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HomeMy WebLinkAboutNC0003433_Tables_20150902TABLE 2-1 NPDES GROUNDWATER MONITORING REQUIREMENTS CAPE FEAR STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, MONCURE, NC Well Nomenclature Parameter Description Frequency Aluminum Chloride Mercury TDS Monitoring Wells CMW-1, CTMW-1, Antimony Chromium Nickel Thallium Arsenic Copper Nitrate Zinc CMW-2, CTMW-2, CMW-3, CMW-5, March, June, Barium Iron pH CMW-6, CMW-7, CTMW-7, CMW-8, and October CTMW-8, BGMW-4, BGTMW-4 Boron Lead Selenium Cadmium Manganese Sulfate Prepared by: RBI Checked by CJS P:\Duke Energy Progress.1026\103. Cape Fear Ash Basin GW Assessment\1.11 CSA Reporting\Tables\Table 2-1 NPDES GW Req.xlsx Page 1 of 1 TABLE 2-2 COMPLIANCE WELL 15A NCAC 2L EXCEEDANCES CAPE FEAR STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, MONCURE, NC Analytical Parameter pH Antimony Arsenic Boron Cadmium Cobalt Iron Manganese Nitrate Selenium Sulfate Total Dissolved Solids Reporting Units S.U. ug/I ug/I ug/I ug/I ug/I ug/I ug/I mg/I ug/I mg/I mg/I 15A NCAC 02L Standard 6.5-8.5 1* 10 700 2 1* 300 50 10 20 250 500 Sample ID Sample Collection Date Analytical Results BGMW-04 12/15/2010 5.7 BE BE BE BE BE BE BE BE BE BE BE BGMW-04 03/07/2011 5.7 BE BE BE BE BE BE BE BE BE BE BE BGMW-04 06/01/2011 5.7 BE BE BE BE BE BE BE BE BE BE BE BGMW-04 10/10/2011 5.6 BE BE BE BE BE BE BE BE BE BE BE BGMW-04 03/12/2012 5.4 BE BE BE BE BE BE 83 BE BE BE BE BGMW-04 06/11/2012 5.6 BE BE BE BE BE BE BE BE BE BE BE BGMW-04 10/15/2012 5.5 BE BE BE BE BE 3130 61.2 BE BE BE BE BGMW-04 03/05/2013 5.5 BE BE BE BE BE BE BE BE BE BE BE BGMW-04 06/03/2013 5.4 BE BE BE BE BE BE BE BE BE BE BE BGMW-04 10/08/2013 5.7 BE BE BE BE BE BE BE BE BE BE BE BGMW-04 03/11/2014 5.7 BE BE BE BE BE 494 BE BE BE BE BE BGMW-04 06/09/2014 5.7 BE BE BE BE BE BE BE BE BE BE BE BGMW-04 10/13/2014 5.1 BE BE BE BE BE BE BE BE BE BE BE BGMW-04 03/04/2015 5.9 BE BE BE BE BE 360 BE BE BE BE BE BGMW-04 06/08/2015 5.7 BE BE BE BE BE 3810 BE 15 BE BE BE BGTMW-04 12/15/2010 10.3 1.1 BE BE BE BE BE BE BE BE BE BE BGTMW-04 03/07/2011 9.4 BE BE BE BE BE BE BE BE BE BE BE BGTMW-04 06/01/2011 9.1 BE BE BE BE BE BE BE BE BE BE BE BGTMW-04 10/10/2011 BE BE BE BE BE BE BE 95.7 BE BE BE BE BGTMW-04 03/12/2012 BE BE BE BE BE BE 406 b 130 BE BE BE BE BGTMW-04 06/11/2012 BE BE BE BE BE BE BE 99.5 BE BE BE BE BGTMW-04 10/15/2012 BE BE BE BE BE BE BE 161 BE BE BE BE BGTMW-04 03/05/2013 BE BE BE BE BE BE BE 136 BE BE BE BE BGTMW-04 06/03/2013 BE BE BE BE BE BE BE 72 BE BE BE BE BGTMW-04 10/08/2013 BE BE BE BE BE BE BE 91 BE BE BE BE BGTMW-04 03/11/2014 BE BE BE BE BE BE BE 142 BE BE BE BE BGTMW-04 10/13/2014 BE BE BE BE BE BE BE 110 BE BE BE BE BGTMW-04 03/04/2015 BE BE BE BE BE BE BE 172 BE BE BE BE BGTMW-04 06/08/2015 BE BE BE BE BE BE BE 59 BE BE BE BE CMW-01 12/17/2010 6.3 BE BE 1810 BE BE 51100 1370 BE BE BE BE CMW-01 03/08/2011 BE BE BE 1790 BE BE 50300 1790 BE BE BE BE CMW-01 06/03/2011 6.1 BE BE 1840 BE BE 51500 1350 BE BE BE BE CMW-01 10/11/2011 6.2 BE BE 2910 BE BE 46300 1180 BE BE BE BE CMW-01 03/12/2012 6.4 BE BE 2030 BE BE 41700 1050 BE BE BE BE CMW-01 DUP 03/12/2012 6.4 BE BE 2080 BE BE 43400 1080 BE BE BE BE CMW-01 06/12/2012 6.2 BE BE 2300 BE BE 54600 1160 BE BE BE BE CMW-01 10/15/2012 6.3 BE BE 2950 BE BE 42200 1000 BE BE BE BE CMW-01 03/04/2013 6.2 BE BE 1880 BE BE 28100 1610 BE BE BE BE CMW-01 06/04/2013 6.2 BE BE 2160 BE BE 50000 1250 BE BE BE BE CMW-01 10/09/2013 6.3 BE BE 2550 2.41 BE 54200 1190 BE BE BE BE CMW-01 03/12/2014 6.0 BE BE 1020 BE BE 34100 2750 BE BE BE BE CMW-01 06/09/2014 6.2 BE BE 1600 BE BE 59600 1300 BE BE BE BE CMW-01 DUP 06/09/2014 6.2 BE BE 1560 BE BE 60900 1300 BE BE BE BE CMW-01 10/14/2014 6.1 BE BE 2750 BE BE 38500 899 BE BE BE BE CMW-01 03/04/2015 6.1 BE BE 1380 BE BE 28700 1390 BE BE BE BE CMW-01 06/09/2015 6.2 BE BE 1830 BE BE 52700 1250 BE BE BE BE CMW-01 06/17/2015 6.4 BE BE BE BE BE BE BE BE BE BE BE CMW-02 12/16/2010 5.5 BE BE BE BE BE 2290 5480 BE BE 449 735 CMW-02 03/07/2011 5.6 BE BE BE BE BE BE 5160 BE BE 571 797 CMW-02 06/02/2011 5.4 BE BE BE BE BE 429 b 5240 BE BE 463 747 CMW-02 10/11/2011 5.4 BE BE BE BE BE 1830 5640 BE BE BE 687 CMW-02 03/13/2012 5.5 BE BE BE BE BE 609 b 3110 BE BE 455 803 CMW-02 06/12/2012 5.2 BE BE BE BE BE 1730 4120 BE BE 260 877 CMW-02 DUP 06/12/2012 5.2 BE BE BE BE BE 1600 3690 BE BE 556 882 CMW-02 10/16/2012 6.0 BE BE BE BE BE 5950 8300 BE BE 591 898 CMW-02 03/05/2013 5.1 BE BE BE BE BE 422 3180 BE BE 630 1100 CMW-02 06/04/2013 5.3 BE BE BE BE BE 3910 5580 BE BE 630 1100 CMW-02 10/08/2013 5.3 BE BE BE BE BE 1960 2280 BE BE 550 930 CMW-02 03/12/2014 5.3 BE BE BE BE BE 320 3690 BE BE 790 1300 CMW-02 06/10/2014 5.4 BE BE BE BE BE 2230 4440 BE BE 530 960 CMW-02 10/14/2014 5.2 BE BE BE BE BE 1390 4700 BE BE 440 780 CMW-02 03/04/2015 5.3 BE BE BE BE BE 792 6380 BE BE 430 770 CMW-02 06/09/2015 5.3 BE BE BE BE 1.82 796 6760 BE BE 480 780 CMW-02 06/17/2015 5.3 BE BE BE BE BE BE BE BE BE BE BE CMW-03 12/15/2010 6.2 BE BE 714 BE BE BE 1220 BE 22.6 BE BE CMW-03 03/07/2011 6.1 BE BE BE BE BE BE 257 BE 41.2 BE BE CMW-03 06/02/2011 6.0 BE BE 761 BE BE BE 282 BE 39 BE BE CMW-03 10/10/2011 6.0 BE BE 1230 BE BE BE 6160 BE 37.7 BE BE CMW-03 03/13/2012 6.3 BE BE 1030 BE BE 602 b 1500 BE 36.8 BE BE CMW-03 06/11/2012 6.1 BE BE 1070 BE BE 1910 3120 BE 27.6 BE BE CMW-03 10/16/2012 6.1 BE BE 1260 BE BE 453 9750 BE 20.6 388 729 CMW-03 03/05/2013 6.0 BE BE 1180 BE BE BE 4670 BE 40.7 BE 630 CMW-03 06/04/2013 6.1 BE BE 1320 2.39 BE BE 3670 BE BE BE 600 CMW-03 10/08/2013 6.2 BE BE 1300 BE BE BE 2360 BE 34.5 BE 520 CMW-03 03/12/2014 6.0 BE BE 1020 BE BE BE 1650 BE 66.6 BE BE CMW-03 06/10/2014 6.1 BE BE 815 BE BE BE 959 BE 55.4 BE BE CMW-03 10/14/2014 5.9 BE BE 982 BE BE BE 1810 BE 20.3 BE BE CMW-03 03/04/2015 6.2 BE BE 969 BE BE BE 3200 BE BE BE BE CMW-03 06/09/2015 6.1 BE BE BE BE BE BE 85 BE 46.8 BE BE CMW-05 12/16/2010 5.9 BE BE BE BE BE 1860 217 BE BE BE BE CMW-05 03/07/2011 6.4 BE BE BE BE BE BE 232 BE BE BE BE CMW-05 06/03/2011 6.1 BE BE BE BE BE 2750 211 BE BE BE BE CMW-05 10/10/2011 6.3 BE BE BE BE BE 1960 182 BE BE BE BE CMW-05 03/12/2012 BE BE BE BE BE BE 3360 94 BE BE BE BE P:\Duke Energy Progress.1026\103. Cape Fear Ash Basin GW Assessment\l.11 CSA Reporting\Tables\Table 2-2 Compliance Well 2L Exceedances.xlsx Page 1 of 3 TABLE 2-2 COMPLIANCE WELL 15A NCAC 2L EXCEEDANCES CAPE FEAR STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, MONCURE, NC Analytical Parameter pH Antimony Arsenic Boron Cadmium Cobalt Iron Manganese Nitrate Selenium Sulfate Total Dissolved Solids Reporting Units S.U. ug/I ug/I ug/I ug/I ug/I ug/I ug/I mg/I ug/I mg/I mg/I 15A NCAC 02L Standard 6.5-8.5 1* 10 700 2 1* 300 50 10 20 250 500 Sample ID Sample Collection Date Analytical Results CMW-05 06/11/2012 6.4 BE BE BE BE BE 834 57.4 BE BE BE BE CMW-05 10/15/2012 6.3 BE BE BE BE BE 1530 BE BE BE BE BE CMW-05 03/05/2013 6.1 BE BE BE BE BE 316 BE BE BE BE BE CMW-05 06/03/2013 6.0 BE BE BE BE BE 362 BE BE BE BE BE CMW-05 10/08/2013 6.3 BE BE BE BE BE 2910 BE BE BE BE BE CMW-05 03/11/2014 6.3 BE BE BE BE BE BE BE BE BE BE BE CMW-05 06/09/2014 6.2 BE BE BE BE BE 2800 BE BE BE BE BE CMW-05 10/13/2014 5.9 BE BE BE BE BE 5650 96 BE BE BE BE CMW-05 03/04/2015 6.1 BE BE BE BE BE 2650 BE BE BE BE BE CMW-05 06/09/2015 5.9 BE BE BE BE BE BE BE BE BE BE BE CMW-06 12/15/2010 BE BE BE 704 BE BE 696 178 BE BE BE BE CMW-06 03/08/2011 BE BE BE BE BE BE BE 195 BE BE BE 508 CMW-06 DUP 03/08/2011 BE BE BE BE BE BE BE 194 BE BE BE 511 CMW-06 06/02/2011 BE BE BE BE BE BE BE 179 BE BE BE BE CMW-06 10/11/2011 BE BE BE 874 BE BE BE 135 BE BE BE BE CMW-06 03/13/2012 BE BE BE 780 BE BE BE BE BE BE BE BE CMW-06 06/12/2012 BE BE BE 722 BE BE BE 362 BE BE BE 509 CMW-06 10/15/2012 BE BE BE 1010 BE BE BE BE BE BE BE BE CMW-06 03/04/2013 BE BE BE 825 BE BE BE BE BE BE BE BE CMW-06 06/03/2013 BE BE BE 1040 BE BE BE 58 BE BE BE BE CMW-06 10/08/2013 BE BE BE 1100 BE BE BE BE BE BE BE BE CMW-06 03/13/2014 BE BE BE 1320 BE BE BE BE BE BE BE BE CMW-06 06/10/2014 BE BE BE 1390 BE BE BE BE BE BE BE BE CMW-06 10/13/2014 BE BE BE 1210 BE BE BE BE BE BE BE BE CMW-06 DUP 10/13/2014 BE BE BE 1290 BE BE BE BE BE BE BE BE CMW-06 03/04/2015 6.2 BE BE BE BE BE 5050 908 BE BE BE BE CMW-06 06/09/2015 BE BE BE 1560 BE 1.14 556 204 BE BE BE BE CMW-07 12/17/2010 BE BE BE BE BE BE 8470 5480 BE BE BE BE CMW-07 03/08/2011 BE BE BE BE BE BE 1840 4850 BE BE BE BE CMW-07 06/02/2011 BE BE BE BE BE BE 9250 5270 BE BE BE BE CMW-07 10/11/2011 BE BE BE BE BE BE 9920 5600 BE BE BE BE CMW-07 DUP 10/11/2011 BE BE BE BE BE BE 9180 5640 BE BE BE BE CMW-07 03/13/2012 BE BE BE BE BE BE 8730 4550 BE BE BE BE CMW-07 06/12/2012 BE BE BE BE BE BE 13200 6030 BE BE BE BE CMW-07 10/15/2012 BE BE BE BE BE BE 12500 6300 BE BE BE BE CMW-07 03/04/2013 BE BE BE BE BE BE 12400 5800 BE BE BE BE CMW-07 06/03/2013 BE BE BE BE BE BE 16000 6380 BE BE BE BE CMW-07 10/09/2013 BE BE BE BE BE BE 19200 9040 BE BE BE BE CMW-07 03/13/2014 5.1 BE BE BE BE BE 817 655 BE BE BE BE CMW-07 10/14/2014 6.4 BE BE BE BE BE 18700 8510 BE BE BE BE CMW-07 03/04/2015 5.1 BE BE BE BE BE 2460 770 BE BE BE BE CMW-07 06/09/2015 5.6 BE BE BE BE 16.5 10300 2210 BE BE BE BE CMW-08 12/17/2010 BE BE BE 1070 BE BE 35200 9770 BE BE BE BE CMW-08 03/08/2011 BE BE BE 1300 BE BE 41300 18000 BE BE BE BE CMW-08 06/02/2011 6.3 BE BE 1210 BE BE 22700 12600 BE BE BE BE CMW-08 DUP 06/02/2011 6.3 BE BE 1160 BE BE 23100 13100 BE BE BE BE CMW-08 10/10/2011 6.2 BE BE 1250 BE BE 27900 9910 BE BE BE BE CMW-08 03/13/2012 6.4 BE BE 1320 BE BE 38600 15300 BE BE BE BE CMW-08 06/12/2012 6.3 BE BE 1300 BE BE 42400 12700 BE BE BE BE CMW-08 10/16/2012 6.4 BE BE 1340 BE BE 39000 9820 BE BE BE BE CMW-08 03/05/2013 6.1 BE BE 1240 BE BE 52700 14400 BE BE BE BE CMW-08 06/04/2013 6.3 BE BE 1350 BE BE 49900 14400 BE BE BE BE CMW-08 10/08/2013 6.3 BE BE 1210 BE BE 26100 10100 BE BE BE BE CMW-08 03/12/2014 6.4 BE BE 1260 BE BE 50400 15700 BE BE BE BE CMW-08 06/10/2014 6.3 BE BE 1160 BE BE 41800 12500 BE BE BE BE CMW-08 10/14/2014 6.0 BE BE 1190 BE BE 27800 9920 BE BE BE BE CMW-08 03/04/2015 6.4 BE BE 1250 BE BE 49200 13400 BE BE BE BE CMW-08 06/09/2015 6.3 BE BE 1300 BE 3.89 41800 13000 BE BE BE BE CMW-08 06/17/2015 6.3 BE BE BE BE BE BE BE BE BE BE BE CTMW-01 12/17/2010 BE BE BE BE BE BE 723 1220 BE BE BE BE CTMW-01 03/08/2011 BE BE BE BE BE BE 822 1220 BE BE BE BE CTMW-01 06/02/2011 BE BE BE BE BE BE 416 b 303 BE BE BE BE CTMW-01 10/11/2011 BE BE BE BE BE BE 886 1250 BE BE BE BE CTMW-01 03/12/2012 BE BE BE BE BE BE 1480 b 1160 BE BE BE BE CTMW-01 06/12/2012 BE BE BE BE BE BE 1210 1460 BE BE BE BE CTMW-01 10/15/2012 BE BE BE BE BE BE 951 1260 BE BE BE BE CTMW-01 03/04/2013 BE BE BE BE BE BE 887 1460 BE BE BE BE CTMW-01 DUP 03/04/2013 BE BE BE BE BE BE 905 1460 BE BE BE BE CTMW-01 06/03/2013 BE BE BE BE BE BE 899 1260 BE BE BE BE CTMW-01 10/09/2013 BE BE BE BE BE BE 823 1250 BE BE BE BE CTMW-01 03/12/2014 BE BE BE BE BE BE 798 1440 BE BE BE BE CTMW-01 06/09/2014 BE BE BE BE BE BE 540 979 BE BE BE BE CTMW-01 10/14/2014 BE BE BE BE BE BE 1160 1440 BE BE BE BE CTMW-01 03/04/2015 BE BE BE BE BE BE 874 1430 BE BE BE BE CTMW-01 06/09/2015 BE BE BE BE BE BE 385 546 BE BE BE BE CTMW-02 12/16/2010 8.8 BE BE BE BE BE BE BE BE BE BE BE CTMW-02 03/08/2011 BE BE BE BE BE BE BE 51.9 BE BE BE BE CTMW-02 06/09/2011 BE BE BE BE BE BE 1340 BE BE BE BE BE CTMW-02 10/11/2011 BE BE BE BE BE BE 402 BE BE BE BE BE CTMW-07 12/21/2010 9.0 BE BE BE BE BE BE 105 BE BE BE BE CTMW-07 03/08/2011 BE BE BE BE BE BE 673 89.2 BE BE BE BE CTMW-07 06/03/2011 BE BE BE BE BE BE BE 148 BE BE BE BE CTMW-07 03/13/2012 BE BE BE BE BE BE 303 b 53 BE BE BE BE CTMW-07 10/15/2012 BE BE BE BE BE BE BE 80.5 BE BE BE BE P:\Duke Energy Progress.1026\103. Cape Fear Ash Basin GW Assessment\1.11 CSA Reporting\Tables\Table 2-2 Compliance Well 2L Exceedances.xlsx Page 2 of 3 TABLE 2-2 COMPLIANCE WELL 15A NCAC 2L EXCEEDANCES CAPE FEAR STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, MONCURE, NC Analytical Parameter pH Antimony Arsenic Boron Cadmium Cobalt Iron Manganese Nitrate Selenium Sulfate Total Dissolved Solids Reporting Units S.U. ug/I ug/I ug/I ug/I ug/I ug/I ug/I mg/I ug/I mg/I mg/I 15A NCAC 02L Standard 6.5-8.5 1* 10 700 2 1* 300 50 10 20 250 500 Sample ID Sample Collection Date Analytical Results CTMW-07 03/04/2013 BE BE BE BE BE BE BE 371 BE BE BE BE CTMW-07 06/03/2013 BE BE BE BE BE BE BE 291 BE BE BE BE CTMW-07 DUP 06/03/2013 BE BE BE BE BE BE BE 273 BE BE BE BE CTMW-07 10/09/2013 BE BE BE BE BE BE BE 634 BE BE BE BE CTMW-07 03/13/2014 BE BE BE BE BE BE BE 758 BE BE BE BE CTMW-07 06/10/2014 BE BE BE BE BE BE BE 276 BE BE BE BE CTMW-07 10/14/2014 BE BE BE BE BE BE BE 201 BE BE BE BE CTMW-07 03/04/2015 BE BE BE BE BE BE BE 138 BE BE BE BE CTMW-07 06/08/2015 BE BE BE BE BE BE BE 110 BE BE BE BE CTMW-08 12/16/2010 BE 1.7 BE BE BE BE 1240 409 BE BE BE 608 CTMW-08 03/08/2011 BE BE BE BE BE BE 2170 568 BE BE BE 616 CTMW-08 06/01/2011 BE BE BE BE BE BE 1180 b 475 BE BE BE 561 CTMW-08 10/10/2011 BE BE BE BE BE BE 1230 586 BE BE BE BE CTMW-08 03/13/2012 BE BE BE BE BE BE 1540 b 709 BE BE BE 503 CTMW-08 06/12/2012 BE BE 10.5 BE BE BE 1680 658 BE BE BE 502 CTMW-08 10/16/2012 BE BE BE BE BE BE 434 269 BE BE BE BE CTMW-08 DUP 10/16/2012 BE BE BE BE BE BE 648 404 BE BE BE BE CTMW-08 03/05/2013 BE BE BE BE BE BE 1190 733 BE BE BE BE CTMW-08 06/04/2013 BE BE BE BE BE BE 958 737 BE BE BE BE CTMW-08 DUP 10/08/2013 BE BE BE BE BE BE 1070 712 BE BE BE BE CTMW-08 10/08/2013 BE BE BE BE BE BE 680 642 BE BE BE BE CTMW-08 03/12/2014 BE BE BE BE BE BE 1850 947 BE BE BE 510 CTMW-08 06/10/2014 BE BE BE BE BE BE 1090 814 BE BE BE BE CTMW-08 10/14/2014 BE BE BE BE BE BE 1040 642 BE BE BE BE CTMW-08 03/04/2015 BE BE BE BE BE BE 2070 980 BE BE BE BE CTMW-08 DUP 03/04/2015 BE BE BE BE BE BE 2580 1050 BE BE BE BE CTMW-08 06/09/2015 BE BE BE BE BE BE 1270 686 BE BE BE BE CTMW-08 DUP 06/09/2015 BE BE BE BE BE BE 1640 750 BE BE BE BE Prepared by: KDF Checked by: CIS Notes• = - Bold highlighted concentration indicates exceedance of the 15A NCAC 02L Standard, Appendix 2, April 1, 2013. ug/I = microgram per liter mg/I = milligrams per liter S.U. = Standard Units * - Interim Maximum Allowable Concentrations (IMACs) of the 15A NCAC 02L Standard, Appendix 1, April, 1, 2013. BE = indicates concentration was below the 15A NCAC 02L Standard, April 1, 2013. DUP = Duplicate P:\Duke Energy Progress.1026\103. Cape Fear Ash Basin GW Assessment\1.11 CSA Reporting\Tables\Table 2-2 Compliance Well 2L Exceedances.xlsx Page 3 of 3 TABLE 3-1 ASH, ROCK, AND SOIL COMPOSITION Fly Ash* Bottom Ash* Rock** I Soil*** Aluminum, mg/kg 70,000 - 140,000 59,000 - 130,000 9,800 - 96,000 15,000 - 100,000 Calcium, mg/kg 7,400 - 150,00 5,700 - 150,000 6,000 - 83,000 1,500 - 62,000 Iron, mg/kg 34,000- 130,000 40,000 - 160,000 8,800 - 95,000 7,000 - 50,000 Silicon, mg/kg 160,000 - 270,000 160,000 - 280,000 57,000 - 380,000 230,000 - 390,000 Magnesium, mg/kg 3,900 - 23,000 3,400 - 17,000 700 - 56,000 1,000 - 15,000 Potassium, mg/kg 6,200 - 21,000 4,600 - 18,000 4,000 - 45,000 4,500 - 25,000 Sodium, mg/kg 11700 - 17,000 1,600 - 11,000 900 - 34,000 1,000 - 20,000 Sulfur, mg/kg 1,900 - 34,000 BDL - 15,000 200 - 42,000 840 - 1,500 Titanium, mg/kg 4,300 - 9,000 4,100 - 7,200 200 - 5,400 1,000 - 5,000 Antimony, mg/kg BDL - 16 All BDL 0.08 - 1.8 BDL - 1.3 Arsenic, mg/kg 22 - 260 2.6 - 21 0.50 - 14 2.0 - 12 Barium, mg/kg 380 - 5,100 380 - 3,600 67 - 1,400 200 - 1,000 Beryllium, mg/kg 2.2 - 26 0.21 - 14 0.10 - 4.4 BDL - 2.0 Boron, mg/kg 120 - 1,000 BDL - 335 0.2 - 220 BDL - 70 Cadmium, mg/kg BDL - 3.7 All BDL 0.5 - 3.6 BDL - 0.5 Chromium, mg/kg 27 - 300 51 - 1,100 1.9 - 310 15 - 100 Copper, mg/kg 62 - 220 39 - 120 10 - 120 5.0 - 50 Lead, mg/kg 21 - 230 8.1 - 53 3.8 - 44 BDL - 30 Manganese, mg/kg 91 - 700 85 - 890 175 - 1,400 100 - 1,000 Mercury, mg/kg 0.01 - 0.51 BDL - 0.07 0.1 - 2.0 0.02 - 0.19 Molybdenum, mg/kg 9.0 - 60 3.8 - 27 1.0 - 16 All BDL Nickel, mg/kg 47 - 230 39 - 440 2.0 - 220 5.0 - 30 Selenium, mg/kg 1.8- 18 BDL - 4.2 0.60 - 4.9 BDL - 0.75 Strontium, mg/kg 270 - 3,100 270 - 2,000 61 - 890 20 - 500 Thallium, mg/kg BDL - 45 All BDL 0.1 - 1.8 0.20 - 0.70 Uranium, mg/kg BDL - 19 BDL - 16 0.84 - 43 1.2 - 3.9 Vanadium, mg/kg BDL - 360 BDL - 250 19 - 330 20 - 150 Zinc, mg/kg 63 - 680 16- 370 25 - 140 22 - 99 BDL- Below Detection Limit *Source for most fly ash data is EPRI CP-INFO Database3. Beryllium, Thallium, Mercury (bottom ash only) and Boron (bottom ash only) are from the EPRI PISCES Database.6 **Source for rock data is US Geological Survey National Geochemical database. 7 ***Source for most soils data is Shacklette and Boerngen (1984)8; Cadmium and Thallium data are from Smith et al (2005).9 Table was obtained from the EPRI Technical update- Coal Combustion Products- Environmental Issue, Coal Ash: Characteristics, management, and Environmental Issues, Table 2, pg 5, EPRI, 2009. P:\Duke Energy Progress.1026\103. Cape Fear Ash Basin GW Assessment\1.11 CSA Reporting\Tables\Table 3-1 Ash, Rock, and Soil Composition.xlsx Page 1 of 1 TABLE 6-1 SUMMARY OF REVISED SAMPLE LOCATIONS CAPE FEAR STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, MONCURE, NC Well/ General Location on Relocation,Approximate Addition, Distance and Justification for Relocation, NCDENR Concurrence/Comment Boring ID Groundwater Assessment Plan or Deletion? Direction of Relocation Addition, or Deletion ABMW-1/S/BR Ash stack in the central portion of Relocation Approximately 500 feet south Stability concerns on ash stack. NCDENR approved of the revised location the 1985 Ash Basin ABMW-2SU/SL Northcentral portion of 1978 ash Relocation West side of 1978 ash basin Stability concerns on ash basin NCDENR approved of the revised location basin Northeast portion of the 1956 Ash Approximately 300 feet southwest Originally proposed location was within the ABMW-5/S/BR Basin Relocation to be adjacent to existing footprint of a planned ash and stormwater NCDENR approved of the revised location. piezometer PZ-10 management project Within the 1985 Ash Basin (on the NCDENR requested that an additional boring be ABB-6 NA Addition north side of the basin) installed to obtain additional ash quality data from NCDENR approved of location. different portions of the ash basin Access to the the originally proposed location would Background location north of have been unnecessarily difficult requiring crossing MW-15SU/SL/BR Shaddox Creek and north of the Relocation Approximately 150 feet west a ditch and traversing through wetlands. Access to Yes, NCDENR approved of revised location. 1956 ash basin the reivsed location was relatively easy. Revised location is still upgradient of the ash basins. Background location north of Revised location is further from the ash basins and MW-16S/BR Corinth Road Relocation Approximately 360 feet northeast likely not hydraulically influenced by the ash Yes, NCDENR approved of revised location. basins. East/outside of side of security Approximately 300 feet Location moved to be inside of secured portion of / L/ MW-17SU S BR gate along main plant entrance. Relocation southwest. the property, while remaining in the same general NCDENR approved of location. (north of driveway) vicinity of the originally proposed location. After well was installed NCDENR requested Location moved to avoid being installed in flooded that the location be installed on the MW-19S South of 1978 ash basin Relocation Approximately 600 feet north property/compliance boundary. Well area. sampling results may determine if another well on the boundary needs to be installed. Prepared by: KDF Checked by: RKD P:\Duke Energy Progress. 1026\103. Cape Fear Ash Basin GW Assessment\1.11 CSA Reporting\Tables\Table 6-1 Revised Sample Locations.xlsx Page 1 of 1 TABLE 6-2 EXPLORATION AND SAMPLING PLAN - SOIL CAPE FEAR STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, MONCURE, NC Location ID Top Interval (bgs) Bottom Interval (bgs) Table 10 Parameters + TOC SPLP Ash Leach Kd Rdo edox Index Permeability (Shelby Tube) Minerology Ash, Soil, or Rock 3 5 x Ash 14 15 >1 X Ash ABB-06 40 44 x Ash/Soil Mix 47 1 48 x Soil 3 5 x x x Ash 5 7 x x Ash 10 15 x Ash 13 15 x Ash 14 15 x x Ash ABMW-01 34 35 x x Ash 39 41 x x x x x Soil 47 50 x x Soil 57 59 x x Rock 69 71 x Rock 0 2 x x Ash 1 2 x Ash ABMW-02 2 3 x x Ash 5 6 x x x x Soil 11 12 x x Soil 27 28 x x Rock 3 5 x x x Ash 19 20 x x x Ash ABMW-03 25 26 x x X x Soil 30 32 x x Soil 63 64 x Rock 0 2 x x Ash 1 2 x Ash ABMW-04 21 22 x x x Ash 28 30 x x x x Soil 42.5 44.5 x x Rock 0 2 x Ash 3 4 x Ash ABMW-05 3 5 x x Ash 23 24 x x x Ash 29 30 x x x x Soil 0 2 x x Ash 14 16 x x Ash 3-N1963 22 24 x x x Ash/Soil Mix 28 30 x x Soil 0 2 x x Soil MW-05BR 10 12 x x Soil 18 20 x x x Soil 0 2 x x Soil 6 7 x Soil MW-06BR 14 16 x X x Soil 26 27 x Rock 36 37 x Rock 0 2 x x Soil 2 3 x x x Soil 6 7 x x x Soil MW-09BR 16 17 x x x Soil 23.5 24 x Rock 29 29.5 x Rock 35 36 x Rock 0 2 x x Soil 4 5 x Soil MW-10BR 8 9 x x Soil 15 16 x Soil 26 27 x Rock 0 2 x x Soil 11 12 x x Soil 17 18 x x x x Soil MW-12BR 20 21 x Soil 44 47 x Rock 71 74 x Rock 0 2 x x Soil 7 9 x x x Soil 18 19 x x x x x Soil MW-15 35 36 x x x Soil 58 59 x Rock 73 74 x Rock 0 2 x x x x x Soil MW-16 4 6 x x x Soil 13 15 x x x Soil 0 2 x x Soil 2 3 x x Soil 5 7 x x Soil 8 9 x Soil MW-17 12 15 x x Soil 14 15 x Soil 24 27 x x Soil 25 27 x Soil 26 27 x Soil 0 2 x Soil MW-18 2.5 3 x Soil 0 2 x Soil MW-19 4 5 x Soil 0 2 x x Soil 2 3 x Soil 5 6 x x Soil MW-20 10 12 x Soil 17 19 x x x Soil 22 23 x Soil 24 25 x x x Soil and Rock 0 2 x Soil 5 6 x x x Soil MW-21 9 11 x x x x Soil 17 20 x x Soil 28 30 x Soil Prepared by: CIS Checked by: KDF/RKD Notes: bgs = depth below ground surface P:\Duke Energy Progress.1026\103. Cape Fear Ash Basin GW Assessment\l.11 CSA Reporting\Tables\Table 6-2 Explor_Samp_Plan_Solids.xlsx Page 1 of 1 TABLE 6-3 SOIL, SEDIMENT, AND ASH ANALYTICAL METHODS CAPE FEAR STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, MONCURE, NC INORGANIC COMPOUNDS UNITS METHOD Aluminum mg/kg EPA 6010C Antimony mg/kg EPA 6020A Arsenic mg/kg EPA 6020A Barium mg/kg EPA 6010C Beryllium mg/kg EPA 6010C Boron mg/kg EPA 6010C Cadmium mg/kg EPA 6020A Calcium mg/kg EPA 6010C Chloride mg/kg EPA 9056A Chromium mg/kg EPA 6010C Cobalt mg/kg EPA 6020A Copper mg/kg EPA 6010C Iron mg/kg EPA 6010C Lead mg/kg EPA 6020A Magnesium mg/kg EPA 6010C Manganese mg/kg EPA 6010C Mercury mg/kg EPA Method 7470A/7471B Molybdenum mg/kg EPA 6010C Nickel mg/kg EPA 6010C Nitrate as Nitrogen mg/kg EPA 9056A pH SU EPA 9045D Potassium mg/kg EPA 6010C Selenium mg/kg EPA 6020A Sodium mg/kg EPA 6010C Strontium mg/kg EPA 6010C Sulfate mg/kg EPA 9056A Thallium (low level) (SPLP Extract only) mg/kg EPA 6020A Total Organic Carbon mg/kg EPA 9060 Vanadium mg/kg EPA 6020A Zinc mg/kg EPA 6010C Sediment Specific Samples Cation exchange capacity meg/100g EPA 9081 Particle size distribution % Percent solids % Percent organic matter % EPA/600/R-02/069 Redox potential mV Faulkner et al. 1898 Prepared by: RBI Checked by: TCP Notes: 1. Soil samples to be analyzed for Total Inorganics using USEPA Methods 6010/6020 and pH using USEPA Method 9045, as noted 2. Ash samples to be analyzed for Total Inorganics using USEPA Methods 6010/6020 and pH using USEPA Method 9045; select ash samples will also be analyzed for leaching potential using SPLP Extraction Method 1312 in conjunction with USEPA Methods 6010/6020. P:\Duke Energy Progress.1026\103. Cape Fear Ash Basin GW Assessment\1.11 CSA Reporting\Tables\Table 6-3 Soil, Sediment and Ash Analytical Methods.xlsx Page 1 of 1 TABLE 6-4 EXPLORATION AND SAMPLING PLAN - ASH PORE WATER AND GROUNDWATER CAPE FEAR STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, MONCURE, NC Sample Identification Analytical Parameters Notes Field, Inorganics, Major Ions, TOC, TDS TSS Speciation (Fe, Mn, As, Cr) Speciation (Se) Uranium & Radium ABMW-01 x x ABMW-01S x x ABMW-01BR x x ABMW-02SU x x ABMW-02SL x x ABMW-03 x x ABMW-03S x x ABMW-03BR x x ABMW-04 x x ABMW-04S x x ABMW-05 Well was dry ABMW-05S x x ABMW-05BR x x x BG M W-04 x BGTMW-04 x CMW-01 x x x CTMW-01 x x CMW-02 x x CTMW-02 x x CMW-03 x CMW-05 x CMW-06 x x x CMW-07 x CTMW-07 x CMW-08 x x CTMW-08 x x MW-05BR x MW-06BR x x MW-09 x x MW-09BR x x MW-10 x x MW-10D x x MW-10BR x x MW-11 x MW-12 x x x MW-12BR x x x MW-13 x MW-14 x MW-15SU x MW-15SL x x MW-15BR x x MW-16S x x x x MW-16BR x x x MW-17SU x x x MW-17SL x x x MW-17BR x x x MW-18S x MW-19S x MW-20S x x x MW-20BR x x x MW-21SU x x x MW-21SL x x x MW-21BR x x x PZ-01 x PZ-02 x PZ-03S x PZ-03D x PZ-04 x PZ-05 x PZ-06 x PZ-07 x PZ-08 x PZ-09 x PZ-10 Well was dry Prepared by: CJS Checked by: DGN P:\Duke Energy Progress.1026\103. Cape Fear Ash Basin GW Assessment\1.11 CSA Reporting\Tables\Table 6-4 Explor_ Sam p_Plan_Water.xlsx Page 1 of 1 TABLE 6-5 ASH PORE WATER, GROUNDWATER, SURFACE WATER AND SEEP ANALYTICAL METHODS CAPE FEAR STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, MONCURE, NC PARAMETER RL UNITS METHOD FIELD PARAMETERS H NA SU Field Water Quality Meter Specific Conductance NA µS/cm Field Water Quality Meter Temperature NA 0C Field Water Quality Meter Dissolved Oxygen NA m L Field Water Quality Meter Oxidation Reduction Potential NA mV Field Water Quality Meter Turbidity NA NTU Field Water Quality Meter Ferrous Iron INA I m L I Field Test Kit INORGANICS Aluminum 0.005 m L EPA 200.7 or 6010C Antimony 0.001 m L EPA 200.8 or 6020A Arsenic 0.001 m L EPA 200.8 or 6020A Barium 0.005 m L EPA 200.7 or 6010C Beryllium 0.001 m L EPA 200.8 or 6020A Boron 0.05 m L EPA 200.7 or 6010C Cadmium 0.001 m L EPA 200.8 or 6020A Chromium 0.001 m L EPA 200.8 or 6010C Cobalt 0.001 m L EPA 200.8 or 6020A Copper 0.005 m L EPA 200.8 or 6010C Iron 0.01 m L EPA 200.7 or 6010C Lead 0.001 m L EPA 200.8 or 6020A Man anese 0.005 m L EPA 200.7 or 6010C Mercury low level 0.000012 m L EPA 245.7 or 1631 Molybdenum 0.005 m L EPA 200.8 or 6010C Nickel 0.005 m L EPA 200.8 or 6010C Selenium 0.001 m L EPA 200.8 or 6020A Strontium 0.005 m L EPA 200.7 or 6010C Thallium low level 0.0002 m L EPA 200.8 or 6020A Vanadium low level 0.0003 m L EPA 200.8 or 6020A Zinc 0.005 m L EPA 200.7 or 6010C RADIONUCLIDES Radium 226 11 Ci L I EPA 903.1 Modified Radium 228 13 1 pCi/L I EPA 904.0 SW846 9320 Modified Uranium 233 234 236 238 Varies by Isotope u mL ISW846 3010A 6020A ANIONS/CATIONS Alkalinity as CaCO3 20 m L SM 2320B Bicarbonate 20 m L SM 2320 Calcium 0.01 m L EPA 200.7 Carbonate 20 m L SM 2320 Chloride 0.1 m L EPA 300.0 or 9056A Magnesium 0.005 m L EPA 200.7 Methane 0.1 m L RSK 175 Nitrate as Nitrogen 0.023 m -N L EPA 300.0 or 9056A or 353.2 Potassium 0.1 m L EPA 200.7 Sodium 0.05 m L EPA 200.7 Sulfate 0.1 m L EPA 300.0 or 9056A Sulfide 0.05 mg/L SM4500S2-D Total Dissolved Solids 25 m /L SM 2540C Total Organic Carbon 0.1 m /L SM 5310C/EPA9060A Total Suspended Solids 2 m /L SM 2450D ADDITIONAL GROUNDWATER CONSTITUENTS Arsenic S eciation lVendor Specific I m /L IC-ICP-CRC-MS Iron S eciation JVendor Specific I m /L IC-ICP-CRC-MS ..Manganese S eciation IVendor Specific I m L IC-ICP-CRC-MS Prepared by: RBI Checked by: SRW/TCP Notes• 1. Select constituents will be analyzed for total and dissolved concentrations. NA = not applicable P:\Duke Energy Progress.1026\103. Cape Fear Ash Basin GW Assessment\1.11 CSA Reporting\Tables\Table 6-5 ASH PORE WATER, GW, SW, AND SEEP ANALYTICAL METHODS.xlsx Page 1 of 1 TABLE 6-6 WELL CONSTRUCTION DATA CAPE FEAR STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, MONCURE, NC IDENTIFICATION DATE INSTALLED MONITORING ZONE MATERIAL DIAMETER (INCHES) NORTHING (FEET) EASTING (FEET) BORING DEPTH' (FEET BGS) SURFACE CASING DEPTH' (FEET BGS) TOTAL WELL DEPTH' (FEET BGS) MEASURED WELL DEPTHZ (FEET BTOC) SCREENED INTERVAL' (FEET BGS) TOP OF SCREEN ELEVATIONS FEET MSL BOTTOM OF SCREEN ELEVATIONS FEET MSL)(FEET MEASURING POINT TOC MSL) GROUND SURFACE (FEET MSL) MONITORING WELLS ABMW-01 3/23/2015 Ash Pore Water PVC 2 669755.80 1987963.85 35 NA 35 37.20 30-35 169.40 164.40 201.60 198.66 ABMW-01S 3/25/2015 Surficial - Lower PVC 2 669762.22 1987950.15 51 38 51 53.00 46-51 153.83 148.83 201.83 198.64 ABMW-01BR 3/24/2015 Bedrock PVC 2 669764.64 1987936.38 105 55 73 73.00 68-73 133.44 128.44 201.44 198.5 ABMW-02SU 3/26/2015 Surficial - Upper PVC 2 668917.88 1985754.47 12 NA 12 15.52 7-12 183.14 178.14 193.66 190.47 ABMW-02SL 3/26/2015 Surficial - Lower PVC 2 668932.48 1985740.95 30 10 30 32.28 20-30 171.36 161.36 193.64 190.59 ABMW-03 4/22/2015 Ash Pore Water PVC 2 667363.16 1985346.947 20 NA 20 23.07 15-20 169.16 164.16 187.23 184.33 ABMW-03S 4/22/2015 Surficial - Lower PVC 2 667353.24 1985364.171 40 30 37 40.20 32-37 151.97 146.97 187.17 184.26 ABMW-03BR 4/21/2015 Bedrock PVC 2 667358.49 1985355.134 90 42 66 69.12 61-66 123.12 118.12 187.24 184.29 ABMW-04 4/11/2015 Ash Pore Water PVC 2 668904.00 1985275.893 26 NA 26 30.20 21-26 160.40 155.40 185.60 182.55 ABMW-04S 4/13/2015 Surficial - Lower PVC 2 668915.16 1985272.356 45 31 45 45.60 40-45 144.95 139.95 185.55 182.47 ABMW-05 5/8/2015 Ash Pore Water PVC 2 672319.99 1985006.451 20 NA 17 19.80 12-17 171.98 166.98 186.78 183.57 ABMW-05S 5/8/2015 Surficial - Lower PVC 2 672313.76 1984987.412 33 25 33 35.20 28-33 156.19 151.19 186.39 183.34 ABMW-05BR 5/9/2015 Bedrock PVC 2 672317.28 1984996.572 90 40 60 63.11 55-60 128.45 123.45 186.56 183.54 BGMW-04 7/28/2010 Surficial - Upper PVC 2 672664.35 1986489.61 19 NA 19 22.19 9-19 168.55 158.55 180.74 177.70 BGTMW-04 11/18/2010 Bedrock PVC 2 672663.82 1986496.35 50 NA 48 52.24 38-48 138.61 128.61 180.85 175.50 CMW-01 8/24/2010 Surficial - Upper PVC 2 666928.02 1985167.50 16 NA 15 18.55 5-15 157.12 147.12 165.67 162.30 CTMW-01 8/26/2010 Bedrock PVC 2 666936.52 1985163.26 53 NA 53 55.61 38-53 125.43 110.43 166.04 163.40 CMW-02 8/30/2010 Surficial - Upper PVC 2 671530.05 1984677.55 14 NA 14 17.25 4-14 162.15 152.15 169.40 166.60 CTMW-02 9/1/2010 Bedrock PVC 2 671538.77 1984675.45 53 NA 52.5 56.47 42.5-52.5 122.70 112.70 169.17 166.50 CMW-03 9/2/2010 Surficial - Upper PVC 2 672774.76 1985020.89 15 NA 15 18.92 5-15 167.04 157.04 175.96 172.70 CMW-05 11/19/2010 Surficial - Lower PVC 2 670569.11 1988084.54 21 NA 20 23.52 10-20 168.92 158.92 182.44 178.60 CMW-06 11/22/2010 Surficial - Upper PVC 2 668117.34 1988906.82 16 NA 14 18.12 4-14 161.77 151.77 169.89 166.60 CMW-07 12/1/2010 Surficial - Lower PVC 2 668474.28 1986974.79 26 NA 26.5 28.36 16.5-26.5 166.22 156.22 184.58 181.50 CTMW-07 12/3/2010 Bedrock PVC 2 668479.37 1986975.86 50 NA 48 52.34 38-48 142.32 132.32 184.66 181.40 CMW-08 11/30/2010 Surficial - Upper PVC 2 668852.85 1984746.56 16 NA 15 18.39 5-15 161.82 151.82 170.21 167.70 CTMW-08 11/30/2010 Bedrock PVC 2 668845.58 1984743.29 50.5 NA 48.5 52.60 38.5-48.5 127.72 117.72 170.32 167.40 MW-05BR 4/24/2015 Bedrock PVC 2 670565.59 1988071.28 50 30 50 52.98 45-50 133.46 128.46 181.44 178.09 MW-06BR 6/1/2015 Bedrock PVC 2 668110.53 1988860.94 38 21 37.5 40.82 32.5-37.5 134.42 129.42 170.24 166.93 MW-09 8/26/2013 Bedrock PVC 2 668146.44 1990530.01 20 NA 20 22.97 10-20 178.81 168.81 191.78 187.30 MW-09BR 4/27/2015 Bedrock PVC 2 668137.20 1990518.16 40 17 40 43.09 35-40 153.97 148.97 192.06 188.35 MW-10 8/22/2013 Surficial - Lower PVC 2 672858.64 1985066.52 20 NA 20 22.70 10-20 161.12 151.12 173.82 170.94 MW-10D 4/9/2015 Bedrock PVC 2 672854.72 1985048.553 35 NA 35 37.32 30-35 141.97 136.97 174.29 171.10 MW-10BR 4/10/2015 Bedrock PVC 2 672860.37 1985054.601 65 37 58 60.27 53-58 118.95 113.95 174.22 171.05 MW-11 8/19/2013 Surficial - Upper PVC 2 671306.96 1986219.74 20 NA 20 22.66 10-20 162.36 152.36 175.02 171.74 MW-12 8/23/2013 Surficial - Upper PVC 2 667647.84 1987858.33 20 NA 20 22.90 10-20 158.22 148.22 171.12 167.72 P:\Duke Energy Progress.1026\103. Cape Fear Ash Basin GW Assessment\1.11 CSA Reporting\Tables\Table 6-6 Well Construction Data.xlsx Page 1 of 3 TABLE 6-6 WELL CONSTRUCTION DATA CAPE FEAR STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, MONCURE, NC IDENTIFICATION DATE INSTALLED MONITORING ZONE MATERIAL DIAMETER (INCHES) NORTHING (FEET) EASTING (FEET) BORING DEPTH' (FEET BGS) SURFACE CASING DEPTH' (FEET BGS) TOTAL WELL DEPTH' (FEET BGS) MEASURED WELL DEPTHZ (FEET BTOC) SCREENED INTERVAL' (FEET BGS) TOP OF SCREEN ELEVATIONS FEET MSL BOTTOM OF SCREEN ELEVATIONS FEET MSL)(FEET MEASURING POINT TOC MSL) GROUND SURFACE (FEET MSL) MW-12BR 3/4/2015 Bedrock PVC 2 667661.05 1987855.866 75 27 49 52.89 44-49 122.87 117.87 170.76 167.89 MW-13 8/23/2013 Surficial - Upper PVC 2 666832.43 1985629.89 20 NA 20 23.25 10-20 158.70 148.70 171.95 168.95 MW-14 8/21/2013 Bedrock PVC 2 668866.24 1984754.72 80 NA 80 NM* 70-80 101 91 173.94 171.37 MW-15SU 4/1/2015 Surficial - Upper PVC 2 672863.71 1985761.215 10 NA 10 13.15 5-10 164.58 159.58 172.73 169.48 MW-15SL 4/1/2015 Surficial - Lower PVC 2 672863.92 1985751.233 23 NA 20 23.36 15-20 154.33 149.33 172.69 169.45 MW-15BR 4/7/2015 Bedrock PVC 2 672864.58 1985740.579 80 27 60 63.30 55-60 114.62 109.62 172.92 169.69 MW-16S 4/29/2015 Surficial - Lower PVC 2 671693.45 1988875.56 17 NA 16 19.07 6-16 158.98 148.98 168.05 165.1 MW-16BR 5/5/2015 Bedrock PVC 2 671676.17 1988871.14 70 20 51 53.91 46-51 119.64 114.64 168.55 165.35 MW-17SU 3/7/2015 Surficial - Upper PVC 2 670959.16 1986544.617 19 NA 19 23.23 9-19 158.95 148.95 172.18 169.02 MW-17SL 3/6/2015 Surficial - Lower PVC 2 670965.96 1986551.728 30 NA 30 32.38 25-30 145.28 140.28 172.66 169.54 MW-17BR 3/10/2015 Bedrock PVC 2 670972.22 1986559.353 87 34 57 60.30 52-57 118.19 113.19 173.49 170.34 MW-18S 2/11/2015 Surficial - Upper PVC 2 667943.80 1988841.906 9.5 NA 9.5 12.18 4.5-9.5 162.08 157.08 169.26 165.90 MW-19S 2/11/2015 Surficial - Upper PVC 2 667928.43 1986427.024 7.8 NA 7.8 10.51 2.8-7.8 171.40 166.40 176.91 173.83 MW-20S 5/13/2015 Surficial - Lower PVC 2 666368.14 1985879.58 20 NA 25 27.72 15-25 153.05 143.05 170.77 168.01 MW-20BR 5/14/2015 Bedrock PVC 2 666368.04 1985860.32 65 27 61 64.34 56-61 111.89 106.89 171.23 167.98 MW-21SU 4/23/2015 Surficial - Upper PVC 2 669923.29 1984803.14 16 NA 16 19.83 11-16 162.09 157.09 176.92 173.85 MW-21SL 4/23/2015 Surficial - Lower PVC 2 669935.84 1984808.19 30 NA 29 31.77 24-29 150.19 145.19 176.96 173.88 MW-21BR 4/23/2015 Bedrock PVC 2 669944.61 1984810.47 87 34 60 63.81 50-60 123.33 113.33 177.14 174.03 PIEZOMETERS CHATH-075-P100* 12/14/2014 Surficial - Lower* PVC 2 672718.80 1985333.1 30 NA 30 21.60 20-30 163.48 153.48 175.08 175.20 CHATH-075-P101* 12/17/2014 Surficial - Upper* PVC 2 672294.10 1985551.70 20.4 NA 20.4 25.43 10-20 168.68 158.68 184.11 184.39 CHATH-075-P102* 12/16/2014 Surficial - Upper*" PVC 2 672684.00 1985320.30 25 NA 25 30.26 15-25 166.40 156.40 186.66 187.01 CHATH-075-P103* 12/15/2014 Surficial - Lower* PVC 2 672305.60 1985615.80 15 NA 14.6 14.50 4.6-14.6 161.01 151.01 165.51 165.78 CHATH-076-P100* 12/18/2014 Surficial - Lower* PVC 2 669219.20 1984742.70 35 NA 35 NM* 25-35 144* 134* 168.85 169.09 CHATH-076-P101* 12/17/2014 Ash Pore Water* PVC 2 669225.30 1984797.30 15 NA 15 NM* 5-15 190* 180* 194.56 194.87 CHATH-076-P102* 12/18/2014 Surficial - Upper* PVC 2 668705.00 1984823.80 35 NA 35 NM* 25-35 170* 160* 