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Home My WebLink AboutNC0038377_J15040305 Report_20150902+ DUE Analytical Laboratory 1 of66 ENERGY Order Number: Project Name: Customer Name(s): Customer Address: Lab Contact: Report Authorized By: (Signature) Program Comments: 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone:980-875-5245 Fax:980-875-4349 Order Summary Report J15040305 MAYO STEAM - AB GW ASSESSMENT SOIL Tim Hunsucker, Jerry Wylie, Kathy Webb, John Toepfer Margaret Galvin -Karr MXG4644 (101161) 2015.06.0510:06:09 (�-04'00' Margaret Galvin -Karr Phone: 980-875-5219 Date: Please contact the Program Manager (Margaret Galvin -Karr) with any questions regarding this report. Data Flags & Calculations: 6/5/2015 Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Sample M's & Descriptions: 2 of 66 Collection Sample ID Plant/Station Date and Time Collected By Sample Description 2015010590 MAYO STEAM 12-Apr-15 2:30 PM illegible MW-1313R (0-2) 2015010591 MAYO STEAM 13-Apr-15 2:30 PM illegible MW-13BR (52-54) 2015010592 MAYO STEAM 13-Apr-15 2:30 PM illegible MW13BR (52-54) Dup 2015010593 MAYO STEAM 08-Apr-15 1:52 PM illegible MW-09BR-EB 2015010594 MAYO STEAM 12-Apr-15 2:15 PM illegible MW-13BR-EB 5 Total Samples 3 3 of 66 Technical Validation Review Checklist: COC and .pdf report are in agreement with sample totals Yes No and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. ❑ Yes❑ No All laboratory QA/QC requirements are acceptable.❑ Yes ❑ No Report Sections Included: U Job Summary Report ❑ Sample Identification n Technical Validation of Data Package ❑ Analytical Laboratory Certificate of Analysis ❑ Analytical Laboratory QC Report Sub -contracted Laboratory Results ❑ Customer Specific Data Sheets, Reports, & Documentation ❑ Customer Database Entries 66 Chain of Custody [I/0] Electronic Data Deliverable (EDD) Sent Separately Reviewed By: Anne Pifer Date: 5/26/2015 4 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040305 Site: MW-13BR (0-2) Collection Date: 12-Apr-15 2:30 PM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 4 of 66 Sample #: 2015010590 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE 5 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040305 Site: MW-13BR (52-54) Collection Date: 13-Apr-15 2:30 PM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 5 of 66 Sample #: 2015010591 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE 6 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040305 Site: MW 13BR (52-54) Dup Collection Date: 13-Apr-15 2:30 PM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 6 of 66 Sample #: 2015010592 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE 7 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040305 Site: MW-09BR-EB Collection Date: 08-Apr-15 1:52 PM Analyte Result Units Qualifiers RDL DF METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Sample #: 2015010593 Matrix: SOIL 7 of 66 Method Analysis Date/Time Analyst Vendor Method V_PACE 8 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040305 Site: MW-13BR-EB Collection Date: 12-Apr-15 2:15 PM Analyte Result Units Qualifiers RDL DF METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Sample #: 2015010594 Matrix: SOIL 8 of 66 Method Analysis Date/Time Analyst Vendor Method V_PACE ac.Analy�ical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kig,8y&ie. Suite 100 Huntersville, INC 28078 (704)875-9092 May 29, 2015 Program Manager Duke Energy 13339 Hagers Ferry Road Bldg.7405 MG30A2 Huntersville, NC 28078 RE: Project: J 15040305 Pace Project No.: 92245417 Dear Program Manager: Enclosed are the analytical results for sample(s) received by the laboratory on April 14, 2015. The results relate only to the samples included in this report. Results reported herein conform to the most current TN standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Herring kevin.herring@pacelabs.com HORIZON Database Administrator Enclosures cc: Marge Galvin -Karr, Duke Energy Program Manager, Duke Energy Rodney Wilke, Duke Energy p«FO REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, lqe� �� without the written consent of Pace Analytical Services, Inc.. BRAT, Page 1 of 57 lace Analytical www.pacelabs.com Pace Analytical Services, Inc. 9800 FSiinf&e. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040305 Pace Project No.: 92245417 Minnesota Certification IDs 1700 Elm Street SE Suite 200, Minneapolis, MN 55414 A21-A Certification #: 2926.01 Alaska Certification #: UST-078 Alaska Certification #MN00064 Alabama Certification #40770 Arizona Certification #: AZ-0014 Arkansas Certification #: 88-0680 California Certification #: 01155CA Colorado Certification #Pace Connecticut Certification #: PH-0256 EPA Region 8 Certification #: 8TMS-L Florida/NELAP Certification #: E87605 Guam Certification #:14-008r Georgia Certification #: 959 Georgia EPD #: Pace Idaho Certification #: MN00064 Hawaii Certification #MN00064 Illinois Certification #: 200011 Indiana Certification#C-MN-01 Iowa Certification #: 368 Kansas Certification #: E-10167 Kentucky Dept of Envi. Protection - DW #90062 Kentucky Dept of Envi. 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Page 2 of 57 ac.Analy�ical www.pacelabs.com Pace Analytical Services, Inc. 9800 ff�in� c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040305 Pace Project No.: 92245417 Asheville Certification IDs North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 CERTIFICATIONS West Virginia Certification #: 356 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 3 of 57 ac..-.nayical www.pacelabs.com Pace Analytical Services, Inc. 9800 ff�i�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: J15040305 Pace Project No.: 92245417 Lab ID Sample ID Matrix Date Collected Date Received 92245417001 2015010590 Solid 04/12/1514:30 04/14/1515:00 92245417002 2015010591 Solid 04/13/1514:30 04/14/1515:00 92245417003 2015010592 Solid 04/13/1514:30 04/14/1515:00 92245417004 2015010593 Water 04/08/1513:52 04/14/1515:00 92245417005 2015010594 Water 04/12/1514:15 04/14/1515:00 92245417006 2015010590 SPLP Water 04/12/15 14:30 04/14/15 15:00 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 4 of 57 ac.�naly�ical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffli�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: J15040305 Pace Project No.: 92245417 Lab ID Sample ID Method Analysts Analytes Reported Laboratory 92245417001 2015010590 EPA 6010 CKJ, TAP 16 PASI-0 EPA 6020 DRS 8 PASI-O EPA 7471 TAP 1 PASI-O ASTM D2974-87 MLO 1 PASI-O EPA 9045 KAM 1 PASI-O EPA 300.0 AES2 1 PASI-A EPA 353.2 DMN 1 PASI-A SM 4500-CI-E SER 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92245417002 2015010591 EPA 6010 CKJ, TAP 16 PASI-0 EPA 6020 DRS 8 PASI-O EPA 7471 TAP 1 PASI-O ASTM D2974-87 MLO 1 PASI-O EPA 9045 KAM 1 PASI-O EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92245417003 2015010592 EPA 6010 CKJ, TAP 16 PASI-0 EPA 6020 DRS 8 PASI-O EPA 7471 TAP 1 PASI-O ASTM D2974-87 MLO 1 PASI-O EPA 9045 KAM 1 PASI-O EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92245417004 2015010593 EPA 6020A TT3 24 PASI-M EPA 7470 LMW 1 PASI-M 92245417005 2015010594 EPA 6020A TT3 24 PASI-M EPA 7470 LMW 1 PASI-M 92245417006 2015010590 SPLP EPA 6020A TT3 24 PASI-M EPA 7470A JDD 1 PASI-M REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 5 of 57 ac.�naly�ical www.pacelabs.com Pace Analytical Services, Inc. 9800 %c y&.. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040305 Pace Project No.: 92245417 Lab Sample ID Client Sample ID Method Parameters SUMMARY OF DETECTION Result Units Report Limit Analyzed 92245417001 2015010590 EPA 6010 Aluminum 15500 mg/kg 6.5 04/20/15 18:03 EPA 6010 Barium 72.9 mg/kg 0.65 04/20/15 18:03 EPA 6010 Beryllium 0.33 mg/kg 0.065 04/20/15 18:03 EPA 6010 Calcium 38.1 mg/kg 32.6 04/20/15 18:03 EPA 6010 Chromium 6.1 mg/kg 0.33 04/20/15 18:03 EPA 6010 Copper 10.9 mg/kg 0.33 04/20/15 18:03 EPA 6010 Iron 19600 mg/kg 2.6 04/20/15 18:03 EPA 6010 Magnesium 1840 mg/kg 32.6 04/20/15 18:03 EPA 6010 Manganese 82.8 mg/kg 0.33 04/20/15 18:03 EPA 6010 Molybdenum 0.42J mg/kg 0.65 04/20/15 18:03 EPA 6010 Nickel 0.53 mg/kg 0.33 04/20/15 18:03 EPA 6010 Potassium 1360 mg/kg 65.1 04/20/15 18:03 EPA 6010 Strontium 1.8 mg/kg 0.65 04/20/15 18:03 EPA 6010 Zinc 25.4 mg/kg 1.3 04/20/15 18:03 EPA 6020 Lead 6.2J mg/kg 6.5 04/26/15 09:37 EPA 6020 Vanadium 32.4 mg/kg 6.5 04/26/15 09:37 EPA 7471 Mercury 0.029 mg/kg 0.010 04/22/15 10:22 ASTM D2974-87 Percent Moisture 26.2 % 0.10 04/21/15 15:51 EPA 9045 pH at 25 Degrees C 4.9 Std. Units 0.10 05/29/15 12:40 H6 EPA 300.0 Sulfate 6.1 mg/L 2.7 04/29/15 14:49 B EPA 353.2 Nitrogen, Nitrate 0.35 mg/L 0.27 04/29/15 20:57 H1 EPA 9060 Total Organic Carbon 1360 mg/kg 810 05/05/15 07:57 EPA 9060 Total Organic Carbon 1190 mg/kg 813 05/05/15 08:02 EPA 9060 Total Organic Carbon 1260 mg/kg 809 05/05/15 08:09 EPA 9060 Total Organic Carbon 1030 mg/kg 808 05/05/15 08:15 EPA 9060 Mean Total Organic Carbon 1210 mg/kg 810 05/05/15 07:57 EPA 9060 RSD% 11.3 % 05/05/15 07:57 92245417002 2015010591 EPA 6010 Aluminum 4770 mg/kg 5.1 04/20/15 18:40 EPA 6010 Barium 62.3 mg/kg 0.51 04/20/15 18:40 EPA 6010 Beryllium 0.19 mg/kg 0.051 04/20/15 18:40 EPA 6010 Calcium 2300 mg/kg 25.3 04/20/15 18:40 EPA 6010 Chromium 9.2 mg/kg 0.25 04/20/15 18:40 EPA 6010 Copper 48.4 mg/kg 0.25 04/20/15 18:40 EPA 6010 Iron 10400 mg/kg 2.0 04/20/15 18:40 EPA 6010 Magnesium 2370 mg/kg 25.3 04/20/15 18:40 EPA 6010 Manganese 789 mg/kg 2.5 04/21/15 09:58 EPA 6010 Molybdenum 0.75 mg/kg 0.51 04/20/15 18:40 EPA 6010 Nickel 5.8 mg/kg 0.25 04/20/15 18:40 EPA 6010 Potassium 1780 mg/kg 50.6 04/20/15 18:40 EPA 6010 Sodium 133 mg/kg 50.6 04/20/15 18:40 EPA 6010 Strontium 17.6 mg/kg 0.51 04/20/15 18:40 EPA 6010 Zinc 26.8 mg/kg 1.0 04/20/15 18:40 EPA 6020 Cobalt 6.6 mg/kg 5.1 04/26/15 09:39 EPA 6020 Vanadium 13.1 mg/kg 5.1 04/26/15 09:39 ASTM D2974-87 Percent Moisture 4.6 % 0.10 04/21/15 15:52 EPA 9045 pH at 25 Degrees C 8.3 Std. Units 0.10 05/29/15 12:40 H6 REPORT OF LABORATORY ANALYSIS Qualifiers This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 6 of 57 ac.