The URL can be used to link to this page

Home My WebLink AboutNC0038377_J15040385 Report_20150902+ DUKE Analytical Laboratory 1 of58 ENERGY Order Number: Project Name: Customer Name(s): Customer Address: Lab Contact: Report Authorized By: (Signature) Program Comments: 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone:980-875-5245 Fax:980-875-4349 Order Summary Report J15040385 MAYO STEAM - AB GW ASSESSMENT SOIL Tim Hunsucker, Jerry Wylie, Kathy Webb, John Toepfer Margaret Galvin -Karr Margaret Galvin -Karr MXG4644 (101 161) 2015.06.0814:56:34 -04'00' Phone: 980-875-5219 Date: Please contact the Program Manager (Margaret Galvin -Karr) with any questions regarding this report. Data Flags & Calculations: 6/8/2015 Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Sample ID's & Descriptions: 2 of 58 Collection Sample ID Plant/Station Date and Time Collected By Sample Description 2015011113 MAYO STEAM 14-Apr-15 2:30 PM illegible MW-11 EB 2015011114 MAYO STEAM 14-Apr-15 2:50 PM illegible MW-11BR 0-2 2015011115 MAYO STEAM 15-Apr-15 12:30 PM illegible MW-11BR 30-32 3 Total Samples 3 of 58 Technical Validation Review Checklist: COC and .pdf report are in agreement with sample totals Yes No and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. ❑ Yes❑ No All laboratory QA/QC requirements are acceptable.❑ Yes ❑ No Report Sections Included: U Job Summary Report ❑ Sample Identification n Technical Validation of Data Package ❑ Analytical Laboratory Certificate of Analysis ❑ Analytical Laboratory QC Report Reviewed By: Date: Sub -contracted Laboratory Results ❑ Customer Specific Data Sheets, Reports, & Documentation ❑ Customer Database Entries ❑ Chain of Custody ❑ Electronic Data Deliverable (EDD) Sent Separately Certificate of Laboratory Analysis 4 of 58 This report shall not be reproduced, except in full. Order # J15040385 Site: MW-11 EB Collection Date: 14-Apr-15 2:30 PM Analyte Result Units Qualifiers RDL DF METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Sample #: 2015011113 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040385 Site: MW-11 BR 0-2 Collection Date: 14-Apr-15 2:50 PM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 5 of 58 Sample #: 2015011114 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040385 Site: MW-11 BR 30-32 Collection Date: 15-Apr-15 12:30 PM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 6 of 58 Sample #: 2015011115 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE -- Additional Information -- Sample 2015011115: Blank for sulfate by method 300.0 is 3.4 mg/L. Sulfate result for this sample is 3.0 mg/L. Result is suspect. M. Galvin -Karr 6/6/2015 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kic&fie. Suite 100 Huntersville, INC 28078 (704)875-9092 May 13, 2015 Program Manager Duke Energy 13339 Hagers Ferry Road Bldg.7405 MG30A2 Huntersville, NC 28078 RE: Project: J 15040385 Pace Project No.: 92246033 Dear Program Manager: Enclosed are the analytical results for sample(s) received by the laboratory on April 17, 2015. The results relate only to the samples included in this report. Results reported herein conform to the most current TN standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Herring kevin.herring@pacelabs.com HORIZON Database Administrator Enclosures cc: Marge Galvin -Karr, Duke Energy Program Manager, Duke Energy Rodney Wilke, Duke Energy p«FO REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, lqe� �� without the written consent of Pace Analytical Services, Inc.. BRAT, Page 1 of 51 lacmnalyfica( www.pacelabs.com Pace Analytical Services, Inc. 9800 Kinfb6ge. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040385 Pace Project No.: 92246033 Minnesota Certification IDs 1700 Elm Street SE Suite 200, Minneapolis, MN 55414 A21-A Certification #: 2926.01 Alaska Certification #: UST-078 Alaska Certification #MN00064 Alabama Certification #40770 Arizona Certification #: AZ-0014 Arkansas Certification #: 88-0680 California Certification #: 01155CA Colorado Certification #Pace Connecticut Certification #: PH-0256 EPA Region 8 Certification #: 8TMS-L Florida/NELAP Certification #: E87605 Guam Certification #:14-008r Georgia Certification #: 959 Georgia EPD #: Pace Idaho Certification #: MN00064 Hawaii Certification #MN00064 Illinois Certification #: 200011 Indiana Certification#C-MN-01 Iowa Certification #: 368 Kansas Certification #: E-10167 Kentucky Dept of Envi. Protection - DW #90062 Kentucky Dept of Envi. Protection - WW #:90062 Louisiana DEQ Certification #: 3086 Louisiana DHH #: LA140001 Maine Certification #: 2013011 Maryland Certification #: 322 Michigan DEPH Certification #: 9909 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification #: 41320 Connecticut Certification #: PH-0216 Delaware Certification: FL NELAC Reciprocity Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Massachusetts Certification #: M-FL1264 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Green Bay Certification IDs 1241 Bellevue Street, Green Bay, WI 54302 Florida/NELAP Certification #: E87948 Illinois Certification #: 200050 Kentucky Certification #: 82 Louisiana Certification #: 04168 Minnesota Certification #: 055-999-334 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 CERTIFICATIONS Minnesota Certification #: 027-053-137 Mississippi Certification #: Pace Montana Certification #: MT0092 Nevada Certification #: MN_00064 Nebraska Certification #: Pace New Jersey Certification #: MN-002 New York Certification #: 11647 North Carolina Certification #: 530 North Carolina State Public Health #: 27700 North Dakota Certification #: R-036 Ohio EPA#: 4150 Ohio VAP Certification #: CL101 Oklahoma Certification #: 9507 Oregon Certification #: MN200001 Oregon Certification #: MN300001 Pennsylvania Certification #: 68-00563 Puerto Rico Certification Saipan (CNMI) #:MP0003 South Carolina #:74003001 Texas Certification #: T104704192 Tennessee Certification #: 02818 Utah Certification #: MN000642013-4 Virginia DGS Certification #: 251 Virginia/VELAP Certification #: Pace Washington Certification #: C486 West Virginia Certification #: 382 West Virginia DHHR #:9952C Wisconsin Certification #: 999407970 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 Nevada Certification: FL NELAC Reciprocity New Hampshire Certification #: 2958 New Jersey Certification #: FL765 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FLO1264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 Washington Certification #: C955 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity North Dakota Certification #: R-150 South Carolina Certification #: 83006001 Texas Certification #: T104704529-14-1 US Dept of Agriculture #: S-76505 Wisconsin Certification #: 405132750 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 2 of 51 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kigc&y&ie. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040385 Pace Project No.: 92246033 Asheville Certification IDs North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 CERTIFICATIONS West Virginia Certification #: 356 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 3 of 51 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ff�i�c&� �e. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: J15040385 Pace Project No.: 92246033 Lab ID Sample ID Matrix Date Collected Date Received 92246033001 2015011113 Water 04/14/1514:30 04/17/1512:40 92246033002 2015011114 Solid 04/14/1514:50 04/17/1512:40 92246033003 2015011115 Solid 04/15/1512:30 04/17/1512:40 92246033004 2015011115 SPLP Water 04/15/15 12:30 04/17/15 12:40 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 4 of 51 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 fflinl c&� �e. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: J15040385 92246033 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92246033001 2015011113 EPA 6020A RJS 24 PASI-M EPA 7470A LMW 1 PASI-M 92246033002 2015011114 EPA 6010 TAP 16 PASI-0 EPA 6020 DRS 8 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 MLO 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92246033003 2015011115 EPA 6010 TAP 16 PASI-0 EPA 6020 DRS 8 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 MLO 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 300.0 AES2 1 PASI-A EPA 353.2 DMN 1 PASI-A SM 4500-CI-E SER 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92246033004 2015011115 SPLP EPA 6020A TT3 24 PASI-M EPA 7470A JDD 1 PASI-M REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 5 of 51 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffli�c&� �e. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040385 Pace Project No.: 92246033 Lab Sample ID Client Sample ID Method Parameters SUMMARY OF DETECTION Result Units Report Limit Analyzed 92246033001 2015011113 EPA 6020A Aluminum 36.3 ug/L 10.0 04/23/15 19:27 EPA 6020A Barium 1.2 ug/L 0.30 04/23/15 19:27 EPA 6020A Calcium 417 ug/L 40.0 04/23/15 19:27 EPA 6020A Chromium 0.52 ug/L 0.50 04/23/15 19:27 EPA 6020A Cobalt 1.2 ug/L 0.50 04/23/15 19:27 EPA 6020A Copper 1.9 ug/L 1.0 04/23/15 19:27 EPA 6020A Iron 121 ug/L 50.0 04/23/15 19:27 EPA 6020A Lead 0.15 ug/L 0.10 04/23/15 19:27 EPA 6020A Magnesium 27.4 ug/L 10.0 04/23/15 19:27 EPA 6020A Manganese 4.1 ug/L 0.50 04/23/15 19:27 EPA 6020A Molybdenum 0.73 ug/L 0.50 04/23/15 19:27 EPA 6020A Potassium 122 ug/L 50.0 04/23/15 19:27 EPA 6020A Sodium 108 ug/L 50.0 04/23/15 19:27 EPA 6020A Strontium 0.81 ug/L 0.50 04/23/15 19:27 EPA 6020A Zinc 9.4 ug/L 5.0 04/23/15 19:27 EPA 7470A Mercury 0.030J ug/L 0.20 04/23/15 20:53 92246033002 2015011114 EPA 6010 Aluminum 19700 mg/kg 37.6 04/29/15 09:10 EPA 6010 Barium 43.1 mg/kg 3.8 04/29/15 09:10 EPA 6010 Calcium 1690 mg/kg 188 04/29/15 09:10 EPA 6010 Chromium 22.6 mg/kg 1.9 04/29/15 09:10 EPA 6010 Copper 59.1 mg/kg 1.9 04/29/15 09:10 EPA 6010 Iron 52900 mg/kg 15.1 04/29/15 09:10 EPA 6010 Magnesium 1590 mg/kg 188 04/29/15 09:10 EPA 6010 Manganese 52.6 mg/kg 1.9 04/29/15 09:10 EPA 6010 Nickel 1 AJ mg/kg 1.9 04/29/15 09:10 EPA 6010 Strontium 18.6 mg/kg 3.8 04/29/15 09:10 EPA 6010 Zinc 17.2 mg/kg 7.5 04/29/15 09:10 EPA 6020 Cobalt 6AJ mg/kg 7.5 04/27/15 23:51 EPA 6020 Lead 6.1J mg/kg 7.5 04/27/15 23:51 EPA 6020 Vanadium 208 mg/kg 7.5 04/27/15 23:51 EPA 7471 Mercury 0.13 mg/kg 0.012 04/26/15 19:35 ASTM D2974-87 Percent Moisture 31.6 % 0.10 04/30/15 14:21 D6 EPA 9045 pH at 25 Degrees C 5.2 Std. Units 0.10 04/23/15 10:00 EPA 9060 Total Organic Carbon 3010 mg/kg 883 05/11/15 21:38 EPA 9060 Total Organic Carbon 2910 mg/kg 874 05/11/15 21:44 EPA 9060 Total Organic Carbon 2840 mg/kg 875 05/11/15 21:51 EPA 9060 Total Organic Carbon 3030 mg/kg 878 05/11/15 21:59 EPA 9060 Mean Total Organic Carbon 2950 mg/kg 878 05/11/15 21:38 EPA 9060 RSD% 3.0 % 05/11/15 21:38 92246033003 2015011115 EPA 6010 Aluminum 15000 mg/kg 26.3 04/29/15 09:14 EPA 6010 Barium 179 mg/kg 2.6 04/29/15 09:14 EPA 6010 Calcium 4700 mg/kg 131 04/29/15 09:14 EPA 6010 Chromium 2.3 mg/kg 1.3 04/29/15 09:14 EPA 6010 Copper 363 mg/kg 1.3 04/29/15 09:14 REPORT OF LABORATORY ANALYSIS Qualifiers This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 6 of 51 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffli�c&� �e. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040385 Pace Project No.: 92246033 Lab Sample ID Client Sample ID Method Parameters SUMMARY OF DETECTION Result Units Report Limit Analyzed Qualifiers 92246033003 2015011115 EPA 6010 Iron 44000 mg/kg 10.5 04/29/15 09:14 EPA 6010 Magnesium 12200 mg/kg 131 04/29/15 09:14 EPA 6010 Manganese 212 mg/kg 1.3 04/29/15 09:14 EPA 6010 Nickel 16.2 mg/kg 1.3 04/29/15 09:14 EPA 6010 Potassium 5870 mg/kg 263 04/29/15 09:14 EPA 6010 Strontium 23.7 mg/kg 2.6 04/29/15 09:14 EPA 6010 Zinc 64.7 mg/kg 5.3 04/29/15 09:14 EPA 6020 Cobalt 40.9 mg/kg 5.3 04/27/15 23:53 EPA 6020 Vanadium 191 mg/kg 5.3 04/27/15 23:53 ASTM D2974-87 Percent Moisture 2.5 % 0.10 04/30/15 14:21 EPA 9045 pH at 25 Degrees C 7.4 Std. Units 0.10 04/23/15 10:00 EPA 300.0 Sulfate 3.0 mg/L 2.1 04/29/15 17:46 B EPA 9060 RSD% 3.9 % 05/12/15 09:30 92246033004 2015011115 SPLP EPA 6020A Aluminum 13100 ug/L 10.0 05/04/15 16:49 EPA 6020A Arsenic 1.5 ug/L 0.50 05/04/15 16:49 EPA 6020A Barium 350 ug/L 0.30 05/04/15 16:49 EPA 6020A Beryllium 0.18J ug/L 0.20 05/04/15 16:49 EPA 6020A Boron 52.2 ug/L 5.0 05/04/15 16:49 EPA 6020A Cadmium 0.14 ug/L 0.080 05/04/15 16:49 EPA 6020A Calcium 4600 ug/L 40.0 05/04/15 16:49 EPA 6020A Chromium 4.0 ug/L 0.50 05/04/15 16:49 EPA 6020A Cobalt 26.5 ug/L 0.50 05/04/15 16:49 EPA 6020A Copper 617 ug/L 200 05/05/15 16:15 EPA 6020A Iron 49600 ug/L 10000 05/05/15 16:15 EPA 6020A Lead 1.0 ug/L 0.10 05/04/15 16:49 EPA 6020A Magnesium 7320 ug/L 10.0 05/04/15 16:49 EPA 6020A Manganese 231 ug/L 0.50 05/04/15 16:49 EPA 6020A Molybdenum 4.4 ug/L 0.50 05/04/15 16:49 EPA 6020A Nickel 14.2 ug/L 0.50 05/04/15 16:49 EPA 6020A Potassium 2590 ug/L 50.0 05/04/15 16:49 EPA 6020A Sodium 2180 ug/L 50.0 05/04/15 16:49 EPA 6020A Strontium 29.4 ug/L 0.50 05/04/15 16:49 EPA 6020A Thallium 0.046J ug/L 0.10 05/04/15 16:49 EPA 6020A Vanadium 213 ug/L 1.0 05/04/15 16:49 EPA 6020A Zinc 179 ug/L 5.0 05/04/15 16:49 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 7 of 51 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 fflic&) �e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040385 Pace Project No.: 92246033 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: May 13, 2015 General Information: 2 samples were analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/23799 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92246059001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1193768) • Aluminum • Barium • Boron • Iron • Molybdenum • MSD (Lab ID: 1193769) • Aluminum • Barium • Iron R1: RPD value was outside control limits. • MSD (Lab ID: 1193769) • Aluminum • Barium • Iron REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 8 of 51 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffli�c&� �e. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040385 Pace Project No.: 92246033 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: May 13, 2015 Additional Comments: PROJECT NARRATIVE REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 9 of 51 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffli�c&) �e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040385 Pace Project No.: 92246033 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: May 13, 2015 General Information: 2 samples were analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/23800 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92246059001 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • MS (Lab ID: 1193774) • Antimony • Arsenic • Cadmium • Selenium • Vanadium • MSD (Lab ID: 1193775) • Antimony • Arsenic • Selenium • Vanadium Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 10 of 51 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffiic&� �e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040385 Pace Project No.: 92246033 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: May 13, 2015 Analyte Comments: QC Batch: MPRP/23800 N2: The lab does not hold TNI accreditation for this parameter. •2015011114 (Lab ID:92246033002) • Antimony •2015011115 (Lab ID:92246033003) • Antimony • BLANK (Lab ID: 1193772) • Antimony • LCS (Lab ID: 1193773) • Antimony • MS (Lab ID: 1193774) • Antimony • MSD (Lab ID: 1193775) • Antimony REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 11 of 51 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffligc&) �e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040385 Pace Project No.: 92246033 Method: EPA 6020A Description: 6020A MET ICPMS Client: Duke Energy Date: May 13, 2015 General Information: 2 samples were analyzed for EPA 6020A. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3020 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/53822 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92246088001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1945457) • Aluminum • MSD (Lab ID: 1945458) • Aluminum QC Batch: MPRP/54102 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92247835001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1954383) • Aluminum • Calcium • Iron • Magnesium • MSD (Lab ID: 1954384) REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 12 of 51 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kiigc&y&ie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040385 Pace Project No.: 92246033 Method: EPA 6020A Description: 6020A MET ICPMS Client: Duke Energy Date: May 13, 2015 QC Batch: MPRP/54102 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92247835001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • Aluminum • Calcium • Iron • Magnesium • Thallium Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 13 of 51 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KP�c&) �e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040385 Pace Project No.: 92246033 Method: EPA 7470A Description: 7470A Mercury Client: Duke Energy Date: May 13, 2015 General Information: 2 samples were analyzed for EPA 7470A. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7470A with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 14 of 51 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K�nic&) �e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040385 Pace Project No.: 92246033 Method: EPA 7471 Description: 7471 Mercury Client: Duke Energy Date: May 13, 2015 General Information: 2 samples were analyzed for EPA 7471. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7471 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 15 of 51 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KP�c&� �e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040385 Pace Project No.: 92246033 Method: EPA 9045 Description: 9045 pH Soil Client: Duke Energy Date: May 13, 2015 General Information: 2 samples were analyzed for EPA 9045. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Duplicate Sample: All duplicate sample results were within method acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 16 of 51 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KP�c&� �e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040385 Pace Project No.: 92246033 Method: EPA 300.0 Description: 300.0 IC Anions, SPLP Client: Duke Energy Date: May 13, 2015 General Information: 1 sample was analyzed for EPA 300.0. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. QC Batch: WETA/22735 B: Analyte was detected in the associated method blank. • BLANK for HBN 261569 [WETA/227 (Lab ID: 1445696) • Sulfate Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 17 of 51 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KPc&) �e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040385 Pace Project No.: 92246033 Method: EPA 353.2 Description: 353.2 Nitrogen, NO2/NO3, SPLP Client: Duke Energy Date: May 13, 2015 General Information: 1 sample was analyzed for EPA 353.2. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 1-11: Analysis conducted outside the EPA method holding time. •2015011115 (Lab ID:92246033003) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 18 of 51 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KP�c&� �e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040385 Pace Project No.: 92246033 Method: SM 4500-CI-E Description: 4500 Chloride, SPLP Client: Duke Energy Date: May 13, 2015 General Information: 1 sample was analyzed for SM 4500-CI-E. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 19 of 51 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K��c&� �e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040385 Pace Project No.: 92246033 Method: EPA 9056 Description: 9056 IC Anions Client: Duke Energy Date: May 13, 2015 General Information: 2 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/45717 DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015011114 (Lab ID:92246033002) • Chloride • Sulfate •2015011115 (Lab ID:92246033003) • Chloride • Sulfate REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 20 of 51 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K�c&) �e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040385 Pace Project No.: 92246033 Method: EPA 9056 Description: 9056 IC Anions 48hr Client: Duke Energy Date: May 13, 2015 General Information: 2 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 1-13: Sample was received or analysis requested beyond the recognized method holding time. •2015011114 (Lab ID:92246033002) •2015011115 (Lab ID:92246033003) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 21 of 51 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KPgc&� �e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040385 Pace Project No.: 92246033 Method: EPA 9060 Description: Total Organic Carbon Quad Client: Duke Energy Date: May 13, 2015 General Information: 2 samples were analyzed for EPA 9060. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: This data package has been reviewed for quality and completeness and is approved for release. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 22 of 51 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K��c&� �e. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15040385 Pace Project No.: 92246033 Sample: 2015011113 Lab ID: 92246033001 Collected: 04/14/15 14:30 Received: 04/17/15 12:40 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;I➢ZI7c\�i,I=11 l[99�� 6? Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470A Mercury Mercury Date: 05/13/2015 07:40 AM Analytical Method: EPA 6020A Preparation Method: EPA 3020 36.3 ug/L 10.0 3.0 1 04/22/1514:55 04/23/1519:27 7429-90-5 ND ug/L 0.50 0.15 1 04/22/1514:55 04/23/1519:27 7440-36-0 ND ug/L 0.50 0.11 1 04/22/1514:55 04/23/1519:27 7440-38-2 1.2 ug/L 0.30 0.081 1 04/22/1514:55 04/23/1519:27 7440-39-3 ND ug/L 0.20 0.067 1 04/22/1514:55 04/23/1519:27 7440-41-7 ND ug/L 5.0 1.1 1 04/22/1514:55 04/23/1519:27 7440-42-8 ND ug/L 0.080 0.024 1 04/22/1514:55 04/23/1519:27 7440-43-9 417 ug/L 40.0 16.0 1 04/22/1514:55 04/23/1519:27 7440-70-2 0.52 ug/L 0.50 0.17 1 04/22/1514:55 04/23/1519:27 7440-47-3 1.2 ug/L 0.50 0.13 1 04/22/1514:55 04/23/1519:27 7440-48-4 1.9 ug/L 1.0 0.21 1 04/22/1514:55 04/23/1519:27 7440-50-8 121 ug/L 50.0 13.7 1 04/22/1514:55 04/23/1519:27 7439-89-6 0.15 ug/L 0.10 0.046 1 04/22/1514:55 04/23/1519:27 7439-92-1 27.4 ug/L 10.0 3.2 1 04/22/1514:55 04/23/1519:27 7439-95-4 4.1 ug/L 0.50 0.24 1 04/22/1514:55 04/23/1519:27 7439-96-5 0.73 ug/L 0.50 0.094 1 04/22/1514:55 04/23/1519:27 7439-98-7 ND ug/L 0.50 0.16 1 04/22/1514:55 04/23/1519:27 7440-02-0 122 ug/L 50.0 11.7 1 04/22/1514:55 04/23/1519:27 7440-09-7 ND ug/L 0.50 0.20 1 04/22/1514:55 04/23/1519:27 7782-49-2 108 ug/L 50.0 16.3 1 04/22/1514:55 04/23/1519:27 7440-23-5 0.81 ug/L 0.50 0.13 1 04/22/1514:55 04/23/1519:27 7440-24-6 ND ug/L 0.10 0.015 1 04/22/1514:55 04/23/1519:27 7440-28-0 ND ug/L 1.0 0.28 1 04/22/1514:55 04/23/1519:27 7440-62-2 9.4 ug/L 5.0 2.4 1 04/22/1514:55 04/23/1519:27 7440-66-6 Analytical Method: EPA 7470A Preparation Method: EPA 7470A 0.030J ug/L 0.20 0.022 1 04/22/15 17:55 04/23/15 20:53 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 23 of 51 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K��c&� �e. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15040385 Pace Project No.: 92246033 Sample: 2015011114 Lab ID: 92246033002 Collected: 04/14/15 14:50 Received: 04/17/15 12:40 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 19700 mg/kg 37.6 18.8 5 04/25/15 19:00 04/29/15 09:10 7429-90-5 Barium 43.1 mg/kg 3.8 1.9 5 04/25/15 19:00 04/29/15 09:10 7440-39-3 Beryllium ND mg/kg 0.38 0.19 5 04/25/15 19:00 04/29/15 09:10 7440-41-7 Boron ND mg/kg 18.8 9.4 5 04/25/15 19:00 04/29/15 09:10 7440-42-8 Calcium 1690 mg/kg 188 94.1 5 04/25/15 19:00 04/29/15 09:10 7440-70-2 Chromium 22.6 mg/kg 1.9 0.94 5 04/25/15 19:00 04/29/15 09:10 7440-47-3 Copper 59.1 mg/kg 1.9 0.94 5 04/25/15 19:00 04/29/15 09:10 7440-50-8 Iron 52900 mg/kg 15.1 7.5 5 04/25/15 19:00 04/29/15 09:10 7439-89-6 Magnesium 1590 mg/kg 188 94.1 5 04/25/15 19:00 04/29/15 09:10 7439-95-4 Manganese 52.6 mg/kg 1.9 0.94 5 04/25/15 19:00 04/29/15 09:10 7439-96-5 Molybdenum ND mg/kg 3.8 1.9 5 04/25/15 19:00 04/29/15 09:10 7439-98-7 Nickel 1.4J mg/kg 1.9 0.94 5 04/25/15 19:00 04/29/15 09:10 7440-02-0 Potassium ND mg/kg 376 188 5 04/25/15 19:00 04/29/15 09:10 7440-09-7 Sodium ND mg/kg 376 188 5 04/25/15 19:00 04/29/15 09:10 7440-23-5 Strontium 18.6 mg/kg 3.8 1.9 5 04/25/15 19:00 04/29/15 09:10 7440-24-6 Zinc 17.2 mg/kg 7.5 3.8 5 04/25/15 19:00 04/29/15 09:10 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 7.5 3.7 100 04/25/15 19:00 04/27/15 23:51 7440-36-0 N2 Arsenic ND mg/kg 7.5 3.7 100 04/25/15 19:00 04/27/15 23:51 7440-38-2 Cadmium ND mg/kg 0.89 0.45 100 04/25/15 19:00 04/27/15 23:51 7440-43-9 Cobalt 6AJ mg/kg 7.5 3.7 100 04/25/15 19:00 04/27/15 23:51 7440-48-4 Lead 6.1J mg/kg 7.5 3.7 100 04/25/15 19:00 04/27/15 23:51 7439-92-1 Selenium ND mg/kg 7.5 3.7 100 04/25/15 19:00 04/27/15 23:51 7782-49-2 Thallium ND mg/kg 7.5 3.7 100 04/25/15 19:00 04/27/15 23:51 7440-28-0 Vanadium 208 mg/kg 7.5 3.7 100 04/25/15 19:00 04/27/15 23:51 7440-62-2 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury 0.13 mg/kg 0.012 0.0060 1 04/25/1519:20 04/26/1519:35 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 31.6 % 0.10 0.10 1 04/30/15 14:21 D6 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 5.2 Std. Units 0.10 0.10 1 04/23/15 10:00 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 354 177 5 04/23/1518:23 16887-00-6 D3,M1 Sulfate ND mg/kg 354 177 5 04/23/1518:23 14808-79-8 D3,M1 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 35.4 17.7 5 04/23/15 18:23 14797-55-8 H3 Date: 05/13/2015 07:40 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 24 of 51 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K�n�c&� �e. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15040385 Pace Project No.: 92246033 Sample: 2015011114 Lab ID: 92246033002 Collected: 04/14/15 14:50 Received: 04/17/15 12:40 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 3010 mg/kg 883 442 1 05/11/15 21:38 7440-44-0 Total Organic Carbon 2910 mg/kg 874 437 1 05/11/15 21:44 7440-44-0 Total Organic Carbon 2840 mg/kg 875 438 1 05/11/15 21:51 7440-44-0 Total Organic Carbon 3030 mg/kg 878 439 1 05/11/15 21:59 7440-44-0 Mean Total Organic Carbon 2950 mg/kg 878 439 1 05/11/15 21:38 7440-44-0 Surrogates RSD% 3.0 % 1 05/11/15 21:38 Date: 05/13/2015 07:40 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 25 of 51 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K3�c&� �e. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15040385 Pace Project No.: 92246033 Sample: 2015011115 Lab ID: 92246033003 Collected: 04/15/15 12:30 Received: 04/17/15 12:40 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Aluminum Barium Beryllium Boron Calcium Chromium Copper Iron Magnesium Manganese Molybdenum Nickel Potassium Sodium Strontium Zinc 6020 MET ICPMS Antimony Arsenic Cadmium Cobalt Lead Selenium Thallium Vanadium 7471 Mercury Mercury Percent Moisture Percent Moisture 9045 pH Soil pH at 25 Degrees C 300.0 IC Anions, SPLP Sulfate 353.2 Nitrogen, NO2/NO3, SPLP Nitrogen, Nitrate 4500 Chloride, SPLP Chloride Date: 05/13/2015 07:40 AM Analytical Method: EPA 6010 Preparation Method: EPA 3050 15000 mg/kg 26.3 13.1 5 04/25/15 19:00 04/29/15 09:14 7429-90-5 179 mg/kg 2.6 1.3 5 04/25/15 19:00 04/29/15 09:14 7440-39-3 ND mg/kg 0.26 0.13 5 04/25/15 19:00 04/29/15 09:14 7440-41-7 ND mg/kg 13.1 6.6 5 04/25/15 19:00 04/29/15 09:14 7440-42-8 4700 mg/kg 131 65.7 5 04/25/15 19:00 04/29/15 09:14 7440-70-2 2.3 mg/kg 1.3 0.66 5 04/25/15 19:00 04/29/15 09:14 7440-47-3 363 mg/kg 1.3 0.66 5 04/25/15 19:00 04/29/15 09:14 7440-50-8 44000 mg/kg 10.5 5.3 5 04/25/15 19:00 04/29/15 09:14 7439-89-6 12200 mg/kg 131 65.7 5 04/25/15 19:00 04/29/15 09:14 7439-95-4 212 mg/kg 1.3 0.66 5 04/25/15 19:00 04/29/15 09:14 7439-96-5 ND mg/kg 2.6 1.3 5 04/25/15 19:00 04/29/15 09:14 7439-98-7 16.2 mg/kg 1.3 0.66 5 04/25/15 19:00 04/29/15 09:14 7440-02-0 5870 mg/kg 263 131 5 04/25/15 19:00 04/29/15 09:14 7440-09-7 ND mg/kg 263 131 5 04/25/15 19:00 04/29/15 09:14 7440-23-5 23.7 mg/kg 2.6 1.3 5 04/25/15 19:00 04/29/15 09:14 7440-24-6 64.7 mg/kg 5.3 2.6 5 04/25/15 19:00 04/29/15 09:14 7440-66-6 Analytical Method: EPA 6020 Preparation Method: EPA 3050 ND mg/kg 5.3 2.6 100 04/25/15 19:00 04/27/15 23:53 7440-36-0 ND mg/kg 5.3 2.6 100 04/25/15 19:00 04/27/15 23:53 7440-38-2 ND mg/kg 0.63 0.32 100 04/25/15 19:00 04/27/15 23:53 7440-43-9 40.9 mg/kg 5.3 2.6 100 04/25/15 19:00 04/27/15 23:53 7440-48-4 ND mg/kg 5.3 2.6 100 04/25/15 19:00 04/27/15 23:53 7439-92-1 ND mg/kg 5.3 2.6 100 04/25/15 19:00 04/27/15 23:53 7782-49-2 ND mg/kg 5.3 2.6 100 04/25/15 19:00 04/27/15 23:53 7440-28-0 191 mg/kg 5.3 2.6 100 04/25/15 19:00 04/27/15 23:53 7440-62-2 Analytical Method: EPA 7471 Preparation Method: EPA 7471 ND mg/kg 0.0084 0.0042 1 04/25/1519:20 04/26/1519:37 7439-97-6 Analytical Method: ASTM D2974-87 2.5 % 0.10 0.10 1 04/30/1514:21 Analytical Method: EPA 9045 7.4 Std. Units 0.10 0.10 1 04/23/15 10:00 N2 Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 04/20/15 00:00 3.0 mg/L 2.1 1.0 1 04/29/1517:46 14808-79-8 B Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 04/20/15 00:00 ND mg/L 0.21 0.21 1 04/29/15 21:10 H1 Analytical Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 04/20/15 00:00 ND mg/L 5.1 2.6 1 04/30/15 01:51 16887-00-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 26 of 51 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K3c&� �e. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15040385 Pace Project No.: 92246033 Sample: 2015011115 Lab ID: 92246033003 Collected: 04/15/15 12:30 Received: 04/17/15 12:40 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 257 128 5 04/23/1519:27 16887-00-6 D3 Sulfate ND mg/kg 257 128 5 04/23/1519:27 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 25.7 12.8 5 04/23/15 19:27 14797-55-8 H3 Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon ND mg/kg 614 307 1 05/12/15 09:30 7440-44-0 Total Organic Carbon ND mg/kg 611 306 1 05/12/15 09:36 7440-44-0 Total Organic Carbon ND mg/kg 620 310 1 05/12/15 09:42 7440-44-0 Total Organic Carbon ND mg/kg 611 306 1 05/12/15 09:49 7440-44-0 Mean Total Organic Carbon ND mg/kg 614 307 1 05/12/15 09:30 7440-44-0 Surrogates RSD% 3.9 % 1 05/12/15 09:30 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/13/2015 07:40 AM without the written consent of Pace Analytical Services, Inc.. Page 27 of 51 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K3c&� �e. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15040385 Pace Project No.: 92246033 Sample: 2015011115 SPLP Lab ID: 92246033004 Collected: 04/15/15 12:30 Received: 04/17/15 12:40 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;T➢Z17c\�iil=11 a Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470A Mercury Mercury Date: 05/13/2015 07:40 AM Analytical Method: EPA 6020A Preparation Method: EPA 3020 13100 ug/L 10.0 3.0 1 05/04/15 08:49 05/04/15 16:49 7429-90-5 ND ug/L 0.50 0.15 1 05/04/15 08:49 05/04/15 16:49 7440-36-0 1.5 ug/L 0.50 0.11 1 05/04/15 08:49 05/04/15 16:49 7440-38-2 350 ug/L 0.30 0.081 1 05/04/15 08:49 05/04/15 16:49 7440-39-3 0.18J ug/L 0.20 0.067 1 05/04/15 08:49 05/04/15 16:49 7440-41-7 52.2 ug/L 5.0 1.1 1 05/04/15 08:49 05/04/15 16:49 7440-42-8 0.14 ug/L 0.080 0.024 1 05/04/15 08:49 05/04/15 16:49 7440-43-9 4600 ug/L 40.0 16.0 1 05/04/15 08:49 05/04/15 16:49 7440-70-2 4.0 ug/L 0.50 0.17 1 05/04/15 08:49 05/04/15 16:49 7440-47-3 26.5 ug/L 0.50 0.13 1 05/04/15 08:49 05/04/15 16:49 7440-48-4 617 ug/L 200 42.8 200 05/04/15 08:49 05/05/15 16:15 7440-50-8 49600 ug/L 10000 2740 200 05/04/15 08:49 05/05/15 16:15 7439-89-6 1.0 ug/L 0.10 0.046 1 05/04/15 08:49 05/04/15 16:49 7439-92-1 7320 ug/L 10.0 3.2 1 05/04/15 08:49 05/04/15 16:49 7439-95-4 231 ug/L 0.50 0.24 1 05/04/15 08:49 05/04/15 16:49 7439-96-5 4.4 ug/L 0.50 0.094 1 05/04/15 08:49 05/04/15 16:49 7439-98-7 14.2 ug/L 0.50 0.16 1 05/04/15 08:49 05/04/15 16:49 7440-02-0 2590 ug/L 50.0 11.7 1 05/04/15 08:49 05/04/15 16:49 7440-09-7 ND ug/L 0.50 0.20 1 05/04/15 08:49 05/04/15 16:49 7782-49-2 2180 ug/L 50.0 16.3 1 05/04/15 08:49 05/04/15 16:49 7440-23-5 29.4 ug/L 0.50 0.13 1 05/04/15 08:49 05/04/15 16:49 7440-24-6 0.046J ug/L 0.10 0.015 1 05/04/15 08:49 05/04/15 16:49 7440-28-0 213 ug/L 1.0 0.28 1 05/04/15 08:49 05/04/15 16:49 7440-62-2 179 ug/L 5.0 2.4 1 05/04/15 08:49 05/04/15 16:49 7440-66-6 Analytical Method: EPA 7470A Preparation Method: EPA 7470A ND ug/L 0.20 0.022 1 05/04/15 12:00 05/04/15 20:36 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 28 of 51 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K��c&� �e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040385 Pace Project No.: 92246033 QC Batch: MERP/13313 Analysis Method: EPA 7470A QC Batch Method: EPA 7470A Analysis Description: 7470A Mercury Water Associated Lab Samples: 92246033001 METHOD BLANK: 1945566 Matrix: Water Associated Lab Samples: 92246033001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury ug/L ND 0.20 04/23/15 20:16 LABORATORY CONTROL SAMPLE: 1945567 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 5 5.1 102 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1945568 1945569 MS MSD 92246044001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 5 5 5.2 5.2 103 104 80-120 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/13/2015 07:40 AM without the written consent of Pace Analytical Services, Inc.. Page 29 of 51 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K��c&� �e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040385 Pace Project No.: 92246033 QC Batch: MERP/13418 Analysis Method: EPA 7470A QC Batch Method: EPA 7470A Analysis Description: 7470A Mercury Water Associated Lab Samples: 92246033004 METHOD BLANK: 1954385 Matrix: Water Associated Lab Samples: 92246033004 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury ug/L ND 0.20 05/04/15 20:27 LABORATORY CONTROL SAMPLE: 1954386 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 5 4.8 97 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1954387 1954388 MS MSD 92247835002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 5 5 5.1 5.2 103 103 80-120 0 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/13/2015 07:40 AM without the written consent of Pace Analytical Services, Inc.. Page 30 of 51 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K�c&� �e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040385 Pace Project No.: 92246033 QC Batch: MERP/5633 Analysis Method: EPA 7471 QC Batch Method: EPA 7471 Analysis Description: 7471 Mercury Associated Lab Samples: 92246033002, 92246033003 METHOD BLANK: 1193779 Matrix: Solid Associated Lab Samples: 92246033002, 92246033003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury mg/kg ND 0.0082 04/26/1519:13 LABORATORY CONTROL SAMPLE: 1193780 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury mg/kg .083 0.080 96 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1193781 1193782 MS MSD 92246059001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury mg/kg 0.011 .0898 .091 0.097 0.10 96 99 80-120 3 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/13/2015 07:40 AM without the written consent of Pace Analytical Services, Inc.. Page 31 of 51 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K�gc&� �e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040385 Pace Project No.: 92246033 QC Batch: MPRP/23799 Analysis Method: EPA 6010 QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid Associated Lab Samples: 92246033002, 92246033003 METHOD BLANK: 1193766 Associated Lab Samples: 92246033002, 92246033003 Parameter Units Aluminum mg/kg Barium mg/kg Beryllium mg/kg Boron mg/kg Calcium mg/kg Chromium mg/kg Copper mg/kg Iron mg/kg Magnesium mg/kg Manganese mg/kg Molybdenum mg/kg Nickel mg/kg Potassium mg/kg Sodium mg/kg Strontium mg/kg Zinc mg/kg Matrix: Solid Blank Result Reporting Limit Analyzed ND 5.1 04/29/15 08:25 ND 0.51 04/29/15 08:25 ND 0.051 04/29/15 08:25 ND 2.5 04/29/15 08:25 ND 25.4 04/29/15 08:25 ND 0.25 04/29/15 08:25 ND 0.25 04/29/15 08:25 ND 2.0 04/29/15 08:25 ND 25.4 04/29/15 08:25 ND 0.25 04/29/15 08:25 ND 0.51 04/29/15 08:25 ND 0.25 04/29/15 08:25 ND 50.9 04/29/15 08:25 ND 50.9 04/29/15 08:25 ND 0.51 04/29/15 08:25 ND 1.0 04/29/15 08:25 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 1193767 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Aluminum mg/kg 127 128 101 80-120 Barium mg/kg 12.7 12.7 100 80-120 Beryllium mg/kg 1.3 1.2 96 80-120 Boron mg/kg 127 121 95 80-120 Calcium mg/kg 635 651 103 80-120 Chromium mg/kg 12.7 11.5 90 80-120 Copper mg/kg 12.7 11.8 93 80-120 Iron mg/kg 127 128 101 80-120 Magnesium mg/kg 635 623 98 80-120 Manganese mg/kg 12.7 12.4 98 80-120 Molybdenum mg/kg 12.7 12.3 97 80-120 Nickel mg/kg 12.7 12.6 99 80-120 Potassium mg/kg 635 629 99 80-120 Sodium mg/kg 635 641 101 80-120 Strontium mg/kg 12.7 12.9 101 80-120 Zinc mg/kg 63.5 63.4 100 80-120 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/13/2015 07:40 AM without the written consent of Pace Analytical Services, Inc.. Page 32 of 51 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K��c&� �e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040385 Pace Project No.: 92246033 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1193768 1193769 MS MSD 92246059001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qua] Aluminum mg/kg 3860 146 140 5800 7750 1320 2770 75-125 29 20 M1,R1 Barium mg/kg 21.6 14.6 14 31.1 40.1 65 131 75-125 25 20 M1,R1 Beryllium mg/kg ND 1.52 1.4 1.2 1.4 78 92 75-125 12 20 Boron mg/kg ND 146 140 107 114 72 80 75-125 6 20 M1 Calcium mg/kg ND 731 702 665 738 84 98 75-125 10 20 Chromium mg/kg 2.8 14.6 14 13.9 16.6 76 98 75-125 17 20 Copper mg/kg 1.01 14.6 14 12.1 13.7 76 90 75-125 12 20 Iron mg/kg 1510 146 140 1760 2390 166 621 75-125 30 20 M1,R1 Magnesium mg/kg 127J 731 702 744 868 84 106 75-125 15 20 Manganese mg/kg 5.3 14.6 14 17.9 20.3 86 107 75-125 12 20 Molybdenum mg/kg ND 14.6 14 11.1 11.8 74 82 75-125 6 20 M1 Nickel mg/kg 0.80J 14.6 14 13.0 14.8 84 100 75-125 13 20 Potassium mg/kg ND 731 702 682 748 84 97 75-125 9 20 Sodium mg/kg ND 731 702 584 623 80 89 75-125 6 20 Strontium mg/kg ND 14.6 14 13.7 15.5 85 101 75-125 12 20 Zinc mg/kg ND 73.1 70.2 61.8 68.9 82 95 75-125 11 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/13/2015 07:40 AM without the written consent of Pace Analytical Services, Inc.. Page 33 of 51 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040385 Pace Project No.: 92246033 QC Batch: MPRP/23800 Analysis Method: EPA 6020 QC Batch Method: EPA 3050 Analysis Description: 6020 MET SOLID Associated Lab Samples: 92246033002, 92246033003 METHOD BLANK: 1193772 Matrix: Solid Associated Lab Samples: 92246033002, 92246033003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Antimony mg/kg ND 0.051 04/27/15 23:26 N2 Arsenic mg/kg ND 0.051 04/27/15 23:26 Cadmium mg/kg ND 0.0061 04/27/15 23:26 Cobalt mg/kg ND 0.051 04/27/15 23:26 Lead mg/kg ND 0.051 04/27/15 23:26 Selenium mg/kg ND 0.051 04/27/15 23:26 Thallium mg/kg ND 0.051 04/27/15 23:26 Vanadium mg/kg ND 0.051 04/27/15 23:26 LABORATORY CONTROL SAMPLE: 1193773 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Antimony mg/kg 2.5 2.4 94 80-120 N2 Arsenic mg/kg 2.5 2.4 97 80-120 Cadmium mg/kg .25 0.23 91 80-120 Cobalt mg/kg 2.5 2.4 94 80-120 Lead mg/kg 2.5 2.4 94 80-120 Selenium mg/kg 2.5 2.4 97 80-120 Thallium mg/kg 2.5 2.4 96 80-120 Vanadium mg/kg 2.5 2.4 94 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1193774 1193775 MS MSD 