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HomeMy WebLinkAboutNC0038377_Figures_20150902' - aye,. !` • . . 1.Z��. ��, i+f.�'- _y • 40, 4 r♦ '1 ! • �.� i Y. .f i ate•. ' f1 o 40, ♦C .. - Yr NOTES: 41 +' ` a• a I ♦' . I r� , - r^jam :� "�� •:���! 1 ♦♦ 1 r oo .lop ra ._ _ _ '1., r .� -I', - `•i _ - d�l�. _� x, _ "'� -. _� - - .-. .. _ ' i�L 1��_: �}r'. - r _. r- l .• Y�F�t✓ , �-7 -� - T3 NIO ���Ih� 11 PROPERTY BOUNDARY �J 1' Z�` t - 4 /f i r _ ' WASTE `BOUNDARY ��f � : � _ii • I i 11 "j���� COMPLIANCE `BOUNDARY �v ll�frdr1''�i1' j I J fi I SOURCE: USGS TOPOGRAPHIC MAP OBTAINED FROM THE NRCS GEOSPATIA71ATA GATEWACI AT http://datagateway.nres.usda.gov/ MAYO LAKE POWER PLANT PERSON COUNTY FIGURE 1-1 SITE LOCATION MAP GREENSBORO. MAYO STEAM ELECTRIC PLANT *RALEIGH GREENVILLE 10660 BOSTON RD EEN• Terra •CHARLOTE *FAYETTEVILLE ROXBORO, NORTH CAROLINA CLUSTER SPRINGS, VA QUADRANGLE 148 RIVER STREET, SUITE 220 WILMINGTON GREENVILLE, SOUTH CAROLINA DRAWN BY: 1. CHASTAIN DATE: 201412-22 GRAPHIC SCALE PHONE 864-421-9999 PROJECT MANAGER: K. WEBB CONTOUR INTERVAL: 10R 1000 0 1000 2000 PHONEnterrac 1-99 9 LAYOUT: FIG 1(SITE LOCATION MAP) MAP DATE: 1987 www.syP:\Duke Energy Progress. 026\ 0a. Mayo Asft Basin GW Assessment Plan\i.11 GSA Reporting\Figures\FIGURE - - SGS SITE LOCATIONI.dwg IN FEET VIRGIN,IA` L V I R G I N I A rH' NORTH CIA R 0 L I N A NORTH' CAROLI /;-�-��,. = � �� . �®• I r / r FRW • MAYO ASH i Lr', BASIN ! �..: "1'A • ., �, . • - _ MAYO, PLANT `� ems.• Cr= hL". a I,MONOFI r ', F ` , ' MAYO LAKE MAYO •• ? ... PLANT 7. y ' 1---------- f. LQUISIAN C. ' J \ •�� / •L 1 ... 4. 1 �� `�; . _ rJ. LEGEND bP STREAM STATE BOUNDARY ACTIVE ASH BASIN ASH BASIN COMPLIANCE BOUNDARY �^ DUKE ENERGY PROGRESS MAYO PLANT SITE BOUNDARY :. 7 S��yp1 NOTES: 2014 NAIP AERIAL ORTHOIMAGERY OBTAINED FROM THE ARCGIS IMAGE SERVICE, SERVICE NAME: NAIP/North_Carolina_2014_1m. (httpsl/gis,apfo.usda.gov) 2 PARCEL BOUNDARY WAS OBTAINED FROM THE NC CENTER FOR GEOGRAPHIC INFORMATION AND ANALYSIS. (http://servioes.noonemap.gov/) 9 DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE COORDINATE SYSTEM FIPS 3200 (NAD83/2011). �11 synTerra 148 RIVER STREET, SUITE GREENVILLE, SC 29601 664421-9999 www.synterracorp.com DRAWN BY: R. SPRING ��DUKE ENERGY DATE: 08/26/2015 PROGRESS CHECKED BY: J. MEADOWS MAYO STEAM ELECTRIC POWER PLANT DATE: 08/26/2015 10660 BOSTON RD ROXBORO, NORTH CAROLINA27574 PROJECT MANAGER: J. WYLIE NA L 0 GRAPHIC SCALE 750 0 750 1,500 2,250 3.000 IN FEET FIGURE 1-2 MAYO PLANT VICINITY MAP RAI�ROgD IF A \( ✓ /i \ �/ /i � Jill �%h\�� //�/i�/ Jai � /� � � �_ —� /-� \\1 \1\\ K 10 _-��% iJ% In �//// — i� ��///�J ��iii�%/� � � %%\\\ i_ -\ II��✓ it / / // � \� /%\\\\ Ill ^�,�1 � — _ . , < ■: � �� / � � \ d"t / � �._ \� �-�� ,� � � � -� � �--� „� • : - / / ��-�. ,;� ATAIL�J l\ \ �� �� �_ (\ \ - - — Ems/ [i ■ d �� ,r,////%�\o \ � � � iii� =�\� � = \(( � / \ �(/(( �` !% � / I � 1 1 � \\� mil- --` (/,\ / �\\(�� ®.•- � ®'l I f • l (1��/���\�� j-�— �_ 1 \\\ ` ` I � /ice\\ 1 L � (• � J l/ / `\\ ., 1 Il � l� HALIFAX COUNTY NORTH CAROLINAXIRGINIA STATE LINE (APPROXIMATE) WORI(�s\S�J� � � r �\1\111 I ���.1I111111111 M 11\\�\�\�� ��(I \=� ��b-- _\^\��-�)I��,��////�--_1 1 ( f IIf/1///r-\\1\\�I/I � l I I ��� \ � ///�� I /l - � �, � % = �� \\t\` ��\� - w 1 (( �-�/ ��- � — - — ��\ \(I \ / � / y / �\\ � � - c \ \ \\\ ' • = _/ire �- o �--_� ///����5(i��;./����--� / �� ��� ti��—f� / �• °\ \lu 1� .� � �:�� III � �I1 III I I I ( = � �II% //( �- ��� i! _ ��0, / � lf= = �1�� I � � ` / l `�( ° \1� / � / �\ -- � � �• /!� � �� =�� � '- � — � � 1 %J IIIII�1� III I ( / \ � � �- � � � � �� �����/ �</ �1 / ' • O / �-' ��'`�� � /' � � -\ �\\\ ? ` �`__ � J I I pao \� 1 ll ////�- _ � \\ ✓mil i ( \� oii //ii/,/`��� ��\��/Illilllll�\mow/%/�/0��\\� /�%/// / i/ �.`\� //�ii���� / I it / =,\ � /� \ ��I � �- \r /� S >,� � �/o � / i/�i 1 � � I � . ��� /l II ICI 1\ �\\✓// \\\�11 \\ `,//( a lid . (I \/ /(�l �\ \���/////�\ 111111 ��1\\\111 / \\�� 11 /4 C�/® : m■[ \, / >>/ �� ��_r\� \ ���))II\\\\\\� \ �. \ � � �� \I\��� II �\\ //�/// I / �%" ✓/ i �� 1 I) � f /jam � �7 ( i / / / „' /o � � � — ` ^ �i�� � �\\\ \"\ ti \ \ \\ \ I,QLP\�l/1)IIIII, >>, f �� •, �1 ;// / ^ J �� �,� /ill /%r a% ✓i�� �w" /(\ / I % �\�__=%_ _J�/ I� IP jvcICI � . _tom/oo J / 1 •. d I l� '0 — MAYO LAKE 0, A& 1 IVRI We ..! 5/! 1`BR 341 _ _ HALIFAX CO, - � -- - 1 PERSON CO /FUTURE MAYO LA � � . l '- - - % / 1 FUTURE1981 / LANDFILL r PERMIT NO. 73-B 01 \♦ FUTURE ACTIVE \ ASH BASIN 1 —FUTURE\ _ i ) MAYO LAKE. ��/5 C✓v r� . = _ �^ ♦ FUTURE /_�— POWER PLANT L 1 J << �FUTUREPIAN�OAD � 584 / l L✓1�� v l AN J1 1 (0/ C Bet el Ch Hill MAYO STEAM ELECTRIC PLANT MontaguE � `-• \ _' C e m / Illy Bethel Hill. 1 SOURCE: y) Ilk USGS TOPOGRAPHIC MAP OBTAINED FROM NRCS GEOSPTIAL DATA GATEWAY AT i http://datagateway.nres.usda.gov/ �� PERSON COUNTY FIGURE 2-2 GREGN5130WWILMINGTOIN 1968 USGS TOPOGRAPHIC MAP DUKE ENERGY PROGRESS MAYO STEAM ELECTRIC PLANT Terra � ROXBORO, NORTH CAROLINA CLUSTER SPRINGS VA -NC QUADRANGLE 148 RIVER STREET, SUITE LIN DRAWN BY: JOHN CHASTAIN DATE: 08/16/2015 GREENVILLE, SOUTH CAROLINA GRAPHIC SCALE PHONE 864-421-9999 PROJECT MANAGER; JERRY WYLIE CONTOUR INTERVAL: 10 FEET 1000 0 1000 2000 www.synterracorp.com LAYOUT: FIG 2-2 (1968 USGS TOPO MAP) MAP DATE: 1968 P: Duke EnergyPro ress.1026 105. Mao Ash Basin GW Assessment Plan 1.11 CSA Re ortin Fi ures DE MAYO 1968 USGS TOPO MAP.dw IN FEET 4 y � • FUTURE ACTIVE ASH BASIN FUT�1111 ! .. LANDFILL �� \ PERMIT NO. 73-B / 4.•j�:e�\ z FUTURE POWER PLANT WmFIIMAY0 STEAM /— ELECTRIC PLANT x (q W -~` SOURCE: MARCH 25, 1948 AERIAL PHOTOGRAPH OBTAINED FROM THE USGS EARTH EXPLORER WEB SITE AT http://earthexplorer.usgs.gov/ L —�1 Ir \ ,)0 /i 1 e000* 1 ♦l 1• s / I I /• 1 rr �j /� A• j1 10 rl 000t) 1 j ram,, 4 / 1 1 I GRAPHIC SCALE 500 0 500 1000 IN FEET 148 RIVER STREET, SUITE 220 GREENVILLE, SOUTH CAROLINA 29601 PHONE 864-421-9999 wwwsynterracorp.com synTerra DRAWN BY JOHN CHASTAIN DATE 08/11/2015 n PROJECT MANAGER: JERRY WYLIE \ 1, LAYOUT: FIG 2-3 (1948 AERIAL) \., 08/29/2015 9:11 PM P:\Duke Energy Progress.1026\105. 1 FIGURE 2-3 1948 AERIAL PHOTOGRAPH DUKE ENERGY PROGRESS MAYO STEAM ELECTRIC PLANT ROXBORO, NORTH CAROLINA T�Z J\ SOURCE: JANUARY 24, 1981 AERIAL PHOTOGRAPH OBTAINED FROM THE USGS EXPLORER WEB SITE AT http://earthexplorer.usgs.gov/ 11 ACTIVE POWER PLANT IlMEMili.- ''"'_" I MAYO STEAM ELECTRIC PLANT H FUTURE 1981 —� ; a LANDFILL ♦ \ \♦/ \ / \ PERMIT NO. 73-84. / 1 1 1 / \1 FUTURE MAYO LAKE / F / I l / it 1 / \� )(A \ I /•If/ GRAPHIC SCALE 500 0 500 1000 IN FEET 148 RIVER STREET, SUITE 220 GREENVILLE, SOUTH CAROLINA 29601 PHONE 864-421-9999 www.synte rraco rp. co m JOHNIN DATE 08/11/2015 PROJECT MANAGER:R: JERRJERRY WYLIE TerraiDRAWN8Y OUT: FIG 21(1981 AERIAL) LAYR/ 916 PM a niiva cncrav ornarccc 1n n 1 nS i Q/ n1 721 FIGURE 2-4 1981 AERIAL PHOTOGRAPH DUKE ENERGY PROGRESS MAYO STEAM ELECTRIC PLANT ROXBORO, NORTH CAROLINA �u lr • -— • FOMAVO M ♦ ACTIVE ASH BASIN 1981LANDFILL `� G-�♦�,j/,,�� j�j f\ i/ \ , PERMIT NO. 73-8 l \ A i • i \♦ r/ \ 4. .............. <N ooPoyP�'\I MAYO LAKE POWER PLANT ; I / If If MAYO STEAM ! ELECTRIC PLANT r SOURCE rx` 1993 AERIAL PHOTOGRAPH OBTAINED FROM THE USGS EARTH EXPLORER WEB SITE AT \ \ http://earthexplorer.usgs.gov/ ♦ 1 I 1 t Evaporation Outfall Dug 11 E ling Towers 1a III Maya Reservoir Storm water Outfall 001 14 2 1 14 3 Misc. Equlpmenl Heat 18 Make Structure r�4 Exchangers — 13 Alternate 26 S � Fe Water Storage Ash Sluice Protection Wales I P 1 1 112 Boiler 6 Turbina Condensate Storage Evap and seepage Ash Basin vutiau 1 11 1 Gypsum and See Page OD9 Llmestane Pile 2 and 3 of 7 3 15 Runofi t7 Coal P" A.000 Road Skim econdary Contatnment FGfl Blowdawn Runoff 'water, Power botch SW ar anhydreus ammonia Highway 601 AfgR, tanks ralaFall Mayo Reservoir Ion Exchange Potable water From City of Roxwro Potable & Sanitary 8 Misc.low Volume Duke Energy Progress, Inc. Mayo Stearn ElectrlaPlanl Person County, NC SChemallcot Water Fbw P 1 of 7 octobe 4 Ash basin FGD Make-up Pumps AN 38 (alternate) cE 27 DI botto�ash ' seal wa 29 Evaporation FGD System 37 E� ly ' r Cooling Towers Excess Manaflll teachate Settling Pond _______ _ 33 Bottom Ash Silo 3g 36 Fly Ash Silas 34 Thermal Evaporator 32 Clean Distillate _ Demin-Bialer (Conditioning Water) 31 Make-up 35 Cooling water Monoflll 3s r puke Energy Progress, Inc. Proposed Water balance detail +aye steam Electric Plant Rainfall Dust for thermal evaporator Person County,14C suppression and Dry bottom Ash system Schematic of Water Flow Pape 3 of 7 oco6er Sewage treatment Oily Waste Treatment 7 A 16 OuHall002 Mayo Reservoir 11 CodingTowers d Ouitrall 001 14 41 L._._._._._._--------.._..-----.--_._ ............ Proposed Future 25 24 i Side Stream 14 2 Misc, Equornanl He 18 Intake 2 20 Exchangers Intake t FGD 19 , FGD System 28 12 i 21 Bottom Ash Condensers Sluice Water Fartxlss Mcnoittl Leachate FGD Setging Pond 3 Alternate 12 Boiler B Turbine 22 Emergency Ovaraow Flush Pond 9 Outiall DD9 Bloreaclor Ash Basin 23 Duke Energy Pi Water balance detail for FGD WW Mayo slaam El treatment system (bloreaclor) and Person County, Cooling System only Schematic of w Page 2of7 Potential Dust Groundwater • suppression For- irrigation Outfall 004 Storm water Switchyard C]ulfahs runoff la 006a 006a, b, c, d and e Potential Cooling Tower Draft Outfail 005 Potential Dust Groundwater A suppression irrigation Storm water Proposed Water balance detall for thermal evaporator and Dry bottom Ash system Mayo Reservoir r Y � J y F E R An !,,-�� Fw xsxaza9 ac cono 4 m cm ft) - Figure 5: Known sample of ash for comparison. Figure 3-1: Known sample of ash for comparison. (Source: Duke Energy 2014) Range (10`" percentile — 901" percentile) in bulk composition of fly ash, bottom ash, rock, and soil. (Source: EPRI 2009a) 100% 90% p 80% p 70% a 0 60% U cv 50% 0 ,~40% 6 c 30% 20% 10% 0% Volcanic Ash Shale Fly Ash Bottom Ash ■Si ■AI Fe Ca ■Other Major Elements ■Minor Elements ■Trace Elements Figure 3-2: Elemental composition for bottom ash, fly ash, shale, and volcanic ash. (Source: EPRI 2009a) C J_ E 10 v O 1 0.1 v = 0.01 O V a 0.001 J U H 0.0001 0.00001 ' As Ba Me>orfwjM 9oRh Percentile TCLP Regulatory Lunt loth Peroentiie Mirwnnxn Cd Cr Pb Element Hg Se Ag Figure 3-3: Coal ash TCLP leachate concentration ranges compared to regulatory limits. (Source: EPRI 2010) 100000 10000 a7 1000 tM E l00 • • v 10 loop 0.1 0.01 0.001 As Ba Cd Cr Pb Hg Se Ag Sb Be B Co Cu Mn Ni TI V Zn EPA Residential Soil Screening Level Element *Concentrations less than Fly Ash Range (1021 and 90m percentile) method detection limits. Figure 3-4: Trace element concentration ranges in fly ash compared to EPA residential soil screening levels. (Source: EPRI 2009b) Page 1 of 2 100000 10000 Y 1000 CM E 100 r. Q 10 cc L V 0 0.1 0.01 IIII%III � I • • 1• •• I I I I As Ba Cd Cr Pb Ng Se Ag Sb Be B Cu Mn Ni TI V Zn S EPA Residential Soil Screening Level Element *Concentrations less than Bottom Ash Range (1014 and 90 percentile) method detection limits. Trace element concentration ranges in bottom ash compared to EPA residential soil screening levels. (Source: EPRI 2009b) Page 2 of 2 C6 w ry UF Q M U O Q / a� i7 / tiro O a a) Q co U c-1 -I E_ (6 E_ a) E N U) Q 0 E_ C6 m U) Q O (>3 LS') O 7-1 Q0 N O ui V) a� O ti1.0 Q) LLB a) s r) / 7 M N LO O N M N M 0 4'-5'-. metals, TOC .1.50MEMEME %all MAINE 6 23 A; a MEN 11111111111,11111s, oil 6—a FACING NORTHEAST LEGEND I COAL ASH TRANSITION ZONE BEDROCK REGOLITH SOIL/FILL SAPROLITE ALLUVIUM WATER LEVEL (JUNE 17, 2015) SURFICIAL WATER LEVEL TRANSITION ZONE WATER LEVEL BEDROCK WATER LEVEL FRACTURED/OXIDIZED ZONE OBSERVED IN ROCK CORE 4.4 x 10-4 K Value BORING SYMBOLS SOIL SAMPLE WITH VERTICAL HYDRAULIC WELL SCREEN WITH CONDUCTIVITY HYDRAULIC CONDUCTIVITY OF UNDISTURBED IN CENTIMETERS PER SECOND SAMPLE (SOURCE: SYNTERRA SLUG TEST) (SOURCE: BLE) f, SAMPLE DESCRIPTIONS metals TOTAL METALS TOC TOTAL ORGANIC CARBON IP GRAIN SIZE, MOISTURE CONTEXT HC HYDRAULIC CONDUCTIVITY, SPECIFIC GRAVITY SPLP SYNTHETIC PRECIPITATION LEACHING PROCEDURE Kd SORPTION COEFFICIENTS HFO HYDROUS FERRIC OXIDES min MINERALOGY BY X-RAY DIFFRACTION AND WHOLE ROCK CHEMISTRY SOURCES: 1. THE TOPOGRAPHY SURVEY DATA WITHIN THE PROPERTY BOUNDARY DATED MAY 19, 2015 WAS OBTAINED FROM WSP OF CARY, NORTH CAROLINA. 2. SELECT TOPOGRAPHIC ADJUSTMENTS BASED ON SITE SURVEY AND COMPARISON TO AERIAL PHOTOGRAPH. 3. 2015 LITHOLOGY INFORMATION OF SOIL AND WELL LOG TOPOGRAPHY IS FROM SYNTERRA. 4. GEOLOGIC INFORMATION FOR BORINGS AND MONITORING WELLS INSTALLED PRIOR TO 2015 TAKEN FROM S&ME (2010) AND QUANTEX (2008). NOTE: 1. CROSS SECTION LOCATIONS SHOWN ON FIGURE 2-1. 2. WATER LEVELS WERE COLLECTED BY SYNTERRA ON JUNE 17, 2015. erra 148 River Street, Suite 220 Greenville, South Carolina 29601 864-421-9999 www.synterracorp.com DRAWN BY: C. NEWELL I DATE: 8/5/2015 CHECKED BY: J. WYLIE DATE: 8/5/2015 PROJECT MANAGER: K. WEBB LAYOUT NAME: FIGURE 6-1 DUKE GRAPHIC SCALE ENERGY 300 0 300 600 PROGRESS IN FEET MAYO STEAM ELECTRIC PLANT HORIZONTAL: 1"=300' 10660 BOSTON RD 30 0 30 60 ROXBORO, NORTH CAROLINA IN FEET VERTICAL:1"=30' FIGURE 6-1 NOTE: 10:1 VERTICAL EXAGGERATION GEOLOGIC CROSS SECTION A -A' I Cf 0k1r% )ao 07 LU n, D C� Q 0 U O Q / a� )ao ii / tiA o 0 ry a W U rl rl C6 n a) E U) Q 0 c cn M 00 Q 0 IO O / N O 1H vi cn a� uo 0 n )ao a� LU r) 0 Qo N O N 1-1 00 N 0 � J oU) M2 u.l 550 540 530 520 510 500 490 480 470 0 J 460 450 W 440 430 420 410 400 390 380 370 360 550 540 530 520 510 500 490 480 - W LLI Cn W J U - Q - 400 - 390 - 380 - 370 - 360 d COAL ASH TRANSITION ZONE BEDROCK REGOLITH SOIL/FILL SAPROLITE ALLUVIUM WATER LEVEL (JUNE 17, 2015) SURFICIAL WATER LEVEL TRANSITION ZONE WATER LEVEL BEDROCK WATER LEVEL o FRACTURED/OXIDIZED ZONE ^� OBSERVED IN ROCK CORE W 0 E = 4.4 x 10-4 K Value BORING SYMBOLS SOIL SAMPLE WITH VERTICAL HYDRAULIC WELL SCREEN WITH CONDUCTIVITY HYDRAULIC CONDUCTIVITY OF UNDISTURBED IN CENTIMETERS PER SECOND SAMPLE (SOURCE: SYNTERRA SLUG TEST) (SOURCE: BLE) O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O o O O O O O O O O O O o O O O o O O O O O O O O O O O O O CD O O O O O CD O O O O O O O O O O O O O O CD O O O CD O O CD O CD CD O O O O O O O O + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + CD O .- N M �h u) (O f� M O CD— N CO LO (O I- CO M CD— N M � LO (9 f� CO M O N M � LO (O I� M O CD— N M ,I- LO coLO (o IM CD— N co It LO (D I1_ co N N N N N N N N N N co M co M M M co M co co It It It It It - It V) V) V) V) V) V) V) LO LO LO CO CO co CO CO (0 CO CO (0 co metals WEST Station (feet) TOC SECTION C-C' IP FACING NORTH HC C' I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I L 19' MIN 0 550 - 540 - 530 - 520 - 510 - 500 - 490 - 480 - 470 - 460 o co - 450 0 w� 440 - 430 - 420 - 410 - 400 - 390 - 380 - 370 360 O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O + + + + + + + + + + + + + + + + + + + + O — N CO � LO (D f— CO O O — N co � U) (D fl- M M ti � ti ti � ti rl- I— I— � CO co CO co co CO co co CO co EAST SECTION C-C' FACING NORTH SPLP Kd HFO SAMPLE DESCRIPTIONS TOTAL METALS TOTAL ORGANIC CARBON GRAIN SIZE, MOISTURE CONTEXT HYDRAULIC CONDUCTIVITY, SPECIFIC GRAVITY SYNTHETIC PRECIPITATION LEACHING PROCEDURE SORPTION COEFFICIENTS HYDROUS FERRIC OXIDES min MINERALOGY BY X-RAY DIFFRACTION AND WHOLE ROCK CHEMISTRY SOURCES: 1. THE TOPOGRAPHY SURVEY DATA WITHIN THE PROPERTY BOUNDARY DATED MAY 19, 2015 WAS OBTAINED FROM WSP OF CARY, NORTH CAROLINA. 2. SELECT TOPOGRAPHIC ADJUSTMENTS BASED ON SITE SURVEY AND COMPARISON TO AERIAL PHOTOGRAPH. 3. 2015 LITHOLOGY INFORMATION OF SOIL AND WELL LOG TOPOGRAPHY IS FROM SYNTERRA. 4. GEOLOGIC INFORMATION FOR BORINGS AND MONITORING WELLS INSTALLED PRIOR TO 2015 TAKEN FROM S&ME (2010) AND QUANTEX (2008). NOTE. 1. CROSS SECTION LOCATIONS SHOWN ON FIGURE 2-1. 2. WATER LEVELS WERE COLLECTED BY SYNTERRA ON JUNE 17, 2015. rra 148 River Street, Suite 220 Greenville, South Carolina 29601 864-421-9999 www.synterracorp.com DRAWN BY: C. NEWELL DATE: 8/5/2015 CHECKED BY: J. WYLIE DATE: 8/5/2015 PROJECT MANAGER: K. WEBB LAYOUT NAME: FIGURE 6-3 DUKE GRAPHIC SCALE ENERGY 300 0 300 600 PROGRESS IN FEET MAYO STEAM ELECTRIC PLANT HORIZONTAL: 1"=300' 10660 BOSTON RD 30 0 30 60 ROXBORO, NORTH CAROLINA IN FEET VERTICAL:1"=30' FIGURE 6-3 NOTE: 10:1 VERTICAL EXAGGERATION GEOLOGIC CROSS SECTION C-Cl tiA LLJ n, D (D Q U O Q a� tiA ii tiA o 0 a U rl C6 n a) E 4) U) >Q 0 (B m V) Q O (6 L6 O / U N O 1H vi a� uo 0 n E. � LIJ 0 / a_ 00 N Ln 1H O N 00 N 0 /' 550 540 530 520 510 500 490 OJ 480 W LLI 470 460 450 440 430 420 410 NOI MW-05BR(42.0-44.5) SHARP CONTACT BETWEEN FELSIC AND MARC GNEISS MW-05BR (44.5-47.0) MARC BEDROCK WITH MYLONITIC TEXTURE AND CALCITE STRINGERS LEGEND COAL ASH TRANSITION ZONE BEDROCK REGOLITH SOIL/FILL SAPROLITE ALLUVIUM WATER LEVEL (JUNE 17, 2015) SURFICIAL WATER LEVEL TRANSITION ZONE WATER LEVEL BEDROCK WATER LEVEL z1U FRACTURED/OXIDIZED ZONE OBSERVED IN ROCK CORE 4.4 x 10-4 K Value BORING SYMBOLS SOIL SAMPLE WITH VERTICAL HYDRAULIC WELL SCREEN WITH CONDUCTIVITY HYDRAULIC CONDUCTIVITY OF UNDISTURBED IN CENTIMETERS PER SECOND SAMPLE (SOURCE: SYNTERRA SLUG TEST) (SOURCE: BLE) SAMPLE DESCRIPTIONS metals TOC IP HC SPLP Kd HFO min SOURCES: TOTAL METALS TOTAL ORGANIC CARBON GRAIN SIZE, MOISTURE CONTEXT HYDRAULIC CONDUCTIVITY, SPECIFIC GRAVITY SYNTHETIC PRECIPITATION LEACHING PROCEDURE SORPTION COEFFICIENTS HYDROUS FERRIC OXIDES MINERALOGY BY X-RAY DIFFRACTION AND WHOLE ROCK CHEMISTRY 1. THE TOPOGRAPHY SURVEY DATA WITHIN THE PROPERTY BOUNDARY DATED MAY 19, 2015 WAS OBTAINED FROM WSP OF CARY, NORTH CAROLINA. 2. SELECT TOPOGRAPHIC ADJUSTMENTS BASED ON SITE SURVEY AND COMPARISON TO AERIAL PHOTOGRAPH. 3. 2015 LITHOLOGY INFORMATION OF SOIL AND WELL LOG TOPOGRAPHY IS FROM SYNTERRA. 4. GEOLOGIC INFORMATION FOR BORINGS AND MONITORING WELLS INSTALLED PRIOR TO 2015 TAKEN FROM S&ME (2010) AND QUANTEX (2008). NOTE. 1. CROSS SECTION LOCATIONS SHOWN ON FIGURE 2-1. 2. WATER LEVELS WERE COLLECTED BY SYNTERRA ON JUNE 17, 2015. Wni(erra 148 River Street, Suite 220 Greenville, South Carolina 29601 864-421-9999 www.synterracorp.com DRAWN BY: C. NEWELL DATE: 8/5/2015 CHECKED BY: J. WYLIE DATE: 8/5/2015 PROJECT MANAGER: K. WEBB LAYOUT NAME: FIGURE 6-4 DUKE GRAPHIC SCALE ENERGY 300 0 300 600 PROGRESS IN FEET MAYO STEAM ELECTRIC PLANT HORIZONTAL: 1"=300' 10660 BOSTON RD 30 0 30 60 ROXBORO, NORTH CAROLINA IN FEET FIGURE 6-4 VERTICAL:1"=30' GEOLOGIC CROSS SECTION A -A' NOTE: 10:1 VERTICAL EXAGGERATION WITH PHOTOGRAPHS 1 CP%C\Ir% )ao LU Q U O Q a� i.i / i 0 Of a W U rl rl C6 a) 4) U) >Q 0 cB m Q 0 c� I6 O / N O 1H vi N uo 0 n )ao a� LU / 0 r.1 0) N I-0 O N 00 N 0 Afle MENEM 0 �CMENNow Nil I - of �§ I so III metals,TOC, Kd, HFO, minjI ME 11 HOME- ... .. . . . min -350 340 330 321 Zi SECTION B-B' FACING NORTHWEST MW-16BR(47.0-50.0) CROSSING FRACTURES IN GRANITIC GNEISS MW-16BR (54.0-55.0) BLACK FINE GRAINED PHYLLI I E PIECES ABOVE DARK GRAY SILTY MATRIX �0— .i f r k i ABMW-02BR (117.0-120.0) GRANITIC GNEISS TO 119.3' BGS, SHARP CONTACT WITH DARK GRAY PHYLLITE GRAPHIC SCALE 300 0 300 IN FEET HORIZONTAL: 1"=300' 30 0 30 COAL ASH TRANSITION ZONE BEDROCK REGOLITH --¢ SOIL/FILL 0 SAPROLITE ALLUVIUM WATER LEVEL (JUNE 17, 2015) SURFICIAL WATER LEVEL TRANSITION ZONE WATER LEVEL BEDROCK WATER LEVEL FRACTURED/OXIDIZED ZONE OBSERVED IN ROCK CORE 4.4 x 10-4 K Value BORING SYMBOLS SOIL SAMPLE WITH VERTICAL HYDRAULIC WELL SCREEN WITH CONDUCTIVITY HYDRAULIC CONDUCTIVITY OF UNDISTURBED IN CENTIMETERS PER SECOND SAMPLE (SOURCE: SYNTERRA SLUG TEST) (SOURCE: BLE) SAMPLE DESCRIPTIONS metals TOTAL METALS TOC TOTAL ORGANIC CARBON IP GRAIN SIZE, MOISTURE CONTEXT HC HYDRAULIC CONDUCTIVITY, SPECIFIC GRAVITY SPLP SYNTHETIC PRECIPITATION LEACHING PROCEDURE Kd SORPTION COEFFICIENTS HFO HYDROUS FERRIC OXIDES min MINERALOGY BY X-RAY DIFFRACTION AND WHOLE ROCK CHEMISTRY SOURCES: 1. THE TOPOGRAPHY SURVEY DATA WITHIN THE PROPERTY BOUNDARY DATED MAY 19, 2015 WAS OBTAINED FROM WSP OF CARY, NORTH CAROLINA. 2. SELECT TOPOGRAPHIC ADJUSTMENTS BASED ON SITE SURVEY AND COMPARISON TO AERIAL PHOTOGRAPH. 3. 2015 LITHOLOGY INFORMATION OF SOIL AND WELL LOG TOPOGRAPHY IS FROM SYNTERRA. 4. GEOLOGIC INFORMATION FOR BORINGS AND MONITORING WELLS INSTALLED PRIOR TO 2015 TAKEN FROM S&ME (2010) AND QUANTEX (2008). NOTE. 1. CROSS SECTION LOCATIONS SHOWN ON FIGURE 2-1. 2. WATER LEVELS WERE COLLECTED BY SYNTERRA ON JUNE 17, 2015. erra 148 River Street, Suite 220 Greenville, South Carolina 29601 864-421-9999 www.synterracorp.com DRAWN BY: C. NEWELL DATE: 8/5/2015 CHECKED BY: J. WYLIE DATE: 8/5/2015 PROJECT MANAGER: K. WEBB LAYOUT NAME: FIGURE 6-5 DUKE ENERGY 600 PROGRESS MAYO STEAM ELECTRIC PLANT 10660 BOSTON RD 60 ROXBORO, NORTH CAROLINA IN FEET VERTICAL: 1"=30' NOTE: 10:1 VERTICAL EXAGGERATION FIGURE 6-5 GEOLOGIC CROSS SECTION B-B' WITH PHOTOGRAPHS MW-13BR (47.0-57.0) SAPROLITE GRADING INTO PWR )ao Y5 LU n, D C� Q 0 U O Q / a� )ao i.i / tiA o ry a W U rl rl C6 n Q) E v! U) Q 0 c cn M 00 Q 0 I6 O / N O vi cn 0 uo 0 n )ao a� LU r) / �7 a_ O N 00 N 0 qllpsa-i 0 550 540 530 520 510 500 490 480 - W U) LU - Q - 400 - 390 - 380 - 370 - 360 ABMW-02BR (102.0-105.0) GRANITIC GNEISS WITH SHARP CONTACT INTO HORNBLENDE GNEISS MW-07BR (57.0-67.0) GREENSCHIST FACIES ROCK TO 65.7' BGS SHARPE CONTACT WITH GRANITIC GNEISS I I I I I I I I I I I I I I I I I I I 1 I I I I I I I I C r AMAT, X 1 1. MI imms MW Emilio 0 550 - 540 - 530 - 520 - 510 - 500 - 490 - 470 - 460 0� - 450 0 w� 440 - 430 - 420 ABMW-03S (53.0-58.0) SATURATED SAPROLITE BELOW ASH 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + O — N M 'T LO (O r— a0 O O — N co It LO co I1- 00 M O N co It Lf) (D I1- co M 4c- It 'IT `71It It I It It It V) V) V) LO LO Ln LO (f) Lf) LO (0 CO co CO CO co (0 CO co (D \Station (feet) ABMW-02BR (117.0-120.0) GRANITIC GNEISS TO 119.3' BGS, SHARP CONTACT WITH DARK GRAY PHYLLITE MW-08S/ 08D (26.5-36.5) SAPROLITE INTO TRANSITION ZONE j !� � � %" y�y°{�. �.`�"f � � `,F, rf� r� a � ,.tea r � L '�„ _ •; fe �'^. ��,�1. ly k �'y' a \ � r • � � V'1 �1 � t .c�.� •A�• s .,'n i 1 '.,:. I MW-08BR (76.5-86.5) HARD, FRESH META-ARGILLITE OR METAVOLCANIC BEDROCK WITH PHYLLITE ON FOLIATION BREAKS - 410 f - 380 I 4.. - 370 360 � ����� O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O CD CD CD CD CD CD CD + + + + + + + + + + + + + + + + + + + + CD N CO Lf) (D f— 00 O O N co L0 (D f— 00 O) ti � ti ti r-- I-- � I --I-- � 00 co co co co coco co co co EAST SECTION C-C' FACING NORTH A - MW-09BR(34.0-36.0) LEGEND SAPROLITIC SCHIST COAL ASH TRANSITION ZONE BEDROCK REGOLITH SOIL/FILL SAPROLITE ALLUVIUM WATER LEVEL (JUNE 17, 2015) 500 SURFICIAL WATER LEVEL 4 TRANSITION ZONE WATER LEVEL 480 W BEDROCK WATER LEVEL LU z: 0 �U FRACTURED/OXIDIZED ZONE -j c� OBSERVED IN ROCK CORE 07 (D 0 w 4.4 x 10-4 K Value Z J BORING SYMBOLS U H Q SOIL SAMPLE 2 WITH VERTICAL 400 HYDRAULIC WELL SCREEN WITH CONDUCTIVITY HYDRAULIC CONDUCTIVITY 390 OF UNDISTURBED IN CENTIMETERS PER SECOND SAMPLE (SOURCE: SYNTERRA SLUG TEST) 380 (SOURCE: BLE) 370 360 SAMPLE DESCRIPTIONS metals TOTAL METALS TOC TOTAL ORGANIC CARBON IP GRAIN SIZE, MOISTURE CONTEXT HC HYDRAULIC CONDUCTIVITY, SPECIFIC GRAVITY SPLP SYNTHETIC PRECIPITATION LEACHING PROCEDURE Kd SORPTION COEFFICIENTS HFO HYDROUS FERRIC OXIDES min MINERALOGY BY X-RAY DIFFRACTION AND WHOLE ROCK CHEMISTRY SOURCES: 1. THE TOPOGRAPHY SURVEY DATA WITHIN THE PROPERTY BOUNDARY DATED MAY 19, 2015 WAS OBTAINED FROM WSP OF CARY, NORTH CAROLINA. 2. SELECT TOPOGRAPHIC ADJUSTMENTS BASED ON SITE SURVEY AND COMPARISON TO AERIAL PHOTOGRAPH. 3. 2015 LITHOLOGY INFORMATION OF SOIL AND WELL LOG TOPOGRAPHY IS FROM SYNTERRA. 4. GEOLOGIC INFORMATION FOR BORINGS AND MONITORING WELLS INSTALLED PRIOR TO 2015 TAKEN FROM S&ME (2010) AND QUANTEX (2008). NOTE. 1. CROSS SECTION LOCATIONS SHOWN ON FIGURE 2-1. 2. WATER LEVELS WERE COLLECTED BY SYNTERRA ON JUNE 17, 2015. Icip WnTerra 148 River Street, Suite 220 Greenville, South Carolina 29601 864-421-9999 www.synterracorp.com DRAWN BY: C. NEWELL DATE: 8/5/2015 CHECKED BY: J. WYLIE DATE: 8/5/2015 PROJECT MANAGER: K. WEBB LAYOUT NAME: FIGURE 6-6 DUKE GRAPHIC SCALE ENERGY 300 0 300 600 � p ®� p C IN FEET HORIZONTAL: 1"=300' MAYO STEAM ELECTRIC PLANT 10660 BOSTON RD 30 0 30 60 ROXBORO, NORTH CAROLINA IN FEET FIGURE 6-6 VERTICAL:1"=30' GEOLOGIC CROSS SECTION C-C' NOTE: 10:1 VERTICAL EXAGGERATION WITH PHOTOGRAPHS N di m� A Zh Maro G��EK _ VIRGINIA F ' - MW-15BR NORTH CAROLINA J � CW-04 CW-03 j6, - - PA CZfg MW-05BR MW-0� SR 501 5-01 CW-02 \ s CW-02D MW-08S - S-02' MW-08D 9 qt h � CW-08 1111W�0813R MW-08BR M' W�U7D ° ACTIVE Mr 7BR ASH BASIN (� �4, MW-04 tip MW-136R �k. JMW-naRR ` ABMW-01 } '* • ABMW-02 �' • `` ABMW-02BR ABMW-03S CW-01D ►- `�;� ABMW-04 ABMW-04D • BG-01 ABMW-04BR -� � a — JL MW-10BR _ .. r • - ♦ ♦ BG-02 _ r CZfg P MW-11 BR' • CzfV . J nNII •, `♦ MW-12S I/ MW-12D — •• ♦ I , `•, J4•♦ �• cn J � I ♦ LEGEND NORTH CAROLINA GEOLOGIC UNITS' CZfg - FELSIC MICA GNEISS (CHARLOTTETERRANE) CZfv - FELSIC I MARC METAVOLCANIC ROCK (CAROLINA TERRANE) VIRGINIA GEOLOGIC UNITS2 Zh - PROTEROZOIC METAVOLCANIC SCHIST di - PROTEROZOIC QUARTZ DIORITE MONITORING WELL TOE DRAIN ACTIVE ASH BASIN BOUNDARY �^ DUKE ENERGY PROGRESS MAYO PLANT SITE STATE BOUNDARY > STREAM NOTES: ' NORTH CAROLINA GEOLOGIC BOUNDARIES MODIFED TO CORRESPOND WITH SYNTERRA FIELD OBSERVATIONS. MAP BASED ON GEOLOGIC SHAPEFILES OBTAINED FROM THE USGS. USGS OPEN -FILE REPORT 2005-1323, PRELIMINARY INTEGRATED GEOLOGIC MAP DATABASE FOR THE UNITED STATES: ALABAMA, FLORIDA, GEORGIA, MISSISSIPPI, NORTH CAROLINAAND SOUTH CAROLINA, DATED 2007. (https://pubs.usgs.gov/of/2005/1323/) 2 VIRGINIA GEOLOGIC BOUNDARIES WERE NOT MODIFIED, AND ARE SHOWN FOR REFERENCE. GEOLOGIC FEATURE CLASSES OBTAINED FROM THE USGS. OPEN -FILE REPORT 2005-1325. PRELIMINARY INTEGRATED GEOLOGIC MAP DATABASE FOR THE UNITED STATES: DELAWARE, MARYLAND, NEW YORK, PENNSYLVANIA, AND VIRGINIA. (http://pubs.usgs.gov/of/2005/1325/) ] SHADED RELIEF MAP BASED ON LIDAR DEM 20 DATA FROM NORTH CAROLINA FLOOD RISK INFORMATION SYSTEM. ACCESSED ON JANUARY 2, 2015. 4 PARCEL BOUNDARY WAS OBTAINED FROM THE NC CENTER FOR GEOGRAPHIC INFORMATION AND ANALYSIS. (http:llservices.nconemap.gov/) 5 DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE COORDINATE SYSTEM RIPS 3200 (NAD8312011). GRAPHIC SCALE 500 0 500 1 000 1 500 2000 2 500 IN FEET DUKEv C �' ENERGY synTerra PROGRESS 148 RIVER STREET, SUITE 220, MAYO STEAM ELECTRIC POWER PLANT a c 6REENVILLE, SC 29601 10660 BOSTON RD 864-421-9999 ROXBORO, NORTH CAROLINA27574 www.synterracorp.com a FIGURE 6-7 GENERALIZED GEOLOGIC MAP //, or - 000-. bfjlLm IsO s r /a o ►� SR•1501 ` � y ACTIVE ASH BASIN Z . `' -GNP 1- . 1981 �. �.NDFILL ..� if/1 + ■ r _ AA , / dw 0 r L - # i • Cho 400 Y ° • 'jolp LEGEND O WATER SUPPLY WELD ■ DUKE ENERGY PRODUCTION WELL' MONITORING WELL FRACTURE TRACE ASH BASIN BOUNDARY L ! ASH BASIN COMPLIANCE BOUNDARY DUKE ENERGY PROGRESS MAYO PLANT SITE BOUNDARY NOTES: DRINKING WATER WELLAND RECEPTOR STUDY (APPENDIX B). SHADED RELIEF MAP BASED ON LIDAR DEM 20 DATA FROM NORTH CAROLINA FLOOD a RISK INFORMATION SYSTEM ACCESSED ON JANUARY 2, 2015. a PARCEL BOUNDARY WAS OBTAINED FROM THE NC CENTER FOR GEOGRAPHIC INFORMATION AND ANALYSIS. (http://services.nconemap.gov/) DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE ~' COORDINATE SYSTEM RIPS 3200 (NAD8312011). GRAPHIC SCALE w 600 0 600 1,200 1,800 2,400 3,000 LL (IN FEET) LL 4nDUKE 141P0 _ ENERGY syn Terra PROGRESS a 148 RIVER STREET, SUITE 220, MAYO STEAM ELECTRIC POWER PLANT GREENVILLE, SC 29601 10660 BOSTON RD m 864 421-9999 ROXBORO, NC 27574 m FIGURE 6-8 FRACTURE TRACE ANALYSIS 4Lj Ir t .,,;r1► ' i ' ' yl' f T r ti .1 , �,;t - r, - `• ,' ;� `ir r+r�1r +�1 ';; {`y�,' �► .4` -�_ i, .�� /� r ..y ,� s �♦i� ►. q� ♦ � � �t •� „ 'L ' /`! �•Cf ♦ I �. �,T�}.;, ,� ,I'--�_/-�-.i R � \` .r ��r•*� f',•� y � � y� i 1 •� �T' '� - ; r _ f , t ' ! • a. a• ` « r. �'�EC"�+ -'' -' # ' • ,-!' ,e r a . •' . f , • � . ' , Y i, � ' ^ -{� J., d4• Y ` .7t • { r ♦•,� • _ 3ra r• y 1, , ' e• ,+L� fps �"�'1�" , c - �ti1 f' �, t •°} r, -•.� J 4 �'7* Yt '• 1? ,- t i[ r/ / .r `� '1� 4}' _ ' S '? ♦ 'i rA'����"`���- - *. ' HAD COUNTY _ '� ., 1 • i •'_ w f + HALIFAX COUNTY NSTATE LINE (APPaox MATE)A _ t► `ti'r,ate• t ...M�. #A 1 ` N> ►� PERSON COUNTY - JI 4 1F r PERSON COUNTY �I y a -� ,. • � r"� .•a ,�.,�.! y♦`• - .. t r fit' y'•ti•tr 't_,^,= MW-15BR '� 1 ti .�.h ; �� 4• J 402.68 �► 0 [ y 'j. a` '`f i'1# 427.70 . ��/ a • ` b MAYOLAKERD A � `, '•�+.�, shy. 'y�; .i MW-16D' �s MW3BR C 421.83 41.88 O60 SO MW 16S 470 r r - 0� ��b ii - i t ♦ ♦,'� :+ 1 r MW-14BR M r ' . * '� �i 2 504.61 I _ - I v UNNAMED BRANCH t . i` L rt CRUTCHFIELD Y .i . vor BRANCH -v. ya �. • a,_ . f• i L p `D _ `....; 435.11 f c .iy-....,, rd .r• ,� '.' ITT/ . .y••r..t . `� j + MW 05BR CW 05 P1 PIAaYpLAKERD 501.94 S 0104 375CW-.29 400_+ �\ MA 1 i.•t� .' [.4jc ,�• , v �� r'I ` 1�� , d' t_ P2 P2A 44.7 MW 3 D s 'r _ # f % f t _ `♦' 377.32 �� 375.29 '1 ' .!• .. I [ 4�0 47 . - 1 �• +�' w l`/' - r w 'r q C + ♦ 4�o As a 3° S'02A �NLV s�. 407.15 dF 1 i i 1 � . ` ' • 1 + at' r-fall 4 o So qao 382± O �� le `` 1 .� �. ;1 ', R '� { •.�l - _ � . 376± � CW-06 _ - ','4 a - r . � - - t - i Y , �a l • f �.X` y ` �y[ '%1l i/ / +S' ' • I r `r. 1,,�M P3A P3 . 450.81 i +1 ✓ d ]+i+a. �, A 4, pT M p� P4A S 08 4 MW-08BR �p !432.54 } • •. ,, r + y `E►. 191A 446± rI Mw-08S i Pr �• T+ ,.y r�,'.i`X•►'�rt 'N - �TF9 } �` ,i~ as �+ �k ® 437.02 �• 't Z � P r _ MW 08D • 1 =i?4!+,. i {,r o e -° ► .� MW 07D ®MW-07BR • i . .,. • . � �,,. " 433.53 t ;� tS t' ". "Z..! �470 " Ali s 444.46 1 �ti � � 445.94 OyQ ••.. ;� • `o'er ♦ '; 1 i' .�` r •.. ,, •r' r. , i t T� ACTIVE ASH BASIN � . h , t�"t ''. _. / ' ` .. WATER LEVEL 479.8 4 ,. jl If a { + 4 ..i'#r f '•, L� rl. e.� } E ��► r ♦f �� MW-4 fy�r� I `. .� / ' •,� 3,R• E �7 >i r.' •'•� ' J t0� , r• • >i 1. 4 496.61 f�, is T rt 1981 LANDFILL • r1 . L o 1, *^ t . q 3 4Lg`' '��0 �F _ /' �:j ' • t� PERMIT NO. 73-B oP �'� t.. 3 / MW 13BR a �•. Sri `o 4;�P \ MW-09BR i ! r.. ` P •`.' " AN 470.42 ♦ 1 ' ' 'r`.t ` ABMW-01 rE' a 477.93 HAUL ROAD TO MONOFILL ' t HAUL ROAD TO MONOFILL - l' - - 2 •1 ' �y ' Zw J1010 ♦ I V } '� 4, s ABMW-02 4 ' •r ! 481.56 ABMW 03S -°L .. + , . CW 01D z .,•1 4 ` •'�„ !r* i - ` rj 'y. 483.04 471.93 ? >i ,lf • N ABMW-02BR ► ® 482.75 CW ;' • ] �! O ABM W-03 b Y tit r 483.02 Tt 1`f �t;.