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Home My WebLink AboutNC0038377_J15020119report_20150902DUE Analytical Laboratory Page 1 of40 ENERGY Order Number: Project Name: Customer Name(s): Customer Address: Lab Contact: Report Authorized By: (Signature) Program Comments: 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone:980-875-5245 Fax:980-875-4349 Order Summary Report J15020119 Tim Hunsucker, Jerry Wylie, Kathy Webb, John Toepfer Mary Ann Ogle Ann r 1.' 01r5.02.20 1g11 03:45 F GY. _05,00, Mary Ann Ogle Phone: 980-875-5274 Date: Please contact the Program Manager (Mary Ann Ogle) with any questions regarding this report. Data Flags & Calculations: 2/19/2015 Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Sample ID's & Descriptions: Collection Sample ID Plant/Station Date and Time Collected By Sample Description 2015002836 MAYO STEAM 03-Feb-15 3:19 PM Water Source 2015002837 MAYO STEAM 03-Feb-15 3:33 PM illegible Water Source 2015002838 MAYO STEAM 03-Feb-15 3:25 PM illegible Water Source 2015002840 MAYO STEAM 03-Feb-15 3:26 PM illegible Water Source 2015002841 MAYO STEAM 03-Feb-15 3:27 PM illegible Water Source 2015002843 MAYO STEAM 03-Feb-15 3:31 PM illegible Water Source 2015002844 MAYO STEAM 03-Feb-15 3:40 PM illegible Water Source 2015002845 MAYO STEAM 03-Feb-15 3:21 PM illegible Water Source 2015002846 MAYO STEAM 03-Feb-15 3:24 PM illegible Water Source 2015002851 MAYO STEAM 03-Feb-15 3:33 PM illegible Field Blank 2015002852 MAYO STEAM 03-Feb-15 3:38 PM illegible Trip Blank 11 Total Samples Page 2 of 40 Page 3 of 40 Technical Validation Review Checklist: COC and .pdf report are in agreement with sample totals Yes No and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. ❑ Yes No All laboratory QA/QC requirements are acceptable. (] Yes ❑ No Report Sections Included: L� Job Summary Report ❑ Sample Identification n Technical Validation of Data Package 6 Analytical Laboratory Certificate of Analysis ❑ Analytical Laboratory QC Report LVI Sub -contracted Laboratory Results ❑ Customer Specific Data Sheets, Reports, & Documentation ❑ Customer Database Entries 6 Chain of Custody LVI Electronic Data Deliverable (EDD) Sent Separately Reviewed By: DBA Account Date: 2/19/2015 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15020119 Site: Water Source Collection Date: 03-Feb-15 3:19 PM Analyte Result Units Qualifiers RDL DF TOTAL DISSOLVED SOLIDS TDS < 25 mg/L 25 1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 1 Page 4 of 40 Sample #: 2015002836 Matrix: GW WW Method Analysis Date/Time Analyst SM2540C 02/10/201515:53 GHUTCHI SM2540D 02/05/2015 09:41 GHUTCHI Certificate of Laboratory Analysis Page 5 of 40 This report shall not be reproduced, except in full. Order # J15020119 Site: Water Source Collection Date: 03-Feb-15 3:33 PM Analyte Result Units Qualifiers RDL DF METHANE - (Analysis Performed by Shealy Labs) Methane (CH4) Complete Sample #: 2015002837 Matrix: GW WW Method Analysis Date/Time Analyst Vendor Method V_SHEALY Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15020119 Site: Water Source Collection Date: 03-Feb-15 3:25 PM Analyte Result Units Qualifiers RDL DF INORGANIC IONS BY IC Chloride < 0.1 mg/L 0.1 