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NC0038377_Table 12-1 Ash Pore Water Risk Screening_20150902
TABLE 12-1 RISK SCREENING TABLE: COAL ASH PORE WATER DATA MAYO STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, ROXBORO, NC Chromium Water Spec Ferrous Aluminum Antimony Arsenic Barium Beryllium Bi- Boron Cadmium Calcium Carbonate (III)/Chro Cobalt Copper Analytical Parameter Redox Assignment pH Level Temp Cond DO ORP Eh Turbidity Iron Alkalinity carbonate Alkalinity Chloride mium (VI) Alkalinity DIS TOT DIS TOT DIS TOT DIS TOT DIS TOT DIS TOT DIS TOT TOT DIS TOT DIS TOT DIS TOT Reporting Units P 9 None S.U. ft De C 9 umhos cm m /I 9 mV mV NTU m /I 9 m /I 9 u /I 9 ug/I u /I 9 ug/I ug/I ug/I ug/I u /I 9 u /I 9 ug/I m /1 9 u /I 9 u /I 9 1 ug/I ug/I m /I 9 m /I 9 m /I 9 u /I 9 ug/I u /I 9 ug/I m /1 9 m /1 9 SSA NCAC 02L Standard NE 6.5-8.5 NE NE NE NE NE NE NE NE NE NE NE NE 1* NE 1 10 1 NE 700 NE 4* NE NE 700 NE 2 NE NE 250 NE 10 NE 1* NE 1 Sample ID Sample Field Parameters Analytical Results Collection Date ASH PORE WATER ABMW-01 06/25/2015 Mixed (anoxic) 7.6 5.65 27 1009 0.32 -159 46 3.58 0.5 450 146 179 43 38 369 SIB 850 925 <1 <1 450 4530 4560 <1 <1 100 <10 16 <1 <1 5.55 6.09 0.0106 <0.001 ABMW-02(') 06/17/2015 Mixed (oxic-anoxic) 7.8 10.96 27 684 0.6 -187.1 17.9 2 <0.5 290 23 61 <1 <1 874 1020 149 173 1.22 1.42 290 8100 9200 <1 <1 82.2 <10 12 <1 <1 <1 <1 <0.001 <0.001 ABMW-03(') 06/17/2015 Anoxic 6.63 17.15 23 527 0.2 -136 69 2.13 3 80 18 119 <1 <1 197 193 200 200 <1 <1 80 1960 1940 <1 <1 54.5 <10 76 <1 <1 <1 <1 <0.001 <0.001 ABMW-04(1) 06/22/2015 Mixed (oxic-anoxic) 7.5 5.96 25.1 818 0.6 238 443 1.35 0.5 370 21 71 <1 <1 496 499 449 448 <1 <1 370 5040 4930 <1 <1 120 <10 11 <1 <1 1.43 1.49 <0.001 <0.001 DETECTIONS/SAMPLES --- --- --- --- --- --- --- --- --- --- 4/4 4/4 4/4 1/4 1/4 4/4 4/4 4/4 4/4 1/4 1/4 4/4 4/4 4/4 0/4 0/4 4/4 0/4 4/4 0/4 0/4 2/4 2/4 1/4 0/4 AVERAGE ASH PORE WATER CONCENTRATION (DETECTIONS --- --- --- --- --- --- --- --- --- --- 298 52 108 43 38 484 558 412 437 1.22 1.42 298 4,908 5,158 --- --- 89.2 --- 29 --- --- 3.49 3.79 0.0106 --- ONLY) MAXIMUM ASH PORE WATER GROUNDWATER CONCENTRATION --- --- --- --- --- --- --- --- --- 450 146 179 43 38 874 1,020 850 925 1.22 1.42 450 8,100 9,200 --- --- 120.0 --- 76 --- - 5.55 6.09 0.0106 NUMBER OF ASH PORE WATER SAMPLES EXCEEDING 15A NCAC 2L --- --- --- --- --- --- --- --- --- --- 0 0 0 0 1 0 4 0 1 0 0 0 0 4 0 0 0 0 0 0 0 0 2 0 0 STANDARD Notes: 0 - Bold highlighted concentration indicates exceedance of the 15A NCAC 02L Standard, Appendix 2, April 1, 2013. ORP = Oxidation Reduction Potential mV = millivolts DIS = Dissolved NE = Not established TOT = Total NTU = nephelometric turbidity unit Temp = Temperature S.U. = Standard Unit DO = Dissolved Oxygen ug/I = microgram per liter Deg C = Degree Celsius umhos/cm = micro mhos per centimeter mg/I = milligrams per liter Spec Cord = Specific Conductance mg-N/L = miligram nitrogen per liter ft = feet --- = Not applicable < = concentration not detected at or above the reporting limit. * - Interim Maximum Allowable Concentrations (IMACs) of the 15A NCAC 02L Standard, Appendix 1, April, 1, 2013. Note 1: Hexavalent Chromium concentration is less than EPA screening value for tapwater (0.035 mg/Q. See Table 10-3 (USEPA Regional Screening Levels [RSLs] rev., June 26. 2015). Prepared by: VTV/SRW Checked by: RLP P:\Duke Energy Progress. 