Molybdenum
2.9J
mg/kg
3.8
05/07/15 11:04
EPA 6010
Nickel
2.9
mg/kg
1.9
05/07/15 11:04
EPA 6010
Potassium
2890
mg/kg
376
05/07/15 11:04
EPA 6010
Sodium
384
mg/kg
376
05/07/15 11:04
EPA 6010
Strontium
37.5
mg/kg
3.8
05/07/15 11:04
EPA 6010
Zinc
54.6
mg/kg
7.5
05/07/15 11:04
EPA 6020
Cobalt
12.0
mg/kg
7.5
05/06/15 18:08
EPA 6020
Lead
3.8J
mg/kg
7.5
05/06/15 18:08
EPA 6020
Vanadium
16.3
mg/kg
7.5
05/06/15 18:08
ASTM D2974-87
Percent Moisture
30.7
%
0.10
05/13/15 10:30
EPA 9045
pH at 25 Degrees C
8.1
Std. Units
0.10
04/29/15 14:50
REPORT OF LABORATORY ANALYSIS
Qualifiers
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 10 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 KPi '8ffte. Suite 100
Huntersville, NC 28078
[phone]
Project: J15040671
Pace Project No.: 92247383
Lab Sample ID Client Sample ID
Method Parameters
SUMMARY OF DETECTION
Result Units Report Limit Analyzed Qualifiers
92247383007
2015012325
EPA 300.0
Sulfate
5.4
mg/L
2.9
05/14/15 19:29 B
EPA 9060
RSD%
3.0
%
05/20/15 14:27
92247383008
2015012326
EPA 6010
Aluminum
4860
mg/kg
25.0
05/07/15 11:08
EPA 6010
Barium
28.2
mg/kg
2.5
05/07/15 11:08
EPA 6010
Beryllium
0.20J
mg/kg
0.25
05/07/15 11:08
EPA 6010
Boron
10.01
mg/kg
12.5
05/07/15 11:08
EPA 6010
Calcium
2710
mg/kg
125
05/07/15 11:08
EPA 6010
Chromium
2.1
mg/kg
1.3
05/07/15 11:08
EPA 6010
Copper
5.3
mg/kg
1.3
05/07/15 11:08
EPA 6010
Iron
10600
mg/kg
10.0
05/07/15 11:08
EPA 6010
Magnesium
3200
mg/kg
125
05/07/15 11:08
EPA 6010
Manganese
885
mg/kg
1.3
05/07/15 11:08
EPA 6010
Nickel
1.2J
mg/kg
1.3
05/07/15 11:08
EPA 6010
Potassium
1390
mg/kg
250
05/07/15 11:08
EPA 6010
Sodium
182J
mg/kg
250
05/07/15 11:08
EPA 6010
Strontium
23.3
mg/kg
2.5
05/07/15 11:08
EPA 6010
Zinc
35.6
mg/kg
5.0
05/07/15 11:08
EPA 6020
Cobalt
4.6J
mg/kg
5.0
05/06/15 18:11
EPA 6020
Vanadium
8.4
mg/kg
5.0
05/06/15 18:11
ASTM D2974-87
Percent Moisture
2.4
%
0.10
05/13/15 10:30
EPA 9045
pH at 25 Degrees C
7.8
Std. Units
0.10
05/04/15 14:00
EPA 300.0
Sulfate
3.8
mg/L
2.0
05/14/15 19:43 B
EPA 9060
RSD%
2.7
%
05/20/15 14:50
92247383009
2015012327
EPA 6010
Aluminum
24500
mg/kg
25.8
05/07/15 11:12
EPA 6010
Barium
237
mg/kg
2.6
05/07/15 11:12
EPA 6010
Beryllium
0.40
mg/kg
0.26
05/07/15 11:12
EPA 6010
Boron
32.3
mg/kg
12.9
05/07/15 11:12
EPA 6010
Calcium
19400
mg/kg
129
05/07/15 11:12
EPA 6010
Chromium
37.2
mg/kg
1.3
05/07/15 11:12
EPA 6010
Copper
26.7
mg/kg
1.3
05/07/15 11:12
EPA 6010
Iron
38300
mg/kg
10.3
05/07/15 11:12
EPA 6010
Magnesium
21800
mg/kg
129
05/07/15 11:12
EPA 6010
Manganese
1010
mg/kg
1.3
05/07/15 11:12
EPA 6010
Nickel
28.1
mg/kg
1.3
05/07/15 11:12
EPA 6010
Potassium
16600
mg/kg
258
05/07/15 11:12
EPA 6010
Sodium
261
mg/kg
258
05/07/15 11:12
EPA 6010
Strontium
40.0
mg/kg
2.6
05/07/15 11:12
EPA 6010
Zinc
101
mg/kg
5.2
05/07/15 11:12
EPA 6020
Cobalt
19.6
mg/kg
5.2
05/06/15 18:13
EPA 6020
Vanadium
87.0
mg/kg
5.2
05/06/15 18:13
ASTM D2974-87
Percent Moisture
6.5
%
0.10
05/13/15 10:30
EPA 9045
pH at 25 Degrees C
9.6
Std. Units
0.10
05/04/15 14:00
EPA 9060
RSD%
12.2
%
05/20/15 15:12
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 11 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kai %yfte. Suite 100
Huntersville, NC 28078
[phone]
Project: J15040671
Pace Project No.: 92247383
Lab Sample ID Client Sample ID
Method Parameters
SUMMARY OF DETECTION
Result Units Report Limit Analyzed
92247383010
2015012328
EPA 6010
Aluminum
3530
mg/kg
29.9
05/07/15 11:17
EPA 6010
Barium
67.4
mg/kg
3.0
05/07/15 11:17
EPA 6010
Boron
9.8J
mg/kg
14.9
05/07/15 11:17
EPA 6010
Chromium
3.2
mg/kg
1.5
05/07/15 11:17
EPA 6010
Copper
22.4
mg/kg
1.5
05/07/15 11:17
EPA 6010
Iron
11900
mg/kg
12.0
05/07/15 11:17
EPA 6010
Magnesium
1190
mg/kg
149
05/07/15 11:17
EPA 6010
Manganese
395
mg/kg
1.5
05/07/15 11:17
EPA 6010
Potassium
1520
mg/kg
299
05/07/15 11:17
EPA 6010
Zinc
15.0
mg/kg
6.0
05/07/15 11:17
EPA 6020
Cobalt
6.0
mg/kg
6.0
05/06/15 18:15
EPA 6020
Lead
7.2
mg/kg
6.0
05/06/15 18:15
EPA 6020
Vanadium
8.2
mg/kg
6.0
05/06/15 18:15
ASTM D2974-87
Percent Moisture
16.8
%
0.10
05/13/15 10:30
EPA 9045
pH at 25 Degrees C
5.9
Std. Units
0.10
05/04/15 14:00
EPA 300.0
Sulfate
3.1
mg/L
2.4
05/14/15 19:56
EPA 353.2
Nitrogen, Nitrate
0.25
mg/L
0.24
05/15/15 21:10
EPA 9060
RSD%
2.3
%
05/20/15 15:35
92247383011
2015012329
EPA 6010
Aluminum
4410
mg/kg
31.3
05/07/15 11:21
EPA 6010
Barium
81.5
mg/kg
3.1
05/07/15 11:21
EPA 6010
Beryllium
0.25J
mg/kg
0.31
05/07/15 11:21
EPA 6010
Boron
9.2J
mg/kg
15.6
05/07/15 11:21
EPA 6010
Chromium
1.9
mg/kg
1.6
05/07/15 11:21
EPA 6010
Copper
19.1
mg/kg
1.6
05/07/15 11:21
EPA 6010
Iron
10700
mg/kg
12.5
05/07/15 11:21
EPA 6010
Magnesium
1410
mg/kg
156
05/07/15 11:21
EPA 6010
Manganese
855
mg/kg
1.6
05/07/15 11:21
EPA 6010
Nickel
1 AJ
mg/kg
1.6
05/07/15 11:21
EPA 6010
Potassium
1680
mg/kg
313
05/07/15 11:21
EPA 6010
Strontium
4.6
mg/kg
3.1
05/07/15 11:21
EPA 6010
Zinc
27.7
mg/kg
6.3
05/07/15 11:21
EPA 6020
Cobalt
9.2
mg/kg
6.3
05/06/15 18:18
EPA 6020
Lead
9.2
mg/kg
6.3
05/06/15 18:18
EPA 6020
Vanadium
7.7
mg/kg
6.3
05/06/15 18:18
ASTM D2974-87
Percent Moisture
20.3
%
0.10
05/13/15 10:30
EPA 9045
pH at 25 Degrees C
5.5
Std. Units
0.10
05/04/15 14:00
EPA 300.0
Sulfate
3.4
mg/L
2.5
05/14/15 20:10
EPA 9060
RSD%
1.8
%
05/20/15 16:00
92247383012
2015012325 SPLP
EPA 6020A
Aluminum
13200
ug/L
10.0
05/29/15 17:20
EPA 6020A
Arsenic
2.8
ug/L
0.50
05/29/15 17:20
EPA 6020A
Barium
360
ug/L
0.30
05/29/15 17:20
EPA 6020A
Beryllium
0.48
ug/L
0.20
05/29/15 17:20
EPA 6020A
Boron
32.7
ug/L
5.0
05/29/15 17:20
EPA 6020A
Cadmium
0.062J
ug/L
0.080
05/29/15 17:20
REPORT OF LABORATORY ANALYSIS
W
B
H1
B
Qualifiers
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 12 of 82

aceAnaiXical
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[phone]
Project: J15040671
Pace Project No.: 92247383
Lab Sample ID Client Sample ID
Method Parameters
SUMMARY OF DETECTION
Result Units Report Limit Analyzed
92247383012
2015012325 SPLP
EPA 6020A
Calcium
3370
ug/L
40.0
05/29/15 17:20
EPA 6020A
Chromium
8.8
ug/L
0.50
05/29/15 17:20
EPA 6020A
Cobalt
12.7
ug/L
0.50
05/29/15 17:20
EPA 6020A
Copper
155
ug/L
1.0
05/29/15 17:20
EPA 6020A
Iron
21000
ug/L
50.0
05/29/15 17:20
EPA 6020A
Lead
5.6
ug/L
0.10
05/29/15 17:20
EPA 6020A
Magnesium
4960
ug/L
10.0
05/29/15 17:20
EPA 6020A
Manganese
1990
ug/L
10.0
05/31/1510:13
EPA 6020A
Molybdenum
10.9
ug/L
0.50
05/29/15 17:20
EPA 6020A
Nickel
4.2
ug/L
0.50
05/29/15 17:20
EPA 6020A
Potassium
3800
ug/L
50.0
05/29/15 17:20
EPA 6020A
Selenium
2.1
ug/L
0.50
05/29/15 17:20
EPA 6020A
Sodium
3900
ug/L
50.0
05/29/15 17:20
EPA 6020A
Strontium
47.0
ug/L
0.50
05/29/15 17:20
EPA 6020A
Thallium
0.045J
ug/L
0.10
05/29/15 17:20
EPA 6020A
Vanadium
18.5
ug/L
1.0
05/29/15 17:20
EPA 6020A
Zinc
90.9
ug/L
5.0
05/29/15 17:20
92247383013
2015012326 SPLP
EPA 6020A
Aluminum
4500
ug/L
10.0
05/29/15 17:25
EPA 6020A
Arsenic
0.191
ug/L
0.50
05/29/15 17:25
EPA 6020A
Barium
126
ug/L
0.30
05/29/15 17:25
EPA 6020A
Beryllium
0.18J
ug/L
0.20
05/29/15 17:25
EPA 6020A
Boron
30.2
ug/L
5.0
05/29/15 17:25
EPA 6020A
Calcium
1140
ug/L
40.0
05/29/15 17:25
EPA 6020A
Chromium
1.4
ug/L
0.50
05/29/15 17:25
EPA 6020A
Cobalt
2.5
ug/L
0.50
05/29/15 17:25
EPA 6020A
Copper
3.8
ug/L
1.0
05/29/15 17:25
EPA 6020A
Iron
5980
ug/L
50.0
05/29/15 17:25
EPA 6020A
Lead
1.0
ug/L
0.10
05/29/15 17:25
EPA 6020A
Magnesium
1670
ug/L
10.0
05/29/15 17:25
EPA 6020A
Manganese
701
ug/L
2.5
05/31/1510:18
EPA 6020A
Molybdenum
0.96
ug/L
0.50
05/29/15 17:25
EPA 6020A
Nickel
0.92
ug/L
0.50
05/29/15 17:25
EPA 6020A
Potassium
1650
ug/L
50.0
05/29/15 17:25
EPA 6020A
Sodium
3740
ug/L
50.0
05/29/15 17:25
EPA 6020A
Strontium
23.8
ug/L
0.50
05/29/15 17:25
EPA 6020A
Vanadium
7.2
ug/L
1.0
05/29/15 17:25
EPA 6020A
Zinc
38.7
ug/L
5.0
05/29/15 17:25
92247383014
2015012328 SPLP
EPA 6020A
Aluminum
3.2J
ug/L
10.0
05/29/15 17:44
EPA 6020A
Barium
55.5
ug/L
0.30
05/29/15 17:44
EPA 6020A
Boron
38.0
ug/L
5.0
05/29/15 17:44
EPA 6020A
Calcium
123
ug/L
40.0
05/29/15 17:44
EPA 6020A
Chromium
0.23J
ug/L
0.50
05/29/15 17:44
EPA 6020A
Cobalt
0.191
ug/L
0.50
05/29/15 17:44
EPA 6020A
Copper
0.74J
ug/L
1.0
05/29/15 17:44
REPORT OF LABORATORY ANALYSIS
Qualifiers
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 13 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 KPi %Yfte. Suite 100
Huntersville, NC 28078
[phone]
Project: J15040671
Pace Project No.: 92247383
Lab Sample ID
Method
Client Sample ID
Parameters
92247383014
2015012328 SPLP
EPA 6020A
Lead
EPA 6020A
Magnesium
EPA 6020A
Manganese
EPA 6020A
Nickel
EPA 6020A
Potassium
EPA 6020A
Sodium
EPA 6020A
Strontium
EPA 6020A
Zinc
92247383015
2015012329 SPLP
EPA 6020A
Aluminum
EPA 6020A
Barium
EPA 6020A
Boron
EPA 6020A
Calcium
EPA 6020A
Chromium
EPA 6020A
Copper
EPA 6020A
Lead
EPA 6020A
Magnesium
EPA 6020A
Manganese
EPA 6020A
Nickel
EPA 6020A
Potassium
EPA 6020A
Sodium
EPA 6020A
Strontium
EPA 6020A
Zinc
SUMMARY OF DETECTION
Result Units Report Limit Analyzed Qualifiers
0.053J
ug/L
0.10
05/29/1517:44
137
ug/L
10.0
05/29/1517:44
3.3
ug/L
0.50
05/29/1517:44
0.34J
ug/L
0.50
05/29/1517:44
96.5
ug/L
50.0
05/29/1517:44
1250
ug/L
50.0
05/29/1517:44
2.2
ug/L
0.50
05/29/1517:44
25.3
ug/L
5.0
05/29/1517:44
5.7J
ug/L
10.0
05/29/1517:49
64.1
ug/L
0.30
05/29/1517:49
47.3
ug/L
5.0
05/29/1517:49
148
ug/L
40.0
05/29/1517:49
0.47J
ug/L
0.50
05/29/1517:49
1.0
ug/L
1.0
05/29/1517:49
0.088J
ug/L
0.10
05/29/1517:49
100
ug/L
10.0
05/29/1517:49
2.7
ug/L
0.50
05/29/1517:49
0.37J
ug/L
0.50
05/29/1517:49
151
ug/L
50.0
05/29/1517:49
1330
ug/L
50.0
05/29/1517:49
3.5
ug/L
0.50
05/29/1517:49
23.6
ug/L
5.0
05/29/1517:49
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 14 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 try ,8yftie. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15040671
Pace Project No.: 92247383
Method: EPA 6010
Description: 6010 MET ICP
Client: Duke Energy
Date: June 15, 2015
General Information:
8 samples were analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 3050 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: MPRP/23950
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92247232001
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1203100)
• Aluminum
• Iron
• Molybdenum
• MSD (Lab ID: 1203101)
• Aluminum
• Barium
• Calcium
• Iron
• Manganese
• Strontium
R1: RPD value was outside control limits.
• MSD (Lab ID: 1203101)
• Calcium
• Molybdenum
• Strontium
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 15 of 82