�*,'' • <„ .,T'�� , { t a �. r may'_. ''+ ''• r TLr 'r f�j ' �l, t w < A -BM W 04BR . .t f -4 a ► /° '' lr' A,. - r - / ABMW-04D 483.42 1 �. ! • 4 �.+.� ,�. =.�q , .j• i ±._ {j. 485.06 ® ABMW-04 l i x • . � • ;� t I . 485.11 1 r - 4 r/ "� �� ��;i MAYO LAKE ' 3 [ '+� - r - • s ' j ,� ' + � � y � { • � �• � WATER ELEVAT-44 ION 436' 51026 O y' f �k' i► 4 "oft i4 • 'y • e r J �*y • r r i. `'1r y a� ` �` ' , q SO 4' {1 r �f `` I ?�90 d0p' L •' •,��j.r,.." `i -►`,•f 11 .r' / • r r f 5 ' r ' ��� i ' ; o , • a MW 10BR - s . [ 'f• f, . ` va o r T +i 499.57 % S� M ,` ..� �• r+ r �1}, �' -, q f L RAW WATER INTAKE STRUCTURE ,♦ w t C w, -- V F.•• '. v 1 � ! (} ' w•. � '�,r � ' ♦ •, `:� _ \ '� '.�,.. . ! y y� � • __ _. _ �.i= L .. °' � Ate`` qu - ' ELECTRIC PLANT f a/ ,46._, t r x 511.16� IL Ir i f s 4A d� 4. t 41 OP r t �(, 1 f-r .. � r,f � .! •`, ' ,. +• '� _ � . � 488.05 p Ilk N r p q ti CO t Z. ' 1 DEP 2 t♦ 4; ` ti l a._ ♦yi1, - q DEP 3 1 I �` I \ 1:4t `� rah AAA q' I a AL LOUISIANA PACIFIC CORPORATION PL ESSROAD MW-12D MW 12S 4 556.90 ® 556.60 / / N 1 i. -- 1 1 Ilk qr ` DEP 1 'VIE-Nor- ir t!r` A. Ot T `• `ft .��.'. l -ter ' • I .'}op 1 1 ri♦"�ir• r}'f� Li to LEGEND Mw o6BR ASSESSMENT WELL WELL 407.15 ELEVATION IN FEET (msl.) BG 02 BACKGROUND COMPLIANCE WELL 511.16 ELEVATION IN FEET (msl.) l COMPLIANCE WELL 4 0.81 EELOEVATIONDIN FEET (msIENT MW 3 MONITORING WELL 377.32 ELEVATION IN FEET (msl.) WATER LEVEL CONTOUR IN FEET (msl.) - - INFERRED WATER LEVEL CONTOUR (msl.) f GROUNDWATER FLOW DIRECTION DUKE ENERG PROGRESS ❑❑❑ COMPLIANCE BOUNDAR WASTE BOUNDAR PARCEL LINE (APPROXIMATE) SOURCES: AERIAL PHOTOGRAPH OF PERSON COUNT ! NORTH CAROLINA OBTAINED FROM THE NRCS GEOSPATIAL DATA GATEWA_ AT http://datagateway. nres. usda.gov/ ❑❑ ❑❑❑r AERIAL PHOTOGRAPH WAS OBTAINED FROM WSP FLOWN ON APRIL i DRAWING HAS BEEN SET WITH A PRO ECTION OF NORTH CAROLINA STATE PLANE COORDINATE S STEM FIPS __-_ (NAD __)_ WATER LEVELS: 1.) WATER LEVELS WERE COLLECTED BY SYNTERRA ON JUNE 17, 2015 2.) NEW WELLS WERE SURVEYED BY McKIM& CREED. THE HORIZONTAL DATUM IS SET TO NAD83 AND THE VERTICAL DATUM IS SET NGVD88. 3.) COMPLIANCE MONITORING WELL LOCATIONS AND WASTE BOUNDARYPROVIDED BU DUKE ENERGY PROGRESS 4.) ADDITIONAL MONITORING WELL AND PIEZOMETER LOCATIONS WERE BASED ON DATA PROVIDED BY PROGRESS ENERGY. GRAPHIC SCALE 400 0 100 400 800 (IN FEET) s n erra 148 River Street, Suite 220 Greenville, South Carolina 29601 864-421-9999 www.synterracorp.com DRAWN BY: JOHN CHASTAIN DATE: 08/27/2015 CHECKED BY: JERRY WYLIE DATE: 08/27/2015 PROJECT MANAGER: KATHY WEBB LAYOUT NAME: FIG 6-9 (WL MAP) DUKE ENERGY PROGRESS MAYO STEAM ELECTRIC PLANT 10660 BOSTON RD ROXBORO, NORTH CAROLINA FIGURE 6-9 WATER LEVEL MAP JUNE 2015 3 a W w J cr w a U 0 Q w 0 i ap bA 0 Q a 0 U c-I i a E ID Q s= co m a O cu Lfi 0 i O N 0 N bA a LU W 0 s 0 a a rn c� LO -1 0 N N NORTHWEST RGO ASH AREA OF CONCENTRATIONS IN GROUNDWATER ABOVE 2L & IMAC LEGEND INFERRED OR MEASURED APPROXIMATE WATER TABLE ACTIVE ASH BASIN (SOURCE) ASH PORE WATER Al synTerra K REGOQTH t•Li�i�Y�L1�� ASH BASIN DAM 148 RIVER STREET, SUITE 220 GREENVILLE, SOUTH CAROLINA 29601 PHONE 864-421-9999 www.synterracorp.com DRAWN BY: JOHN CHASTAIN DATE: 08/17/2015 PROJECT MANAGER: JERRY WYLIE LAY�OUo. G 6n10 nCONEPToUAL LSECTIONo.,,�.e« �mc�anc i SOUTHEAST I DX CULVERT CRUTCHFIELD BF2A�NCH NDER ROAD II 'T�P9f 1�_ FIGURE 6-10 CROSS-SECTION SITE CONCEPTUAL MODEL DUKE ENERGY PROGRESS MAYO STEAM ELECTRIC PLANT ROXBORO, NORTH CAROLINA 1 C^=k1r% tiw U7 w n, C� Q cn U O Q / U) N taA LL o Q D' a U) U �i cB n a) E U) 0) U) cn a 0 cn m m cn a 0 c� I6 O / O N O vi U) a) w 0 A E. E. � w 0 / im 00 O ri LO O N 00 N 0 SB-4/ MW-10BR SB-4: pH 7.86 / Sb <1 / As <1 / Ba 27 / B <50 / Cr(VI) NS / Co <1 / Fe 883 / Mn 894 / TI <0.2 / TDS 330 / V 1.66 MW-14BR 0.75'-1.0': Sb <1.1 / As 1.4 / Ba 81.8 / B 13.6 j / Cr 41.9 / Co 12.4 / Fe 18600 / Mn 527 / TI <1.1 / V 35.1 MW-14BR: pH 6.7 / Sb <1 / As <1 / Ba 30 / B <50 / Cr(VI) NS / Co 1.41 / Fe 907 / Mn 544 / TI <0.2 / TDS 190 / V 1.29 13.0'-13.75': Sb <1.1 / As 1.1 / Ba 479 / B 26.4 j / Cr 68.3 / Co 22.2 / Fe 35500 / Mn 3200 / TI 0.97 j / V 46.2 ABMW-03/ 03S 1 A ABMW-03: pH 6.63 / Sb <1 / As 193 / Ba 200 / B 1940 / Cr(VI) <0.005 / Co <1 / Fe 3890 / Mn 451 / TI 0.289 / TDS 350 / V 0.68 A 550 ABMW-03S: pH 5.21 / Sb <1 / As 1.04 / Ba 25 / B 1100 / C00 <0.005 / Co 3.98 / Fe 2630 / Mn 478 / TI <0.2 / TDS 110 / V <0.3 m 550 CW-05 51'-53': Sb<6.8/As<6.8/Ba56.1/B<17/Cr1.3j/Co6.6j/Fe16900/Mn319/TI<6.8/V28.8 C) 540 CW-05: pH 6.6 / Sb NS / As NS / Ba NS / B NS / Cr(VI) NS / Co NS / Fe NS / Mn NS / TI NS / TDS NS / V NS PLANT 540 530 MW-05BR 0 530 520 MW-05BR: pH 7.1 / Sb <1 / As <1 / Ba 31 / B <50 / Cr(VI) NS / Co <1 / Fe 4240 / Mn 1740 / TI <0.2 / TDS 380 / V <0.3 m 520 510 - 510 500 - - - - - - - - - 500 71 0 J 490 _ - - _ O O _ ASH BASIN �� 490 0 4_1 480 - --- - -- - N w� 470 - --- -- --- - - _--_ -- _-- O O O \� COALASH O =--= - =--- - 470 w� 4.16 x 10-s - O - - - - - - 3.12 x 10- 460 460 - - --- - -- ---- ---- - ---- -- - -- 450 - --- --- --- 4.44x10 = ---- --- --- --- --- �� --- --- _--_ _--_ - 450 - --- - -- ---- ---- --- --- -- - --- __ --- O 1.61x10 --- --- ---_ _- 440 --- --- ---- ---- --- --- O D D D --- --- --- --- --- --- --- --- -- -- --- ---- ---- - --- --- -- ---- --- --- --- ---- ---- -- 430 --- --- ---- ---- --- --- --- --- -- -- --- --- --- --- --- --- --- ----__ --- ---- __ ---- ---- --- --- --- --- ___ 420 - --- --- --- ---- _--_ --- --- --- --- --- --- --- --- --- --- --- - O O O O O --- --- --- --- --- --- ---- ---- _- 420 - - - - - - - - - - - - - - - - -- -- 410 - --- --- ---- ---- --- --- --- --- --- --- ---- 1--- - --- --- --- --- --- ---- - 410 0 O 0 o O 0 0 0 0 o O 0 O O O O O O O O O O O O O O O O O O o 0 0 0 0 0 0 0 O o o O O 0 O o o O O o O O O O o 0 0 O O O O O 0 O 0 0 O 0 0 0 0 0 O 0 O O O O O 0 O O O O O O O O O O O O o 0 0 0 0 0 0 0 0 o O O O 0 O O O O O 0 0 0 0 0 0 0 0 0 0 o O o + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + O N co It Lr') Co I- co m O - N 10 It LC) Cfl � 00 O O - N M � Ln (o I- m M o - N M ,T LO Co I- CO O 0 - N M � Ln (9 r­ W M O N N N N N N N N N N M co co M M co M m M co It I It It Nt NT NT NT LO LO LO LO LO Lr) LO LO LO LO Co Co NORTHWEST Station SOUTHEAST (feet) SECTION A -A' FACING NORTHEAST GRAPHIC SCALE 300 0 300 IN FEET HORIZONTAL: 1"=300' 30 0 30 COAL ASH TRANSITION ZONE BEDROCK SOIL/FILL SAPROLITE ALLUVIUM WATER LEVEL (JUNE 17, 2015) SURFICIAL WATER LEVEL TRANSITION ZONE WATER LEVEL BEDROCK WATER LEVEL ^� FRACTURED/OXIDIZED ZONE OBSERVED IN ROCK CORE 4.4 x 10-4 K Value ABMW-02BR: WATER ANALYTICAL RESULTS IN pg/L 45'-45.5' SOIL TOTAL ANALYTICAL RESULTS IN mg/kg BORING SYMBOLS SOIL SAMPLE WITH VERTICAL HYDRAULIC WELL SCREEN WITH CONDUCTIVITY HYDRAULIC CONDUCTIVITY OF UNDISTURBED IN CENTIMETERS PER SECOND SAMPLE (SOURCE: SYNTERRA SLUG TEST) (SOURCE: BLE) SOURCES: 1. THE TOPOGRAPHY SURVEY DATA WITHIN THE PROPERTY BOUNDARY DATED MAY 19, 2015 WAS OBTAINED FROM WSP OF CARY, NORTH CAROLINA. 2. SELECT TOPOGRAPHIC ADJUSTMENTS BASED ON SITE SURVEY AND COMPARISON TO AERIAL PHOTOGRAPH. 3. 2015 LITHOLOGY INFORMATION OF SOIL AND WELL LOG TOPOGRAPHY IS FROM SYNTERRA. 4. GEOLOGIC INFORMATION FOR BORINGS AND MONITORING WELLS INSTALLED PRIOR TO 2015 TAKEN FROM S&ME (2010) AND QUANTEX (2008). NOTE: 1. CROSS SECTION LOCATIONS SHOWN ON FIGURE 2-1. 2. WATER LEVELS WERE COLLECTED BY SYNTERRA ON JUNE 17, 2015. iT(erra 148 River Street, Suite 220 Greenville, South Carolina 29601 864-421-9999 www.synterracorp.com DRAWN BY: C. NEWELL DATE: 8/5/2015 CHECKED BY: J. WYLIE DATE: 8/5/2015 PROJECT MANAGER: K. WEBB LAYOUT NAME: FIGURE 8-1 DUKE ENERGY boo PROGRESS MAYO STEAM ELECTRIC PLANT 10660 BOSTON RD 60 ROXBORO, NORTH CAROLINA IN FEET VERTICAL: 1"=30' NOTE: 10:1 VERTICAL EXAGGERATION FIGURE 8-1 GEOLOGIC CROSS SECTION A -A' WITH ANALYTICAL RESULTS 1 C^=k1r% )ao v7 LU n, C� Q W U O Q a� tao i.i / 1ao 1` o 0- 0 CC a W U �i C6 a) E U) 0 U) cn a 0 cn m m cn Q O ('3 L6 O / O N O vi U) N do 0 I E. a� w (D 0 / W7 7 620 610 600 590 580 570 560 550 540 530 520 510 500 490 480 ow 470 m� aa) 460 LLJ 450 440 430 420 410 400 390 380 370 360 350 340 330 320 310 300 620 610 600 590 580 570 560 550 540 530 520 510 500 490 480 470 460 450 440 430 420 410 400 390 W LU 3E LU - Z_ J U Q �. 300 O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + CD N m d CO r'- m O N M ,I-LO CO r- CO O O �- N CO LO (D r-- co m CD M "I-LO Co r1- m m O �- N M � Ln Co a0 M O N m -' Lo Co r1- M O CD M ,I- LO CO r'-m M CDN m 'z Lo •- - - - - - - c- N N N N N N N N N N co co m M co co co m m M It " It I- dt It It cp It IT U') LO LO LO LO LO LO LO LO LO Co Co Co Co Co Co Co Co Co Co r- r1-r*- I� r1-r- SOUTHWEST Station (feet) SB-07 SECTION B-B' 1'-2': Sb <5.8 / As <5.8 / Ba 68.8 / B <14.5 / Cr 11.4 / Co 5.9 / Fe 9460 / Mn 693 / TI <5.8 / V 17.6 FACING NORTHWEST 4.5'-7.5':Sb<6/As<6/Ba15.5/B<15/Cr8.2/Co<6/Fe6040/Mn226/TI<6/V8.2 M W-3 MW-3: pH5.71/Sb<1/As<1/Ba56/B847/Cr(VI)0.155/Co<1/Fe34/Mn880/TI<0.2/TDS 190/V<0.3 off I mill In i Emmomp! CW-2/ 2D 470 CW-2: pH 6.5 / Sb <1 / As <1 / Ba 54 / B 804 / Cr(VI) <0.021 / Co <1 / Fe 467 / Mn 135 / TI <0.2 / TDS 370 / V 5.88 CW-2D: pH 6.1 / Sb <1 / As <1 / Ba 38 / B 363 / Cr(VI) 0.084 / Co <1 / Fe 278 / Mn 81 / TI <0.2 / TDS 250 / V 0.585 460 460 N 50 MW-16S/ 16D/ 16BR MW-16S: pH 6.02 / Sb <1 / As <1 / Ba 46 / B <50 / Cr(VI) 0.011 / Co 4.32 / Fe 860 / Mn 260 / TI <0.2 / TDS 100 / V 0.303 4 0 Q MW-16D: pH7.1/Sb<1/As<1/Ba13/B<50/Cr(VI)0.051/Co<1/Fe87/Mn269/TI<0.2/TDS160/V0.617 of MW-16BR: pH8.67/Sb<1/As2.05/Ba11/B<50/Cr(VI)0.017/Co<1/Fe80/Mn30/TI<0.2/TDS170/V2.79 43 w 1'-2':Sb<6.5/As<6.5/Ba95.4/B<16.2/Cr7.6/Co6j/Fe7710/Mn1250/TI<6.5/V17.3 J 23'-24': Sb<5/As<5/Ba28.2/B10j/Cr2.1/Co4.6j/Fe10600/Mn885/TI<5/V8.4 420 0 33'-35':Sb<7.5/As<7.5/Ba131/616.8j/Cr9.2/Co12/Fe19100/Mn1630/A<7.5/V16.3 Q 54.5'-55.5': Sb <5.2 / As <5.2 / Ba 237 / B 32.3 / Cr 37.2 / Co 19.6 / Fe 38300 / Mn 1010 / TI <5.2 / V 87 410 � 400 0 400 J wA390 390 w 380 Q 380 01 �fy W7 - U m 370 - L IN 6.90 x 10 360 U --- 350 340 W --- --- -_ 4.68x10" Z --- _ J --- --- --- --- -- 330 U-- - - - - - - 320 - - - - 310 --- --- ---- ---- --- 300 --- --- --- --- --- 300 O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O + + + CO r1- 00 + + O O + + + + + + + + + + + N CO � LO Co r-- 00 M O f� ti r1- 00 00 00 Co 00 00 00 00 00 00 O O NORTHEAST SECTION B-B' FACING NORTHWEST C J 0 w� COAL ASH TRANSITION ZONE BEDROCK SOIL/FILL SAPROLITE ALLUVIUM WATER LEVEL (JUNE 17, 2015) SURFICIAL WATER LEVEL TRANSITION ZONE WATER LEVEL BEDROCK WATER LEVEL ^� FRACTURED/OXIDIZED ZONE OBSERVED IN ROCK CORE 4.4 x 10-4 K Value ABMW-02BR: WATER ANALYTICAL RESULTS IN pg/L 45-45.5' SOIL TOTAL ANALYTICAL RESULTS IN mg BORING SYMBOLS SOIL SAMPLE WITH VERTICAL HYDRAULIC WELL SCREEN WITH CONDUCTIVITY HYDRAULIC CONDUCTIVITY OF UNDISTURBED IN CENTIMETERS PER SECOND SAMPLE (SOURCE: SYNTERRA SLUG TEST) (SOURCE: BLE) SOURCES: 1. THE TOPOGRAPHY SURVEY DATA WITHIN THE PROPERTY BOUNDARY DATED MAY 19, 2015 WAS OBTAINED FROM WSP OF CARY, NORTH CAROLINA. 2. SELECT TOPOGRAPHIC ADJUSTMENTS BASED ON SITE SURVEY AND COMPARISON TO AERIAL PHOTOGRAPH. 3. 2015 LITHOLOGY INFORMATION OF SOIL AND WELL LOG TOPOGRAPHY IS FROM SYNTERRA. 4. GEOLOGIC INFORMATION FOR BORINGS AND MONITORING WELLS INSTALLED PRIOR TO 2015 TAKEN FROM S&ME (2010) AND QUANTEX (2008). NOTE.- 1. CROSS SECTION LOCATIONS SHOWN ON FIGURE 2-1. 2. WATER LEVELS WERE COLLECTED BY SYNTERRA ON JUNE 17, 2015. A erra 148 River Street, Suite 220 Greenville, South Carolina 29601 864-421-9999 www.synterracorp.com DRAWN BY: C. NEWELL DATE: 8/5/2015 CHECKED BY: J. WYLIE DATE: 8/5/2015 PROJECT MANAGER: K. WEBB LAYOUT NAME: FIGURE 8-2 f%,. D U K E GRAPHIC SCALE vqc� E N E RGY 300 0 300 600 PROGRESS IN FEET HORIZONTAL: 1"=300' MAYO STEAM ELECTRIC PLANT 10660 BOSTON RD 30 0 30 60 ROXBORO, NORTH CAROLINA IN FEET FIGURE 8-2 VERTICAL:1"=30' GEOLOGIC CROSS SECTION B-B' NOTE: 10:1 VERTICAL EXAGGERATION WITH ANALYTICAL RESULTS MW-13BR: pH7.2/Sb<I/As<1/Ba 40/B<50/Cr(VI) 0.005 / Co 1.19 / Fe 1130/ Mn 474/ TI<0.2/ TDS 370/ V 0.381 0'2%Sb<6.5/As<6.5/Ba 72.9 / B <16.3 / Cr 6.1/Co<6.5/Fe 196M Mn 82.8 /TI<6.5/V 32.4 52'-54':Sb<5.1/As<5.1/Ba62.3/B<2.5/Cr9.2/C.6.6/Fe 10400/Mn 789 /TI<5.1/V 13.1 ABMW-02: pH7.8/Sb<1/As 1020/Ba 173/B 9200/Cr(VI)0.017/Co<I/Fe 356/ Mn 1110/ TI <0.2/ TD5450/ V 3.53 ABMW-02BR: pH7.2/5b<S/As<1/Ba 159/B<50/Cr(VI)0.007/Co<I/Fe 107/Mn 149/TI<0.2/ TDS 370/ V 0.873 45'-45.5':5b<6/As<6/Ba 92.2 / B <15 / Cr 8 / Co 6 1 / Fe 18300/ Mn 579/ TI<6/ V 30.3 57.5'-58': 5b<5.1/As<5.1/Ba41.2/B<12.8/Cr56.7/Co37.4/Fe43400/Mn782/TI<5.1/V84.9 ABMW-03: pH6.63/5b<1/As 193/Ba 2W/B 1940/Cr(VI)<OAW/Co<1/Fe 3890/ Mn 451/ TI 0.289/ TD5350/ V 0.68 C< ABMW-01 ABMW-035: pH5.21/5b<1/As1.04/Ba25/BIIOO/Cr(VI)<0.005/Co3.98/Fe2630/Mn478/TI<0.2/TD5110/V<0.3 CW-01 550 0 h ABMW-01: pH7.6/Sb38/As518/Ba925/B4560/Cr(VI)NS/Co6.09/Fe1370/Mn2280/TI2.47/TDS540/V 314 51'-53':Sb<6.8/As<6.8/Ba56.1/B<17/Cr1.3j/Cob.6j/Fe16900/Mn319/TI<6.8/V28.8 CW-01: CW-01:pH5.5/5b<3/As<S/Ba<5/B<50/CrIVIINS/Co<1/Fe31/Mn6/TI <0.2/TD5150/V0.543 Z 1'-1.5':5b<8.7/As16.6/Ba15D/B27.4/Cr25/Co7.6j/Fe2240/Mn18.4/TI<8.7/V39.3 CW-01D: pH6.8/Sb<1/As<1/Ba<5/B<50/Cr(VI)NS/Co<1/Fe<10/Mn<5/TI<0.2/TD5200/V1.09 540 OF= 11.5-12': Sb<7.8/As26.2/Ba152/B27.4/Cr26.9/Co8.3/Fe2710/Mn31.3/TI<7.8/V46.2 � W 13'-13.5%Sb<6.2/As<6.2/Sa 53.8 / 8 <15.5 / Cr 3.7 / Co <6.2 / Fe 8770/ Mn 92.2/ TI<6.2/V 11.9 Q 530 m O MW-096R J MW-09BR: pH6.3/Sb<llAsri/Ba 301B<50/Cr(VI)NS/Co<1/Fe 3000/Mn 809/ TI<0.2 / TDS 220/ V 4.17 moon ,1/111111111111111111111111►.r���:11111111111111111111111111111111111111111111111111111111111111111_�������:.� � IIII/lllllllllllllllllllllllllll� IIIIIIMIIIIIIIIIIII !� 1/11111111�111 1��111111111111111111111111��1111����!IIII 11 '-' 1lI1�ILlI w�.i,� :�:omm :�:�SppC e�lS_� 1 Ilk" I�+I., I,AlII■, 1�1 11 1�1�1�1�1�1�1�1� 1111ill1�111■1■1■1.111 141'1�I1Ia 11�11i111111_1111-=1111-a 111as11111�s11■s 11■11�a1.aV1a. 1�■!1■11.•1.•a1.Is11�I•1a�I41s: 11.11.•1.ap1I�s, 11al ' ■s1■4�■1■a�aa�a�1aa1�a1 !I-1I!I1I1I1I�1IJ'1II11I1I1I1�1IG11I1�1r111� On 11 - da7AM- �-mIr-C-aaG �� I•:.ICPo1r1� AAII�I1 --mmm 111106=1011 1 MINIMUM 11111 1$11111111111$11111$11111111111111111111111111111 Fill 11111111 1 1911111 111 F, 1�1�1I>�sa■az 1�$a1a11111a1a1111$11g1g11 � .,111111111111a1a11111a1a11111a1a11111a1a$1111a1a11111a1a11111a1a111111 ., aa aa aa .,Illlllllllllllllllllllllllllllllllglllllgllllllllllllll Illllllllllllllllglllllllllllglllllglllllllllllgllllllll ., MW-07D: pH6.4/5b<1/As<1/Ba24/B<50/Cr(VI)NS/Co<1/Fe69/Mn188/TI<0.2/TD539D/V 0.798 MW-07ER: pH 7.4/5b<1/As <1/Ba 140/B<50/CrIVIINS/Co<I/ Fe 339/ Mn 263/ TI<0.2/ TDS 270/V<0.3 CF 550 P-2%Sb<5.1/As<5.1/Ba21.5/B<12.9/Cr4.1/Co<5.1/ Fe 7320/ Mn 27.7/ TI<5.1/ V 12.8 550 540 540 MW-08S/ 08D/ 08BR 530 p MW-086R: pH6.56/Sb<3/As<I/Ba 66/B<50/Cr(V0 N5/Coq/Fe 2200/Mn 2680/TI <0.2/TDS 550/V<0.3 O 0.75'-1.25':Sb<3.2/As<3.2/Ba147/B<63.4/Cr62.2/Co21.3/Fe24700/Mn1230/TI<3.2/V50.6 520 of 25.5'-26':Sb<2.7/As<2.7/Ba193/B33j/Cr419/Co32.9/Fe31300/Mn933/TI<2.7/V75.8 30.5'-31': Sb<2.7 As<2.7 Ba130 B<53.1 Cr67.1 Co7.4 Fe11400 Mn875/TI<2.7/V25.2 11/111����111111111111111111111111!!11111 F F „ ,. 1/1�1111111111111111111111.NIIlllll C111 111111111111111111�11111�1111 ,., ., ., 111111111111111 11111�1'lll., ''111111111111 Illll66111,., . Illllllllli�l . , ; , iaiasis�C��aias$4�4C��a�a - ssgg . �rrrs$srrrrrs$srrrrrg$g�. $$rr :F �1111g11111g11111 111 .F ., - - - - - - - - - - - - - - - - - - - - I SECTION C-C' FACING NORTH LEGEND _ COAL ASH _ TRANSITION ZONE BEDROCK REGOLITH SOIL/FILL SAPROLITE ALLUVIUM WATER LEVEL (JUNE 17, 2015) • SURFICIAL WATER LEVEL • TRANSITION ZONE WATER LEVEL • BEDROCK WATER LEVEL FRACTURED/OXIDIZED ZONE m� OBSERVED IN ROCK CORE UJ w 4.4 x 10-0 K Value ABMW-0219R: WATER ANALYTICAL RESULTS IN p9/1- 45'45.5' SOIL TOTAL ANALYTICAL RESULTS IN mg/kg BORING SYMBOLS SOIL SAMPLE WITH VERTICAL HYDRAULIC WELL SCREEN WITH CONDUCTIVITY HYDRAULIC CONDUCTIVITY OF UNDISTURBED IN CENTIMETERS PER SECOND SAMPLE (SOURCE: SYNTERRA SLUG TEST) (SOURCE: BILE) SOURCES: 1. THE TOPOGRAPHY SURVEY DATA WITHIN THE PROPERTY BOUNDARY DATED MAY 19, 2015 WAS OBTAINED FROM WSP OF CARY, NORTH CAROLINA. 2. SELECT TOPOGRAPHIC ADJUSTMENTS BASED ON SITE SURVEY AND COMPARISON TO AERIAL PHOTOGRAPH. 3. 2015 LITHOLOGY INFORMATION OF SOIL AND WELL LOG TOPOGRAPHY IS FROM SYNTERRA. 4. GEOLOGIC INFORMATION FOR BORINGS AND MONITORING WELLS INSTALLED PRIOR TO 2015 TAKEN FROM S&ME (2010) AND QUANTEX (2008). NOTE, 1. CROSS SECTION LOCATIONS SHOWN ON FIGURE 2-1. 2. WATER LEVELS WERE COLLECTED BV SYNTERRA ON DUNE 17, 2015. VIP syn Terra 148 River Street, Suite 220 Greenville, South Carolina 29601 864-421-9999 www.synterracorp.com DRAWN BY: C. NEWELL DATE: 8/5/2015 CHECKED BY: J. WYLIE DATE: 8/5/2015 PROJECT MANAGER: K. WEBB LAYOUT NAME: FIGURE 8-3 'DUKE GRAPHIC SCALE <c ENERGY 300 0 300 600 IN FEET HORIZONTAL: 1"=300' 30 0 30 60 IN FEET VERTICAL: 1"=30' NOTE: 10:1 VERTICAL EXAGGERATION PROGRESS MAYO STEAM ELECTRIC PLANT 10660 BOSTON RD ROXBORO, NORTH CAROLINA FIGURE 8-3 GEOLOGIC CROSS SECTION C-C' WITH ANALYTICAL RESULTS 100% 90% 80% i Mullite 70% ■ Kaolinite 60% ■ Illite 50°� ■ I (.7)/ S c a ■ Dolomite a 40% ■ Chlorite ao 30% °J ■Amphibole 20% ■ Feldspar 10% � ■Quartz 0% P Sample Location 148 RIVER STREET, SUITE 220 FIGURE 8-4 GREENVILLE, SOUTH CAROLINA 29601 DOMINANT MINERALOGY OF SOIL PHONE 864-421-9999 www.synterracorp.com DRAWN BY: E. BLACK DATE: AUGUST 2015 synTerra PROJECT MANAGER: J. WVLIE MAYO STEAM ELECTRIC PLANT LAYOUT: [P:\Duke Energy Progress.1026\105. Mayo Ash Basin GW 10660 BOSTON ROAD Assessment Plan\1.11 CSA Reporting\Figures\ ROXBORO, NORTH CAROLINA 27574 100% 90% 80% 70% 60% c u 50% v a ao 40% 30% 20% 10% 0% <c\ fro\ I� titi ��04 ti� Sample Location 410 148 RIVER STREET, SUITE 220 GREENVILLE, SOUTH CAROLINA 29601 PHONE 864-421-9999 www.s nterracor .com DRAWN BY: E. BLACK DATE: AUGUST 2015 synTerra PROJECT MANAGER J. WYLIE LAYOUT: P:\Duke Energy Progress. 1 026\1 05. Mayo Ash Basin GW Assessment PIan\1.11 CSA Reporting\Figures\ L01 V205 Ti02 SrO Si02 ■ P205 Na20 ■ MnO ■ Mg0 K20 ■ Fe203 ■ Cr203 ■ CaO ■ BaO ■ A1203 FIGURE 8-5 DOMINANT METAL OXIDE COMPOSITION OF SOIL MAYO STEAM ELECTRIC PLANT 10660 BOSTON ROAD ROXBORO, NORTH CAROLINA 27574 100% 90% 80% 70% 60% a 50% u L a 40% 4, 30% 3 20% 10% 0% R ly �p�\D `yh�Q` Sample Location 410 148 RIVER STREET, SUITE 220 GREENVILLE, SOUTH CAROLINA 29601 PHONE 864-421-9999 www.s nter.com racor DRAWN BY: E. BLACK DATE: AUGUST 2015 synTerra PROJECT MANAGER J. WYLIE LAYOUT: P:\Duke Energy Progress. 1 026\1 05. Mayo Ash Basin GW Assessment Plan\1.11 CSA Reporting\Figures\ L01 V205 Ti02 ■ SrO ■ Si02 ■ P205 Na20 ■ MnO ■ Mg0 ■ K20 ■ Fe203 ■ Cr203 • CaO ■ BaO ■ A1203 FIGURE 8-6 DOMINANT METAL OXIDE COMPOSITION OF ROCK CORE MAYO STEAM ELECTRIC PLANT 10660 BOSTON ROAD ROXBORO, NORTH CAROLINA 27574 100% 90% 80% Zeolite 70% Siderite 60% Muscovite 50% ■ Lepidocrocite v v 40% ■ Kaolinite a " r Illite a_o 30% w ■ Gibbsite 3 20% ■ Dolomite 10% ■ Chlorite 0% ■ Calcite (11\ fin\ Lp\ c\ gyp\ gyp\ hp\ c\ fin\ �c\ ■ Biotite 00. Qil N11 ■ #REF! ■ Feldspar Q ■ Quartz Sample Location 148 RIVER STREET, SUITE 220 GREENVILLE, SOUTH CAROLINA 29601 PHONE 864-421-9999 www.synterracorp.com DRAWN BY: E. BLACK DATE: AUGUST 2015 synTerra PROJECT MANAGER J. WYLIE LAYOUT: P:\Duke Energy Progress.1026\105. Mayo Ash Basin GW Assessment Plan\1.11 CSA Reporting\Figures\ FIGURE 8-7 DOMINANT MINERALOGY OF CORE MAYO STEAM ELECTRIC PLANT 10660 BOSTON ROAD ROXBORO, NORTH CAROLINA 27574 N MW-03BR' START DEPTH END DEPTH Co Fe Mn 0.8 1.2 5.4 8480 327 14.75 15 4.37750468 17 18 3.6 - 459 SB-012 START DEPTH END DEPTH I As Co Fe 1 2 1.2 j 3.7 1240 13.5 14.5 1.2 j 8.9 849067481.4 ABMW-015 START DEPTH I END DEPTH I Fe 13 1 13.5 18770 ABMW-02BR4 START DEPTH END DEPTH I Al I Ba I Co I Cu I Fe I Mn I V 45 45.5 192.216 j 172.711830015791 - 57.5 58 1202001 - 37.4 81.7 43400 782 84.9 SB-022 START DEPTH END DEPTH Al As Co Fe Mn Se V 0.5 2 10200 1.9 6.4 18300 365 1.3 j 44.8 11.0 12.5 1.5 - 10300' I0.85 j - SB-032 START DEPTH END DEPTH Al As Co Fe Mn 17 18.5 11800 1.6 10.64 5.2 18100 - 5 6 j 14.918070 348 �ru]Mi MW-11 BR3 START DEPTH END DEPTH Al Ba Co Cu Fe Hg Mn V 0 2 19700 - 6.4 j 59.1 52900 0.13 - 208 30 32 15000 17940 .9 363 44000 - 212191 N �I g 40Myy' SR•1328 4 l Dr �q 4p J MWA 5BR4 START DEPTH END DEPTH Al Co Fe 0.5 1 1844013.9 jj 15600 1981 MWA 6BR3 START DEPTH END DEPTH Al E 1 2 9 23 24 33 35 9030 1 54.5 55.5 24500 2 fi� SB-074 START DEPTH END DEPTH Al Co Fe 1 2 9000 5.9 9460 �226 4.5 7.5 - 6040 MW-08BR' START DEPTH END DEPTH Al Ba Co Feg1.7 1' 0.75 1.25 14500 147 21.3 24700 25.5 26 23700 193 32.9 3130030.5 31 8330 130 7.4 11400 LANDFILL--�--�- ter+ MW-07BR3 START DEPTH END DEPTH 7�. ♦r 1 2 r.4 r` SB-052 START DEPTH END DEPTH As Co Fe Mn Se 1 2 1.8 2.8 8280 406 1.9 2.3 3.3 1.1 - 6670 393 1.2 8 9 1 j - 5790 195 0.87 j ♦r SB-062 �.„ START DEPTH END DEPTH .�. L .. 1 2 MW-10BR' START DEPTH END DEPTH Al As Ba 0.75 1.0 1.4 - 13.0 13.75 18700 1.1 479 5Q' LEGEND MONITORING WELL SOIL BORING ACTIVE ASH BASIN L - _ . -' ASH BASIN COMPLIANCE BOUNDARY :7 DUKE ENERGY PROGRESS MAYO PLANT SITE BOUNDARY - - - DITCH STREAM Analytical Parameter 01-Industrial Health EPA RSL 2015-06 m 02-Residential Health EPA RSL 2015-06 m 03-Protection of Groundwater EPA RSL 2015-06 m Aluminum (Al) 110000 7700 Arsenic(As) 3 0.68 0.29 Barium (Ba) 22000 1500 82 Cobalt(Co) 35 2.3 Copper (Cu) 4700 310 46 Iron (Fe) 82000 5500 Lead (Pb) 800 400 14 Manganese (Mn) 2600 180 Mercury(Hg) 4 0.94 0.1 Nickel (Ni) 2200 150 Selenium (Se) 580 39 0.26 Thallium(TI) 1.2 0.078 0.14 Vanadium (V) 580. 39 NOTES: i CONCENTRATIONS SHOWN ARE FROM THE FEBRUARY 2015 SAMPLING EVENT. 2 CONCENTRATIONS SHOWN ARE FROM THE MARCH 2O15 SAMPLING EVENT. oQ 3 CONCENTRATIONS SHOWN ARE FROM THE APRIL2015 SAMPLING EVENT. 4 CONCENTRATIONS SHOWN ARE FROM THE MAY 2015 SAMPLING EVENT. 5 CONCENTRATIONS SHOWN ARE FROM THE JUNE 2015 SAMPLING EVENT. sSITE AERIAL ORTHOPHOTOGRAPHY IS DATED APRIL 17, 2014. IT WAS OBTAINED FROM WSP. 3 ADDITIONAL OFFSITE AERIAL ORTHOPHOTOGRAPHY IS DATED 2012. IT WAS OBTAINED FROM THE NC CENTER FOR GEOGRAPHIC INFORMATION AND ANALYSIS AT (http:11servioes.nconemap.gov1) e PARCEL BOUNDARY WAS OBTAINED FROM THE NC CENTER FOR GEOGRAPHIC INFORMATION AND ANALYSIS AT (h0p:l/services.nconemap.gov0 9 DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE COORDINATE SYSTEM FIPS 3200 (NAD83Y2011). Tj = INDICATES CONCENTRATION REPORTED BELOW PQL, BUT ABOVE MDLAND THEREFORE CONCENTRATION IS ESTIMATED 7 j 46.2 GRAPHIC SCALE 1,000 0 1,000 2,000 3,000 4,000 5,000 „ (IN FEET) LL SR•1507 �' DUKE _ ENERGY synTerra ° PROGRESS g 148 RIVER STREET, SUITE 220, MAYO STEAM ELECTRIC POWER PLANT r L GREENVILLE, SC 29601 10660 BOSTON RD o 864421-9999 ROXBORO, NORTH CAROLINA27574 N www.synterracorp.com m FIGURE 8-8 SITE MAP WITH SOIL EXCEEDANCES a S- 01 5-02 o S-02D S-03 +IIF S-04 6-05 11-00, S-06 6 Z S-08 4 { x- 80% i � 80% ' 60% � � 60% � 40% 40% 1� Q ff t 1 20% pr 77 20% cp t �4 O O O O 148 RIVER STREET, SUITE 220 FIGURE 9-1 GREENVILLE, SOUTH CAROLINA 29601 PIPER DIAGRAM — SEEPS AND SURFACE WATER PHONE 864-421-9999 www.s nterracor .com DRAWN BY: J. GILMER DATE: JUNE 2015 synTerra[P:\Duke PROJECT MANAGER J. wvuE MAYO STEAM ELECTRIC PLANT LAYOUT: Energy Progress.1026\105. Mayo Ash Basin GW 10660 BOSTON ROAD Assessment Plan\1.11 CSA ROXBORO, NORTH CAROLINA 27574 Reporting\Figures\Statistics\Piper Diagrams ABMW-013 CONSTITUENT RESULT As 518 B 4560 Ba 925 Co 6.09 Fe Mn 1370 2280 Sb 38 TDS 540 TI 2.47 V 314 SRA 500 gQ SR.1329 !A .. SR lh;.-' SK-13z8 �400 SQ'0"e SR.1 gt ` - ABMW-023 CONSTITUENT RESULT As 1020 B 9200 Fe 356 Mn 1110 V 3.53 ABMW-033 CONSTITUENT RESULT As 193 1981 B 1940 LANDF Fe 3890 Mn 451 TI 0.289 l M V 0.68 -Ar.' �. s ABMW-043 ISTITUENT RESULT As 499 B 4930 Co 1.49 Fe 940 Mn 641 TDS 520 V 2.84 NIP" .r soA r f �4 _ 7 �.r.4. ♦ r 1 LEGEND MONITORING WELL 0 ACTIVE ASH BASIN ASH BASIN COMPLIANCE BOUNDARY r. _. DUKE ENERGY PROGRESS MAYO PLANT SITE BOUNDARY — - — - DITCH STREAM North Carolina 2LStandards Constituent Abbreviation Upper Limit Units Lower Limit Antimonys Sb 1 µg/L --- Arsenic As 10 µg/L --- Boron B 700 µg/L --- Chloride CI 250 mg/L --- Chromium Cr 10 µg/L --- Cobalt-' Co 1 µg/L --- Iron Fe 300 µg/L Manganese Mn 50 µg/L pH pH 8.5 S.U. 6.5 Selenium Se 20 µg/L --- Sulfate SO4 250 mg/L --- Thalliums TI 0.2 µg/L --- Total Dissolved Solids TDS 500 mg/L Vanadium V NOTES: CONCENTRATIONS SHOWN ARE FROM THE APRIL 2015 SAMPLING EVENT. Z CONCENTRATIONS SHOWN ARE FROM THE MAY 2015 SAMPLING EVENT. 3 CONCENTRATIONS SHOWN ARE FROM THE JUNE 2015 SAMPLING EVENT. 4 CONCENTRATIONS SHOWN ARE FROM THE JULY 2015 SAMPLING EVENT. 5NORTH CAROLINA 21- INTERIM MAXIMUM ALLOWABLE CONCENTRATION (IMAC) 6SITE AERIAL ORTHOPHOTOGRAPHY IS DATED APRIL 17. 2014. IT WAS OBTAINED FROM WSP. 7ADDITIONAL OFFSITE AERIAL ORTHOPHOTOGRAPHY IS DATED 2012. IT WAS OBTAINED FROM THE NC CENTER FOR GEOGRAPHIC INFORMATION AND ANALYSIS AT (http://services.nconemap.gov/) 8 PARCEL BOUNDARY WAS OBTAINED FROM THE NC CENTER FOR GEOGRAPHIC INFORMATION AND ANALYSIS AT (http://services.nconemap.gov/) 9 DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE COORDINATE SYSTEM FIPS 3200 (NAD83/2011). GRAPHIC SCALE 1,000 0 1,000 2,000 3,000 4,000 5,000 (IN FEET) SR•1507tip synTerra 148 RIVER STREET, SUITE 220, L GREENVILLE, SC 29601 864421-9999 www.synterracorp.com w 4 DUKE ENERGY PROGRESS MAYO STEAM ELECTRIC POWER PLANT 10660 BOSTON RD ROXBORO, NORTH CAROLINA27574 J1 CHECKED BY: J. MEADOWS DATE: 827/2015 PROJECT MANAGER: J. WYLIE sow FIGURE 10-1 w SITE LAYOUT WITH 2L EXCEEDANCES s� N� ASH PORE WATER WELLS cn w A ♦ `i l . e MW-12S3 s *7 �^ CONSTITUENT RESULT Co 1.09 .' . �..—..—.. Mn 267 Ak pH 5.7 . J V 0.403 h J SRA 500 gQ SR.1329 !A .. SR lh;.-' SK-13z8 '4po SQ'028 SR.1 gt , - s1,7so? MW-03' CONSTITUENT RESULT B 847 Mn 880 pH 5.7 ACTIVE ASH BASIN NIP" MWA 6S3 CONSTITUENT I RESULT Co 4.32 Fe 860 Mn 260 pH 6.0 V 0.303 ABMW-03S3 CONSTITUENT RESULT B 1100 Co 3.98 Fe 2630 Mn EZI pH ♦ , . ♦ , u1 r � 2jjSR-!i501 o= sp 7sp I 11~� 1 r- L r• ,J LEGEND MONITORING WELL Q ACTIVE ASH BASIN ASH BASIN COMPLIANCE BOUNDARY r: — �� DUKE ENERGY PROGRESS MAYO PLANT SITE BOUNDARY -—-— DITCH STREAM North Carolina 2L Standards Constituent Abbreviation Upper Limit Units Lower Limit Antimony5 Sb 1 µg/L --- Arsenic As 10 µg/L --- Boron B 700 µg/L --- Chloride CI 250 mg/L --- Chromium Cr 10 µg/L Cobalts Co 1 µg/L Iron Fe 300 µg/L --- Manganese Mn 50 µg/L --- pH pH 8.5 S.U. 6.5 Selenium Se 20 µg/L --- Sulfate SO4 250 mg/1-1 --- Thalliums TI 0.2 µg/L --- Total Dissolved Solids TDS 500 mg/L --- Vanadium5 V 0.3 µg/L --- NOTES: CONCENTRATIONS SHOWN ARE FROM THE APRIL 2015 SAMPLING EVENT. Z CONCENTRATIONS SHOWN ARE FROM THE MAY 2015 SAMPLING EVENT. 3 CONCENTRATIONS SHOWN ARE FROM THE JUNE 2015 SAMPLING EVENT. 4 CONCENTRATIONS SHOWN ARE FROM THE JULY 2015 SAMPLING EVENT. 5NORTH CAROLINA 2L INTERIM MAXIMUM ALLOWABLE CONCENTRATION (IMAC) 6SITE AERIAL ORTHOPHOTOGRAPHY IS DATED APRIL 17. 2014. IT WAS OBTAINED FROM WSP. 7ADDITIONAL OFFSITE AERIAL ORTHOPHOTOGRAPHY IS DATED 2012. IT WAS OBTAINED FROM THE NC CENTER FOR GEOGRAPHIC INFORMATION AND ANALYSIS AT (http://services.nconemap.gov/) 8 PARCEL BOUNDARY WAS OBTAINED FROM THE NC CENTER FOR GEOGRAPHIC INFORMATION AND ANALYSIS AT (http://services.nconemap.gov/) 9 DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE COORDINATE SYSTEM FIPS 3200 (NAD83I2011). GRAPHIC SCALE 1,000 0 1,000 2,000 3,000 4,000 5,000 (IN FEET) 141P synTerra 148 RIVER STREET, SUITE 220, GREENVILLE, SC 29601 864421-9999 www.synterracorp.com 4 DUKE ENERGY PROGRESS MAYO STEAM ELECTRIC POWER PLANT 10660 BOSTON RD ROXBORO, NORTH CAROLINA27574 FIGURE 10-2 SITE LAYOUT WITH 2L EXCEEDANCES SURFICIAL WELLS MW-02' CONSTITUENT RESULT Co 2.78 Fe 756 Mn 833 pH 5.8 V 1.68 � o h � J� Nt SRA 500 gQ SR.1329 'so? lh;.-' SK-03z8 I 1 40 0 S4t'028 SR•1 gt , - CW-034 CONSTITUENT RESULT V 1 1.41 MW-12D3 CONSTITUENT RESULT Co 1.37 Fe 326 Mn 683 pH 6.2 Sb 1.63 V 0.719 NIP" MW-16D3 CONSTITUENT RESULT Mn 269 V 0.617 C W-024 CONSTITUENT RESULT B 804 Mn 393 pH 5.1 MW-07D3 CONSTITUENT RESULT Mn 1 88 6.4 * , 5� 798 1 SR1so' L0 o: sp �S Oy LEGEND Q� MONITORING WELL . ACTIVE ASH BASIN ASH BASIN COMPLIANCE BOUNDARY DUKE ENERGY PROGRESS MAYO PLANT SITE BOUNDARY — — — — DITCH STREAM North Carolina 2L Standards Constituent Abbreviation Upper Limit Units Lower Limit Antimonys Sb 1 µg/L --- Arsenic As 10 µg/L --- Boron B 700 µg/L --- Chloride CI 250 mg/L --- Chromium Cr 10 µg/L --- Cobalt-' Co 1 µg/L --- Iron Fe 300 µg/L I --- Manganese Mn 50 µg/L --- pH pH 8.5 S.U. 6.5 Selenium Se 20 µg/L --- Sulfate SO4 250 mg/L --- Thalliums TI 0.2 µg/L --- Total Dissolved Solids TDS 500 mg/L Vanadium-' NOTES: CONCENTRATIONS SHOWN ARE FROM THE APRIL 2015 SAMPLING EVENT. Z CONCENTRATIONS SHOWN ARE FROM THE MAY 2015 SAMPLING EVENT. 3 CONCENTRATIONS SHOWN ARE FROM THE JUNE 2015 SAMPLING EVENT. 4 CONCENTRATIONS SHOWN ARE FROM THE JULY 2015 SAMPLING EVENT. 5NORTH CAROLINA 2L INTERIM MAXIMUM ALLOWABLE CONCENTRATION (IMAC) 6SITE AERIAL ORTHOPHOTOGRAPHY IS DATED APRIL 17, 2014. IT WAS OBTAINED FROM WSP. 7ADDITIONAL OFFSITE AERIAL ORTHOPHOTOGRAPHY IS DATED 2012. IT WAS OBTAINED FROM THE NC CENTER FOR GEOGRAPHIC INFORMATION AND ANALYSIS AT (http://services.nconemap.gov/) 8 PARCEL BOUNDARY WAS OBTAINED FROM THE NC CENTER FOR GEOGRAPHIC INFORMATION AND ANALYSIS AT (http://services.nconemap.gov/) 9 DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE COORDINATE SYSTEM FIPS 3200 (NAD83I2011). GRAPHIC SCALE 1,000 0 1,000 2,000 3,000 4,000 5,000 (IN FEET) SR•1507tip synTerra 148 RIVER STREET, SUITE 220, L GREENVILLE, SC 29601 864421-9999 www.synterracorp.com w 4 DUKE ENERGY PROGRESS MAYO STEAM ELECTRIC POWER PLANT 10660 BOSTON RD ROXBORO, NORTH CAROLINA27574 FIGURE 10-3 SITE LAYOUT WITH 2L EXCEEDANCES TRANSITION ZONE WELLS 07 3R• 1400 m0f MW-13BR3 CONSTITUENT RESULT Co 1.19 Fe 1130 Mn 474 V 0.381 4- ABMW-02BR3 CONSTITUENT RESULT Mn 149 V 0.873 BG-014 CONSTITUENT RESULT Fe 557 pH 5.6 V 4.94 MW-11 BR3 CONSTITUENT RESULT Mn 67 Sb 1.32 TI 0.32 V 2.6 SR•1328 S P...71 SR13Zg� c9 40 J CW-054 CONSTITUENT RESULT Fe 1060 Mn 785 MW-05BR' CONSTITUENT RESULT Fe 4240 Mn 1740 ABMW-04BR3 CONSTITUENT RESULT Fe 1590 Mn 407 V 0.382 9 SR-1500 gQ SR.1329 sl,7so? CW-044 CONSTITUENT RESULT pH 5.9 V 1.02 MW-03BR' CONSTITUENT RESULT Fe 648 Mn 731 TDS 660 V 0.781 MW-16BR3 CONSTITUENT I RESULT pH 8.7 V 2.79 �t SR-1501- � e W-10BR' `'VV-U t" . CONSTITUENT RESULT • r1 ITUENT RESULT V 1.09 i =e 883 ♦ ♦' An 894 +� .ram i 1.J CW-02D4 CONSTITUENT RESULT Mn 81 pH 6.1 V 0.585 C W-064 CONSTITUENT RESULT Fe 2040 Mn 1450 TDS 560 LEGEND MONITORING WELL ACTIVE ASH BASIN ASH BASIN COMPLIANCE BOUNDARY DUKE ENERGY PROGRESS MAYO PLANT SITE BOUNDARY — - — - DITCH STREAM North Carolina 2L Standards Constituent Abbreviation Upper Limit Units Lower Limit Antimony Sb 1 µg/L --- Arsenic As 10 µg/L --- Boron B 700 µg/L --- Chloride CI 250 mg/L --- Chromium Cr 10 µg/L --- Cobalt-' Co 1 µg/L --- Iron Fe 300 µg/L --- Manganese Mn 50 µg/L --- pH pH 8.5 S.U. 6.5 Selenium Se 20 µg/L --- Sulfate SO4 250 mg/L --- Thalliums TI 0.2 µg/L --- Total Dissolved Solids TDS 500 mg/L Vanadium V 0.3 µ /-L --- NOTES: CONCENTRATIONS SHOWN ARE FROM THE APRIL 2015 SAMPLING EVENT. Z CONCENTRATIONS SHOWN ARE FROM THE MAY 2015 SAMPLING EVENT. 