NC0038377_J15030573report_20150902

Lab
DUI E Analytical Laboratory APage11aof30
ENERGY
Order Number:
Project Name:
Customer Name(s):
Customer Address:
Lab Contact:
Report Authorized By:
(Signature)
Program Comments:
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone:[phone] Fax:[phone]
Order Summary Report
J15030573
MAYO STEAM - AB GW ASSESSMENT WATER
Tim Hunsucker, Jerry Wylie, Kathy Webb, John Toepfer
Mary Ann Ogle Mary Ann Ogle Phone: [phone]
"(� ✓ 2015.04.15 14:26:05
n
-04'00' Date:
Mary Ann Ogle
Please contact the Program Manager (Mary Ann Ogle) with any questions regarding this report.
Data Flags & Calculations:
4/15/2015
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Sample ID's & Descriptions:
Analytical Lab
Page 2 of 30
Sample ID Plant/Station
2015008082 MAYO STEAM
1 Total Samples
Collection
Date and Time Collected By
20-Mar-15 12:30 PM illegible
Sample Description
M W-4

Analytical Lab
Page 3 of 30
Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals 0 Yes ❑ No
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits. ❑ Yes 0 No
All laboratory QA/QC requirements are acceptable. 0 Yes ❑ No
Report Sections Included:
E%-'] Job Summary Report
❑� Sample Identification
Technical Validation of Data Package
❑� Analytical Laboratory Certificate of Analysis
❑ Analytical Laboratory QC Report
❑d Sub -contracted Laboratory Results
❑ Customer Specific Data Sheets, Reports, & Documentation
❑ Customer Database Entries
❑� Chain of Custody
❑� Electronic Data Deliverable (EDD) Sent Separately
Reviewed By: Mary Ann Ogle Date: 4/15/2015

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15030573
Site: MW-4
Collection Date: 20-Mar-15 12:30 PM
Analyte
Result
Units
Qualifiers
RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter
Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)
0.295
mg-N/L
0.01
INORGANIC IONS BY IC
Chloride
6.6
mg/L
N1
0.1
Sulfate
34
mg/L
N1
1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
0.033
mg/L
0.005
Barium (Ba)
0.005
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.013
mg/L
0.01
Manganese (Mn)
0.006
mg/L
0.005
Strontium (Sr)
0.098
mg/L
0.005
Zinc (Zn)
0.008
mg/L
0.005
UNDIGESTED METALS BY lCP
Calcium (Ca)
28.4
mg/L
M4
0.1
Magnesium (Mg)
6.96
mg/L
M4
0.005
Potassium (K)
5.48
mg/L
0.1
Sodium (Na)
17.8
mg/L
M4
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.118
mg/L
0.005
Barium (Ba)
0.006
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.070
mg/L
0.01
Manganese (Mn)
0.015
mg/L
0.005
Strontium (Sr)
0.099
mg/L
0.005
Zinc (Zn)
0.009
mg/L
0.005
Sample #: 2015008082
Matrix: GW WW
Analytical Lab
Page 4 of 30
DF Method Analysis Date/Time Analyst
Vendor Method
V_SHEALY
1
EPA 353.2
03/24/2015 14:18
TLINN
1
EPA 300.0
03/26/2015 15:10
BGN9034
10
EPA 300.0
03/26/2015 15:10
BGN9034
1
EPA 245.1
03/25/2015 17:06
ACPAYNE
1
EPA 245.1
03/25/2015 18:31
ACPAYNE
1
EPA 200.7
03/24/2015 12:08
MHALL3
1
EPA 200.7
03/24/2015 12:08
MHALL3
1
EPA 200.7