aceAnaiXical
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Pace Analytical Services, Inc.
9800 Kai %yfte. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15040671
Pace Project No.: 92247383
Method: EPA 6010
Description: 6010 MET ICP
Client: Duke Energy
Date: June 15, 2015
Additional Comments:
Batch Comments:
Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
• QC Batch: ICP / 14654
Analyte Comments:
QC Batch: MPRP/23950
P8: Analyte was detected in the method blank. All associated samples had concentrations of at least ten times greater than the blank
or were below the reporting limit.
• BLANK (Lab ID: 1203098)
• Manganese
• BLANK (Lab ID: 1203098)
• Manganese
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 16 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 �n%yfte. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15040671
Pace Project No.: 92247383
Method: EPA 6020
Description: 6020 MET ICPMS
Client: Duke Energy
Date: June 15, 2015
General Information:
8 samples were analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 3050 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: MPRP/23951
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92247232001
M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
• MS (Lab ID: 1203104)
• Arsenic
• Selenium
• Thallium
• Vanadium
• MSD (Lab ID: 1203105)
• Arsenic
• Lead
• Selenium
• Thallium
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 17 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 �Q%yfte. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15040671
Pace Project No.: 92247383
Method: EPA 6020
Description: 6020 MET ICPMS
Client: Duke Energy
Date: June 15, 2015
Analyte Comments:
QC Batch: MPRP/23951
N2: The lab does not hold TNI accreditation for this parameter.
•2015012320 (Lab ID:92247383002)
• Antimony
•2015012322 (Lab ID:92247383004)
• Antimony
•2015012324 (Lab ID:92247383006)
• Antimony
•2015012325 (Lab ID:92247383007)
• Antimony
•2015012326 (Lab ID:92247383008)
• Antimony
•2015012327 (Lab ID:92247383009)
• Antimony
•2015012328 (Lab ID:92247383010)
• Antimony
•2015012329 (Lab ID:92247383011)
• Antimony
• BLANK (Lab ID: 1203102)
• Antimony
• LCS (Lab ID: 1203103)
• Antimony
• MS (Lab ID: 1203104)
• Antimony
• MSD (Lab ID: 1203105)
• Antimony
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 18 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 K�c&) �e. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15040671
Pace Project No.: 92247383
Method: EPA 6020A
Description: 6020A MET ICPMS
Client: Duke Energy
Date: June 15, 2015
General Information:
7 samples were analyzed for EPA 6020A. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 3020 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: MPRP/54700
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92251147009
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1977700)
• Boron
• MSD (Lab ID: 1977701)
• Boron
QC Batch: MPRP/54062
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92247374001
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1953030)
• Aluminum
• MSD (Lab ID: 1953031)
• Aluminum
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 19 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 1�4c8y ft.. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15040671
Pace Project No.: 92247383
Method: EPA 7470A
Description: 7470A Mercury
Client: Duke Energy
Date: June 15, 2015
General Information:
7 samples were analyzed for EPA 7470A. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 7470A with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 20 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kai %yfte. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15040671
Pace Project No.: 92247383
Method: EPA 7471
Description: 7471 Mercury
Client: Duke Energy
Date: June 15, 2015
General Information:
8 samples were analyzed for EPA 7471. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 7471 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: MERP/5678
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92247232001
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1203120)
• Mercury
• MSD (Lab ID: 1203121)
• Mercury
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 21 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kai %yft.. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15040671
Pace Project No.: 92247383
Method: EPA 9045
Description: 9045 pH Soil
Client: Duke Energy
Date: June 15, 2015
General Information:
8 samples were analyzed for EPA 9045. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
QC Batch: WET/37120
D6: The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits.
• DUP (Lab ID: 1445735)
• pH at 25 Degrees C
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 22 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 K�c&� �e. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15040671
Pace Project No.: 92247383
Method: EPA 300.0
Description: 300.0 IC Anions, SPLP
Client: Duke Energy
Date: June 15, 2015
General Information:
4 samples were analyzed for EPA 300.0. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
QC Batch: WETA/22924
B: Analyte was detected in the associated method blank.
• BLANK for HBN 263861 [WETA/229 (Lab ID: 1459398)
• Sulfate
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: WETA/22924
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92247374003,92247911005
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1459402)
• Sulfate
• MSD (Lab ID: 1459403)
• Sulfate
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc.. Page 23 of 82

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PROJECT NARRATIVE
Project: J15040671
Pace Project No.: 92247383
Method: EPA 353.2
Description: 353.2 Nitrogen, NO2/NO3, SPLP
Client: Duke Energy
Date: June 15, 2015
General Information:
4 samples were analyzed for EPA 353.2. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
1-11: Analysis conducted outside the EPA method holding time.
•2015012325 (Lab ID:92247383007)
•2015012326 (Lab ID:92247383008)
•2015012328 (Lab ID:92247383010)
•2015012329 (Lab ID:92247383011)
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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PROJECT NARRATIVE
Project: J15040671
Pace Project No.: 92247383
Method: SM 4500-CI-E
Description: 4500 Chloride, SPLP
Client: Duke Energy
Date: June 15, 2015
General Information:
4 samples were analyzed for SM 4500-CI-E. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 25 of 82

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PROJECT NARRATIVE
Project: J15040671
Pace Project No.: 92247383
Method: EPA 9056
Description: 9056 IC Anions
Client: Duke Energy
Date: June 15, 2015
General Information:
8 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
Analyte Comments:
QC Batch: WETA/46021
DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
•2015012320 (Lab ID:92247383002)
• Chloride
• Sulfate
•2015012322 (Lab ID:92247383004)
• Chloride
• Sulfate
•2015012324 (Lab ID:92247383006)
• Chloride
• Sulfate
QC Batch: WETA/46023
DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
•2015012325 (Lab ID:92247383007)
• Chloride
• Sulfate
•2015012326 (Lab ID:92247383008)
• Chloride
• Sulfate
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 26 of 82

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PROJECT NARRATIVE
Project: J15040671
Pace Project No.: 92247383
Method: EPA 9056
Description: 9056 IC Anions
Client: Duke Energy
Date: June 15, 2015
Analyte Comments:
QC Batch: WETA/46023
DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
•2015012327 (Lab ID:92247383009)
• Chloride
• Sulfate
•2015012328 (Lab ID:92247383010)
• Chloride
• Sulfate
•2015012329 (Lab ID:92247383011)
• Chloride
• Sulfate
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 27 of 82

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PROJECT NARRATIVE
Project: J15040671
Pace Project No.: 92247383
Method: EPA 9056
Description: 9056 IC Anions 48hr
Client: Duke Energy
Date: June 15, 2015
General Information:
8 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
1-13: Sample was received or analysis requested beyond the recognized method holding time.
•2015012320 (Lab ID:92247383002)
•2015012322 (Lab ID:92247383004)
•2015012324 (Lab ID:92247383006)
•2015012325 (Lab ID:92247383007)
•2015012326 (Lab ID:92247383008)
•2015012327 (Lab ID:92247383009)
•2015012328 (Lab ID:92247383010)
•2015012329 (Lab ID:92247383011)
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc.. Page 28 of 82

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PROJECT NARRATIVE
Project: J15040671
Pace Project No.: 92247383
Method: EPA 9060
Description: Total Organic Carbon Quad
Client: Duke Energy
Date: June 15, 2015
General Information:
8 samples were analyzed for EPA 9060. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc.. Page 29 of 82

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ANALYTICAL RESULTS
Project: J15040671
Pace Project No.: 92247383
Sample: 2015012319 Lab ID: 92247383001 Collected: 04/23/15 12:15 Received: 04/28/15 14:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
;I➢ZI7c\�i,I=11 l[99�� 6?
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Sodium
Strontium
Thallium
Vanadium
Zinc
7470A Mercury
Mercury
Date: 06/15/2015 07:24 AM
Analytical Method: EPA 6020A Preparation Method: EPA 3020
7.6J
ug/L
10.0
3.0
1
05/01/15 11:28
05/06/15 09:10
7429-90-5
ND
ug/L
0.50
0.15
1
05/01/15 11:28
05/05/15 14:46
7440-36-0
ND
ug/L
0.50
0.11
1
05/01/15 11:28
05/05/15 14:46
7440-38-2
0.22J
ug/L
0.30
0.081
1
05/01/15 11:28
05/05/15 14:46
7440-39-3
ND
ug/L
0.20
0.067
1
05/01/15 11:28
05/05/15 14:46
7440-41-7
ND
ug/L
5.0
1.1
1
05/01/15 11:28
05/05/15 14:46
7440-42-8
ND
ug/L
0.080
0.024
1
05/01/15 11:28
05/05/15 14:46
7440-43-9
68.7
ug/L
40.0
16.0
1
05/01/15 11:28
05/05/15 14:46
7440-70-2
1.3
ug/L
0.50
0.17
1
05/01/15 11:28
05/05/15 14:46
7440-47-3
0.50J
ug/L
0.50
0.13
1
05/01/15 11:28
05/05/15 14:46
7440-48-4
0.74J
ug/L
1.0
0.21
1
05/01/15 11:28
05/05/15 14:46
7440-50-8
166
ug/L
50.0
13.7
1
05/01/15 11:28
05/05/15 14:46
7439-89-6
ND
ug/L
0.10
0.046
1
05/01/15 11:28
05/05/15 14:46
7439-92-1
19.0
ug/L
10.0
3.2
1
05/01/15 11:28
05/05/15 14:46
7439-95-4
2.7
ug/L
0.50
0.24
1
05/01/15 11:28
05/05/15 14:46
7439-96-5
0.32J
ug/L
0.50
0.094
1
05/01/15 11:28
05/05/15 14:46
7439-98-7
0.36J
ug/L
0.50
0.16
1
05/01/15 11:28
05/05/15 14:46
7440-02-0
ND
ug/L
50.0
11.7
1
05/01/15 11:28
05/05/15 14:46
7440-09-7
ND
ug/L
0.50
0.20
1
05/01/15 11:28
05/05/15 14:46
7782-49-2
ND
ug/L
50.0
16.3
1
05/01/15 11:28
05/05/15 14:46
7440-23-5
0.26J
ug/L
0.50
0.13
1
05/01/15 11:28
05/05/15 14:46
7440-24-6
ND
ug/L
0.10
0.015
1
05/01/15 11:28
05/05/15 14:46
7440-28-0
ND
ug/L
1.0
0.28
1
05/01/15 11:28
05/05/15 14:46
7440-62-2
4.9J
ug/L
5.0
2.4
1
05/01/15 11:28
05/05/15 14:46
7440-66-6
Analytical Method: EPA 7470A Preparation Method: EPA 7470A
ND ug/L 0.20 0.022 1 05/01/15 21:15 05/04/15 16:40 7439-97-6
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: J15040671
Pace Project No.: 92247383
Sample: 2015012320
Lab ID:
92247383002 Collected:
04/23/15 12:30
Received: 04/28/15 14:30 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample
size and any dilutions.
Report
Parameters
Results
Units Limit
MDL
DF
Prepared
Analyzed
CAS No.
Qual
6010 MET ICP
Analytical
Method: EPA 6010
Preparation
Method: EPA
3050
Aluminum
3080
mg/kg
25.5
12.8
5
05/06/1513:50
05/07/1510:38
7429-90-5
Barium
21.5
mg/kg
2.6
1.3
5
05/06/1513:50
05/07/1510:38
7440-39-3
Beryllium
0.29
mg/kg
0.26
0.13
5
05/06/1513:50
05/07/1510:38
7440-41-7
Boron
ND
mg/kg
12.8
6.4
5
05/06/1513:50
05/07/1510:38
7440-42-8
Calcium
68.5J
mg/kg
128
63.8
5
05/06/1513:50
05/07/1510:38
7440-70-2
Chromium
4.1
mg/kg
1.3
0.64
5
05/06/1513:50
05/07/1510:38
7440-47-3
Copper
7.0
mg/kg
1.3
0.64
5
05/06/1513:50
05/07/1510:38
7440-50-8
Iron
7320
mg/kg
10.2
5.1
5
05/06/1513:50
05/07/1510:38
7439-89-6
Magnesium
437
mg/kg
128
63.8
5
05/06/1513:50
05/07/1510:38
7439-95-4
Manganese
27.7
mg/kg
1.3
0.64
5
05/06/1513:50
05/07/1510:38
7439-96-5
Molybdenum
ND
mg/kg
2.6
1.3
5
05/06/1513:50
05/07/1510:38
7439-98-7
Nickel
0.68J
mg/kg
1.3
0.64
5
05/06/1513:50
05/07/1510:38
7440-02-0
Potassium
315
mg/kg
255
128
5
05/06/1513:50
05/07/1510:38
7440-09-7
Sodium
ND
mg/kg
255
128
5
05/06/1513:50
05/07/1510:38
7440-23-5
Strontium
2.OJ
mg/kg
2.6
1.3
5
05/06/1513:50
05/07/1510:38
7440-24-6
Zinc
7.0
mg/kg
5.1
2.6
5
05/06/1513:50
05/07/1510:38
7440-66-6
6020 MET ICPMS
Analytical
Method: EPA 6020
Preparation
Method: EPA
3050
Antimony
ND
mg/kg
5.1
2.6
100
05/06/1513:50
05/06/1517:54
7440-36-0
N2
Arsenic
ND
mg/kg
5.1
2.6
100
05/06/1513:50
05/06/1517:54
7440-38-2
Cadmium
ND
mg/kg
0.61
0.31
100
05/06/1513:50
05/06/1517:54
7440-43-9
Cobalt
ND
mg/kg
5.1
2.6
100
05/06/1513:50
05/06/1517:54
7440-48-4
Lead
5.4
mg/kg
5.1
2.6
100
05/06/1513:50
05/06/1517:54
7439-92-1
Selenium
ND
mg/kg
5.1
2.6
100
05/06/1513:50
05/06/1517:54
7782-49-2
Thallium
ND
mg/kg
5.1
2.6
100
05/06/1513:50
05/06/1517:54
7440-28-0
Vanadium
12.8
mg/kg
5.1
2.6
100
05/06/1513:50
05/06/1517:54
7440-62-2
7471 Mercury
Analytical
Method: EPA 7471
Preparation
Method: EPA
7471
Mercury
0.0073J
mg/kg 0.0086
0.0043
1
05/06/1513:45
05/07/1513:57
7439-97-6
Percent Moisture
Analytical
Method: ASTM D2974-87
Percent Moisture
2.8
%
0.10
0.10
1
05/13/15 10:29
9045 pH Soil
Analytical
Method: EPA 9045
pH at 25 Degrees C
5.6
Std. Units
0.10
0.10
1
04/29/15 14:50
9056 IC Anions
Analytical
Method: EPA 9056
Chloride
ND
mg/kg
257
129
5
05/03/15 03:18
16887-00-6
D3
Sulfate
ND
mg/kg
257
129
5
05/03/15 03:18
14808-79-8
D3
9056 IC Anions 48hr
Analytical
Method: EPA 9056
Nitrate as N
ND
mg/kg
25.7
12.9
5
05/03/15 03:18
14797-55-8
H3
Date: 06/15/2015 07:24 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 31 of 82

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[phone]
ANALYTICAL RESULTS
Project: J15040671
Pace Project No.: 92247383
Sample: 2015012320
Lab ID:
92247383002
Collected:
04/23/15 12:30
Received: 04/28/15 14:30 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample
size and any dilutions.
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared Analyzed
CAS No. Qual
Total Organic Carbon Quad
Analytical
Method: EPA 9060
Total Organic Carbon
485J
mg/kg
613
307
1
05/18/15 09:33
7440-44-0
Total Organic Carbon
418J
mg/kg
618
309
1
05/18/15 09:38
7440-44-0
Total Organic Carbon
383J
mg/kg
612
306
1
05/18/15 09:45
7440-44-0
Total Organic Carbon
394J
mg/kg
623
311
1
05/18/15 09:51
7440-44-0
Mean Total Organic Carbon
420J
mg/kg
617
308
1
05/18/15 09:33
7440-44-0
Surrogates
RSD%
10.8
%
1
05/18/15 09:33
Date: 06/15/2015 07:24 AM
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
Page 32 of 82

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Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040671
Pace Project No.: 92247383
Sample: 2015012321 Lab ID: 92247383003 Collected: 04/26/15 15:30 Received: 04/28/15 14:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
;I➢ZI7c\�i,I=11 l[99�� 6?
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Sodium
Strontium
Thallium
Vanadium
Zinc
7470A Mercury
Mercury
Date: 06/15/2015 07:24 AM
Analytical Method: EPA 6020A Preparation Method: EPA 3020
64.1
ug/L
10.0
3.0
1
05/01/15 11:28
05/06/15 09:52
7429-90-5
ND
ug/L
0.50
0.15
1
05/01/15 11:28
05/05/15 14:51
7440-36-0
ND
ug/L
0.50
0.11
1
05/01/15 11:28
05/05/15 14:51
7440-38-2
1.1
ug/L
0.30
0.081
1
05/01/15 11:28
05/05/15 14:51
7440-39-3
ND
ug/L
0.20
0.067
1
05/01/15 11:28
05/05/15 14:51
7440-41-7
7.3
ug/L
5.0
1.1
1
05/01/15 11:28
05/05/15 14:51
7440-42-8
ND
ug/L
0.080
0.024
1
05/01/15 11:28
05/05/15 14:51
7440-43-9
971
ug/L
40.0
16.0
1
05/01/15 11:28
05/05/15 14:51
7440-70-2
1.8
ug/L
0.50
0.17
1
05/01/15 11:28
05/05/15 14:51
7440-47-3
7.6
ug/L
0.50
0.13
1
05/01/15 11:28
05/05/15 14:51
7440-48-4
1.3
ug/L
1.0
0.21
1
05/01/15 11:28
05/05/15 14:51
7440-50-8
663
ug/L
50.0
13.7
1
05/01/15 11:28
05/05/15 14:51
7439-89-6
0.38
ug/L
0.10
0.046
1
05/01/15 11:28
05/05/15 14:51
7439-92-1
39.8
ug/L
10.0
3.2
1
05/01/15 11:28
05/05/15 14:51
7439-95-4
14.3
ug/L
0.50
0.24
1
05/01/15 11:28
05/05/15 14:51
7439-96-5
0.21J
ug/L
0.50
0.094
1
05/01/15 11:28
05/05/15 14:51
7439-98-7
0.68
ug/L
0.50
0.16
1
05/01/15 11:28
05/05/15 14:51
7440-02-0
22.OJ
ug/L
50.0
11.7
1
05/01/15 11:28
05/05/15 14:51
7440-09-7
ND
ug/L
0.50
0.20
1
05/01/15 11:28
05/05/15 14:51
7782-49-2
20.OJ
ug/L
50.0
16.3
1
05/01/15 11:28
05/05/15 14:51
7440-23-5
1.7
ug/L
0.50
0.13
1
05/01/15 11:28
05/05/15 14:51
7440-24-6
ND
ug/L
0.10
0.015
1
05/01/15 11:28
05/05/15 14:51
7440-28-0
ND
ug/L
1.0
0.28
1
05/01/15 11:28
05/05/15 14:51
7440-62-2
9.0
ug/L
5.0
2.4
1
05/01/15 11:28
05/05/15 14:51
7440-66-6
Analytical Method: EPA 7470A Preparation Method: EPA 7470A
ND ug/L 0.20 0.022 1 05/01/15 21:15 05/04/15 16:43 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 33 of 82

