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Home My WebLink AboutNC0003433_J15080088report_20150902Lab DUI E Analytical Laboratory APagel1aof64 ENERGY Order Number: Project Name: Customer Name(s): Customer Address: Lab Contact: Report Authorized By: (Signature) Program Comments: 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone:980-875-5245 Fax:980-875-4349 Order Summary Report J15080088 CAPE FEAR - AB GW ASSESSMENT WATER Tim Hunsucker, Chris Suttell, Kathy Webb, John Toepfer Mary Ann Ogle Phone: 980-875-5274 m ergy.ce@duke ✓/�/S 2015.0.12 Date: 2015.08.12 11:27:14-04'00' Mary Ann Ogle Please contact the Program Manager (Mary Ann Ogle) with any questions regarding this report. Data Flags & Calculations: 8/12/2015 Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Sample ID's & Descriptions: Collection Sample ID Plant/Station Date and Time 2015025942 2015025943 2015025944 2015025945 2015025946 2015025947 2015025948 2015025949 8 Total Samples Collected By Sample Description Cape Fear 05-Aug-15 10:21 AM Joshua Hunter PZ-4 Cape Fear 05-Aug-15 1:35 PM Joshua Hunter PZ-3S Cape Fear 05-Aug-15 12:12 PM Joshua Hunter PZ-6 Cape Fear 05-Aug-15 9:15 AM Joshua Hunter PZ-5 Cape Fear 05-Aug-15 2:48 PM Joshua Hunter PZ-3D Cape Fear 05-Aug-15 4:48 PM Joshua Hunter PZ-8 Cape Fear 05-Aug-15 7:30 AM Filter Blank Cape Fear 05-Aug-15 7:30 AM Equipment Blank Analytical Lab Page 2 of 64 Analytical Lab Page 3 of 64 Technical Validation Review Checklist: COC and .pdf report are in agreement with sample totals 0 Yes ❑ No and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. ❑ Yes 0 No All laboratory QA/QC requirements are acceptable. 0 Yes ❑ No Report Sections Included: E%-'] Job Summary Report ❑� Sample Identification Technical Validation of Data Package ❑� Analytical Laboratory Certificate of Analysis ❑ Analytical Laboratory QC Report ❑d Sub -contracted Laboratory Results ❑ Customer Specific Data Sheets, Reports, & Documentation ❑ Customer Database Entries ❑� Chain of Custody ❑� Electronic Data Deliverable (EDD) Sent Separately Reviewed By: Mary Ann Ogle Date: 8/12/2015 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15080088 Site: PZ-4 Collection Date: 05-Aug-15 10:21 AM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.038 mg-N/L 0.01 INORGANIC IONS BY IC Chloride 55 mg/L 1 Sulfate 150 mg/L 5 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) < 0.005 mg/L 0.005 Barium (Ba) 0.035 mg/L 0.005 Boron (B) 1.46 mg/L 0.05 Iron (Fe) 1.08 mg/L 0.01 Manganese (Mn) 0.508 mg/L 0.005 Strontium (Sr) 0.338 mg/L 0.005 Zinc (Zn) 0.019 mg/L 0.005 UNDIGESTED METALS BY lCP Calcium (Ca) 33.9 mg/L 0.01 Magnesium (Mg) 25.3 mg/L M4 0.05 Potassium (K) 0.305 mg/L 0.1 Sodium (Na) 88.1 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.087 mg/L 0.005 Barium (Ba) 0.036 mg/L 0.005 Boron (B) 1.44 mg/L 0.05 Iron (Fe) 1.29 mg/L 0.01 Manganese (Mn) 0.519 mg/L 0.005 Strontium (Sr) 0.341 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 Sample #: 2015025942 Matrix: GW_WW Analytical Lab Page 4 of 64 DF Method Analysis Date/Time Analyst Vendor Method V_SHEALY 1 EPA 353.2 08/10/2015 13:54 LSTARLI 10 EPA 300.0 08/07/2015 08:58 BGN9034 50 EPA 300.0 08/07/2015 08:58 BGN9034 1 EPA 245.1 08/07/2015 13:33 ACPAYNE 1 EPA 245.1 08/06/2015 16:15 ACPAYNE 1 EPA 200.7 08/07/2015 10:35 MHALL3 1 EPA 200.7 08/07/2015 10:35 MHALL3 1 EPA 200.7 08/07/2015 10:35 MHALL3 1 EPA 200.7 08/07/2015 10:35 MHALL3 1 EPA 200.7 08/07/2015 10:35 MHALL3 1 EPA 200.7 08/07/2015 10:35 MHALL3 1 EPA 200.7 08/07/2015 10:35 MHALL3 1 EPA 200.7 08/10/2015 09:54 FCJORDA 10 EPA 200.7 08/10/2015 09:54 FCJORDA 1 EPA 200.7 08/10/2015 09:54 FCJORDA 1 EPA 200.7 08/10/2015 09:54 FCJORDA 1 EPA 200.7 08/10/2015 12:31 MHALL3 1 EPA 200.7 08/10/2015 12:31 MHALL3 1 EPA 200.7 08/10/2015 12:31 MHALL3 1 EPA 200.7 08/10/2015 12:31 MHALL3 1 EPA 200.7 08/10/2015 12:31 MHALL3 1 EPA 200.7 08/10/2015 12:31 MHALL3 1 EPA 200.7 08/10/2015 12:31 MHALL3 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15080088 Site: PZ-4 Collection Date: 05-Aug-15 10:21 AM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) 1.30 ug/L 1 Copper (Cu) 1.89 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) 3.51 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level 0.351 ug/L 0.2 Vanadium (V) Low