1 Nitrate < 0.1 mg/L 0.1 1 Nitrate as N < 0.023 mg-N/L 0.023 1 Sulfate < 0.1 mg/L 0.1 1 Page 6 of 40 Sample #: 2015002838 Matrix: GW WW Method Analysis Date/Time Analyst EPA 300.0 02/05/2015 22:26 BGN9034 EPA 300.0 02/05/2015 22:26 BGN9034 EPA 300.0 02/05/2015 22:26 BGN9034 EPA 300.0 02/05/2015 22:26 BGN9034 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15020119 Site: Water Source Collection Date: 03-Feb-15 3:26 PM Analyte Result NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) < 0.01 Total Carbon TOC < 0.1 Units Qualifiers RDL DF mg-N/L 0.01 1 Page 7 of 40 Sample #: 2015002840 Matrix: GW WW Method Analysis Date/Time Analyst EPA 353.2 02/14/2015 11:24 TLINN mg/L 0.1 1 SM5310C/EPA9060A 02/12/201515:45 TJA7067 Certificate of Laboratory Analysis Page 8 of 40 This report shall not be reproduced, except in full. Order # J15020119 Site: Water Source Collection Date: 03-Feb-15 3:27 PM Analyte Result Units Qualifiers RDL DF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Sample #: 2015002841 Matrix: GW WW Method Analysis Date/Time Analyst Vendor Method V_SHEALY Certificate of Laboratory Analysis Page 9 of 40 This report shall not be reproduced, except in full. Order # J15020119 Site: Water Source Collection Date: 03-Feb-15 3:31 PM Analyte Result Units Qualifiers RDL DF SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Sample #: 2015002843 Matrix: GW WW Method Analysis Date/Time Analyst Vendor Method V_ELE1 Certificate of Laboratory Analysis Page 10 of 40 This report shall not be reproduced, except in full. Order # J15020119 Site: Water Source Collection Date: 03-Feb-15 3:40 PM Analyte Result Units Qualifiers RDL DF MERCURY IN WATER - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Sample #: 2015002844 Matrix: GW WW Method Analysis Date/Time Analyst Vendor Method V_SHEALY Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15020119 Site: Water Source Collection Date: 03-Feb-15 3:21 PM Analyte Result MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 UNDIGESTED METALS BY ICP Calcium (Ca) < 0.01 Magnesium (Mg) < 0.005 Potassium (K) < 0.1 Sodium (Na) < 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) < 0.005 Barium (Ba) < 0.005 Boron (B) < 0.05 Iron (Fe) < 0.01 Manganese (Mn) < 0.005 Strontium (Sr) < 0.005 Zinc (Zn) 0.006 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 Arsenic (As) < 1 Beryllium (Be) < 1 Cadmium (Cd) < 1 Chromium (Cr) < 1 Cobalt (Co) < 1 Copper (Cu) < 1 Lead (Pb) < 1 Molybdenum (Mo) < 1 Nickel (Ni) < 1 Selenium (Se) < 1 Thallium (TI) Low Level < 0.2 Vanadium (V) Low Level < 0.3 Page 11 of 40 Sample #: 2015002845 Matrix: GW WW Units Qualifiers RDL DF Method Analysis Date/Time Analyst ug/L 0.05 1 EPA 245.1 02/06/2015 09:28 TLINN mg/L 0.01 1 EPA 200.7 02/11/2015 15:14 MHALL3 mg/L 0.005 1 EPA 200.7 02/11/2015 15:14 MHALL3 mg/L 0.1 1 EPA 200.7 02/11/2015 15:14 MHALL3 mg/L 0.05 1 EPA 200.7 02/11/2015 15:14 MHALL3 mg/L 0.005 1 EPA 200.7 02/05/2015 15:21 MHH7131 mg/L 0.005 1 EPA 200.7 02/05/2015 15:21 MHH7131 mg/L 0.05 1 EPA 200.7 02/05/2015 15:21 MHH7131 mg/L 0.01 1 EPA 200.7 02/05/2015 15:21 MHH7131 mg/L 0.005 1 EPA 200.7 02/05/2015 15:21 MHH7131 mg/L 0.005 1 EPA 200.7 02/05/2015 15:21 MHH7131 mg/L 0.005 