aceAnaiXical
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Pace Analytical Services, Inc.
9800 %%Yft.. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040671
Pace Project No.: 92247383
Sample: 2015012322
Lab ID:
92247383004 Collected:
04/26/15 15:45
Received: 04/28/15 14:30 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample
size and any dilutions.
Report
Parameters
Results
Units Limit
MDL
DF
Prepared
Analyzed
CAS No.
Qual
6010 MET ICP
Analytical
Method: EPA 6010
Preparation
Method: EPA
3050
Aluminum
11000
mg/kg
29.9
15.0
5
05/06/1513:50
05/07/1510:42
7429-90-5
Barium
19.6
mg/kg
3.0
1.5
5
05/06/1513:50
05/07/1510:42
7440-39-3
Beryllium
ND
mg/kg
0.30
0.15
5
05/06/1513:50
05/07/1510:42
7440-41-7
Boron
27.4
mg/kg
15.0
7.5
5
05/06/1513:50
05/07/1510:42
7440-42-8
Calcium
ND
mg/kg
150
74.8
5
05/06/1513:50
05/07/1510:42
7440-70-2
Chromium
43.6
mg/kg
1.5
0.75
5
05/06/1513:50
05/07/1510:42
7440-47-3
Copper
12.4
mg/kg
1.5
0.75
5
05/06/1513:50
05/07/1510:42
7440-50-8
Iron
31200
mg/kg
12.0
6.0
5
05/06/1513:50
05/07/1510:42
7439-89-6
Magnesium
139J
mg/kg
150
74.8
5
05/06/1513:50
05/07/1510:42
7439-95-4
Manganese
22.1
mg/kg
1.5
0.75
5
05/06/1513:50
05/07/1510:42
7439-96-5
Molybdenum
ND
mg/kg
3.0
1.5
5
05/06/1513:50
05/07/1510:42
7439-98-7
Nickel
0.83J
mg/kg
1.5
0.75
5
05/06/1513:50
05/07/1510:42
7440-02-0
Potassium
182J
mg/kg
299
150
5
05/06/1513:50
05/07/1510:42
7440-09-7
Sodium
ND
mg/kg
299
150
5
05/06/1513:50
05/07/1510:42
7440-23-5
Strontium
ND
mg/kg
3.0
1.5
5
05/06/1513:50
05/07/1510:42
7440-24-6
Zinc
5.2J
mg/kg
6.0
3.0
5
05/06/1513:50
05/07/1510:42
7440-66-6
6020 MET ICPMS
Analytical
Method: EPA 6020
Preparation
Method: EPA
3050
Antimony
ND
mg/kg
6.0
3.0
100
05/06/1513:50
05/06/1517:56
7440-36-0
N2
Arsenic
3.6J
mg/kg
6.0
3.0
100
05/06/1513:50
05/06/1517:56
7440-38-2
Cadmium
ND
mg/kg
0.72
0.36
100
05/06/1513:50
05/06/1517:56
7440-43-9
Cobalt
ND
mg/kg
6.0
3.0
100
05/06/1513:50
05/06/1517:56
7440-48-4
Lead
6.8
mg/kg
6.0
3.0
100
05/06/1513:50
05/06/1517:56
7439-92-1
Selenium
ND
mg/kg
6.0
3.0
100
05/06/1513:50
05/06/1517:56
7782-49-2
Thallium
ND
mg/kg
6.0
3.0
100
05/06/1513:50
05/06/1517:56
7440-28-0
Vanadium
61.0
mg/kg
6.0
3.0
100
05/06/1513:50
05/06/1517:56
7440-62-2
7471 Mercury
Analytical
Method: EPA 7471
Preparation
Method: EPA
7471
Mercury
0.036
mg/kg 0.0093
0.0046
1
05/06/1513:45
05/07/1513:59
7439-97-6
Percent Moisture
Analytical
Method: ASTM D2974-87
Percent Moisture
17.5
%
0.10
0.10
1
05/13/15 10:29
9045 pH Soil
Analytical
Method: EPA 9045
pH at 25 Degrees C
4.9
Std. Units
0.10
0.10
1
04/29/15 14:50
9056 IC Anions
Analytical
Method: EPA 9056
Chloride
ND
mg/kg
302
151
5
05/03/15 03:39
16887-00-6
D3
Sulfate
ND
mg/kg
302
151
5
05/03/15 03:39
14808-79-8
D3
9056 IC Anions 48hr
Analytical
Method: EPA 9056
Nitrate as N
ND
mg/kg
30.2
15.1
5
05/03/15 03:39
14797-55-8
H3
Date: 06/15/2015 07:24 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 34 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 %%yft.. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040671
Pace Project No.: 92247383
Sample: 2015012322
Lab ID:
92247383004
Collected:
04/26/15 15:45
Received: 04/28/15 14:30 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample
size and any dilutions.
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared Analyzed
CAS No. Qual
Total Organic Carbon Quad
Analytical
Method: EPA 9060
Total Organic Carbon
848
mg/kg
724
362
1
05/20/15 11:04
7440-44-0
Total Organic Carbon
979
mg/kg
725
363
1
05/20/15 11:10
7440-44-0
Total Organic Carbon
1460
mg/kg
730
365
1
05/20/15 11:16
7440-44-0
Total Organic Carbon
1170
mg/kg
726
363
1
05/20/15 11:23
7440-44-0
Mean Total Organic Carbon
1110
mg/kg
726
363
1
05/20/15 11:04
7440-44-0
Surrogates
RSD%
23.7
%
1
05/20/15 11:04
Date: 06/15/2015 07:24 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 35 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Iji %Yfte. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040671
Pace Project No.: 92247383
Sample: 2015012323 Lab ID: 92247383005 Collected: 04/25/15 13:40 Received: 04/28/15 14:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
;I➢ZI7c\��,I=11a
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Sodium
Strontium
Thallium
Vanadium
Zinc
7470A Mercury
Mercury
Date: 06/15/2015 07:24 AM
Analytical Method: EPA 6020A Preparation Method: EPA 3020
13.5
ug/L
10.0
3.0
1
05/01/15 11:28
05/06/15 09:57
7429-90-5
ND
ug/L
0.50
0.15
1
05/01/15 11:28
05/05/15 14:56
7440-36-0
ND
ug/L
0.50
0.11
1
05/01/15 11:28
05/05/15 14:56
7440-38-2
0.30
ug/L
0.30
0.081
1
05/01/15 11:28
05/05/15 14:56
7440-39-3
ND
ug/L
0.20
0.067
1
05/01/15 11:28
05/05/15 14:56
7440-41-7
ND
ug/L
5.0
1.1
1
05/01/15 11:28
05/05/15 14:56
7440-42-8
ND
ug/L
0.080
0.024
1
05/01/15 11:28
05/05/15 14:56
7440-43-9
65.9
ug/L
40.0
16.0
1
05/01/15 11:28
05/05/15 14:56
7440-70-2
0.58
ug/L
0.50
0.17
1
05/01/15 11:28
05/05/15 14:56
7440-47-3
1.0
ug/L
0.50
0.13
1
05/01/15 11:28
05/05/15 14:56
7440-48-4
0.44J
ug/L
1.0
0.21
1
05/01/15 11:28
05/05/15 14:56
7440-50-8
96.7
ug/L
50.0
13.7
1
05/01/15 11:28
05/05/15 14:56
7439-89-6
ND
ug/L
0.10
0.046
1
05/01/15 11:28
05/05/15 14:56
7439-92-1
14.2
ug/L
10.0
3.2
1
05/01/15 11:28
05/05/15 14:56
7439-95-4
1.7
ug/L
0.50
0.24
1
05/01/15 11:28
05/05/15 14:56
7439-96-5
0.14J
ug/L
0.50
0.094
1
05/01/15 11:28
05/05/15 14:56
7439-98-7
ND
ug/L
0.50
0.16
1
05/01/15 11:28
05/05/15 14:56
7440-02-0
ND
ug/L
50.0
11.7
1
05/01/15 11:28
05/05/15 14:56
7440-09-7
ND
ug/L
0.50
0.20
1
05/01/15 11:28
05/05/15 14:56
7782-49-2
ND
ug/L
50.0
16.3
1
05/01/15 11:28
05/05/15 14:56
7440-23-5
0.15J
ug/L
0.50
0.13
1
05/01/15 11:28
05/05/15 14:56
7440-24-6
ND
ug/L
0.10
0.015
1
05/01/15 11:28
05/05/15 14:56
7440-28-0
ND
ug/L
1.0
0.28
1
05/01/15 11:28
05/05/15 14:56
7440-62-2
ND
ug/L
5.0
2.4
1
05/01/15 11:28
05/05/15 14:56
7440-66-6
Analytical Method: EPA 7470A Preparation Method: EPA 7470A
ND ug/L 0.20 0.022 1 05/01/15 21:15 05/04/15 16:45 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 36 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 1jin%yft.. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040671
Pace Project No.: 92247383
Sample: 2015012324
Lab ID:
92247383006 Collected:
04/25/15 14:10
Received: 04/28/15 14:30 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample
size and any dilutions.
Report
Parameters
Results
Units Limit
MDL
DF
Prepared
Analyzed
CAS No.
Qual
6010 MET ICP
Analytical
Method: EPA 6010
Preparation
Method: EPA
3050
Aluminum
5360
mg/kg
32.4
16.2
5
05/06/1513:50
05/07/1510:59
7429-90-5
Barium
95.4
mg/kg
3.2
1.6
5
05/06/1513:50
05/07/1510:59
7440-39-3
Beryllium
0.40
mg/kg
0.32
0.16
5
05/06/1513:50
05/07/1510:59
7440-41-7
Boron
ND
mg/kg
16.2
8.1
5
05/06/1513:50
05/07/1510:59
7440-42-8
Calcium
253
mg/kg
162
80.9
5
05/06/1513:50
05/07/1510:59
7440-70-2
Chromium
7.6
mg/kg
1.6
0.81
5
05/06/1513:50
05/07/1510:59
7440-47-3
Copper
4.3
mg/kg
1.6
0.81
5
05/06/1513:50
05/07/1510:59
7440-50-8
Iron
7710
mg/kg
12.9
6.5
5
05/06/1513:50
05/07/1510:59
7439-89-6
Magnesium
454
mg/kg
162
80.9
5
05/06/1513:50
05/07/1510:59
7439-95-4
Manganese
1250
mg/kg
1.6
0.81
5
05/06/1513:50
05/07/1510:59
7439-96-5
Molybdenum
ND
mg/kg
3.2
1.6
5
05/06/1513:50
05/07/1510:59
7439-98-7
Nickel
1.9
mg/kg
1.6
0.81
5
05/06/1513:50
05/07/1510:59
7440-02-0
Potassium
254J
mg/kg
324
162
5
05/06/1513:50
05/07/1510:59
7440-09-7
Sodium
ND
mg/kg
324
162
5
05/06/1513:50
05/07/1510:59
7440-23-5
Strontium
3.2J
mg/kg
3.2
1.6
5
05/06/1513:50
05/07/1510:59
7440-24-6
Zinc
10.4
mg/kg
6.5
3.2
5
05/06/1513:50
05/07/1510:59
7440-66-6
6020 MET ICPMS
Analytical
Method: EPA 6020
Preparation
Method: EPA
3050
Antimony
ND
mg/kg
6.5
3.2
100
05/06/1513:50
05/06/1518:06
7440-36-0
N2
Arsenic
ND
mg/kg
6.5
3.2
100
05/06/1513:50
05/06/1518:06
7440-38-2
Cadmium
ND
mg/kg
0.78
0.39
100
05/06/1513:50
05/06/1518:06
7440-43-9
Cobalt
6.OJ
mg/kg
6.5
3.2
100
05/06/1513:50
05/06/1518:06
7440-48-4
Lead
6.3J
mg/kg
6.5
3.2
100
05/06/1513:50
05/06/1518:06
7439-92-1
Selenium
ND
mg/kg
6.5
3.2
100
05/06/1513:50
05/06/1518:06
7782-49-2
Thallium
ND
mg/kg
6.5
3.2
100
05/06/1513:50
05/06/1518:06
7440-28-0
Vanadium
17.3
mg/kg
6.5
3.2
100
05/06/1513:50
05/06/1518:06
7440-62-2
7471 Mercury
Analytical
Method: EPA 7471
Preparation
Method: EPA
7471
Mercury
0.012
mg/kg
0.011
0.0055
1
05/06/1513:45
05/07/1514:02
7439-97-6
Percent Moisture
Analytical
Method: ASTM D2974-87
Percent Moisture
24.9
%
0.10
0.10
1
05/13/15 10:29
9045 pH Soil
Analytical
Method: EPA 9045
pH at 25 Degrees C
5.1
Std. Units
0.10
0.10
1
04/29/15 14:50
9056 IC Anions
Analytical
Method: EPA 9056
Chloride
ND
mg/kg
333
166
5
05/03/15 04:00
16887-00-6
D3
Sulfate
ND
mg/kg
333
166
5
05/03/15 04:00
14808-79-8
D3
9056 IC Anions 48hr
Analytical
Method: EPA 9056
Nitrate as N
ND
mg/kg
33.3
16.6
5
05/03/15 04:00
14797-55-8
H3
Date: 06/15/2015 07:24 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 37 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 IjiQ%yft.. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040671
Pace Project No.: 92247383
Sample: 2015012324
Lab ID:
92247383006
Collected:
04/25/15 14:10
Received: 04/28/15 14:30 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample
size and any dilutions.
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared Analyzed
CAS No. Qual
Total Organic Carbon Quad
Analytical
Method: EPA 9060
Total Organic Carbon
2880
mg/kg
800
400
1
05/20/15 12:17
7440-44-0
Total Organic Carbon
3740
mg/kg
796
398
1
05/20/15 12:24
7440-44-0
Total Organic Carbon
3380
mg/kg
804
402
1
05/20/15 12:29
7440-44-0
Total Organic Carbon
3410
mg/kg
801
401
1
05/20/15 12:34
7440-44-0
Mean Total Organic Carbon
3350
mg/kg
800
400
1
05/20/15 12:17
7440-44-0
Surrogates
RSD%
10.6
%
1
05/20/15 12:17
Date: 06/15/2015 07:24 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 38 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 IjiS%yft.. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040671
Pace Project No.: 92247383
Sample: 2015012325 Lab ID: 92247383007 Collected: 04/25/15 17:30 Received: 04/28/15 14:30 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Aluminum
Barium
Beryllium
Boron
Calcium
Chromium
Copper
Iron
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Sodium
Strontium
Zinc
6020 MET ICPMS
Antimony
Arsenic
Cadmium
Cobalt
Lead
Selenium
Thallium
Vanadium
7471 Mercury
Mercury
Percent Moisture
Percent Moisture
9045 pH Soil
pH at 25 Degrees C
300.0 IC Anions, SPLP
Sulfate
353.2 Nitrogen, NO2/NO3, SPLP
Nitrogen, Nitrate
4500 Chloride, SPLP
Chloride
Date: 06/15/2015 07:24 AM
Analytical Method: EPA 6010 Preparation Method: EPA 3050
9030
mg/kg
37.6
18.8
5
05/06/1513:50
05/07/1511:04
7429-90-5
131
mg/kg
3.8
1.9
5
05/06/1513:50
05/07/1511:04
7440-39-3
0.36J
mg/kg
0.38
0.19
5
05/06/1513:50
05/07/1511:04
7440-41-7
16.8J
mg/kg
18.8
9.4
5
05/06/1513:50
05/07/1511:04
7440-42-8
4470
mg/kg
188
94.0
5
05/06/1513:50
05/07/1511:04
7440-70-2
9.2
mg/kg
1.9
0.94
5
05/06/1513:50
05/07/1511:04
7440-47-3
126
mg/kg
1.9
0.94
5
05/06/1513:50
05/07/1511:04
7440-50-8
19100
mg/kg
15.0
7.5
5
05/06/1513:50
05/07/1511:04
7439-89-6
5220
mg/kg
188
94.0
5
05/06/1513:50
05/07/1511:04
7439-95-4
1630
mg/kg
1.9
0.94
5
05/06/1513:50
05/07/1511:04
7439-96-5
2.9J
mg/kg
3.8
1.9
5
05/06/1513:50
05/07/1511:04
7439-98-7
2.9
mg/kg
1.9
0.94
5
05/06/1513:50
05/07/1511:04
7440-02-0
2890
mg/kg
376
188
5
05/06/1513:50
05/07/1511:04
7440-09-7
384
mg/kg
376
188
5
05/06/1513:50
05/07/1511:04
7440-23-5
37.5
mg/kg
3.8
1.9
5
05/06/1513:50
05/07/1511:04
7440-24-6
54.6
mg/kg
7.5
3.8
5
05/06/1513:50
05/07/1511:04
7440-66-6
Analytical
Method: EPA 6020 Preparation
Method: EPA 3050
ND
mg/kg
7.5
3.8
100
05/06/1513:50
05/06/1518:08
7440-36-0
ND
mg/kg
7.5
3.8
100
05/06/1513:50
05/06/1518:08
7440-38-2
ND
mg/kg
0.90
0.45
100
05/06/1513:50
05/06/1518:08
7440-43-9
12.0
mg/kg
7.5
3.8
100
05/06/1513:50
05/06/1518:08
7440-48-4
3.8J
mg/kg
7.5
3.8
100
05/06/1513:50
05/06/1518:08
7439-92-1
ND
mg/kg
7.5
3.8
100
05/06/1513:50
05/06/1518:08
7782-49-2
ND
mg/kg
7.5
3.8
100
05/06/1513:50
05/06/1518:08
7440-28-0
16.3
mg/kg
7.5
3.8
100
05/06/1513:50
05/06/1518:08
7440-62-2
Analytical Method: EPA 7471 Preparation Method: EPA 7471
ND mg/kg 0.012 0.0059 1 05/06/1513:45 05/07/1514:04 7439-97-6
Analytical Method: ASTM D2974-87
30.7 % 0.10 0.10 1 05/13/1510:30
Analytical Method: EPA 9045
8.1 Std. Units 0.10 0.10 1 04/29/15 14:50
N2
Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 05/07/15 03:30
5.4 mg/L 2.9 1.4 1 05/14/1519:29 14808-79-8 B
Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 05/07/15 03:30
ND mg/L 0.29 0.29 1 05/15/15 21:08 H1
Analytical Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 05/07/15 03:30
ND mg/L 7.2 3.6 1 05/14/15 05:50 16887-00-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 39 of 82