Level 0.432 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) 1.31 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) 9.70 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level 0.979 ug/L 0.3 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4) Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 470 mg/L 25 Total Carbon TOC 1.9 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 Sample #: 2015025942 Matrix: GW_WW Analytical Lab Page 5 of 64 DF Method Analysis Date/Time Analyst 1 EPA 200.8 08/10/2015 15:55 JAHERMA 1 EPA 200.8 08/10/2015 15:55 JAHERMA 1 EPA 200.8 08/10/2015 15:55 JAHERMA 1 EPA 200.8 08/10/2015 15:55 JAHERMA 1 EPA 200.8 08/10/2015 15:55 JAHERMA 1 EPA 200.8 08/10/2015 15:55 JAHERMA 1 EPA 200.8 08/10/2015 15:55 JAHERMA 1 EPA 200.8 08/10/2015 15:55 JAHERMA 1 EPA 200.8 08/10/2015 15:55 JAHERMA 1 EPA 200.8 08/10/2015 15:55 JAHERMA 1 EPA 200.8 08/10/2015 15:55 JAHERMA 1 EPA 200.8 08/10/2015 15:55 JAHERMA 1 EPA 200.8 08/10/2015 15:55 JAHERMA 1 EPA 200.8 08/06/2015 17:10 MHALL3 1 EPA 200.8 08/06/2015 17:10 MHALL3 1 EPA 200.8 08/06/2015 17:10 MHALL3 1 EPA 200.8 08/06/2015 17:10 MHALL3 1 EPA 200.8 08/06/2015 17:10 MHALL3 1 EPA 200.8 08/06/2015 17:10 MHALL3 1 EPA 200.8 08/06/2015 17:10 MHALL3 1 EPA 200.8 08/06/2015 17:10 MHALL3 1 EPA 200.8 08/06/2015 17:10 MHALL3 1 EPA 200.8 08/06/2015 17:10 MHALL3 1 EPA 200.8 08/06/2015 17:10 MHALL3 1 EPA 200.8 08/06/2015 17:10 MHALL3 1 EPA 200.8 08/06/2015 17:10 MHALL3 Vendor Method V_SHEALY Vendor Method V_PACE 1 SM2540C 08/06/201516:15 GHUTCHI 1 SM5310C/EPA9060A 08/06/201513:06 TJA7067 1 SM2540D 08/06/2015 09:15 GHUTCHI Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15080088 Site: PZ-3S Collection Date: 05-Aug-15 1:35 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.032 mg-N/L 0.01 INORGANIC IONS BY IC Chloride 67 mg/L 1 Sulfate 170 mg/L 5 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) < 0.005 mg/L 0.005 Barium (Ba) 0.013 mg/L 0.005 Boron (B) 2.44 mg/L 0.05 Iron (Fe) 0.015 mg/L 0.01 Manganese (Mn) 0.131 mg/L 0.005 Strontium (Sr) 0.187 mg/L 0.005 Zinc (Zn) 0.078 mg/L 0.005 UNDIGESTED METALS BY lCP Calcium (Ca) 20.6 mg/L 0.01 Magnesium (Mg) 16.6 mg/L 0.005 Potassium (K) 0.146 mg/L 0.1 Sodium (Na) 142 mg/L 0.5 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.275 mg/L 0.005 Barium (Ba) 0.015 mg/L 0.005 Boron (B) 2.44 mg/L 0.05 Iron (Fe) 0.255 mg/L 0.01 Manganese (Mn) 0.182 mg/L 0.005 Strontium (Sr) 0.196 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 Sample #: 2015025943 Matrix: GW_WW Analytical Lab Page 6 of 64 DF Method Analysis Date/Time Analyst Vendor Method V_SHEALY 1 EPA 353.2 08/10/2015 13:57 LSTARLI 10 EPA 300.0 08/07/2015 09:16 BGN9034 50 EPA 300.0 08/07/2015 09:16 BGN9034 1 EPA 245.1 08/07/2015 13:17 ACPAYNE 1 EPA 245.1 08/06/2015 16:22 ACPAYNE 1 EPA 200.7 08/07/2015 11:27 MHALL3 1 EPA 200.7 08/07/2015 11:27 MHALL3 1 EPA 200.7 08/07/2015 11:27 MHALL3 1 EPA 200.7 08/07/2015 11:27 MHALL3 1 EPA 200.7 08/07/2015 11:27 MHALL3 1 EPA 200.7 08/07/2015 11:27 MHALL3 1 EPA 200.7 08/07/2015 11:27 MHALL3 1 EPA 200.7 08/10/2015 10:05 FCJORDA 1 EPA 200.7 08/10/2015 10:05 FCJORDA 1 EPA 200.7 08/10/2015 10:05 FCJORDA 10 EPA 200.7 08/10/2015 10:05 FCJORDA 1 EPA 200.7 08/10/2015 12:35 MHALL3 1 EPA 200.7 08/10/2015 12:35 MHALL3 1 EPA 200.7 08/10/2015 12:35 MHALL3 1 EPA 200.7 08/10/2015 12:35 MHALL3 1 EPA 200.7 08/10/2015 12:35 MHALL3 1 EPA 200.7 08/10/2015 12:35 MHALL3 1 EPA 200.7 08/10/2015 12:35 MHALL3 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15080088 Site: PZ-3S Collection Date: 05-Aug-15 1:35 PM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) 9.03 ug/L 1 Lead (Pb) 1.10 ug/L 1 Molybdenum (Mo) 1.50 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level 1.26 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) 1.48 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level 1.97 ug/L 0.3 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4) Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 590 mg/L 25 Total Carbon TOC 0.733 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 Sample #: 2015025943 Matrix: GW_WW Analytical Lab Page 7 of 64 DF Method Analysis Date/Time Analyst 1 EPA 200.8 08/10/2015 16:02 JAHERMA 1 EPA 200.8 08/10/2015 16:02 JAHERMA 1 EPA 200.8 08/10/2015 16:02 JAHERMA 1 EPA 