03/24/2015 12:08
MHALL3
1
EPA 200.7
03/24/2015 12:08
MHALL3
1
EPA 200.7
03/24/2015 12:08
MHALL3
1
EPA 200.7
03/24/2015 12:08
MHALL3
1
EPA 200.7
03/24/2015 12:08
MHALL3
10
EPA 200.7
03/24/2015 14:18
MHALL3
1
EPA 200.7
03/24/2015 14:18
MHALL3
1
EPA 200.7
03/24/2015 14:18
MHALL3
1
EPA 200.7
03/24/2015 14:18
MHALL3
1
EPA 200.7
03/25/2015 13:07
MHALL3
1
EPA 200.7
03/25/2015 13:07
MHALL3
1
EPA 200.7
03/25/2015 13:07
MHALL3
1
EPA 200.7
03/25/2015 13:07
MHALL3
1
EPA 200.7
03/25/2015 13:07
MHALL3
1
EPA 200.7
03/25/2015 13:07
MHALL3
1
EPA 200.7
03/25/2015 13:07
MHALL3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15030573
Site: MW-4
Collection Date: 20-Mar-15 12:30 PM
Analyte
Result
DISSOLVED METALS BY ICP-MS
Antimony (Sb)
< 1
Arsenic (As)
< 1
Beryllium (Be)
< 1
Cadmium (Cd)
< 1
Chromium (Cr)
< 1
Cobalt (Co)
< 1
Copper (Cu)
< 1
Lead (Pb)
< 1
Molybdenum (Mo)
2.30
Nickel (Ni)
< 1
Selenium (Se)
< 1
Thallium (TI) Low Level
< 0.2
Vanadium (V) Low Level
0.596
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
Arsenic (As)
< 1
Beryllium (Be)
< 1
Cadmium (Cd)
< 1
Chromium (Cr)
< 1
Cobalt (Co)
< 1
Copper (Cu)
1.01
Lead (Pb)
< 1
Molybdenum (Mo)
2.38
Nickel (Ni)
< 1
Selenium (Se)
< 1
Thallium (TI) Low Level
< 0.2
Vanadium (V) Low Level
0.891
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
190
Total Carbon
TOC
0.553
TOTAL SUSPENDED SOLIDS
TSS
< 5
Sample #: 2015008082
Matrix: GW WW
Analytical Lab
Page 5 of 30
Units Qualifiers
RDL
DF
Method
Analysis Date/Time
Analyst
ug/L
1
1
EPA 200.8
04/14/2015 15:36
JAHERMA
ug/L
1
1
EPA 200.8
04/14/2015 15:36
JAHERMA
ug/L
1
1
EPA 200.8
04/14/2015 15:36
JAHERMA
ug/L
1
1
EPA 200.8
04/14/2015 15:36
JAHERMA
ug/L
1
1
EPA 200.8
04/14/2015 15:36
JAHERMA
ug/L
1
1
EPA 200.8
04/14/2015 15:36
JAHERMA
ug/L
1
1
EPA 200.8
04/14/2015 15:36
JAHERMA
ug/L
1
1
EPA 200.8
04/14/2015 15:36
JAHERMA
ug/L
1
1
EPA 200.8
04/14/2015 15:36
JAHERMA
ug/L
1
1
EPA 200.8
04/14/2015 15:36
JAHERMA
ug/L
1
1
EPA 200.8
04/14/2015 15:36
JAHERMA
ug/L
0.2
1
EPA 200.8
04/14/2015 15:36
JAHERMA
ug/L
0.3
1
EPA 200.8
04/14/2015 15:36
JAHERMA
ug/L
1
1
EPA 200.8
04/13/2015 16:29
JAHERMA
ug/L
1
1
EPA 200.8
04/13/2015 16:29
JAHERMA
ug/L
1
1
EPA 200.8
04/13/2015 16:29
JAHERMA
ug/L
1
1
EPA 200.8
04/13/2015 16:29
JAHERMA
ug/L
1
1
EPA 200.8
04/13/2015 16:29
JAHERMA
ug/L
1
1
EPA 200.8
04/13/2015 16:29
JAHERMA
ug/L
1
1
EPA 200.8
04/13/2015 16:29
JAHERMA
ug/L
1
1
EPA 200.8
04/13/2015 16:29
JAHERMA
ug/L
1
1
EPA 200.8
04/13/2015 16:29
JAHERMA
ug/L
1
1
EPA 200.8
04/13/2015 16:29
JAHERMA
ug/L
1
1
EPA 200.8
04/13/2015 16:29
JAHERMA
ug/L
0.2
1
EPA 200.8
04/13/2015 16:29
JAHERMA
ug/L
0.3
1
EPA 200.8
04/13/2015 16:29
JAHERMA
Vendor Method
V_SHEALY
mg/L 25
mg/L N1 0.1
mg/L 5
Vendor Method
V_ELE1
1 SM2540C 03/24/201511:00
AGIBBS5
1 SM5310C/EPA9060A 03/31/201516:16
TJA7067
1 SM2540D 02/25/2015 08:46
AGIBBS5

Analytical Lab
Certificate of Laboratory Analysis Page 6 of 30
This report shall not be reproduced, except in full.