aceAnaiXical
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Pace Analytical Services, Inc.
9800 14,8y ft.. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040671
Pace Project No.: 92247383
Sample: 2015012325 Lab ID: 92247383007 Collected: 04/25/15 17:30 Received: 04/28/15 14:30 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
9056 IC Anions Analytical Method: EPA 9056
Chloride
ND mg/kg
359
179
5
05/03/15 05:47
16887-00-6 D3,M1
Sulfate
ND mg/kg
359
179
5
05/03/15 05:47
14808-79-8 D3
9056 IC Anions 48hr
Analytical Method: EPA 9056
Nitrate as N
ND mg/kg
35.9
17.9
5
05/03/15 05:47
14797-55-8 H3
Total Organic Carbon Quad
Analytical Method: EPA 9060
Total Organic Carbon
ND mg/kg
861
431
1
05/20/15 14:27
7440-44-0
Total Organic Carbon
ND mg/kg
871
435
1
05/20/15 14:33
7440-44-0
Total Organic Carbon
ND mg/kg
871
436
1
05/20/15 14:38
7440-44-0
Total Organic Carbon
ND mg/kg
864
432
1
05/20/15 14:44
7440-44-0
Mean Total Organic Carbon
ND mg/kg
867
433
1
05/20/15 14:27
7440-44-0
Surrogates
RSD%
3.0 %
1
05/20/15 14:27
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2015 07:24 AM without the written consent of Pace Analytical Services, Inc..
Page 40 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Ijig%yft.. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040671
Pace Project No.: 92247383
Sample: 2015012326 Lab ID: 92247383008 Collected: 04/26/15 09:00 Received: 04/28/15 14:30 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Aluminum
Barium
Beryllium
Boron
Calcium
Chromium
Copper
Iron
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Sodium
Strontium
Zinc
6020 MET ICPMS
Antimony
Arsenic
Cadmium
Cobalt
Lead
Selenium
Thallium
Vanadium
7471 Mercury
Mercury
Percent Moisture
Percent Moisture
9045 pH Soil
pH at 25 Degrees C
300.0 IC Anions, SPLP
Sulfate
353.2 Nitrogen, NO2/NO3, SPLP
Nitrogen, Nitrate
4500 Chloride, SPLP
Chloride
Date: 06/15/2015 07:24 AM
Analytical Method: EPA 6010 Preparation Method: EPA 3050
4860
mg/kg
25.0
12.5
5
05/06/1513:50
05/07/1511:08
7429-90-5
28.2
mg/kg
2.5
1.3
5
05/06/1513:50
05/07/1511:08
7440-39-3
0.20J
mg/kg
0.25
0.13
5
05/06/1513:50
05/07/1511:08
7440-41-7
10.0J
mg/kg
12.5
6.3
5
05/06/1513:50
05/07/1511:08
7440-42-8
2710
mg/kg
125
62.6
5
05/06/1513:50
05/07/1511:08
7440-70-2
2.1
mg/kg
1.3
0.63
5
05/06/1513:50
05/07/1511:08
7440-47-3
5.3
mg/kg
1.3
0.63
5
05/06/1513:50
05/07/1511:08
7440-50-8
10600
mg/kg
10.0
5.0
5
05/06/1513:50
05/07/1511:08
7439-89-6
3200
mg/kg
125
62.6
5
05/06/1513:50
05/07/1511:08
7439-95-4
885
mg/kg
1.3
0.63
5
05/06/1513:50
05/07/1511:08
7439-96-5
ND
mg/kg
2.5
1.3
5
05/06/1513:50
05/07/1511:08
7439-98-7
1.2J
mg/kg
1.3
0.63
5
05/06/1513:50
05/07/1511:08
7440-02-0
1390
mg/kg
250
125
5
05/06/1513:50
05/07/1511:08
7440-09-7
182J
mg/kg
250
125
5
05/06/1513:50
05/07/1511:08
7440-23-5
23.3
mg/kg
2.5
1.3
5
05/06/1513:50
05/07/1511:08
7440-24-6
35.6
mg/kg
5.0
2.5
5
05/06/1513:50
05/07/1511:08
7440-66-6
Analytical
Method: EPA 6020 Preparation
Method: EPA 3050
ND
mg/kg
5.0
2.5
100
05/06/1513:50
05/06/1518:11
7440-36-0
ND
mg/kg
5.0
2.5
100
05/06/1513:50
05/06/1518:11
7440-38-2
ND
mg/kg
0.60
0.30
100
05/06/1513:50
05/06/1518:11
7440-43-9
4.6J
mg/kg
5.0
2.5
100
05/06/1513:50
05/06/1518:11
7440-48-4
ND
mg/kg
5.0
2.5
100
05/06/1513:50
05/06/1518:11
7439-92-1
ND
mg/kg
5.0
2.5
100
05/06/1513:50
05/06/1518:11
7782-49-2
ND
mg/kg
5.0
2.5
100
05/06/1513:50
05/06/1518:11
7440-28-0
8.4
mg/kg
5.0
2.5
100
05/06/1513:50
05/06/1518:11
7440-62-2
Analytical Method: EPA 7471 Preparation Method: EPA 7471
ND mg/kg 0.0083 0.0042 1 05/06/1513:45 05/07/1514:06 7439-97-6
Analytical Method: ASTM D2974-87
2.4 % 0.10 0.10 1 05/13/1510:30
Analytical Method: EPA 9045
7.8 Std. Units 0.10 0.10 1 05/04/15 14:00
N2
Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 05/07/15 03:30
3.8 mg/L 2.0 1.0 1 05/14/1519:43 14808-79-8 B
Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 05/07/15 03:30
ND mg/L 0.20 0.20 1 05/15/15 21:09 H1
Analytical Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 05/07/15 03:30
ND mg/L 5.1 2.6 1 05/14/15 05:51 16887-00-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 41 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 16,8y ft.. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040671
Pace Project No.: 92247383
Sample: 2015012326 Lab ID: 92247383008 Collected: 04/26/15 09:00 Received: 04/28/15 14:30 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
9056 IC Anions Analytical Method: EPA 9056
Chloride
ND mg/kg
256
128
5
05/03/15 06:52
16887-00-6 D3
Sulfate
ND mg/kg
256
128
5
05/03/15 06:52
14808-79-8 D3
9056 IC Anions 48hr
Analytical Method: EPA 9056
Nitrate as N
ND mg/kg
25.6
12.8
5
05/03/15 06:52
14797-55-8 H3
Total Organic Carbon Quad
Analytical Method: EPA 9060
Total Organic Carbon
ND mg/kg
619
310
1
05/20/15 14:50
7440-44-0
Total Organic Carbon
ND mg/kg
619
309
1
05/20/15 14:56
7440-44-0
Total Organic Carbon
ND mg/kg
613
307
1
05/20/15 15:01
7440-44-0
Total Organic Carbon
ND mg/kg
613
306
1
05/20/15 15:07
7440-44-0
Mean Total Organic Carbon
ND mg/kg
616
308
1
05/20/15 14:50
7440-44-0
Surrogates
RSD%
2.7 %
1
05/20/15 14:50
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2015 07:24 AM without the written consent of Pace Analytical Services, Inc..
Page 42 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Iji ,8fft.. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040671
Pace Project No.: 92247383
Sample: 2015012327
Lab ID:
92247383009 Collected:
04/26/15 15:50
Received: 04/28/15 14:30 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample
size and any dilutions.
Report
Parameters
Results
Units Limit
MDL
DF
Prepared
Analyzed
CAS No.
Qual
6010 MET ICP
Analytical
Method: EPA 6010
Preparation
Method: EPA
3050
Aluminum
24500
mg/kg
25.8
12.9
5
05/06/1513:50
05/07/1511:12
7429-90-5
Barium
237
mg/kg
2.6
1.3
5
05/06/1513:50
05/07/1511:12
7440-39-3
Beryllium
0.40
mg/kg
0.26
0.13
5
05/06/1513:50
05/07/1511:12
7440-41-7
Boron
32.3
mg/kg
12.9
6.4
5
05/06/1513:50
05/07/1511:12
7440-42-8
Calcium
19400
mg/kg
129
64.4
5
05/06/1513:50
05/07/1511:12
7440-70-2
Chromium
37.2
mg/kg
1.3
0.64
5
05/06/1513:50
05/07/1511:12
7440-47-3
Copper
26.7
mg/kg
1.3
0.64
5
05/06/1513:50
05/07/1511:12
7440-50-8
Iron
38300
mg/kg
10.3
5.2
5
05/06/1513:50
05/07/1511:12
7439-89-6
Magnesium
21800
mg/kg
129
64.4
5
05/06/1513:50
05/07/1511:12
7439-95-4
Manganese
1010
mg/kg
1.3
0.64
5
05/06/1513:50
05/07/1511:12
7439-96-5
Molybdenum
ND
mg/kg
2.6
1.3
5
05/06/1513:50
05/07/1511:12
7439-98-7
Nickel
28.1
mg/kg
1.3
0.64
5
05/06/1513:50
05/07/1511:12
7440-02-0
Potassium
16600
mg/kg
258
129
5
05/06/1513:50
05/07/1511:12
7440-09-7
Sodium
261
mg/kg
258
129
5
05/06/1513:50
05/07/1511:12
7440-23-5
Strontium
40.0
mg/kg
2.6
1.3
5
05/06/1513:50
05/07/1511:12
7440-24-6
Zinc
101
mg/kg
5.2
2.6
5
05/06/1513:50
05/07/1511:12
7440-66-6
6020 MET ICPMS
Analytical
Method: EPA 6020
Preparation
Method: EPA
3050
Antimony
ND
mg/kg
5.2
2.6
100
05/06/1513:50
05/06/1518:13
7440-36-0
N2
Arsenic
ND
mg/kg
5.2
2.6
100
05/06/1513:50
05/06/1518:13
7440-38-2
Cadmium
ND
mg/kg
0.62
0.31
100
05/06/1513:50
05/06/1518:13
7440-43-9
Cobalt
19.6
mg/kg
5.2
2.6
100
05/06/1513:50
05/06/1518:13
7440-48-4
Lead
ND
mg/kg
5.2
2.6
100
05/06/1513:50
05/06/1518:13
7439-92-1
Selenium
ND
mg/kg
5.2
2.6
100
05/06/1513:50
05/06/1518:13
7782-49-2
Thallium
ND
mg/kg
5.2
2.6
100
05/06/1513:50
05/06/1518:13
7440-28-0
Vanadium
87.0
mg/kg
5.2
2.6
100
05/06/1513:50
05/06/1518:13
7440-62-2
7471 Mercury
Analytical
Method: EPA 7471
Preparation
Method: EPA
7471
Mercury
ND
mg/kg 0.0089
0.0044
1
05/06/1513:45
05/07/1514:08
7439-97-6
Percent Moisture
Analytical
Method: ASTM D2974-87
Percent Moisture
6.5
%
0.10
0.10
1
05/13/15 10:30
9045 pH Soil
Analytical
Method: EPA 9045
pH at 25 Degrees C
9.6
Std. Units
0.10
0.10
1
05/04/15 14:00
9056 IC Anions
Analytical
Method: EPA 9056
Chloride
ND
mg/kg
266
133
5
05/03/15 07:13
16887-00-6
D3
Sulfate
ND
mg/kg
266
133
5
05/03/15 07:13
14808-79-8
D3
9056 IC Anions 48hr
Analytical
Method: EPA 9056
Nitrate as N
ND
mg/kg
26.6
13.3
5
05/03/15 07:13
14797-55-8
H3
Date: 06/15/2015 07:24 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 43 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Iji %yft.. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040671
Pace Project No.: 92247383
Sample: 2015012327
Lab ID:
92247383009
Collected:
04/26/15 15:50
Received: 04/28/15 14:30 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample
size and any dilutions.
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared Analyzed
CAS No. Qual
Total Organic Carbon Quad
Analytical
Method: EPA 9060
Total Organic Carbon
ND
mg/kg
643
321
1
05/20/15 15:12
7440-44-0
Total Organic Carbon
ND
mg/kg
641
320
1
05/20/15 15:18
7440-44-0
Total Organic Carbon
ND
mg/kg
645
323
1
05/20/15 15:23
7440-44-0
Total Organic Carbon
ND
mg/kg
647
323
1
05/20/15 15:30
7440-44-0
Mean Total Organic Carbon
ND
mg/kg
644
322
1
05/20/15 15:12
7440-44-0
Surrogates
RSD%
12.2
%
1
05/20/15 15:12
Date: 06/15/2015 07:24 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 44 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Iji %Yft.. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040671
Pace Project No.: 92247383
Sample: 2015012328 Lab ID: 92247383010 Collected: 04/27/15 08:30 Received: 04/28/15 14:30 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Aluminum
Barium
Beryllium
Boron
Calcium
Chromium
Copper
Iron
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Sodium
Strontium
Zinc
6020 MET ICPMS
Antimony
Arsenic
Cadmium
Cobalt
Lead
Selenium
Thallium
Vanadium
7471 Mercury
Mercury
Percent Moisture
Percent Moisture
9045 pH Soil
pH at 25 Degrees C
300.0 IC Anions, SPLP
Sulfate
353.2 Nitrogen, NO2/NO3, SPLP
Nitrogen, Nitrate
4500 Chloride, SPLP
Chloride
Date: 06/15/2015 07:24 AM
Analytical Method: EPA 6010 Preparation Method: EPA 3050
3530
mg/kg
29.9
14.9
5
05/06/1513:50
05/07/1511:17
7429-90-5
67.4
mg/kg
3.0
1.5
5
05/06/1513:50
05/07/1511:17
7440-39-3
ND
mg/kg
0.30
0.15
5
05/06/1513:50
05/07/1511:17
7440-41-7
9.8J
mg/kg
14.9
7.5
5
05/06/1513:50
05/07/1511:17
7440-42-8
ND
mg/kg
149
74.7
5
05/06/1513:50
05/07/1511:17
7440-70-2
3.2
mg/kg
1.5
0.75
5
05/06/1513:50
05/07/1511:17
7440-47-3
22.4
mg/kg
1.5
0.75
5
05/06/1513:50
05/07/1511:17
7440-50-8
11900
mg/kg
12.0
6.0
5
05/06/1513:50
05/07/1511:17
7439-89-6
1190
mg/kg
149
74.7
5
05/06/1513:50
05/07/1511:17
7439-95-4
395
mg/kg
1.5
0.75
5
05/06/1513:50
05/07/1511:17
7439-96-5
ND
mg/kg
3.0
1.5
5
05/06/1513:50
05/07/1511:17
7439-98-7
ND
mg/kg
1.5
0.75
5
05/06/1513:50
05/07/1511:17
7440-02-0
1520
mg/kg
299
149
5
05/06/1513:50
05/07/1511:17
7440-09-7
ND
mg/kg
299
149
5
05/06/1513:50
05/07/1511:17
7440-23-5
ND
mg/kg
3.0
1.5
5
05/06/1513:50
05/07/1511:17
7440-24-6
15.0
mg/kg
6.0
3.0
5
05/06/1513:50
05/07/1511:17
7440-66-6
Analytical
Method: EPA 6020 Preparation
Method: EPA 3050
ND
mg/kg
6.0
3.0
100
05/06/1513:50
05/06/1518:15
7440-36-0 N2
ND
mg/kg
6.0
3.0
100
05/06/1513:50
05/06/1518:15
7440-38-2
ND
mg/kg
0.72
0.36
100
05/06/1513:50
05/06/1518:15
7440-43-9
6.0
mg/kg
6.0
3.0
100
05/06/1513:50
05/06/1518:15
7440-48-4
7.2
mg/kg
6.0
3.0
100
05/06/1513:50
05/06/1518:15
7439-92-1
ND
mg/kg
6.0
3.0
100
05/06/1513:50
05/06/1518:15
7782-49-2
ND
mg/kg
6.0
3.0
100
05/06/1513:50
05/06/1518:15
7440-28-0
8.2
mg/kg
6.0
3.0
100
05/06/1513:50
05/06/1518:15
7440-62-2
Analytical Method: EPA 7471 Preparation Method: EPA 7471
ND mg/kg 0.0095 0.0047 1 05/06/1513:45 05/07/1514:10 7439-97-6
Analytical Method: ASTM D2974-87
16.8 % 0.10 0.10 1 05/13/1510:30 D6
Analytical Method: EPA 9045
5.9 Std. Units 0.10 0.10 1 05/04/15 14:00
Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 05/07/15 03:30
3.1 mg/L 2.4 1.2 1 05/14/1519:56 14808-79-8 B
Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 05/07/15 03:30
0.25 mg/L 0.24 0.24 1 05/15/15 21:10 H1
Analytical Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 05/07/15 03:30
ND mg/L 6.0 3.0 1 05/14/15 05:52 16887-00-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 45 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 t 6,8y ft.. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040671
Pace Project No.: 92247383
Sample: 2015012328 Lab ID: 92247383010 Collected: 04/27/15 08:30 Received: 04/28/15 14:30 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
9056 IC Anions Analytical Method: EPA 9056
Chloride
ND mg/kg
301
150
5
05/03/15 07:34
16887-00-6 D3
Sulfate
ND mg/kg
301
150
5
05/03/15 07:34
14808-79-8 D3
9056 IC Anions 48hr
Analytical Method: EPA 9056
Nitrate as N
ND mg/kg
30.1
15.0
5
05/03/15 07:34
14797-55-8 H3
Total Organic Carbon Quad
Analytical Method: EPA 9060
Total Organic Carbon
ND mg/kg
723
362
1
05/20/15 15:35
7440-44-0
Total Organic Carbon
ND mg/kg
719
359
1
05/20/15 15:41
7440-44-0
Total Organic Carbon
ND mg/kg
724
362
1
05/20/15 15:48
7440-44-0
Total Organic Carbon
ND mg/kg
719
359
1
05/20/15 15:53
7440-44-0
Mean Total Organic Carbon
ND mg/kg
721
361
1
05/20/15 15:35
7440-44-0
Surrogates
RSD%
2.3 %
1
05/20/15 15:35
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2015 07:24 AM without the written consent of Pace Analytical Services, Inc..
Page 46 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 �n%yft.. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040671
Pace Project No.: 92247383
Sample: 2015012329 Lab ID: 92247383011 Collected: 04/27/15 08:45 Received: 04/28/15 14:30 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Aluminum
Barium
