NC0038377_J15030555 Report_20150902

DUE Analytical Laboratory Page 1 of 125
' ENERGY
Order Number:
Project Name:
Customer Name(s):
Customer Address:
Lab Contact:
Report Authorized By:
(Signature)
Program Comments:
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone:[phone] Fax:[phone]
Order Summary Report
J15030555
AB GW ASSESSMENT SOIL
Tim Hunsucker, Jerry Wylie, Kathy Webb, John Toepfer
Margaret Galvin -Karr Phone: [phone]
marge.galvin-karr@duke-
v�,�ye energy.com Date:
ll 2015.04.23 14:30:49-04'00'
Margaret Galvin -Karr
Please contact the Program Manager (Margaret Galvin -Karr) with any questions regarding this report.
Data Flags & Calculations:
4/22/2015
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Sample ID's & Descriptions:
Page 2 of 125
Sample ID
Plant/Station
Collection
Date and Time
Collected By
Sample Description
2015007996
MAYO STEAM
18-Mar-15 3:35 PM
illegible
Well MAY-AB2(18-20)
2015007997
MAYO STEAM
18-Mar-15 3:50 PM
illegible
Well MAY-AB2(32.9-33.7)
2015007998
MAYO STEAM
18-Mar-15 9:30 AM
illegible
Well MAY-AB3(4-5)
2015007999
MAYO STEAM
17-Mar-15 3:45 PM
illegible
Well MAY-AB4(53-55)
2015008000
MAYO STEAM
18-Mar-15 2:30 PM
illegible
Well MAY-AB2(4-5)
2015008001
MAYO STEAM
17-Mar-15 1:05 PM
illegible
Well MAY-AB4(4-5)
2015008002
MAYO STEAM
18-Mar-15 12:20 PM
illegible
Well MAY-AB3(21.6-23.4)
2015008003
MAYO STEAM
18-Mar-15 1:15 PM
illegible
Well MAY-AB3(41.7-42.5)
2015008004
MAYO STEAM
17-Mar-15 3:30 PM
illegible
Well MAY-AB4(33-35)
2015008005
MAYO STEAM
17-Mar-15 3:30 PM
illegible
Well MAY-AB4(33-35)-DUP
2015008006
MAYO STEAM
19-Mar-15 9:20 AM
illegible
Well MAY-AB1(4-5)
2015008007
MAYO STEAM
19-Mar-15 12:30 PM
illegible
Well MAY-AB1(48-50)
2015008008
MAYO STEAM
19-Mar-15 12:40 PM
illegible
Well MAY-AB1(34.3-35.0)
2015008009
MAYO STEAM
19-Mar-15 9:00 AM
illegible
Well AB-1 EB
2015008010
MAYO STEAM
18-Mar-15 8:50 AM
illegible
Well AB-3EB
2015008011
MAYO STEAM
17-Mar-15 12:35 PM
illegible
Well AB-4EB
2015008012
MAYO STEAM
18-Mar-15 4:00 PM
illegible
Well AB-2EB
17 Total Samples

Page 3 of 125
Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals Yes No
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits. ❑ Yes No
All laboratory QA/QC requirements are acceptable. (] Yes ❑ No
Report Sections Included:
L� Job Summary Report
❑ Sample Identification
n Technical Validation of Data Package
6 Analytical Laboratory Certificate of Analysis
❑ Analytical Laboratory QC Report
LVI Sub -contracted Laboratory Results
❑ Customer Specific Data Sheets, Reports, & Documentation
❑ Customer Database Entries
6 Chain of Custody
LVI Electronic Data Deliverable (EDD) Sent Separately
Reviewed By: DBA Account Date: 4/22/2015

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15030555
Site: Well MAY-AB2(18-20)
Collection Date: 18-Mar-15 3:35 PM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
SPLP LEACHATE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Page 4 of 125
Sample #: 2015007996
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15030555
Site: Well MAY-AB2(32.9-33.7)
Collection Date: 18-Mar-15 3:50 PM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Page 5 of 125
Sample #: 2015007997
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15030555
Site: Well MAY-AB3(4-5)
Collection Date: 18-Mar-15 9:30 AM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Page 6 of 125
Sample #: 2015007998
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15030555
Site: Well MAY-AB4(53-55)
Collection Date: 17-Mar-15 3:45 PM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
SPLP LEACHATE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Page 7 of 125
Sample #: 2015007999
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15030555
Site: Well MAY-AB2(4-5)
Collection Date: 18-Mar-15 2:30 PM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Page 8 of 125
Sample #: 2015008000
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15030555
Site: Well MAY-AB4(4-5)
Collection Date: 17-Mar-15 1:05 PM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Page 9 of 125
Sample #: 2015008001
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15030555
Site: Well MAY-AB3(21.6-23.4)
Collection Date: 18-Mar-15 12:20 PM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
SPLP LEACHATE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Page 10 of 125
Sample #: 2015008002
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15030555
Site: Well MAY-AB3(41.7-42.5)
Collection Date: 18-Mar-15 1:15 PM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Page 11 of 125
Sample #: 2015008003
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15030555
Site: Well MAY-AB4(33-35)
Collection Date: 17-Mar-15 3:30 PM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Page 12 of 125
Sample #: 2015008004
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15030555
Site: Well MAY-AB4(33-35)-DUP
Collection Date: 17-Mar-15 3:30 PM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Page 13 of 125
Sample #: 2015008005
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15030555
Site: Well MAY-AB1(4-5)
Collection Date: 19-Mar-15 9:20 AM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Page 14 of 125
Sample #: 2015008006
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15030555
Site: Well MAY-AB1(48-50)
Collection Date: 19-Mar-15 12:30 PM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
SPLP LEACHATE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Page 15 of 125
Sample #: 2015008007
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15030555
Site: Well MAY-AB1(34.3-35.0)
Collection Date: 19-Mar-15 12:40 PM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Page 16 of 125
Sample #: 2015008008
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis Page 17 of 125
This report shall not be reproduced, except in full.
Order # J15030555
Site: Well AB-1 EB
Collection Date: 19-Mar-15 9:00 AM
Analyte Result Units Qualifiers RDL DF
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Sample #: 2015008009
Matrix: OTHER
Method Analysis Date/Time Analyst
Vendor Method V_PACE

Certificate of Laboratory Analysis Page 18 of 125
This report shall not be reproduced, except in full.
Order # J15030555
Site: Well AB-3EB
Collection Date: 18-Mar-15 8:50 AM
Analyte Result Units Qualifiers RDL DF
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Sample #: 2015008010
Matrix: OTHER
Method Analysis Date/Time Analyst
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15030555
Site: Well AB-4EB
Collection Date: 17-Mar-15 12:35 PM
Analyte Result Units Qualifiers RDL DF
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Page 19 of 125
Sample #: 2015008011
Matrix: OTHER
Method Analysis Date/Time Analyst
Vendor Method V_PACE

Certificate of Laboratory Analysis Page 20 of 125
This report shall not be reproduced, except in full.
Order # J15030555
Site: Well AB-2EB
Collection Date: 18-Mar-15 4:00 PM
Analyte Result Units Qualifiers RDL DF
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Sample #: 2015008012
Matrix: OTHER
Method Analysis Date/Time Analyst
Vendor Method V_PACE

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
P3S�O�I WY24Y e. Suite 100
y Huntersville, INC 28078
[phone]
April 08, 2015
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg.7405 MG30A2
Huntersville, NC 28078
RE: Project: J 150305555
Pace Project No.: 92242381
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on March 23, 2015. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TN standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc: Marge Galvin -Karr, Duke Energy
Program Manager, Duke Energy
Rodney Wilke, Duke Energy
p«FO
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
y without the written consent of Pace Analytical Services, Inc.. Page 1 of 104

lacmnalyfica(
www.pacelabs.com
Pace Analytical Services, Inc.
pgaal�y2lge. Suite 100
Huntersville, NC 28078
[phone]
Project: J150305555
Pace Project No.: 92242381
Minnesota Certification IDs
1700 Elm Street SE Suite 200, Minneapolis, MN 55414
A21-A Certification #: 2926.01
Alaska Certification #: UST-078
Alaska Certification #MN00064
Alabama Certification #40770
Arizona Certification #: AZ-0014
Arkansas Certification #: 88-0680
California Certification #: 01155CA
Colorado Certification #Pace
Connecticut Certification #: PH-0256
EPA Region 8 Certification #: 8TMS-L
Florida/NELAP Certification #: E87605
Guam Certification #:14-008r
Georgia Certification #: 959
Georgia EPD #: Pace
Idaho Certification #: MN00064
Hawaii Certification #MN00064
Illinois Certification #: 200011
Indiana Certification#C-MN-01
Iowa Certification #: 368
Kansas Certification #: E-10167
Kentucky Dept of Envi. Protection - DW #90062
Kentucky Dept of Envi. Protection - WW #:90062
Louisiana DEQ Certification #: 3086
Louisiana DHH #: LA140001
Maine Certification #: 2013011
Maryland Certification #: 322
Michigan DEPH Certification #: 9909
Ormond Beach Certification IDs
8 East Tower Circle, Ormond Beach, FL 32174
Alabama Certification #: 41320
Connecticut Certification #: PH-0216
Delaware Certification: FL NELAC Reciprocity
Florida Certification #: E83079
Georgia Certification #: 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification #: 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383
Kentucky Certification #: 90050
Louisiana Certification #: FL NELAC Reciprocity
Louisiana Environmental Certificate #: 05007
Maryland Certification: #346
Massachusetts Certification #: M-FL1264
Michigan Certification #: 9911
Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236
Green Bay Certification IDs
1241 Bellevue Street, Green Bay, WI 54302
Florida/NELAP Certification #: E87948
Illinois Certification #: 200050
Kentucky Certification #: 82
Louisiana Certification #: 04168
Minnesota Certification #: 055-999-334
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
CERTIFICATIONS
Minnesota Certification #: 027-053-137
Mississippi Certification #: Pace
Montana Certification #: MT0092
Nevada Certification #: MN_00064
Nebraska Certification #: Pace
New Jersey Certification #: MN-002
New York Certification #: 11647
North Carolina Certification #: 530
North Carolina State Public Health #: 27700
North Dakota Certification #: R-036
Ohio EPA#: 4150
Ohio VAP Certification #: CL101
Oklahoma Certification #: 9507
Oregon Certification #: MN200001
Oregon Certification #: MN300001
Pennsylvania Certification #: 68-00563
Puerto Rico Certification
Saipan (CNMI) #:MP0003
South Carolina #:74003001
Texas Certification #: T104704192
Tennessee Certification #: 02818
Utah Certification #: MN000642013-4
Virginia DGS Certification #: 251
Virginia/VELAP Certification #: Pace
Washington Certification #: C486
West Virginia Certification #: 382
West Virginia DHHR #:9952C
Wisconsin Certification #: 999407970
Montana Certification #: Cert 0074
Nebraska Certification: NE-OS-28-14
Nevada Certification: FL NELAC Reciprocity
New Hampshire Certification #: 2958
New Jersey Certification #: FL765
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FLO1264
South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
Washington Certification #: C955
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
North Dakota Certification #: R-150
South Carolina Certification #: 83006001
Texas Certification #: T104704529-14-1
US Dept of Agriculture #: S-76505
Wisconsin Certification #: 405132750
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 2 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
P3S�OzlSWM249e. Suite 100
y Huntersville, NC 28078
[phone]
Project: J150305555
Pace Project No.: 92242381
Asheville Certification IDs
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
CERTIFICATIONS
West Virginia Certification #: 356
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 3 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
P3Sy RG&WY2'9e. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE SUMMARY
Project: J150305555
Pace Project No.: 92242381
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92242381001
2015007996
Solid
03/18/1515:33
03/23/15 15:04
92242381002
2015007999
Solid
03/17/1515:45
03/23/15 15:04
92242381003
2015008002
Solid
03/18/1512:20
03/23/15 15:04
92242381004
2015008007
Solid
03/19/1512:30
03/23/15 15:04
92242381005
2015007997
Solid
03/18/1515:50
03/23/15 15:04
92242381006
2015007998
Solid
03/18/15 09:30
03/23/15 15:04
92242381007
2015008000
Solid
03/18/1514:30
03/23/15 15:04
92242381008
2015008001
Solid
03/17/1513:05
03/23/15 15:04
92242381009
2015008003
Solid
03/18/1513:15
03/23/15 15:04
92242381010
2015008004
Solid
03/17/1515:30
03/23/15 15:04
92242381011
2015008005
Solid
03/17/1515:30
03/23/15 15:04
92242381012
2015008006
Solid
03/19/15 09:20
03/23/15 15:04
92242381013
2015008008
Solid
03/19/1512:40
03/23/15 15:04
92242381014
2015008009
Water
03/19/15 09:00
03/23/15 15:04
92242381015
2015008010
Water
03/18/15 08:50
03/23/15 15:04
92242381016
2015008011
Water
03/17/1512:35
03/23/15 15:04
92242381017
2015008012
Water
03/18/1516:00
03/23/15 15:04
92242381018
2015007996 SPLP
Water
03/18/15 15:35
03/23/15 15:04
92242381019
2015007999 SPLP
Water
03/17/15 15:45
03/23/15 15:04
92242381020
2015008002 SPLP
Water
03/18/15 12:20
03/23/15 15:04
92242381021
2015008007 SPLP
Water
03/18/15 12:30
03/23/15 15:04
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 4 of 104

aceAnaiXical
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Pace Analytical Services, Inc.
P 36 90A r6f Y 2'9 e. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project: J150305555
Pace Project No.: 92242381
Lab ID
Sample ID
Method
Analysts
Analytes
Reported
Laboratory
92242381001
2015007996
EPA 6010
TAP
16
PASI-0
EPA 6020
CRT
8
PASI-O
EPA7471
HEA
1
PASI-O
ASTM D2974-87
RPM
1
PASI-O
EPA 9045
MLS
1
PASI-A
EPA 300.0
AES2
1
PASI-A
EPA 353.2
DMN
1
PASI-A
SM 4500-CI-E
SER
1
PASI-A
EPA 9056
CMB
2
PASI-O
EPA 9056
CMB
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92242381002
2015007999
EPA 6010
TAP
16
PASI-0
EPA 6020
CRT
8
PASI-O
EPA 7471
HEA
1
PASI-O
ASTM D2974-87
RPM
1
PASI-O
EPA 9045
MLS
1
PASI-A
EPA 300.0
AES2
1
PASI-A
EPA 353.2
DMN
1
PASI-A
SM 4500-CI-E
SER
1
PASI-A
EPA 9056
CMB
2
PASI-O
EPA 9056
CMB
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92242381003
2015008002
EPA 6010
CKJ
16
PASI-0
EPA 6020
CRT
8
PASI-O
EPA7471
HEA
1
PASI-O
ASTM D2974-87
RPM
1
PASI-O
EPA 9045
MLS
1
PASI-A
EPA 300.0
AES2
1
PASI-A
EPA 353.2
DMN
1
PASI-A
SM 4500-CI-E
SER
1
PASI-A
EPA 9056
CMB
2
PASI-O
EPA 9056
CMB
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92242381004
2015008007
EPA 6010
CKJ
16
PASI-0
EPA 6020
CRT
8
PASI-O
EPA7471
HEA
1
PASI-O
ASTM D2974-87
RPM
1
PASI-O
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 5 of 104