195.04 195.26 CHATH-076-P103* 12/17/2014 Surficial - Upper* PVC 2 668699.00 1984763.20 15 NA 15 NM* 5-15 162* 152* 166.72 167.07 CHATH-077-P100* 12/18/2014 Surficial - Upper* PVC 2 667949.50 1984891.90 31 NA 31 NM* 21-31 174* 164* 194.93 195.35 CHATH-077-P102* 12/18/2014 Surficial - Upper* PVC 2 666990.00 1985800.60 30 NA 30 NM* 20-30 166* 156* 185.72 186.03 CHATH-077-P103* 12/17/2014 Surficial - Upper* PVC 2 666961.60 1985795.00 19.5 NA 19.5 NM* 9.5-19.5 171* 161* 180.31 180.67 CHATH-079-P100* 12/18/2014 Surficial - Upper* PVC 2 669306.10 1987629.60 25.4 NA 25.4 NM* 15-25 178* 168* 193.03 193.35 CHATH-079-P101* 12/18/2014 Surficial - Upper* PVC 2 668386.40 1988221.80 30.4 NA 30.4 NM* 20-30 173* 163* 192.94 193.29 CHATH-079-P102* 12/16/2014 Surficial - Upper* PVC 2 668340.60 1988190.70 15 NA 15 NM* 5-15 168* 158* 173.41 173.73 CHATH-079-P103* 12/18/2014 Surficial - Upper* PVC 2 669272.40 1988713.50 30.4 NA 30.4 NM* 20-30 173* 163* 193.67 193.93 CHATH-079-P104* 12/17/2014 Surficial - Upper* PVC 2 670440.10 1987674.30 30.4 NA 30.4 NM* 20-30 173* 163* 193.59 193.82 CHATH-079-P105* 12/17/2014 Surficial - Upper* PVC 2 670515.30 1987699.10 15 NA 15 NM* 5-15 168* 158* 173.08 173.40 P:\Duke Energy Progress.1026\103. Cape Fear Ash Basin GW Assessment\1.11 CSA Reporting\Tables\Table 6-6 Well Construction Data.xlsx Page 2 of 3 TABLE 6-6 WELL CONSTRUCTION DATA CAPE FEAR STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, MONCURE, NC IDENTIFICATION DATE INSTALLED MONITORING ZONE MATERIAL DIAMETER (INCHES) NORTHING (FEET) EASTING (FEET) BORING DEPTH' (FEET BGS) SURFACE CASING DEPTH' FEET BGS TOTAL WELL DEPTH' (FEET BGS) MEASURED WELL DEPTH' (FEET BTOC) SCREENED INTERVAL' (FEET BGS) TOP OF SCREEN ELEVATIONS FEET MSL BOTTOM OF SCREEN ELEVATIONS FEET MSL MEASURING POINT TOC (FEET MSL) GROUND SURFACE (FEET MSL) PZ-01 3/2/2007 Surficial - Upper PVC 2 670759.20 1986562.10 15 NA 13 NM* 3-13 162* 152* 168.0 168.20 PZ-02 3/2/2007 Surficial - Upper PVC 2 670692.80 1987397.20 15 NA 15 NM* 5-15 167* 157* 175.0 172.60 PZ-03S 3/2/2007 Surficial - Upper PVC 2 669287.10 1988781.60 15 NA 13 NM* 3-13 168* 158* 174.0 171.00 PZ-03D 3/2/2007 Bedrock PVC 2 669278.80 1988780.30 60 NA 60 NM* 45-60 121* 111* 173.9 171.10 PZ-04 3/2/2007 Surficial - Upper PVC 2 668139.91 1988446.45 15 NA 13 NM* 3-13 168* 158* 173.72 170.99 PZ-05 3/2/2007 Surficial - Upper PVC 2 669245.50 1987543.10 16 NA 13 NM* 3-13 164* 154* 169.80 170.00 PZ-06 8/21/2013 Ash Pore Water PVC 1 669621.57 1988202.29 43 NA 33 NM* 23-33 172* 162* 198.03 195.47 PZ-07 8/16/2013 Ash Pore Water PVC 1 668345.75 1985623.36 25 NA 18 NM* 8-18 179* 169* 189.74 187.29 PZ-08 8/15/2013 Ash Pore Water PVC 1 669441.46 1985252.22 23.5 NA 21 NM* 11-21 180* 170* 193.31 193.17 PZ-09 8/15/2013 Surficial - Upper PVC 1 668894.95 1985735.69 25 NA 22 NM* 12-22 179* 169* 193.82 190.82 PZ-10 8/19/2013 Ash Pore Water PVC 1 672333.12 1984978.51 35 NA 18 19.64 8-18 175.82 165.82 185.46 183.53 Notes: Prepared by: KFD Checked by: CJS BGS - Below ground surface NA - Not Applicable MSL - Mean sea level PVC - Polyvinyl Chloride BTOC - Below top of casing NM - Not Measured 'Depths measured from ground surface during well installation and reported on the monitoring well construction logs 2Well depths measured by SynTerra, June 30 and July 1, 2015 3 Where total depth was not measured well screen elevations were estimated, based on the difference between TOC and ground surface elevations. Monitoring well coordinate and elevation data for newly installed wells from surveys provided by McKim & Creed, completed 8/14/15. McKim and Creed also verified survey location at several existing locations. * No boring logs available for "CHATH" piezometers, monitoring zone assigned based on depths and comparison to nearby sample locations with boring logs P:\Duke Energy Progress.1026\103. Cape Fear Ash Basin GW Assessment\1.11 CSA Reporting\Tables\Table 6-6 Well Construction Data.xlsx Page 3 of 3 TABLE 6-7 WATER LEVELS AND VERTICAL HYDRAULIC GRADIENTS CAPE FEAR STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, MONCURE, NC Identification Monitoring Zone Total Well Depth' (feet bgs) Screened Interval (feet bgs) Measuring Point TOC (feet MSL) Ground Surface (feet MSL) Depth toPotentionmetric Water' (feet BTOC Surface Elevation (feet MSL) Vertical Gradient Direction BACKGROUND WELLS BGMW-04 Surficial 19 9-19 180.74 177.70 15.85 164.89 BGTMW-04 Bedrock 48 38-48 180.85 175.50 16.45 164.40 -0.016 downward MW-09 Bedrock 20 10-20 191.78 187.30 14.2 177.58 MW-09BR Bedrock 40 35-40 192.06 188.35 17.9 174.16 -0.153 downward MW-15SU Surficial 10 5-10 172.73 169.48 6.49 166.24 MW-15SL Surficial 20 15-20 172.69 169.45 10.44 162.25 -0.389 downward MW-15BR Bedrock 60 55-60 172.92 169.69 9.62 163.30 0.027 upward MW-16S Surficial 16 6-16 168.05 165.1 3.77 164.28 downward MW-16BR Bedrock 51 46-51 168.55 165.35 4.62 163.93 -0.010 SOURCE AREA WELLS AND PIEZOMETERS ABMW-01 Ash Pore Water 35 30-35 201.60 198.66 20.08 181.52 ABMW-01S Surficial 51 46-51 201.83 198.64 28.16 173.67 -0.504 downward ABMW-01BR Bedrock 73 68-73 201.44 198.5 28.88 172.56 -0.054 downward ABMW-02SU Surficial 12 7-12 193.66 190.47 9.5 184.16 PZ-09 Surficial 22 12-22 193.82 190.82 9.7 184.12 -0.005 downward ABMW-02SL Surficial 30 20-30 193.64 190.59 8.88 184.76 0.043 upward ABMW-03 Ash Pore Water 20 15-20 187.23 184.33 14.43 172.80 ABMW-03S Surficial 37 32-37 187.17 184.26 18 169.17 -0.211 downward ABMW-03BR Bedrock 66 61-66 187.24 184.29 23.25 163.99 -0.180 downward ABMW-04 Ash Pore Water 26 21-26 193.94 190.89 16.65 177.29 downward ABMW-04S Surficial 45 40-45 193.88 190.81 19.96 173.92 -0.218 PZ-07 Ash Pore Water 18 8-18 189.74 187.29 14.44 175.30 - - P:\Duke Energy Progress.1026\103. Cape Fear Ash Basin GW Assessment\1.11 CSA Reporting\Tables\Table 6-7 Water Levels and Vertical Hydraulic Gradients. xlsx Page 1 of 4 TABLE 6-7 WATER LEVELS AND VERTICAL HYDRAULIC GRADIENTS CAPE FEAR STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, MONCURE, NC Identification Monitoring Zone Total Well Depth' (feet bgs) Screened Interval (feet bgs) Measuring Point TOC (feet MSL) Ground Surface (feet MSL) Depth toPotentionmetric Water' (feet BTOC Surface Elevation (feet MSL) Vertical Gradient Direction PZ-08 Ash Pore Water 21 11-21 193.31 193.17 17.69 175.62 - - PZ-10 Ash Pore Water 18 8-18 185.46 183.53 Dry <165.53 - - ABMW-05 Ash Pore Water 17 12-17 186.78 183.57 Dry <169.78 - - ABMW-05S Surficial 33 28-33 186.39 183.34 25.11 161.28 downward ABMW-05BR Bedrock 60 55-60 186.56 183.54 25.37 161.19 -0.003 SITE WELLS AND PIEZOMETERS CMW-01 Surficial 15 5-15 165.67 162.30 8.01 157.66 CTMW-01 Bedrock 53 38-53 166.04 163.40 7.11 158.93 0.037 upward CMW-02 Surficial 14 4-14 169.40 166.60 10.66 158.74 CTMW-02 Bedrock 52.5 42.5-52.5 169.17 166.50 11.55 157.62 -0.028 downward CMW-05 Surficial 20 10-20 182.44 178.60 15.24 167.20 MW-05BR Bedrock 50 45-50 181.44 178.09 14.62 166.82 -0.012 downward CMW-06 Surficial 14 4-14 169.89 166.60 4.46 165.43 MW-06BR Bedrock 37.5 32.5-37.5 170.24 166.93 5.06 165.18 -0.010 downward CMW-07 Surficial 26.5 16.5-26.5 184.58 181.50 22.07 162.51 CTMW-07 Bedrock 48 38-48 184.66 181.40 24.29 160.37 -0.090 downward CMW-08 Surficial 15 5-15 170.21 167.70 9.17 161.04 CTMW-08 Bedrock 48.5 38.5-48.5 170.32 167.40 11.53 158.79 -0.066 downward MW-14 Bedrock 80 70-80 173.94 171.37 11.8 162.14 0.125 upward CMW-03 Surficial 15 5-15 175.96 172.70 15.38 160.58 MW-10 Surficial 20 10-20 173.82 170.94 13.36 160.46 -0.021 downward MW-10D Bedrock 35 30-35 174.29 171.1 15.44 158.85 -0.096 downward MW-10BR Bedrock 58 53-58 174.22 171.05 15.61 158.61 -0.011 downward P:\Duke Energy Progress.1026\103. Cape Fear Ash Basin GW Assessment\1.11 CSA Reporting\Tables\Table 6-7 Water Levels and Vertical Hydraulic Gradients. xlsx Page 2 of 4 TABLE 6-7 WATER LEVELS AND VERTICAL HYDRAULIC GRADIENTS CAPE FEAR STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, MONCURE, NC Identification Monitoring Zone Total Well Depth' (feet bgs) Screened Interval (feet bgs) Measuring Point TOC (feet MSL) Ground Surface (feet MSL) Depth toPotentionmetric Water' (feet BTOC Surface Elevation (feet MSL) Vertical Gradient Direction MW-11 Surficial 20 10-20 175.02 171.74 13.34 161.68 - - MW-12 Surficial 20 10-20 171.12 167.72 12.46 158.66 MW-12BR Bedrock 49 44-49 170.76 167.89 11.57 159.19 0.016 upward MW-13 Surficial 20 10-20 171.95 168.95 11.6 160.35 - - MW-17SU Surficial 19 14-19 172.18 169.02 9.1 163.08 MW-17SL Surficial 30 25-30 172.66 169.54 8.23 164.43 0.156 upward MW-17BR Bedrock 57 52-57 173.49 170.34 7.9 165.59 0.043 upward MW-18S Surficial 9.5 4.5-9.5 169.26 165.9 3.6 165.66 - - MW-19S Surficial 7.8 2.8-7.8 176.91 173.83 8.38 168.53 - - MW-20S Surficial 25 15-25 170.77 168.01 12.2 158.57 downward MW-20BR Bedrock 61 56-61 171.23 167.98 13.06 158.17 -0.010 MW-21SU Surficial 16 11-16 176.92 173.85 10.73 166.19 MW-21SL Surficial 29 24-29 176.96 173.88 11.68 165.28 -0.077 downward MW-21BR Bedrock 60 50-60 177.14 174.03 19.34 157.80 -0.255 downward PZ-01 Surficial 13 3-13 168.0 168.2 3.42 164.58 - - PZ-02 Surficial 15 5-15 175.0 172.6 5.33 169.67 - - PZ-03S Surficial 13 3-13 174.0 171.0 5.08 168.92 PZ-03D Bedrock 60 45-60 173.9 171.1 4.96 168.94 0.778 upward PZ-04 Surficial 13 3-13 173.72 170.99 8.71 165.01 - - PZ-05 Surficial 13 3-13 169.80 170.0 1.65 168.15 - - PZ-06 Surficial 33 23-33 198.03 195.47 19.16 178.87 - - P:\Duke Energy Progress.1026\103. Cape Fear Ash Basin GW Assessment\1.11 CSA Reporting\Tables\Table 6-7 Water Levels and Vertical Hydraulic Gradients. xlsx Page 3 of 4 TABLE 6-7 WATER LEVELS AND VERTICAL HYDRAULIC GRADIENTS CAPE FEAR STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, MONCURE, NC Identification Monitoring Zone Total Well Depth' (feet bgs) Screened Interval (feet bgs) Measuring Point TOC (feet MSL) Ground Surface (feet MSL) Depth toPotentionmetric Water' (feet BTOC Surface Elevation (feet MSL) Vertical Gradient Direction CHATH-075-P100 Surficial* 30 20-30 175.08 175.20 14.51 160.57 - - CHATH-075-P101 Surficial* 20.4 10-20 184.11 184.39 22.71 161.40 - - CHATH-075-P102 Surficial* 25 15-25 186.66 187.01 25.91 160.75 - - CHATH-075-P103 Surficial* 14.6 4.6-14.6 165.51 165.78 4.43 161.08 - - CHATH-076-P100 Surficial* 35 25-35 168.85 169.09 2.43 166.42 - - CHATH-076-P101 Surficial* 15 5-15 194.56 194.87 24.15 170.41 - - CHATH-076-P102 Surficial* 35 25-35 195.04 195.26 28.3 166.74 - - CHATH-076-P103 Surficial* 15 5-15 166.72 167.07 2.4 164.32 - - CHATH-077-P100 Surficial* 31 21-31 194.93 195.35 29.7 165.23 - - CHATH-077-P102 Surficial* 30 20-30 185.72 186.03 22.09 163.63 - - CHATH-077-P103 Surficial* 19.5 9.5-19.5 180.31 180.67 13.49 166.82 - - CHATH-079-P100 Surficial* 25.4 15-25 193.03 193.35 22.32 170.71 - - CHATH-079-P101 Surficial* 30.4 20-30 192.94 193.29 28.63 164.31 - - CHATH-079-P102 Surficial* 15 5-15 173.41 173.73 7.81 165.60 - - CHATH-079-P103 Surficial* 30.4 20-30 193.67 193.93 28.85 164.82 - - CHATH-079-P104 Surficial* 30.4 20-30 193.59 193.82 27.23 166.36 - - CHATH-079-P105 Surficial* 15 5-15 173.08 173.40 3.44 169.64 - - Prepared by: CJS Checked by: TCP Notes: BGS - Below ground surface BTOC - Below top of casing MSL - Mean sea level 'Well depths and water levels measured by SynTerra, June 30 and July 1, 2015 * No boring logs available for "CHATH" piezometers, monitoring zone assigned based on depths and comparison to nearby sample locations with boring logs P:\Duke Energy Progress.1026\103. Cape Fear Ash Basin GW Assessment\1.11 CSA Reporting\Tables\Table 6-7 Water Levels and Vertical Hydraulic Gradients.xlsx Page 4 of 4 TABLE 6-8 BEDROCK LEVELS CAPE FEAR STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, MONCURE, NC Well ID Ground Surface Elevation (Feet- MSL) Depth to Bedrock (Feet-BGS) Bedrock Surface Elevation (Feet-MSL) ABMW-01BR 198.50 51 147.5 ABMW-02SL 190.59 27.5 163.1 ABMW-03BR 184.29 38.5 145.8 ABMW-03S 184.26 37 147.3 ABM W-04S 182.47 42 140.5 ABMW-05BR 183.54 36 147.5 ABMW-5S 183.34 33 150.3 MW-5BR 178.09 26.5 151.6 MW-6BR 166.93 19 147.9 MW-9BR 188.35 13 175.4 MW-10BR 171.05 36 135.1 MW-12BR 167.89 21.5 146.4 MW-15BR 169.69 23 146.7 MW-15SL 169.45 19.5 150.0 MW-16BR 165.35 16 149.4 MW-16S 165.10 16 149.1 MW-17BR 170.34 28 142.3 MW-17SL 169.54 29 140.5 MW-20BR 167.98 24.5 143.5 MW-20S 168.01 24.5 143.5 MW-21BR 174.03 31.5 142.5 MW-21SL 173.88 28.5 145.4 MW-14 171.37 24 147.4 PZ-3D 171.10 32 139.1 CTMW-1 163.40 17 146.4 CTMW-2 166.50 17.5 149.0 BGTM W-4 175.50 14 161.5 CTMW-8 167.40 20.5 146.9 Notes: BGS - Below Ground Surface MSL - Mean Sea Level Prepared by: KFD Checked by: CJS P:\Duke Energy Progress.1026\103. Cape Fear Ash Basin GW Assessment\1.11 CSA Reporting\Tables\Table 6-8 Bedrock Surface Elevations.xlsx Page 1 of 1 TABLE 6-9 HORIZONTAL GROUNDWATER GRADIENTS AND FLOW VELOCITIES CAPE FEAR STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, MONCURE, NC Ash Basin Groundwater Gradients Direction Aquifer Data Points Gradient (ft per ft) Velocity (ft per yr) 1985 Ash Basin NE Surficial ABMW-01S to CMW-5 0.0080 25* NE Bedrock ABMW-01BR to MW-5BR 0.0068 0.7 - 3 S Surficial ABMW-01S to PZ-5 0.0084 33* NW Surficial ABMW-01S to MW-17SL 0.0050 13 NW Bedrock ABMW-01BR to MW-17BR 0.0038 5 - 20 SE Surficial ABMW-01S to CMW-6 0.0043 17* SE Bedrock ABMW-01BR to MW-6BR 0.0040 7 - 20 1956 Ash Basin E Surficial BGMW-04 to ABMW-05S 0.0023 21* E Bedrock BGTMW-04 to ABMW-05BR 0.0021 0.4 - 1* SW Surficial ABMW-05S to CMW-02 0.0030 22* SW Bedrock ABMW-05BR to CTMW-02 0.0042 1 - 2* NW Surficial ABMW-05S to MW-10 0.0015 14* NW Bedrock ABMW-05BR to MW-10BR 0.0048 1- 2 1978 Ash Basin SE Surficial ABMW-02SL to CMW-07 0.0169 27* 1963 Ash Basin W Surficial ABMW-04S to CMW-8 0.0239 52* 1970 Ash Basin SW Surficial ABMW-03S to CMW-1 0.0240 6* SW Bedrock ABMW-03BR to CTMW-1 0.0106 39 - 164* Prepared by: RKD Checked by: CJS Notes: ft = feet yr = year *In the absence of hydraulic conductivity data for one of these wells, the hydraulic conductivity value used is the geometric mean of other wells in the same hydrologic monitoring zone (surficial or bedrock). Water level measurements used for these calculations were collected on June 30 and July 1, 2015 P:\Duke Energy Progress.1026\103. Cape Fear Ash Basin GW Assessment\1.11 CSA Reporting\Tables\Table 6-9 Horizontal Groundwater Gradients.xlsx Page 1 of 1 TABLE 6-10 IN -SITU HYDRAULIC CONDUCTIVITY TEST RESULTS CAPE FEAR STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, MONCURE, NC Ash Basin Hydraulic Conductivity Hydraulic Conductivity Well ID Slug Test Slug Test Number (cm/sec) (ft/day) Measured Geometric Mean Measured Geometric Mean ABMW-01 Slug Out Test 1 6.73E-04 4.54E-04 1.91E+00 1.29E+00 Test 2 3.06E-04 8.67E-01 ABMW-03 Slug Out Test 1 4.01E-04 4.61E-041.31E+00 14E+00 Test 2 5.29E-04 Hl..50E+00 ABMW-04 Slug Out Test 1 1.58E-04 1.77E-04 4.47E-01 5.01E-01 Test 2 1.98E-04 5.60E-01 ABMW-05 DRY GEOMETRIC MEAN 3.33E-04 9.44E-01 HIGHEST CONDUCTIVITY 6.73E-04 1.91E+00 LOWEST CONDUCTIVITY 1.58E-04 4.47E-01 Upper Surficial Well ID Slug Test Slug Test Number Hydraulic Conductivity (cm/sec) Hydraulic Conductivity (ft/day) Measured Geometric Mean Measured Geometric Mean ABMW-02SU Slu -Out Test 1 1.46E-04 1.38E-04 4.13E-01 3.92E-01 Slug -Out Test 2 1.32E-04 3.73E-01 MW-15SU Slug Out Test 1 1.12E-03 1.12E-03 3.19E+00 3.19E+00 MW-17SU Slug In Test 1 1.46E-03 1.03E-03 4.13E+00 2.93E+00 Test 2 1.27E-03 3.59E+00 Test 3 1.08E-03 3.05E+00 Test 4 1.21E-03 3.43E+00 Slug Out Test 2 6.69E-04 1.90E+00 Test 4 7.55E-04 2.14E+00 MW-18S Slug Out Test 1 8.41E-05 8.41E-05 2.38E-01 2.38E-01 MW-19S DRY MW-21SU Slug Out Test 1 2.84E-05 2.84E-05 8.06E-02 8.06E-02 GEOMETRIC MEAN 4.15E-04 1.18E+00 HIGHEST CONDUCTIVITY 1.46E-03 4.13E+00 LOWEST CONDUCTIVITY 2.84E-05 8.06E-02 P:\Duke Energy Progress.1026\103. Cape Fear Ash Basin GW Assessment\1.11 CSA Reporting\Tables\Table 6-10 Insitu Hydraulic Conductivity Test Results.xlsxSummary Results by Unit Page 1 of 3 TABLE 6-10 IN -SITU HYDRAULIC CONDUCTIVITY TEST RESULTS CAPE FEAR STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, MONCURE, NC Lower Surficial Well ID Slug Test Slug Test Number Hydraulic Conductivity (cm/sec) Hydraulic Conductivity (ft/day) Measured Geometric Mean Measured Geometric mean ABMW-01S Su Out Test 2 1.02E-03 1.02E-03 2.89E+00 2.89E+00 ABMW-02SL Slug -Out Test 1 8.75E-05 9 78E-05 2.48E-01 2.77E-01 Slug -Out Test 2 1.09E-04 3.10E-01 ABMW-03S Slug -Out Test 1 4.50E-06 4.50E-06 1.27E-02 1.27E-02 ABMW-04S Slug Out Test 1 2.48E-04 2.89E-04 7.02E-01 8.19E-01 Test 2 3.37E-04 9.56E-01 ABMW-05S Slug -Out Test 1 4.15E-03 4.77E-03 1.18E+01 1.35E+01 Slug -Out Test 2 4.49E-03 1.27E+01 Slug -Out Test 3 5.83E-03 1.65E+01 MW-15SL Slug -Out Test 1 3.29E-05 3.29E-05 9.34E-02 9.34E-02 MW-16S Slug Out Test 1 6.10E-03 5.98E-03 1.73E+01 1.70E+01 Test 2 6.32E-03 1.79E+01 Test 3 6.11E-03 1.73E+01 Test 4 6.25E-03 1.77E+01 Test 5 5.22E-03 1.48E+01 MW-17SL Slug In Test 1 7.39E-04 5.71E-04 2.10E+00 1.62E+00 Test 2 5.35E-04 1.52E+00 Test 3 5.12E-04 1.45E+00 Slug Out Test 1 5.47E-04 1.55E+00 Test 2 5.89E-04 1.67E+00 Test 3 5.35E-04 1.52E+00 MW-20S Slug Out Test 1 1.79E-03 1.96E-03 5.06E+00 5.55E+00 Test 2 1.69E-03 4.80E+00 Test 3 2.49E-03 7.06E+00 MW-21SL Slug -Out Test 1 2.79E-03 3.39E-03 7.90E+00 9 60E+00 Test 2 4.12E-03 1.17E+01 GEOMETRIC MEAN 9.55E-04 2.71E+00 HIGHEST CONDUCTIVITY 6.32E-03 1.79E+01 LOWEST CONDUCTIVITY 4.50E-06 1.27E-02 Transition Zone Hydraulic Conductivity Hydraulic Conductivity Well ID Slug Test Slug Test Number (cm/sec) (ft/day) Measured Geometric Mean Measured Average MW-10D Slug -Out Test 1 2.00E-05 2.00E-05 5.68E-02 5.68E-02 GEOMETRIC MEAN 2.00E-05 5.68E-02 HIGHEST CONDUCTIVITY 2.00E-05 5.68E-02 LOWEST CONDUCTIVITY 2.00E-05 5.68E-02 P:\Duke Energy Progress.1026\103. Cape Fear Ash Basin GW Assessment\1.11 CSA Reporting\Tables\Table 6-10 Insitu Hydraulic Conductivity Test Results.xlsxSummary Results by Unit Page 2 of 3 TABLE 6-10 IN -SITU HYDRAULIC CONDUCTIVITY TEST RESULTS CAPE FEAR STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, MONCURE, NC Bedrock Well ID Slug Test Slug Test Number Hydraulic Conductivity (cm/sec) Hydraulic Conductivity (ft/day) Measured Geometric Mean Measured Average ABMW-01BR Slug -Out Test 1 8.86E-04 9.23E-04 2.51E+00 2.62E+00 Slug -Out Test 2 9.24E-04 2.62E+00 Slug -Out Test 3 9.61E-04 2.72E+00 ABMW-03BR Slug -Out Test 1 7.88E-03 8.85E-03 2.23E+01 2.51E+01 Slug -Out Test 2 7.58E-03 2.15E+01 Slug -Out Test 3 1.16E-02 3.29E+01 ABMW-05BR PK-SI Test 1 1.44E-05 1.44E-05 4.08E-02 4.08E-02 MW-05BR Slug -Out Test 1 3.00E-06 3.00E-06 8.50E-03 8.50E-03 MW-06BR Slug -Out Test 1 5.47E-05 8.14E-05 1.55E-01 2.31E-01 Slug -Out Test 2 1.21E-04 3.43E-01 MW-09BR PK-SO Test 1 2.95E-05 2.95E-05 8.36E-02 8.36E-02 MW-10BR Slug -Out Test 1 1.55E-04 1.82E-04 4.41E-01 5.16E-01 Slug -Out Test 2 2.14E-04 6.05E-01 MW-12BR Slug -In Test 1 7.39E-04 6.67E-04 2.09E+00 1.89E+00 Slug -Out Test 1 7.63E-04 2.16E+00 Slug -Out Test 2 5.56E-04 1.58E+00 Slug -Out Test 3 6.30E-04 1.78E+00 MW-15BR Slug -Out Test 1 9.75E-06 9.75E-06 2.76E-02 2.76E-02 MW-16BR Slug -Out Test 1 6.51E-04 6.28E-04 1.85E+00 1.78E+00 Test 2 5.96E-04 1.69E+00 Test 3 6.37E-04 1.80E+00 MW-17BR Slug -In Test 1 3.98E-04 3.96E-04 1.13E+00 1.12E+00 Slug -In Test 2 3.63E-04 1.03E+00 Slug -Out Test 1 3.95E-04 1.12E+00 Slug -Out Test 2 4.32E-04 1.22E+00 MW-20BR PK-SI Test 1 1.37E-02 1.62E-02 .89E+01 4.58E+01 PK-SO Test 1 1.90E-02 H5.38E+01 MW-21BR PK-SI Test 1 1.28E-06 1.28E-06 3.63E-03 3.63E-03 GEOMETRIC MEAN 3.66E-04 1.04E+00 HIGHEST CONDUCTIVITY 1.90E-02 5.38E+01 LOWEST CONDUCTIVITY 1.28E-06 3.63E-03 Created by: RAG Checked by: HJF Notes: Slug tests were analyzed using the Hvorslev mathmatical model. DRY= dry well PK-SI = Packer Test, Slug -In PK-SO = Packer Test, Slug Out Sandstone Mudstone Mudstone and Sandstone P:\Duke Energy Progress.1026\103. Cape Fear Ash Basin GW Assessment\1.11 CSA Reporting\Tables\Table 6-10 Insitu Hydraulic Conductivity Test Results.xlsxSummary Results by Unit Page 3 of 3 TABLE 6-11 VERTICAL HYDRAULIC CONDUCTIVITY OF UNDISTURBED SOIL SAMPLES CAPE FEAR STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, MONCURE, NC Bottom Top Depth Depth Hydraulic Sample Interval Interval General Sample Conductivity Location (feet BGS) (feet BGS) Description (cm/sec) ABMW-01 5 7 Ash - fine to medium 1.40E-04 sandy silt ABMW-03 30 32 Fine sandy clay 1.30E-06 MW-16 0 2 Fine sandy clay 8.20E-08 MW-17 5 7 Fine sandy clay 1.30E-07 MW-21 17 20 Fine sandy clay 3.60E-08 Prepared by: KFD Checked by: CIS Notes• BGS = below ground surface cm/sec = centimeter per second P:\Duke Energy Progress.1026\103. Cape Fear Ash Basin GW Assessment\1.11 CSA Repo rting\Tables\Table 6-11 Vert Hydraulic UD.xlsx Page 1 of 1 TABLE 7-1 PHYSICAL PROPERTIES OF ASH CAPE FEAR STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, MONCURE, NC Sample Depth (Feet BGS) Moisture Content (%) Gravel (%) Sand (%) Silt (%) Clay (%) Specific Gravity From To ABMW-01 AB 3 5 32.60 0.00 15.40 75.1 9.50 2.15 ABMW-01 AB 5 7 36.30 1.20 32.50 59.8 6.50 2.25 ABMW-01 AB 10 15 33.20 0.30 38.10 57.6 4.00 2.22 ABMW-3 30 32 29.10 0.00 36.20 44.9 18.90 2.69 Prepared by: KFD Checked by: CJS Notes: = Percent BGS= below ground surface P:\Duke Energy Progress.1026\103. Cape Fear Ash Basin GW Assessment\1.11 CSA Reporting\Tables\Table 7-1 Physical Properties of Ash.xlsx Page 1 of 1 TABLE 7-2 MINERALOGY OF ASH CAPE FEAR STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, MONCURE, NC Sample ID (bgs) Type Sand Silt Clay Quartz Biotite Calcite Mullite Hematite Magnetite ABMW-1AB (13-15) Ash 35.48 58.74 5.78 30.1 ND ND 69.9 ND ND ABMW-2 (0-2) Ash 29.85 47.31 22.84 35.9 ND ND 56.6 7.2 ND ABMW-3 (0-2) Ash 26.57 61.20 12.23 40.8 ND ND 52.7 6.5 ND ABMW-3 (19-20) Ash 32.58 52.37 15.05 33.2 ND 2.3 56.9 7.9 ND ABMW-4 (0-2) Ash 64.21 29.40 6.39 41.6 6.4 0.0 45.1 3.5 2.8 ABMW-5 (0-2) Ash 38.79 49.05 12.16 46.2 ND 0.0 51.0 nd 2.8 Prepared by: DZH Checked by: KFD Notes: %= percent ND= Not detected bgs = depth below ground surface P:\Duke Energy Progress.1026\103. Cape Fear Ash Basin GW Assessment\1.11 CSA Reporting\Tables\Table 7-2 Mineralogy of Ash.xlsx Page 1 of 1 TABLE 7-3 CHEMICAL PROPERTIES OF ASH CAPE FEAR STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, MONCURE, NC Analytical Parameter Percent Moisture pH at 25 Degrees C Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chloride Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury Molybdenum Nickel Nitrate (as N) Potassium Selenium Sodium Strontium Sulfate Thallium Total Organic Carbon Vanadium Zinc Reporting Units ^/o S.U. ni mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg Soil RSL- Industrial Health NE NE 110000 47 3 22000 230 23000 98 NE NE NE 35 4700 82000 Soo NE 2600 4 580 2200 NE NE 580 NE 70000 NE 1.2 NE 580 35000 Soil RSL- Residential Health NE NE 7700 3.1 0.68 1500 16 I600 7.1 NE NE NE 2.3 310 5500 400 NE ISO 0.94 39 150 NE NE 39 NE 4700 NE 0.078 NE 39 2300 Soil RSL- Protection of Groundwater NE NE NE 0.27 0.29 82 3.2 NE NE NE NE 180000 NE 46 NE 14 NE NE 0.1 NE NE NE NE 0.26 NE NE NE 0.14 NE NE NE Sample ID b s Sample Collection Date Analytical Results ABB-06 AB (3-5) 04/13/2015 17.9 6.3 10700 <6.2 20.5 173 2.2 10.6 j <0.74 2660 <305 14.2 12.6 26.6 23600 22.6 2250 220 0.24 9 19.1 <30.5 1530 12 <310 83.4 <305 <6.2 102000 51.5 48.2 ABB-06 AB (14-15) 04/13/2015 40.1 7.7 8180 <8.6 37.8 162 2.7 23.4 <1 2150 <417 14.2 12.6 33.1 5960 14.8 581 26 0.44 16.1 22.2 <41.7 1180 18.8 <428 98.8 <417 <8.6 85600 59.6 25.9 ABB-06 AB (40-44) 04/13/2015 30.4 7.2 11500 <7.3 95.1 159 0.97 9.3 j <0.88 2160 <354 19.9 6.8 j 48.9 22600 49.5 1450 123 0.34 56.9 11.2 <35.4 896 4.4 j <367 102 <354 <7.3 80000 42.7 43.4 ABMW-01 AB (3-5) 03/18/2015 22.7 8.0 16400 2.1 54.2 282 6.4 78.7 0.47 4200 <321 26.3 23.1 71.3 8070 36 1030 60.5 0.32 2.9 j 39.3 <32.1 1980 21.2 430 287 <321 <3.3 46600 105 55.2 ABMW-01 AB (14-15) 03/18/2015 42.3 8.0 9500 <4.3 33.5 11 192 3.5 33.6 0.42 j 1770 <431 11.1 15.8 45.8 3700 27.4 554 23.1 0.53 1.4 26 <43.1 1370 45.9 247 132 <431 <4.3 163000 71.2 35.3 ABMW-01 AB (34-35) 03/18/2015 51.2 7.1 6060 2.9 j 35.1 147 2.8 33.1 <0.65 1390 <513 10.9 10.2 28 2840 14.9 390 13.9 0.16 3.4 15.2 <51.3 821 25.8 139 105 257 j <5.4 46100 63.4 18.9 ABM W-02 AB (2-3) 03/25/2015 31.3 5.7 12700 <3.8 115 217 2.9 27.8 0.37 j 1700 <362 15.4 9.4 48.8 7270 18.3 947 49.6 0.14 5.4 21.4 <36.2 2350 14.9 3041 139 244 j <3.8 48800 51.2 43.5 ABMW-03 AB (3-5) 04/15/2015 22.5 5.4 9150 <6.8 46.2 460 2.1 24.5 <0.81 1970 <321 14.3 7.3 34.7 11000 9.5 732 51.9 0.25 2.4 j 15.7 <32.1 1470 14.7 <338 162 <321 <6.8 83300 37.3 16.3 ABMW-03 AB (19-20) 04/14/2015 50.6 8.9 9690 <9.9 52.6 316 2.3 29.8 <1.2 4700 <496 16 6.2 j 29.2 8410 10.8 1130 59 0.23 <5 12.3 <49.6 1560 8.5 j 323 j 230 523 <9.9 175000 33 13.5 ABMW-03 AB (19-20) DUP 04/14/2015 43.8 8.8 12300 <9.3 72.9 407 3 35.2 <1.1 6170 <444 21.1 7.8 j 1 36.5 10000 13.6 1480 73.4 0.24 <4.7 15.2 <44.4 1870 10.4 353 j 301 437 j <9.3 160000 44.8 17.4 ABMW-04 AB (1-2) 04/11/2015 42.3 5.4 5200 <8.4 21.8 482 1.1 <21.1 0.59 j 1390 <432 10.5 6.9 j 19.3 20500 <8.4 447 56.2 0.093 <4.2 13 <43.2 853 6.9 j <422 97.4 <432 <8.4 104000 20.4 9.7 ABMW-04 AB (1-2) DUP 04/11/2015 19 6.6 6260 <6.1 30.4 389 1.4 <15.1 <0.73 1710 <308 11.5 6.5 25.7 16800 5.5 j 523 55.7 0.13 1.8 j 16.1 <30.8 1030 7.1 <303 135 <308 <6.1 82900 25.8 14.5 ABMW-04 AB (21-22) 04/11/2015 26.9 7.5 10700 <7 44 603 3.4 10.11 <0.84 3830 <343 18.8 9.5 34.2 19100 11.5 991 93.5 0.1 <3.5 17.8 <34.3 1990 8.8 352 251 209 j <7 61300 40.5 15.1 ABMW-05 AB (3-5) 05/07/2015 4.8 6.8 9100 <5.4 43 495 2.4 <13.4 <0.64 2580 <261 11.7 6.8 27.2 10400 7.5 968 47.9 0.1 <2.7 13.2 <26.1 1440 <5.4 314 197 <261 <5.4 40100 29.7 10.4 ABMW-05 AB (3-5) DUP 05/07/2015 35.9 6.7 14700 <7.9 64.5 880 3.8 10.6 j <0.94 4120 <390 19.1 11.7 44.2 19000 12.2 1500 79.9 0.17 <3.9 21.8 <39 2220 <7.9 514 333 <390 <7.9 58900 50.3 16.6 B-N1963 (0-2) 03/30/2015 11.8 3.2 1920 <2.8 118 47.8 <0.28 40 <0.34 3400 <288 9.3 2.1 j 19 50400 42.1 1170 68.8 0.13 1.7 j 3.9 <28.8 750 4.7 <283 20.2 5650 <2.8 162000 24.9 10.3 B-N1963 (14-16) 03/30/2015 13.8 3.5 4580 <5.8 13.1 374 1.2 19.6 <0.7 873 <291 7.6 6.3 14.3 16600 2.9 j 449 106 0.017 <2.9 17.3 <29.1 468 4.2 <290 107 3330 <5.8 28000 13.4 27.3 B-N1963 (22-24) 03/30/2015 13.5 5.5 4830 <2.9 1 2.9 1 47.5 0.37 <14.4 1 <0.35 180 <286 1 6.9 9.8 4.9 8660 6.9 402 596 0,013 <2.9 1 3.1 <28.6 I <288 I <2.9 <288 3 <286 <5.8 2130 18.7 9.5 Prepared by: BE MAH Checked by: RLP Notes: Bold color highlighted concentrations indicate highest exceedance of the EPA Mid -Atlantic Risk Assessment regional screening levels for soil, June 2015, for the category listed below: - Soil RSL - Industrial Health 0 - Soil RSL - Residential Health 0 - Soil RSL - Protection of Groundwater mg/kg = milligrams per kilogram DUP = Duplicate NE = Not established bgs = depth below ground surface S.U. = Standard Units % = Percent j = indicates concentration reported below Practical Quantitation Limit (PQL), but above Method Detection Limit (MDL) and therefore concentration is estimated. < = concentration not detected at or above the reporting limit. P:\Duke Energy Progress.1026\103. Cape Fear Ash Basin GW Assessment\l.11 CSA Reporting\Tables\Table 7-3 Chemical Properties of Ash..I. Page 1 of 1 TABLE 7-4 LEACHING PROPERTIES OF ASH CAPE FEAR STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, MONCURE, NC Analytical Parameter yt Aluminum Antimony y Arsenic Barium Beryllium ry Boron Cadmium Calcium Chloride Chromium Cobalt Copper Co Iron Lead Magnesium Manganese Mercury Molybdenum Nickel Nitrate (as N) Potassium Selenium Sodium Strontium Sulfate Thallium Vanadium Zinc Reporting Units ug/I ug/I ug/I ug/I ug/I ug/I ug/l mg/I mg/I ug/I ug/I mg/l ug/I ug/I mg/l ug/I ug/I ug/I ug/I mg/l mg/I ug/l mg/l mg/I mg/l ug/I ug/I mg/I 15A NCAC 02L Standard NE 1* 10 700 4* 700 2 NE 250 10 1* 1 300 15 NE So 1 NE 100 10 NE 20 NE NE 250 0.2* 0.3* 1 Sample ID (bgs) Sample collection t Analytical Results ABB-06 AB (3-5) 04/13/2015 24900 S.1 24.6 429 0.94 166 0.083 6.37 <6.1 15.1 6.3 0.0131 18000 8.1 2.27 117 0.08 j 129 9 <0.24 2.28 13.9 1.98 0.187 13.8 0.51 45.6 0.124 ABMW-01 AB (3-5) 03/18/2015 696 7.1 73.7 159 <0.2 143 <0.08 9.62 <6.5 4.4 <0.5 0.0003 j <50 <0.1 0.28 1.4 <0.2 23.1 0.33 j <0.26 0.0966 198 1.44 0.319 6.1 <0.1 160 0.0226 ABMW-01 AB (34-35) 03/18/2015 865 31.1 93.4 245 0.49 137 0.063 j 2.54 <10.3 5 1.7 0.0054 261 3.6 0.335 9.2 <0.2 46.8 2.8 <0.41 0.373 21.7 1.73 0.142 12.7 0.2 319 0.0421 ABMW-02 AB (2-3) 03/25/2015 16.2 4.3 3.9 292 <0.2 81.5 0.18 3.45 <7.3 0.46 j 4.7 0.0008 j <50 <0.1 0,593 26.6 <0.2 14.3 13.5 <0.29 0.45 14.8 2.4 0.267 18.9 <0.1 9.9 0.0666 ABMW-03 AB (3-5) 04/15/2015 154 1.1 3.6 163 <0.2 52.2 <0.08 0.858 <6.4 2.1 0.43 j 0.00042 j <50 0.056 j 0.443 1.9 <0.2 11.1 1.2 <0.26 0.897 23 1.27 0.0885 7.8 <0.1 14.2 0.0357 ABMW-03 AB (19-20) 04/14/2015 1080 2.1 131 149 <0.2 316 <0.08 9.79 <10.1 2.1 <0.5 0.003 36.3 j 0.2 0.905 3 <0.2 5.5 0.89 <0.4 0.398 37.1 1.48 0.271 24.8 <0.1 48.2 0.0098 ABMW-04 AB (21-22) 04/11/2015 428 3.6 90.5 251 <0.2 61.5 <0.08 9.48 <6.8 2.2 <0.5 0.00066 j 18.9 j 0.05 j 0.605 5.3 <0.2 8.2 1 0.35 j <0.27 0.238 58.3 1 2.23 0.344 12.6 <0.1 33.5 0.0224 ABMW-05 AB (3-5) 05/07/2015 1210 1.3 50.4 237 0.42 64.6 0.077 j 1.77 <5.3 10 1.3 0.0074 691 2 0.62 10.9 0.09 j 2.3 3.4 <0.21 1.4 2.3 1.45 0.1 6.2 0.29 41.6 0.0543 ABMW-05 AB (3-5) DUP 05/07/2015 1300 1.3 52.6 244 0.42 73.2 0.064 j 1.76 <7.8 10.7 1.4 0.0083 758 2.1 0.616 12.2 0.09 j 2.2 4.3 <0.31 1.39 2.4 1.47 0.102 9.1 0.26 40 0.0566 B-N1963 (0-2) 03/30/2015 969 <0.5 0.33 j 147 0.21 51.5 0.19 88.7 <5.7 0.52 2.4 0.0039 160 4.7 0.546 128 <0.2 <0.5 6 <0.23 1.02 0.92 0,799 0.0896 275 0.06 j <1 0.143 B-N1963 (14-16) 03/30/2015 13600 <0.5 8.6 149 15.5 168 8 4.94 <5.8 2.1 127 0.0885 1950 1.9 6.31 2060 <0.2 <0.5 320 <0.23 1.86 3.6 2.32 0.398 173 0.77 <1 1.64 B-N1963 (22-24) 03/30/2015 6730 <0.5 1.4 422 0.45 161 <0.08 1.52 <5.8 9.7 9.6 0.0088 8720 12.8 0.461 1 162 0.17 j <0.5 2.3 0.24 0.495 0.27 j 3.3 0.0257 7.2 0.057 j 37.6 0.192 Prepared by: BER/MAH Checked by: RLP Notes: 0 - Bold highlighted concentration indicates exceedance of the 15A NCAC 02L Standard, Appendix 2, April 1, 2013. Synthetic Precipitation Leaching Procedure, USEPA Method 1312 mg/I = milligrams per liter ug/I = microgram per liter NE = Not established j = indicates concentration reported below Practical Quantitation Limit (PQL), but above Method Detection Limit (MDL) and therefore concentration is estimated. < = concentration not detected at or above the reporting limit. * - Interim Maximum Allowable Concentrations (IMACs) of the 15A NCAC 02L Standard, Appendix 1, April, 1, 2013. DUP = Duplicate bgs= depth below ground surface P:\Duke Energy Progress. 