Beryllium
Boron
Calcium
Chromium
Copper
Iron
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Sodium
Strontium
Zinc
6020 MET ICPMS
Antimony
Arsenic
Cadmium
Cobalt
Lead
Selenium
Thallium
Vanadium
7471 Mercury
Mercury
Percent Moisture
Percent Moisture
9045 pH Soil
pH at 25 Degrees C
300.0 IC Anions, SPLP
Sulfate
353.2 Nitrogen, NO2/NO3, SPLP
Nitrogen, Nitrate
4500 Chloride, SPLP
Chloride
Date: 06/15/2015 07:24 AM
Analytical Method: EPA 6010 Preparation Method: EPA 3050
4410
mg/kg
31.3
15.6
5
05/06/1513:50
05/07/1511:21
7429-90-5
81.5
mg/kg
3.1
1.6
5
05/06/1513:50
05/07/1511:21
7440-39-3
0.25J
mg/kg
0.31
0.16
5
05/06/1513:50
05/07/1511:21
7440-41-7
9.2J
mg/kg
15.6
7.8
5
05/06/1513:50
05/07/1511:21
7440-42-8
ND
mg/kg
156
78.2
5
05/06/1513:50
05/07/1511:21
7440-70-2
1.9
mg/kg
1.6
0.78
5
05/06/1513:50
05/07/1511:21
7440-47-3
19.1
mg/kg
1.6
0.78
5
05/06/1513:50
05/07/1511:21
7440-50-8
10700
mg/kg
12.5
6.3
5
05/06/1513:50
05/07/1511:21
7439-89-6
1410
mg/kg
156
78.2
5
05/06/1513:50
05/07/1511:21
7439-95-4
855
mg/kg
1.6
0.78
5
05/06/1513:50
05/07/1511:21
7439-96-5
ND
mg/kg
3.1
1.6
5
05/06/1513:50
05/07/1511:21
7439-98-7
1.4J
mg/kg
1.6
0.78
5
05/06/1513:50
05/07/1511:21
7440-02-0
1680
mg/kg
313
156
5
05/06/1513:50
05/07/1511:21
7440-09-7
ND
mg/kg
313
156
5
05/06/1513:50
05/07/1511:21
7440-23-5
4.6
mg/kg
3.1
1.6
5
05/06/1513:50
05/07/1511:21
7440-24-6
27.7
mg/kg
6.3
3.1
5
05/06/1513:50
05/07/1511:21
7440-66-6
Analytical
Method: EPA 6020 Preparation
Method: EPA 3050
ND
mg/kg
6.3
3.1
100
05/06/1513:50
05/06/1518:18
7440-36-0
ND
mg/kg
6.3
3.1
100
05/06/1513:50
05/06/1518:18
7440-38-2
ND
mg/kg
0.75
0.38
100
05/06/1513:50
05/06/1518:18
7440-43-9
9.2
mg/kg
6.3
3.1
100
05/06/1513:50
05/06/1518:18
7440-48-4
9.2
mg/kg
6.3
3.1
100
05/06/1513:50
05/06/1518:18
7439-92-1
ND
mg/kg
6.3
3.1
100
05/06/1513:50
05/06/1518:18
7782-49-2
ND
mg/kg
6.3
3.1
100
05/06/1513:50
05/06/1518:18
7440-28-0
7.7
mg/kg
6.3
3.1
100
05/06/1513:50
05/06/1518:18
7440-62-2
Analytical Method: EPA 7471 Preparation Method: EPA 7471
ND mg/kg 0.010 0.0050 1 05/06/1513:45 05/07/1514:17 7439-97-6
Analytical Method: ASTM D2974-87
20.3 % 0.10 0.10 1 05/13/1510:30
Analytical Method: EPA 9045
5.5 Std. Units 0.10 0.10 1 05/04/15 14:00
N2
Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 05/08/15 03:30
3.4 mg/L 2.5 1.3 1 05/14/15 20:10 14808-79-8 B
Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 05/08/15 03:30
ND mg/L 0.25 0.25 1 05/15/15 21:11 H1
Analytical Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 05/08/15 03:30
ND mg/L 6.3 3.1 1 05/14/15 05:53 16887-00-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 47 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 �Q%yft.. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040671
Pace Project No.: 92247383
Sample: 2015012329 Lab ID: 92247383011 Collected: 04/27/15 08:45 Received: 04/28/15 14:30 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
9056 IC Anions Analytical Method: EPA 9056
Chloride
ND mg/kg
313
156
5
05/03/15 07:56
16887-00-6 D3
Sulfate
ND mg/kg
313
156
5
05/03/15 07:56
14808-79-8 D3
9056 IC Anions 48hr
Analytical Method: EPA 9056
Nitrate as N
ND mg/kg
31.3
15.6
5
05/03/15 07:56
14797-55-8 H3
Total Organic Carbon Quad
Analytical Method: EPA 9060
Total Organic Carbon
ND mg/kg
755
378
1
05/20/15 16:00
7440-44-0
Total Organic Carbon
ND mg/kg
748
374
1
05/20/15 16:06
7440-44-0
Total Organic Carbon
ND mg/kg
753
377
1
05/20/15 16:13
7440-44-0
Total Organic Carbon
ND mg/kg
753
377
1
05/20/15 16:19
7440-44-0
Mean Total Organic Carbon
ND mg/kg
753
376
1
05/20/15 16:00
7440-44-0
Surrogates
RSD%
1.8 %
1
05/20/15 16:00
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2015 07:24 AM without the written consent of Pace Analytical Services, Inc..
Page 48 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Disc yft.. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040671
Pace Project No.: 92247383
Sample: 2015012325 SPLP Lab ID: 92247383012 Collected: 04/25/15 17:30 Received: 04/28/15 14:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
;T➢Z17c\�iil=11 a
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Sodium
Strontium
Thallium
Vanadium
Zinc
7470A Mercury
Mercury
Date: 06/15/2015 07:24 AM
Analytical Method: EPA 6020A Preparation Method: EPA 3020
13200
ug/L
10.0
3.0
1
05/28/15 21:12
05/29/15 17:20
7429-90-5
ND
ug/L
0.50
0.15
1
05/28/15 21:12
05/29/15 17:20
7440-36-0
2.8
ug/L
0.50
0.11
1
05/28/15 21:12
05/29/15 17:20
7440-38-2
360
ug/L
0.30
0.081
1
05/28/15 21:12
05/29/15 17:20
7440-39-3
0.48
ug/L
0.20
0.067
1
05/28/15 21:12
05/29/15 17:20
7440-41-7
32.7
ug/L
5.0
1.1
1
05/28/15 21:12
05/29/15 17:20
7440-42-8
0.062J
ug/L
0.080
0.024
1
05/28/15 21:12
05/29/15 17:20
7440-43-9
3370
ug/L
40.0
16.0
1
05/28/15 21:12
05/29/15 17:20
7440-70-2
8.8
ug/L
0.50
0.17
1
05/28/15 21:12
05/29/15 17:20
7440-47-3
12.7
ug/L
0.50
0.13
1
05/28/15 21:12
05/29/15 17:20
7440-48-4
155
ug/L
1.0
0.21
1
05/28/15 21:12
05/29/15 17:20
7440-50-8
21000
ug/L
50.0
13.7
1
05/28/15 21:12
05/29/15 17:20
7439-89-6
5.6
ug/L
0.10
0.046
1
05/28/15 21:12
05/29/15 17:20
7439-92-1
4960
ug/L
10.0
3.2
1
05/28/15 21:12
05/29/15 17:20
7439-95-4
1990
ug/L
10.0
4.8
20
05/28/15 21:12
05/31/15 10:13
7439-96-5
10.9
ug/L
0.50
0.094
1
05/28/15 21:12
05/29/15 17:20
7439-98-7
4.2
ug/L
0.50
0.16
1
05/28/15 21:12
05/29/15 17:20
7440-02-0
3800
ug/L
50.0
11.7
1
05/28/15 21:12
05/29/15 17:20
7440-09-7
2.1
ug/L
0.50
0.20
1
05/28/15 21:12
05/29/15 17:20
7782-49-2
3900
ug/L
50.0
16.3
1
05/28/15 21:12
05/29/15 17:20
7440-23-5
47.0
ug/L
0.50
0.13
1
05/28/15 21:12
05/29/15 17:20
7440-24-6
0.045J
ug/L
0.10
0.015
1
05/28/15 21:12
05/29/15 17:20
7440-28-0
18.5
ug/L
1.0
0.28
1
05/28/15 21:12
05/29/15 17:20
7440-62-2
90.9
ug/L
5.0
2.4
1
05/28/15 21:12
05/29/15 17:20
7440-66-6
Analytical Method: EPA 7470A Preparation Method: EPA 7470A
ND ug/L 0.20 0.022 1 05/30/1510:30 06/01/1513:09 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 49 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 t 4'8y ft.. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040671
Pace Project No.: 92247383
Sample: 2015012326 SPLP Lab ID: 92247383013 Collected: 04/26/15 09:00 Received: 04/28/15 14:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
;T➢Z17c\�iil=11 a
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Sodium
Strontium
Thallium
Vanadium
Zinc
7470A Mercury
Mercury
Date: 06/15/2015 07:24 AM
Analytical Method: EPA 6020A Preparation Method: EPA 3020
4500
ug/L
10.0
3.0
1
05/28/15 21:12
05/29/15 17:25
7429-90-5
ND
ug/L
0.50
0.15
1
05/28/15 21:12
05/29/15 17:25
7440-36-0
0.191
ug/L
0.50
0.11
1
05/28/15 21:12
05/29/15 17:25
7440-38-2
126
ug/L
0.30
0.081
1
05/28/15 21:12
05/29/15 17:25
7440-39-3
0.181
ug/L
0.20
0.067
1
05/28/15 21:12
05/29/15 17:25
7440-41-7
30.2
ug/L
5.0
1.1
1
05/28/15 21:12
05/29/15 17:25
7440-42-8
ND
ug/L
0.080
0.024
1
05/28/15 21:12
05/29/15 17:25
7440-43-9
1140
ug/L
40.0
16.0
1
05/28/15 21:12
05/29/15 17:25
7440-70-2
1.4
ug/L
0.50
0.17
1
05/28/15 21:12
05/29/15 17:25
7440-47-3
2.5
ug/L
0.50
0.13
1
05/28/15 21:12
05/29/15 17:25
7440-48-4
3.8
ug/L
1.0
0.21
1
05/28/15 21:12
05/29/15 17:25
7440-50-8
5980
ug/L
50.0
13.7
1
05/28/15 21:12
05/29/15 17:25
7439-89-6
1.0
ug/L
0.10
0.046
1
05/28/15 21:12
05/29/15 17:25
7439-92-1
1670
ug/L
10.0
3.2
1
05/28/15 21:12
05/29/15 17:25
7439-95-4
701
ug/L
2.5
1.2
5
05/28/15 21:12
05/31/15 10:18
7439-96-5
0.96
ug/L
0.50
0.094
1
05/28/15 21:12
05/29/15 17:25
7439-98-7
0.92
ug/L
0.50
0.16
1
05/28/15 21:12
05/29/15 17:25
7440-02-0
1650
ug/L
50.0
11.7
1
05/28/15 21:12
05/29/15 17:25
7440-09-7
ND
ug/L
0.50
0.20
1
05/28/15 21:12
05/29/15 17:25
7782-49-2
3740
ug/L
50.0
16.3
1
05/28/15 21:12
05/29/15 17:25
7440-23-5
23.8
ug/L
0.50
0.13
1
05/28/15 21:12
05/29/15 17:25
7440-24-6
ND
ug/L
0.10
0.015
1
05/28/15 21:12
05/29/15 17:25
7440-28-0
7.2
ug/L
1.0
0.28
1
05/28/15 21:12
05/29/15 17:25
7440-62-2
38.7
ug/L
5.0
2.4
1
05/28/15 21:12
05/29/15 17:25
7440-66-6
Analytical Method: EPA 7470A Preparation Method: EPA 7470A
ND ug/L 0.20 0.022 1 05/30/1510:30 06/01/1513:11 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 50 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 �g%yfte. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040671
Pace Project No.: 92247383
Sample: 2015012328 SPLP Lab ID: 92247383014 Collected: 04/27/15 08:30 Received: 04/28/15 14:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
;T➢Z17c\�iil=11 a
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Sodium
Strontium
Thallium
Vanadium
Zinc
7470A Mercury
Mercury
Date: 06/15/2015 07:24 AM
Analytical Method: EPA 6020A Preparation Method: EPA 3020
3.2J
ug/L
10.0
3.0
1
05/28/15 21:12
05/29/15 17:44
7429-90-5
ND
ug/L
0.50
0.15
1
05/28/15 21:12
05/29/15 17:44
7440-36-0
ND
ug/L
0.50
0.11
1
05/28/15 21:12
05/29/15 17:44
7440-38-2
55.5
ug/L
0.30
0.081
1
05/28/15 21:12
05/29/15 17:44
7440-39-3
ND
ug/L
0.20
0.067
1
05/28/15 21:12
05/29/15 17:44
7440-41-7
38.0
ug/L
5.0
1.1
1
05/28/15 21:12
05/29/15 17:44
7440-42-8
ND
ug/L
0.080
0.024
1
05/28/15 21:12
05/29/15 17:44
7440-43-9
123
ug/L
40.0
16.0
1
05/28/15 21:12
05/29/15 17:44
7440-70-2
0.23J
ug/L
0.50
0.17
1
05/28/15 21:12
05/29/15 17:44
7440-47-3
0.191
ug/L
0.50
0.13
1
05/28/15 21:12
05/29/15 17:44
7440-48-4
0.74J
ug/L
1.0
0.21
1
05/28/15 21:12
05/29/15 17:44
7440-50-8
ND
ug/L
50.0
13.7
1
05/28/15 21:12
05/29/15 17:44
7439-89-6
0.053J
ug/L
0.10
0.046
1
05/28/15 21:12
05/29/15 17:44
7439-92-1
137
ug/L
10.0
3.2
1
05/28/15 21:12
05/29/15 17:44
7439-95-4
3.3
ug/L
0.50
0.24
1
05/28/15 21:12
05/29/15 17:44
7439-96-5
ND
ug/L
0.50
0.094
1
05/28/15 21:12
05/29/15 17:44
7439-98-7
0.34J
ug/L
0.50
0.16
1
05/28/15 21:12
05/29/15 17:44
7440-02-0
96.5
ug/L
50.0
11.7
1
05/28/15 21:12
05/29/15 17:44
7440-09-7
ND
ug/L
0.50
0.20
1
05/28/15 21:12
05/29/15 17:44
7782-49-2
1250
ug/L
50.0
16.3
1
05/28/15 21:12
05/29/15 17:44
7440-23-5
2.2
ug/L
0.50
0.13
1
05/28/15 21:12
05/29/15 17:44
7440-24-6
ND
ug/L
0.10
0.015
1
05/28/15 21:12
05/29/15 17:44
7440-28-0
ND
ug/L
1.0
0.28
1
05/28/15 21:12
05/29/15 17:44
7440-62-2
25.3
ug/L
5.0
2.4
1
05/28/15 21:12
05/29/15 17:44
7440-66-6
Analytical Method: EPA 7470A Preparation Method: EPA 7470A
ND ug/L 0.20 0.022 1 05/30/1510:30 06/01/1513:14 7439-97-6
REPORT OF LABORATORY ANALYSIS
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Pace Analytical Services, Inc.
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[phone]
ANALYTICAL RESULTS
Project: J15040671
Pace Project No.: 92247383
Sample: 2015012329 SPLP Lab ID: 92247383015 Collected: 04/27/15 08:45 Received: 04/28/15 14:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
;T➢Z17c\�iil=11 a
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Sodium
Strontium
Thallium
Vanadium
Zinc
7470A Mercury
Mercury
Date: 06/15/2015 07:24 AM
Analytical Method: EPA 6020A Preparation Method: EPA 3020
5.7J
ug/L
10.0
3.0
1
05/28/15 21:12
05/29/15 17:49
7429-90-5
ND
ug/L
0.50
0.15
1
05/28/15 21:12
05/29/15 17:49
7440-36-0
ND
ug/L
0.50
0.11
1
05/28/15 21:12
05/29/15 17:49
7440-38-2
64.1
ug/L
0.30
0.081
1
05/28/15 21:12
05/29/15 17:49
7440-39-3
ND
ug/L
0.20
0.067
1
05/28/15 21:12
05/29/15 17:49
7440-41-7
47.3
ug/L
5.0
1.1
1
05/28/15 21:12
05/29/15 17:49
7440-42-8
ND
ug/L
0.080
0.024
1
05/28/15 21:12
05/29/15 17:49
7440-43-9
148
ug/L
40.0
16.0
1
05/28/15 21:12
05/29/15 17:49
7440-70-2
0.47J
ug/L
0.50
0.17
1
05/28/15 21:12
05/29/15 17:49
7440-47-3
ND
ug/L
0.50
0.13
1
05/28/15 21:12
05/29/15 17:49
7440-48-4
1.0
ug/L
1.0
0.21
1
05/28/15 21:12
05/29/15 17:49
7440-50-8
ND
ug/L
50.0
13.7
1
05/28/15 21:12
05/29/15 17:49
7439-89-6
0.088J
ug/L
0.10
0.046
1
05/28/15 21:12
05/29/15 17:49
7439-92-1
100
ug/L
10.0
3.2
1
05/28/15 21:12
05/29/15 17:49
7439-95-4
2.7
ug/L
0.50
0.24
1
05/28/15 21:12
05/29/15 17:49
7439-96-5
ND
ug/L
0.50
0.094
1
05/28/15 21:12
05/29/15 17:49
7439-98-7
0.37J
ug/L
0.50
0.16
1
05/28/15 21:12
05/29/15 17:49
7440-02-0
151
ug/L
50.0
11.7
1
05/28/15 21:12
05/29/15 17:49
7440-09-7
ND
ug/L
0.50
0.20
1
05/28/15 21:12
05/29/15 17:49
7782-49-2
1330
ug/L
50.0
16.3
1
05/28/15 21:12
05/29/15 17:49
7440-23-5
3.5
ug/L
0.50
0.13
1
05/28/15 21:12
05/29/15 17:49
7440-24-6
ND
ug/L
0.10
0.015
1
05/28/15 21:12
05/29/15 17:49
7440-28-0
ND
ug/L
1.0
0.28
1
05/28/15 21:12
05/29/15 17:49
7440-62-2
23.6
ug/L
5.0
2.4
1
05/28/15 21:12
05/29/15 17:49
7440-66-6
Analytical Method: EPA 7470A Preparation Method: EPA 7470A
ND ug/L 0.20 0.022 1 05/30/1510:30 06/01/1513:16 7439-97-6
REPORT OF LABORATORY ANALYSIS
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Pace Analytical Services, Inc.
9800 ",8fftie. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040671
Pace Project No.: 92247383
QC Batch: MERP/13401 Analysis Method: EPA 7470A
QC Batch Method: EPA 7470A Analysis Description: 7470A Mercury Water
Associated Lab Samples: 92247383001, 92247383003, 92247383005
METHOD BLANK: 1953012 Matrix: Water
Associated Lab Samples: 92247383001, 92247383003, 92247383005
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Mercury ug/L ND 0.20 05/04/1516:06
LABORATORY CONTROL SAMPLE: 1953013
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Mercury ug/L 5 5.0 101 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1953014 1953015
MS MSD
92247233001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Mercury ug/L ND 5 5 5.1 5.1 103 102 80-120 1 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2015 07:24 AM without the written consent of Pace Analytical Services, Inc..
Page 53 of 82