aceAnaiXical
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Pace Analytical Services, Inc.
P369QAr6fY2'9e. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project: J150305555
Pace Project No.: 92242381
Lab ID
Sample ID
Method
Analysts
Analytes
Reported
Laboratory
EPA 9045
MLS
1
PASI-A
EPA 300.0
AES2
1
PASI-A
EPA 353.2
DMN
1
PASI-A
SM 4500-CI-E
SER
1
PASI-A
EPA 9056
CMB
2
PASI-O
EPA 9056
CMB
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92242381005
2015007997
EPA 6010
CKJ
16
PASI-0
EPA 6020
CRT
8
PASI-O
EPA7471
HEA
1
PASI-O
ASTM D2974-87
RPM
1
PASI-O
EPA 9045
MLS
1
PASI-A
EPA 9056
CMB
2
PASI-O
EPA 9056
CMB
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92242381006
2015007998
EPA 6010
CKJ
16
PASI-0
EPA 6020
CRT
8
PASI-O
EPA7471
HEA
1
PASI-O
ASTM D2974-87
RPM
1
PASI-O
EPA 9045
MLS
1
PASI-A
EPA 9056
CMB
2
PASI-O
EPA 9056
CMB
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92242381007
2015008000
EPA 6010
CKJ
16
PASI-0
EPA 6020
CRT
8
PASI-O
EPA7471
HEA
1
PASI-O
ASTM D2974-87
RPM
1
PASI-O
EPA 9045
MLS
1
PASI-A
EPA 9056
CMB
2
PASI-O
EPA 9056
CMB
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92242381008
2015008001
EPA 6010
CKJ, TAP
16
PASI-0
EPA 6020
CRT
8
PASI-O
EPA7471
HEA
1
PASI-O
ASTM D2974-87
RPM
1
PASI-O
EPA 9045
MLS
1
PASI-A
EPA 9056
CMB
2
PASI-O
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 6 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
P369'*r6fY2'9e. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project:
J150305555
Pace Project No.:
92242381
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
EPA 9056
CMB
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92242381009
2015008003
EPA 6010
CKJ, TAP
16
PASI-0
EPA 6020
CRT
8
PASI-O
EPA7471
HEA
1
PASI-O
ASTM D2974-87
RPM
1
PASI-O
EPA 9045
MLS
1
PASI-A
EPA 9056
AIS
2
PASI-O
EPA 9056
AIS
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92242381010
2015008004
EPA 6010
CKJ
16
PASI-0
EPA 6020
CRT
8
PASI-O
EPA7471
HEA
1
PASI-O
ASTM D2974-87
RPM
1
PASI-O
EPA 9045
MLS
1
PASI-A
EPA 9056
AIS
2
PASI-O
EPA 9056
AIS
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92242381011
2015008005
EPA 6010
CKJ
16
PASI-0
EPA 6020
CRT
8
PASI-O
EPA7471
HEA
1
PASI-O
ASTM D2974-87
RPM
1
PASI-O
EPA 9045
MLS
1
PASI-A
EPA 9056
AIS
2
PASI-O
EPA 9056
AIS
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92242381012
2015008006
EPA 6010
CKJ
16
PASI-0
EPA 6020
CRT
8
PASI-O
EPA7471
HEA
1
PASI-O
ASTM D2974-87
RPM
1
PASI-O
EPA 9045
MLS
1
PASI-A
EPA 9056
AIS
2
PASI-O
EPA 9056
AIS
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92242381013
2015008008
EPA 6010
CKJ
16
PASI-0
EPA 6020
CRT
8
PASI-O
EPA7471
HEA
1
PASI-O
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 7 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
P369QAr6fY2'9e. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project: J150305555
Pace Project No.: 92242381
Lab ID
Sample ID
Method
Analysts
Analytes
Reported
Laboratory
ASTM D2974-87
RPM
1
PASI-O
EPA 9045
MLS
1
PASI-A
EPA 9056
AIS
2
PASI-O
EPA 9056
AIS
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92242381014
2015008009
EPA 6020A
TT3
24
PASI-M
EPA 7470
DM
1
PASI-M
92242381015
2015008010
EPA 6020A
TT3
24
PASI-M
EPA 7470
DM
1
PASI-M
92242381016
2015008011
EPA 6020A
TT3
24
PASI-M
EPA 7470
DM
1
PASI-M
92242381017
2015008012
EPA 6020A
TT3
24
PASI-M
EPA 7470
DM
1
PASI-M
92242381018
2015007996 SPLP
EPA 6020A
RJS
24
PASI-M
EPA 7470
JDD
1
PASI-M
92242381019
2015007999 SPLP
EPA 6020A
RJS
24
PASI-M
EPA 7470
JDD
1
PASI-M
92242381020
2015008002 SPLP
EPA 6020A
RJS
24
PASI-M
EPA 7470
JDD
1
PASI-M
92242381021
2015008007 SPLP
EPA 6020A
RJS
24
PASI-M
EPA 7470
JDD
1
PASI-M
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 8 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
P 36 90A r6f Y 2'9 e. Suite 100
Huntersville, NC 28078
[phone]
SUMMARY OF DETECTION
Project:
Pace Project No.:
J150305555
92242381
Lab Sample ID
Client Sample ID
Method
Parameters
Result
Units
Report Limit
Analyzed
Qualifiers
92242381001
2015007996
EPA 6010
Aluminum
3200
mg/kg
7.7
04/02/15 09:35
M1
EPA 6010
Barium
44.1
mg/kg
0.77
04/02/15 09:35
M1
EPA 6010
Beryllium
0.73
mg/kg
0.077
04/02/15 09:35
EPA 6010
Boron
7.3
mg/kg
3.9
04/02/15 09:35
EPA 6010
Calcium
551
mg/kg
38.7
04/02/15 09:35
EPA 6010
Chromium
10.6
mg/kg
0.39
04/02/15 09:35
EPA 6010
Copper
10.6
mg/kg
0.39
04/02/15 09:35
EPA 6010
Iron
2840
mg/kg
3.1
04/02/15 09:35
M1
EPA 6010
Magnesium
212
mg/kg
38.7
04/02/15 09:35
EPA 6010
Manganese
24.1
mg/kg
0.39
04/02/15 09:35
M1
EPA 6010
Molybdenum
0.53J
mg/kg
0.77
04/02/15 09:35
EPA 6010
Nickel
7.2
mg/kg
0.39
04/02/15 09:35
EPA 6010
Potassium
396
mg/kg
77.4
04/02/15 09:35
M1
EPA 6010
Sodium
81.5
mg/kg
77.4
04/02/15 09:35
EPA 6010
Strontium
25.4
mg/kg
0.77
04/02/15 09:35
M1
EPA 6010
Zinc
10.5
mg/kg
1.5
04/02/15 09:35
EPA 6020
Arsenic
3.3J
mg/kg
3.9
03/31/15 21:42
D3
EPA 6020
Cobalt
4.5
mg/kg
3.9
03/31/15 21:42
D3
EPA 6020
Lead
7.4
mg/kg
3.9
03/31/15 21:42
D3
EPA 6020
Vanadium
16.9
mg/kg
3.9
03/31/15 21:42
D3
ASTM D2974-87
Percent Moisture
33.9
%
0.10
04/01/15 16:19
EPA 9045
pH at 25 Degrees C
6.4
Std. Units
0.10
03/30/15 12:55
EPA300.0
Sulfate
17.8
mg/L
15.1
04/01/1520:10
B,D3
EPA353.2
Nitrogen, Nitrate
308
mg/L
15.1
03/31/1519:26
B,H1
EPA 9056
Sulfate
200J
mg/kg
378
03/28/15 11:06
D3
EPA 9060
Total Organic Carbon
25300
mg/kg
2660
04/03/15 12:07
EPA 9060
Total Organic Carbon
25200
mg/kg
2650
04/03/15 12:14
EPA 9060
Total Organic Carbon
26400
mg/kg
2620
04/03/15 12:20
EPA 9060
Total Organic Carbon
16700
mg/kg
2610
04/03/15 12:27
EPA 9060
Mean Total Organic Carbon
23400
mg/kg
2640
04/03/15 12:07
EPA 9060
RSD%
19.3
%
04/03/15 12:07
92242381002
2015007999
EPA 6010
Aluminum
8960
mg/kg
8.6
04/02/15 09:46
EPA 6010
Barium
67.3
mg/kg
0.86
04/02/15 09:46
EPA 6010
Beryllium
2.3
mg/kg
0.086
04/02/15 09:46
EPA 6010
Boron
25.5
mg/kg
4.3
04/02/15 09:46
EPA 6010
Calcium
1100
mg/kg
42.8
04/02/15 09:46
EPA 6010
Chromium
24.5
mg/kg
0.43
04/02/15 09:46
EPA 6010
Copper
33.1
mg/kg
0.43
04/02/15 09:46
EPA 6010
Iron
2860
mg/kg
3.4
04/02/15 09:46
EPA 6010
Magnesium
497
mg/kg
42.8
04/02/15 09:46
EPA 6010
Manganese
13.6
mg/kg
0.43
04/02/15 09:46
EPA 6010
Molybdenum
1.2
mg/kg
0.86
04/02/15 09:46
EPA 6010
Nickel
18.5
mg/kg
0.43
04/02/15 09:46
EPA 6010
Potassium
1230
mg/kg
85.6
04/02/15 09:46
EPA 6010
Sodium
119
mg/kg
85.6
04/02/15 09:46
EPA 6010
Strontium
60.6
mg/kg
0.86
04/02/15 09:46
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 9 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
P369'�VWY249e. Suite 100
Huntersville, NC 28078
[phone]
SUMMARY OF DETECTION
Project:
Pace Project No.:
J150305555
92242381
Lab Sample ID
Client Sample ID
Method
Parameters
Result
Units
Report Limit
Analyzed
Qualifiers
92242381002
2015007999
EPA 6010
Zinc
19.0
mg/kg
1.7
04/02/15 09:46
EPA 6020
Arsenic
10
mg/kg
4.3
03/31/15 21:58
D3
EPA 6020
Cobalt
12.9
mg/kg
4.3
03/31/1521:58
D3,M6
EPA 6020
Lead
14.5
mg/kg
4.3
03/31/1521:58
D3,M6
EPA 6020
Vanadium
64.7
mg/kg
4.3
03/31/1521:58
D4,M6
ASTM D2974-87
Percent Moisture
39.9
%
0.10
04/01/15 16:19
EPA 9045
pH at 25 Degrees C
7.8
Std. Units
0.10
03/25/15 11:50
EPA300.0
Sulfate
12.6
mg/L
6.7
04/01/1520:24
B,D3
EPA353.2
Nitrogen, Nitrate
333
mg/L
16.6
03/31/1519:27
B,H1
EPA 9060
Total Organic Carbon
19600
mg/kg
3870
04/03/15 13:19
EPA 9060
Total Organic Carbon
19400
mg/kg
3940
04/03/15 13:26
EPA 9060
Total Organic Carbon
18500
mg/kg
3870
04/03/15 13:32
EPA 9060
Total Organic Carbon
26500
mg/kg
3940
04/03/15 13:38
EPA 9060
Mean Total Organic Carbon
21000
mg/kg
3900
04/03/15 13:19
EPA 9060
RSD%
17.6
%
04/03/15 13:19
92242381003
2015008002
EPA 6010
Aluminum
3760
mg/kg
6.7
04/01/15 21:21
EPA 6010
Barium
41.1
mg/kg
0.67
04/01/15 21:21
EPA 6010
Beryllium
0.93
mg/kg
0.067
04/01/15 21:21
EPA 6010
Boron
7.3
mg/kg
3.4
04/01/15 21:21
EPA 6010
Calcium
581
mg/kg
33.6
04/01/15 21:21
EPA 6010
Chromium
13.3
mg/kg
0.34
04/01/15 21:21
EPA 6010
Copper
12.9
mg/kg
0.34
04/01/15 21:21
EPA 6010
Iron
2470
mg/kg
2.7
04/01/15 21:21
EPA 6010
Magnesium
204
mg/kg
33.6
04/01/15 21:21
EPA 6010
Manganese
14.1
mg/kg
0.34
04/01/15 21:21
EPA 6010
Molybdenum
0.591
mg/kg
0.67
04/01/15 21:21
EPA 6010
Nickel
6.8
mg/kg
0.34
04/01/15 21:21
EPA 6010
Potassium
451
mg/kg
67.2
04/01/15 21:21
EPA 6010
Sodium
63.OJ
mg/kg
67.2
04/01/15 21:21
EPA 6010
Strontium
20.6
mg/kg
0.67
04/01/15 21:21
EPA 6010
Zinc
8.2
mg/kg
1.3
04/01/15 21:21
EPA 6020
Arsenic
3.3J
mg/kg
3.4
03/31/15 22:05
D3
EPA 6020
Cobalt
4.0
mg/kg
3.4
03/31/15 22:05
D3
EPA 6020
Lead
5.2
mg/kg
3.4
03/31/15 22:05
D3
EPA 6020
Vanadium
15.0
mg/kg
3.4
03/31/15 22:05
D3
ASTM D2974-87
Percent Moisture
27.6
%
0.10
04/01/15 16:19
EPA 9045
pH at 25 Degrees C
6.4
Std. Units
0.10
03/30/15 12:55
EPA300.0
Sulfate
19.9
mg/L
13.8
04/01/1520:38
B,D3
EPA353.2
Nitrogen, Nitrate
236
mg/L
13.8
03/31/15 19:28
B,H1
EPA 9056
Sulfate
326J
mg/kg
350
03/28/15 11:49
D3
EPA 9060
Total Organic Carbon
10800
mg/kg
834
04/03/15 13:44
EPA 9060
Total Organic Carbon
14800
mg/kg
822
04/03/15 13:49
EPA 9060
Total Organic Carbon
23100
mg/kg
826
04/03/15 13:55
EPA 9060
Total Organic Carbon
11700
mg/kg
824
04/03/15 14:02
EPA 9060
Mean Total Organic Carbon
15100
mg/kg
826
04/03/15 13:44
EPA 9060
RSD%
37.1
%
04/03/15 13:44
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 10 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
P36903f WY2"Y e. Suite 100
Huntersville, NC 28078
[phone]
SUMMARY OF DETECTION
Project:
Pace Project No.:
J150305555
92242381
Lab Sample ID
Client Sample ID
Method
Parameters
Result
Units
Report Limit
Analyzed
Qualifiers
92242381004
2015008007
EPA 6010
Aluminum
3060
mg/kg
7.0
04/01/15 21:25
EPA 6010
Barium
34.7
mg/kg
0.70
04/01/15 21:25
EPA 6010
Beryllium
0.64
mg/kg
0.070
04/01/15 21:25
EPA 6010
Boron
5.9
mg/kg
3.5
04/01/15 21:25
EPA 6010
Calcium
483
mg/kg
35.0
04/01/15 21:25
EPA 6010
Chromium
8.0
mg/kg
0.35
04/01/15 21:25
EPA 6010
Copper
8.0
mg/kg
0.35
04/01/15 21:25
EPA 6010
Iron
1820
mg/kg
2.8
04/01/15 21:25
EPA 6010
Magnesium
180
mg/kg
35.0
04/01/15 21:25
EPA 6010
Manganese
9.4
mg/kg
0.35
04/01/15 21:25
EPA 6010
Molybdenum
0.63J
mg/kg
0.70
04/01/15 21:25
EPA 6010
Nickel
5.4
mg/kg
0.35
04/01/15 21:25
EPA 6010
Potassium
367
mg/kg
70.0
04/01/15 21:25
EPA 6010
Sodium
55.OJ
mg/kg
70.0
04/01/15 21:25
EPA 6010
Strontium
17.9
mg/kg
0.70
04/01/15 21:25
EPA 6010
Zinc
6.8
mg/kg
1.4
04/01/15 21:25
EPA 6020
Arsenic
2.6J
mg/kg
3.5
03/31/15 22:08
D3
EPA 6020
Cobalt
3AJ
mg/kg
3.5
03/31/15 22:08
D3
EPA 6020
Lead
4.0
mg/kg
3.5
03/31/15 22:08
D3
EPA 6020
Vanadium
13.7
mg/kg
3.5
03/31/15 22:08
D3
ASTM D2974-87
Percent Moisture
30.7
%
0.10
04/01/15 16:20
EPA 9045
pH at 25 Degrees C
7.3
Std. Units
0.10
03/30/15 12:55
EPA300.0
Sulfate
11.8
mg/L
5.8
04/02/1511:14
B,D3
EPA353.2
Nitrogen, Nitrate
180
mg/L
8.7
03/31/1518:44
B,H1
EPA 9060
Total Organic Carbon
49000
mg/kg
3100
04/03/15 14:08
EPA 9060
Total Organic Carbon
30100
mg/kg
3110
04/03/15 14:15
EPA 9060
Total Organic Carbon
43500
mg/kg
3140
04/03/15 14:22
EPA 9060
Total Organic Carbon
34500
mg/kg
3100
04/03/15 14:30
EPA 9060
Mean Total Organic Carbon
39300
mg/kg
3110
04/03/15 14:08
EPA 9060
RSD%
21.7
%
04/03/15 14:08
92242381005
2015007997
EPA 6010
Aluminum
3460
mg/kg
7.8
04/01/15 21:29
EPA 6010
Barium
51.8
mg/kg
0.78
04/01/15 21:29
EPA 6010
Beryllium
0.78
mg/kg
0.078
04/01/15 21:29
EPA 6010
Boron
7.7
mg/kg
3.9
04/01/15 21:29
EPA 6010
Calcium
632
mg/kg
38.9
04/01/15 21:29
EPA 6010
Chromium
10.2
mg/kg
0.39
04/01/15 21:29
EPA 6010
Copper
11.7
mg/kg
0.39
04/01/15 21:29
EPA 6010
Iron
2420
mg/kg
3.1
04/01/15 21:29
EPA 6010
Magnesium
231
mg/kg
38.9
04/01/15 21:29
EPA 6010
Manganese
22.6
mg/kg
0.39
04/01/15 21:29
EPA 6010
Molybdenum
0.54J
mg/kg
0.78
04/01/15 21:29
EPA 6010
Nickel
7.2
mg/kg
0.39
04/01/15 21:29
EPA 6010
Potassium
402
mg/kg
77.7
04/01/15 21:29
EPA 6010
Sodium
92.2
mg/kg
77.7
04/01/15 21:29
EPA 6010
Strontium
28.9
mg/kg
0.78
04/01/15 21:29
EPA 6010
Zinc
10.1
mg/kg
1.6
04/01/15 21:29
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 11 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
P369'*r6fY2'9e. Suite 100
Huntersville, NC 28078
[phone]
SUMMARY OF DETECTION
Project:
Pace Project No.:
J150305555
92242381
Lab Sample ID
Client Sample ID
Method
Parameters
Result
Units
Report Limit
Analyzed
Qualifiers
92242381005
2015007997
EPA 6020
Arsenic
3AJ
mg/kg
3.9
03/31/15 22:10
D3
EPA 6020
Cobalt
4.7
mg/kg
3.9
03/31/15 22:10
D3
EPA 6020
Lead
5.3
mg/kg
3.9
03/31/15 22:10
D3
EPA 6020
Vanadium
16.7
mg/kg
3.9
03/31/15 22:10
D3
ASTM D2974-87
Percent Moisture
32.3
%
0.10
04/01/15 16:20
EPA 9045
pH at 25 Degrees C
6.4
Std. Units
0.10
03/30/15 12:55
EPA 9056
Sulfate
216J
mg/kg
362
03/28/15 12:32
D3
EPA 9060
Total Organic Carbon
16200
mg/kg
2380
04/03/15 14:36
EPA 9060
Total Organic Carbon
17800
mg/kg
2340
04/03/15 14:42
EPA 9060
Total Organic Carbon
15200
mg/kg
2380
04/03/15 14:48
EPA 9060
Total Organic Carbon
14200
mg/kg
2320
04/03/15 14:57
EPA 9060
Mean Total Organic Carbon
15800
mg/kg
2350
04/03/15 14:36
EPA 9060
RSD%
9.5
%
04/03/15 14:36
92242381006
2015007998
EPA 6010
Aluminum
863
mg/kg
6.7
04/01/15 21:33
EPA 6010
Barium
38.7
mg/kg
0.67
04/01/15 21:33
EPA 6010
Beryllium
0.20
mg/kg
0.067
04/01/15 21:33
EPA 6010
Boron
2.6J
mg/kg
3.3
04/01/15 21:33
EPA 6010
Calcium
377
mg/kg
33.3
04/01/15 21:33
EPA 6010
Chromium
2.0
mg/kg
0.33
04/01/15 21:33
EPA 6010
Copper
3.0
mg/kg
0.33
04/01/15 21:33
EPA 6010
Iron
1010
mg/kg
2.7
04/01/15 21:33
EPA 6010
Magnesium
58.1
mg/kg
33.3
04/01/15 21:33
EPA 6010
Manganese
11.9
mg/kg
0.33
04/01/15 21:33
EPA 6010
Molybdenum
0.38J
mg/kg
0.67
04/01/15 21:33
EPA 6010
Nickel
2.6
mg/kg
0.33
04/01/15 21:33
EPA 6010
Potassium
110
mg/kg
66.7
04/01/15 21:33
EPA 6010
Strontium
8.0
mg/kg
0.67
04/01/15 21:33
EPA 6010
Zinc
2.1
mg/kg
1.3
04/01/15 21:33
EPA 6020
Vanadium
2.9J
mg/kg
3.3
03/31/15 22:12
D3
ASTM D2974-87
Percent Moisture
21.6
%
0.10
04/01/15 16:21
EPA 9045
pH at 25 Degrees C
6.4
Std. Units
0.10
03/30/15 12:55
EPA 9060
Total Organic Carbon
6380
mg/kg
1110
04/03/15 15:03
EPA 9060
Total Organic Carbon
7810
mg/kg
1120
04/03/15 15:09
EPA 9060
Total Organic Carbon
5960
mg/kg
1120
04/03/15 15:15
EPA 9060
Total Organic Carbon
6370
mg/kg
1120
04/03/15 15:21
EPA 9060
Mean Total Organic Carbon
6630
mg/kg
1120
04/03/15 15:03
EPA 9060
RSD%
12.3
%
04/03/15 15:03
92242381007
2015008000
EPA 6010
Aluminum
281
mg/kg
8.8
04/01/15 21:37
EPA 6010
Barium
9.9
mg/kg
0.88
04/01/15 21:37
EPA 6010
Beryllium
0.091
mg/kg
0.088
04/01/15 21:37
EPA 6010
Calcium
70.7
mg/kg
44.1
04/01/15 21:37
EPA 6010
Chromium
0.86
mg/kg
0.44
04/01/15 21:37
EPA 6010
Copper
1.2
mg/kg
0.44
04/01/15 21:37
EPA 6010
Iron
320
mg/kg
3.5
04/01/15 21:37
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 12 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
P360SrfY249e. Suite 100
Huntersville, NC 28078
[phone]
SUMMARY OF DETECTION
Project:
Pace Project No.:
J150305555
92242381
Lab Sample ID
Client Sample ID
Method
Parameters
Result
Units
Report Limit
Analyzed
Qualifiers
92242381007
2015008000
EPA 6010
Magnesium
25AJ
mg/kg
44.1
04/01/15 21:37
EPA 6010
Manganese
1.7
mg/kg
0.44
04/01/15 21:37
EPA 6010
Nickel
1.1
mg/kg
0.44
04/01/15 21:37
EPA 6010
Strontium
2.9
mg/kg
0.88
04/01/15 21:37
EPA 6010
Zinc
1.1J
mg/kg
1.8
04/01/15 21:37
ASTM D2974-87
Percent Moisture
41.2
%
0.10
04/01/15 16:21
EPA 9045
pH at 25 Degrees C
6.3
Std. Units
0.10
03/30/15 12:55
EPA 9060
Total Organic Carbon
11400
mg/kg
1030
04/03/15 15:42
EPA 9060
Total Organic Carbon
19400
mg/kg
1020
04/03/15 15:52
EPA 9060
Total Organic Carbon
10300
mg/kg
1020
04/03/15 15:59
EPA 9060
Total Organic Carbon
8260
mg/kg
1010
04/03/15 16:05
EPA 9060
Mean Total Organic Carbon
12300
mg/kg
1020
04/03/15 15:42
EPA 9060
RSD%
39.4
%
04/03/15 15:42
92242381008
2015008001
EPA 6010
Aluminum
485
mg/kg
7.0
04/01/15 21:41
EPA 6010
Barium
16.9
mg/kg
3.5
04/02/15 10:11
D3
EPA 6010
Beryllium
0.14
mg/kg
0.070
04/01/15 21:41
EPA 6010
Calcium
199
mg/kg
34.9
04/01/15 21:41
EPA 6010
Chromium
1.9
mg/kg
0.35
04/01/15 21:41
EPA 6010
Copper
2.8
mg/kg
1.7
04/02/15 10:11
D3
EPA 6010
Iron
554
mg/kg
2.8
04/01/15 21:41
EPA 6010
Magnesium
36.2
mg/kg
34.9
04/01/15 21:41
EPA 6010
Manganese
37.7
mg/kg
0.35
04/01/15 21:41
EPA 6010
Molybdenum
0.38J
mg/kg
0.70
04/01/15 21:41
EPA 6010
Nickel
2.1
mg/kg
0.35
04/01/15 21:41
EPA 6010
Potassium
63.7J
mg/kg
69.9
04/01/15 21:41
EPA 6010
Strontium
4.7
mg/kg
0.70
04/01/15 21:41
ASTM D2974-87
Percent Moisture
28.0
%
0.10
04/01/15 16:21
EPA 9045
pH at 25 Degrees C
6.6
Std. Units
0.10
03/25/15 11:50
EPA 9060
Total Organic Carbon
16800
mg/kg
828
04/03/15 16:10
EPA 9060
Total Organic Carbon
16000
mg/kg
827
04/03/15 16:17
EPA 9060
Total Organic Carbon
10900
mg/kg
837
04/03/15 16:28
EPA 9060
Total Organic Carbon
14200
mg/kg
833
04/03/15 16:35
EPA 9060
Mean Total Organic Carbon
14500
mg/kg
831
04/03/15 16:10
EPA 9060
RSD%
18.3
%
04/03/15 16:10
92242381009
2015008003
EPA 6010
Aluminum
13900
mg/kg
6.9
04/01/15 21:45
EPA 6010
Barium
83.2
mg/kg
0.69
04/01/15 21:45
EPA 6010
Beryllium
3.1
mg/kg
0.35
04/02/15 10:15
D3
EPA 6010
Boron
32.9
mg/kg
17.3
04/02/15 10:15
D3
EPA 6010
Calcium
1080
mg/kg
34.6
04/01/15 21:45
EPA 6010
Chromium
54.7
mg/kg
1.7
04/02/15 10:15
D3
EPA 6010
Copper
43.4
mg/kg
1.7
04/02/15 10:15
D3
EPA 6010
Iron
3020
mg/kg
2.8
04/01/15 21:45
EPA 6010
Magnesium
541
mg/kg
34.6
04/01/15 21:45
EPA 6010
Manganese
69.4
mg/kg
1.7
04/02/15 10:15
D3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 13 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
P3690ArWY249e. Suite 100
Huntersville, NC 28078
[phone]
SUMMARY OF DETECTION
Project:
Pace Project No.:
J150305555
92242381
Lab Sample ID
Client Sample ID
Method
Parameters
Result
Units
Report Limit
Analyzed
Qualifiers
92242381009
2015008003
EPA 6010
Molybdenum
1.4
mg/kg
0.69
04/01/15 21:45
EPA 6010
Nickel
22.5
mg/kg
0.35
04/01/15 21:45
EPA 6010
Potassium
1650
mg/kg
69.2
04/01/15 21:45
EPA 6010
Sodium
155
mg/kg
69.2
04/01/15 21:45
EPA 6010
Strontium
83.7
mg/kg
0.69
04/01/15 21:45
EPA 6010
Zinc
36.4
mg/kg
1.4
04/01/15 21:45
EPA 6020
Arsenic
11.2
mg/kg
3.5
03/31/15 22:19
D3
EPA 6020
Cobalt
17.7
mg/kg
3.5
03/31/15 22:19
D3
EPA 6020
Lead
21.9
mg/kg
3.5
03/31/15 22:19
D3
EPA 6020
Vanadium
88.1
mg/kg
3.5
03/31/15 22:19
D4
ASTM D2974-87
Percent Moisture
24.7
%
0.10
04/01/15 16:22
EPA 9045
pH at 25 Degrees C
6.4
Std. Units
0.10
03/25/15 11:50
EPA 9060
Total Organic Carbon
9330
mg/kg
5670
04/03/15 16:42
EPA 9060
Total Organic Carbon
7650
mg/kg
5810
04/03/15 16:48
EPA 9060
Total Organic Carbon
8290
mg/kg
5860
04/03/15 16:54
EPA 9060
Total Organic Carbon
8680
mg/kg
5890
04/03/15 16:59
EPA 9060
Mean Total Organic Carbon
8490
mg/kg
5810
04/03/15 16:42
EPA 9060
RSD%
8.3
%
04/03/15 16:42
92242381010
2015008004
EPA 6010
Aluminum
9620
mg/kg
7.1
04/01/15 21:49
EPA 6010
Barium
80.9
mg/kg
0.71
04/01/15 21:49
EPA 6010
Beryllium
2.6
mg/kg
0.071
04/01/15 21:49
EPA 6010
Boron
31.3
mg/kg
3.5
04/01/15 21:49
EPA 6010
Calcium
1150
mg/kg
35.4
04/01/15 21:49
EPA 6010
Chromium
31.9
mg/kg
0.35
04/01/15 21:49
EPA 6010
Copper
33.3
mg/kg
0.35
04/01/15 21:49
EPA 6010
Iron
3290
mg/kg
2.8
04/01/15 21:49
EPA 6010
Magnesium
388
mg/kg
35.4
04/01/15 21:49
EPA 6010
Manganese
21.1
mg/kg
0.35
04/01/15 21:49
EPA 6010
Molybdenum
1.6
mg/kg
0.71
04/01/15 21:49
EPA 6010
Nickel
18.7
mg/kg
0.35
04/01/15 21:49
EPA 6010
Potassium
895
mg/kg
70.9
04/01/15 21:49
EPA 6010
Sodium
102
mg/kg
70.9
04/01/15 21:49
EPA 6010
Strontium
53.0
mg/kg
0.71
04/01/15 21:49
EPA 6010
Zinc
24.0
mg/kg
1.4
04/01/15 21:49
EPA 6020
Arsenic
13.4
mg/kg
3.5
04/02/15 16:09
D3
EPA 6020
Cobalt
13.6
mg/kg
3.5
03/31/15 22:29
D3
EPA 6020
Lead
17.8
mg/kg
3.5
04/02/15 16:09
D3
EPA 6020
Vanadium
63.6
mg/kg
3.5
03/31/15 22:29
D4
ASTM D2974-87
Percent Moisture
28.8
%
0.10
04/01/15 16:23
EPA 9045
pH at 25 Degrees C
8.0
Std. Units
0.10
03/25/15 11:50
EPA 9060
Total Organic Carbon
16700
mg/kg
3390
04/03/15 17:06
EPA 9060
Total Organic Carbon
18700
mg/kg
3440
04/03/15 17:12
EPA 9060
Total Organic Carbon
17300
mg/kg
3500
04/03/15 17:19
EPA 9060
Total Organic Carbon
25100
mg/kg
3450
04/03/15 17:25
EPA 9060
Mean Total Organic Carbon
19400
mg/kg
3450
04/03/15 17:06
EPA 9060
RSD%
19.8
%
04/03/15 17:06
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 14 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
P369'Ar6fY2'9e. Suite 100
Huntersville, NC 28078
[phone]
SUMMARY OF DETECTION
Project:
Pace Project No.:
J150305555
92242381
Lab Sample ID
Client Sample ID
Method
Parameters
Result
Units
Report Limit
Analyzed Qualifiers
92242381011
2015008005
EPA 6010
Aluminum
13400
mg/kg
6.2
04/01/15 21:54
EPA 6010
Barium
96.9
mg/kg
0.62
04/01/15 21:54
EPA 6010
Beryllium
3.1
mg/kg
0.062
04/01/15 21:54
EPA 6010
Boron
36.4
mg/kg
3.1
04/01/15 21:54
EPA 6010
Calcium
1520
mg/kg
31.1
04/01/15 21:54
EPA 6010
Chromium
39.4
mg/kg
0.31
04/01/15 21:54
EPA 6010
Copper
40.6
mg/kg
0.31
04/01/15 21:54
EPA 6010
Iron
3320
mg/kg
2.5
04/01/15 21:54
EPA 6010
Magnesium
603
mg/kg
31.1
04/01/15 21:54
EPA 6010
Manganese
15.8
mg/kg
0.31
04/01/15 21:54
EPA 6010
Molybdenum
2.0
mg/kg
0.62
04/01/15 21:54
EPA 6010
Nickel
25.7
mg/kg
0.31
04/01/15 21:54
EPA 6010
Potassium
1560
mg/kg
62.1
04/01/15 21:54
EPA 6010
Sodium
158
mg/kg
62.1
04/01/15 21:54
EPA 6010
Strontium
78.8
mg/kg
0.62
04/01/15 21:54
EPA 6010
Zinc
39.0
mg/kg
1.2
04/01/15 21:54
EPA 6020
Arsenic
17.0
mg/kg
3.1
04/02/15 16:11
EPA 6020
Cadmium
0.30J
mg/kg
0.37
04/02/15 16:11
EPA 6020
Cobalt
19.7
mg/kg
3.1
03/31/15 22:31 D3
EPA 6020
Lead
25.5
mg/kg
3.1
04/02/15 16:11
EPA 6020
Vanadium
112
mg/kg
3.1
03/31/15 22:31 D4
ASTM D2974-87
Percent Moisture
21.5
%
0.10
04/01/15 16:23
EPA 9045
pH at 25 Degrees C
7.8
Std. Units
0.10
03/25/15 11:50
EPA 9060
Total Organic Carbon
22500
mg/kg
3700
04/06/15 07:40
EPA 9060
Total Organic Carbon
12400
mg/kg
3730
04/06/15 07:46
EPA 9060
Total Organic Carbon
19200
mg/kg
3790
04/06/15 07:52
EPA 9060
Total Organic Carbon
14200
mg/kg
3780
04/06/15 07:57
EPA 9060
Mean Total Organic Carbon
17100
mg/kg
3750
04/06/15 07:40
EPA 9060
RSD%
27.1
%
04/06/15 07:40
92242381012
2015008006
EPA 6010
Aluminum
859
mg/kg
6.2
04/01/15 21:58
EPA 6010
Barium
38.6
mg/kg
0.62
04/01/15 21:58
EPA 6010
Beryllium
0.26
mg/kg
0.062
04/01/15 21:58
EPA 6010
Calcium
248
mg/kg
30.8
04/01/15 21:58
EPA 6010
Chromium
2.2
mg/kg
0.31
04/01/15 21:58
EPA 6010
Copper
4.8
mg/kg
0.31
04/01/15 21:58
EPA 6010
Iron
1100
mg/kg
2.5
04/01/15 21:58
EPA 6010
Magnesium
65.1
mg/kg
30.8
04/01/15 21:58
EPA 6010
Manganese
17.7
mg/kg
0.31
04/01/15 21:58
EPA 6010
Molybdenum
0.42J
mg/kg
0.62
04/01/15 21:58
EPA 6010
Nickel
3.3
mg/kg
0.31
04/01/15 21:58
EPA 6010
Potassium
116
mg/kg
61.5
04/01/15 21:58
EPA 6010
Strontium
11.0
mg/kg
0.62
04/01/15 21:58
EPA 6010
Zinc
4.5
mg/kg
1.2
04/01/15 21:58
EPA 6020
Vanadium
2.7J
mg/kg
3.1
03/31/15 22:33 D3
ASTM D2974-87
Percent Moisture
19.9
%
0.10
04/01/15 16:24
EPA 9045
pH at 25 Degrees C
6.2
Std. Units
0.10
03/30/15 12:55
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 15 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
P3y RGAr6fY2'9e. Suite 100
Huntersville, NC 28078
[phone]
Project: J150305555
Pace Project No.: 92242381
Lab Sample ID
Method
Client Sample ID
Parameters
92242381012
2015008006
EPA 9060
Total Organic Carbon
EPA 9060
Total Organic Carbon
EPA 9060
Total Organic Carbon
EPA 9060
Total Organic Carbon
EPA 9060
Mean Total Organic Carbon
EPA 9060
RSD%
92242381013
2015008008
EPA 6010
Aluminum
EPA 6010
Barium
EPA 6010
Beryllium
EPA 6010
Boron
EPA 6010
Calcium
EPA 6010
Chromium
EPA 6010
Copper
EPA 6010
Iron
EPA 6010
Magnesium
EPA 6010
Manganese
EPA 6010
Molybdenum
EPA 6010
Nickel
EPA 6010
Potassium
EPA 6010
Sodium
EPA 6010
Strontium
EPA 6010
Zinc
EPA 6020
Arsenic
EPA 6020
Cobalt
EPA 6020
Lead
EPA 6020
Vanadium
ASTM D2974-87
Percent Moisture
EPA 9045
pH at 25 Degrees C
EPA 9060
Total Organic Carbon
EPA 9060
Total Organic Carbon
EPA 9060
Total Organic Carbon
EPA 9060
Total Organic Carbon
EPA 9060
Mean Total Organic Carbon
EPA 9060
RSD%
SUMMARY OF DETECTION
Result
Units
Report Limit
Analyzed Qualifiers
14300
mg/kg
747
04/06/15 08:49
9190
mg/kg
748
04/06/15 08:55
11400
mg/kg
757
04/06/15 09:00
8370
mg/kg
745
04/06/15 09:06
10800
mg/kg
749
04/06/15 08:49
24.6
%
04/06/15 08:49
3530
mg/kg
7.7
04/01/15 22:14
34.6
mg/kg
0.77
04/01/15 22:14
0.96
mg/kg
0.077
04/01/15 22:14
9.2
mg/kg
3.9
04/01/15 22:14
517
mg/kg
38.7
04/01/15 22:14
10.6
mg/kg
0.39
04/01/15 22:14
12.1
mg/kg
0.39
04/01/15 22:14
2230
mg/kg
3.1
04/01/15 22:14
206
mg/kg
38.7
04/01/15 22:14
9.4
mg/kg
0.39
04/01/15 22:14
0.551
mg/kg
0.77
04/01/15 22:14
7.0
mg/kg
0.39
04/01/15 22:14
436
mg/kg
77.3
04/01/15 22:14
53.9J
mg/kg
77.3
04/01/15 22:14
19.5
mg/kg
0.77
04/01/15 22:14
8.5
mg/kg
1.5
04/01/15 22:14
2.9J
mg/kg
3.9
04/02/1516:15
4.2
mg/kg
3.9
03/31/15 22:35 D3
4.8
mg/kg
3.9
04/02/1516:15
19.0
mg/kg
3.9
03/31/15 22:35 D3
34.2
%
0.10
04/01/1516:24
7.2
Std. Units
0.10
03/30/15 12:55
14400
mg/kg
1800
04/06/15 09:11
18800
mg/kg
1820
04/06/15 09:18
23100
mg/kg
1820
04/06/15 09:23
15800
mg/kg
1810
04/06/15 09:30
18000
mg/kg
1810
04/06/15 09:11
21.3
%
04/06/15 09:11
92242381014
2015008009
EPA 6020A
Barium
0.44
ug/L
0.30
03/28/15 15:37
EPA 6020A
Chromium
1.5
ug/L
0.50
03/28/15 15:37
EPA 6020A
Iron
93.2
ug/L
50.0
03/28/15 15:37
EPA 6020A
Manganese
1.2
ug/L
0.50
03/28/15 15:37
92242381015
2015008010
EPA 6020A
Calcium
46.3
ug/L
40.0
03/28/15 15:40
EPA 6020A
Chromium
0.60
ug/L
0.50
03/28/15 15:40
EPA 6020A
Manganese
1.3
ug/L
0.50
03/28/15 15:40
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 16 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
P369'*r6fY2'9e. Suite 100
Huntersville, NC 28078
[phone]
Project: J150305555
Pace Project No.: 92242381
Lab Sample ID Client Sample ID
Method Parameters
SUMMARY OF DETECTION
Result Units Report Limit Analyzed Qualifiers
92242381016
2015008011
EPA 6020A
Barium
1.8
ug/L
0.30
03/28/15 15:43
EPA 6020A
Calcium
85.2
ug/L
40.0
03/28/15 15:43
EPA 6020A
Chromium
2.7
ug/L
0.50
03/28/15 15:43
EPA 6020A
Iron
169
ug/L
50.0
03/28/15 15:43
EPA 6020A
Magnesium
12.0
ug/L
10.0
03/28/15 15:43
EPA 6020A
Manganese
4.3
ug/L
0.50
03/28/15 15:43
EPA 6020A
Molybdenum
0.95
ug/L
0.50
03/28/15 15:43
EPA 6020A
Nickel
1.1
ug/L
0.50
03/28/15 15:43
EPA 6020A
Strontium
0.59
ug/L
0.50
03/28/15 15:43
92242381017
2015008012
EPA 6020A
Barium
0.40
ug/L
0.30
03/28/15 15:46
EPA 6020A
Calcium
124
ug/L
40.0
03/28/15 15:46
EPA 6020A
Chromium
1.6
ug/L
0.50
03/28/15 15:46
EPA 6020A
Iron
66.4
ug/L
50.0
03/28/15 15:46
EPA 6020A
Magnesium
14.6
ug/L
10.0
03/28/15 15:46
EPA 6020A
Manganese
3.1
ug/L
0.50
03/28/15 15:46
EPA 6020A
Molybdenum
0.88
ug/L
0.50
03/28/15 15:46
EPA 6020A
Sodium
94.2
ug/L
50.0
03/28/15 15:46
EPA 6020A
Strontium
0.53
ug/L
0.50
03/28/15 15:46
92242381018
2015007996 SPLP
EPA 6020A
Aluminum
152
ug/L
10.0
04/06/15 08:53
EPA 6020A
Antimony
5.0
ug/L
0.50
04/06/15 08:53
EPA 6020A
Arsenic
3.5
ug/L
0.50
04/06/15 08:53
EPA 6020A
Barium
308
ug/L
0.30
04/06/15 08:53
EPA 6020A
Boron
119
ug/L
5.0
04/06/15 08:53
EPA 6020A
Calcium
3060
ug/L
40.0
04/06/15 08:53
EPA 6020A
Chromium
1.8
ug/L
0.50
04/06/15 08:53
EPA 6020A
Cobalt
0.89
ug/L
0.50
04/06/15 08:53
EPA 6020A
Copper
3.0
ug/L
1.0
04/06/15 08:53
EPA 6020A
Lead
0.73
ug/L
0.10
04/06/15 08:53
EPA 6020A
Magnesium
688
ug/L
10.0
04/06/15 08:53
EPA 6020A
Manganese
148
ug/L
0.50
04/06/15 08:53
EPA 6020A
Molybdenum
2.2
ug/L
0.50
04/06/15 08:53
EPA 6020A
Nickel
4.4
ug/L
0.50
04/06/15 08:53
EPA 6020A
Potassium
643
ug/L
50.0
04/06/15 08:53
EPA 6020A
Selenium
1.9
ug/L
0.50
04/06/15 08:53
EPA 6020A
Sodium
2110
ug/L
50.0
04/06/15 08:53
EPA 6020A
Strontium
37.2
ug/L
0.50
04/06/15 08:53
EPA 6020A
Thallium
0.11
ug/L
0.10
04/06/15 08:53
EPA 6020A
Vanadium
72.6
ug/L
1.0
04/06/15 08:53
EPA 6020A
Zinc
159
ug/L
5.0
04/06/15 08:53
92242381019
2015007999 SPLP
EPA 6020A
Aluminum
330
ug/L
10.0
04/06/15 08:58
EPA 6020A
Antimony
3.4
ug/L
0.50
04/06/15 08:58
EPA 6020A
Arsenic
27.0
ug/L
0.50
04/06/15 08:58
EPA 6020A
Barium
346
ug/L
0.30
04/06/15 08:58
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 17 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
P3690Ar6fY2'9e. Suite 100
Huntersville, NC 28078
[phone]
Project: J150305555
Pace Project No.: 92242381
Lab Sample ID Client Sample ID
Method Parameters
SUMMARY OF DETECTION
Result Units Report Limit Analyzed Qualifiers
92242381019
2015007999 SPLP
EPA 6020A
Boron
208
ug/L
25.0
04/06/15 10:26
EPA 6020A
Calcium
2940
ug/L
40.0
04/06/15 08:58
EPA 6020A
Chromium
1.3
ug/L
0.50
04/06/15 08:58
EPA 6020A
Copper
8.0
ug/L
1.0
04/06/15 08:58
EPA 6020A
Lead
0.68
ug/L
0.10
04/06/15 08:58
EPA 6020A
Magnesium
617
ug/L
10.0
04/06/15 08:58
EPA 6020A
Manganese
19.5
ug/L
0.50
04/06/15 08:58
EPA 6020A
Molybdenum
6.6
ug/L
0.50
04/06/15 08:58
EPA 6020A
Nickel
0.76
ug/L
0.50
04/06/15 08:58
EPA 6020A
Potassium
1040
ug/L
50.0
04/06/15 08:58
EPA 6020A
Sodium
1590
ug/L
50.0
04/06/15 08:58
EPA 6020A
Strontium
89.0
ug/L
0.50
04/06/15 08:58
EPA 6020A
Vanadium
120
ug/L
1.0
04/06/15 08:58
EPA 6020A
Zinc
157
ug/L
5.0
04/06/15 08:58
92242381020
2015008002 SPLP
EPA 6020A
Aluminum
122
ug/L
10.0
04/06/15 09:03
EPA 6020A
Arsenic
1.1
ug/L
0.50
04/06/15 09:03
EPA 6020A
Barium
303
ug/L
0.30
04/06/15 09:03
EPA 6020A
Boron
133
ug/L
5.0
04/06/15 09:03
EPA 6020A
Calcium
5870
ug/L
40.0
04/06/15 09:03
EPA 6020A
Chromium
2.4
ug/L
0.50
04/06/15 09:03
EPA 6020A
Cobalt
0.54
ug/L
0.50
04/06/15 09:03
EPA 6020A
Copper
2.9
ug/L
1.0
04/06/15 09:03
EPA 6020A
Lead
0.73
ug/L
0.10
04/06/15 09:03
EPA 6020A
Magnesium
455
ug/L
10.0
04/06/15 09:03
EPA 6020A
Manganese
53.7
ug/L
0.50
04/06/15 09:03
EPA 6020A
Molybdenum
9.2
ug/L
0.50
04/06/15 09:03
EPA 6020A
Nickel
2.2
ug/L
0.50
04/06/15 09:03
EPA 6020A
Potassium
679
ug/L
50.0
04/06/15 09:03
EPA 6020A
Sodium
1750
ug/L
50.0
04/06/15 09:03
EPA 6020A
Strontium
39.2
ug/L
0.50
04/06/15 09:03
EPA 6020A
Vanadium
2.5
ug/L
1.0
04/06/15 09:03
EPA 6020A
Zinc
160
ug/L
5.0
04/06/15 09:03
92242381021
2015008007 SPLP
EPA 6020A
Aluminum
252
ug/L
10.0
04/06/15 09:08
EPA 6020A
Antimony
7.1
ug/L
0.50
04/06/15 09:08
EPA 6020A
Arsenic
11.9
ug/L
0.50
04/06/15 09:08
EPA 6020A
Barium
285
ug/L
0.30
04/06/15 09:08
EPA 6020A
Boron
127
ug/L
5.0
04/06/15 09:08
EPA 6020A
Calcium
4500
ug/L
40.0
04/06/15 09:08
EPA 6020A
Chromium
1.6
ug/L
0.50
04/06/15 09:08
EPA 6020A
Cobalt
0.92
ug/L
0.50
04/06/15 09:08
EPA 6020A
Copper
4.6
ug/L
1.0
04/06/15 09:08
EPA 6020A
Lead
0.89
ug/L
0.10
04/06/15 09:08
EPA 6020A
Magnesium
475
ug/L
10.0
04/06/15 09:08
EPA 6020A
Manganese
43.0
ug/L
0.50
04/06/15 09:08
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 18 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
P369'ArWY249e. Suite 100
Huntersville, NC 28078
[phone]
SUMMARY OF DETECTION
Project: J150305555
Pace Project No.: 92242381
Lab Sample ID
Client Sample ID
Method
Parameters
Result
Units
92242381021
2015008007 SPLP
EPA 6020A
Molybdenum
4.3
ug/L
EPA 6020A
Nickel
2.0
ug/L
EPA 6020A
Potassium
657
ug/L
EPA 6020A
Selenium
1.5
ug/L
EPA 6020A
Sodium
1600
ug/L
EPA 6020A
Strontium
50.8
ug/L
EPA 6020A
Thallium
0.23
ug/L
EPA 6020A
Vanadium
134
ug/L
EPA 6020A
Zinc
150
ug/L
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Report Limit Analyzed Qualifiers
0.50
04/06/15 09:08
0.50
04/06/15 09:08
50.0
04/06/15 09:08
0.50
04/06/15 09:08
50.0
04/06/15 09:08
0.50
04/06/15 09:08
0.10
04/06/15 09:08
1.0
04/06/15 09:08
5.0
04/06/15 09:08
Page 19 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
P3y 9041bir6fY249e. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J150305555
Pace Project No.: 92242381
Method: EPA 6010
Description: 6010 MET ICP
Client: Duke Energy
Date: April 08, 2015
General Information:
13 samples were analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 3050 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: MPRP/23322
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92242381001
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1169014)
• Aluminum
• Barium
• Iron
• Strontium
• MSD (Lab ID: 1169015)
• Aluminum
• Barium
• Iron
• Manganese
• Potassium
• Strontium
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 20 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
P36904ff WY24Y e. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J150305555
Pace Project No.: 92242381
Method: EPA 6010
Description: 6010 MET ICP
Client: Duke Energy
Date: April 08, 2015
Analyte Comments:
QC Batch: MPRP/23322
DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
•2015008001 (Lab ID:92242381008)
• Barium
• Copper
• Zinc
•2015008003 (Lab ID:92242381009)
• Boron
• Beryllium
• Chromium
• Copper
• Manganese
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 21 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
P36904K WeYle. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J150305555
Pace Project No.: 92242381
Method: EPA 6020
Description: 6020 MET ICPMS
Client: Duke Energy
Date: April 08, 2015
General Information:
13 samples were analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 3050 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: MPRP/23323
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92242381002
M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
• MS (Lab ID: 1169018)
• Antimony
• Cobalt
• Lead
• Vanadium
• MSD (Lab ID: 1169019)
• Antimony
• Cobalt
• Lead
• Selenium
• Vanadium
R1: RPD value was outside control limits.
• MSD (Lab ID: 1169019)
• Selenium
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 22 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
P36904WeYlge. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J150305555
Pace Project No.: 92242381
Method: EPA 6020
Description: 6020 MET ICPMS
Client: Duke Energy
Date: April 08, 2015
Additional Comments:
Analyte Comments:
QC Batch: MPRP/23323
D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
•2015007996 (Lab ID:92242381001)
• Arsenic
• Cadmium
• Cobalt
• Lead
• Antimony
• Selenium
• Thallium
• Vanadium
•2015007997 (Lab ID:92242381005)
• Arsenic
• Cadmium
• Cobalt
• Lead
• Antimony
• Selenium
• Thallium
• Vanadium
•2015007998 (Lab ID:92242381006)
• Arsenic
• Cadmium
• Cobalt
• Lead
• Antimony
• Selenium
• Thallium
• Vanadium
•2015007999 (Lab ID:92242381002)
• Arsenic
• Cadmium
• Cobalt
• Lead
• Antimony
• Selenium
• Thallium
•2015008000 (Lab ID:92242381007)
• Arsenic
• Cadmium
• Cobalt
• Lead
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 23 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
P3y 904r6fY249e. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J150305555
Pace Project No.: 92242381
Method: EPA 6020
Description: 6020 MET ICPMS
Client: Duke Energy
Date: April 08, 2015
Analyte Comments:
QC Batch: MPRP/23323
DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
•2015008000 (Lab ID:92242381007)
• Antimony
• Selenium
• Thallium
• Vanadium
•2015008001 (Lab ID:92242381008)
• Arsenic
• Cadmium
• Cobalt
• Lead
• Antimony
• Selenium
• Thallium
• Vanadium
•2015008002 (Lab ID:92242381003)
• Arsenic
• Cadmium
• Cobalt
• Lead
• Antimony
• Selenium
• Thallium
• Vanadium
•2015008003 (Lab ID:92242381009)
• Arsenic
• Cadmium
• Cobalt
• Lead
• Antimony
• Selenium
• Thallium
•2015008004 (Lab ID:92242381010)
• Arsenic
• Cadmium
• Cobalt
• Lead
• Antimony
• Selenium
• Thallium
•2015008005 (Lab ID:92242381011)
• Cobalt
•2015008006 (Lab ID:92242381012)
• Cobalt
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 24 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
P369041 WeYlge. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J150305555
Pace Project No.: 92242381
Method: EPA 6020
Description: 6020 MET ICPMS
Client: Duke Energy
Date: April 08, 2015
Analyte Comments:
QC Batch: MPRP/23323
DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
•2015008006 (Lab ID:92242381012)
• Vanadium
•2015008007 (Lab ID:92242381004)
• Arsenic
• Cadmium
• Cobalt
• Lead
• Antimony
• Selenium
• Thallium
• Vanadium
•2015008008 (Lab ID:92242381013)
• Cobalt
• Vanadium
• MS (Lab ID: 1169018)
• Arsenic
• Cadmium
• Cobalt
• Lead
• Antimony
• Selenium
• Thallium
• MSD (Lab ID: 1169019)
• Arsenic
• Cadmium
• Cobalt
• Lead
• Antimony
• Selenium
• Thallium
D4: Sample was diluted due to the presence of high levels of target analytes.
•2015007999 (Lab ID:92242381002)
• Vanadium
•2015008003 (Lab ID:92242381009)
• Vanadium
•2015008004 (Lab ID:92242381010)
• Vanadium
•2015008005 (Lab ID:92242381011)
• Vanadium
• MS (Lab ID: 1169018)
• Vanadium
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 25 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
P369041 WeY249e. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J150305555
Pace Project No.: 92242381
Method: EPA 6020
Description: 6020 MET ICPMS
Client: Duke Energy
Date: April 08, 2015
Analyte Comments:
QC Batch: MPRP/23323
D4: Sample was diluted due to the presence of high levels of target analytes.
• MSD (Lab ID: 1169019)
• Vanadium
N2: The lab does not hold TNI accreditation for this parameter.
•2015007996 (Lab ID:92242381001)
• Antimony
•2015007997 (Lab ID:92242381005)
• Antimony
•2015007998 (Lab ID:92242381006)
• Antimony
•2015007999 (Lab ID:92242381002)
• Antimony
•2015008000 (Lab ID:92242381007)
• Antimony
•2015008001 (Lab ID:92242381008)
• Antimony
•2015008002 (Lab ID:92242381003)
• Antimony
•2015008003 (Lab ID:92242381009)
• Antimony
•2015008004 (Lab ID:92242381010)
• Antimony
•2015008005 (Lab ID:92242381011)
• Antimony
•2015008006 (Lab ID:92242381012)
• Antimony
•2015008007 (Lab ID:92242381004)
• Antimony
•2015008008 (Lab ID:92242381013)
• Antimony
• BLANK (Lab ID: 1169016)
• Antimony
• LCS (Lab ID: 1169017)
• Antimony
• MS (Lab ID: 1169018)
• Antimony
• MSD (Lab ID: 1169019)
• Antimony
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 26 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
P36904f WeY249e. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J150305555
Pace Project No.: 92242381
Method: EPA 6020A
Description: 6020A MET ICPMS
Client: Duke Energy
Date: April 08, 2015
General Information:
8 samples were analyzed for EPA 6020A. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 3020 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 27 of 104