1 EPA 200.7 02/05/2015 15:21 MHH7131 ug/L 1 1 EPA 200.8 02/06/2015 12:07 JAHERMA ug/L 1 1 EPA 200.8 02/06/2015 12:07 JAHERMA ug/L 1 1 EPA 200.8 02/06/2015 12:07 JAHERMA ug/L 1 1 EPA 200.8 02/06/2015 12:07 JAHERMA ug/L 1 1 EPA 200.8 02/06/2015 12:07 JAHERMA ug/L 1 1 EPA 200.8 02/06/2015 12:07 JAHERMA ug/L 1 1 EPA 200.8 02/06/2015 12:07 JAHERMA ug/L 1 1 EPA 200.8 02/06/2015 12:07 JAHERMA ug/L 1 1 EPA 200.8 02/06/2015 12:07 JAHERMA ug/L 1 1 EPA 200.8 02/06/2015 12:07 JAHERMA ug/L 1 1 EPA 200.8 02/06/2015 12:07 JAHERMA ug/L 0.2 1 EPA 200.8 02/06/2015 12:07 JAHERMA ug/L 0.3 1 EPA 200.8 02/06/2015 12:07 JAHERMA Certificate of Laboratory Analysis Page 12 of 40 This report shall not be reproduced, except in full. Order # J15020119 Site: Water Source Collection Date: 03-Feb-15 3:24 PM Analyte Result Units Qualifiers RDL Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (Al) < 0.005 mg/L 0.005 Barium (Ba) < 0.005 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) < 0.01 mg/L 0.01 Manganese (Mn) < 0.005 mg/L 0.005 Strontium (Sr) < 0.005 mg/L 0.005 Zinc (Zn) 0.005 mg/L 0.005 DISSOLVED METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 Sample #: 2015002846 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 245.1 02/18/2015 19:47 TLINN 1 EPA 200.7 02/09/2015 15:46 MHH7131 1 EPA 200.7 02/09/2015 15:46 MHH7131 1 EPA 200.7 02/09/2015 15:46 MHH7131 1 EPA 200.7 02/09/2015 15:46 MHH7131 1 EPA 200.7 02/09/2015 15:46 MHH7131 1 EPA 200.7 02/09/2015 15:46 MHH7131 1 EPA 200.7 02/09/2015 15:46 MHH7131 1 EPA 200.8 02/11/2015 12:32 DJSULL1 1 EPA 200.8 02/11/2015 12:32 DJSULL1 1 EPA 200.8 02/11/2015 12:32 DJSULL1 1 EPA 200.8 02/11/2015 12:32 DJSULL1 1 EPA 200.8 02/11/2015 12:32 DJSULL1 1 EPA 200.8 02/11/2015 12:32 DJSULL1 1 EPA 200.8 02/11/2015 12:32 DJSULL1 1 EPA 200.8 02/11/2015 12:32 DJSULL1 1 EPA 200.8 02/11/2015 12:32 DJSULL1 1 EPA 200.8 02/11/2015 12:32 DJSULL1 1 EPA 200.8 02/11/2015 12:32 DJSULL1 1 EPA 200.8 02/11/2015 12:32 DJSULL1 1 EPA 200.8 02/11/2015 12:32 DJSULL1 Certificate of Laboratory Analysis Page 13 of 40 This report shall not be reproduced, except in full. Order # J15020119 Site: Field Blank Collection Date: 03-Feb-15 3:33 PM Analyte Result Units Qualifiers RDL DF MERCURY IN WATER - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Sample #: 2015002851 Matrix: GW WW Method Analysis Date/Time Analyst Vendor Method V_SHEALY Certificate of Laboratory Analysis Page 14 of 40 This report shall not be reproduced, except in full. Order # J15020119 Site: Trip Blank Collection Date: 03-Feb-15 3:38 PM Analyte Result Units Qualifiers RDL DF MERCURY IN WATER - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Sample #: 2015002852 Matrix: GW WW Method Analysis Date/Time Analyst Vendor Method V_SHEALY Page 15 of 40 Duke Energy Laboratory Services 13339 Hagers Ferry Road Bid. MG03A Huntersville, NC 28078 Sample Matrix Other Date Analyzed 02/10/2015 Delivered by FedEx eOne ID Duke Energy ID 23995 Water source (drilling) Eernent One Vnc. 6319-0 CaroHnai Beach Rd. IjVilmngton, HC 28412 Phone: 910 793-0128 Fay:: 010 7 92-6853 e10ab@e1lab.com REPORT OF ANALYSES February 12, 2015 Client Project Name AB GW Assessment water Client Project Number J15020119 PO Number Sample Type Grab Method SM 4500 S2- D Parameter Result Unit Dil Sulfide < 0.1 mg/L 1 Ken math, Laboratory Director 23995 Duke Report Packet Compiled by-Q&) NC Certifications: DW 37788 and DWQ DENR 604 Date Received 02/06/2015 Time Received 1200 Received by LLB DL Date Time Sampled Sampled 0.1 02/03/15 1531 Page T, 7� o Ld POAIOSSI(] 1 TM —01 a M, > .. ..... . .. 