1026\103. Cape Fear Ash Basin GW Assessment\5.11 CSA Reporting\Tables\Table 7-4 Leaching Properties of Ash.xlsx Page 1 of 1 TABLE 7-5 WHOLE ROCK METAL OXIDE ANALYSIS OF ASH CAPE FEAR STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, MONCURE, NC Sample ID (bgs) Type AIz03 BaO CaO Cii Fe203 K20 Mgi MnO Na20 P205 S'02 Sri Ti02 V205 LOI ABMW-1(AB 13-15) Ash 35.42 0.07 0.94 0.03 3.87 2.08 2 0.07 0.22 0.23 41.39 0.02 0.72 <0.01 10.94 ABMW-2(0-2) Ash 35.23 0.14 1.2 0.02 6.91 2.08 1.25 0.03 0.04 0.08 44.42 0.16 1.28 0.05 6.27 ABMW-3(0-2) Ash 32.49 0.13 1.05 0.04 6.41 2.02 1.18 0.04 0.03 0.07 42.44 0.13 1.23 0.05 10.75 ABMW-3(19-20) Ash 31.49 0.12 1.8 0.03 7.99 1.8 1.12 0.03 0.04 0.06 36.5 0.18 1.25 0.04 13.65 ABMW-4(0-2) Ash 29.71 0.13 0.88 0.03 11.62 1.97 1.11 0.03 0.02 0.04 41.87 0.11 1.17 0.04 8.59 ABMW-5(0-2) Ash 32.99 0.14 1.55 0.04 9.91 1.96 1.21 0.03 0.03 0.05 44.42 0.14 1.27 0.04 8.68 Prepared by: DZH Checked by: KDF Notes: %= percent < = concentration not detected at or above the reporting limit bgs = depth below ground surface P:\Duke Energy Progress.1026\103. Cape Fear Ash Basin GW Assessment\1.11 CSA Reporting\Tables\Table 7-5 Whole Rock Metal Oxide Analysis of Ash.xlsx Page 1 of 1 TABLE 7-6 WHOLE ROCK ELEMENTAL ANALYSIS OF ASH CAPE FEAR STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, MONCURE, NC Sample ID Type As Cd Ce Co Cu Ga La Mo Ni Pb Sb Se Sn W Zn Zr (b9s) ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ABMW-1AB (13-15) Ash 33 0.4 148 21 137 32 1 3 14 12 6 27 5 3 75 81 ABMW-2 (0-2) Ash 111 0.3 27 9 52 48 80 14 75 26 3 8 3 3 122 7 ABMW-3 (0-2) Ash 138 0.5 29 10 55 47 75 7 102 20 3 7 3 7 113 5 ABMW-3 (19-20) Ash 82 0.3 22 7 34 41 75 13 95 10 <1 8 2 2 81 5 ABMW-4 (0-2) Ash 55 <0.2 14 9 37 23 71 3 71 8 <1 1 1 1 47 5 ABMW-5 (0-2) Ash 49 0.2 24 13 43 28 84 4 113 17 1 3 2 3 100 ND Prepared by: DZH Checked by: KDF Notes: ppm = parts per million < = concentration not detected at or above the reporting limit bgs = depth below ground surface P:\Duke Energy Progress.1026\103. Cape Fear Ash Basin GW Assessment\l.11 CSA Reporting\Tables\Table 7-6 Whole Rock Elemental Analysis of Ash.xlsx Page 1 of 1 TABLE 7-7 ASH PORE WATER ANALYTICAL RESULTS CAPE FEAR STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, MONCURE, NC Water Spec Ferrous Aluminum Aluminum Antimony Antimony Arsenic Arsenic Barium Barium Beryllium Beryllium Bi- Boron Boron Cadmium Cadmium Calcium Carbonate Chromium Chromium Cobalt Cobalt Copper Copper Analytical Parameter Redox Assignment PH Level Temp Cond DO ORP Eh Turbidity Iron Alkalinity carbonate Alkalinity Alkalinity Chloride DIS TOT DIS TOT DIS TOT DIS TOT DIS TOT DIS TOT DIS TOT TOT DIS TOT DIS TOT DIS TOT urnh s Reporting Units None S.U. ft Deg C mg/l mV mV NTU mg/I mg/l ug/1 ug/l ug/I ug/I ug/I ug/I ug/1 ug/I ug/I ug/I mg/I ug/I ug/I ug/I ug/I mg/I mg/I mg/l ug/I ug/I ug/I ug/I mg/l mg/l 15A NCAC 02L Standard NE 6.5-8.5 NE NE NE NE NE NE NE NE NE NE NE NE 1* NE 10 NE 700 NE 4* NE NE 700 NE 2 NE NE 250 NE 10 NE 1* NE 1 Sample ID Sample Field Parameters Analytical Results Collection Date ABMW-01 05/08/2015 Anoxic 8.0 19.65 25 468 0.39 -202 3 4.13 NM 75 26 61 <1 <1 532 582 117 119 <1 <1 75 2310 2270 <1 <1 53.6 <10 18 <1 <1 <I <I <0.001 <0.001 ABMW-03 05/20/2015 Mixed (oxic-anoxic) 8.3 13.54 18 1152 1.41 -78 127 0.72 NM 170 215 232 3.1 3.59 361 341 133 137 <1 <1 160 6250 6360 <1 <i 120 <10 6.7 <1 <1 <1 <1 <0.001 <0.001 ABMW-04 05/14/2015 Anoxic 7.3 16.23 19 840 0.19 -184 21 4.36 NM 230 13 30 <1 <1 709 1010 266 258 <1 <1 230 1410 1350 <1 <1 82.4 <10 37 <1 <1 <1 <1 <0.001 <0.001 PZ-06 08/05/2015 Anoxic 7.5 19.45 21 1083 0.31 -161 44 4.63 NM 310 43 170 2.17 2.3 607 647 307 312 <1 <1 310 5160 5380 <1 <1 183 <10 23 <1 <1 18.6 18.7 0.00381 <0.001 PZ-07 08/06/2015 Anoxic 4.0 10.80 18 7193 0.2 1179 384 4.79 NM <10 431000 466000 <10 <10 201 193 42 <500 305 318 <10 1050 <5000 <10 <10 370 <10 13 145 138 1100 1050 <0.01 <0.01 PZ-08 08/05/2015 Anoxic 6.7 111A0 23 975 0.36 -34 172 4.17 NM 190 7 16 4.22 2.85 224 1.24 68 61 <1 <1 1 190 1 463 1 461 <1 <1 107 <10 41 <1 <1 12.7 17.8 <0.001 <0.001 Prepared by: BER/SRW Checked by: CIS Notes 0 - Bold highlighted concentration indicates exceedance of the 15A NCAC 02L Standard, Appendix 2, April 1, 2013 ORP = Oxidation Reduction Potential NA = Not analyzed DIS = Dissolved NE = Not established TOT = Total NTU = nephelometric turbidity unit Temp = Temperature S.U. = Standard Unit DO = Dissolved Oxygen ug/I = microgram per liter Deg C = Degree Celsius umhos/cm = micro mhos per centimeter mg/I = milligrams per liter Spec Cord = Specific Conductance mg-N/L = miligram nitrogen per liter NM = Not Measured my = millivolts < = concentration not detected at or above the reporting limit. * - Interim Maximum Allowable Concentrations (IMACs) of the 15A NCAC 02L Standard, Appendix 1, April, 1, 2013. Qualitative Redox State derived using USGS Excel ® Workbook for Identifying Redox Processes in ground water P:\Duke Energy Progress.1026\103. Cape Fear Ash Basin GW Assessment\1.11 CSA Reporting\Tables\Table 7-7 Ash Pare Water Analytical Results.xlsx Page I of 2 TABLE 7-7 ASH PORE WATER ANALYTICAL RESULTS CAPE FEAR STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, MONCURE, NC Analytical Parameter Iron Iron Lead Lead Magnesium Manganese Manganese Mercury Mercury Methane Molybdenum Molybdenum Nickel Nickel Nitrate (as N) Potassium Selenium Selenium Sodium Strontium Strontium Sulfate Sulfide Thallium Thallium Total Dissolved Solids Total Organic Carbon Total Suspended Solids Vanadium Vanadium Zinc Zinc DIS TOT DIS TOT TOT DIS TOT DIS TOT DIS TOT DIS TOT TOT DIS TOT TOT DIS TOT DIS TOT DIS TOT DIS TOT Reporting Units ug/I ug/I ug/l ug/I mg/I ug/I ug/I ug/I ug/I ug/I ug/I ug/I ug/I ug/I mg-N/L mg/I ug/I ug/I mg/I mg/I mg/I mg/I mg/I ug/I ug/I mg/I mg/I mg/I ug/I ug/l mg/I mg/I ISA NCAC 02L Standard NE 300 NE IS NE NE 50 NE 1 NE NE NE NE 100 10 NE NE 20 NE NE NE 250 NE NE 0.2* Soo NE NE NE 0.3* NE 1 Sample ID Sample Collection Date Analytical Results ABMW-01 05/08/2015 1570 1620 <1 <1 7.08 163 161 <0.05 <0.05 <10 449 457 1.97 1.92 <0.01 8.64 1.26 <1 19 1.21 1.21 96 0.137 <0.2 <0.2 280 1.8 6 <0.3 0.522 <0.005 0.006 ABMW-03 05/20/2015 70 91 <1 <1 67.4 124 124 <0.05 <0.05 940 261 239 5.1 5.45 0.016 19.7 1.92 2.32 23.4 4.37 4.45 410 <0.2 0.442 0.422 820 1.2 <5 22.3 22.1 0.005 <0.005 ABMW-04 05/14/2015 3960 3630 <1 <1 17.3 409 395 <0.05 <0.05 6200 32.4 35.3 3.38 3.07 <0.01 13.4 1.67 <1 57 3.27 3.2 120 <0.2 <0.2 <0.2 500 1.3 10 <0.3 <0.3 0.006 <0.005 PZ-06 08/05/2015 2660 3050 <1 <1 24.9 1070 1110 <0.05 <0.05 56 263 269 16.2 15.9 <0.01 13 <1 <1 22 5.23 5.22 230 <0.1 <0.2 0.255 760 1.1 13 9.31 11.1 0.022 <0.005 PZ-07 08/06/2015 2040000 2140000 11.2 10.3 185 24800 26300 <0.05 <0.05 310 <10 <10 2180 2050 <0.01 97.9 16.1 16.4 79.7 10 11 18000 <0.1 13.2 12.6 12000 1.1 16 1910 1880 2.69 3.45 PZ-OB 011/05/201.1 2560 2390 <1 <1 25.4 1570 2170 <0.05 <0.05 <SO -1 16.9 213.9 43.5 0.082 12.4 <1 1.07 59.2 2.62 2.79 220 <0.1 1.02 1.31 61.0 0.492 42 9.49 6.43 0.028 0.011 Prepared by: BER/SRW Checked by: CIS Notes 0 - Bold highlighted concentration indicates exceedance of the 15A NCAC 02L Standard, Appendix 2, April 1, 2013 ORP = Oxidation Reduction Potential NA = Not analyzed DIS = Dissolved NE = Not established TOT = Total NTU = nephelometric turbidity unit Temp = Temperature S.U. = Standard Unit DO = Dissolved Oxygen ug/1 = microgram per liter Deg C = Degree Celsius umhos/cm = micro mhos per centimeter mg/I = milligrams per liter Spec Cord = Specific Conductance mg-N/L = miligram nitrogen per liter NM = Not Measured my = millivolts < = concentration not detected at or above the reporting limit. * - Interim Maximum Allowable Concentrations (IMACs) of the 15A NCAC 02L Standard, Appendix 1, April, 1, 2013. Qualitative Redox State derived using USGS Excel ® Workbook for Identifying Redox Processes in ground water P:\Duke Energy Progress.1026\103. Cape Fear Ash Basin GW Assessment\1.11 CSA Reporting\Tables\Table 7-7 Ash Pare Water Analytical Results.xlsx Page 2 of 2 TABLE 7-8 1SA NCAC 2L EXCEEDANCES IN ASH PORE WATER CAPE FEAR STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, MONCURE, NC Analytical Parameter pH Antimony Arsenic Beryllium Boron Chromium Cobalt Iron Manganese Nickel Sulfate Thallium Total Dissolved Solids Vanadium Zinc Reporting Units S.U. ug/1 ug/1 ug/I ug/I ug/I ug/1 ug/1 ug/I ug/1 mg/I ug/1 mg/1 ug/1 mg/1 15A NCAC 02L Standard 6.5-8.5 1* 10 4* 700 10 1* 300 50 100 250 0.2* 500 0.3* 1 Sample ID Sample Collection Date Analytical Results ABMW-01 05/08/2015 BE BE 582 BE 2270 BE BE 1620 161 BE BE BE BE 0.522 BE ABMW-03 05/20/2015 BE 3.59 341 BE 6360 BE BE BE 124 BE 410 0.422 820 22.1 BE ABMW-04 05/14/2015 BE BE 1010 BE 1350 BE BE 3630 395 BE BE BE BE BE BE PZ-06 08/05/2015 BE 2.3 647 BE 5380 BE 18.7 3050 1110 BE BE 0.255 760 11.1 BE PZ-07 08/06/2015 4.0 BE 193 318 BE 138 1050 2140000 26300 2050 18000 12.6 12000 1880 3.45 PZ-08 08/05/2015 BE 2.85 124 BE BE BE 17.8 2390 2170 BE BE 1.31. 620 6.43 BE Prepared by: BER/SRW Checked by: CIS Notes: 0 - Bold highlighted concentration indicates exceedance of the 15A NCAC 02L Standard, Appendix 2, April 1, 2013. ug/I = microgram per liter mg/I = milligrams per liter S.U. = Standard Units * - Interim Maximum Allowable Concentrations (IMACs) of the 15A NCAC 02L Standard, Appendix 1, April, 1, 2013. BE = indicates concentration was below the 15A NCAC 02L Standard, April 1, 2013. P:\Duke Energy Progress.1026\103. Cape Fear Ash Basin GW Assessment\1.11 CSA Reporting\Tables\Table 7-8 2L Exceedances in Ash Pore Water.xlsx Page 1 of 1 TABLE 7-9 VALENCE SPECIATION OF ASH PORE WATER CAPE FEAR STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, MONCURE, NC Analytical Parameter As(III) As(V) MMAs DMAs As (UK) Cr(VI) Fe(II) Fe(III) Mn(II) Mn(IV) Se(IV) Se(VI) SeCN McSe(IV) SeMe Se (UK) Reporting Units ug/I ug/1 ug/I ug/l ug/l ug/l ug/l ug/l ug/1 ug/I ug/1 ug/I ug/1 ug/I ug/I ug/1 Sample ID Sample Collection Date Analytical Results ABMW-01 06/15/2015 27.6 0.253 <0.035 <0.015 NA <0.005 38.7 <6.7 186 2.36 NA NA NA NA NA NA ABMW-03 06/16/2015 62 235 <0.053 <0.083 NA 0.015 21 17.2 114 6.08 NA NA NA NA NA NA ABMW-04 06/16/2015 699 15.2 <0.053 <0.083 NA <0.005 2860 <5 378 <0.38 NA NA NA NA NA NA Prepared by: BER/MAH Checked by: RLP Notes: ug/I = microgram per liter < = concentration not detected at or above the reporting limit NA = not analyzed P:\Duke Energy Progress.1026\103. Cape Fear Ash Basin GW Assess ment\1.11 CSA Repo rting\Tables\Table 7-9 Valence Speciation of Ash Pore Water.xlsx Page 1 of 1 TABLE 8-1 PHYSICAL PROPERTIES OF SOIL CAPE FEAR STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, MONCURE, NC Sample ID Depth (Feet BGS) Moisture Content Gravel (%) Sand (%) Silt (%) Clay (%) Specific Gravity From To MW-12 BR SB 0 2 3.00 0.00 8.50 59.1 32.40 2.37 MW-12 BR SB 17 18 13.90 0.00 96.00 1.2 2.70 2.67 MW-15 SB 18 19 14.80 18.3 59.1 17.3 5.3 2.674 Notes: % = Percent BGS= below ground surface Prepared by: KDF Checked by: CJS P:\Duke Energy Progress.1026\103. Cape Fear Ash Basin GW Assessment\1.11 CSA Reporting\Tables\Table 8-1 Physical Properties of Soil.xlsx Page 1 of 1 TABLE 8-2 MINERALOGY OF SOILS CAPE FEAR STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, MONCURE, NC Sample ID Sand Silt Clay Quartz Feldspar Amphibole Calcite Chlorite Dolomite Hematite I (.7)/ S Illite Magnetit Mullite Kaolinite Pyrite (bgs) Type % % % ABMW-1(SB 39-41) Clayey silt 57.48 28.46 14.06 30.1 55.9 ND ND ND ND ND ND 6.1 ND ND 8.0 ND ABMW-2(SB 27-28) Saprolite with coal and 79.98 weathered mudstone 13.12 6.90 17.5 13.2 ND ND ND ND ND ND 41.4 ND ND 26 1.9 ABMW-3BR(63-64) Mudstone 17.57 70.50 11.93 27.1 8.1 ND 2.5 4.5 ND 6.5 ND 51.5 0.2 ND ND ND MW-6BR(SB 36-37) Sandstone, Arkosic 67.78 Conglomerate 25.15 7.07 20.3 38.0 ND ND 1.2 0.9 ND ND 39.4 ND ND ND ND MW-6BR(SB 26-27) Sandstone, Arkosic 66.16 I I Conglomerate 24.53 9.31 23.6 42.5 ND ND 2.3 0.9 ND ND 30.1 ND ND ND ND MW-9BR(29-29.5) Sandstone 44.47 47.52 1 8.01 1 28.1 1 30.5 ND ND 6.2 0.9 ND ND ND ND ND ND ND MW-9BR(23.5-24) Mudstone 23.52 64.00 12.48 23.7 20.7 ND ND 2.4 ND ND ND 49.9 ND ND 3.3 ND MW-9BR(35-36) Sandstone, Graywacke 53.27 40.42 6.31 16.2 35.0 ND ND 5.7 ND ND ND 39.4 ND ND 3.6 ND MW-15(SB 35-36) Mudstone, weathered 17.72 74.46 7.82 31.8 10.0 ND ND ND ND 2 ND 46.4 ND ND 9.8 ND MW-15(SB 18-19) Sand 74.88 18.98 6.14 54.2 1 24.4 2.3 ND 7.2 ND ND ND 8.4 ND ND 3.6 ND MW-15BR(73-74) Sandstone 56.40 34.68 8.92 21.1 10.0 ND ND 5.3 ND ND ND 57.8 ND ND 3.4 ND MW-15BR(58-59) Mudstone 42.30 53.42 4.28 25.1 10.3 ND ND 4.2 ND 0.4 ND 55.6 ND ND 4.8 ND Prepared by: DZH Checked by: KDF Notes: %= percent ND = not detected bgs = depth below ground surface P:\Duke Energy Progress.1026\103. Cape Fear Ash Basin GW Assessment\1.11 CSA Reporting\Tables\Table 8-2 Mineralogy of Soils.xlsx Page 1 of 1 TABLE 8-3 CHEMICAL PROPERTIES OF SOIL CAPE FEAR STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, MONCURE, NC Sail RSL-Industrial Soil Soil RSL - Protection of Groundwater Analytical Results MT : EW."A.3����������®���o���������m����� Prepared by: BE8/MAH Checked by: S1L Notes: Bold color highlighted concentrations indicate highest exceedance of the EPA Mid -Atlantic Risk Assessment regional screening levels for soil, June 2015, for the category listed below: 0 - Soil RSL- Industrial Health O - Soil RSL - Residential Health O- Soil RSL - Protection of Groundwater mg/kg = milligrams per kilogram NE = Not established S.U. = Standard Unit: % = Percent DUP = Duplicate NA = Not analyzed j = indicates concentration reported below Practical Quantitation Limit (PQL), but above Method Detection Limit (MDL) and therefore concentration is estimated. < =concentration not detected at or above the reporting limit. P:\Duke Energy Progress.1026\103. Cape Fear Ash Basin GW Assessment\1.11 CSA Reporting\Tables\Table 8-3 Chemical Properties of SmI.Asx Page 1 of 1 TABLE 8-4 LEACHING PROPERTIES OF SOIL CAPE FEAR STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, MONCURE, NC Analytical Parameter y Aluminum Antimony y Arsenic Barium Beryllium y Boron Cadmium Calcium Chloride Chromium Cobalt Copper Co Iron Lead Magnesium Manganese Mercury Molybdenum Nickel Nitrate (as N) Potassium Selenium Sodium Strontium Sulfate Thallium Vanadium Zinc Reporting Units ug/I ug/I ug/I ug/I ug/I ug/I ug/I mg/I mg/I ug/I ug/I mg/I ug/I ug/I mg/I ug/I ug/I ug/I ug/I mg/I mg/I ug/I mg/I mg/I mg/I ug/I ug/I mg/I 15A NCAC 02L Standard NE 1* SO 700 4* 700 2 NE 250 SO 1* 1 1 300 15 NE 50 1 NE 100 10 NE 20 NE NE 250 0.2* 0.3* 1 Sample ID (bgs) Sample Collection Date Analytical Results ABMW-01 SB (39-41) 03/23/2015 91800 <0.5 23.6 606 4.1 97.3 0.11 11.8 <5.7 110 34.4 0.0625 56500 36.5 5.97 694 0.23 64.9 39.6 0.23 2.06 6.1 1.63 0.276 5.5 0.37 313 0.196 ABMW-01 SB (57-59) 03/24/2015 6300 0.16 j 5 265 0.24 47.6 0.035 j 8.71 3.9 j 4.1 1.8 0.0033 6490 3.5 2.36 182 0.03 j 4.6 2 <0.21 2.64 0.42 j 3.05 0.0499 3.9 0.044 j 25.2 0.0387 ABMW-02 SB (5-6) 03/26/2015 145 <0.5 <0.5 168 <0.2 95.5 0.063 j 1.35 <6.4 0.4 j 1.8 0.0013 1560 0.21 0.823 ISO <0.2 <0.5 1.8 <0.26 0.696 <0.5 2.57 0.0227 19 <0.1 <1 0.16 ABMW-02 SB (11-12) 03/26/2015 7.7 j <0.5 <0.5 182 <0.2 97 0.031 j 0.598 <6.5 0.84 5.6 0.00079 j <50 0.11 0.383 152 0.03 j <0.5 1.9 <0.26 0.326 <0.5 2.03 0.0104 7.8 <0.1 <1 0.128 ABMW-03 SB (25-26) 04/14/2015 54000 <0.5 3.8 347 1.1 183 0.03 j 5.32 <6.9 42.6 16.3 0.0469 47400 11.9 4.07 1340 0.1 j 0.37 j 26.1 0.74 1.27 0.65 2.17 0.117 13.7 0.24 86 0.133 ABMW-04 SB(28-30) 04/11/2015 282000 <0.5 17.7 1340 6.6 181 0.25 18.5 15.2 288 43.6 0.155 278000 52.6 22.1 2210 0.39 0.37j 125 <0.26 3.24 3.9 2.76 0.274 5.3 1 370 0.554 ABMW-04 SB (42.5-44.5) 04/13/2015 44000 0.47 j 7 359 1.8 43.9 0.21 2.55 7.3 53.2 13.5 0.039 22900 23.8 3.38 ISO 0.04 j 1.4 22.4 <0.27 1.38 0.82 2.68 0.0302 6.3 0.18 161 0.182 ABMW-05 AS (23-24) 05/07/2015 528 1.9 64.9 349 <0.2 76.9 <0.08 8.31 <6.4 1.5 <0.5 0.0015 15.3 j 0.077 j 0.706 7.2 <0.2 5 0.65 <0.25 0.177 87.7 1.39 0.309 6.8 <0.1 39.8 0.0339 ABMW-05 AB (29-30) 05/07/2015 8.6 j <0.5 <0.5 143 <0.2 68.6 <0.08 2.1 <6.3 0.39 j 2.8 0.0012 <50 0.046 j 0.726 300 <0.2 0.21 j 1.9 <0.25 0.421 <0.5 2.42 0.0506 12.9 <0.1 <1 0.038 MW-05BR SB (0-2) 04/23/2015 17400 <0.5 0.82 166 0.2 43.4 <0.08 1.37 <6.2 15.8 2.1 0.0087 15400 3.3 1.18 31.5 <0.2 <0.5 4.9 0.31 0.29 0.25 j 2.4 0.0196 6 0.091 j 40.1 0.0852 MW-05BR SB (10-12) 04/23/2015 108000 <0.5 7.6 854 7.4 52.4 0.08 12.8 16.6 162 52 0.117 161000 37 13.9 1980 0.09 j 0.24 j 61.6 <0.24 1.5 1.8 5.31 0.193 6.3 0.34 411 0.255 MW-06BR SB (0-2) 05/30/2015 12500 <0.5 1.7 350 0.85 60.1 <0.08 0.979 5.1 j 13.3 6.1 0.0123 12500 8.2 2.38 313 0.038 j 0.13 j 6 <0.23 0.394 1.6 9.36 0.0199 16.4 0.068 j 40.8 0.112 MW-09 SB (0-2) 04/25/2015 16400 0.21 j 3.6 532 0.29 266 0.028 j 0.483 <6.3 12.1 3.1 0.0107 26000 8.3 0.953 42.7 <0.2 0.51 4 <0.25 1.27 0.32 j 3.54 0.0127 7.7 0.14 25.6 0.328 MW-09 SB (2-3) 04/25/2015 9070 0.27 j 4.3 241 0.73 88.9 0.032 j 0.496 <5.4 3.9 15.9 0.0047 10800 5.5 1.01 173 <0.2 2.1 5.5 <0.22 1.23 0.42 j 4.91 0.01 6.6 0.049 j 10.2 0.0888 MW-09 SB (6-7) 04/25/2015 11600 <0.5 0.93 228 0.4 72.4 0.053 j 1.02 <5.8 6.3 2 0.0059 10100 6.3 1.47 175 <0.2 3.5 2.8 <0.23 1.92 <0.5 4.9 0.0192 4.7 0.045 j 10.8 0.0747 MW-09 SB (16-17) 04/25/2015 10200 <0.5 0.32 j 189 0.22 61.7 <0.08 0.889 <5.5 4.7 0.88 0.0036 8210 1.7 0.802 36.3 <0.2 0.28 j 2.1 <0.22 1.44 <0.5 3.05 0.0115 4.4 0.032 j 9 0.0509 MW-IOBR SB (0-2) 04/08/2015 7460 <2.5 1.1 j 206 0.41 74 <0.4 1.1 <5.6 10.7 4.7 0.011 8770 6.7 0.651 350 <0.6 <2.5 3.8 0.26 0.264 <2.5 1.57 0.0158 4 <0.5 27.5 0.13 MW-S0BR SB (8-9) 04/08/2015 1720 <0.5 0.16 j 148 0.075 j 57.9 <0.08 0.902 <6.1 1.9 0.86 0.0032 1520 0.88 0.37 64.9 <0.6 <0.5 1.6 <0.24 0.0917 <0.5 1.39 0.0128 5.2 <0.1 5 0.0461 MW-12 BR SB (11-12) 02/24/2015 9630 <0.5 3 666 3 11.4 0.089 13.3 8.6 8 13.5 0.0255 8290 27.7 10.8 560 0.6 <0.5 11.7 0.45 0.204 1.2 11 0.153 9.5 <0.1 154 0.0393 MW-15 SB (0-2) 04/01/2015 16300 <0.5 1.1 248 0.64 148 0.034 j 2.5 <6.1 17.4 3.1 0.0096 14600 4.5 3.1 ISO 0.08 j <0.5 8.1 <0.24 0.604 0.42 j 10.1 0.0356 36.6 0.1 31.4 0.189 MW-15 SB (7-9) 04/01/2015 11500 <0.5 1.3 334 0.76 57.7 0.034 j 3.62 3.2 j 10.7 3.6 0.0116 7510 6.2 3.89 126 0.13 j 0.2 j 6.2 0.29 0.542 0.53 10.3 0.0519 14.3 0.071 j 35.5 0.088 MW-15 SB (18-19) 04/01/2015 40900 <0.5 2.8 379 1.4 80 0.056 j 1.32 <6 29.1 10 0.0284 26400 16.3 1.93 417 0.05 j 0.18 j 15.3 <0.24 1.42 0.35 j 2.31 0.0234 4.4 0.19 93.2 0.199 MW-15 SB (35-36) 04/07/2015 1160 <0.5 0.87 130 0.15 j 32.9 <0.08 1.12 <5.5 1.3 1.9 0.0076 802 2.1 0.503 41.8 <0.6 0.18 j 1.4 <0.22 0.267 <0.5 1.77 0.0126 3.5 <0.1 2.8 0.0358 MW-16 SB (0-2) 04/28/2015 31900 <0.5 2.3 425 0.59 129 0.52 1.35 <7.1 14.9 5.5 0.0098 19600 8.3 2.52 405 <0.2 0.14 j 9.6 <0.28 1.31 0.4 j 3.11 0.0209 7.1 0.2 41.2 0.18 MW-16 SB (4-6) 04/28/2015 205000 <0.5 6.7 2350 4 79.9 0.11 10.3 14 96.7 38.2 0,0519 160000 84.2 24.6 427 0.21 0.11 j 73.7 <0.24 2.66 1.6 25 0.191 9.1 1.2 275 0.388 MW-16 SB (13-15) 04/28/2015 28200 <0.5 2.2 256 1.3 58.5 <0.08 2.04 <6.4 19.6 7.2 0.0132 13300 7.7 1.71 66.1 <0.2 <0.5 11.5 <0.26 0.969 0.28j 2.71 0.0293 6.1 0.076j 60.8 0.0941 MW-17BR SB (0-2) 06/29/2015 4600 <5 <5 22.2 j <2 50.4 <0.8 0.715 <6 3.7 j <5 0.0047 j 3320 2.8 0.502 29.5 <0.2 <5 13.1 0.62 0.324 j <5 1.65 0.0055 8 <1 8.3 j <0.05 MW-17BR SB (2-3) 03/06/2015 17400 <2.5 <2.5 590 2.5 <25 <0.4 10.6 11.7 15.6 4.6 0.0328 16300 12.1 3.17 548 <0.6 <2.5 10 <0.24 0.259 <2.5 1.6 0.127 6.7 <0.5 64 0.0603 MW-20 SB(0-2) 05/13/2015 78300 <0.5 4.8 537 2 104 0.084 5.34 <6.2 108 33.9 0.101 104000 36.7 10.7 2540 <0.2 0.32j 36 <0.25 1.1 1.7 2.17 0.0801 6.7 0.41 218 0.289 MW-20 SB (5-6) 05/13/2015 74700 <0.5 4.5 698 2.3 67.3 0.079 j 4.12 <5.9 80.7 27.3 0.0912 98100 34.5 7.33 2970 <0.2 0.32 j 30.2 <0.24 1.08 1.3 2.26 0.0657 5.8 0.34 216 0.274 MW-20 SB (24-25) 05/13/2015 16700 <0.5 1.1 308 0.72 107 0.033 j 2.03 <6.2 24.2 4.6 0.0103 8330 5.3 3.15 189 <0.2 0.81 6.1 <0.25 1.88 0.42 j 3 0.0284 4.7 0.062 j 48 0.118 MW-21 SB (0-2) 06/18/2015 406 j <5 j 10.9 j 11.8 j j <2 j 75.5 j <0.8 j 1.88 j <7.9 j <5 <5 0.0032 j 724 2.5 0.37 45.8 0.14 j <5 <5 1.1 1 2.5 j 5.44 0.0122 1 16.4 0.3 j <10 <0.05 MW-21 SB (5-6) 04/21/2015 116 <0.5 <0.5 278 0.13 j 57 <0.08 1.56 <5.6 0.33 j 3.2 0.0017 16.5 j 0.26 0.234 255 <0.2 <0.5 1.8 0.23 0.602 <0.5 0.424 0.0432 11.4 <0.1 <1 0.0778 MW-21 SB (9-11) 04/21/2015 49.2 <0.5 <0.5 204 0.22 108 0.056 j 2.02 <5.7 1 0.39 j 10.9 0.003 15.2 j 0.078 j 0.806 554 <0.2 <0.5 2.5 0.26 0.497 10.5 1.97 0.0517 14.3 <0.1 <1 0.127 Prepared by: BER/MAH Checked by: RLP Notes: 0 - Bold highlighted concentration indicates exceedance of the 15A NCAC 02L Standard, Appendix 2, April 1, 2013. Synthetic Precipitation Leaching Procedure, USEPA Method 1312 mg/I = milligrams per liter ug/I = microgram per liter NE = Not established j = indicates concentration reported below Practical Quantitation Limit (PQL), but above Method Detection Limit (MDL) and therefore concentration is estimated. < = concentration not detected at or above the reporting limit. * - Interim Maximum Allowable Concentrations (IMACs) of the 15A NCAC 02L Standard, Appendix 1, April 1, 2013. bgs = depth below ground surface P:\Duke Energy Progress.1026\503. Cape Fear Ash Basin GW Assessment\3.11 CSA Reporting\Tables\Table BA Leaching Properties of Soil.xlsz Page 1 of 1 TABLE 8-5 WHOLE ROCK METAL OXIDE ANALYSIS OF SOIL CAPE FEAR STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, MONCURE, NC Sample ID (bgs) Type Al2O3 BaO CaO Cr2O3 Fe2O3 K2O Mg0 MnO Na2O P2O1 S'02 SrO TiO2 V2O5 LOI % % % % % % % % % % % % % % % ABMW-1(SB 39-41) Clayey silt 21.08 0.05 0.38 0.04 6.26 1.66 3.28 0.15 1.04 0.26 65.92 <0.01 0.76 0.01 2.29 ABMW-2(SB 27-28) Saprolite with coal and weathered mudstone 27.20 0.05 0.31 0.03 3.56 2.70 2.33 0.10 0.17 0.12 31.64 0.01 0.81 0.01 21.68 ABMW-3BR(63-64) Mudstone 18.62 0.06 2.07 <0.01 11.95 1.66 1.12 0.07 0.85 0.16 54.37 0.01 0.59 <0.01 4.93 MW-6BR(SB 36-37) Sandstone, Arkosic Conglomerate 15.12 0.04 2.95 0.02 4.50 0.89 1.08 0.08 1.71 0.06 69.82 0.04 0.57 <0.01 1.98 MW-6BR(SB 26-27) Sandstone, Arkosic Con lomerate 16.71 0.04 2.59 0.03 4.80 0.95 1.02 0.09 1.75 0.20 69.28 0.03 0.48 <0.01 3.48 MW-9BR(29-29.5) Sandstone 18.3 0.03 1.92 <0.01 2.59 0.87 0.51 0.05 1.58 0.02 64.95 0.03 0.45 <0.01 2.33 MW-9BR(23.5-24) Mudstone 21.71 0.05 1.05 <0.01 6.23 1.56 1.1 0.03 1.28 0.03 56.09 0.02 0.65 <0.01 3.93 MW-9BR(35-36) Sandstone, Graywacke 19.51 0.04 2.43 <0.01 5.22 0.94 1.17 0.07 1.55 0.11 61.26 0.03 0.6 <0.01 2.46 MW-15(SB 35-36) Mudstone, weathered 16.78 0.06 1.57 <0.01 8.16 1.07 1.23 0.03 0.64 0.95 65.54 <0.01 0.55 0.02 4.77 MW-15(SB 18-19) Sand 8.96 0.05 1.51 <0.01 3.77 1.32 0.68 0.06 1.03 0.06 80.71 0.02 0.59 0.01 1.29 MW-15BR(73-74) Sandstone 18.32 0.08 1.15 0.01 7.17 0.91 1.58 0.13 0.74 0.16 64.43 0.01 0.59 0.03 5.47 MW-15BR(58-59) Mudstone 15.23 1 0.06 1 0.43 0.01 1 5.67 0.69 1 1.12 0.03 0.82 1 0.04 71.30 1 <0.01 0.63 1 0.02 3.68 Prepared by: DZH Checked by: KDF Notes: % = percent < = concentration not detected at or above the reporting limit bgs = depth below ground surface P:\Duke Energy Progress. 1026\103. Cape Fear Ash Basin GW Assessment\1.11 CSA Reporting\Tables\Table 8-5 Whole Rock Metal Oxide Analysis of Soils.xlsx Page 1 of 1 TABLE 8-6 WHOLE ROCK ELEMENTAL ANALYSIS OF SOIL CAPE FEAR STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, MONCURE, NC Sample ID (b9s) Type As Cd Ce Co Cu Ga La Mo Ni Pb Sb Se Sn W Zn Zr ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ABMW-1(SB 39-41) Clayey silt 4 <0.2 135 40 16 11 2 7 56 9 <1 <1 1 <1 32 19 ABMW-2(SB 27-28) Saprolite with coal and weathered mudstone 34 <0.2 328 25 91 20 <1 5 43 13 4 1 3 <1 85 53 ABMW-3BR(63-64) Mudstone 6 <0.2 72 15 27 17 30 4 19 36 5 <1 1 <1 106 66 MW-6BR(SB 36-37) Sandstone, Arkosic Conglomerate 2 <0.2 8 11 12 14 19 1 9 12 <1 <1 1 <1 76 20 MW-6BR(SB 26-27) Sandstone, Arkosic Conglomerate 2 <0.2 7 9 9 15 18 <1 11 11 <1 <1 1 <1 67 16 MW-9BR(29-29.5) Sandstone 2 <0.2 55 7 11 16 22 2 7 17 1 <1 2 3 137 25 MW-9BR(23.5-24) Mudstone 3 <0.2 37 12 11 21 16 3 10 19 2 <1 2 1 123 46 MW-9BR(35-36) Sandstone, Graywacke 2 0.4 55 14 12 19 22 2 12 17 3 <1 2 <1 94 31 MW-15(SB 35-36) Mudstone, weathered 8 <0.2 62 19 45 16 30 4 51 16 2 <1 2 <1 88 57 MW-15(SB 18-19) Sand 2 <0.2 39 21 13 9 17 1 13 15 <1 1 <1 121 41 26 MW-15BR(73-74) Sandstone 9 <0.2 65 22 43 19 29 2 32 20 1 2 2 <1 118 41 MW-15BR(58-59) Mudstone 5 <0.2 58 18 32 13 26 2 27 18 2 <1 2 <1 88 35 Prepared by: DZH Checked by: KDF Notes: ppm = parts per million < = concentration not detected at or above the reporting limit. bgs = depth below ground surface P:\Duke Energy Progress. 1026\103. Cape Fear Ash Basin GW Assessment\1.11 CSA Reporting\Tables\Table 8-6 Whole Rock Elemental Analysis of Soil.xlsx Page 1 of 1 TABLE 9-1 SEDIMENT ANALYTICAL RESULTS CAPE FEAR STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, MONCURE, NC Analytical Parameter Percent Moisture pH at 25 Degrees C Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chloride Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury Molybdenum Nickel Nitrate (as N) Potassium Selenium Sodium Strontium Sulfate Thallium Total Organic Carbon Vanadium Zint Reporting Units % S.U. m9/k9 m9/kg m9/k9 Mg/kg m9/k9 mg/kg Mg/kg m9/kg m9/kg mg/kg m9/k9 m9/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg Mg/kg mg/kg mg/kg m9/k9 mg/kg mg/kg m9/kg mg/kg mg/kg Soil RSL- Industrial Health NE NE 110000 47 3 22000 230 23000 98 NE NE NE 35 4700 82000 Soo NE 2600 4 580 2200 NE NE 580 NE 70000 NE 1.2 NE 580 35000 Soil RSL - Residential Health NE NE 7700 3.1 0.68 .00 16 1600 7A NE NE NE 2.3 310 .00 400 NE 180 0.94 39 150 NE NE 39 NE 4700 NE 0.078 NE 39 2300 Soil RSL - Protection of Groundwater NE NE NE 0.27 0.29 82 3.2 NE NE NE NE 180000 NE 46 NE 14 NE NE 0.1 NE NE NE NE 0.26 NE NE NE 0.14 NE NE NE Sample ID Sample Collection Date Analytical Results 5-04 06/11/2015 88.9 6.8 10600 <45.8 45.8j 235 6.8 187 <5.5 9650 <435 8.9j 87.8 39.4 193000 <45.8 2820 1450 0.051j <22.9 66.7 <43.5 <2290 <45.8 <2290 98.7 2671 <45.8 166000 30.91 524 5-09 05/20/2015 88.4 6.4 2390 <44.4 <44A 23.9 2.3 86.2j <5.3 6500 <2200 <11.1 158 10.61 11200 <44.4 1490 277 0.068 <22.2 76.2 <220 <2220 <33.3 <2220 47.5 1660j <44.4 200000 <44.4 51.8 5-10 06/11/2015 74.8 7.0 19000 <19.9 <19.9 ISO 1.2 <49.7 <2.4 3740 <200 25.6 41 27.5 29600 15.1j 2930 606 0.056 <9.9 18 <20 <993 <19.9 <993 41.2 1051 <19.9 47600 62 106 5-16 05/28/2015 55.5 2.9 2660 <11.2 230 34.4 0.461 160 <1.3 647 <567 2.3 j <11.2 12.1 34SO00 <11.2 317 54.8 0.024 <5.6 <2.8 <56.7 1190 <11.2 <559 16.1 <567 <11.2 19500 25.1 20.7 5-16 06/11/2015 58A 3.6 3670 <11.5 237 18.5 0.82 38 <1.4 984 <606 21 14.3 <2.9 420000 <11.5 386 143 0.02 <5.7 29.5 <60.6 585 <11.5 <2300 21.7 4680 <11.5 50400 15.3 73.9 SW-85DS 06/11/2015 63.8 6.7 10100 <14.1 <14.1 80.2 0.65j <35.3 <1.7 1950 <135 15.3 23.2 13.9 30200 10.21 2050 267 0.035 <7.1 11.1 <13.5 <705 <14.1 <705 19.8 75.11 <14.1 34800 42.7 56.2 SW-BA1 05/20/2015 39 6.1 5520 <8.4 <8.4 46.2 0.261 <21 <1 669 <410 5.2 <8.4 7.4 12600 8.21 728 223 0.02 <4.2 2.3 <41 <420 <6.3 <420 8.4 <410 <8.4 11000 12.6 17.3 SW-BA2 05/20/2015 68.3 5.0 10200 <16.4 <16.4 127 0.62 j 25.6 j <2 1010 <760 23.3 12.8 j 61.1 33900 11.2 j 1300 502 0.057 <8.2 14.5 <76 <818 <12.3 <818 12.3 <760 <16.4 198000 34.6 46.2 SW-BBI 05/20/2015 23.4 5.9 1660 <6.4 <6.4 13.9 <0.32 <16.1 <0.77 226 <321 1.4 j <6.4 2 3640 <6.4 215 32.6 0.0067 j <3.2 0.87 j <32.1 <322 <4.8 <322 1.9 j <321 <6.4 1060 3.4 j 7.8 SW-CFDG 05/28/2015 62.7 6.4 11700 <13.2 <13.2 Its 0.45 j 18.8 j <1.6 1510 <678 21 12.4 j 18.8 20700 14.1 1830 1020 0.078 <6.6 7.9 <67.8 385 j <13.2 <662 15.1 <678 <13.2 26300 41.9 60.8 SW-CFDG 06/11/2015 32.8 6.2 8270 <7.5 <7.5 69.4 0.3j <18.8 <0.9 875 <365 47 11.6 17.1 15500 13.3 1300 537 0.055 <3.8 6.2 <37.1 2711 <7.5 <376 9.9 <365 <7.5 15500 38.5 42.6 SW-CFDG DUP 06/11/2015 34 6.0 6120 <7.6 <7.6 46 0.21j <19 <0.91 603 <373 24.3 8.5 10.1 12200 8.5 918 300 0.03 <3.8 4.3 <37.3 1931 <7.6 <381 7 <373 <7.6 20600 31.6 29A SW-DEEPR 05/28/2015 47.8 6.4 6470 <9.3 -9.3 58.7 0.261 <23.3 <1.1 917 <470 8.9 7.8j 9.6 11200 7.21 1020 459 0.06 <4.7 4.1 <47 <467 <9.3 <467 8.7 <470 <9.3 18000 23.8 25.3 SW -HAW 05/28/2015 39.6 7.4 3890 <8.5 <8.5 45.3 <0.43 <21.4 <1 510 <418 16.6 6.6j 6.7 10000 5.9j 726 731 0.026 <4.3 3 <41.8 <427 <8.5 <427 5.4 <418 <8.5 4210 24.6M SW-HAW 06/11/2015 31.2 6.0 3620 <7 <7 37.1 <0.35 <17.5 <0.84 481 <364 16 5.9 j 5.6 8810 5.1 j 660 503 0.018 <3.5 3.2 <36.4 <350 <7 <350 5.6 <364 <7 8620 21.3 SW-SHD-56 05/19/2015 41.9 6.4 13600 <8.2 <8.2 123 0.66 <20.4 <0.98 1030 <423 44.6 22.6 24.3 30600 17.7 2200 1550 0.12 <4.1 7.9 <42.3 3931 <6.1 <408 13.5 <423 <8.2 29800 66.9 SW-SHD-PLANT 05/19/2015 41.2 6.1 6780 <8.6 <8.6 74.6 0.56 <21.5 1 1010 <415 18.2 7.3j 11.6 11500 6.71 1440 380 0.023 <4.3 5.6 <41.5 4221 <6.4 <430 12.7 <415 <8.6 6930 20.2 HD-REF Pt 05/20/2015 51.7 617710 <10.2 <10.2 101 0.49j <25.5 <1.2 1320 <504 8.8 9j 12.5 15600 9.21 2390 358 0.024 <5.1 9.8 <50.4 428j <7.6 <509 14.3 <504 <10.2 15600 14.5-UNT ./19/2015 36.9 6.8 5900 <8.2 <8.2 120 0.97 24.9 <0.99 40300 <391 15 21.4 14.2 29500 8.5 1210 1200 0.014 2.4j 5.4 <39.1 <411 <6.2 3621 104 <391 <8.2 4240 41.3 Prepared by: RKD Checked by: RLP Notes: Bold color highlighted concentrations indicate highest exceedance of the EPA Mid -Atlantic Risk Assessment regional screening levels for soil, June 2015, for the category listed below: O - Soil RSL - Industrial Health 0 - Soil RSL - Residential Health - Soil RSL - Protection of Groundwater = Percent mg/kg = milligrams per kilogram NE = Not established S.U. = Standard Units CUP = Duplicate j = indicates concentration reported below Practical Quantitation Limit (PQL), but above Method Detection Limit (MDL) and therefore concentration is estimated. < = concentration not detected at or above the reporting limit. P:\Duke Energy Progress.1026\103. Cape Fear Ash Basin GW Assessment\1.11 CSA Reporting\Tables\Table 9-1 Sediment Analytical Results.xlsx Page 1 of 1 TABLE 9-2 SEEP ANALYTICAL RESULTS CAPE FEAR STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, MONCURE, NC Aluminum Aluminum Antimony Antimony Arsenic Arsenic Barium Barium Beryllium Beryllium Bi- Boron Boron Cadmium Cadmium Calcium Carbonate Chromium Chromium Cobalt Cobalt Copper Copper Iron Iron Analytical Parameter Redox Assignment PH Temp Spec Cond DO ORP Eh Turbidity Alkalinity carbonate Alkalinity Alkalinity Chloride DIS TOT DIS TOT DIS TOT DIS TOT DIS TOT DIS TOT DIS TOT TOT DIS TOT DIS TOT DIS TOT DIS TOT Reporting Units None S.U. Deg C u��ms mg/l mV mV NTU mg/I ug/I ug/I ug/I ug/I ug/I ug/I ug/l ug/I ug/I ug/I mg/I ug/l ug/I ug/I ug/1 mg/I mg/I mg/I ug/I ug/I ug/I ug/I mg/I mg/I ug/I ug/I 15A NCAC 02L Standard NE 6.5-8.5 NE NE NE NE NE NE NE NE NE NE 1* NE SO NE 700 NE 4* NE NE 700 NE 2 NE NE 250 NE SO NE 1* NE 1 NE 300 15A NCAC 02B Standard NE 6-9 NE I NE NE I NE NE NE NE NE NE NE NE NE 10 NE NE 6.5 NE NE NE I NE 1 0.15 NE NE NE 230 24 NE NE NE 0.0027 1 NE I NE NE Sample Sample ID Collection Field Parameter Analytical Results Date S-04 06/11/2015 Anoxic 7.0 21 768 0.2 -279 -74 NM 180 70 134000 <1 -10 1.011 408 79 3620 <1 .13.1 180 5050 6730 <1 29.4 148 -10 22 <1 69.4 <1 763 0.00117 0.467 30300 3100000 S-09 05/20/2015 Mixed (oxic-anoxic) 6.8 24 508 2.9 -286 -81 18.7 110 10 132 <1 <1 <1 <1 51 56 <1 <1 110 3710 3790 <1 <1 36.9 <10 21 <1 <1 <1 1.4 <0.001 <0.001 297 596 5-10 06/11/2015 Mixed (oxic-anoxic) 7.0 23 431 0.7 -202 3 148 130 178 2740 <1 <1 1.36 2.64 57 119 <1 <1 130 1540 1530 <1 <1 18.7 <10 32 <1 1.91 1.14 3.2 <0.001 0.00265 1950 15600 S-16 05/28/2015 Mixed (oxic-anoxic) 2.7 24 3512 8.47 380 585 406 '10 5250 6240 <1 <1 47.6 200 19 37 20.4 20.8 <10 596 619 1.09 1.12 333 <10 13 <1 <1 287 300 <0.001 <0.001 240000 286000 S-16 06/11/2015 Anoxic 2.9 24 2700 0.39 270 475 55.6 <10 7050 3760 <1 <1 19.9 118 19 21 31.4 14.4 <10 724 553 <1 <1 314 <SO 10 <1 <1 361 272 0.00104 0.00106 249000 257000 Prepared by: BER Checked by: RKD Notes: - Bold highlighted concentration indicates exceedance of the 15A NCAC 02L Standard, Appendix 2, April 1, 2013. - - Bold highlighted concentration indicates exceedance of the 15A NCAC 02B Standard, April 22, 2015. Deg C = Degree Celsius NTU = nephelometric turbidity unit Temp = Temperature mg/I = milligrams per liter S.U. = Standard Unit ORP = Oxidation Reduction Potential mV = millivolts Spec Cord = Specific Conductance DIS = Dissolved NE = Not established ug/I = microgram per liter TOT = Total NM = Not Measured umhos/cm = micro mhos per centimeter DO = Dissolved Oxygen < = concentration not detected at or above the reporting limit. mg-N/L= milligrams of nitrogen per liter * - Interim Maximum Allowable Concentrations (IMACs) of the 15A NCAC 02L Standard, Appendix 1, April, 1, 2013. P:\Duke Energy Progress. 1026\103. Cape Fear Ash Basin GW Assessment\1.11 CSA Reporting\Tables\Table 9-2 Seep Analytical Results Page I of 2 TABLE 9-2 SEEP ANALYTICAL RESULTS CAPE FEAR STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, MONCURE, NC Analytical Parameter Lead Lead Magnesium Manganese Manganese Mercury Methane Molybdenum Molybdenum Nickel Nickel Nitrate (as N) Potassium Selenium Selenium Sodium Strontium Strontium Sulfate Sulfide Thallium Thallium Total Dissolved Solids Total Organic Carbon Total Suspended Solids Vanadium Vanadium Zinc Zinc DIS TOT TOT DIS TOT TOT DIS TOT DIS TOT TOT DIS TOT TOT DIS TOT DIS TOT DIS TOT DIS TOT Reporting Units ug/1 ug/I mg/I ug/1 ug/I ug/l ug/I ug/I ug/I ug/I ug/I mg-N/L mg/I ug/I ug/I mg/I mg/I mg/I mg/I mg/I ug/I ug/I mg/I mg/I mg/I ug/I ug/I mg/I mg/I 15A NCAC 02L Standard NE 15 NE NE 50 1 NE NE NE NE 100 SO NE NE 20 NE NE NE 250 NE NE 0.2* Soo NE NE NE 0.3* NE 1 15A NCAC 02B Standard 0.54 NE NE NE NE 0.012 NE NE NE 16 25 10 NE NE 5 NE NE NE 250 NE NE NE 500 NE NE NE NE 0.036J�NE Sample ID Sample Collection Date Analytical Results S-04 06/11/2015 <1 76.2 59 1770 27100 0.00682 180 1.04 <10 3.48 519 <0.01 2.39 <1 10.6 39.6 0.405 1.97 150 <0.1 <0.2 5.13 51 93 15000 <0.3 217 0.013S-09 05/20/2015 <1 <1 59 2260 2360 0.00267 42 <1 <1 4.06 4.29 0.041 1.19 <1 <1 30.6 0.301 0.315 99 <0.5 <0.2 <0.2 360 7.5 180 <0.3 0.739 <0.0055-10 06/11/2015 <1 1.95 59 3070 3910 0.0105 S10 <I <1 1.63 2.67 <0.01 2.87 <1 <1 47.1 0.152 0.167 19 <0.2 <0.2 <0.2 <25 24 940 1.95 9.31 0.015 S-16 05/28/2015 <1 <1 59 21200 21200 0.000939 <10 <1 7.24 230 251 0.018 30.4 1.71 <1 28.9 5.27 5.36 2300 <0.1 0.485 0.505 2500 1.2 2500 0.313 8.74 0.659 S-16 06/11/2015 <1 <1 59 25400 18800 <0.001 13 <1 2.99 352 206 <0.01 31.2 <1 <1 28 6.28 5.01 2700 <0.5 0.255 0.417 2600 0.976 190 <0.3 3.090.802 Prepared by: BER Checked by: RKD Notes: C- Bold highlighted concentration indicates exceedance of the 15A NCAC 02L Standard, Appendix 2, April 1, 2013. - Bold highlighted concentration indicates exceedance of the 15A NCAC 02B Standard, April 22, 2015, Deg C = Degree Celsius NTU = nephelometric turbidity unit Temp = Temperature mg/I = milligrams per liter S.U. = Standard Unit ORP = Oxidation Reduction Potential mV = millivolts Spec Cond = Specific Conductance DIS = Dissolved NE - Not established ug/I = microgram per liter TOT = Total NM = Not Measured umhos/cm = micro mhos per centimeter DO = Dissolved Oxygen < = concentration not detected at or above the reporting limit. mg-N/L= milligrams of nitrogen per liter " - Interim Maximum Allowable Concentrations (IMACs) of the 15A NCAC 02L Standard, Appendix 1, April, 1, 2013. P:\Duke Energy Progress. 1026\103. Cape Fear Ash Basin GW Assessment\1.11 CSA Reporting\Tables\Table 9-2 Seep Analytical Results Page 2 of 2 TABLE 9-3 SURFACE WATER ANALYTICAL RESULTS CAPE FEAR STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, MONCURE, NC Analytical Parameter Redox Assignment pH Temp Spec Cond DO ORP Eh Turbidity Alkalinity Aluminum Aluminum Antimony Antimony Arsenic Arsenic Barium Barium Beryllium Beryllium Bi carbonate Alkalinity Boron Boron Cadmium Cadmium Calcium Carbonate Alkalinity Chloride Chromium Chromium Cobalt Cobalt Copper Copper DIS TOT DIS TOT DIS TOT DIS TOT DIS TOT DIS TOT DIS TOT DIS TOT DIS TOT DIS TOT Reporting Units None S.U. Deg C u/cm mg/l mV mV NTU mg/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l mg/l ug/l ug/l ug/l ug/l mg/1 mg/I mg/I ug/l ug/l ug/l ug/l mg/1 mg/l SSA NCAC 02B Standard NE 6-9 NE NE NE NE NE NE NE NE NE NE NE NE 10 NE NE 6.5 NE NE NE NE 0.15 NE NE NE 230 24 NE NE NE 0.0027 NE Sample ID Sample Collection Date Field Parameters Analytical Results SW-85DS 06/11/2015 Anoxic 6.9 23 139 0.4 -205 0 NM 100 106 51400 <1 <1 1.57 5.56 73 524 <1 2.56 100 2120 2170 <1 <1 25.1 <10 31 <1 40.4 <1 60.1 <0.001 0.055 SW-BAI 05/20/2015 Mixed (oxic-anoxic) 6.5 20 370 7 -58 147 75.5 27 182 1600 <1 <1 1.04 1.54 70 84 <1 <1 27 <50 <50 <1 <1 13.8 <10 73 <1 <1 2.25 2.67 0.00159 0.00166 SW -BAT DUP 05/20/2015 Mixed (oxic-anoxic) 6.5 20 370 7 -58 147 75.5 26 167 1810 <1 <1 1.06 1.58 69 88 <1 <1 26 <50 <50 <1 <1 13.8 <10 72 <1 <1 2.08 2.79 0.00126 0.00167 SW-BA2 05/20/2015 Mixed (oxic-anoxic) 7.0 21 258 1.71 -220 -15 58.4 45 126 685 <1 <1 1.17 1.92 50 77 <1 <1 45 358 361 <1 <1 10.6 <10 12 <1 <1 3.53 4.6 0.00201 0.00193 SW-BBI 05/20/2015 Mixed (oxic-anoxic) 6.6 19 91 6.3 39 244 37.6 20 200 843 <1 <1 <1 <1 29 35 <1 <1 20 <50 <50 <1 <1 4.99 <10 9.6 <1 <1 <1 <1 0.00128 0.00117 SW-CFDG 05/28/2015 Mixed (oxic-anoxic) 7.1 26 169 7.63 144 349 14.8 38 75 236 <1 <1 <1 <1 20 24 <1 <1 37 <50 <50 <1 <1 9.04 <10 17 <1 <1 <1 <3 0.00138 0.00193 SW-CFDG 06/11/2015 Mixed (oxic-anoxic) 6.6 27 171 7.41 1 87 292 18.4 34 153 298 <1 <1 <1 <1 19 23 <1 <1 34 <50 <50 <1 <1 7.99 <10 16 <1 <1 <1 <1 0.00177 0.00187 SW-CFDG DUP 05/28/2015 Mixed (oxic-anoxic) 7.4 26 168 7.56 87 292 22.8 38 72 199 <1 <1 <1 <1 19 24 <1 <1 37 <50 <50 <1 <1 9.05 <10 17 <1 <1 <1 <3 0.00207 0,00208 SW-CFDG DUP 06/11/2015 Mixed (oxic-anoxic) 6.7 26 176 7.29 95 300 16.7 33 153 266 <1 <1 <1 <1 19 24 <1 <1 33 <50 <50 <1 <1 8.07 <10 16 <1 <1 <1 <1 0.00195 0.00179 SW-DEEPR 05/28/2015 Mixed (oxic-anoxic) 7.1 25 168 7.67 81 286 14.5 39 96 257 <1 <1 <3 <1 21 24 <1 <1 39 <50 <50 <1 <1 9.19 <10 17 <1 <1 <1 <3 <0.001 0.002 SW-DEEPR 06/11/2015 Mixed (oxic-anoxic) 7.1 27 150 6.66 69 294 16.6 27 198 346 <1 <1 <1 <1 19 21 <1 <1 27 <50 <50 <1 <1 7.37 <10 14 <1 <1 <1 <1 0.00224 0.002 SW -HAW 05/28/2015 Mixed (oxic-anoxic) 7.1 24 162 8.43 73 278 9.44 35 43 137 <1 <1 <1 <1 20 24 <1 <1 35 <50 <50 <1 <1 8.55 <10 17 <1 <1 <1 <1 <0.001 0.00174 SW -HAW 06/11/2015 Oxic 7.0 25 202 6.34 105 0 10 40 16 88 1.26 <1 <1 <1 22 25 <1 <1 40 63 50 <1 <1 9.33 <10 21 <1 <1 <1 <1 0.00124 0.00131 SW-SHD-56 05/19/2015 Mixed (oxic-anoxic) 6.7 23 219 3 25 230 20.4 34 112 511 <1 <1 <1 <1 28 33 <1 <1 34 <50 <50 <1 <1 8.74 <10 13 <1 <1 <1 <1 0.00177 0.00181 SW-SHD-PLANT 05/19/2015 Mixed (oxic-anoxic) 6.6 21 301 1 8.4 -199 6 31.3 1 110 1 143 1 348 <1 I <1 1.4 1.74 85 95 <1 <1 110 61 67 <1 <1 15.1 <10 25 <1 1.02 2.51 2.77 0.00201 0.0027 SW-SHD-REF 05/20/2015 Mixed (oxic-anoxic) 6.8 21 159 1 6.3 1 -18 187 187 1 37 247 5070 <1 <1 1.66 3.04 41 87 <1 <1 37 <50 <50 <1 <1 8.21 <10 16 <1 2.12 1.43 3.08 0.00182 0.00336 SW-UNT 05/19/2015 Mixed (oxic-anoxic) 7.3 24 549 6.9 39 237 10.2 83 46 211 <1 <1 <1 1.38 52 57 <1 <1 83 3040 1090 <1 <1 43.6 <10 17 <1 <1 <1 1.06 <0.001 0.00106 Prepared by: BER MEH Checked by: RKD Notes: = - Bold highlighted concentration indicates exceedance of the 15A NCAC 02B Standard, April 22, 2015. Deg C = Degree Celsius Spec Cord = Specific Conductance DUP = Duplicate mV = millivolts umhos/cm = micro mhos per centimeter NTU = nephelometric turbidity unit mg/I = milligram per liter S.U. = standard unit DO= Dissolved Oxygen TOT = Total ORP = Oxidation Reduction Potential ug/L= micrograms per liter < = concentration not detected at or above the reporting limit Dis= Dissolved PADuke Energy Progress. 