Order # J15030573
Qualifiers:
M4 The spike recovery value was unusable since the analyte concentration in the sample was disproportionate to
the spike level. The associated Laboratory Control Spike recovery was acceptable.
N1 See additional information listed below.
-- Additional Information --
This sample was stored in a refrigerator that malfunctioned causing the sample to freeze. The state was notified and
the results may be reported for compliance purposes as long as the data is flagged. Any parameter requiring
preservation at < 6C and that was tested after 3/25/2015 at 15:45 when the refrigerator was documented to be in
compliance are flagged with N1.

Analytical Lab
Page 7 of 30
�7lCl!1!■!■lLV71■Illt�I ■ lei
Duke Energy
Laboratory Services
13339 Hagers Ferry Road Bid. MG03A
Huntersville, NC 28078
Sample Matrix
GW WW
Date Analyzed
03/26/2015
Delivered by
FedEx
eOne ID Duke Energy ID
24351-1" MW-4
EF elrnent One Inc.
6319-D Carolina Beach Rd.
Wiimington, IBC 284112
Rhone: 910 793-0128
Fax: [phone]
[e-mail]
REPORT OF ANALYSES
March 27, 2015
Client Project Name AB GW Assessment Water Mayo
Client Project Number J15030573
PO Number
Sample Type
Grab
Date Received
03/25/2015
Method
SM 4500 S2- D
Time Received
0940
Received by
LLB
Parameter
Result Unit Dil
DL Date
Time
Sampled
Sampled
Sulfide
< 1.00 mg/L 10
0.1 03/20/15
1230
"Sample spike recovery outside of QA limits of 85-115%; dilution necessary to meet laboratory QA limits.
Ken 9mith, Laboratory Director
24351 Duke Report Packet Compiled by�
NC Certifications: DW 37788 and DWQ DENR 604

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elementOne SAMPLE SUBMISSION FORM
TAT 7 BD
Hold Time Expiration 03.27.15 @ 1230 PM
Client: Duke Energy
LIMS No J15030573
Project ID AB GW Assessment Water — Mayo
Analytical Lab
Lab IDPagJv1
Analysis Due Date 03.26.15
Report Due Date 04.03.15
Date Rec:
03.25.15
Time Rec:
0940
Rec By
LLB
H >9 No
Temp < 6°C Yes No
Ref. Method:
SM4500 S2 D
If No, Record
If No, Record
Sample Identification & Collection Information
Lab ID Client ID Collection Date Collection Time Analysis Requested
1 MW-4 03.20.15 1230 PM Sulfide
NOTE for Sulfide The MS/MSD spike should approximate 2 to 3 times the sample concentration. If no sulfide detected
at 100 pg/L spike the sample to render the final spike concentration at — 500 pg/L

Analytical Lab
Page 10 of 30
METHOD:
SM 4500 S2- D
ELEMENT ONE
ELEMENT ASSAY:
Sulfide
Spectrophotometer
Wave Length 664
UNITS OF ANSWER
ug/mL
DETECTION LIMIT u
1.000
CLIENT:
Duke
SPK LEVEL u
5
Lab ID#
24347/348/349/350/351
Na2S•9H2O Lo t#
40721
MAX ALIQUOT
10.00
Date:
3.26.15
STANDARD conc(ppm)
X
Time Analysis Begun
800
10
Time Analysis Ended
1100
Analyst:
KLS/KMS
JSTD ABSORPTION
Y
X
Y
o roo
ug STD
SOLUTION
STD
ABS
oeoo
05�
-
0.00
1.00
2.50
5.00
7.50
10.00
0.000
0.065
0.159
0.305
0.455
0.598
0400
6
, ao
0 300
- 0
0200
-
0,00
-
.000
°�
.00 zoo am eoo ano 1000 ,z 00
X
Sloe 0.059665934
Correlation 0.999868769
SAMPLE
I.D.