7- . . .... < < 0i o opl;ing ka 'oltuoqjeo 13 i 1 'Allu Blell'N '001 N Se 1 I tON 'VOS'lo E —A (9Z� ouvqlaw E E i. ell N a 7 u d, cn j 1111 rl 5 13 2i J J-1 2 lu w I, ul co elementOne SAMPLE SUBMISSION FORM TAT 7 BD Hold Time Expiration 02.10.16 @ 1531 PM Client: Duke Energy LIMS No J15020119 Project ID AB GW Assessment Water Lab (age Il j�tg5 Analysis Due Date 02.09.15 Report Due Date 02.17.15 Date Rec: 02.06.15 Time Rec: 1200 Rec By LLB H >9 Yes No Tem s 60C Yes No Ref. Method: If No, Record If No, Record SM4500 S2 D Sam ie laentitication & Collection Information Lab ID I Client ID Collection Date Collection Time Analysis Requested 1 Water Source (drilling) 02.03.15 1531 PM ulfide NOTE for Sulfide The MS/MSD spike should approximate 2 to 3 times the sample concentration. If no sulfide detected at 100 pg/L spike the sample to render the final spike concentration at - 500 pg/L SS Page 1 oo 1 Prep By / Date SS by v V Labeled By / Date 2/6/2015 1:29:44 PM ID Verification By /Date Page 18 of 40 METHOD: SM 4500 S2- d ELEMENT ONE ELEMENT ASSAY: Sulfide Spectrophotometer Wave Length 664 Sulfide Standard 1000ppm Lot# 5010904 UNITS OF ANSWER ug/rnL DETECTION LIMIT (um 2.500 CLIENT: Lab ID# DUKE 23995, 23996 SPK LEVEL fug) 5 MAX ALIQUOT 25.00 Date: 02/10/15 STANDARD conc(ppm) X Time Analysis Begun 13:30 10 Time Analysis Ended 14:55 - - Analyst: KAM STD ABSORPTION y X Y _ 0 350 .....,. .......................................... ............ ....................................................... ........................... 0300 0309 0250 ug STD SOLUTION STD ABS 0.00 2.50 5.00 7.50 10.00 0.000 0,086 0.160 0.247 0.309 0mo y 0 150 ~-- 0050 �- U WO . .f-- 0 U 200 400 300 300 1000 1200 SAMPLE I.D. SAMP ABS ug PER ALIQUOT ALI in mL ANALYZED to PREP ALI in mL RESULTS VOL in mL TAKEN ug/mL r ton<::<:<:: Correlation LESS THAN SPIKE % SPK REC LEVEL LRB 0.000 0.0000 25 25 25 < 0 LRB SPK 0.166 5.3684 25 25 25 0.215 108% 5.0 23995 0.000 0.0000 25 25 25 23995 dup 0.003 -5.3553 25 25 25 < 23995 s k 0.166 5.3684 25 25 25 0.215 107% 5.0 Blk 0.000 0.0000 25 25 25 < QC 0.159 4.9079 25 25 25 0.196 98% 5.0 23996-1 0.003 -5.3553 25 25 25 23996-2 0.007 -5.0921 25 25 25 23996-3 0.003 -5.3553 25 25 23996-4 0.005 -5.2237 25 25 25 Blk 0.000 0.0000 25 25 25 < QC 0.160 4.9737 25 25 25 0.199 99% 5.0 u m e o— Date: 2/10/2015 By: (Print) KAM (sign): a SHEALY ENVIRONMENTAL SERVICES, INC. Report of Analysis Duke Energy 13339 Hagers Ferry Rd Bldg 7405 Huntersville, NC 28078 Attention: Mary Ann Ogle Project Name: AB GW Assessment Water Project Number:J15020119 Lot Number:QB05069 Date Completed:02/12/2015 Grant Wilton Project Manager This report shall not be reproduced, except in its entirety, without the written approval of Shealy Environmental Services, Inc. The following non -paginated documents are considered part