3 CONCENTRATIONS SHOWN ARE FROM THE JUNE 2015 SAMPLING EVENT. 4 CONCENTRATIONS SHOWN ARE FROM THE JULY 2015 SAMPLING EVENT. NORTH CAROLINA 2L INTERIM MAXIMUM ALLOWABLE CONCENTRATION (IMAC) 6SITE AERIAL ORTHOPHOTOGRAPHY IS DATED APRIL 17, 2014. IT WAS OBTAINED FROM WSP. 7ADDITIONAL OFFSITE AERIAL ORTHOPHOTOGRAPHY IS DATED 2012. IT WAS OBTAINED FROM THE NC CENTER FOR GEOGRAPHIC INFORMATION AND ANALYSIS AT (http://services.nconemap.gov/) 8 PARCEL BOUNDARY WAS OBTAINED FROM THE NC CENTER FOR GEOGRAPHIC INFORMATION AND ANALYSIS AT (http://services.nconemap.gov/) 9 DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE COORDINATE SYSTEM FIPS 3200 (NAD83I2011). GRAPHIC SCALE 1,000 0 1,000 2,000 3,000 4,000 5,000 (IN FEET) SR•1507 40�ENERGY DUKE synTerra PROGRESS 148 RIVER STREET, SUITE 220, MAYO STEAM ELECTRIC POWER PLANT L GREENVILLE, SC 29601 10660 BOSTON RD 864421-9999 ROXBORO, NORTH CAROLINA27574 www.synterracorp.com w FIGURE 10-4 SITE LAYOUT WITH 2L EXCEEDANCES BEDROCK WELLS N---------------� •�--------------------- A • S-012 Flu < 1 (< <1 (21) AEIMW-04' �.,<1 (<1) j ♦............. -.- r-..-1 A 1981W. LANDFILL s. MAYO LAKE , . ,-.. l . LEGEND 1 N N NV h X 1 BOLD VALUESN N N (1) N N IW hX (1) BOLD VALUESN N N N N N ITV N N W N N N N N N N 0 N O N N N N N N N N N N N N NOTES: N N N N hhi nr N N g N N N N Idi nrN N g ^ N N N N Ni nrN N g o N N N N hhi nrN N g N N N N IW M N N Nn hg N N N N N hit )hi npg% N N N g r N N N N N Ni nnp N N N N N N N N N N g W 0 9 9 �x N N N N N N N N N N N ON 0 9 g BK w N N N N NN N N N N N N N Nni i IW vohti" N pi i pii vii ranii nuii ndii WN X tip DUKE ENERGY° s mTerra PROGRESS rrpvN N N Nni c N N N N a IN NMI m ni ssi N N o vspEpnnawmw N N Ntrtp w 9 9 FIGURE 10-5 ISOCONCENTRATION MAP ANTIMONY IN ASH PORE WATER WELLS N---------------� ••------------ h • �J A / r • ? �S-012 3.45(2.06) p -• - wcrnio �_s� d A ABMW-01a 10. g� V' 518 (369) ABMW-02a biik 1020(87a)-03'�97) I L. ♦................ r-.. -1 Lam. MAYO LAKE , iLEGEND 10 N N frYV h X 10 BOLD VALUESN N N (10) N N RV X (10) BOLD VALUESN N N N hh N fW N N W N N N N N N N L N O N N N N N N N N N N N N 1. ti r ♦'� / J - X X NOTES: N N N N hhi nr N N g N N N N fdi nrN N g ^ N N N N Ni nrN N g p N N N N hhi nrN N g N N hh N N N hhN h g N N N N N Ntddi npJpJ N N N g r N N N N N hhi nnp N N N N N N N N N N 9 W 0 9 9 �x N N N N N N N N N N N VN 0 g g fX w N N N N NN N N N N N N N fdni i IVV voh" N pi i pii vii ranii nuii ndii WN X 1�lp synTerra rrpvN N N Nni c IN NMI m vspEpnmm~ 9 9 �� DUKE ENERGY PROGRESS N N N N ni ssi N N < N N Ntrtp FIGURE 10-6 ISOCONCENTRATION MAP ARSENIC IN ASH PORE WATER WELLS N---------------� ••---------- o .. A • •J - S-012.�- �142(131) -�-'�- S-022 ABMW-04 (449) 9r1 j ♦. — .. — .. — ..... — .. r_ .. —1 MAYO LAKE , 1• A"� `-1 1 LEGEND 700 N N NV h X 700 BOLD VALUESN N N (700) N N IW h X (700) BOLD VALUESN N N N N N Kry N N W N N N N N N N 0 N O N N N N N N N N N N N N NOTES: N N N N hhi nr N N g N N N N Idi nrN N g ^ N N N N Ni nrN N g p N N N N hhi nrN N g N N hhN N NNiiNhg N N N N N Ntddi npJpJ N N N g r N N N N N hhi nnp N N N N N N N N N N 9 W 0 9 9 �x N N N N N N N N N N N VN 0 g g Bx w N N N N NN N N N N N N N Idni i IW voh" N pi i pii vii ranii nuii ndii WN Xtip = DUKE a ENERGY s mTerra PROGRESS rrpvN N N Nni c N N N N a IN NMI m ni ssi N N vspEpnnawmw N N Ntrtp LL 9 9 a FIGURE 10-7 ISOCONCENTRATION MAP BARIUM IN ASH PORE WATER WELLS N---------------� •�--------------------- A • ABMW-01' g� 4560 (4530) goo ABMW-02' 9200 (8100) J j .. -..... -..... -.. r_..-1 A MAYO LAKE , LEGEND 700 N N NV h X 700 BOLD VALUESN N N (700) N N RV h X (700) BOLD VALUESN N N N hh N Kry N N N 0 N O N N N N N N �... mz N N N N N N NOTES: N N N N hhi nr N N g N N N N fdi nrN N g ^ N N N N Ni nrN N g p N N N N hhi nrN N g N N hhN N NNiiN hg N N N N N Ntddi npJpJ N N N g r N N N N N hhi nnp N N N N N N N N N N 9 W 0 9 9 �x N N N N N N N N N N N VN 0 g g Bx w N N N N NN N N N N N N N hhni i IW voh" N pi i pii vii ranii nuii ndii WN X DUKE 1�lp ENERGY° s mTerra PROGRESS rrpvN N N Nni c N N N N a IN NMI m ni ssi N N o vspEpnmm~ N N Nt rt p W 9 9 FIGURE 10-8 ISOCONCENTRATION MAP BORON IN ASH PORE WATER WELLS N---------------� •a------------ h , • '• �J a L ♦. - .. - .. - ..... - .. LEGEND 0.035 N NV m IW h X 0.035 BOLD VALUESN N N -• ' c W.i "e ., T N NV N N X W N N N N N N N �- N N N �._._ N N N N N N N N N I — MAYO LAKE , 1• _`Ils` 1 - X NOTES: m N N N N fdi nr N N g N N N N fdi nrN N g ^ N N N N Ni nrN N g o N N N N fdi nr N N g N N N N N NVMNgorN hJW c ni nrX N N N N N Nt Ni npg% N N N g r N N N N N Ni nnp N N N N N N N N N N g W 0 9 9 �x N N N N N N N N N N N ON 0 9 g hX w N N N N NN N N N N N N N fdni i IW vohti" N pi i pii vii rrmii nuii ndii WN X DUKE All ENERGY° s mTerra PROGRESS rrpvN N N Nni c N N N N a IN NMI m ni ssi N N o vspEpnmm~ N N Nt rt p w 9 9 FIGURE 10-9 ISOCONCENTRATION MAP CHROMIUM (VI) IN ASH PORE WATER WELLS N---------------� •�--------------------- A • S-01Z n 8.05 Q.n) AB M W-03' j ♦. — ..... — ..... — . . r_ .. —1 J vrm. 1• A"� `-1 1 LEGEND 1 N N NV h X 1 BOLD VALUESN N N (1) N N NV hX (1) BOLD VALUESN N N N N N NV N N W N N N N N N N 0 N O N N N N N N N N N N N N NOTES: N N N N hhi nr N N g N N N N Idi nrN N g ^ N N N N Ni nrN N 9 p N N N N hhi nrN N 9 N N N N IW )N N N NN h g N N N N N Ntddi npJpJ N N N g r N N N N N hhi nnp N N N N N N N N N N 9 W 0 9 9 �x N N N N N N N N N N N VN 0 g g Bx w N N N N NN N N N N N N N Idni i IW voh" N pi i 31i vii ranii nuii ndii WN Xtip = DUKE a ENERGY s mTerra PROGRESS rrpvN N N Nni c N N N N a IN NMI m ni ssi N N vspEpnnawmw N N Ntrtp LL 9 9 a FIGURE 10-10 ISOCONCENTRATION MAP COBALT IN ASH PORE WATER WELLS N---------------� •a------------ h • �J , a , slo1Z �J , • 22000 (15100) ASH BASIN i 1981 � ♦W. LANDFILL s. ABMW-013 All I00" 1370 (483) ABMW-02' -356(172, 1 aoo AB W 03�3'Ali Lou , Lam. ' MAYO LAKE j .. —..... —..... —.. r_..-1 LEGEND 300 N N f+YV h X 300 BOLD VALUESN N N (300) N N IW h X (300) BOLD VALUESN N N N N N IW N N W N N N N N N N 0 N O N N N N N N N N N N N N NOTES: N N N N hhi nr N N g N N N N Idi nrN N g ^ N N N N Ni nrN N g p N N N N Ni nrN N g N N N N N N Idii N h g N N N N N Ntddi npJpJ N N N g r N N N N N Ni nnp N N N N N N N N N N 9 W 0 9 9 �x N N N N N N N N N N N VN 0 g g fX w N N N N NN N N N N N N N Nni i IW voh" N pi i pii vii ranii nuii ndii WN X DUKE Alp ENERGY° s mTerra PROGRESS rrpvN N N Nni c N N N N a IN NMI m ni ssi N N o vspEpnnawmw N N Ntrtp w 9 9 FIGURE 10-11 ISOCONCENTRATION MAP IRON IN ASH PORE WATER WELLS N---------------� •�--------------------- A • �, 50 ABMW-02' o 1 1110 (957) ABMW-03'� j L. .. —..... —..... —.. r_..-1 -4 .•�- Ali. v Lam. MAYO LAKE 1• Its •1 1 - iLEGEND 50 N N fW h X 50 BOLD VALUESN N N (50) N N hl'V h X (50) BOLD VALUESN N N r N hh N Kry N N N L N O N N N N N N N N N N N N NOTES: N N N N hhi nr N N g N N N N fdi nrN N g ^ N N N N Ni nrN N g p N N N N hhi nrN N g N N hh N N N NiN hg N N N N N Ntddi npJpJ N N N g r N N N N N hhi nnp N N N N N N N N N N 9 W 0 9 9 �x N N N N N N N N N N N VN 0 g g Bx w N N N N NN N N N N N N N fdni i IW voh" N pi i pii vii ranii nuii ndii WN X = DUKE All a ENERGY symTerra PROGRESS rrpvN N N Nni c N N N N a IN NMI m ni ssi N N vspEpnmm~ N N Nt rt p LL 9 9 a FIGURE 10-12 ISOCONCENTRATION MAP MANGANESE IN ASH PORE WATER WELLS N---------------� •a------------ h . • �J • m a j 1 .--------------- ---1 LEGEND 6.5-8.5 TOTAL pH CONCENTRATION (S.U.) 6.5-8.5 BOLD VALUES INDICATE AN EXCEEDANCES NORTH CAROLINA2L CONTOUR (DASHED WHERE ESTIMATED) (HASH MARKS INDICATE DIRECTION OF EXCEEDANCES) MONITORING WELL - 0 TOE DRAIN Q ACTIVE ASH BASIN BOUNDARY ASH BASIN COMPLIANCE BOUNDARY DUKE ENERGY PROGRESS MAYO PLANT SITE BOUNDARY .- STREAM LAKE 1• 4 NOTES: 1 CONCENTRATIONS ARE FROM THE MARCH 2O15 SAMPLING EVENT. 2 CONCENTRATIONS ARE FROM THE MAY 2015 SAMPLING EVENT. 3 CONCENTRATIONS ARE FROM THE JUNE 2015 SAMPLING EVENT. 4 CONCENTRATIONS ARE FROM THE JULY 2015 SAMPLING EVENT. 5 THE NORTH CAROLINA 2L RANGE FOR pH IS 6.5 TO 8.5 S.U.. 6 SITE AERIAL ORTHOPHOTOGRAPHY IS DATED APRIL 17, 2014. IT WAS OBTAINED FROM WSP. 7 ADDITIONAL OFFSITE AERIAL ORTHOPHOTOGRAPHY IS DATED 2012. IT WAS OBTAINED FROM THE INC CENTER FOR GEOGRAPHIC INFORMATION AND ANALYSIS. (http://services.nconemap.gov/) 8 PARCEL BOUNDARY WAS OBTAINED FROM THE INC CENTER FOR GEOGRAPHIC INFORMATION AND ANALYSIS. (hftp://services.nconemap.gov/) 9 DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE COORDINATE SYSTEM RIPS 3200 (NAD8312011). GRAPHIC SCALE 400 0 400 800 1,200 1,600 2,000 (IN FEET) 1�lp symTerra 148 RIVER STREET, SUITE 220, GREENVILLE, SC 29601 864-421-9999 www.synterracorp.com �� DUKE ENERGY PROGRESS MAYO STEAM ELECTRIC POWER PLANT 10660 BOSTON RD ROXBORO, NORTH CAROLINA 27574 FIGURE 10-13 ISOCONCENTRATION MAP pH IN ASH PORE WATER WELLS N---------------� ••------------ o .. A • •J - W02(-1:0.2) S-022 it .. -.. -.. -..... -.. r_..-1 L. 4SIN i 1981 LANDFILL s. MW-03'-� •' Ira , Ali .. �.s;:.. Lam. MAYO LAKE LEGEND 0.2 N N fW h X 0.2 BOLD VALUESN N N (0.2) N N IW h X (0.2) BOLD VALUESN N N N N N IW N N W N N N N N N N 0 N O N N N -� N N N N N N N N N NOTES: N N N N hhi nr N N g N N N N Idi nrN N g ^ N N N N Ni nrN N g o N N N N Ni nrN N g N N N N RVM N N N gt hg N N N N N Nt Ni npg% N N N g r N N N N N Ni nnp N N N N N N N N N N g W 0 9 9 �x N N N N N N N N N N N ON 0 9 g fX w N N N N NN N N N N N N N Nni i IW vohti" N pi i pii vii ranii nuii ndii WN X DUKE All ENERGY° s mTerra PROGRESS rrpvN N N Nni c N N N N a IN NMI m ni ssi N N o vspEpnmm~ N N Nt rt p w 9 9 FIGURE 10-14 ISOCONCENTRATION MAP THALLIUM IN ASH PORE WATER WELLS N--------------- ••--------------------- A • ' ff s" LEGEND 500 TOTAL DISSOLVED SOLIDS CONCENTRATION (mg/L) 500 BOLD VALUES INDICATE AN EXCEEDANCE5 NORTH CAROLINA2L CONTOUR (DASHED WHERE ESTIMATED) (HASH MARKS INDICATE DIRECTION OF LOWER CONCENTRATIONS) MONITORING WELL - 0 TOE DRAIN Q ACTIVE ASH BASIN BOUNDARY ASH BASIN COMPLIANCE BOUNDARY DUKE ENERGY PROGRESS MAYO PLANT SITE BOUNDARY .- STREAM MAYO LAKE • z,4 1• s .J :.r 1 NOTES: 1 CONCENTRATIONS ARE FROM THE MARCH 2O15 SAMPLING EVENT. 2 CONCENTRATIONS ARE FROM THE MAY 2015 SAMPLING EVENT. 3 CONCENTRATIONS ARE FROM THE JUNE 2015 SAMPLING EVENT. 4 CONCENTRATIONS ARE FROM THE JULY 2015 SAMPLING EVENT. 5 THE NORTH CAROLINA2L FOR TOTAL DISSOLVED SOLIDS IS 500 mg/L. 6 SITE AERIAL ORTHOPHOTOGRAPHY IS DATED APRIL 17, 2014. IT WAS OBTAINED FROM WSP. 7 ADDITIONAL OFFSITE AERIAL ORTHOPHOTOGRAPHY IS DATED 2012. IT WAS OBTAINED FROM THE INC CENTER FOR GEOGRAPHIC INFORMATION AND ANALYSIS. (http://services.nconemap.gov/) 8 PARCEL BOUNDARY WAS OBTAINED FROM THE INC CENTER FOR GEOGRAPHIC INFORMATION AND ANALYSIS. (hftp://services.nconemap.gov/) 9 DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE COORDINATE SYSTEM RIPS 3200 (NAD8312011). GRAPHIC SCALE 400 0 400 800 1,200 1,600 2,000 (IN FEET) 1�lp symTerra 148 RIVER STREET, SUITE 220, GREENVILLE, SC 29601 864-421-9999 www.synterracorp.com �� DUKE ENERGY PROGRESS MAYO STEAM ELECTRIC POWER PLANT 10660 BOSTON RD ROXBORO, NORTH CAROLINA 27574 FIGURE 10.15 ISOCONCENTRATION MAP TOTAL DISSOLVED SOLIDS IN ASH PORE WATER WELLS N---------------� ••------------ h , • �J n 0.45(<0.3) R��1 ..�--�''_-• S-022 i' AE 31 A ABMW-02' .� �3.53 (2.59) h-ft< W-03'0.3) J j .. —.. —.. —..... —.. r_..-1 Lam. MAYO LAKE � / s 1• A"� `-1 1 LEGEND 0.3 N N NV h X 0.3 BOLD VALUESN N N (0.3) N N KV h X (0.3) BOLD VALUESN N N N N N tW N N W N N N N N N � N 0 N O N N N N N N N N N N N N NOTES: N N N N hhi nr N N g N N N N fdi nrN N g ^ N N N N Ni nrN N g o N N N N hhi nrN N g N N N N RV M N N Ng) hg N N N N N hit Ni npg% N N N g r N N N N N Ni nnp N N N N N N N N N N g W 0 9 9 �x N N N N N N N N N N N ON 0 9 g BK w N N N N NN N N N N N N N fdni i IW vohti" N pi i pii vii ranii nuii ndii WN X = DUKE All a ENERGY symTerra PROGRESS rrpvN N N Nni c N N N N a IN NMI m ni ssi N N vspEpnnawmw N N Ntrtp LL 9 9 a FIGURE 10-16 ISOCONCENTRATION MAP VANADIUM IN ASH PORE WATER WELLS N---------------� A • h • • J ' r • MWP16S' • • <1 (<1) j _ MW-12S' ♦.—.....1 <1.....—..�..� � MAYO LAKE LEGEND 1 N N tW h X 1 BOLD VALUESN N N (1) N N fW hX (1) BOLD VALUESN N N N N N tW N N W N N N N N N N N N N �._._ N N N N N N N N N I — NOTES: m N N N N fdi nr N N g N N N N fdi nrN N g ^ N N N N Ni nrN N g o N N N N fdi nr N N g N N N N tW M N N Nn hg N N N N N Nt ddi npp N N N g r N N N N N Ni nnp N N N N N N N N N N g W 0 9 9 �x N N N N N N N N N N N ON 0 9 g hX w N N N N NN N N N N N N N fdni i IW vohti" N pi i pii vii ranii nuii ndii WN X 1�lp synTerra rrpvN N N Nni c IN NMI m vspEpnm"" 9 9 �� DUKE ENERGY PROGRESS N N N N ni ssi N N < N N Ntrtp FIGURE 10-17 ISOCONCENTRATION MAP ANTIMONY IN SURFICIAL WELLS N---------------� A • h • J ' r • MWP16S' • • <1 (<1) j _ MW-12S' •.—.....1 <1.....—..�..� � LEGEND 10 N N fW h X 10 BOLD VALUESN N N (10) N N RV h X (10) BOLD VALUESN N N N fd N fW N N W N N N N N N •�- N N N �._._ N N N N N N N N N I — Lam.. � • MAYO LAKE , J X X NOTES: m N N N N fdi nr N N g N N N N fdi nrN N g ^ N N N N Ni nrN N g p N N N N fdi nr N N g N N fd N N N hh N h g N N N N N Ntddi npJpJ N N N g r N N N N N fdi nnp N N N N N N N N N N 9 W 0 9 9 �x N N N N N N N N N N N VV 0 g g Bx w N N N N NN N N N N N N N fdni i IW voh" N pi i 31i vii rrmii nbii ndii WN X 1�lp synTerra rrpvN N N Nni c IN NMI m vspEpnm"" 9 9 �� DUKE ENERGY PROGRESS N N N N ni ssi N N < N N Ntrtp FIGURE 10-18 ISOCONCENTRATION MAP ARSENIC IN SURFICIAL WELLS N---------------� A , h • • • MWP16S' • . 46 (46) j _ MW-12S' 24 (23) ♦.—...... ...�.. L MAYO LAKE , LEGEND 700 N N NV h X 700 BOLD VALUESN N N (700) N N IW h X (700) BOLD VALUESN N N N fd N fW N N W N N N N N N N N N N �._._ N N N N N N N N N I — X X NOTES: m N N N N fdi nr N N g N N N N fdi nrN N g ^ N N N N Ni nrN N g p N N N N fdi nr N N g N N fdN N NNiiNhg N N N N N Ntddi npJpJ N N N g r N N N N N fdi rm pJ N N N N N N N N N N 9 W 0 9 9 �x N N N N N N N N N N N VN 0 g g Bx w N N N N NN N N N N N N N fdni i IW voh" N pi i pii vii nmii nbii ndii WN X 1�lp synTerra rrpvN N N Nni c IN NMI m vspEpnm"" 9 9 �� DUKE ENERGY PROGRESS N N N N ni ssi N N < N N Ntrtp FIGURE 10-19 ISOCONCENTRATION MAP BARIUM IN SURFICIAL WELLS N---------------� ••--------------------- A , ' ♦ / 4 ♦ _ MWP16S' / ♦ ♦ < 50 (< 50) ' SR.1501`,' '. MW-03' 847 (815) - — �00 _ a • ' •• ACTIVE - � - - - - ASH BASIN ' ABMW-03S' , 1100 (1070) 1 L MW-12S' <.5� 050) i ,l MAYO LAKE ♦ $ . A ` J LEGEND 700 N N NV h X 700 BOLD VALUESN N N (700) N N RV h X (700) BOLD VALUESN N N N Id N fW N N W N N N N N N N N N N �._._ N N N N N N N N N X X NOTES: N N N N fdi nr N N g N N N N Idi nrN N g ^ N N N N Ni nrN N g p N N N N Idi nrN N g N N IdN N NNiiN hg N N N N N Ntddi npJpJ N N N g r N N N N N Idi rm pJ N N N N N N N N N N 9 W 0 9 9 �x N N N N N N N N N N N VN 0 g g Bx w N N N N NN N N N N N N N Idni i IW voh" N pi i pii vii ranii nuii ndii WN X 1�lp synTerra rrpvN N N Nni c IN NMI m vspEpnmm~ 9 9 �� DUKE ENERGY PROGRESS N N N N m ssi N N < N N Ntrtp FIGURE 10-20 ISOCONCENTRATION MAP BORON IN SURFICIAL WELLS N--------------- •�--------------------- A • • SR:l— j .. -.. -.. -..... -.. r_..-1 4 MWP16S' 0.011 LEGEND 0.035 N NV m 0.035 BOLD VALUESN N N N NV W N N •�• � N •�- N N N �-• U._._ � N N N N I — Lam.. � • MAYO LAKE , J IW h X N N X N N N N X N N N N N NOTES: m N N N N fdi nr N N g N N N N fdi nrN N g ^ N N N N Ni nrN N g o N N N N fdi nr N N g N N N N N NVMNgorN hJW c ni nrX N N N N N Nt Ni npg% N N N g r N N N N N Ni nnp N N N N N N N N N N g W 0 9 9 �x N N N N N N N N N N N ON 0 9 g hX w N N N N NN N N N N N N N fdni i IW vohti" N pi i 31i vii rrmii nuii ndii WN X 1�lp symTerra rrpvN N N Nni c IN NMI m vspEpnm"" 9 9 �� DUKE ENERGY PROGRESS N N N N ni ssi N N < N N Ntrtp FIGURE 10-21 ISOCONCENTRATION MAP CHROMIUM (VI) IN SURFICIAL WELLS �Il N---------------� •�--------------------- Flu L 31 ♦ FILL s. f-, ``�. Lam. MAYO LAKE , LEGEND 1 N N NV h X 1 BOLD VALUESN N N (1) N N NV hX (1) BOLD VALUESN N N N N N NV N N W N N N N N N N N N N �._._ N N N N N N N N N I — NOTES: N N N N hhi nr N N g N N N N Idi nrN N g ^ N N N N Ni nr N N 9 p N N N N hhi nrN N 9 N N N N IW )N N N NrN h g N N N N N Ntddi npJpJ N N N g r N N N N N hhi nnp N N N N N N N N N N 9 W 0 9 9 �x N N N N N N N N N N N VN 0 g g Bx w N N N N NN N N N N N N N Idni i IW voh" N pi i pii vii ranii nuii ndii WN X DUKE All ENERGY° s mTerra PROGRESS rrpvN N N Nni c N N N N a IN NMI m ni ssi N N o vspEpnmm~ N N Nt rt p w 9 9 FIGURE 10-22 ISOCONCENTRATION MAP COBALT IN SURFICIAL WELLS N---------------� ••--------------------- n • �y • • � • MW-16S3 L _ MW-12S' 295 (< 10) �.. ...... FW MAYO LAKE J LEGEND 300 N N fW h X 300 BOLD VALUESN N N (300) N N RV h X (300) BOLD VALUESN N N N fd N fW N N � W N N N N N N N N N N �._._ N N N N N N N N N I — X X NOTES: m N N N N fdi nr N N g N N N N fdi nrN N g ^ N N N N Ni nrN N g p N N N N fdi nr N N g N N fd N N N fdi i N h g N N N N N Ntddi npJpJ N N N g r N N N N N fdi rm pJ N N N N N N N N N N 9 W 0 9 9 �x N N N N N N N N N N N VV 0 g g Bx w N N N N NN N N N N N N N fdni i IW voh" N pi i 31i vii rrmii nbii ndii WN X 1�lp synTerra rrpvN N N Nni c IN NMI m vspEpnmm~ 9 9 �� DUKE ENERGY PROGRESS N N N N ni ssi N N < N N Ntrtp FIGURE 10-23 ISOCONCENTRATION MAP IRON IN SURFICIAL WELLS N---------------� ••--------------------- n • �y • • � • MW-16S3 L MW-12S3 267 (249) LEGEND 50 N N fW h X 50 BOLD VALUESN N N (50) N N hl'r/ h X (50) BOLD VALUESN N N N fd N fW N N W N N N N N N •�� � N •�- N N N �._._ N N N N N N N N N I — MAYO LAKE , J 1 X X NOTES: m N N N N fdi nr N N g N N N N fdi nrN N g ^ N N N N Ni nrN N g p N N N N fdi nr N N g N N fd N N N NiN hg N N N N N Ntddi npJpJ N N N g r N N N N N fdi nnp N N N N N N N N N N 9 W 0 9 9 �x N N N N N N N N N N N VN 0 g g Bx w N N N N NN N N N N N N N fdni i IW voh" N pi i 31i vii rrmii nbii ndii WN X 1�lp synTerra rrpvN N N Nni c IN NMI m vspEpnm"" 9 9 �� DUKE ENERGY PROGRESS N N N N ni ssi N N < N N Ntrtp FIGURE 10-24 ISOCONCENTRATION MAP MANGANESE IN SURFICIAL WELLS N--------------- •�--------------------- A • ' Ao• - I..;&Mu 94' j _ MW-12S3 5.7 L 17 Flu 1 1• 4 LEGEND 6.5-8.5 TOTAL pH CONCENTRATION (S.U.) 6.5-8.5 BOLD VALUES INDICATE AN EXCEEDANCE5 NORTH CAROLINA2L CONTOUR (DASHED WHERE ESTIMATED) (HASH MARKS INDICATE DIRECTION OF EXCEEDANCES) MONITORING WELL ACTIVE ASH BASIN BOUNDARY ASH BASIN COMPLIANCE BOUNDARY �^ DUKE ENERGY PROGRESS MAYO PLANT SITE BOUNDARY — STREAM NOTES: CONCENTRATIONS ARE FROM THE MARCH 2O15 SAMPLING EVENT. s CONCENTRATIONS ARE FROM THE MAY 2015 SAMPLING EVENT. 3 CONCENTRATIONS ARE FROM THE JUNE 2015 SAMPLING EVENT. 4 CONCENTRATIONS ARE FROM THE JULY 2015 SAMPLING EVENT. 5 THE NORTH CAROLINA 2L RANGE FOR pH IS 6.5 TO 8.5 S.U.. 6 SITE AERIAL ORTHOPHOTOGRAPHY IS DATED APRIL 17, 2014. IT WAS OBTAINED FROM WSP. 7 ADDITIONAL OFFSITE AERIAL ORTHOPHOTOGRAPHY IS DATED 2012. IT WAS OBTAINED FROM THE INC CENTER FOR GEOGRAPHIC INFORMATION AND ANALYSIS. (http://services.nconemap.gov/) 8 PARCEL BOUNDARY WAS OBTAINED FROM THE INC CENTER FOR GEOGRAPHIC INFORMATION AND ANALYSIS. (hftp://services.nconemap.gov/) 9 DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE COORDINATE SYSTEM RIPS 3200 (NAD8312011). GRAPHIC SCALE 400 0 400 800 1,200 1,600 2,000 (IN FEET) 1�lp symTerra 148 RIVER STREET, SUITE 220, GREENVILLE, SC 29601 864-421-9999 www.synterracorp.com �� DUKE ENERGY PROGRESS MAYO STEAM ELECTRIC POWER PLANT 10660 BOSTON RD ROXBORO, NORTH CAROLINA 27574 FIGURE 10-25 ISOCONCENTRATION MAP pH IN SURFICIAL WELLS N---------------� A • h • • J ' r • MWP16S' • • < 0.2 (< 0.2) _ MW-12S' < 0.2 (< 0.2) ♦.—...... ...... L MAYO LAKE , 1 LEGEND 0.2 N N fW h X 0.2 BOLD VALUESN N N (0.2) N N fW h X (0.2) BOLD VALUESN N N N N N fW N N W N N N N N N N N N N �._._ N N N N N N N N N I — NOTES: m N N N N fdi nr N N g N N N N fdi nrN N g ^ N N N N Ni nr N N g o N N N N fdi nr N N g N N N N RVM N N Ngt hg N N N N N fdt ddi npg% N N N g r N N N N N Ni nnp N N N N N N N N N N g W 0 9 9 �x N N N N N N N N N N N ON 0 9 g fX w N N N N NN N N N N N N N Idni i IVr/ vohti" N pi i pii vii ranii nuii ndii WN X 1�lp synTerra rrpvN N N Nni c IN NMI m vspEpnm"" 9 9 �� DUKE ENERGY PROGRESS N N N N ni ssi N N < N N Ntrtp FIGURE 10-26 ISOCONCENTRATION MAP THALLIUM IN SURFICIAL WELLS N--------------:% A / h • • J ' r • MWP16S' • • 100 _ MW-12S' 50 .-- -- — -..�.., li LEGEND 500 TOTAL DISSOLVED SOLIDS CONCENTRATION (mg/L) 500 BOLD VALUES INDICATE AN EXCEEDANCE5 NORTH CAROLINA2L CONTOUR (DASHED WHERE ESTIMATED) (HASH MARKS INDICATE DIRECTION OF LOWER CONCENTRATIONS) • MONITORING WELL • • - ACTIVE ASH BASIN BOUNDARY . _ . _ ASH BASIN COMPLIANCE BOUNDARY �^ DUKE ENERGY PROGRESS MAYO PLANT SITE BOUNDARY - STREAM MAYO LAKE , 1 R OPT 1• ' J s •J :.r NOTES: 1 CONCENTRATIONS ARE FROM THE MARCH 2O15 SAMPLING EVENT. 2 CONCENTRATIONS ARE FROM THE MAY 2015 SAMPLING EVENT. 3 CONCENTRATIONS ARE FROM THE JUNE 2015 SAMPLING EVENT. 4 CONCENTRATIONS ARE FROM THE JULY 2015 SAMPLING EVENT. 5 THE NORTH CAROLINA2L FOR TOTAL DISSOLVED SOLIDS IS 500 mg/L. 6 SITE AERIAL ORTHOPHOTOGRAPHY IS DATED APRIL 17, 2014. IT WAS OBTAINED FROM WSP. 7 ADDITIONAL OFFSITE AERIAL ORTHOPHOTOGRAPHY IS DATED 2012. IT WAS OBTAINED FROM THE INC CENTER FOR GEOGRAPHIC INFORMATION AND ANALYSIS. (http://services.nconemap.gov/) 8 PARCEL BOUNDARY WAS OBTAINED FROM THE INC CENTER FOR GEOGRAPHIC INFORMATION AND ANALYSIS. (hftp://services.nconemap.gov/) 9 DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE COORDINATE SYSTEM RIPS 3200 (NAD8312011). GRAPHIC SCALE 400 0 400 800 1,200 1,600 2,000 (IN FEET) 1�lp symTerra 148 RIVER STREET, SUITE 220, GREENVILLE, SC 29601 864-421-9999 www.synterracorp.com �� DUKE ENERGY PROGRESS MAYO STEAM ELECTRIC POWER PLANT 10660 BOSTON RD ROXBORO, NORTH CAROLINA 27574 FIGURE 10.27 ISOCONCENTRATION MAP TOTAL DISSOLVED SOLIDS IN SURFICIAL WELLS N---------------� ••--------------------- n • �y \\ • i • I L •,1 Lam.. � • MAYO LAKE , J 1• A"� `-1 LEGEND 0.3 N N NV h X 0.3 BOLD VALUESN N N (0.3) N N KV h X (0.3) BOLD VALUESN N N N N N tW N N W N N N N N N •�� N N N N U-_-_ N N N N N N N N N I — NOTES: m N N N N fdi nr N N g N N N N fdi nrN N g ^ N N N N Ni nrN N g o N N N N fdi nr N N g N N N N RV M N N Ng) hg N N N N N Nt Ni npg% N N N g r N N N N N Ni nnp N N N N N N N N N N g W 0 9 9 �x N N N N N N N N N N N ON 0 9 g BK w N N N N NN N N N N N N N fdni i IW vohti" N pi i 31i vii ranii nuii ndii WN X = DUKE Alp a ENERGY s mTerra PROGRESS rrpvN N N Nni c N N N N a IN NMI m ni ssi N N vspEpnnawmw N N Ntrtp c 9 9 a FIGURE 10-28 ISOCONCENTRATION MAP VANADIUM IN SURFICIAL WELLS N---------------� A • 0 h J . . . . . . .... . L it 1• A- Ala > .J LEGEND 1 N N NV h X 1 BOLD VALUESN N N (1) N N KV hX (1) BOLD VALUESN N N N N N NV N N W N N N N N N N N N N U-_-_ N N N N N N N N N I - NOTES: m N N N N fdi nr N N g N N N N fdi nrN N g ^ N N N N Ni nrN N g o N N N N fdi nr N N g N N N N RV M N N Nn hg N N N N N Nt Ni npg% N N N g r N N N N N Ni nnp N N N N N N N N N N g W 0 9 9 �x N N N N N N N N N N N ON 0 9 g BK w N N N N NN N N N N N N N fdni i IW vohti" N pi i pii vii ranii nuii ndii WN X tip DUKE ENERGY° s mTerra PROGRESS rrpvN N N Nni c N N N N a IN NMI m ni ssi N N o vspEpnmm~ N N Nt rt p w 9 9 FIGURE 10-29 ISOCONCENTRATION MAP ANTIMONY IN TRANSITION ZONE WELLS N---------------� ••-------- • �y * ON A • • , j L. _ MW-12D' 1(C1) �.—.....—...... , LEGEND 10 N N IW h X 10 BOLD VALUESN N N (10) N N fW h X MW-16D' (10) BOLD VALUESN N N N N N IW N N W N N N N N N +a.. N '•� •�- N N N '4 - N N N < I (Ns) - -�� �^ N N N N N N x 1981 � ♦ LANDFILL . _ • CW-01" < 1 (NS) ��•�'00, MAYO LAKE NOTES: N N N N hhi nr N N g N N N N Idi nrN N g ^ N N N N Ni nrN N g p N N N N Ni nrN N g N N N N N N hhN h g N N N N N Ntddi npJpJ N N N g r N N N N N Ni nnp N N N N N N N N N N 9 W 0 9 9 �x N N N N N N N N N N N VN 0 g g fX w N N N N NN N N N N N N N Nni i IW voh" N pi i pii vii ranii nuii ndii WN X = DUKE 1�lp a ENERGY s mTerra PROGRESS rrpvN N N Nni c N N N N a IN NMI m ni ssi N N vspEpnnawmw N N Ntrtp LL 9 9 a FIGURE 10-30 ISOCONCENTRATION MAP ARSENIC IN TRANSITION ZONE WELLS N------ ---------� h A• Jy i' iri MW-02 Wet 711171'- 55(53) 7 cw-021 129 (NS) L. MW-12D' 26 (23) �.—...... ..�.., 1► Flu 24(23)----- 1981 � ♦ LANDFILL s•. ' CW-014 < 5 (NS) MAYO LAKE Ilk LEGEND 700 N N NV h X 700 BOLD VALUESN N N (700) N N IW h X (700) BOLD VALUESN N N N N N fW N N W N N N N N N N N N N �._._ N N N N N N N N N I — NOTES: N N N N hhi nr N N g N N N N Idi nrN N g ^ N N N N Ni nrN N g p N N N N hhi nrN N g N N hhN N NNiiNhg N N N N N Ntddi npJpJ N N N g r N N N N N hhi rm pJ N N N N N N N N N N 9 W 0 9 9 �x N N N N N N N N N N N VN 0 g g Bx w N N N N NN N N N N N N N Nni i IW voh" N pi i pii vii ranii nuii ndii WN XLl = DUKE All a ENERGY symTerra PROGRESS rrpvN N N Nni c N N N N a IN NMI m ni ssi N N vspEpnmm~ N N Nt rt p LL 9 9 a FIGURE 10-31 ISOCONCENTRATION MAP BARIUM IN TRANSITION ZONE WELLS N---------------� A MW-12D' <50(<50) ♦.—...... ...... L i) 7 it 1• A— Ala s .J `-1 1 LEGEND 700 N N NV h X 700 BOLD VALUESN N N (700) N N RV h X (700) BOLD VALUESN N N N fd N fW N N W N N N N N N N N N N �._._ N N N N N N N N N I — NOTES: m N N N N fdi nr N N g N N N N fdi nrN N g ^ N N N N Ni nrN N g p N N N N fdi nr N N g N N fdN N NNiiN hg N N N N N Ntddi npJpJ N N N g r N N N N N fdi rm pJ N N N N N N N N N N 9 W 0 9 9 �x N N N N N N N N N N N VN 0 g g Bx w N N N N NN N N N N N N N Nni i IW voh" N pi i pii vii rrmii nbii ndii WN X DUKE All ENERGY° s mTerra PROGRESS rrpvN N N Nni c N N N N a IN NMI m ni ssi N N o vspEpnmm~ N N Nt rt p w 9 9 FIGURE 10-32 ISOCONCENTRATION MAP BORON IN TRANSITION ZONE WELLS N---------------� A • ♦ MW-12D' / 0.334 j L. MW 16D' / 0.051 LEGEND 0.035 N NV m 0.035 BOLD VALUESN N N N NV W N N •�� � N •�- N N N �._._ N N ��— N N I — ' MAYO LAKE IW h X N N X N N N N X N N N N N NOTES: m N N N N fdi nr N N g N N N N fdi nrN N g ^ N N N N Ni nrN N g o N N N N fdi nr N N g N N N N N NVMNgorN hJW c ni nrX N N N N N Nt Ni npg% N N N g r N N N N N Ni nnp N N N N N N N N N N g W 0 9 9 �x N N N N N N N N N N N ON 0 9 g hX w N N N N NN N N N N N N N fdni i IVr/ vohti" N pi i pii vii ranii nuii ndii WN X 1�lp symTerra rrpvN N N Nni c IN NMI m vspEpnmm~ 9 9 �� DUKE ENERGY PROGRESS N N N N ni ssi N N < N N Ntrtp FIGURE 10-33 ISOCONCENTRATION MAP CHROMIUM (VI) IN TRANSITION ZONE WELLS N---------------� A - • I h • • J ' r CW-031 r - < 1 (NS) MW-02' a4 MW-12D' / LEGEND 1 N N NV h X 1 BOLD VALUESN N N (1) N N NV hX _ MW-'16D' (1) BOLD VALUESN N N <1 (<1) N N N NV N N W N N N N N N •�� � N •�� � N N N SS)-��..�- N N N N N N ;�• I - a' ACTIVE - ASH BASIN ' 1981 � ♦ will -e LANDFILL s.. ' J, CW-014 < 1 (NS) ' , c` 9 ♦ MAYO LAKE , j Ilk NOTES: N N N N hhi nr N N g N N N N Idi nrN N g ^ N N N N Ni nrN N 9 p N N N N hhi nrN N 9 N N N N IW )N N N NrN h g N N N N N Ntddi npJpJ N N N g r N N N N N hhi nnp N N N N N N N N N N 9 W 0 9 9 �x N N N N N N N N N N N VN 0 g g Bx w N N N N NN N N N N N N N Idni i IW voh" N pi i pii vii ranii nuii ndii WN X = DUKE All a ENERGY symTerra PROGRESS rrpvN N N Nni c N N N N a IN NMI m ni ssi N N vspEpnnawmw N N Ntrtp LL 9 9 a FIGURE 10-34 ISOCONCENTRATION MAP COBALT IN TRANSITION ZONE WELLS N---------------� ••--------------------- A /y i r L MAYO LAKE , ' 1• A"� 4 `-1 1 LEGEND 300 N N W h X 300 BOLD VALUESN N N (300) N N RV h X (300) BOLD VALUESN N N N htt N Kry N N � W N N N N N N •�� � N N N N �._._ N N N N N N N N N I — NOTES: m N N N N hhi nr N N g N N N N fdi nrN N g ^ N N N N Ni nrN N g p N N N N hhi nrN N g N N hh N N N hbi i N h g N N N N N Ntddi npJpJ N N N g r N N N N N hhi nnp N N N N N N N N N N 9 W 0 9 9 �x N N N N N N N N N N N VN 0 g g Bx w N N N N NN N N N N N N N fdni i IW voh" N pi i pii vii rrmii nbii ndii WN X = DUKE All a ENERGY symTerra PROGRESS rrpvN N (N Mni c N N N N a (N Nmi m M ssi N N vspEpnnawmw N N Ntrtp LL 9 9 a FIGURE 10-35 ISOCONCENTRATION MAP IRON IN TRANSITION ZONE WELLS N---------------� ••--------------------- A , ' • • � CW-[ • / M wwo?- �. - • MW-02' 833 (_ 7. r BG-02° 135 (NS In35 L 4 4 LEGEND 50 N N fW h X 50 BOLD VALUESN N N M6D' (50) N N hl'V h X W-7, 269 (260) T r i. (50) BOLD VALUESN N N N hh N Kry N N 50 W N N N N N N • N •�- N N N 024 ._.•��• U.= ._ N N N 1(NS) �•�-��-�_• ��^ N N N N N N a' Fm PPOI88176) • ♦ 1 � -F L 4.� '• 1 Lam.. ♦ MAYO LAKE • .v NOTES: N N N N hhi nr N N g N N N N fdi nrN N g ^ N N N N Ni nrN N g p N N N N hhi nrN N g N N hh N N N NiN hg N N N N N Ntddi npJpJ N N N g r N N N N N hhi nnp N N N N N N N N N N 9 W 0 9 9 �x N N N N N N N N N N N VN 0 g g Bx w N N N N NN N N N N N N N fdni i IW voh" N pi i pii viirrmii nuii ndii WN X = DUKE All ENERGYa s mTerra PROGRESS rrpvN N dN Nni c N N N N a IN NMI m ni ssi N N vspEpnmm~ N N Nt rt p LL 9 9 a N N FIGURE 10-36 ISOCONCENTRATION MAP MANGANESE IN TRANSITION ZONE WELLS N---------------� A • � • • r 6D' 1 OPT LAKE LEGEND 6.5-8.5 TOTAL pH CONCENTRATION (S.U.) 6.5-8.5 BOLD VALUES INDICATE AN EXCEEDANCES NORTH CAROLINA2L CONTOUR (DASHED WHERE ESTIMATED) (HASH MARKS INDICATE DIRECTION OF EXCEEDANCES) MONITORING WELL ACTIVE ASH BASIN BOUNDARY ASH BASIN COMPLIANCE BOUNDARY �^ DUKE ENERGY PROGRESS MAYO PLANT SITE BOUNDARY — STREAM NOTES: 1 CONCENTRATIONS ARE FROM THE MARCH 2O15 SAMPLING EVENT. 2 CONCENTRATIONS ARE FROM THE MAY 2015 SAMPLING EVENT. 3 CONCENTRATIONS ARE FROM THE JUNE 2015 SAMPLING EVENT. 4 CONCENTRATIONS ARE FROM THE JULY 2015 SAMPLING EVENT. 