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Home My WebLink AboutNC0038377_J15020349 Report_20150902DUKE ENERGY Analytical Laboratory Order Number: Project Name: Customer Name(s): Customer Address: Lab Contact: Report Authorized By: (Signature) Program Comments: 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone:980-875-5245 Fax:980-875-4349 Order Summary Report J15020349 AB GW ASSESSMENT SOIL Tim Hunsucker, Jerry Wylie, Kathy Webb, John Toepfer Margaret Galvin -Karr Phone: 980-875-5219 marge.galvin-karr@duke- energy.com Date: R Y, 2015.03.18 11:40:17-04'00' Margaret Galvin -Karr Please contact the Program Manager (Margaret Galvin -Karr) with any questions regarding this report. Data Flags & Calculations: 3/10/2015 Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Sample ID's & Descriptions: Collection Sample ID Plant/Station Date and Time Collected By Sample Description 2015003935 MAYO STEAM 05-Feb-15 2:30 PM illegible MW-3BR (0.8-1.2) 2015003950 MAYO STEAM 05-Feb-15 5:15 PM illegible MW 3BR (14.75-15) 2015003951 MAYO STEAM 05-Feb-15 5:15 PM illegible MW 3BR (17-18) 2015003952 MAYO STEAM 05-Feb-15 2:30 PM illegible MW 3BR (2.0-2.25) 2015003953 MAYO STEAM 11-Feb-15 3:08 PM illegible MW 8BR (25.5-26) 2015003954 MAYO STEAM 11-Feb-15 11:09 AM illegible MW 8BR (0.75-1.25) 2015003955 MAYO STEAM 11-Feb-15 3:18 PM illegible MW 8BR (30.5-31) 7 Total Samples Technical Validation Review Checklist: COC and .pdf report are in agreement with sample totals Yes No and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. ❑ Yes No All laboratory QA/QC requirements are acceptable.❑ Yes ❑ No Report Sections Included: U Job Summary Report ❑ Sample Identification ❑ Technical Validation of Data Package d❑ Analytical Laboratory Certificate of Analysis ❑ Analytical Laboratory QC Report 0 Sub -contracted Laboratory Results ❑ Customer Specific Data Sheets, Reports, & Documentation ❑ Customer Database Entries d❑ Chain of Custody d❑ Electronic Data Deliverable (EDD) Sent Separately Reviewed By: DBA Account Date: 3/10/2015 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15020349 Site: MW-3BR (0.8-1.2) Sample #: 2015003935 Collection Date: 05-Feb-15 2:30 PM Matrix: SOIL Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE Site: MW 3BR (14.75-15) Collection Date: 05-Feb-15 5:15 PM Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15020349 Sample #: 2015003950 Matrix: SOIL Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE Site: MW 3BR (17-18) Collection Date: 05-Feb-15 5:15 PM Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15020349 Sample #: 2015003951 Matrix: SOIL Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15020349 Site: MW 3BR (2.0-2.25) Collection Date: 05-Feb-15 2:30 PM Analyte Result Units Qualifiers RDL DF SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Sample #: 2015003952 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Site: MW 8BR (25.5-26) Collection Date: 11-Feb-15 3:08 PM Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15020349 Sample #: 2015003953 Matrix: SOIL Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15020349 Site: MW 8BR (0.75-1.25) Collection Date: 11-Feb-15 11:09 AM Sample #: 2015003954 Matrix: SOIL Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE Site: MW 8BR (30.5-31) Collection Date: 11-Feb-15 3:18 PM Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15020349 Sample #: 2015003955 Matrix: SOIL Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, INC 28078 (704)875-9092 March 05, 2015 Program Manager Duke Energy 13339 Hagers Ferry Road Bldg.7405 MG30A2 Huntersville, NC 28078 RE: Project: J 15020349 Pace Project No.: 92237760 Dear Program Manager: Enclosed are the analytical results for sample(s) received by the laboratory on February 13, 2015. The results relate only to the samples included in this report. Results reported herein conform to the most current TN standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Herring kevin.herring@pacelabs.com HORIZON Database Administrator Enclosures cc: Marge Galvin -Karr, Duke Energy Program Manager, Duke Energy Rodney Wilke, Duke Energy pie p«FO REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. A Page 1 of 65 lacmnalyfica( www.pacelabs.com Pace Analytical Services, Inc. 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15020349 Pace Project No.: 92237760 Minnesota Certification IDs 1700 Elm Street SE Suite 200, Minneapolis, MN 55414 A21-A Certification #: 2926.01 Alaska Certification #: UST-078 Alaska Certification #MN00064 Alabama Certification #40770 Arizona Certification #: AZ-0014 Arkansas Certification #: 88-0680 California Certification #: 01155CA Colorado Certification #Pace Connecticut Certification #: PH-0256 EPA Region 8 Certification #: 8TMS-L Florida/NELAP Certification #: E87605 Guam Certification #:14-008r Georgia Certification #: 959 Georgia EPD #: Pace Idaho Certification #: MN00064 Hawaii Certification #MN00064 Illinois Certification #: 200011 Indiana Certification#C-MN-01 Iowa Certification #: 368 Kansas Certification #: E-10167 Kentucky Dept of Envi. Protection - DW #90062 Kentucky Dept of Envi. Protection - WW #:90062 Louisiana DEQ Certification #: 3086 Louisiana DHH #: LA140001 Maine Certification #: 2013011 Maryland Certification #: 322 Michigan DEPH Certification #: 9909 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification #: 41320 Arizona Certification #: AZ0735 Connecticut Certification #: PH-0216 Delaware Certification: FL NELAC Reciprocity Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Massachusetts Certification #: M-FL1264 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Green Bay Certification IDs 1241 Bellevue Street, Green Bay, WI 54302 Florida/NELAP Certification #: E87948 Illinois Certification #: 200050 Kentucky Certification #: 82 Louisiana Certification #: 04168 Minnesota Certification #: 055-999-334 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 CERTIFICATIONS Minnesota Certification #: 027-053-137 Mississippi Certification #: Pace Montana Certification #: MT0092 Nevada Certification #: MN_00064 Nebraska Certification #: Pace New Jersey Certification #: MN-002 New York Certification #: 11647 North Carolina Certification #: 530 North Carolina State Public Health #: 27700 North Dakota Certification #: R-036 Ohio EPA#: 4150 Ohio VAP Certification #: CL101 Oklahoma Certification #: 9507 Oregon Certification #: MN200001 Oregon Certification #: MN300001 Pennsylvania Certification #: 68-00563 Puerto Rico Certification Saipan (CNMI) #:MP0003 South Carolina #:74003001 Texas Certification #: T104704192 Tennessee Certification #: 02818 Utah Certification #: MN000642013-4 Virginia DGS Certification #: 251 Virginia/VELAP Certification #: Pace Washington Certification #: C486 West Virginia Certification #: 382 West Virginia DHHR #:9952C Wisconsin Certification #: 999407970 Missouri Certification #: 236 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 Nevada Certification: FL NELAC Reciprocity New Hampshire Certification #: 2958 New Jersey Certification #: FL765 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FLO1264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 Washington Certification #: C955 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity New York Certification #: 11888 North Dakota Certification #: R-150 South Carolina Certification #: 83006001 Texas Certification #: T104704529-14-1 US Dept of Agriculture #: S-76505 Wisconsin Certification #: 405132750 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 2 of 65 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15020349 Pace Project No.: 92237760 Asheville Certification IDs North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 CERTIFICATIONS West Virginia Certification #: 356 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 3 of 65 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: J15020349 Pace Project No.: 92237760 Lab ID Sample ID Matrix Date Collected Date Received 92237760001 2015003935 Solid 02/05/1514:30 02/13/15 13:38 92237760002 2015003950 Solid 02/05/1517:15 02/13/15 13:38 92237760003 2015003951 Solid 02/05/1517:15 02/13/15 13:38 92237760004 2015003954 Solid 02/11/1511:09 02/13/15 13:38 92237760005 2015003955 Solid 02/11/1515:18 02/13/15 13:38 92237760006 2015003952 Solid 02/05/1514:30 02/13/15 13:38 92237760007 2015003953 Solid 02/11/1515:08 02/13/15 13:38 92237760008 2015003952 SPLP METALS Water 02/05/15 14:30 02/13/15 13:38 92237760009 2015003953 SPLP METALS Water 02/11/15 15:08 02/13/15 13:38 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 4 of 65 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: J15020349 92237760 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92237760001 2015003935 EPA 6010 CKJ 15 PASI-0 EPA 6020 CRT 9 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 HEA 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92237760002 2015003950 EPA 6010 CKJ 15 PASI-0 EPA 6020 CRT 9 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 HEA 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92237760003 2015003951 EPA 6010 CKJ 15 PASI-0 EPA 6020 CRT 9 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 HEA 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92237760004 2015003954 EPA 6010 CKJ 15 PASI-0 EPA 6020 CRT, DRS 9 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 HEA 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92237760005 2015003955 EPA 6010 CKJ 15 PASI-0 EPA 6020 CRT 9 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 HEA 1 PASI-O EPA 9045 MLS 1 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 5 of 65 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: J15020349 Pace Project No.: 92237760 Analytes Lab ID Sample ID Method Analysts Reported Laboratory EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92237760006 2015003952 EPA 300.0 AES2 1 PASI-A EPA 353.2 DMN 1 PASI-A SM 4500-CI-E SER 1 PASI-A 92237760007 2015003953 EPA 6010 CKJ 15 PASI-0 EPA 6020 CRT 9 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 HEA 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 300.0 AES2 1 PASI-A EPA 353.2 DMN 1 PASI-A SM 4500-CI-E SER 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92237760008 2015003952 SPLP METALS EPA 6020A TT3 24 PASI-M EPA 7470 JDD 1 PASI-M 92237760009 2015003953 