of this report: Chain of Custody Record and Sample Receipt Checklist. *QB05069* Shealy Environmental Services, Inc. Page: 1 of 9 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. SC DHEC No: 32010 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative Duke Energy Lot Number: QB05069 Project Name: AB GW Assessment Water Project Number: J15020119 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the Shealy Environmental Services, Inc. ("Shealy") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPS), and Shealy policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below. If you have any questions regarding this report please contact the Shealy Project Manager listed on the cover page Shealy Environmental Services, Inc. Page: 2 of 9 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. Sample Summary Duke Energy Lot Number: QB05069 Project Name: AB GW Assessment Water Project Number: J15020119 Sample Number Sample ID Matrix Date Sampled Date Received 001 2015002837 Water Source (drilling) Aqueous 02/03/2015 1533 02/05/2015 002 2015002841 Water Source (drilling) Aqueous 02/03/2015 1527 02/05/2015 003 2015002844 Water Source (drilling) Aqueous 02/03/2015 1540 02/05/2015 004 2015002851 Field Blank Aqueous 02/03/2015 1535 02/05/2015 005 2015002852 Trip Blank Aqueous 02/03/2015 1530 02/05/2015 (5 samples) Shealy Environmental Services, Inc. Page: 3 of 9 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. Executive Summary Duke Energy Lot Number: QB05069 Project Name: AB GW Assessment Water Project Number: J15020119 Sample Sample ID Matrix Parameter Method Result Q Units Page (0 detections) Shealy Environmental Services, Inc. Page: 4 of 9 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane Client: Duke Energy Laboratory ID: QB05069-001 Description: 2015002837 Water Source (drilling) Matrix: Aqueous Date Sampled:02/03/2015 1533 Project Name: AB GW Assessment Water Date Received:02/05/2015 Project Number: J15020119 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 02/06/2015 2307 JJG 67181 CAS Analytical Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 10 ug/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 5 of 9 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals Client: Duke Energy Laboratory ID: QB05069-002 Description: 2015002841 Water Source (drilling) Matrix: Aqueous Date Sampled:02/03/2015 1527 Project Name: AB GW Assessment Water Date Received:02/05/2015 Project Number: J15020119 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 02/06/2015 2251 BWS 67140 1 (Bicarbonate ) SM 2320B-2011 1 02/06/2015 2251 BWS 02/06/2015 2251 1 (Carbonate Al) SM 2320B-2011 1 02/06/2015 2251 BWS 02/06/2015 2251 CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 ND 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 6 of 9 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Mercury (CVAFS) Client: Duke Energy Laboratory ID: QB05069-003 Description: 2015002844 Water Source (drilling) Matrix: Aqueous Date Sampled:02/03/2015 1540 Project Name: AB GW Assessment Water Date Received:02/05/2015 Project Number: J15020119 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 1631E 1 02/11/20151112 COH 02/09/20151616 67306 CAS