aceAnaiXical
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Pace Analytical Services, Inc.
P369041 WeYlge. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J150305555
Pace Project No.: 92242381
Method: EPA 7470
Description: 7470 Mercury
Client: Duke Energy
Date: April 08, 2015
General Information:
8 samples were analyzed for EPA 7470. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 7470 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 28 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
P36904f WeYlge. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J150305555
Pace Project No.: 92242381
Method: EPA 7471
Description: 7471 Mercury
Client: Duke Energy
Date: April 08, 2015
General Information:
13 samples were analyzed for EPA 7471. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 7471 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: MERP/5528
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 35180845003
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1169345)
• Mercury
• MSD (Lab ID: 1169346)
• Mercury
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 29 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
P3yy SMr6fY2'9e. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J150305555
Pace Project No.: 92242381
Method: EPA 9045
Description: 9045 pH Soil
Client: Duke Energy
Date: April 08, 2015
General Information:
13 samples were analyzed for EPA 9045. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
QC Batch: WET/36413
D6: The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits.
• DUP (Lab ID: 1418511)
• pH at 25 Degrees C
• DUP (Lab ID: 1418512)
• pH at 25 Degrees C
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 30 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
P369CAWM24 e" Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J150305555
Pace Project No.: 92242381
Method: EPA 300.0
Description: 300.0 IC Anions, SPLP
Client: Duke Energy
Date: April 08, 2015
General Information:
4 samples were analyzed for EPA 300.0. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
QC Batch: WETA/22392
B: Analyte was detected in the associated method blank.
• BLANK for HBN 257605 [WETA/223 (Lab ID: 1422994)
• Sulfate
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
Analyte Comments:
QC Batch: WETA/22392
DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
•2015007996 (Lab ID:92242381001)
• Sulfate
•2015007999 (Lab ID:92242381002)
• Sulfate
•2015008002 (Lab ID:92242381003)
• Sulfate
•2015008007 (Lab ID:92242381004)
• Sulfate
• BLANK (Lab ID: 1422994)
• Sulfate
• MS (Lab ID: 1422996)
• Sulfate
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 31 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
P3yy S�05kf�ir6fY2'9e. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J150305555
Pace Project No.: 92242381
Method: EPA 300.0
Description: 300.0 IC Anions, SPLP
Client: Duke Energy
Date: April 08, 2015
Analyte Comments:
QC Batch: WETA/22392
DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
• MS (Lab ID: 1422998)
• Sulfate
• MSD (Lab ID: 1422997)
• Sulfate
• MSD (Lab ID: 1422999)
• Sulfate
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 32 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
P3yy SMr6fY2'9e. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J150305555
Pace Project No.: 92242381
Method: EPA 353.2
Description: 353.2 Nitrogen, NO2/NO3, SPLP
Client: Duke Energy
Date: April 08, 2015
General Information:
4 samples were analyzed for EPA 353.2. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
1-11: Analysis conducted outside the EPA method holding time.
•2015007996 (Lab ID:92242381001)
•2015007999 (Lab ID:92242381002)
•2015008002 (Lab ID:92242381003)
•2015008007 (Lab ID:92242381004)
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
QC Batch: WETA/22398
B: Analyte was detected in the associated method blank.
• BLANK for HBN 257673 [WETA/223 (Lab ID: 1423321)
• Nitrogen, Nitrate
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: WETA/22398
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92241508005,92242371020
M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
• MS (Lab ID: 1423323)
• Nitrogen, Nitrate
• MS (Lab ID: 1423325)
• Nitrogen, Nitrate
• MSD (Lab ID: 1423324)
• Nitrogen, Nitrate
• MSD (Lab ID: 1423326)
• Nitrogen, Nitrate
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 33 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
P3y M'ir6fY2'9e. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J150305555
Pace Project No.: 92242381
Method: EPA 353.2
Description: 353.2 Nitrogen, NO2/NO3, SPLP
Client: Duke Energy
Date: April 08, 2015
Analyte Comments
QC Batch: WETA/22398
P8: Analyte was detected in the method blank. All associated samples had concentrations of at least ten times greater than the blank
or were below the reporting limit.
• BLANK (Lab ID: 1423321)
• Nitrogen, Nitrate
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 34 of 104

aceAnaiXical
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Pace Analytical Services, Inc.
P3y 90Ar6fY2'9e. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J150305555
Pace Project No.: 92242381
Method: SM 4500-CI-E
Description: 4500 Chloride, SPLP
Client: Duke Energy
Date: April 08, 2015
General Information:
4 samples were analyzed for SM 4500-CI-E. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
Analyte Comments:
QC Batch: WETA/22399
DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
•2015007999 (Lab ID:92242381002)
• Chloride
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 35 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
P3Sy Mr6fY2'9e. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J150305555
Pace Project No.: 92242381
Method: EPA 9056
Description: 9056 IC Anions
Client: Duke Energy
Date: April 08, 2015
General Information:
13 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
Analyte Comments:
QC Batch: WETA/44900
DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
•2015007996 (Lab ID:92242381001)
• Chloride
• Sulfate
•2015007997 (Lab ID:92242381005)
• Chloride
• Sulfate
•2015007998 (Lab ID:92242381006)
• Chloride
• Sulfate
•2015007999 (Lab ID:92242381002)
• Chloride
• Sulfate
•2015008000 (Lab ID:92242381007)
• Chloride
• Sulfate
•2015008001 (Lab ID:92242381008)
• Chloride
• Sulfate
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 36 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
P3Sy Mr6fY2'9e. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J150305555
Pace Project No.: 92242381
Method: EPA 9056
Description: 9056 IC Anions
Client: Duke Energy
Date: April 08, 2015
Analyte Comments:
QC Batch: WETA/44900
DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
•2015008002 (Lab ID:92242381003)
• Chloride
• Sulfate
•2015008007 (Lab ID:92242381004)
• Chloride
• Sulfate
QC Batch: WETA/44904
DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
•2015008003 (Lab ID:92242381009)
• Chloride
• Sulfate
•2015008004 (Lab ID:92242381010)
• Chloride
• Sulfate
•2015008005 (Lab ID:92242381011)
• Chloride
• Sulfate
•2015008006 (Lab ID:92242381012)
• Chloride
• Sulfate
•2015008008 (Lab ID:92242381013)
• Chloride
• Sulfate
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 37 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
P3y 90Ar6fY2'9e. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J150305555
Pace Project No.: 92242381
Method: EPA 9056
Description: 9056 IC Anions 48hr
Client: Duke Energy
Date: April 08, 2015
General Information:
13 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
1­13: Sample was received or analysis requested beyond the recognized method holding time.
•2015007996 (Lab ID:92242381001)
•2015007997 (Lab ID:92242381005)
•2015007998 (Lab ID:92242381006)
•2015007999 (Lab ID:92242381002)
•2015008000 (Lab ID:92242381007)
•2015008001 (Lab ID:92242381008)
•2015008002 (Lab ID:92242381003)
•2015008003 (Lab ID:92242381009)
•2015008004 (Lab ID:92242381010)
•2015008005 (Lab ID:92242381011)
•2015008006 (Lab ID:92242381012)
•2015008007 (Lab ID:92242381004)
•2015008008 (Lab ID:92242381013)
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
Analyte Comments:
QC Batch: WETA/44899
D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
•2015007996 (Lab ID:92242381001)
• Nitrate as N
•2015007997 (Lab ID:92242381005)
• Nitrate as N
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 38 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
P3Sy Mr6fY2'9e. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J150305555
Pace Project No.: 92242381
Method: EPA 9056
Description: 9056 IC Anions 48hr
Client: Duke Energy
Date: April 08, 2015
Analyte Comments:
QC Batch: WETA/44899
DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
•2015007998 (Lab ID:92242381006)
• Nitrate as N
•2015007999 (Lab ID:92242381002)
• Nitrate as N
•2015008000 (Lab ID:92242381007)
• Nitrate as N
•2015008001 (Lab ID:92242381008)
• Nitrate as N
•2015008002 (Lab ID:92242381003)
• Nitrate as N
•2015008007 (Lab ID:92242381004)
• Nitrate as N
QC Batch: WETA/44903
DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
•2015008003 (Lab ID:92242381009)
• Nitrate as N
•2015008004 (Lab ID:92242381010)
• Nitrate as N
•2015008005 (Lab ID:92242381011)
• Nitrate as N
•2015008008 (Lab ID:92242381013)
• Nitrate as N
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 39 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
�0 P3y S8r6fY2'9e. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J150305555
Pace Project No.: 92242381
Method: EPA 9060
Description: Total Organic Carbon Quad
Client: Duke Energy
Date: April 08, 2015
General Information:
13 samples were analyzed for EPA 9060. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 40 of 104

aceAnaiXical
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Pace Analytical Services, Inc.
P369%-)ir6fY2'9e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J150305555
Pace Project No.: 92242381
Sample: 2015007996 Lab ID: 92242381001 Collected: 03/18/15 15:33 Received: 03/23/15 15:04 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Aluminum
Barium
Beryllium
Boron
Calcium
Chromium
Copper
Iron
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Sodium
Strontium
Zinc
6020 MET ICPMS
Antimony
Arsenic
Cadmium
Cobalt
Lead
Selenium
Thallium
Vanadium
7471 Mercury
Mercury
Percent Moisture
Percent Moisture
9045 pH Soil
pH at 25 Degrees C
300.0 IC Anions, SPLP
Sulfate
353.2 Nitrogen, NO2/NO3, SPLP
Nitrogen, Nitrate
4500 Chloride, SPLP
Chloride
Date: 04/08/2015 12:54 PM
Analytical Method: EPA 6010 Preparation Method: EPA 3050
3200
mg/kg
7.7
3.9
1
03/29/15 16:04
04/02/15 09:35
7429-90-5
M1
44.1
mg/kg
0.77
0.39
1
03/29/15 16:04
04/02/15 09:35
7440-39-3
M1
0.73
mg/kg
0.077
0.039
1
03/29/15 16:04
04/02/15 09:35
7440-41-7
7.3
mg/kg
3.9
1.9
1
03/29/15 16:04
04/02/15 09:35
7440-42-8
551
mg/kg
38.7
19.4
1
03/29/15 16:04
04/02/15 09:35
7440-70-2
10.6
mg/kg
0.39
0.19
1
03/29/15 16:04
04/02/15 09:35
7440-47-3
10.6
mg/kg
0.39
0.19
1
03/29/15 16:04
04/02/15 09:35
7440-50-8
2840
mg/kg
3.1
1.5
1
03/29/15 16:04
04/02/15 09:35
7439-89-6
M1
212
mg/kg
38.7
19.4
1
03/29/15 16:04
04/02/15 09:35
7439-95-4
24.1
mg/kg
0.39
0.19
1
03/29/15 16:04
04/02/15 09:35
7439-96-5
M1
0.53J
mg/kg
0.77
0.39
1
03/29/15 16:04
04/02/15 09:35
7439-98-7
7.2
mg/kg
0.39
0.19
1
03/29/15 16:04
04/02/15 09:35
7440-02-0
396
mg/kg
77.4
38.7
1
03/29/15 16:04
04/02/15 09:35
7440-09-7
M1
81.5
mg/kg
77.4
38.7
1
03/29/15 16:04
04/02/15 09:35
7440-23-5
25.4
mg/kg
0.77
0.39
1
03/29/15 16:04
04/02/15 09:35
7440-24-6
M1
10.5
mg/kg
1.5
0.77
1
03/29/15 16:04
04/02/15 09:35
7440-66-6
Analytical
Method: EPA 6020 Preparation Method: EPA 3050
ND
mg/kg
3.9
1.9
50
03/29/15 16:04
03/31/15 21:42
7440-36-0
D3,N2
3.3J
mg/kg
3.9
1.9
50
03/29/15 16:04
03/31/15 21:42
7440-38-2
D3
ND
mg/kg
0.46
0.23
50
03/29/15 16:04
03/31/15 21:42
7440-43-9
D3
4.5
mg/kg
3.9
1.9
50
03/29/15 16:04
03/31/15 21:42
7440-48-4
D3
7.4
mg/kg
3.9
1.9
50
03/29/15 16:04
03/31/15 21:42
7439-92-1
D3
ND
mg/kg
3.9
1.9
50
03/29/15 16:04
03/31/15 21:42
7782-49-2
D3
ND
mg/kg
3.9
1.9
50
03/29/15 16:04
03/31/15 21:42
7440-28-0
D3
16.9
mg/kg
3.9
1.9
50
03/29/15 16:04
03/31/15 21:42
7440-62-2
D3
Analytical
Method: EPA 7471
Preparation Method: EPA 7471
ND
mg/kg
0.012
0.0060
1
03/31/1510:20
04/01/1513:06
7439-97-6
Analytical
Method: ASTM D2974-87
33.9
%
0.10
0.10
1
04/01/1516:19
Analytical
Method: EPA 9045
6.4
Std. Units
0.10
0.10
1
03/30/15 12:55
Analytical
Method: EPA 300.0 Leachate Method/Date:
EPA 1312; 03/26/15
00:00
17.8
mg/L
15.1
7.6
5
04/01/1520:10
14808-79-8
B,D3
Analytical
Method: EPA 353.2 Leachate Method/Date:
EPA 1312; 03/26/15
00:00
308
mg/L
15.1
15.1
50
03/31/1519:26
B,H1
Analytical
Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 03/26/15 00:00
ND
mg/L
7.6
3.8
1
03/31/1515:30
16887-00-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 41 of 104