aceAnaiXical
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Pace Analytical Services, Inc.
9800 �gc&yfie. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040671
Pace Project No.: 92247383
QC Batch: MERP/13677
Analysis Method: EPA 7470A
QC Batch Method: EPA 7470A
Analysis Description: 7470A Mercury Water
Associated Lab Samples: 92247383012, 92247383013,
92247383014, 92247383015
METHOD BLANK: 1977489
Matrix: Water
Associated Lab Samples: 92247383012, 92247383013,
92247383014, 92247383015
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Mercury ug/L
ND 0.20
06/01/1513:04
LABORATORY CONTROL SAMPLE: 1977490
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Mercury ug/L
5 5.0
99 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1980282 1980283
MS MSD
92251147009
Spike Spike MS
MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec Limits RPD RPD Qual
Mercury ug/L ND
5 5 5.2
5.1 103 102 80-120 1 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2015 07:24 AM without the written consent of Pace Analytical Services, Inc..
Page 54 of 82

aceAnaiXical
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Pace Analytical Services, Inc.
9800 %%Yft.. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040671
Pace Project No.: 92247383
QC Batch: MERP/5678 Analysis Method: EPA 7471
QC Batch Method: EPA 7471 Analysis Description: 7471 Mercury
Associated Lab Samples: 92247383002, 92247383004, 92247383006, 92247383007, 92247383008, 92247383009, 92247383010,
92247383011
METHOD BLANK: 1203118 Matrix: Solid
Associated Lab Samples: 92247383002, 92247383004, 92247383006, 92247383007, 92247383008, 92247383009, 92247383010,
92247383011
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Mercury mg/kg ND 0.0081 05/07/1513:36
LABORATORY CONTROL SAMPLE: 1203119
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Mercury mg/kg .077 0.083 108 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1203120 1203121
MS MSD
92247232001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qua]
Mercury mg/kg 0.036 .185 .194 0.18 0.16 78 65 80-120 11 20 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2015 07:24 AM without the written consent of Pace Analytical Services, Inc..
Page 55 of 82

aceAnaiXical
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Pace Analytical Services, Inc.
9800 1�6c8yfie. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040671
Pace Project No.: 92247383
QC Batch: MPRP/23950 Analysis Method: EPA 6010
QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid
Associated Lab Samples: 92247383002, 92247383004, 92247383006, 92247383007, 92247383008, 92247383009, 92247383010,
92247383011
METHOD BLANK: 1203098 Matrix: Solid
Associated Lab Samples: 92247383002, 92247383004, 92247383006, 92247383007, 92247383008, 92247383009, 92247383010,
92247383011
Parameter
Units
Blank
Result
Reporting
Limit
Aluminum
mg/kg
ND
5.0
Barium
mg/kg
ND
0.50
Beryllium
mg/kg
ND
0.050
Boron
mg/kg
ND
2.5
Calcium
mg/kg
ND
25.1
Chromium
mg/kg
ND
0.25
Copper
mg/kg
ND
0.25
Iron
mg/kg
ND
2.0
Magnesium
mg/kg
ND
25.1
Manganese
mg/kg
0.20J
0.25
Molybdenum
mg/kg
ND
0.50
Nickel
mg/kg
ND
0.25
Potassium
mg/kg
ND
50.3
Sodium
mg/kg
ND
50.3
Strontium
mg/kg
ND
0.50
Zinc
mg/kg
ND
1.0
Analyzed Qualifiers
05/07/15 12:04
05/07/15 12:04
05/07/15 12:04
05/07/15 12:04
05/07/15 12:04
05/07/15 12:04
05/07/15 12:04
05/07/15 12:04
05/07/15 12:04
05/07/15 12:04 P8
05/07/15 12:04
05/07/15 12:04
05/07/15 12:04
05/07/15 12:04
05/07/15 12:04
05/07/15 12:04
LABORATORY CONTROL SAMPLE:
Parameter
1203099
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
Aluminum
mg/kg
122
127
104
80-120
Barium
mg/kg
12.2
12.5
102
80-120
Beryllium
mg/kg
1.2
1.3
103
80-120
Boron
mg/kg
122
124
101
80-120
Calcium
mg/kg
611
637
104
80-120
Chromium
mg/kg
12.2
12.2
100
80-120
Copper
mg/kg
12.2
12.2
100
80-120
Iron
mg/kg
122
121
99
80-120
Magnesium
mg/kg
611
623
102
80-120
Manganese
mg/kg
12.2
12.8
105
80-120
Molybdenum
mg/kg
12.2
11.8
96
80-120
Nickel
mg/kg
12.2
12.3
100
80-120
Potassium
mg/kg
611
591
97
80-120
Sodium
mg/kg
611
645
106
80-120
Strontium
mg/kg
12.2
12.2
100
80-120
Zinc
mg/kg
61.1
61.9
101
80-120
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2015 07:24 AM without the written consent of Pace Analytical Services, Inc.. Page 56 of 82