Analytical Parameter Number Method Result Q PQL Units Run Mercury (CVAFS) 7439-97-6 1631 E ND 0.500 ng/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 7 of 9 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Mercury (CVAFS) Client: Duke Energy Laboratory ID: QB05069-004 Description: 2015002851 Field Blank Matrix: Aqueous Date Sampled:02/03/2015 1535 Project Name: AB GW Assessment Water Date Received:02/05/2015 Project Number: J15020119 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 1631E 1 02/11/20151126 COH 02/09/20151616 67306 CAS Analytical Parameter Number Method Result Q PQL Units Run Mercury (CVAFS) 7439-97-6 1631 E ND 0.500 ng/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 8 of 9 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Mercury (CVAFS) Client: Duke Energy Laboratory ID: QB05069-005 Description: 2015002852 Trip Blank Matrix: Aqueous Date Sampled:02/03/2015 1530 Project Name: AB GW Assessment Water Date Received:02/05/2015 Project Number: J15020119 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 1631E 1 02/11/20151130 COH 02/09/20151616 67306 CAS Analytical Parameter Number Method Result Q PQL Units Run Mercury (CVAFS) 7439-97-6 1631 E ND 0.500 ng/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 9 of 9 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 QC Summary Shealy Environmental Services, Inc. QC Data for Lot Number: QB05069 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals - Ii Sample ID: QQ67140-001 Matrix: Aqueous Batch: 67140 Analytical Method: SM 2320B-2011 Parameter Result Q Dil PQL Units Analysis Date Alkalinity ND 1 10 mg/L 02/06/2015 2041 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QB05069 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals - LCS Sample ID: QQ67140-002 Matrix: Aqueous Batch: 67140 Analytical Method: SM 2320B-2011 Spike Amount Result % Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Alkalinity 100 100 1 102 90-110 02/06/2015 2047 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QB05069 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane - MB Sample ID: QQ67181-001 Matrix: Aqueous Batch: 67181 Analytical Method: RSK - 175 Parameter Result Q Dil PQL Units Analysis Date Methane ND 1 10 ug/L 02/06/2015 2014 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QB05069 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane - LCS Sample ID: QQ67181-002 Matrix: Aqueous Batch: 67181 Analytical Method: RSK - 175 Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Methane 150 120 1 77 70-130 02/06/20151931 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QB05069 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane - LCSD Sample ID: QQ67181-003 Matrix: Aqueous Batch: 67181 Analytical Method: RSK - 175 Spike Amount Result % Rec % RPD Parameter (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date Methane 150 120 1 78 1.1 70-130 30 02/06/20151957 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QB05069 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Mercury (CVAFS) - MB Sample ID: QQ67306-001 Matrix: Aqueous Batch:67306 Prep Method: 1631E Analytical Method: 1631E Prep Date: 02/09/2015 1616 Parameter Result Q Dil PQL