200.8 08/10/2015 16:02 JAHERMA 1 EPA 200.8 08/10/2015 16:02 JAHERMA 1 EPA 200.8 08/10/2015 16:02 JAHERMA 1 EPA 200.8 08/10/2015 16:02 JAHERMA 1 EPA 200.8 08/10/2015 16:02 JAHERMA 1 EPA 200.8 08/10/2015 16:02 JAHERMA 1 EPA 200.8 08/10/2015 16:02 JAHERMA 1 EPA 200.8 08/10/2015 16:02 JAHERMA 1 EPA 200.8 08/10/2015 16:02 JAHERMA 1 EPA 200.8 08/10/2015 16:02 JAHERMA 1 EPA 200.8 08/06/2015 17:38 MHALL3 1 EPA 200.8 08/06/2015 17:38 MHALL3 1 EPA 200.8 08/06/2015 17:38 MHALL3 1 EPA 200.8 08/06/2015 17:38 MHALL3 1 EPA 200.8 08/06/2015 17:38 MHALL3 1 EPA 200.8 08/06/2015 17:38 MHALL3 1 EPA 200.8 08/06/2015 17:38 MHALL3 1 EPA 200.8 08/06/2015 17:38 MHALL3 1 EPA 200.8 08/06/2015 17:38 MHALL3 1 EPA 200.8 08/06/2015 17:38 MHALL3 1 EPA 200.8 08/06/2015 17:38 MHALL3 1 EPA 200.8 08/06/2015 17:38 MHALL3 1 EPA 200.8 08/06/2015 17:38 MHALL3 Vendor Method V_SHEALY Vendor Method V_PACE 1 SM2540C 08/06/201516:15 GHUTCHI 1 SM5310C/EPA9060A 08/06/201513:06 TJA7067 1 SM2540D 08/06/2015 09:15 GHUTCHI Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15080088 Site: PZ-6 Collection Date: 05-Aug-15 12:12 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) < 0.01 mg-N/L 0.01 INORGANIC IONS BY IC Chloride 23 mg/L 1 Sulfate 230 mg/L 5 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) 0.043 mg/L 0.005 Barium (Ba) 0.307 mg/L 0.005 Boron (B) 5.16 mg/L 0.05 Iron (Fe) 2.66 mg/L 0.01 Manganese (Mn) 1.07 mg/L 0.005 Strontium (Sr) 5.23 mg/L 0.005 Zinc (Zn) 0.022 mg/L 0.005 UNDIGESTED METALS BY lCP Calcium (Ca) 183 mg/L 0.1 Magnesium (Mg) 24.9 mg/L 0.05 Potassium (K) 13.0 mg/L 0.1 Sodium (Na) 22.0 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.170 mg/L 0.005 Barium (Ba) 0.312 mg/L 0.005 Boron (B) 5.38 mg/L 0.05 Iron (Fe) 3.05 mg/L 0.01 Manganese (Mn) 1.11 mg/L 0.005 Strontium (Sr) 5.22 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 Sample #: 2015025944 Matrix: GW_WW Analytical Lab Page 8 of 64 DF Method Analysis Date/Time Analyst Vendor Method V_SHEALY 1 EPA 353.2 08/10/2015 13:59 LSTARLI 10 EPA 300.0 08/07/2015 09:34 BGN9034 50 EPA 300.0 08/07/2015 09:34 BGN9034 1 EPA 245.1 08/07/2015 13:19 ACPAYNE 1 EPA 245.1 08/06/2015 16:25 ACPAYNE 1 EPA 200.7 08/07/2015 10:52 MHALL3 1 EPA 200.7 08/07/2015 10:52 MHALL3 1 EPA 200.7 08/07/2015 10:52 MHALL3 1 EPA 200.7 08/07/2015 10:52 MHALL3 1 EPA 200.7 08/07/2015 10:52 MHALL3 1 EPA 200.7 08/07/2015 10:52 MHALL3 1 EPA 200.7 08/07/2015 10:52 MHALL3 10 EPA 200.7 08/10/2015 10:09 FCJORDA 10 EPA 200.7 08/10/2015 10:09 FCJORDA 1 EPA 200.7 08/10/2015 10:09 FCJORDA 1 EPA 200.7 08/10/2015 10:09 FCJORDA 1 EPA 200.7 08/10/2015 13:26 MHALL3 1 EPA 200.7 08/10/2015 13:26 MHALL3 1 EPA 200.7 08/10/2015 13:26 MHALL3 1 EPA 200.7 08/10/2015 13:26 MHALL3 1 EPA 200.7 08/10/2015 13:26 MHALL3 1 EPA 200.7 08/10/2015 13:26 MHALL3 1 EPA 200.7 08/10/2015 13:26 MHALL3 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15080088 Site: PZ-6 Collection Date: 05-Aug-15 12:12 PM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) 2.17 ug/L 1 Arsenic (As) 607 ug/L 10 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) 18.6 ug/L 1 Copper (Cu) 3.81 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) 263 ug/L 1 Nickel (Ni) 16.2 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level 9.31 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) 2.30 ug/L 1 Arsenic (As) 647 ug/L 10 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) 18.7 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) 269 ug/L 1 Nickel (Ni) 15.9 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level 0.255 ug/L 0.2 Vanadium (V) Low Level 11.1 ug/L 0.3 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4) Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 760 mg/L 25 Total Carbon TOC 1.1 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS 13 mg/L 5 Sample #: 2015025944 Matrix: GW_WW Analytical Lab Page 9 of 64 DF Method Analysis Date/Time Analyst 1 EPA 200.8 08/10/2015 16:09 JAHERMA 10 EPA 200.8 08/10/2015 16:09 JAHERMA 1 EPA 200.8 08/10/2015 16:09 JAHERMA 1 EPA 200.8 08/10/2015 16:09 JAHERMA 1 EPA 200.8 08/10/2015 16:09 JAHERMA 1 EPA 200.8 08/10/2015 16:09 JAHERMA 1 EPA 200.8 08/10/2015 16:09 JAHERMA 1 EPA 200.8 08/10/2015 16:09 JAHERMA 1 EPA 200.8 08/10/2015 16:09 JAHERMA 1 EPA 200.8 08/10/2015 16:09 JAHERMA 1 EPA 200.8 