SAMP
ABS
ug PER
ALIQUOT
ALI in mL
ANALYZED
PREP
VOL in mL
ALI in mL
TAKEN
RESULTS
ug/mL
LESS THAN
% SPK REC
SPIKE
LEVEL
0
0.00
-0.1179
10
10
10
<
1 QC
0.059
0.8650
10
10
10
<
86%
1.0
2.5 QC
0.154
2.4749
10
10
10
0.247
99%
2.5
5 QC
0.307
5.0677
10
10
10
0.507
101 %
5.0
7.5 QC
0.455
7.5757
10
10
10
0.758
101 %
7.5
10 QC
0.585
9.7788
10
10
10
0.978
98%
10.0
LRB Su ernant
0.001
-0.1179
10
10
10
<
LRB S k Su ernant
0.064
0.9497
10
10
10
<
LRB Floculent
0.002
-0.1010
10
10
10
<
LRB SPK Floculent
0.121
1.9157
10
10
1
1.916
103%
1.864
24351
0.002
-0.1010
10
10
10
<
24351 s k
0.234
3.8306
10
10
10
0.383
77%
5.0
24350
0.002
-0.1010
10
10
10
<
24350 s k
0.022
0.2380
10
10
10
<
5%
5.0
24249-1
0.016
0.1363
10
10
10
<
24249-1 s k
0.243
3.9831
10
10
10
0.398
80%
5.0
24249-2
0.037
0.4922
10
10
10
<
24249-2 s k
0.158
2.5427
10
10
10
0.254
51 %
5.0
24249-3
0.002
-0.1010
10
10
10
<
24249-3 s k
0.135
2.1529
10
10
10
0.215
43%
5.0
24249-4
0.003
-0.0840
10
10
10
<
24249-4 s k
0.201
3.2714
10
10
10
0.327
65%
5.0
Submitted for QA/QC-
Date: 3.26.15
By: (Print)
KLS/KMS
(sign):

Analytical Lab
Page 11 of 30
METHOD:
SM 4500 S2- D
ELEMENT ONE
ELEMENT ASSAY:
Sulfide
Spectrophotometer
Wave Length 664
UNITS OF ANSWER
ug/mL
DETECTION LIMIT u
1.000
CLIENT:
Duke
SPK LEVELLu_qj
5
Lab ID#
24347/348/349/350/351
Na2S•9H2O Lo t#
40721
MAX ALIQUOT
10.00
Date:
3.26.15
STANDARD conc(ppm)
X
Time Analysis Begun
800
1
10
Time Analysis Ended
1100
Analyst:
KLS/KMS
STD ABSORPTION
Y
X
Y
o ,00
ug STD
SOLUTION
STD
ABS
osoo
osoo
0.00
1.00
2.50
5.00
7.50
10.00
0.000
0.065
0.159
0.305
0.455
0.598
0 <00
v
-
-
o aoo
0200
0,00
o 00o
ow 200 4� 000 Boo ,200 oao
X
Sloe 0.059665934
Correlation 0.999868769
SAMPLE
I.D.