Units Analysis Date Mercury (CVAFS) ND 1 0.500 ng/L 02/11/2015 1102 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QB05069 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Mercury (CVAFS) - LCS Sample ID: QQ67306-002 Matrix: Aqueous Batch:67306 Prep Method: 1631E Analytical Method: 1631E Prep Date: 02/09/2015 1616 Spike Amount Result % Rec Parameter (ng/L) (ng/L) Q Dil % Rec Limit Analysis Date Mercury (CVAFS) 5.00 5.06 1 101 75-125 02/11/2015 1107 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QB05069 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Mercury (CVAFS) - MS Sample ID: QB05069-003MS Matrix: Aqueous Batch: 67306 Prep Method: 1631 E Analytical Method: 1631E Prep Date: 02/09/2015 1616 Sample Spike Amount Amount Result % Rec Parameter (ng/L) (ng/L) (ng/L) Q Dil % Rec Limit Analysis Date Mercury (CVAFS) ND 5.00 4.72 1 94 71-125 02/11/2015 1116 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QB05069 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Mercury (CVAFS) - MSD Sample ID: QB05069-003MD Matrix: Aqueous Batch: 67306 Prep Method: 1631 E Analytical Method: 1631E Prep Date: 02/09/2015 1616 Sample Spike Amount Amount Result % Rec % RPD Parameter (ng/L) (ng/L) (ng/L) Q Dil % Rec % RPD Limit Limit Analysis Date Mercury (CVAFS) ND 5.00 4.69 1 94 0.64 71-125 24 02/11/2015 1121 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QB05069 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. M a $ WW s+R+ ! J3 ff J / i1Y'Ri i i 4k 8 `-j IQAAIYY w2f�j 1* {4 luw—: 3-llj pPUM Ym"LE in e�euaG.l¢� �¢unaYllw� 'Allull¢X17 i 8Q1'45u g �. R4 � S 42 JX1wj"r4 h¢ul'aP a1¢0IP.. U�ld !3ugWdwl'i:udQL 1p E Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. ShLe l;r ``..ovi es, IRO. Dwwuaaa Nuaitu: F-AD-4J6 kavisio>n Nuutbe-- 14 PROetofI Pj*acca Dmc' 07111/14 Effective Dstc. IIM!14 Sample Receipt Cbeckks,[ (SRC) Client: hLke j Coolerinwertcd byfdat� ? 1�� Lot #: Me= ofre"ipt: [.]' $ S1 [] Cheat ❑ UPS ❑ FodEx ❑ Airborne E'sp ❑ [}[her Yes No 1. Wje eustvdy scab present oa the -cooler? No N-A - If cu:Audy mmis ac rescnle were tha intact and imbrnken? CQoler I+DA)rigiture nal temperaupon rccciptlDcaivcd (wrrcct+xl) tetrlpemwfe upon r ipt= p+ hldh4d; [:1 Temperaturt: Blank ffAongi Bottles IR Gun ID: 94 IR (An Cometion Factor —q- I "C Method of coolar.it; [ �rc1 Ice 0 131tie Toe ❑ Djy Ioe ❑ ]Mona YC5 ❑ No ❑ NA 3. if temperature of any cwter exceeded 6-0°C, -was Project Manager nolifieM PM notified by SRC, phone, n (circle: one), other: _ (For o 1ers received Via oDainiir4.la1 Chic-', Plods are to be notified immediately.) Yes ❑ No ❑ NA Z 4- Is thq, coramcrcial courier's pur;Lng Wip attoeliedto this frrt'rn? Yes No 5. Were propercuslud rocedur t'elin ishedlreceived) foEowed? Yes No ❑ T A 5a Were samples relin iihed by client tD commrrcial comfier;' No ❑ 6- Were! sample IDs listed an the C-GC? ❑ T Were sane le ZL s listed on all sa lc wntaimnl Vitas ovllection daw & time Listed on the COC? ❑8- '- 1�r'as c�ollec#ican dare & tlixrle Ifisted r?za all s Ic containers? ❑10. Did all mmtainff label ilifonnatinti TD,date,time) agr with tht COC? tYesNa[E] 1l.'4W=tests w be erfomwd listed. ran the C OC?