92246059001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony mg/kg ND 3.03 2.92 ND ND 59 58 75-125 20 M6, N2 Arsenic mg/kg ND 3.03 2.92 ND ND 73 69 75-125 20 M6 Cadmium mg/kg ND .303 .292 ND ND 66 102 75-125 20 M6 Cobalt mg/kg ND 3.03 2.92 3AJ 3AJ 98 97 75-125 20 Lead mg/kg 4.1J 3.03 2.92 7.3 7.3 105 109 75-125 1 20 Selenium mg/kg ND 3.03 2.92 ND ND 55 50 75-125 20 M6 Thallium mg/kg ND 3.03 2.92 ND ND 81 81 75-125 20 Vanadium mg/kg 6.2 3.03 2.92 11.2 11.6 168 183 75-125 3 20 M6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/13/2015 07:40 AM without the written consent of Pace Analytical Services, Inc.. Page 34 of 51 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 1inic&� �e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040385 Pace Project No.: 92246033 QC Batch: MPRP/53822 Analysis Method: EPA 6020A QC Batch Method: EPA 3020 Analysis Description: 6020A Water UPD4 Associated Lab Samples: 92246033001 METHOD BLANK: 1945455 Associated Lab Samples: 92246033001 Parameter Units Matrix: Blank Result Water Reporting Limit Analyzed Qualifiers Aluminum ug/L ND 10.0 04/23/1517:17 Antimony ug/L ND 0.50 04/23/1517:17 Arsenic ug/L ND 0.50 04/23/1517:17 Barium ug/L ND 0.30 04/23/1517:17 Beryllium ug/L ND 0.20 04/23/1517:17 Boron ug/L 1.6J 5.0 04/23/1517:17 Cadmium ug/L ND 0.080 04/23/1517:17 Calcium ug/L ND 40.0 04/23/1517:17 Chromium ug/L ND 0.50 04/23/1517:17 Cobalt ug/L ND 0.50 04/23/1517:17 Copper ug/L 0.46J 1.0 04/23/1517:17 Iron ug/L ND 50.0 04/23/1517:17 Lead ug/L ND 0.10 04/23/1517:17 Magnesium ug/L ND 10.0 04/23/1517:17 Manganese ug/L ND 0.50 04/23/1517:17 Molybdenum ug/L ND 0.50 04/23/1517:17 Nickel ug/L 0.38J 0.50 04/23/1517:17 Potassium ug/L ND 50.0 04/23/1517:17 Selenium ug/L ND 0.50 04/23/1517:17 Sodium ug/L ND 50.0 04/23/1517:17 Strontium ug/L ND 0.50 04/23/1517:17 Thallium ug/L 0.016J 0.10 04/23/1517:17 Vanadium ug/L ND 1.0 04/23/1517:17 Zinc ug/L ND 5.0 04/23/1517:17 LABORATORY CONTROL SAMPLE: Parameter 1945456 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Aluminum ug/L 80 83.6 105 80-120 Antimony ug/L 80 77.2 97 80-120 Arsenic ug/L 80 77.4 97 80-120 Barium ug/L 80 77.0 96 80-120 Beryllium ug/L 80 78.9 99 80-120 Boron ug/L 80 82.3 103 80-120 Cadmium ug/L 80 77.8 97 80-120 Calcium ug/L 1000 1010 101 80-120 Chromium ug/L 80 79.6 99 80-120 Cobalt ug/L 80 77.7 97 80-120 Copper ug/L 80 81.6 102 80-120 Iron ug/L 1000 955 96 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/13/2015 07:40 AM without the written consent of Pace Analytical Services, Inc.. Page 35 of 51 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040385 Pace Project No.: 92246033 LABORATORY CONTROL SAMPLE: 1945456 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Lead ug/L 80 80.4 101 80-120 Magnesium ug/L 1000 970 97 80-120 Manganese ug/L 80 79.4 99 80-120 Molybdenum ug/L 80 76.6 96 80-120 Nickel ug/L 80 77.9 97 80-120 Potassium ug/L 1000 974 97 80-120 Selenium ug/L 80 77.9 97 80-120 Sodium ug/L 1000 938 94 80-120 Strontium ug/L 80 76.4 95 80-120 Thallium ug/L 80 83.1 104 80-120 Vanadium ug/L 80 78.3 98 80-120 Zinc ug/L 80 80.8 101 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1945457 1945458 MS MSD 92246088001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum ug/L 36.8 80 80 146 145 137 135 75-125 1 20 M1 Antimony ug/L ND 80 80 79.6 79.2 99 99 75-125 0 20 Arsenic ug/L 0.12J 80 80 79.5 79.6 99 99 75-125 0 20 Barium ug/L 1.1 80 80 81.5 82.8 100 102 75-125 2 20 Beryllium ug/L ND 80 80 78.6 79.4 98 99 75-125 1 20 Boron ug/L ND 80 80 84.7 84.2 105 104 75-125 1 20 Cadmium ug/L ND 80 80 82.0 81.4 102 102 75-125 1 20 Calcium ug/L 138 1000 1000 1230 1250 109 111 75-125 2 20 Chromium ug/L 0.46J 80 80 84.4 85.2 105 106 75-125 1 20 Cobalt ug/L ND 80 80 81.5 82.2 102 103 75-125 1 20 Copper ug/L 0.84J 80 80 85.9 85.9 106 106 75-125 0 20 Iron ug/L 122 1000 1000 1110 1130 99 100 75-125 1 20 Lead ug/L 0.0801 80 80 83.6 85.0 104 106 75-125 2 20 Magnesium ug/L 26.8 1000 1000 1040 1070 101 104 75-125 3 20 Manganese ug/L 2.8 80 80 85.5 86.0 103 104 75-125 1 20 Molybdenum ug/L ND 80 80 79.9 80.9 100 101 75-125 1 20 Nickel ug/L 0.21J 80 80 81.6 82.7 102 103 75-125 1 20 Potassium ug/L 40.2J 1000 1000 1060 1060 102 102 75-125 1 20 Selenium ug/L ND 80 80 82.1 82.1 103 103 75-125 0 20 Sodium ug/L 53.4 1000 1000 1030 1050 98 100 75-125 2 20 Strontium ug/L 0.88 80 80 80.5 81.4 99 101 75-125 1 20 Thallium ug/L ND 80 80 88.1 89.6 110 112 75-125 2 20 Vanadium ug/L ND 80 80 82.7 82.7 103 103 75-125 0 20 Zinc ug/L 2.6J 80 80 85.0 85.8 103 104 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/13/2015 07:40 AM without the written consent of Pace Analytical Services, Inc.. Page 36 of 51 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040385 Pace Project No.: 92246033 QC Batch: MPRP/54102 Analysis Method: EPA 6020A QC Batch Method: EPA 3020 Analysis Description: 6020A Water UPD4 Associated Lab Samples: 92246033004 METHOD BLANK: 1954381 Associated Lab Samples: 92246033004 Parameter Units Aluminum ug/L Antimony ug/L Arsenic ug/L Barium ug/L Beryllium ug/L Boron ug/L Cadmium ug/L Calcium ug/L Chromium ug/L Cobalt ug/L Copper ug/L Iron ug/L Lead ug/L Magnesium ug/L Manganese ug/L Molybdenum ug/L Nickel ug/L Potassium ug/L Selenium ug/L Sodium ug/L Strontium ug/L Thallium ug/L Vanadium ug/L Zinc ug/L Matrix: Water Blank Result Reporting Limit Analyzed ND 10.0 05/04/1516:41 ND 0.50 05/04/1516:41 ND 0.50 05/04/1516:41 ND 0.30 05/04/1516:41 ND 0.20 05/04/1516:41 ND 5.0 05/04/1516:41 ND 0.080 05/04/1516:41 ND 40.0 05/04/1516:41 ND 0.50 05/04/1516:41 ND 0.50 05/04/1516:41 ND 1.0 05/05/1516:04 ND 50.0 05/04/1516:41 ND 0.10 05/04/1516:41 ND 10.0 05/04/1516:41 ND 0.50 05/04/1516:41 ND 0.50 05/04/1516:41 ND 0.50 05/04/1516:41 ND 50.0 05/04/1516:41 ND 0.50 05/04/1516:41 ND 50.0 05/04/1516:41 ND 0.50 05/04/1516:41 ND 0.10 05/04/1516:41 ND 1.0 05/04/1516:41 ND 5.0 05/04/1516:41 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 1954382 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Aluminum ug/L 80 81.4 102 80-120 Antimony ug/L 80 81.8 102 80-120 Arsenic ug/L 80 78.7 98 80-120 Barium ug/L 80 93.0 116 80-120 Beryllium ug/L 80 82.9 104 80-120 Boron ug/L 80 83.9 105 80-120 Cadmium ug/L 80 84.8 106 80-120 Calcium ug/L 1000 1100 110 80-120 Chromium ug/L 80 80.7 101 80-120 Cobalt ug/L 80 82.3 103 80-120 Copper ug/L 80 84.5 106 80-120 Iron ug/L 1000 1100 110 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/13/2015 07:40 AM without the written consent of Pace Analytical Services, Inc.. Page 37 of 51 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040385 Pace Project No.: 92246033 LABORATORY CONTROL SAMPLE: 1954382 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Lead ug/L 80 79.9 100 80-120 Magnesium ug/L 1000 1030 103 80-120 Manganese ug/L 80 78.3 98 80-120 Molybdenum ug/L 80 80.0 100 80-120 Nickel ug/L 80 84.8 106 80-120 Potassium ug/L 1000 975 97 80-120 Selenium ug/L 80 88.1 110 80-120 Sodium ug/L 1000 997 100 80-120 Strontium ug/L 80 85.2 107 80-120 Thallium ug/L 80 91.2 114 80-120 Vanadium ug/L 80 81.0 101 80-120 Zinc ug/L 80 85.9 107 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1954383 1954384 MS MSD 92247835001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum ug/L 2510 80 80 4310 4250 2250 2180 75-125 1 20 M1 Antimony ug/L 0.43J 80 80 73.3 76.3 91 95 75-125 4 20 Arsenic ug/L 0.27J 80 80 80.4 82.5 100 103 75-125 3 20 Barium ug/L 17.0 80 80 107 113 112 120 75-125 6 20 Beryllium ug/L ND 80 80 89.4 92.4 112 115 75-125 3 20 Boron ug/L 4AJ 80 80 102 101 122 121 75-125 1 20 Cadmium ug/L 0.063J 80 80 85.9 88.8 107 111 75-125 3 20 Calcium ug/L 2110 1000 1000 3750 3810 164 170 75-125 1 20 M1 Chromium ug/L 17.4 80 80 102 105 106 110 75-125 3 20 Cobalt ug/L 2.1 80 80 78.7 81.6 96 99 75-125 4 20 Copper ug/L 9.1 80 80 88.0 91.0 99 102 75-125 3 20 Iron ug/L 8200 1000 1000 10200 10500 201 226 75-125 2 20 M1 Lead ug/L 0.51 80 80 79.4 80.8 99 100 75-125 2 20 Magnesium ug/L 990 1000 1000 2400 