08/10/2015 16:09 JAHERMA 1 EPA 200.8 08/10/2015 16:09 JAHERMA 1 EPA 200.8 08/10/2015 16:09 JAHERMA 1 EPA 200.8 08/06/2015 17:45 MHALL3 10 EPA 200.8 08/06/2015 17:45 MHALL3 1 EPA 200.8 08/06/2015 17:45 MHALL3 1 EPA 200.8 08/06/2015 17:45 MHALL3 1 EPA 200.8 08/06/2015 17:45 MHALL3 1 EPA 200.8 08/06/2015 17:45 MHALL3 1 EPA 200.8 08/06/2015 17:45 MHALL3 1 EPA 200.8 08/06/2015 17:45 MHALL3 1 EPA 200.8 08/06/2015 17:45 MHALL3 1 EPA 200.8 08/06/2015 17:45 MHALL3 1 EPA 200.8 08/06/2015 17:45 MHALL3 1 EPA 200.8 08/06/2015 17:45 MHALL3 1 EPA 200.8 08/06/2015 17:45 MHALL3 Vendor Method V_SHEALY Vendor Method V_PACE 1 SM2540C 08/06/201516:15 GHUTCHI 1 SM5310C/EPA9060A 08/06/201513:06 TJA7067 1 SM2540D 08/06/2015 09:15 GHUTCHI Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15080088 Site: PZ-5 Collection Date: 05-Aug-15 9:15 AM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) < 0.01 mg-N/L 0.01 INORGANIC IONS BY IC Chloride 28 mg/L 1 Sulfate 270 mg/L 5 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) 0.008 mg/L 0.005 Barium (Ba) 0.025 mg/L 0.005 Boron (B) 4.77 mg/L 0.05 Iron (Fe) 0.075 mg/L 0.01 Manganese (Mn) 2.93 mg/L 0.005 Strontium (Sr) 0.351 mg/L 0.005 Zinc (Zn) 0.026 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 36.5 mg/L 0.01 Magnesium (Mg) 31.3 mg/L 0.05 Potassium (K) 0.316 mg/L 0.1 Sodium (Na) 58.6 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.087 mg/L 0.005 Barium (Ba) 0.026 mg/L 0.005 Boron (B) 4.91 mg/L 0.05 Iron (Fe) 0.200 mg/L 0.01 Manganese (Mn) 2.99 mg/L 0.005 Strontium (Sr) 0.358 mg/L 0.005 Zinc (Zn) 0.006 mg/L 0.005 Sample #: 2015025945 Matrix: GW_WW Analytical Lab Page 10 of 64 DF Method Analysis Date/Time Analyst Vendor Method V_SHEALY 1 EPA 353.2 08/10/2015 14:00 LSTARLI 10 EPA 300.0 08/07/2015 09:52 BGN9034 50 EPA 300.0 08/07/2015 09:52 BGN9034 1 EPA 245.1 08/07/2015 13:21 ACPAYNE 1 EPA 245.1 08/06/2015 16:27 ACPAYNE 1 EPA 200.7 08/07/2015 11:01 MHALL3 1 EPA 200.7 08/07/2015 11:01 MHALL3 1 EPA 200.7 08/07/2015 11:01 MHALL3 1 EPA 200.7 08/07/2015 11:01 MHALL3 1 EPA 200.7 08/07/2015 11:01 MHALL3 1 EPA 200.7 08/07/2015 11:01 MHALL3 1 EPA 200.7 08/07/2015 11:01 MHALL3 1 EPA 200.7 08/10/2015 10:13 FCJORDA 10 EPA 200.7 08/10/2015 10:13 FCJORDA 1 EPA 200.7 08/10/2015 10:13 FCJORDA 1 EPA 200.7 08/10/2015 10:13 FCJORDA 1 EPA 200.7 08/10/2015 12:43 MHALL3 1 EPA 200.7 08/10/2015 12:43 MHALL3 1 EPA 200.7 08/10/2015 12:43 MHALL3 1 EPA 200.7 08/10/2015 12:43 MHALL3 1 EPA 200.7 08/10/2015 12:43 MHALL3 1 EPA 200.7 08/10/2015 12:43 MHALL3 1 EPA 200.7 08/10/2015 12:43 MHALL3 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15080088 Site: PZ-5 Collection Date: 05-Aug-15 9:15 AM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) 7.67 ug/L 1 Copper (Cu) 8.26 ug/L 1 Lead (Pb) 1.26 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) 6.39 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) 8.24 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) 6.53 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level 0.535 ug/L 0.3 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4) Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 510 mg/L 25 Total Carbon TOC 0.684 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 Sample #: 2015025945 Matrix: GW_WW Analytical Lab Page 11 of 64 DF Method Analysis Date/Time Analyst 1 EPA 200.8 08/10/2015 16:16 JAHERMA 1 EPA 200.8 08/10/2015 16:16 JAHERMA 1 EPA 200.8 08/10/2015 16:16 JAHERMA 1 EPA 200.8 08/10/2015 16:16 JAHERMA 1 EPA 200.8 08/10/2015 16:16 JAHERMA 1 EPA 200.8 08/10/2015 16:16 JAHERMA 1 EPA 200.8 08/10/2015 16:16 JAHERMA 1 EPA 200.8 08/10/2015 16:16 JAHERMA 1 EPA 200.8 08/10/2015 16:16 JAHERMA 1 EPA 200.8 08/10/2015 16:16 JAHERMA 1 EPA 200.8 08/10/2015 16:16 JAHERMA 1 EPA 200.8 08/10/2015 16:16 JAHERMA 1 EPA 200.8 08/10/2015 16:16 JAHERMA 1 EPA 200.8 08/06/2015 17:52 MHALL3 1 EPA 200.8 08/06/2015 17:52 MHALL3 1 EPA 200.8 08/06/2015 17:52 MHALL3 1 EPA 200.8 08/06/2015 17:52 MHALL3 1 EPA 200.8 08/06/2015 17:52 MHALL3 1 EPA 200.8 08/06/2015 17:52 MHALL3 1 EPA 200.8 08/06/2015 17:52 MHALL3 1 EPA 200.8 08/06/2015 17:52 MHALL3 1 EPA 200.8 08/06/2015 17:52 MHALL3 1 EPA 200.8 08/06/2015 17:52 MHALL3 1 EPA 200.8 08/06/2015 17:52 MHALL3 1 EPA 200.8 08/06/2015 17:52 MHALL3 1 EPA 200.8 08/06/2015 17:52 MHALL3 Vendor Method V_SHEALY