SPLP METALS EPA 6020A TT3 24 PASI-M EPA 7470 JDD 1 PASI-M REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 6 of 65 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15020349 Pace Project No.: 92237760 Lab Sample ID Client Sample ID Method Parameters SUMMARY OF DETECTION Result Units Report Limit Analyzed 92237760001 2015003935 EPA 6010 Aluminum 7030 mg/kg 6.0 02/20/15 17:39 EPA 6010 Barium 57.6 mg/kg 0.60 02/20/15 17:39 EPA 6010 Calcium 332 mg/kg 29.8 02/20/15 17:39 EPA 6010 Chromium 11.3 mg/kg 3.0 02/21/1516:50 EPA 6010 Copper 6.3 mg/kg 3.0 02/21/1516:50 EPA 6010 Iron 8480 mg/kg 2.4 02/20/15 17:39 EPA 6010 Magnesium 2500 mg/kg 29.8 02/20/15 17:39 EPA 6010 Manganese 327 mg/kg 3.0 02/21/1516:50 EPA 6010 Nickel 5.1 mg/kg 3.0 02/21/1516:50 EPA 6010 Potassium 1070 mg/kg 59.7 02/20/15 17:39 EPA 6010 Strontium 5.4 mg/kg 0.60 02/20/15 17:39 EPA 6010 Zinc 25.3 mg/kg 11.9 02/21/1516:50 EPA 6020 Beryllium 0.34J mg/kg 0.36 02/20/15 11:26 EPA 6020 Cobalt 5.4 mg/kg 3.0 02/20/15 11:26 EPA 6020 Lead 3.3 mg/kg 3.0 02/20/15 11:26 EPA 6020 Vanadium 16.0 mg/kg 3.0 02/20/15 11:26 EPA 7471 Mercury 0.013 mg/kg 0.0093 02/22/15 09:59 ASTM D2974-87 Percent Moisture 16.8 % 0.10 03/04/15 13:21 EPA 9045 pH at 25 Degrees C 5.0 Std. Units 0.10 02/17/15 11:50 EPA 9060 Total Organic Carbon 3280 mg/kg 603 02/24/15 08:46 EPA 9060 Total Organic Carbon 3450 mg/kg 598 02/24/15 08:52 EPA 9060 Total Organic Carbon 3480 mg/kg 603 02/24/15 08:58 EPA 9060 Total Organic Carbon 3660 mg/kg 598 02/24/15 09:04 EPA 9060 Mean Total Organic Carbon 3470 mg/kg 601 02/24/15 08:46 EPA 9060 RSD% 4.4 % 02/24/15 08:46 92237760002 2015003950 EPA 6010 Aluminum 4850 mg/kg 5.1 02/20/15 17:47 EPA 6010 Barium 74.4 mg/kg 0.51 02/20/15 17:47 EPA 6010 Calcium 1740 mg/kg 25.4 02/20/15 17:47 EPA 6010 Chromium 1.51 mg/kg 2.5 02/21/1516:54 EPA 6010 Copper 4.8 mg/kg 2.5 02/21/1516:54 EPA 6010 Iron 7750 mg/kg 2.0 02/20/15 17:47 EPA 6010 Magnesium 3050 mg/kg 25.4 02/20/15 17:47 EPA 6010 Manganese 468 mg/kg 2.5 02/21/1516:54 EPA 6010 Potassium 3780 mg/kg 50.9 02/20/15 17:47 EPA 6010 Sodium 161 mg/kg 50.9 02/20/15 17:47 EPA 6010 Strontium 9.6 mg/kg 0.51 02/20/15 17:47 EPA 6010 Zinc 25.4 mg/kg 10.2 02/21/1516:54 EPA 6020 Beryllium 0.24J mg/kg 0.31 02/20/15 11:29 EPA 6020 Cobalt 4.3 mg/kg 2.5 02/20/15 11:29 EPA 6020 Lead 1.3J mg/kg 2.5 02/20/15 11:29 EPA 6020 Vanadium 7.6 mg/kg 2.5 02/20/15 11:29 ASTM D2974-87 Percent Moisture 2.0 % 0.10 03/04/15 13:21 EPA 9045 pH at 25 Degrees C 8.4 Std. Units 0.10 02/17/15 11:50 EPA 9060 RSD% 4.7 % 02/24/15 09:56 REPORT OF LABORATORY ANALYSIS D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 Qualifiers This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 7 of 65 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15020349 Pace Project No.: 92237760 Lab Sample ID Method Client Sample ID Parameters 92237760003 2015003951 EPA 6010 Aluminum EPA 6010 Barium EPA 6010 Calcium EPA 6010 Copper EPA 6010 Iron EPA 6010 Magnesium EPA 6010 Manganese EPA 6010 Potassium EPA 6010 Sodium EPA 6010 Strontium EPA 6010 Zinc EPA 6020 Beryllium EPA 6020 Cobalt EPA 6020 Vanadium ASTM D2974-87 Percent Moisture EPA 9045 pH at 25 Degrees C EPA 9060 RSD% 92237760004 2015003954 EPA 6010 Aluminum EPA 6010 Barium EPA 6010 Calcium EPA 6010 Chromium EPA 6010 Copper EPA 6010 Iron EPA 6010 Magnesium EPA 6010 Manganese EPA 6010 Nickel EPA 6010 Potassium EPA 6010 Strontium EPA 6010 Zinc EPA 6020 Beryllium EPA 6020 Cobalt EPA 6020 Lead EPA 6020 Vanadium ASTM D2974-87 Percent Moisture EPA 9045 pH at 25 Degrees C EPA 9060 RSD% 92237760005 2015003955 EPA 6010 Aluminum EPA 6010 Barium EPA 6010 Calcium EPA 6010 Chromium EPA 6010 Copper EPA 6010 Iron EPA 6010 Magnesium EPA 6010 Manganese SUMMARY OF DETECTION Result Units Report Limit Analyzed Qualifiers 3230 mg/kg 5.5 02/20/1517:51 74.5 mg/kg 0.55 02/20/1517:51 1490 mg/kg 27.3 02/20/1517:51 5.9 mg/kg 2.7 02/21/1516:58 D3 4450 mg/kg 2.2 02/20/1517:51 2040 mg/kg 27.3 02/20/1517:51 459 mg/kg 2.7 02/21/1516:58 D3 2250 mg/kg 54.7 02/20/1517:51 92.1 mg/kg 54.7 02/20/1517:51 10.7 mg/kg 0.55 02/20/1517:51 14.1 mg/kg 10.9 02/21/1516:58 D3 0.16J mg/kg 0.33 02/20/1511:41 D3 3.6 mg/kg 2.7 02/20/1511:41 D3 4.4 mg/kg 2.7 02/20/1511:41 D3 10.4 % 0.10 03/04/1513:21 8.6 Std. Units 0.10 02/17/15 11:50 5.9 % 02/24/1510:20 14500 mg/kg 127 02/21/1517:03 D3 147 mg/kg 12.7 02/21/1517:03 D3 1120 mg/kg 634 02/21/1517:03 D3 62.2 mg/kg 6.3 02/21/1517:03 D3 34.7 mg/kg 6.3 02/21/1517:03 D3 24700 mg/kg 50.7 02/21/1517:03 D3 10500 mg/kg 634 02/21/1517:03 D3 1230 mg/kg 6.3 02/21/1517:03 D3 29.4 mg/kg 6.3 02/21/1517:03 D3 6590 mg/kg 1270 02/21/1517:03 D3 13.2 mg/kg 12.7 02/21/1517:03 D3 88.9 mg/kg 25.4 02/21/1517:03 D3 0.82 mg/kg 0.38 02/20/1511:44 D3 21.3 mg/kg 3.2 02/20/1511:44 D3 8.9 mg/kg 3.2 02/20/1511:44 D3 50.6 mg/kg 3.2 02/20/1511:44 D4 19.5 % 0.10 03/04/1513:21 6.0 Std. Units 0.10 02/18/15 11:30 25.0 % 02/24/1510:43 8330 mg/kg 106 02/21/1517:07 D3 130 mg/kg 0.53 02/20/1518:42 883 mg/kg 26.5 02/20/1518:42 67.1 mg/kg 5.3 02/21/1517:07 D3 19.8 mg/kg 5.3 02/21/1517:07 D3 11400 mg/kg 2.1 02/20/1518:42 6370 mg/kg 26.5 02/20/1518:42 875 mg/kg 5.3 02/21/1517:07 D3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 8 of 65 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15020349 Pace Project No.: 92237760 Lab Sample ID Client Sample ID Method Parameters SUMMARY OF DETECTION Result Units Report Limit Analyzed Qualifiers 92237760005 2015003955 EPA 6010 Nickel 24.0 mg/kg 5.3 02/21/1517:07 D3 EPA 6010 Potassium 2700 mg/kg 53.1 02/20/15 18:42 EPA 6010 Sodium 68.7 mg/kg 53.1 02/20/15 18:42 EPA 6010 Strontium 9.9 mg/kg 0.53 02/20/15 18:42 EPA 6010 Zinc 29.0 mg/kg 21.2 02/21/1517:07 D3 EPA 6020 Beryllium 0.24J mg/kg 0.32 02/20/15 11:47 D3 EPA 6020 Cobalt 7.4 mg/kg 2.7 02/20/15 11:47 D3 EPA 6020 Lead 3.4 mg/kg 2.7 02/20/15 11:47 D3 EPA 6020 Vanadium 25.2 mg/kg 2.7 02/20/15 11:47 D4 ASTM D2974-87 Percent Moisture 6.6 % 0.10 03/04/15 13:21 EPA 9045 pH at 25 Degrees C 6.9 Std. Units 0.10 02/19/15 10:25 EPA 9060 RSD% 5.7 % 02/24/15 11:04 92237760006 2015003952 EPA300.0 Sulfate 2.6 mg/L 2.0 02/21/1519:24 EPA 353.2 Nitrogen, Nitrate 0.27 mg/L 0.20 02/20/15 21:33 P4 92237760007 2015003953 EPA 6010 Aluminum 23700 mg/kg 5.5 02/20/15 18:46 EPA 6010 Barium 193 mg/kg 0.55 02/20/15 18:46 EPA 6010 Boron 31.OJ mg/kg 54.5 02/21/1517:11 D3 EPA 6010 Calcium 3740 mg/kg 27.3 02/20/15 18:46 EPA 6010 Chromium 419 mg/kg 5.5 02/21/1517:11 D3 EPA 6010 Copper 45.7 mg/kg 5.5 02/21/1517:11 D3 EPA 6010 Iron 31300 mg/kg 43.6 02/21/1517:11 D3 EPA 6010 Magnesium 29900 mg/kg 545 02/21/1517:11 D3 EPA 6010 Manganese 933 mg/kg 5.5 02/21/1517:11 D3 EPA 6010 Nickel 157 mg/kg 5.5 02/21/1517:11 D3 EPA 6010 Potassium 5450 mg/kg 54.5 02/20/15 18:46 EPA 6010 Sodium 173 mg/kg 54.5 02/20/15 18:46 EPA 6010 Strontium 33.6 mg/kg 0.55 02/20/15 18:46 EPA 6010 Zinc 59.4 mg/kg 21.8 02/21/1517:11 D3 EPA 6020 Beryllium 0.39 mg/kg 0.33 02/20/15 11:50 D3 EPA 6020 Cobalt 32.9 mg/kg 2.7 02/20/15 11:50 D4 EPA 6020 Lead 2.OJ mg/kg 2.7 02/20/15 11:50 D3 EPA 6020 Vanadium 75.8 mg/kg 2.7 02/20/15 11:50 D4 ASTM D2974-87 Percent Moisture 8.4 % 0.10 03/04/15 13:21 EPA 9045 pH at 25 Degrees C 7.4 Std. Units 0.10 02/22/15 14:10 EPA300.0 Sulfate 2.8 mg/L 2.2 02/21/1519:38 EPA 353.2 Nitrogen, Nitrate 0.29 mg/L 0.22 02/20/15 21:34 P4 EPA 9060 RSD% 1.8 % 02/24/15 11:27 92237760008 2015003952 SPLP METALS EPA 6020A Aluminum 8440 ug/L 10.0 02/25/15 09:07 EPA 6020A Arsenic 0.67 ug/L 0.50 02/25/15 09:07 EPA 6020A Barium 96.5 ug/L 0.30 02/25/15 09:07 EPA 6020A Beryllium 0.42 ug/L 0.20 02/25/15 09:07 EPA 6020A Boron 7.8 ug/L 5.0 02/25/15 09:07 EPA 6020A Calcium 1160 ug/L 40.0 02/25/15 09:07 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 9 of 65 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15020349 Pace Project No.: 92237760 Lab Sample ID Client Sample ID Method Parameters SUMMARY OF DETECTION Result Units Report Limit Analyzed 92237760008 2015003952 SPLP METALS EPA 6020A Chromium 7.2 ug/L 0.50 02/25/15 09:07 EPA 6020A Cobalt 1.7 ug/L 0.50 02/25/15 09:07 EPA 6020A Copper 5.0 ug/L 1.0 02/25/15 09:07 EPA 6020A Iron 6500 ug/L 50.0 02/25/15 09:07 EPA 6020A Lead 3.2 ug/L 0.10 02/25/15 09:07 EPA 6020A Magnesium 1580 ug/L 10.0 02/25/15 09:07 EPA 6020A Manganese 72.8 ug/L 0.50 02/25/15 09:07 EPA 6020A Nickel 3.2 ug/L 0.50 02/25/15 09:07 EPA 6020A Potassium 738 ug/L 50.0 02/25/15 09:07 EPA 6020A Sodium 3220 ug/L 50.0 02/25/15 09:07 EPA 6020A Strontium 18.7 ug/L 0.50 02/25/15 09:07 EPA 6020A Vanadium 11.6 ug/L 1.0 02/25/15 09:07 EPA 6020A Zinc 23.1 ug/L 5.0 02/25/15 09:07 92237760009 2015003953 SPLP METALS EPA 6020A Aluminum 53900 ug/L 100 02/25/15 09:50 EPA 6020A Arsenic 0.82 ug/L 0.50 02/25/15 09:16 EPA 6020A Barium 702 ug/L 3.0 02/25/15 09:50 EPA 6020A Beryllium 0.78 ug/L 0.20 02/25/15 09:16 EPA 6020A Cadmium 0.24 ug/L 0.080 02/25/15 10:10 EPA 6020A Calcium 12800 ug/L 40.0 02/25/15 09:16 EPA 6020A Chromium 858 ug/L 5.0 02/25/15 09:50 EPA 6020A Cobalt 83.7 ug/L 0.50 02/25/15 09:16 EPA 6020A Copper 161 ug/L 1.0 02/25/15 09:16 EPA 6020A Iron 93400 ug/L 500 02/25/15 09:50 EPA 6020A Lead 5.7 ug/L 0.10 02/25/15 09:16 EPA 6020A Magnesium 58200 ug/L 100 02/25/15 09:50 EPA 6020A Manganese 3410 ug/L 5.0 02/25/15 09:50 EPA 6020A Nickel 311 ug/L 0.50 02/25/15 09:16 EPA 6020A Potassium 6360 ug/L 50.0 02/25/15 09:16 EPA 6020A Sodium 3740 ug/L 50.0 02/25/15 09:16 EPA 6020A Strontium 169 ug/L 0.50 02/25/15 09:16 EPA 6020A Thallium 0.28 ug/L 0.10 02/25/15 09:16 EPA 6020A Vanadium 166 ug/L 1.0 02/25/15 09:16 EPA 6020A Zinc 118 ug/L 5.0 02/25/15 09:16 REPORT OF LABORATORY ANALYSIS Qualifiers This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 10 of 65 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020349 Pace Project No.: 92237760 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: March 05, 2015 General Information: 6 samples were analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/22732 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92237739001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1134160) • Aluminum • Iron • Manganese • MSD (Lab ID: 1134161) • Aluminum • Iron • Manganese Additional Comments: Analyte Comments: QC Batch: MPRP/22732 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015003935 (Lab ID:92237760001) • Chromium • Copper REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 11 of 65 