�naly�ical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffli�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040305 Pace Project No.: 92245417 Lab Sample ID Client Sample ID Method Parameters SUMMARY OF DETECTION Result Units Report Limit Analyzed 92245417002 2015010591 EPA 9060 RSD% 8.2 % 05/05/15 09:08 92245417003 2015010592 EPA 6010 Aluminum 4630 mg/kg 5.9 04/20/15 18:44 EPA 6010 Barium 61.5 mg/kg 0.59 04/20/15 18:44 EPA 6010 Beryllium 0.19 mg/kg 0.059 04/20/15 18:44 EPA 6010 Calcium 2250 mg/kg 29.3 04/20/15 18:44 EPA 6010 Chromium 8.7 mg/kg 0.29 04/20/15 18:44 EPA 6010 Copper 38.7 mg/kg 0.29 04/20/15 18:44 EPA 6010 Iron 10200 mg/kg 2.3 04/20/15 18:44 EPA 6010 Magnesium 2730 mg/kg 29.3 04/20/15 18:44 EPA 6010 Manganese 803 mg/kg 2.9 04/21/1510:02 EPA 6010 Molybdenum 0.74 mg/kg 0.59 04/20/15 18:44 EPA 6010 Nickel 8.7 mg/kg 0.29 04/20/15 18:44 EPA 6010 Potassium 1570 mg/kg 58.7 04/20/15 18:44 EPA 6010 Sodium 108 mg/kg 58.7 04/20/15 18:44 EPA 6010 Strontium 18.1 mg/kg 0.59 04/20/15 18:44 EPA 6010 Zinc 30.8 mg/kg 1.2 04/20/15 18:44 EPA 6020 Cobalt 7.2 mg/kg 5.9 04/26/15 09:42 EPA 6020 Vanadium 13.9 mg/kg 5.9 04/26/15 09:42 ASTM D2974-87 Percent Moisture 15.6 % 0.10 04/21/15 15:53 EPA 9045 pH at 25 Degrees C 8.4 Std. Units 0.10 05/29/15 12:40 H6 EPA 9060 RSD% 6.1 % 05/05/15 09:32 92245417004 2015010593 EPA 6020A Aluminum 83.2 ug/L 10.0 04/17/15 14:50 EPA 6020A Arsenic 0.14J ug/L 0.50 04/17/15 14:50 EPA 6020A Barium 4.4 ug/L 0.30 04/17/15 14:50 EPA 6020A Boron 35.7 ug/L 5.0 04/17/15 14:50 EPA 6020A Calcium 445 ug/L 40.0 04/17/15 14:50 EPA 6020A Chromium 3.9 ug/L 0.50 04/17/15 14:50 EPA 6020A Cobalt 29.1 ug/L 0.50 04/17/15 14:50 EPA 6020A Copper 13.7 ug/L 1.0 04/17/15 14:50 EPA 6020A Iron 7230 ug/L 50.0 04/17/15 14:50 EPA 6020A Lead 0.44 ug/L 0.10 04/17/15 14:50 EPA 6020A Magnesium 67.6 ug/L 10.0 04/17/15 14:50 EPA 6020A Manganese 61.7 ug/L 0.50 04/17/15 14:50 EPA 6020A Molybdenum 5.7 ug/L 0.50 04/17/15 14:50 EPA 6020A Nickel 2.3 ug/L 0.50 04/17/15 14:50 EPA 6020A Potassium 41.1J ug/L 50.0 04/17/15 14:50 EPA 6020A Sodium 132 ug/L 50.0 04/17/15 14:50 EPA 6020A Strontium 1.4 ug/L 0.50 04/17/15 14:50 EPA 6020A Zinc 12.9 ug/L 5.0 04/17/15 14:50 92245417005 2015010594 EPA 6020A Aluminum 44.7 ug/L 10.0 04/17/15 14:53 EPA 6020A Barium 0.66 ug/L 0.30 04/17/15 14:53 EPA 6020A Boron 1.5J ug/L 5.0 04/17/15 14:53 EPA 6020A Calcium 157 ug/L 40.0 04/17/15 14:53 REPORT OF LABORATORY ANALYSIS Qualifiers This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 7 of 57 ac.�naly�ical www.pacelabs.com Pace Analytical Services, Inc. 9800 %c y&.. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040305 Pace Project No.: 92245417 Lab Sample ID Method Client Sample ID Parameters 92245417005 2015010594 EPA 6020A Chromium EPA 6020A Copper EPA 6020A Iron EPA 6020A Lead EPA 6020A Magnesium EPA 6020A Manganese EPA 6020A Molybdenum EPA 6020A Nickel EPA 6020A Potassium EPA 6020A Sodium EPA 6020A Strontium EPA 6020A Zinc 92245417006 2015010590 SPLP EPA 6020A Aluminum EPA 6020A Barium EPA 6020A Boron EPA 6020A Calcium EPA 6020A Chromium EPA 6020A Cobalt EPA 6020A Copper EPA 6020A Lead EPA 6020A Magnesium EPA 6020A Manganese EPA 6020A Potassium EPA 6020A Sodium EPA 6020A Strontium EPA 6020A Zinc SUMMARY OF DETECTION Result Units Report Limit Analyzed Qualifiers 1.0 ug/L 0.50 04/17/1514:53 1.7 ug/L 1.0 04/17/1514:53 181 ug/L 50.0 04/17/1514:53 0.20 ug/L 0.10 04/17/1514:53 30.7 ug/L 10.0 04/17/1514:53 4.8 ug/L 0.50 04/17/1514:53 0.21J ug/L 0.50 04/17/1514:53 0.42J ug/L 0.50 04/17/1514:53 23AJ ug/L 50.0 04/17/1514:53 23.7J ug/L 50.0 04/17/1514:53 0.60 ug/L 0.50 04/17/1514:53 11.6 ug/L 5.0 04/17/1514:53 9AJ ug/L 10.0 05/04/1516:46 93.6 ug/L 0.30 05/04/1516:46 42.2 ug/L 5.0 05/04/1516:46 354 ug/L 40.0 05/04/1516:46 0.38J ug/L 0.50 05/04/1516:46 0.20J ug/L 0.50 05/04/1516:46 0.44J ug/L 1.0 05/05/1516:12 0.047J ug/L 0.10 05/04/1516:46 547 ug/L 10.0 05/04/1516:46 3.0 ug/L 0.50 05/04/1516:46 117 ug/L 50.0 05/04/1516:46 1200 ug/L 50.0 05/04/1516:46 6.0 ug/L 0.50 05/04/1516:46 48.8 ug/L 5.0 05/04/1516:46 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 8 of 57 ac.�naly�ical www.pacelabs.com Pace Analytical Services, Inc. 9800 fflic&)e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040305 Pace Project No.: 92245417 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: May 29, 2015 General Information: 3 samples were analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/23700 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92245086014 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1188105) • Aluminum • Barium • Boron • Chromium • Iron • Manganese • Molybdenum • MSD (Lab ID: 1188106) • Aluminum • Barium • Boron • Iron • Manganese • Molybdenum R1: RPD value was outside control limits. • MSD (Lab ID: 1188106) REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 9 of 57 ac.�naly�ical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffligc y&.. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040305 Pace Project No.: 92245417 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: May 29, 2015 QC Batch: MPRP/23700 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92245086014 R1: RPD value was outside control limits. • Manganese Additional Comments: Batch Comments: Samples on this batch were diluted due to the presence of high levels of non -target analytes or other matrix interference. • QC Batch: ICP / 14486 Analyte Comments: QC Batch: MPRP/23700 E: Analyte concentration exceeded the calibration range. The reported result is estimated. • MS (Lab ID: 1188105) • Iron • MSD (Lab ID: 1188106) • Iron REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 10 of 57 ac.�naly�ical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffli�c&)e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040305 Pace Project No.: 92245417 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: May 29, 2015 General Information: 3 samples were analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/23701 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92244601001 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • MS (Lab ID: 1188109) • Antimony • Arsenic • Cadmium • Cobalt • Lead • Thallium • Vanadium • MSD (Lab ID: 1188110) • Antimony • Arsenic • Cadmium • Cobalt • Lead REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 11 of 57 ac.�nayy�ical www.pacelabs.com Pace Analytical Services, Inc. 9800 %c y&.. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040305 Pace Project No.: 92245417 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: May 29, 2015 QC Batch: MPRP/23701 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92244601001 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • Selenium • Thallium • Vanadium Additional Comments: Analyte Comments: QC Batch: MPRP/23701 N2: The lab does not hold TNI accreditation for this parameter. •2015010590 (Lab ID:92245417001) • Antimony •2015010591 (Lab ID:92245417002) • Antimony •2015010592 (Lab ID:92245417003) • Antimony • BLANK (Lab ID: 1188107) • Antimony • LCS (Lab ID: 1188108) • Antimony • MS (Lab ID: 1188109) • Antimony • MSD (Lab ID: 1188110) • Antimony REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 12 of 57 ac.Anayy�ical www.pacelabs.com Pace Analytical Services, Inc. 9800 K�nic&)e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040305 Pace Project No.: 92245417 Method: EPA 6020A Description: 6020A MET ICPMS Client: Duke Energy Date: May 29, 2015 General Information: 3 samples were analyzed for EPA 6020A. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3020 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/54102 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92247835001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1954383) • Aluminum • Calcium • Iron • Magnesium • MSD (Lab ID: 1954384) • Aluminum • Calcium • Iron • Magnesium • Thallium Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 13 of 57 ac.�naly�ical www.pacelabs.com Pace Analytical Services, Inc. 9800 KP�c&)e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040305 Pace Project No.: 92245417 Method: EPA 7470 Description: 7470 Mercury Client: Duke Energy Date: May 29, 2015 General Information: 2 samples were analyzed for EPA 7470. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7470 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 14 of 57 ac.�naly�ical www.pacelabs.com Pace Analytical Services, Inc. 9800 KP�c&)e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040305 Pace Project No.: 92245417 Method: EPA 7470A Description: 7470A Mercury Client: Duke Energy Date: May 29, 2015 General Information: 1 sample was analyzed for EPA 7470A. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7470A with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 15 of 57 ac.�nayy�ical www.pacelabs.com Pace Analytical Services, Inc. 9800 KPc&)e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040305 Pace Project No.: 92245417 Method: EPA 7471 Description: 7471 Mercury Client: Duke Energy Date: May 29, 2015 General Information: 3 samples were analyzed for EPA 7471. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7471 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 16 of 57 ac.�nayical www.pacelabs.com Pace Analytical Services, Inc. 9800 KP�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040305 Pace Project No.: 92245417 Method: EPA 9045 Description: 9045 pH Soil Client: Duke Energy Date: May 29, 2015 General Information: 3 samples were analyzed for EPA 9045. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 1-16: Analysis initiated outside of the 15 minute EPA recommended holding time. •2015010590 (Lab ID:92245417001) •2015010591 (Lab ID:92245417002) •2015010592 (Lab ID:92245417003) Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 17 of 57 ac.�nayical www.pacelabs.com Pace Analytical Services, Inc. 9800 %cy&.. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040305 Pace Project No.: 92245417 Method: EPA 300.0 Description: 300.0 IC Anions, SPLP Client: Duke Energy Date: May 29, 2015 General Information: 1 sample was analyzed for EPA 300.0. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. QC Batch: WETA/22735 B: Analyte was detected in the associated method blank. • BLANK for HBN 261569 [WETA/227 (Lab ID: 1445696) • Sulfate Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 18 of 57 ac.�naly�ical www.pacelabs.com Pace Analytical Services, Inc. 9800 K�c&)e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040305 Pace Project No.: 92245417 Method: EPA 353.2 Description: 353.2 Nitrogen, NO2/NO3, SPLP Client: Duke Energy Date: May 29, 2015 General Information: 1 sample was analyzed for EPA 353.2. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 1-11: Analysis conducted outside the EPA method holding time. •2015010590 (Lab ID:92245417001) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 19 of 57 ac.�naly�ical www.pacelabs.com Pace Analytical Services, Inc. 9800 KPigc y&.. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040305 Pace Project No.: 92245417 Method: SM 4500-CI-E Description: 4500 Chloride, SPLP Client: Duke Energy Date: May 29, 2015 General Information: 1 sample was analyzed for SM 4500-CI-E. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 20 of 57 ac...-.nayical www.pacelabs.com Pace Analytical Services, Inc. 9800 K��c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040305 Pace Project No.: 92245417 Method: EPA 9056 Description: 9056 IC Anions Client: Duke Energy Date: May 29, 2015 General Information: 3 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/45547 DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015010590 (Lab ID:92245417001) • Chloride • Sulfate QC Batch: WETA/45549 DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015010591 (Lab ID:92245417002) • Chloride • Sulfate •2015010592 (Lab ID:92245417003) • Chloride • Sulfate REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 21 of 57 ac.�nayical www.pacelabs.com Pace Analytical Services, Inc. 9800 %cy&.. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040305 Pace Project No.: 92245417 Method: EPA 9056 Description: 9056 IC Anions 48hr Client: Duke Energy Date: May 29, 2015 General Information: 3 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 1-13: Sample was received or analysis requested beyond the recognized method holding time. •2015010590 (Lab ID:92245417001) •2015010591 (Lab ID:92245417002) •2015010592 (Lab ID:92245417003) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 22 of 57 ac.Anayical www.pacelabs.com Pace Analytical Services, Inc. 9800 K�nlc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040305 Pace Project No.: 92245417 Method: EPA 9060 Description: Total Organic Carbon Quad Client: Duke Energy Date: May 29, 2015 General Information: 3 samples were analyzed for EPA 9060. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: This data package has been reviewed for quality and completeness and is approved for release. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 23 of 57 ac.�naly�ical www.pacelabs.com Pace Analytical Services, Inc. 9800 K3�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15040305 Pace Project No.: 92245417 Sample: 2015010590 Lab ID: 92245417001 Collected: 04/12/15 14:30 Received: 04/14/15 15:00 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Aluminum Barium Beryllium Boron Calcium Chromium Copper Iron Magnesium Manganese Molybdenum Nickel Potassium Sodium Strontium Zinc 6020 MET ICPMS Antimony Arsenic Cadmium Cobalt Lead Selenium Thallium Vanadium 7471 Mercury Mercury Percent Moisture Percent Moisture 9045 pH Soil pH at 25 Degrees C 300.0 IC Anions, SPLP Sulfate 353.2 Nitrogen, NO2/NO3, SPLP Nitrogen, Nitrate 4500 Chloride, SPLP Chloride Date: 05/29/2015 02:56 PM Analytical Method: EPA 6010 Preparation Method: EPA 3050 15500 mg/kg 6.5 3.3 1 04/20/15 03:50 04/20/15 18:03 7429-90-5 72.9 mg/kg 0.65 0.33 1 04/20/15 03:50 04/20/15 18:03 7440-39-3 0.33 mg/kg 0.065 0.033 1 04/20/15 03:50 04/20/15 18:03 7440-41-7 ND mg/kg 16.3 8.1 5 04/20/15 03:50 04/21/15 09:50 7440-42-8 38.1 mg/kg 32.6 16.3 1 04/20/15 03:50 04/20/15 18:03 7440-70-2 6.1 mg/kg 0.33 0.16 1 04/20/15 03:50 04/20/15 18:03 7440-47-3 10.9 mg/kg 0.33 0.16 1 04/20/15 03:50 04/20/15 18:03 7440-50-8 19600 mg/kg 2.6 1.3 1 04/20/15 03:50 04/20/15 18:03 7439-89-6 1840 mg/kg 32.6 16.3 1 04/20/15 03:50 04/20/15 18:03 7439-95-4 82.8 mg/kg 0.33 0.16 1 04/20/15 03:50 04/20/15 18:03 7439-96-5 0.42J mg/kg 0.65 0.33 1 04/20/15 03:50 04/20/15 18:03 7439-98-7 0.53 mg/kg 0.33 0.16 1 04/20/15 03:50 04/20/15 18:03 7440-02-0 1360 mg/kg 65.1 32.6 1 04/20/15 03:50 04/20/15 18:03 7440-09-7 ND mg/kg 65.1 32.6 1 04/20/15 03:50 04/20/15 18:03 7440-23-5 1.8 mg/kg 0.65 0.33 1 04/20/15 03:50 04/20/15 18:03 7440-24-6 25.4 mg/kg 1.3 0.65 1 04/20/15 03:50 04/20/15 18:03 7440-66-6 Analytical Method: EPA 6020 Preparation Method: EPA 3050 ND mg/kg 6.5 3.3 100 04/20/15 03:50 04/26/15 09:37 7440-36-0 N2 ND mg/kg 6.5 3.3 100 04/20/15 03:50 04/26/15 09:37 7440-38-2 ND mg/kg 0.78 0.39 100 04/20/15 03:50 04/26/15 09:37 7440-43-9 ND mg/kg 6.5 3.3 100 04/20/15 03:50 04/26/15 09:37 7440-48-4 6.2J mg/kg 6.5 3.3 100 04/20/15 03:50 04/26/15 09:37 7439-92-1 ND mg/kg 6.5 3.3 100 04/20/15 03:50 04/26/15 09:37 7782-49-2 ND mg/kg 6.5 3.3 100 04/20/15 03:50 04/26/15 09:37 7440-28-0 32.4 mg/kg 6.5 3.3 100 04/20/15 03:50 04/26/15 09:37 7440-62-2 Analytical Method: EPA 7471 Preparation Method: EPA 7471 0.029 mg/kg 0.010 0.0051 1 04/21/1514:55 04/22/1510:22 7439-97-6 Analytical Method: ASTM D2974-87 26.2 % 0.10 0.10 1 04/21/1515:51 Analytical Method: EPA 9045 4.9 Std. Units 0.10 0.10 1 05/29/15 12:40 H6 Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 04/16/15 03:15 6.1 mg/L 2.7 1.4 1 04/29/1514:49 14808-79-8 B Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 04/16/15 03:15 0.35 mg/L 0.27 0.27 1 04/29/15 20:57 H1 Analytical Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 04/16/15 03:15 ND mg/L 6.8 3.4 1 04/30/15 01:42 16887-00-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 24 of 57 ac.�naly�ical www.pacelabs.com Pace Analytical Services, Inc. 9800 K�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15040305 Pace Project No.: 92245417 Sample: 2015010590 Lab ID: 92245417001 Collected: 04/12/15 14:30 Received: 04/14/15 15:00 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 334 167 5 04/18/1519:48 16887-00-6 D3 Sulfate ND mg/kg 334 167 5 04/18/1519:48 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 33.4 16.7 5 04/18/15 19:48 14797-55-8 H3 Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 1360 mg/kg 810 405 1 05/05/15 07:57 7440-44-0 Total Organic Carbon 1190 mg/kg 813 407 1 05/05/15 08:02 7440-44-0 Total Organic Carbon 1260 mg/kg 809 404 1 05/05/15 08:09 7440-44-0 Total Organic Carbon 1030 mg/kg 808 404 1 05/05/15 08:15 7440-44-0 Mean Total Organic Carbon 1210 mg/kg 810 405 1 05/05/15 07:57 7440-44-0 Surrogates RSD% 11.3 % 1 05/05/15 07:57 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/29/2015 02:56 PM without the written consent of Pace Analytical Services, Inc.. Page 25 of 57 ac.