SAMP
ABS
ug PER
ALIQUOT
ALI in mL
ANALYZED
PREP
VOL in mL
ALI in mL
TAKEN
RESULTS
ug/mL
LESS THAN
% SPK REC
SPIKE
LEVEL
24348-2
0.00
0.0000
10
10
10
<
24348-2 s k
0.049
0.6955
10
10
10
<
14%
5.0
24348-3
0.009
0.0177
10
10
10
<
24348-3 s k
0.048
0.6786
10
10
10
<
14%
5.0
24348-4
0.013
0.0855
10
10
10
<
24348-4 s k
0.101
1.5767
10
10
10
0.158
32%
5.0
24351
0.002
-0.1010
10
10
5
<
24351 s k
0.208
3.3900
10
10
5
0.678
68%
5.0
24350
0
0.0000
10
10
2
<
24350 s k
0.066
0.9836
10
10
2
<
20%
5.0
24249-1
0.009
0.0177
10
10
5
<
24249-1 s k
0.219
3.5764
10
10
5
0.715
72%
5.0
24249-2
0.035
0.4583
10
10
5
<
24249-2 s k
0.234
3.8306
10
10
5
0.766
77%
5.0
24249-3
0.016
0.1363
10
10
5
<
24249-3 s k
0.169
2.7291
10
10
5
0.546
55%
5.0
24249-4
0.004
-0.0671
10
10
5
<
24249-4 s k
0.194
3.1527
10
10
5
0.631
63%
5.0
24348-2
0.002
-0.1010
10
10
2
<
24348-2 s k
0.133
2.1190
10
10
2
1.06
42%
5.0
24348-3
0
0.0000
10
10
2
<
24348-3 s k
0.126
2.0004
10
10
2
1.00
40%
5.0
24348-4
0.007
-0.0162
1 10
10
2
<
24348-4 s k
0.184
2.9833
10
10
2
1.49
60%
5.0
Submitted for QA/QC-
Date: 3.26.15
By: (Print)
KLS/KMS
(sign):

Analytical Lab
Page 12 of 30
METHOD:
SM 4500 S2- D
ELEMENT ONE
ELEMENT ASSAY:
Sulfide
Spectrophotometer
Wave Length 664
UNITS OF ANSWER
ug/mL
DETECTION LIMIT u
1.000
CLIENT:
Duke
SPK LEVELLug)
5
Lab ID#
24347/348/349/350/351
Na2S•9H2O Lo t#
40721
ISTD
MAX ALIQUOT
10.00
Date:
3.26.15
STANDARD conc(ppm)
X
Time Analysis Begun
800
10
Time Analysis Ended
1100
Analyst:
KLS/KMS
ABSORPTION
Y
X
Y
0 700
ug STD
SOLUTION
STD
ABS
o0oo
-
6
-loo
0.00
1.00
2.50
5.00
7.50
10.00
0.000
0.065
0.159
0.305
0.455
0.598
0 <oo
Y
-
0 30o
--
- s°
0200
0100
o 00o
o W 200 400 0.00 300 10Uo 1200
X
Sloe 0.059665934
Correlation 0.999868769
SAMPLE
I.D.
SAMP
ABS
ug PER
ALIQUOT
ALI in mL
ANALYZED
PREP
VOL in mL
ALI in mL
TAKEN
RESULTS
ug/mL
LESS THAN
% SPK REC
SPIKE
LEVEL
24351
0.01
-0.0501
10
10
1
< 1.0
24351 s k
0.309
5.1016
10
10
1
5.10
102%
5.0
24350
0.004
-0.0671
10
10
0.5
<
24350 s k
0.176
2.8477
10
10
0.5
5.70
57%
5.0
24249-1
0.003
-0.0840
10
10
1
< 1.0
24249-1 s k
0.315
5.2032
10
10
1
5.20
104%
5.0
24249-2
0.008
0.0007
10
10
1
< 1.0
24249-2 s k
0.299
4.9321
10
10
1
4.93
99%
5.0
24249-3
0.003
-0.0840
10
10
1
< 1.0
24249-3 s k
0.297
4.8982
10
10
1
4.90
98%
5.0
24249-4
0.001
-0.1179
10
10
1
< 1.0
24249-4 s k
0.309
5.1016
10
10
1
5.10
102%
5.0
24348-2
0
0.0000
10
10
1
<
24348-2 s k
0.252
4.1356
10
10
1
4.14
83%
5.0
24348-3
0.001
-0.1179
10
10
1
<
24348-3 s k
0.245
4.0170
10
10
1
4.02
80%
5.0
24348-4
0.001
-0.1179
10
10
1
< 1.0
24348-4 s k
0.292
4.8135
10
10
1
4.81
96%
5.0
Submitted for QA/QC-
Date: 3.26.15
By: (Print)
KLS/KMS
(sign):

Analytical Lab
Page 13 of 30
METHOD:
SM 4500 S2- D
ELEMENT ONE
ELEMENT ASSAY:
Sulfide
Spectrophotometer
Wave Length 664
UNITS OF ANSWER
ug/mL
DETECTION LIMIT u
1.000
CLIENT:
Duke
SPK LEVELjuM
5
Lab ID#
24347/348/349/350/351
Na2S•9H2O Lo t#
40721
MAX ALIQUOT
10.00
Date:
3.26.15
STANDARD conc(ppm)
X
Time Analysis Begun
800
1 1
10
Time Analysis Ended
1100
Analyst:
KLS/KMS
STD ABSORPTION
Y
XY
070
ug STD
SOLUTION
STD
oeW
ABS
es
°
0.00
1.00
2.50
5.00
7.50
10.00
0.000 °`°°
0.065 I
Ono
o
0.159
o,W
0.305
OW 2W 400 900 900 1000 14.00
0.455
0.598
Sloe 0.059665934
Correlation 0.999868769
SAMPLE
I.D.