aceAnaiXical
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Pace Analytical Services, Inc.
P369%f 6fY2'9e. Suite 100
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[phone]
ANALYTICAL RESULTS
Project: J150305555
Pace Project No.: 92242381
Sample: 2015007996 Lab ID: 92242381001 Collected: 03/18/15 15:33 Received: 03/23/15 15:04 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
9056 IC Anions Analytical Method: EPA 9056
Chloride
ND mg/kg
378
189
5
03/28/1511:06
16887-00-6 D3
Sulfate
200J mg/kg
378
189
5
03/28/1511:06
14808-79-8 D3
9056 IC Anions 48hr
Analytical Method: EPA 9056
Nitrate as N
ND mg/kg
37.8
18.9
5
03/28/15 11:06
14797-55-8 D3,1-13
Total Organic Carbon Quad
Analytical Method: EPA 9060
Total Organic Carbon
25300 mg/kg
2660
1330
1
04/03/15 12:07
7440-44-0
Total Organic Carbon
25200 mg/kg
2650
1330
1
04/03/15 12:14
7440-44-0
Total Organic Carbon
26400 mg/kg
2620
1310
1
04/03/15 12:20
7440-44-0
Total Organic Carbon
16700 mg/kg
2610
1310
1
04/03/15 12:27
7440-44-0
Mean Total Organic Carbon
23400 mg/kg
2640
1320
1
04/03/15 12:07
7440-44-0
Surrogates
RSD%
19.3 %
1
04/03/15 12:07
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/08/2015 12:54 PM without the written consent of Pace Analytical Services, Inc..
Page 42 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
P3y SHSr6fY2'9e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J150305555
Pace Project No.: 92242381
Sample: 2015007999 Lab ID: 92242381002 Collected: 03/17/15 15:45 Received: 03/23/15 15:04 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Aluminum
Barium
Beryllium
Boron
Calcium
Chromium
Copper
Iron
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Sodium
Strontium
Zinc
6020 MET ICPMS
Antimony
Arsenic
Cadmium
Cobalt
Lead
Selenium
Thallium
Vanadium
7471 Mercury
Mercury
Percent Moisture
Percent Moisture
9045 pH Soil
pH at 25 Degrees C
300.0 IC Anions, SPLP
Sulfate
353.2 Nitrogen, NO2/NO3, SPLP
Nitrogen, Nitrate
Date: 04/08/2015 12:54 PM
Analytical Method: EPA 6010 Preparation Method: EPA 3050
8960
mg/kg
8.6
4.3
1
03/29/15 16:04
04/02/15 09:46
7429-90-5
67.3
mg/kg
0.86
0.43
1
03/29/15 16:04
04/02/15 09:46
7440-39-3
2.3
mg/kg
0.086
0.043
1
03/29/15 16:04
04/02/15 09:46
7440-41-7
25.5
mg/kg
4.3
2.1
1
03/29/15 16:04
04/02/15 09:46
7440-42-8
1100
mg/kg
42.8
21.4
1
03/29/15 16:04
04/02/15 09:46
7440-70-2
24.5
mg/kg
0.43
0.21
1
03/29/15 16:04
04/02/15 09:46
7440-47-3
33.1
mg/kg
0.43
0.21
1
03/29/15 16:04
04/02/15 09:46
7440-50-8
2860
mg/kg
3.4
1.7
1
03/29/15 16:04
04/02/15 09:46
7439-89-6
497
mg/kg
42.8
21.4
1
03/29/15 16:04
04/02/15 09:46
7439-95-4
13.6
mg/kg
0.43
0.21
1
03/29/15 16:04
04/02/15 09:46
7439-96-5
1.2
mg/kg
0.86
0.43
1
03/29/15 16:04
04/02/15 09:46
7439-98-7
18.5
mg/kg
0.43
0.21
1
03/29/15 16:04
04/02/15 09:46
7440-02-0
1230
mg/kg
85.6
42.8
1
03/29/15 16:04
04/02/15 09:46
7440-09-7
119
mg/kg
85.6
42.8
1
03/29/15 16:04
04/02/15 09:46
7440-23-5
60.6
mg/kg
0.86
0.43
1
03/29/15 16:04
04/02/15 09:46
7440-24-6
19.0
mg/kg
1.7
0.86
1
03/29/15 16:04
04/02/15 09:46
7440-66-6
Analytical
Method: EPA 6020 Preparation Method: EPA 3050
ND
mg/kg
4.3
2.1
50
03/29/15 16:04
03/31/15 21:58
7440-36-0
D3,M6,
N2
10
mg/kg
4.3
2.1
50
03/29/15 16:04
03/31/15 21:58
7440-38-2
D3
ND
mg/kg
0.51
0.26
50
03/29/15 16:04
03/31/15 21:58
7440-43-9
D3
12.9
mg/kg
4.3
2.1
50
03/29/15 16:04
03/31/15 21:58
7440-48-4
D3,M6
14.5
mg/kg
4.3
2.1
50
03/29/15 16:04
03/31/15 21:58
7439-92-1
D3,M6
ND
mg/kg
4.3
2.1
50
03/29/15 16:04
03/31/15 21:58
7782-49-2
D3,M6,
R1
ND
mg/kg
4.3
2.1
50
03/29/15 16:04
03/31/15 21:58
7440-28-0
D3
64.7
mg/kg
4.3
2.1
50
03/29/15 16:04
03/31/15 21:58
7440-62-2
D4,M6
Analytical
Method: EPA 7471
Preparation Method: EPA 7471
ND
mg/kg
0.014
0.0068
1
03/31/1510:20
04/01/1513:09
7439-97-6
Analytical
Method: ASTM D2974-87
39.9
%
0.10
0.10
1
04/01/1516:19
Analytical
Method: EPA 9045
7.8
Std. Units
0.10
0.10
1
03/25/15 11:50
Analytical
Method: EPA 300.0 Leachate Method/Date:
EPA 1312; 03/26/15
00:00
12.6
mg/L
6.7
3.3
2
04/01/15 20:24
14808-79-8
B,D3
Analytical
Method: EPA 353.2 Leachate Method/Date:
EPA 1312; 03/26/15
00:00
333
mg/L
16.6
16.6
50
03/31/1519:27
B,H1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 43 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
P3y H� 'irfY2'9e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J150305555
Pace Project No.: 92242381
Sample: 2015007999 Lab ID: 92242381002 Collected: 03/17/15 15:45 Received: 03/23/15 15:04 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
4500 Chloride, SPLP
Chloride
9056 IC Anions
Chloride
Sulfate
9056 IC Anions 48hr
Nitrate as N
Total Organic Carbon Quad
Total Organic Carbon
Total Organic Carbon
Total Organic Carbon
Total Organic Carbon
Mean Total Organic Carbon
Surrogates
RSD%
Date: 04/08/2015 12:54 PM
Analytical Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 03/26/15 00:00
ND mg/L
41.6
20.8
5
03/31/1515:55
16887-00-6
D3
Analytical Method: EPA 9056
ND mg/kg
418
209
5
03/28/1511:27
16887-00-6
D3
ND mg/kg
418
209
5
03/28/1511:27
14808-79-8
D3
Analytical Method: EPA 9056
ND mg/kg
41.8
20.9
5
03/28/1511:27
14797-55-8
D3,H3
Analytical Method: EPA 9060
19600 mg/kg
3870
1930
1
04/03/1513:19
7440-44-0
19400 mg/kg
3940
1970
1
04/03/1513:26
7440-44-0
18500 mg/kg
3870
1930
1
04/03/1513:32
7440-44-0
26500 mg/kg
3940
1970
1
04/03/1513:38
7440-44-0
21000 mg/kg
3900
1950
1
04/03/1513:19
7440-44-0
17.6 %
1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
04/03/15 13:19
Page 44 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
P3y R8r6fY2'9e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J150305555
Pace Project No.: 92242381
Sample: 2015008002 Lab ID: 92242381003 Collected: 03/18/15 12:20 Received: 03/23/15 15:04 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Aluminum
Barium
Beryllium
Boron
Calcium
Chromium
Copper
Iron
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Sodium
Strontium
Zinc
6020 MET ICPMS
Antimony
Arsenic
Cadmium
Cobalt
Lead
Selenium
Thallium
Vanadium
7471 Mercury
Mercury
Percent Moisture
Percent Moisture
9045 pH Soil
pH at 25 Degrees C
300.0 IC Anions, SPLP
Sulfate
353.2 Nitrogen, NO2/NO3, SPLP
Nitrogen, Nitrate
4500 Chloride, SPLP
Chloride
Date: 04/08/2015 12:54 PM
Analytical Method: EPA 6010 Preparation Method: EPA 3050
3760
mg/kg
6.7
3.4
1
03/29/15 16:04
04/01/15 21:21
7429-90-5
41.1
mg/kg
0.67
0.34
1
03/29/15 16:04
04/01/15 21:21
7440-39-3
0.93
mg/kg 0.067
0.034
1
03/29/15 16:04
04/01/15 21:21
7440-41-7
7.3
mg/kg
3.4
1.7
1
03/29/15 16:04
04/01/15 21:21
7440-42-8
581
mg/kg
33.6
16.8
1
03/29/15 16:04
04/01/15 21:21
7440-70-2
13.3
mg/kg
0.34
0.17
1
03/29/15 16:04
04/01/15 21:21
7440-47-3
12.9
mg/kg
0.34
0.17
1
03/29/15 16:04
04/01/15 21:21
7440-50-8
2470
mg/kg
2.7
1.3
1
03/29/15 16:04
04/01/15 21:21
7439-89-6
204
mg/kg
33.6
16.8
1
03/29/15 16:04
04/01/15 21:21
7439-95-4
14.1
mg/kg
0.34
0.17
1
03/29/15 16:04
04/01/15 21:21
7439-96-5
0.59J
mg/kg
0.67
0.34
1
03/29/15 16:04
04/01/15 21:21
7439-98-7
6.8
mg/kg
0.34
0.17
1
03/29/15 16:04
04/01/15 21:21
7440-02-0
451
mg/kg
67.2
33.6
1
03/29/15 16:04
04/01/15 21:21
7440-09-7
63.OJ
mg/kg
67.2
33.6
1
03/29/15 16:04
04/01/15 21:21
7440-23-5
20.6
mg/kg
0.67
0.34
1
03/29/15 16:04
04/01/15 21:21
7440-24-6
8.2
mg/kg
1.3
0.67
1
03/29/15 16:04
04/01/15 21:21
7440-66-6
Analytical
Method: EPA 6020
Preparation Method: EPA 3050
ND
mg/kg
3.4
1.7
50
03/29/15 16:04
03/31/15 22:05
7440-36-0
D3,N2
3.3J
mg/kg
3.4
1.7
50
03/29/15 16:04
03/31/15 22:05
7440-38-2
D3
ND
mg/kg
0.40
0.20
50
03/29/15 16:04
03/31/15 22:05
7440-43-9
D3
4.0
mg/kg
3.4
1.7
50
03/29/15 16:04
03/31/15 22:05
7440-48-4
D3
5.2
mg/kg
3.4
1.7
50
03/29/15 16:04
03/31/15 22:05
7439-92-1
D3
ND
mg/kg
3.4
1.7
50
03/29/15 16:04
03/31/15 22:05
7782-49-2
D3
ND
mg/kg
3.4
1.7
50
03/29/15 16:04
03/31/15 22:05
7440-28-0
D3
15.0
mg/kg
3.4
1.7
50
03/29/15 16:04
03/31/15 22:05
7440-62-2
D3
Analytical
Method: EPA 7471
Preparation Method: EPA 7471
ND
mg/kg
0.011
0.0054
1
03/31/1510:20
04/01/1513:11
7439-97-6
Analytical
Method: ASTM D2974-87
27.6
%
0.10
0.10
1
04/01/1516:19
Analytical
Method: EPA 9045
6.4
Std. Units
0.10
0.10
1
03/30/15 12:55
Analytical
Method: EPA 300.0 Leachate Method/Date:
EPA 1312; 03/26/15
00:00
19.9
mg/L
13.8
6.9
5
04/01/1520:38
14808-79-8
B,D3
Analytical
Method: EPA 353.2 Leachate Method/Date:
EPA 1312; 03/26/15
00:00
236
mg/L
13.8
13.8
50
03/31/1519:28
B,H1
Analytical
Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 03/26/15 00:00
ND
mg/L
6.9
3.5
1
03/31/1515:32
16887-00-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 45 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
P369Wr6fY2'9e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J150305555
Pace Project No.: 92242381
Sample: 2015008002 Lab ID: 92242381003 Collected: 03/18/15 12:20 Received: 03/23/15 15:04 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
9056 IC Anions Analytical Method: EPA 9056
Chloride
ND mg/kg
350
175
5
03/28/1511:49
16887-00-6 D3
Sulfate
326J mg/kg
350
175
5
03/28/1511:49
14808-79-8 D3
9056 IC Anions 48hr
Analytical Method: EPA 9056
Nitrate as N
ND mg/kg
35.0
17.5
5
03/28/15 11:49
14797-55-8 D3,1-13
Total Organic Carbon Quad
Analytical Method: EPA 9060
Total Organic Carbon
10800 mg/kg
834
417
1
04/03/15 13:44
7440-44-0
Total Organic Carbon
14800 mg/kg
822
411
1
04/03/15 13:49
7440-44-0
Total Organic Carbon
23100 mg/kg
826
413
1
04/03/15 13:55
7440-44-0
Total Organic Carbon
11700 mg/kg
824
412
1
04/03/15 14:02
7440-44-0
Mean Total Organic Carbon
15100 mg/kg
826
413
1
04/03/15 13:44
7440-44-0
Surrogates
RSD%
37.1 %
1
04/03/15 13:44
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/08/2015 12:54 PM without the written consent of Pace Analytical Services, Inc..
Page 46 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
P3Sy RVr6fY2'9e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J150305555
Pace Project No.: 92242381
Sample: 2015008007 Lab ID: 92242381004 Collected: 03/19/15 12:30 Received: 03/23/15 15:04 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Aluminum
Barium
Beryllium
Boron
Calcium
Chromium
Copper
Iron
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Sodium
Strontium
Zinc
6020 MET ICPMS
Antimony
Arsenic
Cadmium
Cobalt
Lead
Selenium
Thallium
Vanadium
7471 Mercury
Mercury
Percent Moisture
Percent Moisture
9045 pH Soil
pH at 25 Degrees C
300.0 IC Anions, SPLP
Sulfate
353.2 Nitrogen, NO2/NO3, SPLP
Nitrogen, Nitrate
4500 Chloride, SPLP
Chloride
Date: 04/08/2015 12:54 PM
Analytical Method: EPA 6010 Preparation Method: EPA 3050
3060
mg/kg
7.0
3.5
1
03/29/15 16:04
04/01/15 21:25
7429-90-5
34.7
mg/kg
0.70
0.35
1
03/29/15 16:04
04/01/15 21:25
7440-39-3
0.64
mg/kg 0.070
0.035
1
03/29/15 16:04
04/01/15 21:25
7440-41-7
5.9
mg/kg
3.5
1.7
1
03/29/15 16:04
04/01/15 21:25
7440-42-8
483
mg/kg
35.0
17.5
1
03/29/15 16:04
04/01/15 21:25
7440-70-2
8.0
mg/kg
0.35
0.17
1
03/29/15 16:04
04/01/15 21:25
7440-47-3
8.0
mg/kg
0.35
0.17
1
03/29/15 16:04
04/01/15 21:25
7440-50-8
1820
mg/kg
2.8
1.4
1
03/29/15 16:04
04/01/15 21:25
7439-89-6
180
mg/kg
35.0
17.5
1
03/29/15 16:04
04/01/15 21:25
7439-95-4
9.4
mg/kg
0.35
0.17
1
03/29/15 16:04
04/01/15 21:25
7439-96-5
0.63J
mg/kg
0.70
0.35
1
03/29/15 16:04
04/01/15 21:25
7439-98-7
5.4
mg/kg
0.35
0.17
1
03/29/15 16:04
04/01/15 21:25
7440-02-0
367
mg/kg
70.0
35.0
1
03/29/15 16:04
04/01/15 21:25
7440-09-7
55.01
mg/kg
70.0
35.0
1
03/29/15 16:04
04/01/15 21:25
7440-23-5
17.9
mg/kg
0.70
0.35
1
03/29/15 16:04
04/01/15 21:25
7440-24-6
6.8
mg/kg
1.4
0.70
1
03/29/15 16:04
04/01/15 21:25
7440-66-6
Analytical
Method: EPA 6020
Preparation Method: EPA 3050
ND
mg/kg
3.5
1.7
50
03/29/15 16:04
03/31/15 22:08
7440-36-0
D3,N2
2.6J
mg/kg
3.5
1.7
50
03/29/15 16:04
03/31/15 22:08
7440-38-2
D3
ND
mg/kg
0.42
0.21
50
03/29/15 16:04
03/31/15 22:08
7440-43-9
D3
3AJ
mg/kg
3.5
1.7
50
03/29/15 16:04
03/31/15 22:08
7440-48-4
D3
4.0
mg/kg
3.5
1.7
50
03/29/15 16:04
03/31/15 22:08
7439-92-1
D3
ND
mg/kg
3.5
1.7
50
03/29/15 16:04
03/31/15 22:08
7782-49-2
D3
ND
mg/kg
3.5
1.7
50
03/29/15 16:04
03/31/15 22:08
7440-28-0
D3
13.7
mg/kg
3.5
1.7
50
03/29/15 16:04
03/31/15 22:08
7440-62-2
D3
Analytical
Method: EPA 7471
Preparation Method: EPA 7471
ND
mg/kg
0.011
0.0057
1
03/31/1510:20
04/01/1513:13
7439-97-6
Analytical
Method: ASTM D2974-87
30.7
%
0.10
0.10
1
04/01/1516:20
Analytical
Method: EPA 9045
7.3
Std. Units
0.10
0.10
1
03/30/15 12:55
Analytical
Method: EPA 300.0 Leachate Method/Date:
EPA 1312; 03/26/15
00:00
11.8
mg/L
5.8
2.9
2
04/02/1511:14
14808-79-8
B,D3
Analytical
Method: EPA 353.2 Leachate Method/Date:
EPA 1312; 03/26/15
00:00
180
mg/L
8.7
8.7
30
03/31/1518:44
B,H1
Analytical
Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 03/26/15 00:00
ND
mg/L
7.2
3.6
1
03/31/1515:34
16887-00-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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ANALYTICAL RESULTS
Project: J150305555
Pace Project No.: 92242381
Sample: 2015008007 Lab ID: 92242381004 Collected: 03/19/15 12:30 Received: 03/23/15 15:04 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
9056 IC Anions Analytical Method: EPA 9056
Chloride
ND mg/kg
352
176
5
03/28/1512:10
16887-00-6 D3
Sulfate
ND mg/kg
352
176
5
03/28/1512:10
14808-79-8 D3
9056 IC Anions 48hr
Analytical Method: EPA 9056
Nitrate as N
ND mg/kg
35.2
17.6
5
03/28/15 12:10
14797-55-8 D3,1-13
Total Organic Carbon Quad
Analytical Method: EPA 9060
Total Organic Carbon
49000 mg/kg
3100
1550
1
04/03/15 14:08
7440-44-0
Total Organic Carbon
30100 mg/kg
3110
1550
1
04/03/15 14:15
7440-44-0
Total Organic Carbon
43500 mg/kg
3140
1570
1
04/03/15 14:22
7440-44-0
Total Organic Carbon
34500 mg/kg
3100
1550
1
04/03/15 14:30
7440-44-0
Mean Total Organic Carbon
39300 mg/kg
3110
1560
1
04/03/15 14:08
7440-44-0
Surrogates
RSD%
21.7 %
1
04/03/15 14:08
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/08/2015 12:54 PM without the written consent of Pace Analytical Services, Inc..
Page 48 of 104

aceAnaiXical
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Pace Analytical Services, Inc.
P369%6r6fY2'9e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J150305555
Pace Project No.: 92242381
Sample: 2015007997
Lab ID:
92242381005
Collected:
03/18/15 15:50
Received: 03/23/15 15:04 Matrix: Solid
Results reported on a "dry weight"
basis and are adjusted for percent moisture, sample
size and any dilutions.
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared
Analyzed
CAS No.
Qual
6010 MET ICP
Analytical
Method: EPA 6010
Preparation
Method: EPA
3050
Aluminum
3460
mg/kg
7.8
3.9
1
03/29/15 16:04
04/01/15 21:29
7429-90-5
Barium
51.8
mg/kg
0.78
0.39
1
03/29/15 16:04
04/01/15 21:29
7440-39-3
Beryllium
0.78
mg/kg
0.078
0.039
1
03/29/15 16:04
04/01/15 21:29
7440-41-7
Boron
7.7
mg/kg
3.9
1.9
1
03/29/15 16:04
04/01/15 21:29
7440-42-8
Calcium
632
mg/kg
38.9
19.4
1
03/29/15 16:04
04/01/15 21:29
7440-70-2
Chromium
10.2
mg/kg
0.39
0.19
1
03/29/15 16:04
04/01/15 21:29
7440-47-3
Copper
11.7
mg/kg
0.39
0.19
1
03/29/15 16:04
04/01/15 21:29
7440-50-8
Iron
2420
mg/kg
3.1
1.6
1
03/29/15 16:04
04/01/15 21:29
7439-89-6
Magnesium
231
mg/kg
38.9
19.4
1
03/29/15 16:04
04/01/15 21:29
7439-95-4
Manganese
22.6
mg/kg
0.39
0.19
1
03/29/15 16:04
04/01/15 21:29
7439-96-5
Molybdenum
0.54J
mg/kg
0.78
0.39
1
03/29/15 16:04
04/01/15 21:29
7439-98-7
Nickel
7.2
mg/kg
0.39
0.19
1
03/29/15 16:04
04/01/15 21:29
7440-02-0
Potassium
402
mg/kg
77.7
38.9
1
03/29/15 16:04
04/01/15 21:29
7440-09-7
Sodium
92.2
mg/kg
77.7
38.9
1
03/29/15 16:04
04/01/15 21:29
7440-23-5
Strontium
28.9
mg/kg
0.78
0.39
1
03/29/15 16:04
04/01/15 21:29
7440-24-6
Zinc
10.1
mg/kg
1.6
0.78
1
03/29/15 16:04
04/01/15 21:29
7440-66-6
6020 MET ICPMS
Analytical
Method: EPA 6020
Preparation
Method: EPA
3050
Antimony
ND
mg/kg
3.9
1.9
50
03/29/15 16:04
03/31/15 22:10
7440-36-0
D3,N2
Arsenic
3AJ
mg/kg
3.9
1.9
50
03/29/15 16:04
03/31/15 22:10
7440-38-2
D3
Cadmium
ND
mg/kg
0.47
0.23
50
03/29/15 16:04
03/31/15 22:10
7440-43-9
D3
Cobalt
4.7
mg/kg
3.9
1.9
50
03/29/15 16:04
03/31/15 22:10
7440-48-4
D3
Lead
5.3
mg/kg
3.9
1.9
50
03/29/15 16:04
03/31/15 22:10
7439-92-1
D3
Selenium
ND
mg/kg
3.9
1.9
50
03/29/15 16:04
03/31/15 22:10
7782-49-2
D3
Thallium
ND
mg/kg
3.9
1.9
50
03/29/15 16:04
03/31/15 22:10
7440-28-0
D3
Vanadium
16.7
mg/kg
3.9
1.9
50
03/29/15 16:04
03/31/15 22:10
7440-62-2
D3
7471 Mercury
Analytical
Method: EPA 7471 Preparation
Method: EPA
7471
Mercury
ND
mg/kg
0.012
0.0058
1
03/31/1510:20
04/01/1513:15
7439-97-6
Percent Moisture
Analytical
Method: ASTM
D2974-87
Percent Moisture
32.3
%
0.10
0.10
1
04/01/15 16:20
9045 pH Soil
Analytical
Method: EPA 9045
pH at 25 Degrees C
6.4
Std. Units
0.10
0.10
1
03/30/15 12:55
9056 IC Anions
Analytical
Method: EPA 9056
Chloride
ND
mg/kg
362
181
5
03/28/1512:32
16887-00-6
D3
Sulfate
216J
mg/kg
362
181
5
03/28/1512:32
14808-79-8
D3
9056 IC Anions 48hr
Analytical
Method: EPA 9056
Nitrate as N
ND
mg/kg
36.2
18.1
5
03/28/15 12:32
14797-55-8
D3,H3
Date: 04/08/2015 12:54 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 49 of 104

aceAnaiXical
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Pace Analytical Services, Inc.
P3690?bir6fY2'9e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J150305555
Pace Project No.: 92242381
Sample: 2015007997
Lab ID:
92242381005
Collected:
03/18/15 15:50
Received: 03/23/15 15:04 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample
size and any dilutions.
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared Analyzed
CAS No. Qual
Total Organic Carbon Quad
Analytical
Method: EPA 9060
Total Organic Carbon
16200
mg/kg
2380
1190
1
04/03/15 14:36
7440-44-0
Total Organic Carbon
17800
mg/kg
2340
1170
1
04/03/15 14:42
7440-44-0
Total Organic Carbon
15200
mg/kg
2380
1190
1
04/03/15 14:48
7440-44-0
Total Organic Carbon
14200
mg/kg
2320
1160
1
04/03/15 14:57
7440-44-0
Mean Total Organic Carbon
15800
mg/kg
2350
1180
1
04/03/15 14:36
7440-44-0
Surrogates
RSD%
9.5
%
1
04/03/15 14:36
Date: 04/08/2015 12:54 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 50 of 104