1026\103. Cape Fear Ash Basin GW Assessment\1.11 CSA Reporting\Tables\Table 9-3 Surface Water Analytical Results Page 1 of 2 TABLE 9-3 SURFACE WATER ANALYTICAL RESULTS CAPE FEAR STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, MONCURE, NC Analytical Parameter Iron DIS Iron TOT Lead DIS Lead TOT Magnesium Manganese Manganese Mercury Methane Molybdenum Molybdenum Nickel Nickel Nitrate as N) Potassium Selenium DIS Selenium TOT Sodium Strontium DIS Strontium TOT Sulfate Sulfide Thallium DIS Thallium TOT Total Dissolved Solids Total Organic Carbon Total Suspended Solids Vanadium Vanadium Zinc Zinc DIS TOT DIS TOT DIS TOT DIS TOT DIS TOT Reporting Units ug/I ug/I ug/I ug/I mg/I ug/1 ug/l ug/I ug/1 ug/I ug/I ug/I ug/I mg-N/L mg/I ug/I ug/l mg/I mg/I mg/I mg/I mg/I ug/l ug/1 mg/I mg/I mg/I ug/I ug/I mg/1 mg/I 15A NCAC 026 Standard NE NE 0.54 NE NE NE NE 0.012 NE NE NE 16 25 10 NE NE 5 NE NE NE 250 NE NE NE Soo NE NE NE NE 0.036 NE Sample ID Sample Collection Date Analytical Results SW-85DS 06/11/2015 3080 94300 <1 35.1 17.9 1710 4340 0.00551 150 <1 <1 1.17 27.4 <0.01 1.96 <1 1.77 55.7 0.141 0.25 76 <0.2 <0.2 0.309 69 19 31000 4.24 107 <0.005 0.231 SW-BA1 05/20/2015 1210 5350 <1 2.47 8.63 3080 3300 0.0026 95 <1 <1 1.18 1.57 0.029 2.84 <1 <1 31.6 0.141 0.147 4.1 <0.5 <0.2 <0.2 260 21 64 0.494 2.33 0.052 0.008 SW-BA1 DUP 05/20/2015 1140 6110 <1 2.57 6.59 3100 3410 0.00124 110 <1 <1 1.12 1.71 0.04 2.91 <1 <1 31.6 0.142 0.15 3.5 <0.5 <0.2 <0.2 250 21 130 0.384 2.31 0.164 0.011 SW-BA2 05/20/2015 2510 8910 8.84 5.66 2470. 3300 0.00262 15 <1 <1 1.55 1.87 0.018 2.01 <1 <S 12.9 0.092 0.1 5.7 <0.1 <0.2 <0.2 150 22 25 1.29 4.31 0.04 0.018 SW-BB1 05/20/2015 561 1930 <1 <1 2.48 43 50 0.00468 26 <1 <1 <1 1.06 0.21 1.24 <1 <1 7.82 0.036 0.038 3.6 <0.1 <0.2 <0.2 82 5 10 0.306 1.39 0.013 <0.005 SW-CFDG 05/28/2015 341 765 <1 <1 3.77 45 137 0.00204 <10 1.28 1.29 <1 <1 0.564 3.66 <1 <1 15.5 0.072 0.074 11 <0.1 <0.2 <0.2 97 6.4 9 1.39 1.96 0.04 <0.005 SW-CFDG 06/11/2015 378 790 <1 <1 3.57 29 126 0.0015 14 1.52 1.4 <1 1.12 0.619 3..76 <1 <1 16.1 0.067 0.065 12 <0.1 <0.2 <0.2 110 7.3 11 1.44 1.59 0.008 <0.005 SW-CFDG DUP 05/28/2015 359 864 <1 <1 3.78 43 131 0.00221 19 1.26 1.3 <1 1.05 0.542 3.69 <1 <1 15.4 0.072 0.078 13 <0.1 <0.2 0.274 91 6.2 14 1.5 1.87 0.016 0.007 SW-CFDG DUP 06/11/2015 377 765 <1 <1 3.59 27 154 0.0014 14 1.4 1.42 <1 1.03 0.674 3.77 <1 <1 16.2 0.067 0.064 12 <0.1 <0.2 <0.2 100 7.3 10 1.42 1.63 JIM 0.191 SW-DEEPR 05/28/2015 468 909 <1 <1 4.02 51 83 0.00241 16 1.09 1.23 <1 <1 0.748 3.98 <1 <1 15.3 0.071 0.072 10 <0.1 <0.2 <0.2 100 6.2 8 1.69 2.17 <0.005 <0.005 SW-DEEPR 06/11/2015 580 997 <1 <1 3.52 47 64 0.0019 19 <1 <1 <1 <1 0.708 3.88 <1 <1 13.2 0.059 0.056 12 <0.1 0.383 <0.2 100 7.4 7 1.71 1.93 0.008 <0.005 SW -HAW 05/28/2015 139 390 <3 <1 3.38 7 186 0.000948 20 1.57 1.56 <1 <1 0.337 3.03 <1 <1 16 0.075 0.076 12 <0.1 <0.2 <0.2 90 6.4 7 0.883 1.41 0.012 <0.005 SW -HAW 06/11/2015 59 294 <1 <1 3.85 <5 208 <0.001 18 2.45 2.54 1.18 1.41 0.298 3.63 <1 <1 22.2 0.083 0.08 16 <0.1 <0.2 <0.2 120 6.3 6 0.698 1.1 <0.005 <0.005 SW-SHD-56 05/19/2015 369 1210 <1 1 <1 1 3.45 3-94 401 1 0.00288 1 21 1.17 <1 <1 11 0.484 4.09 <1 <1 12.8 0.074 0.077 12 <0.1 <0.2 <0.2 100 7.8 14 1.42 2.39 0.009 <0.005 SW-SHD-PLANT 05/19/2015 1150 2530 1 <1 I <1 1 4.91 1 1820 1 1910 1 0.00202 1 31 1 1.22 1.15 1 2.04 1 2.08 1 0.03 36 <1 <1 19.9 0.124 0.13 9 <0.1 <0.2 <0.2 230 37 12 1.32 2.43 0.016 0.014 SW-SHD-REF 05/20/2015 963 9180 <1 3.6 3.61 1 869 1 1150 1 0.00274 1 62 <1 <1 1.31 2.92 0.032 2.13 <1 <1 16.2 0.069 0.082 2 <1 <0.2 <0.2 140 19 150 1.03 7.82 0.021 0.016 SW-UNT 05/19/2015 67 534 <1 <1 19.6 1 3280 1 3420 1 0.000786 1 <10 3.03 2.83 1.89 2.13 0.078 2.56 <1 <1 31.2 1 0.275 0,292 140 <0.1 <0.2 <0.2 350 4.7 8 0.705 1.67 0.006 <0.005 Prepared by: BE MEH Checked by: RLP Notes: _ - Bold highlighted concentration indicates exceedance of the 15A NCAC 02B Standard, April 22, 2015. Deg C = Degree Celsius Spec Cond = Specific Conduc DUP = Duplicate mV = millivolts umhos/cm = micro mhos per NTU = nephelometric turbidity unit mg/I = milligram per liter S.U. = standard unit DO= Dissolved Oxygen TOT = Total ORP = Oxidation Reduction P ug/L= micrograms per liter < = concentration not detected at or above the reporting limit Dis= Dissolved PADuke Energy Progress. 1026\103. Cape Fear Ash Basin GW Assessment\1.11 CSA Reporting\Tables\Table 9-3 Surface Water Analytical Results Page 2 of 2 TABLE 9-4 NC DENR 2014 SEEP ANALYTICAL RESULTS CAPE FEAR STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, MONCURE, NC Analytical Parameter Aluminum Antimony Arsenic Barium Boron Cadmium Chloride Chromium Copper Fluoride Hardness Iron Lead Manganese Molybdenum Nickel Selenium Sulfate Total Dissolved Solids Zinc Reporting Units ug/I ug/I ug/I ug/I ug/I ug/I mg/I ug/I mg/I mg/I mg/I ug/I ug/I ug/I ug/I ug/I ug/I mg/I mg/I mg/I 15A NCAC 02L Standard NE 1* 10 700 700 2 250 10 1 2 NE 300 15 50 NE 100 20 250 500 1 15A NCAC 02B Standard NE NE 10 NE NE NE 230 NE NE 1.8 100 NE NE NE NE 25 5 250 500 NE Sample ID Sample Description Sample Collection Date Analytical Results 2014007219 OUTFALL 001 03/11/2014 42 <1 3.26 65 162 <1 34 <1 <0.005 <1 55.5 185 <1 109 1.43 8.81 1.4 80 199 0.0468 2014007220 Outfall005 03/11/2014 291 14.5 25.9 191 1100 <1 18 <1 <0.005 <1 102 199 <1 99 186 8.77 62.8 92 219 0.0033 2014007221 Outfall007 03/11/2014 2550 <1 2.63 55 453 <1 15 1.64 <0.005 <1 59.2 2580 1.07 865 9.99 4.72 3.44 55 159 0.0221 2014007222 Outfall008 03/11/2014 3440 <1 <1 19 3410 <1 20 <1 <0.005 <1 247 4920 <1 4430 <1 14.6 <1 400 580 0.0327 2014007223 Outfall 008 to Shaddux Creek 03/11/2014 1530 <1 1.08 69 166 <1 11 2.23 <0.005 <1 145 2860 <1 795 <1 3.91 <1 120 301 0.0196 2014007251 1978 South Standing Water 03/11/2014 1600 <1 <1 28 <50 <1 9.7 <5 <0.005 <1 19.6 2680 <1 400 <1 <5 <1 20 99 0.013 2014007257 Standing Water West of RR 03/11/2014 436 <1 1.07 34 2960 <1 19 <5 <0.005 <1 192 2330 <1 2460 <1 5 <1 160 311 0.005 2014007258 85 East of RR 03/11/2014 770 <1 <1 30 640 <1 21 <5 <0.005 <1 120 1990 <1 1950 <1 <5 <1 110 249 0.014 2014008015 SEEP 1956 Pond SW-1 03/18/2014 1350 <1 4.44 531 53 <1 17 6 0.013 <1 290 1540 1.48 6620 <1 6 1.23 240 NA 0.079 2014008016 SEEP 1963 Ash Pond S 03/18/2014 77 <1 39.4 78 1380 <1 35 <5 <0.005 <1 340 2050 <1 1730 101 <5 <1 180 NA <0.005 8017 SEEP South End of 70 AP 03/18/2014 1350 <1 <1 52 412 <1 14 <5 <0.005 <1 55.5 3430 <1 2650 <1 <5 <1 73 NA 0.016 8018 L2O4 SEEP 78 Ash Pond Down Gradient 03/18/2014 1520 <1 <1 30 130 <1 22 <5 0.007 <1 103 418 <1 3790 <1 26 <1 160 NA 0.065 8019 SEEP Corner of 78 & Cooling Tower 03/18/2014 153 <1 <1 21 221 <1 33 <5 <0.005 <1 146 17900 <1 6380 <1 <17 <1 220 NA 0.016 Prepared by: BER/SRW Checked by: RLP Notes• Bold highlighted concentration indicates exceedance of the 15A NCAC 02L Standard, Appendix 2, April 1, 2013. C Bold highlighted concentration indicates exceedance of the 15A NCAC 02B Standard, April 22, 2015. ug/I = micrograms per liter mg/I = milligrams per liter NE = Not established < = concentration not detected at or above the reporting limit. * Interim Maximum Allowable Concentrations (IMACs) of the 15A NCAC 02L Standard, Appendix 1, April, 1, 2013. P:\Duke Energy Progress.1026\103. Cape Fear Ash Basin GW Assessment\1.11 CSA Reporting\Tables\Table 9-4 NCDENR Seep Analytical Results Page 1 of 1 TABLE 9-5 15A NCAC 2B EXCEEDANCES IN SEEPS AND SURFACE WATER CAPE FEAR STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, MONCURE, NC Analytical Parameter pH Arsenic Cadmium Lead Nickel Nickel Selenium Sulfate Total Dissolved Solids Zinc TOT DIS DIS DIS TOT TOT DIS Reporting Units S.U. ug/I ug/l ug/l ug/1 ug/I ug/l mg/I ug/I mg/I 15A NCAC 02B Standard 6-9 10 0.15 0.54 16 25 5 250 500 0.036 Sample ID Sample Collection Date Analytical Results S-04 06/11/2015 BE 408 BE BE BE 519 10.6 BE BE BE S-16 05/28/2015 2.7 200 1.09 BE 230 251 BE 2300 2500 0.659 S-16 06/11/2015 2.9 118 BE BE 352 206 BE 2700 2600 0.802 SW-85DS 06/11/2015 BE BE BE BE BE 27.4 BE BE BE BE SW-BA1 05/20/2015 BE BE BE BE BE BE BE BE BE 0.052 SW-BA1 DUP 05/20/2015 BE BE BE BE BE BE BE BE BE 0.164 SW-BA2 05/20/2015 BE BE BE 1.55 BE BE BE BE BE 0.04 SW-CFDG 05/28/2015 BE BE BE BE BE BE BE BE BE 0.04 SW-CFDG DUP 06/11/2015 BE BE BE BE BE BE BE BE BE 0.059 Prepared by: BER/SRW Checked by: RLP Notes: 0 - Bold highlighted concentration indicates exceedance of the 15A NCAC 02B Standard, April 22, 2015. S.U. = Standard Unit ug/I = micrograms per liter mg/I = milligrams per liter BE = indicates concentration was below (or within range for pH) the 15A NCAC 02B Standard, April 22, 2015. DUP = Duplicate DIS = Dissolved TOT = Total P:\Duke Energy Progress. 1026\103. Cape Fear Ash Basin GW Assessment\l.11 CSA Reporting\Tables\Table 9-5 2B Exceedances in Seeps and Surface Water Page 1 of 1 TABLE 10-1 GROUNDWATER ANALYTICAL RESULTS CAPE FEAR STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, MONCURE, NC ��mmmmmmmmommomm®mmmmm®mmmmmmm®m®mmmmm®m® ��m®m®mm®mmmmmmmmm®mmmm®mm®mmmmmmmmmmmmmm ��mmmmmm®®mmmommmmmm®mmmmmmmmmmmmmmmmmmmm ��mmmmmmmmmmmmm®m®®mmmmmm®m®mmm®mmmmmmmm ��m®mmmm®®mmm®®mm®m®mm®mmm®mmm®mmmmmmmm®m ��m®m®m®mmmmmm®m®mmmmmmmmmm®mmmmmm®mmm®mm ��mmmmmm®mmmm®mm®®mmmm®mmm®®mm®m®ommmmmmm ��mmm®mmmmmmm®mmmmmmmm®m®0®m®m©mmmmmm®mm® ��mmmmmm®®mmmm®m®m®®mm®m®mmmmm®m®m®mmmmmm ��mmmmmm®mmmm®®mmmmmmm®mmmmm®m®mmm®mmmmm ��mmmmm®m®mmmmmm®mmm®mommmmmmmmm®mmmmmmmm ��m®mmmammmmmmmmmm®mmm®mmmm®®®mm®m®mmmmm® ��m®®m®mo®mmmmmm®m®mmmmmmmmmommm®mmmmm®mm ��mmmmm®mmmm®mmm®mmmmm®®mmmmm®mm®m®mmm®mm m�mmmmmmm®®mmmmm®m®mmmmmmmmmmmmm®mmmmmmmm mmmmm®mmmmmmmmm®mmmmm®mmmmm®®mm®m®mmmmmm mmm®m®mmmmmmmmmm®m®mmmmmmmmmmmmm®mmmmmmmm mmm®mmmmmmmmmm®m®mmm®m®mmmmmm®mm®mmmmmmm® mmmm®mmmm®mmm®mmm®m®mmmmmmmmmmm®mmmmmmm® mmmmmmm®mmmmmmm®m®m®m®mmmmmm®mm®m®mmm®m® mmmm®m®mmmmmmmm®m®m®mmmmmmmmmmm®mmmmmmm® mmmmm®mm®mmmmmmmm®m®m®m®mmmmmm®mm®mmmmmmm® mmmm®mmommmmmmm®m®m®mmmmmmmmm®m®mmmmmmmm m�mmmmmmmmmmmmmmmmmmmm®mmmmmm®mm®mmmmmmm® mmm®mmmmmmmmmmmm®m®mmmmmmmmmmm®m®mmmmmmmm mmmmmmm®mmmmmmmmm®mmm®mmmmmm®®m®mmmmmmmm mmmm®mmm®mmmmmm®mmm®mommmmmmmmm®mmmmmmm® mmmm®mmmm®mmm®mmm®mmmmmmmm®m®mm®mmmmmmm® mmm®mmmmm®mmmmommm®mmmmmmmm®om®m®mmmmmmm® mmm®m®mmmmmmmmmmmm®mmm®mmmm®m®®m®m®mmmmmm ��mmmmmmmm®mmmmmmmmmmmmmmmmmommm®mmmmmmm® mmmm®mmm®mm®mmmmmmmmm®®mmmmm®mm®m®mmm®mm m�mmmmmmm®mmmm®mmm®mmmmmm®mmmm®m®mmmmmmm® mmm®m®mmmmmmmmmmmm®mmm®mm®mmm®®m®m®mmmmmm mmm®m®mmmmmmmm®m®mmmmmmmmmmmmmmm®mmmmmmm® ��m®m®mmmmmmmmmm®mmmmmmmmmmmmmmm®mmmmmmmm mmm®mmmm®mmmmmmmmmmmmm®mmmmmm®mm®mmmmmmmm ��m®mmmm®mmmmmmm®m®mmmmmmmmmm®mm®m®mmmmmm ��m®m®mmmmmm®mmm®®mm®®®®mmmmm®®®m®mmmmmm® ��mmmmmm®mmmomm®mmm®mmmmmmmmmmmmm®mmmmm® ���mmm®mm®momomm®®®mmmmmmm®mmmmmmm®mm®mmm mmm®m®mmmm®®mom®m®®mmm®mmm®mmmmm®mmmmmmmm ���®mmmmm®®mmmmm®®®mmmmmmm®®mmmmmm®mmmmmm m�mmmmmmmmm©mmmmm®®mm®®mmm®®mm®mmm®mmmmmm ��mmmmmmmmmmm®®m®mmmmmmm®m®mmmm®mmmmmm®mm m�mmmmmmmmmm®m®®®mmm®mmm®mmmm®m®m®mmmmm® ®mmmmm®mmm®m®momm®m®mmm®mmmmm®m®m®mmmmmmm® ®��mm®®mmm®mm®®®®mmm®m®mmmmm®mmm®mmmmmmmm ��mmmm®mmmmom®mm®m®mmm®mmmmmmm®®mm®mmmmmm ®��mmmmmmmmmmmmm®®®mmm®m®mmmmmmm®®mmm®mm® m�mmmmmmmmmommmm®®®®ommm®®m®mmmmmm®mmmmmm ��mmm®m®®mmmm®o®®mmmm®®mmm®mmmm®®®®mmmm®m ���mmmmm®m®om®mmmmmmmm®mmm®mmm®®mmmmm®®mm ®mmmmmmm®mmmmmm®®mmmmmmmmmmmmmm®m®mmmmmm ®�mmmmmmmmmmmmmm®®mmmm®mmmmm®mmmmm®mmmmmm ®mmmmm®®mmmmmmm®mmmmmmmmmm®mm®mmmmmmmmmm ��®mmmmmmmmmomm®m®®mmmm®®m®mm®m®m®mmmmmm mmmm®mm®mmmm®mmm®®mmm®m®mmmmmm®m®®mm®mm® ��mmmmmm®mmmm®mm®m®mmm®mmm®mmmm®mmmmm®mmm ��mmmmmmmmmomom®mmmmm®®mmmmmmm®®®m®mmmmmm ®mmm®mmmm®mmmm®®®m®mmm®mmmmmmmmm®mmmmmmmm ®��mm®mmmmm®mmm®®m®mm®®mmm®mmmmm®mmmmmmmm m��®mm®mmmmmm®®m®m®omm®m®mmmmmmm®m®mmmmm® mmm®m®mmmmmmm®mm®mmmmm®mmm®mmm®m®m®mmmmmm ��m®mm®mmmmmmomm®m®mmm®mmmmm®m®®®m®mmmmmm m�mmmmmmmmmmm®mmmmmmmm®mmm®mmmm®mm®mmmmm® ��mmmmm®mmmmmmmmmmmmmmmm®®®mmmmm®m®mmmmm® ®��®mmmmmmmmmommmm®mmmmm®m®mmm®mm®mmmm®mm ®�a�mm®mm®m®mmmmm®mmm®mmmmm®m®m®mm®mmmmmmm mmmm®mm®mmmm®mm®m®mmm®mmmmm®mmm®mmmmmmmm m��mm®mm®mmmmmmm®m®m®m®mmm®mmmmm®®mmmmmmm m��mm®mm®mmmmomm®mmm®m®mmmmmmmmmmmmmmmmmm mmmm®mmmmmmm®®mmmm®mm®mmmmmmmmm®®mmm®mmm mmmm®mmm®mmm®®m®m®®®mmmmmmmmmmm®mmmm®m®m mmmm®mmmmmmm®mmmm®®mm®mmmmmmm®mm®®mmmmmm mmm®mmmmmmmmomm®m®®mmmmmmmmmmmm®mmmmmmmm m��mmmmmm®®mmmmm®m®m0®®mmm®®mmm®m®mmmmmmm Prepared by: 8E� Checked by: RLP Notes: 0 -Bald highlighted concentration indlcat....... dance of the 15A NC C 02L Standard, Appendix 2, Apnl 1, 2013 ORP = Oxitlatign Red'— potential NC= Not calculated DIS = Dissolved NE = Npt established TOT = Total NTU = nephel...io is turbidity unit Temp = Temperature S.U. = Standard Unit DO = Dissolved Oxygen ug/I = microgram per liter/micro mhos per centimeter Deg C = Degree Celsius umhos/cm = micro mhos per centimeter mg/I = millio.— per liter Spec Cond = Specific Conductance mg-N/L = miligam nitrogen per liter NM = Not Measured mV = millivolts - cen- [on not det.-, at or above the reporting limit. NA= Not Analyzed DUP = Duplicate * - Interim Maximum Allowable Conc.ntations (IMACQ of the 15A NCAC 02L Standard, Appendix 1, April, 1, 2013. NA = Not analyzed Qualitative Redo, State derived using USGS Excel® Workbook for Identifying lk d- Processes in ground water. P:\Duke Energy Progress.1026\103. Cape Fear Ash Basin GW Assessment\l.11 CSA Reporting\Tables\Table 30-1 Groundwater Analytical Resul[s.xlsz Page 1 of 2 TABLE 10-1 GROUNDWATER ANALYTICAL RESULTS CAPE FEAR STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, MONCURE, NC ��mmm��mmmm®mmmmmmm®mm��mmmmm ��®mmm�mm®m®®��®�mmmmm��m®mmm ��mm®m�mmmm®mmmmmmm®mm��mmmmm ��mm�m�mmmm©mmm®mmm®mm��mmmmm ��®m�m�mmmm®��m®�mm�mm��mmmmm ��mm�m�mmmmmmmm®mmm�mm��mmmmm� ���m�m�mmmm®��m®�mm�mm��m®mmm ��mm�m�mmm�®mmm�m�m�mm��mmmmm ���mmm�mmmm®��m��mmmmm��m®mmm ��mm�m�mmmm®mmm®mmmm����mmmmm ���m®m�mm®m®��m®�mmmmm��m®mmm ��mm�m�mmmm®mmmmmmm�mm��mmmmm ���m�m�mmmm®��mm�mm�mm��mommm ��mm�m�mmmm®mmmmmmmmmm�mmmm�m ���m�m�mm®m®��m®�mmmmm��mmmmm� ��mm�m�mmmmommm®mmm��m��mmmmm ��mm�m�mmmm®mmm®mmm�mm��mmmmm ���m�m�mmmm®��m®�mm�mm��m®mmm ��mmom�mmmm®mmm®mmmomm��mmmmm ���mmm�mm�m®��m®�mm�mm��m®mmm ��mm�m�mmmm®mmm®mmmmmm��mmmmm ���m�m�mm®m®��m®®mmmmm��m®mmm ��mmmm�m�mm®mmm®mmm�mm��mmmmm ��mm�m�mmmm®mmm®mmm�mm��mmmmm Prepared by: BER/MAH Checked by: RLP Notes: 0 -Bald highlighted concentration indicates .... edarce of the SSA NC C 02L Standard, Appendix 2, April 1, 2013 ORP = O.idatipn Red—, Potential NC= Not calculated DIS = Dissolved NE = Not established TOT = Total N U = n,ph,lomet,ic turbidity ,it Temp = Temperature S.U. = Standard Unit DO = Dissolved Oxygen ug/I = microgram per liter/micro mhos per centimeter Deg C = Degree Celsius umhos/cm = micro mhos per centimeter mg/I = milligrams per liter Spec Cord = Specific Conductance mg-N/L = millgram nitrogen per liter NM = Not Measured my = millivolts - cemra[ion not detected at or above the NA= Not Analyzed reporting limit. DUP = Duplicate * - Interim Maximum Allowable Concentrations (IMACQ of the 15A NCAC 02L Standard, Appendix 1, April, 1, 2013. NA = Not analyzed Qualitative Redox State derived using USGS Excel® Workbook for Identirying Redo. Processes in ground water. P:\Duke Energy Progress.1026\103. Cape Fear Ash Basin GW Assessment\l.11 CSA Reporting\Tables\Table 30-1 Groundwater Analytical Resul[s.xlsz Page 2 of 2 TABLE 10-2 15A NCAC 2L EXCEEDANCES IN GROUNDWATER CAPE FEAR STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, MONCURE, NC Analytical Parameter pH Antimony Arsenic Barium Beryllium Boron Cobalt Iron Manganese Nickel Nitrate Selenium Sulfate Thallium Total Dissolved Solids Vanadium Reporting Units S.U. ug/I ug/I ug/I ug/I ug/I ug/I ug/I ug/I ug/I mg/I ug/I mg/I ug/I mg/I ug/I 15A NCAC 02L Standard 6.5-8.5 1* 10 1 700 4* 700 1* 300 50 100 10 20 250 0.2* Soo 0.3* Sample ID Sample Collection Date Analytical Results ABMW-01BR 05/08/2015 BE BE BE BE BE 891 BE BE 629 BE BE BE BE BE BE 0.867 ABMW-01BR 06/15/2015 11 BE BE BE BE BE BE BE BE BE BE BE BE BE BE BE ABMW-01S 05/08/2015 11.2 1.85 27.7 BE BE 2930 BE BE BE BE BE BE BE BE BE 73.3 ABMW-01S 06/15/2015 9.7 BE BE BE BE BE BE BE BE BE BE BE BE BE BE BE ABMW-02SL 05/20/2015 6.2 BE BE BE BE BE BE 3450 519 BE BE BE BE BE BE BE ABMW-02SU 05/20/2015 3.8 BE BE BE BE BE 19 15900 1540 BE BE BE 270 BE BE BE ABMW-02SU 06/16/2015 3.8 BE BE BE BE BE BE BE BE BE BE BE BE BE BE BE ABMW-03BR 05/19/2015 BE BE BE BE BE BE BE 1660 1690 BE BE BE BE BE 540 BE ABMW-03S 05/27/2015 11.7 BE BE BE BE BE BE BE BE BE BE BE BE 0.22 780 2.53 ABMW-03S 06/16/2015 12.1 BE BE BE BE BE BE BE BE BE BE BE BE BE BE BE ABMW-04S 05/14/2015 6.2 BE BE BE BE BE 1.02 18000 1110 BE BE BE BE BE BE 0.328 ABMW-05BR 05/19/2015 BE BE BE BE BE BE BE BE 63 BE BE BE BE 0.359 BE BE ABMW-05S 06/02/2015 6 BE BE BE BE BE 327 1 99600 32400 147 BE BE 1400 0.306 1600 BE ABMW-05S DUP 06/02/2015 6 BE BE BE BE BE 325 103000 33700 149 BE BE 1300 0.317 1700 BE ABMW-05S 06/16/2015 6.3 BE BE BE BE BE BE BE BE BE BE BE BE BE BE BE BGMW-04 03/04/2015 5.9 BE BE BE BE BE BE 360 BE BE BE BE BE BE BE BE BGMW-04 06/08/2015 5.7 BE BE BE BE BE BE 3810 BE BE 15 BE BE BE BE BE BGTMW-04 03/04/2015 BE BE BE BE BE BE BE BE 172 BE BE BE BE BE BE BE BGTMW-04 06/08/2015 BE BE BE BE BE BE BE BE 59 BE BE BE BE BE BE BE CMW-01 03/04/2015 6.1 BE BE BE BE 1380 BE 28700 1390 BE BE BE BE BE BE BE CMW-01 06/09/2015 6.2 BE BE BE BE 1830 BE 52700 1250 BE BE BE BE BE BE BE CMW-01 06/17/2015 6.4 BE BE BE BE BE BE BE BE BE BE BE BE BE BE BE CMW-02 03/04/2015 5.3 BE BE BE BE BE BE 792 6380 BE BE BE 430 BE 770 BE CMW-02 06/09/2015 5.3 BE BE BE BE BE 1.82 796 6760 BE BE BE 480 BE 780 BE CMW-02 06/17/2015 5.3 BE BE BE BE BE BE BE BE BE BE BE BE BE BE BE CMW-03 03/04/2015 6.2 BE BE BE BE 969 BE BE 3200 BE BE BE BE BE BE BE CMW-03 06/09/2015 6.1 BE BE BE BE BE BE BE 85 BE BE 46.8 BE BE BE BE CMW-05 03/04/2015 6.1 BE BE BE BE BE BE 2650 BE BE BE BE BE BE BE BE CMW-05 06/09/2015 5.9 BE BE BE BE BE BE BE BE BE BE BE BE BE BE BE CMW-06 03/04/2015 6.2 BE BE BE BE BE BE 5050 908 BE BE BE BE BE BE BE CMW-06 06/09/2015 BE BE BE BE BE 1560 1.14 556 204 BE BE BE BE BE BE BE CMW-07 03/04/2015 5.1 BE BE BE BE BE BE 2460 770 BE BE BE BE BE BE BE CMW-07 06/09/2015 5.6 BE BE BE BE BE 16.5 10300 2210 BE BE BE BE BE BE BE CMW-08 03/04/2015 6.4 BE BE BE BE 1250 BE 49200 13400 BE BE BE BE BE BE BE CMW-08 06/09/2015 6.3 BE BE BE BE 1300 3.89 41800 13000 BE BE BE BE BE BE BE CMW-08 06/17/2015 6.3 BE BE BE BE BE BE BE BE BE BE BE BE BE BE BE CTMW-01 03/04/2015 BE BE BE BE BE BE BE 874 1430 BE BE BE BE BE BE BE CiMW-01 06/09/2015 BE BE BE BE BE BE BE 385 546 BE BE BE BE BE BE BE CFMW-07 03/04/2015 BE BE BE BE BE BE BE BE 138 BE BE BE BE BE BE BE CTMW-07 06/08/2015 BE BE BE BE BE BE BE BE 110 BE BE BE BE BE BE BE CTMW-08 03/04/2015 BE BE BE BE BE BE BE 2070 980 BE BE BE BE BE BE BE CTMW-08 DUP 03/04/2015 BE BE BE BE BE BE BE 2580 1050 BE BE BE BE BE BE BE CTMW-08 06/09/2015 BE BE BE BE BE BE BE 1270 686 BE BE BE BE BE BE BE CTMW-08 DUP 06/09/2015 BE BE BE BE BE BE BE 1640 750 BE BE BE BE BE BE BE MW-05BR 06/18/2015 11.2 BE BE BE BE BE BE BE BE BE BE BE BE BE BE 14.4 MW-06BR 06/03/2015 BE BE BE 757 BE BE BE BE 475 BE BE BE BE BE 790 2.19 MW-06BR 06/30/2015 BE BE BE 842 BE BE BE BE 743 BE BE BE BE BE 770 0.659 MW-09 06/17/2015 0.9 BE BE BE BE BE BE BE BE BE BE BE BE BE BE BE MW-09 06/30/2015 5.7 BE BE BE BE BE 6.7 1800 826 BE BE BE BE BE 660 BE MW-09BR 05/30/2015 BE BE BE BE BE BE BE 441 829 BE BE BE BE BE BE BE MW-10 06/17/2015 5.9 BE BE BE BE BE BE BE BE BE BE BE BE BE BE BE MW-10 07/01/2015 5.8 BE BE BE BE 922 21 2800 12500 BE BE BE 610 BE 1100 0.366 MW-IOBR 05/27/2015 BE BE BE BE BE BE BE BE 336 BE BE BE BE BE BE 3.34 MW-IOBR 06/16/2015 9 BE BE BE BE BE BE BE BE BE BE BE BE BE BE BE MW-lOD 05/28/2015 BE BE BE BE BE BE BE BE 974 BE BE BE 410 0.233 890 0.938 MW-101) 06/16/2015 60.5 BE BE BE BE BE BE BE BE BE BE BE BE BE BE BE MW-11 07/01/2015 6.2 BE BE BE BE BE 1.03 3810 912 BE BE BE BE BE 550 0.867 MW-12 06/30/2015 BE BE BE BE BE BE 2.43 456 843 BE BE BE 260 BE 740 BE MW-12BR 03/19/2015 BE BE BE BE BE BE BE BE 482 BE BE BE BE BE BE 0.338 MW-12BR 06/11/2015 BE BE BE BE BE BE BE BE BE BE BE BE BE BE BE BE MW-13 06/29/2015 5.8 BE BE BE BE BE 1.46 BE 820 BE BE BE BE 0.297 BE 1.07 MW-14 06/30/2015 9.1 BE BE BE BE BE BE 419 BE BE BE BE BE BE BE 1.37 MW-15BR 06/01/2015 BE BE BE BE BE BE BE BE 72 BE BE BE BE BE BE 1.73 MW-15BR 06/30/2015 BE BE BE BE BE BE BE BE 69 BE BE BE BE BE BE 1.82 MW-15SL 05/29/2015 6 BE BE BE BE BE 21.1 45500 4560 BE BE BE BE BE BE BE MW-15SL 06/30/2015 6.1 BE BE BE BE BE 12.3 38400 3860 BE BE BE BE BE BE 0.383 MW-15SU 05/29/2015 4.6 BE BE BE 10 BE 387 2490 33700 150 BE BE 1600 0.218 BE 4.57 MW-16BR 05/20/2015 BE BE BE BE BE BE BE 329 326 BE BE BE BE BE BE BE MW-16S 05/20/2015 6.2 BE BE BE BE BE 3.52 BE 202 BE BE BE BE BE 630 1.1 MW-16S DUP 05/20/2015 6.2 BE BE BE BE BE 3.9 BE 207 BE BE BE BE BE 620 1.05 MW-16S 06/11/2015 6.1 BE BE BE BE BE BE BE BE BE BE BE BE BE BE BE MW-16S 06/30/2015 6.1 BE BE BE BE BE BE BE BE BE BE BE BE BE BE BE MW-17BR 03/19/2015 BE BE BE BE BE BE BE BE BE BE BE BE BE BE BE 0.761 MW-17BR 06/10/2015 BE BE BE BE BE BE BE BE BE BE BE BE BE BE BE BE MW-17SL 03/19/2015 6 BE BE BE BE BE 6.76 1 175000 7380 BE BE BE 570 BE 900 0.919 MW-17SL 06/10/2015 5.7 BE BE BE BE BE BE BE BE BE BE BE BE BE BE BE MW-17SU 03/19/2015 5 BE BE BE BE BE 241 2620 45500 BE BE BE 710 BE 910 0.381 MW-17SU 06/10/2015 5.7 BE BE BE BE BE BE BE BE BE BE BE BE BE BE BE MW-18S 06/03/2015 BE BE BE BE BE BE BE BE 137 BE BE BE BE BE BE 1.63 MW-19S 03/11/2015 5.3 BE BE BE BE BE BE 486 BE BE BE BE BE BE BE 0.81 MW-20BR 05/27/2015 BE BE BE BE BE BE BE 730 131 BE BE BE BE BE BE 1.61 MW-20S 02/21/2015 6.3 BE BE BE BE BE BE I BE BE BE BE BE BE BE BE BE MW-20S 05/21/2015 6.3 BE BE BE BE BE BE 4270 1210 BE BE BE BE BE BE 1.03 MW-20S 06/11/2015 6.4 BE BE BE BE BE BE BE BE BE BE BE BE BE BE BE MW-21BR 05/07/2015 8.8 BE BE BE BE BE BE BE BE BE BE BE BE BE BE 0.997 MW-21BR 06/10/2015 8.8 BE BE BE BE BE BE BE BE BE BE BE BE BE BE BE MW-21SL 05/07/2015 5.7 BE BE BE BE BE 18.7 731 2430 BE BE BE 930 BE 1300 0.313 MW-21SL 06/10/2015 5.8 BE BE BE BE BE BE BE BE BE BE BE BE BE BE BE MW-21SU 05/07/2015 4.1 BE BE BE 8.94 BE 180 BE 9720 BE BE BE 300 0.335 BE BE MW-21SU 06/10/2015 4.1 BE BE BE BE BE BE BE BE BE BE BE BE BE BE BE PZ-01 08/06/2015 6.1 BE BE BE BE BE 4.35 14700 4250 BE BE BE 260 BE BE 0.604 PZ-02 08/06/2015 6.3 BE BE BE BE 3810 8.24 1140 2440 BE BE BE BE BE BE 1.66 PZ-02 DUP 08/06/2015 6.3 BE BE BE BE 3830 7.8 763 2440 BE BE BE BE BE BE 1.27 PZ-03D 08/05/2015 BE BE BE BE BE BE BE BE 475 BE BE BE BE BE BE 0.384 PZ-03S 08/05/2015 BE BE BE BE BE 2440 BE BE 182 BE BE BE BE BE 590 1.97 PZ-04 08/05/2015 6.4 BE BE BE BE 1440 1.31 1290 519 BE BE BE BE BE BE 0.979 PZ-05 08/05/2015 5.4 BE BE BE BE 4910 8.24 BE 2990 BE BE BE 270 BE 70.535 PZ-09 08/06/2015 4.6 BE BE BE BE BE 28.4 1170 627 BE BE 96.1 BE 0.574 BE 0.811 Prepared by: BER/SRW Checked by: CIS Notes: =- Bold highlighted concentration indicates exceedance of the 15A NCAC 02L Standard, Appendix 2, Apirl 1, 2013. = Interim Maximum Allowable Concentrations (IMACs) of the 15A NCAC 02L Standard, Appendix 1, April 1, 2013. DUP = Duplicate BE = indicates concentration was below the 15A NCAC 02L Standard, May 1, 2007. mg/I = milligrams per liter S.U. = Standard Units ug/I = micrograms per liter P:\Duke Energy Progress.1026\303. Cape Fear Ash Basin GW Assessment\1.11 CSA Reporting\Tables\Table 10-2 2L Exceedances in Groundwater.xlsx Page 1 of 1 TABLE IO-3 VALENCE SPECIATION OF GROUNDWATER CAPE FEAR STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, MONCURE, NC Analytical Parameter As(III) As(V) MMAs DMAS As (UK) Cr(VI) Fe(II) Fe(III) Mn(II) Mn(IV) Se(IV) Se(VI) SeCN MCSe(IV) SeMe Se (UK) Reporting Units u /I u /I a /I u /I u /I u /I a /I u /I a /I u /1 u /I u /I a /I u /1 u /I u /I Sample ID Sample Collection Analytical Results ABMW-01 06/15/2015 27.6 0.253 <0.035 <0.015 NA <0.005 38.7 <6.7 186 2.36 NA NA NA NA NA NA ABMW-03 06/16/2015 62 235 <0.053 <0.2 NA 0.015 21 17.2 114 6.08 NA NA NA NA NA NA ABMW-04 06/16/2015 699 15.2 <0.053 <0.2 NA <0.005 2860 <5 378 <0.38 NA NA NA NA NA NA ABMW-01BR 06/15/2015 <0.062 0.464 <0.035 <0.015 NA 10.5 4.8 <6.7 4.01 36.6 NA NA NA NA NA NA ABMW-01S 06/15/2015 17.2 11 <0.035 <0.015 NA 0.016 7.3 <6.7 28.8 <0.38 NA NA NA NA NA NA ABMW-02SL 06/16/2015 0.916 0.14 <0.053 <0.083 NA <0.005 5000 685 630 <0.38 NA NA NA NA NA NA ABMW-02SU 06/16/2015 0.174 0.196 <0.053 <0.083 NA <0.005 11400 652 1570 83.2 NA NA NA NA NA NA ABMW-03BR 06/16/2015 0.772 <0.028 <0.053 <0.083 NA <0.005 805 123 391 110 NA NA NA NA NA NA ABMW-03S 06/16/2015 <0.049 0.224 0.1 0.094 NA 8.31 14 33.5 <0.26 <0.07 NA NA NA NA NA NA ABMW-04S 06/16/2015 1.69 0.42 <0.053 <0.083 NA 0.005 26900 2890 1790 31.3 NA NA NA NA NA NA ABMW-05BR 06/11/2015 1.52 0.294 <0.035 <0.015 <0.035 0.012 14.1 <6.7 68.9 8.38 <0.27 <0.11 <0.26 <0.21 <0.21 <0.21 ABMW-05S 06/16/2015 0.561 0.262 <0.053 <0.083 NA <0.005 111000 3220 33000 60.8 NA NA NA NA NA NA CMW-01 06/17/2015 0.604 0.077 <0.053 <0.083 <0.053 <0.005 52600 <500 1170 <0.19 NA NA NA NA NA NA CMW-02 06/17/2015 0.076 <0.076 <0.061 <0.064 <0.061 NA 943 19.3 7090 260 NA NA NA NA NA NA CMW-06 06/18/2015 0.147 <0.03 <0.039 0.111 <0.039 0.007 237 19.6 187 8.27 NA NA NA NA NA NA CMW-08 06/17/2015 0.201 <0.028 <0.053 <0.083 <0.053 <0.005 34000 1000 12000 <0.19 NA NA NA NA NA NA CTMW-01 06/16/2015 <0.049 0.244 <0.053 <0.083 NA <0.005 98 70.7 148 175 NA NA NA NA NA NA CTMW-02 06/17/2015 0.285 6.38 10.061 <0.064 <0.061 NA <5 <5 <0.026 1.74 NA NA NA NA NA NA CTMW-08 06/17/2015 3.67 1.42 <0.053 <0.083 <0.053 <0.005 7620 <500 1270 <0.19 NA NA NA NA NA NA MW-06SR 06/30/2015 0.582 1.57 NA NA NA NA 1 176 6.1 827 <0.12 NA NA NA NA NA NA MW-09 06/17/2015 0.102 0.055 <0.053 <0.083 <0.053 0.014 376 26.3 556 <0.19 NA NA NA NA NA NA MW-09BR 06/17/2015 0.07 <0.028 <0.053 c0.083 <0.053 <0.005 431 <5 908 <0.19 NA NA NA NA NA NA MW-30 06/17/2015 0.071 <0.028 <0.053 <0.083 <0.053 0.007 771 <5 13400 <0.19 NA NA NA NA NA NA MW-10BR 06/16/2015 1.36 0.228 <0.053 <0.083 NA 0.023 <5 <5 212 <0.07 NA NA NA NA NA NA MW-10D 06/16/2015 0.318 0.603 <0.053 <0.083 NA 0.006 43 9 1100 <0.38 NA NA NA NA NA NA MW-12 06/11/2015 0.152 <0.028 <0.035 <0.015 <0.035 <0.006 163 34.3 879 103 <0.27 <0.11 <0.26 <0.21 <0.21 <0.21 MW-12BR 06/11/2015 0.893 0.135 <0.035 <0.015 <0.035 0.045 <3.6 8.9 679 <0.45 <0.27 <0.11 <0.26 <0.21 <0.21 <0.21 MW-15BR 06/30/2015 11.2 61.1 NA NA NA NA <5 9.3 72 3 NA NA NA NA NA NA MW-15SL 06/30/2015 14 3.75 NA NA NA NA 22600 16200 4170 201 NA NA NA NA NA NA MW-16BR 06/11/2015 1.19 0.134 <0.035 <0.015 <0.035 0.019 115 <6.7 303 <0.45 <0.27 <0.11 <0.26 <0.21 <0.21 <0.21 MW-165 06/11/2015 <0.062 <0.028 <0.035 <0.015 <0.035 <0.006 28.3 18.7 133 8.85 <0.27 <0.11 <0.26 <0.21 <0.21 <0.21 MW-17BR 06/10/2015 <0.062 <0.028 <0.035 <0.015 <0.035 0.393 15.9 <3.9 30.2 4.6 <0.069 <0.085 <0.028 <0.061 <0.061 <0.061 MW-17SL 06/10/2015 0.138 <0.028 <0.035 <0.015 0.608 0.1 79100 3100 6640 290 <0.069 <0.085 <0.028 <0.061 <0.061 <0.061 MW-17SU 06/10/2015 <0.062 <0.028 <0.035 <0.015 <0.035 0.058 24900 2300 39400 <2.3 <0.069 <0.085 <0.028 <0.061 <0.061 <0.061 MW-20BR 06/11/2015 0.758 0.233 <0.035 <0.015 <0.035 0.022 25.9 <6.7 132 13.3 <0.27 <0.11 <0.26 <0.21 <0.21 <0.21 MW-20S 06/11/2015 0.129 0.063 <0.035 <0.015 <0.035 0.018 4595 439 1340 48.9 <0.27 <0.11 <0.26 <0.21 <0.21 <0.21 MW-21BR 06/10/2015 0.093 2.34 <0.035 <0.015 10.035 0.11 <3.4 4.5 <0.91 4.07 0.414 <0.085 <0.028 <0.061 <0.061 <0.061 MW-21SL 06/10/2015 0.625 0.218 <0.035 <0.015 <0.035 0.052 775 170 1910 <0.12 1 <0.069 1 <0.085 1 <0.028 <0.061 <0.061 <0.061 MW-215U 06/10/2015 1 <0.062 1 10.028 1 <0.035 <0.015 <0.035 0.19 45.5 28.5 11900 530 1 <0.069 1 0.183 1 <0.028 <0.061 <0.061 <0.061 Prepared by: BER/MEH Checked by: RKD Notes: 1 9 /1 = microgram per liter = concentration not detected at or above the reporting limit. NA = not analyzed P:\Duke Energy Progress. 1026\103. Cape Fear Ash Basin GW Assessment\1.11 CSA Reporting\Tables\Table 10-3 Valence Speciation of GroundWater.xlsx Page 1 of 1 TABLE 10-4 CHARGE BALANCE SUMMARY CAPE FEAR STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, MONCURE, NC Sample ID Anions Cations % Difference Ash Pore water ABM W-01 3.72 5.04 15.066 ABMW-03 11.3 14.9 13.526 ABM W-04 6.95 8.98 12.763 Bedrock Groundwater ABMW-0113R 5.51 6.68 9.548 ABMW-03BR 7.15 9.15 12.296 ABMW-05BR 2.74 3.37 10.333 BGTM W-04 2.6 3.11 8.966 CTMW-01 5.66 7.40 13.360 CTMW-02 2.45 3.26 14.223 CTM W-07 4.96 6.1 10.298 CTM W-08 6.38 8.18 12.362 MW-05BR 5.34 3.58 19.677 MW-06BR 10.6 11.3 3.073 M W-09BR 6.07 6.72 5.074 MW-10D 11.3 14.1 11.211 MW-10BR 6.75 7.46 5.019 MW-12BR 4.16 5.43 13.310 MW-15BR 3.26 4.19 12.477 MW-16BR 4.57 5.8 11.777 MW-17BR 4.17 5.22 11.164 MW-20BR 2.79 3.58 12.388 M W-21 BR 2.56 3.45 14.824 M W-09 7.88 8.71 5.032 MW-14 3.51 4.31 10.314 Surficial Groundwater ABMW-01S 8.08 6.760 8.929 ABMW-02SL 7.420E-03 1.36 29.424 ABMW-02SU 6.72 6.23 3.769 ABMW-03S 16.8 16.0 2.668 ABMW-04S 1.56 3.57 39.087 ABMW-05S 30.5 25.1 9.577 BGMW-04 9.54E-03 1.94 34.014 CMW-01 1.71 3.39 32.999 CMW-02 10.8 10.3 2.411 CMW-03 3.19 4.06 11.993 CMW-05 1.34 1.72 12.278 CMW-06 4.48 5.83 13.127 CMW-07 2.19 2.43 5.186 CMW-08 2.64 5.96 38.629 MW-10 13.8 14.4 2.258 MW-11 5.89 7.97 14.977 MW-12 9.49 11.3 8.714 P:\Duke Energy Progress.1026\103. Cape Fear Ash Basin GW Assessment\1.11 CSA Reporting\Tables\Table 10-4 Charge Balance Summary.xlsx Page 1 of 2 TABLE 10-4 CHARGE BALANCE SUMMARY CAPE FEAR STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, MONCURE, NC Sample ID Anions Cations % Difference MW-13 2.9 4 15.868 MW-15SL 1.64 2.78 25.956 M W-15SU 34.8 26.9 12.755 MW-16S 7.42 8.85 8.798 MW-17SL 12.8 14.4 5.809 M W-17SU 15.9 13.1 9.403 MW-18S 5.96 6.7 5.806 MW-19S 4.77E-03 5.26E-03 4.89 MW-20S 2.91 4.95 26.024 MW-21SL 20.2 18.8 3.637 M W-21SU 6.48 3.87 25.197 Seep 5-04 6.18 16.6 45.687 5-09 3.99 6.27 22.224 5-10 3.04 4.69 21.317 5-16 48.3 37.3 12.815 Surface Water SW-85DS 3.74 5.96 22.91 SW-BA1 2.4 3 11.139 SW-BA2 1.06 1.89 28.204 SW-BB1 5.890E-03 8.480E-03 18.040 SW-CFDG 1.23 1.54 11.467 SW-DEEPR 1.03 1.35 13.600 SW -HAW 1.46 1.86 12.224 SW-SHD-56 1.01 1.41 16.708 SW SHD PLANT 2.22 3.07 16.106 SW-SHD-REF 9.370E-03 1.53 24.131 SW-UNT 4.62 5.63 9.807 Prepared by: DH Checked by: JHG P:\Duke Energy Progress.1026\103. Cape Fear Ash Basin GW Assessment\1.11 CSA Reporting\Tables\Table 10-4 Charge Balance Summary.xlsx Page 2 of 2 TABLE 10-5 RADIOLOGICAL ANALYTICAL RESULTS CAPE FEAR STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, MONCURE, NC Analytical Parameter Radium-226 Radium-228 Uranium-233 Uranium-234 Uranium-236 Uranium-238 Reporting Units pCi/I pCi/I ug/mL ug/mL ug/mL ug/mL Sample ID Sample Collection Date Analytical Results CMW-01 06/17/2015 0.57 <3 <0.00005 <0.00005 <0.00005 <0.0002 MW-05BR 06/18/2015 <1 <3 <0.00005 <0.00005 <0.00005 <0.0002 MW-16S 06/30/2015 3 <3 <0.00005 <0.00005 <0.00005 0.000209 Prepared by: MEH Checked by: RKD Notes• pCi/I = Picocuries per limit ug/mL= microgram per liter < = concentration not detected at or above the reporting limit. j = indicates concentration reported below Practical Quantitation Limit (PQL), but above Method Detection Limit (MDL) and therefore concentration is estimated. P:\Duke Energy Progress.1026\103. Cape Fear Ash Basin GW Assessment\1.11 CSA Reporting\Tables\Table 10-5 Radiological Analytical Results.xlsx Page 1 of 1 TABLE 12-1 RISK SCREENING TABLE: COAL ASH PORE WATER DATA CAPE FEAR STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, MONCURE, NC Redox Water Spec Ferrous Aluminum Antimony Arsenic Barium Beryllium gi- Boron Cadmium Calcium Carbonate Chromium Cobalt Copper Iron Analytical Parameter pH Temp DO ORP Eh Turbidity Alkalinity carbonate Chloride Cr(III)/Cr(VI) Assignment Level Cond Iron Alkalinity Alkalinity DIS TOT DIS TOT DIS TOT DIS TOT DIS TOT DIS TOT DIS TOT TOT DIS TOT DIS TOT DIS TOT DIS TOT Reporting Units None S.U. ft Deg C u/cos m g/l mV mV NTU mg/I mg/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/1 ug/l ug/l mg/I ug/I ug/I ug/l ug/l mg/l mg/I mg/l ug/I ug/l ug/l ug/l mg/l mg/l ug/I ug/l m 15A NCAC 02L Standard NE 6.5-8.5 NE NE NE NE NE NE NE NE NE NE NE NE 1* NE 10 NE 700 NE 4* NE NE 700 NE 2 NE NE 250 NE 10 NE 1* NE 1 NE 300 Sample ID Sample Field Parameters Analytical Results Collection Date ASH PORE WATER ABMW-011'I 05/08/2015 Anoxic 8.0 19.65 25 468 0.39 -202 3 4.13 NM 75 26 61 <1 <1 532 582 117 119 <1 <1 75 2310 2270 <1 <1 53.6 <10 18 <1 <1 <1 <1 <0.001 <0.001 1570 1620 ABMW-03(') 05/20/2015 NM NM NM NM NM NM NM NM NM NM 170 215 232 3.1 3.59 361 341 133 137 <1 <1 160 6250 6360 <1 <1 120 <10 6.7 <1 <1 <1 <1 <0.001 <0.001 70 91 ABMW-04(') 05/14/2015 Anoxic 7.3 16.23 19 840 0.19 -184 21 4.36 NM 230 13 30 <1 <1 709 1010 266 258 <1 <1 230 1410 1350 <1 <1 82.4 <10 37 <1 <1 <1 <1 <0.001 <0.001 3960 3630 PZ-06 08/05/2015 Anoxic 7.5 19.45 21 1083 0.31 -161 44 4.63 NM 310 43 170 2.17 2.3 607 647 307 312 <1 <1 310 5160 5380 <1 <1 183 <10 23 <1 <1 18.6 18.7 0.00381 <0.001 2660 3050 PZ-07 08/06/2015 Anoxic 4.0 10.80 18 7193 0.29 179 384 4.79 NM <10 431000 466000 <10 <10 201 193 42 <500 305 318 <10 1050 <5000 <10 <10 370 <10 13 145 138 1100 1050 <0.01 <0.01 2040000 2140000 PZ-08 08/05/2015 Anoxic 6.7 18.10 23 975 0.36 -34 172 4.17 NM 190 7 16 4.22 2.85 224 124 68 61 <1 <1 190 463 465 <1 <1 107 <10 41 <1 <1 12.7 17.8 <0.001 <0.001 2560 2390 DETECTIONS/SAMPLES --- --- --- --- --- --- --- --- --- --- 5/6 6/6 6/6 3/6 3/6 6/6 6/6 6/6 5/6 1/6 1/6 5/6 6/6 5/6 0/6 0/6 6/6 0/6 6/6 1/6 1/6 3/6 3/6 1/6 0/6 6/6 6/6 AVERAGE ASH PORE WATER CONCENTRATION (DETECTIONS --- --- --- --- --- --- --- --- --- --- 195 71,884 77,752 3.16 2.91 439 483 156 177 305 318 193 2,774 3,165 --- --- 153 --- 23 145 138 377 362 0.00381 --- 341,803 358,464 ONLY) MAXIMUM ASH PORE WATER GROUNDWATER CONCENTRATION --- --- --- --- --- --- --- --- --- 310 431,000 466,000 4.22 3.59 709 1,010 307 312 305 318 310 6,250 6,360 --- --- 370 --- 41 145 138 1,100 1,050 0.00381 --- 2,040,000 2,140,000 NUMBER OF ASH PORE WATER SAMPLES EXCEEDING 02L ___ 0 0 0 0 4 0 6 0 0 0 1 0 0 3 0 1 0 0 0 0 1 0 3 0FO 0 5 Prepared by: KDF Checked by: RLP Notes: 0- Bold highlighted concentration indicates exceedance of the 15A NCAC 02L, Appendix 2, April 1, 2013. 0- Highlighted concentration indicates analytical reporting limit is greater than the 15A NCAC 02L, Appendix 2, April 1, 2013. ORP = Oxidation Reduction Potential my = millivolts --- = Not applicable DIS = Dissolved NE = Not established TOT = Total NTU = nephelometric turbidity unit Temp = Temperature S.U. = Standard Unit DO = Dissolved Oxygen ug/I = microgram per liter Deg C = Degree Celsius umhos/cm = micro mhos per centimeter mg/I = milligrams per liter Spec Cond = Specific Conductance mg-N/L = miligram nitrogen per liter ft = feet < = concentration not detected at or above the reporting limit. * - Interim Maximum Allowable Concentrations (IMACs) of the 15A NCAC 02L, Appendix 1, April, 1, 2013. Note 1: Hexavalent Chromium concentration is less than EPA screening value for tapwater (0.035 ug/L). See Table 10-3 (USEPA Regional Screening Levels [RSLs] rev., ]une 26, 2015) P:\Duke Energy Progress. 