5 THE NORTH CAROLINA 2L RANGE FOR pH IS 6.5 TO 8.5 S.U.. 6 SITE AERIAL ORTHOPHOTOGRAPHY IS DATED APRIL 17, 2014. IT WAS OBTAINED FROM WSP. 7 ADDITIONAL OFFSITE AERIAL ORTHOPHOTOGRAPHY IS DATED 2012. IT WAS OBTAINED FROM THE INC CENTER FOR GEOGRAPHIC INFORMATION AND ANALYSIS. (http://services.nconemap.gov/) 8 PARCEL BOUNDARY WAS OBTAINED FROM THE INC CENTER FOR GEOGRAPHIC INFORMATION AND ANALYSIS. (hftp://services.nconemap.gov/) 9 DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE COORDINATE SYSTEM RIPS 3200 (NAD8312011). GRAPHIC SCALE 400 0 400 800 1,200 1,600 2,000 (IN FEET) 1�lp symTerra 148 RIVER STREET, SUITE 220, GREENVILLE, SC 29601 864-421-9999 www.synterracorp.com �� DUKE ENERGY PROGRESS MAYO STEAM ELECTRIC POWER PLANT 10660 BOSTON RD ROXBORO, NORTH CAROLINA 27574 FIGURE 10-37 ISOCONCENTRATION MAP pH IN TRANSITION ZONE WELLS N---------------� h A• Jy L MW-12D' < 0.2 (< 0.2) �.—...... ...... 7 it SR:15p1 , CW-024 <0.2(NS)----���• 1981 � ♦ LANDFILL s.♦ ' J , CW-01° Y ♦' MAYO LAKE 1• A"� Ala lt� .JJ� .� LEGEND 0.2 N N fW h X 0.2 BOLD VALUESN N N (0.2) N N IW h X (0.2) BOLD VALUESN N N N N N IW N N W N N N N N N N N N N �._._ N N N N N N N N N I — NOTES: N N N N hhi nr N N g N N N N Idi nrN N g ^ N N N N Ni nrN N g o N N N N Ni nrN N g N N N N RVM N N N gt hg N N N N N Nt Ni npg% N N N g r N N N N N Ni nnp N N N N N N N N N N g W 0 9 9 �x N N N N N N N N N N N ON 0 9 g fX w N N N N NN N N N N N N N Nni i IW vohti" N pi i pii vii ranii nuii ndii WN X DUKE All ENERGY° s mTerra PROGRESS rrpvN N N Nni c N N N N a IN NMI m ni ssi N N o vspEpnmm~ N N Nt rt p w 9 9 FIGURE 10-38 ISOCONCENTRATION MAP THALLIUM IN TRANSITION ZONE WELLS ff CW-034 _ MW=16D' `• , 200 CW-024`�- -� _�• 210 MW-12D8 120 1 1, • MAYO LAKE 1• ' J s •J :.r LEGEND 500 TOTAL DISSOLVED SOLIDS CONCENTRATION (mg/L) 500 BOLD VALUES INDICATE AN EXCEEDANCE5 NORTH CAROLINA2L CONTOUR (DASHED WHERE ESTIMATED) (HASH MARKS INDICATE DIRECTION OF LOWER CONCENTRATIONS) MONITORING WELL ACTIVE ASH BASIN BOUNDARY ASH BASIN COMPLIANCE BOUNDARY �^ DUKE ENERGY PROGRESS MAYO PLANT SITE BOUNDARY — STREAM NOTES: 1 CONCENTRATIONS ARE FROM THE MARCH 2O15 SAMPLING EVENT. 2 CONCENTRATIONS ARE FROM THE MAY 2015 SAMPLING EVENT. 3 CONCENTRATIONS ARE FROM THE JUNE 2015 SAMPLING EVENT. 4 CONCENTRATIONS ARE FROM THE JULY 2015 SAMPLING EVENT. 5 THE NORTH CAROLINA2L FOR TOTAL DISSOLVED SOLIDS IS 500 mg/L. 6 SITE AERIAL ORTHOPHOTOGRAPHY IS DATED APRIL 17, 2014. IT WAS OBTAINED FROM WSP. 7 ADDITIONAL OFFSITE AERIAL ORTHOPHOTOGRAPHY IS DATED 2012. IT WAS OBTAINED FROM THE INC CENTER FOR GEOGRAPHIC INFORMATION AND ANALYSIS. (http://services.nconemap.gov/) 8 PARCEL BOUNDARY WAS OBTAINED FROM THE INC CENTER FOR GEOGRAPHIC INFORMATION AND ANALYSIS. (hftp://services.nconemap.gov/) 9 DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE COORDINATE SYSTEM RIPS 3200 (NAD8312011). GRAPHIC SCALE 400 0 400 800 1,200 1,600 2,000 (IN FEET) 1�lp symTerra 148 RIVER STREET, SUITE 220, GREENVILLE, SC 29601 864-421-9999 www.synterracorp.com �� DUKE ENERGY PROGRESS MAYO STEAM ELECTRIC POWER PLANT 10660 BOSTON RD ROXBORO, NORTH CAROLINA 27574 FIGURE 10.39 ISOCONCENTRATION MAP TOTAL DISSOLVED SOLIDS IN TRANSITION ZONE WELLS N---------------� A El j 4- 0.3 (N '�----�� a' MW-07D' • 1981 LANDFILL s. CW-01" 0.543 (NNS Lam. MAYO LAKE , LEGEND 0.3 N N NV h X 0.3 BOLD VALUESN N N (0.3) N N IW h X (0.3) BOLD VALUESN N N N N N IW N N W N N N N N N N N N N �._._ N N N N N N N N N I — NOTES: N N N N hhi nr N N g N N N N Idi nrN N g ^ N N N N Ni nrN N g o N N N N hhi nrN N g N N N N IW M N N Ng) hg N N N N N hit ddi npg% N N N g r N N N N N Ni nnp N N N N N N N N N N g W 0 9 9 �x N N N N N N N N N N N ON 0 9 g fX w N N N N NN N N N N N N N Nni i IW vohti" N pi i pii vii ranii nuii ndii WN X DUKE Alp ENERGY° s mTerra PROGRESS rrpvN N N Nni c N N N N a IN NMI m ni ssi N N o vspEpnmm~ N N Nt rt p w 9 9 FIGURE 10-40 ISOCONCENTRATION MAP VANADIUM IN TRANSITION ZONE WELLS N---------------� •�--------------------- h / •'� _ CW-04a < 1 (NS) • MW-03BR' / ftMW205BRia <1 (NS) ,-o5a LEGEND 1 N N NV hX 7 BOLD VALUESN N N (1) N N fW hX MW;16BR' (1) BOLD VALUESN N N <1 (<1) m6mmo6m N N N NV N N W N N N N N N •�� � N •�� N N N a ._.•�� U._._ N N N -�. .•�� ��^ N N N N N N c�ei_ncai_ ' .r III/ Q-'07�9BR;i 1; .f ��•�' X Cam.. • MAYO LAKE , / s NOTES: N N N N hhi nr N N g N N N N fdi nrN N g ^ N N N N Ni nrN N g o N N N N hhi nrN N g N N N N RV M N N Nn hg N N N N N Nt Ni npg% N N N g r N N N N N Ni nnp N N N N N N N N N N g W 0 9 9 �x N N N N N N N N N N N ON 0 9 g hX w N N N N NN N N N N N N N fdni i IW vohti" N pi i pii vii rttnii nuii ndii WN X DUKE 1�lp ENERGY° s mTerra PROGRESS rrpvN N N Nni c N N N N a IN NMI m ni ssi N N o vspEpnmm~ N N Nt rt p w 9 9 FIGURE 10-41 ISOCONCENTRATION MAP ANTIMONY IN BEDROCK WELLS N---------------� ••--------------------- • �rn • A / •'� _ CW-04a < 1 (NS) • MW-03BR' / ftMW205BRia <1 (NS) -n5a LEGEND 10 N N fW h X 10 BOLD VALUESN N N (10) N N fW h X MW;16BR' (10) BOLD VALUESN N N 2.05 (2.07) N hh N fW N N � W N N N N N N •�• N •�- � N N N a ._.•�� U-_-_ � N N N -�. .•�• ��^ N N N N N N c�ei_ncai_ ' J 1 M�Wj096B f , .fl Lam• . ♦ ♦' MAYO LAKE , NOTES: N N N N hhi nr N N g N N N N fdi nrN N g ^ N N N N Ni nrN N g p N N N N hhi nrN N g N N hh N N N hhN h g N N N N N Ntddi npJpJ N N N g r N N N N N hhi nnp N N N N N N N N N N 9 W 0 9 9 �x N N N N N N N N N N N VN 0 g g fX w N N N N NN N N N N N N N fdni i IVV voh" N pi i pii vii rttnii nuii ndii WN X DUKE 1�lp , ENERGY., s mTerra PROGRESS rrpvN N N Nni c N N N N a IN NMI m ni ssi N N o vspEpnmm~ N N Nt rt p w 9 9 FIGURE 10-42 ISOCONCENTRATION MAP ARSENIC IN BEDROCK WELLS N---------------� W %.,- i0 J C-04° - 25 (NS) x _ i MW-03BR' / • M1N=14BR' r 46 (NS) A2105BRWKWOMIC- LEGEND 700 N N NV h X 700 BOLD VALUESN N N (700) N N NV h X MW;16BR' (700) BOLD VALUESN N N 11 (9) N N N NV N � W N N N N N •�• N •�- � N N N a ._.•�� U._._ � N N N -�. .•�• ��^ N N N N N N I — Rmw �..—.. ENNER MWL09BR ._ 1 LAKE , N X N X NOTES: N N N N hhi nr N N g N N N N fdi nrN N g ^ N N N N Ni nrN N g p N N N N hhi nrN N g N N hhN N NNiiNhg N N N N N Ntddi npJpJ N N N g r N N N N N Ni nnp N N N N N N N N N N 9 W 0 9 9 �x N N N N N N N N N N N VN 0 g g Bx w N N N N NN N N N N N N N fdni i NV voh" N pi i pii vii ranii nuii ndii WN X = DUKE a ENERGY synTerra PROGRESS rrpvN N dN Nni c N N N N a IN NMI m ni ssi N N vspEpnmm~ N N Nt rt p LL 9 9 a arw,� N N N PtWpi m h,E N N N PtWpi m '# N N FIGURE 10-43 ISOCONCENTRATION MAP BARIUM IN BEDROCK WELLS N---------------� %., 0 J • - AW, < 50 (NS) - 'x - i MW-03BR' < 50 (NS) IIV=I4BR' 50 (<''50) �SR:1501 " LEGEND 700 N N NV h X 700 BOLD VALUESN N N (700) N N RV h X MW;16BR' (700) BOLD VALUESN N N < 50 (< 50) N hh N Kry N N � W N N N N N N •�• � N •�� N N N .�� _ N N N ( _'-� .•�• ��^ N N N N N N I — 1961 b 7r LANDFILL - - V • . MW-096R3 < 50 (< 50) • 1 NOTES: . ,` • m N N N N hhi nr N N g D21B ` a ` N N N N hhi nrN N g 90) CW-01D <50 (NS) : N N N N Ni nrN N g p N N N N hhi nrN N g D4BR' •�� N N hhN N NNiiN hg i0) ; N N N N N Nt bi npJpJ N N • N g Y `� -♦ • N N N N N hhi nnp N N N N N N N N N N 9 ♦' MAYO W 9 9 N N N N N N N N N LAKE i �. ♦ N N VN 0 9 9 M�BR.NN N N Idni i IW vohN N N N N</ . ,.... ,' �� �•L 0. pi vi i rani i nui i nd i i WN X DUKE -! w�A<t5ENERGYoo F=j Ter PROGRESS 01 rrpvN N dN Mni c N N N N a (N Nvzi m M ssi N N o vspEpnmmymw N N Nt rt p w 9 9 < m N N Ptwplm FIGURE 10-44 ISOCONCENTRATION MAP a 1 BORON IN BEDROCK WELLS a N--------------- •�--------------------- A • \- • SR,1501 �a-- ABMW-02BR 0.00741 � I I l• � r r / I • j .. -.. -.. -..... -.. r_..-1 4 MW;16BR' LEGEND 0.035 N NV m 0.035 BOLD VALUESN N N 0.017 N NV � W N N N •�• � •�� N N N W-02D° .�••�� U._-_ N N .084--��-•�- ��^ N N \� 1981 � LANDFILL � _ ' MAYO LAKE , $ • A ` J �-� -� `-1 1 IW h X N N X N N N N X N N N N N NOTES: N N N N hhi nr N N g N N N N Idi nrN N g ^ N N N N Ni nrN N g o N N N N hhi nrN N g N N N N N NVMNgorN hJW c ni nrX N N N N N hit Ni npg% N N N g r N N N N N Ni nnp N N N N N N N N N N g W 0 9 9 �x N N N N N N N N N N N ON 0 g g fX w N N N N NN N N N N N N N Nni i IW vohti" N pi i pii vii ranii nuii ndii WN X 1�lp symTerra rrpvN N N Nni c IN NMI m vspEpnmm~ 9 9 �� DUKE ENERGY PROGRESS N N N N I'll ssi N N < N N Ntrtp FIGURE 10-45 ISOCONCENTRATION MAP CHROMIUM (VI) IN BEDROCK WELLS N---------------� A • ' I ♦ / N MW-11BR' .'------------------ LEGEND h ' 1 N N NV h X •J` - cW-04° ' 7 BOLD VALUESN N N r — / <1 (NS) • (1) N N NV hX MW-03BR' MW;16BR' (1) BOLD VALUESN N N MW-14BR' < 1 (NS) < 1 (< 1) , , N N N fW N N 1.41 (1.41) W N N N N N N 1 cW-05° ,SR fspl • _ . • N N N < 1 (NS) cW-02U° . • U . _ . _ N N N MW-O5BR' <1(NS) --�. --•��� ��^ N N N N N N I - GW-O6° ' I .r f MW-09BR ._ fl - LAKE , k -. 3R' NOTES: N N N N hhi nr N N g N N N N fdi nrN N g ^ N N N N Ni nrN N 9 p N N N N hhi nrN N 9 N N N N KV XN N N NN h g N N N N N Ntddi npJpJ N N N g r N N N N N Ni nnp N N N N N N N N N N 9 W 0 9 9 �x N N N N N N N N N N N VN 0 g g Bx w N N N N NN N N N N N N N fdni i IW voh" N pi i pii vii rttnii nuii ndii WN X tip DUKE ENERGY° s mTerra PROGRESS ol rrpvN N N Nni c N N N N a IN NMI m ni ssi N N o vspEpnmm~ N N Nt rt p w 9 9 FIGURE 10-46 ISOCONCENTRATION MAP COBALT IN BEDROCK WELLS N---------------� A • • ----------------------. LEGEND ^°' "` • 300 N N IW h X 300 BOLD VALUESN N N • (300) N N f+YV h X •' " $ MW=03BR (300) BOLD VALUESN N N W-146R' 300 648 (NS)°' y ,MW-16BR' � N hh N fW N N 80 W N N N N N N (12), - SR - / / - CW-05° CW-02D° - - _ . - N N N 1060 (NS) 278 (NS) , / ' U - _ - _ N N N N N N N N N I — CW-064 2040 (NS) MW-07BR' MW-08BR' 339 (223) 2200 (2030) ACTIVE - - - ASH BASIN ...�' LANDFILL � • MW-09BR 3000 (102) .' 0 1 f♦ MAYO LAKE , .� r NOTES: m N N N N hhi nr N N g N N N N Idi nrN N g ^ N N N N Ni nrN N g p N N N N Ni nrN N g N N N N N N Idii N h g N N N N N Ntddi npJpJ N N N g r N N N N N Ni nnp N N N N N N N N N N 9 W 0 9 9 �x N N N N N N N N N N N VN 0 g g fX w N N N N NN N N N N N N N Idni i IW voh" N pi i pii vii rttnii nuii ndii WN X tip DUKE ENERGY., s mTerra PROGRESS rrpvN N N Nni c N N N N a IN NMI m ni ssi N N o vspEpnmm~ N N Nt rt p w 9 9 FIGURE 10-47 ISOCONCENTRATION MAP IRON IN BEDROCK WELLS N---------------� •'--------------------- h • A , • �J CW-04° < 5 (NS) . ..: y ' MV1 73 544 (543) MW-O5BR' CW OCTIKIC u . .. . .. . .. . .. . .. W It- . SR,150 1 LEGEND 50 N N fW h X 50 BOLD VALUESN N N (50) N N h1V h X V=16BR' (50) BOLD VALUESN N N (25) 1 1 N hh N Kry N N � W N N N N N N •�• N } .•�- N N N N N N �. .•�• ��^ N N N N N N CW-064 1450 (NS) .�y MW-07BR' .. nco—T ol3 A . 981 ND LANDFILL � J MW-096R X �' MAYO LAKE FEW0BR'95�4) ♦ r NOTES: N N N N hhi nr N N g N N N N Idi nrN N g ^ N N N N Ni nrN N g p N N N N hhi nrN N g N N hh N N N NiN hg N N N N N Ntddi npJpJ N N N g r N N N N N hhi nnp N N N N N N N N N N 9 W 0 9 9 �x N N N N N N N N N N N VN 0 g g Bx w N N N N NN N N N N N N N Idni i IW voh" N pi i pii vii rttnii nuii ndii WN X tip DUKE ENERGY., s mTerra PROGRESS rrpvN N N Nni c N N N N a IN NMI m ni ssi N N o vspEpnmm~ N N Nt rt p w 9 9 FIGURE 10-48 ISOCONCENTRATION MAP MANGANESE IN BEDROCK WELLS N---------------� A • 4 MW-16BR' 8.7� LEGEND 6.5-8.5 TOTAL pH CONCENTRATION (S.U.) 6.5-8.5 BOLD VALUES INDICATE AN EXCEEDANCE5 NORTH CAROLINA2L CONTOUR (DASHED WHERE ESTIMATED) (HASH MARKS INDICATE DIRECTION OF EXCEEDANCES) • MONITORING WELL • ACTIVE ASH BASIN BOUNDARY ASH BASIN COMPLIANCE BOUNDARY - . �— . • f �^ DUKE ENERGY PROGRESS MAYO PLANT SITE BOUNDARY > - STREAM 1981 LANDFILL s ♦ ' MW-09BR 6.5 � • CW-01 D4 6.8 , - - 1 Cam.. ♦ `♦' � MAYO LAKE my jOQ 79 ' .v NOTES: CONCENTRATIONS ARE FROM THE MARCH 2O15 SAMPLING EVENT. s CONCENTRATIONS ARE FROM THE MAY 2015 SAMPLING EVENT. 8 CONCENTRATIONS ARE FROM THE JUNE 2015 SAMPLING EVENT. 4 CONCENTRATIONS ARE FROM THE JULY 2015 SAMPLING EVENT. 5 THE NORTH CAROLINA 2L RANGE FOR pH IS 6.5 TO 8.5 S.U.. 6 SITE AERIAL ORTHOPHOTOGRAPHY IS DATED APRIL 17, 2014. IT WAS OBTAINED FROM WSP. 7 ADDITIONAL OFFSITE AERIAL ORTHOPHOTOGRAPHY IS DATED 2012. IT WAS OBTAINED FROM THE INC CENTER FOR GEOGRAPHIC INFORMATION AND ANALYSIS. (http://services.nconemap.gov/) 8 PARCEL BOUNDARY WAS OBTAINED FROM THE INC CENTER FOR GEOGRAPHIC INFORMATION AND ANALYSIS. (hftp://services.nconemap.gov/) 9 DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE COORDINATE SYSTEM RIPS 3200 (NAD8312011). GRAPHIC SCALE 400 0 400 800 1,200 1,600 2,000 (IN FEET) _ DUKE a ENERGY s mTerra PROGRESS 148 RIVER STREET, SUITE 220, MAYO STEAM ELECTRIC POWER PLANT a GREENVILLE, SC 29601 10660 BOSTON RD 864-421-9999 ROXBORO, NORTH CAROLINA 27574 LL www.synterracorp.com a FIGURE 10-49 ISOCONCENTRATION MAP pH IN BEDROCK WELLS N---------------� h -------------------- • Jy - < ... x _ MW-03BR' / • M1N=14BR' + < 0.2 (NS) • < 0.2 (<0.2) . . �SR;1 ' M_0W-O5BR� CW5°1 _. .. .. _ 7.., 5p. LEGEND 0.2 N N f+YV h X 0.2 BOLD VALUESN N N (0.2) N N fW h X MW;16B R' (0.2) BOLD VALUESN N N < 0.2 (< 0.2) N N N NV N � W N N N N N N •�� N •�� � N N N a ._.•��• N N N �) �.�—.•�� ��^ N N N N N N J h.. M.1 R 0.2) -1 .f `♦' � MAYO LAKE • .v NOTES: N N N N hhi nr N N g N N N N fdi nrN N g ^ N N N N Ni nrN N g o N N N N Ni nrN N g N N N N RVM N N Ngt hg N N N N N Nt Ni npg% N N N g r N N N N N Ni nnp N N N N N N N N N N g W 0 9 9 �x N N N N N N N N N N N ON 0 9 g fX w N N N N NN N N N N N N N Nni i IVV vohti" N pi i pii vii rttnii nuii ndii WN X tip DUKE ENERGY., s mTerra PROGRESS rrpvN N N Nni c N N N N a IN NMI m ni ssi N N o vspEpnmm~ N N Nt rt p w 9 9 FIGURE 10-50 ISOCONCENTRATION MAP THALLIUM IN BEDROCK WELLS N-------------- A / mIAI rr a SR.1501 - 1'l-- I ' CW-02DU 250 - ..... ' 190 1961 LANDFILL ,r � a MW-09BR .- 220, ABMW-02BR' 370 CW-01 D° 200 ' , AIBM W-04BR' 370 X ' MAYO LAKE LEGEND 500 TOTAL DISSOLVED SOLIDS CONCENTRATION (mg/L) 500 BOLD VALUES INDICATE AN EXCEEDANCE5 NORTH CAROLINA2L CONTOUR (DASHED WHERE ESTIMATED) (HASH MARKS INDICATE DIRECTION OF LOWER CONCENTRATIONS) MONITORING WELL ACTIVE ASH BASIN BOUNDARY ASH BASIN COMPLIANCE BOUNDARY �^ DUKE ENERGY PROGRESS MAYO PLANT SITE BOUNDARY - STREAM NOTES: 1 CONCENTRATIONS ARE FROM THE MARCH 2O15 SAMPLING EVENT. 2 CONCENTRATIONS ARE FROM THE MAY 2015 SAMPLING EVENT. 3 CONCENTRATIONS ARE FROM THE JUNE 2015 SAMPLING EVENT. ° CONCENTRATIONS ARE FROM THE JULY 2015 SAMPLING EVENT. THE NORTH CAROLINA2L FOR TOTAL DISSOLVED SOLIDS IS 500 mg/L. 6 SITE AERIAL ORTHOPHOTOGRAPHY IS DATED APRIL 17, 2014. IT WAS OBTAINED FROM WSP. 7 ADDITIONAL OFFSITE AERIAL ORTHOPHOTOGRAPHY IS DATED 2012. IT WAS OBTAINED FROM THE INC CENTER FOR GEOGRAPHIC INFORMATION AND ANALYSIS. (http://services.nconemap.gov/) 8 PARCEL BOUNDARY WAS OBTAINED FROM THE INC CENTER FOR GEOGRAPHIC INFORMATION AND ANALYSIS. (hftp://services.nconemap.gov/) 9 DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE COORDINATE SYSTEM RIPS 3200 (NAD8312011). GRAPHIC SCALE 400 0 400 800 1,200 1,600 2,000 (IN FEET) tT i DUKE ENERGY., s mTerra PROGRESS 148 RIVER STREET, SUITE 220, MAYO STEAM ELECTRIC POWER PLANT GREENVILLE, SC 29601 10660 BOSTON RD o 864-421-9999 ROXBORO, NORTH CAROLINA 27574 w www.synterracorp.com Q FIGURE 10-51 ISOCONCENTRATION MAP TOTAL DISSOLVED SOLIDS IN BEDROCK WELLS N---------------� A • , , M W-71 BR' 2.69 (2.39) ................ LEGEND 0.3 N N NV h X 0.3 BOLD VALUESN N N (0.3) N N NV h X tMW-16R" (0.3) BOLD VALUESN N N 2.68) m6mmo6m N N N NV N N W N N N N N N •�• N •�� � N N N •�� �._._-1 N N N g) ��.•�•�_-�^ N N N N N N + F-' I — < 0.3 Q 0.3) .. — . . 0.3 _:;Ooo • MW-096R 1• LAKE , h- �A- \� f NOTES: m N N N N hhi nr N N g N N N N fdi nrN N g ^ N N N N Ni nrN N g o N N N N hhi nrN N g N N N N NV M N N Ng) hg N N N N N hit Ni npg% N N N g r N N N N N Ni nnp N N N N N N N N N N g W 0 9 9 �x N N N N N N N N N N N ON 0 9 g BK w N N N N NN N N N N N N N fdni i NV vohti" N pi i pii vii rttnii nuii ndii WN X tip DUKE ENERGY.,. symTerra PROGRESS rrpvN N dN Nni c N N N N a (N Nmi m M ssi N N o vspEpnmm~ N N Nt rt p w 9 9 a m N N N InWnl h,E N N N In:m �'#._'N N 1N QJ F FIGURE 10-52 "`- ISOCONCENTRATION MAP l _ VANADIUM IN BEDROCK WELLS *A&Mn ti ABMW-013 � I CONSTITUENT RESULT B 4560 Ca 100 CI 16 t. • pH 7.6 ��•••,���� � SO4 5.8 Sp Cond 1009 �\ TDS 540 t s' r� . i , � r e � s* .� •/ - •"� n - �f - r t 3R• 1400 SR•1328 P...�_ siQ�3?8 SRl-OV. !i �3 SR-1500 gQ SR.1329 / U J h J ABMW-023 CONSTITUENT RESULT B 9200 Ca 82.2 CI 12 pH 7.8 SO4 36 Sp Cond 684 TDS 450 7so? F I r , ABMW-033 CONSTITUENT RESULT B 1940 Ca 54.5 CI 76 pH 6.6 SO4 42 Sp Cond 527 TDS 350 . "',' ��♦ �pA A TIVE ANDFILL f , 1 AS BASIN v M r ABMW-043 z oQ CONSTITUENT RESULT • �� B 4930 Ca 120 r CI 11 -� A 4 pH 7.5 SO4 38 r Sp Cond 818 ����' i♦+-� TDS 520 +� -lie , 1 N too• = 1.J LEGEND MONITORING WELL Q ACTIVE ASH BASIN ASH BASIN COMPLIANCE BOUNDARY DUKE ENERGY PROGRESS MAYO PLANT SITE BOUNDARY — — — — DITCH STREAM Constituent Abbreviation Units Boron B µg/L Calcium Ca mg/L Chloride CI mg/L Specific Conductance Sp Cond µmhos/cm pH pH SU Sulfate SO4 mg/L Total Dissolved Solids TDS mg/L NOTES: CONCENTRATIONS SHOWN ARE FROM THE APRIL 2015 SAMPLING EVENT. Z CONCENTRATIONS SHOWN ARE FROM THE MAY 2015 SAMPLING EVENT. 3 CONCENTRATIONS SHOWN ARE FROM THE JUNE 2015 SAMPLING EVENT. 4 CONCENTRATIONS SHOWN ARE FROM THE JULY 2015 SAMPLING EVENT. SSITE AERIAL ORTHOPHOTOGRAPHY IS DATEDAPRIL 17, 2014. IT WAS OBTAINED FROM WSP 6ADDITIONAL OFFSITE AERIAL ORTHOPHOTOGRAPHY IS DATED 2012. IT WAS OBTAINED FROM THE NC CENTER FOR GEOGRAPHIC INFORMATION ANDANALYSIS AT (http://services.nconemap.gov/) 3 PARCEL BOUNDARY WAS OBTAINED FROM THE NC CENTER FOR GEOGRAPHIC INFORMATION AND ANALYSIS AT (http://servioes.nconemap.gov/) e DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE COORDINATE SYSTEM FIPS 3200 (NAD83/2011). GRAPHIC SCALE 1,000 0 1,000 2,000 3,000 4,000 5,000 (IN FEET) SR•1507tip synTerra 148 RIVER STREET, SUITE 220, L GREENVILLE, SC 29601 864421-9999 www.synterracorp.com w 4 DUKE ENERGY PROGRESS MAYO STEAM ELECTRIC POWER PLANT 10660 BOSTON RD ROXBORO, NORTH CAROLINA27574 FIGURE 10-53 CCR RULE DETECTION MONITORING s� - ND. CONSTITUENT MAP i� '�, ASH PORE WATER MW-03' CONSTITUENT RESULT B 847 pH 5.7 TDS 190 MW-1 ISS3 CONSTITUENT RESULT B <50 Ca 9.57 CI 13 pH 6.0 SO4 5.3 Sp Cond TDS 144.3 100 - - / SR.1501' 1981 � 1 • S, -n+ �` !� \ sR Aso ACTIVE LANDFILL f , H BASIN r ♦ V M 19 r♦4 • 41 r y� I t . 401- \� r ABMW-03S3 CONSTITUENT RESULT B 1100 Ca 4.78 CI 6.9 pH 5.2 SO4 <0.1 Sp Cond 136.5 TDS 110 / .. MW-12S3 t � 4. CONSTITUENT RESULT 11 B <50 Ca 2.36 CI 3.1 _ k �1 pH 5.7 SO4 1.9 MR Sp Cond 54.8 TDS 50 SR-1500 gQ SR.1329 s1,7so? 2jkSR-i501 .J LEGEND MONITORING WELL Q ACTIVE ASH BASIN ASH BASIN COMPLIANCE BOUNDARY r DUKE ENERGY PROGRESS MAYO PLANT SITE BOUNDARY — - — - DITCH STREAM Constituent Abbreviation Units Boron B µg/L Calcium Ca mg/L Chloride CI mg/L Specific Conductance Sp Cond µmhos/cm pH pH SU Sulfate SO4 mg/L Total Dissolved Solids TDS mg/L NOTES: CONCENTRATIONS SHOWN ARE FROM THE APRIL 2015 SAMPLING EVENT. CONCENTRATIONS SHOWN ARE FROM THE MAY 2015 SAMPLING EVENT. a CONCENTRATIONS SHOWN ARE FROM THE JUNE 2015 SAMPLING EVENT. 4 CONCENTRATIONS SHOWN ARE FROM THE JULY 2015 SAMPLING EVENT. SSITE AERIAL ORTHOPHOTOGRAPHY IS DATEDAPRIL 17, 2014. IT WAS OBTAINED FROM WSP. 6ADDITIONAL OFFSITE AERIAL ORTHOPHOTOGRAPHY IS DATED 2012. IT WAS OBTAINED FROM THE NC CENTER FOR GEOGRAPHIC INFORMATION ANDANALYSIS AT (http://services.nconemap.gov/) 7 PARCEL BOUNDARY WAS OBTAINED FROM THE NC CENTER FOR GEOGRAPHIC INFORMATION AND ANALYSIS AT (http://servioes.nconemap.gov/) e DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE COORDINATE SYSTEM FIPS 3200 (NAD83/2011). GRAPHIC SCALE 1,000 0 1,000 2,000 3,000 4,000 5,000 (IN FEET) 141P synTerra 148 RIVER STREET, SUITE 220, GREENVILLE, SC 29601 864421-9999 www.synterracorp.com 4 DUKE ENERGY PROGRESS MAYO STEAM ELECTRIC POWER PLANT 10660 BOSTON RD ROXBORO, NORTH CAROLINA27574 FIGURE 10-54 CCR RULE DETECTION MONITORING CONSTITUENT MAP SURFICIAL AQUIFER . -3411 MW-021 CONSTITUENT RESULT B <50 pH TDS 5.8 200 CW-034 CW-024 CONSTITUENT RESULT CONSTITUENT B RESULT 804 B <50 Ca 66.6 Ca CI 17.6 54 CI 100 pH 6.5 pH 5.1 SO4 15 SO4 49 Sp Cond 645 Sp Cond 285.E TDS 440 TDS 210 h J A ACTIVE W ASH BASIN A ' .` �. u�a . i �o • h .1 y f ul i r e � I n ABMW-04D3 CONSTITUENT RESULT B 5090 Ca CI 143 11 pH 6.6 SO4 19 Sp Cond 1174 TDS 680 BG-024 CONSTITUENT RESULT B <50 Ca CI 56.1 30 pH 6.5 SO4 5.1 Sp Cond 623 TDS 370 w-'. IV I. SR.1329 !A .. gR lh;.-' SK•13z8 '4po SQ`F"'e SR.1 gt , - b � � a h SR-1500 gQ SR'so? MW-16D3 CONSTITUENT RESULT B <50 25.6 Ca CI 8.8 pH 7.1 7.7 SO4 221 Sp Cond 160 - TDS ZZ1111"Ir " . _ � SR-15p1 MW-07h.d- CONSTITUENT B Ca 1 pH 78 6.4 SO4 9 Sp Cond 668 TDS 390 �♦ S°A r 1 1981 .• , LANDFILL • •4 1♦ v M MW-12D3 CONSTITUENT RESULT B <50 Ca 12.6 CI 4 pH 6.2 SO4 0.96 Sp Cond 135.7 TDS 120 �IPI s� CW-014 CONSTITUENT RESULT B <50 Ca 10.9 CI 23 pH 5.5 SO4 9.5 Sp Cond TDS 182 150 LEGEND Z MONITORING WELL ® ACTIVE ASH BASIN 1: _ : =r ASH BASIN COMPLIANCE BOUNDARY C :: ] DUKE ENERGY PROGRESS MAYO PLANT SITE BOUNDARY — - — DITCH STREAM Constituent Abbreviation Units Boron B µg/L Calcium Ca mg/L Chloride CI mg/L Specific Conductance Sp Cond µmhos/cm pH pH SU Sulfate SO4 mg/L Total Dissolved Solids TDS MR/L NOTES: CONCENTRATIONS SHOWN ARE FROM THE APRIL 2015 SAMPLING EVENT. Z CONCENTRATIONS SHOWN ARE FROM THE MAY 2015 SAMPLING EVENT. 3 CONCENTRATIONS SHOWN ARE FROM THE JUNE 2015 SAMPLING EVENT. 4 CONCENTRATIONS SHOWN ARE FROM THE JULY 2015 SAMPLING EVENT. SSITE AERIAL ORTHOPHOTOGRAPHY IS DATEDAPRIL 17, 2014. IT WAS OBTAINED FROM WSP. 6ADDITIONAL OFFSITE AERIAL ORTHOPHOTOGRAPHY IS DATED 2012. IT WAS OBTAINED FROM THE NC CENTER FOR GEOGRAPHIC INFORMATION ANDANALYSIS AT (http://services.nconemap.gov/) 3 PARCEL BOUNDARY WAS OBTAINED FROM THE NC CENTER FOR GEOGRAPHIC INFORMATION AND ANALYSIS AT (http://servioes.nconemap.gov/) e DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE COORDINATE SYSTEM FIPS 3200 (NAD83/2011). GRAPHIC SCALE 1,000 0 1,000 2,000 3,000 4,000 5,000 (IN FEET) 114rip synTerra 148 RIVER STREET, SUITE 220, GREENVILLE, SC 29601 864421-9999 www.synterracorp.com DUKE ENERGY PROGRESS MAYO STEAM ELECTRIC POWER PLANT 10660 BOSTON RD ROXBORO, NORTH CAROLINA27574 FIGURE 10-55 CCR RULE DETECTION MONITORING CONSTITUENT MAP TRANSITION ZONE MW-05BR' CONSTITUENT RESULT B <50 Ca 95.9 CI 62 pH 7.1 SO4 3.8 Sp Cond 491.1 TDS 380 MW-13BR3 CONSTITUENT RESULT B <50 Ca 75.2 CI 46 pH SO4 7.2 18 Sp Cond 580 TDS 370 BG-014 CONSTITUENT RESULT B <50 Ca 13.1 CI 11 pH 5.6 SO4 0.32 Sp Cond 151 TDS 130 SR 1828 SR,1400 MW-11 BR3 CONSTITUENT RESULT B <50 Ca 49.6 CI 16 pH 8.1 SO4 14 Sp Cond 381.5 TDS 250 '�28 SRA�sr." c9 �O J CW-044 CONSTITUENT RESULT B <50 Ca 11.6 CI 6.4 pH 5.9 SO4 19 Sp Cond 162 TDS 160 ABMW-02BR3 CONSTITUENT RESULT B <50 Ca 81.5 CI 27 pH 7.2 SO4 12 Sp Cond 631 TDS 370 MW-03BR' CONSTITUENT RESULT B <50 Ca 145 CI 160 SO4 9.4 TDS 660 ACTIVE ASH BASIN MW-16BR3 CONSTITUENT RESULT B <50 Ca 22.5 CI 7 pH 8.7 SO4 12 Sp COnd 238.7 TDS 170 CW-02D4 CONSTITUENT RESULT B 363 Ca 36.6 CI 42 pH 6.1 SO4 49 Sp Cond 358.8 TDS 250 Ji i SR-1501' ' r 1981 NDFILL MW-10BR' CONSTITUENT RESULT B <50 Ca 36.8 CI 23 pH 7.9 SO4 83 Sp Cond 345.5 TDS 330 ABMW-04BR3 CONSTITUENT RESULT B <50 Ca 85.3 CI 4.8 pH 7.4 SO4 80 Sp Cond 556 TDS 370 CW-064 CONSTITUENT RESULT B <50 Ca 108 CI 89 pH 6.7 SO4 47 Sp Cond 890 TDS 560 5� 01 v o ` MW-07BR3 co CONSTITUENT RESULT ' B <50 Ca 57.3 AP, MW-08BR3 CONSTITUENT RESULT B <50 Ca 91.5 CI 120 pH 6.6 SO4 33 Sp Cond 858 TDS 550 LEGEND Q� MONITORING WELL „i�ACTIVEASH BASIN _ ;ASH BASIN COMPLIANCE BOUNDARY r. : J DUKE ENERGY PROGRESS MAYO PLANT SITE BOUNDARY - - - DITCH STREAM Constituent Abbreviation Units Boron B µg/L Calcium Ca mg/L Chloride Cl mg/L Specific Conductance Sp Cond µmhos/cm pH pH SU Sulfate SO4 mg/L Total Dissolved Solids TDS mg/L $ `r CI 15 rOQ v p H NOTES: o 7.4 1 CONCENTRATIONS SHOWN ARE FROM THE APRIL 2015 SAMPLING EVENT. SO4 1.6 a Sp Cond 469.5 2 CONCENTRATIONS SHOWN ARE FROM THE MAY 2015 SAMPLING EVENT.ol ? TDS 270 3 CONCENTRATIONS SHOWN ARE FROM THE JUNE 2015 SAMPLING EVENT. MW-04' 4 CONCENTRATIONS SHOWN ARE FROM THE JULY 2015 SAMPLING EVENT. o CONSTITUENT RESULT MW-096R3 5STTE AERIAL ORTHOPHOTOGRAPHY IS DATED APRIL 17, 2014. IT WAS OBTAINED FROM WSP. m B <50 1 CONSTITUENT RESULT sADDITIONAL OFFSITE AERIAL ORTHOPHOTOGRAPHY IS DATED 2012. IT WAS OBTAINED FROM THE NC o pH 6.3 CENTER FOR GEOGRAPHIC INFORMATION AND ANALYSIS AT (http://services.nconemap.gov/) <50 B TDS 190 22.6 r Ca 7 PARCEL BOUNDARY WAS OBTAINED FROM THE NC CENTER FOR GEOGRAPHIC INFORMATION AND 10 ANALYSIS AT (http://services.neonemap.gov/) 2 CI 16 81 pH 6.3 e DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE COORDINATE1. d SYSTEM RIPS 3200 (NAD8312011). CW-01 D4 CONSTITUENT RESULT B <50 Ca 45.3 CI 10 pH 6.8 SO4 4.1 Sp Cond 348 TDS 200 r SO4 8.9 Sp Cond 226.4 GRAPHIC SCALE TDS 220 1,000 0 1,000 2,000 3,000 4,000 5,000 0 + + a (IN FEET) NONE DUKE ENERGY bynTerra PROGRESS 148 RIVER STREET, SUITE 220, MAYO STEAM ELECTRIC POWER PLANT L GREENVILLE, SC 29601 10660 BOSTON RD 864A21-9999 ROXBORO, NORTH CAROLINA27574 w www.synterracorp.com FIGURE 10-56 CCR RULE DETECTION MONITORING CONSTITUENT MAP BEDROCK WELLS ABMW-023 CONST RESULT Al 61 As 1020 Ba 173 Be 1.42 Cd <1 Cr <1 Cu <0.001 Fe 356 Hg <0.05 Mn 1110 MO 1830 Pb <1 S2 <0.1 Sb <1 Se <1 SO4 36 TI <0.2 V 3.53 11 1981 LANDFILL ABMW-043 CONST RESULT ' Al 71 As 499 Ba 448 Be <1 Cd <1 Cr <1 Cu <0.001 Fe 940 Hg <0.05 Mn 641 MO 428 3 . ( Pb <1 o^ o S2 <0.2 D: Sb <1 y Se <1 4 � SO4 38 TI <0.2 V 2.84 S�'sod `'124! ,A SR4400 SR-1328 sR�3?8 N w � o 'k � J h SR-1322 j ABMW-033 CONST RESULT Al 119 As 193 Ba 200 Be <1 Cd <1 Cr <1 Cu <0.001 Fe 3890 Hg <0.05 Mn 451 MO 75.6 Pb <1 S2 <0.2 Sb <1 Se <1 SO4 42 TI 0.289 V 0.68 SR•1507 LEGEND Q� MONITORING WELL f ACTIVE ASH BASIN . _._. ASH BASIN COMPLIANCE BOUNDARY DUKE ENERGY PROGRESS MAYO PLANT SITE BOUNDARY - DITCH STREAM Constituent Abbreviation Units Aluminum AI µg/L Antimony Sb µg/L Arsenic As µg/L Barium Ba µg/L Beryllium Be µg/L Cadmium Cd µg/L Chromium Cr µg/L Copper Cu mg/L Iron Fe µg/L Lead Pb µg/L Manganese Mn µg/L Mercury Hg µg/L Molybdenum Mo µg/L Selenium Se µg/L Sulfate SO4 mg/L Sulfide S2 mg/L Thallium TI µg/L Vanadium V µg/L NOTES: i CONCENTRATIONS SHOWN ARE FROM THE APRIL2015 SAMPLING EVENT. 2 CONCENTRATIONS SHOWN ARE FROM THE MAY 2015 SAMPLING EVENT. CONCENTRATIONS SHOWN ARE FROM THE JUNE 2015 SAMPLING EVENT. CONCENTRATIONS SHOWN ARE FROM THE JULY 2015 SAMPLING EVENT. 'SITE AERIAL ORTHOPHOTOGRAPHY IS DATED APRIL 17, 2014. IT WAS OBTAINED FROM WSP. e ADDITIONAL OFFSITE AERIAL ORTHOPHOTOGRAPHY IS DATED 2012. IT WAS OBTAINED FROM THE NC CENTER FOR GEOGRAPHIC INFORMATION AND ANALYSIS AT (http:/1services.n00nemap.gov1) 7 PARCEL BOUNDARY WAS OBTAINED FROM THE NC CENTER FOR GEOGRAPHIC INFORMATION AND ANALYSIS AT (httpl/servioes.noonemap.govo s DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE COORDINATE SYSTEM FIPS 3200 (NAD8312011). GRAPHIC SCALE 1,000 0 1,000 2,000 3,000 4,000 5,000 (IN FEET) 44�ENERGY DUKE synTerra PROGRESS 148 RIVER STREET, SUITE 220, MAYO STEAM ELECTRIC POWER PLANT GREENVILLE, SC 29601 10660 BOSTON RD 864421-9999 ROXBORO, NORTH CAROLINA27574 www.synterracorp.com - FIGURE 10-57 >> CCR RULE ASSESSMENT MONITORING fsR1y12 SR�s� CONSTITUENT MAP :r. 2 ASH PORE WATER , w1. L M� MW-12S3 CONST RESULT ' I Al 292 �3j4 As <1 Ba 24 Be <1 ABMW-03S3 CONST RESULT Al 30 As 1.04 Ba 25 Be <1 Cd <1 Cr <1 Cu <0.001 Fe 2630 Hg <0.05 Mn 478 MO <1 Pb <1 S2 <0.1 Sb <1 Se <1 SO4 <0.1 TI <0.2 V <0.3 Cd <1 Cr 1.61 Cu <0.001 Fe 295 Hg <0.05 Mn 267 ' 11 MO <1 Pb <1 �J p S2 <0.1 Sb <1 7p?,$e - V' <1 SO4 1.9 TI <0.2 V 0.403 SR.1500 , � SR 1329 a 3?8 j SR4400 SR-1328 s .43 8 N w � o J SR-1322 j MW-03' CONST RESULT As <1 Ba 56 Fe 34 S, Mn 880 Sb <1 TI <0.2 V t� MW-16S3 CONST RESULT AI 17 As <1 Ba 46 Be <1 Cd <1 Cr <1 Cu 0.00102 Fe 860 Hg <0.05 Mn 260 MO 1.24 Pb <1 S2 <0.1 Sb <1 Se <1 SO4 5.3 ' TI <0.2 - - hoN, - V 0.303 r op 01- SR-1504i6m_ ACTIVE SH BASIN 1981 .160 LANDFILL f is Cl) too 4� r `69 K- e , r LAKE S94 sR lg�? SR-1507 LEGEND Q� MONITORING WELL �fy ACTIVE ASH BASIN ASH BASIN COMPLIANCE BOUNDARY DUKE ENERGY PROGRESS MAYO PLANT SITE BOUNDARY - DITCH STREAM Constituent Abbreviation Units Aluminum AI µg/L Antimony Sb µg/L Arsenic As µg/L Barium Ba µg/L Beryllium Be µg/L Cadmium Cd µg/L Chromium Cr µg/L Copper Cu mg/L Iron Fe µg/L Lead Pb µg/L Manganese Mn µg/L Mercury Hg µg/L Molybdenum Mo µg/L Selenium Se µg/L Sulfate SO4 mg/L Sulfide S2 mg/L Thallium TI µg/L Vanadium V µg/L NOTES: i CONCENTRATIONS SHOWN ARE FROM THE APRIL2015 SAMPLING EVENT. 2 CONCENTRATIONS SHOWN ARE FROM THE MAY 2015 SAMPLING EVENT. CONCENTRATIONS SHOWN ARE FROM THE JUNE 2015 SAMPLING EVENT. CONCENTRATIONS SHOWN ARE FROM THE JULY 2015 SAMPLING EVENT. 'SITE AERIAL ORTHOPHOTOGRAPHY IS DATED APRIL 17, 2014. IT WAS OBTAINED FROM WSP. e ADDITIONAL OFFSITE AERIAL ORTHOPHOTOGRAPHY IS DATED 2012. IT WAS OBTAINED FROM THE NC CENTER FOR GEOGRAPHIC INFORMATION AND ANALYSIS AT (http:/1services.n00nemap.gov1) 7 PARCEL BOUNDARY WAS OBTAINED FROM THE NC CENTER FOR GEOGRAPHIC INFORMATION AND ANALYSIS AT (httpl/servioes.noonemap.govo 9 DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE COORDINATE SYSTEM FIPS 3200 (NAD831'2011). GRAPHIC SCALE 1,000 0 1,000 2,000 3,000 4,000 5,000 (IN FEET) 44�ENERGY DUKE synTerra PROGRESS 148 RIVER STREET, SUITE 220, MAYO STEAM ELECTRIC POWER PLANT GREENVILLE, SC 29601 10660 BOSTON RD 864421-9999 ROXBORO, NORTH CAROLINA27574 www.synterracorp.com FIGURE 10-58 CCR RULE ASSESSMENT MONITORING s CONSTITUENT MAP - 2 SURFICIAL AQUIFER I e SR4400 SR-1322 MW-16D3 CW-034 CONST RESULT CONST RESULT Al 102 Al 89 As <1 As <1 Ba 13 Ba 19 Be I <1 Be <1 Cd <1 Cd <1 Cr <1 Cr <5 Cu <0.001 Fe 87 Cu <0.005 f ,Is e,-,wk Fe 71 �► :1_--t�i Hg <0.05 Hg <0.05, - ((/�+{/"� Mn 269 N Mn <5 JA Mo 10.1 CW Mo <1 Pb <1 CONST Al 47. ., Sb <1 Sb <1 As s Se <1 Ba .✓ Se <1 SO4 15 SO4 7.7 Be y r .. .. TI <0.2 .. .. �♦ o .. TI <0.2 �� .. _ Cd <1 N ♦ y 617 V 1.41 Cr <5 V 0.o'o I ,. J T . ! - .. 1 Cu <0.005 S,Q 13 � .150 Fe <10 MW-021 ?4 .� �. Hg <0.05 SR-1504 L . 1 - CONST RESULT Mn 393 4411 As <1 j ACTIVE - ABMW-04D3 Ba 55 U) ASH BASIN 1981 - • �� ; �'� Pb <1 5� LANDFILL CONST RESULT Fe 756 �' ' •� Sb <1 h Al 199 Mn 833 ��+, p `,� MW-07D3 Se <1 y4 As 140 Sb <1 \ CONST RESULT SO4 49 Ba 755 TI <0.2 �Al 147 TI <0.2 Be <1 V 1.68 As <1 V <0.3 Cd <1 .