aceAnaiXical
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Pace Analytical Services, Inc.
9800 �n%yfte. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040671
Pace Project No.: 92247383
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
1203100
1203101
MS
MSD
92247232001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Aluminum
mg/kg
8980
303
296
12500
12400
1160
1160
75-125
1
20 M1
Barium
mg/kg
31.5
30.3
29.6
62.1
69.1
101
128
75-125
11
20 M1
Beryllium
mg/kg
ND
3.08
2.84
3.1
2.9
96
94
75-125
4
20
Boron
mg/kg
43.1
303
296
330
331
95
98
75-125
1
20
Calcium
mg/kg
4920
1510
1470
6580
8370
110
234
75-125
24
20 M1,R1
Chromium
mg/kg
11.3
30.3
29.6
41.6
39.8
100
97
75-125
4
20
Copper
mg/kg
3.9
30.3
29.6
32.7
32.1
95
96
75-125
2
20
Iron
mg/kg
14000
303
296
13000
14900
-324
308
75-125
14
20 M1
Magnesium
mg/kg
313
1510
1470
1890
1880
104
106
75-125
1
20
Manganese
mg/kg
102
30.3
29.6
135
143
108
138
75-125
6
20 M1
Molybdenum
mg/kg
168
30.3
29.6
282
196
379
98
75-125
36
20 M1,R1
Nickel
mg/kg
2.6J
30.3
29.6
35.2
32.4
108
101
75-125
8
20
Potassium
mg/kg
ND
1510
1470
1590
1520
97
94
75-125
5
20
Sodium
mg/kg
ND
1510
1470
1720
1650
100
98
75-125
4
20
Strontium
mg/kg
195
30.3
29.6
226
291
101
325
75-125
25
20 M1,R1
Zinc
mg/kg
ND
151
147
158
149
101
98
75-125
6
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2015 07:24 AM without the written consent of Pace Analytical Services, Inc..
Page 57 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 t Qgigy fie. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040671
Pace Project No.: 92247383
QC Batch: MPRP/23951 Analysis Method: EPA 6020
QC Batch Method: EPA 3050 Analysis Description: 6020 MET SOLID
Associated Lab Samples: 92247383002, 92247383004, 92247383006, 92247383007, 92247383008, 92247383009, 92247383010,
92247383011
METHOD BLANK: 1203102
Matrix:
Solid
Associated Lab Samples:
92247383002, 92247383004, 92247383006,
92247383007, 92247383008, 92247383009,
92247383010,
92247383011
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed
Qualifiers
Antimony
mg/kg
ND
0.049
05/06/1517:35
N2
Arsenic
mg/kg
ND
0.049
05/06/1517:35
Cadmium
mg/kg
ND
0.0059
05/06/1517:35
Cobalt
mg/kg
ND
0.049
05/06/1517:35
Lead
mg/kg
ND
0.049
05/06/1517:35
Selenium
mg/kg
ND
0.049
05/06/1517:35
Thallium
mg/kg
ND
0.049
05/06/1517:35
Vanadium
mg/kg
ND
0.049
05/06/1517:35
LABORATORY CONTROL
SAMPLE: 1203103
Spike
LCS
LCS %
Rec
Parameter
Units
Conc.
Result
% Rec Limits Qualifiers
Antimony
mg/kg
2.6
2.7
105
80-120 N2
Arsenic
mg/kg
2.6
2.7
104
80-120
Cadmium
mg/kg
.26
0.25
99
80-120
Cobalt
mg/kg
2.6
2.7
105
80-120
Lead
mg/kg
2.6
2.6
103
80-120
Selenium
mg/kg
2.6
2.8
108
80-120
Thallium
mg/kg
2.6
2.7
104
80-120
Vanadium
mg/kg
2.6
2.7
104
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
1203104
1203105
MS
MSD
92247232001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD RPD Qua]
Antimony
mg/kg
ND
5.68
6.15
ND
ND
77
76
75-125
20 N2
Arsenic
mg/kg
613
5.68
6.15
576
605
-646
-129
75-125
5 20 M6
Cadmium
mg/kg
ND
.568
.615
0.85J
0.79J
111
94
75-125
20
Cobalt
mg/kg
ND
5.68
6.15
8.81
9.5J
103
106
75-125
20
Lead
mg/kg
7.3J
5.68
6.15
13.1
15.2
101
127
75-125
15 20 M6
Selenium
mg/kg
ND
5.68
6.15
6.2J
ND
55
49
75-125
20 M6
Thallium
mg/kg
ND
5.68
6.15
5.8J
6AJ
70
73
75-125
20 M6
Vanadium
mg/kg
23.4
5.68
6.15
27.2
30.0
66
106
75-125
10 20 M6
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2015 07:24 AM without the written consent of Pace Analytical Services, Inc..
Page 58 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 ",8yftie. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040671
Pace Project No.: 92247383
QC Batch: MPRP/54062 Analysis Method: EPA 6020A
QC Batch Method: EPA 3020 Analysis Description: 6020A Water UPD4
Associated Lab Samples: 92247383001, 92247383003, 92247383005
METHOD BLANK: 1953028 Matrix:
Associated Lab Samples: 92247383001, 92247383003, 92247383005
Blank
Parameter Units Result
Water
Reporting
Limit
Analyzed
Aluminum
ug/L
3.1J
10.0
05/05/1513:47
Antimony
ug/L
ND
0.50
05/05/1513:47
Arsenic
ug/L
ND
0.50
05/05/1513:47
Barium
ug/L
ND
0.30
05/05/1513:47
Beryllium
ug/L
ND
0.20
05/05/1513:47
Boron
ug/L
ND
5.0
05/05/1513:47
Cadmium
ug/L
ND
0.080
05/05/1513:47
Calcium
ug/L
ND
40.0
05/05/1513:47
Chromium
ug/L
ND
0.50
05/05/1513:47
Cobalt
ug/L
ND
0.50
05/05/1513:47
Copper
ug/L
0.28J
1.0
05/05/1513:47
Iron
ug/L
ND
50.0
05/05/1513:47
Lead
ug/L
ND
0.10
05/05/1513:47
Magnesium
ug/L
3.6J
10.0
05/05/1513:47
Manganese
ug/L
0.24J
0.50
05/05/1513:47
Molybdenum
ug/L
ND
0.50
05/05/1513:47
Nickel
ug/L
ND
0.50
05/05/1513:47
Potassium
ug/L
ND
50.0
05/05/1513:47
Selenium
ug/L
ND
0.50
05/05/1513:47
Sodium
ug/L
ND
50.0
05/05/1513:47
Strontium
ug/L
ND
0.50
05/05/1513:47
Thallium
ug/L
ND
0.10
05/05/1513:47
Vanadium
ug/L
ND
1.0
05/05/1513:47
Zinc
ug/L
ND
5.0
05/05/1513:47
Qualifiers
LABORATORY CONTROL SAMPLE:
Parameter
1953029
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
Aluminum
ug/L
80
80.3
100
80-120
Antimony
ug/L
80
78.2
98
80-120
Arsenic
ug/L
80
79.4
99
80-120
Barium
ug/L
80
78.9
99
80-120
Beryllium
ug/L
80
81.2
102
80-120
Boron
ug/L
80
80.1
100
80-120
Cadmium
ug/L
80
78.8
98
80-120
Calcium
ug/L
1000
930
93
80-120
Chromium
ug/L
80
83.9
105
80-120
Cobalt
ug/L
80
79.0
99
80-120
Copper
ug/L
80
82.7
103
80-120
Iron
ug/L
1000
1020
102
80-120
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2015 07:24 AM without the written consent of Pace Analytical Services, Inc.. Page 59 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 %%Yfte. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040671
Pace Project No.: 92247383
LABORATORY CONTROL SAMPLE: 1953029
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits
Qualifiers
Lead
ug/L
80
82.0
103
80-120
Magnesium
ug/L
1000
1020
102
80-120
Manganese
ug/L
80
79.0
99
80-120
Molybdenum
ug/L
80
78.6
98
80-120
Nickel
ug/L
80
81.0
101
80-120
Potassium
ug/L
1000
1020
102
80-120
Selenium
ug/L
80
79.3
99
80-120
Sodium
ug/L
1000
981
98
80-120
Strontium
ug/L
80
77.8
97
80-120
Thallium
ug/L
80
80.2
100
80-120
Vanadium
ug/L
80
82.4
103
80-120
Zinc
ug/L
80
80.6
101
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
1953030
1953031
MS
MSD
92247374001
Spike
Spike
MS
MSD
MS MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec % Rec
Limits
RPD
RPD Qual
Aluminum
ug/L
1340
80
80
1490
1720
192
478
75-125
14
20 M1
Antimony
ug/L
ND
80
80
79.8
77.2
100
96
75-125
3
20
Arsenic
ug/L
0.91
80
80
80.0
78.2
99
97
75-125
2
20
Barium
ug/L
47.7
80
80
125
123
97
94
75-125
2
20
Beryllium
ug/L
0.22
80
80
81.4
79.0
101
99
75-125
3
20
Boron
ug/L
1.51
80
80
83.1
81.7
102
100
75-125
2
20
Cadmium
ug/L
0.25
80
80
78.7
77.1
98
96
75-125
2
20
Calcium
ug/L
3950
1000
1000
4870
4760
92
81
75-125
2
20
Chromium
ug/L
1.8
80
80
84.9
83.9
104
103
75-125
1
20
Cobalt
ug/L
7.4
80
80
85.6
83.9
98
96
75-125
2
20
Copper
ug/L
35.4
80
80
118
115
103
99
75-125
3
20
Iron
ug/L
1040
1000
1000
2040
2180
101
115
75-125
6
20
Lead
ug/L
53.8
80
80
135
132
101
98
75-125
2
20
Magnesium
ug/L
1040
1000
1000
2050
2010
101
97
75-125
2
20
Manganese
ug/L
229
80
80
306
298
96
86
75-125
3
20
Molybdenum
ug/L
ND
80
80
78.9
76.5
99
96
75-125
3
20
Nickel
ug/L
3.1
80
80
84.4
81.6
102
98
75-125
3
20
Potassium
ug/L
554
1000
1000
1540
1540
99
98
75-125
0
20
Selenium
ug/L
1.3
80
80
80.6
76.9
99
94
75-125
5
20
Sodium
ug/L
139
1000
1000
1120
1090
98
95
75-125
3
20
Strontium
ug/L
9.0
80
80
86.6
84.5
97
94
75-125
2
20
Thallium
ug/L
0.046J
80
80
82.6
81.5
103
102
75-125
1
20
Vanadium
ug/L
3.7
80
80
85.6
84.8
102
101
75-125
1
20
Zinc
ug/L
41.7
80
80
122
120
100
98
75-125
2
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2015 07:24 AM without the written consent of Pace Analytical Services, Inc..
Page 60 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 �gc&yfie. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040671
Pace Project No.: 92247383
QC Batch: MPRP/54700 Analysis Method: EPA 6020A
QC Batch Method: EPA 3020 Analysis Description: 6020A Water UPD4
Associated Lab Samples: 92247383012, 92247383013, 92247383014, 92247383015
METHOD BLANK: 1977698 Matrix: Water
Associated Lab Samples: 92247383012, 92247383013, 92247383014, 92247383015
Blank Reporting
Parameter Units Result Limit
Analyzed
Aluminum
ug/L
ND
10.0
05/29/1516:47
Antimony
ug/L
ND
0.50
05/29/1516:47
Arsenic
ug/L
ND
0.50
05/29/1516:47
Barium
ug/L
ND
0.30
05/29/1516:47
Beryllium
ug/L
ND
0.20
05/29/1516:47
Boron
ug/L
ND
5.0
05/29/1516:47
Cadmium
ug/L
ND
0.080
05/29/1516:47
Calcium
ug/L
ND
40.0
05/29/1516:47
Chromium
ug/L
ND
0.50
05/29/1516:47
Cobalt
ug/L
ND
0.50
05/29/1516:47
Copper
ug/L
ND
1.0
05/29/1516:47
Iron
ug/L
ND
50.0
05/29/1516:47
Lead
ug/L
ND
0.10
05/29/1516:47
Magnesium
ug/L
ND
10.0
05/29/1516:47
Manganese
ug/L
ND
0.50
05/29/1516:47
Molybdenum
ug/L
ND
0.50
05/29/1516:47
Nickel
ug/L
ND
0.50
05/29/1516:47
Potassium
ug/L
ND
50.0
05/29/1516:47
Selenium
ug/L
ND
0.50
05/29/1516:47
Sodium
ug/L
ND
50.0
05/29/1516:47
Strontium
ug/L
ND
0.50
05/29/1516:47
Thallium
ug/L
ND
0.10
05/29/1516:47
Vanadium
ug/L
ND
1.0
05/29/1516:47
Zinc
ug/L
ND
5.0
05/29/1516:47
Qualifiers
LABORATORY CONTROL SAMPLE:
Parameter
1977699
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
Aluminum
ug/L
80
85.4
107
80-120
Antimony
ug/L
80
78.9
99
80-120
Arsenic
ug/L
80
79.8
100
80-120
Barium
ug/L
80
79.2
99
80-120
Beryllium
ug/L
80
77.9
97
80-120
Boron
ug/L
80
81.4
102
80-120
Cadmium
ug/L
80
81.2
102
80-120
Calcium
ug/L
1000
1020
102
80-120
Chromium
ug/L
80
81.9
102
80-120
Cobalt
ug/L
80
79.1
99
80-120
Copper
ug/L
80
82.4
103
80-120
Iron
ug/L
1000
1020
102
80-120
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2015 07:24 AM without the written consent of Pace Analytical Services, Inc.. Page 61 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 %%Yfte. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040671
Pace Project No.: 92247383
LABORATORY CONTROL SAMPLE: 1977699
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits
Qualifiers
Lead
ug/L
80
77.4
97
80-120
Magnesium
ug/L
1000
1030
103
80-120
Manganese
ug/L
80
83.1
104
80-120
Molybdenum
ug/L
80
79.8
100
80-120
Nickel
ug/L
80
81.4
102
80-120
Potassium
ug/L
1000
1010
101
80-120
Selenium
ug/L
80
80.3
100
80-120
Sodium
ug/L
1000
975
97
80-120
Strontium
ug/L
80
79.5
99
80-120
Thallium
ug/L
80
79.0
99
80-120
Vanadium
ug/L
80
81.7
102
80-120
Zinc
ug/L
80
83.0
104
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
1977700
1977701
MS
MSD
92251147009
Spike
Spike
MS
MSD
MS MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec % Rec
Limits
RPD
RPD Qual
Aluminum
ug/L
230
80
80
317
320
109
112
75-125
1
20
Antimony
ug/L
ND
80
80
80.4
80.8
100
101
75-125
0
20
Arsenic
ug/L
ND
80
80
81.4
81.4
102
102
75-125
0
20
Barium
ug/L
3.5
80
80
83.5
83.9
100
101
75-125
0
20
Beryllium
ug/L
ND
80
80
80.8
79.0
101
99
75-125
2
20
Boron
ug/L
39.5
80
80
84.1
84.4
56
56
75-125
0
20 M1
Cadmium
ug/L
ND
80
80
83.0
82.3
104
103
75-125
1
20
Calcium
ug/L
229
1000
1000
1270
1250
104
102
75-125
2
20
Chromium
ug/L
ND
80
80
82.0
83.4
102
104
75-125
2
20
Cobalt
ug/L
ND
80
80
80.4
80.6
100
101
75-125
0
20
Copper
ug/L
2.1
80
80
85.6
85.8
104
105
75-125
0
20
Iron
ug/L
138
1000
1000
1160
1170
102
104
75-125
1
20
Lead
ug/L
0.37
80
80
80.3
80.0
100
99
75-125
0
20
Magnesium
ug/L
20.5
1000
1000
1070
1070
105
105
75-125
0
20
Manganese
ug/L
15.1
80
80
98.9
99.4
105
105
75-125
0
20
Molybdenum
ug/L
ND
80
80
80.9
81.7
101
102
75-125
1
20
Nickel
ug/L
ND
80
80
81.5
82.9
101
103
75-125
2
20
Potassium
ug/L
51.5
1000
1000
1070
1070
101
102
75-125
1
20
Selenium
ug/L
ND
80
80
82.2
78.4
103
98
75-125
5
20
Sodium
ug/L
ND
1000
1000
1020
1000
98
96
75-125
1
20
Strontium
ug/L
2.2
80
80
82.7
82.9
101
101
75-125
0
20
Thallium
ug/L
ND
80
80
83.8
83.8
105
105
75-125
0
20
Vanadium
ug/L
ND
80
80
82.6
83.3
103
104
75-125
1
20
Zinc
ug/L
ND
80
80
84.0
88.6
100
106
75-125
5
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2015 07:24 AM without the written consent of Pace Analytical Services, Inc..
Page 62 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 ",8fftie. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040671
Pace Project No.: 92247383
QC Batch: PMST/3554
Analysis Method:
ASTM
D2974-87
QC Batch Method: ASTM
D2974-87
Analysis Description:
Dry Weight/Percent Moisture
Associated Lab Samples:
92247383002, 92247383004, 92247383006, 92247383007,
92247383008, 92247383009,
92247383010,
92247383011
SAMPLE DUPLICATE:
1211608
35185823001
Dup
Max
Parameter
Units
Result
Result
RPD
RPD
Qualifiers
Percent Moisture
%
82.0
76.6
7
10
SAMPLE DUPLICATE:
1211609
92247383010
Dup
Max
Parameter
Units
Result
Result
RPD
RPD
Qualifiers
Percent Moisture
%
16.8
18.9
12
10 D6
SAMPLE DUPLICATE:
1211610
92247834001
Dup
Max
Parameter
Units
Result
Result
RPD
RPD
Qualifiers
Percent Moisture
%
56.4
56.6
0
10
SAMPLE DUPLICATE:
1211611
92247835014
Dup
Max
Parameter
Units
Result
Result
RPD
RPD
Qualifiers
Percent Moisture
%
35.2
33.3
6
10
SAMPLE DUPLICATE:
1211612
92247827006
Dup
Max
Parameter
Units
Result
Result
RPD
RPD
Qualifiers
Percent Moisture
%
12.5
13.5
7
10
SAMPLE DUPLICATE:
1211613
35187206001
Dup
Max
Parameter
Units
Result
Result
RPD
RPD
Qualifiers
Percent Moisture
%
65.0
68.0
5
10
SAMPLE DUPLICATE:
1211614
92248416004
Dup
Max
Parameter
Units
Result
Result
RPD
RPD
Qualifiers
Percent Moisture
%
24.5
23.9
3
10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2015 07:24 AM without the written consent of Pace Analytical Services, Inc.. Page 63 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Edge Yft.. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040671
Pace Project No.: 92247383
SAMPLE DUPLICATE: 1211615
92248416014
Dup
Max
Parameter
Units
Result
Result
RPD
RPD
Qualifiers
Percent Moisture
%
12.6
11.6
9
10
SAMPLE DUPLICATE: 1211616
92248424009
Dup
Max
Parameter
Units
Result
Result
RPD
RPD
Qualifiers
Percent Moisture
%
18.7
18.7
0
10
SAMPLE DUPLICATE: 1211617
92248424020
Dup
Max
Parameter
Units
Result
Result
RPD
RPD
Qualifiers
Percent Moisture
%
38.9
38.8
0
10
SAMPLE DUPLICATE: 1211618
35187430003
Dup
Max
Parameter
Units
Result
Result
RPD
RPD
Qualifiers
Percent Moisture
%
25.1
27.5
9
10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2015 07:24 AM without the written consent of Pace Analytical Services, Inc.. Page 64 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 %g8yftie. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040671
Pace Project No.: 92247383
QC Batch: WET/37120 Analysis Method: EPA 9045
QC Batch Method: EPA 9045 Analysis Description: 9045 pH
Associated Lab Samples: 92247383002, 92247383004, 92247383006, 92247383007
SAMPLE DUPLICATE: 1445734
92246794001 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
pH at 25 Degrees C Std. Units 8.4 8.3 0 10
SAMPLE DUPLICATE: 1445735
92247232003 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
pH at 25 Degrees C Std. Units 6.9 7.0 1 10 D6
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2015 07:24 AM without the written consent of Pace Analytical Services, Inc.. Page 65 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 %g8yftie. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040671
Pace Project No.: 92247383
QC Batch: WET/37157 Analysis Method: EPA 9045
QC Batch Method: EPA 9045 Analysis Description: 9045 pH
Associated Lab Samples: 92247383008, 92247383009, 92247383010, 92247383011
SAMPLE DUPLICATE: 1447040
92247393001 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
pH at 25 Degrees C Std. Units 7.6 7.7 0 10
SAMPLE DUPLICATE: 1447041
Parameter
pH at 25 Degrees C
92247393012 Dup
Units Result Result
Std. Units 7.5 7.5
Max
RPD RPD Qualifiers
0 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2015 07:24 AM without the written consent of Pace Analytical Services, Inc.. Page 66 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 tginlc&yfie. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040671
Pace Project No.: 92247383
QC Batch: WETA/22924 Analysis Method: EPA 300.0
QC Batch Method: EPA 300.0 Analysis Description: 300.0 IC Anions
Associated Lab Samples: 92247383007, 92247383008, 92247383010, 92247383011
METHOD BLANK: 1459398 Matrix: Water
Associated Lab Samples: 92247383007, 92247383008, 92247383010, 92247383011
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Sulfate mg/L 3.4 2.0 05/14/1518:08
LABORATORY CONTROL SAMPLE: 1459399
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Sulfate mg/L 20 19.3 96 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1459400 1459401
MS MSD
92247374003 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfate mg/L 7.1 22.5 22.5 28.3 28.3 94 94 0
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1459402 1459403
MS MSD
92247911005 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfate mg/L 27.6 23 23 47.7 48.2 87 90 1 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2015 07:24 AM without the written consent of Pace Analytical Services, Inc..
Page 67 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Ig2,8 r fie. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040671
Pace Project No.: 92247383
QC Batch: WETA/22957
Analysis Method: EPA 353.2
QC Batch Method: EPA 353.2
Analysis Description: 353.2 Nitrate + Nitrite, Unpres.
Associated Lab Samples: 92247383007, 92247383008,
92247383010, 92247383011
METHOD BLANK: 1461218
Matrix: Water
Associated Lab Samples: 92247383007, 92247383008,
92247383010, 92247383011
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Nitrogen, Nitrate mg/L
0.18 0.020
05/15/15 20:50 Z2
LABORATORY CONTROL SAMPLE: 1461219
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Nitrogen, Nitrate mg/L
2.5 2.5
99 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1461220 1461221
MS MSD
92247374003
Spike Spike MS
MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec Limits RPD RPD Qual
Nitrogen, Nitrate mg/L 0.26
2.8 2.8 2.9
2.9 93 93 90-110 0 10 H1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1461222 1461223
MS MSD
92247374005 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Nitrogen, Nitrate mg/L 0.75 2.9 2.9 3.5 3.5 94 93 90-110 0 10 H1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2015 07:24 AM without the written consent of Pace Analytical Services, Inc..
Page 68 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 %,8yftie. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040671
Pace Project No.: 92247383
QC Batch: WETA/22916
Analysis Method: SM 4500-CI-E
QC Batch Method: SM 4500-CI-E
Analysis Description: 4500 Chloride
Associated Lab Samples: 92247383007, 92247383008,
92247383010, 92247383011
METHOD BLANK: 1458586
Matrix: Water
Associated Lab Samples: 92247383007, 92247383008,
92247383010, 92247383011
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Chloride mg/L
ND 1.0
05/14/15 05:46
LABORATORY CONTROL SAMPLE: 1458587
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Chloride mg/L
20 19.9
100 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1458588 1458589
MS MSD
92247374003
Spike Spike MS
MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec Limits RPD RPD Qual
Chloride mg/L ND
22.5 22.5 23.9
23.3 105 102 90-110 3 10
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1458590 1458591
MS MSD
92247911005 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Chloride mg/L ND 23 23 24.1 23.9 103 102 90-110 1 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 06/15/2015 07:24 AM without the written consent of Pace Analytical Services, Inc..
Page 69 of 82