1026\103. Cape Fear Ash Basin GW Assessment\1.11 CSA Reporting\Tables\Table 12-1 Ash Pore Water Risk Screening.xlsx Page 1 of 2 TABLE 12-1 RISK SCREENING TABLE: COAL ASH PORE WATER DATA CAPE FEAR STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, MONCURE, NC Lead Magnesium Manganese Mercury Molybdenum Nickel Nitrate Potassium Selenium Sodium Strontium Thallium Total Total Total Vanadium Zinc Analytical Parameter Methane (as N) Sulfate Sulfide Dissolved Organic Suspended Solids Carbon Solids DIS TOT TOT DIS TOT DIS I TOT DIS TOT DIS TOT TOT DIS TOT TOT DIS TOT DIS TOT DIS TOT DIS TOT Reporting Units ug/1 ug/I mg/l ug/I ug/I ug/I ug/I ug/I ug/I ug/I ug/I ug/I mg-N/L mg/I ug/I ug/I mg/I mg/I mg/l mg/I mg/I ug/I ug/I mg/l mg/I mg/I ug/I ug/1 mg/l mg/I 1 15A NCAC 02L Standard NE 15 NE NE 50 NE 1 NE NE NE NE 100 10 NE NE 20 NE NE NE 250 NE NE 0.2* 500 NE NE NE 0.3* NE 1 Sample ID Sample Analytical Results Collection Date ASH PORE WATER ABMW-011'I 05/08/2015 <1 <1 7.08 163 161 <0.05 <0.05 <10 449 457 1.97 1.92 <0.01 8.64 1.26 <1 19 1.21 1.21 96 0.137 <0.2 <0.2 280 1.8 6 <0.3 0.522 <0.005 0.006 ABMW-031'i 05/20/2015 <1 <1 67.4 124 124 <0.05 <0.05 940 261 239 5.1 5.45 0.016 19.7 1.92 2.32 23.4 4.37 4.45 410 <0.2 0.442 0.422 820 1.2 <5 22.3 22.1 0.005 <0.005 ABMW-041'i 05/14/2015 <1 <1 17.3 409 395 <0.05 <0.05 6200 32.4 35.3 3.38 3.07 <0.01 13.4 1.67 <1 57 3.27 3.2 120 <0.2 <0.2 <0.2 500 1.3 10 <0.3 <0.3 0.006 <0.005 PZ-06 08/05/2015 <1 <1 24.9 1070 1110 <0.05 <0.05 56 263 269 16.2 15.9 <0.01 13 <1 <1 22 5.23 5.22 230 <0.1 <0.2 0.255 760 1.1 13 9.31 11.1 0.022 <0.005 PZ-07 08/06/2015 11.2 10.3 185 24800 26300 <0.05 <0.05 310 <10 <10 2180 2050 <0.01 97.9 16.1 16.4 79.7 10 11 18000 <0.1 13.2 12.6 12000 1.1 16 1910 1880 2.69 3.45 PZ-08 08/05/2015 <1 <1 1 25.4 1570 1 2170 <0.05 I <0.05 <10 122.1 1 16.9 33.9 1 43.5 0.082 1 12.4 <1 1.07 59.2 2.62 2.79 220 <0.1 1.02 1.31 620 0.492 42 9.49 6.43 0.028 0.011 DETECTIONS SAMPLES 1/6 1/6 6/6 6/6 6/6 0/6 0/6 4/6 5/6 5/6 6/6 6/6 2/6 6/6 4/6 3/6 6/6 6/6 6/6 6/6 1/6 3/6 4/6 6/6 6/6 5/6 4/6 5/6 5/6 3/6 AVERAGE ASH PORE WATER CONCENTRATION (DETECTIONS 11.2 10.3 54.5 4,689 5,043 --- --- 1,877 206 203 373.4 353.3 0.049 27.5 5.24 6.6 43.4 4.45 4.6 3,179 0.137 4.89 3.65 2,497 1.2 17 487.8 384.03 0.550 1.156 ONLY) MAXIMUM ASH PORE WATER GROUNDWATER CONCENTRATION 11.2 10.3 185.0 24,800 26,300 --- --- 6,200 449 457 2,180.0 2,050.0 0.082 97.9 16.10 16.4 79.7 10.00 11.0 18,000 0.137 13.20 12.60 12,000 1.8 42 1,910.0 1,880.00 2.690 3.450 NUMBER OF ASH PORE WATER SAMPLES EXCEEDING 02L 0 0 0 0 6 0 0 0 0F 0 1 0 0 0 0 0 0 0 1 2 0 0 4 4 0 0 0 5 0 1 Prepared by: KDF Checked by: RLP Notes: 0- Bold highlighted concentration indicates exceedance of the 15A NCAC 02L, Appendix 2, April 1, 2013. 0- Highlighted concentration indicates analytical reporting limit is greater than the 15A NCAC 02L, Appendix 2, April 1, 2013. ORP = Oxidation Reduction Potential my = millivolts --- = Not applicable DIS = Dissolved NE = Not established TOT = Total NTU = nephelometric turbidity unit Temp = Temperature S.U. = Standard Unit DO = Dissolved Oxygen ug/I = microgram per liter Deg C = Degree Celsius umhos/cm = micro mhos per centimeter mg/I = milligrams per liter Spec Cond = Specific Conductance mg-N/L = miligram nitrogen per liter ft = feet < = concentration not detected at or above the reporting limit. * - Interim Maximum Allowable Concentrations (IMACs) of the 15A NCAC 02L, Appendix 1, April, 1, 2013. Note 1: Hexavalent Chromium concentration is less than EPA screening value for tapwater (0.035 ug/L). See Table 10-3 (USEPA Regional Screening Levels [RSLs] rev., June 26, 2015) P:\Duke Energy Progress. 1026\103. Cape Fear Ash Basin GW Assessment\1.11 CSA Reporting\Tables\Table 12-1 Ash Pore Water Risk Screening.xlsx Page 2 of 2 TABLE 12-2 COAL ASH COPC DETERMINATION CAPE FEAR STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS,LLC, MONCURE, NC Constituent Coal Ash > EPA Soil RSL(') Coal Ash Pore Water Conc.> NC 2L(2) Coal Ash COPC Basis For Coal Ash COPC Determination Aluminum Yes Not Established Yes Above soil RSL Antimony Yes Yes Yes Above soil RSL and groundwater 2L Arsenic Yes Yes Yes Above soil RSL and groundwater 2L Barium Yes No No Below groundwater 2L Beryllium Yes Yes Yes Above soil RSL and groundwater 2L Boron No Yes Yes Above groundwater 2L Cadmium No Yes Yes Above groundwater 2L Calcium Not Established Not Established No Note 3 Chloride Not Established No No Below groundwater 2L Chromium [Cr(III)/Cr(VI)] No Yes Yes Above groundwater 2L Cobalt Yes Yes Yes Above soil RSL and groundwater 2L Copper Yes No No Below groundwater 2L Iron Yes Yes Yes Above soil RSL and groundwater 2L Lead Yes No No Below groundwater 2L Magnesium Not Established Not Established No Note 3 Manganese Yes Yes Yes Above soil RSL and groundwater 2L Mercury Yes No No jBelow groundwater 2L Molybdenum Yes Not Established Yes jAbove soil RSL Nickel No Yes Yes jAbove groundwater 2L Nitrate (as N) Not Established No No Below groundwater 2L Potassium Not Established Not Established No Note 3 Selenium Yes No No Below groundwater 2L Sodium Not Established Not Established No Note 3 Strontium No Not Established No Below soil RSL Sulfate Not Established Yes Yes jAbove groundwater 2L Thallium Yes Yes Yes Above soil RSL and groundwater 2L TDS Not Established Yes Yes Above groundwater 2L Vanadium Yes Yes Yes Above soil RSL and groundwater 2L Zinc No Yes Yes Above groundwater 2L Prepared by: KDF Checked by: VTV Notes: Constituent is a coal ash COPC Constituent is not a coal ash COPC Note 1: See Table 7-3 Note 2: See Tables 7-8 and 12-1 Note 3: Naturally occurring at moderate concentrations in most water bearing units, present at moderate concentrations in many foods and available in dietary supplements. Unlikely to pose potentially unacceptable risk to human health when compared to other P:\Duke Energy Progress. 1026\103. Cape Fear Ash Basin GW Assessment\1.11 CSA Reporting\Tables\Table 12-2 Coal Ash COPCS.xlsx Page 1 of 1 TABLE 12-3 RISK SCREENING TABLE: BACKGROUND GROUNDWATER DATA CAPE FEAR STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, MONCURE, NC Analytical Parameter Redox As PH Water Level Temp Spec Cond DO ORP Turbidity Ferrous Iron Alkalinity Aluminum Antimony Arsenic Barium Beryllium gi- carbonate Alkalinity Boron Cadmium Calcium Carbonate Alkalinity Chloride Chromium Cr(III)/Cr(VI) Cobalt Copper DIS TOT DIS TO DIS TOT DIS TOT DIS TOT DIS TOT DIS TOT TOT DIS TOT DIS TOT DIS TOT Reporting Units None S.U. ft Deg C u/cros mg/I mV NTU mg/I mg/I ug/I ug/I ug/I ug/1 ug/I ug/I ug/I ug/1 ug/I ug/I mg/1 ug/I ug/I ug/I ug/I mg/I mg/l mg/1 ug/I ug/I ug/I ug/1 mg/I mg/1 SSA NCAC 02L Standard NE 6.5-8.5 NE NE NE NE NE NE NE NE NE NE NE 1* NE 10 NE 700 NE 4* NE NE 700 NE 2 NE NE 250 NE 10 NE 1* NE 1 Sample ID Sample Collection Date Field Parameters Analytical Results SURFICIAL BGMW-04 03/04/2015 NM 5.9 14.49 14 189 1.33 70 8.11 NM NA NA 462 NA <1 NA <1 NA 31 NA NA NA NA <50 NA <1 NA NA 8.3 NA <5 NA NA NA 0.007 BGMW-04 06/08/2015 NM 5.7 16.20 18 188 1 97 9.85 NM 31.9 NA 3970 NA <1 NA <1 NA 91 NA <1 31.9 NA 482 NA <1 11.1 <5 9.3 NA <5 NA <1 NA <0.005 MW-15SU 05/29/2015 NM 4.6 10.47 24 2530 2.22 371 4.1 NM 11 NA 6850 NA <1 NA 2.47 NA 29 NA 10 11 NA <50 NA 1.21 147 <10 51 NA 3.39 NA 387 NA 0.0307 MW-15SL 05/29/2015 Anoxic 6.0 10.58 18 329 0.1 116 4.97 NM 47 58 76 <1 <1 2.37 2.4 76 76 <1 <1 47 <50 <50 <1 <1 10 <10 6.3 <1 <1 19.8 21.1 <0.001 <0.001 MW-15SL 06/30/2015 Anoxic 6.1 10.44 19 282 0.3 -61 5.26 4.5 58 71 161 <1 <1 1.77 1.91 67 69 <1 <1 58 <50 <50 <1 <1 7.21 <10 7.6 <1 <1 12 12.3 <0.001 <0.001 MW-16S1l,'l 05/20/2015 Anoxic 6.2 2.19 17 978 16.6 111 4.26 NM 84 <5 110 <1 <1 <1 <1 159 160 <1 <1 84 217 140 <1 <1 59.9 <10 210 <1 <1 5.31 3.52 <0.001 <0.001 MW-16S DUP 05/20/2015 Anoxic 6.2 2.19 17 978 16.6 111 4.26 NM 83 <5 64 <1 <1 <1 <1 156 162 <1 11 83 202 140 <1 <1 59.7 <10 200 <1 <1 5.19 3.9 <0.001 <0.001 BEDROCK BGTMW-04 03/04/2015 NM 7.7 15A2 14 321 0.8 48 0.46 NM NA NA 11 NA <1 NA <1 NA 128 NA NA NA NA <50 NA <1 NA NA 17 NA <5 NA NA NA <0.005 BGTMW-04 06/08/2015 NM 8.1 16.63 20 310 2.3 -43 2.54 NM 122 NA 44 NA <1 NA 3.05 NA 129 NA <1 122 NA <50 NA <1 28.5 <5 16 NA <5 NA <1 NA <0.005 MW-0911,2l 06/30/2015 Anoxic 5.7 14.20 21 1049 0.23 101 3.21 1.5 83 6 16 <1 <1 <1 <1 80 76 <1 <1 82 <50 <50 <1 <1 68.9 <10 240 <1 <1 4.56 6.7 <0.001 <0.001 MW-09BRIt,zi 05/30/2015 Mixed (anoxic) 7.7 17.46 19 706 0.12 -238 2.1 NM 160 82 138 <1 <1 <1 <1 416 420 <1 <1 160 <50 <50 <1 <1 60.3 <10 120 <1 <1 <1 <1 <0.001 <0.001 MW-15BR 06/01/2015 NM 8.2 10.87 21 410 1.52 -71 4.75 NM 150 51 7 <5 <1 6.44 6.76 424 429 <5 <1 150 <50 <50 <5 <1 34.4 <10 NA <5 <1 <5 <1 <0.005 <0.001 MW-15BR 06/30/2015 Mixed (oxic-anoxic) 7.9 9.62 18 431 0.52 137 2.32 0 130 15 30 <1 <1 6.6 6.07 369 398 <1 <1 130 <50 <50 <1 <1 31.9 <10 13 <1 <1 <1 <1 <0.001 <0.001 MW-16BRl1'2l 05/20/2015 Mixed (anoxic) 7.7 53.91 16 589 0.17 -149 4.83 NM 180 6 118 <1 <1 2.59 2.5 352 360 <1 <1 170 51 51 <1 <1 41.1 <10 37 <1 <1 <1 <1 <0.001 0.0025 Detections/Samples --- --- --- --- --- --- --- --- --- 12/12 7/9 14/14 0/9 0/14 5/9 7/14 9/9 14/14 0/9 1/12 12/12 3/9 4/14 0/9 1/14 12/14 0/12 13/13 0/9 1/14 5/9 6/12 0/9 3/14 Average Background Concentrations (Detections Only) ___ ___ ___ ___ ___ ___ ___ ___ --- 87.7 36 804 --- --- 3.30 3.15 210 171 --- 10 87 118 163 --- 1.21 43.1 --- 67 --- 3.39 7.8 62 --- 0.010 Maximum Concentration --- --- --- --- --- --- --- --- --- 180.0 82 6850 --- --- 6.60 6.76 424 429 --- 10 170 217 482 --- 1.21 147.0 --- 240 --- 3.39 19.8 387 --- 0.031 Number of Backgroundwater Samples that are Greater Than NCAC 2L --- --- --- --- --- --- --- --- --- 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 6 0 0 Notes: 0- Bold highlighted concentration indicates exceedance of the 15A NCAC 02L, Appendix 2, April 1, 2013. ORP = Oxidation Reduction Potential mg/I = milligrams per liter ug/I = microgram per liter DIS = Dissolved mg-N/L = milligram nitrogen per liter umhos/cm = micro mhos per centimeter TOT = Total my = millivolts Spec Cord = Specific Conductance Temp = Temperature NE = Not established NM = Not Measured DO = Dissolved Oxygen NTU = nephelometric turbidity unit ft = feet Deg C = Degree Celsius S.U. = Standard Unit --- = Not applicable < = concentration not detected at or above the reporting limit. NA = Not analyzed * - Interim Maximum Allowable Concentrations (IMACs) of the 15A NCAC 02L Standard, Appendix 1, April, 1, 2013. Note 1: Hexavalent chromium concentration is less than EPA screening value for tapwater (0.035 ug/L). See Table 10-3 (USEPA Regional Screening Levels [RSLs] rev., June 26, 2015) Note 2: Sampling for hexavalent chromium was conducted independent of site assessment sampling. Prepared by: BE MAH Checked by: VTV P:\Duke Energy Progress.1026\503. Cape Fear Ash Basin GW Assessment\3.11 CSA Reporting\Tables\Table 12-3 Background Wells GW Results.xlsx page 1 of 2 TABLE 12-3 RISK SCREENING TABLE: BACKGROUND GROUNDWATER DATA CAPE FEAR STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, MONCURE, NC Analytical Parameter Iron Lead Magnesium Manganese Mercury Methane Molybdenum Nickel Nitrate (as N) Potassium Selenium Sodium Strontium Sulfate Sulfide Thallium Total Dissolved Solids Total Organic Carbon Total Suspended Solids Vanadium Zinc DIS TOT DIS TOT TOT DIS TOT DIS TOT DIS TOT DIS TOT TOT DIS TOT TOT DIS TOT DIS TOT DIS TOT DIS TOT Reporting Units ug/I ug/I ug/I ug/I mg/I ug/I ug/I ug/I ug/I ug/I ug/I ug/I ug/I ug/I mg-N/L mg/I ug/I ug/I mg/I mg/I mg/I mg/I mg/I ug/I ug/I mg/I mg/I mg/I ug/I ug/I mg/I mg/I 15A NCAC 02L Standard NE 300 NE 15 NE NE So NE 1 NE NE NE NE 100 30 NE NE 20 NE NE NE 250 NE NE 0.2* Soo NE NE NE 0.3- NE 1 Sample ID Sample Collection Date Analytical Results UPPER SURFICIAL BGMW-04 03/04/2015 NA 360 NA <1 NA NA 11 NA <0.05 NA NA NA NA <5 NA NA NA <1 NA NA NA 25 NA NA <0.2 140 NA NA NA NA NA <0.005 BGMW-04 06/08/2015 NA 3810 NA 1.22 7.11 NA 49 NA <0.05 NA NA <1 NA <5 3.5 0.339 NA <1 18.1 NA NA 26 NA NA <0.2 150 NA <5 NA NA NA 0.007 MW-15SU 05/29/2015 NA 2490 NA 2.48 82.3 NA 33700 NA <0.05 <10 NA <1 NA ISO 0.623 0.623 NA 1.45 293 NA 1.27 1600 <1 NA 0.218 NA 7.4 NA NA 4.57 NA 0.288 MW-15SL 05/29/2015 45000 45500 <1 <1 3.62 4600 4560 <0.05 <0.05 11 <1 <1 1.53 1.69 0.018 1.57 <1 <1 15.6 0.132 0.133 80 <0.1 <0.2 <0.2 210 1.3 27 <0.3 <0.3 0.005 <0.005 MW-15SL 06/30/2015 37300 38400 <1 <1 2.88 3800 3860 <0.05 <0.05 <10 <1 <1 <1 <1 0.026 1.42 <1 <1 15.5 0.113 0.114 52 <0.1 <0.2 <0.2 190 1.2 30 <0.3 0.383 <0.005 <0.005 MW-16SI','l 05/20/2015 35 93 <1 <1 26 319 202 <0.05 <0.05 <10 <1 <1 5.14 3.14 0.018 0.992 <1 <1 83.1 0.428 0.624 44 <0.1 <0.2 <0.2 630 0.706 <5 0.954 1.1 0.005 <0.005 MW-16S DUP 05/20/2015 33 72 <1 11 26 305 207 <0.05 <0.05 110 <1 <1 4.59 2.95 1 0.015 0.943 <1 <1 82.2 0.41 0.627 44 10.1 <0.2 <0.2 620 0.747 <5 0.827 1.05 <0.005 <0.005 BEDROCK BGTMW-04 03/04/2015 NA 111 NA <1 NA NA 172 NA <0.05 NA NA NA NA <5 NA NA NA <1 NA NA NA 5.7 NA NA <0.2 180 NA NA NA NA NA <0.005 BGTMW-04 06/08/2015 NA 57 NA <1 8.14 NA 59 NA <0.05 NA NA 4.22 NA <5 0.05 2.28 NA <1 22.1 NA NA 8.1 NA NA <0.2 180 NA <5 NA NA NA <0.005 MW-0911'2l 06/30/2015 1130 1800 <1 <1 30.3 792 826 <0.05 <0.05 25 <1 <1 2.21 1.8 <0.01 0.962 <1 <1 61.4 0.506 0.538 41 <0.1 <0.2 <0.2 660 1.3 <5 <0.3 <0.3 0.01 0.01 MW-09BRIt,2i 05/30/2015 268 441 <1 <1 24.1 805 829 <0.05 <0.05 <10 <1 <1 <1 <1 <0.01 2.1 <1 <1 37.2 0.68 0,677 7.9 <0.1 <0.2 <0.2 410 0.517 5 <0.3 <0.3 0.017 <0.005 MW-15BR 06/01/2015 <10 <10 <5 <1 8.49 72 72 <0.05 <0.05 14 16.9 17 <5 <1 NA 1.48 <5 2.02 36.7 0.498 0.501 NA <0.1 <1 <0.2 NA NA NA 1.81 1.73 <0.005 <0.005 MW-15BR 06/30/2015 15 31 <1 <1 8.24 65 69 <0.05 <0.05 <10 11.8 11.5 <1 <1 2.7 1.69 1.95 1.98 42.9 0.469 0.493 37 <0.1 <0.2 <0.2 260 0.371 <5 2 1.82 <0.005 <0.005 MW-1680,2I 05/20/2015 187 329 <1 <1 13.9 332 326 <0.05 <0.05 11 2.89 2.97 <1 <1 <0.01 2.49 <1 <1 57.3 0.494 0.505 41 <0.1 <0.2 <0.2 340 0.892 <5 <0.3 <0.3 <0.005 <0.005 Detections/Samples 8/9 13/14 0/9 2/14 12/12 9/9 14/14 0/9 0/14 4/10 3/10 4/12 4/9 5/14 8/11 12/12 1/9 3/14 12/12 9/9 10/10 13/13 0/10 0/9 1/14 12/12 9/9 3/10 4/10 6/10 4/9 3/14 Average Background Concentrations (Detections Only) 9330 6678 --- 1.85 18.5 1109 2996 --- --- 12 10.5 8.9 3.36 31.9 0.87 1.41 1.95 1.82 63.8 0.418 0.548 154.7 --- --- 0.218 330 1.60 15.5 1.40 1.78 0.009 0.102 Maximum Concentration 45000 45500 --- 2.48 82.3 4600 33700 --- --- 25 16.9 17.0 5.14 ISO 3.50 2.49 1.95 2.02 293.0 0.680 1.27 1600 --- --- 0.218 660 7.40 30.0 2.00 4.57 0.017 0.288 Number of Backgroundwater Samples that are Greater Than NCAC 2L 0 8 0 0 0 0 12 0 0 0 0 0 0 1 0 0 0 0 0 0 0 1 0 0 1 3 0 0 0 6 0 0 Notes: 0 - Bold highlighted concentration indicates exceedance of the 15A NCAC 02L, Appendix 2, April 1, 2013 ORP = Oxidation Reduction Potential mg/I = milligrams per liter ug/I = microgram per liter DIS = Dissolved mg-N/L = milligram nitrogen per liter umhos/cm = micro mhos per centimeter TOT = Total my = millivolts Spec Cord = Specific Conductance Temp = Temperature NE = Not established NM = Not Measured DO = Dissolved Oxygen NTU = nephelometric turbidity unit ft = feet Deg C = Degree Celsius S.U. = Standard Unit --- = Not applicable < = concentration not detected at or above the reporting limit. NA = Not analyzed * - Interim Maximum Allowable Concentrations (IMACs) of the 15A NCAC 02L Standard, Appendix 1, April, 1, 2013. Note 1: Hexavalent Chromium concentration is less than EPA screening value for tapwater (0.035 ug/L). See Table 10-3 (USEPA Regional Screening Levels [RSLs] rev., June 26, 2015) Note 2: Sampling for hexavalent chromium was conducted independent of site assessment sampling. Prepared by: BE MAH Checked by: VTV P:\Duke Energy Progress.1026\503. Cape Fear Ash Basin GW Assessment\3.11 CSA Reporting\Tables\Table 12-3 Background Wells GW Results.xlsx page 2 of 2 TABLE 12-4 RISK SCREENING TABLE: SURFICIAL GROUNDWATER DATA CAPE FEAR STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, MONCURE, NC Analytical Parameter Redox Assignment PH Water Level Temp Spec Cond DO ORP Eh Turbidity Ferrous Iron Alkalinity Aluminum Antimony Arsenic Barium Beryllium gi- carbonate Alkalinity ron CadE2' Calcium Carbonate Alkalinity Chloride Chromium Cr(III)/Cr(VI) Cobalt Copper Iron DIS TOT DIS TOT DIS TOT DIS TOT DIS TOT jDI;S, TOT DIS TOT DIS TOT Reporting Units None S.U. ft Deg C u��rOSmg/I mV mV NTU mg/I mg/1 ug/I ug/I ug/I ug/I ug/I ug/I ug/I ug/I ug/I ug/I mg/I ug/I ug/Img/I mg/I mg/1 ug/I ug/I ug/I ug/I mg/I mg/I ug/I ug/I 15A NCAC 02L Standard NE 6.5-8.5 NE NE NE NE NE NE NE NE NE NE NE NE 1* NE SO NE 700 NE 4* NE 700 NE NE NE 250 NE SO NE 1* NE 1 NE 300 Sample ID Sample Collection Date Field Parameters Analytical Results ABMW-015I4,5l 05/08/2015 Suboxic 11.2 27.41 27 788 0.35 -133 72 0.91 NM 100 602 720 1.67 1.85 28.5 27.7 90 94 <1 <1 55 2970 2930 <1 <1 94 41 20 <1 <1 <1 <1 <0.001 <0.001 <10 14 ABMW-02SLI4,al 05/20/2015 Anoxic 6.2 9.16 17 1785 0.37 32 237 3.69 NM 39 8 69 <1 <1 1.18 <1 14 15 <1 <1 39 <50 <50 <1 <1 8.72 <10 6.6 <1 <10 4.17 <1 <0.001 <0.01 3260 3450 ABMW-02SUI4''i 05/20/2015 Mixed (oxic-anoxic) 3.8 8.75 20 765 6.03 143 348 4.24 NM <10 1980 2090 <1 <1 <1 <1 27 28 <1 <1 <10 200 198 <1 <1 21 <10 39 <1 <1 18 19 0.0024 0.0024 16800 15900 ABMW-03SI4.31 05/27/2015 Oxic 11.7 17.54 21 3186 1.22 -39 166 0.86 NM 600 549 537 <1 <1 <1 1.09 643 638 <1 <1 <10 206 205 <1 <1 236 280 18 7.96 8.68 <1 <1 0.0078 0.0089 <10 21 ABMW-04SI4'si 05/14/2015 Anoxic 6.2 19.53 18 413 0.24 -75 130 2.67 NM 120 23 43 <1 <1 1.55 1.62 66 94 <1 <1 120 <50 <50 <1 <1 26.8 <10 23 <1 <1 1 1.02 <0.001 <0.001 18000 18000 ABMW-05S(4•11 06/02/2015 Anoxic 6.0 24.75 18 1991 0.33 -133 72 3.16 1 NM 110 167 225 <1 <1 <1 <1 55 61 <1 <1 110 177 187 1.05 <1 236 <10 25 <1 <1 326 327 <0.001 <0.001 96800 99600 ABMW-05S DUP 06/02/2015 Anoxic 6.0 24.75 1 18 1 1991 0.33 1 -133 72 3.16 NM 110 173 222 <1 I <1 <1 <1 58 61 <1 <1 110 1 184 187 1,06 1 <1 231 1 <10 25 1 <1 <1 1 349 325 <0.001 <0.001 99300 103000 CMW-01 03/04/2015 NM 6.1 5.80 16 400 0.08 -54 151 13.2 NM NA NA 176 NA <1 NA <1 NA 156 NA NA NA NA 1380 NA <1 NA NA 29 NA <5 NA NA NA <0.005 NA 28700 CMW_01(4,$) 06/09/2015 NM 6.2 8.26 20 517 0.16 -189 16 8.84 NM 178 NA 299 NA <1 NA <1 NA 229 NA <1 178 NA 1830 NA <1 25 <5 16 NA <5 NA <1 NA <0.005 NA 52700 CMW-02 03/04/2015 NM 5.3 8.70 13 965 0.32 224 429 9.08 NM NA NA 38 NA <1 NA <1 NA 20 NA NA NA NA 71 NA <1 NA NA 20 NA <5 NA NA NA <0.005 NA 792 CMW-02 06/09/2015 NM 5.3 10.52 19 947 0.57 -43 162 1.9 NM 23.9 NA 32 NA <1 NA <1 NA 23 NA <1 23.9 NA 78 NA <1 108 <5 28 NA <5 NA 1.82 NA <0.005 NA 796 CMW-02 06/17/2015 NM 5.3 10.96 19 974 0.4 -58 147 323 NM NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA CMW-03 03/04/2015 NM 6.2 14.70 1 12 1 851 0.82 74 279 2.51 NM NA NA 32 NA <1 NA <1 NA 53 NA NA NA NA 969 NA <1 NA NA 34 NA <5 NA NA NA <0.005 NA 129 CMW-03 06/09/2015 NM 6.1 14.98 19 442 2.74 31 236 1.54 NM 61.2 NA 50 NA <1 NA <1 NA 55 NA <1 61.2 NA 653 NA <1 45.9 <5 36 NA <5 NA <1 NA <0.005 NA 55 CMW-05 03/04/2015 NM 6.1 11.90 15 230 3.77 89 294 35.6 NM NA NA 2970 NA <1 NA <1 NA 72 NA NA NA NA 359 NA <1 NA NA 10 NA <5 NA NA NA 0.005 NA 2650 CMW-05 06/09/2015 NM 5.9 15.11 20 201 3.32 -14 191 47.6 NM 28.1 NA 154 NA <1 NA <1 NA 32 NA <1 28.1 NA <50 NA <1 2.59 <5 8.8 NA <5 NA <1 NA <0.005 NA 99 CMW-06 03/04/2015 NM 6.2 4.09 15 462 0.26 9 214 44.4 NM NA NA 4380 NA <1 NA <1 NA 21 NA NA NA NA 413 NA <1 NA NA 23 NA <5 NA NA NA 0.008 NA 5050 CMW-06"") 06/09/2015 NM 6.7 4.94 18 623 0.3 -189 16 6.27 NM 61.2 NA 388 NA <1 NA <1 NA 18 NA <1 61.2 NA 1560 NA <1 9.5 <5 16 NA <5 NA 1.14 NA <0.005 NA 556 CMW-07 03/04/2015 NM 5.1 21.62 1 17 1 67 0.16 1 139 344 1 29 NM NA NA 1110 NA <1 NA <1 NA 59 NA NA NA NA <50 NA <1 NA NA 3.2 NA <5 NA NA NA <0.005 NA 2460 CMW-07 06/09/2015 NM 5.6 23.54 19 282 0.38 -131 75 9.1 NM 28.3 NA 415 NA <1 NA 1.1 NA 162 NA <1 28.3 NA 98 NA <1 9.57 <5 22 NA <5 NA 16.5 NA <0.005 NA 10300 CMW-08 03/04/2015 NM 6.4 6.68 15 724 0.16 -84 122 63.7 NM NA NA 126 NA <1 NA <1 NA 221 NA NA NA NA 1250 NA <1 NA NA 14 NA <5 NA NA NA <0.005 NA 49200 CMW-08"") 06/09/2015 NM 6.3 8.92 23 694 0.29 -85 120 22 NM 163 NA 131 NA <1 NA <1 NA 209 NA <1 163 NA 1300 NA <1 38.4 <5 14 NA <5 NA 3.89 NA <0.005 NA 41800 MW-1014'si 07/01/2015 Anoxic 5.8 13.36 18 1360 0.28 -114 91 3.01 2 120 8 27 <1 <1 <1 I <1 28 29 <1 <1 120 692 922 <1 <1 158 <10 23 <1 <1 19.8 21 <0.001 <0.001 2540 2800 MW-11 07/01/2015 Anoxic 6.2 13.34 21 815 0.18 -148 57 4.65 2 160 6 76 <1 <1 <1 <1 58 59 <1 <1 1 160 <50 <50 <1 <1 53.5 <10 22 <1 <1 <1 1 1.03 1 <0.001 <0.001 2750 3810 MW-12(4,$) 06/30/2015 Mixed (anoxic) 6.7 12.46 22 1 12 0.24 1 -165 1 41 2.1 0.5 210 <5 <5 <1 <1 <1 <1 54 55 <1 <1 210 465 448 <1 <1 35.3 <10 59 <1 <1 2.64 2.43 <0.001 <0.001 414 456 MW-13 06/29/2015 Mixed (anoxic) 5.8 11.64 18 432 0.33 136 341 2.88 0.5 60 14 206 <3 <1 <1 <1 84 102 <3 <1 60 223 319 <1 <1 24.1 <10 28 <1 <1 1.2 1.46 0.0018 <0.001 127 248 MW-17SL""i 03/19/2015 Anoxic 6.0 7.23 14 1189 0.29 -50 155 4.76 6.5 83 203 525 <1 <1 <1 <1 118 126 <1 <1 83 <50 <50 <1 <1 80.9 <10 17 <1 <1 6.3 6.76 <0.001 <0.001 174000 175000 MW-17SU13,5) 03/19/2015 Mixed (anoxic) 5.0 8.15 13 1129 0.33 63 268 4.46 2.5 11 566 607 <1 <1 <1 <1 43 42 1.21 1.3 it <50 <50 <1 <1 110 <10 38 <1 <1 247 241 0.0027 0.0024 2560 2620 MW-18S 06/03/2015 Mixed (oxic-anoxic) 7.1 5.00 17 725 1.68 -10 195 2.99 NM 100 <5 325 <1 <1 <1 I <1 8 1 10 1 <1 <1 100 173 1 180 <1 <1 10.5 <10 29 <1 <1 <1 <1 0.0082 <0.001 <10 288 MW-195 03/11/2015 Oxic 5.3 4.50 15 66 7.05 164 369 19.6 0 <10 55 998 <1 <1 <1 <1 34 47 <1 <1 <10 <50 <50 <1 <1 1.29 <10 15 <1 <1 <1 <1 I <0.001 <0.001 16 486 MW-20514'si 05/21/2015 Anoxic 6.3 9.86 1 16 1 474 0.14 1 -24 181 1 4.98 1 NM 130 11 190 <1 <1 <1 <1 164 163 <1 <1 130 <50 <50 <1 <1 29.4 <10 29 <1 <1 <1 <1 <0.001 <0.001 4040 4270 MW-21SLI3.3i 05/07/2015 Mixed (anoxic) 5.7 10.03 17 1476 0.22 80 285 1.24 NM 63 9 38 <1 <1 <1 <1 39 30 <1 <1 63 57 60 <1 <1 170 <10 23 <1 <1 15.7 18.7 <0.001 <0.001 580 731 MW-21SUi3's1 05/07/2015 Mixed (oxic-anoxic) 4.1 10.21 22 497 3.96 155 360 2.51 NM <10 8070 8180 <1 <1 1.92 4.15 26 27 9.89 8.94 <10 <50 <50 <1 <1 37.7 <10 5.5 <1 <1 173 180 0.0238 0.022 65 181 PZ-01 08/06/2015 Anoxic 6.1 4.88 22 881 0.15 -35 170 8.1 NM 160 22 62 <3 <1 <1 <1 28 30 <1 <1 160 620 650 <1 <1 57.5 <10 19 <1 <1 4.57 4.35 <0.001 <0.001 13500 14700 PZ-02 08/06/2015 Mixed (anoxic) 6.3 6.33 21 632 0.33 55 260 4.08 NM 71 14 167 <1 I <1 <1 <1 1 50 53 1 <1 <1 71 3670 3810 <1 <1 30.5 <10 19 <1 <1 7.7 8.24 0.0083 0.0014 678 1140 PZ-02 DUP 08/06/2015 Mixed (anoxic) 6.3 6.33 21 632 0.33 55 260 4.08 NM 72 9 76 <1 <1 <1 <1 50 53 <1 <1 72 3680 3830 1 <1 <1 30.3 <10 19 <1 <1 7.9 7.8 0.0023 0.0013 687 763 PZ-03S 08/05/2015 Anoxic 7.4 5.84 1 23 1 918 0.16 1 67 272 1 4.96 1 NM 170 <5 275 <1 <1 <1 <1 13 15 <1 <1 170 2440 2440 <1 <1 20.6 <10 67 <1 <1 <1 <1 1 0.009 1 <0.001 15 255 PZ-04 08/05/2015 Anoxic 6.4 9.33 22 747 0.34 -85 120 4.96 NM 130 <5 87 <1 <1 <1 <1 35 36 <1 <1 130 1460 1440 <1 <1 33.9 <10 55 <1 <1 1.3 1.31 0.0019 <0.001 1080 1290 PZ-05 08/05/2015 Mixed (oxic-anoxic) 5.4 2.13 24 692 0.68 214 419 4.1 NM 28 8 87 <1 <1 <1 <1 25 26 <1 <1 28 4770 4910 11 <1 36.5 <10 28 <1 <1 7.67 8.24 0.0083 <0.001 75 200 PZ-09 08/06/2015 Mixed (anoxic) 4.6 12.10 19 358 0.2 370 575 13 NM <10 349 1110 <1 <1 <1 I <1 41 44 <1 <1 <10 86 103 <1 <1 18.4 <10 29 1.5 1.91 27.3 28.4 0.0063 0.0069 18 1170 DETECTIONS/SAMPLES --- --- --- --- --- --- --- --- --- --- 28/33 21/25 38/39 1/25 1/39 4/25 5/39 25/25 39/39 2/25 2/32 27/32 17/25 29/39 2/25 0/39 32/32 2/32 39/39 2/25 2/39 18/25 22/32 21/40 9/39 22/25 39/39 AVERAGE SURFICIAL WATER CONCENTRATION (DETECTIONS ONLY) --- --- --- --- --- --- --- --- --- --- 114.0 611.7 716.9 1.7 1.9 8.29 7.13 74.8 83.8 5.55 5.1 94.3 1,310.2 1,130.3 1.1 --- 63.5 160.5 24.1 4.7 1.3 67.8 55.7 0.0069 0.0065 19,11711.4 16,555.9 MAXIMUM SURFICIAL WATER GROUNDWATER CONCENTRATION ___ ___ ___ ___ ___ ___ ___ ___ ___ ___ 600.0 8,070.0 8,180.0 1.7 1.9 28.50 27.70 643.0 638.0 9.89 8.9 210.0 4,770.0 4,910.0 1.1 --- 236.0 280.0 67.0 8.0 8.7 349.0 327.0 0.0238 0.0220 174,000.0 175,000.0 NUMBER OF SURFICIAL WATER SAMPLES EXCEEDING 21---- --- --- --- --- --- 0 0 0 0 I 1 0 1 0 0 0 1 0 0 13 0 0 0 0 0 0 0 0 22 0 0 0 29 P:\Duke Energy Progress.1026\103. Cape Fear Ash Basin GW Assessment\1.11 CSA Reporting\Tables\Table 12-4 Surficial GW Results KDF.xlsx Page 1 of 4 TABLE 12-4 RISK SCREENING TABLE: SURFICIAL GROUNDWATER DATA CAPE FEAR STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, MONCURE, NC Water Ferrous Aluminum Antimony Arsenic Barium Beryllium gi- ron CadmE2/ Calcium Carbonate Chromium Cobalt Copper Iron Analytical Parameter Redox Assignment PH Temp Spec Cond DO ORP Eh Turbidity Alkalinity carbonate Chloride E.r(III)/Cr(VI) Level Iron Alkalinity Alkalinity DIS TOT DIS TOT DIS TOT DIS TOT DIS TOT jDI;S, TOT DIS TOT DIS TOT Reporting Units None S.U. ft Deg C o. u/cmmg/I my mV NTU mg/I mg/1 ug/I ug/I ug/I ug/I ug/I ug/I ug/I ug/I ug/I ug/I mg/I ug/I ug/Img/I mg/I mg/1 ug/I ug/I ug/I ug/I mg/I mg/I ug/I ug/I SSA NCAC 02L Standard NE 6.S-8.5 NE NE NE NE NE NE NE NE NE NE NE NE 1* NE SO NE 700 NE 4* NE 700 NE NE NE 2S0 NE SO NE 1* NE 1 NE 300 Sample ID Sample Field Parameters Analytical Results Collection Date Detections/Samples --- --- --- --- --- --- --- --- --- 12/14 7/9 14/14 0/9 0/14 5/9 7/14 9/9 14/14 0/9 1/12 12/12 3/9 4/14 0/9 1/14 12/14 0/12 13/13 0/9 1/14 5/9 6/12 0/9 3/14 8/9 13/14 Average Background Concentrations (Detections Only) ___ ___ ___ ___ ___ ___ ___ ___ ___ 87.7 36 804 --- --- 3.30 3.15 210 171 --- 10 87 118 163 --- 1.21 43.1 --- 67 --- 3.39 7.8 62 --- 0.010 9330 6678 Maximum Concentration --- --- --- --- --- --- --- --- --- 180.0 82 68SO --- --- 6.60 6.76 424 429 --- SO 170 217 482 --- 1.21 147.0 --- 240 --- 3.39 19.8 387 --- 0.031 45000 45500 Number of Backgroundwater Samples that are Greater Than --- --- --- --- --- --- --- --- --- 0 O O 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 6 0 O O 8 NCAC 2L Notes: - Analytical method detection limit is greater than 15A NCAC 02L groundwater criteria - Bold highlighted concentration Indicates exceedance of the 15A NCAC 02L Appendix 2, April 1, 2013. - Indicates support/rationale for soil COPC attributable to coal ash. _ - Indicates constituent is not a soil COPC attributable to coal ash. ORP = Oxidation Reduction Potential my = millivolts DIS = Dissolved NE = Not established TOT = Total Temp = Temperature NTUS = nephelometric turbidity unit S.U. = Standard Unit DO = Dissolved Oxygen ug/I = microgram per liter Deg C = Degree Celsius umhos/cm = micro siemens per centimeter mg/I = milligrams per liter Spec Cord = Specific Conductance mg-N/L = miligram nitrogen per liter ft = feet < = concentration not detected at or above the reporting limit. * - Interim Maximum Allowable Concentrations (IMACs) of the 15A NCAC 02L Appendix 1, April, 1, 2013. --- = Not applicable Coal Ash CC NCAC Surficial Aquifer Water conc. > NCAC Surficial Aquifer CC Note 1: Consitituent is retained as a COPC if analytical method detection limit or concentration is greater than the groundwater criteria Note 2: Constituent is retained as a COPC if no groundwater criteria Note 3: Hexavalent Chromium concentration is greater than EPA screening value for tapwater (0.035 ug/L). See Table 10-3 (USEPA Regional Screening Levels [RSLs] rev., June 26, 2015) Note 4: Hexavalent Chromium concentration is less than EPA screening value for tapwater (0.035 ug/L). See Table 30-3 (USEPA Regional Screening Levels [RSLs] rev., June 26, 2015) Note 5: Speciation Sample date does not match listed sample collection date P:\Duke Energy Progress.1026\103. Cape Fear Ash Basin GW Assessment\l.11 CSA Reporting\Tables\Table 12-4 Surficial GW Results KDF.xlsx Page 2 of 4 TABLE 12-4 RISK SCREENING TABLE: SURFICIAL GROUNDWATER DATA CAPE FEAR STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, MONCURE, NC Analytical Parameter Lead Magnesium Manganese Mercury Methane Molybdenum Nickel Nitrate (as N) Potassium Selenium Sodium Strontium Sulfate Sulfide Thallium Total Dissolved Solids Total Organic Carbon Total Suspended Solids Vanadium Zinc DIS TOT TOT DIS TOT DIS TOT DIS I TOT DIS TOT TOT DIS TOT TOT DIS TOT DIS TOT DIS TOT DIS TOT Reporting Units ug/I ug/I mg/I ug/I ug/l ug/l ug/I ug/l ug/l ug/I ug/I ug/l mg-N/L mg/l ug/l ug/l mg/l mg/1 mg/I mg/I mg/I ug/I ug/I mg/I m9/1 mg/I ug/I ug/1 mg/I mg/I 15A NCAC 02L Standard NE 15 NE NE 50 NE 1 NE NE NE NE 100 10 NE NE 20 NE NE NE 250 NE NE 0.2* Soo NE NE NE 0.3* NE 1 Sample ID Sample Collection Date Analytical Results ABMW-OIS1"'si 05/08/2015 <1 <1 1.51 <5 <5 <0.05 <0.05 <10 1230 1240 4.26 4.5 <0.01 5.53 3.86 3.4 22.1 0.644 0.655 130 <0.1 <0.2 <0.2 360 1.8 <5 63.1 73.3 <0.005 <0.005 ABMW-02SLI4,3i 05/20/2015 <1 <10 4.25 493 519 <0.05 <0.05 <10 <1 <10 6.83 QO 0.271 1.09 <1 <10 9.47 0.028 0.03 14 <0.1 <0.2 <0.2 100 0.898 <5 <0.3 <0.3 0.053 0.638 ABMW-02SUi4,1I 05/20/2015 6.16 6.24 8.71 1560 1540 <0.05 <0.05 30 <1 <1 14.4 14.8 0.03 3.66 <1 <1 79.9 0.552 0.549 270 <0.5 <0.2 <0.2 440 2.5 <5 <0.3 <0.3 0.036 0.037 ABMW-03S14•al 05/27/2015 <1 <1 0.072 <5 <5 <0.05 <0.05 160 51 56 4.51 5.72 0,016 43.5 1.39 1.73 67.8 2.12 2.05 58 <0.1 <0.2 0.22 780 6.2 8 2.34 2.53 <0.005 <0.005 ABMW-04SI"'sl 05/14/2015 <1 <1 11.5 1070 1110 <0.05 <0.05 50 1.09 1.27 <1 <1 0.025 0.525 1.47 <1 13.5 0.143 0.153 5 <0A <0.2 <0.2 230 1.7 <5 <0.3 0.328 <0.005 <0.005 ABMW-05514•11 06/02/2015 <1 <1 81.1 31100 32400 <0.05 <0.05 19 1.42 1.69 145 147 0.021 4.35 <1 <1 43.4 1.57 1.7 1400 <0.5 0.365 0.306 1600 1.5 25 <0.3 <0.3 0.256 0.249 ABMW-05S DUP 06/02/2015 1 <1 <1 1 79.3 32000 1 33700 <0.05 <0.05 18 1 1.73 1 1.84 154 1 149 0.021 1 4.42 <1 <1 44 1.63 1.7 1300 <0.2 1 0.369 0.317 1700 1 1.5 22 0.339 <0.3 0.264 0.25 CMW-01 03/04/2015 NA <1 NA NA 1390 NA <0.05 NA NA NA NA 5 NA NA NA <1 NA NA NA 2.1 NA NA <0.2 200 NA NA NA NA NA <0.005 CMW-01(4's) 06/09/2015 NA <1 13.1 NA 1250 NA <0.05 NA NA <1 NA <5 <0.023 0.674 NA <1 24.1 NA NA <0.1 NA NA <0.2 240 NA 45 NA NA NA 0.008 CMW-02 03/04/2015 NA <1 NA NA 6380 NA <0.05 NA NA NA NA 71 NA NA NA <1 NA NA NA 430 NA NA <0.2 770 NA NA NA NA NA 0.017 CMW-02 06/09/2015 NA <1 40.3 NA 6760 NA <0.05 NA NA <1 NA 72 0.05 0.882 NA <1 36.2 NA NA 480 NA NA <0.2 780 NA <5 NA NA NA 0.019 CMW-02 06/17/2015 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA CMW-03 03/04/2015 NA <1 NA NA 3200 NA <0.05 NA NA NA NA <5 NA NA NA 8.9 NA NA NA 170 NA NA <0.2 450 NA NA NA NA NA <0.005 CMW-03 06/09/2015 NA <1 10.3 NA 85 NA <0.05 NA NA <1 NA <5 <0.023 2.6 NA 46.8 19.6 NA NA 87 NA NA <0.2 250 NA <5 NA NA NA <0.005 CMW-05 03/04/2015 NA 1.2 NA NA 34 NA <0.05 NA NA NA NA <5 NA NA NA <1 NA NA NA 43 NA NA <0.2 240 NA NA NA NA NA 0.007 CMW-05 06/09/2015 NA <1 0.991 NA <5 NA <0.05 NA NA <1 NA <5 <0.023 <0.1 NA <1 34.7 NA NA 47 NA NA <0.2 200 NA 35 NA NA NA 0.005 CMW-06 03/04/2015 NA <1 NA NA 908 NA <0.05 NA NA NA NA <5 NA NA NA <1 NA NA NA 110 NA NA <0.2 330 NA NA NA NA NA 0.008 CMW-0614's1 06/09/2015 NA <1 8.52 NA 204 NA <0.05 NA NA <1 NA <5 0.03 0.123 NA <1 107 NA NA 160 NA NA <0.2 380 NA 9 NA NA NA 0.014 CMW-07 03/04/2015 NA <1 NA NA 770 NA <0.05 NA NA NA NA <5 NA NA NA <1 NA NA NA 10 NA NA <0.2 67 NA NA NA NA NA 0.006 CMW-07 06/09/2015 NA <1 6.39 NA 2210 NA <0.05 NA NA <1 NA <5 <0.023 0.503 NA <1 32.4 NA NA 72 NA NA <0.2 180 NA 10 NA NA NA 0.01 CMW-08 03/04/2015 NA <1 NA NA 13400 NA <0.05 NA NA NA NA 6 NA NA NA <1 NA NA NA 130 NA NA <0.2 430 NA NA NA NA NA <0.005 CMW-0814,3i 06/09/2015 NA <1 28.9 NA 13000 NA <0.05 NA NA <1 NA <5 <0.023 0.168 NA <1 38.2 NA NA 47 NA NA <0.2 400 NA 56 NA NA NA <0.005 MW-100") 07/01/2015 <1 <1 50.9 11700 12500 <0.05 <0.05 17 <1 <1 3.49 3.55 <0.01 2.72 <1 <1 34.6 1.4 1.46 610 <0.2 <0.2 <0.2 1100 1 <5 <0.3 0.366 <0.005 1 <0.005 MW-11 07/01/2015 <1 <1 36.9 792 912 <0.05 <0.05 460 <1 <1 4.5 4.23 <0.01 0.486 <1 <1 48.5 0.532 1 0.535 1 200 <0.1 <0.2 I <0.2 550 5.8 5 0.372 0.867 <0.005 <0.005 MW-121"'si 06/30/2015 1 <1 <1 26.5 842 1 843 <0.05 <0.05 11 1.42 1.57 1.28 11 <1 0.09 0.136 <1 <1 165 0.258 0.257 260 <0.2 <0.2 <0.2 740 1.2 <5 <0.3 <0.3 0.008 <0.005 MW-13 06/29/2015 <1 <1 15.1 641 820 <0.05 <0.05 <10 <1 <1 3.41 3.31 0.094 0.145 <1 <1 33.4 0.18 0.223 91 <0.2 <0.2 0.297 270 0.91 <5 0.587 1.07 0.204 0.011 MW-17SL1'''' 03/19/2015 <1 <1 24.4 7060 7380 <0.05 <0.05 520 <1 <1 1.37 1.58 0.031 1.06 <1 <1 41.3 0.381 0.389 570 <1 <0.2 <0.2 900 2.9 49 <0.3 0.919 <0.005 <0.005 MW-175U13•11 03/19/2015 <1 <1 47.1 45700 45500 <0.05 <0.05 630 <1 <1 61 59 <0.01 0.711 <1 <1 45.2 0.847 0.801 710 <1 <0.2 <0.2 910 48 <5 <0.3 0.381 0.381 0.362 MW-18S 06/03/2015 <1 <1 10.4 118 137 <0.05 <0.05 <10 <1 <1 <1 <1 <0.01 <0.1 <1 <1 1 121 0.09 0.093 180 <0.1 <0.2 <0.2 450 0.481 6 0.876 1.63 0.013 <0.005 MW-19S 03/11/2015 <1 <1 1.78 19 27 <0.05 <0.05 <10 <1 <1 <1 <1 <0.01 <0.1 <1 <1 7.09 0.029 0.037 2.6 <2 <0.2 I <0.2 54 0.44 19 <0.3 0.81 <0.005 <0.005 MW-20Si4'sl 05/21/2015 <1 <1 1 19.6 1190 1 1210 <0.05 1 <0.05 1 12 <1 <1 <1 <1 0.029 0.341 <1 <1 38.4 0.266 1 0.263 1 52 <0.2 <0.2 <0.2 320 1.6 9 0.682 1.03 0.006 <0.005 MW-21SL13,11 05/07/2015 <1 <1 91.3 2130 2430 <0.05 <0.05 <10 <1 <1 7.6 7.9 <0.01 0.806 <1 <1 60.9 0.611 0.627 930 <0.5 <0.2 <0.2 1300 0.651 <5 <0.3 0.313 0.018 0.024 MW-215U1'•si 05/07/2015 <1 <1 12.9 9240 9720 <0.05 <0.05 <10 <1 <1 51.2 49.1 4.8 3.39 1.53 1.96 9.27 0.517 0.526 300 <0.1 <0.2 0.335 360 2.2 <5 <0.3 <0.3 0.197 0.191 PZ-01 08/06/2015 <1 <1 42.4 4150 4250 <0.05 <0.05 30 <1 <1 4.93 4.46 0.026 0.513 <1 <1 68.1 0.273 0.273 260 <0.1 0.592 <0.2 650 1.1 14 0.309 0.604 0.047 <0.005 PZ-02 08/06/2015 <1 <1 16.9 2320 2440 <0.05 <0.05 <10 <1 <1 6.23 8.58 0.105 0.447 <1 <1 1 67.5 0.311 0.319 180 <0.1 <0.2 <0.2 430 2.9 <5 1 0.818 1.66 0.049 <0.005 PZ-02 DUP 08/06/2015 <1 <1 16.8 2350 2440 <0.05 <0.05 <10 <1 <1 6.26 6.02 0.55 0.438 <1 <1 67.1 0.316 0.322 180 <0.1 I <0.2 I <0.2 450 3.4 <5 0.873 1.27 0.011 <0.005 PZ-03S 08/05/2015 1.1 <1 1 16.6 131 1 182 <0.05 I <0.05 1 22 1.5 1.48 1 <1 <1 0.032 0.146 <1 <1 142 0.187 0.196 170 <0A <0.2 <0.2 590 0.733 <5 1.26 1.97 0.078 <0.005 PZ-04 08/05/2015 <1 <1 25.3 508 519 <0.05 <0.05 38 <1 <1 3.51 9.7 0.038 0.305 <1 <1 88.1 0.338 0.341 150 <0.1 0.351 <0.2 470 1.9 <5 0.432 0.979 0.019 <0.005 PZ-05 08/05/2015 1.26 <1 31.3 2930 2990 <0.05 <0.05 33 <1 <1 6.39 6.53 <0.01 0.316 <1 <1 58.6 0.351 0.358 270 <0.1 <0.2 <0.2 510 0.684 <5 <0.3 0.535 0.026 0.006 PZ-09 08/06/2015 <1 <1 8.3 580 627 <0.05 <0.05 <10 <1 <1 36.9 41.9 0.802 4.94 91.3 96.1 30.1 0.617 0.671 110 <0.1 0.65 0.574 240 1.1 39 <0.3 0.811 0.105 0.099 DETECTIONS/SAMPLES 3/25 2/39 32/32 23/25 36/40 0/25 0/39 15/25 7/25 7/32 20/25 22/39 19/32 29/32 5/25 6/39 32/32 25/25 25/25 38/39 0/25 5/25 6/39 39/39 25/25 15/32 12/25 19/25 18/25 19/39 AVERAGE SURFICIAL WATER CONCENTRATION (DETECTIONS ONLY) 2.84 3.72 24.7 6,896.7 5,938.5 --- --- 136.7 184.0 186.3 26.4 30.9 0.372 2.928 19.91 26.49 53.1 0.568 0.581 268.2 --- 0.465 0.342 523.6 3.72 23.4 5.999 4.8 0.098 0.103 MAXIMUM SURFICIAL WATER GROUNDWATER CONCENTRATION 6.16 6.24 91.3 45,700.0 45,500.0 --- --- 630.0 1,230.0 1,240.0 154.0 149.0 4.800 43.500 91.30 96.10 165.0 2.120 2.050 1,400.0 --- 0.650 0.574 1,700.0 48.00 56.0 63.100 73.3 0.381 0.638 NUMBER OF SURFICIAL