SAMP
ABS
ug PER
ALIQUOT
ALI in mL
ANALYZED
PREP
VOL in mL
ALI in mL
TAKEN
RESULTS
ug/mL
LESS THAN
% SPK REC
SPIKE
LEVEL
24350
0.00
0.0000
10
10
0.25
<
24350 s k
0.23
3.7628
10
10
0.25
15.1
75%
5.0
24348-2
0.001
-0.1179
10
10
0.5
< 2.0
24348-2 s k
0.29
4.7796
10
10
0.5
9.56
96%
5.0
24348-3
0.003
-0.0840
10
10
0.5
< 2.0
24348-3 s k
0.291
4.7965
10
10
0.5
9.59
96%
5.0
24350
0.005
-0.0501
10
10
0.2
< 5.0
24350 s k
0.245
4.0170
10
10
0.2
20.1
80%
5.0
1 QC
0.066
0.9836
10
10
10
<
98%
1.0
2.5 QC
0.161
2.5935
10
10
10
0.259
104%
2.5
5 QC
0.31
5.1185
10
10
10
0.512
102%
5.0
7.5 QC
0.46
7.6605
10
10
10
0.766
102%
7.5
10 QC
0.604
10.1007
10
10
10
1.010
101 %
10.0
Submitted for QA/QC-
Date: 3.26.15
By: (Print)
KLS/KMS
(sign):

SHEALY ENVIRONMENTAL SERVICES, INC.
Report of Analysis
Duke Energy
13339 Hagers Ferry Rd
Bldg 7405
Huntersville, NC 28078
Attention: Mary Ann Ogle
Project Name: AB GW Assessment Water - Mayo
Project Number:J15030573
Lot Number:QC27016
Date Completed:04/08/2015
Grant Wilton
Project Manager
This report shall not be reproduced, except in its entirety, without the written approval of Shealy Environmental Services, Inc.
The following non -paginated documents are considered part of this report: Chain of Custody Record and Sample Receipt Checklist.
*QC27016*
Shealy Environmental Services, Inc. Page: 1 of 6
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SHEALY ENVIRONMENTAL SERVICES, INC.
SC DHEC No: 32010 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
Case Narrative
Duke Energy
Lot Number: QC27016
Project Name: AB GW Assessment Water - Mayo
Project Number: J15030573
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample
receiving date is documented in the header information associated with each sample.
All results listed in this report relate only to the samples that are contained within this report.
Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the
Shealy Environmental Services, Inc. ("Shealy") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPS), and Shealy
policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below.
If you have any questions regarding this report please contact the Shealy Project Manager listed on the cover page
Shealy Environmental Services, Inc. Page: 2 of 6
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SHEALY ENVIRONMENTAL SERVICES, INC.
Sample Summary
Duke Energy
Lot Number: QC27016
Project Name: AB GW Assessment Water - Mayo
Project Number: J15030573
Sample Number Sample ID Matrix Date Sampled Date Received
001 2015008082 Aqueous 03/20/20151230 03/27/2015
(1 sample)
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SHEALY ENVIRONMENTAL SERVICES, INC.