Vendor Method V_PACE 1 SM2540C 08/06/201516:15 GHUTCHI 1 SM5310C/EPA9060A 08/06/201513:06 TJA7067 1 SM2540D 08/06/2015 09:15 GHUTCHI Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15080088 Site: PZ-3D Collection Date: 05-Aug-15 2:48 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.028 mg-N/L 0.01 INORGANIC IONS BY IC Chloride 62 mg/L 1 Sulfate 74 mg/L 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) < 0.005 mg/L 0.005 Barium (Ba) 0.131 mg/L 0.005 Boron (B) 0.057 mg/L 0.05 Iron (Fe) 0.021 mg/L 0.01 Manganese (Mn) 0.448 mg/L 0.005 Strontium (Sr) 0.662 mg/L 0.005 Zinc (Zn) 0.056 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 48.8 mg/L 0.01 Magnesium (Mg) 9.24 mg/L 0.005 Potassium (K) 2.40 mg/L 0.1 Sodium (Na) 73.2 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.057 mg/L 0.005 Barium (Ba) 0.138 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 0.097 mg/L 0.01 Manganese (Mn) 0.475 mg/L 0.005 Strontium (Sr) 0.646 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 Sample #: 2015025946 Matrix: GW_WW Analytical Lab Page 12 of 64 DF Method Analysis Date/Time Analyst Vendor Method V_SHEALY 1 EPA 353.2 08/10/2015 14:01 LSTARLI 10 EPA 300.0 08/06/2015 14:23 BGN9034 10 EPA 300.0 08/06/2015 14:23 BGN9034 1 EPA 245.1 08/07/2015 13:24 ACPAYNE 1 EPA 245.1 08/06/2015 16:29 ACPAYNE 1 EPA 200.7 08/07/2015 11:05 MHALL3 1 EPA 200.7 08/07/2015 11:05 MHALL3 1 EPA 200.7 08/07/2015 11:05 MHALL3 1 EPA 200.7 08/07/2015 11:05 MHALL3 1 EPA 200.7 08/07/2015 11:05 MHALL3 1 EPA 200.7 08/07/2015 11:05 MHALL3 1 EPA 200.7 08/07/2015 11:05 MHALL3 1 EPA 200.7 08/10/2015 10:17 FCJORDA 1 EPA 200.7 08/10/2015 10:17 FCJORDA 1 EPA 200.7 08/10/2015 10:17 FCJORDA 1 EPA 200.7 08/10/2015 10:17 FCJORDA 1 EPA 200.7 08/10/2015 12:51 MHALL3 1 EPA 200.7 08/10/2015 12:51 MHALL3 1 EPA 200.7 08/10/2015 12:51 MHALL3 1 EPA 200.7 08/10/2015 12:51 MHALL3 1 EPA 200.7 08/10/2015 12:51 MHALL3 1 EPA 200.7 08/10/2015 12:51 MHALL3 1 EPA 200.7 08/10/2015 12:51 MHALL3 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15080088 Site: PZ-3D Collection Date: 05-Aug-15 2:48 PM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) 5.01 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) 5.42 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) 5.49 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) 5.58 ug/L 1 Nickel (Ni) 1.36 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level 0.384 ug/L 0.3 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4) Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 390 mg/L 25 Total Carbon TOC 0.685 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS 5.0 mg/L 5 Sample #: 2015025946 Matrix: GW_WW Analytical Lab Page 13 of 64 DF Method Analysis Date/Time Analyst 1 EPA 200.8 08/10/2015 15:34 JAHERMA 1 EPA 200.8 08/10/2015 15:34 JAHERMA 1 EPA 200.8 08/10/2015 15:34 JAHERMA 1 EPA 200.8 08/10/2015 15:34 JAHERMA 1 EPA 200.8 08/10/2015 15:34 JAHERMA 1 EPA 200.8 08/10/2015 15:34 JAHERMA 1 EPA 200.8 08/10/2015 15:34 JAHERMA 1 EPA 200.8 08/10/2015 15:34 JAHERMA 1 EPA 200.8 08/10/2015 15:34 JAHERMA 1 EPA 200.8 08/10/2015 15:34 JAHERMA 1 EPA 200.8 08/10/2015 15:34 JAHERMA 1 EPA 200.8 08/10/2015 15:34 JAHERMA 1 EPA 200.8 08/10/2015 15:34 JAHERMA 1 EPA 200.8 08/06/2015 17:59 MHALL3 1 EPA 200.8 08/06/2015 17:59 MHALL3 1 EPA 200.8 08/06/2015 17:59 MHALL3 1 EPA 200.8 08/06/2015 17:59 MHALL3 1 EPA 200.8 08/06/2015 17:59 MHALL3 1 EPA 200.8 08/06/2015 17:59 MHALL3 1 EPA 200.8 08/06/2015 17:59 MHALL3 1 EPA 200.8 08/06/2015 17:59 MHALL3 1 EPA 200.8 08/06/2015 17:59 MHALL3 1 EPA 200.8 08/06/2015 17:59 MHALL3 1 EPA 200.8 08/06/2015 17:59 MHALL3 1 EPA 200.8 08/06/2015 17:59 MHALL3 1 EPA 200.8 08/06/2015 17:59 MHALL3 Vendor Method V_SHEALY Vendor Method V_PACE 1 SM2540C 08/06/201516:15 GHUTCHI 1 SM5310C/EPA9060A 08/06/201513:06 TJA7067 1 SM2540D 08/06/2015 09:15 GHUTCHI Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15080088 Site: PZ-8 Collection Date: 05-Aug-15 4:48 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.082 mg-N/L 0.01 INORGANIC IONS BY IC Chloride 41 mg/L 1 Sulfate 220 mg/L 5 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) 0.007 mg/L 0.005 Barium (Ba) 0.068 mg/L 0.005 Boron (B) 0.463 mg/L 0.05 Iron (Fe) 2.56 mg/L 0.01 Manganese (Mn) 1.57 mg/L 0.005 Strontium (Sr) 2.62 mg/L 