aceAnaiXical
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Pace Analytical Services, Inc.
P3690AirWY2"�e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J150305555
Pace Project No.: 92242381
Sample: 2015007998
Lab ID:
92242381006
Collected:
03/18/15 09:30
Received: 03/23/15 15:04 Matrix: Solid
Results reported on a "dry weight"
basis and are adjusted for percent moisture, sample
size and any dilutions.
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared
Analyzed
CAS No.
Qual
6010 MET ICP
Analytical
Method: EPA 6010
Preparation
Method: EPA
3050
Aluminum
863
mg/kg
6.7
3.3
1
03/29/15 16:04
04/01/15 21:33
7429-90-5
Barium
38.7
mg/kg
0.67
0.33
1
03/29/15 16:04
04/01/15 21:33
7440-39-3
Beryllium
0.20
mg/kg
0.067
0.033
1
03/29/15 16:04
04/01/15 21:33
7440-41-7
Boron
2.6J
mg/kg
3.3
1.7
1
03/29/15 16:04
04/01/15 21:33
7440-42-8
Calcium
377
mg/kg
33.3
16.7
1
03/29/15 16:04
04/01/15 21:33
7440-70-2
Chromium
2.0
mg/kg
0.33
0.17
1
03/29/15 16:04
04/01/15 21:33
7440-47-3
Copper
3.0
mg/kg
0.33
0.17
1
03/29/15 16:04
04/01/15 21:33
7440-50-8
Iron
1010
mg/kg
2.7
1.3
1
03/29/15 16:04
04/01/15 21:33
7439-89-6
Magnesium
58.1
mg/kg
33.3
16.7
1
03/29/15 16:04
04/01/15 21:33
7439-95-4
Manganese
11.9
mg/kg
0.33
0.17
1
03/29/15 16:04
04/01/15 21:33
7439-96-5
Molybdenum
0.38J
mg/kg
0.67
0.33
1
03/29/15 16:04
04/01/15 21:33
7439-98-7
Nickel
2.6
mg/kg
0.33
0.17
1
03/29/15 16:04
04/01/15 21:33
7440-02-0
Potassium
110
mg/kg
66.7
33.3
1
03/29/15 16:04
04/01/15 21:33
7440-09-7
Sodium
ND
mg/kg
66.7
33.3
1
03/29/15 16:04
04/01/15 21:33
7440-23-5
Strontium
8.0
mg/kg
0.67
0.33
1
03/29/15 16:04
04/01/15 21:33
7440-24-6
Zinc
2.1
mg/kg
1.3
0.67
1
03/29/15 16:04
04/01/15 21:33
7440-66-6
6020 MET ICPMS
Analytical
Method: EPA 6020
Preparation
Method: EPA
3050
Antimony
ND
mg/kg
3.3
1.7
50
03/29/15 16:04
03/31/15 22:12
7440-36-0
D3,N2
Arsenic
ND
mg/kg
3.3
1.7
50
03/29/15 16:04
03/31/15 22:12
7440-38-2
D3
Cadmium
ND
mg/kg
0.40
0.20
50
03/29/15 16:04
03/31/15 22:12
7440-43-9
D3
Cobalt
ND
mg/kg
3.3
1.7
50
03/29/15 16:04
03/31/15 22:12
7440-48-4
D3
Lead
ND
mg/kg
3.3
1.7
50
03/29/15 16:04
03/31/15 22:12
7439-92-1
D3
Selenium
ND
mg/kg
3.3
1.7
50
03/29/15 16:04
03/31/15 22:12
7782-49-2
D3
Thallium
ND
mg/kg
3.3
1.7
50
03/29/15 16:04
03/31/15 22:12
7440-28-0
D3
Vanadium
2.9J
mg/kg
3.3
1.7
50
03/29/15 16:04
03/31/15 22:12
7440-62-2
D3
7471 Mercury
Analytical
Method: EPA 7471 Preparation
Method: EPA
7471
Mercury
ND
mg/kg
0.0097
0.0049
1
03/31/1510:20
04/01/1513:17
7439-97-6
Percent Moisture
Analytical
Method: ASTM
D2974-87
Percent Moisture
21.6
%
0.10
0.10
1
04/01/15 16:21
9045 pH Soil
Analytical
Method: EPA 9045
pH at 25 Degrees C
6.4
Std. Units
0.10
0.10
1
03/30/15 12:55
9056 IC Anions
Analytical
Method: EPA 9056
Chloride
ND
mg/kg
322
161
5
03/28/1512:53
16887-00-6
D3
Sulfate
ND
mg/kg
322
161
5
03/28/1512:53
14808-79-8
D3
9056 IC Anions 48hr
Analytical
Method: EPA 9056
Nitrate as N
ND
mg/kg
32.2
16.1
5
03/28/15 12:53
14797-55-8
D3,H3
Date: 04/08/2015 12:54 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 51 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
P3690hr6fY2'9e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J150305555
Pace Project No.: 92242381
Sample: 2015007998
Lab ID:
92242381006
Collected:
03/18/15 09:30
Received: 03/23/15 15:04 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample
size and any dilutions.
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared Analyzed
CAS No. Qual
Total Organic Carbon Quad
Analytical
Method: EPA 9060
Total Organic Carbon
6380
mg/kg
1110
556
1
04/03/15 15:03
7440-44-0
Total Organic Carbon
7810
mg/kg
1120
558
1
04/03/15 15:09
7440-44-0
Total Organic Carbon
5960
mg/kg
1120
559
1
04/03/15 15:15
7440-44-0
Total Organic Carbon
6370
mg/kg
1120
562
1
04/03/15 15:21
7440-44-0
Mean Total Organic Carbon
6630
mg/kg
1120
559
1
04/03/15 15:03
7440-44-0
Surrogates
RSD%
12.3
%
1
04/03/15 15:03
Date: 04/08/2015 12:54 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 52 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
P3690hr6fY2'9e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J150305555
Pace Project No.: 92242381
Sample: 2015008000
Lab ID:
92242381007
Collected:
03/18/15 14:30
Received: 03/23/15 15:04 Matrix: Solid
Results reported on a "dry weight"
basis and are adjusted for percent moisture, sample
size and any dilutions.
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared
Analyzed
CAS No.
Qual
6010 MET ICP
Analytical
Method: EPA 6010
Preparation
Method: EPA
3050
Aluminum
281
mg/kg
8.8
4.4
1
03/29/15 16:04
04/01/15 21:37
7429-90-5
Barium
9.9
mg/kg
0.88
0.44
1
03/29/15 16:04
04/01/15 21:37
7440-39-3
Beryllium
0.091
mg/kg
0.088
0.044
1
03/29/15 16:04
04/01/15 21:37
7440-41-7
Boron
ND
mg/kg
4.4
2.2
1
03/29/15 16:04
04/01/15 21:37
7440-42-8
Calcium
70.7
mg/kg
44.1
22.1
1
03/29/15 16:04
04/01/15 21:37
7440-70-2
Chromium
0.86
mg/kg
0.44
0.22
1
03/29/15 16:04
04/01/15 21:37
7440-47-3
Copper
1.2
mg/kg
0.44
0.22
1
03/29/15 16:04
04/01/15 21:37
7440-50-8
Iron
320
mg/kg
3.5
1.8
1
03/29/15 16:04
04/01/15 21:37
7439-89-6
Magnesium
25AJ
mg/kg
44.1
22.1
1
03/29/15 16:04
04/01/15 21:37
7439-95-4
Manganese
1.7
mg/kg
0.44
0.22
1
03/29/15 16:04
04/01/15 21:37
7439-96-5
Molybdenum
ND
mg/kg
0.88
0.44
1
03/29/15 16:04
04/01/15 21:37
7439-98-7
Nickel
1.1
mg/kg
0.44
0.22
1
03/29/15 16:04
04/01/15 21:37
7440-02-0
Potassium
ND
mg/kg
88.3
44.1
1
03/29/15 16:04
04/01/15 21:37
7440-09-7
Sodium
ND
mg/kg
88.3
44.1
1
03/29/15 16:04
04/01/15 21:37
7440-23-5
Strontium
2.9
mg/kg
0.88
0.44
1
03/29/15 16:04
04/01/15 21:37
7440-24-6
Zinc
1.1J
mg/kg
1.8
0.88
1
03/29/15 16:04
04/01/15 21:37
7440-66-6
6020 MET ICPMS
Analytical
Method: EPA 6020
Preparation
Method: EPA
3050
Antimony
ND
mg/kg
4.4
2.2
50
03/29/15 16:04
03/31/15 22:14
7440-36-0
D3,N2
Arsenic
ND
mg/kg
4.4
2.2
50
03/29/15 16:04
03/31/15 22:14
7440-38-2
D3
Cadmium
ND
mg/kg
0.53
0.26
50
03/29/15 16:04
03/31/15 22:14
7440-43-9
D3
Cobalt
ND
mg/kg
4.4
2.2
50
03/29/15 16:04
03/31/15 22:14
7440-48-4
D3
Lead
ND
mg/kg
4.4
2.2
50
03/29/15 16:04
03/31/15 22:14
7439-92-1
D3
Selenium
ND
mg/kg
4.4
2.2
50
03/29/15 16:04
03/31/15 22:14
7782-49-2
D3
Thallium
ND
mg/kg
4.4
2.2
50
03/29/15 16:04
03/31/15 22:14
7440-28-0
D3
Vanadium
ND
mg/kg
4.4
2.2
50
03/29/15 16:04
03/31/15 22:14
7440-62-2
D3
7471 Mercury
Analytical
Method: EPA 7471 Preparation
Method: EPA
7471
Mercury
ND
mg/kg
0.014
0.0070
1
03/31/1510:20
04/01/1513:19
7439-97-6
Percent Moisture
Analytical
Method: ASTM
D2974-87
Percent Moisture
41.2
%
0.10
0.10
1
04/01/15 16:21
9045 pH Soil
Analytical
Method: EPA 9045
pH at 25 Degrees C
6.3
Std. Units
0.10
0.10
1
03/30/15 12:55
9056 IC Anions
Analytical
Method: EPA 9056
Chloride
ND
mg/kg
416
208
5
03/28/1513:15
16887-00-6
D3
Sulfate
ND
mg/kg
416
208
5
03/28/1513:15
14808-79-8
D3
9056 IC Anions 48hr
Analytical
Method: EPA 9056
Nitrate as N
ND
mg/kg
41.6
20.8
5
03/28/15 13:15
14797-55-8
D3,H3
Date: 04/08/2015 12:54 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 53 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
P36907 rWY2'9e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J150305555
Pace Project No.: 92242381
Sample: 2015008000
Lab ID:
92242381007
Collected:
03/18/15 14:30
Received: 03/23/15 15:04 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample
size and any dilutions.
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared Analyzed
CAS No. Qual
Total Organic Carbon Quad
Analytical
Method: EPA 9060
Total Organic Carbon
11400
mg/kg
1030
513
1
04/03/15 15:42
7440-44-0
Total Organic Carbon
19400
mg/kg
1020
510
1
04/03/15 15:52
7440-44-0
Total Organic Carbon
10300
mg/kg
1020
510
1
04/03/15 15:59
7440-44-0
Total Organic Carbon
8260
mg/kg
1010
507
1
04/03/15 16:05
7440-44-0
Mean Total Organic Carbon
12300
mg/kg
1020
510
1
04/03/15 15:42
7440-44-0
Surrogates
RSD%
39.4
%
1
04/03/15 15:42
Date: 04/08/2015 12:54 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 54 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
P36908r6fY2'9e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J150305555
Pace Project No.: 92242381
Sample: 2015008001
Lab ID:
92242381008 Collected:
03/17/15 13:05
Received: 03/23/15 15:04 Matrix: Solid
Results reported on a "dry weight"
basis and are adjusted for percent moisture, sample
size and any dilutions.
Report
Parameters
Results
Units Limit
MDL
DF
Prepared
Analyzed
CAS No.
Qual
6010 MET ICP
Analytical
Method: EPA 6010
Preparation
Method: EPA
3050
Aluminum
485
mg/kg
7.0
3.5
1
03/29/15 16:04
04/01/15 21:41
7429-90-5
Barium
16.9
mg/kg
3.5
1.7
5
03/29/15 16:04
04/02/1510:11
7440-39-3
D3
Beryllium
0.14
mg/kg 0.070
0.035
1
03/29/15 16:04
04/01/15 21:41
7440-41-7
Boron
ND
mg/kg
3.5
1.7
1
03/29/15 16:04
04/01/15 21:41
7440-42-8
Calcium
199
mg/kg
34.9
17.5
1
03/29/15 16:04
04/01/15 21:41
7440-70-2
Chromium
1.9
mg/kg
0.35
0.17
1
03/29/15 16:04
04/01/15 21:41
7440-47-3
Copper
2.8
mg/kg
1.7
0.87
5
03/29/15 16:04
04/02/1510:11
7440-50-8
D3
Iron
554
mg/kg
2.8
1.4
1
03/29/15 16:04
04/01/15 21:41
7439-89-6
Magnesium
36.2
mg/kg
34.9
17.5
1
03/29/15 16:04
04/01/15 21:41
7439-95-4
Manganese
37.7
mg/kg
0.35
0.17
1
03/29/15 16:04
04/01/15 21:41
7439-96-5
Molybdenum
0.38J
mg/kg
0.70
0.35
1
03/29/15 16:04
04/01/15 21:41
7439-98-7
Nickel
2.1
mg/kg
0.35
0.17
1
03/29/15 16:04
04/01/15 21:41
7440-02-0
Potassium
63.7J
mg/kg
69.9
34.9
1
03/29/15 16:04
04/01/15 21:41
7440-09-7
Sodium
ND
mg/kg
69.9
34.9
1
03/29/15 16:04
04/01/15 21:41
7440-23-5
Strontium
4.7
mg/kg
0.70
0.35
1
03/29/15 16:04
04/01/15 21:41
7440-24-6
Zinc
ND
mg/kg
7.0
3.5
5
03/29/15 16:04
04/02/1510:11
7440-66-6
D3
6020 MET ICPMS
Analytical
Method: EPA 6020
Preparation
Method: EPA
3050
Antimony
ND
mg/kg
3.5
1.7
50
03/29/15 16:04
03/31/15 22:17
7440-36-0
D3,N2
Arsenic
ND
mg/kg
3.5
1.7
50
03/29/15 16:04
03/31/15 22:17
7440-38-2
D3
Cadmium
ND
mg/kg
0.42
0.21
50
03/29/15 16:04
03/31/15 22:17
7440-43-9
D3
Cobalt
ND
mg/kg
3.5
1.7
50
03/29/15 16:04
03/31/15 22:17
7440-48-4
D3
Lead
ND
mg/kg
3.5
1.7
50
03/29/15 16:04
03/31/15 22:17
7439-92-1
D3
Selenium
ND
mg/kg
3.5
1.7
50
03/29/15 16:04
03/31/15 22:17
7782-49-2
D3
Thallium
ND
mg/kg
3.5
1.7
50
03/29/15 16:04
03/31/15 22:17
7440-28-0
D3
Vanadium
ND
mg/kg
3.5
1.7
50
03/29/15 16:04
03/31/15 22:17
7440-62-2
D3
7471 Mercury
Analytical
Method: EPA 7471
Preparation
Method: EPA
7471
Mercury
ND
mg/kg
0.011
0.0055
1
03/31/1511:55
04/01/1513:39
7439-97-6
Percent Moisture
Analytical
Method: ASTM D2974-87
Percent Moisture
28.0
%
0.10
0.10
1
04/01/15 16:21
9045 pH Soil
Analytical
Method: EPA 9045
pH at 25 Degrees C
6.6
Std. Units
0.10
0.10
1
03/25/15 11:50
9056 IC Anions
Analytical
Method: EPA 9056
Chloride
ND
mg/kg
344
172
5
03/28/1513:36
16887-00-6
D3
Sulfate
ND
mg/kg
344
172
5
03/28/1513:36
14808-79-8
D3
9056 IC Anions 48hr
Analytical
Method: EPA 9056
Nitrate as N
ND
mg/kg
34.4
17.2
5
03/28/15 13:36
14797-55-8
D3,H3
Date: 04/08/2015 12:54 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 55 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
P3690Mr6fY2'9e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J150305555
Pace Project No.: 92242381
Sample: 2015008001
Lab ID:
92242381008
Collected:
03/17/15 13:05
Received: 03/23/15 15:04 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample
size and any dilutions.
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared Analyzed
CAS No. Qual
Total Organic Carbon Quad
Analytical
Method: EPA 9060
Total Organic Carbon
16800
mg/kg
828
414
1
04/03/15 16:10
7440-44-0
Total Organic Carbon
16000
mg/kg
827
414
1
04/03/15 16:17
7440-44-0
Total Organic Carbon
10900
mg/kg
837
418
1
04/03/15 16:28
7440-44-0
Total Organic Carbon
14200
mg/kg
833
417
1
04/03/15 16:35
7440-44-0
Mean Total Organic Carbon
14500
mg/kg
831
416
1
04/03/15 16:10
7440-44-0
Surrogates
RSD%
18.3
%
1
04/03/15 16:10
Date: 04/08/2015 12:54 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 56 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
P3690nr6fY2'9e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J150305555
Pace Project No.: 92242381
Sample: 2015008003
Lab ID:
92242381009 Collected:
03/18/15 13:15
Received: 03/23/15 15:04 Matrix: Solid
Results reported on a "dry weight"
basis and are adjusted for percent moisture, sample
size and any dilutions.
Report
Parameters
Results
Units Limit
MDL
DF
Prepared
Analyzed
CAS No.
Qual
6010 MET ICP
Analytical
Method: EPA 6010
Preparation
Method: EPA
3050
Aluminum
13900
mg/kg
6.9
3.5
1
03/29/15 16:04
04/01/15 21:45
7429-90-5
Barium
83.2
mg/kg
0.69
0.35
1
03/29/15 16:04
04/01/15 21:45
7440-39-3
Beryllium
3.1
mg/kg
0.35
0.17
5
03/29/15 16:04
04/02/1510:15
7440-41-7
D3
Boron
32.9
mg/kg
17.3
8.6
5
03/29/15 16:04
04/02/1510:15
7440-42-8
D3
Calcium
1080
mg/kg
34.6
17.3
1
03/29/15 16:04
04/01/15 21:45
7440-70-2
Chromium
54.7
mg/kg
1.7
0.86
5
03/29/15 16:04
04/02/1510:15
7440-47-3
D3
Copper
43.4
mg/kg
1.7
0.86
5
03/29/15 16:04
04/02/1510:15
7440-50-8
D3
Iron
3020
mg/kg
2.8
1.4
1
03/29/15 16:04
04/01/15 21:45
7439-89-6
Magnesium
541
mg/kg
34.6
17.3
1
03/29/15 16:04
04/01/15 21:45
7439-95-4
Manganese
69.4
mg/kg
1.7
0.86
5
03/29/15 16:04
04/02/1510:15
7439-96-5
D3
Molybdenum
1.4
mg/kg
0.69
0.35
1
03/29/15 16:04
04/01/15 21:45
7439-98-7
Nickel
22.5
mg/kg
0.35
0.17
1
03/29/15 16:04
04/01/15 21:45
7440-02-0
Potassium
1650
mg/kg
69.2
34.6
1
03/29/15 16:04
04/01/15 21:45
7440-09-7
Sodium
155
mg/kg
69.2
34.6
1
03/29/15 16:04
04/01/15 21:45
7440-23-5
Strontium
83.7
mg/kg
0.69
0.35
1
03/29/15 16:04
04/01/15 21:45
7440-24-6
Zinc
36.4
mg/kg
1.4
0.69
1
03/29/15 16:04
04/01/15 21:45
7440-66-6
6020 MET ICPMS
Analytical
Method: EPA 6020
Preparation
Method: EPA
3050
Antimony
ND
mg/kg
3.5
1.7
50
03/29/15 16:04
03/31/15 22:19
7440-36-0
D3,N2
Arsenic
11.2
mg/kg
3.5
1.7
50
03/29/15 16:04
03/31/15 22:19
7440-38-2
D3
Cadmium
ND
mg/kg
0.42
0.21
50
03/29/15 16:04
03/31/15 22:19
7440-43-9
D3
Cobalt
17.7
mg/kg
3.5
1.7
50
03/29/15 16:04
03/31/15 22:19
7440-48-4
D3
Lead
21.9
mg/kg
3.5
1.7
50
03/29/15 16:04
03/31/15 22:19
7439-92-1
D3
Selenium
ND
mg/kg
3.5
1.7
50
03/29/15 16:04
03/31/15 22:19
7782-49-2
D3
Thallium
ND
mg/kg
3.5
1.7
50
03/29/15 16:04
03/31/15 22:19
7440-28-0
D3
Vanadium
88.1
mg/kg
3.5
1.7
50
03/29/15 16:04
03/31/15 22:19
7440-62-2
D4
7471 Mercury
Analytical
Method: EPA 7471
Preparation
Method: EPA
7471
Mercury
ND
mg/kg
0.011
0.0055
1
03/31/1511:55
04/01/1513:45
7439-97-6
Percent Moisture
Analytical
Method: ASTM D2974-87
Percent Moisture
24.7
%
0.10
0.10
1
04/01/15 16:22
9045 pH Soil
Analytical
Method: EPA 9045
pH at 25 Degrees C
6.4
Std. Units
0.10
0.10
1
03/25/15 11:50
9056 IC Anions
Analytical
Method: EPA 9056
Chloride
ND
mg/kg
332
166
5
03/29/1513:00
16887-00-6
D3,M1
Sulfate
ND
mg/kg
332
166
5
03/29/1513:00
14808-79-8
D3
9056 IC Anions 48hr
Analytical
Method: EPA 9056
Nitrate as N
ND
mg/kg
33.2
16.6
5
03/29/15 13:00
14797-55-8
D3,H3
Date: 04/08/2015 12:54 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 57 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
P3690 6fY2'9e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J150305555
Pace Project No.: 92242381
Sample: 2015008003
Lab ID:
92242381009
Collected:
03/18/15 13:15
Received: 03/23/15 15:04 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample
size and any dilutions.
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared Analyzed
CAS No. Qual
Total Organic Carbon Quad
Analytical
Method: EPA 9060
Total Organic Carbon
9330
mg/kg
5670
2840
1
04/03/15 16:42
7440-44-0
Total Organic Carbon
7650
mg/kg
5810
2910
1
04/03/15 16:48
7440-44-0
Total Organic Carbon
8290
mg/kg
5860
2930
1
04/03/15 16:54
7440-44-0
Total Organic Carbon
8680
mg/kg
5890
2940
1
04/03/15 16:59
7440-44-0
Mean Total Organic Carbon
8490
mg/kg
5810
2900
1
04/03/15 16:42
7440-44-0
Surrogates
RSD%
8.3
%
1
04/03/15 16:42
Date: 04/08/2015 12:54 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 58 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
P3690hr6fY2'9e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J150305555
Pace Project No.: 92242381
Sample: 2015008004
Lab ID:
92242381010 Collected:
03/17/15 15:30
Received: 03/23/15 15:04 Matrix: Solid
Results reported on a "dry weight"
basis and are adjusted for percent moisture, sample
size and any dilutions.
Report
Parameters
Results
Units Limit
MDL
DF
Prepared
Analyzed
CAS No.
Qual
6010 MET ICP
Analytical
Method: EPA 6010
Preparation
Method: EPA
3050
Aluminum
9620
mg/kg
7.1
3.5
1
03/29/15 16:04
04/01/15 21:49
7429-90-5
Barium
80.9
mg/kg
0.71
0.35
1
03/29/15 16:04
04/01/15 21:49
7440-39-3
Beryllium
2.6
mg/kg 0.071
0.035
1
03/29/15 16:04
04/01/15 21:49
7440-41-7
Boron
31.3
mg/kg
3.5
1.8
1
03/29/15 16:04
04/01/15 21:49
7440-42-8
Calcium
1150
mg/kg
35.4
17.7
1
03/29/15 16:04
04/01/15 21:49
7440-70-2
Chromium
31.9
mg/kg
0.35
0.18
1
03/29/15 16:04
04/01/15 21:49
7440-47-3
Copper
33.3
mg/kg
0.35
0.18
1
03/29/15 16:04
04/01/15 21:49
7440-50-8
Iron
3290
mg/kg
2.8
1.4
1
03/29/15 16:04
04/01/15 21:49
7439-89-6
Magnesium
388
mg/kg
35.4
17.7
1
03/29/15 16:04
04/01/15 21:49
7439-95-4
Manganese
21.1
mg/kg
0.35
0.18
1
03/29/15 16:04
04/01/15 21:49
7439-96-5
Molybdenum
1.6
mg/kg
0.71
0.35
1
03/29/15 16:04
04/01/15 21:49
7439-98-7
Nickel
18.7
mg/kg
0.35
0.18
1
03/29/15 16:04
04/01/15 21:49
7440-02-0
Potassium
895
mg/kg
70.9
35.4
1
03/29/15 16:04
04/01/15 21:49
7440-09-7
Sodium
102
mg/kg
70.9
35.4
1
03/29/15 16:04
04/01/15 21:49
7440-23-5
Strontium
53.0
mg/kg
0.71
0.35
1
03/29/15 16:04
04/01/15 21:49
7440-24-6
Zinc
24.0
mg/kg
1.4
0.71
1
03/29/15 16:04
04/01/15 21:49
7440-66-6
6020 MET ICPMS
Analytical
Method: EPA 6020
Preparation
Method: EPA
3050
Antimony
ND
mg/kg
3.5
1.8
50
03/29/15 16:04
04/02/1516:09
7440-36-0
D3,N2
Arsenic
13.4
mg/kg
3.5
1.8
50
03/29/15 16:04
04/02/1516:09
7440-38-2
D3
Cadmium
ND
mg/kg
0.43
0.21
50
03/29/15 16:04
04/02/1516:09
7440-43-9
D3
Cobalt
13.6
mg/kg
3.5
1.8
50
03/29/15 16:04
03/31/1522:29
7440-48-4
D3
Lead
17.8
mg/kg
3.5
1.8
50
03/29/15 16:04
04/02/1516:09
7439-92-1
D3
Selenium
ND
mg/kg
3.5
1.8
50
03/29/15 16:04
04/02/1516:09
7782-49-2
D3
Thallium
ND
mg/kg
3.5
1.8
50
03/29/15 16:04
04/02/1516:09
7440-28-0
D3
Vanadium
63.6
mg/kg
3.5
1.8
50
03/29/15 16:04
03/31/1522:29
7440-62-2
D4
7471 Mercury
Analytical
Method: EPA 7471
Preparation
Method: EPA
7471
Mercury
ND
mg/kg
0.011
0.0053
1
03/31/1511:55
04/01/1513:50
7439-97-6
Percent Moisture
Analytical
Method: ASTM D2974-87
Percent Moisture
28.8
%
0.10
0.10
1
04/01/15 16:23
9045 pH Soil
Analytical
Method: EPA 9045
pH at 25 Degrees C
8.0
Std. Units
0.10
0.10
1
03/25/15 11:50
9056 IC Anions
Analytical
Method: EPA 9056
Chloride
ND
mg/kg
350
175
5
03/29/1514:04
16887-00-6
D3
Sulfate
ND
mg/kg
350
175
5
03/29/1514:04
14808-79-8
D3
9056 IC Anions 48hr
Analytical
Method: EPA 9056
Nitrate as N
ND
mg/kg
35.0
17.5
5
03/29/15 14:04
14797-55-8
D3,H3
Date: 04/08/2015 12:54 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 59 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
P3yy RVr6fY2'9e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J150305555
Pace Project No.: 92242381
Sample: 2015008004
Lab ID:
92242381010
Collected:
03/17/15 15:30
Received: 03/23/15 15:04 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample
size and any dilutions.
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared Analyzed
CAS No. Qual
Total Organic Carbon Quad
Analytical
Method: EPA 9060
Total Organic Carbon
16700
mg/kg
3390
1690
1
04/03/15 17:06
7440-44-0
Total Organic Carbon
18700
mg/kg
3440
1720
1
04/03/15 17:12
7440-44-0
Total Organic Carbon
17300
mg/kg
3500
1750
1
04/03/15 17:19
7440-44-0
Total Organic Carbon
25100
mg/kg
3450
1730
1
04/03/15 17:25
7440-44-0
Mean Total Organic Carbon
19400
mg/kg
3450
1720
1
04/03/15 17:06
7440-44-0
Surrogates
RSD%
19.8
%
1
04/03/15 17:06
Date: 04/08/2015 12:54 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 60 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
P36908 WY2'9 . Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J150305555
Pace Project No.: 92242381
Sample: 2015008005
Lab ID:
92242381011
Collected:
03/17/15 15:30
Received: 03/23/15 15:04 Matrix: Solid
Results reported on a "dry weight"
basis and are adjusted for percent moisture, sample
size and any dilutions.
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared
Analyzed
CAS No.
Qual
6010 MET ICP
Analytical
Method: EPA 6010
Preparation
Method: EPA
3050
Aluminum
13400
mg/kg
6.2
3.1
1
03/29/15 16:04
04/01/15 21:54
7429-90-5
Barium
96.9
mg/kg
0.62
0.31
1
03/29/15 16:04
04/01/15 21:54
7440-39-3
Beryllium
3.1
mg/kg
0.062
0.031
1
03/29/15 16:04
04/01/15 21:54
7440-41-7
Boron
36.4
mg/kg
3.1
1.6
1
03/29/15 16:04
04/01/15 21:54
7440-42-8
Calcium
1520
mg/kg
31.1
15.5
1
03/29/15 16:04
04/01/15 21:54
7440-70-2
Chromium
39.4
mg/kg
0.31
0.16
1
03/29/15 16:04
04/01/15 21:54
7440-47-3
Copper
40.6
mg/kg
0.31
0.16
1
03/29/15 16:04
04/01/15 21:54
7440-50-8
Iron
3320
mg/kg
2.5
1.2
1
03/29/15 16:04
04/01/15 21:54
7439-89-6
Magnesium
603
mg/kg
31.1
15.5
1
03/29/15 16:04
04/01/15 21:54
7439-95-4
Manganese
15.8
mg/kg
0.31
0.16
1
03/29/15 16:04
04/01/15 21:54
7439-96-5
Molybdenum
2.0
mg/kg
0.62
0.31
1
03/29/15 16:04
04/01/15 21:54
7439-98-7
Nickel
25.7
mg/kg
0.31
0.16
1
03/29/15 16:04
04/01/15 21:54
7440-02-0
Potassium
1560
mg/kg
62.1
31.1
1
03/29/15 16:04
04/01/15 21:54
7440-09-7
Sodium
158
mg/kg
62.1
31.1
1
03/29/15 16:04
04/01/15 21:54
7440-23-5
Strontium
78.8
mg/kg
0.62
0.31
1
03/29/15 16:04
04/01/15 21:54
7440-24-6
Zinc
39.0
mg/kg
1.2
0.62
1
03/29/15 16:04
04/01/15 21:54
7440-66-6
6020 MET ICPMS
Analytical
Method: EPA 6020
Preparation
Method: EPA
3050
Antimony
ND
mg/kg
3.1
1.6
50
03/29/15 16:04
04/02/1516:11
7440-36-0
N2
Arsenic
17.0
mg/kg
3.1
1.6
50
03/29/15 16:04
04/02/1516:11
7440-38-2
Cadmium
0.30J
mg/kg
0.37
0.19
50
03/29/15 16:04
04/02/1516:11
7440-43-9
Cobalt
19.7
mg/kg
3.1
1.6
50
03/29/15 16:04
03/31/1522:31
7440-48-4
D3
Lead
25.5
mg/kg
3.1
1.6
50
03/29/15 16:04
04/02/1516:11
7439-92-1
Selenium
ND
mg/kg
3.1
1.6
50
03/29/15 16:04
04/02/1516:11
7782-49-2
Thallium
ND
mg/kg
3.1
1.6
50
03/29/15 16:04
04/02/1516:11
7440-28-0
Vanadium
112
mg/kg
3.1
1.6
50
03/29/15 16:04
03/31/1522:31
7440-62-2
D4
7471 Mercury
Analytical
Method: EPA 7471 Preparation
Method: EPA
7471
Mercury
ND
mg/kg
0.010
0.0051
1
03/31/1511:55
04/01/1513:52
7439-97-6
Percent Moisture
Analytical
Method: ASTM
D2974-87
Percent Moisture
21.5
%
0.10
0.10
1
04/01/15 16:23
9045 pH Soil
Analytical
Method: EPA 9045
pH at 25 Degrees C
7.8
Std. Units
0.10
0.10
1
03/25/15 11:50
9056 IC Anions
Analytical
Method: EPA 9056
Chloride
ND
mg/kg
314
157
5
03/29/1514:25
16887-00-6
D3
Sulfate
ND
mg/kg
314
157
5
03/29/1514:25
14808-79-8
D3
9056 IC Anions 48hr
Analytical
Method: EPA 9056
Nitrate as N
ND
mg/kg
31.4
15.7
5
03/29/15 14:25
14797-55-8
D3,H3
Date: 04/08/2015 12:54 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 61 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
P3Sy Mr6fY2'9e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J150305555
Pace Project No.: 92242381
Sample: 2015008005
Lab ID:
92242381011
Collected:
03/17/15 15:30
Received: 03/23/15 15:04 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample
size and any dilutions.
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared Analyzed
CAS No. Qual
Total Organic Carbon Quad
Analytical
Method: EPA 9060
Total Organic Carbon
22500
mg/kg
3700
1850
1
04/06/15 07:40
7440-44-0
Total Organic Carbon
12400
mg/kg
3730
1860
1
04/06/15 07:46
7440-44-0
Total Organic Carbon
19200
mg/kg
3790
1890
1
04/06/15 07:52
7440-44-0
Total Organic Carbon
14200
mg/kg
3780
1890
1
04/06/15 07:57
7440-44-0
Mean Total Organic Carbon
17100
mg/kg
3750
1870
1
04/06/15 07:40
7440-44-0
Surrogates
RSD%
27.1
%
1
04/06/15 07:40
Date: 04/08/2015 12:54 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 62 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
P369% r6fY2'9e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J150305555
Pace Project No.: 92242381
Sample: 2015008006
Lab ID:
92242381012
Collected:
03/19/15 09:20
Received: 03/23/15 15:04 Matrix: Solid
Results reported on a "dry weight"
basis and are adjusted for percent moisture, sample
size and any dilutions.
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared
Analyzed
CAS No.
Qual
6010 MET ICP
Analytical
Method: EPA 6010
Preparation
Method: EPA
3050
Aluminum
859
mg/kg
6.2
3.1
1
03/29/15 16:04
04/01/15 21:58
7429-90-5
Barium
38.6
mg/kg
0.62
0.31
1
03/29/15 16:04
04/01/15 21:58
7440-39-3
Beryllium
0.26
mg/kg
0.062
0.031
1
03/29/15 16:04
04/01/15 21:58
7440-41-7
Boron
ND
mg/kg
3.1
1.5
1
03/29/15 16:04
04/01/15 21:58
7440-42-8
Calcium
248
mg/kg
30.8
15.4
1
03/29/15 16:04
04/01/15 21:58
7440-70-2
Chromium
2.2
mg/kg
0.31
0.15
1
03/29/15 16:04
04/01/15 21:58
7440-47-3
Copper
4.8
mg/kg
0.31
0.15
1
03/29/15 16:04
04/01/15 21:58
7440-50-8
Iron
1100
mg/kg
2.5
1.2
1
03/29/15 16:04
04/01/15 21:58
7439-89-6
Magnesium
65.1
mg/kg
30.8
15.4
1
03/29/15 16:04
04/01/15 21:58
7439-95-4
Manganese
17.7
mg/kg
0.31
0.15
1
03/29/15 16:04
04/01/15 21:58
7439-96-5
Molybdenum
0.42J
mg/kg
0.62
0.31
1
03/29/15 16:04
04/01/15 21:58
7439-98-7
Nickel
3.3
mg/kg
0.31
0.15
1
03/29/15 16:04
04/01/15 21:58
7440-02-0
Potassium
116
mg/kg
61.5
30.8
1
03/29/15 16:04
04/01/15 21:58
7440-09-7
Sodium
ND
mg/kg
61.5
30.8
1
03/29/15 16:04
04/01/15 21:58
7440-23-5
Strontium
11.0
mg/kg
0.62
0.31
1
03/29/15 16:04
04/01/15 21:58
7440-24-6
Zinc
4.5
mg/kg
1.2
0.62
1
03/29/15 16:04
04/01/15 21:58
7440-66-6
6020 MET ICPMS
Analytical
Method: EPA 6020
Preparation
Method: EPA
3050
Antimony
ND
mg/kg
3.1
1.5
50
03/29/15 16:04
04/02/1516:13
7440-36-0
N2
Arsenic
ND
mg/kg
3.1
1.5
50
03/29/15 16:04
04/02/1516:13
7440-38-2
Cadmium
ND
mg/kg
0.37
0.18
50
03/29/15 16:04
04/02/1516:13
7440-43-9
Cobalt
ND
mg/kg
3.1
1.5
50
03/29/15 16:04
03/31/1522:33
7440-48-4
D3
Lead
ND
mg/kg
3.1
1.5
50
03/29/15 16:04
04/02/1516:13
7439-92-1
Selenium
ND
mg/kg
3.1
1.5
50
03/29/15 16:04
04/02/1516:13
7782-49-2
Thallium
ND
mg/kg
3.1
1.5
50
03/29/15 16:04
04/02/1516:13
7440-28-0
Vanadium
2.7J
mg/kg
3.1
1.5
50
03/29/15 16:04
03/31/1522:33
7440-62-2
D3
7471 Mercury
Analytical
Method: EPA 7471 Preparation
Method: EPA
7471
Mercury
ND
mg/kg
0.0096
0.0048
1
03/31/1511:55
04/01/1513:54
7439-97-6
Percent Moisture
Analytical
Method: ASTM
D2974-87
Percent Moisture
19.9
%
0.10
0.10
1
04/01/15 16:24
9045 pH Soil
Analytical
Method: EPA 9045
pH at 25 Degrees C
6.2
Std. Units
0.10
0.10
1
03/30/15 12:55
9056 IC Anions
Analytical
Method: EPA 9056
Chloride
ND
mg/kg
311
156
5
03/29/1514:47
16887-00-6
D3
Sulfate
ND
mg/kg
311
156
5
03/29/1514:47
14808-79-8
D3
9056 IC Anions 48hr
Analytical
Method: EPA 9056
Nitrate as N
ND
mg/kg
31.1
15.6
5
03/29/15 14:47
14797-55-8
H3
Date: 04/08/2015 12:54 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 63 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
P3y M'ir6fY2'9e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J150305555
Pace Project No.: 92242381
Sample: 2015008006
Lab ID:
92242381012
Collected:
03/19/15 09:20
Received: 03/23/15 15:04 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample
size and any dilutions.
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared Analyzed
CAS No. Qual
Total Organic Carbon Quad
Analytical
Method: EPA 9060
Total Organic Carbon
14300
mg/kg
747
374
1
04/06/15 08:49
7440-44-0
Total Organic Carbon
9190
mg/kg
748
374
1
04/06/15 08:55
7440-44-0
Total Organic Carbon
11400
mg/kg
757
378
1
04/06/15 09:00
7440-44-0
Total Organic Carbon
8370
mg/kg
745
372
1
04/06/15 09:06
7440-44-0
Mean Total Organic Carbon
10800
mg/kg
749
375
1
04/06/15 08:49
7440-44-0
Surrogates
RSD%
24.6
%
1
04/06/15 08:49
Date: 04/08/2015 12:54 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 64 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
P369W6fY2'9e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J150305555
Pace Project No.: 92242381
Sample: 2015008008
Lab ID:
92242381013
Collected:
03/19/15 12:40
Received: 03/23/15 15:04 Matrix: Solid
Results reported on a "dry weight"
basis and are adjusted for percent moisture, sample
size and any dilutions.
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared
Analyzed
CAS No.
Qual
6010 MET ICP
Analytical
Method: EPA 6010
Preparation
Method: EPA
3050
Aluminum
3530
mg/kg
7.7
3.9
1
03/29/15 16:04
04/01/15 22:14
7429-90-5
Barium
34.6
mg/kg
0.77
0.39
1
03/29/15 16:04
04/01/15 22:14
7440-39-3
Beryllium
0.96
mg/kg
0.077
0.039
1
03/29/15 16:04
04/01/15 22:14
7440-41-7
Boron
9.2
mg/kg
3.9
1.9
1
03/29/15 16:04
04/01/15 22:14
7440-42-8
Calcium
517
mg/kg
38.7
19.3
1
03/29/15 16:04
04/01/15 22:14
7440-70-2
Chromium
10.6
mg/kg
0.39
0.19
1
03/29/15 16:04
04/01/15 22:14
7440-47-3
Copper
12.1
mg/kg
0.39
0.19
1
03/29/15 16:04
04/01/15 22:14
7440-50-8
Iron
2230
mg/kg
3.1
1.5
1
03/29/15 16:04
04/01/15 22:14
7439-89-6
Magnesium
206
mg/kg
38.7
19.3
1
03/29/15 16:04
04/01/15 22:14
7439-95-4
Manganese
9.4
mg/kg
0.39
0.19
1
03/29/15 16:04
04/01/15 22:14
7439-96-5
Molybdenum
0.551
mg/kg
0.77
0.39
1
03/29/15 16:04
04/01/15 22:14
7439-98-7
Nickel
7.0
mg/kg
0.39
0.19
1
03/29/15 16:04
04/01/15 22:14
7440-02-0
Potassium
436
mg/kg
77.3
38.7
1
03/29/15 16:04
04/01/15 22:14
7440-09-7
Sodium
53.9J
mg/kg
77.3
38.7
1
03/29/15 16:04
04/01/15 22:14
7440-23-5
Strontium
19.5
mg/kg
0.77
0.39
1
03/29/15 16:04
04/01/15 22:14
7440-24-6
Zinc
8.5
mg/kg
1.5
0.77
1
03/29/15 16:04
04/01/15 22:14
7440-66-6
6020 MET ICPMS
Analytical
Method: EPA 6020
Preparation
Method: EPA
3050
Antimony
ND
mg/kg
3.9
1.9
50
03/29/15 16:04
04/02/1516:15
7440-36-0
N2
Arsenic
2.9J
mg/kg
3.9
1.9
50
03/29/15 16:04
04/02/1516:15
7440-38-2
Cadmium
ND
mg/kg
0.46
0.23
50
03/29/15 16:04
04/02/1516:15
7440-43-9
Cobalt
4.2
mg/kg
3.9
1.9
50
03/29/15 16:04
03/31/1522:35
7440-48-4
D3
Lead
4.8
mg/kg
3.9
1.9
50
03/29/15 16:04
04/02/1516:15
7439-92-1
Selenium
ND
mg/kg
3.9
1.9
50
03/29/15 16:04
04/02/1516:15
7782-49-2
Thallium
ND
mg/kg
3.9
1.9
50
03/29/15 16:04
04/02/1516:15
7440-28-0
Vanadium
19.0
mg/kg
3.9
1.9
50
03/29/15 16:04
03/31/1522:35
7440-62-2
D3
7471 Mercury
Analytical
Method: EPA 7471 Preparation
Method: EPA
7471
Mercury
ND
mg/kg
0.012
0.0062
1
03/31/1511:55
04/01/1514:00
7439-97-6
Percent Moisture
Analytical
Method: ASTM
D2974-87
Percent Moisture
34.2
%
0.10
0.10
1
04/01/15 16:24
9045 pH Soil
Analytical
Method: EPA 9045
pH at 25 Degrees C
7.2
Std. Units
0.10
0.10
1
03/30/15 12:55
9056 IC Anions
Analytical
Method: EPA 9056
Chloride
ND
mg/kg
379
190
5
03/29/1515:08
16887-00-6
D3
Sulfate
ND
mg/kg
379
190
5
03/29/1515:08
14808-79-8
D3
9056 IC Anions 48hr
Analytical
Method: EPA 9056
Nitrate as N
ND
mg/kg
37.9
19.0
5
03/29/15 15:08
14797-55-8
D3,H3
Date: 04/08/2015 12:54 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 65 of 104