♦ J Ba 24 Cr <1 ♦♦ CW-014 Be <1 Cu <0.001 Fe 28300 ♦� c' CONST RESULT + Cd <1 CONST s ♦• v� . Cr �Q Hg <0.05 r Al 35 + Cu <0.001 �r0 Mn 3640 . 4 ` + 1 As <1 Fe 69 BG-02 Ba <5 Mo 269 r .� t Hg <0.05 Pb <1 I CONST RESULT ! Be <1 S2 <0.5 ` Al 193 - � - Cd <1 •./ Mn 188 Mo 1.35 Sb 3.68 As <1 (� ♦ - I Cr <5♦� Pb <1 Ba 54 ao Cu <0.005 Se <1 ' ` �� o o . S2 <0.1 � 1 SO4 19 Be <1 r y � Fe 31 Sb <1 Cd <1 J (0 Hg <0.05 V 233.3 Cr <5 MW-12D3 Mn 6 �• se <1 SO4 9 Cu <0.005 CONST RESULT +,�+ • Mo <1 %%r - TI <0.2 Fe 467 9 SR•1500 Al 184 �� �-• Pb <1 1507 �►'.. SR- Hg <0.05 '132 As <1 Sb <1 r �� V 0.798 11^,• Mn 135 Ba 26 Se <1 V }. •� Mo <1 Be <1 SO4 9.5 I 1 Pb <1 Cd <1 S�X54 TI <0.2 Sb <1 Cr <1 V 0.543 Se <1 Cu <0.001 SO4 5.1 Fe 326 .. -�7�, Hg <0.05 1 1, SR-1328 SR70, 1. S�V 5.88 Mo Mn 675 N Pb <1 `,- S2 <0.1 N 'r w � � o Sb 1.63 r _ J Se <1 ` SO4 0.96 5 T _ TI <0.2 SR-1512 SR-1512 V 0.719 0 ss [r S11-15 2 cn sp J SR-1512 rs>2 SR1512 S47S'? ' LEGEND Q� MONITORING WELL ACTIVE ASH BASIN ASH BASIN COMPLIANCE BOUNDARY DUKE ENERGY PROGRESS MAYO PLANT SITE BOUNDARY - - - DITCH STREAM Constituent Abbreviation Units Aluminum Al µg/L Antimony Sb µg/L Arsenic As µg/L Barium Ba µg/L Beryllium Be µg/L Cadmium Cd µg/L Chromium Cr µg/L Copper Cu mg/L Iron Fe µg/L Lead Pb µg/L Manganese Mn µg/L Mercury Hg µg/L Molybdenum Mo µg/L Selenium Se µg/L Sulfate SO4 mg/L Sulfide S2 mg/L Thallium TI µg/L Vanadium V µg/L NOTES: 'm I CONCENTRATIONS SHOWN ARE FROM THE APRIL 2015 SAMPLING EVENT. 2 CONCENTRATIONS SHOWN ARE FROM THE MAY 2015 SAMPLING EVENT. w 3 CONCENTRATIONS SHOWN ARE FROM THE JUNE 2015 SAMPLING EVENT. a m a CONCENTRATIONS SHOWN ARE FROM THE JULY 2015 SAMPLING EVENT. o 0 'SITE AERIAL ORTHOPHOTOGRAPHY IS DATED APRIL 17, 2014. IT WAS OBTAINED FROM WSP. c 'ADDITIONAL OFFSITE AERIAL ORTHOPHOTOGRAPHY IS DATED 2012. IT WAS OBTAINED FROM THE NC d CENTER FOR GEOGRAPHIC INFORMATION AND ANALYSIS AT (http://services.neonemap.gov/) S m 7 PARCEL BOUNDARY WAS OBTAINED FROM THE NC CENTER FOR GEOGRAPHIC INFORMATION AND ANALYSIS AT (http://services.neonemap.gov/) d w` e DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE COORDINATE x SYSTEM RIPS 3200 NAD83/2011 . 9 GRAPHIC SCALE a 1,000 0 1,000 2,000 3,000 4,000 5,000 (IN FEET) tT 4 DUKE ENERGY symTerm PROGRESS 148 RIVER STREET, SUITE 220, MAYO STEAM ELECTRIC POWER PLANT GREENVILLE, SC 29601 10660 BOSTON RD 864421-9999 ROXBORO, NORTH CAROLINA27574 www.synterracorp.com DRAWN BY: A. ROBINSON IDATE: 8/27/2015 FIGURE 10-59 CCR RULE ASSESSMENT MONITORING CONSTITUENT MAP TRANSITION ZONE N CW-044 MW-03BR' MW-16BR3 CW-064 LEGEND MW-14BR' CONST RESULT CONST. RESULT CONST RESULT CONST RESULT A CONST RESULT Al 200 AI 118 Al 88 AI 57 MONITORING WELL Al 589 As <1 As Ba <1 46 As 2.05 As <1 ACTIVE ASH BASIN As <1 Ba 25 Be <1 Ba 11 Ba 48 Be <1 Be <1 Be <1 .. _ . _ - ASH BASIN COMPLIANCE BOUNDARY Ba 30 Cd <1 Be <1 Cd <1 Cr <1 Cd <1 Cd <1 �i DUKE ENERGY PROGRESS MAYO PLANT SITE BOUNDARY Cd I <1 Cr <5 Cu <0.001 Cr <1 Cr <5 _ _ - _ _ DITCH Cr <1 Cu <0.005 Fe 648 Cu <0.001 Cu <0.005 a Cu 00045 Fe 87 Hg <0.05 Fe 80 Fe 2040 STREAM Fe 907 Hg <0.05 Mn 731 Hg <0.05 Hg <0.05 Hg <0.05 Mn <5 Mo 1.39 Mn 30 Mn 1450 CW-054 Mn 544 Mo <1 Pb <1 Mo 23.4 Mo 6.86 _ Pb <1 S2 <0.5 Pb <1 Pb <1 jHg RESULT Mo 14 Sb <1 qS9e <' S2 0.264 MW-08BR3 sb <1 Pb <1 Al 272 S2 <1 - Se <1 9 4 Sb <1 CONST RESULT Se <1 `1 Sb <1 SO4 19 <0.2 Se <1 Al 110 SO4 47 57 TI <0.2 0.781 SO4 12 As <1 TI <0.2 <1 Se <' �..�..�..�. �..�. SO4 12 r V 1.02 TI <0.2 Ba 66 V <1 TI <0.2 , J V 2.79 �' �, Be <1 <5-- ` <0.005 V 1.29 S •.`- `,SR1501 .:5' Cr <1 4 ` SR-1504 MW-05BR' ` <0.05 L .'� 1 +N rn .. Fe 2200 <0.05 785 CONST RESULT • / JASHSIN 1981 • - •.• `S Hg ACTIVE <1 AI 57 ' rj .Mn 2680 <1 As <1 �It L DFILL Q'•Mo 5.86 <1 Ba 31 / •\ + P • .� :`� Pb <1 Q 5 S2 0.196 Se <1 Be <1 - + � � r' SO4 7.5 Cd <1 '��� V Cr <1 � h 4 Sb <1 MW-07BR3 TI < Se <1 V <0.3 Cu <0.001 11 N' I ,` _ SO4 33 CONST RESULT � e 2 m i v Q o' U o` a 0 0 Fe 4240 TI <0.2 AI 15 i NOTES: Hg <0.05 V <g 3 As <1 ' CONCENTRATIONS SHOWN ARE FROM THE APRIL 2015 SAMPLING EVENT. o Mn 1740 c ` Ba 140 w �•- • S < 2 CONCENTRATIONS SHOWN ARE FROM THE MAY 2015 SAMPLING EVENT. Mo 4.27 �� + Be 1 m Pb <1 `??j , C = Cd <1 3 CONCENTRATIONS SHOWN ARE FROM THE JUNE 2015 SAMPLING EVENT. S2 <0.1 �� r - - - - ,h}• +v-9 /� ,► Cr <1 'CONCENTRATIONS SHOWN ARE FROM THE JULY 2015 SAMPLING EVENT. Sb <1 `� ' ♦ +� ♦� *� 3 Cu <0.001 1. " MW-09BR 'SITE AERIAL ORTHOPHOTOGRAPHY IS DATED APRIL 17, 2014. IT WAS OBTAINED FROM WSP. Se <1 L _ CONST RESULT Fe 339 �.. �1-k /i ,• Hg <0.05 lo sADDITIONAL OFFSITE AERIAL ORTHOPHOTOGRAPHY ISDATED 2012. IT WAS OBTAINED FROM THE NC Q MW-13BR MAYO Al3720 CENTER FOR GEOGRAPHIC INFORMATION AND ANALYSIS AT htt llservices.neonema ovl 3 SO4 3.8 i o . Mn 263 P P 9 ) , TI <0.2 ��' o^' o . „ LAKE AS <1 PARCEL BOUNDARY WAS OBTAINED FROM THE NC CENTER FOR GEOGRAPHIC INFORMATION AND CONST RESULT V <p 3 `� r' Mo 3.72 w � Ba 30 ANALYSIS AT (httpalservices.nconemap.govl) Al 37 J ai .� Pb <1 x AS <1 ` � Be `1 S2 0.112 a DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE COORDINATE 9 i Cd <1 SYSTEM FIRS 3200 NAD8312011 . ti-..�,a Ba 40 1500 ' ' 1 Cr 3.4 Sb <' GRAPHIC SCALE SR �'� •L MW-04 se <1 Be <1 BG-014 1329 � �✓` Cu 0.00591 1,000 0 1,000 2,000 3,000 4,000 5,000 Cd <1 R . CONST RESULT SO4 1.6 CONST RESULT MW-11 BR3 BMW-04BIRMW-10BR' CW-01 D4 As <1 Fe 3000 TI <0.2 (IN FEET) Cr <1 BMW-02BR 4 Hg <0.05 Al 418 CONST RESULT CONST RESULT CW-02D CONST RESULT CONST RESULT Ba 6 Mn 809 V <0.3 DUKE Cu <0.001 CONST RESULT As <1 AI 80 Al20 CONST RESULT •, Al641 Al11 o, Fe 70 1508 Fe 1130 Ba 97 As <1 „,� AI 64 As 1.08 Al 472 As <1 As <1 Mn 15 Mo 1.75 SR Hg <0.05 As <1 Be <1 Ba 44 Ba 115 As <1 Ba 27 Ba <5 Pb <1 ; ENERGY Mn .2 Cd <1 Q73a8 Ba <1 Ba 38 r Be <1 Sb <1 S2 <1 Mo 8.28 Be <1 Be <1 Be <1 �Be <1 TI <0.2 I Cr <5 Cd <1 Cd <1 Be <1 Cd <1 Cd <1 Sb <1 s mTerm PROGRESS Pb <1 `Y1 Cd <1 V 0.891 Se <1 S2 0.115 SR Cu <0.005 SR-1328 Cr 1.73 Cr <1 Cr <1 Cd <1 Cr 1.3 Cr <5 Sb <1 Fe 557 Cu <0.001 Cu <0.001 Cu <0.001 Cr <5 f Cu <0.001 Cu <0.005 SO4 8.9 148 RIVER STREET, SUITE 220, MAYO STEAM ELECTRIC POWER PLANT H <0.05 Cu <0.005 Fe 883 TI <0.2 GREENVILLE, SC 29601 10660 BOSTON RD Se <1 ! g Fe 115 Fe 107 Fe 1590 Fe <10 V 4.17 864421-9999 ROXBORO, NORTH CAROLINA27574 SO4 18 Mn 23 Hg <0.05 Hg <0.05 Hg <0.05 Fe 278 Hg <0.05 Hg <0.05 LA www.synterracorp.com Mo <1 H <0.05 Mn 894 TI <0.2 Mn 67 0 Mn 149 Mn 407 g Mn <5 DRAWN BY: A. ROBINSON DATE: 812712015 V 0.381 Pb <1 Mo 5.41 Mo 5.67 Mo 6.12 Mn 81 Mo 2.37 Mo 20.8 r� CHECKED BY: J. MEADOWS DATE: 8/27/2015 PROJECT MANAGER: J. WYLIE Sb <1 Pb <1 Pb <1 Pb <1 Mo <1 Pb <1 Pb <1 1 Se <1 S2 <0.1 S2 <O.1 S2 <0.1 Pb <1 S2 <10 Sb <1 FIGURE 10-60 SO4 0.32 Sb 1.32 - Sb <1 Sb <1 Sb <1 Sb <1 SR-1 Se <1 CCR RULE ASSESSMENT MONITORING Se <1 Se <1 SF Se <1 Se <1 !- Se <1 SO4 4.1 S V 4.94 SO4 14 SO4 12 SO4 80 SO4 49 SO4 83 CONSTITUENT MAP TI <0.2 TI 0.323 TI <0.2 TI <0.2 TI <0.2 % TI <0.2 V 1.09 SR 1512 SQ 7512 BEDROCK �+ V 2.69 V 0.873 V 0,382 V 0.585 °N V 1.66 DE�RO"K WELL) Constituent Abbreviation Units Aluminum AI µg/L Antimony Sb µg/L Arsenic As µg/L Barium Ba µg/L Beryllium Be µg/L Cadmium Cd µg/L Chromium Cr µg/L Copper Cu mg/L Iron Fe µg/L Lead Pb µg/L Manganese Mn µg/L Mercury Hg µg/L Molybdenum Mo µg/L Selenium Se µg/L Sulfate 504 mg/L Sulfide S2 mg/L Thallium TI µg/L Vanadium V µg/L 80% ' 6096 40% m t 2 0 96 .� vo va cl cl a — 814 1410 synTerra ►J AL 148 RIVER STREET, SUITE 220 GREENVILLE, SOUTH CAROLINA 29601 PHONE 864-421-9999 www.synterracorp.Com DRAWN BY: J. GILMER DATE: JUNE 2015 PROJECT MANAGER: J. WYLIE LAYOUT: P:\Duke Energy Progress.1026\105. Mayo Ash Basin GW Assessment Plan\1.11 CSA Reporting\Figures\Statistics\Piper Diagrams 0 96 6 0 % 40% 0% ■ ABMW-01 • ABMW-02 • ABMW-03 7 ABMW-04 Z MW-163 V ABMW-03S V M-12S at ABMW-04D AL D -02 ,L W-01 • W-02 AL W-03 AL MW-07D 1 MW-12D k MW-16D } ABMW-02BR } ABMW-048R } D-01 } CW-01 D } W-02D } W-04 } W-05 } W-06 } MW-03BR } MW-05BR } MW-07DR MW-02 �} MW-03 MW-04 FIGURE 10-61 PIPER DIAGRAM — ALL GEOLOGIC UNITS MAYO STEAM ELECTRIC PLANT 10660 BOSTON ROAD ROXBORO, NORTH CAROLINA 27574 o q} a ABMW-01 • ABMW-02 ; o • ABMW-03 V ABMW-04 o � 0 ■ a t30 80% 80% 60% � � 6 0 % p 40% 40% a CPO. 20% if A 20% O, O, O� 1k 110 0 0 0 0 CaCI 148 RIVER STREET, SUITE 220 FIGURE 10-62 GREENVILLE, SOUTH CAROLINA 29601 PIPER DIAGRAM - ASH PORE WATER PHONE 864-421-9999 www.s nterracor .com DRAWN BY: J. GILMER DATE: JUNE 2015 synTerra LAYOUT: MANAGER:J. wvue MAYO STEAM ELECTRIC PLANT LAYOUT: P:\Duke Energy Progress.1026\105. Mayo Ash Basin GW 10660 BOSTON ROAD Assessment .11 CSA ROXBORO, NORTH CAROLINA 27574 Reporting\Figures\ures\Statistics\Piper Diagrams w a IrtVIpV �V,-1�1 / r8 �7 �� yy AL 1F�'�S1Q�M �V11 Vim�}}-��0 3 3 Cf a i IVIVV-12S AL -ol i� xa V CW-02 M-07D z M -12D 80 ' E 80 °'� 60% " � c� � 60% 0 a 40% cl 40% a 20% � E 2 0 % 7 7 7 0a loa �oa a FIGURE 10-63 148 GREEN ILLE,S ET,SUITE AROLI PIPER DIAGRAM —ALLUVIAL SAPROLITE, AND GREENVILLE, SOUTH CAROLINA 29601 , PHONE864-421-9999 TRANSITION ZONE www.s nterracor .com DRAWN BY: J. GILMER DATE: JUNE 2015 synTerra[P:\Duke PROJECT MANAGER J. WYLIE LAYOUT: MAYO STEAM ELECTRIC PLANT Energy Progress.1026\105. Mayo Ash Basin GW 10660 BOSTON ROAD Assess Plan\1.11 CSA Reporting\Figures\Statistics\Piper Diagrams ROXBORO NORTH CAROLINA 27574 cp a ■ ABMVV-020R ABMVV-040R 61 ;off �� 1 BC-01 CVV-01 D o CW-02D / 40, Z CVV-04 'a ■ CVV-05 cl J► CVV-06 V MVV-030R MVV-050R Z MVV-07BR MVV-08BR ! MVV-090R a 1 MVV-100R IF MVV-110R 80% � 80% MVV-13BR ° C?, o MVV-14BR 60% � ,�� 60% Jr MVV-160R ea MVV-02 40% 40% MVV 03 a co% r MVV-04 —1�1a a a a 0 0 0 0 Ca CI �! 410 synTerra 148 RIVER STREET, SUITE 220 GREENVILLE, SOUTH CAROLINA 29601 PHONE 864-421-9999 www.synterracorp.Com DRAWN BY: J. GILMER DATE: JUNE 2015 PROJECT MANAGER: J. WYLIE LAYOUT: P:\Duke Energy Progress.1026\105. Mayo Ash Basin GW Assessment Plan\1.11 CSA Reporting\Figures\Statistics\Piper Diagrams FIGURE 10-64 PIPER DIAGRAM - BEDROCK MAYO STEAM ELECTRIC PLANT 10660 BOSTON ROAD ROXBORO, NORTH CAROLINA 27574 0 9 7 m a-, 0 o 4 _ o y LIG.1 BG 2 C+N-1 Cw.1D CW-2 CW-2D Cw-3 CW-4 Cw5 cw-& 15 NCAC 02L Standard = 700 µg/L 15 NCAC 02L Standard = 700 µg/L 0 J O O V ra O ry 1313•1 Bc 2 cw.1 CW1D CW-2 cw.2D CW3 CW4 Cw-5 cw-6 ram., 0 15 NCAC 02L Standard = 2 µg/L — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — J E � a E m u 0 G 150•1 813•2 cw•1 cw•10 CW-2 CW-213 Cw G'A 4 CW5 CW 6 FIGURE 10-65 148 RIVER STREET, SUITE 220 GRLI GREENVILLE, SOUTH CAROLINA 29601 COMPLIANCE WELL BOX AND WHISKER PLOTS PHONE 864-421-9999 BARIUM, BORON, CADMIUM www.s nterracor .com DRAWN BY: J. GILMER DATE: AUGUST 2015 PROJECT MANAGER J WYLIE S)m err, LAYOUT: MAYO STEAM ELECTRIC PLANT P:\Duke Energy Progress.1026\105. Mayo Ash Basin GW Assessment Plan\1.11 CSA Reporting\Figures\Statistics\Box Plots 10660 BOSTON ROAD ROXBORO, NORTH CAROLINA 27574 E i7 0 L V r� 15 NCAC 02L Standard = 10 µg/L P P BG-1 BC 2 c w 1 CbV 1D GW-2 CW-21D CW-3 CW-4 CW-5 cW-6 0 9 RG 1 6G 2 C%V 1 C',^d ;n CGV 2 GW-21) GIN-3 CW4 CW-5 CW-6 15 NCAC 02L Standard = 250 mg/L 15 NCAC 02L Standard = 300 µg/L V — — — — — — — 77 — — — — — — — — — — - — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — BG 1 [sC, 2 G:'! 1 G'A'' 1 D CW 2 C:','':' ?D C',''J 3 C+,'d 4 :'.^ C11116 FIGURE 10-66 148 RIVER STREET, SUITE 220 GREENVILLE, SOUTH CAROLINA 29601 COMPLIANCE WELL BOX AND WHISKER PLOTS GRLI PHONE 864-421-9999 CHROMIUM, CHLORIDE, IRON ,tip www.s nterracor .com DRAWN BY: J. GILMER DATE: AUGUST 2015 S)m err, PROJECT MANAGER J WYLIE LAYOUT: MAYO STEAM ELECTRIC PLANT P:\Duke Energy Progress.1026\105. Mayo Ash Basin GW 10660 BOSTON ROAD Assessment Plan\1.11 CSA ROXBORO, NORTH CAROLINA 27574 Reporting\Figures\Statistics\Box Plots 4 O O T o —� T 15 NCAC 02L Standard = 50 — -- -- BCr1 BG-2 CW-1 CW-10 CW-2 CW-20 CW3 CW-4 cv.. 5 c1N-6 7 4 n 0 J OG n N Y V n Z � O O O O O vs —� i3G 1 RG 2 CW1 CW10 CW-2 CW-213 CW3 CW-4 cw-5 CW-6 15 NCAC 02L Standard = 100 µg/L 0G 1 90-2 CW-1 CW-1D CW2 CW-2D cw-3 GW. 4 Cw-5 CW rn 15 NCAC 02L Standard = 250 mg/L FIGURE 10-67 148 RIVER STREET, SUITE 220 GREENVILLE, SOUTH CAROLINA 29601 COMPLIANCE WELL BOX AND WHISKER PLOTS GRLI PHONE 864-421-9999 MANGANESE, NICKEL, SULFATE www.synterracorp.com DRAWN BY: J. GILMER DATE: AUGUST 2015 s�mTerra PROJECTMANAGER . WYLIE LAYOUT: MAYO STEAM ELECTRIC PLANT P:\Duke Energy Progres51026\105. Mayo Ash Basin GW 10660 BOSTON ROAD Assessment Plan\1.11 CSA ROXBORO, NORTH CAROLINA 27574 Reporting\Figures\Statistics\Box Plots ra F 15 NCAC 02L IMAC = 0.2 µg/L BG-1 BG-2 cw-1 Cw-1D CWO 2 Cw-211) CW-3 CW-4 CM5 Cw.6 15 NCAC 02L Standard = 500 µg/L _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ T O BG.1 RG2 CIN1 CW.1U C`N.2 GW21) Cw.3 CW-4 CW.5 FIGURE 10-68 148 RIVER STREET, SUITE 220 GREENVILLE, SOUTH CAROLINA 29601 COMPLIANCE WELL BOX AND WHISKER PLOTS GRLI PHONE 864-421-9999 THALLIUM, TOTAL DISSOLVED SOLIDS www.synterracorp.co,tip m DRAWN BY: J. GILMER DATE: AUGUST 2015 synTerr, PROJECT MANAGER J WYLIE LAvour: MAYO STEAM ELECTRIC PLANT P:\Duke Energy Progress.1026\105. Mayo Ash Basin GW 10660 BOSTON ROAD Assessment Plan\1.11 GSA ROXBORO, NORTH CAROLINA 27574 Reporting\Figures\Statistics\Box Plots 1 0t'%0A1r% 1ao v7 LU n, C� L7 Q W U O Q a� 1aA IL 1a0 O 0- (3) Cf, a W U �i / C6 O E U) O U) Cn a 0 Cn M m Cn Q 0 (B L6 O / O N O rH vi U) N w 0 n E. a� LU 0 / .E 7 co ri LO O N 00 N 0 620 610 600 590 580 570 560 550 540 530 520 510 500 490 480 ow 470 M� aa) 460 w= 450 440 430 420 410 400 390 380 370 360 350 340 330 320 310 300 NEI ANNE law.- ONE 620 610 600 590 580 570 560 550 540 530 520 510 500 490 480 470 460 450 440 430 420 410 400 390 W 3E CO CO I- Z_ J U Q O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O OD O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + O N M d co r'- M O CD- N M ,I-LO CO r- CO O O �- N •- - - - - - - c- N N N CO � LO (D r-- co M CD- N M "I-LO Cfl r1- co O �- N M � N N N N N N N co co M M co co co co M M It " It I- dt Ln CO It It r` M M O N M -' Lo CO r1- M O CD- N M ,I- LO (fl r'-M M CD M 'z Lo cp It IT U') LO LO LO LO LO LO LO LO LO CO CO CO (0 (0 CO CO CO (0 (0 r- r1-r- I� r1-r- SOUTHWEST Station (feet) SB-7 SECTION B-B' - ANTIMONY 1'-2': Sb <5.8 / As <5.8 / Ba 68.8 / B <14.5 / Cr 11.4 / Co 5.9 / Fe 9460 / Mn 693 / TI <5.8 / V 17.6 FACING NORTHWEST 4.5'-7.5':Sb<6/As<6/Ba15.5/B<15/Cr8.2/Co<6/Fe6040/Mn226/TI<6/V8.2 MW-3 MW-3: pH5.71/Sb<1/As<1/Ba56/B847/Cr(VI)0.155/Co<1/Fe34/Mn880/TI<0.2/TDS 190/V<0.3 CW-2/ 2D CW-2: 470 pH 6.5 / Sb <1 / As <1 / Ba 54 / B 804 / Cr(VI) <0.021 / Co <1 / Fe 467 / Mn 135 / TI <0.2 / TDS 370 / V 5.88 CW-2D: pH 6.1 / Sb <1 / As <1 / Ba 38 / B 363 / Cr(VI) 0.084 / Co <1 / Fe 278 / Mn 81 / TI <0.2 / TDS 250 / V 0.585 T460 460 50 MW-16S/ 16D/ 16BR 0 MW-16S: pH 6.02 / Sb <1 / As <1 / Ba 46 / B <50 / Cr(VI) 0.011 / Co 4.32 / Fe 860 / Mn 260 / TI <0.2 / TDS 100 / V 0.303 4 MW-16113: pH7.1/Sb<1/As<1/Ba13/B<50/Cr(VI)0.051/Co<1/Fe87/Mn269/TI<0.2/TDS 160/V0.617 0 of MW-16BR: pH8.67/Sb<1/As2.05/Ba11/B<50/Cr(VI)0.017/Co<1/Fe80/Mn30/TI<0.2/TDS 170/V2.79 43 w 1'-2':Sb<6.5/As<6.5/Ba95.4/B<16.2/Cr7.6/Co6j/Fe7710/Mn1250/TI<6.5/V17.3 23'-24': Sb<5/As<5/Ba28.2/B10j/Cr2.1/Co4.6j/Fe10600/Mn885/TI<5/V8.4 J p 33'-35':Sb<7.5/As<7.5/Ba131/B16.8j/Cr9.2/Co12/Fe19100/Mn1630/TI<7.5/V16.3 420 410 Q 54.5'-55.5': Sb <5.2 / As <5.2 / Ba 237 / B 32.3 / Cr 37.2 / Co 19.6 / Fe 38300 / Mn 1010 / TI <5.2 / V 87 400 0 400 J w w 390 390 380 c Q 380 W<1 U m 370 W _ 360 07 U) --- 350 340 W Z --- --- -- 330 ----____ ___ J--- --- --- --- --- 320 --- --- --- --- --- ---- --- <1-- --- --- 310 --- --- ---- ---- --- 300 --- --- --- --- --- 300 O O O O O CDO O O O O O O O O O O O O O O CDO O O O CD O O CD CD + + + CO r1- 00 + O + + + + + + + + + + + + O N CO � LO O r-- 00 O O f� ti r1- 00 00 00 0o 00 00 00 00 00 00 O O NORTHEAST SECTION B-B' - ANTIMONY FACING NORTHWEST ICOALASH TRANSITION ZONE - - - - BEDROCK SOIL/FILL SAPROLITE ALLUVIUM CONCENTRATION CONTOUR CONCENTRATION CONTOURS DASHED WHERE INFERRED HASH MARKS POINT TO DECREASING CONCENTRATIONS WATER LEVEL (JUNE 17, 2015) SURFICIAL WATER LEVEL TRANSITION ZONE WATER LEVEL BEDROCK WATER LEVEL .2u) FRACTURED/OXIDIZED ZONE m OBSERVED IN ROCK CORE w` NOT SAMPLED ABMW-02BR: WATER ANALYTICAL RESULTS IN pg/L 45'-45.5' SOIL TOTAL ANALYTICAL RESULTS IN mg/kg BORING SYMBOLS GRAPHIC SCALE 0 300 IN FEET HORIZONTAL: 1"=300' 0 30 IN FEET VERTICAL: 1"=30' NOTE: 10:1 VERTICAL EXAGGERATION SOIL SAMPLE WELL SCREEN WITH CONCENTRATION (micrograms per liter) SOURCES: 1. THE TOPOGRAPHY SURVEY DATA WITHIN THE PROPERTY BOUNDARY DATED MAY 19, 2015 WAS OBTAINED FROM WSP OF CARY, NORTH CAROLINA. 2. SELECT TOPOGRAPHIC ADJUSTMENTS BASED ON SITE SURVEY AND COMPARISON TO AERIAL PHOTOGRAPH. 3. 2015 LITHOLOGY INFORMATION OF SOIL AND WELL LOG TOPOGRAPHY IS FROM SYNTERRA. 4. GEOLOGIC INFORMATION FOR BORINGS AND MONITORING WELLS INSTALLED PRIOR TO 2015 TAKEN FROM S&ME (2010) AND QUANTEX (2008). NOTE: 1. CROSS SECTION LOCATIONS SHOWN ON FIGURE 2-1. 2. WATER LEVELS WERE COLLECTED BY SYNTERRA ON JUNE 17, 2015. 3. IMAC VALUE FOR ANTIMONY IS 1 pg/L. erra 148 River Street, Suite 220 Greenville, South Carolina 29601 864-421-9999 www.synterracorp.com DRAWN BY: C. NEWELL DATE: 8/5/2015 CHECKED BY: J. WYLIE DATE: 8/5/2015 PROJECT MANAGER: K. WEBB LAYOUT NAME: FIGURE 11-1A f%,. DUKE � ENERGY PROGRESS MAYO STEAM ELECTRIC PLANT 10660 BOSTON RD ROXBORO, NORTH CAROLINA FIGURE 11-1a GEOLOGIC CROSS SECTION B-B' WITH ANTIMONY 1 0t'%0A1r% 1ao v7 w C� Q W U O Q a� 1a0 IL 1a0 O 0- O Q' a W U �i / C6 O E U) O U) Cn a 0 Cn M C0 Cn Q 0 (B L6 O / O N O rH vi U) N w 0 I E. a� w 0 / .E 7 co ri U0 O N 00 N 0 620 610 600 590 580 570 560 550 540 530 520 510 500 490 480 o� 470 460 w= 450 440 430 420 410 400 390 380 370 360 350 340 330 320 310 300 0 MEN I Von. MEMO= 620 610 600 590 580 570 560 550 540 530 520 510 500 490 480 470 460 450 440 430 420 410 400 390 CO 2 CO I- Z_ J U Q Cff O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O OD O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + O N M d co r'- M O CD- N M ,I-LO CO r- CO O O �- N •- - - - - - - c- N N N CO � LO (D r-- 00 M CD- N M "I-LO co r1- co O �- N M � N N N N N N N co co M M co co co co M M It " It I- dt Ln CO It It r` M M O N M -' Lo CO r1- M O CD- N M ,I- LO CO r'-M M CD M 'z Lo cp It IT U') LO LO LO LO LO LO LO LO LO CO CO CO (0 (0 CO CO CO (0 (0 r- r1-r*- I� r1-r- SOUTHWEST Station (feet) SB-7 SECTION B-B' - ANTIMONY 1'-2': Sb <5.8 / As <5.8 / Ba 68.8 / B <14.5 / Cr 11.4 / Co 5.9 / Fe 9460 / Mn 693 / TI <5.8 / V 17.6 FACING NORTHWEST 4.5'-7.5':Sb<6/As<6/Ba15.5/B<15/Cr8.2/Co<6/Fe6040/Mn226/TI<6/V8.2 MW-3 MW-3: pH5.71/Sb<1/As<1/Ba56/6847/Cr(VI)0.155/Co<1/Fe34/Mn880/TI<0.2/TDS 190/V<0.3 CW-2/ 2D CW-2: 470 - pH 6.5 / Sb <1 / As <1 / Ba 54 / B 804 / Cr(VI) <0.021 / Co <1 / Fe 467 / Mn 135 / TI <0.2 / TDS 370 / V 5.88 CW-2111): pH 6.1 / Sb <1 / As <1 / Ba 38 / B 363 / Cr(VI) 0.084 / Co <1 / Fe 278 / Mn 81 / TI <0.2 / TDS 250 / V 0.585 460 460 50 MW-16S/ 16D/ 16BR 0 MW-16S: pH 6.02 / Sb <1 / As <1 / Ba 46 / B <50 / Cr(VI) 0.011 / Co 4.32 / Fe 860 / Mn 260 / TI <0.2 / TDS 100 / V 0.303 MW-161113: pH 7.1 / Sb <1 / As <1 / Ba 13 / B <50 / Cr(VI) 0.051 / Co <1 / Fe 87 / Mn 269 / TI <0.2 / TDS 160 / V 0.617 4 0 Of MW-16BR: pH8.67/Sb<1/As2.05/Ba11/B<50/Cr(VI)0.017/Co<1/Fe80/Mn30/TI<0.2/TDS 170/V2.79 43 w 1'-2':Sb<6.5/As<6.5/Ba95.4/B<16.2/Cr7.6/Co6j/Fe7710/Min 1250/TI<6.5/V17.3 J 23'-24': Sb<5/As<5/Ba28.2/B10j/Cr2.1/Co4.6j/Fe10600/Mn885/TI<5/V8.4 1 33'-35': Sb <7.5 / As <7.5 / Ba 131 / B 16.8 j / Cr 9.2 / Co 12 / Fe 19100 / Mn 1630 / TI <7.5 / V 16.3 o 420 Q 54.5'-55.5': Sb<5.2/As<5.2/Ba237/632.3/Cr37.2/Co19.6/Fe38300/Mn1010/TI<5.2/V87 410 400 0 400 J w w li 390 390 Q 380 380 j<1 V 00 370 W _IN 360 07 U) --- 350 340 Z --- --- 330 --- - - - - - - - - - - - - - - - - - 320 --- --- --- --- --- ---- --- <1-- --- --- 310 --- --- ---- --- --- 300 --- --- --- --- 300 O O O O O O O O O O O O O O O O O O O O O O O O O O CD O O CD CD + + + CO r1- 00 + + + + + + + + + + + + + O O N CO � LO O r-- 00 M O f� ti r1- 00 00 00 00 00 00 00 00 00 00 O O NORTHEAST SECTION B-B' - ANTIMONY FACING NORTHWEST ICOALASH TRANSITION ZONE BEDROCK SOIL/FILL SAPROLITE ALLUVIUM CONCENTRATION CONTOUR CONCENTRATION CONTOURS DASHED WHERE INFERRED HASH MARKS POINT TO DECREASING CONCENTRATIONS WATER LEVEL (JUNE 17, 2015) SURFICIAL WATER LEVEL TRANSITION ZONE WATER LEVEL BEDROCK WATER LEVEL �� FRACTURED/OXIDIZED ZONE m OBSERVED IN ROCK CORE U NOT SAMPLED ABMW-02BR: WATER ANALYTICAL RESULTS IN pg/L 45'-45.5' SOIL TOTAL ANALYTICAL RESULTS IN mg/kg BORING SYMBOLS GRAPHIC SCALE 0 300 IN FEET HORIZONTAL: 1"=300' 0 30 IN FEET VERTICAL: 1"=30' NOTE: 10:1 VERTICAL EXAGGERATION SOIL SAMPLE WELL SCREEN WITH CONCENTRATION (micrograms per liter) SOURCES.- 1 . THE TOPOGRAPHY SURVEY DATA WITHIN THE PROPERTY BOUNDARY DATED MAY 19, 2015 WAS OBTAINED FROM WSP OF CARY, NORTH CAROLINA. 2. SELECT TOPOGRAPHIC ADJUSTMENTS BASED ON SITE SURVEY AND COMPARISON TO AERIAL PHOTOGRAPH. 3. 2015 LITHOLOGY INFORMATION OF SOIL AND WELL LOG TOPOGRAPHY IS FROM SYNTERRA. 4. GEOLOGIC INFORMATION FOR BORINGS AND MONITORING WELLS INSTALLED PRIOR TO 2015 TAKEN FROM S&ME (2010) AND QUANTEX (2008). NOTE: 1. CROSS SECTION LOCATIONS SHOWN ON FIGURE 2-1. 2. WATER LEVELS WERE COLLECTED BY SYNTERRA ON JUNE 17, 2015. 3. IMAC VALUE FOR ANTIMONY IS 1 pg/L. erra 148 River Street, Suite 220 Greenville, South Carolina 29601 864-421-9999 www.synterracorp.com DRAWN BY: C. NEWELL DATE: 8/5/2015 CHECKED BY: J. WYLIE DATE: 8/5/2015 PROJECT MANAGER: K. WEBB LAYOUT NAME: FIGURE 11-1A DUKE ENERGY PROGRESS MAYO STEAM ELECTRIC PLANT 10660 BOSTON RD ROXBORO, NORTH CAROLINA FIGURE 11-1a GEOLOGIC CROSS SECTION B-B' WITH ANTIMONY I 0t'%0A1r% tiA LU n, C� Q W U O Q / U) 0) YaA IL 1a0 O 0- 0) a W U rl c6 n a) E U) 0) U) Cn a 0 Cn M m Cn a 0 I6 O / N O vi U) a) w 0 n E. a) LU 0 / WE 7 00 ri LO O N 00 N 0 MW-13BR MW-13BR: pH7.2/Sb<1/As<1/Ba40/B<50/Cr(VI)0.005/Col.19/Fe1130/Mn474/TI<0.2/TDS370/V0.381 0'-2': Sb<6.5/As<6.5/Ba72.9/B<16.3/Cr6.1/Co<6.5/Fe19600/Min 82.8/TI<6.5/V32.4 52'-54': Sb<5.1/As<5.1/Ba62.3/B<2.5/Cr9.2/Co6.6/Fe10400/Min 789/TI<5.1/V13.1 ABMW-02/ 02BR ABMW-02: pH 7.8 / Sb <1 / As 1020 / Ba 173 / B 9200 / Cr(VI) 0.017 / Co <1 / Fe 356 / Mn 1110 / TI <0.2 / TDS 450 / V 3.53 ABMW-02BR: pH 7.2 / Sb <1 / As <1 / Ba 159 / B <50 / Cr(VI) 0.007 / Co <1 / Fe 107 / Mn 149 / TI <0.2 / TDS 370 / V 0.873 45'-45.5': Sb<6/As<6/Ba92.2/B<15/Cr8/Co6j/Fe18300/Mn579/TI<6/V30.3 57.5'-58': Sb<5.1/As<5.1/Ba41.2/B<12.8/Cr56.7/Co37.4/Fe43400/Mn782/TI<5.1/V84.9 ABMW-03/ 03S u so 61 PAN- .1 NMI Ow w 7 A 1 OWL s y MW-07D/ 07BR MW-07D: pH 6.4 / Sb <1 / As <1 / Ba 24 / B <50 / Cr(VI) NS / Co <1 / Fe 69 / Mn 188 / TI <0.2 / TDS 390 / V 0.798 MW-07BR: pH 7.4 / Sb <1 / As <1 / Ba 140 / B <50 / Cr(VI) NS / Co <1 / Fe 339 / Mn 263 / TI <0.2 / TDS 270 / V <0.3 C 1 550 1'-2': Sb<5.1/As<5.1/Ba21.5/B<12.8/Cr4.1/Co<5.1/Fe7320/Mn27.7/TI<5.1/V12.8 550 540 540 MW-08S/ 08D/ 08BR 530 p MW-08BR: pH 6.56 / Sb <1 / As <1 / Ba 66 / B <50 / Cr(VI) NS / Co <1 / Fe 2200 / Mn 2680 / TI <0.2 / TDS 550 / V <0.3 a0 0.75'-1.25': Sb <3.2 / As <3.2 / Ba 147 / B <63.4 / Cr 62.2 / Co 21.3 / Fe 24700 / Mn 1230 / TI <3.2 / V 50.6 520 25.5'-26': Sb<2.7/As<2.7/Ba193/B31j/Cr419/Co32.9/Fe31300/Mn933/TI<2.7/V75.8 1-1<5i- � 1 30.5'-31': Sb <2.7 / As <2.7 Ba 130 B <53.1 Cr 67.1 Co 7.4 Fe 11400 Mn 875 / TI <2.7 / V 25.2 SECTION C-C' - ANTIMONY FACING NORTH GRAPHIC SCALE 300 0 300 IN FEET HORIZONTAL: 1"=300' 30 0 30 ICOALASH TRANSITION ZONE BEDROCK SOIL/FILL SAPROLITE ALLUVIUM CONCENTRATION CONTOUR CONCENTRATION CONTOURS DASHED WHERE INFERRED HASH MARKS POINT TO DECREASING CONCENTRATIONS V WATER LEVEL (JUNE 17, 2015) SURFICIAL WATER LEVEL TRANSITION ZONE WATER LEVEL BEDROCK WATER LEVEL FRACTURED/OXIDIZED ZONE OBSERVED IN ROCK CORE NS NOT SAMPLED ABMW-02BR: WATER ANALYTICAL RESULTS IN pg/L 45'-45.5' SOIL TOTAL ANALYTICAL RESULTS IN mg/kg BORING SYMBOLS SOIL SAMPLE WELL SCREEN WITH CONCENTRATION (micrograms per liter) SOURCES: 1. THE TOPOGRAPHY SURVEY DATA WITHIN THE PROPERTY BOUNDARY DATED MAY 19, 2015 WAS OBTAINED FROM WSP OF CARY, NORTH CAROLINA. 2. SELECT TOPOGRAPHIC ADJUSTMENTS BASED ON SITE SURVEY AND COMPARISON TO AERIAL PHOTOGRAPH. 3. 2015 LITHOLOGY INFORMATION OF SOIL AND WELL LOG TOPOGRAPHY IS FROM SYNTERRA. 4. GEOLOGIC INFORMATION FOR BORINGS AND MONITORING WELLS INSTALLED PRIOR TO 2015 TAKEN FROM S&ME (2010) AND QUANTEX (2008). NOTE. 1. CROSS SECTION LOCATIONS SHOWN ON FIGURE 2-1. 2. WATER LEVELS WERE COLLECTED BY SYNTERRA ON JUNE 17, 2015. 3. IMAC VALUE FOR ANTIMONY IS 1 pg/L. erra 148 River Street, Suite 220 Greenville, South Carolina 29601 864-421-9999 www.synterracorp.com DRAWN BY: C. NEWELL DATE: 8/5/2015 CHECKED BY: J. WYLIE DATE: 8/5/2015 PROJECT MANAGER: K. WEBB LAYOUT NAME: FIGURE 11-113 DUKE ENERGY boo PROGRESS MAYO STEAM ELECTRIC PLANT 10660 BOSTON RD 60 ROXBORO, NORTH CAROLINA IN FEET VERTICAL: 1"=30' NOTE: 10:1 VERTICAL EXAGGERATION FIGURE 11-1 b GEOLOGIC CROSS SECTION C-C' WITH ANTIMONY 1 0t'%0A1r% U0 w Of LL Q W U O 75 / a� la,0 IL w O tf O Q- (1) Q W U r-I r-I / c co IZ C N V7 N N Q 0 co m Q O co Ln O / C9 N O r-i vi N U0 O N w N 75 a- 0') cYi In O N N 0 620 610 600 590 580 570 560 550 540 530 520 510 500 490 480 ow 470 M� aa) 460 w= 450 440 430 420 410 400 390 380 370 360 350 340 330 320 310 300 SEEN mossomommom NONE MEN FA I F P- INN 620 610 600 590 580 570 560 550 540 530 520 510 500 490 480 470 460 450 440 430 420 410 400 390 w LU CO CO LU - Z_ J U Q O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O OD O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + O N M d co r'- M O CD- N M ,I-LO CO I- CO O O �- N •- - - - - - - c- N N N CO � LO (D r--00 M CD- N M "I-LO co ti co O �- N M � N N N N N N N co co M M co co co co M M It " It I- dt Ln CO It It f-- M M O N M -' Lo CO fl- M O CD- N M ,I- LO CO I- M M CD M 'z Loj cp It IT Lr) LO LO LO LO LO LO LO LO LO CO CO CO (0 (0 CO CO CO (0 (0 r- ti r- ti ti r- SOUTHWEST Station (feet) S113-7 SECTION B-B' - ARSENIC 1'-2': Sb <5.8 / As <5.8 / Ba 68.8 / B <14.5 / Cr 11.4 / Co 5.9 / Fe 9460 / Mn 693 / TI <5.8 / V 17.6 FACING NORTHWEST 4.5'-7.5':Sb<6/As<6/13a15.5/B<15/Cr8.2/Co<6/Fe6040/Mn226/TI<6/V8.2 MW-3 MW-3: pH5.71/Sb<1/As<1/Ba56/B847/Cr(VI)0.155/Co<1/Fe34/Mn880/TI<0.2/TDS190/V<0.3 CW-2/ 2D 470 1 1 1 1CW-2: pH 6.5 / Sb <1 / As <1 / Ba 54 / B 804 / Cr(VI) <0.021 / Co <1 / Fe 467 / Mn 135 / TI <0.2 /TDS 370 / V 5.88 CW-211): pH 6.1 / Sb <1 / As <1 / Ba 38 / B 363 / Cr(VI) 0.084 / Co <1 / Fe 278 / Mn 81 / TI <0.2 / TDS 250 / V 0.585 460 460 N a) 50 MW-16S/ 16D/ 16BR MW-16S: pH 6.02 / Sb <1 / As <1 / Ba 46 / B <50 / Cr(VI) 0.011 / Co 4.32 / Fe 860 / Mn 260 / TI <0.2 / TDS 100 / V 0.303 4 0 Q O MW-16D: pH7.1/Sb<1/As<1/Ba13/B<50/Cr(VI)0.051/Co<1/Fe87/Mn269/TI<0.2/TDS160/V0.617 of MW-16BR: pH8.67/Sb<1/As2.05/Ba11/B<50/Cr(VI)0.017/Co<1/Fe80/Mn30/TI<0.2/TDS170/V2.79 43 w Y 1'-2':Sb<6.5/As<6.5/Ba95.4/B<16.2/Cr7.6/Co6j/Fe7710/Mn1250/TI<6.5/V17.3 J 23'-24': Sb<5/As<5/Ba28.2/B10j/Cr2.1/Co4.6j/Fe10600/Mn885/TI<5/V8.4 420 p 33'-35':Sb<7.5/As<7.5/Ba131/B16.8j/Cr9.2/Co12/Fe19100/Mn1630/TI<7.5/V16.3 Q 54.5'-55.5': Sb <5.2 / As <5.2 / Ba 237 / B 32.3 / Cr 37.2 / Co 19.6 / Fe 38300 / Mn 1010 / TI <5.2 / V 87 410 400 0 400 J w 390 w 39U � 10 _= 380 (DI ALI C) I I I '--- Q 380 370 w _ = - - _ <1 360 0) U) --- 350 . 340 w ---_ --- <1 Z --- _ --- --- --- -- 330 J--- - - - ---- - - - - - - - - - - - U --- --- --- 320 --- --- --- --- ---- _--- 2.05_ --- ---- --- --- Q 310 300 - - - - - - 300 O O O O O CDO O O O O O O O O O O O O O O CDO O O O CD O O O O O + + + CO fl- 00 + + O O + + + + + + + + + + + N M � LO O r- M M O I- rl- ti r- 00 00 00 00 00 00 00 00 00 00 O O NORTHEAST SECTION B-B' - ARSENIC FACING NORTHWEST ICOALASH TRANSITION ZONE - - - - BEDROCK SOIL/FILL SAPROLITE ALLUVIUM CONCENTRATION CONTOUR CONCENTRATION CONTOURS DASHED WHERE INFERRED HASH MARKS POINT TO DECREASING CONCENTRATIONS WATER LEVEL (JUNE 17, 2015) SURFICIAL WATER LEVEL TRANSITION ZONE WATER LEVEL BEDROCK WATER LEVEL .2u) FRACTURED/OXIDIZED ZONE m OBSERVED IN ROCK CORE w` NOT SAMPLED ABMW-02BR: WATER ANALYTICAL RESULTS IN pg/L 45'-45.5' SOIL TOTAL ANALYTICAL RESULTS IN mg/kg BORING SYMBOLS GRAPHIC SCALE 0 300 IN FEET HORIZONTAL: 1"=300' 0 30 IN FEET VERTICAL: 1"=30' NOTE: 10:1 VERTICAL EXAGGERATION SOIL SAMPLE WELL SCREEN WITH CONCENTRATION (micrograms per liter) SOURCES.- 1 THE TOPOGRAPHY SURVEY DATA WITHIN THE PROPERTY BOUNDARY DATED MAY 19, 2015 WAS OBTAINED FROM WSP OF CARY, NORTH CAROLINA. 2. SELECT TOPOGRAPHIC ADJUSTMENTS BASED ON SITE SURVEY AND COMPARISON TO AERIAL PHOTOGRAPH. 3. 2015 LITHOLOGY INFORMATION OF SOIL AND WELL LOG TOPOGRAPHY IS FROM SYNTERRA. 4. GEOLOGIC INFORMATION FOR BORINGS AND MONITORING WELLS INSTALLED PRIOR TO 2015 TAKEN FROM S&ME (2010) AND QUANTEX (2008). NOTE.- 1 . CROSS SECTION LOCATIONS SHOWN ON FIGURE 2-1. 2. WATER LEVELS WERE COLLECTED BY SYNTERRA ON JUNE 17, 2015. 3. 2L VALUE FOR ARSENIC IS 10 pg/L. erra 148 River Street, Suite 220 Greenville, South Carolina 29601 864-421-9999 www.synterracorp.com DRAWN BY: C. NEWELL DATE: 8/5/2015 CHECKED BY: J. WYLIE DATE: 8/5/2015 PROJECT MANAGER: K. WEBB LAYOUT NAME: FIGURE 11-2A (� DUKE � ENERGY PROGRESS MAYO STEAM ELECTRIC PLANT 10660 BOSTON RD ROXBORO, NORTH CAROLINA FIGURE 11-2a GEOLOGIC CROSS SECTION B-B' WITH ARSENIC I 0t'%0A1r% tiA LU n, C� Q W U O Q / U) a) YaA IL 1a0 O 0- 0) a W U rl / C6 n a) E U) 0) U) Cn a 0 Cn M m Cn a 0 I6 O / N O vi U) a) w 0 n E. a) LU 0 / WE N ri LO O N 00 N 0 MW-13BR MW-13BR: pH7.2/Sb<1/As<1/Ba40/B<50/Cr(VI)0.005/Col.19/Fe1130/Mn474/TI<0.2/TDS370/V0.381 0'-2': Sb<6.5/As<6.5/Ba72.9/B<16.3/Cr6.1/Co<6.5/Fe19600/Min 82.8/TI<6.5/V32.4 52'-54': Sb<5.1/As<5.1/Ba62.3/B<2.5/Cr9.2/Co6.6/Fe10400/Min 789/TI<5.1/V13.1 ABMW-02/ 02BR ABMW-02: pH 7.8 / Sb <1 / As 1020 / Ba 173 / B 9200 / Cr(VI) 0.017 / Co <1 / Fe 356 / Mn 1110 / TI <0.2 / TDS 450 / V 3.53 ABMW-02BR: pH 7.2 / Sb <1 / As <1 / Ba 159 / B <50 / Cr(VI) 0.007 / Co <1 / Fe 107 / Mn 149 / TI <0.2 / TDS 370 / V 0.873 45'-45.5': Sb<6/As<6/Ba92.2/B<15/Cr8/Co6j/Fe18300/Mn579/TI<6/V30.3 57.5'-58': Sb<5.1/As<5.1/Ba41.2/B<12.8/Cr56.7/Co37.4/Fe43400/Mn782/TI<5.1/V84.9 ABMW-03/ 03S BMV' mm. 1 6 in u 44 s y MW-07D/ 07BR MW-07D: pH 6.4 / Sb <1 / As <1 / Ba 24 / B <50 / Cr(VI) NS / Co <1 / Fe 69 / Mn 188 / TI <0.2 / TDS 390 / V 0.798 MW-07BR: pH 7.4 / Sb <1 / As <1 / Ba 140 / B <50 / Cr(VI) NS / Co <1 / Fe 339 / Mn 263 / TI <0.2 / TDS 270 / V <0.3 C 1 550 1'-2': Sb<5.1/As<5.1/Ba21.5/B<12.8/Cr4.1/Co<5.1/Fe7320/Mn27.7/TI<5.1/V12.8 550 540 111�1540 MW-08S/ 08D/ 08BR 530 p MW-08BR: pH 6.56 / Sb <1 / As <1 / Ba 66 / B <50 / Cr(VI) NS / Co <1 / Fe 2200 / Mn 2680 / TI <0.2 / TDS 550 / V <0.3 a0 0.75'-1.25': Sb <3.2 / As <3.2 / Ba 147 / B <63.4 / Cr 62.2 / Co 21.3 / Fe 24700 / Mn 1230 / TI <3.2 / V 50.6 520 25.5'-26': Sb<2.7/As<2.7/Ba193/B31j/Cr419/Co32.9/Fe31300/Mn933/TI<2.7/V75.8 30.5'-31': Sb <2.7 / As <2.7 Ba 130 B <53.1 Cr 67.1 Co 7.4 Fe 11400 Mn 875 / TI <2.7 / V 25.2 ML bw SECTION C-C' - ARSENIC FACING NORTH 510 500 490 ►D 'Coll" 380 370 360 GRAPHIC SCALE 300 0 300 IN FEET HORIZONTAL: 1"=300' 30 0 30 ICOALASH TRANSITION ZONE BEDROCK SOIL/FILL SAPROLITE ALLUVIUM CONCENTRATION CONTOUR CONCENTRATION CONTOURS DASHED WHERE INFERRED HASH MARKS POINT TO DECREASING CONCENTRATIONS V WATER LEVEL (JUNE 17, 2015) SURFICIAL WATER LEVEL TRANSITION ZONE WATER LEVEL BEDROCK WATER LEVEL FRACTURED/OXIDIZED ZONE OBSERVED IN ROCK CORE NS NOT SAMPLED ABMW-02BR: WATER ANALYTICAL RESULTS IN pg/L 45'-45.5' SOIL TOTAL ANALYTICAL RESULTS IN mg/kg BORING SYMBOLS SOIL SAMPLE WELL SCREEN WITH CONCENTRATION (micrograms per liter) SOURCES.