0.005 Zinc (Zn) 0.028 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 107 mg/L 0.01 Magnesium (Mg) 25.4 mg/L 0.05 Potassium (K) 12.4 mg/L 0.1 Sodium (Na) 59.2 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.016 mg/L 0.005 Barium (Ba) 0.061 mg/L 0.005 Boron (B) 0.465 mg/L 0.05 Iron (Fe) 2.39 mg/L 0.01 Manganese (Mn) 2.17 mg/L 0.005 Strontium (Sr) 2.79 mg/L 0.005 Zinc (Zn) 0.011 mg/L 0.005 Sample #: 2015025947 Matrix: GW_WW Analytical Lab Page 14 of 64 DF Method Analysis Date/Time Analyst Vendor Method V_SHEALY 1 EPA 353.2 08/10/2015 14:02 LSTARLI 10 EPA 300.0 08/07/2015 10:09 BGN9034 50 EPA 300.0 08/07/2015 10:09 BGN9034 1 EPA 245.1 08/07/2015 13:26 ACPAYNE 1 EPA 245.1 08/06/2015 16:32 ACPAYNE 1 EPA 200.7 08/07/2015 11:09 MHALL3 1 EPA 200.7 08/07/2015 11:09 MHALL3 1 EPA 200.7 08/07/2015 11:09 MHALL3 1 EPA 200.7 08/07/2015 11:09 MHALL3 1 EPA 200.7 08/07/2015 11:09 MHALL3 1 EPA 200.7 08/07/2015 11:09 MHALL3 1 EPA 200.7 08/07/2015 11:09 MHALL3 1 EPA 200.7 08/10/2015 10:21 FCJORDA 10 EPA 200.7 08/10/2015 10:21 FCJORDA 1 EPA 200.7 08/10/2015 10:21 FCJORDA 1 EPA 200.7 08/10/2015 10:21 FCJORDA 1 EPA 200.7 08/10/2015 12:55 MHALL3 1 EPA 200.7 08/10/2015 12:55 MHALL3 1 EPA 200.7 08/10/2015 12:55 MHALL3 1 EPA 200.7 08/10/2015 12:55 MHALL3 1 EPA 200.7 08/10/2015 12:55 MHALL3 1 EPA 200.7 08/10/2015 12:55 MHALL3 1 EPA 200.7 08/10/2015 12:55 MHALL3 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15080088 Site: PZ-8 Collection Date: 05-Aug-15 4:48 PM Analyte Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) 4.22 ug/L 1 Arsenic (As) 224 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) 12.7 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) 22.1 ug/L 1 Nickel (Ni) 33.9 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level 1.02 ug/L 0.2 Vanadium (V) Low Level 9.49 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) 2.85 ug/L 1 Arsenic (As) 124 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) 17.8 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) 16.9 ug/L 1 Nickel (Ni) 43.5 ug/L 1 Selenium (Se) 1.07 ug/L 1 Thallium (TI) Low Level 1.31 ug/L 0.2 Vanadium (V) Low Level 6.43 ug/L 0.3 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4) Complete SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 620 mg/L 25 Total Carbon TOC 0.492 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS 42 mg/L 5 Sample #: 2015025947 Matrix: GW_WW Analytical Lab Page 15 of 64 DF Method Analysis Date/Time Analyst 1 EPA 200.8 08/10/2015 16:23 JAHERMA 1 EPA 200.8 08/10/2015 16:23 JAHERMA 1 EPA 200.8 08/10/2015 16:23 JAHERMA 1 EPA 200.8 08/10/2015 16:23 JAHERMA 1 EPA 200.8 08/10/2015 16:23 JAHERMA 1 EPA 200.8 08/10/2015 16:23 JAHERMA 1 EPA 200.8 08/10/2015 16:23 JAHERMA 1 EPA 200.8 08/10/2015 16:23 JAHERMA 1 EPA 200.8 08/10/2015 16:23 JAHERMA 1 EPA 200.8 08/10/2015 16:23 JAHERMA 1 EPA 200.8 08/10/2015 16:23 JAHERMA 1 EPA 200.8 08/10/2015 16:23 JAHERMA 1 EPA 200.8 08/10/2015 16:23 JAHERMA 1 EPA 200.8 08/06/2015 18:06 MHALL3 1 EPA 200.8 08/06/2015 18:06 MHALL3 1 EPA 200.8 08/06/2015 18:06 MHALL3 1 EPA 200.8 08/06/2015 18:06 MHALL3 1 EPA 200.8 08/06/2015 18:06 MHALL3 1 EPA 200.8 08/06/2015 18:06 MHALL3 1 EPA 200.8 08/06/2015 18:06 MHALL3 1 EPA 200.8 08/06/2015 18:06 MHALL3 1 EPA 200.8 08/06/2015 18:06 MHALL3 1 EPA 200.8 08/06/2015 18:06 MHALL3 1 EPA 200.8 08/06/2015 18:06 MHALL3 1 EPA 200.8 08/06/2015 18:06 MHALL3 1 EPA 200.8 08/06/2015 18:06 MHALL3 Vendor Method V_SHEALY Vendor Method V_PACE 1 SM2540C 08/06/201516:15 GHUTCHI 1 SM5310C/EPA9060A 08/06/201513:06 TJA7067 1 SM2540D 08/06/2015 09:15 GHUTCHI Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15080088 Site: Filter Blank Collection Date: 05-Aug-15 7:30 AM Analyte Result Units Qualifiers RDL Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) < 0.005 mg/L 0.005 Barium (Ba) < 0.005 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) < 0.01 mg/L 0.01 Manganese (Mn) < 0.005 mg/L 0.005 Strontium (Sr) < 0.005 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 Sample #: 2015025948 Matrix: GW_WW Analytical Lab Page 16 of 64 DF Method Analysis Date/Time Analyst 1 EPA 245.1 08/06/2015 16:34 ACPAYNE 1 EPA 200.7 08/07/2015 11:12 MHALL3 1 EPA 200.7 08/07/2015 11:12 MHALL3 1 EPA 200.7 08/07/2015 11:12 MHALL3 1 EPA 200.7 08/07/2015 11:12 