WATER SAMPLES EXCEEDING 2L 0 0 0 0 34 0 0 0 0 0 0 2 0 0 0 1 0 0 0 13 0 0 5 14 0 0 0 19 0 0 P:\Duke Energy Progress.1026\103. Cape Fear Ash Basin GW Assessment\1.11 CSA Reporting\Tables\Table 12-4 Surficial GW Results KDF.xlsx Page 3 of 4 TABLE 12-4 RISK SCREENING TABLE: SURFICIAL GROUNDWATER DATA CAPE FEAR STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, MONCURE, NC Lead Magnesium Manganese Mercury Molybdenum Nickel Nitrate Potassium Selenium Sodium Strontium Thallium Total Total Total Vanadium Zinc Analytical Parameter Methane (as N) Sulfate Sulfide Dissolved Solids Organic Carbon Suspended Solids DIS TOT 707 DIS TOT DIS TOT DIS TOT DIS TOT TOT DIS TOT TOT DIS TOT DIS TOT DIS TOT DIS TOT Reporting Units ug/I ug/I mg/I ug/I ug/I ug/I ug/1 ug/I ug/I ug/I ug/1 ug/I mg-N/L mg/I ug/1 ug/l mg/I mg/I mg/I mg/l mg/1 ug/I ug/I mg/I mg/I mg/I ug/I ug/I mg/I mg/I SSA NCAC 02L Standard NE 15 NE NE 50 NE 1 NE NE NE NE 300 20 NE NE 20 NE NE NE 250 NE NE 0.2* Soo NE NE NE 0.3* NE 1 Sample ID Sample Analytical Results Collection Date Detections/Samples 0/9 2/14 12/12 9/9 14/14 0/9 0/14 4/10 3/10 4/12 4/9 5/14 8/11 12/12 1/9 3/14 12/12 9/9 10/10 13/13 0/10 0/9 1/14 12/12 9/9 3/10 4/10 6/10 4/9 3/14 Average Background Concentrations (Detections Only) 1.85 18.5 1109 2996 --- --- 12 10.5 8.9 3.36 31.9 0.87 1.41 1.95 1.82 63.8 0.418 0.548 154.7 --- --- 0.218 330 1.60 15.5 1.40 1.78 0.009 0.102 Maximum Concentration --- 2.48 82.3 4600 33700 --- --- 25 16.9 17.0 5.14 ISO 3.50 2.49 1.95 2.02 293.0 0.680 1.27 1600 --- --- 0.218 660 7.40 30.0 2.00 4.57 0.017 0.288 Number of Backgroundwater Samples that are Greater Than NCAC 2L O 0 O 0 12 0 O O O O O 1 0 0 O 0 O O 0 1 0 0 1 3 0 0 O 6 0 0 Coal Ash �u r, u.,ai Hyu i-Srwcial Aquifer COP( Notes: - Analytical method detection limit is greater than 15A NCAC 02L groundwater criteria - Bold highlighted concentration Indicates exceedance of the 15A NCAC 02L Appendix 2, April 1, 2013. - Indicates support/rationale for soil COPC attributable to coal ash. _ - Indicates constituent is not a soil COPC attributable to coal ash. ORP = Oxidation Reduction Potential my = millivolts DIS = Dissolved NE = Not established TOT = Total Temp = Temperature NTUS = nephelometric turbidity unit S.U. = Standard Unit DO = Dissolved Oxygen ug/I = microgram per liter Deg C = Degree Celsius umhos/cm = micro siemens per centimeter mg/I = milligrams per liter Spec Cord = Specific Conductance mg-N/L = miligram nitrogen per liter ft = feet < = concentration not detected at or above the reporting limit. * - Interim Maximum Allowable Concentrations (IMACs) of the 15A NCAC 02L Appendix 1, April, 1, 2013. --- = Not applicable Note 1: Consitituent is retained as a COPC if analytical method detection limit or concentration is greater than the groundwater criteria Note 2: Constituent is retained as a COPC if no groundwater criteria Note 3: Hexavalent Chromium concentration is greater than EPA screening value for tapwater (0.035 ug/L). See Table 10-3 (USEPA Regional Screening Levels [RSLs] rev., June 26, 2015) Note 4: Hexavalent Chromium concentration is less than EPA screening value for tapwater (0.035 ug/L). See Table 10-3 (USEPA Regional Screening Levels [RSLs] rev., June 26, 2015) Note 5: Speciation Sample date does not match listed sample collection date P:\Duke Energy Progress.1026\103. Cape Fear Ash Basin GW Assessment\1.11 CSA Reporting\Tables\Table 12-4 Surficial GW Results KDF.xlsx Page 4 of 4 TABLE 12-5 RISK SCREENING TABLE: BEDROCK GROUNDWATER DATA CAPE FEAR ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, MONCURE NC Analytical Parameter Redox Assignment PH Water Level Temp Spec Cond DO ORP Eh Turbidity Ferrous Iron Alkalinity Aluminum Antimony Arsenic Barium Beryllium gi- carbonate Alkalinity Boron Cadmium Calcium Carbonate Alkalinity Chloride Chromium Cr(III)/Cr(VI) Cobalt Copper Iron DIS TOT DIS TOT DIS TOT DIS TOT DIS TOT DIS TOT TOTReporting Units None S.U. ft Deg C u/crosmg/I mV mV NTUs mg/l mg/I ug/I ug/I ug/I ug/I ug/I ug/I ug/I ug/I ug/I ug/I mg/1 ug/I ug/I JISTOT' g/I mg/I mg/I15A NCAC 2L Standard NE 6.5-8.5 NE NE NE NE NE NE NE NE NE NE NE NE 1* NE SO NE 700 NE 4* NE NE 700 NE NE 250 NE SO NE 1* NE 1 NE 300 Sample ID Sample ection Date Coll Field Parameters Analytical Results BEDROCK ABMW-OIBRI'•'I 05/08/2015 Anoxic 8.1 28.07 28 639 0.37 -138 67 4 NM 120 7 103 <1 <i 5.34 5.64 119 124 <1 <i 120 1010 891 <1 <1 64.7 <10 23 <1 <1 <1 <1 <0.001 <0.001 72 173 ABMW-03BRI4•sl 05/19/2015 Anoxic 7.1 22.84 19 863 0.13 -72 133 8.44 NM 250 <5 177 <1 <1 1.2 1.28 127 129 <1 <1 240 189 188 <1 <1 96.7 <10 31 <1 <1 <1 <1 <0.001 <0.001 1400 1660 ABMW-05BR14•11 05/19/2015 Anoxic 6.2 24.58 21 329 0.14 -264 -59 4.68 NM 140 13 88 <1 <1 2.76 2.58 295 310 <1 <1 140 55 54 <1 <1 23.5 <10 5 <1 <1 <1 <1 <0.001 <0.001 21 129 CTMW-01 03/04/2015 NM 7.1 5.20 18 707 0.37 -54 151 5.48 NM NA NA 9 NA <1 NA <1 NA 185 NA NA NA NA 379 NA <1 NA NA 33 NA <5 NA NA NA <0.005 NA 874 CTMW-0114•1l 06/09/2015 NM 7.1 7.10 21 700 0.7 -140 65 2.6 NM 191 NA 11 NA <1 NA <1 NA 178 NA <1 191 NA 379 NA <1 104 <5 32 NA <5 NA <1 NA <0.005 NA 385 CTMW-02 03/04/2015 NM 6.2 9.14 14 304 3.19 210 415 3.72 NM NA NA 39 NA <1 NA 7.65 NA 245 NA NA NA NA <50 NA <1 NA NA 3.6 NA <5 NA NA NA 0.006 NA 59 CTMW-02 06/09/2015 NM 6.0 11.45 21 302 2.47 -78 127 4.47 NM 137 NA 105 NA <1 NA 8.69 NA 255 NA <1 137 NA <50 NA <1 20.3 <5 3.6 NA <5 NA <1 NA <0.005 NA 172 CTMW-07 03/04/2015 NM 7.0 23.80 18 576 1.89 28 233 1.26 NM NA NA 27 NA <1 NA 1AS NA 36 NA NA NA NA 53 NA <1 NA NA 31 NA <5 NA NA NA <0.005 NA 50 CTMW-07 06/08/2015 NM 7.2 24.43 22 576 1.88 64 269 0.25 NM 161 NA 14 NA <1 NA 1.5 NA 49 NA <1 161 NA 55 NA <1 62.4 <5 31 NA <5 NA <1 NA <0.005 NA 17 CTMW-08 03/04/2015 NM 7.1 9.58 15 783 0.23 -62 143 1.93 NM NA NA 21 NA <1 NA 6.69 NA 185 NA NA NA NA 382 NA <1 NA NA 16 NA <5 NA NA NA 0.005 NA 2070 CTMW-0814•11 06/09/2015 NM 7.3 11.56 19 759 0.55 -111 94 6.97 NM 260 NA 38 NA <1 NA 4.55 NA 187 NA <1 260 NA 356 NA <1 79.4 <5 16 NA <5 NA <1 NA <0.005 NA 1270 CTMW-08 DUP 03/04/2015 NM 7.1 9.58 15 783 0.23 -62 143 1.93 NM NA NA 16 NA <1 NA 6.61 NA 191 NA NA NA NA 422 NA <1 NA NA 16 NA <5 NA NA NA 0.005 NA 2580 CTMW-08 DUP 06/09/2015 NM 7.3 11.56 19 759 0.55 -111 94 6.97 NM 248 NA 50 NA <1 NA 5.15 NA 193 NA <1 248 NA 368 NA <1 81.1 <5 16 NA <5 NA <1 NA <0.005 NA 1640 MW-05BR 06/18/2015 Oxic 11.2 17.86 21 539 1.34 -165 40 3.44 NM 53 1210 1210 <1 <1 <1 <1 36 37 <1 <1 22 <50 <50 <1 <1 45 25 23 <1 1.07 <1 <1 0.00527 <0.001 <10 39 MW-06BR 06/03/2015 Mixed (oxic-anoxic) 7.6 5.40 19 1294 0.78 -193 12 4.64 NM 160 8 82 <1 <1 <1 <1 714 757 <1 <1 160 <50 <50 <1 <1 97.7 <10 250 <1 <1 <1 <1 <0.001 <0.001 <10 116 MW-06BR 06/30/2015 Mixed (anoxic) 7.4 5.06 19 1211 0.31 -248 -43 0.42 0 180 6 10 <1 <1 <1 <1 826 842 <1 <1 180 <50 <50 <1 <1 97.6 <10 250 <1 <1 <1 <1 <0.001 <0.001 157 178 MW-10D14•sl 05/28/2015 Mixed (oxic-anoxic) 6.6 15.40 18 1214 1.18 136 341 4.95 NM 200 <5 154 <1 <1 1.75 1.88 43 56 <1 <1 200 201 221 <1 <1 179 <10 21 <1 <1 <1 <1 <0.001 <0.001 130 243 MW-IOBR14•sl 05/27/2015 Anoxic 8.4 16.60 18 703 0.13 -41 164 3.92 NM 120 23 213 <1 <1 2.42 2.49 73 64 <1 <1 120 127 110 <1 <1 81.4 <10 14 <1 <1 <1 <1 <0.001 <0.001 20 137 MW-12BR1'•sl 03/19/2015 Anoxic 7.4 10.90 16 523 0.28 -43 162 3.88 0 160 <5 88 <1 <1 1.04 1.12 605 612 <1 <1 160 <50 <50 <1 <1 42.5 <10 53 <1 <1 <1 <1 <0.001 <0.001 20 107 MW-14 06/30/2015 Suboxic 9.1 11.80 19 423 0.13 -309 -104 31.6 0 110 104 614 <1 <1 <1 <1 55 64 <1 <1 100 125 132 <1 <1 10.3 <10 40 <1 1.06 <1 <1 0.00155 <0.001 <10 419 MW-17BR1'•sl 03/19/2015 Suboxic 8.2 6.34 14 491 0.23 -19 166 4.6 0 150 8 193 <1 <1 2.18 2.24 540 536 <1 <1 150 <50 <50 <1 <1 38.7 <10 33 <i <1 <1 <1 <0.001 <0.001 <10 143 MW-20BR14•sl 05/27/2015 Anoxic 7.7 13.00 16 331 0.07 -124 81 6.37 NM 140 6 621 <1 <1 1.43 1.57 136 145 <1 <1 140 <50 <50 <1 <1 25.1 <10 12 <i <1 <1 <1 <0.001 <0.001 63 730 MW-21BR1'•s1 05/07/2015 Oxic 8.8 20.45 30 368 1.7 60 265 4.78 NM 76 39 463 <1 <1 1.92 1.98 95 106 <1 <1 74 151 151 <1 <1 5.45 <10 42 <1 <1 <1 <1 <0.001 <0.001 <10 209 PZ-03D 08/05/2015 Anoxic 7.6 6.05 23 645 0.47 -38 167 4.41 NM 150 <5 57 <1 <1 5.01 5.49 131 138 <1 <1 140 57 <50 <1 <1 48.8 <10 62 <1 <1 <1 <1 <0,001 <0.001 21 97 DETECTIONS SAMPLES "-- --- --- --- --" --- --- --- --- --- 19/19 10/14 24/24 0/14 0/24 10/14 18/24 14/24 24/24 0/14 0/19 19/19 8/14 15/24 0/14 0/24 19/19 1/19 24/24 0114 2/24 0/14 0/19 2/14 3/24 9/41 AVERAGE BEDROCK WATER CONCENTRATION (DETECTIONS ONLY) --- --- --- --- --- --- --- --- --- --- 158 142 183 --- --- 2.51 3.81 271 234 --- --- 155 239 276 --- --- 63.4 25 44 --- 1,065 --- --- 0.00341 0.0053 2 MAXIMUM BEDROCK WATER GROUNDWATER CONCENTRATION ___ ___ ___ ___ ___ ___ ___ ___ --- 260 1,210 1,210 --- --- 5.34 8.89 826 842 --- --- 260 1,010 891 --- --- 179.0 25 250 --- 1,070 --- --- 0.00527 0.0060 1,4 NUMBER OF BEDROCK WATER SAMPLES EXCEEDING 02L 0 0 0 0 0 0 0 0 2 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 Detections/Samples --- --- --- --- --- --- --- --- --- 12/14 7/9 14/14 0/9 0/14 5/9 7/14 9/9 14/14 0/9 1/12 12/12 3/9 4/14 0/9 1/14 12/14 0/12 13/13 0/9 1/14 5/9 6/12 0/9 3/14 8/9 13/14 Average Background Concentrations (Detections Only) --- --- --- --- --- --- --- --- --- 87.7 36 804 --- --- 3.30 3.15 210 171 --- 10 87 118 163 --- 1.21 43.1 --- 67 --- 3.39 7.8 62 --- 0.010 9330 6678 Maximum Concentration --- --- --- --- --- --- --- --- --- 180.0 82 6850 --- --- 6.60 6.76 424 429 --- 10 170 217 482 --- 1.21 147.0 --- 240 --- 3.39 19.8 387 --- 0.0307 45000 45500 Number of eackgroundwater Samples that are Greater Than NCAC 2L --- --- --- --- --- --- --- --- 0 0 0 0 O 0 O 0 O O 1 0 0 0 0 0 O O 0 O 0 0 6 0 0 0 8 Notes: - Bold highlighted concentration indicates exceedance of the 15A NCAC 02L, Appendix 2, April 1, 2013. Ey:e:: - Indicates support/rationale for soil COPC attributable to coal ash. - Indicates constituent is not a soil COPC attributable to coal ash. ORP = Oxidation Reduction Potential mV = millivolts DIS = Dissolved NE = Not established TOT = Total NTUs = nephelometric turbidity unit Temp = Temperature S.U. = Standard Unit DO = Dissolved Oxygen ug/I = microgram per liter Deg C = Degree Celsius umhos/cm = micro siemens per centimeter mg/I = milligrams per liter Spec Cord = Specific Conductance mg-N/L = miligram nitrogen per liter ft = feet < = concentration not detected at or above the reporting limit. * - Interim Maximum Allowable Concentrations (IMACs) of the 15A NCAC 02L, Appendix 1, April, 1, 2013 --- = Not applicable Coal Ash COPC NCAC 21 Bedrock Groundwater cone. > NCAC 2L Bedrock Groundwater COPC No Yes No Yes No Yes No No Yes No No Yes No Yes No No No Yes No Yes No No No Yes No Yes Yes Ves Ves Yes Ves Yes Ves Yes' No No No YesNoNo jNo NoNo NO No No No�No No No No No No Yes No No No No No No No No No No No Ves Note 1: Constituent is retained as a COPC if analytical method detection limit or concentration is greater than the groundwater criteria Note 2: Constituent is retained as a COPC if no groundwater criteria Note 3: Hexavalent Chromium concentration is greater than EPA screening value for tapwater (0.035 ug/L). See Table 10-3 (USEPA Regional Screening Levels [RSLs] rev., June 26, 2015) Note 4: Hexavalent Chromium concentration is less than EPA screening value for tapwater (0.035 ug/L). See Table 10-3 (USEPA Regional Screening Levels [RSLs] rev., June 26, 2015) Note 5: Speciation Sample date does not match listed sample collection date Prepared by: KDF Checked by: VTV P:\Duke Energy Progress.1026\103. Cape Fear Ash Basin GW Assessment\1.11 C5A Reporting\Tables\Table 12-5 Bedrock GW Results KDF.xlsx page 1 of 2 TABLE 12-5 RISK SCREENING TABLE: BEDROCK GROUNDWATER DATA CAPE FEAR ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, MONCURE NC Analytical Parameter Lead Magnesium Manganese Mercury Methane Molybdenum Nickel Nitrate (as N) Potassium Selenium Sodium Strontium Sulfate Sulfide Thallium Total Dissolved Solids Total Organic Carbon Total Suspended Solids Vanadium Zinc DIS TOT TOT DIS TOT DIS TOT DIS TOT DIS FTOT TOT DIS I TOT TOT DIS TOT DIS TOT DIS I TOT DIS TOT Reporting Units ug/I ug/I mg/I ug/I ug/I ug/I ug/I ug/I ug/I ug/I ug/I ug/I mg-N/L mg/I ug/I ug/I mg/I mg/I mg/I mg/I mg/I ug/I ug/I mg/I mg/I mg/I ug/I ug/I mg/I mg/I SSA NCAC 2L Standard NE 15 NE NE SO NE 1 NE NE NE NE 100 10 NE NE 20 NE NE NE 250 NE NE 0.2* 500 NE NE NE 0.3* NE 1 Sample ID Sample Collection Date Analytical Results 11 ROCK ABMW-01BRI"'1 OS/08/2015 <1 <1 11.2 616 629 <0.05 <0.05 <10 70.3 68.8 1.95 1.67 <0.01 2.33 3.76 <1 49.4 0.535 0.542 140 0.345 <0.2 <0.2 400 2.1 7 <0.3 0.867 <0.005 <0.005 ABMW-03BRI4lsl 05/19/2015 <1 <1 16.9 1690 1690 <0.05 <0.05 <10 1.75 1.48 <1 <1 0.018 2.01 <1 <1 62.3 0.575 0.573 140 <0.1 <0.2 <0.2 540 0.883 9 <0.3 <0.3 <0.005 <0.005 ABMW-05BRI"'I 05/19/2015 <1 <1 5.49 63 63 <0.05 <0.05 <10 7.35 7.25 <1 <1 <0.01 1.8 <1 <1 38.4 0.353 0.358 15 <0.1 <0.2 0.359 200 0.471 <5 <0.3 <0.3 <0.005 <0.005 CTMW-01 03/04/2015 NA <1 NA NA 1430 NA <0.05 NA NA NA NA <5 NA NA NA <1 NA NA NA 100 NA NA <0.2 460 NA NA NA NA NA <0.005 CTMW-0114•11 06/09/2015 NA <1 13.8 NA 546 NA <0.05 NA NA <1 NA <5 0.07 1.59 NA <1 23.8 NA NA 100 NA NA <0.2 460 NA <5 NA NA NA <0.005 CTMW-02 03/04/2015 NA <1 NA NA 6 NA <0.05 NA NA NA NA <5 NA NA NA <1 NA NA NA 6 NA NA <0.2 180 NA NA NA NA NA <0.005 CTMW-02 06/09/2015 NA <1 3.05 NA 10 NA <0.05 NA NA 12.6 NA <5 0.16 1.43 NA <1 45.1 NA NA 6.6 NA NA 10.2 170 NA <5 NA NA NA 10.001 CTMW-07 03/04/2015 NA <1 NA NA 138 NA <0.05 NA NA NA NA <5 NA NA NA <1 NA NA NA 85 NA NA <0.2 350 NA NA NA NA NA <0.005 CTMW-07 06/08/2015 NA <1 24.7 NA 110 NA <0.05 NA NA <1 NA <5 <0.023 1.39 NA <1 21.2 NA NA 85 NA NA <0.2 380 NA <5 NA NA NA <0.005 CTMW-08 03/04/2015 NA <1 NA NA 980 NA <0.05 NA NA NA NA <5 NA NA NA <1 NA NA NA 110 NA NA <0.2 480 NA NA NA NA NA <0.005 C-MW-0814•11 06/09/2015 NA <1 15.4 NA 686 NA <0.05 NA NA 7.11 NA <5 0.06 2.34 NA <1 66.5 NA NA 100 NA NA <0.2 450 NA <5 NA NA NA <0.005 CTMW-08 DUP 03/04/2015 NA <1 NA NA 1050 NA <0.05 NA NA NA NA <5 NA NA NA <1 NA NA NA 110 NA NA <0.2 490 NA NA NA NA NA <0.005 CTMW-08 DUP 06/09/2015 NA <1 15.6 NA 750 NA <0.05 NA NA 6.54 NA <5 0.05 2.39 NA <1 65.6 NA NA 110 NA NA <0.2 460 NA <5 NA NA NA <0.005 MW-05BR 06/18/2015 <1 <1 0.91 <5 <5 <0.05 <0.05 <10 6.22 6.56 <1 <1 0.019 2A7 <1 <1 27.7 0.136 0.135 71 <0.1 <0.2 <0.2 220 0.769 <5 14.1 14.4 0.01 <0.005 MW-06BR 06/03/2015 <1 <1 32.5 417 475 <0.05 <0.05 18 4.73 4.57 <1 <1 0.011 4.15 <1 <1 94.1 0.892 0.907 39 <0.1 0.362 <0.2 790 0.653 <5 1.88 2.19 <0.005 <0.005 MW-06BR 06/30/2015 <1 <1 29.2 748 743 <0.05 <0.05 11 3.47 3.17 <1 <1 0.018 3.89 <1 <1 89.6 0.951 0.946 42 <0.1 <0.2 <0.2 770 0.683 <5 0.53 0.659 0.013 <0.005 MW-10D14,s1 05/28/2015 <1 <1 48.5 950 974 <0.05 <0.05 17 <1 <1 <1 <1 <0.01 3.7 <1 <1 22.6 1.33 1.3 410 <0.1 <0.2 0.233 890 0.508 8 0.547 0.938 <0.005 0.017 MW-10BR14,11 05/27/2015 <1 <1 13 375 336 <0.05 <0.05 13 6.04 6.57 <1 <1 0.013 2.46 <1 <1 50.5 0.949 0.941 210 <0.1 <0.2 <0.2 490 0.976 9 2.91 3.34 0.015 <0.005 MW-12BRIal'1 03/19/2015 <1 <1 18.4 476 482 <0.05 <0.05 <10 <1 1.02 <1 <1 <0.01 1.92 <1 <1 39.6 0.448 0.453 12 <1 <0.2 <0.2 280 0.777 <5 <0.3 0.338 <0.005 <0.005 MW-14 06/30/2015 <1 <1 1.48 <5 24 <0.05 <0.05 53 70.9 72 <1 <1 <0.01 2.92 <1 <1 81.9 0.26 0.278 30 0.282 <0.2 <0.2 260 0.795 16 <0.3 1.37 0.009 <0.005 MW-17BRIal'1 03/19/2015 <1 <1 10.1 34 34 <0.05 <0.05 300 4.76 4.88 <1 <1 <0.01 2.05 <1 <1 54.9 0.596 0.595 38 <1 <0.2 <0.2 290 3.6 <5 0.5 0.761 <0.005 <0.005 MW-20BRI4,'1 05/27/2015 <1 <1 6.37 124 131 <0.05 <0.05 <10 2.3 2.55 <1 <1 <0.01 1.92 <1 <1 40 0.316 0.317 12 <0.1 <0.2 <0.2 210 0.548 11 0.826 1.61 <0.005 0.006 MW-216R1"'I 05/07/2015 <1 <1 0.688 <5 <5 <0.05 <0.05 <10 269 232 <1 <1 <0.01 1.21 <1 <1 70.1 0.109 0.109 5.9 <0.1 <0.2 <0.2 180 0.318 <5 0.515 0.997 <0.005 <0.005 PZ-03D O8/05/2015 <1 <1 9.24 448 475 <0.05 <0.05 <10 5.42 5.58 <1 1.36 0.028 2.4 <1 <1 73.2 0.662 0.646 74 <0.1 <0.2 <0.2 390 0.685 5 <0.3 0.384 0.056 <0.005 DETECTIONS/SAMPLES 0/14 0/24 19/19 11/14 22/24 0/14 0/24 6/14 12/14 16/19 1/14 2124 10/19 19/19 1/14 0/24 19/19 14/14 14/14 24/24 2/14 1/14 2/24 24/24 14/14 7119 8/14 12/14 5/14 2/24 AVERAGE BEDROCK WATER CONCENTRATION (DETECTIONS ONLY) --- --- 14.6 540 535 --- --- 69 37.7 27.7 1.95 1.52 0.045 2.32 3.76 --- 53.5 0.58 0.579 86 0.314 0.362 0.296 408 1.0 9 2.73 2.32 0.021 0.012 MAXIMUM BEDROCK WATER GROUNDWATER CONCENTRATION ___ --- 48.5 1,690 1,690 --- --- 300 269.0 232.0 1.95 1.67 0.160 4.15 3.76 --- 94.1 1.33 1.300 410 0.345 0.362 0.359 890 3.8 16 14.10 14.40 0.056 0.017 NUMBER OF BEDROCK WATER SAMPLES EXCEEDING 02L 0 0 0 0 18 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 2 4 0 0 0 12 0 0 Detections/Samples 0/9 2/14 12/12 9/9 14/14 0/9 0/14 4/10 3/10 4/12 4/9 5/14 8/11 12/12 1/9 3/14 12/12 9/9 10/10 13/13 0/10 0/9 1/14 1 12/12 9/9 3/10 4/10 6/10 4/9 3/14 Average Background --- 1.85 18.5 1109 2996 --- --- 12 10.5 8.9 3.36 31.9 0.87 1.41 1.95 1.82 63.8 0.418 0.548 154.7 --- --- 0.218 330 1.60 15.5 1.40 1.78 0.009 0.102 Concentrations (Detections Only) Maximum Concentration --- 2.48 82.3 4600 33700 --- --- 25 16.9 17.0 5.14 ISO 3.50 2.49 1.95 2.02 293.0 0.680 1.27 1600 --- --- 0.218 660 7.40 30.0 2.00 4.57 0.017 0.288 Number of Backgroundwater Samples that are Greater Than 0 0 0 0 12 0 0 O O 0 0 1 0 O 0 0 0 0 0 1 0 0 1 3 0 O 0 6 0 0 NCAC 2L Coal Ash COPC .CAC 2L Bedrock Groundwater conc. > .CAC 2L Bedrock Groundwater COPC No No No No Yes No No No No Yes No Yes=NoNo No No No No No Yes No No Yes Yes No No No Yes No Yes Yes No Yes Yes Yes Yes Yes Yes Yes Yes' No Yes Yes Yes Yes No No No No No Yes No No No No Yes No NoNo No No No No Yes No No Yes Yes No No Yes No No Notes - Bold highlighted concentration indicates exceedance of the 15A NCAC 02L, Appendix 2, April 1, 2013 F .e$ - Indicates support/rationale for soil COPC attributable to coal ash. iiiiij - Indicates constituent is not a soil COPC attributable to coal ash. ORP = Oxidation Reduction Potential mV = millivolts DIS = Dissolved NE = Not established TOT = Total NTUs = nephelometric turbidity unit Temp = Temperature S.U. = Standard Unit DO = Dissolved Oxygen ug/I = microgram per liter Deg C = Degree Celsius umhos/cm = micro siemens per centimeter mg/I = milligrams per liter Spec Cond = Specific Conductance mg-N/L = miligram nitrogen per liter ft = feet < = concentration not detected at or above the reporting limit. * - Interim Maximum Allowable Concentrations (IMACs) of the 15A NCAC 02L, Appendix 1, April, 1, 2013. --- = Not applicable Note 1: Constituent is retained as a COPC if analytical method detection limit or concentration is greater than the groundwater criteria Note 2: Constituent Is retained as a COPC if n0 groundwater criteria Note 3: Hexavalent Chromium concentration is greater than EPA screening value for tapwater (0.035 ug/L). See Table 10-3 (USEPA Regional Screening Levels [RSLs] rev., June 26, 2015) Note 4: Hexavalent Chromium concentration is less than EPA screening value for tapwater (0.035 ug/L). See Table 10-3 (USEPA Regional Screening Levels [RSLs] rev., June 26, 2015) Note 5: Speciation Sample date does not match listed sample collection date Prepared by: KDF Checked by: VTV P:\Duke Energy Progress.1026\103. Cape Fear Ash Basin GW Assessment\1.11 C5A Reporting\Tables\Table 12-5 Bedrock GW Results KDF.xlsx page 2 of 2 TABLEI2-6 SOILS (0-2') ANALYTICAL RESULTS WITH SCREENING CRITERIA - INDUSTRIAL-USE/RESIDENTIAL-USE SOIL RSLs HUMAN HEALTH CAPE FEAR STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, MONCURE, NC Analytical Parameter Percent Moisture pH at 25 Degrees C Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chloride Chromium Cr(III)/Cr(VI) Cobalt Copper Iron Lead Magnesium Manganese Mercury Molybdenum Nickel Nitrate (as N) Potassium Selenium Sodium Strontium Sulfate Thallium Total Organic Carbon Vanadium Zinc Reporting Units % S.U. mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg Soil RSL - Industrial Health NE NE 110000 47 3 22000 230 23000 98 NE NE NE 35 4700 a2000 Boo NE 2600 4 Sao 2200 NE NE Sao NE 70000 NE 1.2 NE Sao 3S000 Soil RSL- Residential Health NE NE 7700 3.1 0.68 1500 16 1600 7.1 NE NE NE 2.3 310 55 00 400 NE ISO 0.94 39 150 NE NE 39 NE 4700 NE 0.078 NE 39 2300 Sample ID Sample Collection Date Analytical Results ABMW-04 AB (1-2) 04/11/2015 42.3 5.4 5200 <4.2 21.9 482 1.1 <10.6 0.59j 1390 <216 10.5 6.9j 19.3 20500 <4.2 447 56.2 0.093 <2.1 13 <21.6 853 6.9j <211 97.4 <216 <4.2 104000 20.4 9.7 ABMW-04 AB (1-2) DUP 04/11/2015 19 6.6 6260 <3 30.4 389 1.4 <7.6 <0.36 1710 <154 11.5 6.5 25.7 16800 5.5j 523 55.7 0.13 1.8j 16.1 <15.4 1030 7.1 <151 135 <154 <3 82900 25.8 14.5 B-N1963(0-2) 03/30/2015 11.8 3.2 1920 <1.4 118 47.8 <0.14 40 <0.17 3400 <144 9.3 2.1j 19 50400 42.1 1170 68.8 0.13 1.7j 3.9 <14.4 750 4.7 <141 20.2 5650 <1.4 162000 24.9 10.3 MW-05BR SB (0-2) 04/23/2015 19.8 5.6 11500 <3 <3 62.8 0.21j <7.6 <0.36 1230 <156 24.7 3.7j 8.2 26200 7.4 905 78 0.037 <1.5 1.31 <15.6 <152 <3 <152 17.5 <156 <3 1480 89.6 11.6 MW-06BR SB (0-2) 05/30/2015 14.6 5.5 9800 <3 <3 100 0.58 <7.6 <0.37 442 <144 18.7 17.5 12.7 18900 10.6 1840 1080 0.05 <1.5 6.9 <14.4 <152 <3 <152 8.6 145j <3 4790 50.2 27.6 MW-09 SB (0-2) 04/25/2015 21.2 4.1 4250 <3.3 <3.3 18.1 <0.17 <8.3 <0.4 <83.2 <155 4.3 <3.3 4.7 13000 6.3 j 305 19.4 0.011 <1.7 <0.83 <15.5 <166 <3.3 <166 <1.7 <155 <3.3 6550 10.2 9.4 MW-10BR SB (0-2) 04/08/2015 10 5.0 3300 <2.9 <2.9 33.5 0.21 6.4 <0.35 291 <136 20.6 9.3 7.1 10600 6.9 650 363 0.029 <0.29 2.7 <13.6 114 <2.9 <29 3.9 <136 <2.9 3780 31.6 27.2 MW-12BR SB (0-2) 02/24/2015 17.3 1 5.7 6230 <0.58 1 0.82 j 77.8 1 0.47 7.8 0.092 NA <150 9.4 13.2 8.4 13500 8.7 1520 1510 0.032 <0.29 4.2 <15 68 1.11 79.2 1 14 <150 1 <0.58 2140 1 30.9 19.3 MW-15 SB (0-2) 04/01/2015 18.3 5.2 9980 <1.5 <2.9 64.9 0.6 18.2 <0.18 1120 <153 15.2 6.4 11.4 24100 8.5 2170 367 0.019 <1.5 8.8 <15.3 <146 <2.9 177 j 15.9 539 <2.9 1530 55.1 32.8 MW-16 SB (0-2) 04/28/2015 29.3 5.0 4130 <3.4 <3.4 69.2 0.26 j <8.4 <0.4 642 <180 3.8 4.3 j 4 7250 8.1 1380 392 0.018 <1.7 3.9 <18 227 j <3.4 <168 9.5 <180 <3.4 13400 12.1 18.9 MW-17 SB (0-2) 06/29/2015 16 5.4 7370 <3.1 <3.1 140 0.71 <7.8 <0.37 850 <138 13.3 13.3 12.8 14600 13.1 1400 1230 0.063 <1.6 5.5 <13.8 249j <3.1 <155 11.8 <138 <3.1 13900 46.1 27 MW-18 SB (0-2) 02/11/2015 28.3 5.2 11800 <1.7 <1.7 103 0.73 <34.3 <0.21 664 <173 16.4 34.7 15.9 17500 12.2 1670 3520 0.05 <6.9 6.5j <17.3 73.5 <1.7 241 10.2 344j <1.7 4260 53.9 29.1 MW-19 SB (0-2) 02/11/2015 19.7 5.1 9130 <1.6 1.7 j 58 0.46 <31.4 <0.19 215 275 j 26.5 33.7 7.2 19400 23.4 294 2070 0.052 <0.31 3.9 <15.5 88.6 <1.6 <31.4 4.4 447 <1.6 1610 58.8 8.2 MW-20 SB (0-2) 05/13/2015 19.9 5.1 10100 <3.1 <3.1 75.7 0.39 <7.8 <0.37 1350 <154 16.9 15.2 17.1 18800 9 2470 747 0.0061j <1.6 5.9 <15.4 <156 <3.1 312 16.8 <154 <3.1 2950 47.3 32.2 MW-21 SB(0-2) 04/21/2015 13.9 3.8 1480 <3 60.3 66.1 <0.15 <7.5 <0.36 93.3j <141 3.7 <3 2.2 8420 <3 178 25.3 0.013 <1.5 <0.75 <14.1 <151 3.2j <151 4 <141 <3 932 14.9 3.1j MW-21 SB (0-2) 06/18/2015 36.6 5.2 1610 <4.1 1 40.1 87.5 <0.2 <10.2 1 <0.49 2490 <191 3.1 <4.1 8.3 5980 13.1 393 781 1 0.75 <2 1.8j <19.1 338j 5.7j <205 25 285j <4.1 42700 8.8 20.6 Nitrate Total(as Soil Constituents Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chloride Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury Molybdenum Nickel Potassium Selenium Sodium Strontium Sulfate Thallium Organic Vanadium Zinc N) Carbon Detected Above Industrial Soil Screening Levels 0 0 S 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 Detection Limit > Industrial Soil Screening Level 0 0 4 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 1s 0 0 0 Detected Above Residential Soil Screening Levels 6 1 0 1 7 1 0 1 0 0 1 0 1 0 1 0 1 0 1 12 1 0 1 16 1 0 1 0 1 10 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 7 0 Detection Limit > Residential Soil Screening Level 0 4 9 1 0 0 0 0 0 1 0 0 3 1 0 1 0 1 0 0 0 0 0 0 1 0 0 0 0 0 0 1 16 1 0 0 0 Coal Ash COPC Soil RSL Soil conc. > Soil RSL Soil COPC potentially attributable to coal ash Yes Yes Yes No Yes Yes Yes No No Yes Yes No Yes No No Yes No Yes Yes No No No No No Yes Yes No Yes Yes Yes Yes Yes Yes Yes Yes No Yes Yes Yes Yes Yes No Yes Yes Yes Yes Yes' Yes No No No Yes' Yes Yes Ves No No Yes' Yes' Ves No Yes Yes Yes No No No No No No Yes Yes No Yes No No Ves No No No No No No No No Yes Yes No Yes No Prepared by: KDF Checked by: MMS NotesL Bold color highlighted concentrations indicate highest exceedance of the EPA Mid -Atlantic Risk Assessment regional screening levels for soil, June 26, 2015, for the category listed below: - Concentration Greater than Soil RSL - Residential -Use Scenario Note 1: COPC is retained if analytical method detection limit or concentration is greater than soil RSL - Concentration Greater than Soil RSL - Industrial -Use Scenario Note 2: COPC is retained if no soil RSL - Detection limit Greater Than Residential Soil RSL - Detection Limit Greater Than Industrial Soil RSL - Indicates support/rationale for soil COPC potentially attributable to coal ash. O- Indicates constituent is not a soil COPC potentially attributable to coal ash. S.U. = Standard Units mg/kg = milligram per kilogram < = concentration not detected at or above the reporting limit. j = indicates concentration reported below Practical Quantitation Limit (PQL), but above Method Detection Limit (MDL) and therefore concentration is estimated DUP = Duplicate P:\Duke Energy Progress. 1026\103. Cape Fear Ash Basin GW Assessment\1.11 CSA Reporting\Tables\Table 12-6 Soils (0-2) Analytical Results- Industrial and Residential.xlsx Page 1 of 1 TABLE12-7 SEDIMENT ANALYTICAL RESULTS WITH SCREENING CRITERIA - INDUSTRIAL-USE/RESIDENTIAL-USE SOIL RSLs HUMAN HEALTH CAPE FEAR STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, MONCURE, NC Analytical Parameter Percent Moisture pH at 25 Degrees C Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chloride Chromium Cr(III)/Cr(VI) Cobalt Copper Iron Lead Magnesium Manganese Mercury Molybdenum Nickel Nitrate (as N) Potassium Selenium Sodium Strontium Sulfate Thallium Total Organic Carbon Vanadium Zinc Reporting Units % S.U. mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg Soil RSL- Industrial Health NE NE 110000 47 3 22000 230 23000 98 NE NE NE 35 4700 82000 goo NE 2600 4 580 2200 NE NE 580 NE 70000 NE 1.2 NE 580 35000 Soil RSL - Residential Health NE NE 7700 3.1 0.68 1500 16 1600 7.1 NE NE NE 2.3 310 5500 400 NE ISO 0.94 39 ISO NE NE 39 NE 4700 NE 0.078 NE 39 2300 Sample ID Sample Collection Date Analytical Results S-04 06/11/2015 88.9 6.8 10600 <22.9 45.8j 235 6.8 187 <2.8 9650 <218 8.9j 87.9 39.4 193000 <22.9 2820 1450 0.051j <11.5 66.7 <21.8 <1150 <22.9 <1150 98.7 267j <22.9 166000 30.9j 524 S-09 05/20/2015 88.4 6.4 2390 <22.2 <22.2 23.9 2.3 86.2j <2.7 6500 <1100 <5.6 158 10.6j 11200 <22.2 1490 277 0.068 <11.1 76.2 <110 <1110 <16.7 <1110 47.5 16601 <22.2 200000 <22.2 51.8 S-10 06/11/2015 74.8 7.0 19000 <9.9 <9.9 150 1.2 <24.8 <1.2 3740 <100 25.6 41 27.5 29600 15.1j 2930 606 0.056 <5 18 <10 <497 <9.9 <497 41.2 105j <9.9 47600 62 106 S-16 06/11/2015 58.1 3.6 3670 <5.7 237 18.5 0.82 38 <0.69 984 <303 2j 14.3 <1.4 420000 <5.7 386 143 0.02 <2.9 29.5 <30.3 585 <5.7 <1150 21.7 4680 <5.7 50400 15.3 73.9 SW-85DS 06/11/2015 63.8 6.7 10100 <7.1 <7.1 80.2 0.65j <17.6 <0.85 1950 <67.6 15.3 23.2 13.9 30200 10.2j 2050 267 0.035 <3.5 11.1 <6.8 <353 <7.1 <353 19.8 75.1j <7.1 34800 42.7 56.2 SW-BA1 05/20/2015 39 6.1 5520 <4.2 <4.2 46.2 0.26j <10.5 <0.5 669 <205 5.2 <4.2 7.4 12600 8.2j 728 223 0.02 <2.1 2.3 <20.5 <210 <3.2 <210 8.4 <205 <4.2 11000 12.6 17.3 SW-BA2 05/20/2015 68.3 5.0 10200 <8.2 <8.2 127 0.62j 25.61 <0.98 1010 <380 23.3 12.8j 61.1 33900 11.2j 1300 502 0.057 <4.1 14.5 <38 <409 <6.1 <409 12.3 <380 <8.2 198000 34.6 46.2 SW-BB1 05/20/2015 23.4 5.9 1660 <3.2 <3.2 1 13.9 <0.16 1 <8.1 <0.39 226 <160 1.4j <3.2 2 3640 <3.2 215 32.6 0.0067j <1.6 0.87j <16 <161 <2.4 <161 1.9j <160 <3.2 1060 3.4j 7.8 SW-CFDG 06/11/2015 32.8 6.2 8270 <3.8 <3.8 69.4 0.3j <9.4 <0.45 875 <182 47 11.6 17.1 15500 13.3 1300 537 0.055 <1.9 6.2 <18.6 271j <3.8 <188 9.9 <182 <3.8 15500 38.5 42.6 SW-CFDG CUP 06/11/2015 34 6.0 6120 <3.8 <3.8 46 0.21j <9.5 <0.46 603 <187 24.3 8.5 10.1 12200 8.5 918 300 0.03 <1.9 4.3 <18.7 193j <3.8 <190 7 <187 <3.8 20600 31.6 29.1 SW -HAW 06/11/2015 31.2 6.0 3620 <3.5 <3.5 37.1 <0.18 <8.8 <0.42 481 <182 16 5.9j 5.6 8810 5.1j 660 503 0.018 <1.8 3.2 <18.2 <175 <3.5 <175 5.6 <182 <3.5 8620 21.3 29.2 SW-SHD-56 05/19/2015 41.9 6.4 13600 1 <4.1 <4.1 123 0.66 <10.2 <0.49 1030 <211 44.6 22.6 24.3 30600 17.7 2200 1550 0.12 <2 7.9 <21.1 393j <3.1 <204 13.5 <211 <4.1 29800 66.9 53.3 SW-SHD-PLANT 05/19/2015 41.2 6.1 6780 <4.3 <4.3 74.6 0.56 <10.7 1 1010 <207 18.2 7.3j 11.6 11500 6.71 1440 380 0.023 <2.1 5.6 <20.7 422j <3.2 <215 12.7 <207 <4.3 6930 20.2 34.7 SW-SHD-REF 05/20/2015 51.7 6.1 7710 <5.1 <5.1 101 0.49j <12.7 <0.61 1320 <252 8.8 9j 12.5 15600 9.2j 2390 358 0.024 <2.5 9.8 <25.2 428j <3.8 <255 14.3 <252 <5.1 15600 14.5 39.7 SW 05/19/2015 36.9 6.8 5900 <4.1 <4.1 120 0.97 24.9 <0.49 40300 <195 15 21.4 14.2 29500 8.5 1210 1200 0.014 2.4j 5.4 <19.5 <205 <3.1 362j 104 <195 <4.1 4240 41.3 23.7 Nitrate Total Soil Constituents -- -- Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chloride Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury Molybdenum Nickel Potassium Selenium Sodium Strontium Sulfate Thallium Organic Vanadium Zinc as N) Carbon Detected Above Industrial Soil Screening Levels 0 0 2 0 0 0 0 0 0 0 3 0 2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 Detection Limit > Industrial Soil ScreeningLevel 0 0 13 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 15 0 0 0 DetectedAbove esi entia m 7 0 2 0 0 0 0 0 0 0 13 0 14 0 0 13 0 0 0 0 0 0 0 0 0 0 0 4�Eo Screenin Levels Detection Limit > Residential Soil Screening Level 0 15 13 0 0 0 0 0 0 0 2 0 0 0 iJ 0 0 0 0 0 0 0 0 0 0 15 0 0 Coal Ash COPC Soil RSL Soil cone. > Soil RSL Soil COPC potentially attributable to coal ash Yes Yes Yes No Yes Yes Yes No No Yes Yes No Yes No No Yes No Yes Yes No No No No No Yes Yes No Yes Yes Yes Yes Yes Yes Yes Yes No Yes Yes Yes Yes Yes No Yes Yes Yes Yes Yes' Yes No No No Yes' Yes I Yes Yes No No I Yes' Yes' Yes I No Yes Yes Yes No No I No No No No Yes Yes No Yes No No Yes No No No No No I No No No Yes Yes No Yes No Prepared by: KDF Checked by: MMS Notes Bold color highlighted concentrations indicate highest exceedance of the EPA Mid -Atlantic Risk Assessment regional screening levels (RSLs) for soil, June 26, 2015, for the category listed below: - Concentration Greater than Soil RSL - Residential -Use Scenario Note 1: COPC is retained if analytical method detection limit or concentration is greater than soil RSL - Concentration Greater than Soil RSL - Industrial -Use Scenario Note 2: COPC is retained if no soil RSL - Detection limit Greater Than Residential Soil RSL - Detection Limit Greater Than Industrial Soil RSL 0 -Indicates support/rationale for soil COPC potentially attributable to coal ash. - Indicates constituent is not a soil COPC potentially attributable to coal ash. S.U. = Standard Units mg/kg = milligram per kilogram < = concentration not detected at or above the reporting limit. j = indicates concentration reported below Practical Quantitation Limit (PQL), but above Method Detection Limit (MDL) and therefore concentration is estimated DUP = Duplicate P:\Duke Energy Progress. 