2430 141 144 75-125 1 20 M1 Manganese ug/L 78.0 80 80 168 175 112 121 75-125 4 20 Molybdenum ug/L 4.8 80 80 86.2 89.6 102 106 75-125 4 20 Nickel ug/L 4.6 80 80 92.2 95.4 109 113 75-125 3 20 Potassium ug/L 775 1000 1000 1660 1720 88 94 75-125 4 20 Selenium ug/L ND 80 80 90.4 91.2 113 114 75-125 1 20 Sodium ug/L 603 1000 1000 1670 1730 107 113 75-125 4 20 Strontium ug/L 13.3 80 80 97.3 102 105 111 75-125 5 20 Thallium ug/L ND 80 80 98.0 102 122 128 75-125 4 20 M1 Vanadium ug/L 9.9 80 80 96.3 98.5 108 111 75-125 2 20 Zinc ug/L 12.2 80 80 97.8 101 107 111 75-125 3 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/13/2015 07:40 AM without the written consent of Pace Analytical Services, Inc.. Page 38 of 51 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040385 Pace Project No.: 92246033 QC Batch: PMST/3517 Analysis Method: ASTM D2974-87 QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture Associated Lab Samples: 92246033002, 92246033003 SAMPLE DUPLICATE: 1199589 92246033002 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 31.6 28.5 11 10 D6 SAMPLE DUPLICATE: 1199590 35185176001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 4.8 4.5 8 10 SAMPLE DUPLICATE: 1199591 92246632007 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 15.8 13.2 18 10 D6 SAMPLE DUPLICATE: 1199592 35185410006 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 1.7 1.1 46 10 D6 SAMPLE DUPLICATE: 1199593 35185410015 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 1.0 1.7 49 10 D6 SAMPLE DUPLICATE: 1199594 35185412002 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 2.7 2.4 10 10 SAMPLE DUPLICATE: 1199595 35185412013 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 2.1 2.1 2 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/13/2015 07:40 AM without the written consent of Pace Analytical Services, Inc.. Page 39 of 51 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040385 Pace Project No.: 92246033 SAMPLE DUPLICATE: 1199596 35185412029 Dup Parameter Units Result Result Percent Moisture % 2.9 3.0 SAMPLE DUPLICATE: 1199597 Parameter Percent Moisture Max RPD RPD Qualifiers 5 10 35185412038 Dup Max Units Result Result RPD RPD Qualifiers % 2.3 2.7 17 10 D6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/13/2015 07:40 AM without the written consent of Pace Analytical Services, Inc.. Page 40 of 51 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040385 Pace Project No.: 92246033 QC Batch: WET/36969 Analysis Method: EPA 9045 QC Batch Method: EPA 9045 Analysis Description: 9045 pH Associated Lab Samples: 92246033002, 92246033003 SAMPLE DUPLICATE: 1439466 92246075024 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 6.6 6.6 1 10 SAMPLE DUPLICATE: 1439467 92246088011 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 7.5 7.5 0 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/13/2015 07:40 AM without the written consent of Pace Analytical Services, Inc.. Page 41 of 51 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040385 Pace Project No.: 92246033 QC Batch: WETA/22735 Analysis Method: EPA 300.0 QC Batch Method: EPA 300.0 Analysis Description: 300.0 IC Anions Associated Lab Samples: 92246033003 METHOD BLANK: 1445696 Matrix: Water Associated Lab Samples: 92246033003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Sulfate mg/L 3.4 2.0 04/29/1513:00 LABORATORY CONTROL SAMPLE: 1445697 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfate mg/L 20 19.4 97 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1445698 1445699 MS MSD 92245352011 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfate mg/L 1.7J 23.9 23.9 23.5 23.2 91 90 1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1445700 1445701 MS MSD 92245637002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfate mg/L 11.0 20 20 31.2 31.3 101 102 0 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/13/2015 07:40 AM without the written consent of Pace Analytical Services, Inc.. Page 42 of 51 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040385 Pace Project No.: 92246033 QC Batch: WETA/22748 Analysis Method: EPA 353.2 QC Batch Method: EPA 353.2 Analysis Description: 353.2 Nitrate + Nitrite, Unpres. Associated Lab Samples: 92246033003 METHOD BLANK: 1446743 Matrix: Water Associated Lab Samples: 92246033003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, Nitrate mg/L 0.15 0.020 04/29/15 20:34 Z2 LABORATORY CONTROL SAMPLE: 1446744 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Nitrate mg/L 2.5 2.6 102 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1446745 1446746 MS MSD 92245352011 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Nitrate mg/L ND 3 3 3.3 3.3 103 103 90-110 0 10 H1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1446747 1446748 MS MSD 92245352012 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Nitrate mg/L ND 3.2 3.2 3.5 3.4 102 102 90-110 0 10 H1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/13/2015 07:40 AM without the written consent of Pace Analytical Services, Inc.. Page 43 of 51 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040385 Pace Project No.: 92246033 QC Batch: WETA/22743 Analysis Method: SM 4500-CI-E QC Batch Method: SM 4500-CI-E Analysis Description: 4500 Chloride Associated Lab Samples: 92246033003 METHOD BLANK: 1446034 Matrix: Water Associated Lab Samples: 92246033003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/L ND 1.0 04/30/15 01:35 LABORATORY CONTROL SAMPLE: 1446035 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloride mg/L 20 21.1 106 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1446036 1446037 MS MSD 92245352011 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride mg/L ND 23.9 23.9 24.6 24.4 102 101 90-110 1 10 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1446038 1446039 MS MSD 92245637002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride mg/L ND 20 20 22.3 22.0 103 101 90-110 1 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/13/2015 07:40 AM without the written consent of Pace Analytical Services, Inc.. Page 44 of 51 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 1j ni c&� �e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040385 Pace Project No.: 92246033 QC Batch: WETA/45717 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92246033002, 92246033003 METHOD BLANK: 1192868 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/kg ND 49.7 04/23/1517:19 Sulfate mg/kg ND 49.7 04/23/1517:19 LABORATORY CONTROL SAMPLE: 1192869 Parameter Units Chloride mg/kg Sulfate mg/kg MATRIX SPIKE SAMPLE: 1192871 Parameter Units Chloride mg/kg Sulfate mg/kg SAMPLE DUPLICATE: 1192870 Parameter Chloride Sulfate Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 507 484 95 80-120 507 484 95 80-120 92246033002 Spike MS MS % Rec Result Conc. Result % Rec Limits Qualifiers ND 706 657 74 80-120 M 1 ND 706 680 79 80-120 M 1 92246033002 Dup Units Result Result mg/kg ND ND mg/kg ND ND Max RPD RPD Qualifiers 20 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/13/2015 07:40 AM without the written consent of Pace Analytical Services, Inc.. Page 45 of 51 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040385 Pace Project No.: 92246033 QC Batch: WETA/45719 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92246033002, 92246033003 METHOD BLANK: 1192877 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrate as N mg/kg ND 5.0 04/23/15 17:19 LABORATORY CONTROL SAMPLE: 1192878 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg 50.7 49.4 97 80-120 MATRIX SPIKE SAMPLE: 1192880 92246033002 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg ND 70.6 65.2 92 80-120 H3 SAMPLE DUPLICATE: 1192879 92246033002 Dup Max Parameter Units Result Result RPD RPD Qualifiers Nitrate as N mg/kg ND ND 20 H3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/13/2015 07:40 AM without the written consent of Pace Analytical Services, Inc.. Page 46 of 51 