- 1 THE TOPOGRAPHY SURVEY DATA WITHIN THE PROPERTY BOUNDARY DATED MAY 19, 2015 WAS OBTAINED FROM WSP OF CARY, NORTH CAROLINA. 2. SELECT TOPOGRAPHIC ADJUSTMENTS BASED ON SITE SURVEY AND COMPARISON TO AERIAL PHOTOGRAPH. 3. 2015 LITHOLOGY INFORMATION OF SOIL AND WELL LOG TOPOGRAPHY IS FROM SYNTERRA. 4. GEOLOGIC INFORMATION FOR BORINGS AND MONITORING WELLS INSTALLED PRIOR TO 2015 TAKEN FROM S&ME (2010) AND QUANTEX (2008). NOTE.- 1 . CROSS SECTION LOCATIONS SHOWN ON FIGURE 2-1. 2. WATER LEVELS WERE COLLECTED BY SYNTERRA ON JUNE 17, 2015. 3. 2L VALUE FOR ARSENIC IS 10 pg/L. erra 148 River Street, Suite 220 Greenville, South Carolina 29601 864-421-9999 www.synterracorp.com DRAWN BY: C. NEWELL DATE: 8/5/2015 CHECKED BY: J. WYLIE DATE: 8/5/2015 PROJECT MANAGER: K. WEBB LAYOUT NAME: FIGURE 11-213 DUKE ENERGY boo PROGRESS MAYO STEAM ELECTRIC PLANT 10660 BOSTON RD 60 ROXBORO, NORTH CAROLINA IN FEET VERTICAL: 1"=30' NOTE: 10:1 VERTICAL EXAGGERATION FIGURE 11-2b GEOLOGIC CROSS SECTION C-C' WITH ARSENIC 1 0t'%0A1r% 1aA v7 LU n, C� L7 Q W U O Q a� 1a0 IL 1aA O 0- (3) Cf, a W U �i / C6 O E U) O U) Cn a 0 Cn M m Cn Q 0 ('3 L6 O / O N O vi U) N w 0 n E. a� LU (v 0 / .E 7 c� N M LO O N 00 N 0 620 610 600 590 580 570 560 550 540 530 520 510 500 490 480 ow 470 M� aa) 460 w= 450 440 430 420 410 400 390 380 370 360 350 340 330 320 310 300 owl ENNN 620 610 600 590 580 570 560 550 540 530 520 510 500 490 480 470 460 450 440 430 420 410 400 390 W LU 3E CO CO LU - Z_ J U Q O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O OD O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + O N M d co r'- M O CD- N M ,I-LO CO r- CO O O �- N •- - - - - - - c- N N N CO � LO (D r-- co M CD- N M "I-LO co ti co O �- N M � N N N N N N N co co M M co co co co M M It " It I- dt Ln CO It It r` M M O N M -' Lo CO rl- M O CD- N M ,I- LO CO r- M M CD M 'z Lo cp It IT U') LO LO LO LO LO LO LO LO LO co co (0 (0 (0 cc (0 cc (0 (0 r- ti r- ti ti r- SOUTHWEST Station (feet) S113-7 SECTION B-B' - BARIUM 1'-2': Sb <5.8 / As <5.8 / Ba 68.8 / B <14.5 / Cr 11.4 / Co 5.9 / Fe 9460 / Mn 693 / TI <5.8 / V 17.6 FACING NORTHWEST 4.5'-7.5':Sb<6/As<6/Ba15.5/B<15/Cr8.2/Co<6/Fe6040/Mn226/TI<6/V8.2 MW-03 MW-03: MW-03: pH 5.71 / Sb <1 / As <1 / Ba 56 / B 847 / Cr(VI) 0.155 / Co <1 / Fe 34 / Mn 880 / TI <0.2 / TDS 190 / V <0.3 COAL ASH TRANSITION ZONE - - - - BEDROCK SOIL/FILL SAPROLITE ALLUVIUM CONCENTRATION CONTOUR CONCENTRATION CONTOURS DASHED WHERE INFERRED HASH MARKS POINT TO DECREASING CONCENTRATIONS WATER LEVEL (JUNE 17, 2015) SURFICIAL WATER LEVEL TRANSITION ZONE WATER LEVEL BEDROCK WATER LEVEL o� �/ FRACTURED/OXIDIZED ZONE m OBSERVED IN ROCK CORE w` NOT SAMPLED ABMW-02BR: WATER ANALYTICAL RESULTS IN pg/L 45'-45.5' SOIL TOTAL ANALYTICAL RESULTS IN mg/kg BORING SYMBOLS SOIL SAMPLE WELL SCREEN WITH CONCENTRATION (micrograms per liter) SOURCES. 1. THE TOPOGRAPHY SURVEY DATA WITHIN THE PROPERTY BOUNDARY DATED MAY 19, 2015 WAS OBTAINED FROM WSP OF CARY, NORTH CAROLINA. 2. SELECT TOPOGRAPHIC ADJUSTMENTS BASED ON SITE SURVEY AND COMPARISON TO AERIAL PHOTOGRAPH. 3. 2015 LITHOLOGY INFORMATION OF SOIL AND WELL LOG TOPOGRAPHY IS FROM SYNTERRA. 4. GEOLOGIC INFORMATION FOR BORINGS AND MONITORING WELLS INSTALLED PRIOR TO 2015 TAKEN FROM S&ME (2010) AND QUANTEX (2008). NOTE.- 1 . CROSS SECTION LOCATIONS SHOWN ON FIGURE 2-1. 2. WATER LEVELS WERE COLLECTED BY SYNTERRA ON JUNE 17, 2015. 3. 2L VALUE FOR BARIUM IS 700 pg/L. CW-2/ 2D 470 CW-2: pH 6.5 / Sb <1 / As <1 / Ba 54 / B 804 / Cr(VI) <0.021 / Co <1 / Fe 467 / Mn 135 / TI <0.2 / TDS 370 / V 5.88 CW-2D: pH 6.1 / Sb <1 / As <1 / Ba 38 / B 363 / Cr(VI) 0.084 / Co <1 / Fe 278 / Mn 81 / TI <0.2 / TDS 250 / V 0.585 460 1 1 1 1 1 1 1460 -i� �� I MMM�l 50 MW-16S/ 16D/ 16BR p MW-16S: pH 6.02 / Sb <1 / As <1 / Ba 46 / B <50 / Cr(VI) 0.011 / Co 4.32 / Fe 860 / Mn 260 / TI <0.2 / TDS 100 / V 0.303 4 0 a0 MW-16D: pH7.1/Sb<1/As<1/Ba13/B<50/Cr(VI)0.051/Co<1/Fe87/Mn269/TI<0.2/TDS160/V0.617 of MW-16BR: pH8.67/Sb<1/As2.05/Ba11/B<50/Cr(VI)0.017/Co<1/Fe80/Mn30/TI<0.2/TDS170/V2.79 43 w 1'-2':Sb<6.5/As<6.5/Ba95.4/B<16.2/Cr7.6/Co6j/Fe7710/Mn1250/TI<6.5/V17.3 J 23'-24': Sb<5/As<5/Ba28.2/B10j/Cr2.1/Co4.6j/Fe10600/Mn885/TI<5/V8.4 420 p 33'-35':Sb<7.5/As<7.5/Ba131/B16.8j/Cr9.2/Co12/Fe19100/Mn1630/TI<7.5/V16.3 erra } 54.5'-55.5': Sb <5.2 / As <5.2 / Ba 237 / B 32.3 / Cr 37.2 / Co 19.6 / Fe 38300 / Mn 1010 / TI <5.2 / V 87 410 148 River Street, Suite 220 Greenville, South Carolina 29601 400 0 400 864-421-9999 w www.synterracorp.com 390 w LL 390 0 0 DRAWN BY: C. NEWELL DATE: 8/5/2015 380 41< 380 CHECKED BY: J. WYLIE DATE: 8/5/2015 j 54 v m 370 PROJECT MANAGER: K. WEBB W LAYOUT NAME: FIGURE 11-3A 46 360 r DUKE_ --- 350 340 W -38 - - 0 13 GRAPHIC SCALE J --- --- --- ---- 330 ENERGY --- --- --- --- ---- --- --- --- --- --- 320 300 0 300 600 PROGRESS --- ---- ---- --- ___ --- IN FEET Q 310 MAYO STEAM ELECTRIC PLANT 7 ___ ___ ___ ____ __ ____ __ ____ ___ ___ HORIZONTAL:1"=300' 10660 BOSTON RD --- --- ---- ---- --- 300 - - - - - - - - - - - - - - - 300 30 0 30 60 ROXBORO, NORTH CAROLINA o O O O O O O O O O O O O O O O o O O O O O O O O O O O O O O O (0 rl- 0+0 M +O + N M � LO (0 r` 0+0 M O + IN FEET FIGURE 11-3a r` ti r-- 00 o0 00 00 00 00 00 00 00 00 M rn NORTHEAST VERTICAL:1"=30' GEOLOGIC CROSS SECTION B-B' SECTION B-B' - BARIUM NOTE: 10:1 VERTICAL EXAGGERATION FACING NORTHWEST WITH BARIUM I 0t'%0A1r% tiA w n, C� Q W U O Q / U) a� YaA IL 1a0 O Q O a W U rl / ('3 n a) E U) O U) Cn 0 Cn M m Cn Q O c>3 I6 O / N O vi U) N w 0 n E. a� w a� 0 / .E 7 LO N LO O N 00 N 0 MW-13BR MW-13BR: pH7.2/Sb<1/As<1/Ba40/B<50/Cr(VI)0.005/Col.19/Fe1130/Mn474/TI<0.2/TDS370/V0.381 0'-2': Sb<6.5/As<6.5/Ba72.9/B<16.3/Cr6.1/Co<6.5/Fe19600/Min 82.8/TI<6.5/V32.4 52'-54': Sb<5.1/As<5.1/Ba62.3/B<2.5/Cr9.2/Co6.6/Fe10400/Min 789/TI<5.1/V13.1 ABMW-02/ 02BR ABMW-02: pH 7.8 / Sb <1 / As 1020 / Ba 173 / B 9200 / Cr(VI) 0.017 / Co <1 / Fe 356 / Mn 1110 / TI <0.2 / TDS 450 / V 3.53 ABMW-02BR: pH 7.2 / Sb <1 / As <1 / Ba 159 / B <50 / Cr(VI) 0.007 / Co <1 / Fe 107 / Mn 149 / TI <0.2 / TDS 370 / V 0.873 45'-45.5': Sb<6/As<6/Ba92.2/B<15/Cr8/Co6j/Fe18300/Mn579/TI<6/V30.3 57.5'-58': Sb<5.1/As<5.1/Ba41.2/B<12.8/Cr56.7/Co37.4/Fe43400/Mn782/TI<5.1/V84.9 ABMW-03/ 03S BMV' mm. 1 6 in u 144 ROOM 44 PA b Few Whom qwwq oil IBM s y MW-07D/ 07BR MW-07D: pH 6.4 / Sb <1 / As <1 / Ba 24 / B <50 / Cr(VI) NS / Co <1 / Fe 69 / Mn 188 / TI <0.2 / TDS 390 / V 0.798 MW-07BR: pH 7.4 / Sb <1 / As <1 / Ba 140 / B <50 / Cr(VI) NS / Co <1 / Fe 339 / Mn 263 / TI <0.2 / TDS 270 / V <0.3 C 1 550 1'-2': Sb<5.1/As<5.1/Ba21.5/B<12.8/Cr4.1/Co<5.1/Fe7320/Mn27.7/TI<5.1/V12.8 550 540 540 MW-08S/ 08D/ 08BR 530 p MW-08BR: pH 6.56 / Sb <1 / As <1 / Ba 66 / B <50 / Cr(VI) NS / Co <1 / Fe 2200 / Mn 2680 / TI <0.2 / TDS 550 / V <0.3 a0 0.75'-1.25': Sb <3.2 / As <3.2 / Ba 147 / B <63.4 / Cr 62.2 / Co 21.3 / Fe 24700 / Mn 1230 / TI <3.2 / V 50.6 520 25.5'-26': Sb<2.7/As<2.7/Ba193/B31j/Cr419/Co32.9/Fe31300/Mn933/TI<2.7/V75.8 30.5'-31': Sb <2.7 / As <2.7 / Ba 130 / B <53.1 / Cr 67.1 / Co 7.4 / Fe 11400 / Mn 875 / TI <2.7 / V 25.2 510 51U 500 500 490 NO DATA 490 480 480 H LL) 470 LLI c J J �� U)460 �� 4O w°' _ 50 O O w� W 440 Z --- --- NS _ J --- ---_ --- 24_ 430 _ --- --- --- --- --- -- oQoQ 420 U--- --- -- -- 410 -- --- --- --- --- -- -- --- --- --- --- --- -- 66 --- -- --- --- -- 400 --- --- -- --- ---- --- --- --- --- --- ---- --- -- 390 --- --- -- --- - --- 390 380 --- --- --- --- --- -- 140 - --- --- --- --- --- 380 --- --- -- --- ---- --- 370 370 360 360 --- --- --- --- ---- --- -- O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O ++++++++++++++++++++ O - N CO It LO CO r- co M O r N C0 't Lr) (D rl- 00 M ti rl- rl- I- r-- r-- rl- rl- rl- r%- co co 0o co 0o 0o co co 00 00 EAST SECTION C-C' - BARIUM FACING NORTH SECTION C-C' - BARIUM FACING NORTH 510 500 490 ED 041111 380 370 360 GRAPHIC SCALE 300 0 300 IN FEET HORIZONTAL: 1"=300' 30 0 30 ICOALASH TRANSITION ZONE BEDROCK SOIL/FILL SAPROLITE ALLUVIUM CONCENTRATION CONTOUR CONCENTRATION CONTOURS DASHED WHERE INFERRED HASH MARKS POINT TO DECREASING CONCENTRATIONS WATER LEVEL (JUNE 17, 2015) SURFICIAL WATER LEVEL TRANSITION ZONE WATER LEVEL BEDROCK WATER LEVEL FRACTURED/OXIDIZED ZONE OBSERVED IN ROCK CORE NS NOT SAMPLED ABMW-02BR: WATER ANALYTICAL RESULTS IN pg/L 45'-45.5' SOIL TOTAL ANALYTICAL RESULTS IN mg/kg BORING SYMBOLS SOIL SAMPLE WELL SCREEN WITH CONCENTRATION (micrograms per liter) SOURCES.- 1 THE TOPOGRAPHY SURVEY DATA WITHIN THE PROPERTY BOUNDARY DATED MAY 19, 2015 WAS OBTAINED FROM WSP OF CARY, NORTH CAROLINA. 2. SELECT TOPOGRAPHIC ADJUSTMENTS BASED ON SITE SURVEY AND COMPARISON TO AERIAL PHOTOGRAPH. 3. 2015 LITHOLOGY INFORMATION OF SOIL AND WELL LOG TOPOGRAPHY IS FROM SYNTERRA. 4. GEOLOGIC INFORMATION FOR BORINGS AND MONITORING WELLS INSTALLED PRIOR TO 2015 TAKEN FROM S&ME (2010) AND QUANTEX (2008). NOTE.- 1 . CROSS SECTION LOCATIONS SHOWN ON FIGURE 2-1. 2. WATER LEVELS WERE COLLECTED BY SYNTERRA ON JUNE 17, 2015. 3. 2L VALUE FOR BARIUM IS 700 pg/L. erra 148 River Street, Suite 220 Greenville, South Carolina 29601 864-421-9999 www.synterracorp.com DRAWN BY: C. NEWELL DATE: 8/5/2015 CHECKED BY: J. WYLIE DATE: 8/5/2015 PROJECT MANAGER: K. WEBB LAYOUT NAME: FIGURE 11-313 DUKE ENERGY boo PROGRESS MAYO STEAM ELECTRIC PLANT 10660 BOSTON RD 60 ROXBORO, NORTH CAROLINA IN FEET VERTICAL: 1"=30' NOTE: 10:1 VERTICAL EXAGGERATION FIGURE 11-3b GEOLOGIC CROSS SECTION C-C' WITH BARIUM I Cl%CA1r% tiA 70 LEI C� 4 Q W U O Q U) (a) ta.0 IL tao i o 0- (3) CC a W U c� / (>3 d a) U) a) v7 >Q 0 C= CID m Q O ca L6 O O N 0 vi U) a) w 0 n E. a) C U-I 0 0 rag h ti N C'0 LO O N 00 N 0 620 610 600 590 580 570 560 550 540 530 520 510 500 490 480 ow 470 M� aa) 460 LLI 450 440 430 420 410 400 390 380 370 360 350 340 330 320 310 300 620 610 600 590 580 570 560 550 540 530 520 510 500 490 480 470 460 450 440 430 420 410 400 390 LU LU 3E CO CO LU Z_ J U Q �. 300 O O O O o O O O O O O O O O O O O o O O O o O O O O O O O O O O O O O O O O O O O O O O O O o O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O o O O O O O O O O O O O O o O O O O o O o O O CD o O O O O O O O O O O O O O O O O o O O o O O O O O O O O O O O O O O O O O O O O O O O O O O O + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + O N M d co r'- M O CD- N M ,I-LO CO r- CO O O �- N CO � LO (D r-- 00 M CD- N M "I- LIDCfl ti CID O �- N M � Ln CO r` M M O N M -' LID CO r1- M O CD- N M ,I- LO (fl r- M M CD M 'z Lo •- - - - - - - c- N N N N N N N N N N co co M M co co co co M M It" It I- dt It It cp It IT U') LO LID LO LO LID LO LO LID LO CO CO CO (0 (0 CO CO CO (0 (0 r- ti r- ti ti r- SOUTHWEST Station (feet) S113-7 SECTION B-B' - BORON 1'-2': Sb <5.8 / As <5.8 / Ba 68.8 / B <14.5 / Cr 11.4 / Co 5.9 / Fe 9460 / Mn 693 / TI <5.8 / V 17.6 FACING NORTHWEST 4.5'-7.5': Sb <6 / As <6 / Ba 15.5 / B <15 / Cr 8.2 / Co <6 / Fe 6040 / M n 226 / TI <6 / V 8.2 MENhow- - Not M W-3 MW-3: pH 5.71 / Sb <1 / As <1 / Ba 56 / B 847 / Cr(VI) 0.155 / Co <1 / Fe 34 / Mn 880 / TI <0.2 / TDS 190 / V <0.3 COAL ASH TRANSITION ZONE - - - - BEDROCK SOIL/FILL SAPROLITE ALLUVIUM CONCENTRATION CONTOUR CONCENTRATION CONTOURS DASHED WHERE INFERRED HASH MARKS POINT TO DECREASING CONCENTRATIONS WATER LEVEL (JUNE 17, 2015) SURFICIAL WATER LEVEL TRANSITION ZONE WATER LEVEL BEDROCK WATER LEVEL o� �/ FRACTURED/OXIDIZED ZONE m OBSERVED IN ROCK CORE w` NOT SAMPLED ABMW-02BR: WATER ANALYTICAL RESULTS IN pg/L 45'-45.5' SOIL TOTAL ANALYTICAL RESULTS IN mg/kg BORING SYMBOLS SOIL SAMPLE WELL SCREEN WITH CONCENTRATION (micrograms per liter) SOURCES.- 1 THE TOPOGRAPHY SURVEY DATA WITHIN THE PROPERTY BOUNDARY DATED MAY 19, 2015 WAS OBTAINED FROM WSP OF CARY, NORTH CAROLINA. 2. SELECT TOPOGRAPHIC ADJUSTMENTS BASED ON SITE SURVEY AND COMPARISON TO AERIAL PHOTOGRAPH. 3. 2015 LITHOLOGY INFORMATION OF SOIL AND WELL LOG TOPOGRAPHY IS FROM SYNTERRA. 4. GEOLOGIC INFORMATION FOR BORINGS AND MONITORING WELLS INSTALLED PRIOR TO 2015 TAKEN FROM S&ME (2010) AND QUANTEX (2008). NOTE: 1. CROSS SECTION LOCATIONS SHOWN ON FIGURE 2-1. 2. WATER LEVELS WERE COLLECTED BY SYNTERRA ON JUNE 17, 2015. 3. 2L VALUE FOR BORON IS 700 pg/L. CW-2/ 2D 470 1 1 1 1 1 CW-2: pH 6.5 / Sb <1 / As <1 / Ba 54 / B 804 / Cr(VI) <0.021 / Co <1 / Fe 467 / Mn 135 / TI <0.2 /TDS 370 / V 5.88 CW-211): pH 6.1 / Sb <1 / As <1 / Ba 38 / B 363 / Cr(VI) 0.084 / Co <1 / Fe 278 / Mn 81 / TI <0.2 / TDS 250 / V 0.585 460 460 aW!g 50 Q MW-16S/ 16D/ 16BR p MW-16S: pH 6.02 / Sb <1 / As <1 / Ba 46 / B <50 / Cr(VI) 0.011 / Co 4.32 / Fe 860 / Mn 260 / TI <0.2 / TDS 100 / V 0.303 4 0 MW-16D: pH7.1/Sb<1/As<1/Ba13/B<50/Cr(VI)0.051/Co<1/Fe87/Mn269/TI<0.2/TDS160/V0.617 W 43 MW-16BR: pH8.67/Sb<1/As2.05/Ba11/B<50/Cr(VI)0.017/Co<1/Fe80/Mn30/TI<0.2/TDS170/V2.79 Q 1'-2':Sb<6.5/As<6.5/Ba95.4/B<16.2/Cr7.6/Co6j/Fe7710/Mn1250/TI<6.5/V17.3 J 23'-24': Sb<5/As<5/Ba28.2/B10j/Cr2.1/Co4.6j/Fe10600/Mn885/TI<5/V8.4 erra 420 33'-35':Sb<7.5/As<7.5/Ba131/B16.8j/Cr9.2/Co12/Fe19100/Mn1630/TI<7.5/V16.3 410-7 � 1� � 54.5'-55.5': Sb <5.2 / As <5.2 / Ba 237 / B 32.3 / Cr 37.2 / Co 19.6 / Fe 38300 / Mn 1010 / TI <5.2 / V 87 148 River Street, Suite 220 � p Greenville, South Carolina 29601 400 w 400 864-421-9999 LL www.synterracorp.com 390 w 2 2 390 F- H z DRAWN BY: C. NEWELL DATE: 8/5/2015 380 U D Q 380 CHECKED BY: J. WYLIE DATE: 8/5/2015 w 804 rle U m 370 PROJECT MANAGER: K. WEBB W LAYOUT NAME: FIGURE 11-4A _ - <50 360 07 _ _ 350 DUKE 340 -363- z - - - - 330 GRAPHIC SCALE E N E RGY -j --- ---- --- --- --- --- ---- --- . . . . .--- --- --- --- 320 300 0 300 600 PROGRESS � --- --- ---_ --- --- _ ---- <50- ---_ --- IN FEET Q 310 MAYO STEAM ELECTRIC PLANT HORIZONTAL:1"=300' 10660 BOSTON RD --- --- ---- ---- --- 300 - - - - - - - - - - - - - - - 300 30 0 30 60 ROXBORO, NORTH CAROLINA o O O O O O O O O O O O O O O O 0 o O o O O O O O O O O o O O O + + + + + + + + + + + + + + + + CO rl- 00 O O N CO � LO (0r--00 M CD IN FEET FIGURE 11-4a r` r_ r-- co 00 00 co 0o co co 0o co co M rn NORTHEAST VERTICAL:1"=30' GEOLOGIC CROSS SECTION B-B' SECTION B-B' - BORON NOTE: 10:1 VERTICAL EXAGGERATION FACING NORTHWEST WITH BORON I 0t'%0A1r% tiA LU n, C� Q W U O Q / U) a) YaA IL 1a0 O 0- 0) a W U rl / C6 n a) E U) 0) U) Cn a 0 Cn M m Cn a 0 I6 O / N O vi U) a) w 0 n E. a) LU 0 / WE 00 N ri LO O N 00 N 0 MW-13BR MW-13BR: pH7.2/Sb<1/As<1/Ba40/B<50/Cr(VI)0.005/Col.19/Fe1130/Mn474/TI<0.2/TDS370/V0.381 0'-2': Sb<6.5/As<6.5/Ba72.9/B<16.3/Cr6.1/Co<6.5/Fe19600/Min 82.8/TI<6.5/V32.4 52'-54': Sb<5.1/As<5.1/Ba62.3/B<2.5/Cr9.2/Co6.6/Fe10400/Min 789/TI<5.1/V13.1 ABMW-02/ 02BR ABMW-02: pH 7.8 / Sb <1 / As 1020 / Ba 173 / B 9200 / Cr(VI) 0.017 / Co <1 / Fe 356 / Mn 1110 / TI <0.2 / TDS 450 / V 3.53 ABMW-02BR: pH 7.2 / Sb <1 / As <1 / Ba 159 / B <50 / Cr(VI) 0.007 / Co <1 / Fe 107 / Mn 149 / TI <0.2 / TDS 370 / V 0.873 45'-45.5': Sb<6/As<6/Ba92.2/B<15/Cr8/Co6j/Fe18300/Mn579/TI<6/V30.3 57.5'-58': Sb<5.1/As<5.1/Ba41.2/B<12.8/Cr56.7/Co37.4/Fe43400/Mn782/TI<5.1/V84.9 ABMW-03/ 03S rm=mmmmmmm SEEMS lip, IN IN-0 u Moll ago ME WFI-Ifth A all I MEMO OEM s y MW-07D/ 07BR MW-07D: pH 6.4 / Sb <1 / As <1 / Ba 24 / B <50 / Cr(VI) NS / Co <1 / Fe 69 / Mn 188 / TI <0.2 / TDS 390 / V 0.798 MW-07BR: pH 7.4 / Sb <1 / As <1 / Ba 140 / B <50 / Cr(VI) NS / Co <1 / Fe 339 / Mn 263 / TI <0.2 / TDS 270 / V <0.3 C 1 550 1'-2': Sb<5.1/As<5.1/Ba21.5/B<12.8/Cr4.1/Co<5.1/Fe7320/Mn27.7/TI<5.1/V12.8 550 540 540 MW-08S/ 08D/ 08BR 530 p MW-08BR: pH 6.56 / Sb <1 / As <1 / Ba 66 / B <50 / Cr(VI) NS / Co <1 / Fe 2200 / Mn 2680 / TI <0.2 / TDS 550 / V <0.3 a0 0.75'-1.25': Sb <3.2 / As <3.2 / Ba 147 / B <63.4 / Cr 62.2 / Co 21.3 / Fe 24700 / Mn 1230 / TI <3.2 / V 50.6 520 25.5'-26': Sb<2.7/As<2.7/Ba193/B31j/Cr419/Co32.9/Fe31300/Mn933/TI<2.7/V75.8 30.5'-31': Sb <2.7 / As <2.7 Ba 130 B <53.1 Cr 67.1 Co 7.4 Fe 11400 Mn 875 / TI <2.7 / V 25.2 SECTION C-C' - BORON FACING NORTH GRAPHIC SCALE 300 0 300 IN FEET HORIZONTAL: 1"=300' 30 0 30 ICOALASH TRANSITION ZONE BEDROCK SOIL/FILL SAPROLITE ALLUVIUM CONCENTRATION CONTOUR CONCENTRATION CONTOURS DASHED WHERE INFERRED HASH MARKS POINT TO DECREASING CONCENTRATIONS V WATER LEVEL (JUNE 17, 2015) SURFICIAL WATER LEVEL TRANSITION ZONE WATER LEVEL BEDROCK WATER LEVEL FRACTURED/OXIDIZED ZONE OBSERVED IN ROCK CORE NS NOT SAMPLED ABMW-02BR: WATER ANALYTICAL RESULTS IN pg/L 45'-45.5' SOIL TOTAL ANALYTICAL RESULTS IN mg/kg BORING SYMBOLS SOIL SAMPLE WELL SCREEN WITH CONCENTRATION (micrograms per liter) SOURCES.- 1 THE TOPOGRAPHY SURVEY DATA WITHIN THE PROPERTY BOUNDARY DATED MAY 19, 2015 WAS OBTAINED FROM WSP OF CARY, NORTH CAROLINA. 2. SELECT TOPOGRAPHIC ADJUSTMENTS BASED ON SITE SURVEY AND COMPARISON TO AERIAL PHOTOGRAPH. 3. 2015 LITHOLOGY INFORMATION OF SOIL AND WELL LOG TOPOGRAPHY IS FROM SYNTERRA. 4. GEOLOGIC INFORMATION FOR BORINGS AND MONITORING WELLS INSTALLED PRIOR TO 2015 TAKEN FROM S&ME (2010) AND QUANTEX (2008). NOTE.- 1 . CROSS SECTION LOCATIONS SHOWN ON FIGURE 2-1. 2. WATER LEVELS WERE COLLECTED BY SYNTERRA ON JUNE 17, 2015. 3. 2L VALUE FOR BORON IS 700 pg/L. erra 148 River Street, Suite 220 Greenville, South Carolina 29601 864-421-9999 www.synterracorp.com DRAWN BY: C. NEWELL DATE: 8/5/2015 CHECKED BY: J. WYLIE DATE: 8/5/2015 PROJECT MANAGER: K. WEBB LAYOUT NAME: FIGURE 11-413 DUKE ENERGY boo PROGRESS MAYO STEAM ELECTRIC PLANT 10660 BOSTON RD 60 ROXBORO, NORTH CAROLINA IN FEET VERTICAL: 1"=30' NOTE: 10:1 VERTICAL EXAGGERATION FIGURE 11-4b GEOLOGIC CROSS SECTION C-C' WITH BORON 1 0t'%0A1r% U0 w Of LL Q W 0 O 75 a� la,0 IL w C O Q- (1) Q W 0 r-I r-I / c co IZ C N V7 N N v7 Q C co m Q O 03 Ln O C9 N O vi CAI tuo O m w N 0 / Iry 75 a- 117-1 cm &5 LO 117-1 N N 0 620 610 600 590 580 570 560 550 540 530 520 510 500 490 480 o� 470 460 w= 450 440 430 420 410 400 390 380 370 360 350 340 330 320 310 300 620 610 600 590 580 570 560 550 540 530 520 510 500 490 480 470 460 450 440 430 420 410 400 390 W LU CO CO LU Z_ J U Q �. 300 O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + O N M d co ti M O CD- N M ,I-LO CO I- CO O O �- N CO � LO (D � co M CD- N M "I-LO Cfl ti co O �- N M � Ln CO f-- M M O N M -' Lo CO fl- M O CD- N M ,I- LO (fl ti M M CD N M 'z LID •- - - - - - - c- N N N N N N N N N N co co M M co co co co M M It " It I- dt It It cp It IT Lr) LO LID LO LO LID LO LO LID LO CO CO CO (0 (0 CO CO CO (0 (0r- ti r- ti ti r- SOUTHWEST Station (feet) SB-7 SECTION B-B' - COBALT 1'-2': Sb <5.8 / As <5.8 / Ba 68.8 / B <14.5 / Cr 11.4 / Co 5.9 / Fe 9460 / Mn 693 / TI <5.8 / V 17.6 FACING NORTHWEST 4.5'-7.5':Sb<6/As<6/Ba15.5/B<15/Cr8.2/Co<6/Fe6040/Mn226/TI<6/V8.2 MW-3 MW-3: pH5.71/Sb<1/As<1/Ba56/B847/Cr(VI)0.155/Co<1/Fe34/Mn880/TI<0.2/TDS190/V<0.3 IN pip COAL ASH TRANSITION ZONE SOIL/FILL SAPROLITE ALLUVIUM CONCENTRATION CONTOUR CONCENTRATION CONTOURS DASHED WHERE INFERRED HASH MARKS POINT TO DECREASING CONCENTRATIONS WATER LEVEL (JUNE 17, 2015) SURFICIAL WATER LEVEL TRANSITION ZONE WATER LEVEL BEDROCK WATER LEVEL .2u) FRACTURED/OXIDIZED ZONE m OBSERVED IN ROCK CORE w` NOT SAMPLED ABMW-02BR: WATER ANALYTICAL RESULTS IN pg/L 45'-45.5' SOIL TOTAL ANALYTICAL RESULTS IN mg/kg BORING SYMBOLS SOIL SAMPLE WELL SCREEN WITH CONCENTRATION (micrograms per liter) SOURCES: 1. THE TOPOGRAPHY SURVEY DATA WITHIN THE PROPERTY BOUNDARY DATED MAY 19, 2015 WAS OBTAINED FROM WSP OF CARY, NORTH CAROLINA. 2. SELECT TOPOGRAPHIC ADJUSTMENTS BASED ON SITE SURVEY AND COMPARISON TO AERIAL PHOTOGRAPH. 3. 2015 LITHOLOGY INFORMATION OF SOIL AND WELL LOG TOPOGRAPHY IS FROM SYNTERRA. 4. GEOLOGIC INFORMATION FOR BORINGS AND MONITORING WELLS INSTALLED PRIOR TO 2015 TAKEN FROM S&ME (2010) AND QUANTEX (2008). NOTE: 1. CROSS SECTION LOCATIONS SHOWN ON FIGURE 2-1. 2. WATER LEVELS WERE COLLECTED BY SYNTERRA ON JUNE 17, 2015. 3. IMAC VALUE FOR COBALT IS 1 pg/L. CW-2/ 2D 470 1 1 1 1CW-2: pH 6.5 / Sb <1 / As <1 / Ba 54 / B 804 / Cr(VI) <0.021 / Co <1 / Fe 467 / Mn 135 / TI <0.2 /TDS 370 / V 5.88 CW-211): pH 6.1 / Sb <1 / As <1 / Ba 38 / B 363 / Cr(VI) 0.084 / Co <1 / Fe 278 / Mn 81 / TI <0.2 / TDS 250 / V 0.585 460 460 50 Q MW-16S/ 16D/ 16BR p MW-16S: pH 6.02 / Sb <1 / As <1 / Ba 46 / B <50 / Cr(VI) 0.011 / Co 4.32 / Fe 860 / Mn 260 / TI <0.2 / TDS 100 / V 0.303 4 0 MW-16D: pH7.1/Sb<1/As<1/Ba13/B<50/Cr(VI)0.051/Co<1/Fe87/Mn269/TI<0.2/TDS160/V0.617 w 43 MW-16BR: pH8.67/Sb<1/As2.05/Ba11/B<50/Cr(VI)0.017/Co<1/Fe80/Mn30/TI<0.2/TDS170/V2.79 Q 1'-2':Sb<6.5/As<6.5/Ba95.4/B<16.2/Cr7.6/Co6j/Fe7710/Mn1250/TI<6.5/V17.3 J 23'-24': Sb<5/As<5/Ba28.2/B10j/Cr2.1/Co4.6j/Fe10600/Mn885/TI<5/V8.4 erra 420 33'-35': Sb <7.5 / As <7.5 / Ba 131 / B 16.8 j / Cr 9.2 / Co 12 / Fe 19100 / Mn 1630 / TI <7.5 / V 16.3 410 < 54.5'-55.5': Sb <5.2 / As <5.2 / Ba 237 / B 32.3 / Cr 37.2 / Co 19.6 / Fe 38300 / Mn 1010 / TI <5.2 / V 87 148 River Street, Suite 220 p Greenville, South Carolina 29601 400 w 400 864-421-9999 www.synterracorp.com 390 w 2 2 390 H z DRAWN BY: C. NEWELL DATE: 8/5/2015 380 D < 380 CHECKED BY: J. WYLIE DATE: 8/5/2015 11 j 7 0 co 370 PROJECT MANAGER: K. WEBB LU _ LAYOUT NAME: FIGURE 11-5A = _ _ ! 4.32 360 C0 DUKE_ _ --- --- 350 340 LU z _ _ _ `1 _ _ _ _ <1 330 GRAPHIC SCALE J--- --- --- ---- - - - - - - - - - - - - - - --- -_-_-_ --- -_-_-_ ---_ _--_ --- ---_ --- -_-- 320 PROGRESS --- --- ---_ ------ --- `1-- ---_ --- IN FEET 310 HORIZONTAL: 1"=300' MAYO STEAM ELECTRIC PLANT --- ---_ ---_ ---- --- 10660 BOSTON RD --- --- ---- ---- --- 300 - - - - - - - - - - - - - - - 300 30 0 30 60 ROXBORO, NORTH CAROLINA O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O + + + + + + + + + + + + + + + + IN FEET 00 M O N CO � (0� 00 M O FIGURE 11-5a 00 00 00 00 00 00 00 00 00 M NORTHEAST VERTICAL:1"=30' GEOLOGIC CROSS SECTION B-B' SECTION B-B' - COBALT NOTE: 10:1 VERTICAL EXAGGERATION FACING NORTHWEST WITH COBALT I 0t'%0A1r% tiA LU n, C� Q W U O Q U) a) taA IL 1a0 O 0- 0) a W U rl / C6 n a) E U) 0) U) Cn a 0 Cn M m Cn a 0 I6 O / N O vi U) a) w 0 n E. a) LU 0 / WE c� M ri LO O N 00 N 0 MW-13BR MW-13BR: pH7.2/Sb<1/As<1/Ba40/B<50/Cr(VI)0.005/Col.19/Fe1130/Mn474/TI<0.2/TDS370/V0.381 0'-2': Sb<6.5/As<6.5/Ba72.9/B<16.3/Cr6.1/Co<6.5/Fe19600/Mn82.8/TI<6.5/V32.4 52'-54': Sb<5.1/As<5.1/Ba62.3/B<2.5/Cr9.2/Co6.6/Fe10400/Mn789/TI<5.1/V13.1 ABMW-02/ 02BR ABMW-02: pH 7.8 / Sb <1 / As 1020 / Ba 173 / B 9200 / Cr(VI) 0.017 / Co <1 / Fe 356 / Mn 1110 / TI <0.2 / TDS 450 / V 3.53 ABMW-02BR: pH 7.2 / Sb <1 / As <1 / Ba 159 / B <50 / Cr(VI) 0.007 / Co <1 / Fe 107 / Mn 149 / TI <0.2 / TDS 370 / V 0.873 45'-45.5': Sb<6/As<6/Ba92.2/B<15/Cr8/Co6j/Fe18300/Mn579/TI<6/V30.3 57.5'-58': Sb<5.1/As<5.1/Ba41.2/B<12.8/Cr56.7/Co37.4/Fe43400/Mn782/TI<5.1/V84.9 ABMW-03/ 03S BMV' mm. 1 6 in u 144 ROOM 44 ago b was I -To 01 tol, �p has -pirl s y MW-07D/ 07BR MW-07D: pH 6.4 / Sb <1 / As <1 / Ba 24 / B <50 / Cr(VI) NS / Co <1 / Fe 69 / Mn 188 / TI <0.2 / TDS 390 / V 0.798 MW-07BR: pH 7.4 / Sb <1 / As <1 / Ba 140 / B <50 / Cr(VI) NS / Co <1 / Fe 339 / Mn 263 / TI <0.2 / TDS 270 / V <0.3 C 1 550 1'-2': Sb<5.1/As<5.1/Ba21.5/B<12.8/Cr4.1/Co<5.1/Fe7320/Mn27.7/TI<5.1/V12.8 550 540 540 MW-08S/ 08D/ 08BR 530 p MW-08BR: pH 6.56 / Sb <1 / As <1 / Ba 66 / B <50 / Cr(VI) NS / Co <1 / Fe 2200 / Mn 2680 / TI <0.2 / TDS 550 / V <0.3 a0 0.75'-1.25': Sb <3.2 / As <3.2 / Ba 147 / B <63.4 / Cr 62.2 / Co 21.3 / Fe 24700 / Mn 1230 / TI <3.2 / V 50.6 520 25.5'-26': Sb<2.7/As<2.7/Ba193/B31j/Cr419/Co32.9/Fe31300/Mn933/TI<2.7/V75.8 30.5'-31': Sb <2.7 / As <2.7 Ba 130 B <53.1 Cr 67.1 Co 7.4 Fe 11400 Mn 875 / TI <2.7 / V 25.2 SECTION C-C' - COBALT FACING NORTH 510 500 490 w Q J a� TLIJ LU Z_ J U Q 400 'Coll" 380 370 360 GRAPHIC SCALE 300 0 300 IN FEET HORIZONTAL: 1"=300' 30 0 30 ICOALASH TRANSITION ZONE BEDROCK SOIL/FILL SAPROLITE ALLUVIUM CONCENTRATION CONTOUR CONCENTRATION CONTOURS DASHED WHERE INFERRED HASH MARKS POINT TO DECREASING CONCENTRATIONS V WATER LEVEL (JUNE 17, 2015) SURFICIAL WATER LEVEL TRANSITION ZONE WATER LEVEL BEDROCK WATER LEVEL FRACTURED/OXIDIZED ZONE OBSERVED IN ROCK CORE NS NOT SAMPLED ABMW-02BR: WATER ANALYTICAL RESULTS IN pg/L 45'-45.5' SOIL TOTAL ANALYTICAL RESULTS IN mg/kg BORING SYMBOLS SOIL SAMPLE WELL SCREEN WITH CONCENTRATION (micrograms per liter) SOURCES: 1. THE TOPOGRAPHY SURVEY DATA WITHIN THE PROPERTY BOUNDARY DATED MAY 19, 2015 WAS OBTAINED FROM WSP OF CARY, NORTH CAROLINA. 2. SELECT TOPOGRAPHIC ADJUSTMENTS BASED ON SITE SURVEY AND COMPARISON TO AERIAL PHOTOGRAPH. 3. 2015 LITHOLOGY INFORMATION OF SOIL AND WELL LOG TOPOGRAPHY IS FROM SYNTERRA. 4. GEOLOGIC INFORMATION FOR BORINGS AND MONITORING WELLS INSTALLED PRIOR TO 2015 TAKEN FROM S&ME (2010) AND QUANTEX (2008). NOTE: 1. CROSS SECTION LOCATIONS SHOWN ON FIGURE 2-1. 2. WATER LEVELS WERE COLLECTED BY SYNTERRA ON JUNE 17, 2015. 3. IMAC VALUE FOR COBALT IS 1 fag/L. erra 148 River Street, Suite 220 Greenville, South Carolina 29601 864-421-9999 www.synterracorp.com DRAWN BY: C. NEWELL DATE: 8/5/2015 CHECKED BY: J. WYLIE DATE: 8/5/2015 PROJECT MANAGER: K. WEBB LAYOUT NAME: FIGURE 11-513 DUKE ENERGY boo PROGRESS MAYO STEAM ELECTRIC PLANT 10660 BOSTON RD 60 ROXBORO, NORTH CAROLINA IN FEET VERTICAL: 1"=30' NOTE: 10:1 VERTICAL EXAGGERATION FIGURE 11-5b GEOLOGIC CROSS SECTION C-C' WITH COBALT 1 0t'%0A1r% 1ao v7 LU n, C� L7 Q W U O Q a� 1ao IL 1ao O 0- (3) a W U �i / C6 0 E U) 0 U) Cn >a 0 Cn M m Cn Q 0 c>3 L6 O / O N O vi U) N w 0 n E. a� LU 0 0 / .E LO co ri LO O N 00 N 0 620 610 600 590 580 570 560 550 540 530 520 510 500 490 480 ow 470 M� 460 L1J 450 440 430 420 410 400 390 380 370 360 350 340 330 320 310 300 MEN S121011 milk! M1 =11 wo Ila O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O OD O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + O N M d co r'- M O CD- N M ,I-LO CO r- CO O O �- N CO � LO (D r-- 00 M CD- N M "I-LO co rl- co O �- N M � Ln CO r` M M O N M -' Lo CO rl- M O CD- N M ,I- LO CO r- M M CD M 'z Lo •- - - - - - - c- N N N N N N N N N N co co M M co co co co M M It" It I- dt It It cp It IT U') LO LO LO LO LO LO LO LO LO CO CO CO (0 (0 CO CO CO (0 (0 r- rl-r- rl- rl-r- SOUTHWEST Station (feet) SB-7 SECTION B-B' - IRON 1'-2': Sb <5.8 / As <5.8 / Ba 68.8 / B <14.5 / Cr 11.4 / Co 5.9 / Fe 9460 / Mn 693 / TI <5.8 / V 17.6 FACING NORTHWEST 4.5'-7.5':Sb<6/As<6/Ba15.5/B<15/Cr8.2/Co<6/Fe6040/Mn226/TI<6/V8.2 M W-3 MW-3: pH 5.71 / Sb <1 / As <1 / Ba 56 / B 847 / Cr(VI) 0.155 / Co <1 / Fe 34 / Mn 880 / TI <0.2 / TDS 190 / V <0.3 CW-2/ 2D CW-2: pH 6.5 / Sb <1 / As <1 / Ba 54 / B 804 / Cr(VI) <0.021 / Co <1 / Fe 467 / Mn 135 / TI <0.2 / TDS 370 / V 5.88 470 CW-211): pH6.1/Sb<1/As<1/Ba38/B363/Cr(VI)0.084/Co<1/Fe278/Mn81/TI<0.2/TDS250/V0.585 77 460 460 Q MW-16S/ 16D/ 16BR 50 Q MW-16S: pH 6.02 / Sb <1 / As <1 / Ba 46 / B <50 / Cr(VI) 0.011 / Co 4.32 / Fe 860 / Mn 260 / TI <0.2 / TDS 100 / V 0.303 MW-16D: pH7.1/Sb<1/As<1/Ba13/B<50/Cr(VI)0.051/Co<1/Fe87/Mn269/TI<0.2/TDS160/V0.617 4 0 L1J MW-16BR: pH8.67/Sb<1/As2.05/Ba11/B<50/Cr(VI)0.017/Co<1/Fe80/Mn30/TI<0.2/TDS170/V2.79 Q 1'-2':Sb<6.5/As<6.5/Ba95.4/B<16.2/Cr7.6/Co6j/Fe7710/Mn1250/TI<6.5/V17.3 43 J 23'-24': Sb<5/As<5/Ba28.2/B10j/Cr2.1/Co4.6j/Fe10600/Mn885/TI<5/V8.4 420 33'-35':Sb<7.5/As<7.5/Ba131/B16.8j/Cr9.2/Co12/Fe19100/Mn1630/TI<7.5/V16.3 Q 54.5'-55.5': Sb <5.2 / As <5.2 / Ba 237 / B 32.3 / Cr 37.2 / Co 19.6 / Fe 38300 / Mn 1010 / TI <5.2 / V 87 410 0 400 W 400 < w LL 2 2 390 390 U U D LU Q 380 LU 0� IY 467 U m 370 07 _ _30017, 860 360 ~ --- LLI 350 --- z 340 -278_ _ 87 _ --- --- - --- -- 330 CC --- --- ---- ---- ---320 ------__---- --- 80._ --- --- --- --- ---_ 310 310 - - - - - - 300 300 O O O O O CDO O O O O O O O O O O O O O O CDO O O O CD O O CD CD + + + CO rl- 00 + + + + + + + + + + + + + O O N CO � LO O r-- 00 O O f� ti rl- 00 00 00 0o co 0o co 00 0o co O O NORTHEAST SECTION B-B' - IRON FACING NORTHWEST 620 610 600 590 580 570 560 550 540 530 520 510 500 490 480 470 460 450 440 430 420 410 400 390 LU LU 3E CO CO LU - Z_ J U Q COAL ASH TRANSITION ZONE - - - - BEDROCK SOIL/FILL SAPROLITE ALLUVIUM CONCENTRATION CONTOUR CONCENTRATION CONTOURS DASHED WHERE INFERRED HASH MARKS POINT TO DECREASING CONCENTRATIONS WATER LEVEL (JUNE 17, 2015) SURFICIAL WATER LEVEL TRANSITION ZONE WATER LEVEL BEDROCK WATER LEVEL 2J FRACTURED/OXIDIZED ZONE m OBSERVED IN ROCK CORE w` NOT SAMPLED ABMW-02BR: WATER ANALYTICAL RESULTS IN pg/L 45'-45.5' SOIL TOTAL ANALYTICAL RESULTS IN mg/kg BORING SYMBOLS GRAPHIC SCALE 0 300 IN FEET HORIZONTAL: 1"=300' 0 30 IN FEET VERTICAL: 1"=30' NOTE: 10:1 VERTICAL EXAGGERATION SOIL SAMPLE WELL SCREEN WITH CONCENTRATION (micrograms per liter) SOURCES. 1. THE TOPOGRAPHY SURVEY DATA WITHIN THE PROPERTY BOUNDARY DATED MAY 19, 2015 WAS OBTAINED FROM WSP OF CARY, NORTH CAROLINA. 2. SELECT TOPOGRAPHIC ADJUSTMENTS BASED ON SITE SURVEY AND COMPARISON TO AERIAL PHOTOGRAPH. 3. 2015 LITHOLOGY INFORMATION OF SOIL AND WELL LOG TOPOGRAPHY IS FROM SYNTERRA. 4. GEOLOGIC INFORMATION FOR BORINGS AND MONITORING WELLS INSTALLED PRIOR TO 2015 TAKEN FROM S&ME (2010) AND QUANTEX (2008). NOTE.- 1 . CROSS SECTION LOCATIONS SHOWN ON FIGURE 2-1. 2. WATER LEVELS WERE COLLECTED BY SYNTERRA ON JUNE 17, 2015. 3. 