MHALL3 1 EPA 200.7 08/07/2015 11:12 MHALL3 1 EPA 200.7 08/07/2015 11:12 MHALL3 1 EPA 200.7 08/07/2015 11:12 MHALL3 1 EPA 200.8 08/10/2015 16:30 JAHERMA 1 EPA 200.8 08/10/2015 16:30 JAHERMA 1 EPA 200.8 08/10/2015 16:30 JAHERMA 1 EPA 200.8 08/10/2015 16:30 JAHERMA 1 EPA 200.8 08/10/2015 16:30 JAHERMA 1 EPA 200.8 08/10/2015 16:30 JAHERMA 1 EPA 200.8 08/10/2015 16:30 JAHERMA 1 EPA 200.8 08/10/2015 16:30 JAHERMA 1 EPA 200.8 08/10/2015 16:30 JAHERMA 1 EPA 200.8 08/10/2015 16:30 JAHERMA 1 EPA 200.8 08/10/2015 16:30 JAHERMA 1 EPA 200.8 08/10/2015 16:30 JAHERMA 1 EPA 200.8 08/10/2015 16:30 JAHERMA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15080088 Site: Equipment Blank Collection Date: 05-Aug-15 7:30 AM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.011 mg-N/L 0.01 INORGANIC IONS BY IC Chloride < 0.1 mg/L 0.1 Sulfate < 0.1 mg/L 0.1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 UNDIGESTED METALS BY lCP Calcium (Ca) 0.029 mg/L 0.01 Magnesium (Mg) < 0.005 mg/L 0.005 Potassium (K) < 0.1 mg/L 0.1 Sodium (Na) < 0.05 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) < 0.005 mg/L 0.005 Barium (Ba) < 0.005 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) < 0.01 mg/L 0.01 Manganese (Mn) < 0.005 mg/L 0.005 Strontium (Sr) < 0.005 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 Sample #: 2015025949 Matrix: GW_WW Analytical Lab Page 17 of 64 DF Method Analysis Date/Time Analyst Vendor Method V_SHEALY 1 EPA 353.2 08/10/2015 14:03 LSTARLI 1 EPA 300.0 08/06/2015 14:59 BGN9034 1 EPA 300.0 08/06/2015 14:59 BGN9034 1 EPA 245.1 08/07/2015 13:40 ACPAYNE 1 EPA 200.7 08/10/2015 10:24 FCJORDA 1 EPA 200.7 08/10/2015 10:24 FCJORDA 1 EPA 200.7 08/10/2015 10:24 FCJORDA 1 EPA 200.7 08/10/2015 10:24 FCJORDA 1 EPA 200.7 08/10/2015 12:59 MHALL3 1 EPA 200.7 08/10/2015 12:59 MHALL3 1 EPA 200.7 08/10/2015 12:59 MHALL3 1 EPA 200.7 08/10/2015 12:59 MHALL3 1 EPA 200.7 08/10/2015 12:59 MHALL3 1 EPA 200.7 08/10/2015 12:59 MHALL3 1 EPA 200.7 08/10/2015 12:59 MHALL3 1 EPA 200.8 08/06/2015 18:13 MHALL3 1 EPA 200.8 08/06/2015 18:13 MHALL3 1 EPA 200.8 08/06/2015 18:13 MHALL3 1 EPA 200.8 08/06/2015 18:13 MHALL3 1 EPA 200.8 08/06/2015 18:13 MHALL3 1 EPA 200.8 08/06/2015 18:13 MHALL3 1 EPA 200.8 08/06/2015 18:13 MHALL3 1 EPA 200.8 08/06/2015 18:13 MHALL3 1 EPA 200.8 08/06/2015 18:13 MHALL3 1 EPA 200.8 08/06/2015 18:13 MHALL3 1 EPA 200.8 08/06/2015 18:13 MHALL3 1 EPA 200.8 08/06/2015 18:13 MHALL3 1 EPA 200.8 08/06/2015 18:13 MHALL3 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4) Complete Vendor Method V_SHEALY Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15080088 Site: Equipment Blank Collection Date: 05-Aug-15 7:30 AM Analyte Result Units Qualifiers RDL DF SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS < 25 mg/L 25 1 Total Carbon Sample #: 2015025949 Matrix: GW_WW Analytical Lab Page 18 of 64 Method Analysis Date/Time Analyst Vendor Method V_PACE SM2540C 08/06/201516:15 GHUTCHI TOC 1.3 mg/L 0.1 1 SM5310C/EPA9060A 08/06/201513:06 TJA7067 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 1 SM2540D 08/06/2015 09:15 GHUTCHI Qualifiers: M4 The spike recovery value was unusable since the analyte concentration in the sample was disproportionate to the spike level. The associated Laboratory Control Spike recovery was acceptable. SHEALY ENVIRONMENTAL SERVICES, INC. Report of Analysis Duke Energy 13339 Hagers Ferry Rd Bldg 7405 Huntersville, NC 28078 Attention: Mary Ann Ogle Project Name: AB GW Assessment Water - Cape Fear Project Number:J15080088 Lot Number:QH06103 Date Completed:08/11/2015 Grant Wilton Project Manager This report shall not be reproduced, except in its entirety, without the written approval of Shealy Environmental Services, Inc. The following non -paginated documents are considered part of this report: Chain of Custody Record and Sample Receipt Checklist. Shealy Environmental Services, Inc. Page: 1 of 18 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com SHEALY ENVIRONMENTAL SERVICES, INC. SC DHEC No: 32010 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative Duke Energy Lot Number: QH06103 Project Name: AB GW Assessment Water - Cape Fear Project Number: J15080088 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the Shealy Environmental