�nayy�ical www.pacelabs.com Pace Analytical Services, Inc. 9800 K3c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15040305 Pace Project No.: 92245417 Sample: 2015010591 Lab ID: 92245417002 Collected: 04/13/15 14:30 Received: 04/14/15 15:00 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Aluminum Barium Beryllium Boron Calcium Chromium Copper Iron Magnesium Manganese Molybdenum Nickel Potassium Sodium Strontium Zinc 6020 MET ICPMS Antimony Arsenic Cadmium Cobalt Lead Selenium Thallium Vanadium 7471 Mercury Mercury Percent Moisture Percent Moisture 9045 pH Soil pH at 25 Degrees C 9056 IC Anions Chloride Sulfate 9056 IC Anions 48hr Nitrate as N Date: 05/29/2015 02:56 PM Analytical Method: EPA 6010 Preparation Method: EPA 3050 4770 mg/kg 5.1 2.5 1 04/20/15 03:50 04/20/15 18:40 7429-90-5 62.3 mg/kg 0.51 0.25 1 04/20/15 03:50 04/20/15 18:40 7440-39-3 0.19 mg/kg 0.051 0.025 1 04/20/15 03:50 04/20/15 18:40 7440-41-7 ND mg/kg 2.5 1.3 1 04/20/15 03:50 04/20/15 18:40 7440-42-8 2300 mg/kg 25.3 12.7 1 04/20/15 03:50 04/20/15 18:40 7440-70-2 9.2 mg/kg 0.25 0.13 1 04/20/15 03:50 04/20/15 18:40 7440-47-3 48.4 mg/kg 0.25 0.13 1 04/20/15 03:50 04/20/15 18:40 7440-50-8 10400 mg/kg 2.0 1.0 1 04/20/15 03:50 04/20/15 18:40 7439-89-6 2370 mg/kg 25.3 12.7 1 04/20/15 03:50 04/20/15 18:40 7439-95-4 789 mg/kg 2.5 1.3 10 04/20/15 03:50 04/21/15 09:58 7439-96-5 0.75 mg/kg 0.51 0.25 1 04/20/15 03:50 04/20/15 18:40 7439-98-7 5.8 mg/kg 0.25 0.13 1 04/20/15 03:50 04/20/15 18:40 7440-02-0 1780 mg/kg 50.6 25.3 1 04/20/15 03:50 04/20/15 18:40 7440-09-7 133 mg/kg 50.6 25.3 1 04/20/15 03:50 04/20/15 18:40 7440-23-5 17.6 mg/kg 0.51 0.25 1 04/20/15 03:50 04/20/15 18:40 7440-24-6 26.8 mg/kg 1.0 0.51 1 04/20/15 03:50 04/20/15 18:40 7440-66-6 Analytical Method: EPA 6020 Preparation Method: EPA 3050 ND mg/kg 5.1 2.5 100 04/20/15 03:50 04/26/15 09:39 7440-36-0 ND mg/kg 5.1 2.5 100 04/20/15 03:50 04/26/15 09:39 7440-38-2 ND mg/kg 0.61 0.30 100 04/20/15 03:50 04/26/15 09:39 7440-43-9 6.6 mg/kg 5.1 2.5 100 04/20/15 03:50 04/26/15 09:39 7440-48-4 ND mg/kg 5.1 2.5 100 04/20/15 03:50 04/26/15 09:39 7439-92-1 ND mg/kg 5.1 2.5 100 04/20/15 03:50 04/26/15 09:39 7782-49-2 ND mg/kg 5.1 2.5 100 04/20/15 03:50 04/26/15 09:39 7440-28-0 13.1 mg/kg 5.1 2.5 100 04/20/15 03:50 04/26/15 09:39 7440-62-2 Analytical Method: EPA 7471 Preparation Method: EPA 7471 ND mg/kg 0.0088 0.0044 1 04/21/1514:55 04/22/1510:28 7439-97-6 Analytical Method: ASTM D2974-87 4.6 % 0.10 0.10 1 04/21/1515:52 Analytical Method: EPA 9045 8.3 Std. Units 0.10 0.10 1 Analytical Method: EPA 9056 ND mg/kg 266 133 5 ND mg/kg 266 133 5 Analytical Method: EPA 9056 ND mg/kg 26.6 13.3 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. [��'iX-17116'iif JC , N2 04/18/15 21:35 16887-00-6 D3 04/18/15 21:35 14808-79-8 D3 04/18/15 21:35 14797-55-8 H3 Page 26 of 57 ac.�naly�ical www.pacelabs.com Pace Analytical Services, Inc. 9800 %cy&.. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15040305 Pace Project No.: 92245417 Sample: 2015010591 Lab ID: 92245417002 Collected: 04/13/15 14:30 Received: 04/14/15 15:00 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon ND mg/kg 632 316 1 05/05/15 09:08 7440-44-0 Total Organic Carbon ND mg/kg 630 315 1 05/05/15 09:13 7440-44-0 Total Organic Carbon ND mg/kg 625 313 1 05/05/15 09:19 7440-44-0 Total Organic Carbon ND mg/kg 630 315 1 05/05/15 09:25 7440-44-0 Mean Total Organic Carbon ND mg/kg 629 315 1 05/05/15 09:08 7440-44-0 Surrogates RSD% 8.2 % 1 05/05/15 09:08 Date: 05/29/2015 02:56 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 27 of 57 ac.�naly�ical www.pacelabs.com Pace Analytical Services, Inc. 9800 %c y&.. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15040305 Pace Project No.: 92245417 Sample: 2015010592 Lab ID: 92245417003 Collected: 04/13/15 14:30 Received: 04/14/15 15:00 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Aluminum Barium Beryllium Boron Calcium Chromium Copper Iron Magnesium Manganese Molybdenum Nickel Potassium Sodium Strontium Zinc 6020 MET ICPMS Antimony Arsenic Cadmium Cobalt Lead Selenium Thallium Vanadium 7471 Mercury Mercury Percent Moisture Percent Moisture 9045 pH Soil pH at 25 Degrees C 9056 IC Anions Chloride Sulfate 9056 IC Anions 48hr Nitrate as N Date: 05/29/2015 02:56 PM Analytical Method: EPA 6010 Preparation Method: EPA 3050 4630 mg/kg 5.9 2.9 1 04/20/15 03:50 04/20/15 18:44 7429-90-5 61.5 mg/kg 0.59 0.29 1 04/20/15 03:50 04/20/15 18:44 7440-39-3 0.19 mg/kg 0.059 0.029 1 04/20/15 03:50 04/20/15 18:44 7440-41-7 ND mg/kg 2.9 1.5 1 04/20/15 03:50 04/20/15 18:44 7440-42-8 2250 mg/kg 29.3 14.7 1 04/20/15 03:50 04/20/15 18:44 7440-70-2 8.7 mg/kg 0.29 0.15 1 04/20/15 03:50 04/20/15 18:44 7440-47-3 38.7 mg/kg 0.29 0.15 1 04/20/15 03:50 04/20/15 18:44 7440-50-8 10200 mg/kg 2.3 1.2 1 04/20/15 03:50 04/20/15 18:44 7439-89-6 2730 mg/kg 29.3 14.7 1 04/20/15 03:50 04/20/15 18:44 7439-95-4 803 mg/kg 2.9 1.5 10 04/20/15 03:50 04/21/15 10:02 7439-96-5 0.74 mg/kg 0.59 0.29 1 04/20/15 03:50 04/20/15 18:44 7439-98-7 8.7 mg/kg 0.29 0.15 1 04/20/15 03:50 04/20/15 18:44 7440-02-0 1570 mg/kg 58.7 29.3 1 04/20/15 03:50 04/20/15 18:44 7440-09-7 108 mg/kg 58.7 29.3 1 04/20/15 03:50 04/20/15 18:44 7440-23-5 18.1 mg/kg 0.59 0.29 1 04/20/15 03:50 04/20/15 18:44 7440-24-6 30.8 mg/kg 1.2 0.59 1 04/20/15 03:50 04/20/15 18:44 7440-66-6 Analytical Method: EPA 6020 Preparation Method: EPA 3050 ND mg/kg 5.9 2.9 100 04/20/15 03:50 04/26/15 09:42 7440-36-0 ND mg/kg 5.9 2.9 100 04/20/15 03:50 04/26/15 09:42 7440-38-2 ND mg/kg 0.70 0.35 100 04/20/15 03:50 04/26/15 09:42 7440-43-9 7.2 mg/kg 5.9 2.9 100 04/20/15 03:50 04/26/15 09:42 7440-48-4 ND mg/kg 5.9 2.9 100 04/20/15 03:50 04/26/15 09:42 7439-92-1 ND mg/kg 5.9 2.9 100 04/20/15 03:50 04/26/15 09:42 7782-49-2 ND mg/kg 5.9 2.9 100 04/20/15 03:50 04/26/15 09:42 7440-28-0 13.9 mg/kg 5.9 2.9 100 04/20/15 03:50 04/26/15 09:42 7440-62-2 Analytical Method: EPA 7471 Preparation Method: EPA 7471 ND mg/kg 0.0092 0.0046 1 04/21/1514:55 04/22/1510:33 7439-97-6 Analytical Method: ASTM D2974-87 15.6 % 0.10 0.10 1 04/21/1515:53 Analytical Method: EPA 9045 8.4 Std. Units 0.10 0.10 1 Analytical Method: EPA 9056 ND mg/kg 296 148 5 ND mg/kg 296 148 5 Analytical Method: EPA 9056 ND mg/kg 29.6 14.8 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. [��'iX-17116'iif JC , N2 04/18/15 21:56 16887-00-6 D3 04/18/15 21:56 14808-79-8 D3 04/18/15 21:56 14797-55-8 H3 Page 28 of 57 ac.�naly�ical www.pacelabs.com Pace Analytical Services, Inc. 9800 K�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15040305 Pace Project No.: 92245417 Sample: 2015010592 Lab ID: 92245417003 Collected: 04/13/15 14:30 Received: 04/14/15 15:00 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon ND mg/kg 716 358 1 05/05/15 09:32 7440-44-0 Total Organic Carbon ND mg/kg 718 359 1 05/05/15 09:37 7440-44-0 Total Organic Carbon ND mg/kg 710 355 1 05/05/15 09:44 7440-44-0 Total Organic Carbon ND mg/kg 709 355 1 05/05/15 09:50 7440-44-0 Mean Total Organic Carbon ND mg/kg 713 357 1 05/05/15 09:32 7440-44-0 Surrogates RSD% 6.1 % 1 05/05/15 09:32 Date: 05/29/2015 02:56 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 29 of 57 ac.�naly�ical www.pacelabs.com Pace Analytical Services, Inc. 9800 K3igc y&.. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15040305 Pace Project No.: 92245417 Sample: 2015010593 Lab ID: 92245417004 Collected: 04/08/15 13:52 Received: 04/14/15 15:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;I➢ZI7c\�i,I=11a 99�r6? Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470 Mercury Mercury Date: 05/29/2015 02:56 PM Analytical Method: EPA 6020A Preparation Method: EPA 3020 83.2 ug/L 10.0 3.0 1 04/17/15 08:56 04/17/15 14:50 7429-90-5 ND ug/L 0.50 0.15 1 04/17/15 08:56 04/17/15 14:50 7440-36-0 0.14J ug/L 0.50 0.11 1 04/17/15 08:56 04/17/15 14:50 7440-38-2 4.4 ug/L 0.30 0.081 1 04/17/15 08:56 04/17/15 14:50 7440-39-3 ND ug/L 0.20 0.067 1 04/17/15 08:56 04/17/15 14:50 7440-41-7 35.7 ug/L 5.0 1.1 1 04/17/15 08:56 04/17/15 14:50 7440-42-8 ND ug/L 0.080 0.024 1 04/17/15 08:56 04/17/15 14:50 7440-43-9 445 ug/L 40.0 16.0 1 04/17/15 08:56 04/17/15 14:50 7440-70-2 3.9 ug/L 0.50 0.17 1 04/17/15 08:56 04/17/15 14:50 7440-47-3 29.1 ug/L 0.50 0.13 1 04/17/15 08:56 04/17/15 14:50 7440-48-4 13.7 ug/L 1.0 0.21 1 04/17/15 08:56 04/17/15 14:50 7440-50-8 7230 ug/L 50.0 13.7 1 04/17/15 08:56 04/17/15 14:50 7439-89-6 0.44 ug/L 0.10 0.046 1 04/17/15 08:56 04/17/15 14:50 7439-92-1 67.6 ug/L 10.0 3.2 1 04/17/15 08:56 04/17/15 14:50 7439-95-4 61.7 ug/L 0.50 0.24 1 04/17/15 08:56 04/17/15 14:50 7439-96-5 5.7 ug/L 0.50 0.094 1 04/17/15 08:56 04/17/15 14:50 7439-98-7 2.3 ug/L 0.50 0.16 1 04/17/15 08:56 04/17/15 14:50 7440-02-0 41.1J ug/L 50.0 11.7 1 04/17/15 08:56 04/17/15 14:50 7440-09-7 ND ug/L 0.50 0.20 1 04/17/15 08:56 04/17/15 14:50 7782-49-2 132 ug/L 50.0 16.3 1 04/17/15 08:56 04/17/15 14:50 7440-23-5 1.4 ug/L 0.50 0.13 1 04/17/15 08:56 04/17/15 14:50 7440-24-6 ND ug/L 0.10 0.015 1 04/17/15 08:56 04/17/15 14:50 7440-28-0 ND ug/L 1.0 0.28 1 04/17/15 08:56 04/17/15 14:50 7440-62-2 12.9 ug/L 5.0 2.4 1 04/17/15 08:56 04/17/15 14:50 7440-66-6 Analytical Method: EPA 7470 Preparation Method: EPA 7470 ND ug/L 0.20 0.022 1 04/17/1513:50 04/19/1518:02 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 30 of 57 ac.�nayy�ical www.pacelabs.com Pace Analytical Services, Inc. 9800 %cy&.. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15040305 Pace Project No.: 92245417 Sample: 2015010594 Lab ID: 92245417005 Collected: 04/12/15 14:15 Received: 04/14/15 15:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;I➢ZI7c\�i,I=11 l[99�r 6? Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470 Mercury Mercury Date: 05/29/2015 02:56 PM Analytical Method: EPA 6020A Preparation Method: EPA 3020 44.7 ug/L 10.0 3.0 1 04/17/15 08:56 04/17/15 14:53 7429-90-5 ND ug/L 0.50 0.15 1 04/17/15 08:56 04/17/15 14:53 7440-36-0 ND ug/L 0.50 0.11 1 04/17/15 08:56 04/17/15 14:53 7440-38-2 0.66 ug/L 0.30 0.081 1 04/17/15 08:56 04/17/15 14:53 7440-39-3 ND ug/L 0.20 0.067 1 04/17/15 08:56 04/17/15 14:53 7440-41-7 1.5J ug/L 5.0 1.1 1 04/17/15 08:56 04/17/15 14:53 7440-42-8 ND ug/L 0.080 0.024 1 04/17/15 08:56 04/17/15 14:53 7440-43-9 157 ug/L 40.0 16.0 1 04/17/15 08:56 04/17/15 14:53 7440-70-2 1.0 ug/L 0.50 0.17 1 04/17/15 08:56 04/17/15 14:53 7440-47-3 ND ug/L 0.50 0.13 1 04/17/15 08:56 04/17/15 14:53 7440-48-4 1.7 ug/L 1.0 0.21 1 04/17/15 08:56 04/17/15 14:53 7440-50-8 181 ug/L 50.0 13.7 1 04/17/15 08:56 04/17/15 14:53 7439-89-6 0.20 ug/L 0.10 0.046 1 04/17/15 08:56 04/17/15 14:53 7439-92-1 30.7 ug/L 10.0 3.2 1 04/17/15 08:56 04/17/15 14:53 7439-95-4 4.8 ug/L 0.50 0.24 1 04/17/15 08:56 04/17/15 14:53 7439-96-5 0.21J ug/L 0.50 0.094 1 04/17/15 08:56 04/17/15 14:53 7439-98-7 0.42J ug/L 0.50 0.16 1 04/17/15 08:56 04/17/15 14:53 7440-02-0 23.4J ug/L 50.0 11.7 1 04/17/15 08:56 04/17/15 14:53 7440-09-7 ND ug/L 0.50 0.20 1 04/17/15 08:56 04/17/15 14:53 7782-49-2 23.7J ug/L 50.0 16.3 1 04/17/15 08:56 04/17/15 14:53 7440-23-5 0.60 ug/L 0.50 0.13 1 04/17/15 08:56 04/17/15 14:53 7440-24-6 ND ug/L 0.10 0.015 1 04/17/15 08:56 04/17/15 14:53 7440-28-0 ND ug/L 1.0 0.28 1 04/17/15 08:56 04/17/15 14:53 7440-62-2 11.6 ug/L 5.0 2.4 1 04/17/15 08:56 04/17/15 14:53 7440-66-6 Analytical Method: EPA 7470 Preparation Method: EPA 7470 ND ug/L 0.20 0.022 1 04/17/1513:50 04/19/1518:04 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 31 of 57 ace��nayy�ical www.pacelabs.com Pace Analytical Services, Inc. 9800 %c y&.. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15040305 Pace Project No.: 92245417 Sample: 2015010590 SPLP Lab ID: 92245417006 Collected: 04/12/15 14:30 Received: 04/14/15 15:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;T➢Z17c\�iil=11 a Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470A Mercury Mercury Date: 05/29/2015 02:56 PM Analytical Method: EPA 6020A Preparation Method: EPA 3020 9AJ ug/L 10.0 3.0 1 05/04/15 08:49 05/04/15 16:46 7429-90-5 ND ug/L 0.50 0.15 1 05/04/15 08:49 05/04/15 16:46 7440-36-0 ND ug/L 0.50 0.11 1 05/04/15 08:49 05/04/15 16:46 7440-38-2 93.6 ug/L 0.30 0.081 1 05/04/15 08:49 05/04/15 16:46 7440-39-3 ND ug/L 0.20 0.067 1 05/04/15 08:49 05/04/15 16:46 7440-41-7 42.2 ug/L 5.0 1.1 1 05/04/15 08:49 05/04/15 16:46 7440-42-8 ND ug/L 0.080 0.024 1 05/04/15 08:49 05/04/15 16:46 7440-43-9 354 ug/L 40.0 16.0 1 05/04/15 08:49 05/04/15 16:46 7440-70-2 0.38J ug/L 0.50 0.17 1 05/04/15 08:49 05/04/15 16:46 7440-47-3 0.20J ug/L 0.50 0.13 1 05/04/15 08:49 05/04/15 16:46 7440-48-4 0.44J ug/L 1.0 0.21 1 05/04/15 08:49 05/05/15 16:12 7440-50-8 ND ug/L 50.0 13.7 1 05/04/15 08:49 05/04/15 16:46 7439-89-6 0.047J ug/L 0.10 0.046 1 05/04/15 08:49 05/04/15 16:46 7439-92-1 547 ug/L 10.0 3.2 1 05/04/15 08:49 05/04/15 16:46 7439-95-4 3.0 ug/L 0.50 0.24 1 05/04/15 08:49 05/04/15 16:46 7439-96-5 ND ug/L 0.50 0.094 1 05/04/15 08:49 05/04/15 16:46 7439-98-7 ND ug/L 0.50 0.16 1 05/04/15 08:49 05/04/15 16:46 7440-02-0 117 ug/L 50.0 11.7 1 05/04/15 08:49 05/04/15 16:46 7440-09-7 ND ug/L 0.50 0.20 1 05/04/15 08:49 05/04/15 16:46 7782-49-2 1200 ug/L 50.0 16.3 1 05/04/15 08:49 05/04/15 16:46 7440-23-5 6.0 ug/L 0.50 0.13 1 05/04/15 08:49 05/04/15 16:46 7440-24-6 ND ug/L 0.10 0.015 1 05/04/15 08:49 05/04/15 16:46 7440-28-0 ND ug/L 1.0 0.28 1 05/04/15 08:49 05/04/15 16:46 7440-62-2 48.8 ug/L 5.0 2.4 1 05/04/15 08:49 05/04/15 16:46 7440-66-6 Analytical Method: EPA 7470A Preparation Method: EPA 7470A ND ug/L 0.20 0.022 1 05/04/15 12:00 05/04/15 20:34 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 32 of 57 ace�Anayy�ical www.pacelabs.com Pace Analytical Services, Inc. 9800 1inlc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040305 Pace Project No.: 92245417 QC Batch: MERP/13262 Analysis Method: EPA 7470 QC Batch Method: EPA 7470 Analysis Description: 7470 Mercury Associated Lab Samples: 92245417004, 92245417005 METHOD BLANK: 1941653 Matrix: Water Associated Lab Samples: 92245417004, 92245417005 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury ug/L ND 0.20 04/19/1517:25 LABORATORY CONTROL SAMPLE: 1941654 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 5 4.9 98 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1941655 1941656 MS MSD 10302585001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 5 5 4.9 4.8 98 96 75-125 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/29/2015 02:56 PM without the written consent of Pace Analytical Services, Inc.. Page 33 of 57 ace�.-.nayical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040305 Pace Project No.: 92245417 QC Batch: MERP/13418 Analysis Method: EPA 7470A QC Batch Method: EPA 7470A Analysis Description: 7470A Mercury Water Associated Lab Samples: 92245417006 METHOD BLANK: 1954385 Matrix: Water Associated Lab Samples: 92245417006 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury ug/L ND 0.20 05/04/15 20:27 LABORATORY CONTROL SAMPLE: 1954386 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 5 4.8 97 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1954387 1954388 MS MSD 92247835002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 5 5 5.1 5.2 103 103 80-120 0 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/29/2015 02:56 PM without the written consent of Pace Analytical Services, Inc.. Page 34 of 57 ace�.-.nayical www.pacelabs.com Pace Analytical Services, Inc. 9800 %c y&.. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040305 Pace Project No.: 92245417 QC Batch: MERP/5609 Analysis Method: EPA 7471 QC Batch Method: EPA 7471 Analysis Description: 7471 Mercury Associated Lab Samples: 92245417001, 92245417002, 92245417003 METHOD BLANK: 1189243 Matrix: Solid Associated Lab Samples: 92245417001, 92245417002, 92245417003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury mg/kg ND 0.0084 04/22/1510:13 LABORATORY CONTROL SAMPLE: 1189244 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury mg/kg .082 0.076 92 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1189389 1189390 MS MSD 92245417001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury mg/kg 0.029 .108 .111 0.11 0.12 80 80 80-120 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/29/2015 02:56 PM without the written consent of Pace Analytical Services, Inc.. Page 35 of 57 ace�.-.nayical www.pacelabs.com Pace Analytical Services, Inc. 9800 %c y&.. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040305 Pace Project No.: 92245417 QC Batch: MPRP/23700 Analysis Method: EPA 6010 QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid Associated Lab Samples: 92245417001, 92245417002, 92245417003 METHOD BLANK: 1188103 Matrix: Associated Lab Samples: 92245417001, 92245417002, 92245417003 Blank Parameter Units Result Solid Reporting Limit Analyzed Aluminum mg/kg ND 5.0 04/20/1515:03 Barium mg/kg ND 0.50 04/20/1515:03 Beryllium mg/kg ND 0.050 04/20/1515:03 Boron mg/kg ND 2.5 04/20/1515:03 Calcium mg/kg ND 25.1 04/20/1515:03 Chromium mg/kg ND 0.25 04/20/1515:03 Copper mg/kg ND 0.25 04/20/1515:03 Iron mg/kg ND 2.0 04/20/1515:03 Magnesium mg/kg ND 25.1 04/20/1515:03 Manganese mg/kg ND 0.25 04/20/1515:03 Molybdenum mg/kg ND 0.50 04/20/1515:03 Nickel mg/kg ND 0.25 04/20/1515:03 Potassium mg/kg ND 50.2 04/20/1515:03 Sodium mg/kg ND 50.2 04/20/1515:03 Strontium mg/kg ND 0.50 04/20/1515:03 Zinc mg/kg ND 1.0 04/20/1515:03 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 1188104 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Aluminum mg/kg 123 128 104 80-120 Barium mg/kg 12.3 12.8 104 80-120 Beryllium mg/kg 1.2 1.3 103 80-120 Boron mg/kg 123 124 101 80-120 Calcium mg/kg 616 653 106 80-120 Chromium mg/kg 12.3 12.5 102 80-120 Copper mg/kg 12.3 12.2 99 80-120 Iron mg/kg 123 128 104 80-120 Magnesium mg/kg 616 641 104 80-120 Manganese mg/kg 12.3 12.7 103 80-120 Molybdenum mg/kg 12.3 12.4 100 80-120 Nickel mg/kg 12.3 12.8 104 80-120 Potassium mg/kg 616 634 103 80-120 Sodium mg/kg 616 661 107 80-120 Strontium mg/kg 12.3 12.6 102 80-120 Zinc mg/kg 61.6 63.8 104 80-120 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/29/2015 02:56 PM without the written consent of Pace Analytical Services, Inc.. Page 36 of 57 ace��nayical www.pacelabs.com Pace Analytical Services, Inc. 9800 %c y&.. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040305 Pace Project No.: 92245417 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1188105 1188106 MS MSD 92245086014 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum mg/kg 9620 168 177 12500 13300 1720 2080 75-125 6 20 M1 Barium mg/kg 33.7 16.8 17.7 62.3 61.8 170 159 75-125 1 20 M1 Beryllium mg/kg 0.21 1.65 1.79 1.6 1.7 85 84 75-125 3 20 Boron mg/kg ND 168 177 113 115 67 65 75-125 2 20 M1 Calcium mg/kg 102 841 885 842 898 88 90 75-125 6 20 Chromium mg/kg 24.2 16.8 17.7 33.4 40.3 55 91 75-125 19 20 M1 Copper mg/kg 15.4 16.8 17.7 30.8 32.9 92 99 75-125 7 20 Iron mg/kg 43500 168 177 29000 33400 -8640 -5690 75-125 14 20 E,M1 Magnesium mg/kg 1120 841 885 2110 2080 118 109 75-125 1 20 Manganese mg/kg 203 16.8 17.7 254 320 302 662 75-125 23 20 M1,R1 Molybdenum mg/kg ND 16.8 17.7 10.2 9.9 60 55 75-125 4 20 M1 Nickel mg/kg 2.3 16.8 17.7 18.2 18.8 95 93 75-125 3 20 Potassium mg/kg 793 841 885 1820 1820 122 116 75-125 0 20 Sodium mg/kg ND 841 885 796 843 95 95 75-125 6 20 Strontium mg/kg 2.2 16.8 17.7 17.3 18.1 90 90 75-125 5 20 Zinc mg/kg 11.6 84.1 88.5 87.8 92.4 91 91 75-125 5 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/29/2015 02:56 PM without the written consent of Pace Analytical Services, Inc.. Page 37 of 57 ace��naly�ical www.pacelabs.com Pace Analytical Services, Inc. 9800 %c y&.. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040305 Pace Project No.: 92245417 QC Batch: MPRP/23701 Analysis Method: EPA 6020 QC Batch Method: EPA 3050 Analysis Description: 6020 MET SOLID Associated Lab Samples: 92245417001, 92245417002, 92245417003 METHOD BLANK: 1188107 Matrix: Solid Associated Lab Samples: 92245417001, 92245417002, 92245417003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Antimony mg/kg ND 0.051 04/26/15 09:21 N2 Arsenic mg/kg ND 0.051 04/26/15 09:21 Cadmium mg/kg ND 0.0061 04/26/15 09:21 Cobalt mg/kg ND 0.051 04/26/15 09:21 Lead mg/kg ND 0.051 04/26/15 09:21 Selenium mg/kg ND 0.051 04/26/15 09:21 Thallium mg/kg ND 0.051 04/26/15 09:21 Vanadium mg/kg ND 0.051 04/26/15 09:21 LABORATORY CONTROL SAMPLE: Parameter 1188108 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Antimony mg/kg 2.5 2.6 101 80-120 N2 Arsenic mg/kg 2.5 2.6 104 80-120 Cadmium mg/kg .25 0.25 100 80-120 Cobalt mg/kg 2.5 2.7 106 80-120 Lead mg/kg 2.5 2.6 103 80-120 Selenium mg/kg 2.5 2.7 107 80-120 Thallium mg/kg 2.5 2.6 103 80-120 Vanadium mg/kg 2.5 2.7 108 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1188109 1188110 MS MSD 92244601001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony mg/kg ND 2.4 2.5 4.6J 4.6J 176 174 75-125 20 M6, N2 Arsenic mg/kg ND 2.4 2.5 5.6 4.3J 212 157 75-125 20 M6 Cadmium mg/kg ND .24 .25 0.97 1.1 359 390 75-125 10 20 M6 Cobalt mg/kg ND 2.4 2.5 15.5 16.6 600 626 75-125 6 20 M6 Lead mg/kg ND 2.4 2.5 17.8 18.4 536 547 75-125 3 20 M6 Selenium mg/kg ND 2.4 2.5 3.OJ ND 113 59 75-125 20 M6 Thallium mg/kg ND 2.4 2.5 12.8 12.9 504 492 75-125 0 20 M6 Vanadium mg/kg ND 2.4 2.5 72.9 80.0 2980 3190 75-125 9 20 M6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/29/2015 02:56 PM without the written consent of Pace Analytical Services, Inc.. Page 38 of 57 ace�.-.nayical www.pacelabs.com Pace Analytical Services, Inc. 9800 Iic&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040305 Pace Project No.: 92245417 QC Batch: MPRP/53693 Analysis Method: EPA 6020A QC Batch Method: EPA 3020 Analysis Description: 6020A Water UPD4 Associated Lab Samples: 92245417004, 92245417005 METHOD BLANK: 1941663 Associated Lab Samples: 92245417004, 92245417005 Parameter Units Aluminum ug/L Antimony ug/L Arsenic ug/L Barium ug/L Beryllium ug/L Boron ug/L Cadmium ug/L Calcium ug/L Chromium ug/L Cobalt ug/L Copper ug/L Iron ug/L Lead ug/L Magnesium ug/L Manganese ug/L Molybdenum ug/L Nickel ug/L Potassium ug/L Selenium ug/L Sodium ug/L Strontium ug/L Thallium ug/L Vanadium ug/L Zinc ug/L Matrix: Water Blank Result Reporting Limit Analyzed ND 10.0 04/17/1513:59 ND 0.50 04/17/1513:59 ND 0.50 04/17/1513:59 ND 0.30 04/17/1513:59 ND 0.20 04/17/1513:59 ND 5.0 04/17/1513:59 ND 0.080 04/17/1513:59 ND 40.0 04/17/1513:59 ND 0.50 04/17/1513:59 ND 0.50 04/17/1513:59 ND 1.0 04/17/1513:59 ND 50.0 04/17/1513:59 ND 0.10 04/17/1513:59 ND 10.0 04/17/1513:59 ND 0.50 04/17/1513:59 ND 0.50 04/17/1513:59 ND 0.50 04/17/1513:59 ND 50.0 04/17/1513:59 ND 0.50 04/17/1513:59 ND 50.0 04/17/1513:59 ND 0.50 04/17/1513:59 ND 0.10 04/17/1513:59 ND 1.0 04/17/1513:59 ND 5.0 04/17/1513:59 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 1941664 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Aluminum ug/L 80 82.3 103 80-120 Antimony ug/L 80 80.8 101 80-120 Arsenic ug/L 80 81.2 102 80-120 Barium ug/L 80 80.2 100 80-120 Beryllium ug/L 80 86.2 108 80-120 Boron ug/L 80 87.1 109 80-120 Cadmium ug/L 80 84.6 106 80-120 Calcium ug/L 1000 1010 101 80-120 Chromium ug/L 80 85.1 106 80-120 Cobalt ug/L 80 84.6 106 80-120 Copper ug/L 80 79.7 100 80-120 Iron ug/L 1000 1050 105 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/29/2015 02:56 PM without the written consent of Pace Analytical Services, Inc.. Page 39 of 57 ace��nayical www.pacelabs.com Pace Analytical Services, Inc. 9800 %c y&.. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040305 Pace Project No.: 92245417 LABORATORY CONTROL SAMPLE: 1941664 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Lead ug/L 80 84.2 105 80-120 Magnesium ug/L 1000 1020 102 80-120 Manganese ug/L 80 85.3 107 80-120 Molybdenum ug/L 80 80.9 101 80-120 Nickel ug/L 80 85.0 106 80-120 Potassium ug/L 1000 1020 102 80-120 Selenium ug/L 80 82.6 103 80-120 Sodium ug/L 1000 1010 101 80-120 Strontium ug/L 80 81.1 101 80-120 Thallium ug/L 80 85.2 107 80-120 Vanadium ug/L 80 83.9 105 80-120 Zinc ug/L 80 84.8 106 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1941683 1941684 MS MSD 92245394017 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum ug/L 12.3 80 80 101 101 111 110 75-125 0 20 Antimony ug/L ND 80 80 82.3 81.2 103 101 75-125 1 20 Arsenic ug/L ND 80 80 82.8 81.7 104 102 75-125 1 20 Barium ug/L 0.23J 80 80 82.5 82.6 103 103 75-125 0 20 Beryllium ug/L ND 80 80 88.3 88.6 110 111 75-125 0 20 Boron ug/L ND 80 80 88.6 88.7 111 111 75-125 0 20 Cadmium ug/L ND 80 80 85.8 84.8 107 106 75-125 1 20 Calcium ug/L 169 1000 1000 1200 1180 103 101 75-125 2 20 Chromium ug/L ND 80 80 87.7 86.6 109 108 75-125 1 20 Cobalt ug/L ND 80 80 86.6 85.9 108 107 75-125 1 20 Copper ug/L 0.41J 80 80 81.7 80.6 102 100 75-125 1 20 Iron ug/L 37.9J 1000 1000 1110 1100 107 106 75-125 1 20 Lead ug/L ND 80 80 88.0 86.6 110 108 75-125 2 20 Magnesium ug/L 9.91 1000 1000 1080 1070 107 106 75-125 1 20 Manganese ug/L 0.38J 80 80 88.4 87.4 110 109 75-125 1 20 Molybdenum ug/L 0.30J 80 80 82.7 80.8 103 101 75-125 2 20 Nickel ug/L ND 80 80 87.3 86.2 109 108 75-125 1 20 Potassium ug/L 23.6J 1000 1000 1080 1060 105 103 75-125 2 20 Selenium ug/L ND 80 80 86.0 84.5 108 106 75-125 2 20 Sodium ug/L 30.6J 1000 1000 1090 1070 106 104 75-125 2 20 Strontium ug/L 0.36J 80 80 83.9 82.2 104 102 75-125 2 20 Thallium ug/L ND 80 80 87.7 86.0 110 107 75-125 2 20 Vanadium ug/L ND 80 80 86.2 85.3 108 107 75-125 1 20 Zinc ug/L ND 80 80 87.6 86.4 107 106 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/29/2015 02:56 PM without the written consent of Pace Analytical Services, Inc.. Page 40 of 57 ace�.-.nayical www.pacelabs.com Pace Analytical Services, Inc. 9800 %c y&.. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040305 Pace Project No.: 92245417 QC Batch: MPRP/54102 Analysis Method: EPA 6020A QC Batch Method: EPA 3020 Analysis Description: 6020A Water UPD4 Associated Lab Samples: 92245417006 METHOD BLANK: 1954381 Associated Lab Samples: 92245417006 Parameter Units Aluminum ug/L Antimony ug/L Arsenic ug/L Barium ug/L Beryllium ug/L Boron ug/L Cadmium ug/L Calcium ug/L Chromium ug/L Cobalt ug/L Copper ug/L Iron ug/L Lead ug/L Magnesium ug/L Manganese ug/L Molybdenum ug/L Nickel ug/L Potassium ug/L Selenium ug/L Sodium ug/L Strontium ug/L Thallium ug/L Vanadium ug/L Zinc ug/L Matrix: Water Blank Result Reporting Limit Analyzed ND 10.0 05/04/1516:41 ND 0.50 05/04/1516:41 ND 0.50 05/04/1516:41 ND 0.30 05/04/1516:41 ND 0.20 05/04/1516:41 ND 5.0 05/04/1516:41 ND 0.080 05/04/1516:41 ND 40.0 05/04/1516:41 ND 0.50 05/04/1516:41 ND 0.50 05/04/1516:41 ND 1.0 05/05/1516:04 ND 50.0 05/04/1516:41 ND 0.10 05/04/1516:41 ND 10.0 05/04/1516:41 ND 0.50 05/04/1516:41 ND 0.50 05/04/1516:41 ND 0.50 05/04/1516:41 ND 50.0 05/04/1516:41 ND 0.50 05/04/1516:41 ND 50.0 05/04/1516:41 ND 0.50 05/04/1516:41 ND 0.10 05/04/1516:41 ND 1.0 05/04/1516:41 ND 5.0 05/04/1516:41 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 1954382 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Aluminum ug/L 80 81.4 102 80-120 Antimony ug/L 80 81.8 102 80-120 Arsenic ug/L 80 78.7 98 80-120 Barium ug/L 80 93.0 116 80-120 Beryllium ug/L 80 82.9 104 80-120 Boron ug/L 80 83.9 105 80-120 Cadmium ug/L 80 84.8 106 80-120 Calcium ug/L 1000 1100 110 80-120 Chromium ug/L 80 80.7 101 80-120 Cobalt ug/L 80 82.3 103 80-120 Copper ug/L 80 84.5 106 80-120 Iron ug/L 1000 1100 110 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/29/2015 02:56 PM without the written consent of Pace Analytical Services, Inc.. Page 41 of 57 ac.�nayical www.pacelabs.com Pace Analytical Services, Inc. 9800 %c y&.. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040305 Pace Project No.: 92245417 LABORATORY CONTROL SAMPLE: 1954382 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Lead ug/L 80 79.9 100 80-120 Magnesium ug/L 1000 1030 103 80-120 Manganese ug/L 80 78.3 98 80-120 Molybdenum ug/L 80 80.0 100 80-120 Nickel ug/L 80 84.8 106 80-120 Potassium ug/L 1000 975 97 80-120 Selenium ug/L 80 88.1 110 80-120 Sodium ug/L 1000 997 100 80-120 Strontium ug/L 80 85.2 107 80-120 Thallium ug/L 80 91.2 114 80-120 Vanadium ug/L 80 81.0 101 80-120 Zinc ug/L 80 85.9 107 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1954383 1954384 MS MSD 92247835001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum ug/L 2510 80 80 4310 4250 2250 2180 75-125 1 20 M1 Antimony ug/L 0.43J 80 80 73.3 76.3 91 95 75-125 4 20 Arsenic ug/L 0.27J 80 80 80.4 82.5 100 103 75-125 3 20 Barium ug/L 17.0 80 80 107 113 112 120 75-125 6 20 Beryllium ug/L ND 80 80 89.4 92.4 112 115 75-125 3 20 Boron ug/L 4AJ 80 80 102 101 122 121 75-125 1 20 Cadmium ug/L 0.063J 80 80 85.9 88.8 107 111 75-125 3 20 Calcium ug/L 2110 1000 1000 3750 3810 164 170 75-125 1 20 M1 Chromium ug/L 17.4 80 80 102 105 106 110 75-125 3 20 Cobalt ug/L 2.1 80 80 78.7 81.6 96 99 75-125 4 20 Copper ug/L 9.1 80 80 88.0 91.0 99 102 75-125 3 20 Iron ug/L 8200 1000 1000 10200 10500 201 226 75-125 2 20 M1 Lead ug/L 0.51 80 80 79.4 80.8 99 100 75-125 2 20 Magnesium ug/L 990 1000 1000 2400 2430 141 144 75-125 1 20 M1 Manganese ug/L 78.0 80 80 168 175 112 121 75-125 4 20 Molybdenum ug/L 4.8 80 80 86.2 89.6 102 106 75-125 4 20 Nickel ug/L 4.6 80 80 92.2 95.4 109 113 75-125 3 20 Potassium ug/L 775 1000 1000 1660 1720 88 94 75-125 4 20 Selenium ug/L ND 80 80 90.4 91.2 113 114 75-125 1 20 Sodium ug/L 603 1000 1000 1670 1730 107 113 75-125 4 20 Strontium ug/L 13.3 80 80 97.3 102 105 111 75-125 5 20 Thallium ug/L ND 80 80 98.0 102 122 128 75-125 4 20 M1 Vanadium ug/L 9.9 80 80 96.3 98.5 108 111 75-125 2 20 Zinc ug/L 12.2 80 80 97.8 101 107 111 75-125 3 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/29/2015 02:56 PM without the written consent of Pace Analytical Services, Inc.. Page 42 of 57 ac.Anayy�ical www.pacelabs.com Pace Analytical Services, Inc. 9800 1j nl c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040305 Pace Project No.: 92245417 QC Batch: PMST/3462 Analysis Method: ASTM D2974-87 QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture Associated Lab Samples: 92245417001, 92245417002, 92245417003 SAMPLE DUPLICATE: 1189700 92245417001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 26.2 26.1 0 10 SAMPLE DUPLICATE: 1189701 92245394003 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 24.2 24.7 2 10 SAMPLE DUPLICATE: 1189702 92245394012 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 18.9 18.8 1 10 SAMPLE DUPLICATE: 1189703 35184627020 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 10.2 9.3 9 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/29/2015 02:56 PM without the written consent of Pace Analytical Services, Inc.. Page 43 of 57 ac.�naly�ical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040305 Pace Project No.: 92245417 QC Batch: WET/31102 Analysis Method: EPA 9045 QC Batch Method: EPA 9045 Analysis Description: 9045 pH Associated Lab Samples: 92245417001, 92245417002, 92245417003 SAMPLE DUPLICATE: 1227314 92245417001 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 4.9 4.9 1 20 H6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/29/2015 02:56 PM without the written consent of Pace Analytical Services, Inc.. Page 44 of 57 ac.�naly�ical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040305 Pace Project No.: 92245417 QC Batch: WETA/22735 Analysis Method: EPA 300.0 QC Batch Method: EPA 300.0 Analysis Description: 300.0 IC Anions Associated Lab Samples: 92245417001 METHOD BLANK: 1445696 Matrix: Water Associated Lab Samples: 92245417001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Sulfate mg/L 3.4 2.0 04/29/1513:00 LABORATORY CONTROL SAMPLE: 1445697 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfate mg/L 20 19.4 97 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1445698 1445699 MS MSD 92245352011 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfate mg/L 1.7J 23.9 23.9 23.5 23.2 91 90 1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1445700 1445701 MS MSD 92245637002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfate mg/L 11.0 20 20 31.2 31.3 101 102 0 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/29/2015 02:56 PM without the written consent of Pace Analytical Services, Inc.. Page 45 of 57 ac.�nayy�ical www.pacelabs.com Pace Analytical Services, Inc. 9800 Ijc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040305 Pace Project No.: 92245417 QC Batch: WETA/22748 Analysis Method: EPA 353.2 QC Batch Method: EPA 353.2 Analysis Description: 353.2 Nitrate + Nitrite, Unpres. Associated Lab Samples: 92245417001 METHOD BLANK: 1446743 Matrix: Water Associated Lab Samples: 92245417001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, Nitrate mg/L 0.15 0.020 04/29/15 20:34 Z2 LABORATORY CONTROL SAMPLE: 1446744 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Nitrate mg/L 2.5 2.6 102 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1446745 1446746 MS MSD 92245352011 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Nitrate mg/L ND 3 3 3.3 3.3 103 103 90-110 0 10 H1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1446747 1446748 MS MSD 92245352012 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Nitrate mg/L ND 3.2 3.2 3.5 3.4 102 102 90-110 0 10 H1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/29/2015 02:56 PM without the written consent of Pace Analytical Services, Inc.. Page 46 of 57 ac.�naly�ical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040305 Pace Project No.: 92245417 QC Batch: WETA/22743 Analysis Method: SM 4500-CI-E QC Batch Method: SM 4500-CI-E Analysis Description: 4500 Chloride Associated Lab Samples: 92245417001 METHOD BLANK: 1446034 Matrix: Water Associated Lab Samples: 92245417001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/L ND 1.0 04/30/15 01:35 LABORATORY CONTROL SAMPLE: 1446035 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloride mg/L 20 21.1 106 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1446036 1446037 MS MSD 92245352011 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride mg/L ND 23.9 23.9 24.6 24.4 102 101 90-110 1 10 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1446038 1446039 MS MSD 92245637002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride mg/L ND 20 20 22.3 22.0 103 101 90-110 1 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/29/2015 02:56 PM without the written consent of Pace Analytical Services, Inc.. Page 47 of 57 ac.�naly�ical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040305 Pace Project No.: 92245417 QC Batch: WETA/45547 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92245417001 METHOD BLANK: 1187883 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/kg ND 49.4 04/18/1510:53 Sulfate mg/kg ND 49.4 04/18/1510:53 LABORATORY CONTROL SAMPLE: 1187884 Parameter Units Chloride mg/kg Sulfate mg/kg MATRIX SPIKE SAMPLE: 1187886 Parameter Units Chloride mg/kg Sulfate mg/kg SAMPLE DUPLICATE: 1187885 Parameter Chloride Sulfate Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 493 469 95 80-120 493 469 95 80-120 92245394002 Spike MS MS % Rec Result Conc. Result % Rec Limits Qualifiers ND 587 576 80 80-120 ND 587 646 90 80-120 92245394002 Dup Units Result Result mg/kg ND ND mg/kg ND ND Max RPD RPD Qualifiers 20 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/29/2015 02:56 PM without the written consent of Pace Analytical Services, Inc.. Page 48 of 57 ac.�naly�ical www.pacelabs.com Pace Analytical Services, Inc. 9800 Ijc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040305 Pace Project No.: 92245417 QC Batch: WETA/45549 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92245417002, 92245417003 METHOD BLANK: 1187892 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/kg ND 49.9 04/18/15 20:52 Sulfate mg/kg ND 49.9 04/18/15 20:52 LABORATORY CONTROL SAMPLE: 1187893 Parameter Units Chloride mg/kg Sulfate mg/kg MATRIX SPIKE SAMPLE: 1187895 Parameter Units Chloride mg/kg Sulfate mg/kg SAMPLE DUPLICATE: 1187894 Parameter Chloride Sulfate Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 500 485 97 80-120 500 484 97 80-120 92245417003 Spike MS MS % Rec Result Conc. Result % Rec Limits Qualifiers ND 590 556 94 80-120 ND 590 578 98 80-120 92245417003 Dup Units Result Result mg/kg ND ND mg/kg ND ND Max RPD RPD Qualifiers 20 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/29/2015 02:56 PM without the written consent of Pace Analytical Services, Inc.. Page 49 of 57 ac.�naly�ical www.pacelabs.com Pace Analytical Services, Inc. 9800 Ijigc y&.. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040305 Pace Project No.: 92245417 QC Batch: WETA/45546 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92245417001 METHOD BLANK: 1187879 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrate as N mg/kg ND 4.9 04/18/15 10:53 LABORATORY CONTROL SAMPLE: 1187880 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg 49.3 47.9 97 80-120 MATRIX SPIKE SAMPLE: 1187882 92245394002 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg ND 58.7 60.2 103 80-120 H3 SAMPLE DUPLICATE: 1187881 92245394002 Dup Max Parameter Units Result Result RPD RPD Qualifiers Nitrate as N mg/kg ND ND 20 H3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/29/2015 02:56 PM without the written consent of Pace Analytical Services, Inc.. Page 50 of 57 ac.