2L VALUE FOR IRON IS 300 pg/L. erra 148 River Street, Suite 220 Greenville, South Carolina 29601 864-421-9999 www.synterracorp.com DRAWN BY: C. NEWELL DATE: 8/5/2015 CHECKED BY: J. WYLIE DATE: 8/5/2015 PROJECT MANAGER: K. WEBB LAYOUT NAME: FIGURE 11-6A (� DUKE � ENERGY PROGRESS MAYO STEAM ELECTRIC PLANT 10660 BOSTON RD ROXBORO, NORTH CAROLINA FIGURE 11-6a GEOLOGIC CROSS SECTION B-B' WITH IRON I 0t'%0A1r% tiA w n, C� Q W U O Q U) a) YaA IL 1a0 O 0- 0) a W U rl / C6 n 0) E U) 0) U) Cn a 0 Cn M m Cn a 0 I6 O / N O vi U) a) w 0 n E. a) w 0 / WE 7 MW-13BR MW-13BR: pH7.2/Sb<1/As<1/Ba40/B<50/Cr(VI)0.005/Col.19/Fe1130/Mn474/TI<0.2/TDS370/V0.381 0'-2': Sb<6.5/As<6.5/Ba72.9/B<16.3/Cr6.1/Co<6.5/Fe19600/Mn82.8/TI<6.5/V32.4 52'-54': Sb<5.1/As<5.1/Ba62.3/B<2.5/Cr9.2/Co6.6/Fe10400/Mn789/TI<5.1/V13.1 ABMW-02/ 02BR ABMW-02: pH 7.8 / Sb <1 / As 1020 / Ba 173 / B 9200 / Cr(VI) 0.017 / Co <1 / Fe 356 / Mn 1110 / TI <0.2 / TDS 450 / V 3.53 ABMW-02BR: pH 7.2 / Sb <1 / As <1 / Ba 159 / B <50 / Cr(VI) 0.007 / Co <1 / Fe 107 / Mn 149 / TI <0.2 / TDS 370 / V 0.873 45'-45.5': Sb<6/As<6/Ba92.2/B<15/Cr8/Co6j/Fe18300/Mn579/TI<6/V30.3 57.5'-58': Sb<5.1/As<5.1/Ba41.2/B<12.8/Cr56.7/Co37.4/Fe43400/Mn782/TI<5.1/V84.9 ABMW-03/ 03S BMV' mm. 1 6 in u 144 ROOM ION b was � 44 oil i4!6 *Ate* i", rig 1111111111111111101111 MIN IN Manor, Mel 121 loan Egli �s MW-07D/ 07BR MW-07D: pH 6.4 / Sb <1 / As <1 / Ba 24 / B <50 / Cr(VI) NS / Co <1 / Fe 69 / Mn 188 / TI <0.2 / TDS 390 / V 0.798 MW-07BR: pH 7.4 / Sb <1 / As <1 / Ba 140 / B <50 / Cr(VI) NS / Co <1 / Fe 339 / Mn 263 / TI <0.2 / TDS 270 / V <0.3 C 1 550 1'-2': Sb<5.1/As<5.1/Ba21.5/B<12.8/Cr4.1/Co<5.1/Fe7320/Mn27.7/TI<5.1/V12.8 550 540 7FTT7 540 MW-08S/ 08D/ 08BR 530 p MW-08BR: pH 6.56 / Sb <1 / As <1 / Ba 66 / B <50 / Cr(VI) NS / Co <1 / Fe 2200 / Mn 2680 / TI <0.2 / TDS 550 / V <0.3 a0 0.75'-1.25': Sb <3.2 / As <3.2 / Ba 147 / B <63.4 / Cr 62.2 / Co 21.3 / Fe 24700 / Mn 1230 / TI <3.2 / V 50.6 520 w 25.5'-26': Sb<2.7/As<2.7/Ba193/B31j/Cr419/Co32.9/Fe31300/Mn933/TI<2.7/V75.8 30.5'-31': Sb <2.7 / As <2.7 Ba 130 B <53.1 Cr 67.1 Co 7.4 Fe 11400 Mn 875 / TI <2.7 / V 25.2 ML MIIIIM SECTION C-C' - IRON FACING NORTH 510 500 490 %E0, LU LU _ 2 0 J r� LU Z_ J U Q 400 390 380 370 360 GRAPHIC SCALE 300 0 300 IN FEET HORIZONTAL: 1"=300' 30 0 30 ICOALASH TRANSITION ZONE BEDROCK SOIL/FILL SAPROLITE ALLUVIUM CONCENTRATION CONTOUR CONCENTRATION CONTOURS DASHED WHERE INFERRED HASH MARKS POINT TO DECREASING CONCENTRATIONS w WATER LEVEL (JUNE 17, 2015) SURFICIAL WATER LEVEL TRANSITION ZONE WATER LEVEL BEDROCK WATER LEVEL FRACTURED/OXIDIZED ZONE OBSERVED IN ROCK CORE NS NOT SAMPLED ABMW-02BR: WATER ANALYTICAL RESULTS IN pg/L 45'-45.5' SOIL TOTAL ANALYTICAL RESULTS IN mg/kg BORING SYMBOLS SOIL SAMPLE WELL SCREEN WITH CONCENTRATION (micrograms per liter) SOURCES.- 1 THE TOPOGRAPHY SURVEY DATA WITHIN THE PROPERTY BOUNDARY DATED MAY 19, 2015 WAS OBTAINED FROM WSP OF CARY, NORTH CAROLINA. 2. SELECT TOPOGRAPHIC ADJUSTMENTS BASED ON SITE SURVEY AND COMPARISON TO AERIAL PHOTOGRAPH. 3. 2015 LITHOLOGY INFORMATION OF SOIL AND WELL LOG TOPOGRAPHY IS FROM SYNTERRA. 4. GEOLOGIC INFORMATION FOR BORINGS AND MONITORING WELLS INSTALLED PRIOR TO 2015 TAKEN FROM S&ME (2010) AND QUANTEX (2008). NOTE: 1. CROSS SECTION LOCATIONS SHOWN ON FIGURE 2-1. 2. WATER LEVELS WERE COLLECTED BY SYNTERRA ON JUNE 17, 2015. 3. 2L VALUE FOR IRON IS 300 pg/L. erra 148 River Street, Suite 220 Greenville, South Carolina 29601 864-421-9999 www.synterracorp.com DRAWN BY: C. NEWELL DATE: 8/5/2015 CHECKED BY: J. WYLIE DATE: 8/5/2015 PROJECT MANAGER: K. WEBB LAYOUT NAME: FIGURE 11-613 DUKE ENERGY boo PROGRESS MAYO STEAM ELECTRIC PLANT 10660 BOSTON RD 60 ROXBORO, NORTH CAROLINA IN FEET VERTICAL: 1"=30' NOTE: 10:1 VERTICAL EXAGGERATION FIGURE 11-6b GEOLOGIC CROSS SECTION C-C' WITH IRON 1 0t'%0A1r% U0 w Of LL Q W U O 75 a� la,0 IL w O tf O Q- (1) Q W U r-I r-I / c CIO C N N N to Q 0 C6 m Q O O Ln O / C9 N O r-i vi N U0 O N s= w N 75 0- cm cri LO O N N 0 620 610 600 590 580 570 560 550 540 530 520 510 500 490 480 ow 470 M� aa) 460 w= 450 440 430 420 410 400 390 380 370 360 350 340 330 320 310 300 NONE ---------------------------------------------------------------------------------------------------- Immommomms son loss monsoons ------------ - Pr - mama O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O OD O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + CD N M d co ti M O N M ,I-LO CO I- CO O O �- N CO LO (D I` 00 M CD M "I-LO Cfl ti co O �- N M � Ln CO I-- M M O N M -' Lo CO I1- M O CD M ,I- LO (fl ti M M CDN M 'z LID •- - - - - - - c- N N N N N N N N N N co co M M co co co co M M It " It I- dt It It cp It IT Lr) LO LID LID LO LID LO LO LID LO CO CO CO (0 (0 CO CO CO (0 (0r- ti r- I` ti r- SOUTHWEST Station (feet) S113-7 SECTION B-B' - MANGANESE 1'-2': Sb <5.8 / As <5.8 / Ba 68.8 / B <14.5 / Cr 11.4 / Co 5.9 / Fe 9460 / Mn 693 / TI <5.8 / V 17.6 4.5'-7.5':Sb<6/As<6/Ba15.5/B<15/Cr8.2/Co<6/Fe6040/Mn226/TI<6/V8.2 MW-3 MW-3: pH5.71/Sb<1/As<1/Ba56/B847/Cr(VI)0.155/Co<1/Fe34/Mn880/TI<0.2/TDS 190/V<0.3 CW-2/ 2D 470 CW-2: pH 6.5 / Sb <1 / As <1 / Ba 54 / B 804 / Cr(VI) <0.021 / Co <1 / Fe 467 / Mn 135 / TI <0.2 / TDS 370 / V 5.88 CW-2D: pH 6.1 / Sb <1 / As <1 / Ba 38 / B 363 / Cr(VI) 0.084 / Co <1 / Fe 278 / Mn 81 / TI <0.2 / TDS 250 / V 0.585 460 T460 N a, 50 MW-16S/ 16D/ 16BR MW-16S: pH 6.02 / Sb <1 / As <1 / Ba 46 / B <50 / Cr(VI) 0.011 / Co 4.32 / Fe 860 / Mn 260 / TI <0.2 / TDS 100 / V 0.303 4 0 Q MW-16D: pH7.1/Sb<1/As<1/Ba13/B<50/Cr(VI)0.051/Co<1/Fe87/Mn269/TI<0.2/TDS160/V0.617 of MW-16BR: pH8.67/Sb<1/As2.05/Ba11/B<50/Cr(VI)0.017/Co<1/Fe80/Mn30/TI<0.2/TDS170/V2.79 43 w Y 1'-2':Sb<6.5/As<6.5/Ba95.4/B<16.2/Cr7.6/Co6j/Fe7710/Mn1250/TI<6.5/V17.3 J 23'-24': Sb<5/As<5/Ba28.2/B10j/Cr2.1/Co4.6j/Fe10600/Mn885/TI<5/V8.4 420 p 33'-35':Sb<7.5/As<7.5/Ba131/B16.8j/Cr9.2/Co12/Fe19100/Mn1630/TI<7.5/V16.3 Q 54.5'-55.5': Sb <5.2 / As <5.2 / Ba 237 / B 32.3 / Cr 37.2 / Co 19.6 / Fe 38300 / Mn 1010 / TI <5.2 / V 87 410 � 400 Q 400 J w 390 w 390 L j - z 380 LU � = U m 370 (n 880 - - (n � _ _ 260 360 ~ --- - 350 LU --- Z - --- - �. 340 J --- - 81 -- --- --- CC 330 320 30-- _ 310 310 300 - - - 300 O O O O O CD O O O O O O O O O O O O O O CD O O O CD CD CD CD + + CO f1- + 00 + + O O + + + + + + + + + + + N CO � LO O r-- 00 O O I� ti r1- 00 00 00 0o 00 00 00 00 00 0o O O NORTHEAST SECTION B-B' - MANGANESE FACING NORTHWEST FACING NORTHWEST 620 610 600 590 580 570 560 550 540 530 520 510 500 490 480 470 460 450 440 430 420 410 400 390 W CO LU CO LLI - Z_ J U Q COAL ASH TRANSITION ZONE BEDROCK SOIL/FILL SAPROLITE ALLUVIUM CONCENTRATION CONTOUR CONCENTRATION CONTOURS DASHED WHERE INFERRED HASH MARKS POINT TO DECREASING CONCENTRATIONS WATER LEVEL (JUNE 17, 2015) SURFICIAL WATER LEVEL TRANSITION ZONE WATER LEVEL BEDROCK WATER LEVEL 2J FRACTURED/OXIDIZED ZONE m OBSERVED IN ROCK CORE w` NOT SAMPLED ABMW-02BR: WATER ANALYTICAL RESULTS IN pg/L 45'-45.5' SOIL TOTAL ANALYTICAL RESULTS IN mg/kg BORING SYMBOLS GRAPHIC SCALE 0 300 IN FEET HORIZONTAL: 1"=300' 0 30 IN FEET VERTICAL: 1"=30' NOTE: 10:1 VERTICAL EXAGGERATION SOIL SAMPLE WELL SCREEN WITH CONCENTRATION (micrograms per liter) SOURCES. 1. THE TOPOGRAPHY SURVEY DATA WITHIN THE PROPERTY BOUNDARY DATED MAY 19, 2015 WAS OBTAINED FROM WSP OF CARY, NORTH CAROLINA. 2. SELECT TOPOGRAPHIC ADJUSTMENTS BASED ON SITE SURVEY AND COMPARISON TO AERIAL PHOTOGRAPH. 3. 2015 LITHOLOGY INFORMATION OF SOIL AND WELL LOG TOPOGRAPHY IS FROM SYNTERRA. 4. GEOLOGIC INFORMATION FOR BORINGS AND MONITORING WELLS INSTALLED PRIOR TO 2015 TAKEN FROM S&ME (2010) AND QUANTEX (2008). NOTE.- 1 . CROSS SECTION LOCATIONS SHOWN ON FIGURE 2-1. 2. WATER LEVELS WERE COLLECTED BY SYNTERRA ON JUNE 17, 2015. 3. 2L VALUE FOR MANGANESE IS 50 pg/L. erra 148 River Street, Suite 220 Greenville, South Carolina 29601 864-421-9999 www.synterracorp.com DRAWN BY: C. NEWELL DATE: 8/5/2015 CHECKED BY: J. WYLIE DATE: 8/5/2015 PROJECT MANAGER: K. WEBB LAYOUT NAME: FIGURE 11-7A (� DUKE � ENERGY PROGRESS MAYO STEAM ELECTRIC PLANT 10660 BOSTON RD ROXBORO, NORTH CAROLINA FIGURE 11-7a GEOLOGIC CROSS SECTION B-B' WITH MANGANESE I 0t'%0A1r% tiA LU n, C� Q W U O Q U) a) YaA IL 1a0 O 0- 0) a W U rl / C6 n 0) E U) 0) U) Cn a 0 Cn M m Cn a 0 I6 O / N O vi U) a) w 0 n E. a) LU a) 0 / .E 7 ti c� LO O N 00 N 0 MW-13BR MW-13BR: pH7.2/Sb<1/As<1/Ba40/B<50/Cr(VI)0.005/Col.19/Fe1130/Mn474/TI<0.2/TDS370/V0.381 0'-2': Sb<6.5/As<6.5/Ba72.9/B<16.3/Cr6.1/Co<6.5/Fe19600/Mn82.8/TI<6.5/V32.4 52'-54': Sb<5.1/As<5.1/Ba62.3/B<2.5/Cr9.2/Co6.6/Fe10400/Mn789/TI<5.1/V13.1 ABMW-02/ 02BR ABMW-02: pH 7.8 / Sb <1 / As 1020 / Ba 173 / B 9200 / Cr(VI) 0.017 / Co <1 / Fe 356 / Mn 1110 / TI <0.2 / TDS 450 / V 3.53 ABMW-02BR: pH 7.2 / Sb <1 / As <1 / Ba 159 / B <50 / Cr(VI) 0.007 / Co <1 / Fe 107 / Mn 149 / TI <0.2 / TDS 370 / V 0.873 45'-45.5': Sb<6/As<6/Ba92.2/B<15/Cr8/Co6j/Fe18300/Mn579/TI<6/V30.3 57.5'-58': Sb<5.1/As<5.1/Ba41.2/B<12.8/Cr56.7/Co37.4/Fe43400/Mn782/TI<5.1/V84.9 ABMW-03/ 03S BMV' mm. 1 6 in uWM ROOM 11IN ago b Few 111104 0 s y MW-07D/ 07BR MW-07D: pH 6.4 / Sb <1 / As <1 / Ba 24 / B <50 / Cr(VI) NS / Co <1 / Fe 69 / Mn 188 / TI <0.2 / TDS 390 / V 0.798 MW-07BR: pH 7.4 / Sb <1 / As <1 / Ba 140 / B <50 / Cr(VI) NS / Co <1 / Fe 339 / Mn 263 / TI <0.2 / TDS 270 / V <0.3 C 1 550 1'-2': Sb<5.1/As<5.1/Ba21.5/B<12.8/Cr4.1/Co<5.1/Fe7320/Mn27.7/TI<5.1/V12.8 550 540 540 MW-08S/ 08D/ 08BR 530 p MW-08BR: pH 6.56 / Sb <1 / As <1 / Ba 66 / B <50 / Cr(VI) NS / Co <1 / Fe 2200 / Mn 2680 / TI <0.2 / TDS 550 / V <0.3 a0 0.75'-1.25': Sb <3.2 / As <3.2 / Ba 147 / B <63.4 / Cr 62.2 / Co 21.3 / Fe 24700 / Mn 1230 / TI <3.2 / V 50.6 520 25.5'-26': Sb<2.7/As<2.7/Ba193/B31j/Cr419/Co32.9/Fe31300/Mn933/TI<2.7/V75.8 30.5'-31': Sb <2.7 / As <2.7 Ba 130 B <53.1 Cr 67.1 Co 7.4 Fe 11400 Mn 875 / TI <2.7 / V 25.2 WE SECTION C-C' - MANGANESE FACING NORTH 510 500 490 ED& 'Coll" 380 370 360 GRAPHIC SCALE 300 0 300 IN FEET HORIZONTAL: 1"=300' 30 0 30 ICOALASH TRANSITION ZONE BEDROCK SOIL/FILL SAPROLITE ALLUVIUM CONCENTRATION CONTOUR CONCENTRATION CONTOURS DASHED WHERE INFERRED HASH MARKS POINT TO DECREASING CONCENTRATIONS WATER LEVEL (JUNE 17, 2015) SURFICIAL WATER LEVEL TRANSITION ZONE WATER LEVEL BEDROCK WATER LEVEL FRACTURED/OXIDIZED ZONE OBSERVED IN ROCK CORE NS NOT SAMPLED ABMW-02BR: WATER ANALYTICAL RESULTS IN pg/L 45'-45.5' SOIL TOTAL ANALYTICAL RESULTS IN mg/kg BORING SYMBOLS SOIL SAMPLE WELL SCREEN WITH CONCENTRATION (micrograms per liter) SOURCES.- 1 THE TOPOGRAPHY SURVEY DATA WITHIN THE PROPERTY BOUNDARY DATED MAY 19, 2015 WAS OBTAINED FROM WSP OF CARY, NORTH CAROLINA. 2. SELECT TOPOGRAPHIC ADJUSTMENTS BASED ON SITE SURVEY AND COMPARISON TO AERIAL PHOTOGRAPH. 3. 2015 LITHOLOGY INFORMATION OF SOIL AND WELL LOG TOPOGRAPHY IS FROM SYNTERRA. 4. GEOLOGIC INFORMATION FOR BORINGS AND MONITORING WELLS INSTALLED PRIOR TO 2015 TAKEN FROM S&ME (2010) AND QUANTEX (2008). NOTE: 1. CROSS SECTION LOCATIONS SHOWN ON FIGURE 2-1. 2. WATER LEVELS WERE COLLECTED BY SYNTERRA ON JUNE 17, 2015. 3. 2L VALUE FOR MANGANESE IS 50 pg/L. erra 148 River Street, Suite 220 Greenville, South Carolina 29601 864-421-9999 www.synterracorp.com DRAWN BY: C. NEWELL DATE: 8/5/2015 CHECKED BY: J. WYLIE DATE: 8/5/2015 PROJECT MANAGER: K. WEBB LAYOUT NAME: FIGURE 11-713 DUKE ENERGY boo PROGRESS MAYO STEAM ELECTRIC PLANT 10660 BOSTON RD 60 ROXBORO, NORTH CAROLINA IN FEET VERTICAL: 1"=30' NOTE: 10:1 VERTICAL EXAGGERATION FIGURE 11-7b GEOLOGIC CROSS SECTION C-C' WITH MANGANESE 1 0t'%0A1r% U0 W Of LL Q W U O 75 a� la,0 IL w O tf O Q- (1) Q W U r-I r-I / c co C N V7 N N v7 Q 0 co m Q O co Ln O / C9 N O r-i vi N tuo O m w m 75 a- O 14 LO O N N O 620 610 600 590 580 570 560 550 540 530 520 510 500 490 480 ow 470 M� aa) 460 w= 450 440 430 420 410 400 390 380 370 360 350 340 330 320 310 300 IN illlliiiiiii MENNEN FIRM NOW NMI O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O OD O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + O O N M d co ti M O N M ,I-LO CO I- CO O O �- N CO LO (D � 00 M CD M "I -LC) co ti co O �- N M � Ln CO f� M M O N M d Lo CO fl- M O CD M ,I- LO CO I- M M CDN M 'z Lo •- - - - - - - c- N N N N N N N N N N co co M M co co co co M M It " It I- dt It It cp It IT Lr) LO LO LO LO LO LO LO LO LC) CO CO CO (0 (0 CO CO CO (0 (0r- ti r- ti ti r- SOUTHWEST Station (feet) S113-7 SECTION B-B' - THALLIUM 1'-2': Sb <5.8 / As <5.8 / Ba 68.8 / B <14.5 / Cr 11.4 / Co 5.9 / Fe 9460 / Mn 693 / TI <5.8 / V 17.6 4.5'-7.5':Sb<6/As<6/13a15.5/B<15/Cr8.2/Co<6/Fe6040/Mn226/TI<6/V8.2 MW-3 MW-3: pH5.71/Sb<1/As<1/Ba56/B847/Cr(VI)0.155/Co<1/Fe34/Mn880/TI<0.2/TDS190/V<0.3 CW-2/ 2D 470 1 1 1 1 1 CW-2: pH 6.5 / Sb <1 / As <1 / Ba 54 / B 804 / Cr(VI) <0.021 / Co <1 / Fe 467 / Mn 135 / TI <0.2 /TDS 370 / V 5.88 CW-211): pH 6.1 / Sb <1 / As <1 / Ba 38 / B 363 / Cr(VI) 0.084 / Co <1 / Fe 278 / Mn 81 / TI <0.2 / TDS 250 / V 0.585 460 460 a) 50 MW-16S/ 16D/ 16BR p MW-16S: pH 6.02 / Sb <1 / As <1 / Ba 46 / B <50 / Cr(VI) 0.011 / Co 4.32 / Fe 860 / Mn 260 / TI <0.2 / TDS 100 / V 0.303 4 0 a0 MW-16D: pH7.1/Sb<1/As<1/Ba13/B<50/Cr(VI)0.051/Co<1/Fe87/Mn269/TI<0.2/TDS160/V0.617 Of MW-16BR: pH8.67/Sb<1/As2.05/Ba11/B<50/Cr(VI)0.017/Co<1/Fe80/Mn30/TI<0.2/TDS170/V2.79 43 w Y 1'-2':Sb<6.5/As<6.5/Ba95.4/B<16.2/Cr7.6/Co6j/Fe7710/Mn1250/TI<6.5/V17.3 J 23'-24': Sb<5/As<5/Ba28.2/B10j/Cr2.1/Co4.6j/Fe10600/Mn885/TI<5/V8.4 420 p 33'-35':Sb<7.5/As<7.5/Ba131/B16.8j/Cr9.2/Co12/Fe19100/Mn1630/TI<7.5/V16.3 Q 54.5'-55.5': Sb <5.2 / As <5.2 / Ba 237 / B 32.3 / Cr 37.2 / Co 19.6 / Fe 38300 / Mn 1010 / TI <5.2 / V 87 410 400 0 400 J w 390 w U- 390 Of W - Q 380 W -' w-fy _ _ U m 370 0 07 - - �71 <0.2 360 2 � W __ ___ � 350 z _ - -- - �. 340 J --- - - - --- - - <0.2 --- C) --- --- __ 330 320 --- --- --- --- --- --- ---- --- --- --- <0.2- --- 310 310 300 - - - - - - 300 O O O O O CDO O O O O O O O O O O O O O O O O O O O O O O O O O + + + CO rl- 00 + + + O O + + + + + + + + + + N M � LO O r-- M M O I� ti rl- 00 00 00 0o 00 00 00 00 00 0o O O NORTHEAST SECTION B-B' - THALLIUM FACING NORTHWEST FACING NORTHWEST 620 610 600 590 580 570 560 550 540 530 520 510 500 490 480 470 460 450 440 430 420 410 400 390 W CO LLI CO LLI - Z_ J U Q Cff COAL ASH TRANSITION ZONE BEDROCK SOIL/FILL SAPROLITE ALLUVIUM CONCENTRATION CONTOUR CONCENTRATION CONTOURS DASHED WHERE INFERRED HASH MARKS POINT TO DECREASING CONCENTRATIONS WATER LEVEL (JUNE 17, 2015) SURFICIAL WATER LEVEL TRANSITION ZONE WATER LEVEL BEDROCK WATER LEVEL .2u) FRACTURED/OXIDIZED ZONE m OBSERVED IN ROCK CORE w` NOT SAMPLED ABMW-02BR: WATER ANALYTICAL RESULTS IN pg/L 45'-45.5' SOIL TOTAL ANALYTICAL RESULTS IN mg/kg BORING SYMBOLS GRAPHIC SCALE 0 300 IN FEET HORIZONTAL: 1"=300' 0 30 IN FEET VERTICAL: 1"=30' NOTE: 10:1 VERTICAL EXAGGERATION SOIL SAMPLE WELL SCREEN WITH CONCENTRATION (micrograms per liter) SOURCES. 1. THE TOPOGRAPHY SURVEY DATA WITHIN THE PROPERTY BOUNDARY DATED MAY 19, 2015 WAS OBTAINED FROM WSP OF CARY, NORTH CAROLINA. 2. SELECT TOPOGRAPHIC ADJUSTMENTS BASED ON SITE SURVEY AND COMPARISON TO AERIAL PHOTOGRAPH. 3. 2015 LITHOLOGY INFORMATION OF SOIL AND WELL LOG TOPOGRAPHY IS FROM SYNTERRA. 4. GEOLOGIC INFORMATION FOR BORINGS AND MONITORING WELLS INSTALLED PRIOR TO 2015 TAKEN FROM S&ME (2010) AND QUANTEX (2008). NOTE.- 1 . CROSS SECTION LOCATIONS SHOWN ON FIGURE 2-1. 2. WATER LEVELS WERE COLLECTED BY SYNTERRA ON JUNE 17, 2015. 3. IMAC VALUE FOR THALLIUM IS 0.2 pg/L. erra 148 River Street, Suite 220 Greenville, South Carolina 29601 864-421-9999 www.synterracorp.com DRAWN BY: C. NEWELL DATE: 8/5/2015 CHECKED BY: J. WYLIE DATE: 8/5/2015 PROJECT MANAGER: K. WEBB LAYOUT NAME: FIGURE 11-8A DUKE PROGRESS MAYO STEAM ELECTRIC PLANT 10660 BOSTON RD ROXBORO, NORTH CAROLINA FIGURE 11-8a GEOLOGIC CROSS SECTION B-B' WITH THALLIUM N O v L0 1-1 N 04 I MW-13BR: pH7.2/Sb<I/As<1/Ba 40 / B <50 / Cr(VI) 0.005 / Co 1.19 / Fe 1130/ Mn 474/ TI<0.2/ TDS 370/ V 0.381 O'-2':Sb<6.5/As<6.5/Ba 72.9 / B <16.3 / Cr 6.1/Co<6.5/Fe 196M Mn 82.8 /TI<6.5/V 32.4 52'-54':Sb<5.1/As<5.1/Ba62.3/B<2.5/Cr9.2/C.6.6/Fe 10400/Mn 789 /TI<5.1/V 13.1 ABMW-02: pH7.8/Sb<1/As 1020/Ba 173/B 9200/Cr(VI)0.017/Co<I/Fe 356/ Mn 1110/ TI <0.2/ TD5450/ V 3.53 ABMW-02BR: pH7.2/5b<S/As<1/Ba 159/B<50/Cr(VI)0.007/Co<I/Fe 107/Mn 149/TI<0.2/ TDS 370/ V 0.873 45'-45.5':5b<6/As<6/Ba 92.2 / B <15 / Cr 8 / Co 6 j / Fe 18300/ Mn 579/ TI<6/ V 30.3 57.5'-58': 5b<5.1/As<5.1/Ba41.2/B<12.8/Cr56.7/Co37.4/Fe43400/Mn782/TI<5.1/V84.9 ABMW-03: pH6.63/5b<1/As 193/Ba 2W/B 1940/Cr(VI)<OAW/Co<1/Fe 3890/ Mn 451/ TI 0.289/ TD5350/ V 0.68 CABMW-01 ABMW-03S: pHI.21/5b<l/A 1.04/Ba25/BIIOO/Cr(VI)<0.005/Co3.98/Fe2630/Mn478/TI<0.2/TD511G/V<0.3 CW-01 550 v�i ABMW-01: pH7.6/Sb38/As518/Ba925/B4560/Cr(VI)NS/[ 6.09/Fe1370/Mn2280/TI2.47/TOS540/V 314 51'-53':Sb<6.8/As<6.8/Ba56.1/B<17/Cr1.3j/Cob.6j/Fe16900/Mn319/TI<6.8/V28.8 CW-01: CW-01:pH5.5/5b<3/As<S/Ba<5/B<50/CrjVIjNS/Co<1/Fe31/Mn6/TI<0.2/TD5150/V0.543 Z 1'-1.5':5b<8.7/As16.6/Ba15D/B27.4/Cr25/Co7.6j/Fe2240/Mn18.4/TI<8.7/V39.3 CW-01 D: pH6.8/Sb<3/As<1/Ba<5/B<50/CrvI)NS/Co<1/Fe<10/Mn<5/TI<0.2/TD5200/V 1.09 540 OF= 11.5'-12%Sb<7.8/As 26.2/Ba 152/B27.4/Cr26.9/Co8.3/ Fe 2710/ Mn 31.3/ TI<7.8/ V 46.2 wo w 13'-13.5':Sb<6.2/As<6.2/Ba53.8/8<15.5/Cr3.7/Co<6.2/ Fe 8770/ Mn 92.2/ TI<6.2/V 11.9 Q 530 m aMW-096R MW-09BR: pH6.3/Sb<llAs</Ba 30/B<50/Dr(VI)NS/Co<1/Fe 3000/Min 809/ TI<0.2 / TDS 220/ V 4.17 1/111111111111111111111111►.r���.11111111111111111111111111111111111111111111111111111111111111111_�������.F IIII/lllllllllllllllllllllllllll� IIIIIIMIIIIIIIIIIII !� ''1/11111111I111 111111111111111111111111111��1111����lIIII''11 ��� 1'IIIG111111111111111111�11111111111�1�1���1111����1� •�C::::��!!!�11141�11'I/IIIIIIIIIIIC1�11111111111111111111111111''.---- ����.., „ ,.,= .rr�iririri■111!!!!111111��1�����������■■■■■■ IIII/IL_______Illli■11111111111111111►V1�!••�•AIA�� � � � � 3� � • 111111111111111111��■■ „ , �r������C�s�rri'Cor� � bw �, -� AAI�1 �+., -� � � IIIIIIIIIIIIIIIIIr1�i==---- Jim � � • �� '® ,All'", „^- ,1$$$1��$$$1111$$1�$1 .,11$111�1$$11111$11111$1111$$11111$g1111$111��as==�__a s �■aas= � _,: � � _ '. ..: :=�aaasss ■aa as■s aa4■saa■■■■aa _■� 1$11111111111$$$ 11111 1$� .,1111a1a111111111111j1j��a1a�j1�j1111a1as1s111a1aa1as1111a11s1s1111a1a11111111111�1j 11 � ., �j �j ss ss aa s1�1j1�s1s1111�1js1s111111111 11111111111111111g11111111111g11111glllllllllllgllllllll .,1111111111111111111111111111111111glllllg11111111111111 ., MW-07D: pH6.4/5b<1/As<1/Ba24/B<50/Cr(VI)NS/Co<1/Fe69/Mn188/TI<0.2/TDS390/VO.798 MW-07ER: pH7.4/5b<1/As<1/Ba 140/B<50/Cr(VI)NS/Co<I/ Fe 339/ Mn 263/ TI<0.2/ TDS 270/ V<0.3 C' 550 P-2':Sb<5.1/As<5.1/Ba21.5/B<12.9/Cr4.1/Co<5.1/ Fe 7320/ Mn 27.7/ TI<5.1/ V 12.8 550 540 540 MW-08S/ OBDI 08BR 530 p MW-08BR: pH6.56/Sb<1/As<I/Ba 66/B<50/Cr(V0 N5/Co</Fe 2200/ Mn 2680/ TI<0.2/ TDS 550 V<0.3 O 0.75'-1.25':Sb<3.2/As<3.2/Ba147/B<63.4/Cr62.2/Co21.3/Fe24700/Mn1230/TI<3.2/V50.6 520 25.5'-26':Sb<2.7/As<2.7/Ba193/B33j/Cr419/Co32.9/Fe31300/Mn933/TI<2.7/V75.8 30.5'-31': Sb<2.7 As<2.7 Ba130 B<53.1 Cr67.1 Co7.4 Fe1140D Mn875/TI<2.7/V25.2 MIN 11/111����111111111111111111111111!!11111 F F „ ,. 1/1�1111111111111111111111.NIIlllll CIII 111111111111111111�11111�1111 ,., ., - '`�1111111111111111� 'lll ., 11111�1 .-, ''1111111111111 1111166111,., . --""'rt1■■ri1111111111i11. , ; , Gm �a�as�sC���a�as�s4�4���a�as�s�CC'_=ieesisgg . �rrr4p$rrrrr$rrrrr$�. r$rr : F �1111g11111g11111 111 .F ., • SECTION C-C' - THALLIUM FACING NORTH 300 30 GRAPHIC SCALE 0 300 IN FEET HORIZONTAL: 1"=300' 0 30 LEGEND _ COAL ASH _ TRANSITION ZONE BEDROCK SOIL/FILL © SAPROLITE ® ALLUVIUM CONCENTRATION CONTOUR CONCENTRATION CONTOURS DASHED WHEREINFERRED --�--r� HASH MARKS POINT TO DECREASING CONCENTRATIONS WATER LEVEL (JUNE 17, 2015) • SURFICIAL WATER LEVEL • TRANSITION ZONE WATER LEVEL • BEDROCK WATER LEVEL FRACTURED/OXIDIZED ZONE OBSERVED IN ROCK CORE NS NOT SAMPLED ABMW-02BR: WATER ANALYTICAL RESULTS IN pg/L 45'-45.5' SOIL TOTAL ANALYTICAL RESULTS IN mg/kg BORING SYMBOLS SOIL SAMPLE WELL SCREEN WITH CONCENTRATION (micrograms per liter) SOURCES: 1. THE TOPOGRAPHY SURVEY DATA WITHIN THE PROPERTY BOUNDARY DATED MAY 19, 2015 WAS OBTAINED FROM WSP OF GARY, NORTH CAROLINA. 2. SELECT TOPOGRAPHIC ADJUSTMENTS BASED ON SITE SURVEY AND COMPARISON TO AERIAL PHOTOGRAPH. 3. 2015 LITHOLOGY INFORMATION OF SOILAND WELL LOG TOPOGRAPHY IS FROM SYNTERRA. 4. GEOLOGIC INFORMATION FOR BORINGS AND MONITORING WELLS INSTALLED PRIOR TO 2015 TAKEN FROM S&ME (2010) AND QUANTEX (2008). NOTE: 1. CROSS SECTION LOCATIONS SHOWN ON FIGURE 2-1. 2. WATER LEVELS WERE COLLECTED BY SYNTERRA ON JUNE 17, 2015. 3. IMAC VALUE FOR THALLIUM IS 0.2 pg/L. I VT s)mTerm 148 River Street, Suite 220 Greenville, South Carolina 29601 864-421-9999 www.synterracorp.com DRAWN BY: C. NEWELL DATE: 8/5/ CHECKED BY: J. WYLIE DATE: 8/5/ PROJECT MANAGER: K. WEBB LAYOUT NAME: FIGURE 11-8B 'DUKE ENERGY boo PROGRESS MAYO STEAM ELECTRIC PLANT 10660 BOSTON RD 60 ROXBORO, NORTH CAROLINA IN FEET VERTICAL: 1"=30' NOTE: 10:1 VERTICAL EXAGGERATION FIGURE 11-8b GEOLOGIC CROSS SECTION C-C' WITH THALLIUM 1 0t'%0A1r% 1aA v7 LU n, C� Q W U O Q a� 1aA IL 1aA O 0- (3) CC a W U �i / C6 0 U) 0 U) Cn a 0 Cn M m Cn Q 0 ('3 L6 O / O N O vi U) N w 0 n E. a� LU (D 0 / .E 7 c� O LO O N 00 N 0 620 610 600 590 580 570 560 550 540 530 520 510 500 490 480 ow 470 M� aa) 460 w= 450 440 430 420 410 400 390 380 370 360 350 340 330 320 310 300 IF M MININS111- IIIIIIIII L WN lad lilt! O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O OD O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + O N M d co r'- M O CD- N M ,I-LO CO r- CO O O �- N CO � LO (D r-- 00 M CD- N M "I-LO co ti co O �- N M � Ln CO r` M M O N M -' Lo CO r1- M O CD- N M ,I- LO CO r'-M M CD M 'z Lo •- - - - - - - c- N N N N N N N N N N co co M M co co co co M M It" It I- dt It It cp It IT U') LO LO LO LO LO LO LO LO LO Co Co Co (0 (0 Co Co Co Co (0 r- ti r- I� ti r- SOUTHWEST Station (feet) SB-7 SECTION B-B' - TDS 1'-2': Sb <5.8 / As <5.8 / Ba 68.8 / B <14.5 / Cr 11.4 / Co 5.9 / Fe 9460 / Mn 693 / TI <5.8 / V 17.6 FACING NORTHWEST 4.5'-7.5': Sb <6 / As <6 / Ba 15.5 / B <15 / Cr 8.2 / Co <6 / Fe 6040 / Mn 226 / TI <6 / V 8.2 MW-3 MW-3:pH5.71/Sb<1/As<1/Ba56/B847/Cr(VI)0.155/Co<1/Fe34/Mn880/TI<0.2/TDS190/V<0.3 CW-2/ 2D 1 1 1 1CW-2: pH 6.5 / Sb <1 / As <1 / Ba 54 / B 804 / Cr(VI) <0.021 / Co <1 / Fe 467 / Mn 135 / TI <0.2 / TDS 370 / V 5.88 470 CW-2D: pH 6.1 / Sb <1 / As <1 / Ba 38 / B 363 / Cr(VI) 0.084 / Co <1 / Fe 278 / Mn 81 / TI <0.2 / TDS 250 / V 0.585 1111111111111460 N HIMMIMMI 460 11142 MW-16S/ 16D/ 16BR 50 p MW-16S: pH 6.02 / Sb <1 / As <1 / Ba 46 / B <50 / Cr(VI) 0.011 / Co 4.32 / Fe 860 / Mn 260 / TI <0.2 / TDS 100 / V 0.303 MW-16D: pH7.1/Sb<1/As<1/Ba13/B<50/Cr(VI)0.051/Co<1/Fe87/Mn269/TI<0.2/TDS160/V0.617 40 of MW-16BR: pH8.67/Sb<1/As2.05/Ba11/B<50/Cr(VI)0.017/Co<1/Fe80/Mn30/TI<0.2/TDS170/V2.79 43 w Y 1'-2':Sb<6.5/As<6.5/Ba95.4/B<16.2/Cr7.6/Co6j/Fe7710/Mn1250/TI<6.5/V17.3 J 23'-24': Sb<5/As<5/Ba28.2/B10j/Cr2.1/Co4.6j/Fe10600/Mn885/TI<5/V8.4 p 33'-35':Sb<7.5/As<7.5/Ba131/B16.8j/Cr9.2/Co12/Fe19100/Mn1630/TI<7.5/V16.3 420 Q 54.5'-55.5': Sb <5.2 / As <5.2 / Ba 237 / B 32.3 / Cr 37.2 / Co 19.6 / Fe 38300 / Mn 1010 / TI <5.2 / V 87 410 400 77 1� p 400 J w 390 390 w __ W Q 380 LU Um = 370 370 (n - _ 100 360 2 - ~ --- 350 LU --- 340 -250- - 160 _ --- --- --- 330 ---- ---- ---320 --- --- --- ---- 170- --- ___ 310 310 - - - - - - 300 300 O O O O O CDO O O O O O O O O O O O O O O CDO O O O CD O O CD CD + + + CO r1- 00 + + + + + + + + + + + + + O O N CO � LO co r-- 00 M CDf� ti r-- co 00 00 co 00 00 00 00 00 00 O O NORTHEAST SECTION B-B' -TDS FACING NORTHWEST 620 610 600 590 580 570 560 550 540 530 520 510 500 490 480 470 460 450 440 430 420 410 400 390 W LU 3E CO CO LLI - Z_ J U Q ICOALASH TRANSITION ZONE - - - - BEDROCK SOIL/FILL SAPROLITE ALLUVIUM CONCENTRATION CONTOUR CONCENTRATION CONTOURS DASHED WHERE INFERRED HASH MARKS POINT TO DECREASING CONCENTRATIONS WATER LEVEL (JUNE 17, 2015) SURFICIAL WATER LEVEL TRANSITION ZONE WATER LEVEL BEDROCK WATER LEVEL .2u) FRACTURED/OXIDIZED ZONE OBSERVED IN ROCK CORE w` NOT SAMPLED ABMW-02BR: WATER ANALYTICAL RESULTS IN pg/L 45'-45.5' SOIL TOTAL ANALYTICAL RESULTS IN mg/kg BORING SYMBOLS GRAPHIC SCALE 0 300 IN FEET HORIZONTAL: 1"=300' 0 30 IN FEET VERTICAL: 1"=30' NOTE: 10:1 VERTICAL EXAGGERATION SOIL SAMPLE WELL SCREEN WITH CONCENTRATION (micrograms per liter) SOURCES. 1. THE TOPOGRAPHY SURVEY DATA WITHIN THE PROPERTY BOUNDARY DATED MAY 19, 2015 WAS OBTAINED FROM WSP OF CARY, NORTH CAROLINA. 2. SELECT TOPOGRAPHIC ADJUSTMENTS BASED ON SITE SURVEY AND COMPARISON TO AERIAL PHOTOGRAPH. 3. 2015 LITHOLOGY INFORMATION OF SOIL AND WELL LOG TOPOGRAPHY IS FROM SYNTERRA. 4. GEOLOGIC INFORMATION FOR BORINGS AND MONITORING WELLS INSTALLED PRIOR TO 2015 TAKEN FROM S&ME (2010) AND QUANTEX (2008). NOTE.- 1 . CROSS SECTION LOCATIONS SHOWN ON FIGURE 2-1. 2. WATER LEVELS WERE COLLECTED BY SYNTERRA ON JUNE 17, 2015. 3. 2L VALUE FOR TDS IS 500 mg/L. erra 148 River Street, Suite 220 Greenville, South Carolina 29601 864-421-9999 www.synterracorp.com DRAWN BY: C. NEWELL DATE: 8/5/2015 CHECKED BY: J. WYLIE DATE: 8/5/2015 PROJECT MANAGER: K. WEBB LAYOUT NAME: FIGURE 11-9A (� DUKE � ENERGY PROGRESS MAYO STEAM ELECTRIC PLANT 10660 BOSTON RD ROXBORO, NORTH CAROLINA FIGURE 11-9a GEOLOGIC CROSS SECTION B-B' WITH TDS I 0t'%0A1r% tiA LU n, C� Q W U O Q U) a) YaA IL 1a0 O 0- 0) a W U rl / C6 n 0) E U) 0) U) Cn a 0 Cn M m Cn a 0 I6 O / N O vi U) a) w 0 n E. a) w 0 / WE 7 LO O N 00 N 0 MW-13BR MW-13BR: pH7.2/Sb<1/As<1/Ba40/B<50/Cr(VI)0.005/Col.19/Fe1130/Mn474/TI<0.2/TDS370/V0.381 0'-2': Sb<6.5/As<6.5/Ba72.9/B<16.3/Cr6.1/Co<6.5/Fe19600/Mn82.8/TI<6.5/V32.4 52'-54': Sb<5.1/As<5.1/Ba62.3/B<2.5/Cr9.2/Co6.6/Fe10400/Mn789/TI<5.1/V13.1 ABMW-02/ 02BR ABMW-02: pH 7.8 / Sb <1 / As 1020 / Ba 173 / B 9200 / Cr(VI) 0.017 / Co <1 / Fe 356 / Mn 1110 / TI <0.2 / TDS 450 / V 3.53 ABMW-02BR: pH 7.2 / Sb <1 / As <1 / Ba 159 / B <50 / Cr(VI) 0.007 / Co <1 / Fe 107 / Mn 149 / TI <0.2 / TDS 370 / V 0.873 45'-45.5': Sb<6/As<6/Ba92.2/B<15/Cr8/Co6j/Fe18300/Mn579/TI<6/V30.3 57.5'-58': Sb<5.1/As<5.1/Ba41.2/B<12.8/Cr56.7/Co37.4/Fe43400/Mn782/TI<5.1/V84.9 ABMW-03/ 03S BMV' mm. 1 6 in u PA dpp WON WEI al s y MW-07D/ 07BR MW-07D: pH 6.4 / Sb <1 / As <1 / Ba 24 / B <50 / Cr(VI) NS / Co <1 / Fe 69 / Mn 188 / TI <0.2 / TDS 390 / V 0.798 MW-07BR: pH 7.4 / Sb <1 / As <1 / Ba 140 / B <50 / Cr(VI) NS / Co <1 / Fe 339 / Mn 263 / TI <0.2 / TDS 270 / V <0.3 C 1 550 1'-2': Sb<5.1/As<5.1/Ba21.5/B<12.8/Cr4.1/Co<5.1/Fe7320/Mn27.7/TI<5.1/V12.8 550 �4540 540 MW-08S/ 08D/ 08BR 530 p MW-08BR: pH 6.56 / Sb <1 / As <1 / Ba 66 / B <50 / Cr(VI) NS / Co <1 / Fe 2200 / Mn 2680 / TI <0.2 / TDS 550 / V <0.3 a0 0.75'-1.25': Sb <3.2 / As <3.2 / Ba 147 / B <63.4 / Cr 62.2 / Co 21.3 / Fe 24700 / Mn 1230 / TI <3.2 / V 50.6 520 25.5'-26': Sb<2.7/As<2.7/Ba193/B31j/Cr419/Co32.9/Fe31300/Mn933/TI<2.7/V75.8 30.5'-31': Sb <2.7 / As <2.7 Ba 130 B <53.1 Cr 67.1 Co 7.4 Fe 11400 Mn 875 / TI <2.7 / V 25.2 EM ML MINE SECTION C-C' - TDS FACING NORTH 510 500 490 ED 'Coll" 380 370 360 GRAPHIC SCALE 300 0 300 IN FEET HORIZONTAL: 1"=300' 30 0 30 ICOALASH TRANSITION ZONE BEDROCK SOIL/FILL SAPROLITE ALLUVIUM CONCENTRATION CONTOUR CONCENTRATION CONTOURS DASHED WHERE INFERRED HASH MARKS POINT TO DECREASING CONCENTRATIONS WATER LEVEL (JUNE 17, 2015) SURFICIAL WATER LEVEL TRANSITION ZONE WATER LEVEL BEDROCK WATER LEVEL FRACTURED/OXIDIZED ZONE OBSERVED IN ROCK CORE NS NOT SAMPLED ABMW-02BR: WATER ANALYTICAL RESULTS IN pg/L 45'-45.5' SOIL TOTAL ANALYTICAL RESULTS IN mg/kg BORING SYMBOLS SOIL SAMPLE WELL SCREEN WITH CONCENTRATION (micrograms per liter) SOURCES.- 1 THE TOPOGRAPHY SURVEY DATA WITHIN THE PROPERTY BOUNDARY DATED MAY 19, 2015 WAS OBTAINED FROM WSP OF CARY, NORTH CAROLINA. 2. SELECT TOPOGRAPHIC ADJUSTMENTS BASED ON SITE SURVEY AND COMPARISON TO AERIAL PHOTOGRAPH. 3. 2015 LITHOLOGY INFORMATION OF SOIL AND WELL LOG TOPOGRAPHY IS FROM SYNTERRA. 4. GEOLOGIC INFORMATION FOR BORINGS AND MONITORING WELLS INSTALLED PRIOR TO 2015 TAKEN FROM S&ME (2010) AND QUANTEX (2008). NOTE.- 1 . CROSS SECTION LOCATIONS SHOWN ON FIGURE 2-1. 2. WATER LEVELS WERE COLLECTED BY SYNTERRA ON JUNE 17, 2015. 3. 2L VALUE FOR TDS IS 500 mg/L. erra 148 River Street, Suite 220 Greenville, South Carolina 29601 864-421-9999 www.synterracorp.com DRAWN BY: C. NEWELL DATE: 8/5/2015 CHECKED BY: J. WYLIE DATE: 8/5/2015 PROJECT MANAGER: K. WEBB LAYOUT NAME: FIGURE 11-913 DUKE ENERGY boo PROGRESS MAYO STEAM ELECTRIC PLANT 10660 BOSTON RD 60 ROXBORO, NORTH CAROLINA IN FEET VERTICAL: 1"=30' NOTE: 10:1 VERTICAL EXAGGERATION FIGURE 11-9b GEOLOGIC CROSS SECTION C-C' WITH TDS 1 0t'%0A1r% 1aA v7 LU n, C� L7 Q W U O Q a� 1a0 IL 1aA O 0- (3) CC a W U �i / C6 0 E U) 0 U) Cn a 0 Cn M m Cn Q 0 ('3 L6 O / O N O vi U) N w 0 n E. a� LU (D 0 / .E 7 LO O LO O N 00 N 0 620 610 600 590 580 570 560 550 540 530 520 510 500 490 480 ow 470 M� aa) 460 w= 450 440 430 420 410 400 390 380 370 360 350 340 330 320 310 300 ILI IN a- 92 1 ANN 11 Imes - O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O OD O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + O N M d co r'- M O CD- N M ,I-LO CO r- CO O O �- N CO � LO (D r-- co M CD- N M "I-LO Cfl rl- co O �- N M � Ln CO r` M M O N M -' Lo CO rl- M O CD- N M ,I- LO (fl r- M M CD N M 'z LID •- - - - - - - c- N N N N N N N N N N co co M M co co co co M M It" It I- dt It It cp It IT U') LID LO LO LO LO LO LID LO LO CO CO CO (0 (0 CO CO CO (0 (0 r- rl-r- rl- rl-r- SOUTHWEST Station (feet) SB-7 SECTION B-B' - VANADIUM 1'-2': Sb <5.8 / As <5.8 / Ba 68.8 / B <14.5 / Cr 11.4 / Co 5.9 / Fe 9460 / Mn 693 / TI <5.8 / V 17.6 FACING NORTHWEST 4.5'-7.5':Sb<6/As<6/Ba15.5/B<15/Cr8.2/Co<6/Fe6040/Mn226/TI<6/V8.2 MW-3 MW-3:pH5.71/Sb<1/As<1/Ba56/B847/Cr(VI)0.155/Co<1/Fe34/Mn880/TI<0.2/TDS 190/V<0.3 CW-2/ 2D 470 1 CW-2: pH 6.5 / Sb <1 / As <1 / Ba 54 / B 804 / Cr(VI) <0.021 / Co <1 / Fe 467 / Mn 135 / TI <0.2 / TDS 370 / V 5.88 CW-211): pH 6.1 / Sb <1 / As <1 / Ba 38 / B 363 / Cr(VI) 0.084 / Co <1 / Fe 278 / Mn 81 / TI <0.2 / TDS 250 / V 0.585 460 460 N 42 50 MW-16S/ 16D/ 16BR p MW-16S: pH 6.02 / Sb <1 / As <1 / Ba 46 / B <50 / Cr(VI) 0.011 / Co 4.32 / Fe 860 / Mn 260 / TI <0.2 / TDS 100 / V 0.303 4 0 a0 MW-16D: pH7.1/Sb<1/As<1/Ba13/B<50/Cr(VI)0.051/Co<1/Fe87/Mn269/TI<0.2/TDS160/V0.617 of MW-16BR: pH8.67/Sb<1/As2.05/Ba11/B<50/Cr(VI)0.017/Co<1/Fe80/Mn30/TI<0.2/TDS170/V2.79 43 w Y 1'-2':Sb<6.5/As<6.5/Ba95.4/B<16.2/Cr7.6/Co6j/Fe7710/Mn1250/TI<6.5/V17.3 J 23'-24': Sb<5/As<5/Ba28.2/B10j/Cr2.1/Co4.6j/Fe10600/Mn885/TI<5/V8.4 420 0 33'-35':Sb<7.5/As<7.5/Ba131/B16.8j/Cr9.2/Co12/Fe19100/Mn1630/A<7.5/V16.3 Q 54.5'-55.5': Sb <5.2 / As <5.2 / Ba 237 / B 32.3 / Cr 37.2 / Co 19.6 / Fe 38300 / Mn 1010 / TI <5.2 / V 87 410 400 0 400 J LU 390 w 390 W U) 380 LU ' Q < 5.88 U °0 370 CO <0.3 3 ., \ 0_ - Cn - 0.303 360 ~ --- - 350 LU --- 340 J --- --- 0.585- Q A --- --- 330 --- 14: --- --- --- --- 320 --- --- ---__ --- --- 2.79- --- 310 310 300 - - - - - - 300 CD O O O CDO O CDO O CDO O CDO O CDO CDO O CDO O O O CD O O CD CD + + CO rl- + + + 00 O O + + + + + + + + + + + N CO � LO O r-- 00 O O f� ti rl- 00 00 00 0o 00 00 00 00 00 00 O O NORTHEAST SECTION B-B' - VANADIUM FACING NORTHWEST 620 610 600 590 580 570 560 550 540 530 520 510 500 490 480 470 460 450 440 430 420 410 400 390 W LU 3E CO CO LU - Z_ J U Q COAL ASH TRANSITION ZONE - - - - BEDROCK SOIL/FILL SAPROLITE ALLUVIUM CONCENTRATION CONTOUR CONCENTRATION CONTOURS DASHED WHERE INFERRED HASH MARKS POINT TO DECREASING CONCENTRATIONS WATER LEVEL (JUNE 17, 2015) SURFICIAL WATER LEVEL TRANSITION ZONE WATER LEVEL BEDROCK WATER LEVEL 2J FRACTURED/OXIDIZED ZONE m OBSERVED IN ROCK CORE w` NOT SAMPLED ABMW-02BR: WATER ANALYTICAL RESULTS IN pg/L 45'-45.5' SOIL TOTAL ANALYTICAL RESULTS IN mg/kg BORING SYMBOLS GRAPHIC SCALE 0 300 IN FEET HORIZONTAL: 1"=300' 0 30 IN FEET VERTICAL: 1"=30' NOTE: 10:1 VERTICAL EXAGGERATION SOIL SAMPLE WELL SCREEN WITH CONCENTRATION (micrograms per liter) SOURCES. 