Executive Summary
Duke Energy
Lot Number: QC27016
Project Name: AB GW Assessment Water - Mayo
Project Number: J15030573
Sample Sample ID Matrix Parameter Method Result Q Units Page
001 2015008082 Aqueous Alkalinity SM 2320B- 88 mg/L 5
001 2015008082 Aqueous Bicarbonate Alkalinity SM 2320B- 88 mg/L 5
(2 detections)
Shealy Environmental Services, Inc. Page: 4 of 6
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Inorganic non-metals
Client: Duke Energy Laboratory ID: QC27016-001
Description: 2015008082 Matrix: Aqueous
Date Sampled:03/20/2015 1230 Project Name: AB GW Assessment Water -
Date Received:03/27/2015 Project Number: J15030573
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 2320B-2011
1 04/02/2015 0001
HMA 71441
1
(Bicarbonate ) SM 2320B-2011
1 04/02/2015 0001
HMA 04/02/2015 1201
1
(Carbonate Al) SM 2320B-2011
1 04/02/2015 0001
HMA 04/02/2015 1201
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
88
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
88
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 5 of 6
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Methane
Client: Duke Energy Laboratory ID: QC27016-001
Description: 2015008082 Matrix: Aqueous
Date Sampled:03/20/2015 1230 Project Name: AB GW Assessment Water -
Date Received:03/27/2015 Project Number: J15030573
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 03/27/2015 1940 DCS 71148
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 6 of 6
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QC Summary
Shealy Environmental Services, Inc. QC Data for Lot Number: QC27016
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals - Ii
Sample ID: QQ71441-001 Matrix: Aqueous
Batch: 71441
Analytical Method: SM 2320B-2011
Parameter Result Q Dil PQL Units Analysis Date
Alkalinity ND 1 10 mg/L 04/01/2015 2201
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QC27016
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals - LCS
Sample ID: QQ71441-002 Matrix: Aqueous
Batch: 71441
Analytical Method: SM 2320B-2011
Spike
Amount Result % Rec
Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Alkalinity 100 98 1 98 90-110 04/01/2015 2207
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QC27016
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals - MS
Sample ID: QC27016-001 MS Matrix: Aqueous
Batch: 71441
Analytical Method: SM 2320B-2011
Sample Spike
Amount Amount Result % Rec
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Alkalinity 88 100 180 1 92 70-130 04/02/2015 0007
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QC27016
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals - MSD
Sample ID: QC27016-001MD Matrix: Aqueous
Batch: 71441
Analytical Method: SM 2320B-2011
Sample Spike
Amount Amount Result % Rec % RPD
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date
Alkalinity 88 100 180 1 91 0.57 70-130 20 04/02/2015 0013
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QC27016
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane - MB
Sample ID: QQ71148-001 Matrix: Aqueous
Batch: 71148
Analytical Method: RSK - 175
Parameter Result Q Dil PQL Units Analysis Date
Methane ND 1 10 ug/L 03/27/20151407
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QC27016
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane - LCS
Sample ID: QQ71148-002 Matrix: Aqueous
Batch: 71148
Analytical Method: RSK - 175
Spike
Amount Result % Rec
Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date
Methane 150 150 1 99 70-130 03/27/20151342
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QC27016
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane - LCSD
Sample ID: QQ71148-003 Matrix: Aqueous
Batch: 71148
Analytical Method: RSK - 175
Spike
Amount Result % Rec % RPD
Parameter (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date
Methane 150 190 1 128 26 70-130 30 03/27/20151355
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QC27016
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

SHEALY ENVIRONMENTAL SERVICES, INC
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Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

SHEALY ENVIRONMENTAL SERVICES, INC.
Shrmlg Fnwro menrml 'jervµm. Inc
Dacurotnl Nurmbee! l--AU-016
Revisicra Nwriber 16
1'Wi+xfI
Repinacs Date: 07115114
F:ff' ive Date: t ti07I14
Sample Receipt Chetkii.st (SRC)
Client' u E { C'iz�aler inxpezted by/date: -f 1 r21-1 S' Lot 'Up
means ofreceipt. ❑ 5E51 ❑ Client ❑ UTPS edEx ❑ Airbornc Exp ❑ Other
ales 0 1. weie ewsilod_y seals on the coiner?
Yes TwloLl I NA Ll 2. if custody seals were ,e:setlt were they intact and unbrokerr7
Cooler IDr'1]riginal tcmperatum upon receiprffierived (corrected) ternprrature upon receipt-
Method: ❑ Ternperalture Fi k Against Baattics I1t Gun 1D; #4 11{ Qua Co 'ctinn Falctor� ¢C
Method vtcoolant: I't Ice S141e 1kx ❑ Dr�� lee ❑ JVs�i1e
3, ifIcinperature Dfany coolerexceeded 6,01C, was Project 14Ianager nntificd?