aceAnaiXical
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Pace Analytical Services, Inc.
P3y RVr6fY2'9e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J150305555
Pace Project No.: 92242381
Sample: 2015008008
Lab ID:
92242381013
Collected:
03/19/15 12:40
Received: 03/23/15 15:04 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample
size and any dilutions.
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared Analyzed
CAS No. Qual
Total Organic Carbon Quad
Analytical
Method: EPA 9060
Total Organic Carbon
14400
mg/kg
1800
898
1
04/06/15 09:11
7440-44-0
Total Organic Carbon
18800
mg/kg
1820
911
1
04/06/15 09:18
7440-44-0
Total Organic Carbon
23100
mg/kg
1820
908
1
04/06/15 09:23
7440-44-0
Total Organic Carbon
15800
mg/kg
1810
907
1
04/06/15 09:30
7440-44-0
Mean Total Organic Carbon
18000
mg/kg
1810
906
1
04/06/15 09:11
7440-44-0
Surrogates
RSD%
21.3
%
1
04/06/15 09:11
Date: 04/08/2015 12:54 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 66 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
P369Vr6fY2'9e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J150305555
Pace Project No.: 92242381
Sample: 2015008009 Lab ID: 92242381014 Collected: 03/19/15 09:00 Received: 03/23/15 15:04 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
;I➢ZI7c\�i,I=11 l[99�r 6?
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Sodium
Strontium
Thallium
Vanadium
Zinc
7470 Mercury
Mercury
Date: 04/08/2015 12:54 PM
Analytical Method: EPA 6020A Preparation Method: EPA 3020
ND
ug/L
10.0
1.2
1
03/27/1512:25
03/28/1515:37
7429-90-5
ND
ug/L
0.50
0.25
1
03/27/1512:25
03/28/1515:37
7440-36-0
ND
ug/L
0.50
0.25
1
03/27/1512:25
03/28/1515:37
7440-38-2
0.44
ug/L
0.30
0.14
1
03/27/1512:25
03/28/1515:37
7440-39-3
ND
ug/L
0.20
0.066
1
03/27/1512:25
03/28/1515:37
7440-41-7
ND
ug/L
5.0
1.0
1
03/27/1512:25
03/28/1515:37
7440-42-8
ND
ug/L
0.080
0.033
1
03/27/1512:25
03/28/1515:37
7440-43-9
ND
ug/L
40.0
8.4
1
03/27/1512:25
03/28/1515:37
7440-70-2
1.5
ug/L
0.50
0.22
1
03/27/1512:25
03/28/1515:37
7440-47-3
ND
ug/L
0.50
0.25
1
03/27/1512:25
03/28/1515:37
7440-48-4
ND
ug/L
1.0
0.22
1
03/27/1512:25
03/28/1515:37
7440-50-8
93.2
ug/L
50.0
8.0
1
03/27/1512:25
03/28/1515:37
7439-89-6
ND
ug/L
0.10
0.046
1
03/27/1512:25
03/28/1515:37
7439-92-1
ND
ug/L
10.0
2.8
1
03/27/1512:25
03/28/1515:37
7439-95-4
1.2
ug/L
0.50
0.14
1
03/27/1512:25
03/28/1515:37
7439-96-5
ND
ug/L
0.50
0.24
1
03/27/1512:25
03/28/1515:37
7439-98-7
ND
ug/L
0.50
0.23
1
03/27/1512:25
03/28/1515:37
7440-02-0
ND
ug/L
50.0
8.3
1
03/27/1512:25
03/28/1515:37
7440-09-7
ND
ug/L
0.50
0.25
1
03/27/1512:25
03/28/1515:37
7782-49-2
ND
ug/L
50.0
18.2
1
03/27/1512:25
03/28/1515:37
7440-23-5
ND
ug/L
0.50
0.057
1
03/27/1512:25
03/28/1515:37
7440-24-6
ND
ug/L
0.10
0.025
1
03/27/1512:25
03/28/1515:37
7440-28-0
ND
ug/L
1.0
0.21
1
03/27/1512:25
03/28/1515:37
7440-62-2
ND
ug/L
5.0
2.5
1
03/27/1512:25
03/28/1515:37
7440-66-6
Analytical Method: EPA 7470 Preparation Method: EPA 7470
ND ug/L 0.20 0.026 1 03/28/1513:55 03/30/1510:53 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 67 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
P369O9r6fY2'9e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J150305555
Pace Project No.: 92242381
Sample: 2015008010 Lab ID: 92242381015 Collected: 03/18/15 08:50 Received: 03/23/15 15:04 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
;I➢ZI7c\ri,I=11 l[99�r 6?
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Sodium
Strontium
Thallium
Vanadium
Zinc
7470 Mercury
Mercury
Date: 04/08/2015 12:54 PM
Analytical Method: EPA 6020A Preparation Method: EPA 3020
ND
ug/L
10.0
1.2
1
03/27/1512:25
03/28/1515:40
7429-90-5
ND
ug/L
0.50
0.25
1
03/27/1512:25
03/28/1515:40
7440-36-0
ND
ug/L
0.50
0.25
1
03/27/1512:25
03/28/1515:40
7440-38-2
ND
ug/L
0.30
0.14
1
03/27/1512:25
03/28/1515:40
7440-39-3
ND
ug/L
0.20
0.066
1
03/27/1512:25
03/28/1515:40
7440-41-7
ND
ug/L
5.0
1.0
1
03/27/1512:25
03/28/1515:40
7440-42-8
ND
ug/L
0.080
0.033
1
03/27/1512:25
03/28/1515:40
7440-43-9
46.3
ug/L
40.0
8.4
1
03/27/1512:25
03/28/1515:40
7440-70-2
0.60
ug/L
0.50
0.22
1
03/27/1512:25
03/28/1515:40
7440-47-3
ND
ug/L
0.50
0.25
1
03/27/1512:25
03/28/1515:40
7440-48-4
ND
ug/L
1.0
0.22
1
03/27/1512:25
03/28/1515:40
7440-50-8
ND
ug/L
50.0
8.0
1
03/27/1512:25
03/28/1515:40
7439-89-6
ND
ug/L
0.10
0.046
1
03/27/1512:25
03/28/1515:40
7439-92-1
ND
ug/L
10.0
2.8
1
03/27/1512:25
03/28/1515:40
7439-95-4
1.3
ug/L
0.50
0.14
1
03/27/1512:25
03/28/1515:40
7439-96-5
ND
ug/L
0.50
0.24
1
03/27/1512:25
03/28/1515:40
7439-98-7
ND
ug/L
0.50
0.23
1
03/27/1512:25
03/28/1515:40
7440-02-0
ND
ug/L
50.0
8.3
1
03/27/1512:25
03/28/1515:40
7440-09-7
ND
ug/L
0.50
0.25
1
03/27/1512:25
03/28/1515:40
7782-49-2
ND
ug/L
50.0
18.2
1
03/27/1512:25
03/28/1515:40
7440-23-5
ND
ug/L
0.50
0.057
1
03/27/1512:25
03/28/1515:40
7440-24-6
ND
ug/L
0.10
0.025
1
03/27/1512:25
03/28/1515:40
7440-28-0
ND
ug/L
1.0
0.21
1
03/27/1512:25
03/28/1515:40
7440-62-2
ND
ug/L
5.0
2.5
1
03/27/1512:25
03/28/1515:40
7440-66-6
Analytical Method: EPA 7470 Preparation Method: EPA 7470
ND ug/L 0.20 0.026 1 03/28/1513:55 03/30/1510:56 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 68 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
P3Sy Mr6fY2'9e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J150305555
Pace Project No.: 92242381
Sample: 2015008011 Lab ID: 92242381016 Collected: 03/17/15 12:35 Received: 03/23/15 15:04 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
;I➢ZI7c\ri,I=11 l[99�r 6?
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Sodium
Strontium
Thallium
Vanadium
Zinc
7470 Mercury
Mercury
Date: 04/08/2015 12:54 PM
Analytical Method: EPA 6020A Preparation Method: EPA 3020
ND
ug/L
10.0
1.2
1
03/27/1512:25
03/28/1515:43
7429-90-5
ND
ug/L
0.50
0.25
1
03/27/1512:25
03/28/1515:43
7440-36-0
ND
ug/L
0.50
0.25
1
03/27/1512:25
03/28/1515:43
7440-38-2
1.8
ug/L
0.30
0.14
1
03/27/1512:25
03/28/1515:43
7440-39-3
ND
ug/L
0.20
0.066
1
03/27/1512:25
03/28/1515:43
7440-41-7
ND
ug/L
5.0
1.0
1
03/27/1512:25
03/28/1515:43
7440-42-8
ND
ug/L
0.080
0.033
1
03/27/1512:25
03/28/1515:43
7440-43-9
85.2
ug/L
40.0
8.4
1
03/27/1512:25
03/28/1515:43
7440-70-2
2.7
ug/L
0.50
0.22
1
03/27/1512:25
03/28/1515:43
7440-47-3
ND
ug/L
0.50
0.25
1
03/27/1512:25
03/28/1515:43
7440-48-4
ND
ug/L
1.0
0.22
1
03/27/1512:25
03/28/1515:43
7440-50-8
169
ug/L
50.0
8.0
1
03/27/1512:25
03/28/1515:43
7439-89-6
ND
ug/L
0.10
0.046
1
03/27/1512:25
03/28/1515:43
7439-92-1
12.0
ug/L
10.0
2.8
1
03/27/1512:25
03/28/1515:43
7439-95-4
4.3
ug/L
0.50
0.14
1
03/27/1512:25
03/28/1515:43
7439-96-5
0.95
ug/L
0.50
0.24
1
03/27/1512:25
03/28/1515:43
7439-98-7
1.1
ug/L
0.50
0.23
1
03/27/1512:25
03/28/1515:43
7440-02-0
ND
ug/L
50.0
8.3
1
03/27/1512:25
03/28/1515:43
7440-09-7
ND
ug/L
0.50
0.25
1
03/27/1512:25
03/28/1515:43
7782-49-2
ND
ug/L
50.0
18.2
1
03/27/1512:25
03/28/1515:43
7440-23-5
0.59
ug/L
0.50
0.057
1
03/27/1512:25
03/28/1515:43
7440-24-6
ND
ug/L
0.10
0.025
1
03/27/1512:25
03/28/1515:43
7440-28-0
ND
ug/L
1.0
0.21
1
03/27/1512:25
03/28/1515:43
7440-62-2
ND
ug/L
5.0
2.5
1
03/27/1512:25
03/28/1515:43
7440-66-6
Analytical Method: EPA 7470 Preparation Method: EPA 7470
ND ug/L 0.20 0.026 1 03/28/1513:55 03/30/1510:58 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 69 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
P3yy RVr6fY2'9e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J150305555
Pace Project No.: 92242381
Sample: 2015008012 Lab ID: 92242381017 Collected: 03/18/15 16:00 Received: 03/23/15 15:04 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
;I➢ZI7c\ri,I=11 l[99�r 6?
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Sodium
Strontium
Thallium
Vanadium
Zinc
7470 Mercury
Mercury
Date: 04/08/2015 12:54 PM
Analytical Method: EPA 6020A Preparation Method: EPA 3020
ND
ug/L
10.0
1.2
1
03/27/1512:25
03/28/1515:46
7429-90-5
ND
ug/L
0.50
0.25
1
03/27/1512:25
03/28/1515:46
7440-36-0
ND
ug/L
0.50
0.25
1
03/27/1512:25
03/28/1515:46
7440-38-2
0.40
ug/L
0.30
0.14
1
03/27/1512:25
03/28/1515:46
7440-39-3
ND
ug/L
0.20
0.066
1
03/27/1512:25
03/28/1515:46
7440-41-7
ND
ug/L
5.0
1.0
1
03/27/1512:25
03/28/1515:46
7440-42-8
ND
ug/L
0.080
0.033
1
03/27/1512:25
03/28/1515:46
7440-43-9
124
ug/L
40.0
8.4
1
03/27/1512:25
03/28/1515:46
7440-70-2
1.6
ug/L
0.50
0.22
1
03/27/1512:25
03/28/1515:46
7440-47-3
ND
ug/L
0.50
0.25
1
03/27/1512:25
03/28/1515:46
7440-48-4
ND
ug/L
1.0
0.22
1
03/27/1512:25
03/28/1515:46
7440-50-8
66.4
ug/L
50.0
8.0
1
03/27/1512:25
03/28/1515:46
7439-89-6
ND
ug/L
0.10
0.046
1
03/27/1512:25
03/28/1515:46
7439-92-1
14.6
ug/L
10.0
2.8
1
03/27/1512:25
03/28/1515:46
7439-95-4
3.1
ug/L
0.50
0.14
1
03/27/1512:25
03/28/1515:46
7439-96-5
0.88
ug/L
0.50
0.24
1
03/27/1512:25
03/28/1515:46
7439-98-7
ND
ug/L
0.50
0.23
1
03/27/1512:25
03/28/1515:46
7440-02-0
ND
ug/L
50.0
8.3
1
03/27/1512:25
03/28/1515:46
7440-09-7
ND
ug/L
0.50
0.25
1
03/27/1512:25
03/28/1515:46
7782-49-2
94.2
ug/L
50.0
18.2
1
03/27/1512:25
03/28/1515:46
7440-23-5
0.53
ug/L
0.50
0.057
1
03/27/1512:25
03/28/1515:46
7440-24-6
ND
ug/L
0.10
0.025
1
03/27/1512:25
03/28/1515:46
7440-28-0
ND
ug/L
1.0
0.21
1
03/27/1512:25
03/28/1515:46
7440-62-2
ND
ug/L
5.0
2.5
1
03/27/1512:25
03/28/1515:46
7440-66-6
Analytical Method: EPA 7470 Preparation Method: EPA 7470
ND ug/L 0.20 0.026 1 03/28/1513:55 03/30/1511:01 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 70 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
P369Vir6fY2'9e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J150305555
Pace Project No.: 92242381
Sample: 2015007996 SPLP Lab ID: 92242381018 Collected: 03/18/15 15:35 Received: 03/23/15 15:04 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
;T➢Z17c\riil=11 a
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Sodium
Strontium
Thallium
Vanadium
Zinc
7470 Mercury
Mercury
Date: 04/08/2015 12:54 PM
Analytical Method: EPA 6020A Preparation Method: EPA 3020
152
ug/L
10.0
3.0
1
04/03/15 12:52
04/06/15 08:53
7429-90-5
5.0
ug/L
0.50
0.15
1
04/03/15 12:52
04/06/15 08:53
7440-36-0
3.5
ug/L
0.50
0.11
1
04/03/15 12:52
04/06/15 08:53
7440-38-2
308
ug/L
0.30
0.081
1
04/03/15 12:52
04/06/15 08:53
7440-39-3
ND
ug/L
0.20
0.067
1
04/03/15 12:52
04/06/15 08:53
7440-41-7
119
ug/L
5.0
1.1
1
04/03/15 12:52
04/06/15 08:53
7440-42-8
ND
ug/L
0.080
0.024
1
04/03/15 12:52
04/06/15 08:53
7440-43-9
3060
ug/L
40.0
16.0
1
04/03/15 12:52
04/06/15 08:53
7440-70-2
1.8
ug/L
0.50
0.17
1
04/03/15 12:52
04/06/15 08:53
7440-47-3
0.89
ug/L
0.50
0.13
1
04/03/15 12:52
04/06/15 08:53
7440-48-4
3.0
ug/L
1.0
0.21
1
04/03/15 12:52
04/06/15 08:53
7440-50-8
ND
ug/L
50.0
13.7
1
04/03/15 12:52
04/06/15 08:53
7439-89-6
0.73
ug/L
0.10
0.046
1
04/03/15 12:52
04/06/15 08:53
7439-92-1
688
ug/L
10.0
3.2
1
04/03/15 12:52
04/06/15 08:53
7439-95-4
148
ug/L
0.50
0.24
1
04/03/15 12:52
04/06/15 08:53
7439-96-5
2.2
ug/L
0.50
0.094
1
04/03/15 12:52
04/06/15 08:53
7439-98-7
4.4
ug/L
0.50
0.16
1
04/03/15 12:52
04/06/15 08:53
7440-02-0
643
ug/L
50.0
11.7
1
04/03/15 12:52
04/06/15 08:53
7440-09-7
1.9
ug/L
0.50
0.20
1
04/03/15 12:52
04/06/15 08:53
7782-49-2
2110
ug/L
50.0
16.3
1
04/03/15 12:52
04/06/15 08:53
7440-23-5
37.2
ug/L
0.50
0.13
1
04/03/15 12:52
04/06/15 08:53
7440-24-6
0.11
ug/L
0.10
0.015
1
04/03/15 12:52
04/06/15 08:53
7440-28-0
72.6
ug/L
1.0
0.28
1
04/03/15 12:52
04/06/15 08:53
7440-62-2
159
ug/L
5.0
2.4
1
04/03/15 12:52
04/06/15 08:53
7440-66-6
Analytical Method: EPA 7470 Preparation Method: EPA 7470
ND ug/L 0.20 0.022 1 04/04/1517:20 04/06/1519:07 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 71 of 104

aceAnaiXical
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Pace Analytical Services, Inc.
P3y 906r6fY2'9e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J150305555
Pace Project No.: 92242381
Sample: 2015007999 SPLP Lab ID: 92242381019 Collected: 03/17/15 15:45 Received: 03/23/15 15:04 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
;T➢Z17c\riil=11 a
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Sodium
Strontium
Thallium
Vanadium
Zinc
7470 Mercury
Mercury
Date: 04/08/2015 12:54 PM
Analytical Method: EPA 6020A Preparation Method: EPA 3020
330
ug/L
10.0
3.0
1
04/03/15 12:52
04/06/15 08:58
7429-90-5
3.4
ug/L
0.50
0.15
1
04/03/15 12:52
04/06/15 08:58
7440-36-0
27.0
ug/L
0.50
0.11
1
04/03/15 12:52
04/06/15 08:58
7440-38-2
346
ug/L
0.30
0.081
1
04/03/15 12:52
04/06/15 08:58
7440-39-3
ND
ug/L
0.20
0.067
1
04/03/15 12:52
04/06/15 08:58
7440-41-7
208
ug/L
25.0
5.6
5
04/03/15 12:52
04/06/1510:26
7440-42-8
ND
ug/L
0.080
0.024
1
04/03/15 12:52
04/06/15 08:58
7440-43-9
2940
ug/L
40.0
16.0
1
04/03/15 12:52
04/06/15 08:58
7440-70-2
1.3
ug/L
0.50
0.17
1
04/03/15 12:52
04/06/15 08:58
7440-47-3
ND
ug/L
0.50
0.13
1
04/03/15 12:52
04/06/15 08:58
7440-48-4
8.0
ug/L
1.0
0.21
1
04/03/15 12:52
04/06/15 08:58
7440-50-8
ND
ug/L
50.0
13.7
1
04/03/15 12:52
04/06/15 08:58
7439-89-6
0.68
ug/L
0.10
0.046
1
04/03/15 12:52
04/06/15 08:58
7439-92-1
617
ug/L
10.0
3.2
1
04/03/15 12:52
04/06/15 08:58
7439-95-4
19.5
ug/L
0.50
0.24
1
04/03/15 12:52
04/06/15 08:58
7439-96-5
6.6
ug/L
0.50
0.094
1
04/03/15 12:52
04/06/15 08:58
7439-98-7
0.76
ug/L
0.50
0.16
1
04/03/15 12:52
04/06/15 08:58
7440-02-0
1040
ug/L
50.0
11.7
1
04/03/15 12:52
04/06/15 08:58
7440-09-7
ND
ug/L
0.50
0.20
1
04/03/15 12:52
04/06/15 08:58
7782-49-2
1590
ug/L
50.0
16.3
1
04/03/15 12:52
04/06/15 08:58
7440-23-5
89.0
ug/L
0.50
0.13
1
04/03/15 12:52
04/06/15 08:58
7440-24-6
ND
ug/L
0.10
0.015
1
04/03/15 12:52
04/06/15 08:58
7440-28-0
120
ug/L
1.0
0.28
1
04/03/15 12:52
04/06/15 08:58
7440-62-2
157
ug/L
5.0
2.4
1
04/03/15 12:52
04/06/15 08:58
7440-66-6
Analytical Method: EPA 7470 Preparation Method: EPA 7470
ND ug/L 0.20 0.022 1 04/04/1517:20 04/06/1519:10 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 72 of 104