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020349 Pace Project No.: 92237760 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: March 05, 2015 Analyte Comments: QC Batch: MPRP/22732 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015003935 (Lab ID:92237760001) • Manganese • Molybdenum • Nickel • Zinc •2015003950 (Lab ID:92237760002) • Boron • Chromium • Copper • Manganese • Molybdenum • Nickel • Zinc •2015003951 (Lab ID:92237760003) • Chromium • Copper • Manganese • Molybdenum • Nickel • Zinc •2015003953 (Lab ID:92237760007) • Boron • Chromium • Copper • Iron • Magnesium • Manganese • Molybdenum • Nickel • Zinc •2015003954 (Lab ID:92237760004) • Aluminum • Boron • Barium • Calcium • Chromium • Copper • Iron • Potassium • Magnesium • Manganese • Molybdenum • Sodium REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 12 of 65 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020349 Pace Project No.: 92237760 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: March 05, 2015 Analyte Comments: QC Batch: MPRP/22732 DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015003954 (Lab ID:92237760004) • Nickel • Strontium • Zinc •2015003955 (Lab ID:92237760005) • Aluminum • Boron • Chromium • Copper • Manganese • Molybdenum • Nickel • Zinc REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 13 of 65 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020349 Pace Project No.: 92237760 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: March 05, 2015 General Information: 6 samples were analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/22733 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92237739001 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • MS (Lab ID: 1134164) • Antimony • Cadmium • Selenium • MSD (Lab ID: 1134165) • Antimony Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 14 of 65 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020349 Pace Project No.: 92237760 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: March 05, 2015 Analyte Comments: QC Batch: MPRP/22733 DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015003935 (Lab ID:92237760001) • Arsenic • Beryllium • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium • Vanadium •2015003950 (Lab ID:92237760002) • Arsenic • Beryllium • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium • Vanadium •2015003951 (Lab ID:92237760003) • Arsenic • Beryllium • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium • Vanadium •2015003953 (Lab ID:92237760007) • Arsenic • Beryllium • Cadmium • Lead • Antimony • Selenium • Thallium •2015003954 (Lab ID:92237760004) • Arsenic • Beryllium • Cadmium • Cobalt REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 15 of 65 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020349 Pace Project No.: 92237760 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: March 05, 2015 Analyte Comments: QC Batch: MPRP/22733 DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015003954 (Lab ID:92237760004) • Lead • Antimony • Selenium • Thallium •2015003955 (Lab ID:92237760005) • Arsenic • Beryllium • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium • MS (Lab ID: 1134164) • Arsenic • Beryllium • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium • Vanadium • MSD (Lab ID: 1134165) • Arsenic • Beryllium • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium • Vanadium D4: Sample was diluted due to the presence of high levels of target analytes. •2015003953 (Lab ID:92237760007) • Cobalt • Vanadium •2015003954 (Lab ID:92237760004) • Vanadium •2015003955 (Lab ID:92237760005) • Vanadium REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 16 of 65 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020349 Pace Project No.: 92237760 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: March 05, 2015 Analyte Comments: QC Batch: MPRP/22733 N2: The lab does not hold TNI accreditation for this parameter. •2015003935 (Lab ID:92237760001) • Antimony •2015003950 (Lab ID:92237760002) • Antimony •2015003951 (Lab ID:92237760003) • Antimony •2015003953 (Lab ID:92237760007) • Antimony •2015003954 (Lab ID:92237760004) • Antimony •2015003955 (Lab ID:92237760005) • Antimony • BLANK (Lab ID: 1134162) • Antimony • LCS (Lab ID: 1134163) • Antimony • MS (Lab ID: 1134164) • Antimony • MSD (Lab ID: 1134165) • Antimony REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 17 of 65 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020349 Pace Project No.: 92237760 Method: EPA 6020A Description: 6020A MET ICPMS Client: Duke Energy Date: March 05, 2015 General Information: 2 samples were analyzed for EPA 6020A. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3020 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/52559 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92238285008 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MSD (Lab ID: 1905180) • Aluminum R1: RPD value was outside control limits. • MSD (Lab ID: 1905180) • Aluminum Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 18 of 65 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020349 Pace Project No.: 92237760 Method: EPA 7470 Description: 7470 Mercury Client: Duke Energy Date: March 05, 2015 General Information: 2 samples were analyzed for EPA 7470. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7470 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 19 of 65 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020349 Pace Project No.: 92237760 Method: EPA 7471 Description: 7471 Mercury Client: Duke Energy Date: March 05, 2015 General Information: 6 samples were analyzed for EPA 7471. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7471 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 20 of 65 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020349 Pace Project No.: 92237760 Method: EPA 9045 Description: 9045 pH Soil Client: Duke Energy Date: March 05, 2015 General Information: 6 samples were analyzed for EPA 9045. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Duplicate Sample: All duplicate sample results were within method acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 21 of 65 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020349 Pace Project No.: 92237760 Method: EPA 300.0 Description: 300.0 IC Anions, SPLP Client: Duke Energy Date: March 05, 2015 General Information: 2 samples were analyzed for EPA 300.0. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 22 of 65 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020349 Pace Project No.: 92237760 Method: EPA 353.2 Description: 353.2 Nitrogen, NO2/NO3, SPLP Client: Duke Energy Date: March 05, 2015 General Information: 2 samples were analyzed for EPA 353.2. All samples were received in acceptable condition with any exceptions noted below. P4: Sample field preservation does not meet EPA or method recommendations for this analysis. •2015003952 (Lab ID:92237760006) •2015003953 (Lab ID:92237760007) Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 23 of 65 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020349 Pace Project No.: 92237760 Method: SM 4500-CI-E Description: 4500 Chloride, SPLP Client: Duke Energy Date: March 05, 2015 General Information: 2 samples were analyzed for SM 4500-CI-E. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 24 of 65 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020349 Pace Project No.: 92237760 Method: EPA 9056 Description: 9056 IC Anions Client: Duke Energy Date: March 05, 2015 General Information: 6 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/43649 DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015003935 (Lab ID:92237760001) • Chloride •2015003950 (Lab ID:92237760002) • Chloride • Sulfate •2015003951 (Lab ID:92237760003) • Chloride •2015003953 (Lab ID:92237760007) • Chloride • Sulfate •2015003954 (Lab ID:92237760004) • Chloride • Sulfate •2015003955 (Lab ID:92237760005) • Chloride • Sulfate REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 25 of 65 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020349 Pace Project No.: 92237760 Method: EPA 9056 Description: 9056 IC Anions 48hr Client: Duke Energy Date: March 05, 2015 General Information: 6 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 1-13: Sample was received or analysis requested beyond the recognized method holding time. •2015003935 (Lab ID:92237760001) •2015003950 (Lab ID:92237760002) •2015003951 (Lab ID:92237760003) •2015003953 (Lab ID:92237760007) •2015003954 (Lab ID:92237760004) •2015003955 (Lab ID:92237760005) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 26 of 65 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020349 Pace Project No.: 92237760 Method: EPA 9060 Description: Total Organic Carbon Quad Client: Duke Energy Date: March 05, 2015 General Information: 6 samples were analyzed for EPA 9060. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: This data package has been reviewed for quality and completeness and is approved for release. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 27 of 65 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15020349 Pace Project No.: 92237760 Sample: 2015003935 Lab ID: 92237760001 Collected: 02/05/15 14:30 Received: 02/13/15 13:38 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 7030 mg/kg 6.0 3.0 1 02/18/1515:48 02/20/1517:39 7429-90-5 Barium 57.6 mg/kg 0.60 0.30 1 02/18/1515:48 02/20/1517:39 7440-39-3 Boron ND mg/kg 3.0 1.5 1 02/18/1515:48 02/20/1517:39 7440-42-8 Calcium 332 mg/kg 29.8 14.9 1 02/18/1515:48 02/20/1517:39 7440-70-2 Chromium 11.3 mg/kg 3.0 1.5 10 02/18/1515:48 02/21/1516:50 7440-47-3 Copper 6.3 mg/kg 3.0 1.5 10 02/18/1515:48 02/21/1516:50 7440-50-8 Iron 8480 mg/kg 2.4 1.2 1 02/18/1515:48 02/20/1517:39 7439-89-6 Magnesium 2500 mg/kg 29.8 14.9 1 02/18/1515:48 02/20/1517:39 7439-95-4 Manganese 327 mg/kg 3.0 1.5 10 02/18/1515:48 02/21/1516:50 7439-96-5 Molybdenum ND mg/kg 6.0 3.0 10 02/18/1515:48 02/21/1516:50 7439-98-7 Nickel 5.1 mg/kg 3.0 1.5 10 02/18/1515:48 02/21/1516:50 7440-02-0 Potassium 1070 mg/kg 59.7 29.8 1 02/18/1515:48 02/20/1517:39 7440-09-7 Sodium ND mg/kg 59.7 29.8 1 02/18/1515:48 02/20/1517:39 7440-23-5 Strontium 5.4 mg/kg 0.60 0.30 1 02/18/1515:48 02/20/1517:39 7440-24-6 Zinc 25.3 mg/kg 11.9 6.0 10 02/18/1515:48 02/21/1516:50 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 3.0 1.5 50 02/18/1515:48 02/20/1511:26 7440-36-0 Arsenic ND mg/kg 3.0 1.5 50 02/18/1515:48 02/20/1511:26 7440-38-2 Beryllium 0.34J mg/kg 0.36 0.18 50 02/18/1515:48 02/20/1511:26 7440-41-7 Cadmium ND mg/kg 0.36 0.18 50 02/18/1515:48 02/20/1511:26 7440-43-9 Cobalt 5.4 mg/kg 3.0 1.5 50 02/18/1515:48 02/20/1511:26 7440-48-4 Lead 3.3 mg/kg 3.0 1.5 50 02/18/1515:48 02/20/1511:26 7439-92-1 Selenium ND mg/kg 3.0 1.5 50 02/18/1515:48 02/20/1511:26 7782-49-2 Thallium ND mg/kg 3.0 1.5 50 02/18/1515:48 02/20/1511:26 7440-28-0 Vanadium 16.0 mg/kg 3.0 1.5 50 02/18/1515:48 02/20/1511:26 7440-62-2 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury 0.013 mg/kg 0.0093 0.0046 1 02/18/15 17:58 02/22/15 09:59 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 16.8 % 0.10 0.10 1 03/04/15 13:21 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 5.0 Std. Units 0.10 0.10 1 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 299 150 5 Sulfate ND mg/kg 299 150 5 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 29.9 15.0 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/05/2015 11:54 AM without the written consent of Pace Analytical Services, Inc.. [�Y]f�/f6'ifi16'SIl D3 D3 D3 D3 D3 D3 D3,N2 D3 D3 D3 D3 D3 D3 D3 D3 UZ:I 02/16/15 09:40 16887-00-6 D3,M1 02/16/15 09:40 14808-79-8 02/16/15 09:40 14797-55-8 H3 Page 28 of 65 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15020349 Pace Project No.: 92237760 Sample: 2015003935 Lab ID: 92237760001 Collected: 02/05/15 14:30 Received: 02/13/15 13:38 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 3280 mg/kg 603 302 1 02/24/15 08:46 7440-44-0 Total Organic Carbon 3450 mg/kg 598 299 1 02/24/15 08:52 7440-44-0 Total Organic Carbon 3480 mg/kg 603 302 1 02/24/15 08:58 7440-44-0 Total Organic Carbon 3660 mg/kg 598 299 1 02/24/15 09:04 7440-44-0 Mean Total Organic Carbon 3470 mg/kg 601 300 1 02/24/15 08:46 7440-44-0 Surrogates RSD% 4.4 % 1 02/24/15 08:46 Date: 03/05/2015 11:54 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 29 of 65 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15020349 Pace Project No.: 92237760 Sample: 2015003950 Lab ID: 92237760002 Collected: 02/05/15 17:15 Received: 02/13/15 13:38 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 4850 mg/kg 5.1 2.5 1 02/18/1515:48 02/20/1517:47 7429-90-5 Barium 74.4 mg/kg 0.51 0.25 1 02/18/1515:48 02/20/1517:47 7440-39-3 Boron ND mg/kg 25.4 12.7 10 02/18/1515:48 02/21/1516:54 7440-42-8 D3 Calcium 1740 mg/kg 25.4 12.7 1 02/18/1515:48 02/20/1517:47 7440-70-2 Chromium 1.51 mg/kg 2.5 1.3 10 02/18/1515:48 02/21/1516:54 7440-47-3 D3 Copper 4.8 mg/kg 2.5 1.3 10 02/18/1515:48 02/21/1516:54 7440-50-8 D3 Iron 7750 mg/kg 2.0 1.0 1 02/18/1515:48 02/20/1517:47 7439-89-6 Magnesium 3050 mg/kg 25.4 12.7 1 02/18/1515:48 02/20/1517:47 7439-95-4 Manganese 468 mg/kg 2.5 1.3 10 02/18/1515:48 02/21/1516:54 7439-96-5 D3 Molybdenum ND mg/kg 5.1 2.5 10 02/18/1515:48 02/21/1516:54 7439-98-7 D3 Nickel ND mg/kg 2.5 1.3 10 02/18/1515:48 02/21/1516:54 7440-02-0 D3 Potassium 3780 mg/kg 50.9 25.4 1 02/18/1515:48 02/20/1517:47 7440-09-7 Sodium 161 mg/kg 50.9 25.4 1 02/18/1515:48 02/20/1517:47 7440-23-5 Strontium 9.6 mg/kg 0.51 0.25 1 02/18/1515:48 02/20/1517:47 7440-24-6 Zinc 25.4 mg/kg 10.2 5.1 10 02/18/1515:48 02/21/1516:54 7440-66-6 D3 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 2.5 1.3 50 02/18/1515:48 02/20/1511:29 7440-36-0 D3,N2 Arsenic ND mg/kg 2.5 1.3 50 02/18/1515:48 02/20/1511:29 7440-38-2 D3 Beryllium 0.24J mg/kg 0.31 0.15 50 02/18/1515:48 02/20/1511:29 7440-41-7 D3 Cadmium ND mg/kg 0.31 0.15 50 02/18/1515:48 02/20/1511:29 7440-43-9 D3 Cobalt 4.3 mg/kg 2.5 1.3 50 02/18/1515:48 02/20/1511:29 7440-48-4 D3 Lead 1.3J mg/kg 2.5 1.3 50 02/18/1515:48 02/20/1511:29 7439-92-1 D3 Selenium ND mg/kg 2.5 1.3 50 02/18/1515:48 02/20/1511:29 7782-49-2 D3 Thallium ND mg/kg 2.5 1.3 50 02/18/1515:48 02/20/1511:29 7440-28-0 D3 Vanadium 7.6 mg/kg 2.5 1.3 50 02/18/1515:48 02/20/1511:29 7440-62-2 D3 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury ND mg/kg 0.0081 0.0040 1 02/18/1517:58 02/22/1510:01 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 2.0 % 0.10 0.10 1 03/04/15 13:21 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 8.4 Std. Units 0.10 0.10 1 02/17/15 11:50 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 255 128 5 02/16/1510:46 16887-00-6 D3 Sulfate ND mg/kg 255 128 5 02/16/1510:46 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 25.5 12.8 5 02/16/15 10:46 14797-55-8 H3 Date: 03/05/2015 11:54 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 30 of 65 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15020349 Pace Project No.: 92237760 Sample: 2015003950 Lab ID: 92237760002 Collected: 02/05/15 17:15 Received: 02/13/15 13:38 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon ND mg/kg 604 302 1 02/24/15 09:56 7440-44-0 Total Organic Carbon ND mg/kg 597 299 1 02/24/15 10:03 7440-44-0 Total Organic Carbon ND mg/kg 604 302 1 02/24/15 10:09 7440-44-0 Total Organic Carbon ND mg/kg 598 299 1 02/24/15 10:14 7440-44-0 Mean Total Organic Carbon ND mg/kg 601 300 1 02/24/15 09:56 7440-44-0 Surrogates RSD% 4.7 % 1 02/24/15 09:56 Date: 03/05/2015 11:54 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 31 of 65 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15020349 Pace Project No.: 92237760 Sample: 2015003951 Lab ID: 92237760003 Collected: 02/05/15 17:15 Received: 02/13/15 13:38 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 3230 mg/kg 5.5 2.7 1 02/18/1515:48 02/20/1517:51 7429-90-5 Barium 74.5 mg/kg 0.55 0.27 1 02/18/1515:48 02/20/1517:51 7440-39-3 Boron ND mg/kg 2.7 1.4 1 02/18/1515:48 02/20/1517:51 7440-42-8 Calcium 1490 mg/kg 27.3 13.7 1 02/18/1515:48 02/20/1517:51 7440-70-2 Chromium ND mg/kg 2.7 1.4 10 02/18/1515:48 02/21/1516:58 7440-47-3 D3 Copper 5.9 mg/kg 2.7 1.4 10 02/18/1515:48 02/21/1516:58 7440-50-8 D3 Iron 4450 mg/kg 2.2 1.1 1 02/18/1515:48 02/20/1517:51 7439-89-6 Magnesium 2040 mg/kg 27.3 13.7 1 02/18/1515:48 02/20/1517:51 7439-95-4 Manganese 459 mg/kg 2.7 1.4 10 02/18/1515:48 02/21/1516:58 7439-96-5 D3 Molybdenum ND mg/kg 5.5 2.7 10 02/18/1515:48 02/21/1516:58 7439-98-7 D3 Nickel ND mg/kg 2.7 1.4 10 02/18/1515:48 02/21/1516:58 7440-02-0 D3 Potassium 2250 mg/kg 54.7 27.3 1 02/18/1515:48 02/20/1517:51 7440-09-7 Sodium 92.1 mg/kg 54.7 27.3 1 02/18/1515:48 02/20/1517:51 7440-23-5 Strontium 10.7 mg/kg 0.55 0.27 1 02/18/1515:48 02/20/1517:51 7440-24-6 Zinc 14.1 mg/kg 10.9 5.5 10 02/18/1515:48 02/21/1516:58 7440-66-6 D3 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 2.7 1.4 50 02/18/1515:48 02/20/1511:41 7440-36-0 D3,N2 Arsenic ND mg/kg 2.7 1.4 50 02/18/1515:48 02/20/1511:41 7440-38-2 D3 Beryllium 0.16J mg/kg 0.33 0.16 50 02/18/1515:48 02/20/1511:41 7440-41-7 D3 Cadmium ND mg/kg 0.33 0.16 50 02/18/1515:48 02/20/1511:41 7440-43-9 D3 Cobalt 3.6 mg/kg 2.7 1.4 50 02/18/1515:48 02/20/1511:41 7440-48-4 D3 Lead ND mg/kg 2.7 1.4 50 02/18/1515:48 02/20/1511:41 7439-92-1 D3 Selenium ND mg/kg 2.7 1.4 50 02/18/1515:48 02/20/1511:41 7782-49-2 D3 Thallium ND mg/kg 2.7 1.4 50 02/18/1515:48 02/20/1511:41 7440-28-0 D3 Vanadium 4.4 mg/kg 2.7 1.4 50 02/18/1515:48 02/20/1511:41 7440-62-2 D3 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury ND mg/kg 0.0091 0.0045 1 02/18/1517:58 02/22/1510:03 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 10.4 % 0.10 0.10 1 03/04/15 13:21 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 8.6 Std. Units 0.10 0.10 1 02/17/15 11:50 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 280 140 5 02/16/1511:08 16887-00-6 D3 Sulfate ND mg/kg 280 140 5 02/16/1511:08 14808-79-8 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 28.0 14.0 5 02/16/15 11:08 14797-55-8 H3 Date: 03/05/2015 11:54 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 32 of 65 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15020349 Pace Project No.: 92237760 Sample: 2015003951 Lab ID: 92237760003 Collected: 02/05/15 17:15 Received: 02/13/15 13:38 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon ND mg/kg 600 300 1 02/24/15 10:20 7440-44-0 Total Organic Carbon ND mg/kg 603 302 1 02/24/15 10:25 7440-44-0 Total Organic Carbon ND mg/kg 596 298 1 02/24/15 10:30 7440-44-0 Total Organic Carbon ND mg/kg 596 298 1 02/24/15 10:36 7440-44-0 Mean Total Organic Carbon ND mg/kg 599 299 1 02/24/15 10:20 7440-44-0 Surrogates RSD% 5.9 % 1 02/24/15 10:20 Date: 03/05/2015 11:54 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 33 of 65 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15020349 Pace Project No.: 92237760 Sample: 2015003954 Lab ID: 92237760004 Collected: 02/11/15 11:09 Received: 02/13/15 13:38 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 14500 mg/kg 127 63.4 20 02/18/1515:48 02/21/1517:03 7429-90-5 D3 Barium 147 mg/kg 12.7 6.3 20 02/18/1515:48 02/21/1517:03 7440-39-3 D3 Boron ND mg/kg 63.4 31.7 20 02/18/1515:48 02/21/1517:03 7440-42-8 D3 Calcium 1120 mg/kg 634 317 20 02/18/1515:48 02/21/1517:03 7440-70-2 D3 Chromium 62.2 mg/kg 6.3 3.2 20 02/18/1515:48 02/21/1517:03 7440-47-3 D3 Copper 34.7 mg/kg 6.3 3.2 20 02/18/1515:48 02/21/1517:03 7440-50-8 D3 Iron 24700 mg/kg 50.7 25.4 20 02/18/1515:48 02/21/1517:03 7439-89-6 D3 Magnesium 10500 mg/kg 634 317 20 02/18/1515:48 02/21/1517:03 7439-95-4 D3 Manganese 1230 mg/kg 6.3 3.2 20 02/18/1515:48 02/21/1517:03 7439-96-5 D3 Molybdenum ND mg/kg 12.7 6.3 20 02/18/1515:48 02/21/1517:03 7439-98-7 D3 Nickel 29.4 mg/kg 6.3 3.2 20 02/18/1515:48 02/21/1517:03 7440-02-0 D3 Potassium 6590 mg/kg 1270 634 20 02/18/1515:48 02/21/1517:03 7440-09-7 D3 Sodium ND mg/kg 1270 634 20 02/18/1515:48 02/21/1517:03 7440-23-5 D3 Strontium 13.2 mg/kg 12.7 6.3 20 02/18/1515:48 02/21/1517:03 7440-24-6 D3 Zinc 88.9 mg/kg 25.4 12.7 20 02/18/1515:48 02/21/1517:03 7440-66-6 D3 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 3.2 1.6 50 02/18/1515:48 02/20/1511:44 7440-36-0 D3,N2 Arsenic ND mg/kg 3.2 1.6 50 02/18/1515:48 02/20/1511:44 7440-38-2 D3 Beryllium 0.82 mg/kg 0.38 0.19 50 02/18/1515:48 02/20/1511:44 7440-41-7 D3 Cadmium ND mg/kg 0.38 0.19 50 02/18/1515:48 02/23/1512:04 7440-43-9 D3 Cobalt 21.3 mg/kg 3.2 1.6 50 02/18/1515:48 02/20/1511:44 7440-48-4 D3 Lead 8.9 mg/kg 3.2 1.6 50 02/18/1515:48 02/20/1511:44 7439-92-1 D3 Selenium ND mg/kg 3.2 1.6 50 02/18/1515:48 02/20/1511:44 7782-49-2 D3 Thallium ND mg/kg 