aceAnaiXical
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Pace Analytical Services, Inc.
9800 %g8yftie. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040671
Pace Project No.: 92247383
QC Batch: WETA/46021 Analysis Method: EPA 9056
QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions
Associated Lab Samples: 92247383002, 92247383004, 92247383006
METHOD BLANK: 1202076 Matrix: Solid
Associated Lab Samples:
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Chloride mg/kg ND 49.8 05/02/1519:05
Sulfate mg/kg ND 49.8 05/02/1519:05
LABORATORY CONTROL SAMPLE:
1202077
Parameter
Units
Chloride
mg/kg
Sulfate
mg/kg
MATRIX SPIKE SAMPLE:
1202079
Parameter
Units
Chloride
mg/kg
Sulfate
mg/kg
SAMPLE DUPLICATE: 1202078
Parameter
Chloride
Sulfate
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
499 486 97 80-120
499 481 96 80-120
92247232001 Spike MS MS % Rec
Result Conc. Result % Rec Limits Qualifiers
ND 1180 1160 79 80-120 M 1
449J 1180 1440 84 80-120
92247232001 Dup
Units Result Result
mg/kg ND ND
mg/kg 449J 428J
Max
RPD RPD Qualifiers
20
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 06/15/2015 07:24 AM without the written consent of Pace Analytical Services, Inc.. Page 70 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 %g8yftie. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040671
Pace Project No.: 92247383
QC Batch: WETA/46023 Analysis Method: EPA 9056
QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions
Associated Lab Samples: 92247383007, 92247383008, 92247383009, 92247383010, 92247383011
METHOD BLANK: 1202084 Matrix: Solid
Associated Lab Samples:
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Chloride mg/kg ND 49.7 05/03/15 05:05
Sulfate mg/kg ND 49.7 05/03/15 05:05
LABORATORY CONTROL SAMPLE:
1202085
Parameter
Units
Chloride
mg/kg
Sulfate
mg/kg
MATRIX SPIKE SAMPLE:
1202087
Parameter
Units
Chloride
mg/kg
Sulfate
mg/kg
SAMPLE DUPLICATE: 1202086
Parameter
Chloride
Sulfate
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
499 506 101 80-120
499 502 101 80-120
92247383007 Spike MS MS % Rec
Result Conc. Result % Rec Limits Qualifiers
ND 716 677 77 80-120 M 1
ND 716 712 99 80-120
92247383007 Dup
Units Result Result
mg/kg ND ND
mg/kg ND ND
Max
RPD RPD Qualifiers
20
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 06/15/2015 07:24 AM without the written consent of Pace Analytical Services, Inc.. Page 71 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 lg6,8 r fie. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040671
Pace Project No.: 92247383
QC Batch: WETA/46020
Analysis Method:
EPA 9056
QC Batch Method: EPA 9056
Analysis Description:
9056 IC Anions
Associated Lab Samples: 92247383002, 92247383004, 92247383006
METHOD BLANK: 1202072
Matrix: Solid
Associated Lab Samples:
Blank Reporting
Parameter
Units
Result Limit
Analyzed
Qualifiers
Nitrate as N
mg/kg
ND 5.0
05/02/15 19:05
LABORATORY CONTROL SAMPLE:
1202073
Spike LCS
LCS
% Rec
Parameter
Units
Conc. Result
% Rec
Limits
Qualifiers
Nitrate as N
mg/kg
49.9 49.0
98
80-120
MATRIX SPIKE SAMPLE:
1202075
92247232001 Spike
MS
MS
% Rec
Parameter
Units
Result Conc.
Result
% Rec
Limits Qualifiers
Nitrate as N
mg/kg
ND 118
111
94 80-120 H3
SAMPLE DUPLICATE: 1202074
92247232001 Dup
Max
Parameter
Units
Result Result
RPD
RPD
Qualifiers
Nitrate as N
mg/kg
ND ND
20 H3
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 06/15/2015 07:24 AM without the written consent of Pace Analytical Services, Inc.. Page 72 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 ",8fftie. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040671
Pace Project No.: 92247383
QC Batch: WETA/46022
Analysis Method: EPA 9056
QC Batch Method: EPA 9056
Analysis Description: 9056 IC Anions
Associated Lab Samples: 92247383007, 92247383008, 92247383009, 92247383010, 92247383011
METHOD BLANK: 1202080
Matrix: Solid
Associated Lab Samples:
Blank Reporting
Parameter
Units
Result Limit Analyzed
Qualifiers
Nitrate as N
mg/kg
ND 5.0 05/03/15 05:05
LABORATORY CONTROL SAMPLE:
1202081
Spike LCS LCS
% Rec
Parameter
Units
Conc. Result % Rec
Limits
Qualifiers
Nitrate as N
mg/kg
49.9 51.1 102
80-120
MATRIX SPIKE SAMPLE:
1202083
92247383007 Spike MS
MS
% Rec
Parameter
Units
Result Conc. Result
% Rec
Limits Qualifiers
Nitrate as N
mg/kg
ND 71.6 69.0
96 80-120 H3
SAMPLE DUPLICATE: 1202082
92247383007 Dup
Max
Parameter
Units
Result Result RPD
RPD
Qualifiers
Nitrate as N
mg/kg
ND ND
20 H3
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 lgigc&yfie. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040671
Pace Project No.: 92247383
QC Batch: WETA/28520
Analysis Method: EPA 9060
QC Batch Method: EPA 9060
Analysis Description: 9060 TOC Average
Associated Lab Samples: 92247383002
METHOD BLANK: 1158740
Matrix: Solid
Associated Lab Samples:
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Mean Total Organic Carbon mg/kg
ND 600
05/18/15 08:42
LABORATORY CONTROL SAMPLE: 1158741
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Mean Total Organic Carbon mg/kg
120000 135000
112 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1158742 1158743
MS MSD
92247383002
Spike Spike MS
MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec Limits RPD RPD Qual
Mean Total Organic Carbon mg/kg 420J
6150 6150 6640
6780 101 103 50-150 2 30
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1158744 1158745
MS MSD
92247835007 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Mean Total Organic Carbon mg/kg 108000 73800 73100 162000 153000 73 62 50-150 6 30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2015 07:24 AM without the written consent of Pace Analytical Services, Inc..
Page 74 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 lgi§c&yfie. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040671
Pace Project No.: 92247383
QC Batch: WETA/28567
Analysis Method: EPA 9060
QC Batch Method: EPA 9060
Analysis Description: 9060 TOC Average
Associated Lab Samples: 92247383004,92247383006,92247383007,92247383008,92247383009,92247383010,92247383011
METHOD BLANK: 1160018
Matrix: Solid
Associated Lab Samples:
Blank Reporting
Parameter Units
Result Limit Analyzed Qualifiers
Mean Total Organic Carbon mg/kg
ND 600 05/20/15 09:57
LABORATORY CONTROL SAMPLE: 1160019
Spike LCS LCS % Rec
Parameter Units
Conc. Result % Rec Limits Qualifiers
Mean Total Organic Carbon mg/kg
120000 120000 100 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1160020 1160021
MS MSD
92247383006
Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Mean Total Organic Carbon mg/kg 3350
8000 7990 10600 11000 91 96 50-150 3 30
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1160022 1160023
MS MSD
92247383004 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Mean Total Organic Carbon mg/kg 1110 7270 7270 8550 8310 102 99 50-150 3 30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2015 07:24 AM without the written consent of Pace Analytical Services, Inc..
Page 75 of 82

aceAnaiXical
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Pace Analytical Services, Inc.
9800 %%yft.. Suite 100
Huntersville, NC 28078
[phone]
QUALIFIERS
Project: J15040671
Pace Project No.: 92247383
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
LABORATORIES
PASI-A
Pace Analytical Services - Asheville
PASI-G
Pace Analytical Services - Green Bay
PASI-M
Pace Analytical Services - Minneapolis
PASI-O
Pace Analytical Services - Ormond Beach
BATCH QUALIFIERS
Batch: ICP/14654
Ill Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
ANALYTE QUALIFIERS
B Analyte was detected in the associated method blank.
D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
D6 The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits.
H1 Analysis conducted outside the EPA method holding time.
H3 Sample was received or analysis requested beyond the recognized method holding time.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
N2 The lab does not hold TN accreditation for this parameter.
REPORT OF LABORATORY ANALYSIS
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Pace Analytical Services, Inc
9800 t
aceAnalXical ® c&rr�ie. Suite 100
Huntersville, INC 28078078
www.pacelabs.com [phone]
QUALIFIERS
Project: J15040671
Pace Project No.: 92247383
ANALYTE QUALIFIERS
P8 Analyte was detected in the method blank. All associated samples had concentrations of at least ten times greater than
the blank or were below the reporting limit.
R1 RPD value was outside control limits.
Z2 Analyte present in the associated method blank above the detection limit.
REPORT OF LABORATORY ANALYSIS
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aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 92,8y ft.. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: J15040671
Pace Project No.: 92247383
Analytical
Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch
92247383002
2015012320
EPA
3050
MPRP/23950
EPA 6010
ICP/14654
92247383004
2015012322
EPA
3050
MPRP/23950
EPA 6010
ICP/14654
92247383006
2015012324
EPA
3050
MPRP/23950
EPA 6010
ICP/14654
92247383007
2015012325
EPA
3050
MPRP/23950
EPA 6010
ICP/14654
92247383008
2015012326
EPA
3050
MPRP/23950
EPA 6010
ICP/14654
92247383009
2015012327
EPA
3050
MPRP/23950
EPA6010
ICP/14654
92247383010
2015012328
EPA
3050
MPRP/23950
EPA 6010
ICP/14654
92247383011
2015012329
EPA
3050
MPRP/23950
EPA 6010
ICP/14654
92247383002
2015012320
EPA 3050
MPRP/23951
EPA 6020
ICPM/9732
92247383004
2015012322
EPA 3050
MPRP/23951
EPA 6020
ICPM/9732
92247383006
2015012324
EPA 3050
MPRP/23951
EPA 6020
ICPM/9732
92247383007
2015012325
EPA 3050
MPRP/23951
EPA 6020
ICPM/9732
92247383008
2015012326
EPA 3050
MPRP/23951
EPA 6020
ICPM/9732
92247383009
2015012327
EPA 3050
MPRP/23951
EPA 6020
ICPM/9732
92247383010
2015012328
EPA 3050
MPRP/23951
EPA 6020
ICPM/9732
92247383011
2015012329
EPA 3050
MPRP/23951
EPA 6020
ICPM/9732
92247383001
2015012319
EPA 3020
MPRP/54062
EPA 6020A
ICPM/24072
92247383003
2015012321
EPA 3020
MPRP/54062
EPA 6020A
ICPM/24072
92247383005
2015012323
EPA 3020
MPRP/54062
EPA 6020A
ICPM/24072
92247383012
2015012325 SPLP
EPA 3020
MPRP/54700
EPA 6020A
ICPM/24507
92247383013
2015012326 SPLP
EPA 3020
MPRP/54700
EPA 6020A
ICPM/24507
92247383014
2015012328 SPLP
EPA 3020
MPRP/54700
EPA 6020A
ICPM/24507
92247383015
2015012329 SPLP
EPA 3020
MPRP/54700
EPA 6020A
ICPM/24507
92247383001
2015012319
EPA 7470A
MERP/13401
EPA 7470A
MERC/15595
92247383003
2015012321
EPA 7470A
MERP/13401
EPA 7470A
MERC/15595
92247383005
2015012323
EPA 7470A
MERP/13401
EPA 7470A
MERC/15595
92247383012
2015012325 SPLP
EPA 7470A
MERP/13677
EPA 7470A
MERC/15927
92247383013
2015012326 SPLP
EPA 7470A
MERP/13677
EPA 7470A
MERC/15927
92247383014
2015012328 SPLP
EPA 7470A
MERP/13677
EPA 7470A
MERC/15927
92247383015
2015012329 SPLP
EPA 7470A
MERP/13677
EPA 7470A
MERC/15927
92247383002
2015012320
EPA 7471
MERP/5678
EPA 7471
MERC/5668
92247383004
2015012322
EPA 7471
MERP/5678
EPA 7471
MERC/5668
92247383006
2015012324
EPA 7471
MERP/5678
EPA 7471
MERC/5668
92247383007
2015012325
EPA 7471
MERP/5678
EPA 7471
MERC/5668
92247383008
2015012326
EPA 7471
MERP/5678
EPA 7471
MERC/5668
92247383009
2015012327
EPA 7471
MERP/5678
EPA 7471
MERC/5668
92247383010
2015012328
EPA 7471
MERP/5678
EPA 7471
MERC/5668
92247383011
2015012329
EPA 7471
MERP/5678
EPA 7471
MERC/5668
92247383002
2015012320
ASTM D2974-87
PMST/3554
92247383004
2015012322
ASTM D2974-87
PMST/3554
92247383006
2015012324
ASTM D2974-87
PMST/3554
92247383007
2015012325
ASTM D2974-87
PMST/3554
92247383008
2015012326
ASTM D2974-87
PMST/3554
92247383009
2015012327
ASTM D2974-87
PMST/3554
92247383010
2015012328
ASTM D2974-87
PMST/3554
REPORT OF LABORATORY ANALYSIS
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aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 9�%Yfte. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: J15040671
Pace Project No.: 92247383
Lab ID
Sample ID
QC Batch Method
QC Batch
92247383011
2015012329
ASTM D2974-87
PMST/3554
92247383002
2015012320
EPA 9045
WET/37120
92247383004
2015012322
EPA 9045
WET/37120
92247383006
2015012324
EPA 9045
WET/37120
92247383007
2015012325
EPA 9045
WET/37120
92247383008
2015012326
EPA 9045
WET/37157
92247383009
2015012327
EPA 9045
WET/37157
92247383010
2015012328
EPA 9045
WET/37157
92247383011
2015012329
EPA 9045
WET/37157
92247383007
2015012325
EPA 300.0
WETA/22924
92247383008
2015012326
EPA 300.0
WETA/22924
92247383010
2015012328
EPA 300.0
WETA/22924
92247383011
2015012329
EPA 300.0
WETA/22924
92247383007
2015012325
EPA 353.2
WETA/22957
92247383008
2015012326
EPA 353.2
WETA/22957
92247383010
2015012328
EPA 353.2
WETA/22957
92247383011
2015012329
EPA 353.2
WETA/22957
92247383007
2015012325
SM 4500-CI-E
WETA/22916
92247383008
2015012326
SM 4500-CI-E
WETA/22916
92247383010
2015012328
SM 4500-CI-E
WETA/22916
92247383011
2015012329
SM 4500-CI-E
WETA/22916
92247383002
2015012320
EPA 9056
WETA/46021
92247383004
2015012322
EPA 9056
WETA/46021
92247383006
2015012324
EPA 9056
WETA/46021
92247383007
2015012325
EPA 9056
WETA/46023
92247383008
2015012326
EPA 9056
WETA/46023
92247383009
2015012327
EPA 9056
WETA/46023
92247383010
2015012328
EPA 9056
WETA/46023
92247383011
2015012329
EPA 9056
WETA/46023
92247383002
2015012320
EPA 9056
WETA/46020
92247383004
2015012322
EPA 9056
WETA/46020
92247383006
2015012324
EPA 9056
WETA/46020
92247383007
2015012325
EPA 9056
WETA/46022
92247383008
2015012326
EPA 9056
WETA/46022
92247383009
2015012327
EPA 9056
WETA/46022
92247383010
2015012328
EPA 9056
WETA/46022
92247383011
2015012329
EPA 9056
WETA/46022
92247383002
2015012320
EPA 9060
WETA/28520
92247383002
2015012320
EPA 9060
WETA/28521
92247383004
2015012322
EPA 9060
WETA/28567
92247383004
2015012322
EPA 9060
WETA/28570
92247383006
2015012324
EPA 9060
WETA/28567
REPORT OF LABORATORY
ANALYSIS
This report shall not be reproduced, except
in full,
Date: 06/15/2015 07:24
AM
without the written consent of Pace Analytical Services, Inc..
Analytical
Analytical Method Batch
Page 79 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 94,8f ft.. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: J15040671
Pace Project No.: 92247383
Lab ID
Sample ID
QC Batch Method
QC Batch
92247383006
2015012324
EPA 9060
WETA/28570
92247383007
2015012325
EPA 9060
WETA/28567
92247383007
2015012325
EPA 9060
WETA/28570
92247383008
2015012326
EPA 9060
WETA/28567
92247383008
2015012326
EPA 9060
WETA/28570
92247383009
2015012327
EPA 9060
WETA/28567
92247383009
2015012327
EPA 9060
WETA/28570
92247383010
2015012328
EPA 9060
WETA/28567
92247383010
2015012328
EPA 9060
WETA/28570
92247383011
2015012329
EPA 9060
WETA/28567
92247383011
2015012329
EPA 9060
WETA/28570
Date: 06/15/2015 07:24 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Analytical Method
Analytical
Batch
Page 80 of 82

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ce��Pytr'ca! Document Number: Issuing I
F-CHR-CS-003-rev.15 pace Huntersvil
of 98
:nt Name: lic
Fed ExEl UPS❑ LISPS❑ Ciient❑ Commercialn Pace Other
Idy Seal on CoolerlBox Present: ❑ yes © no Seats intact: [] yes 0 no
ing material: ❑ Bubble VDP Q/Bubble Bags ❑ None Q Other
nometer Used: IR Gun (,T1�t Type of Ice: (�l�C B[ue None 'Pi Samples on ice, cooling process has begun
1 Correction Factor i1401 No Correction
t)ate and In Is of=777-
1--T g
:clad Cooler'iemp.: .0 Biological Tissue is Frozen: Yes Nq NI contents
should be above freezi6 C Comments: l
i of Custody Present:
I of Custody Filled Out:
r of Custody Relinquished:
aler Name & Signature on COC:
ales Arrived within Mold Time:
t Hold Time Analysis (-972hr).
i Turn Around Time Requeste
cient Volume:
:ct Containers Used:
)ace Containers Used:
:ainers Intact:
red .volume received for Dissoiv,
ve Labels match COC:
t1 es ONO ❑NIA 1.
Yes 13Nv
❑NIA 2.
Yes ONO
❑NIA 3.
DYes ❑No
❑NIA 14,
❑Yes
❑Yes
[]No ❑NIA 5.
a ❑ N1A B.
No ❑NIA 7.
CINo ❑NIA $,
❑MIA9.
❑Noo , ❑NIA
❑No ❑NIA 10.
❑No 113lA 11.
LINO ❑NIA 12.
mtalners needing preservation have, been checked.
Cites ❑Na dN1A 13,
ontainers needing preservation are found to be in ❑Yes ❑No iJNIA
pliance with EPA -recommendation.
.. . _- .— _--- r^^ nr.r± mn_nan Iwararl 0Yes IPNo /
Idspace in VOA Vials (56mm):
dyes ❑No 91NrA M
a Blank Present.
oyes ONo 1A 16.
NI
Custody Seals Present
s Blank y
ayes❑Na I A
ae Trip Blank Lot # (f purchased):
Field Data Required? Y ! N
ent Notification! Resolution:
Person Contacted:
DaterTime:
;omments/ Resolution:
`,llRF Review: Date: l� WO# 92247383
SRF Review:ako
Date:1� IE III� 1111111111111111tote: whenever there is a disncy affecting North Carolina compliance
samples, a copy of this form will be sent to the North Carolina DEHNR 922473t33
Certification Office ( i,e out of hold, incorrect preservative, out of temp,
incorrect containers)
Page 81 of 82

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Page 82 of 82

CHAIN OF CUSTODY RECORD AND ANALYSIS IS FBI l_1k_ T FORM
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MaM Code MG0 "A? I®ulldkM ` 4FI61 l - wo.k c7rder a
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11IJ� Cr Flunlerevills. N. C, 40713 I iF nygod E}� d Tbm
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Ram
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