1. THE TOPOGRAPHY SURVEY DATA WITHIN THE PROPERTY BOUNDARY DATED MAY 19, 2015 WAS OBTAINED FROM WSP OF CARY, NORTH CAROLINA. 2. SELECT TOPOGRAPHIC ADJUSTMENTS BASED ON SITE SURVEY AND COMPARISON TO AERIAL PHOTOGRAPH. 3. 2015 LITHOLOGY INFORMATION OF SOIL AND WELL LOG TOPOGRAPHY IS FROM SYNTERRA. 4. GEOLOGIC INFORMATION FOR BORINGS AND MONITORING WELLS INSTALLED PRIOR TO 2015 TAKEN FROM S&ME (2010) AND QUANTEX (2008). NOTE.- 1 . CROSS SECTION LOCATIONS SHOWN ON FIGURE 2-1. 2. WATER LEVELS WERE COLLECTED BY SYNTERRA ON JUNE 17, 2015. 3. IMAC VALUE FOR VANADIUM IS 0.3 pg/L. erra 148 River Street, Suite 220 Greenville, South Carolina 29601 864-421-9999 www.synterracorp.com DRAWN BY: C. NEWELL DATE: 8/5/2015 CHECKED BY: J. WYLIE DATE: 8/5/2015 PROJECT MANAGER: K. WEBB LAYOUT NAME: FIGURE 11-10A (� DUKE � ENERGY PROGRESS MAYO STEAM ELECTRIC PLANT 10660 BOSTON RD ROXBORO, NORTH CAROLINA FIGURE 11-10a GEOLOGIC CROSS SECTION B-B' WITH VANADIUM I 0t'%0A1r% tiA LU n, C� Q W U O Q U) a) YaA IL 1a0 O 0- 0) a W U rl / C6 n 0) E U) 0) U) Cn a 0 Cn M m Cn a 0 I6 O / N O vi U) a) w 0 n E. a) w 0 / WE 7 LO O N 00 N 0 MW-13BR MW-13BR: pH7.2/Sb<1/As<1/Ba40/B<50/Cr(VI)0.005/Col.19/Fe1130/Mn474/TI<0.2/TDS370/V0.381 0'-2': Sb<6.5/As<6.5/Ba72.9/B<16.3/Cr6.1/Co<6.5/Fe19600/Mn82.8/TI<6.5/V32.4 52'-54': Sb<5.1/As<5.1/Ba62.3/B<2.5/Cr9.2/Co6.6/Fe10400/Mn789/TI<5.1/V13.1 ABMW-02/ 02BR ABMW-02: pH 7.8 / Sb <1 / As 1020 / Ba 173 / B 9200 / Cr(VI) 0.017 / Co <1 / Fe 356 / Mn 1110 / TI <0.2 / TDS 450 / V 3.53 ABMW-02BR: pH 7.2 / Sb <1 / As <1 / Ba 159 / B <50 / Cr(VI) 0.007 / Co <1 / Fe 107 / Mn 149 / TI <0.2 / TDS 370 / V 0.873 45'-45.5': Sb<6/As<6/Ba92.2/B<15/Cr8/Co6j/Fe18300/Mn579/TI<6/V30.3 57.5'-58': Sb<5.1/As<5.1/Ba41.2/B<12.8/Cr56.7/Co37.4/Fe43400/Mn782/TI<5.1/V84.9 ABMW-03/ 03S BMV' mm. 1 6 in u oil 0102 waft..- rig -.agog M'al IBM d s y MW-07D/ 07BR MW-07D: pH 6.4 / Sb <1 / As <1 / Ba 24 / B <50 / Cr(VI) NS / Co <1 / Fe 69 / Mn 188 / TI <0.2 / TDS 390 / V 0.798 MW-07BR: pH 7.4 / Sb <1 / As <1 / Ba 140 / B <50 / Cr(VI) NS / Co <1 / Fe 339 / Mn 263 / TI <0.2 / TDS 270 / V <0.3 C 1 550 1'-2': Sb<5.1/As<5.1/Ba21.5/B<12.8/Cr4.1/Co<5.1/Fe7320/Mn27.7/TI<5.1/V12.8 550 540 540 MW-08S/ 08D/ 08BR 530 p MW-08BR: pH 6.56 / Sb <1 / As <1 / Ba 66 / B <50 / Cr(VI) NS / Co <1 / Fe 2200 / Mn 2680 / TI <0.2 / TDS 550 / V <0.3 a0 0.75'-1.25': Sb <3.2 / As <3.2 / Ba 147 / B <63.4 / Cr 62.2 / Co 21.3 / Fe 24700 / Mn 1230 / TI <3.2 / V 50.6 520 25.5'-26': Sb<2.7/As<2.7/Ba193/B31j/Cr419/Co32.9/Fe31300/Mn933/TI<2.7/V75.8 Sb <2.7 / As <2.7 Ba 130 B <53.1 Cr 67.1 Co 7.4 Fe 11400 Mn 875 / TI <2.7 / V 25.2 1111 SECTION C-C' - VANADIUM FACING NORTH 510 500 490 ED 'Coll" 380 370 360 GRAPHIC SCALE 300 0 300 IN FEET HORIZONTAL: 1"=300' 30 0 30 ICOALASH TRANSITION ZONE BEDROCK SOIL/FILL SAPROLITE ALLUVIUM CONCENTRATION CONTOUR CONCENTRATION CONTOURS DASHED WHERE INFERRED HASH MARKS POINT TO DECREASING CONCENTRATIONS V WATER LEVEL (JUNE 17, 2015) SURFICIAL WATER LEVEL TRANSITION ZONE WATER LEVEL BEDROCK WATER LEVEL FRACTURED/OXIDIZED ZONE OBSERVED IN ROCK CORE NS NOT SAMPLED ABMW-02BR: WATER ANALYTICAL RESULTS IN pg/L 45'-45.5' SOIL TOTAL ANALYTICAL RESULTS IN mg/kg BORING SYMBOLS SOIL SAMPLE WELL SCREEN WITH CONCENTRATION (micrograms per liter) SOURCES.- 1 THE TOPOGRAPHY SURVEY DATA WITHIN THE PROPERTY BOUNDARY DATED MAY 19, 2015 WAS OBTAINED FROM WSP OF CARY, NORTH CAROLINA. 2. SELECT TOPOGRAPHIC ADJUSTMENTS BASED ON SITE SURVEY AND COMPARISON TO AERIAL PHOTOGRAPH. 3. 2015 LITHOLOGY INFORMATION OF SOIL AND WELL LOG TOPOGRAPHY IS FROM SYNTERRA. 4. GEOLOGIC INFORMATION FOR BORINGS AND MONITORING WELLS INSTALLED PRIOR TO 2015 TAKEN FROM S&ME (2010) AND QUANTEX (2008). NOTE.- 1 . CROSS SECTION LOCATIONS SHOWN ON FIGURE 2-1. 2. WATER LEVELS WERE COLLECTED BY SYNTERRA ON JUNE 17, 2015. 3. IMAC VALUE FOR VANADIUM IS 0.3 pg/L. erra 148 River Street, Suite 220 Greenville, South Carolina 29601 864-421-9999 www.synterracorp.com DRAWN BY: C. NEWELL DATE: 8/5/2015 CHECKED BY: J. WYLIE DATE: 8/5/2015 PROJECT MANAGER: K. WEBB LAYOUT NAME: FIGURE 11-10B DUKE ENERGY boo PROGRESS MAYO STEAM ELECTRIC PLANT 10660 BOSTON RD 60 ROXBORO, NORTH CAROLINA IN FEET VERTICAL: 1"=30' NOTE: 10:1 VERTICAL EXAGGERATION FIGURE 11-10b GEOLOGIC CROSS SECTION C-C' WITH VANADIUM Primary Sources Secondary Sources Exposure Medium Exposure Route I Current Land Use (Hypothetical Future Land Use Primary Release Mechanisms Active Ash Basin Secondary Release Mechanisms Seeps to Crutchfield Branch Secondary Release/Exposure Routes Note 1: Evaluation of potential human health risks to off -site residents will be conducted based upon results of ongoing groundwater contaminant fate and transport modeling. Note 2: Would include consumption of fish, as applicable. Active Ash Basin jPotential Human Receptors • Potentially Complete Exposure Pathway Incomplete Exposure Pathway TOE Drain NPDES Discharge Seeps Soil Groundwater I POP Mayo Lake nent Ingestion Soil Dermal Inhalation Ingestion Note 2 Cruchfield TSurface Water Dermal Branch Inhalation Ingestion Sediment Dermal Inhalation Ingestion Groundwater -----1110 Dermal Inhalation Qj 4 w I?.. d 0 ^o Q v o Z 4 w y x 3 U d v d 0 a a o .. s c u y o .. n •.. a d ro o .. 0 .. ro 0 .. d o o o a z~. I&T synTerm 148 River Street, Suite 220 Greenville, SC 29601 Phone: (864) 421-9999 E Figure 12-1 Human Health Conceptual Exposure Model Mayo Steam Plant Roxboro, North Carolina P:\Duke Energy Progress.1026\105. Mayo Ash Basin GW Assessment Plan\1.11 CSA Reporting\Figures\Figure 12-1 Mayo CEM.xlsx8/31/2015 A 4 - - - . • • -- SR.• .ems Ilk 2 -V ABMW-03 As B Fe ' Mn TI V AsJr B ' r CoFe 1� 4. ADS i,lag V r— Rr�� .. -.. IL '98, LANDFILL --- t/♦ram♦- 1 r� r♦ I 'A .+ *�- MAYO •` LAKE 16 :A4 • s � Y 1 { *14 •� ♦ " 4r 1D LEGEND NC2L OR IMAC EXCEEDANCE - BOLDED IF COAL ASH COPC3 (SEE TABLES 12-1 AND 12-2)1'2 ii?� MONITORING WELL DITCH STREAM ASH BASIN BOUNDARY ASH BASIN COMPLIANCE BOUNDARY �^ DUKE ENERGY PROGRESS MAYO PLANT SITE BOUNDARY Constituent Full Name Constituent Abbreviation Antimony Sb Arsenic As Barium Ba Boron B Cobalt Cc Iron Fe Manganese Mn Thallium TI Total Dissolved Solids TDS Vanadium V NOTES: 1 NCDENR. CLASSIFICATIONS AND WATER QUALITY STANDARDS APPLICABLE TO THE SURFACE WATERS OF NORTH CAROLINA. NORTH CAROLINA ADMINISTRATIVE CODE TITLE 15A, SUBCHAPTER 02B. 2015. 2 NC2L FOR ANTIMONY, BERYLLIUM, COBALT, THALLIUM, AND VANADIUM ARE "INTERIM MAXIMUM ALLOWABLE CONCENTRATIONS" (IMAC). 3 CONSTITUENTS IDENTIFIED AS A SITE SPECIFIC CONSTITUENT OF POTENTIAL CONCERN(COPC). 4 SITE AERIAL ORTHOPHOTOGRAPHY IS DATED APRIL 17, 2014. IT WAS OBTAINED FROM WSP. 5 ADDITIONAL OFFSITE AERIAL ORTHOPHOTOGRAPHY IS DATED 2013. IT WAS OBTAINED FROM THE INC CENTER FOR GEOGRAPHIC INFORMATION AND ANALYSIS. (http //services nconemap govl 6 PARCEL BOUNDARY WAS OBTAINED FROM THE INC CENTER FOR GEOGRAPHIC INFORMATION AND ANALYSIS. (http://services.nconemap.gov/) 7 DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE COORDINATE SYSTEM RIPS 3200 (NAD83/2011). GRAPHIC SCALE 400 0 400 800 1,200 1,600 2,000 IN FEET DUKE o U syn Terra ' ENERGY PROGRESS 148 RIVER STREET, SUITE 220 MAYO STEAM ELECTRIC POWER PLANT GREENVILLE, SC 29601 10660 BOSTON RD m 864-421-9999 ROXBORO, NORTH CAROLINA27574 www.synterracorp.com FIGURE 12-2 COPC LOCATIONS FLAGGED GROUNDWATER - ASH PORE WATER HUMAN HEALTH N------------- /t-•---- ----------------- I I \• J SR-1501. 4 AL.- 94I, li a MW-16S pH R, i b- � ao 1 �V ✓a�'s ♦ v+ram♦- 1 I' �- MAYO LAKE r ram''♦ . .#JAW 1 -• 1 Jr � >v r 3" + �+ + fr' ICE l LEGEND NC2L OR IMAC EXCEEDANCE - BOLDED IF COAL ASH COPC3 (SEE TABLES 12-2 AND 12-4)1•2 ii?� MONITORING WELL DITCH > STREAM ASH BASIN BOUNDARY - _ ASH BASIN COMPLIANCE BOUNDARY �^ DUKE ENERGY PROGRESS MAYO PLANT SITE BOUNDARY Constituent Full Name Constituent Abbreviation pH pH Boron B Cobalt Co Iron Fe Manganese Mn Vanadium V NOTES: 1 NCDENR. CLASSIFICATIONS AND WATER QUALITY STANDARDS APPLICABLE TO THE SURFACE WATERS OF NORTH CAROLINA. NORTH CAROLINA ADMINISTRATIVE CODE TITLE 15A, SUBCHAPTER 02B. 2015. 2 NC2L FOR ANTIMONY, BERYLLIUM, COBALT, THALLIUM, AND VANADIUM ARE "INTERIM MAXIMUM ALLOWABLE CONCENTRATIONS" (IMAC). 3 CONSTITUENTS IDENTIFIED AS A SITE SPECIFIC CONSTITUENT OF POTENTIAL CONCERN(COPC). I SITE AERIAL ORTHOPHOTOGRAPHY IS DATED APRIL 17, 2014. T WAS OBTAINED FROM WSP. 5 ADDITIONAL OFFSITE AERIAL ORTHOPHOTOGRAPHY IS DATED 2013. IT WAS OBTAINED FROM THE INC CENTER FOR GEOGRAPHIC INFORMATION AND ANALYSIS. (http://services.nconemap.gov/) 6 PARCEL BOUNDARY WAS OBTAINED FROM THE INC CENTER FOR GEOGRAPHIC INFORMATION AND ANALYSIS. (http://services.nconemap.gov/) 7 DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE COORDINATE SYSTEM RIPS 3200 (NAD8312011). GRAPHIC SCALE 400 0 400 800 1,200 1,600 2,000 IN FEET `=- DUKE synTerra E N E RGY PROGRESS 148 RIVER STREET, SUITE 220 MAYO STEAM ELECTRIC POWER PLANT GREENVILLE, SC 29601 10660 BOSTON RD 864-421-9999 ROXBORO, NORTH CAROLINA 27574 www.synterracorp.com FIGURE 12-3 COPC LOCATIONS FLAGGED GROUNDWATER - ALLUVIAL HUMAN HEALTH • • ...... ...... �.,/ • .ems SR15p, I► ♦ �yo) J 'A .+ *�- MAYO �` LAKE 44 �.°� ram''♦ r 1 -• 1 � all 111111 y J LEGEND NC2L OR IMAC EXCEEDANCE - BOLDED IF COAL ASH COPC3 (SEE TABLES 12-2 AND 12-5)1,2 ii?� MONITORING WELL DITCH STREAM ASH BASIN BOUNDARY ASH BASIN COMPLIANCE BOUNDARY �^ DUKE ENERGY PROGRESS MAYO PLANT SITE BOUNDARY Constituent Full Name Constituent Abbreviation pH pH Boron B Cobalt Co Iron Fe Manganese Mn NOTES: 1 NCDENR. CLASSIFICATIONS AND WATER QUALITY STANDARDS APPLICABLE TO THE SURFACE WATERS OF NORTH CAROLINA. NORTH CAROLINA ADMINISTRATIVE CODE TITLE 15A, SUBCHAPTER 02B. 2015. 2 NC2L FOR ANTIMONY, BERYLLIUM, COBALT, THALLIUM, AND VANADIUM ARE "INTERIM MAXIMUM ALLOWABLE CONCENTRATIONS" (IMAC). 3 CONSTITUENTS IDENTIFIED AS A SITE SPECIFIC CONSTITUENT OF POTENTIAL CONCERN(COPC). 4 SITE AERIAL ORTHOPHOTOGRAPHY IS DATED APRIL 17, 2014. IT WAS OBTAINED FROM WSP. 5 ADDITIONAL OFFSITE AERIAL ORTHOPHOTOGRAPHY IS DATED 2013. IT WAS OBTAINED FROM THE INC CENTER FOR GEOGRAPHIC INFORMATION AND ANALYSIS. (http://services.nconemap.gov/) 6 PARCEL BOUNDARY WAS OBTAINED FROM THE INC CENTER FOR GEOGRAPHIC INFORMATION AND ANALYSIS. (http://services.nconemap.gov/) 7 DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE COORDINATE SYSTEM RIPS 3200 (NAD8312011). GRAPHIC SCALE 400 0 400 800 11200 1,600 2,000 IN FEET 10 4ft� DUKE ENERGY syn Terra 3 PROGRESS 148 RIVER STREET, SUITE 220 MAYO STEAM ELECTRIC POWER PLANT w GREENVILLE, SC 29601 10660 BOSTON RD m 864-421-9999 ROXBORO, NORTH CAROLINA27574 www.synterracorp.com FIGURE 12-4 COPC LOCATIONS FLAGGED GROUNDWATER - SAPROLITE HUMAN HEALTH — / /y • MW-16D • rj / Mn • • CW-03 pH V ► SR 1501. • . ! , Ilk CW-02 pH - B A 4 1► -V CW-01 pH y Fe V 'r 7 MW-07D _♦ pH Mn 81 V )FILL J .�J 'A .+ MAYO •" � LAKE • s LEGEND NC2L OR IMAC EXCEEDANCE - BOLDED IF COAL ASH COPC3 (SEE TABLES 12-2 AND 12-6)1'2 ii?� MONITORING WELL DITCH STREAM ASH BASIN BOUNDARY ASH BASIN COMPLIANCE BOUNDARY �^ DUKE ENERGY PROGRESS MAYO PLANT SITE BOUNDARY Constituent Full Name Constituent Abbreviation pH pH Antimony Sb Arsenic As Barium Ba Boron B Cobalt Cc Iron Fe Manganese Mn Total Dissolved Solids TDS Vanadium V NOTES: 1 NCDENR. CLASSIFICATIONS AND WATER QUALITY STANDARDS APPLICABLE TO THE SURFACE WATERS OF NORTH CAROLINA. NORTH CAROLINA ADMINISTRATIVE CODE TITLE 15A, SUBCHAPTER 02B. 2015. 2 NC2L FOR ANTIMONY, BERYLLIUM, COBALT, THALLIUM, AND VANADIUM ARE "INTERIM MAXIMUM ALLOWABLE CONCENTRATIONS" (IMAC). 3 CONSTITUENTS IDENTIFIED AS A SITE SPECIFIC CONSTITUENT OF POTENTIAL CONCERN(COPC). 4 SITE AERIAL ORTHOPHOTOGRAPHY IS DATED APRIL 17, 2014. IT WAS OBTAINED FROM WSP. 5 ADDITIONAL OFFSITE AERIAL ORTHOPHOTOGRAPHY IS DATED 2013. IT WAS OBTAINED FROM THE INC CENTER FOR GEOGRAPHIC INFORMATION AND ANALYSIS. (http://services.nconemap.gov/) 6 PARCEL BOUNDARY WAS OBTAINED FROM THE INC CENTER FOR GEOGRAPHIC INFORMATION AND ANALYSIS. (http://services.nconemap.gov/) 7 DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE COORDINATE SYSTEM RIPS 3200 (NAD8312011). GRAPHIC SCALE 400 0 400 800 1,200 1,600 2,000 IN FEET 4*�DUKE ENERGY'----,- synTerra PROGRESS 148 RIVER STREET, SUITE 220 MAYO STEAM ELECTRIC POWER PLANT GREENVILLE, SC 29601 10660 BOSTON RD m 864-421-9999 ROXBORO, NORTH CAROLINA27574 www.synterracorp.com FIGURE 12-5 COPC LOCATIONS FLAGGED GROUNDWATER - TRANSITION ZONE HUMAN HEALTH CW-05 Fe Mn MW-05BR Fe Mn 4 i MW-13BR Co Fe Mn \ o� T II r ye • + ) , r-•✓ l ♦ o ------------- LEGEND &WOmi MW-16BR "W pH NC2L OR IMAC EXCEEDANCE - BOLDED IF COAL ASH COPC3 V (SEE TABLES 12-2 AND 12-7)1•2 CW-04 MONITORING WELL H _ —� — - DITCH V p MW-03BR` STREAM Fe `. �' ,� ASH BASIN BOUNDARY Mn ' SR- 15p1' I► _ < 1•� ASH BASIN COMPLIANCE BOUNDARY TDS - - -r - ' -�� DUKE ENERGY PROGRESS MAYO PLANT SITE BOUNDARY V ABMW-02BR Mn V A ABMW-04BR Fe Mn V J FTDS MW-04 pH V CW-01 D V + r MW-07BR ♦ MW-08BR Fe Cr(Total) Mn Co pr, Fe Mn TDS V MW-096R pH _ Fe Mn ...% V `+ 'A .+ *�- MAYO ` LAKE 1 1 it ' � ♦ . r--s r �1 i fr' Constituent Full Name Constituent Abbreviation pH pH Chromium Cr(Total) Cobalt Co Iron Fe Manganese Mn Total Dissolved Solids TDS Vanadium V NOTES: 1 NCDENR. CLASSIFICATIONS AND WATER QUALITY STANDARDS APPLICABLE TO THE SURFACE WATERS OF NORTH CAROLINA. NORTH CAROLINA ADMINISTRATIVE CODE TITLE 15A, SUBCHAPTER 02B. 2015. 2 NC2L FOR ANTIMONY, BERYLLIUM, COBALT, THALLIUM, AND VANADIUM ARE "INTERIM MAXIMUM ALLOWABLE CONCENTRATIONS" (IMAC). 3 CONSTITUENTS IDENTIFIED AS A SITE SPECIFIC CONSTITUENT OF POTENTIAL CONCERN(COPC). I SITE AERIAL ORTHOPHOTOGRAPHY IS DATED APRIL 17, 2014. T WAS OBTAINED FROM WSP. 5 ADDITIONAL OFFSITE AERIAL ORTHOPHOTOGRAPHY IS DATED 2013. IT WAS OBTAINED FROM THE INC CENTER FOR GEOGRAPHIC INFORMATION AND ANALYSIS. (http://services.nconemap.gov/) 6 PARCEL BOUNDARY WAS OBTAINED FROM THE INC CENTER FOR GEOGRAPHIC INFORMATION AND ANALYSIS. (http://services.nconemap.gov/) 7 DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE COORDINATE SYSTEM RIPS 3200 (NAD8312011). GRAPHIC SCALE 400 0 400 800 1200 1600 2,000 IN FEET LT 4ft� D U KE synTerra ENERGY PROGRESS 148 RIVER STREET, SUITE 220 MAYO STEAM ELECTRIC POWER PLANT GREENVILLE, SC 29601 10660 BOSTON RD 864-421-9999 ROXBORO, NORTH CAROLINA27574 www.synterracorp.com FIGURE 12-6 COPC LOCATIONS FLAGGED GROUNDWATER - BEDROCK HUMAN HEALTH • +Jy SB-01 Y.. As Co Fe It MW-03BR Co ; A Fe Mn A BR All - AI C Co o Fe MW-16BR CoCo _l1k Mn SB-07 All Co Fe Mn MW-13BR r All ABMW-01 ` Fe As ABMW-011 As � Co ♦ Y '1 T + ♦ • SB_02 I iI All + . As • + Co ye • o Fe i ) Mn /s V MW-11 BR � + All - Co +/ Fe .. r-•✓ l ♦ o MW-12D ♦, ' ..'�'♦ As MW-12D AI I Fe " ♦ 1 SB-06 SB-05 As Co Fe Mn 7 I � ♦ MW-07BR MW-08BR L I Fe All Co Fe Mn V .- + )0- D l .. [J� /0"11 2 6 r• , LEGEND EPA R4 REGIONAL INDUSTRIAL SOIL SCREENING LEVEL EXCEEDANCE - BOLDED IF COAL ASH COPC (SEE TABLES 12-2 AND 12-8)1 EPA R4 REGIONAL RESIDENTIAL SOIL SCREENING LEVEL EXCEEDANCE - BOLDED IF COAL ASH COPC (SEE TABLES 12-2 AND 12-8)1 io� MONITORING WELL SOIL BORING DITCH STREAM ASH BASIN BOUNDARY ASH BASIN COMPLIANCE BOUNDARY �^ DUKE ENERGY PROGRESS MAYO PLANT SITE BOUNDARY Constituent Full Name Constituent Abbreviation Aluminum Al Arsenic As Cobalt Co Iron Fe Manganese Mn Vanadium V NOTES: 1 USEPA. REGIONAL SCREENING LEVELS FOR CHEMICAL CONTAMINANTSAT SUPERFUND SITES. ACCESSED 07/26/2015. (http://www.epa.gov/reg3hwmd/risk/human/rb-concentration table/Generic-Tables/index.htm) 2 NC2L FOR ANTIMONY, BERYLLIUM, COBALT, THALLIUM, AND VANADIUM ARE "INTERIM MAXIMUM ALLOWABLE CONCENTRATIONS' (IMAC). 3 SITE AERIAL ORTHOPHOTOGRAPHY IS DATED APRIL 17, 2014. IT WAS OBTAINED FROM WSP. 4 ADDITIONAL OFFSITE AERIAL ORTHOPHOTOGRAPHY IS DATED 2013. IT WAS OBTAINED FROM THE INC CENTER FOR GEOGRAPHIC INFORMATION AND ANALYSIS. (http://services.nconemap.gov/) 5 PARCEL BOUNDARY WAS OBTAINED FROM THE NC CENTER FOR GEOGRAPHIC INFORMATION AND ANALYSIS. (http://services.nconemap.gov/) 6 DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE COORDINATE SYSTEM RIPS 3200 (NAD8312011). GRAPHIC SCALE 400 0 400 800 1,200 1,600 2,000 IN FEET 10 DUKE synTerra ENERGY 148 RIVER STREET, SUITE 220 MAYO STEAM ELECTRIC POWER PLANT GREENVILLE, SC 29601 10660 BOSTON RD 864-421-9999 ROXBORO, NORTH CAROLINA27574 www.synterracorp.com FIGURE 12-7 COPC LOCATIONS FLAGGED SOILS (0-2 FEET) - HUMAN HEALTH 4 .�.�'—..—..—..--. S-04 SW-CB2 As Co Fe IF Fe �. Mn S 04 SW-CB1 ► CO As Co - ,- Fe Co Yr _ Mn Fe � Mn Mn �.. ��. Ilk ._---- S-01 r- 1► As S-01 S-02B S-03 Fe As - Co Co Fe Fe Fe Mn Mn Mn , V ACTIVE AS BH ASIN SS-08 g-pg Co{ �— • • — - • > Mn Co .� `,�♦� Mn 1981 LANDFILL ' V i J SW-REF1 Fe >r IN ,, �. MAYO •` LAKE r �* r �4 .- , y'. S-06 Co Fe Mn ; LEGEND EPA R4 REGIONAL INDUSTRIAL SOIL SCREENING LEVEL EXCEEDANCE - BOLDED IF COAL ASH COPC (SEE TABLES 12-2 AND 12-9)1 EPA R4 REGIONAL RESIDENTIAL SOIL SCREENING LEVEL EXCEEDANCE - BOLDED IF COAL ASH COPC (SEE TABLES 12-2 AND 12-9)1 O SEEP IN SURFACE WATER POINT —> DITCH - STREAM -, ASH BASIN BOUNDARY ASH BASIN COMPLIANCE BOUNDARY �^ DUKE ENERGY PROGRESS MAYO PLANT SITE BOUNDARY Constituent Full Name Constituent Abbreviation Arsenic As Cobalt Cc Iron Fe Manganese Mn Vanadium V NOTES: 1 USEPA. REGIONAL SCREENING LEVELS FOR CHEMICAL CONTAMINANTSAT SUPERFUND SITES. ACCESSED 07/26/2015. (http://www.epa.gov/reg3hwmd/risk/human/rb-concentration table/Generic-Tables/index.htm) 2 NC2L FOR ANTIMONY, BERYLLIUM, COBALT, THALLIUM, AND VANADIUM ARE "INTERIM MAXIMUM ALLOWABLE CONCENTRATIONS" (IMAC). 3 SITE AERIAL ORTHOPHOTOGRAPHY IS DATED APRIL 17, 2014. IT WAS OBTAINED FROM WSP. 4 ADDITIONAL OFFSITE AERIAL ORTHOPHOTOGRAPHY IS DATED 2013. IT WAS OBTAINED FROM THE NC CENTER FOR GEOGRAPHIC INFORMATION AND ANALYSIS. (http://services.nconemap.gov/) 5 PARCEL BOUNDARY WAS OBTAINED FROM THE INC CENTER FOR GEOGRAPHIC INFORMATION AND ANALYSIS. (http://services.nconemap.gov/) 6 DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE COORDINATE SYSTEM RIPS 3200 (NAD8312011). GRAPHIC SCALE 400 0 400 800 1,200 1,600 2,000 IN FEET 10 �fDUKE +O'ENERGY synTerra PROGRESS 148 RIVER STREET, SUITE 220 MAYO STEAM ELECTRIC POWER PLANT GREENVILLE, SC 29601 10660 BOSTON RD 864-421-9999 ROXBORO, NORTH CAROLINA27574 www.synterracorp.com FIGURE 12-8 COPC LOCATIONS FLAGGED SEDIMENT - HUMAN HEALTH LEGEND • A •� • � � SW-C62 .,�., i ► S-04 As 5 02 f As Co Co `• �,. • • TDS ` 1 It l S-05 As -�� TDS FF )! )0- D y'. ♦ EPA NATIONAL RECOMMENDED WATER QUALITY SCREENING LEVEL EXCEEDANCE - BOLDED IF COAL ASH COPC (SEE TABLES 12-2,12-10 AND 12-11)1 n SEEP ■ SURFACE WATER POINT —) - — — DITCH 10 STREAM j� ASH BASIN BOUNDARY ASH BASIN COMPLIANCE BOUNDARY �^ DUKE ENERGY PROGRESS MAYO PLANT SITE BOUNDARY Constituent Full Name Constituent Abbreviation Arsenic As Cobalt Cc Total Dissolved Solids TDS NOTES: � USEPA. NATIONAL RECOMMENDED WATER CRITERIA. ACCESSED 07/26/2015. (http://water.epa.gov/scitech/swgu idance/standards/criteria/current/index.cfm) 2 NCDENR. CLASSIFICATIONS AND WATER QUALITY STANDARDS APPLICABLE TO THE SURFACE WATERS OF NORTH CAROLINA. NORTH CAROLINA ADMINISTRATIVE CODE TITLE 15A, SUBCHAPTER 02B. 2015. 3 NC2L FOR ANTIMONY, BERYLLIUM, COBALT, THALLIUM, AND VANADIUM ARE "INTERIM MAXIMUM ALLOWABLE CONCENTRATIONS" (IMAC). 4 SITE AERIAL ORTHOPHOTOGRAPHY IS DATED APRIL 17, 2014. IT WAS OBTAINED FROM WSP. 5 ADDITIONAL OFFSITE AERIAL ORTHOPHOTOGRAPHY IS DATED 2012. IT WAS OBTAINED FROM THE INC CENTER FOR GEOGRAPHIC INFORMATION AND ANALYSIS. (http://services.nconemap.gov/) 6 PARCEL BOUNDARY WAS OBTAINED FROM THE NC CENTER FOR GEOGRAPHIC INFORMATION AND ANALYSIS. (http://services.nconemap.gov/) 7 DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE COORDINATE SYSTEM RIPS 3200 (NAD8312011). GRAPHIC SCALE 400 0 400 800 1,200 1,600 2,000 IN FEET DUKE U ' ENERGY o synTerra PROGRESS 148 RIVER STREET, SUITE 220 MAYO STEAM ELECTRIC POWER PLANT w GREENVILLE, SC 29601 10660 BOSTON RD m 864-421-9999 ROXBORO, NORTH CAROLINA27574 www.synterracorp.com FIGURE 12-9 COPC LOCATIONS FLAGGED SURFACE WATER I SEEPS - HUMAN HEALTH t Ir Primary Sources Secondary Sources Exposure Medium Exposure Route I Current and Hypothetical Future Ecological Receptors Existing Primary Release Mechanisms Ash Basin ou FGD Discharge (Periodic) v Incomplete Pathway - - - - - ► e o Secondary Source Flow 0 Exposure Medium FGD Settling Pond Polishing Pond Ash Basin Potential Human Receptors • Potentially Complete Exposure Pathway Incomplete Exposure Pathway Dermal Soil Incidental Ingestion Ingestion of Prey or Plants Surface Water Dermal Purposeful Ingestion (Drinking) Incidental Ingestion Ingestion of Prey or Plants Dermal Sediment Incidental Ingestion Ingestion of Prey or Plants - - - Groundwater - - Incidental Ingestion Ingestion of Prey or Plants 10P synTerra 148 River Street, Suite 220 Greenville, SC 29601 Phone: (864) 421-9999 Figure 12-10 Ecological Conceptual Exposure Model Mayo Steam Electric Plant s~ UnE-0 P:\Duke Energy Progress.1026\105. Mayo Ash Basin GW Assessment Plan\1.11 CSA Reporting\Figures\Figure 12-10 Ecological CEM Mayo.xlsx8/28/2015 ., o+.. .. . .. , SH4 S AIB S AIB a' N ------ ------ c 2 c 2 1%h S02 S-02 p Fe Fe P t �\ • •. 5-02 SH PH pH / B a v pH B Fe • S-03 pH } Fe B SW-C61 _- 5-04 pH k pH Fe •��� / `` pH Fe SW-CB1 SW-CB1www. jgjpH S-01 _ _ Fe pH A B S-08 B Fe SpH PHB S-02B O Al AI J� o B pH B S 01 Fe Fe pH S-026 S-02B S-08 AI Al �— > Fe pH pH -. ACTIVE Cu Cu ASH BASIN S-OS pH ` + AI .4 1981 , 1 S-OS -;ri: LANDFILL BI 'ram'• S-05 r • _ 1 Al d r J .l - -•, I r- 1 -• ye � /s ° ♦ o ♦ + � o � -01 r �' ++ S-06 AI 1 SW-REF1 Al ... s-os • SW-REF1 Al LEGEND EPA R4 FW CHRONIC EXCEEDANCE - (SEE TABLES 12-2 AND 12-14)4 EPAAQUATIC LIFE ACUTE EXCEEDANCE - (SEE TABLES 12.2 AND 12-14)4 EPAAQUATIC LIFE CHRONIC EXCEEDANCE - (SEE TABLES 12-2 AND 12-14)1 NC213 AQUATIC LIFE ACUTE EXCEEDANCE - (SEE TABLES 12-2 AND 12-14)1 NC2B AQUATIC LIFE CHRONIC EXCEEDANCE - (SEE TABLES 12.2 AND 12.14)1 I 0 SEEP ■ SURFACE WATER POINT —)~ — - DITCH I STREAM ASH BASIN BOUNDARY ASH BASIN COMPLIANCE BOUNDARY DUKE ENERGY PROGRESS MAYO PLANT SITE BOUNDARY Constituent Full Name Constituent Abbreviation pH pH Aluminum Al Boron B Copper Cu Iron Fe NOTES: 1 USEPA. NATIONAL RECOMMENDED WATER CRITERIA. ACCESSED 07/26/2015. (http://water.epa.gov/scitech/swgu id ance/standards/criteria/current/index.cfm) 2 USEPA. SUPPLEMENTAL GUIDANCE TO RISK ASSESSMENT GUIDANCE FOR SUPERFUND: REGION 4 BULLETINS ECOLOGICAL RISKASSESSMENT. ORIGINALLY PUBLISHED NOVEMBER 1995. WEB§TE VERSION LAST UPDATED 11/30/2001: (http://www.epa.gov/region4/su perfund/programs/riskassess/ecol bu l.htm I. ) 3 NCDENR. CLASSIFICATIONS AND WATER QUALITY STANDARDS APPLICABLE TO THE SURFACE WATERS OF NORTH CAROLINA. NORTH CAROLINA ADMINISTRATIVE CODE TITLE 15A, SUBCHAPTER 02B. 2015. 4 SITE AERIAL ORTHOPHOTOGRAPHY IS DATED APRIL 17, 2014. IT WAS OBTAINED FROM WSP. 5 ADDITIONAL OFFSITE AERIAL ORTHOPHOTOGRAPHY IS DATED 2013. IT WAS OBTAINED FROM THE NC CENTER FOR GEOGRAPHIC INFORMATION AND ANALYSIS. (http://services.nconemap.gov/) 6 PARCEL BOUNDARY WAS OBTAINED FROM THE NC CENTER FOR GEOGRAPHIC INFORMATION AND ANALYSIS. (http://services.nconemap.gov/) 7 DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE COORDINATE SYSTEM RIPS 3200 (NAD8312011). GRAPHIC SCALE 400 0 400 800 1,200 1,600 2,000 IN FEET DUKE o U ' ENERGY synTerra PROGRESS 148 RIVER STREET, SUITE 220 MAYO STEAM ELECTRIC POWER PLANT w GREENVILLE, SC 29601 10660 BOSTON RD m 864-421-9999 ROXBORO, NORTH CAROLINA27574 www.synterracorp.com FIGURE 12-11 COPC LOCATIONS FLAGGED SURFACE WATER 1 SEEPS - ECOLOGICAL ------------- ----------------- LEGEND N /t-•---- ' i� MW-03BR Al p' / EPA R4 REGIONAL SOIL SCREENING LEVEL EXCEEDANCE - (SEE TABLES 12-2 AND 12-15)1 Cr(Total) , MW-16BR • . Fe Mn;� ' MW115BR A Al Cr(Total) � MONITORING WELL V Cr(Total) M� SOIL BORING SB-01 - Fe Min VAl , DITCH Cr(Fetal) ! "� �'?l� Si 5� �j a� V �SR:15p� . / > STREAM ASH BASIN BOUNDARY `- - ! Mn - - - ASH BASIN COMPLIANCE BOUNDARY V DUKE ENERGY PROGRESS MAYO PLANT SITE BOUNDARY A 4 -Ai -4- MW-13BR Al Cr(Total) Fe V ABMW-01 ` Al '.\ As + Be o ♦ B ♦ Cr(Total) Fe V T + � r ' I it , r yre r ♦ /s /1r r ♦ r-�✓ l ♦ o 1 v � 0 co MW-11 BR Al Cr(Total) Cu Fe Hg V SB-02 Al B Mom: Cr(Total) Fe Mn Se, V MW-12D Al B A� Cr(Total) Fe V r B �r B - Cr(Total) Fe J Mn Se V ♦ MW-07BR MW-08BR Al Al Cr(Total) Cr(Total) Fe Co V Fe Mn n�».tir• Zn ♦ r r ' d r♦ r+�r MW-10BR Al �. B 1 Cr(Total) Fe Mn Se V Zn Constituent Full Name Constituent Abbreviation Aluminum Al Arsenic As Beryllium Be Boron B Chromium Cr(Total) Cobalt Cc Copper Cu Iron Fe Manganese Mn Mercury Hg Selenium Se Vanadium V Zinc Zn NOTES: 1 USEPA. REGIONAL SCREENING LEVELS FOR CHEMICAL CONTAMINANTSAT SUPERFUND SITES. ACCESSED 07/26/2015. (http://www.epa.gov/reg3hwmd/risk/human/rb-concentration table/Generic-Tables/index.htm) 2 NC2L FOR ANTIMONY, BERYLLIUM, COBALT, THALLIUM, AND VANADIUM ARE "INTERIM MAXIMUM ALLOWABLE CONCENTRATIONS" (IMAC). 3 SITE AERIAL ORTHOPHOTOGRAPHY IS DATED APRIL 17, 2014. IT WAS OBTAINED FROM WSP. 4 ADDITIONAL OFFSITE AERIAL ORTHOPHOTOGRAPHY IS DATED 2013. IT WAS OBTAINED FROM THE NC CENTER FOR GEOGRAPHIC INFORMATION AND ANALYSIS. (http://services.nconemap.gov/) 5 PARCEL BOUNDARY WAS OBTAINED FROM THE INC CENTER FOR GEOGRAPHIC INFORMATION AND ANALYSIS. (http://services.nconemap.gov/) 6 DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE COORDINATE SYSTEM RIPS 3200 (NAD8312011). GRAPHIC SCALE 400 0 400 800 1,200 1,600 2,000 IN FEET 10 4ft� DUKE ENERGY syn Terra 3 PROGRESS 148 RIVER STREET, SUITE 220 MAYO STEAM ELECTRIC POWER PLANT w GREENVILLE, SC 29601 10660 BOSTON RD m 864-421-9999 ROXBORO, NORTH CAROLINA27574 www.synterracorp.com FIGURE 12-12 COPC LOCATIONS FLAGGED SOILS (0-2 FEET) - ECOLOGICAL A 4 l • rJ � ...... - -- — -- • �. / SAl -02 AI • • Cr(Total) • • S-01 Fe / As Mn • • Zn V ' S-01 s. h J Al As Ba B Cr(Total) Fe Mn Zn Al Cr(Total) Fe Mn S-03 1. Cr(Total) SW-CB2 AI S-03 Cr(TotalI Al Fe Mn Cr(Total) Fe V - Mn Nx V SR.1501.N Ilk - r' v SW-CB1 Al Cr(Total) Fe Mn V 1981 LANDFILL 1♦ • r. S-06 .� t. Zn r 40 S-06 All Cr(Total) Fe • + Mn A Zn 7 LEGEND EPA R4 EFFECTS VALUE EXCEEDANCE - (SEE TABLES 12-2 AND 12-16)' EPA R4 SOIL SCREENING LEVEL EXCEEDANCE - (SEE TABLES 12-2 AND 12-16)1 U SEEP ■ SURFACE WATER POINT DITCH STREAM ASH BASIN BOUNDARY ASH BASIN COMPLIANCE BOUNDARY �^ DUKE ENERGY PROGRESS MAYO PLANT SITE BOUNDARY Constituent Full Name Constituent Abbreviation Aluminum Al Arsenic As Barium Be Boron B Chromium Cr(Total) Cobalt Cc Iron Fe Manganese Mn Vanadium V Zinc Zn NOTES: 1 USEPA. SUPPLEMENTAL GUIDANCE TO RISKASSESSMENT GUIDANCE FOR SUPERFUND: REGION 4 BULLETINS ECOLOGICAL RISKASSESSMENT. ORIGINALLY PUBLISHED NOVEMBER 1995. WEB§TE VERSION LAST UPDATED 11/30/2001: (http://www.epa.gov/region4/su perfund/programs/riskassess/ecol bu l.htm I. ) 2 SITE AERIAL ORTHOPHOTOGRAPHY IS DATED APRIL 17, 2014. IT WAS OBTAINED FROM WSP. 3 ADDITIONAL OFFSITE AERIAL ORTHOPHOTOGRAPHY IS DATED 2013. IT WAS OBTAINED FROM THE NC CENTER FOR GEOGRAPHIC INFORMATION AND ANALYSIS. (http://services.nconemap.gov/) 4 PARCEL BOUNDARY WAS OBTAINED FROM THE NC CENTER FOR GEOGRAPHIC INFORMATION AND ANALYSIS. (http://services.nconemap.gov/) 5 DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE COORDINATE SYSTEM RIPS 3200 (NAD8312011). GRAPHIC SCALE 400 0 400 800 1,200 1,600 2,000 IN FEET ,�vj 4ft� DUKETerra ENERGY,- PROGRESS 148 RIVER STREET, SUITE 220 MAYO STEAM ELECTRIC POWER PLANT GREENVILLE, SC 29601 10660 BOSTON RD m 864-421-9999 ROXBORO, NORTH CAROLINA27574 www.synterracorp.com FIGURE 12-13 COPC LOCATIONS FLAGGED x$ SEDIMENT - ECOLOGICAL LEGEND !� MW-1 PROPOSED GROUNDWATER MONITORING LOCATION - ;•,,MW-15BR� S PZ-1 PROPOSED MONITORING LOCATION (NOT SAMPLED) CW-4 DUKE ENERGY PROGRESS MAYO PLANT CW 3 MW-16S MW-16D i 500 ft COMPLIANCE BOUNDARY MW-03BR MW-16BR MW-14BR WASTE BOUNDARY M W-02 SOURCES: {. 2014 AERIAL PHOTOGRAPH WAS OBTAINED FROM WSP FLOWN ON APRIL 17, 2014. DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE COORDINATE MW-5BR CW2D - SYSTEM FIPS 3200 (NAD 83). a ® 2015 GROUNDWATER ASSESSMENT WELL AND BORING LOCATIONS WERE BASED ON SURVEY DATA CW-2 DATED JULY 17, 2015 PROVIDED BY McKIM & CREED OF WILMINGTON, NORTH CAROLINA. ` +r CW-6 Iss W-08S MW-08D ACTIVE ASH BASIN AMW-07DAMW-07BR v MW-04 Q�^� MW-13BR MW-09BR �. ABMW-01 ZMW-0213R�s MW-02 ZMW-03SMW-03 t CW-1D •CW-1 df` ABMW-041�1."w4 ABMW-04D ��• z, ABMW-04BR oO��m " P - �' - • ' �,. - •" y?racy...-...r.. MW 106R 40 A�POWER PLANT r. _ s,4 BG-2 MW-11 BR 1 ',�, �l �b� eLY^ � li -� l •'� . s4�4 1- 6: yJ4l- M ,- " .. k•!,.'r SiY GRAPHIC SCALE 400 0 400 800 FIGURE 16-1 IN FEET PROPOSED GROUNDWATER MONITORING LOCATIONS r` 148 RIVER STREET, SUITE 220 DUKE ENERGY PROGRESS MW-12S � ry;,.• GREENVILLE, SOUTH CAROLINA 29601 .. - MW-12D PHONE864-421-9999 MAYO STEAM ELECTRIC PLANT r - r Terra www•synterracorp.com 1066, BOSTON R DRAWN BY' C NEWELL DATE: 08/13/2015 ROXBORONORTH CAROLINA PROJECT MANAGER J WYLIE LAYOUT PROPOSED LOCATIONS ' - -I 08/30/2015 12.39 PM P:\Duke Energy Pro ress.1026 105. Mao Ash Basin GW Assessment Plan'\1.11 CSA Reportin Fi ures FIGURE 16-1-MAYO-PROP MONT LOCATIONSdw