aceAnaiXical
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Pace Analytical Services, Inc.
P3y 906r6fY2'9e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J150305555
Pace Project No.: 92242381
Sample: 2015008002 SPLP Lab ID: 92242381020 Collected: 03/18/15 12:20 Received: 03/23/15 15:04 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
;T➢Z17c\riil=11 a
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Sodium
Strontium
Thallium
Vanadium
Zinc
7470 Mercury
Mercury
Date: 04/08/2015 12:54 PM
Analytical Method: EPA 6020A Preparation Method: EPA 3020
122
ug/L
10.0
3.0
1
04/03/15 12:52
04/06/15 09:03
7429-90-5
ND
ug/L
0.50
0.15
1
04/03/15 12:52
04/06/15 09:03
7440-36-0
1.1
ug/L
0.50
0.11
1
04/03/15 12:52
04/06/15 09:03
7440-38-2
303
ug/L
0.30
0.081
1
04/03/15 12:52
04/06/15 09:03
7440-39-3
ND
ug/L
0.20
0.067
1
04/03/15 12:52
04/06/15 09:03
7440-41-7
133
ug/L
5.0
1.1
1
04/03/15 12:52
04/06/15 09:03
7440-42-8
ND
ug/L
0.080
0.024
1
04/03/15 12:52
04/06/15 09:03
7440-43-9
5870
ug/L
40.0
16.0
1
04/03/15 12:52
04/06/15 09:03
7440-70-2
2.4
ug/L
0.50
0.17
1
04/03/15 12:52
04/06/15 09:03
7440-47-3
0.54
ug/L
0.50
0.13
1
04/03/15 12:52
04/06/15 09:03
7440-48-4
2.9
ug/L
1.0
0.21
1
04/03/15 12:52
04/06/15 09:03
7440-50-8
ND
ug/L
50.0
13.7
1
04/03/15 12:52
04/06/15 09:03
7439-89-6
0.73
ug/L
0.10
0.046
1
04/03/15 12:52
04/06/15 09:03
7439-92-1
455
ug/L
10.0
3.2
1
04/03/15 12:52
04/06/15 09:03
7439-95-4
53.7
ug/L
0.50
0.24
1
04/03/15 12:52
04/06/15 09:03
7439-96-5
9.2
ug/L
0.50
0.094
1
04/03/15 12:52
04/06/15 09:03
7439-98-7
2.2
ug/L
0.50
0.16
1
04/03/15 12:52
04/06/15 09:03
7440-02-0
679
ug/L
50.0
11.7
1
04/03/15 12:52
04/06/15 09:03
7440-09-7
ND
ug/L
0.50
0.20
1
04/03/15 12:52
04/06/15 09:03
7782-49-2
1750
ug/L
50.0
16.3
1
04/03/15 12:52
04/06/15 09:03
7440-23-5
39.2
ug/L
0.50
0.13
1
04/03/15 12:52
04/06/15 09:03
7440-24-6
ND
ug/L
0.10
0.015
1
04/03/15 12:52
04/06/15 09:03
7440-28-0
2.5
ug/L
1.0
0.28
1
04/03/15 12:52
04/06/15 09:03
7440-62-2
160
ug/L
5.0
2.4
1
04/03/15 12:52
04/06/15 09:03
7440-66-6
Analytical Method: EPA 7470 Preparation Method: EPA 7470
ND ug/L 0.20 0.022 1 04/04/1517:20 04/06/1519:12 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 73 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
P3y 90A"6fY2'9e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J150305555
Pace Project No.: 92242381
Sample: 2015008007 SPLP Lab ID: 92242381021 Collected: 03/18/15 12:30 Received: 03/23/15 15:04 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
;T➢Z17c\�iil=11 a
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Sodium
Strontium
Thallium
Vanadium
Zinc
7470 Mercury
Mercury
Date: 04/08/2015 12:54 PM
Analytical Method: EPA 6020A Preparation Method: EPA 3020
252
ug/L
10.0
3.0
1
04/03/15 12:52
04/06/15 09:08
7429-90-5
7.1
ug/L
0.50
0.15
1
04/03/15 12:52
04/06/15 09:08
7440-36-0
11.9
ug/L
0.50
0.11
1
04/03/15 12:52
04/06/15 09:08
7440-38-2
285
ug/L
0.30
0.081
1
04/03/15 12:52
04/06/15 09:08
7440-39-3
ND
ug/L
0.20
0.067
1
04/03/15 12:52
04/06/15 09:08
7440-41-7
127
ug/L
5.0
1.1
1
04/03/15 12:52
04/06/15 09:08
7440-42-8
ND
ug/L
0.080
0.024
1
04/03/15 12:52
04/06/15 09:08
7440-43-9
4500
ug/L
40.0
16.0
1
04/03/15 12:52
04/06/15 09:08
7440-70-2
1.6
ug/L
0.50
0.17
1
04/03/15 12:52
04/06/15 09:08
7440-47-3
0.92
ug/L
0.50
0.13
1
04/03/15 12:52
04/06/15 09:08
7440-48-4
4.6
ug/L
1.0
0.21
1
04/03/15 12:52
04/06/15 09:08
7440-50-8
ND
ug/L
50.0
13.7
1
04/03/15 12:52
04/06/15 09:08
7439-89-6
0.89
ug/L
0.10
0.046
1
04/03/15 12:52
04/06/15 09:08
7439-92-1
475
ug/L
10.0
3.2
1
04/03/15 12:52
04/06/15 09:08
7439-95-4
43.0
ug/L
0.50
0.24
1
04/03/15 12:52
04/06/15 09:08
7439-96-5
4.3
ug/L
0.50
0.094
1
04/03/15 12:52
04/06/15 09:08
7439-98-7
2.0
ug/L
0.50
0.16
1
04/03/15 12:52
04/06/15 09:08
7440-02-0
657
ug/L
50.0
11.7
1
04/03/15 12:52
04/06/15 09:08
7440-09-7
1.5
ug/L
0.50
0.20
1
04/03/15 12:52
04/06/15 09:08
7782-49-2
1600
ug/L
50.0
16.3
1
04/03/15 12:52
04/06/15 09:08
7440-23-5
50.8
ug/L
0.50
0.13
1
04/03/15 12:52
04/06/15 09:08
7440-24-6
0.23
ug/L
0.10
0.015
1
04/03/15 12:52
04/06/15 09:08
7440-28-0
134
ug/L
1.0
0.28
1
04/03/15 12:52
04/06/15 09:08
7440-62-2
150
ug/L
5.0
2.4
1
04/03/15 12:52
04/06/15 09:08
7440-66-6
Analytical Method: EPA 7470 Preparation Method: EPA 7470
ND ug/L 0.20 0.022 1 04/04/1517:20 04/06/1519:14 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 74 of 104

aceAnaiXical
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Pace Analytical Services, Inc.
P3690r6fY2'9e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J150305555
Pace Project No.: 92242381
QC Batch: MERP/13084
Analysis Method: EPA 7470
QC Batch Method: EPA 7470
Analysis Description: 7470 Mercury
Associated Lab Samples: 92242381014, 92242381015,
92242381016, 92242381017
METHOD BLANK: 1927067
Matrix: Water
Associated Lab Samples: 92242381014, 92242381015,
92242381016, 92242381017
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Mercury ug/L
ND 0.20
03/30/1510:31
LABORATORY CONTROL SAMPLE: 1927068
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Mercury ug/L
5 5.1
103 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1927069 1927070
MS MSD
92242371022
Spike Spike MS
MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec Limits RPD RPD Qual
Mercury ug/L ND
5 5 4.9
5.0 98 100 75-125 1 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/08/2015 12:54 PM without the written consent of Pace Analytical Services, Inc..
Page 75 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
P3690Ar6fY2'9e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J150305555
Pace Project No.: 92242381
QC Batch: MERP/13139 Analysis Method: EPA 7470
QC Batch Method: EPA 7470 Analysis Description: 7470 Mercury
Associated Lab Samples: 92242381018, 92242381019, 92242381020, 92242381021
METHOD BLANK: 1932636 Matrix: Water
Associated Lab Samples: 92242381018, 92242381019, 92242381020, 92242381021
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Mercury ug/L ND 0.20 04/06/1518:28
LABORATORY CONTROL SAMPLE: 1932637
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Mercury ug/L 5 5.8 116 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1932638 1932639
MS MSD
92239540007 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Mercury ug/L ND 15 15 16.1 16.0 107 106 75-125 1 20 H3
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/08/2015 12:54 PM without the written consent of Pace Analytical Services, Inc..
Page 76 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
P3690*r6fY2'9e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J150305555
Pace Project No.: 92242381
QC Batch: MERP/5528
Analysis Method: EPA 7471
QC Batch Method: EPA 7471
Analysis Description: 7471 Mercury
Associated Lab Samples: 92242381001,92242381002,92242381003,92242381004,92242381005,92242381006,92242381007
METHOD BLANK: 1169343
Matrix: Solid
Associated Lab Samples: 92242381001, 92242381002,
92242381003, 92242381004, 92242381005, 92242381006, 92242381007
Blank Reporting
Parameter Units
Result Limit Analyzed Qualifiers
Mercury mg/kg
ND 0.0081 04/01/1512:26
LABORATORY CONTROL SAMPLE: 1169344
Spike LCS LCS % Rec
Parameter Units
Conc. Result % Rec Limits Qualifiers
Mercury mg/kg
.083 0.080 96 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1169345 1169346
MS MSD
35180845003
Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Mercury mg/kg 0.023
.0937 .0902 0.094 0.090 76 74 80-120 4 20 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/08/2015 12:54 PM without the written consent of Pace Analytical Services, Inc..
Page 77 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
P369Vr6fY2'9e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J150305555
Pace Project No.: 92242381
QC Batch: MERP/5529
Analysis Method: EPA 7471
QC Batch Method: EPA 7471
Analysis Description: 7471 Mercury
Associated Lab Samples: 92242381008, 92242381009,
92242381010, 92242381011, 92242381012, 92242381013
METHOD BLANK: 1169347
Matrix: Solid
Associated Lab Samples: 92242381008, 92242381009,
92242381010, 92242381011, 92242381012, 92242381013
Blank Reporting
Parameter Units
Result Limit Analyzed Qualifiers
Mercury mg/kg
ND 0.0077 04/01/1513:35
LABORATORY CONTROL SAMPLE: 1169348
Spike LCS LCS % Rec
Parameter Units
Conc. Result % Rec Limits Qualifiers
Mercury mg/kg
.081 0.084 104 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1169349 1169350
MS MSD
92242381008
Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Mercury mg/kg ND
.107 .106 0.10 0.099 94 93 80-120 2 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/08/2015 12:54 PM without the written consent of Pace Analytical Services, Inc..
Page 78 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
P3y 906r6fY2'9e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J150305555
Pace Project No.: 92242381
QC Batch: MPRP/23322 Analysis Method: EPA 6010
QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid
Associated Lab Samples: 92242381001, 92242381002, 92242381003, 92242381004, 92242381005, 92242381006, 92242381007,
92242381008,92242381009,92242381010,92242381011,92242381012,92242381013
METHOD BLANK: 1169012 Matrix: Solid
Associated Lab Samples: 92242381001, 92242381002, 92242381003, 92242381004, 92242381005, 92242381006, 92242381007,
92242381008,92242381009,92242381010,92242381011,92242381012,92242381013
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Aluminum
mg/kg
ND
5.2
04/02/15 09:26
Barium
mg/kg
ND
0.52
04/02/15 09:26
Beryllium
mg/kg
ND
0.052
04/02/15 09:26
Boron
mg/kg
ND
2.6
04/02/15 09:26
Calcium
mg/kg
ND
25.8
04/02/15 09:26
Chromium
mg/kg
ND
0.26
04/02/15 09:26
Copper
mg/kg
ND
0.26
04/02/15 09:26
Iron
mg/kg
ND
2.1
04/02/15 09:26
Magnesium
mg/kg
ND
25.8
04/02/15 09:26
Manganese
mg/kg
ND
0.26
04/02/15 09:26
Molybdenum
mg/kg
ND
0.52
04/02/15 09:26
Nickel
mg/kg
ND
0.26
04/02/15 09:26
Potassium
mg/kg
ND
51.5
04/02/15 09:26
Sodium
mg/kg
ND
51.5
04/02/15 09:26
Strontium
mg/kg
ND
0.52
04/02/15 09:26
Zinc
mg/kg
ND
1.0
04/02/15 09:26
LABORATORY CONTROL SAMPLE:
Parameter
1169013
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
Aluminum
mg/kg
123
121
99
80-120
Barium
mg/kg
12.3
12.8
104
80-120
Beryllium
mg/kg
1.2
1.3
105
80-120
Boron
mg/kg
123
125
101
80-120
Calcium
mg/kg
614
643
105
80-120
Chromium
mg/kg
12.3
12.4
101
80-120
Copper
mg/kg
12.3
12.8
104
80-120
Iron
mg/kg
123
123
100
80-120
Magnesium
mg/kg
614
618
101
80-120
Manganese
mg/kg
12.3
12.7
103
80-120
Molybdenum
mg/kg
12.3
12.1
99
80-120
Nickel
mg/kg
12.3
12.5
102
80-120
Potassium
mg/kg
614
656
107
80-120
Sodium
mg/kg
614
663
108
80-120
Strontium
mg/kg
12.3
12.6
102
80-120
Zinc
mg/kg
61.4
63.6
104
80-120
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/08/2015 12:54 PM without the written consent of Pace Analytical Services, Inc.. Page 79 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
Pa89QMr6fY2'9e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J150305555
Pace Project No.: 92242381
MATRIX SPIKE & MATRIX SPIKE
DUPLICATE:
1169014
1169015
MS
MSD
92242381001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Aluminum
mg/kg
3200
191
195
4850
4830
868
839
75-125
0
20 M1
Barium
mg/kg
44.1
19.1
19.5
69.4
72.0
133
143
75-125
4
20 M1
Beryllium
mg/kg
0.73
1.97
1.97
2.8
2.7
107
101
75-125
3
20
Boron
mg/kg
7.3
191
195
181
186
91
91
75-125
3
20
Calcium
mg/kg
551
950
976
1550
1640
106
112
75-125
6
20
Chromium
mg/kg
10.6
19.1
19.5
28.5
27.6
94
88
75-125
3
20
Copper
mg/kg
10.6
19.1
19.5
30.1
30.9
103
104
75-125
3
20
Iron
mg/kg
2840
191
195
2940
2870
52
13
75-125
3
20 M1
Magnesium
mg/kg
212
950
976
1150
1280
99
109
75-125
10
20
Manganese
mg/kg
24.1
19.1
19.5
41.4
38.1
91
72
75-125
8
20 M1
Molybdenum
mg/kg
0.53J
19.1
19.5
17.6
18.2
90
91
75-125
3
20
Nickel
mg/kg
7.2
19.1
19.5
26.6
27.2
102
103
75-125
2
20
Potassium
mg/kg
396
950
976
1570
1670
123
131
75-125
6
20 M1
Sodium
mg/kg
81.5
950
976
1070
1180
104
113
75-125
10
20
Strontium
mg/kg
25.4
19.1
19.5
50.8
51.5
134
134
75-125
1
20 M1
Zinc
mg/kg
10.5
95
97.6
102
105
97
97
75-125
2
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/08/2015 12:54 PM without the written consent of Pace Analytical Services, Inc..
Page 80 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
Pa89"lir6fY2'9e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J150305555
Pace Project No.: 92242381
QC Batch: MPRP/23323 Analysis Method: EPA 6020
QC Batch Method: EPA 3050 Analysis Description: 6020 MET SOLID
Associated Lab Samples: 92242381001, 92242381002, 92242381003, 92242381004, 92242381005, 92242381006, 92242381007,
92242381008,92242381009,92242381010,92242381011,92242381012,92242381013
METHOD BLANK: 1169016
Matrix:
Solid
Associated Lab Samples:
92242381001, 92242381002,
92242381003, 92242381004, 92242381005,
92242381006, 92242381007,
92242381008,92242381009,92242381010,92242381011,92242381012,92242381013
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Antimony
mg/kg
ND
0.052
03/31/15 21:37 N2
Arsenic
mg/kg
ND
0.052
03/31/15 21:37
Cadmium
mg/kg
ND
0.0062
03/31/15 21:37
Cobalt
mg/kg
ND
0.052
03/31/15 21:37
Lead
mg/kg
ND
0.052
03/31/15 21:37
Selenium
mg/kg
ND
0.052
03/31/15 21:37
Thallium
mg/kg
ND
0.052
03/31/15 21:37
Vanadium
mg/kg
ND
0.052
03/31/15 21:37
LABORATORY CONTROL SAMPLE:
Parameter
1169017
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
Antimony
mg/kg
2.4
2.5
103
80-120 N2
Arsenic
mg/kg
2.4
2.5
105
80-120
Cadmium
mg/kg
.24
0.27
111
80-120
Cobalt
mg/kg
2.4
2.5
106
80-120
Lead
mg/kg
2.4
2.5
105
80-120
Selenium
mg/kg
2.4
2.3
97
80-120
Thallium
mg/kg
2.4
2.6
111
80-120
Vanadium
mg/kg
2.4
2.4
101
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1169018
MS
92242381002 Spike
Parameter Units Result Conc.
MSD
Spike
Conc.
1169019
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
Max
RPD RPD Qual
Antimony
mg/kg
ND
4.16
4.33
4.OJ
4.3J
61
66
75-125
20 D3,M6,
N2
Arsenic
mg/kg
10
4.16
4.33
15.0
15.1
121
121
75-125
1
20 D3
Cadmium
mg/kg
ND
.416
.433
0.58
0.58
107
106
75-125
0
20 D3
Cobalt
mg/kg
12.9
4.16
4.33
19.5
19.6
157
155
75-125
0
20 D3,M6
Lead
mg/kg
14.5
4.16
4.33
22.2
22.0
183
175
75-125
1
20 D3,M6
Selenium
mg/kg
ND
4.16
4.33
5.7
4.5
95
66
75-125
22
20 D3,M6,
R1
Thallium
mg/kg
ND
4.16
4.33
4.OJ
4.5
87
96
75-125
20 D3
Vanadium
mg/kg
64.7
4.16
4.33
76.0
75.0
271
240
75-125
1
20 D4,M6
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/08/2015 12:54 PM without the written consent of Pace Analytical Services, Inc..
Page 81 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
Padg"ifY2'9e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J150305555
Pace Project No.: 92242381
QC Batch: MPRP/53216 Analysis Method: EPA 6020A
QC Batch Method: EPA 3020 Analysis Description: 6020A Water UPD4
Associated Lab Samples: 92242381014, 92242381015, 92242381016, 92242381017
METHOD BLANK: 1926640 Matrix: Water
Associated Lab Samples: 92242381014, 92242381015, 92242381016, 92242381017
Blank Reporting
Parameter Units Result Limit
Analyzed
Aluminum
ug/L
ND
10.0
03/28/1514:55
Antimony
ug/L
ND
0.50
03/28/1514:55
Arsenic
ug/L
ND
0.50
03/28/1514:55
Barium
ug/L
ND
0.30
03/28/1514:55
Beryllium
ug/L
ND
0.20
03/28/1514:55
Boron
ug/L
ND
5.0
03/28/1514:55
Cadmium
ug/L
ND
0.080
03/28/1514:55
Calcium
ug/L
ND
40.0
03/28/1514:55
Chromium
ug/L
ND
0.50
03/28/1514:55
Cobalt
ug/L
ND
0.50
03/28/1514:55
Copper
ug/L
ND
1.0
03/28/1514:55
Iron
ug/L
ND
50.0
03/28/1514:55
Lead
ug/L
ND
0.10
03/28/1514:55
Magnesium
ug/L
ND
10.0
03/28/1514:55
Manganese
ug/L
ND
0.50
03/28/1514:55
Molybdenum
ug/L
ND
0.50
03/28/1514:55
Nickel
ug/L
ND
0.50
03/28/1514:55
Potassium
ug/L
ND
50.0
03/28/1514:55
Selenium
ug/L
ND
0.50
03/28/1514:55
Sodium
ug/L
ND
50.0
03/28/1514:55
Strontium
ug/L
ND
0.50
03/28/1514:55
Thallium
ug/L
ND
0.10
03/28/1514:55
Vanadium
ug/L
ND
1.0
03/28/1514:55
Zinc
ug/L
ND
5.0
03/28/1514:55
Qualifiers
LABORATORY CONTROL SAMPLE:
Parameter
1926641
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
Aluminum
ug/L
80
84.4
105
80-120
Antimony
ug/L
80
81.0
101
80-120
Arsenic
ug/L
80
81.2
102
80-120
Barium
ug/L
80
80.3
100
80-120
Beryllium
ug/L
80
83.5
104
80-120
Boron
ug/L
80
85.2
107
80-120
Cadmium
ug/L
80
84.6
106
80-120
Calcium
ug/L
1000
1090
109
80-120
Chromium
ug/L
80
86.8
108
80-120
Cobalt
ug/L
80
84.7
106
80-120
Copper
ug/L
80
88.7
111
80-120
Iron
ug/L
1000
1100
110
80-120
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/08/2015 12:54 PM without the written consent of Pace Analytical Services, Inc.. Page 82 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
PadgiWY2'9e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J150305555
Pace Project No.: 92242381
LABORATORY CONTROL SAMPLE: 1926641
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits
Qualifiers
Lead
ug/L
80
86.1
108
80-120
Magnesium
ug/L
1000
1080
108
80-120
Manganese
ug/L
80
86.7
108
80-120
Molybdenum
ug/L
80
83.3
104
80-120
Nickel
ug/L
80
86.3
108
80-120
Potassium
ug/L
1000
1070
107
80-120
Selenium
ug/L
80
81.4
102
80-120
Sodium
ug/L
1000
1080
108
80-120
Strontium
ug/L
80
80.4
100
80-120
Thallium
ug/L
80
87.4
109
80-120
Vanadium
ug/L
80
84.8
106
80-120
Zinc
ug/L
80
86.3
108
80-120
MATRIX SPIKE & MATRIX SPIKE
DUPLICATE:
1926978
1926979
MS
MSD
92241477016
Spike
Spike
MS
MSD
MS MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec % Rec
Limits
RPD
RPD Qual
Aluminum
ug/L
ND
80
80
94.1
94.1
111
111
75-125
0
20
Antimony
ug/L
ND
80
80
83.4
81.0
104
101
75-125
3
20
Arsenic
ug/L
ND
80
80
83.9
81.8
105
102
75-125
3
20
Barium
ug/L
ND
80
80
81.0
79.5
101
99
75-125
2
20
Beryllium
ug/L
ND
80
80
83.6
82.5
104
103
75-125
1
20
Boron
ug/L
ND
80
80
87.7
87.2
109
108
75-125
1
20
Cadmium
ug/L
ND
80
80
85.9
85.2
107
106
75-125
1
20
Calcium
ug/L
45.8
1000
1000
1070
1030
102
99
75-125
3
20
Chromium
ug/L
ND
80
80
86.7
86.6
108
108
75-125
0
20
Cobalt
ug/L
ND
80
80
87.2
85.6
109
107
75-125
2
20
Copper
ug/L
ND
80
80
91.1
89.2
113
111
75-125
2
20
Iron
ug/L
ND
1000
1000
1130
1120
109
109
75-125
1
20
Lead
ug/L
ND
80
80
87.5
85.6
109
107
75-125
2
20
Magnesium
ug/L
ND
1000
1000
1090
1090
109
108
75-125
0
20
Manganese
ug/L
0.67
80
80
87.4
86.6
108
107
75-125
1
20
Molybdenum
ug/L
ND
80
80
83.4
82.3
104
102
75-125
1
20
Nickel
ug/L
0.54
80
80
88.3
87.2
110
108
75-125
1
20
Potassium
ug/L
ND
1000
1000
1090
1060
108
105
75-125
2
20
Selenium
ug/L
ND
80
80
81.2
80.0
101
100
75-125
1
20
Sodium
ug/L
ND
1000
1000
1100
1090
108
106
75-125
1
20
Strontium
ug/L
ND
80
80
81.1
80.5
101
100
75-125
1
20
Thallium
ug/L
ND
80
80
86.8
85.7
109
107
75-125
1
20
Vanadium
ug/L
ND
80
80
85.0
83.9
106
105
75-125
1
20
Zinc
ug/L
ND
80
80
86.8
86.5
104
104
75-125
0
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/08/2015 12:54 PM without the written consent of Pace Analytical Services, Inc..
Page 83 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
Pa89Qffl�'r6fY2'9e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J150305555
Pace Project No.: 92242381
QC Batch: MPRP/53349 Analysis Method: EPA 6020A
QC Batch Method: EPA 3020 Analysis Description: 6020A Water UPD4
Associated Lab Samples: 92242381018, 92242381019, 92242381020, 92242381021
METHOD BLANK: 1931408 Matrix: Water
Associated Lab Samples: 92242381018, 92242381019, 92242381020, 92242381021
Blank Reporting
Parameter Units Result Limit
Analyzed
Aluminum
ug/L
ND
10.0
04/06/15 07:50
Antimony
ug/L
ND
0.50
04/06/15 07:50
Arsenic
ug/L
ND
0.50
04/06/15 07:50
Barium
ug/L
ND
0.30
04/06/15 07:50
Beryllium
ug/L
ND
0.20
04/06/15 07:50
Boron
ug/L
ND
5.0
04/06/15 07:50
Cadmium
ug/L
ND
0.080
04/06/15 07:50
Calcium
ug/L
ND
40.0
04/06/15 07:50
Chromium
ug/L
ND
0.50
04/06/15 07:50
Cobalt
ug/L
ND
0.50
04/06/15 07:50
Copper
ug/L
ND
1.0
04/06/15 07:50
Iron
ug/L
ND
50.0
04/06/15 07:50
Lead
ug/L
ND
0.10
04/06/15 07:50
Magnesium
ug/L
ND
10.0
04/06/15 07:50
Manganese
ug/L
ND
0.50
04/06/15 07:50
Molybdenum
ug/L
ND
0.50
04/06/15 07:50
Nickel
ug/L
ND
0.50
04/06/15 07:50
Potassium
ug/L
ND
50.0
04/06/15 07:50
Selenium
ug/L
ND
0.50
04/06/15 07:50
Sodium
ug/L
ND
50.0
04/06/15 07:50
Strontium
ug/L
ND
0.50
04/06/15 07:50
Thallium
ug/L
ND
0.10
04/06/15 07:50
Vanadium
ug/L
ND
1.0
04/06/15 07:50
Zinc
ug/L
ND
5.0
04/06/15 07:50
Qualifiers
LABORATORY CONTROL SAMPLE:
Parameter
1931409
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
Aluminum
ug/L
80
85.5
107
80-120
Antimony
ug/L
80
80.1
100
80-120
Arsenic
ug/L
80
80.5
101
80-120
Barium
ug/L
80
80.4
101
80-120
Beryllium
ug/L
80
80.5
101
80-120
Boron
ug/L
80
82.6
103
80-120
Cadmium
ug/L
80
81.6
102
80-120
Calcium
ug/L
1000
955
96
80-120
Chromium
ug/L
80
82.7
103
80-120
Cobalt
ug/L
80
79.7
100
80-120
Copper
ug/L
80
78.7
98
80-120
Iron
ug/L
1000
1040
104
80-120
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/08/2015 12:54 PM without the written consent of Pace Analytical Services, Inc.. Page 84 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
Pa89QM'6fY2'9e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J150305555
Pace Project No.: 92242381
LABORATORY CONTROL SAMPLE: 1931409
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits
Qualifiers
Lead
ug/L
80
82.2
103
80-120
Magnesium
ug/L
1000
978
98
80-120
Manganese
ug/L
80
81.3
102
80-120
Molybdenum
ug/L
80
79.2
99
80-120
Nickel
ug/L
80
80.2
100
80-120
Potassium
ug/L
1000
1020
102
80-120
Selenium
ug/L
80
80.1
100
80-120
Sodium
ug/L
1000
1000
100
80-120
Strontium
ug/L
80
79.9
100
80-120
Thallium
ug/L
80
80.4
101
80-120
Vanadium
ug/L
80
80.0
100
80-120
Zinc
ug/L
80
84.4
106
80-120
MATRIX SPIKE & MATRIX SPIKE
DUPLICATE:
1931410
1931411
MS
MSD
92243088001
Spike
Spike
MS
MSD
MS MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec % Rec
Limits
RPD
RPD Qual
Aluminum
ug/L
ND
80
80
94.2
90.2
113
108
75-125
4
20
Antimony
ug/L
ND
80
80
78.6
81.2
98
101
75-125
3
20
Arsenic
ug/L
ND
80
80
80.0
82.5
100
103
75-125
3
20
Barium
ug/L
ND
80
80
79.8
80.3
100
100
75-125
1
20
Beryllium
ug/L
ND
80
80
82.4
80.6
103
101
75-125
2
20
Boron
ug/L
ND
80
80
83.9
81.0
104
100
75-125
4
20
Cadmium
ug/L
ND
80
80
81.0
81.3
101
102
75-125
0
20
Calcium
ug/L
ND
1000
1000
882
953
88
95
75-125
8
20
Chromium
ug/L
ND
80
80
81.8
82.8
102
104
75-125
1
20
Cobalt
ug/L
ND
80
80
79.9
79.6
100
99
75-125
0
20
Copper
ug/L
ND
80
80
79.3
79.0
99
99
75-125
0
20
Iron
ug/L
ND
1000
1000
1030
1040
103
104
75-125
1
20
Lead
ug/L
ND
80
80
81.4
82.8
102
103
75-125
2
20
Magnesium
ug/L
ND
1000
1000
959
978
96
98
75-125
2
20
Manganese
ug/L
ND
80
80
81.1
82.1
101
103
75-125
1
20
Molybdenum
ug/L
ND
80
80
79.0
78.9
99
99
75-125
0
20
Nickel
ug/L
ND
80
80
80.5
79.6
101
100
75-125
1
20
Potassium
ug/L
ND
1000
1000
1030
1030
103
103
75-125
0
20
Selenium
ug/L
ND
80
80
81.5
80.8
102
101
75-125
1
20
Sodium
ug/L
ND
1000
1000
1010
1000
101
100
75-125
1
20
Strontium
ug/L
ND
80
80
79.9
79.8
100
100
75-125
0
20
Thallium
ug/L
ND
80
80
82.6
83.8
103
105
75-125
2
20
Vanadium
ug/L
ND
80
80
79.7
80.0
100
100
75-125
0
20
Zinc
ug/L
ND
80
80
85.3
84.7
105
104
75-125
1
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/08/2015 12:54 PM without the written consent of Pace Analytical Services, Inc..
Page 85 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
Pa89Qft'6fY2'9e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J150305555
Pace Project No.: 92242381
QC Batch: PMST/3404
Analysis Method:
ASTM D2974-87
QC Batch Method: ASTM D2974-87
Analysis Description:
Dry Weight/Percent Moisture
Associated Lab Samples: 92242381001,
92242381002, 92242381003, 92242381004,
92242381005, 92242381006,
92242381007,
92242381008,92242381009,92242381010,92242381011,92242381012,92242381013
SAMPLE DUPLICATE: 1171652
92241996005
Dup
Max
Parameter
Units
Result
Result RPD
RPD
Qualifiers
Percent Moisture
%
20.9
22.3 6
10
SAMPLE DUPLICATE: 1171653
92242647007
Dup
Max
Parameter
Units
Result
Result RPD
RPD
Qualifiers
Percent Moisture
%
9.0 63
10 D6
SAMPLE DUPLICATE: 1171654
92242647020
Dup
Max
Parameter
Units
Result
Result RPD
RPD
Qualifiers
Percent Moisture
%
25.5 29
10 D6
SAMPLE DUPLICATE: 1171655
92242381009
Dup
Max
Parameter
Units
Result
Result RPD
RPD
Qualifiers
Percent Moisture
%
24.7
24.6 0
10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/08/2015 12:54 PM without the written consent of Pace Analytical Services, Inc.. Page 86 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
Padg"ifY2'9e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J150305555
Pace Project No.: 92242381
QC Batch: WET/36413 Analysis Method: EPA 9045
QC Batch Method: EPA 9045 Analysis Description: 9045 pH
Associated Lab Samples: 92242381002, 92242381008, 92242381009, 92242381010, 92242381011
SAMPLE DUPLICATE: 1418511
92241965001 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
pH at 25 Degrees C Std. Units 7.8 7.6 2 10 D6
SAMPLE DUPLICATE: 1418512
92242371021 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
pH at 25 Degrees C Std. Units 9.4 9.2 2 10 D6
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
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aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
Padg"WfY2'9e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J150305555
Pace Project No.: 92242381
QC Batch: WET/36450 Analysis Method: EPA 9045
QC Batch Method: EPA 9045 Analysis Description: 9045 pH
Associated Lab Samples: 92242381001, 92242381003, 92242381004, 92242381005, 92242381006, 92242381007, 92242381012,
92242381013
SAMPLE DUPLICATE: 1419698
92242374004 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
pH at 25 Degrees C Std. Units 5.2 5.2 0 10
SAMPLE DUPLICATE: 1419699
92242504013 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
pH at 25 Degrees C Std. Units 7.9 8.0 0 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/08/2015 12:54 PM without the written consent of Pace Analytical Services, Inc.. Page 88 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
Padg"iWY2'9e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J150305555
Pace Project No.: 92242381
QC Batch: WETA/22392 Analysis Method: EPA 300.0
QC Batch Method: EPA 300.0 Analysis Description: 300.0 IC Anions
Associated Lab Samples: 92242381001, 92242381002, 92242381003, 92242381004
METHOD BLANK: 1422994 Matrix: Water
Associated Lab Samples: 92242381001, 92242381002, 92242381003, 92242381004
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Sulfate mg/L 10.2 4.0 04/02/1511:55 D3
LABORATORY CONTROL SAMPLE: 1422995
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Sulfate mg/L 20 19.2 96 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1422996 1422997
MS MSD
92242374008 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfate mg/L 16.7 24.3 24.3 37.2 37.1 84 84 0 D3
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1422998 1422999
MS MSD
92242502011 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfate mg/L 9.7 27.7 27.7 37.0 37.1 99 99 0 D3
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 04/08/2015 12:54 PM without the written consent of Pace Analytical Services, Inc..
Page 89 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
Pa890P1V6fY2'9e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J150305555
Pace Project No.: 92242381
QC Batch: WETA/22398
Analysis Method: EPA 353.2
QC Batch Method: EPA 353.2
Analysis Description: 353.2 Nitrate + Nitrite, Unpres.
Associated Lab Samples: 92242381001, 92242381002,
92242381003, 92242381004
METHOD BLANK: 1423321
Matrix: Water
Associated Lab Samples: 92242381001, 92242381002,
92242381003, 92242381004
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Nitrogen, Nitrate mg/L
355 2.0
03/31/15 19:29 P8
LABORATORY CONTROL SAMPLE: 1423322
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Nitrogen, Nitrate mg/L
2.5 2.4
95 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1423323 1423324
MS MSD
92241508005
Spike Spike MS
MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec Limits RPD RPD Qual
Nitrogen, Nitrate mg/L 391
3.3 3.3 387
389 -104 -65 90-110 0 10 H1,M6
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1423325 1423326
MS MSD
92242371020 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Nitrogen, Nitrate mg/L 371 3.1 3.1 370 368 -55 -95 90-110 0 10 H1,M6
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/08/2015 12:54 PM without the written consent of Pace Analytical Services, Inc..
Page 90 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
Pa89QP1 ir6fY2'9e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J150305555
Pace Project No.: 92242381
QC Batch: WETA/22399
Analysis Method: SM 4500-CI-E
QC Batch Method: SM 4500-CI-E
Analysis Description: 4500 Chloride
Associated Lab Samples: 92242381001, 92242381002,
92242381003, 92242381004
METHOD BLANK: 1423399
Matrix: Water
Associated Lab Samples: 92242381001, 92242381002,
92242381003, 92242381004
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Chloride mg/L
ND 1.0
03/31/1515:20
LABORATORY CONTROL SAMPLE: 1423400
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Chloride mg/L
20 20.6
103 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1423401 1423402
MS MSD
92241965003
Spike Spike MS
MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec Limits RPD RPD Qual
Chloride mg/L ND
29.5 29.5 32.1
32.2 105 105 90-110 0 10
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1423403 1423404
MS MSD
92242381003 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Chloride mg/L ND 27.6 27.6 29.6 29.1 107 105 90-110 2 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 04/08/2015 12:54 PM without the written consent of Pace Analytical Services, Inc..
Page 91 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
PadgoM�Y2'9 e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J150305555
Pace Project No.: 92242381
QC Batch: WETA/44900 Analysis Method: EPA 9056
QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions
Associated Lab Samples: 92242381001, 92242381002, 92242381003, 92242381004, 92242381005, 92242381006, 92242381007,
92242381008
METHOD BLANK: 1168433 Matrix: Solid
Associated Lab Samples:
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Chloride mg/kg ND 50.0 03/28/15 01:02
Sulfate mg/kg ND 50.0 03/28/15 01:02
LABORATORY CONTROL SAMPLE:
1168434
Parameter
Units
Chloride
mg/kg
Sulfate
mg/kg
MATRIX SPIKE SAMPLE:
1168436
Parameter
Units
Chloride
mg/kg
Sulfate
mg/kg
SAMPLE DUPLICATE: 1168435
Parameter
Chloride
Sulfate
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
495 464 94 80-120
495 468 94 80-120
92242373003 Spike MS MS % Rec
Result Conc. Result % Rec Limits Qualifiers
ND 491 418 85 80-120
612 491 916 62 80-120 M1
92242373003 Dup
Units Result Result
mg/kg ND ND
mg/kg 612 510
Max
RPD RPD Qualifiers
20
18 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/08/2015 12:54 PM without the written consent of Pace Analytical Services, Inc.. Page 92 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
Pa890P1lS�Y2'9e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J150305555
Pace Project No.: 92242381
QC Batch: WETA/44904 Analysis Method: EPA 9056
QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions
Associated Lab Samples: 92242381009, 92242381010, 92242381011, 92242381012, 92242381013
METHOD BLANK: 1168486 Matrix: Solid
Associated Lab Samples:
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Chloride mg/kg ND 49.8 03/29/1512:17
Sulfate mg/kg ND 49.8 03/29/1512:17
LABORATORY CONTROL SAMPLE:
1168487
Parameter
Units
Chloride
mg/kg
Sulfate
mg/kg
MATRIX SPIKE SAMPLE:
1168489
Parameter
Units
Chloride
mg/kg
Sulfate
mg/kg
SAMPLE DUPLICATE: 1168488
Parameter
Chloride
Sulfate
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
496 482 97 80-120
496 485 98 80-120
92242381009 Spike MS MS % Rec
Result Conc. Result % Rec Limits Qualifiers
ND 660 641 78 80-120 M 1
ND 660 796 109 80-120
92242381009 Dup
Units Result Result
mg/kg ND ND
mg/kg ND ND
Max
RPD RPD Qualifiers
20
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 04/08/2015 12:54 PM without the written consent of Pace Analytical Services, Inc.. Page 93 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
Pa890P1Wir6fY2'9e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J150305555
Pace Project No.: 92242381
QC Batch: WETA/44899
Analysis Method: EPA 9056
QC Batch Method: EPA 9056
Analysis Description: 9056 IC Anions
Associated Lab Samples: 92242381001, 92242381002, 92242381003, 92242381004, 92242381005, 92242381006, 92242381007,
92242381008
METHOD BLANK: 1168425
Matrix: Solid
Associated Lab Samples:
Blank Reporting
Parameter
Units
Result Limit Analyzed
Qualifiers
Nitrate as N
mg/kg
ND 5.0 03/28/15 01:02
LABORATORY CONTROL SAMPLE:
1168426
Spike LCS LCS
% Rec
Parameter
Units
Conc. Result % Rec
Limits Qualifiers
Nitrate as N
mg/kg
49.5 48.5 98
80-120
MATRIX SPIKE SAMPLE:
1168428
92242373003 Spike MS
MS % Rec
Parameter
Units
Result Conc. Result
% Rec Limits Qualifiers
Nitrate as N
mg/kg
ND 49.1 42.2
86 80-120 H3
SAMPLE DUPLICATE: 1168427
92242373003 Dup
Max
Parameter
Units
Result Result RPD
RPD Qualifiers
Nitrate as N
mg/kg
ND ND
20 H3
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 04/08/2015 12:54 PM without the written consent of Pace Analytical Services, Inc.. Page 94 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
PadgoflA�Y2'9 e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J150305555
Pace Project No.: 92242381
QC Batch: WETA/44903
Analysis Method: EPA 9056
QC Batch Method: EPA 9056
Analysis Description: 9056 IC Anions
Associated Lab Samples: 92242381009, 92242381010, 92242381011, 92242381012, 92242381013
METHOD BLANK: 1168482
Matrix: Solid
Associated Lab Samples:
Blank Reporting
Parameter
Units
Result Limit Analyzed
Qualifiers
Nitrate as N
mg/kg
ND 5.0 03/29/15 12:17
LABORATORY CONTROL SAMPLE:
1168483
Spike LCS LCS
% Rec
Parameter
Units
Conc. Result % Rec
Limits
Qualifiers
Nitrate as N
mg/kg
49.6 50.7 102
80-120
MATRIX SPIKE SAMPLE:
1168485
92242381009 Spike MS
MS
% Rec
Parameter
Units
Result Conc. Result
% Rec
Limits Qualifiers
Nitrate as N
mg/kg
ND 66 65.7
97 80-120 H3
SAMPLE DUPLICATE: 1168484
92242381009 Dup
Max
Parameter
Units
Result Result RPD
RPD
Qualifiers
Nitrate as N
mg/kg
ND ND
20 H3
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 04/08/2015 12:54 PM without the written consent of Pace Analytical Services, Inc.. Page 95 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
Padgofl*�Y2'9 e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J150305555
Pace Project No.: 92242381
QC Batch: WETA/27838
Analysis Method: EPA 9060
QC Batch Method: EPA 9060
Analysis Description: 9060 TOC Average
Associated Lab Samples: 92242381001, 92242381002,
92242381003, 92242381004, 92242381005, 92242381006, 92242381007,
92242381008,92242381009,92242381010
METHOD BLANK: 1135827
Matrix: Solid
Associated Lab Samples:
Blank Reporting
Parameter Units
Result Limit Analyzed Qualifiers
Mean Total Organic Carbon mg/kg
ND 600 04/03/15 11:12
LABORATORY CONTROL SAMPLE: 1135828
Spike LCS LCS % Rec
Parameter Units
Conc. Result % Rec Limits Qualifiers
Mean Total Organic Carbon mg/kg
120000 117000 97 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1135829 1135830
MS MSD
92242381001
Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Mean Total Organic Carbon mg/kg 23400
26300 26300 43000 45500 75 84 50-150 6 30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 04/08/2015 12:54 PM without the written consent of Pace Analytical Services, Inc..
Page 96 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
PadgoM�Y2'9 e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J150305555
Pace Project No.: 92242381
QC Batch: WETA/27846
Analysis Method: EPA 9060
QC Batch Method: EPA 9060
Analysis Description: 9060 TOC Average
Associated Lab Samples: 92242381011, 92242381012,
92242381013
METHOD BLANK: 1136263
Matrix: Solid
Associated Lab Samples:
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Mean Total Organic Carbon mg/kg
ND 600
04/06/15 06:53
LABORATORY CONTROL SAMPLE: 1136264
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Mean Total Organic Carbon mg/kg
120000 120000
100 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1136265 1136266
MS MSD
92242381011
Spike Spike MS
MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec Limits RPD RPD Qual
Mean Total Organic Carbon mg/kg 17100
37700 37600 52300
58900 94 111 50-150 12 30
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1136267 1136268
MS MSD
92242502005 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Mean Total Organic Carbon mg/kg 71100 70600 70100 138000 140000 95 99 50-150 1 30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/08/2015 12:54 PM without the written consent of Pace Analytical Services, Inc..
Page 97 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
Pa890PA leY2'9e. Suite 100
Huntersville, NC 28078
[phone]
QUALIFIERS
Project: J150305555
Pace Project No.: 92242381
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI -The NELAC Institute.
LABORATORIES
PASI-A
Pace Analytical Services - Asheville
PASI-G
Pace Analytical Services - Green Bay
PASI-M
Pace Analytical Services - Minneapolis
PASI-O
Pace Analytical Services - Ormond Beach
ANALYTE QUALIFIERS
B Analyte was detected in the associated method blank.
D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
D4 Sample was diluted due to the presence of high levels of target analytes.
D6 The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits.
H1 Analysis conducted outside the EPA method holding time.
H3 Sample was received or analysis requested beyond the recognized method holding time.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
N2 The lab does not hold TNI accreditation for this parameter.
P8 Analyte was detected in the method blank. All associated samples had concentrations of at least ten times greater than
the blank or were below the reporting limit.
R1 RPD value was outside control limits.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/08/2015 12:54 PM without the written consent of Pace Analytical Services, Inc.. Page 98 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
P a 89 OP1 9 r6f Y 2'9 e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: J150305555
Pace Project No.: 92242381
Analytical
Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch
92242381001
2015007996
EPA 3050
MPRP/23322
EPA 6010
ICP/14264
92242381002
2015007999
EPA 3050
MPRP/23322
EPA 6010
ICP/14264
92242381003
2015008002
EPA 3050
MPRP/23322
EPA 6010
ICP/14264
92242381004
2015008007
EPA 3050
MPRP/23322
EPA 6010
ICP/14264
92242381005
2015007997
EPA 3050
MPRP/23322
EPA 6010
ICP/14264
92242381006
2015007998
EPA 3050
MPRP/23322
EPA6010
ICP/14264
92242381007
2015008000
EPA 3050
MPRP/23322
EPA 6010
ICP/14264
92242381008
2015008001
EPA 3050
MPRP/23322
EPA 6010
ICP/14264
92242381009
2015008003
EPA 3050
MPRP/23322
EPA 6010
ICP/14264
92242381010
2015008004
EPA 3050
MPRP/23322
EPA 6010
ICP/14264
92242381011
2015008005
EPA 3050
MPRP/23322
EPA 6010
ICP/14264
92242381012
2015008006
EPA 3050
MPRP/23322
EPA 6010
ICP/14264
92242381013
2015008008
EPA 3050
MPRP/23322
EPA 6010
ICP/14264
92242381001
2015007996
EPA 3050
MPRP/23323
EPA 6020
ICPM/9503
92242381002
2015007999
EPA 3050
MPRP/23323
EPA 6020
ICPM/9503
92242381003
2015008002
EPA 3050
MPRP/23323
EPA 6020
ICPM/9503
92242381004
2015008007
EPA 3050
MPRP/23323
EPA 6020
ICPM/9503
92242381005
2015007997
EPA 3050
MPRP/23323
EPA 6020
ICPM/9503
92242381006
2015007998
EPA 3050
MPRP/23323
EPA 6020
ICPM/9503
92242381007
2015008000
EPA 3050
MPRP/23323
EPA 6020
ICPM/9503
92242381008
2015008001
EPA 3050
MPRP/23323
EPA 6020
ICPM/9503
92242381009
2015008003
EPA 3050
MPRP/23323
EPA 6020
ICPM/9503
92242381010
2015008004
EPA 3050
MPRP/23323
EPA 6020
ICPM/9503
92242381011
2015008005
EPA 3050
MPRP/23323
EPA 6020
ICPM/9503
92242381012
2015008006
EPA 3050
MPRP/23323
EPA 6020
ICPM/9503
92242381013
2015008008
EPA 3050
MPRP/23323
EPA 6020
ICPM/9503
92242381014
2015008009
EPA 3020
MPRP/53216
EPA 6020A
ICPM/23581
92242381015
2015008010
EPA 3020
MPRP/53216
EPA 6020A
ICPM/23581
92242381016
2015008011
EPA 3020
MPRP/53216
EPA 6020A
ICPM/23581
92242381017
2015008012
EPA 3020
MPRP/53216
EPA 6020A
ICPM/23581
92242381018
2015007996 SPLP
EPA 3020
MPRP/53349
EPA 6020A
ICPM/23672
92242381019
2015007999 SPLP
EPA 3020
MPRP/53349
EPA 6020A
ICPM/23672
92242381020
2015008002 SPLP
EPA 3020
MPRP/53349
EPA 6020A
ICPM/23672
92242381021
2015008007 SPLP
EPA 3020
MPRP/53349
EPA 6020A
ICPM/23672
92242381014
2015008009
EPA 7470
MERP/13084
EPA 7470
MERC/15200
92242381015
2015008010
EPA 7470
MERP/13084
EPA 7470
MERC/15200
92242381016
2015008011
EPA 7470
MERP/13084
EPA 7470
MERC/15200
92242381017
2015008012
EPA 7470
MERP/13084
EPA 7470
MERC/15200
92242381018
2015007996 SPLP
EPA 7470
MERP/13139
EPA 7470
MERC/15254
92242381019
2015007999 SPLP
EPA 7470
MERP/13139
EPA 7470
MERC/15254
92242381020
2015008002 SPLP
EPA 7470
MERP/13139
EPA 7470
MERC/15254
92242381021
2015008007 SPLP
EPA 7470
MERP/13139
EPA 7470
MERC/15254
92242381001
2015007996
EPA 7471
MERP/5528
EPA 7471
MERC/5519
92242381002
2015007999
EPA 7471
MERP/5528
EPA 7471
MERC/5519
92242381003
2015008002
EPA 7471
MERP/5528
EPA 7471
MERC/5519
92242381004
2015008007
EPA 7471
MERP/5528
EPA 7471
MERC/5519
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/08/2015 12:54 PM without the written consent of Pace Analytical Services, Inc.. Page 99 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
PadgaPAiWY249e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
J150305555
Pace Project No.:
92242381
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92242381005
2015007997
EPA 7471
MERP/5528
EPA 7471
MERC/5519
92242381006
2015007998
EPA 7471
MERP/5528
EPA 7471
MERC/5519
92242381007
2015008000
EPA 7471
MERP/5528
EPA 7471
MERC/5519
92242381008
2015008001
EPA 7471
MERP/5529
EPA 7471
MERC/5520
92242381009
2015008003
EPA 7471
MERP/5529
EPA 7471
MERC/5520
92242381010
2015008004
EPA 7471
MERP/5529
EPA 7471
MERC/5520
92242381011
2015008005
EPA 7471
MERP/5529
EPA 7471
MERC/5520
92242381012
2015008006
EPA 7471
MERP/5529
EPA 7471
MERC/5520
92242381013
2015008008
EPA 7471
MERP/5529
EPA 7471
MERC/5520
92242381001
2015007996
ASTM D2974-87
PMST/3404
92242381002
2015007999
ASTM D2974-87
PMST/3404
92242381003
2015008002
ASTM D2974-87
PMST/3404
92242381004
2015008007
ASTM D2974-87
PMST/3404
92242381005
2015007997
ASTM D2974-87
PMST/3404
92242381006
2015007998
ASTM D2974-87
PMST/3404
92242381007
2015008000
ASTM D2974-87
PMST/3404
92242381008
2015008001
ASTM D2974-87
PMST/3404
92242381009
2015008003
ASTM D2974-87
PMST/3404
92242381010
2015008004
ASTM D2974-87
PMST/3404
92242381011
2015008005
ASTM D2974-87
PMST/3404
92242381012
2015008006
ASTM D2974-87
PMST/3404
92242381013
2015008008
ASTM D2974-87
PMST/3404
92242381001
2015007996
EPA 9045
WET/36450
92242381002
2015007999
EPA 9045
WET/36413
92242381003
2015008002
EPA 9045
WET/36450
92242381004
2015008007
EPA 9045
WET/36450
92242381005
2015007997
EPA 9045
WET/36450
92242381006
2015007998
EPA 9045
WET/36450
92242381007
2015008000
EPA 9045
WET/36450
92242381008
2015008001
EPA 9045
WET/36413
92242381009
2015008003
EPA 9045
WET/36413
92242381010
2015008004
EPA 9045
WET/36413
92242381011
2015008005
EPA 9045
WET/36413
92242381012
2015008006
EPA 9045
WET/36450
92242381013
2015008008
EPA 9045
WET/36450
92242381001
2015007996
EPA 300.0
WETA/22392
92242381002
2015007999
EPA 300.0
WETA/22392
92242381003
2015008002
EPA 300.0
WETA/22392
92242381004
2015008007
EPA 300.0
WETA/22392
92242381001
2015007996
EPA 353.2
WETA/22398
92242381002
2015007999
EPA 353.2
WETA/22398
92242381003
2015008002
EPA 353.2
WETA/22398
92242381004
2015008007
EPA 353.2
WETA/22398
92242381001
2015007996
SM 4500-CI-E
WETA/22399
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/08/2015 12:54 PM without the written consent of Pace Analytical Services, Inc.. Page 100 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
Pa89"lir6fY2'9e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: J150305555
Pace Project No.: 92242381
Lab ID Sample ID QC Batch Method QC Batch
92242381002
2015007999
SM 4500-CI-E
WETA/22399
92242381003
2015008002
SM 4500-CI-E
WETA/22399
92242381004
2015008007
SM 4500-CI-E
WETA/22399
92242381001
2015007996
EPA 9056
WETA/44900
92242381002
2015007999
EPA 9056
WETA/44900
92242381003
2015008002
EPA 9056
WETA/44900
92242381004
2015008007
EPA 9056
WETA/44900
92242381005
2015007997
EPA 9056
WETA/44900
92242381006
2015007998
EPA 9056
WETA/44900
92242381007
2015008000
EPA 9056
WETA/44900
92242381008
2015008001
EPA 9056
WETA/44900
92242381009
2015008003
EPA 9056
WETA/44904
92242381010
2015008004
EPA 9056
WETA/44904
92242381011
2015008005
EPA 9056
WETA/44904
92242381012
2015008006
EPA 9056
WETA/44904
92242381013
2015008008
EPA 9056
WETA/44904
92242381001
2015007996
EPA 9056
WETA/44899
92242381002
2015007999
EPA 9056
WETA/44899
92242381003
2015008002
EPA 9056
WETA/44899
92242381004
2015008007
EPA 9056
WETA/44899
92242381005
2015007997
EPA 9056
WETA/44899
92242381006
2015007998
EPA 9056
WETA/44899
92242381007
2015008000
EPA 9056
WETA/44899
92242381008
2015008001
EPA 9056
WETA/44899
92242381009
2015008003
EPA 9056
WETA/44903
92242381010
2015008004
EPA 9056
WETA/44903
92242381011
2015008005
EPA 9056
WETA/44903
92242381012
2015008006
EPA 9056
WETA/44903
92242381013
2015008008
EPA 9056
WETA/44903
92242381001
2015007996
EPA 9060
WETA/27838
92242381001
2015007996
EPA 9060
WETA/27841
92242381002
2015007999
EPA 9060
WETA/27838
92242381002
2015007999
EPA 9060
WETA/27841
92242381003
2015008002
EPA 9060
WETA/27838
92242381003
2015008002
EPA 9060
WETA/27841
92242381004
2015008007
EPA 9060
WETA/27838
92242381004
2015008007
EPA 9060
WETA/27841
92242381005
2015007997
EPA 9060
WETA/27838
92242381005
2015007997
EPA 9060
WETA/27841
92242381006
2015007998
EPA 9060
WETA/27838
92242381006
2015007998
EPA 9060
WETA/27841
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/08/2015 12:54 PM without the written consent of Pace Analytical Services, Inc..
Analytical
Analytical Method Batch
Page 101 of 104