3.2 1.6 50 02/18/1515:48 02/20/1511:44 7440-28-0 D3 Vanadium 50.6 mg/kg 3.2 1.6 50 02/18/1515:48 02/20/1511:44 7440-62-2 D4 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury ND mg/kg 0.0096 0.0048 1 02/18/1517:58 02/22/1510:05 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 19.5 % 0.10 0.10 1 03/04/15 13:21 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 6.0 Std. Units 0.10 0.10 1 02/18/15 11:30 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 309 154 5 02/16/1511:31 16887-00-6 D3 Sulfate ND mg/kg 309 154 5 02/16/1511:31 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 30.9 15.4 5 02/16/15 11:31 14797-55-8 H3 Date: 03/05/2015 11:54 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 34 of 65 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15020349 Pace Project No.: 92237760 Sample: 2015003954 Lab ID: 92237760004 Collected: 02/11/15 11:09 Received: 02/13/15 13:38 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon ND mg/kg 600 300 1 02/24/15 10:43 7440-44-0 Total Organic Carbon ND mg/kg 598 299 1 02/24/15 10:48 7440-44-0 Total Organic Carbon ND mg/kg 602 301 1 02/24/15 10:53 7440-44-0 Total Organic Carbon ND mg/kg 596 298 1 02/24/15 10:59 7440-44-0 Mean Total Organic Carbon ND mg/kg 599 300 1 02/24/15 10:43 7440-44-0 Surrogates RSD% 25.0 % 1 02/24/15 10:43 Date: 03/05/2015 11:54 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 35 of 65 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15020349 Pace Project No.: 92237760 Sample: 2015003955 Lab ID: 92237760005 Collected: 02/11/15 15:18 Received: 02/13/15 13:38 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 8330 mg/kg 106 53.1 20 02/18/1515:48 02/21/1517:07 7429-90-5 D3 Barium 130 mg/kg 0.53 0.27 1 02/18/1515:48 02/20/1518:42 7440-39-3 Boron ND mg/kg 53.1 26.5 20 02/18/1515:48 02/21/1517:07 7440-42-8 D3 Calcium 883 mg/kg 26.5 13.3 1 02/18/1515:48 02/20/1518:42 7440-70-2 Chromium 67.1 mg/kg 5.3 2.7 20 02/18/1515:48 02/21/1517:07 7440-47-3 D3 Copper 19.8 mg/kg 5.3 2.7 20 02/18/1515:48 02/21/1517:07 7440-50-8 D3 Iron 11400 mg/kg 2.1 1.1 1 02/18/1515:48 02/20/1518:42 7439-89-6 Magnesium 6370 mg/kg 26.5 13.3 1 02/18/1515:48 02/20/1518:42 7439-95-4 Manganese 875 mg/kg 5.3 2.7 20 02/18/1515:48 02/21/1517:07 7439-96-5 D3 Molybdenum ND mg/kg 10.6 5.3 20 02/18/1515:48 02/21/1517:07 7439-98-7 D3 Nickel 24.0 mg/kg 5.3 2.7 20 02/18/1515:48 02/21/1517:07 7440-02-0 D3 Potassium 2700 mg/kg 53.1 26.5 1 02/18/1515:48 02/20/1518:42 7440-09-7 Sodium 68.7 mg/kg 53.1 26.5 1 02/18/1515:48 02/20/1518:42 7440-23-5 Strontium 9.9 mg/kg 0.53 0.27 1 02/18/1515:48 02/20/1518:42 7440-24-6 Zinc 29.0 mg/kg 21.2 10.6 20 02/18/1515:48 02/21/1517:07 7440-66-6 D3 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 2.7 1.3 50 02/18/1515:48 02/20/1511:47 7440-36-0 D3,N2 Arsenic ND mg/kg 2.7 1.3 50 02/18/1515:48 02/20/1511:47 7440-38-2 D3 Beryllium 0.24J mg/kg 0.32 0.16 50 02/18/1515:48 02/20/1511:47 7440-41-7 D3 Cadmium ND mg/kg 0.32 0.16 50 02/18/1515:48 02/20/1511:47 7440-43-9 D3 Cobalt 7.4 mg/kg 2.7 1.3 50 02/18/1515:48 02/20/1511:47 7440-48-4 D3 Lead 3.4 mg/kg 2.7 1.3 50 02/18/1515:48 02/20/1511:47 7439-92-1 D3 Selenium ND mg/kg 2.7 1.3 50 02/18/1515:48 02/20/1511:47 7782-49-2 D3 Thallium ND mg/kg 2.7 1.3 50 02/18/1515:48 02/20/1511:47 7440-28-0 D3 Vanadium 25.2 mg/kg 2.7 1.3 50 02/18/1515:48 02/20/1511:47 7440-62-2 D4 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury ND mg/kg 0.0082 0.0041 1 02/18/1517:58 02/22/1510:08 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 6.6 % 0.10 0.10 1 03/04/15 13:21 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 6.9 Std. Units 0.10 0.10 1 02/19/15 10:25 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 267 134 5 02/16/1511:53 16887-00-6 D3 Sulfate ND mg/kg 267 134 5 02/16/1511:53 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 26.7 13.4 5 02/16/15 11:53 14797-55-8 H3 Date: 03/05/2015 11:54 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 36 of 65 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15020349 Pace Project No.: 92237760 Sample: 2015003955 Lab ID: 92237760005 Collected: 02/11/15 15:18 Received: 02/13/15 13:38 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon ND mg/kg 599 300 1 02/24/15 11:04 7440-44-0 Total Organic Carbon ND mg/kg 597 298 1 02/24/15 11:11 7440-44-0 Total Organic Carbon ND mg/kg 598 299 1 02/24/15 11:16 7440-44-0 Total Organic Carbon ND mg/kg 601 300 1 02/24/15 11:22 7440-44-0 Mean Total Organic Carbon ND mg/kg 599 299 1 02/24/15 11:04 7440-44-0 Surrogates RSD% 5.7 % 1 02/24/15 11:04 Date: 03/05/2015 11:54 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 37 of 65 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15020349 Pace Project No.: 92237760 Sample: 2015003952 Lab ID: 92237760006 Collected: 02/05/15 14:30 Received: 02/13/15 13:38 Matrix: Solid Results reported on a "wet -weight" basis Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 300.0 IC Anions, SPLP Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 02/18/15 16:35 Sulfate 2.6 mg/L 2.0 1.0 1 02/21/1519:24 14808-79-8 353.2 Nitrogen, NO2/NO3, SPLP Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 02/18/15 16:35 Nitrogen, Nitrate 0.27 mg/L 0.20 0.20 1 02/20/15 21:33 P4 4500 Chloride, SPLP Analytical Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 02/18/15 16:35 Chloride ND mg/L 5.0 2.5 1 02/21/15 01:50 16887-00-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/05/2015 11:54 AM without the written consent of Pace Analytical Services, Inc.. Page 38 of 65 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15020349 Pace Project No.: 92237760 Sample: 2015003953 Lab ID: 92237760007 Collected: 02/11/15 15:08 Received: 02/13/15 13:38 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 23700 mg/kg 5.5 2.7 1 02/18/1515:48 02/20/1518:46 7429-90-5 Barium 193 mg/kg 0.55 0.27 1 02/18/1515:48 02/20/1518:46 7440-39-3 Boron 31.OJ mg/kg 54.5 27.3 20 02/18/1515:48 02/21/1517:11 7440-42-8 Calcium 3740 mg/kg 27.3 13.6 1 02/18/1515:48 02/20/1518:46 7440-70-2 Chromium 419 mg/kg 5.5 2.7 20 02/18/1515:48 02/21/1517:11 7440-47-3 Copper 45.7 mg/kg 5.5 2.7 20 02/18/1515:48 02/21/1517:11 7440-50-8 Iron 31300 mg/kg 43.6 21.8 20 02/18/1515:48 02/21/1517:11 7439-89-6 Magnesium 29900 mg/kg 545 273 20 02/18/1515:48 02/21/1517:11 7439-95-4 Manganese 933 mg/kg 5.5 2.7 20 02/18/1515:48 02/21/1517:11 7439-96-5 Molybdenum ND mg/kg 10.9 5.5 20 02/18/1515:48 02/21/1517:11 7439-98-7 Nickel 157 mg/kg 5.5 2.7 20 02/18/1515:48 02/21/1517:11 7440-02-0 Potassium 5450 mg/kg 54.5 27.3 1 02/18/1515:48 02/20/1518:46 7440-09-7 Sodium 173 mg/kg 54.5 27.3 1 02/18/1515:48 02/20/1518:46 7440-23-5 Strontium 33.6 mg/kg 0.55 0.27 1 02/18/1515:48 02/20/1518:46 7440-24-6 Zinc 59.4 mg/kg 21.8 10.9 20 02/18/1515:48 02/21/1517:11 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 2.7 1.4 50 02/18/1515:48 02/20/1511:50 7440-36-0 Arsenic ND mg/kg 2.7 1.4 50 02/18/1515:48 02/20/1511:50 7440-38-2 Beryllium 0.39 mg/kg 0.33 0.16 50 02/18/1515:48 02/20/1511:50 7440-41-7 Cadmium ND mg/kg 0.33 0.16 50 02/18/1515:48 02/20/1511:50 7440-43-9 Cobalt 32.9 mg/kg 2.7 1.4 50 02/18/1515:48 02/20/1511:50 7440-48-4 Lead 2.OJ mg/kg 2.7 1.4 50 02/18/1515:48 02/20/1511:50 7439-92-1 Selenium ND mg/kg 2.7 1.4 50 02/18/1515:48 02/20/1511:50 7782-49-2 Thallium ND mg/kg 2.7 1.4 50 02/18/1515:48 02/20/1511:50 7440-28-0 Vanadium 75.8 mg/kg 2.7 1.4 50 02/18/1515:48 02/20/1511:50 7440-62-2 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury ND mg/kg 0.0089 0.0044 1 02/18/1517:58 02/22/1510:10 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 8.4 % 0.10 0.10 1 03/04/15 13:21 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 7.4 Std. Units 0.10 0.10 1 02/22/15 14:10 300.0 IC Anions, SPLP Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 02/18/15 16:35 Sulfate 2.8 mg/L 2.2 1.1 1 02/21/1519:38 14808-79-8 353.2 Nitrogen, NO2/NO3, SPLP Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 02/18/15 16:35 Nitrogen, Nitrate 0.29 mg/L 0.22 0.22 1 02/20/15 21:34 4500 Chloride, SPLP Analytical Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 02/18/15 16:35 Chloride ND mg/L 5.5 2.7 1 02/21/15 01:51 16887-00-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/05/2015 11:54 AM without the written consent of Pace Analytical Services, Inc.. D3 D3 D3 D3 D3 D3 D3 D3 D3 D3,N2 D3 D3 D3 D4 D3 D3 D3 D4 P4 Page 39 of 65 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15020349 Pace Project No.: 92237760 Sample: 2015003953 Lab ID: 92237760007 Collected: 02/11/15 15:08 Received: 02/13/15 13:38 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 272 136 5 02/16/1512:15 16887-00-6 D3 Sulfate ND mg/kg 272 136 5 02/16/1512:15 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 27.2 13.6 5 02/16/15 12:15 14797-55-8 H3 Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon ND mg/kg 597 298 1 02/24/15 11:27 7440-44-0 Total Organic Carbon ND mg/kg 597 299 1 02/24/15 11:33 7440-44-0 Total Organic Carbon ND mg/kg 597 299 1 02/24/15 11:38 7440-44-0 Total Organic Carbon ND mg/kg 598 299 1 02/24/15 11:45 7440-44-0 Mean Total Organic Carbon ND mg/kg 597 299 1 02/24/15 11:27 7440-44-0 Surrogates RSD% 1.8 % 1 02/24/15 11:27 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/05/2015 11:54 AM without the written consent of Pace Analytical Services, Inc.. Page 40 of 65 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15020349 Pace Project No.: 92237760 Sample: 2015003952 SPLP METALS Lab ID: 92237760008 Collected: 02/05/15 14:30 Received: 02/13/15 13:38 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;T➢Z17c\�iil=11 a Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470 Mercury Mercury Date: 03/05/2015 11:54 AM Analytical Method: EPA 6020A Preparation Method: EPA 3020 8440 ug/L 10.0 1.2 1 02/24/15 22:18 02/25/15 09:07 7429-90-5 ND ug/L 0.50 0.25 1 02/24/15 22:18 02/25/15 09:07 7440-36-0 0.67 ug/L 0.50 0.25 1 02/24/15 22:18 02/25/15 09:07 7440-38-2 96.5 ug/L 0.30 0.14 1 02/24/15 22:18 02/25/15 09:07 7440-39-3 0.42 ug/L 0.20 0.066 1 02/24/15 22:18 02/25/15 09:07 7440-41-7 7.8 ug/L 5.0 1.0 1 02/24/15 22:18 02/25/15 09:07 7440-42-8 ND ug/L 0.080 0.033 1 02/24/15 22:18 02/25/15 09:07 7440-43-9 1160 ug/L 40.0 8.4 1 02/24/15 22:18 02/25/15 09:07 7440-70-2 7.2 ug/L 0.50 0.22 1 02/24/15 22:18 02/25/15 09:07 7440-47-3 1.7 ug/L 0.50 0.25 1 02/24/15 22:18 02/25/15 09:07 7440-48-4 5.0 ug/L 1.0 0.22 1 02/24/15 22:18 02/25/15 09:07 7440-50-8 6500 ug/L 50.0 8.0 1 02/24/15 22:18 02/25/15 09:07 7439-89-6 3.2 ug/L 0.10 0.046 1 02/24/15 22:18 02/25/15 09:07 7439-92-1 1580 ug/L 10.0 2.8 1 02/24/15 22:18 02/25/15 09:07 7439-95-4 72.8 ug/L 0.50 0.14 1 02/24/15 22:18 02/25/15 09:07 7439-96-5 ND ug/L 0.50 0.24 1 02/24/15 22:18 02/25/15 09:07 7439-98-7 3.2 ug/L 0.50 0.23 1 02/24/15 22:18 02/25/15 09:07 7440-02-0 738 ug/L 50.0 8.3 1 02/24/15 22:18 02/25/15 09:07 7440-09-7 ND ug/L 0.50 0.25 1 02/24/15 22:18 02/25/15 09:07 7782-49-2 3220 ug/L 50.0 18.2 1 02/24/15 22:18 02/25/15 09:07 7440-23-5 18.7 ug/L 0.50 0.057 1 02/24/15 22:18 02/25/15 09:07 7440-24-6 ND ug/L 0.10 0.025 1 02/24/15 22:18 02/25/15 09:07 7440-28-0 11.6 ug/L 1.0 0.21 1 02/24/15 22:18 02/25/15 09:07 7440-62-2 23.1 ug/L 5.0 2.5 1 02/24/15 22:18 02/25/15 09:07 7440-66-6 Analytical Method: EPA 7470 Preparation Method: EPA 7470 ND ug/L 1.2 0.16 1 02/24/1517:30 02/25/1517:11 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 41 of 65 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15020349 Pace Project No.: 92237760 Sample: 2015003953 SPLP METALS Lab ID: 92237760009 Collected: 02/11/15 15:08 Received: 02/13/15 13:38 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;T➢Z17c\��il=11 a r 6? Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470 Mercury Mercury Date: 03/05/2015 11:54 AM Analytical Method: EPA 6020A Preparation Method: EPA 3020 53900 ug/L 100 11.5 10 02/24/15 22:18 02/25/15 09:50 7429-90-5 ND ug/L 0.50 0.25 1 02/24/15 22:18 02/25/15 09:16 7440-36-0 0.82 ug/L 0.50 0.25 1 02/24/15 22:18 02/25/15 09:16 7440-38-2 702 ug/L 3.0 1.4 10 02/24/15 22:18 02/25/15 09:50 7440-39-3 0.78 ug/L 0.20 0.066 1 02/24/15 22:18 02/25/15 09:16 7440-41-7 ND ug/L 5.0 1.0 1 02/24/15 22:18 02/25/15 09:16 7440-42-8 0.24 ug/L 0.080 0.033 1 02/24/15 22:18 02/25/15 10:10 7440-43-9 12800 ug/L 40.0 8.4 1 02/24/15 22:18 02/25/15 09:16 7440-70-2 858 ug/L 5.0 2.2 10 02/24/15 22:18 02/25/15 09:50 7440-47-3 83.7 ug/L 0.50 0.25 1 02/24/15 22:18 02/25/15 09:16 7440-48-4 161 ug/L 1.0 0.22 1 02/24/15 22:18 02/25/15 09:16 7440-50-8 93400 ug/L 500 80.2 10 02/24/15 22:18 02/25/15 09:50 7439-89-6 5.7 ug/L 0.10 0.046 1 02/24/15 22:18 02/25/15 09:16 7439-92-1 58200 ug/L 100 28.5 10 02/24/15 22:18 02/25/15 09:50 7439-95-4 3410 ug/L 5.0 1.4 10 02/24/15 22:18 02/25/15 09:50 7439-96-5 ND ug/L 0.50 0.24 1 02/24/15 22:18 02/25/15 09:16 7439-98-7 311 ug/L 0.50 0.23 1 02/24/15 22:18 02/25/15 09:16 7440-02-0 6360 ug/L 50.0 8.3 1 02/24/15 22:18 02/25/15 09:16 7440-09-7 ND ug/L 0.50 0.25 1 02/24/15 22:18 02/25/15 09:16 7782-49-2 3740 ug/L 50.0 18.2 1 02/24/15 22:18 02/25/15 09:16 7440-23-5 169 ug/L 0.50 0.057 1 02/24/15 22:18 02/25/15 09:16 7440-24-6 0.28 ug/L 0.10 0.025 1 02/24/15 22:18 02/25/15 09:16 7440-28-0 166 ug/L 1.0 0.21 1 02/24/15 22:18 02/25/15 09:16 7440-62-2 118 ug/L 5.0 2.5 1 02/24/15 22:18 02/25/15 09:16 7440-66-6 Analytical Method: EPA 7470 Preparation Method: EPA 7470 ND ug/L 1.2 0.16 1 02/24/1517:30 02/25/1517:14 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 42 of 65 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15020349 Pace Project No.: 92237760 QC Batch: MERP/12810 Analysis Method: EPA 7470 QC Batch Method: EPA 7470 Analysis Description: 7470 Mercury Associated Lab Samples: 92237760008, 92237760009 METHOD BLANK: 1905056 Matrix: Water Associated Lab Samples: 92237760008, 92237760009 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury ug/L ND 0.20 02/25/1516:39 LABORATORY CONTROL SAMPLE: 1905057 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 5 5.4 107 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1905794 1905795 MS MSD 92238285007 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 5 5 5.5 5.5 111 109 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/05/2015 11:54 AM without the written consent of Pace Analytical Services, Inc.. Page 43 of 65 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15020349 Pace Project No.: 92237760 QC Batch: MERP/5386 Analysis Method: EPA 7471 QC Batch Method: EPA 7471 Analysis Description: 7471 Mercury Associated Lab Samples: 92237760001, 92237760002, 92237760003, 92237760004, 92237760005, 92237760007 METHOD BLANK: 1134154 Matrix: Solid Associated Lab Samples: 92237760001, 92237760002, 92237760003, 92237760004, 92237760005, 92237760007 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury mg/kg ND 0.0082 02/22/15 09:33 LABORATORY CONTROL SAMPLE: 1134155 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury mg/kg .08 0.082 102 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1134156 1134157 MS MSD 92237650015 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury mg/kg 0.036 .126 .132 0.16 0.16 98 92 80-120 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/05/2015 11:54 AM without the written consent of Pace Analytical Services, Inc.. Page 44 of 65 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15020349 Pace Project No.: 92237760 QC Batch: MPRP/22732 Analysis Method: EPA 6010 QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid Associated Lab Samples: 92237760001, 92237760002, 92237760003, 92237760004, 92237760005, 92237760007 METHOD BLANK: 1134158 Matrix: Solid Associated Lab Samples: 92237760001, 92237760002, 92237760003, 92237760004, 92237760005, 92237760007 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Aluminum mg/kg ND 5.0 02/21/1515:20 Barium mg/kg ND 0.50 02/21/1515:20 Boron mg/kg ND 2.5 02/21/1515:20 Calcium mg/kg ND 25.2 02/21/1515:20 Chromium mg/kg ND 0.25 02/21/1515:20 Copper mg/kg ND 0.25 02/21/1515:20 Iron mg/kg ND 2.0 02/21/1515:20 Magnesium mg/kg ND 25.2 02/21/1515:20 Manganese mg/kg ND 0.25 02/21/1515:20 Molybdenum mg/kg ND 0.50 02/21/1515:20 Nickel mg/kg ND 0.25 02/21/1515:20 Potassium mg/kg ND 50.4 02/21/1515:20 Sodium mg/kg ND 50.4 02/21/1515:20 Strontium mg/kg ND 0.50 02/21/1515:20 Zinc mg/kg ND 1.0 02/21/1515:20 LABORATORY CONTROL SAMPLE: Parameter 1134159 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Aluminum mg/kg 124 124 100 80-120 Barium mg/kg 12.4 12.5 101 80-120 Boron mg/kg 124 126 102 80-120 Calcium mg/kg 619 612 99 80-120 Chromium mg/kg 12.4 12.2 98 80-120 Copper mg/kg 12.4 12.2 99 80-120 Iron mg/kg 124 118 96 80-120 Magnesium mg/kg 619 623 101 80-120 Manganese mg/kg 12.4 12.5 101 80-120 Molybdenum mg/kg 12.4 12.6 102 80-120 Nickel mg/kg 12.4 12.6 102 80-120 Potassium mg/kg 619 608 98 80-120 Sodium mg/kg 619 612 99 80-120 Strontium mg/kg 12.4 12.7 103 80-120 Zinc mg/kg 61.9 63.3 102 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/05/2015 11:54 AM without the written consent of Pace Analytical Services, Inc.. Page 45 of 65 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15020349 Pace Project No.: 92237760 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1134160 1134161 MS MSD 92237739001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum mg/kg 2760 129 135 5310 5320 1990 1900 75-125 0 20 M1 Barium mg/kg 6.0 12.9 13.5 21.0 21.0 117 112 75-125 0 20 Boron mg/kg 3.5 129 135 120 119 91 86 75-125 1 20 Calcium mg/kg 19.01 642 673 664 651 100 94 75-125 2 20 Chromium mg/kg 3.4 12.9 13.5 15.8 16.2 97 95 75-125 2 20 Copper mg/kg 1.9 12.9 13.5 14.9 14.9 101 97 75-125 0 20 Iron mg/kg 3470 129 135 4040 4100 440 464 75-125 1 20 M1 Magnesium mg/kg 106 642 673 822 809 112 104 75-125 2 20 Manganese mg/kg 22.7 12.9 13.5 31.6 30.8 69 60 75-125 3 20 M1 Molybdenum mg/kg ND 12.9 13.5 10.8 11.5 84 85 75-125 6 20 Nickel mg/kg 1.0 12.9 13.5 14.2 15.0 103 104 75-125 5 20 Potassium mg/kg 62.3 642 673 702 725 100 99 75-125 3 20 Sodium mg/kg ND 642 673 647 646 100 95 75-125 0 20 Strontium mg/kg 0.52 12.9 13.5 13.4 14.2 100 102 75-125 6 20 Zinc mg/kg 2.8 64.2 67.3 67.6 69.7 101 100 75-125 3 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/05/2015 11:54 AM without the written consent of Pace Analytical Services, Inc.. Page 46 of 65 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15020349 Pace Project No.: 92237760 QC Batch: MPRP/22733 Analysis Method: EPA 6020 QC Batch Method: EPA 3050 Analysis Description: 6020 MET Associated Lab Samples: 92237760001, 92237760002, 92237760003, 92237760004, 92237760005, 92237760007 METHOD BLANK: 1134162 Matrix: Solid Associated Lab Samples: 92237760001, 92237760002, 92237760003, 92237760004, 92237760005, 92237760007 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Antimony mg/kg ND 0.051 02/20/1510:43 N2 Arsenic mg/kg ND 0.051 02/20/1510:43 Beryllium mg/kg ND 0.0061 02/20/1510:43 Cadmium mg/kg ND 0.0061 02/20/1510:43 Cobalt mg/kg ND 0.051 02/20/1510:43 Lead mg/kg ND 0.051 02/20/1510:43 Selenium mg/kg ND 0.051 02/20/1510:43 Thallium mg/kg ND 0.051 02/20/1510:43 Vanadium mg/kg ND 0.051 02/20/1510:43 LABORATORY CONTROL SAMPLE: Parameter 1134163 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Antimony mg/kg 2.5 2.4 94 80-120 N2 Arsenic mg/kg 2.5 2.5 100 80-120 Beryllium mg/kg .25 0.25 100 80-120 Cadmium mg/kg .25 0.25 98 80-120 Cobalt mg/kg 2.5 2.6 103 80-120 Lead mg/kg 2.5 2.6 102 80-120 Selenium mg/kg 2.5 2.5 98 80-120 Thallium mg/kg 2.5 2.5 100 80-120 Vanadium mg/kg 2.5 2.5 98 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1134164 MS 92237739001 Spike Parameter Units Result Conc. MSD Spike Conc. 1134165 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits Max RPD RPD Qual Antimony mg/kg ND 2.66 2.66 1.5J 1.7J 56 64 75-125 20 D3,M6, N2 Arsenic mg/kg ND 2.66 2.66 3.1 3.0 92 89 75-125 4 20 D3 Beryllium mg/kg 0.17J .266 .266 0.40 0.43 87 100 75-125 7 20 D3 Cadmium mg/kg ND .266 .266 0.34 0.23J 127 89 75-125 20 D3,M6 Cobalt mg/kg 1.4J 2.66 2.66 4.1 4.0 103 99 75-125 5 20 D3 Lead mg/kg 3.4 2.66 2.66 6.3 6.1 109 104 75-125 3 20 D3 Selenium mg/kg ND 2.66 2.66 2.5J 2.7 68 79 75-125 20 D3,M6 Thallium mg/kg ND 2.66 2.66 2.7 2.5J 87 81 75-125 20 D3 Vanadium mg/kg 8.4 2.66 2.66 11.6 11.1 117 102 75-125 4 20 D3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/05/2015 11:54 AM without the written consent of Pace Analytical Services, Inc.. Page 47 of 65 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15020349 Pace Project No.: 92237760 QC Batch: MPRP/52559 Analysis Method: EPA 6020A QC Batch Method: EPA 3020 Analysis Description: 6020A Water UPD4 Associated Lab Samples: 92237760008, 92237760009 METHOD BLANK: 1905028 Associated Lab Samples: 92237760008, 92237760009 