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040385 Pace Project No.: 92246033 QC Batch: WETA/28413 Analysis Method: EPA 9060 QC Batch Method: EPA 9060 Analysis Description: 9060 TOC Average Associated Lab Samples: 92246033002, 92246033003 METHOD BLANK: 1154316 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mean Total Organic Carbon mg/kg ND 600 05/11/15 09:53 LABORATORY CONTROL SAMPLE: 1154317 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mean Total Organic Carbon mg/kg 120000 118000 99 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1154318 1154319 MS MSD 92245627013 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg 175000 74100 74500 234000 263000 79 118 50-150 12 30 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1154320 1154321 MS MSD 92247019006 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg 524J 6950 6920 6130 6060 81 80 50-150 1 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/13/2015 07:40 AM without the written consent of Pace Analytical Services, Inc.. Page 47 of 51 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: J15040385 Pace Project No.: 92246033 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TN -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-G Pace Analytical Services - Green Bay PASI-M Pace Analytical Services - Minneapolis PASI-O Pace Analytical Services - Ormond Beach ANALYTE QUALIFIERS B Analyte was detected in the associated method blank. D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. D6 The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits. H1 Analysis conducted outside the EPA method holding time. H3 Sample was received or analysis requested beyond the recognized method holding time. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. N2 The lab does not hold TN accreditation for this parameter. R1 RPD value was outside control limits. Z2 Analyte present in the associated method blank above the detection limit. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/13/2015 07:40 AM without the written consent of Pace Analytical Services, Inc.. Page 48 of 51 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: J15040385 Pace Project No.: 92246033 Lab ID Sample ID QC Batch Method QC Batch Analytical Method 92246033002 2015011114 EPA 3050 MPRP/23799 EPA 6010 92246033003 2015011115 EPA 3050 MPRP/23799 EPA 6010 92246033002 2015011114 EPA 3050 MPRP/23800 EPA 6020 92246033003 2015011115 EPA 3050 MPRP/23800 EPA 6020 92246033001 2015011113 EPA 3020 MPRP/53822 EPA 6020A 92246033004 2015011115 SPLP EPA 3020 MPRP/54102 EPA 6020A 92246033001 2015011113 EPA 7470A MERP/13313 EPA 7470A 92246033004 2015011115 SPLP EPA 7470A MERP/13418 EPA 7470A 92246033002 2015011114 EPA 7471 MERP/5633 EPA 7471 92246033003 2015011115 EPA 7471 MERP/5633 EPA 7471 92246033002 2015011114 ASTM D2974-87 PMST/3517 92246033003 2015011115 ASTM D2974-87 PMST/3517 92246033002 2015011114 EPA 9045 WET/36969 92246033003 2015011115 EPA 9045 WET/36969 92246033003 2015011115 EPA 300.0 WETA/22735 92246033003 2015011115 EPA 353.2 WETA/22748 92246033003 2015011115 SM 4500-CI-E WETA/22743 92246033002 2015011114 EPA 9056 WETA/45717 92246033003 2015011115 EPA 9056 WETA/45717 92246033002 2015011114 EPA 9056 WETA/45719 92246033003 2015011115 EPA 9056 WETA/45719 92246033002 2015011114 EPA 9060 WETA/28413 92246033002 2015011114 EPA 9060 WETA/28414 92246033003 2015011115 EPA 9060 WETA/28413 92246033003 2015011115 EPA 9060 WETA/28414 Date: 05/13/2015 07:40 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Analytical Batch ICP/14546 ICP/14546 ICPM/9675 ICPM/9675 ICPM/23912 ICPM/24074 MERC/15479 MERC/15601 MERC/5627 MERC/5627 Page 49 of 51 Document Name: Document Revised: September 22. 2014 20OAnalyfical_ Sample Condition Upon Receipt (SCUR) Page 1 of 2 Document Number: Issuing Authority: f F-CHR-CS-003-rev.15 Pace Huntersville Quality Office Client Name: Courier: ❑ Fed Ex ❑ UPS❑ USPS❑ Client❑��no mmercial❑ ac Other Custody Seal on Cooler/Box Present: ❑ABubble Seals intact: ❑ yes El no 9 Packin Material: ❑ Bubble V❑p . Bags ❑ None ❑ Other Thermometer Used: IR Gun 14 Type of Ice: 6e)t Blue None Samples on ice, cooling process has begun Tamn rnrrcr+inn Fhrfnr T1401 Nn C;orrection Corrected Cooler Tem °C p.: Temp should be above freezing to 6°C Biological Tissue is Frozen: Yes No I Comments: date and Initia[s�pf perso �examining contents: lI ii Chain of Custody Present: ❑ es ❑No El NIA 1. Chain of Custody Filled Out: ❑ s o El NIA 2. Chain of Custody Relinquished: Yes No ❑NIA 3. Sampler Name & Signature on COC: es o ❑NIA 4. Samples Arrived within Hold Time: E Yes ON NIA 5, Short Hold Time Analysis (<72hr): Dyes o NIA 6. Rush Turn Around Time Requested: ❑Yes o ❑NIA 7. Sufficient Volume: es No ❑NIA 8. Correct Containers Used: -Pace Containers Used: ❑ es Dyes ❑No o N/A ❑NIA 9. Containers Intact: es ❑No ❑NIA Filtered volume received for Dissolved tests ❑Yes ❑ 6 Of IA 11. Sample Labels match COC: -Includes date/time/IDIAnalysis Matrix: ❑ s ❑No ❑NIA 12. All containers needing preservation have been checked. All containers needing preservation are found to be in compliance with EPA recommendation.exceptions: VOA, coliform, TOC, O&G, W-DRO (water) ��No Dyes ❑Yes ❑NIA ON �N A 13. Samples checked for dechlorination: Dyes ❑No ❑ IA 14. Headspace in VOA Vials (>6mm): Dyes ❑No NIA 15. Trip Blank Present: Trip Blank Custody Seals Present Pace Trip Blank Lot # (if purchased): ❑Yes ❑No ❑Yes ❑No NIA J:1 IA 1.6. Client Notification! Resolution: Person Contacted: Comments/ Resolution: Date/Time: SCURF Review: t. Date: I SRF Review: Date: ( l Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office ( i.e out of hold, incorrect preservative, out of temp, incorrect containers) Field Data Required? Y 1 N WO#:92246033 �jlll�llllllll Page 50 of 51 Coslomer .mu,l - oav�ple!e �i ._ .... _.. .._.._. .. ___ ._ Fr a � � II •�• I ' o � D � 7 •- --+ -• ��- ._• - Costumer !a :omplete appropriate columns !u� right ^ a D ^� / 1 I C'1 n \l I j I I j I I { p a B m n � C 61 f i I I � D n a y I 3 a 9 7 ^ m € N - T1CD I °n a tr w n Ow Gyn 4 m rT 5 rn a ,7„ Y a z r a u I to cn a 2 61 r 111 N a Ir � o .i > v n a n I C3 H• a Iu t¢il m O x "O ] IT i~ g 1 E I � •, �� m m S° 3 i I CL n- M en'$ p a m ?a FA rn c N�s� m m ja p Q, dam o fV1 is 1 3 a, �' N O 2 V " Kn o a�� 00 -p,I m i GQ cx }_ rCamp. ID $Aijaiys g c °o x 2 I 3 cl 3 o k'o R@[� If �� w taGrab a Anions, Total Metals , H 1- 8 oz jar (PACE) 5 `%`oScLA itdS Ed 12 i TOC 1- 4 oz jar 4 ii 9 3 1. N E (PACE) I m M 8 n 2 z io • I it I� i iC A --i ,a I� I� I �m I r-1 I� I TT I N 1� I i Z I Q 'n I iZ min I� I �I di Si oip iC i DTI I N Qi —4 i� CHAIN OF CUSTODY RECORD AND ANALYSIS RLQUEST FORM Anal"r-al LabcratcAy -5vrv+'Qe5 I I Area Lebo U" Only SYNTERRA EDIT W ; I mw order —x- DUKE Moll rgAe MGGLI" jiluilding 7W) i FAmmu! SOIL sc— ! DISTRIBUTION 13am twpure rfsnv Rd44 ORIGINAL Na LAO. ENERGYN kfumtersvifle. M. 2;W719 ILDF,4Md IN luAa 6 T 1COPY bD CLIENT sAmPLE riumn"m i��ij Wmw WDES. .............. .... ........ 1jPr~ AB Groundwater Asgessmerd -Soil :Yen" PACE CoPW T-amp qcI PO 1142081 sap Et LO 'ERrojacs I O Afi�9,14cn.ay lor ]7jrAziirodelLn_. '-@ uva bo K-r �113- Illm dMid. VW11mr, booctilt accounflop +r®■ bnrni onlatHished moan " iiW mkIlumLid olw— IN- WIWm. -, I) E 1m- mu 6 � inu in mv�;P"mmp oi-mLim a,—.. or If I =1 ,.a� nd 11wss IF) - - -- - - - - - - - LA19 USE OW 1 "Leb 0 J M40" Imo.aaraar.�Samp #p Description or 1id. t tj ck LL- F-LO-L) So I L W F ti r BLANK Q PER PAI m 44 ert a. Pte,tervalivem whim used urmst be Ided wilti in I h mfinuter. W sample ao 0 ca U CxAlect6an 0 I* U a w Lu 1A Collocilan InfOFM060" x t JD CL E Dw%-- T 1� sigimiure CL I- L43 m 17 21 jflM1riqu*W@d By "0-,— A,- OK jai "Requ-esled Tu�"ffiftm-d rib.11".161wd RV AiSipMeV-- c"s -46HF Me A], Sb, Asp Be, He, S. Cd, Ca, Cr, Co, C% Fe, Ph, Mg, Mn,Mo N4. Sr. n V, Z,-i, Wprcury, pH AnIam. C�, Whrat" Sedim" SpL eft Pammwmm - %Salkla, CEC, Particle 84zo OwIrlhutknori, RKox Potential