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
Padg"ifY2'9e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: J150305555
Pace Project No.: 92242381
Lab ID
Sample ID
QC Batch Method
QC Batch
92242381007
2015008000
EPA
9060
WETA/27838
92242381007
2015008000
EPA
9060
WETA/27841
92242381008
2015008001
EPA
9060
WETA/27838
92242381008
2015008001
EPA
9060
WETA/27841
92242381009
2015008003
EPA
9060
WETA/27838
92242381009
2015008003
EPA
9060
WETA/27841
92242381010
2015008004
EPA
9060
WETA/27838
92242381010
2015008004
EPA
9060
WETA/27841
92242381011
2015008005
EPA
9060
WETA/27846
92242381011
2015008005
EPA
9060
WETA/27847
92242381012
2015008006
EPA
9060
WETA/27846
92242381012
2015008006
EPA
9060
WETA/27847
92242381013
2015008008
EPA
9060
WETA/27846
92242381013
2015008008
EPA
9060
WETA/27847
Date: 04/08/2015 12:54 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Analytical Method
Analytical
Batch
Page 102 of 104

-- 17106AfialyticaI'
f
V VU! 11.-e191 1 \GII I Iti.
le Condition Upon Receii
Document Number:
F-CHR-CS-603-rev.15
Vvy~ Page 1 of 2
Issuing Authority:
Pace HuntersvilWMW Mice
Client Name: 0
Courier: ❑ Fed Ex ❑ UPS❑ USPS❑ Client❑ trfercial❑ ac ther
Custody Seal on Cooler/Box Present: El yes��mo Seals intact: ❑ yes ❑ no
Packing Material: ❑ Bubble VE)p _ Bubble Bags ❑ None ❑ Other
Thermometer Used: IR Gun Z4O Type of Ice: et' Blue None Samples on ice, cooling process has begun
,r.-- C.,. # - T4An4 Aln Pewrcrlinn
Corrected Cooler Temp.: 'C
Temp should be above freezing to VC
Biological Tissue is Frozen: Yes No
g
Comments:
ate and Initials9f p rsori xaITI ice,,
contents: ll }
Chain of Custody Present:
es
❑
❑NIA
1.
Chain of Custody Filled Out:
es
o
❑NIA
2,
Chain of Custody Relinquished:
Yes
❑No
❑NIA
3.
Sampler Name & Signature on COC:
❑
❑NIA
4,
Samples Arrived within Hold Time:
es
❑No
IA
5.
Short Hold Time Analysis (<72hr):
Dyes
o
/A
6.
Rush Turn Around Time Requested:
Dyes
❑NIA
7.
Sufficient Volume:
❑ es
o
❑NIA
8.
Correct Containers Used:
-Pace Containers Used:
l3fes
t es
❑N
N/
❑wA
g.
Containers Intact:
Dyes
❑No
❑NIA
1 ,
Filtered volume received for Dissolved tests
Dyes
❑
NIA
11.
Sample Labels match COC:
-Includes date/time/ID/Analysis Matrix:
04, ❑No
©NIA
12,
All containers needing preservation have been checked.
All containers needing preservation are found to be in
compliance with EPA recommendation.
exceptions: VOA, coliform, TOO, O&G, WI-DRO (water)
❑es ❑ N/A
❑ es s�❑NIA
❑Yes L'iNo j
13.
Samples checked for dechlorination:
Dyes
©No
DINIA
4.
Headspace in VOA Vials (>6mm):
Dyes
❑Na
IA
•5.
Trip Blank Present:
Trip Blank Custody Seals Present
Pace Trip Blank Lot # (if purchased):
Dyes [-]No
Dyes ❑No;JN/A
16.
Client Notification/ Resolution: Field Data Required? Y / N
Person Contacted: Date/Time:
Comments/ Resolution:
SCURF Review: I�vv` Date:Ljd�II� I
SRF Review: 1 W Date: I a � I' �
Note: Whenever there is a discrepancy affecting North Carolina compliance
samples. a copy of this form will be sent to the North Carolina DEHNR
Certification Office ( Le out of hold, incorrect preservative, out of temp,
incorrect containers)
;g2242381441micV111A
92242381 , viuitict number
(if no label available)
Page 103 of 104

—Y.
Datel'Cime: Erv4
Received By:
Date/Time:
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"Grab JReq
Total Metals, Anio
pH
1 - 8 ozjar (PACE)
TOC 1 - 4 oz jar
(PACE)
SPLP - Total Metals
and Anions
2 - 8 oz jars (PACE)
Sediment specific
tests 2 - 8 oz jar
(ACCESS
ANALYTICAL)
'OTolal 9 of Conlainers
Page 124 of 125
Cil9tomOrmuft ComPlete -
w
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G) M
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c
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10
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CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM
DUKE
Ana�Iyrhlcal Laboratory SaMeas
Mill Godr Mr-03A2 (&uildrig 74051
h i Ana ical Laborsto
t Work tarwr
Use On
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COPY to CLIENT
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1)Froject t�nr Ab GroUrlLiWra'Ilf J4f5@551Ti�RF $F?� 3�Pho ryp.
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ae�+ Y:.
Wrlen WWCMC acrauriilk q Plot been estwbIkUlied *Pic'.r Is ant kik1ICft#4 abave P rt.wriwatives ertien used MUSE be a H �_ G � J �
we ukecd file folr ing7 it Entor coar ll ascourrfing in atl & ancourigng fialds abrrue, (W &1l1Y10 will 11 Ili $5 rnin utes of saimpie �. v +0 Ln
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m ev tq
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µ.lb Collection Inf,arrnati:yn {py m �3 co ;a w 0 < y,
I. 'al.abQt8all, 9.dlrn.:rl, a.hj . .. ~{3'7rIDescription D riSNSI"uu
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Dart nne 's..a.aa -s C"n*d ey ururrom
MoUls: A], Sb, As, B®, Be, B, CA Gar Cr, Car Cu, Fe, Ph, Mg, Mn, Mu, HI, K, So. Na, Sr, Till V, Zn, Mercury, PH
ANems: CI: Nilrats`N. SDA Sediment Specific Parameters: %Solids_ CEC, Pa rticle Size Distributlorl_ Redox P(deaitial
l.r
22Requested Tumaround
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