Parameter Units Aluminum ug/L Antimony ug/L Arsenic ug/L Barium ug/L Beryllium ug/L Boron ug/L Cadmium ug/L Calcium ug/L Chromium ug/L Cobalt ug/L Copper ug/L Iron ug/L Lead ug/L Magnesium ug/L Manganese ug/L Molybdenum ug/L Nickel ug/L Potassium ug/L Selenium ug/L Sodium ug/L Strontium ug/L Thallium ug/L Vanadium ug/L Zinc ug/L Matrix: Water Blank Result Reporting Limit Analyzed ND 10.0 02/25/15 08:41 ND 0.50 02/25/15 08:41 ND 0.50 02/25/15 08:41 ND 0.30 02/25/15 08:41 ND 0.20 02/25/15 08:41 ND 5.0 02/25/15 08:41 ND 0.080 02/25/15 08:41 ND 40.0 02/25/15 08:41 ND 0.50 02/25/15 08:41 ND 0.50 02/25/15 08:41 ND 1.0 02/25/15 08:41 ND 50.0 02/25/15 08:41 ND 0.10 02/25/15 08:41 ND 10.0 02/25/15 08:41 ND 0.50 02/25/15 08:41 ND 0.50 02/25/15 08:41 ND 0.50 02/25/15 08:41 ND 50.0 02/25/15 08:41 ND 0.50 02/25/15 08:41 ND 50.0 02/25/15 08:41 ND 0.50 02/25/15 08:41 ND 0.10 02/25/15 08:41 ND 1.0 02/25/15 08:41 ND 5.0 02/25/15 08:41 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 1905029 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Aluminum ug/L 80 79.8 100 80-120 Antimony ug/L 80 80.0 100 80-120 Arsenic ug/L 80 80.4 100 80-120 Barium ug/L 80 79.1 99 80-120 Beryllium ug/L 80 75.4 94 80-120 Boron ug/L 80 77.0 96 80-120 Cadmium ug/L 80 80.6 101 80-120 Calcium ug/L 1000 969 97 80-120 Chromium ug/L 80 85.1 106 80-120 Cobalt ug/L 80 84.3 105 80-120 Copper ug/L 80 88.0 110 80-120 Iron ug/L 1000 1040 104 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/05/2015 11:54 AM without the written consent of Pace Analytical Services, Inc.. Page 48 of 65 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15020349 Pace Project No.: 92237760 LABORATORY CONTROL SAMPLE: 1905029 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Lead ug/L 80 83.8 105 80-120 Magnesium ug/L 1000 1030 103 80-120 Manganese ug/L 80 84.6 106 80-120 Molybdenum ug/L 80 82.4 103 80-120 Nickel ug/L 80 84.9 106 80-120 Potassium ug/L 1000 1020 102 80-120 Selenium ug/L 80 80.1 100 80-120 Sodium ug/L 1000 1040 104 80-120 Strontium ug/L 80 78.5 98 80-120 Thallium ug/L 80 84.4 105 80-120 Vanadium ug/L 80 83.5 104 80-120 Zinc ug/L 80 86.1 108 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1905179 1905180 MS MSD 92238285008 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum ug/L ND 80 80 84.5 105 102 127 75-125 21 20 M1,R1 Antimony ug/L ND 80 80 83.3 83.6 104 104 75-125 0 20 Arsenic ug/L ND 80 80 83.9 84.6 105 106 75-125 1 20 Barium ug/L ND 80 80 82.1 82.3 103 103 75-125 0 20 Beryllium ug/L ND 80 80 77.8 76.8 97 96 75-125 1 20 Boron ug/L ND 80 80 81.1 80.4 100 100 75-125 1 20 Cadmium ug/L ND 80 80 82.3 82.9 103 104 75-125 1 20 Calcium ug/L ND 1000 1000 1030 1040 102 103 75-125 1 20 Chromium ug/L ND 80 80 88.0 90.0 110 112 75-125 2 20 Cobalt ug/L ND 80 80 87.4 88.8 109 111 75-125 2 20 Copper ug/L ND 80 80 90.9 92.1 113 114 75-125 1 20 Iron ug/L ND 1000 1000 1060 1090 106 108 75-125 2 20 Lead ug/L 24.4 80 80 86.8 87.5 78 79 75-125 1 20 Magnesium ug/L ND 1000 1000 1080 1110 108 111 75-125 2 20 Manganese ug/L ND 80 80 88.0 90.2 110 113 75-125 2 20 Molybdenum ug/L ND 80 80 85.2 87.0 106 109 75-125 2 20 Nickel ug/L ND 80 80 88.3 89.8 110 112 75-125 2 20 Potassium ug/L ND 1000 1000 1050 1080 105 108 75-125 3 20 Selenium ug/L ND 80 80 80.9 80.6 101 101 75-125 0 20 Sodium ug/L ND 1000 1000 1080 1100 108 109 75-125 2 20 Strontium ug/L ND 80 80 81.4 82.5 102 103 75-125 1 20 Thallium ug/L ND 80 80 87.7 88.1 110 110 75-125 0 20 Vanadium ug/L ND 80 80 86.0 87.7 107 109 75-125 2 20 Zinc ug/L ND 80 80 88.0 90.0 108 110 75-125 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/05/2015 11:54 AM without the written consent of Pace Analytical Services, Inc.. Page 49 of 65 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15020349 Pace Project No.: 92237760 QC Batch: PMST/3302 Analysis Method: ASTM D2974-87 QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture Associated Lab Samples: 92237760001, 92237760002, 92237760003, 92237760004, 92237760005, 92237760007 SAMPLE DUPLICATE: 1146078 92237650001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 9.8 9.4 4 10 SAMPLE DUPLICATE: 1146084 92237650011 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 5.0 3.9 25 10 D6 SAMPLE DUPLICATE: 1146085 92237760002 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 2.0 1.9 10 10 SAMPLE DUPLICATE: 1146086 35177074004 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 23.9 24.4 2 10 SAMPLE DUPLICATE: 1146087 92238666008 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 40.9 43.8 7 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/05/2015 11:54 AM without the written consent of Pace Analytical Services, Inc.. Page 50 of 65 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15020349 Pace Project No.: 92237760 QC Batch: WET/35731 Analysis Method: EPA 9045 QC Batch Method: EPA 9045 Analysis Description: 9045 pH Associated Lab Samples: 92237760001, 92237760002, 92237760003 SAMPLE DUPLICATE: 1392421 92237760001 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 5.0 4.9 1 10 SAMPLE DUPLICATE: 1392422 92237650009 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 5.0 5.1 2 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/05/2015 11:54 AM without the written consent of Pace Analytical Services, Inc.. Page 51 of 65 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15020349 Pace Project No.: 92237760 QC Batch: WET/35750 Analysis Method: EPA 9045 QC Batch Method: EPA 9045 Analysis Description: 9045 pH Associated Lab Samples: 92237760004 SAMPLE DUPLICATE: 1393147 Parameter pH at 25 Degrees C SAMPLE DUPLICATE: 1393148 Parameter pH at 25 Degrees C 92237746005 Dup Max Units Result Result RPD RPD Qualifiers Std. Units 6.0 5.6 7 10 92237650012 Dup Max Units Result Result RPD RPD Qualifiers Std. Units 9.2 9.1 1 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/05/2015 11:54 AM without the written consent of Pace Analytical Services, Inc.. Page 52 of 65 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15020349 Pace Project No.: 92237760 QC Batch: WET/35767 Analysis Method: EPA 9045 QC Batch Method: EPA 9045 Analysis Description: 9045 pH Associated Lab Samples: 92237760005 SAMPLE DUPLICATE: 1393405 Parameter pH at 25 Degrees C SAMPLE DUPLICATE: 1393406 Parameter pH at 25 Degrees C 92237903003 Dup Max Units Result Result RPD RPD Qualifiers Std. Units 5.5 5.5 1 10 92237903009 Dup Max Units Result Result RPD RPD Qualifiers Std. Units 5.9 6.0 1 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/05/2015 11:54 AM without the written consent of Pace Analytical Services, Inc.. Page 53 of 65 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15020349 Pace Project No.: 92237760 QC Batch: WET/35836 Analysis Method: EPA 9045 QC Batch Method: EPA 9045 Analysis Description: 9045 pH Associated Lab Samples: 92237760007 SAMPLE DUPLICATE: 1395969 Parameter pH at 25 Degrees C SAMPLE DUPLICATE: 1395970 Parameter pH at 25 Degrees C 92237746017 Dup Max Units Result Result RPD RPD Qualifiers Std. Units 7.4 7.5 2 10 92238285001 Dup Max Units Result Result RPD RPD Qualifiers Std. Units 7.6 7.6 1 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/05/2015 11:54 AM without the written consent of Pace Analytical Services, Inc.. Page 54 of 65 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15020349 Pace Project No.: 92237760 QC Batch: WETA/21979 Analysis Method: EPA 300.0 QC Batch Method: EPA 300.0 Analysis Description: 300.0 IC Anions Associated Lab Samples: 92237760006, 92237760007 METHOD BLANK: 1395669 Matrix: Water Associated Lab Samples: 92237760006, 92237760007 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Sulfate mg/L ND 2.0 02/21/1514:50 LABORATORY CONTROL SAMPLE: 1395670 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfate mg/L 20 19.0 95 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1395671 1395672 MS MSD 92237650008 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfate mg/L 12.7 23.9 23.9 36.9 37.1 101 102 1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1395673 1395674 MS MSD 92237746019 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfate mg/L 5.7 20 20 25.1 25.0 97 96 0 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/05/2015 11:54 AM without the written consent of Pace Analytical Services, Inc.. Page 55 of 65 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15020349 Pace Project No.: 92237760 QC Batch: WETA/21986 Analysis Method: EPA 353.2 QC Batch Method: EPA 353.2 Analysis Description: 353.2 Nitrate + Nitrite, Unpres. Associated Lab Samples: 92237760006, 92237760007 METHOD BLANK: 1395834 Matrix: Water Associated Lab Samples: 92237760006, 92237760007 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, Nitrate mg/L ND 0.020 02/20/15 21:30 LABORATORY CONTROL SAMPLE: 1395835 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Nitrate mg/L 2.5 2.5 99 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1395836 1395837 MS MSD 92236923006 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Nitrate mg/L ND 2.5 2.5 2.4 2.4 96 96 90-110 0 10 P4 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/05/2015 11:54 AM without the written consent of Pace Analytical Services, Inc.. Page 56 of 65 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15020349 Pace Project No.: 92237760 QC Batch: WETA/21977 Analysis Method: SM 4500-CI-E QC Batch Method: SM 4500-CI-E Analysis Description: 4500 Chloride Associated Lab Samples: 92237760006, 92237760007 METHOD BLANK: 1395491 Matrix: Water Associated Lab Samples: 92237760006, 92237760007 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/L ND 1.0 02/21/15 01:31 LABORATORY CONTROL SAMPLE: 1395492 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloride mg/L 20 20.7 103 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1395493 1395494 MS MSD 92237650008 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride mg/L ND 23.9 23.9 24.7 24.2 102 100 90-110 2 10 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1395495 1395496 MS MSD 92237746019 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride mg/L ND 20 20 20.0 20.0 97 97 90-110 0 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/05/2015 11:54 AM without the written consent of Pace Analytical Services, Inc.. Page 57 of 65 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15020349 Pace Project No.: 92237760 QC Batch: WETA/43649 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92237760001, 92237760002, 92237760003, 92237760004, 92237760005, 92237760007 METHOD BLANK: 1131956 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/kg ND 50.1 02/16/15 08:55 Sulfate mg/kg ND 50.1 02/16/15 08:55 LABORATORY CONTROL SAMPLE: 1131957 Parameter Units Chloride mg/kg Sulfate mg/kg MATRIX SPIKE SAMPLE: 1131959 Parameter Units Chloride mg/kg Sulfate mg/kg SAMPLE DUPLICATE: 1131958 Parameter Chloride Sulfate Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 501 481 96 80-120 501 482 96 80-120 92237760001 Spike MS MS % Rec Result Conc. Result % Rec Limits Qualifiers ND 596 550 75 80-120 M 1 ND 596 596 86 80-120 92237760001 Dup Units Result Result mg/kg ND ND mg/kg ND ND Max RPD RPD Qualifiers 20 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/05/2015 11:54 AM without the written consent of Pace Analytical Services, Inc.. Page 58 of 65 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15020349 Pace Project No.: 92237760 QC Batch: WETA/43650 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92237760001, 92237760002, 92237760003, 92237760004, 92237760005, 92237760007 METHOD BLANK: 1131960 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrate as N mg/kg ND 5.0 02/16/15 08:55 LABORATORY CONTROL SAMPLE: 1131961 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg 50.1 48.8 97 80-120 MATRIX SPIKE SAMPLE: 1131963 92237760001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg ND 59.6 57.2 96 80-120 H3 SAMPLE DUPLICATE: 1131962 92237760001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Nitrate as N mg/kg ND ND 20 H3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/05/2015 11:54 AM without the written consent of Pace Analytical Services, Inc.. Page 59 of 65 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15020349 Pace Project No.: 92237760 QC Batch: WETA/27309 Analysis Method: EPA 9060 QC Batch Method: EPA 9060 Analysis Description: 9060 TOC Average Associated Lab Samples: 92237760001, 92237760002, 92237760003, 92237760004, 92237760005, 92237760007 METHOD BLANK: 1119367 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mean Total Organic Carbon mg/kg ND 600 02/24/15 08:02 LABORATORY CONTROL SAMPLE: 1119368 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mean Total Organic Carbon mg/kg 120000 114000 95 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1119369 1119370 MS MSD 92237760001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg 3470 5990 6020 10600 11100 119 126 50-150 4 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/05/2015 11:54 AM without the written consent of Pace Analytical Services, Inc.. Page 60 of 65 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: J15020349 Pace Project No.: 92237760 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-G Pace Analytical Services - Green Bay PASI-M Pace Analytical Services - Minneapolis PASI-O Pace Analytical Services - Ormond Beach ANALYTE QUALIFIERS D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. D4 Sample was diluted due to the presence of high levels of target analytes. D6 The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits. H3 Sample was received or analysis requested beyond the recognized method holding time. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. N2 The lab does not hold TNI accreditation for this parameter. P4 Sample field preservation does not meet EPA or method recommendations for this analysis. R1 RPD value was outside control limits. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/05/2015 11:54 AM without the written consent of Pace Analytical Services, Inc.. Page 61 of 65 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: J15020349 92237760 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92237760001 2015003935 EPA 3050 MPRP/22732 EPA 6010 ICP/13910 92237760002 2015003950 EPA 3050 MPRP/22732 EPA 6010 ICP/13910 92237760003 2015003951 EPA 3050 MPRP/22732 EPA 6010 ICP/13910 92237760004 2015003954 EPA 3050 MPRP/22732 EPA 6010 ICP/13910 92237760005 2015003955 EPA 3050 MPRP/22732 EPA 6010 ICP/13910 92237760007 2015003953 EPA 3050 MPRP/22732 EPA6010 ICP/13910 92237760001 2015003935 EPA 3050 MPRP/22733 EPA 6020 ICPM/9278 92237760002 2015003950 EPA 3050 MPRP/22733 EPA 6020 ICPM/9278 92237760003 2015003951 EPA 3050 MPRP/22733 EPA 6020 ICPM/9278 92237760004 2015003954 EPA 3050 MPRP/22733 EPA 6020 ICPM/9278 92237760005 2015003955 EPA 3050 MPRP/22733 EPA 6020 ICPM/9278 92237760007 2015003953 EPA 3050 MPRP/22733 EPA 6020 ICPM/9278 92237760008 2015003952 SPLP METALS EPA 3020 MPRP/52559 EPA 6020A ICPM/23324 92237760009 2015003953 SPLP METALS EPA 3020 MPRP/52559 EPA 6020A ICPM/23324 92237760008 2015003952 SPLP METALS EPA 7470 MERP/12810 EPA 7470 MERC/14874 92237760009 2015003953 SPLP METALS EPA 7470 MERP/12810 EPA 7470 MERC/14874 92237760001 2015003935 EPA 7471 MERP/5386 EPA 7471 MERC/5380 92237760002 2015003950 EPA 7471 MERP/5386 EPA 7471 MERC/5380 92237760003 2015003951 EPA 7471 MERP/5386 EPA 7471 MERC/5380 92237760004 2015003954 EPA 7471 MERP/5386 EPA 7471 MERC/5380 92237760005 2015003955 EPA 7471 MERP/5386 EPA 7471 MERC/5380 92237760007 2015003953 EPA 7471 MERP/5386 EPA 7471 MERC/5380 92237760001 2015003935 ASTM D2974-87 PMST/3302 92237760002 2015003950 ASTM D2974-87 PMST/3302 92237760003 2015003951 ASTM D2974-87 PMST/3302 92237760004 2015003954 ASTM D2974-87 PMST/3302 92237760005 2015003955 ASTM D2974-87 PMST/3302 92237760007 2015003953 ASTM D2974-87 PMST/3302 92237760001 2015003935 EPA 9045 WET/35731 92237760002 2015003950 EPA 9045 WET/35731 92237760003 2015003951 EPA 9045 WET/35731 92237760004 2015003954 EPA 9045 WET/35750 92237760005 2015003955 EPA 9045 WET/35767 92237760007 2015003953 EPA 9045 WET/35836 92237760006 2015003952 EPA 300.0 WETA/21979 92237760007 2015003953 EPA 300.0 WETA/21979 92237760006 2015003952 EPA 353.2 WETA/21986 92237760007 2015003953 EPA 353.2 WETA/21986 92237760006 2015003952 SM 4500-CI-E WETA/21977 92237760007 2015003953 SM 4500-CI-E WETA/21977 92237760001 2015003935 EPA 9056 WETA/43649 92237760002 2015003950 EPA 9056 WETA/43649 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/05/2015 11:54 AM without the written consent of Pace Analytical Services, Inc.. Page 62 of 65 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: J15020349 Pace Project No.: 92237760 Lab ID Sample ID QC Batch Method QC Batch 92237760003 2015003951 EPA 9056 WETA/43649 92237760004 2015003954 EPA 9056 WETA/43649 92237760005 2015003955 EPA 9056 WETA/43649 92237760007 2015003953 EPA 9056 WETA/43649 92237760001 2015003935 EPA 9056 WETA/43650 92237760002 2015003950 EPA 9056 WETA/43650 92237760003 2015003951 EPA 9056 WETA/43650 92237760004 2015003954 EPA 9056 WETA/43650 92237760005 2015003955 EPA 9056 WETA/43650 92237760007 2015003953 EPA 9056 WETA/43650 92237760001 2015003935 EPA 9060 WETA/27309 92237760001 2015003935 EPA 9060 WETA/27310 92237760002 2015003950 EPA 9060 WETA/27309 92237760002 2015003950 EPA 9060 WETA/27310 92237760003 2015003951 EPA 9060 WETA/27309 92237760003 2015003951 EPA 9060 WETA/27310 92237760004 2015003954 EPA 9060 WETA/27309 92237760004 2015003954 EPA 9060 WETA/27310 92237760005 2015003955 EPA 9060 WETA/27309 92237760005 2015003955 EPA 9060 WETA/27310 92237760007 2015003953 EPA 9060 WETA/27309 92237760007 2015003953 EPA 9060 WETA/27310 Date: 03/05/2015 11:54 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Analytical Method Analytical Batch Page 63 of 65 ,�aeeAllalytical� Sample Condition Upon Receipt (SCUR) Page 1 of 2 Document Number: Issuing Authority: F-CHR-CS-003-rev.15 Pace Huntersville Quality Office Client dame: Courier: ❑ Fed Ex ❑ UPS❑ LISPS❑ Client❑ C mmercial❑ 6e� Other Custody Seal on CoolerlBox Present: ❑ yes a no Seals intact: ❑ yes ❑ no Packing Material: ❑ Bubble VDp ❑ B bi5 le Bap a ❑ None ❑ Other Thermometer Used:. IR Gun T1401 Type of Ice: <&P Blue None Samples on ice, cooling process has begun T.,.,,s— +— T4An4 kin C`nrror•finn Corrected Cooler Temp.: d 'C Biological Tissue is Frozen: Yes No NIA Date and Initial of torson a ram ning contents: Temp should be above freezing to VC Comments: Chain of Custody Present: a ONO ❑NIA 1. Chain of Custody Filled Out; 1140 ONO ❑NIA 2. Chain of Custody Relinquished: EWej ONO ❑NIA 3. Sampler Name & Signature on COC: 13 16 ONO ❑NIA 4. Samples Arrived within Hold Time: N ly/os ONO, ❑NIA 5. Short Hold Time Analysis (<72hr): ❑Yes No ❑NIA 6. Rush Turn Around Time Requested: ❑Ye No ❑NIA 7. Sufficient Volume: Ye Njo ❑NIA 8. Correct Containers Used: es ❑N ❑NIA 9. -Pace Containers Used: ❑Ye No ❑NIA Containers Intact: Yes ❑No ON/ 10. Filtered volume received for Dissolved tests ❑Yes ONO LE41A 11. Sample Labels match COC: es [IN, 0N1A 12. -Includes datelGme11D1Analysis Matrix: All containers needing preservation have been checked. Oyes ONO � ®i 13. All containers needing preservation are found to be in Oyes ONO N1 A compliance with EPA recommendation. exceptions: VOA, col iform, TOC, O&G, W-DRO (water) Oyes 94 Samples checked for dechlorination: ❑Yes ONO ❑ IA 14. Headspace in VOA Vials( >6mm): ❑Yes ONO B 1 15. Trip Blank Present: ❑Yes ONO NI 16. Trip Blank Custody Seals Present ❑Yes ONO NIA Pace Trip Blank Lot # (if purchased): Client Notification[ Resolution: Field Data Required? Y 1 N Person Contacted: Date/Time: Comments! Resolution: SCURF Review: Date: SRF Review: Date: y L3 15 Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (Le out of hold, incorrect preservative, out of temp, incorrect containers) WO#:92237760 92237760 II III Page 64 of 65 0 C� amr z p j O J fu m Q— a" pFyQ 00 l � %I° wa z I Oa I Z xl .!i ir u, i c a f-� 10 E v Hlin l!?� CY!« U� LLI ; o fm E r 8 �!Q �i ( sP- k I 00 I C) � ' u � m ---_ s _ CL LI! 01 Stauleluo0 JO p IPlo4z t!eo!Jnleua SSODOV) S)sa; ol;!oods pauilpog (30dd) suOIUV pue Sle;aV! lejol - dldS (33Vd) Hd (33tld) sua!ud _QjaV ) Sinew IBIO.L gVOjjebVqj,Iou 'd WoD,, u a s E c. E N is C•. $ In E C�or; sE$ e �� cd >_m TIC �5I (nl`I 1 / i v cc 3.- o v . .. u •� Y \ a M x w Y ° ^N c a U) a Z i 0 O � 8o ti E c c r N is a n A G C) r N V V y E N Y « p Q vi O `rCO Q eu ai x t u G. d" G E m Fe a _ reu 3U O��` o �o W G m Q 0 " t' k a Q tp r c ~ O s � L a o a 0 O jp Icy \ E .c h I 9 I tiY E� , � ti kk! II� N o n [� JLJGli of suiunloo elslidoiddv elaldum of muolsnD 0 m II)��PIr-}CA f) I m Page 65 of 65