�naly�ical www.pacelabs.com Pace Analytical Services, Inc. 9800 %c y&.. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040305 Pace Project No.: 92245417 QC Batch: WETA/45548 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92245417002, 92245417003 METHOD BLANK: 1187887 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrate as N mg/kg ND 5.0 04/18/15 20:52 LABORATORY CONTROL SAMPLE: 1187888 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg 50 50.3 101 80-120 MATRIX SPIKE SAMPLE: 1187890 92245417003 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg ND 59 55.5 94 80-120 H3 SAMPLE DUPLICATE: 1187889 92245417003 Dup Max Parameter Units Result Result RPD RPD Qualifiers Nitrate as N mg/kg ND ND 20 H3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/29/2015 02:56 PM without the written consent of Pace Analytical Services, Inc.. Page 51 of 57 ac.�nayy�ical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15040305 Pace Project No.: 92245417 QC Batch: WETA/28317 Analysis Method: EPA 9060 QC Batch Method: EPA 9060 Analysis Description: 9060 TOC Average Associated Lab Samples: 92245417001, 92245417002, 92245417003 METHOD BLANK: 1151665 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mean Total Organic Carbon mg/kg ND 600 05/05/15 06:54 LABORATORY CONTROL SAMPLE: 1151666 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mean Total Organic Carbon mg/kg 120000 112000 93 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1151667 1151668 MS MSD 92245417001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg 1210 8070 8150 7880 8310 83 87 50-150 5 30 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1151669 1151670 MS MSD 92246050004 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg 697J 7910 7920 7420 7490 85 86 50-150 1 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/29/2015 02:56 PM without the written consent of Pace Analytical Services, Inc.. Page 52 of 57 ac.Anayy�ical www.pacelabs.com Pace Analytical Services, Inc. 9800 1�nlc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: J15040305 Pace Project No.: 92245417 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TN -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-G Pace Analytical Services - Green Bay PASI-M Pace Analytical Services - Minneapolis PASI-O Pace Analytical Services - Ormond Beach BATCH QUALIFIERS Batch: ICP/14486 Ill Samples on this batch were diluted due to the presence of high levels of non -target analytes or other matrix interference. ANALYTE QUALIFIERS B Analyte was detected in the associated method blank. D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. E Analyte concentration exceeded the calibration range. The reported result is estimated. H1 Analysis conducted outside the EPA method holding time. H3 Sample was received or analysis requested beyond the recognized method holding time. H6 Analysis initiated outside of the 15 minute EPA recommended holding time. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/29/2015 02:56 PM without the written consent of Pace Analytical Services, Inc.. Page 53 of 57 ac...-.nayical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, INC 28078 (704)875-9092 QUALIFIERS Project: J15040305 Pace Project No.: 92245417 ANALYTE QUALIFIERS N2 The lab does not hold TIN accreditation for this parameter. R1 RPD value was outside control limits. Z2 Analyte present in the associated method blank above the detection limit. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/29/2015 02:56 PM without the written consent of Pace Analytical Services, Inc.. Page 54 of 57 ac.�naly�ical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: J15040305 Pace Project No.: 92245417 Lab ID Sample ID QC Batch Method QC Batch Analytical Method 92245417001 2015010590 EPA 3050 MPRP/23700 EPA 6010 92245417002 2015010591 EPA 3050 MPRP/23700 EPA 6010 92245417003 2015010592 EPA 3050 MPRP/23700 EPA 6010 92245417001 2015010590 EPA 3050 MPRP/23701 EPA 6020 92245417002 2015010591 EPA 3050 MPRP/23701 EPA 6020 92245417003 2015010592 EPA 3050 MPRP/23701 EPA 6020 92245417004 2015010593 EPA 3020 MPRP/53693 EPA 6020A 92245417005 2015010594 EPA 3020 MPRP/53693 EPA 6020A 92245417006 2015010590 SPLP EPA 3020 MPRP/54102 EPA 6020A 92245417004 2015010593 EPA 7470 MERP/13262 EPA 7470 92245417005 2015010594 EPA 7470 MERP/13262 EPA 7470 92245417006 2015010590 SPLP EPA 7470A MERP/13418 EPA 7470A 92245417001 2015010590 EPA 7471 MERP/5609 EPA 7471 92245417002 2015010591 EPA 7471 MERP/5609 EPA 7471 92245417003 2015010592 EPA 7471 MERP/5609 EPA 7471 92245417001 2015010590 ASTM D2974-87 PMST/3462 92245417002 2015010591 ASTM D2974-87 PMST/3462 92245417003 2015010592 ASTM D2974-87 PMST/3462 92245417001 2015010590 EPA 9045 WET/31102 92245417002 2015010591 EPA 9045 WET/31102 92245417003 2015010592 EPA 9045 WET/31102 92245417001 2015010590 EPA 300.0 WETA/22735 92245417001 2015010590 EPA 353.2 WETA/22748 92245417001 2015010590 SM 4500-CI-E WETA/22743 92245417001 2015010590 EPA 9056 WETA/45547 92245417002 2015010591 EPA 9056 WETA/45549 92245417003 2015010592 EPA 9056 WETA/45549 92245417001 2015010590 EPA 9056 WETA/45546 92245417002 2015010591 EPA 9056 WETA/45548 92245417003 2015010592 EPA 9056 WETA/45548 92245417001 2015010590 EPA 9060 WETA/28317 92245417001 2015010590 EPA 9060 WETA/28318 92245417002 2015010591 EPA 9060 WETA/28317 92245417002 2015010591 EPA 9060 WETA/28318 92245417003 2015010592 EPA 9060 WETA/28317 92245417003 2015010592 EPA 9060 WETA/28318 Date: 05/29/2015 02:56 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Analytical Batch ICP/14486 ICP/14486 ICP/14486 ICPM/9634 ICPM/9634 ICPM/9634 ICPM/23840 ICPM/23840 ICPM/24074 MERC/15414 MERC/15414 MERC/15601 MERC/5599 MERC/5599 MERC/5599 Page 55 of 57 Document Name: Document Revised: September 21. ZU14 64 Sample Condition Upon Receipt SCUR aceAn��dyficalU Page 1 of 2 Document Number: issuing Author :° F-CHR-CS-003-rev.15 Pace Huntersville Quality Office Client Name: Courier: ❑ Fed Ex ❑ UPS❑ USPS❑ Client❑ Commerciallff Pace Other Custody Seal on Cooler/Box Present: ❑ yes Elno Seals intact: Elyes Elno Packing Material: ❑ Bubble VDp ❑ .3 bole Bags ❑' None ❑ Other Thermometer Used: IR Gun T1401 Type of Ice: et Blue None ❑ Samples on ice, cooling process has begun Temp Correction Factor T140 No Correction Tissue is Frozen: Yes No N/A Date a�d s�of r�pntexamining Corrected Cooler Temp.: 'C Biological cont nt Temp should be above freezing to 6'C Comments: Chain of Custody Present: ElYes ONO ❑NIA 1. Chain of Custody Filled Out: 21K, ONO ❑NIA 2. Chain of Custody Relinquished: gle, ON, ❑NIA 3. Sampler Name & Signature on COC: es ONO ❑NIA 4. Samples Arrived within Hold Time: FfYes ONO ❑NIA 5. Short Hold Time Analysis (a72hr): Dyes ZNo El N/A 6. Rush Turn Around Time Requested: [Dyes ❑ o ❑NIA 7. Sufficient Volume: ❑y,410No ❑NIA 8. Correct Containers Used: ids ONO ❑NIA 9. -Pace Containers Used: ❑Yes ❑No ❑NIA Containers Intact: 21es ONO ❑NIA 10. Filtered Volume received for Dissolved tests ❑Yes ONO QWK 11. Sample Labels match COC: _Q'Kes ONO ❑NIA 12. -Includes date/time/ID/Analysis Matrix: All containers needing preservation have been checked. 11 ONO All containers needing preservation are found to be in L^res ON, compliance with EPA recommendation. exceptions: VOA, conform, TOC, O&G, WI-DRO (water) Oyes ONO Samples checked for dechlorination: ❑Yes ONO ❑N/A 14. Headspace in VOA Vials (>6mm): ❑Yes ONO ❑NIA 15, Trip Blank Present: ❑Yes ONO ElW 16. Trip Blank Custody Seals Present ❑Yes ❑No ❑NIA Pace Trip Blank Lot # (if purchased): Client Notification/ Resolution: Field Data Required? Y 1 N Person Contacted: Date/Time: Comments/ Resolution: SCURF Review: L (,C{ r Date: I qllym SRF Review: AQ Date: J I /.d Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office ( i.e out of hold, incorrect preservative, out of temp, incorrect containers) WO#:92245417 92245417 Yniuuiuuii Page 56 of 57 I I I a i � a n m I e Ctrstvtner to complete 3ppropria1e cotlumns t°,ngi�t" y i I I i O 713 =. P rJ ff1 e Iw to rA O a A Z th Cf1 w — - 0 to N 3 iE I "Comp. 65 of 66 Cuelamer malt Complete a e ol m u � 2 s T Z C > M C 3 5 `� D a m fMi iD I V � � [ I a_ a N (D i 71 3 E„ d© w 1 'mm3 rra �a1 �! 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AS Groundwuter As5 essnient - Soil I)CLWW ApGA PACE C4N;kkF Tanv W po 1142081 ir A - AB GW 3-H LO V 71mewcudis: Tj f— Opp; ijrtj,ij ry art 4,4 to 16 C < FirwhervP'll iVO4 when used �10'0 bw impoltanL W01ion spych s 0 r2�nmd tho Fa4j.yMjjrj, 11 f5p44t roFF.4 r...Mnu in .14 5 a,. 1,o-Anfl" hKodt Mb'�r of oddedwilt,111 PSK&Oesol sample 1in do P .1j'Id. aoffF l ac.ounkIN tot 0earnk114u I loll mnKt Hm,--- ICr:rrdlectic1112 Z C I "C0jj@Ct6DFj nformation go 4 0 1 'j -J LARUM-IMLY "Lbe "Samplu Description or ID ve!!— 71n" SIUMIlUFM # gC:L R 'n cc '4 201 F % ano 14, to IJ T --T MW 65 -P WATER— -JE@WlFW19N-12LA-- ��-14=n' t4:c tare y-- r—FF-c "Requipstd Turnaround f7_j., FI-- j14 D&O Dmys �mmA Ama�,).�tt� 4[1+6�1 w12 I "F40--ft Ills: At, PKAWE I Cd, Cir Cr, CU, Frf. Pb, MID, M rk, MO, N1, K, Sp, Nor Sr, 3% V, Zfl� Mcrcury, A 5420 j)%trlbutbrk, RedaK RDWOOLM A.L- ri hlk+.AOEAU Fn ';PtMwV qnm--kffic ftrannatir4m: 'ASollf]-h- C EC. Piwtk