1026\105. Mayo Ash Basin GW Assessment Plan\1.11 CSA Repo rting\Tables\Draft Tab les\Table 12-1 Ash Pore Water Risk Screen ing.xlsx page 1 of 2 TABLE 12-1 RISK SCREENING TABLE: COAL ASH PORE WATER DATA MAYO STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, ROXBORO, NC Iron Lead Magnesium Manganese Mercury Molybdenum Nickel Nitrate Potassium Selenium Sodium Strontium Thallium Total Total Total Vanadium Zinc Analytical Parameter Methane (as N) Sulfate Sulfide Dissolved Organic Suspended Solids Carbon Solids DIS TOT DIS TOT TOT DIS TOT DIS TOT DIS TOT DIS TOT TOT DIS TOT TOT DIS TOT DIS TOT DIS TOT DIS TOT Reporting Units ug/I ug/I ug/l ug/I mg/I ug/l ug/I 1 ug/I ug/l ug/I ug/I ug/I ug/I ug/I mg-N/L mg/I ug/I ug/I mg/I mg/I mg/l mg/I mg/l ug/I ug/l mg/I mg/I mg/l ug/I ug/l mg/I mg/l SSA NCAC 02L Standard NE 300 1 NE 15 NE NE 50 1 NE 1 1 1 NE NE NE I NE 100 10 NE NE 20 NE NE NE 250 NE NE 0.2* 500 NE NE NE 0.3* NE 1 Sample ID Sample Analytical Results Collection Date ASH PORE WATER ABMW-01 06/25/2015 483 1370 <1 <1 51.9 2120 2280 <0.05 <0.05 <10 205 213 4.77 5.45 <0.01 24.6 <1 <1 18.7 3.36 3.49 5.8 <0.1 2.13 2.47 540 2.8 6 290 314 0.014 <0.005 ABMW-02('� 06/17/2015 172 356 <1 <1 27 957 1110 <0.05 <0.05 3100 1620 1830 <1 1.12 0.103 15.2 <1 <1 13.4 1.54 1.78 36 <0.1 <0.2 <0.2 450 11 <5 2.59 3.53 <0.005 <0.005 ABMW-03('� 06/17/2015 3870 3890 <1 <1 11.9 451 451 <0.05 <0.05 4400 75.1 75.6 3.16 2.69 0.016 10.2 <1 <1 10.8 1.17 1.17 42 <0.1 <0.2 0.289 350 4.1 9 <0.3 0.68 <0.005 <0.005 ABMW-04(') 06/22/2015 724 940 <1 <1 32.8 657 641 <0.05 <0.05 4600 434 428 1.12 1.71 <0.01 22.1 <1 <1 12.5 2.3 2.25 38 <0.1 <0.2 <0.2 520 2.9 <5 2.44 2.84 0.013 <0.005 DETECTIONS/SAMPLES 4/4 4/4 0/4 0/4 4/4 4/4 4/4 0/4 0/4 3/4 4/4 4/4 3/4 4/4 2/4 4/4 0/4 0/4 4/4 4/4 4/4 4/4 0/4 1/4 2/4 4/4 4/4 2/4 3/4 4/4 2/4 0/4 AVERAGE ASH PORE WATER CONCENTRATION (DETECTIONS 1,312 1,639 --- --- 30.9 1,046 1,121 --- --- 4,033 584 637 3.02 2.74 0.060 18.0 --- --- 13.9 2.09 2.17 30 --- 2.13 1.38 465 5.2 8 98.34 80.26 0.0135 --- ONLY) MAXIMUM ASH PORE WATER GROUNDWATER CONCENTRATION 3,870 3,890 --- --- 51.9 2,120 2,280 --- --- 4,600 1,620 1,830 4.77 5.45 0.103 24.6 --- --- 18.7 3.36 3.49 42 --- 2.13 2.47 540 11.0 9 290 314 0.014 NUMBER OF ASH PORE WATER SAMPLES EXCEEDING 15A NCAC 2L 0 4 0 0 0 0 4 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 2 2 0 0 0 4 0 0 STANDARD Notes: 0 - Bold highlighted concentration indicates exceedance of the 15A NCAC 02L Standard, Appendix 2, April 1, 2013. ORP = Oxidation Reduction Potential mV = millivolts DIS = Dissolved NE = Not established TOT = Total NTU = nephelometric turbidity unit Temp = Temperature S.U. = Standard Unit DO = Dissolved Oxygen ug/I = microgram per liter Deg C = Degree Celsius umhos/cm = micro mhos per centimeter mg/I = milligrams per liter Spec Cond = Specific Conductance mg-N/L = miligram nitrogen per liter ft = feet --- = Not applicable < = concentration not detected at or above the reporting limit. * - Interim Maximum Allowable Concentrations (IMACs) of the 15A NCAC 02L Standard, Appendix 1, April, 1, 2013. Note 1: Hexavalent Chromium concentration is less than EPA screening value for tapwater (0.035 mg/Q. See Table 10-3 (USEPA Regional Screening Levels [RSLs] rev., June 26. 2015). Prepared by: VTV/SRW Checked by: RLP P:\Duke Energy Progress. 1026\105. Mayo Ash Basin GW Assessment Plan\1.11 CSA Repo rting\Tables\Draft Tab les\Table 12-1 Ash Pore Water Risk Screen ing.xlsx page 2 of 2