❑ 12. Did atll s les arrry in the cr ountairten for each teat'? ❑ 13. Did all main anivc 1n ood oondition Unbroken, lids on etc_ ? ❑ 14. Was ad Data. sam t kaluiml ivailarble? ❑ 15. Weiz all samplcs retmi Within Y} tl� ho1jing time or 48 houn. whichever comcs first? Yes No 16, Vkfrre anv samples cnrttainers missing? Yes N. NA El 17, Wm there any excess s3m not Listed on coc'? Yes a No ❑ 18. Wum bubbles present >" size" (' "or 6mur1 in dit mwter in any VOA vials? Yes No NA 19. Wrere all metals10 Cs EEAvi,'nutricnt s lvs r eived at a . H of - Yes ❑ No 0 N 20. Were all c anidc andix sulfide sampiles reeeivead at a pH>11 27 Yes El No ❑ N` 21. Were all applicable NH3TrKNleyanitler'phmo1(<ii-2inVL) samples free of residual chlorine? Yee No ❑ NA 22, Were collection Itc Mures documented on the 00C tbrNC s 1es? Yes ❑ No 0 NAe 23. Were client rcmarkslrryuests (i.e- rNur«zed dilutions, M 1'M:SD desig tkyns, etc-. -) corroctly transcribed frons the COC into tht comment sntiott in MIS? ycs ❑ I Na 24, Was the quote number usedtaken from flw container 1ibel� Sample Preservation (Mug be ecunpleted for any samplef s) in n=. Lty preserved or with headspace.) sample(s) w= ro ehW incorrlectly presmcd and wcm adjusted ac.cordingly in sample receiving with {F-LS04,HNO3 C1 NaClM using SR # Sampl s +-t NY em received with bubbles �6 n= in diameter. sample(s) wm received with TRC >0.2 m 1L T S1 is No SAC DrinIzing Water rs-feel Sampje(s) pH wrihcd t Li be �- 2 by Date: _ Barn 1 s were not received at a PH of <2 and %%rere adjusted accordingly us " r-Sample Labels a lied b vet'ifred Date; 7- �d�,¢�s+. �=+5;:�n=i't}9t��#�ir��,i!r� wa- Ufa i-ar��=i�[��a�•[��is+i�:.i`s-...r.��.� 7=.'. Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM ------------ ------------------ D uke no r Fz gy ---------- - Dukii Eriff" Arallyticell Labuatory i AnalytlLal LabDm 1.11aeonly 7 I I Pago 1 1 Allillytival LabofatriTy Si Ck 10003AZ ffluilfto 7405) 13330 1-16gara Fbjr� Rd OWdGr# M atft ft. mc, -Z GL:. i -- —0 --.- - DISTRIBUTION Sample Log Hiire�"114, N C.WYA "gqbd By OM &Tiffie 7— 44 q SAMPLE PROORAM ()Rlf.-,lW0 In LAB. C, OPY to 01-IEWT -------------- Verdn, '3rftmd Wo"r NFZIES UST RcW% vilaso — -X.-- COC REV DA-rE - -v —t. 7 PKNLI'Wjn� AB QW Assinkirtkarit water 21 � sh'L'aly --------------------------- ..... . .. litrallon (0.45 u m) PO# 1115153 unrIlChftfil 61.1sines jjn'F. R.aPcnnrI.- Pteservatilve H2Sf}4 MG03A3 4w Volume �mL) Element one 900 90" 40 wil 301a Izs Wo No SOD 2W (64 Ll Coniialiner Type PET glass PE-r PLI PET PET HrjPF HrA-F PO# 731367 ;Z' W Sam pie Description or ID DpftaW 2f - 0 ap ;7� T3 -dl = a a q-: uj 0 GPS Locabon c liftc I > IDWW T' a E: IL....... 0 637 r st, xyr 41 A n t��k T D A 0 rq ULT'i t D F 9-4 3 Z _ 3 - S7. W ca(A D r 13 0 0 d e a t4-7 t 71 TOTAL I R 3MPd :710�� UaWTlme Requested TurnaTuund "m0Mwd By u=1fril? 21 Acowf6d By; PI—) e,'fi�L I L4 14 7— "o v -1d Days Da" W 148 llsitsmms/ A-epted Y; n Q Se Seta ms I Seal By S 'E ELEMENTS by ICP_MS (TRIVI); A3, Bo. C-dr Co, Cr, Cu, 111410, N1. Pb. gb.. Se. TI ILL), V (!-Lp -01:1-M2 ASAR EL-E J MENTS by JGP RM); Al, Ea, A. Fe, Viri, Sr, Zri ICP-Undlgersted Co, mg. K.Hs Hg by 245.1 'AM�Fmt V4111 Apply CHilso4vaidmocals, mI11mofjl%lGP,lMS,Hg 0 Total 1 11