1026\103. Cape Fear Ash Basin GW Assessment\1.11 CSA Reporting\Tables\Table 12-7 Sediment Indust Resident.xlsx Page 1 of 1 TABLE 12-8 SURFACE WATER ANALYTICAL RESULTS WITH SCREENING CRITERIA - EPA RECOMMENDED WATER QUALITY CRITERIA AND 15A NCAC 2B STANDARDS HUMAN HEALTH CAPE FEAR ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, MONCURE, NC Analytical Parameter Redox Assignment pH Temp Spec Cond DO ORP Turbidity Alkalinity Aluminum Antimony Arsenic Barium Beryllium Bi- carbonate Alkalinity Boron Cadmium Calcium Carbonate Alkalinity Chloride Chromium Cr(III)/Cr(VI) Cobalt Copper DIS TOT DIS TOT DIS TOT DIS TOT DIS TOT DIS TOT DIS TOT TOT DIS TOT DIS TOT DIS TOT Reporting Units None S.U. Deg C umhos mg/I mV NTU mg/I ug/I ug/I ug/I ug/I ug/I ug/I ug/I ug/I ug/I ug/I mg/I ug/I ug/I ug/I ug/I mg/I mg/I mg/I ug/I ug/I ug/I ug/I mg/I mg/I 15A NCAC 02B Standard NE NE NE NE NE NE 25 NE NE NE NE NE NE 10 NE NE NE NE NE NE NE NE NE NE NE 250 NE NE NE NE NE NE EPA Human Health NE NE NE NE NE NE NE NE NE 6500 NE 5.6 NE 0.018 NE 1000 NE NE NE NE NE NE NE NE NE NE NE NE NE 3 NE 1.3 Sample ID Sample Collection Date Field Parameters Analytical Results SW-85DS 06/11/2015 Anoxic 6.9 23 139 0.4 -205 NM 100 106 51400 <1 <1 1.57 5.56 73 524 <1 2.56 100 2120 2170 <1 <1 25.1 <10 31 <1 40.4 <1 60.1 <0.001 0.055 SW-BA1 05/20/2015 Mixed (oxic-anoxic) 6.5 20 370 7 -58 75.5 27 182 1600 <1 <1 1.04 1.54 70 84 <1 <1 27 <50 <50 <1 <1 13.8 <10 73 <1 <1 2.25 2.67 0.0016 0.0017 SW-BA1 DUP 05/20/2015 Mixed (oxic-anoxic) 6.5 20 370 7 -58 75.5 26 167 1810 <1 <1 1.06 1.S8 69 88 <1 <1 26 <50 <50 <1 <1 13.8 <10 72 <1 <1 2.08 2.79 0.0013 0.0017 SW-BA2 05/20/2015 Mixed (oxic-anoxic) 7.0 21 258 1.71 -220 58.4 45 126 685 <1 <1 1.17 1.92 50 77 <1 <1 45 358 361 <1 <1 10.6 <10 12 <1 <1 3.53 4.6 0.002 0.0019 SW-BBS 05/20/2015 Mixed (oxic-anoxic) 6.6 19 91 6.3 39 37.6 20 200 843 <1 <1 <1 <1 29 35 <1 <1 20 <50 <50 <1 <1 4.99 <10 9.6 <1 <1 <1 <1 0.0013 0,0012 SW-CFDG 06/11/2015 Mixed (oxic-anoxic) 6.6 27 175 7.41 87 18.4 34 153 298 <1 <1 <1 <1 19 23 <1 <1 34 <50 <50 <1 <1 7.99 <10 16 <1 <1 <1 <1 0.0018 0.0019 SW-CFDG DUP 06/11/2015 Mixed (oxic-anoxic) 6.6 27 1 175 7.41 87 18.4 33 153 266 <1 <1 I <1 <1 19 24 <1 <1 33 <50 <50 <1 <1 8.07 <10 16 <1 <1 <1 <1 0.002 0.0018 SW-DEEPR 06/11/2015 Mixed (oxic-anoxic) 7.1 27 150 6.66 89 16.6 27 198 346 <1 <1 <1 <1 19 21 <1 <1 27 <50 <50 <1 <1 7.37 <10 14 <1 <1 <1 <1 0.0022 0.002 SW -HAW 06/11/2015 Oxic 7.0 25 202 6.34 105 10 40 16 88 1.26 <1 <1 <1 22 25 <1 <1 40 63 50 <1 <1 9.33 <10 21 <1 <1 <1 <1 0.0012 0.0013 SW-SHD-56 05/19/2015 Mixed (oxic-anoxic) 6.7 23 219 3 25 20.4 34 112 511 <1 <1 <1 <1 28 33 <1 <1 34 <50 <50 <1 <1 8.74 <10 13 <1 <1 <1 <1 0.0018 0.0018 SW-SHD-PLANT 05/19/2015 Mixed (oxic-anoxic) 6.8 21 301 8.4 -199 31.3 110 143 348 <1 <1 1.4 1.74 85 95 <1 <1 110 61 67 <1 <1 15.1 <10 25 <1 1.02 2.51 2.77 0.002 0.0027 SWSSHD-REF 05/20/2015 Mixed (oxic-anoxic) 6.8 21 156 6.3 -18 187 37 247 5070 <1 <1 1.66 3.04 41 87 <1 <1 37 <50 <50 <1 <1 8.21 <10 16 <1 2.12 1.43 3.08 0.0018 0.0034 SW-UNT 05/19/2015 Mixed (oxic-anoxic) 7.3 24 549 6.9 39 10.2 83 46 211 <1 <1 <1 1.38 52 57 <1 <1 83 1040 1090 <1 <1 43.6 <10 17 <1 <1 <1 1.06 <0.001 0.0011 Human Health Screening Aluminum Antimony Arsenic Barium Beryllium Bi- Boron Cadmium Calcium Carbonate Chromium Cobalt Copper Level COPCs -- -- -- -- -- -- -- - carbonate Alkalinity Chloride Cr(III)/Cr(VI) Alkalinity DIS TOT DIS TOT DIS TOT DIS TOT DIS TOT DIS TOT DIS TOT TOT DIS TOT DIS TOT DIS TOT Detected Above EPA Human Health Surface Water -- -- -- -- -- -- -- -- 0 1 0 0 0 7 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 3 0 0 Screening Levels Detection Limit > EPA Human Health Surface -- -- -- -- -- -- -- -- 0 0 0 0 0 6 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 Water Screening Level Detected Above NC ISA NCAC 02B Surface Water -- -- -- -- -- -- -- -- 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 Screening Levels Detection Limit > NC 1SA NCAC 02B Surface Water -- -- -- -- -- -- -- -- 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 Screening Level Coal Ash COP( NCAC 2B Surface Water conc. > the Screening Criteria Surface Water COP( No Yes No Yes No Yes No No No Yes No No Yes No Yes No No No No Yes No Yes No No Yes Yes Yes No No No No Yes Yes No Yes Yes' YesZ YesZ Yes' Yes No Yes No No No Yes No No No Yes No No Yes No Yes No No No No Yes No Yes No No Notes: - Bold highlighted concentration indicates greater than the EPA National Recommended Water Quality Criteria, Human Health, June 2015. u - Detection Limit is Greater Than the Surface Water Screeening Level - Bold highlighted concentration indicates greater than the 15A NCAC 02B, May 15, 2013 F__I -Detection Limit is Greater Than the Surface Water Screeening Level - Indicates support/rationale for surface water COPC attributable to coal ash. -Indicates constituent is not a surface water COPC attributable to coal ash. Deg C = Degree Celsius Spec Cond = Specific Conductance S.U. = Standard Unit ug/I = microgram per liter mg/I = milligrams per liter Temp = Temperature my = millivolts umhos/cm = micro mhos per centimeter NE = Not established NTU = nephelometric turbidity unit < = concentration not detected at or above the reporting limi DUP = duplicate Note 1: Consitituent is retained as a COPC if analytical method detection limit or concentration is greater than the surface water criteria Note 2: Constituent is retained as a COPC if no surface water criteria Prepared by: KDF Checked by: MMS P:\Duke Energy Progress.1026\103. Cape Fear Ash Basin GW Assessment\1.11 CSA Reporting\Tables\Table 12-5 Surface Water Anaytical Results.xlsx Page 1 of 2 TABLE 12-8 SURFACE WATER ANALYTICAL RESULTS WITH SCREENING CRITERIA - EPA RECOMMENDED WATER QUALITY CRITERIA AND 15A NCAC 2B STANDARDS HUMAN HEALTH CAPE FEAR ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, MONCURE, NC Analytical Parameter Iron Lead Magnesium Manganese Mercury Methane Molybdenum Nickel Nitrate (as N) Potassium Selenium Sodium Strontium Sulfate Sulfide Thallium Total Dissolved Solids Total Organic Carbon Total Suspended Solids Vanadium Zinc DIS TOT DIS TOT TOT DIS TOT TOT DIS TOT DIS TOT TOT DIS TOT TOT DIS TOT DIS TOT DIS TOT DIS TOT Reporting Units ug/l ug/I ug/l ug/I mg/l ug/l ug/I ug/l ug/l ug/l ug/l ug/l ug/l mg-N/L mg/l ug/l ug/l mg/l mg/l mg/l mg/l mg/l ug/l ug/l mg/l mg/l mg/l ug/l ug/l mg/l mg/l 15A NCAC 02B Standard NE NE NE NE NE NE NE NE NE NE NE NE 25 10 NE NE NE NE NE NE 250 NE NE NE 500 NE NE NE NE NE NE EPA Human Health NE NE NE NE NE NE NE NE NE NE 160 NE 610 NE NE NE 170 NE NE 14 NE NE NE 0.24 T 250 NE NE NE NE NE 7.4 Sample ID Sample Collection Date Analytical Results SW-85DS 06/11/2015 3080 94300 <1 35.1 17.9 1710 4340 0.00551 150 <1 <1 1.17 27.4 <0.01 1.96 <1 1.77 55.7 0.141 0.25 76 <0.2 <0.2 0.309 69 19 31000 4.24 107 <0.005 0.231 SW-BA1 05/20/2015 1210 5350 <1 2.47 8.63 3080 3300 0.0026 95 <1 <1 1.18 1.57 0.029 2.84 <1 <1 31.6 0.141 0.147 4.1 <0.5 <0.2 <0.2 260 21 64 0.494 2.33 0.052 0.008 SW-BAI DUP 05/20/2015 1140 6110 <1 2.57 8.59 3100 3410 0.00124 110 <1 <1 1.12 1.71 0.04 2.91 <1 <1 31.6 0.142 0.15 3.5 <0.5 <0.2 <0.2 250 21 130 0.384 2.31 0.164 0.011 SW-BA2 05/20/2015 2510 8910 1.55 8.84 5.66 2470 3300 0.00262 15 <1 <1 1.55 1.87 0.018 2.01 <1 <1 12.9 0.092 0.1 5.7 <0.1 <0.2 <0.2 150 22 25 1.29 4.31 0.04 0.018 SW-BB1 05/20/2015 561 1930 <1 <1 2.48 43 50 0,00468 26 <1 <1 <1 1.06 0.21 1.24 <1 <1 7.82 0.036 0.038 3.6 <0.1 <0.2 <0.2 82 5 10 0.306 1.39 0,013 <0.005 SW-CFDG 06/11/2015 378 790 <1 <1 3.57 29 126 0.0015 14 1.52 1.4 <1 1.12 0.619 3.76 <1 <1 16.1 0.067 0.065 12 <0.1 <0.2 <0.2 110 7.3 11 1.44 1.59 0.008 <0.005 SW-CFDG DUP 06/11/2015 377 765 <1 <1 3.59 27 154 0.0014 14 1.4 1.42 <1 1.03 0.674 3.77 <1 <1 16.2 0.067 0.064 12 <0.1 <0.2 <0.2 100 7.3 10 1.42 1.63 0.059 0.191 SW-DEEPR 06/11/2015 580 997 <1 <1 3.52 47 64 0.0019 19 <1 <1 <1 I <1 1 0,708 3.88 <1 I <1 1 13.2 0.059 1 0.056 12 <0.1 0,383 <0.2 100 7.4 7 1.71 1.93 0.008 <0.005 SW -HAW 06/11/2015 59 294 <1 <1 3.85 <5 208 <0.001 18 2.45 2.54 1.18 1.41 0.298 3.63 <1 <1 22.2 0.083 0.08 16 <0.1 <0.2 <0.2 120 6.3 6 0.698 1.1 <0.005 <0.005 SW-SHD-56 05/19/2015 369 1210 <1 <1 3.45 354 401 0.00288 21 1.17 <1 <1 <1 0.484 4.09 <1 <1 12.8 0.074 0.077 12 <0.1 <0.2 <0.2 100 7.8 14 0.698 2.39 0.009 <0.005 SW-SHD-PLANT 05/19/2015 1150 2530 <1 <1 4.91 1820 1910 0.00202 31 1.22 1.15 2.04 2.08 0.03 36 <1 <1 19.9 0.124 0.13 9 <0.1 <0.2 <0.2 230 37 12 0.696 2.43 0.016 0.014 SW-SHD-REF 05/20/2015 963 9180 <1 3.6 3.61 869 1150 0.00274 62 <1 <1 1.31 2.92 0.032 2.13 <1 <1 16.2 0.069 0.082 2 <1 <0.2 <0.2 140 19 150 0.698 7.82 0.021 0.016 SW-UNT 05/19/2015 67 534 <1 <1 19.6 3280 3420 0.000786 <10 3.03 2.83 1.89 2.13 0.078 2.56 <1 <1 31.2 0.275 0.292 140 <0.1 <0.2 <0.2 350 4.7 8 0.698 1.67 0,006 <0.005 Iron Lead Magnesium Manganese Mercury Molybdenum Nickel Nitrate Potassium Selenium Sodium Strontium Thallium Total Total Total Vanadium Zinc Human Health Screening Level COPCs (TOT) Methane Sulfate Sulfide Dissolved Organic Suspended (as N) Solids Carbon Solids DIS TOT DIS TOT TOT DIS TOT TOT DIS TOT DIS TOT TOT DIS TOT TOT DIS TOT DIS TOT DIS TOT DIS TOT Detected Above EPA Human Health Surface Water Screening Levels 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 2 0 0 0 0 0 0 Detection Limit > EPA Human Health Surface Water Screening Level 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 Detected Above NC SSA NCAC 02B Surface Water Screening Levels 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 Detection Limit > NC 15A NCAC 02B Surface Water Screening Level 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 Coal Ash COP( NCAC 26 Surface Water conc. > the Screening Criteria Surface Water COP( No Yes No No No No Yes No No No Yes No Yes No No No No No No No Yes No No Yes Yes No No No Yes No Yes No No Yes Yes Yes Yes Yes No Yes YesZ YesZ No Yes No Yes Yes YesZ No No Yes No No No No Yes No No No I No No Yes No No No No No No No No No No I Yes Yes No No No Yes No No Notes: - Bold highlighted concentration indicates greater than the EPA National Recommended Water Quality Criteria, Human Health, June 2015. Detection Limit is Greater Than the Surface Water Screeening Level Bold highlighted concentration indicates greater than the 15A NCAC 02B, May 15, 2013. - Detection Limit is Greater Than the Surface Water Screeening Level - Indicates support/rationale for surface water COPC attributable to coal ash. no -Indicates constituent is not a surface water COPC attributable to coal ash. Deg C = Degree Celsius Spec Cond = Specific Conductance S.U. = Standard Unit ug/I = microgram per liter mg/I = milligrams per liter Temp = Temperature my = millivolts umhos/cm = micro mhos per centimeter NE = Not established NTU = nephelometric turbidity unit < = concentration not detected at or above the reporting limit. DUP = duplicate Note 1: Consitituent is retained as a COPC if analytical method detection limit or concentration is greater than the surface water criteria Note 2: Constituent is retained as a COPC if no surface water criteria Prepared by: KDF Checked by: MMS P:\Duke Energy Progress.1026\103. Cape Fear Ash Basin GW Assessment\1.11 CSA Reporting\Tables\Table 12-5 Surface Water Anaytical Results.xlsx Page 2 of 2 TABLE 12-9 SEEP ANALYTICAL RESULTS WITH SCREENING CRITERIA - EPA RECOMMENDED WATER QUALITY CRITERIA AND 15A NCAC 2B STANDARDS HUMAN HEALTH CAPE FEAR STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, MONCURE, NC Spec Aluminum Antimony Arsenic Barium Beryllium Bi- Boron Cadmium Calcium Carbonate Chromium Cobalt Copper Analytical Parameter Redox Assignment pH Temp DO ORP Turbidity Alkalinity carbonate Chloride Cr(III)/Cr(VI) Cond Alkalinity Alkalinity DIS TOT DIS TOT DIS I TOT DIS TOT DIS TOT DIS TOT DIS TOT TOT DIS TOT DIS TOT DIS TOT Reporting Units None S.U. Deg C u mhos mg mV NTU mg/I ug/I ug/1 ug/I ug/1 ug/l ug/1 ug/l ug/I ug/I ug/I mg/l ug/l ug/1 ug/l ug/1 mg/1 mg/I mg/l ug/I ug/l ug/l ug/l mg/I mg/l SSA NCAC 02B Standard NE NE NE NE NE NE 25 NE NE NE NE NE NE 10 NE NE NE NE NE NE NE NE NE NE NE 250 NE NE NE NE NE NE EPA Human Health NE NE NE NE NE NE NE NE NE 6500 NE 5.6 NE 0.018 NE 1000 NE NE NE NE NE NE NE NE NE NE NE NE NE 3 NE 1.3 Sample Sample ID Collection Date Field Parameters Analytical Results S-04 06/11/2015 Anoxic 7.0 21 1 768 1 0.2 1 -2791 NM 180 70 134000 <1 <10 5.08 408 79 3620 <1 83.1 180 5050 6730 <1 29.4 148 <10 22 <1 69.4 <1 763 0,00117 0,467 S-09 05/20/2015 Mixed(oxic-anoxic) 6.8 24 508 2.9 -286 18.7 110 10 132 <1 <1 <1 <1 51 56 <1 <1 110 3710 3790 <1 <1 36.9 <10 21 <1 <1 <1 1.4 <0.001 <0.001 S-10 06/11/2015 Mixed(oxic-anoxic) 7.0 23 431 0.7 -202 148 130 178 2740 <1 <1 1.36 2.64 57 119 <1 <1 130 1540 1530 <1 <1 18.7 <10 32 <1 1.91 1.14 3.2 <0.001 0.00265 S-16 06/11/2015 Anoxic 2.9 24 2700 0.39 270 55.6 <10 7050 3760 <1 <1 19.9 118 19 21 31.4 14.4 <10 724 553 <1 <1 314 <10 10 <1 <1 361 272 0.00104 0.00106 Human Health Screening Aluminum Antimony Y Arsenic Barium Beryllium Y Bi- Boron Cadmium Calcium Carbonate Chromium Cobalt Copper PP Level COPCs -- -- -- -- -- -- - _ - - carbonate Alkalinity Alkalinity Chloride Cr(III)/Cr(VI) DIS TOT DIS TOT DIS TOT DIS TOT DIS TOT DIS TOT DIS TOT TOT DIS TOT DIS TOT DIS TOT Detected Above EPA Human Health Surface Water -- -- -- -- -- -- -- -- 0 4 0 0 0 3 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 3 0 0 Screening Levels Detection Limit > EPA Human Health Surface Water -- -- -- -- -- -- -- -- 0 0 0 1 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 Screening Level Detected Above INC5A NCAC 02B Surface Water Screening -- -- -- -- -- -- -- -- 0 0 0 0 0 2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 Levels Detection Limit > NC 15A NCAC 02B Surface Water -- -- -- -- -- -- -- -- 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 Screening Level Coal Ash COPC 15A NCAC 2B Standard Seep conc. > the Screening Criteria Seep COPC No Yes No Yes No Yes No No No Yes No No Yes No Yes No No No No Yes No Yes No No Yes Yes Yes No No No No Yes Yes Yes' Yes Yes' Yes' Yes' I Yes Yes I No Yes I No Yes No Yes No No No Yes No No Yes No Yes No No No No Yes No Yes No No Prepared by: KDF Checked by: MMS Notes: C- Bold highlighted concentration indicates greater than the EPA National Recommended Water Quality Criteria, Human Health, June 2015 �. -Detection Limit Greater Than The Surface Water Screeening Level Bold highlighted concentration indicates greater than the 15A NCAC 02B, May 15, 2013. Note 1: Consitituent is retained as a COPC if analytical method detection limit or concentration is greater than the surface water criteria - Detection Limit Greater Than The Surface Water Screeening Level Note 2: Constituent is retained as a COPC if no surface water criteria Te5 I -Indicates support/rationale for seep water COPC attributable to coal ash. - Indicates constituent is not a seep water COPC attributable to coal ash. Deg C = Degree Celsius Spec Cord = Specific Conductance S.U. = Standard Unit ug/I = microgram per liter mg/I = milligrams per liter Temp = Temperature my = millivolts umhos/cm = micro mhos per centimeter NE = Not established NTU = nephelometric turbidity unit < = concentration not detected at or above the reporting limit. P:\Duke Energy Progress. 1026\103. Cape Fear Ash Basin GW Assessment\1.11 CSA Reporting\Tables\Table 12-9 Seep Anaytical Results.xlsx Page 1 of 2 TABLE 12-9 SEEP ANALYTICAL RESULTS WITH SCREENING CRITERIA - EPA RECOMMENDED WATER QUALITY CRITERIA AND 15A NCAC 2B STANDARDS HUMAN HEALTH CAPE FEAR STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, MONCURE, NC Analytical Parameter Iron Lead Magnesium Manganese Mercury Methane Molybdenum Nickel Nitrate (as N) Potassium Selenium Sodium Strontium Sulfate Sulfide Thallium Total Dissolved Solids Total Organic Carbon Total Suspended Solids Vanadium Zinc DIS TOT DIS TOT TOT DIS TOT TOT DIS TOT DIS TOT TOT DIS TOT TOT DIS TOT DIS TOT DIS TOT DIS TOT Reporting Units ug/I ug/I ug/I ug/I mg/l ug/I ug/I ug/I ug/I ug/l ug/I ug/l ug/I mg-N/L mg/1 ug/l ug/I mg/I mg/I mg/I mg/I mg/l ug/I ug/I mg/I mg/I mg/I ug/I ug/I mg/I mg/I ISA NCAC 02B Standard NE NE NE NE NE NE NE NE NE NE NE NE 25 10 NE NE NE NE NE NE 250 NE NE NE 500 NE NE NE NE NE NE EPA Human Health NE NE NE NE NE NE NE NE NE NE 160 NE 610 NE NE NE 170 NE NE 14 NE NE NE 0.24 250 NE NE NE NE NE 7.4 Sample ID Sample Collection Date Analytical Results S-04 06/11/2015 30300 3100000 <1 76.2 59 1770 27100 0.00682 180 1.04 <10 3.48 519 <0.01 2.39 <1 10.6 39.6 0.405 1.97 150 <0.1 <0.2 5.13 51 93 15000 <0.3 217 0.013 5.97 S-09 05/20/2015 297 596 <1 <1 23.6 2260 2360 0.00267 42 <1 <1 4.06 4.29 0.041 1.19 <1 <1 30.6 0.301 0.315 99 <0.5 <0.2 <0.2 360 7.5 180 <0.3 0.739 <0.005 0.008 5-10 06/11/2015 1910 15600 <1 1.95 12.4 3070 3910 0.0105 110 <1 <1 1.63 2.67 <0.01 2.87 <1 <1 47.1 0.152 0.167 19 <0.2 <0.2 <0.2 <25 24 940 1.95 9.31 0.015 0.012 Si 06/11/2015 249000 1 257000 <1 <1 78.7 25400 18800 <0.001 13 <1 2.99 352 206 <0.01 31.2 <1 <1 28 6.28 5.01 2700 <0.5 0.255 0.417 2600 0.976 190 <0.3 3.09 0.802 0.599 Iron Lead Magnesium Manganese Mercury Molybdenum Nickel Nitrate Potassium Selenium Sodium Strontium Thallium Total Total Total Vanadium Zinc Human Health Screening Level COPCs Methane (as N) Sulfate Sulfide Dissolved Organic Suspended Solids Carbon Solids DIS TOT DIS TOT TOT DIS TOT TOT DIS TOT DIS TOT TOT DIS TOT TOT DIS TOT DIS TOT DIS TOT DIS TOT Detected Above EPA Human Health Surface Water Screening Levels 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 2 2 0 0 0 0 0 0 Detection Limit > EPA Human Health Surface Water Screening Level 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 Detected Above NC 15A NCAC 02B Surface Water Screening Levels 0 0 0 0 0 0 0 0 0 0 0 0 2 0 0 0 0 0 0 0 1 0 0 0 1 0 0 0 0 0 0 Detection Limit > NC 15A NCAC 02B Surface Water Screening Level 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 Coal Ash COPC 15A NCAC 26 Standard Seep conc. > the Screening Criteria Seep COPC Notes: C u No Yes No No No No Yes No No No Yes No Yes No No No No No No No Yes No No Yes Yes No No No Yes No Yes No No Yes Yes Yes Yes Yes No Yes Yes2 I Yes2 I No Yes �No Yes Yes Yes I Yes No No Yes No No No No I Yes No No No No No Yes No No No No No No Yes No No Yes Yes No No No Yes No I No - Bold highlighted concentration indicates greater than the EPA National Recommended Water Quality Criteria, Human Health, June 2015. - Detection Limit Greater Than The Surface Water Screeening Level Bold highlighted concentration indicates greater than the 15A NCAC 02B, May 15, 2013. Detection Limit Greater Than The Surface Water Screeening Level T- - Indicates support/rationale for seep water COPC attributable to coal ash. - Indicates constituent is not a seep water COPC attributable to coal ash. Deg C = Degree Celsius Spec Cord = Specific Conductance S.U. = Standard Unit ug/I = microgram per liter mg/I = milligrams per liter Temp = Temperature my = millivolts umhos/cm = micro mhos per centimeter NE = Not established NTU = nephelometric turbidity unit < = concentration not detected at or above the reporting limit. Note 1: Consitituent is retained as a COPC if analytical method detection limit or concentration is greater than the surface water criteria Note 2: Constituent is retained as a COPC if no surface water criteria Prepared by: KDF Checked by: MMS P:\Duke Energy Progress. 1026\103. Cape Fear Ash Basin GW Assessment\1. 11 CSA Reporting\Tables\Table 12-9 Seep Anaytical Results.xlsx Page 2 of 2 TABLE 12-10 MATRIX FOR DETERMINATION OF CONSTITUENTS OF POTENTIAL CONCERN - HUMAN HEALTH CAPE FEAR STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, MONCURE, NC Analytical Parameter Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chloride Chromium Hexavalent Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury Molybdenum Nickel Nitrate (as N) Potassium Selenium Sodium Strontium Sulfate Thallium Total Dissolved Solids Vanadium Zinc Medium/Basis for COPC Designation Ash Pore Water Concentration exceeds screening value ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ Analytical detection limit exceeds screening value No screening value ✓ ✓ Surficial Groundwater Concentration exceeds screening value ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ Analytical detection limit exceeds screening value No screening value ✓ ✓ Bedrock Groundwater Concentration exceeds screening value ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ Analytical detection limit exceeds screening value No screening value ✓ ✓ Soil Concentration exceeds screening value ✓ ✓ NE ✓ ✓ ✓ NA ✓ Analytical detection limit exceeds screening value ✓ ✓ NE ✓ NA No screening value ✓ NE ✓ NA Sediment Concentration exceeds screening value ✓ ✓ NE ✓ ✓ ✓ NA ✓ Analytical detection limit exceeds screening value ✓ ✓ NE ✓ NA No screening value ✓ NE ✓ NA Surface Water Concentration exceeds screening value ✓ ✓ NE ✓ ✓ ✓ ✓ Analytical detection limit exceeds screening value ✓ NE No screening value ✓ ✓ ✓ ✓ NE ✓ ✓ ✓ Seep Water Concentration exceeds screening value ✓ ✓ NE ✓ ✓ ✓ ✓ ✓ Analytical detection limit exceeds screening value ✓ ✓ NE No screening value ✓ ✓ ✓ ✓ NE ✓ ✓ ✓ Prepared by: VTV Checked by: MMS Notes: Coal ash COPC (See Table 12-2) Constituent determined to be a human health COPC potentially attributable to coal ash. Constituent not determined to be a human health COPC potentially attributable to coal ash. Hexavalent chromium (Cr`s) is a human health COPC but ash pore water data to date suggest that Cr" in groundwater is not attributable to coal ash (7-10). NA = Not applicable NE = Not evaluated P:\Duke Energy Progress. 1026\103. Cape Fear Ash Basin GW Assessment\1.11 CSA Reporting\Tables\Table 12-10 Matrix Determin COPCs - HH.xlsx Page 1 of 1 TABLE 12-11 THREATENED AND ENDANGERED SPECIES CHATHAM COUNTY, NORTH CAROLINA CAPE FEAR STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, MONCURE, INC Species Protection Status Habitat Requirements Taxonomic Group Common Name Scientific Name State Federal (USFWS) Record Status Triangle Floater Alasmidonta undulata (syn. ) T Current Roanoke, Chowan, Tar, Neuse, Cape Fear drainages Brook Floater Alasmidonta varicosa (syn. ) E FSC Current along Blue Ridge escarpment of Catawba and Yadkin --Pee Dee drainages; Cape Fear drainage Box Spike Elliptio cistellaeformis W3,W5 Current Neuse, Lumber, Pee Dee drainages; Lake Waccamaw Carolina Slabshell Elliptio congaraea W2,W5 Current drainages north to the White Oak drainage Atlantic Spike Elliptio producta W3,W5 Current many Atlantic drainages; very difficult to identify Roanoke Slabshell Elliptio roanokensis (syn. Elliptio judithae) T Current Roanoke, Tar, Neuse, White Oak, Cape Fear, Lumber, and Yadkin --Pee Dee drainages v Atlantic Pigtoe Fusconaia masoni (syn.) E FSC Current Roanoke, Tar, Neuse, Cape Fear, Yadkin --Pee Dee drainages i Yellow Lampmussel Lampsilis cariosa (syn.) E FSC Current Chowan, Roanoke, Neuse, Tar, Cape Fear, Lumber, Yadkin --Pee Dee drainages m Eastern Lampmussel Lampsilis radiata (syn.) T Current Chowan, Roanoke, Tar, Neuse, Cape Fear, Yadkin --Pee Dee drainages Creeper Strophitus undulatus (syn.) T Current Roanoke, Tar, Neuse, Cape Fear, Yadkin --Pee Dee, Catawba, Broad, and French Broad drainage Savannah Lilliput Toxolasma pullus (syn.) E FSC Current Cape Fear, Lumber, and Yadkin --Pee Dee drainages Notched Rainbow Villosa constricta (syn.) SC lCurrent Roanoke, Tar, Neuse, Yadkin --Pee Dee, and Catawba drainages Eastern Creekshell Villosa delumbis (syn.) SR Current Cape Fear, Lumber, Yadkin --Pee Dee, and Catawba drainages Carolina Creekshell Villosa vaughaniana (syn.) E FSC Current Cape Fear, Yadkin --Pee Dee, and Catawba drainages (endemic to North Carolina and adjacent N L 9 N U Carolina Ladle Crayfish Cambarus davidi (syn.) SR Current Neuse and Cape Fear drainages (endemic to North Carolina) N O e N Panhandle Pebblesnail Somatogyrus virginicus (syn.) SR FSC Current Eno River Leonard's Skipper Hesperia leonardus W2 Current wooded borders and openings, brushy fields; host plants -- grasseE Cobweb Skipper Hesperia metea W2 Current dry barren sites, such as powerline clearings and pine/oak sandhills; host plants -- mainly broomsed a <i>Andro 0 on< i> Helicta Satyr Neonympha helicta (syn.) SR Current sedgy wetlands, including sandhi[] seeps, pocosin ecotones, and drained beaver ponds in the Sandhills, low pocosins in the northeast Coastal Plain, and wet open swales in the Piedmont; host plants -- sedges (Alamance*, Anson, Beaufort, Bertie*, Chatham*, Cumberland, Dare, Durham*, Gaston*, Gates*, Granville, Halifax, Harnett, Hoke, Hyde, Martin*, Moore, Pitt, Checkered White Pontia protodice (syn.) SR Current fields, pastures; host plants -- mustard species (Family Brassicaceae) Confused Cloudywing Thorybes confusis W3 Current dry woodland borders and openings, brushy fields; host plants -- legumes Li u Robust Baskettail Epitheca spinosa W3 Current ponds and lakes Spine -crowned Clubtail Gomphus abbreviatus (syn.) SR Current rivers Banner Clubtail Gomphus apomyius W3 Current spring -fed streams Blackwater Clubtail Gomphus dilatatus W3 Current rivers Rapids Clubtail Gomphus quadricolor (syn.) SR Current rocky rivers Septima's Clubtail Gomphus septima (syn.) SR FSC Current rocky rivers Cinnamon Shadowdragon Neurocordulia virginiensis W3 Current large rivers Coppery Emerald Somatochlora georgiana (syn.) SR Current creeks and other slow -moving acidic streams, in forested areas a ma fl Choroter es basalis (syn.) SR Current Waccamaw River DrowningCreek Bear Creek Lanes Creek UT Laurens Creek DutchmanE Magdalen Underwing Catocala illecta W3 Current habitats not known Honey Locust Moth Sphingicampa bicolor W3 Current on honey locust (Gleditsia ) A Liverwort Plagiochila undata W7 Historical on rocks or bark N i Knothole Moss Anacamptodon splachnoides W7 Historical bark of trees > C A Thread Cedar Moss Cryphaea raveneiii W7 Historical on bark of trees e a A Cord Moss Funaria serrata W7 Historical on soil of disturbed places, near streams or ditches Z Fernmoss Thuidium allenii W7 Historical on soil logs, exposed roots and tree bases in swamps, often iust above water line Thin -pod White Wild Indigo Baptisia albescens W1 Historical open woodlands, clearings Fescue Sedge Carex festucacea W7 Current piedmont swamp forests, bogs, upland depression swamps Velvet Sedge Carex vestita (syn.) SC-H Historical low woods Piedmont Horsebalm Collinsonia tuberosa (syn.) SC-V Current rich hardwood forests Autumn Coral -root Corallorhiza odontorhiza Wl Historical forests Dutchman's Breeches Dicentra cucullaria W6 Historical rich, moist forests Ringed Witch Grass Dichanthelium annulum (syn.) SR-P Historical dry sandy or rocky open woods and borders of thickets Leatherwood Dirca palustris W1 Historical rich woods, either alluvial or over mafic or calcareous rocks Purple Coneflower Echinacea purpurea (syn.) SC-V Current open woods and clearings Eastern Isopyrum Enemion biternatum (syn.) SC-V Historical rich bottomlands, levees, and lower slopes Tall Boneset Eupatorium altissimum Wl Current woodlands, openings, and old fields over mafic rocks Showy Aster Eurybia spectabilis (syn.) SR-0 Current pine barrens and woodland borders Large Witch -alder Fothergilla major (syn.) SR-T Current dry ridgetop or bluff forests, seepage wetlands, and Piedmont longleaf pine forests Indian Physic Gillenia stipulata (syn.) T H istorica 11 forests and open woods, mainly over mafic rocks Lewis's Heartleaf Hexastylis lewisii Wl Current mesic mixed hardwood forests, streamhead pocosin ecotones c 0 a Virginia Quillwort Isoetes virginica (syn.) SR-L FSC Historical upland depression swamp forests, clayey soils `m Whiteroot Rush Juncus brachycarpus W7 Historical wet sandy soil N Two -flower Cynthia Krigia biflora W7 Historical rich mesic woods > Catchfly Cutgrass Leersia lenticularis (syn.) SR-P Current low woods Bog Spicebush Lindera subcoriacea (syn.) SR-T FSC ICUrrent streamhead pocosins, white cedar swamps, seepage slopes Sweet Pinesap Monotropsis odorata (syn.) SC-V FSC Current dry forests and bluffs Horsetail Crown Grass Paspalum fluitans (syn.) SR-P Historical drawdown riverbanks and seepage areas in swamp forests Buttercup Phacelia Phacelia covillei (syn.) SR-T FSC Current bottomlands, rich lower slopes Eastern White Pine Pinus strobus W6 Historical dry to moist woods and old fields Harperella Ptilimnium nodosum (syn.) E E Current rocky riverbeds Chinquapin Oak Quercus muehlenbergii Wl I Current calcareous forsts and bluffs Pin Oak Quercus palustris W1 Historicall swamps Three -square Bulrush Schoenoplectus pungens W6 Historical marshes and rocky river bottoms Veined Skullcap Scutellaria nervosa (syn.) E Historical alluvial forests A Heartleaf Skullcap Scutellaria ovata ssp. bracteata W7 Historical rich woods on circumneutral soil Hemlock Water -parsnip Sium suave W6 Historical fresh or brachish marshes, swamps and creek margins Appalachian Golden -banner Thermopsis mollis (syn.) SC-V Historical dry ridges and open woodlands Buffalo Clover Trifolium reFlexum (syn.) T Historical open woods and clearings d Oak Toad Anax rus quercicus (syn.) SR Current pine flatwoods and savannaspine sandhills where near water (many records not yet entered a Four -toed Salamander Hemidactylium scutatum (syn.) SC Current pools, bogs, and other wetlands in hardwood forests v c ti e Grassho pper Sparrow lAnhinga JAmmodramus savannarum W1,W5 Current 1pastures and other grasslands [breeding season only] > Anhin a anhin a W2 Current 1wooded lakes or ponds, or open swamps for nesting) [breeding evidence only] Species Protection Status Habitat Requirements Taxonomic Group Common Name Scientific Name State Federal (USFWS) Record Status Bald Eagle Haliaeetus leucocephalus (syn.) T BGPA Current mature forests near large bodies of water (for nesting); lakes and sounds (for foraging) [nesting sites only] Loggerhead Shrike Lanius ludovicianus W2 SC Current fields and pastures rbreeding season only] Hooded Merganser Lo hod tes cucullatus W3 Current lakes and ponds, with dead trees for nesting breedin evidence only Bachman's Sparrow Peucaea aestivalis (syn.) SC FSC Current open longleaf pine forests old fields rbreeding season only Double -crested Cormorant Phalacrocorax auritus (syn.) SR Current lakes with scattered trees coastal sand bars for nesting) breedin sites only' Red -cockaded Woodpecker Picoides borealis (syn.) E E Historical mature open pine forests mainly in longleaf pine rbreeding evidence only King Rail Rallus ele ans Wl W3 Current fresh to slightly brackish marshes fbireeding season only' m Roanoke Bass Amblo ltes cavifrons (syn.) SR FSC Current streams in Neuse and Tars stems Carolina Darter Etheostoma Collis(syn.)SC FSC Current Roanoke Tar Neuse Cape Fear Yadkin --Pee Dee and Catawba drainage! a r Fantail Darter Etheostoma flabellare WS Current Cape Fear, Neuse, and Tar drainages populations have limited distribution; Pee Dee, Roanoke, New, and French Broad populations stable > Carolina Redhorse Moxostoma sp. 3 (syn. Moxostoma sp. cf. athrurum) T FSC Current Cape Fear and Pee Dee drainages Cape Fear Shiner Notro is mekistocholas (syn.) E E Current Cape Fear drainage endemic to North Carolina` Long-tailed Weasel Mustela frenata W3 Current forests brushy areas Eastern Fox Squirrel Sciurus ni er W2 Current open forests mainly longleaf pine/scrub oaN Slender Glass Lizard Ophisaurus attenuatus (syn.) SR Historical old fields, wooded edges, open woods (Beaufort, Bertie, Bladen, Brunswick, Chatham, Cherokee, Chowan, Clay, Columbus, Durham, Edgecombe, Franklin, Gates, Halifax, Harnett, Iredell, Johnston Lenoir. Oran a Pitt Stanly. Vance Wake Warren Wilson Smooth Earthsnake Virginia valeriae W2 Current deciduous or mixed woods usually in mesic soils P:\Duke Energy Progress.1026\103. Cape Fear Ash Basin GW Assessment\1.11 CSA Reporting\Tables\Table 12-11 ME Chatham County.xlsx Page 1 of 2 TABLE 12-11 THREATENED AND ENDANGERED SPECIES CHATHAM COUNTY, NORTH CAROLINA CAPE FEAR STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, MONCURE, NC A� n 'c E Colonial Wading Bird Colony (syn.) Current m Basic Mesic Forest Piedmont Subtype) (syn. Current Dry Basic Oak --Hickory Forest (syn. Current Dry Oak --Hickory Forest (Piedmont Subtype) (syn. Dry-Mesic Basic Oak --Hickory Forest Piedmont Subt e s n. Dry-Mesic Oak --Hickory Forest (Piedmont Subt e s n.Flood lain Pool s n. durren Low Elevation Seep (Floodplain Subtype) s n.Low Elevation See T is Subt e s n. ' Mesic Mixed Hardwood Forest (Piedmont Subt e s n.Mixed Moisture Hard an Forest s n. Piedmont Acidic Glade s n. Piedmont Alluvial Forest (syn. Current Piedmont Boggy Streamhead (syn. ` Current Piedmont Bottomland Forest (High Subtype) Current (syn. v Piedmont Bottomland Forest (Typic Low Subtype) (syn. Current Piedmont Headwater Stream Forest (Typic Current E Subtype) (syn. $ Piedmont Levee Forest (Typic Subtype) (syn. Current Piedmont Monadnock Forest (Typic Subtype) i Current s n. z Piedmont Swam Forest s n. Current Piedmont Coastal Plain Heath Bluff s n. Current Piedmont/Mountain Semipermanent Impoundment (Open Water Subtype) s n. Current Piedmont/Mountain Semipermanent Impoundment (Piedmont Marsh Subtype) Current (syn. Piedmont/Mountain Semipermanent Impoundment Shrub Subtype) s n. ' Current Rocky Bar and Shore (Mixed Bar Subtype) Current (syn. Rocky Bar and Shore (Southern Wild Rice Subtype) s n. Current Rocky Bar and Shore (Water Willow Subtype) s n. Current Upland De ression Swam Forest s n. Current Upland Pool T is Piedmont Subtype) s n. Current Xeric Hardpan Forest (Acidic Hardpan Subt e s n. Current Xeric Hardpan Forest (Basic Hardpan Subt e) ((syn. Current Prepared by: MMS Checked by: RKD http://porta1.ncdenr.org/web/nhp/database-search US FWS Updated: 3-25-2015 https://www.fws.gov/raleigh/species/cntylist/chatham.html Definitions of Federal Status Codes: E = endangered. A taxon "in danger of extinction throughout all or a significant portion of its range." T = threatened. A taxon "likely to become endangered within the foreseeable future throughout all or a significant portion of its range." C = candidate. A taxon under consideration for official listing for which there is sufficient information to support listing. (Formerly "Cl" candidate species.) BGPA =Bald and Golden Eagle Protection Act. See below. FSC=Federal Species of Concern. FSC is an informal term. It is not defined in the federal Endangered Species Act. In North Carolina, the Asheville and Raleigh Field Offices of the US Fish and Wildlife Service (Service) define Federal Species of Concern as those species that appear to be in decline or otherwise in need of conservation and are under consideration for listing or for which there is insufficient information to support listing at this time.Subsumed under the term "FSC" are all species petitioned by outside parties and other selected focal species identified in Service strategic plans, State Wildlife Action Plans, or Natural Heritage Program Lists. T(S/A) = threatened due to similarity of appearance. A taxon that is threatened due to similarity of appearance with another listed species and is listed for its protection. Taxa listed as T(S/A) are not biologically endangered or threatened and are not subject to Section 7 consultation. See below. EXP = experimental population. A taxon listed as experimental (either essential or nonessential). Experimental, nonessential populations of endangered species (e.g., red wolf) are treated as threatened species on public land, for consultation purposes, and as species proposed for listing on private land. P = proposed. Taxa proposed for official listing as endangered or threatened will be noted as "PE" or "PT", respectively. Bald and Golden Eaale Protection Act (BGPA): In the July 9, 2007 Federal Register( 72:37346-37372), the bald eagle was declared recovered, and removed (de -listed) from the Federal List of Threatened and Endangered wildlife. This delisting took effect August 8,2007. After delisting, the Bald and Golden Eagle Protection Act (Eagle Act) (16 U.S.C. 668-668d) becomes the primary law protecting bald eagles. The Eagle Act prohibits take of bald and golden eagles and provides a statutory definition of "take" that includes "disturb". The USFWS has developed National Bald Eagle Management Guidelines to provide guidance to land managers, landowners, and others as to how to avoid disturbing bald eagles. For mor information, visit http://www.fws.gov/migratorybirds/baideagle.htm Threatened due to similarity of aooearance(T(S/A)1: In the November 4, 1997 Federal Register (55822-55825), the northern population of the bog turtle (from New York south to Maryland) was listed as T (threatened), and the southern population (from Virginia south to Georgia) was listed as T(S/A) (threatened due to similarity of appearance). The T(S/A) designation bans the collection and interstate and international commercial trade of bog turtles from the southern population. The T(S/A) designation has no effect on land management activities by private landowners in North Carolina, part of the southern population of the species. In addition to its official status as T(S/A), the U.S. Fish and Wildlife Service considers the southern population of the bog turtle as a Federal species of concern due to habitat loss. Definitions of Record Status: Current - the species has been observed in the county within the last 50 years. Historic - the species was last observed in the county more than 50 years ago. Obscure - the date and/or location of observation is uncertain. Incidental/migrant - the species was observed outside of its normal range or habitat. Probable/potential - the species is considered likely to occur in this county based on the proximity of known records (in adjacent counties), the presence of potentially suitable habitat, or both. Definition of State Codes: CODE/ STATUS DEFINITION E=Endangered Any native or once -native species of wild animal whose continued existence as a viable component of the State's fauna is determined by the Wildlife Resources Commission to be in jeopardy or any species of wild animal determined to be an 'endangered species' pursuant to the Endangered Species Act. (Article 25 of Chapter 113 of the General Statutes; 1987). T=Threatened Any native or once -native species of wild animal which is likely to become an endangered species within the foreseeable future throughout all or a significant portion of its range, or one that is designated as a threatened species pursuant to the Endangered Species Act. (Article 25 of Chapter 113 of the General Statutes; 1987). SC=Special Concern Any species of wild animal native or once -native to North Carolina which is determined by the Wildlife Resources Commission to require monitoring but which may be taken under regulations adopted under the provisions of this Article. (Article 