Yes ❑ No ❑ t,4 PM nlmificd by SM, phone, mate (circle one,), other.,
V07- ccacrlcrs .received via oornincrciai com ier, PlAs aIr to lie rl+otillcd
i tarnedintelv.l
Yea
w o ❑
NA ❑ 4. 1s the coixifnenill coudur's packing -,lip attached to this form` f
YGj
11 No ❑
5. Wair r cr custody proceduren rel° 11i 17. i.{-etc yed fo lowed?
Yes
o ❑
ETA ❑ 5a Were samples relinquished by client to uumTnercial courier?
Yes
W>0 ❑
+ . Wore stem lc IDs listed on the COC?
Yes
34Q❑
?, Were sarra le Ds listed on all sample containers;'
Yes
a va ❑
$. Was collection date & Carrie listed on the COC?
Yes
ZN0
4_ Was collection date & time, listed on all sample containers?
Yes
Z Io ❑
10, Did all Container label infurrina,tion ID, date, time ag= with the COC?
Yes
El1 1. Were tests to be performed listed on the COU'
,.a ❑ 12- Did a]I samples arrive in the proper containers for ea;ah test?
Y"
Yes
No ❑ 13. Did all containers arrive in Mod condition Linbrokesn, lids on, etc. '?
7es
hTv ❑ 14, Was ade
quate sample volume availa.blc?
Yes ❑ Ne
15- Were all samples re ved within % the holding tirne ar 48 hours, whichever
comes first?
Y€s ❑ Nov16.
Wereanv saml2les contain' missing?
Yes ❑ vo
17. Were there any excess samp Ins not listed on COC?
Yes ❑ No ❑ NA
is, Wem bubbles present>" ea -size" (A"Or 6nun in diameter in any VOA vials?
Yes ❑ No ❑ NA
Z 19, Were ail l rtietalslO&G.IHEM/nutrient samples received at a pH of ?
Yes ❑ No ❑ NA
20- Were all o anide andlor sulfide samples rew— ivcd at a pH > 12?
yes ❑ No ❑ NA
t,'4't+'erealI appiica6lo XH3lTKNkyalnide)phenol samples free of
residual chlorine?
Yes ❑ No ❑ NA
22. Were collection tem eratures doculmenred on the COC for N"IC sam les?
Yes [I Nc ❑ NA
3. Were Clicnl rcmarksftquests (1-e, requested dilutions, h�i5�'IwiSD designations,
etc... cnrr tl rr�nsr;riibrd from the COC. int-3 the udmm rnt section in LIM B?
V P., ❑ Nqe
24- Was the quote number used taken from, the vontainer label?
Sample Preservation
(Must he completed far any sample(s) ineorrectly preserved or with headspace.)
sample(g) were received incorrmily preserved and Caere adjusted
accordingly in sample receiving with (HasQ4jTh][i3, 4Cl,NaOH usin SR4
Samples)
were received with bubbles orb mm in diameter.
sample(s)
mere rsrcivod with ']`KC >Q.2 rn&L (if (t21 is No)
SC Drinking Water Project Sample(s) pH verified to he > 2 by Date:
saeu 1 s -A%-re riot received at a H of aril werz adjusted according usjRg SIB#
sample labels applied by- _. _ Verified by; Diate. 3�7�-
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

CHAIN OF CUSTODY RECORD AND ANALYSiS REQUFST FORM
-------------- --------- I - ----------
---------- ---------- — ------ — — -- --------- — N!W"
Duke F:rinirqy _jMMwx G*-WW
MAO c"twoumu 4wwir.07�1 ordefra Z-3057
Aiialytiul LaWfaForY J3Mq6WgM1.-1iTVW ! — 1 ---7 ORONAL io LAIB. COPY In CLIVNT
chwin of clistaliv & N c 2DIT4 'NY am a T"M S"PLE PROORAM
Snrrkly;c Lug qAAj 6754F20 -is- (3mrid Wslmf NPOES
YJYL Xtav - ------ il OAST
RCJRA MOO
AH 13W.A"4"M -------------- -------------
2nt MOW rad*J"JiM
SHEALY
PO 1142089
SHEALY
Element 1
—PO-1142133
tmum jo," um)
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lmlnwType
BMLMill
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