25 of Chapter 113 of the General Statutes; 1987). Any species which has not been listed by the N.C. Wildlife Resources Commission as an Endangered, Threatened, or Special Concern species, but which exists in the state (or recently occurred in the state) in SR=Significantly Rare small numbers and has been determined by the N.C. Natural Heritage Program to need monitoring. Significantly Rare species include "peripheral" species, whereby North Carolina lies at the periphery of the species' range (such as Hermit Thrush), as well as species of historical occurrence with some likelihood of re -discovery in the state. Species considered extirpated in the state, with little likelihood of re- discovery, are given no N.C. Status (unless already listed by the N.C. Wildlife Resources Commission as E, T, or SC). SR-G=Game Animal Species is a game animal or a furbearer, and therefore (by law) cannot be listed for State protection as E, T, or SC. SC-V=Special Concern -Vulnerable "Any species or higher taxon of plant which is likely to become a threatened species within the foreseeable future"(NCAC 02 NCAC 48F .0401). SC-H=Special Concern -Historical "Any species or higher taxon of plant that occurred in North Carolina at one time, but for which all known populations are currently considered to be either historical or extirpated." "(NCAC 02 NCAC 48F .0401). SR-L= Significantly Rare Limited The range of the species is limited to North Carolina and adjacent states (endemic or near endemic). These are species that may have 20-50 populations in North Carolina, but fewer than 100 populations rangewide. The preponderance of their distribution is in North Carolina and their fate depends largely on conservation here. SR-T=Significantly Rare The species is rare throughout its range (fewer than 100 populations total). Thrnuahnut SR-D=Significantly Rare Disjunct The species is disjunct to North Carolina from a main range in a different part of the country or world. SR-P=Significantly Rare The species is at the periphery of its range in North Carolina. These species are generally more common somewhere else in their ranges, occurring in North Carolina peripherally to their main ranges, mostly in Peripheral habitats which are unusual in North Carolina. SR-O=Significantly Rare Other The range of the species is sporadic or cannot be described by the other Significantly Rare categories W= Watch List Any other species believed to be rare and of conservation concern in the state but not warranting active monitoring at this time P:\Duke Energy Progress.1026\103. Cape Fear Ash Basin GW Assessment\l.11 CSA Reporting\Tables\Table 12-11 T&E Chatham County.xlsx Page 2 of 2 TABLE 12-12 SURFACE WATER AND SEEPS ANALYTICAL RESULTS EPA AND 15A NCAC 2B RECOMMENDED WATER QUALITY CRITERIA FOR AQUATIC LIFE (ACUTE AND CHRONIC) CAPE FEAR STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, MONCURE, NC Analytical Parameter Redox Assignment pH Temp Spec Cond DO ORP Eh Turbidity Alkalinity Aluminum Antimony Arsenic Barium Beryllium Bi- carbonate Alkalinity Boron Cadmium' Calcium Carbonate Alkalinity Chloride Chromium** Cobalt Copper" Iron Lead* DIS T TOT DIS TOT DIS TOT DIS TOT DIS TOT DIS TOT DIS TOT TOT DIS TOT DIS TOT DIS TOT DIS TOT DIS TOT Reporting Units None S.U. Deg C u/cros mg/I my my NTU mg/I ug/I ug/I ug/I ug/I ug/I ug/I ug/I ug/I ug/I ug/I mg/I ug/I ug/I ug/I ug/I mg/I mg/I mg/I ug/I ug/I ug/l ug/I mg/I mg/I ug/I ug/I ug/I ug/I EPA R4 FV1 Chronic NE 6.5-9 NE NE NE NE NE NE NE NE 87 160 NE 190* NE NE NE 0.53 NE NE 750 NE 0.66 NE NE NE 230 11 11 NE NE 0.00654 NE 1000 NE 1.32 NE EPA Aquatic Life Acute NE NE NE NE NE NE NE NE NE NE 750 NE NE 340 NE NE NE NE NE NE NE NE 2 NE NE NE 860.0001 16 16 NE NE 1.3 NE NE NE 65 NE EPA Aquatic Life Chronic NE 6.5-9 NE NE NE NE NE NE NE NE 87 NE NE 150 NE NE NE NE NE NE NE NE 0.25 NE NE NE 230 11 1 11 NE NE 1.3 NE 1000 NE 2.5 NE 15 NCAC 2B Aquatic Life Acute NE 6-9 NE NE NE NE NE NE NE NE NE NE NE 340 NE NE NE 65 NE NE NE NE 0.82 NE NE NE NE NE NE NE NE 0.0036 NE NE NE 14 NE 15 NCAC 2B Aquatic Life Chronic NE 6-9 NE NE NE I NE NE NE NE NE NE NE NE 150 NE NE NE 6.5 NE NE NE NE 0.15 NE NE NE NE NE NE NE NE 0.0027 NE NE NE 0.54 NE Sample ID Sample Collection Date Field Parameters Analytical Results 5-04 06/11/201S Anoxic 7.0 21 768 0.2 -279 -74 NM 180 70 134000 <1 <10 5.08 408 79 3620 <1 83.1 180 5050 6730 <1 29.4 148 <10 22 <1 69.4 <1 763 0.00117 0.467 30300 3100000 <1 76.2 d 5-09 O5/20/2015 Mixed (oxic-anoxic) 6.8 24 508 2.9 -286 -81 18.7 110 10 132 <1 <1 <1 <1 51 56 <1 <1 110 3710 3790 <1 <1 36.9 <10 21 <1 <1 <1 1.4 <0.001 <0.001 297 596 <1 <1 rn 5-10 06/11/2015 Mixed (oxic-anoxic) 7.0 23 431 0.7 -202 3 148 130 178 2740 <1 <1 1.36 2.64 57 119 <1 <1 130 1540 1530 <1 <1 18.7 <10 32 <1 1.91 1.14 3.2 <0.001 0.00265 1950 15600 <1 1.95 SW-85DS 06/11/2015 Anoxic 6.9 23 139 0.4 -205 0 NM 100 106 51400 <1 <1 1.57 5.56 73 524 <1 2.56 100 2120 2170 <1 <1 25.1 <10 31 <1 40.4 <1 60.1 <0.001 0.055 3080 94300 <1 35.1 5-16 06/11/2015 Anoxic 2.9 24 2700 0.39 270 475 55.6 <10 70SO 3760 <1 <1 19.9 118 19 21 31.4 14.4 <10 724 553 <1 <1 314 <10 10 <1 <1 361 272 0.00104 0.00106 249000 257000 <1 <1 SW-BA1 05/20/2015 Mixed (oxic-anoxic) 6.5 20 370 7 -58 147 75.5 27 182 1600 <1 <1 1.04 1.54 70 84 <1 <1 27 <50 <50 <1 <1 13.8 <10 73 <1 <1 2.25 2.67 0.00159 0.00166 1210 5350 <1 2.47 SW-BA1 DUP 05/20/2015 Mixed (oxic-anoxic) 6.5 20 1 370 7 -58 147 75.5 26 167 1 1810 <1 <1 1.06 1.58 69 88 <1 <1 26 <50 <50 <1 <1 1 13.8 <10 72 <1 <1 2.08 2.79 0.00126 0.00167 1140 6110 <1 2.57 SW-BA2 OS/20/2015 Mixed (oxic-anoxic) 7.0 21 258 1.71 -220 -15 58.4 45 126 685 <1 <1 1.17 1.92 50 77 <1 <1 45 358 361 <1 <1 10.6 <10 12 <1 <1 3.53 4.6 0.00201 0.00193 2510 8910 1.55 1 8.84 SW-BB1 05/20/2015 Mixed (oxic-anoxic) 6.6 19 91 6.3 39 244 37.6 20 200 843 <1 <1 <1 <1 29 35 <1 <1 20 <50 <SO <1 <1 4.99 <10 9.6 <1 <1 <1 <1 0.00128 0.00117 561 1930 <1 <1 SW-CFDG 06/11/2015 Mixed (oxic-anoxic) 6.6 27 175 7.41 87 292 18.4 34 153 298 <1 <1 <1 <1 19 23 <1 <1 34 <50 <SO <1 <1 7.99 <10 16 <1 <1 <1 <1 0.00177 0.00187 378 790 <1 <1 'y SW-CFDG DUP 06/11/2015 Mixed (oxic-anoxic) 6.6 27 175 7.41 87 292 18.4 33 153 266 <1 <1 <1 <1 19 24 <1 <1 33 <50 <50 <1 <1 8.07 <10 16 <1 <1 <1 <1 0.00195 0.00179 377 765 <1 <1 SW-DEEPR 06/11/201S Mixed (oxic-anoxic) 7.1 27 150 6.66 89 294 16.6 27 198 346 <1 <1 <1 <1 19 21 <1 <1 27 <50 <SO <1 <1 7.37 <10 14 <1 <1 <1 <1 0.00224 0.002 580 997 <1 <1 SW -HAW 06/11/2015 Oxic 1 7.0 1 25 202 1 6.34 1 105 0 10 1 40 16 88 1.26 <1 <1 <1 22 25 <1 <1 40 63 50 <1 <1 9.33 1 <10 21 <1 <1 <1 <1 0.00124 1 0.00131 59 294 <1 <1 SW-SHD-56 05/19/2015 Mixed (oxic-anoxic) 6.7 23 1 219 1 3 1 25 230 20.4 1 34 1 112 1 511 <1 <1 I <1 <1 28 33 <1 <1 34 <50 <SO <1 <1 1 8.74 1 <10 1 13 <1 <1 <1 I <1 0.00177 0.00181 369 1 1210 <1 <1 SW-SHD-PLANT 05/19/2015 Mixed (oxic-anoxic) 6.8 21 1 301 1 8.4 -199 6 1 31.3 1 110 1 143 1 348 1 <1 I <1 1 1.4 1 1.74 1 85 1 95 1 <1 I <1 1 110 1 61 1 67 1 <1 I <1 1 15.1 1 <10 I 25 I <1 1.02 2.51 1 2.77 0.00201 0.0027 1150 2530 <1 <1 SW-SHD-REF 05/20/2015 Mixed (oxic-anoxic) 6.8 21 156 6.3 -18 187 187 37 247 5070 <1 <1 1.66 3.04 41 87 <1 <1 37 <50 <50 <1 <1 8.21 <10 16 <1 2.12 1.43 3.08 0.00182 0.00336 963 9180 <1 3.6 SW-UNT 05/19/2015 Mixed (oxic-anoxic) 7.3 24 549 6.9 39 237 10.2 83 46 211 <1 <1 <1 1.38 52 57 <1 <1 83 1040 1090 <1 <1 43.6 <10 17 <1 <1 <1 1.06 <O.001 0.00106 67 534 <1 <1 Prepared by: MMS/SRW Checked by: GMH Notes: Bold color highlighted concentrations indicate highest exceedance of the category listed below: - EPA Region 4 Surface Water Quality Criteria - Chronic, Nov 2001 C - EPA National Recommended Water Quality Criteria, Aquatic Life - Acute, June 2015 - EPA National Recommended Water Quality Criteria, Aquatic Life - Chronic, June 2015 - 15A NCAC 02B Criteria, Aquatic Life - Acute, January 2015 - EPA Region 4 Surface Water Quality Criteria - Chronic, Nov 2001 - MDL is greater than EPA National Recommended Water Quality Criteria, Aquatic Life - Acute, June 2015 - MDL is greater than EPA National Recommended Water Quality Criteria, Aquatic Life - Chronic, June 2015 - MDL is greater than 15A NCAC 02B Criteria, Aquatic Life - Acute, January 2015 15A NCAC 02B Criteria, Aquatic Life - Chronic, January 2015 - MDL is greater than 15A NCAC 02B Criteria, Aquatic Life - Chronic, January 2015 Temp = Temperature S.U. = Standard Unit NTU = nephelometric turbidity unit Deg C = Degree Celsius ug/I = microgram per liter DO = Dissolved Oxygen mg/I = milligrams per liter umhos/cm = micro mhos per centimeter Spec Cond = Specific Conductance my = millivolts ORP = Oxidative Reduction Potential < = concentration not detected at or above the reporting limit. NE = Not established NM = Not measured DUP = Duplicate * EPA Region 4 Surface Water Quality Criterion for arsenic is given in terms of As(III), and analytical results are in terms of dissolved arsenic ** EPA and NCAC 2B Water Quality Criteria are given in terms of dissolved Cr(VI), and analytical results are in terms of dissolved chromium Y Hardness dependent - concentrations compared to EPA criteria at a default hardness of 100 mg/L of CaCO, and NCAC 2B criteria at a default hardness of 25 mg/L as Ca CO, Qualitative Redox State derived using USGS Excel ® Workbook for Identifying Redox Processes in ground water. P:\Duke Energy Progress. 1026\103. Cape Fear Ash Basin GW Assessment\l.11 CSA Reporting\Tables\Table 12-12 SW Seep Analytical Results Eco.xlsx Page 1 of 2 TABLE 12-12 SURFACE WATER AND SEEPS ANALYTICAL RESULTS EPA AND 15A NCAC 2B RECOMMENDED WATER QUALITY CRITERIA FOR AQUATIC LIFE (ACUTE AND CHRONIC) CAPE FEAR STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, MONCURE, NC Analytical Parameter Magnesium Manganese Mercury Methane Molybdenum Nickel* Nitrate (as N) Potassium Selenium Sodium Strontium Sulfate Sulfide Thallium Total Dissolved Solids Total Organic Carbon Total Suspended Solids Vanadium Zinc" TOT DIS TOT TOT DIS TOT DIS TOT TOT DIS TOT TOT DIS TOT DIS TOT DIS TOT DIS TOT Reporting Units mg/I ug/I ug/I ug/I ug/I ug/I ug/I ug/I ug/I mg-N/L mg/I ug/I ug/I mg/I mg/I mg/I mg/I mg/I ug/l ug/I mg/l mg/l mg/I ug/l ug/I mg/I mg/I EPA R4 FW Chronic NE NE NE 0.012 NE NE NE 87.71 NE NE NE NE 5 NE NE NE NE 0.002 4 NE NE NE NE NE NE 0.05891 NE EPA Aquatic Life Acute NE NE NE 1.4 NE NE NE 470 NE NE NE NE NE NE NE NE NE NE NE NE NE NE NE NE NE 0.12 NE EPA Aquatic Life Chronic NE NE NE 0.77 NE NE NE 52 NE NE NE NE 5 NE NE NE NE NE NE NE NE NE NE NE NE 0.12 NE NC26_Aquatic Life_Acute NE NE NE NE NE NE NE 140 NE NE NE NE NE NE NE NE NE NE NE NE NE NE NE NE NE 0.036 NE NC2B_Aquatic Life -Chronic NE NE NE 0.012 NE NE NE 16 1 NE NE NE NE 5 NE NE NE NE NE NE I NE NE NE NE NE NE 0.036 NE Sample ID Sample Collection Date Analytical Results S-04 06/11/2015 59 1770 27100 0.00682 180 1.04 <10 3.48 519 <0.01 2.39 <1 10.6 39.6 0.405 1.97 15o <0.1 <0.2 5.13 51 93 15000 <0.3 217 0.013 5.97 d S-09 05/20/2015 23.6 2260 2360 0.00267 42 <1 <1 4.06 4.29 0.041 1.19 <1 <1 30.6 0.301 0.315 99 <0.5 <0.2 <0.2 360 7.5 180 <0.3 0.739 <0.005 0.008 m 5-10 06/11/2015 12.4 3070 3910 0.0105 110 <1 <1 1.63 2.67 <0.01 2.87 <1 <1 47.1 0.152 0.167 19 <0.2 <0.2 <0.2 <25 24 940 1.95 9.31 0.015 0.012 SW-85DS 06/11/2015 17.9 1710 4340 0.00551 150 <1 <1 1.17 27.4 <0.01 1.96 <1 1.77 55.7 0.141 0.25 76 <0.2 <0.2 0.309 69 19 31000 4.24 107 <0.005 0.231 S-16 06/11/2015 78.7 25400 18800 <0.001 13 <1 2.99 352 206 <0.01 31.2 <1 <1 28 6.28 5.01 2700 <0.5 0.255 0.417 2600 0.976 190 <0.3 3.09 0.802 0.599 SW-BA1 05/20/2015 8.63 3080 3300 0.0026 95 <1 <1 1.18 1.57 0.029 2.84 <1 <1 31.6 0.141 0.147 4.1 <0.5 <0.2 <0.2 260 21 64 0.494 2.33 0.052 0.008 SW-BA1 DUP 05/20/2015 8.59 3100 3410 1 0.00124 110 <1 I <1 1.12 1.71 0.04 2.91 <1 <1 1 31.6 0.142 0.15 3.5 <0.5 <0.2 <0.2 250 21 130 0.384 2.31 0.164 0.011 SW-BA2 05/20/2015 5.66 2470 3300 0.00262 15 <1 <1 1.55 1.87 0.018 2.01 <1 <1 12.9 1 0.092 0.1 5.7 1 <0.1 <0.2 <0.2 1 150 22 1 25 1.29 4.31 0.04 0.018 SW-BB1 05/20/2015 2.48 43 50 0.00468 26 <1 <1 <1 1.06 0.21 1.24 <1 <1 7.82 0.036 0.038 3.6 <0.1 <0.2 <0.2 82 5 10 0.306 1.39 0.013 <0.005 SW-CFDG 06/11/2015 3.57 29 126 0.0015 14 1.52 1.4 <1 1.12 0.619 3.76 <1 <1 16.1 0.067 0.065 12 <0.1 <0.2 <0.2 110 7.3 11 1.44 1.59 0.008 <0.005 'y SW-CFDG DUP 06/11/2015 3.59 27 154 0.0015 14 1.4 1.42 <1 1.03 0.674 3.77 <1 <1 16.2 0.067 0.064 12 <0.1 <0.2 <0.2 100 7.3 10 1.42 1.63 0.059 0.191 u � SW-DEEPR 06/11/2015 3.52 47 64 0.0019 19 <1 <1 <1 <1 0.708 3.88 <1 <1 13.2 0.059 0.056 12 <0.1 0.383 <0.2 100 7.4 7 1.71 1.93 0.008 <0.005 SW -HAW 06/11/2015 1 3.85 1 <5 208 <0.001 1 18 1 2.45 2.54 1 1.18 1.41 0.298 3.63 <1 <1 22.2 0.083 0.08 16 <0.1 <0.2 <0.2 120 6.3 6 0.698 1.1 <0.005 <0.005 SW-SHD-56 05/19/2015 3.45 354 401 0.00288 21 1.17 <1 <1 <1 0.484 4.09 <1 <1 12.8 0.074 0.077 12 <0.1 <0.2 <0.2 100 7.8 14 1.42 2.39 0.009 <0.005 SW-SHD-PLANT 05/19/2015 4.91 1820 1910 0.00202 31 1.22 1.15 2.04 2.08 0.03 36 <1 <1 19.9 0.124 0.13 9 <0.1 <0.2 <0.2 230 37 12 1.32 2.43 0.016 0.014 SW-SHD-REF 05/20/2015 3.61 869 1150 0.00274 62 <1 <1 1.31 2.92 0.032 2.13 <1 <1 16.2 0.069 0.082 2 <1 <0.2 <0.2 140 19 150 1.03 7.82 0.021 0.016 SW-UNT O 19/2015 19.6 3280 3420 0.000786 <10 3.03 2.83 1.89 2.13 0.078 2.56 <1 <1 31.2 0.275 0.292 140 <0.1 <0.2 <0.2 350 4.7 8 0.705 1.67 0.006 <0.005 Prepared by: MMS/SRW Checked by: GMH Notes: Bold color highlighted concentrations indicate highest exceedance of the category listed below: - EPA Region 4 Surface Water Quality Criteria - Chronic, Nov 2001 C - EPA National Recommended Water Quality Criteria, Aquatic Life - Acute, June 2015 - EPA National Recommended Water Quality Criteria, Aquatic Life - Chronic, June 2015 - 15A NCAC 02B Criteria, Aquatic Life - Acute, January 2015 - 15A NCAC 02B Criteria, Aquatic Life - Chronic, January 2015 Temp = Temperature S.U. = Standard Unit Deg C = Degree Celsius ug/I = microgram per liter mg/I = milligrams per liter umhos/cm = micro mhos per centimeter my = millivolts ORP = Oxidative Reduction Potential NE = Not established NM= Not measured - EPA Region 4 Surface Water Quality Criteria - Chronic, Nov 2001 - MDL is greater than EPA National Recommended Water Quality Criteria, Aquatic Life - Acute, June 2015 - MDL is greater than EPA National Recommended Water Quality Criteria, Aquatic Life - Chronic, June 2015 - MDL is greater than 15A NCAC 02B Criteria, Aquatic Life - Acute, January 2015 - MDL is greater than 15A NCAC 02B Criteria, Aquatic Life - Chronic, January 2015 NTU = nephelometric turbidity unit DO = Dissolved Oxygen Spec Cord = Specific Conductance < = concentration not detected at or above the reporting limit. DUP = Duplicate * EPA Region 4 Surface Water Quality Criterion for arsenic is given in terms of As(III), and analytical results are in terms of dissolved arsenic ** EPA and NCAC 2B Water Quality Criteria are given in terms of dissolved Cr(VI), and analytical results are in terms of dissolved chromium Y Hardness dependent - concentrations compared to EPA criteria at a default hardness of 100 mg/L of CaCO, and NCAC 2B criteria at a default hardness of 25 mg/L as Ca CO, Qualitative Redox State derived using USGS Excel ® Workbook for Identifying Redox Processes in ground water. P:\Duke Energy Progress. 1026\103. Cape Fear Ash Basin GW Assessment\l.11 CSA Reporting\Tables\Table 12-12 SW Seep Analytical Results Eco.xlsx Page 2 of 2 TABLE 12-13 SOILS (0-2') ANALYTICAL RESULTS WITH SCREENING CRITERIA - EPA REGION 4 RECOMMENDED SCREENING VALUES FOR SOIL - ECOLOGICAL CAPE FEAR STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, MONCURE, NC Analytical Parameter Percent Moisture pH at 25 Degrees C Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chloride Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury Molybdenum Nickel Nitrate (as N) Potassium Selenium Sodium Strontium Sulfate Thallium Total Organic Carbon Vanadium Zinc Reporting Units / Std. Units mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg EPA Region 4-RSL Soil NE NE 50 3.5 SO 165 1.1 0.5 1.6 NE NE 0.4 20 40 200 50 NE 100 0.1 2 30 NE NE 0.81 NE NE NE 1 NE 2 50 Sample ID Sample Collection Date Analytical Results u ABMW-04 AB (1-2) 04/11/2015 42.3 5.4 5200 <4.2 21.8 482 1.1 <10.6 0.59 j 1390 <216 10.5 6.9 j 19.3 20500 <4.2 447 56.2 0.093 <2.1 13 <21.6 853 6.9 j <211 97.4 <216 <4.2 104000 20.4 9.7 u e A3MW-04 AB (1-2) CUP 04/11/2015 19 6.6 6260 <3 30.4 389 1.4 <7.6 <0.36 1710 <154 11.5 6.5 25.7 16800 5.5j 523 55.7 0.13 1.8j 16.1 <15.4 1030 7.1 <151 135 <154 <3 82900 25.8 14.5 B-141963 (0-2) 03/30/2015 11.8 3.2 1920 <1.4 118 47.8 <0.14 40 <0.17 3400 <144 9.3 2.1j 19 50400 42.1 1170 68.8 0.13 1.7j 3.9 <14.4 750 4.7 <141 20.2 5650 <1.4 162000 24.9 10.3 MW-OSBR SB(0-2) 04/23/2015 19.8 5.6 11500 <3 <3 62.8 0.21j <7.6 <0.36 1230 <156 24.7 3.7j 8.2 26200 7.4 905 78 0.037 <1.5 1.3j <15.6 <152 <3 <152 17.5 <156 <3 1480 89.6 11.6 MW-06BR SB(0-2) 05/30/2015 14.6 5.5 9800 <3 <3 100 0.58 <7.6 <0.37 442 <144 1 18.7 17.5 1 12.7 18900 10.6 1840 1080 0.05 <1.5 6.9 <14.4 <152 <3 <152 1 8.6 145j <3 4790 50.2 27.6 MW-09 SB (0-2) 04/25/2015 21.2 4.1 4250 <3.3 <3.3 18.1 <0.17 <8.3 <0.4 <83.2 <155 4.3 <3.3 4.7 13000 6.3 j 305 19.4 0.011 <1.7 <0.83 <15.5 <166 <3.3 <166 <1.7 <155 <3.3 6550 10.2 9.4 MW-10BR SB (0-2) 04/08/2015 10 5 3300 <2.9 <2.9 33.5 0.21 6.4 <0.35 291 <136 20.6 9.3 7.1 10600 6.9 650 363 0.029 <0.29 2.7 <13.6 114 <2.9 <29 3.9 <136 <2.9 3780 31.6 27.2 MW-12BR SB (0-2) 02/24/2015 17.3 5.7 6230 <0.58 0.82 j 77.8 0.47 7.8 0.092 NA <150 9.4 13.2 8.4 13500 8.7 1520 1510 0.032 <0.29 4.2 <15 68 1.1 j 79.2 14 <150 <0.58 2140 30.9 19.3 c MW-15 SB (0-2) 04/O1/2015 18.3 5.2 9980 <1.5 <2.9 64.9 0.6 18.2 <0.18 1120 <153 15.2 6.4 11.4 24100 8.5 2170 367 0.019 <1.5 8.8 <15.3 <146 <2.9 177 j 15.9 539 <2.9 1530 55.1 32.8 2y MW-16 SB (0-2) 04/28/2015 29.3 5 4130 <3.4 <3.4 69.2 0.26 j <8.4 <0.4 642 1 <180 3.8 4.3 j 4 7250 8.1 1380 392 0.018 <1.7 3.9 <18 227 j <3.4 <168 9.5 <180 <3.4 13400 1 12.1 18.9 m C MW-17 SB (0-2) 06/29/2015 16 5.4 7370 <3.1 <3.1 140 0.71 <7.8 <0.37 850 <138 13.3 13.3 12.8 14600 13.1 1400 1230 0.063 <1.6 5.5 <13.8 249 j <3.1 <155 11.8 <138 <3.1 13900 46.1 27 MW-18 SB (0-2) 02/11/2015 28.3 5.2 11800 <1.7 <1.7 103 0.73 <34.3 <0.21 664 <173 16.4 34.7 15.9 17500 12.2 1670 3520 0.05 <6.9 6.5 j <17.3 73.5 <1.7 241 10.2 344 j <1.7 4260 53.9 29.1 MW-19 SB (0-2) 02/11/2015 19.7 5.1 9130 <1.6 1.7 j 58 0.46 <31.4 <0.19 215 275 j 26.5 23.4 294 2070 0.052 <0.31 3.9 <15.5 88.6 <1.6 <31.4 4.4 447 <1.6 1610 58.88.2 MW-20 SB (0-2) 05/13/2015 19.9 5.1 10100 <3.1 <3.1 75.7 0.39 <7.8 <0.37 1350 <154 16.9 18800 9 2470 747 0.0061 j <1.6 5.9 <15.4 <156 <3.1 312 16.8 <154 <3.1 2950 47.3 32.2 MW-21 SB(0-2) 04/21/2015 13.9 3.8 1480 <3 60.3 66A <0.15 <7.5 <0.36 93.3j <141 3.7 177..�19400 8420 <3 178 25.3 0.013 <1.5 <0.75 <14.1 <151 3.2j <151 4 <141 <3 932 14.9 3.1j MW-21SB (0-2) 06/18/2015 36.6 5.2 1610 <4.1 40.1 87.5 <0.2 <10.2 <0.49 2490 <191 3.1 5980 13.1 393 781 0.75 <2 1.8 j <19.1 338 j 5.7 j <205 25 285 j <4.1 42700 8.8 20.6 Prepared by: MMS/SRW Checked by: GMH Notes: Bold color highlighted concentrations indicate highest exceedance of the category listed below: EPA Region 4 Criteria - Soil - MDL is greater than EPA Region 4 Criteria - Soil Dup = Duplicate %=percent NE = Not established mg/kg = miligram per kilogram S.U. = Standard Units j = indicates concentration reported below Practical Quantitation Limit (PQL), but above Method Detection Limit (MDL) and therefore concentration is estimated. < = concentration not detected at or above the reporting limit. P:\Duke Energy Progress. 1026\103. Cape Fear Ash Basin GW Assessment\5.11 CSA Reporting\Tables\Table 12-13 Soils (0-2) Analytical Results Eco.xlsx Page 1 of 1 TABLE 12-14 SEDIMENT ANALYTICAL RESULTS WITH SCREENING CRITERIA EPA REGION 4 SOIL SCREENING LEVELS EPA REGION 4 EFFECTS VALUES - SEDIMENT CAPE FEAR STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, MONCURE, NC Analytical Parameter Percent Moisture pH at 25 Degrees C Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chloride Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury Molybdenum Nickel Nitrate (as N) Potassium Selenium Sodium Strontium Sulfate Thallium Total Organic Carbon Vanadium Zinc Reporting Units % Std. Units mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg EPA Region 4-RSL Soil NE NE 50 3.5 10 165 1.1 0.5 1.6 NE NE 0.4 20 40 200 s0 NE 100 0.1 2 30 NE NE 0.81 NE NE NE 1 NE 2 50 EPA Region 4-Effects Value NE NE NE 2 7.24 NE NE NE 0.676 NE NE 52.3 NE 18.7 NE 30.2 NE NE 0.13 NE 15.9 NE NE NE NE NE NE NE NE NE 124 Sample ID Sample Collection Date Analytical Results S-04 06/11/2015 88.9 6.8 10600 <22.9 45.8j 235 6.8 187 <2.8 9650 <218 8.9j 87.8 39.4 193000 <22.9 2820 1450 0.051j <11.5 66.7 <21.8 <1150 <22.9 <1150 98.7 267j <22.9 166000 30.9j 524 u S-09 05/20/2015 88.4 6.4 2390 <22.2 <22.2 23.9 2.3 86.2j <2.7 6500 <1100 <5.6 is8 10.6j 11200 <22.2 1490 277 0.068 <11.1 76.2 <110 <1110 <16.7 <1110 47.5 1660j <22.2 200000 <22.2 51.8 0 En S-10 06/11/2015 74.8 7 19000 <9.9 <9.9 150 1.2 <24.8 <1.2 3740 <100 25.6 41 27.5 29600 15.1j 2930 606 0.056 <5 18 <10 <497 <9.9 <497 41.2 105j <9.9 47600 62 106 SW-85DS 06/11/2015 63.8 6.7 10100 <7.1 <7.1 80.2 0.65 j <17.6 <0.85 1950 <67.6 15.3 23.2 13.9 30200 10.2 j 2050 267 0.035 <3.5 11.1 <6.8 <353 <7.1 <353 19.8 75.1 j <7.1 34800 42.7 56.2 S-16 06/11/2015 58.1 3.6 3670 <5.7 237 18.5 0.82 38 <0.69 984 <303 2j 14.3 <1.4 420000 <5.7 386 143 0.02 <2.9 29.5 <30.3 585 <5.7 <1150 21.7 4680 <5.7 50400 15.3 73.9 SW-BA1 05/20/2015 39 6.1 5520 <4.2 <4.2 46.2 0.26j <10.5 <0.5 669 <205 5.2 <4.2 7.4 1.2600 8.2j 728 223 0.02 <2.1 2.3 <20.5 <210 <3.2 <210 8.4 <205 <4.2 11000 12.6 17.3 SW-BA2 05/20/2015 68.3 5 10200 <8.2 <8.2 127 0.62j 25.6j <0.98 1010 <380 23.3 12.8j 61.1 33900 11.2j 1300 502 0.057 <4.1 14.5 <38 <409 <6.1 <409 12.3 <380 <8.2 198000 34.6 46.2 SW-BB1 05/20/2015 23.4 5.9 1660 <3.2 <3.2 13.9 <0.16 <8.1 <0.39 226 <160 1.4 j <3.2 2 3640 <3.2 215 32.6 0.0067 j <1.6 0.87 j <16 <161 <2.4 <161 1.9 j <160 <3.2 1060 3.4 j 7.8 SW-CFDG 06/11/2015 32.8 6.2 8270 <3.8 <3.8 69.4 0.3j <9.4 <0.45 875 <182 47 11.6 17.1 15500 13.3 1300 537 0.055 <1.9 6.2 <18.6 2711 <3.8 <188 9.9 <182 <3.8 15500 38.5 42.6 C 'y SW-CFDG DUP 06/11/2015 34 6 6120 <3.8 <3.8 46 0.21 j <9.5 <0.46 603 <187 24.3 8.5 10.1 12200 8.5 918 300 0.03 <1.9 4.3 <18.7 1931 <3.8 <190 7 <187 <3.8 20600 31.6 29.1 d cc SW -HAW 06/11/2015 31.2 6 3620 <3.5 <3.5 37.1 <0.18 <8.8 <0.42 481 <182 16 5.9 j 5.6 8810 5.1 j 660 503 0.018 <1.8 3.2 <18.2 <175 <3.5 <175 5.6 <182 <3.5 8620 21.3 29.2 SW-SHD-56 05/19/2015 41.9 6.4 13600 <4.1 <4.1 123 0.66 <10.2 <0.49 1030 <211 44.6 22.6 24.3 30600 17.7 2200 1550 0.12 <2 7.9 <21.1 393j <3.1 <204 13.5 <211 <4.1 29800 66.9 53.3 SW-SHD-PLANT 05/19/2015 41.2 6.1 6780 <4.3 <4.3 74.6 0.56 <10.7 1 1010 <207 18.2 7.3j 11.6 11500 6.7j 1440 380 0.023 <2.1 5.6 <20.7 4221 <3.2 <215 12.7 <207 <4.3 6930 20.2 34.7 SW-SHD-REF 05/20/2015 51.7 6.1 7710 <5.1 <5.1 101 0.49j <12.7 <0.61 1320 <252 8.8 9j 12.5 15600 9.2j 2390 358 0.024 <2.5 9.8 <25.2 4281 <3.8 <255 14.3 <252 <5.1 15600 14.5 39.7 SW-UNT 05/19/2015 36.9 6.8 5900 <4.1 <4.1 120 0.97 24.9 <0.49 40300 <195 15 21.4 14.2 29500 8.5 1210 1200 0.014 2.4j 5.4 <19.5 <205 <3.1 362j 104 <195 <4.1 4240 41.3 23.7 Prepared by: MMS/SRW Checked by: GMH Notes: Bold highlighted concentrations indicate highest exceedance of the category listed below: - EPA Region 4 Soil Screening Levels - EPA Region 4 Effects Value - MDL is greater than EPA Region 4 Soil Screening Levels - MDL is greater than EPA Region 4 Effects Value Dup = Duplicate mg/kg = miligram per kilogram NE = Not established j = indicates concentration reported below Practical Quantitation Limit (PQL), but above Method Detection Limit (MDL) and therefore concentration is estimated. < = concentration not detected at or above the reporting limit. S.U. = Standard Units %= percent P:\Duke Energy Progress. 1026\103. Cape Fear Ash Basin GW Assessment\1.11 CSA Reporting\Tables\Table 12-14 Sediment Analytical Results Eco.xlsx Page 1 of 1 TABLE 12-15 MATRIX FOR DETERMINATION OF CONSTITUENTS OF POTENTIAL CONCERN - ECOLOGICAL CAPE FEAR STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, MONCURE, NC Analytical Parameter pH Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chloride Chromium Cobalt Copper Iron Lead Magnesium Manganese Mercury Methane Molybdenum Nickel Nitrate (as N) Potassium Selenium Sodium Strontium Sulfate Sulfide Thallium Total Organic Carbon Vanadium Zinc Medium/Basis for COPC Designation Soil Concentration exceeds screening value ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ MDL Exceeds screening value ✓ ✓ ✓ ✓ ✓ No screening value ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ Sediment Concentration exceeds screening value ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ MDL Exceeds screening value ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ No screening value ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ Surface Water Concentration exceeds screening value ✓ ✓ ✓ ✓ ✓ MDL Exceeds screening value ✓ ✓ ✓ ✓ No screening value ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ Seep Concentration exceeds screening value ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ MDL Exceeds screening value ✓ ✓ ✓ ✓ No screening value ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ ✓ Prepared by: MMS KDF Checked by: MMS Notes: Constituent determined to be a COPC due to exceedance of one or more screening criteria at one or more sample locations ✓ Constituent determined to be a tentative COPC due to a lack of screening criteria Constituent not determined to be a COPC due to no exceedances of any screening criteria at any sample locations Based on data from Tables 12-13 through 12-15 P:\Duke Energy Progress. 1026\103. Cape Fear Ash Basin GW Assessment\1.11 CSA Reporting\Tables\Table 12-15 Matrix Determin COPCs- Eco.xlsx Page 1 of 1 TABLE 16-1 RECOMMENDED GROUNDWATER MONITORING PARAMETERS CAPE FEAR STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, MONCURE, NC PARAMETER I RL JUNITS IMETHOD FIELD PARAMETERS pH NA SU Field Water Quality Meter Specific Conductance NA µS/cm Field Water Quality Meter Temperature NA DC Field Water Quality Meter Dissolved Oxygen NA mg/L Field Water Quality Meter Oxidation Reduction Potential NA mV Field Water Quality Meter Turbidity NA NTU Field Water Quality Meter INORGANICS Aluminum 0.005 mg/L EPA 200.7 or 6010C Antimony 0.001 m /L EPA 200.8 or 6020A Arsenic 0.001 mg/L EPA 200.8 or 602OA Barium 0.005 m /L EPA 200.7 or 6010C Beryllium 0.001 mg/L EPA 200.8 or 6020A Boron 0.05 m /L EPA 200.7 or 6010C Cadmium 0.001 mg/L EPA 200.8 or 6020A Chromium 0.001 m /L EPA 200.7 or 6010C Cobalt 0.001 mg/L EPA 200.8 or 602OA Copper 0.001 m /L EPA 200.8 or 602OA Iron 0.01 mg/L EPA 200.7 or 6010C Lead 0.001 m /L EPA 200.8 or 602OA Manganese 0.005 mg/L EPA 200.8 or 602OA Mercury 0.0005 m /L EPA 245.1 Molybdenum 0.001 mg/L EPA 200.8 or 6020A Nickel 0.001 m /L EPA 200.7 or 6010C Selenium 0.001 mg/L EPA 200.8 or 6020A Silver 10.001 m /L EPA 200.8 or 6020A Thallium (low level) 0.0002 mg/L EPA 200.8 or 6020A Vanadium 0.0003 m /L EPA 200.8 or 6020A Zinc 0.005 mg/L EPA 200.7 or 6010C ANIONS/CATIONS Alkalinity (as CaCO3) 20 mg/L SM 2320B Bicarbonate 20 m /L SM 2320 Calcium 0.01 mg/L EPA 200.7 Carbonate 20 m /L SM 2320 Chloride 0.1 mg/L EPA 300.0 or 9056A Magnesium 0.005 m /L EPA 200.7 Nitrate as Nitrogen 0.023 mg-N/L EPA 300.0 or 9056A Potassium 0.1 m /L EPA 200.7 Sodium 0.05 mg/L EPA 200.7 Sulfate 0.1 mq/L EPA 300.0 or 9056A Total Dissolved Solids 25 m /L SM 2540C Total Oraanic Carbon 0.1 ma/L ISM 5310 Total Suspended Solids 12 m L ISM 2450D Prepared by: RBI Checked by: BDW Notes: 1. Select constituents will be analyzed for total and dissolved concentrations. NA indicates not applicable. P:\Duke Energy Progress.1026\103. Cape Fear Ash Basin GW Assessment\1.11 CSA Reporting\Tables\Table 16-1 Recommended Groundwater Monitoring Parameters.xlsx Page 1 of 1 TABLE 16-2 RECOMMENDED GROUNDWATER MONITORING LOCATIONS CAPE FEAR STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, MONCURE, NC Section Monitoring Well ID Geologic Unit Monitored Monitoring Rationale Running Count A -A' ABMW-01 Ash Pore Water Monitor constituent concentrations in the 1985 ash basin 1 A -A' ABMW-01S Surficial - Lower Monitor constituent migration beneath the 1985 ash basin 2 A -A' ABMW-01BR Bedrock Monitor constituent migration beneath the 1985 ash basin 3 B-B' ABMW-02SU Surficial - Upper Monitor constituent migration beneath the 1978 ash basin 4 B-B' ABMW-02SL Surficial - Lower Monitor constituent migration beneath the 1978 ash basin 5 A -A' ABMW-03 Ash Pore Water Monitor constituent concentrations in the 1970 ash basin 6 A -A' ABMW-03S Surficial - Lower Monitor constituent migration beneath the 1970 ash basin 7 A -A' ABMW-03BR Bedrock Monitor constituent migration beneath the 1970 ash basin 8 B-B' ABMW-04 Ash Pore Water Monitor constituent concentrations in the 1963 ash basin 9 B-B' ABMW-04S Surficial - Lower Monitor constituent migration beneath the 1963 ash basin 10 C-C' ABMW-05 Ash Pore Water Monitor constituent concentrations in the 1956 ash basin 11 C-C' ABMW-05S Surficial - Lower Monitor constituent migration beneath the 1956 ash basin 12 C-C' ABMW-05BR Bedrock Monitor constituent migration beneath the 1956 ash basin 13 C-C' BGMW-04 Surficial - Upper Determine & monitor background concentrations upgradient of basins 14 C-C' BGTMW-04 Bedrock Determine & monitor background concentrations upgradient of basins 15 A -A' CMW-01 Surficial - Upper Monitor constituent migration downgradient of the 1970 ash basin 16 A -A' CTMW-01 Bedrock Monitor constituent migration downgradient of the 1970 ash basin 17 C-C' CMW-02 Surficial - Upper Monitor constituent migration downgradient of the 1956 ash basin 18 C-C' CTMW-02 Bedrock Monitor constituent migration downgradient of the 1956 ash basin 19 CMW-03 Surficial - Upper Monitor constituent migration downgradient of the 1956 ash basin 20 A -A' CMW-05 Surficial - Lower Monitor constituent migration downgradient of the 1985 ash basin 21 B-B' CMW-06 Surficial - Upper Monitor constituent migration downgradient of the 1985 ash basin 22 A -A' CMW-07 Surficial - Lower Monitor constituent migration downgradient of the 1978 ash basin 23 A -A' CTMW-07 Bedrock Monitor constituent migration downgradient of the 1978 ash basin 24 B-B' CMW-08 Surficial - Upper Monitor constituent migration downgradient of the 1963 ash basin 25 B-B' CTMW-08 Bedrock Monitor constituent migration downgradient of the 1963 ash basin 26 A -A' MW-05BR Bedrock Monitor constituent migration downgradient of the 1985 ash basin 27 B-B' MW-06BR Bedrock Monitor constituent migration downgradient of the 1985 ash basin 28 B-B' MW-09 Saprolite - Bedrock Determine & monitor background concentrations upgradient of basins 29 B-B' MW-09BR Bedrock Determine & monitor background concentrations upgradient of basins 30 MW-10 Surficial - Lower Monitor constituent migration downgradient of the 1956 ash basin 31 MW-10D Bedrock Monitor constituent migration downgradient of the 1956 ash basin 32 MW-10BR Bedrock Monitor constituent migration downgradient of the 1956 ash basin 33 MW-11 Surficial - Upper Monitor constituent migration downgradient of the 1985 ash basin 34 MW-12 Surficial - Upper Monitor constituent migration downgradient of the 1985 ash basin 35 MW-12BR Bedrock Monitor constituent migration downgradient of the 1985 ash basin 36 MW-13 Surficial - Upper Monitor constituent migration downgradient of the 1970 ash basin 37 B-B' MW-14 Bedrock Monitor constituent migration downgradient of the 1963 ash basin 38 C-C' MW-15SU Surficial - Upper Determine & monitor background concentrations upgradient of basins 39 C-C' MW-15SL Surficial - Lower Determine & monitor background concentrations upgradient of basins 40 C-C' MW-15BR Bedrock Determine & monitor background concentrations upgradient of basins 41 A -A' MW-16S Surficial - Lower Determine & monitor background concentrations upgradient of basins 42 A -A' MW-16BR Bedrock Determine & monitor background concentrations upgradient of basins 43 MW-17SU Surficial - Upper Monitor constituent migration downgradient of the 1985 ash basin 44 MW-17SL Surficial - Lower Monitor constituent migration downgradient of the 1985 ash basin 45 MW-17BR Bedrock Monitor constituent migration downgradient of the 1985 ash basin 46 MW-18S Surficial - Upper Monitor constituent migration downgradient of the 1985 ash basin 47 A -A' MW-19S Surficial - Upper Monitor constituent migration downgradient of the 1978 ash basin 48 MW-20S Surficial - Lower Monitor constituent migration downgradient of the 1970 ash basin 49 MW-20BR Bedrock Monitor constituent migration downgradient of the 1970 ash basin 50 MW-21SU Surficial - Upper Monitor constituent migration downgradient of the 1963 ash basin 51 MW-21SL Surficial - Lower Monitor constituent migration downgradient of the 1963 ash basin 52 MW-21BR Bedrock Monitor constituent migration downgradient of the 1963 ash basin 53 PZ-01* Surficial - Upper Monitor constituent migration downgradient of the 1985 ash basin 54 PZ-02* Surficial - Upper Monitor constituent migration downgradient of the 1985 ash basin 55 PZ-03S* Surficial - Upper Monitor constituent migration downgradient of the 1985 ash basin 56 PZ-03D* Bedrock Monitor constituent migration downgradient of the 1985 ash basin 57 PZ-04* Surficial - Upper Monitor constituent migration downgradient of the 1985 ash basin 58 A-A PZ-05* Surficial - Upper Monitor constituent migration downgradient of the 1985 ash basin 59 PZ-06* Ash Pore Water Monitor constituent concentrations in the 1985 ash basin 60 PZ-07* Ash Pore Water Monitor constituent concentrations in the 1970 ash basin 61 PZ-08* Ash Pore Water Monitor constituent concentrations in the 1963 ash basin 1 Monitor constituent concentrations in the 1956 ash basin 62 C-C' I PZ-10* I Ash Pore Water 63 *Piezometer Prepared by: CJS Checked by:DGN File: P:\Duke Energy Progress. 1 026\1 03. Cape Fear Ash Basin GW Assessment\1.11 CSA Reporting\Tables\Table 16-2 Recommended Monitoring Locations.xlsx Page 1 of 1 TABLE 17-1 MAXIMUM CONCENTRATIONS FOR CONSTITUENTS OF INTEREST CAPE FEAR STEAM ELECTRIC PLANT DUKE ENERGY PROGRESS, LLC, MONCURE, NC Soil Sample Soil Groundwater Groundwater COI Concentration Concentration (depth ft) (mg/kg) (location) (µ9/L) Antimony Not detected Not detected ABMW-01S 1.85 Arsenic ABMW-05 SB 41.9 ABMW-01S 27.7 (23-24) Beryllium ABMW-05 SB 3.6 MW-15SU 10 (23-24) Boron ABMW-02 SB 53.2 PZ-05 4,910 (27-28) AB B-06 06 Chromium 28.7 ABMW-03S 8.68 - Cobalt MW-188)SB 34.7 MW-15SU 387 Iron ABMW-02 SB 60,400 MW-17SL 175,000 (27-28) Manganese MW-18 SB 3520 MW-17SU 45,500 pH (lowest) MW-21 SB 3.6 ABMW-02SU 3.8 (5-6) pH ABMW-01 SB 8.6 ABMW-03S 11.7 (highest) (69-71) Selenium ABMW-05 SB 11.6 PZ-09 96.1 (23-24) Sulfate MW-15 SB 539 MW-15SU 1,600 Total Dissolved NA NA CMW-08 56 mg/L Soils Thallium Not detected Not detected PZ-09 0.574 Vanadium MW-19 SB 97 ABMW-01S 73.3 Prepared by: CIS Checked by: RKD P:\Duke Energy Progress.1026\103. 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