Services, Inc. ("Shealy") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPS), and Shealy policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below. If you have any questions regarding this report please contact the Shealy Project Manager listed on the cover page Shealy Environmental Services, Inc. Page: 2 of 18 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com SHEALY ENVIRONMENTAL SERVICES, INC. Sample Summary Duke Energy Lot Number: QH06103 Project Name: AB GW Assessment Water - Cape Fear Project Number: J15080088 Sample Number Sample ID Matrix Date Sampled Date Received 001 2015025942 Aqueous 08/05/20151021 08/06/2015 002 2015025943 Aqueous 08/05/20151335 08/06/2015 003 2015025944 Aqueous 08/05/20151212 08/06/2015 004 2015025945 Aqueous 08/05/2015 0915 08/06/2015 005 2015025946 Aqueous 08/05/20151448 08/06/2015 006 2015025947 Aqueous 08/05/20151648 08/06/2015 007 2015025949 Aqueous 08/05/2015 0730 08/06/2015 (7 samples) Shealy Environmental Services, Inc. Page: 3 of 18 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com SHEALY ENVIRONMENTAL SERVICES, INC. Executive Summary Duke Energy Lot Number: QH06103 Project Name: AB GW Assessment Water - Cape Fear Project Number: J15080088 Sample Sample ID Matrix Parameter Method Result Q Units Page 001 2015025942 Aqueous Alkalinity SM 2320B- 130 mg/L 5 001 2015025942 Aqueous Bicarbonate Alkalinity SM 2320B- 130 mg/L 5 001 2015025942 Aqueous Methane RSK - 175 38 ug/L 6 002 2015025943 Aqueous Alkalinity SM 2320B- 170 mg/L 7 002 2015025943 Aqueous Bicarbonate Alkalinity SM 2320B- 170 mg/L 7 002 2015025943 Aqueous Methane RSK - 175 22 ug/L 8 003 2015025944 Aqueous Alkalinity SM 2320B- 310 mg/L 9 003 2015025944 Aqueous Bicarbonate Alkalinity SM 2320B- 310 mg/L 9 003 2015025944 Aqueous Methane RSK - 175 56 ug/L 10 004 2015025945 Aqueous Alkalinity SM 2320B- 28 mg/L 11 004 2015025945 Aqueous Bicarbonate Alkalinity SM 2320B- 28 mg/L 11 004 2015025945 Aqueous Methane RSK - 175 33 ug/L 12 005 2015025946 Aqueous Alkalinity SM 2320B- 150 mg/L 13 005 2015025946 Aqueous Bicarbonate Alkalinity SM 2320B- 140 mg/L 13 006 2015025947 Aqueous Alkalinity SM 2320B- 190 mg/L 15 006 2015025947 Aqueous Bicarbonate Alkalinity SM 2320B- 190 mg/L 15 (16 detections) Shealy Environmental Services, Inc. Page: 4 of 18 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Inorganic non-metals Client: Duke Energy Laboratory ID: QH06103-001 Description: 2015025942 Matrix: Aqueous Date Sampled:08/05/2015 1021 Project Name: AB GW Assessment Water - Date Received:08/06/2015 Project Number: J15080088 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 08/08/2015 1341 HMA 81865 1 (Bicarbonate ) SM 2320B-2011 1 08/08/2015 1341 HMA 1 (Carbonate Al) SM 2320B-2011 1 08/08/2015 1341 HMA CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 130 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 130 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 5 of 18 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Methane Client: Duke Energy Laboratory ID: QH06103-001 Description: 2015025942 Matrix: Aqueous Date Sampled:08/05/2015 1021 Project Name: AB GW Assessment Water - Date Received:08/06/2015 Project Number: J15080088 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 08/08/2015 0101 JJG 81986 CAS Analytical Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 38 10 ug/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 6 of 18 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Inorganic non-metals Client: Duke Energy Laboratory ID: QH06103-002 Description: 2015025943 Matrix: Aqueous Date Sampled:08/05/2015 1335 Project Name: AB GW Assessment Water - Date Received:08/06/2015 Project Number: J15080088 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 08/08/2015 1403 HMA 81865 1 (Bicarbonate ) SM 2320B-2011 1 08/08/2015 1403 HMA 1 (Carbonate Al) SM 2320B-2011 1 08/08/2015 1403 HMA CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 170 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 170 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 7 of 18 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Methane Client: Duke Energy Laboratory ID: QH06103-002 Description: 2015025943 Matrix: Aqueous Date Sampled:08/05/2015 1335 Project Name: AB GW Assessment Water - Date Received:08/06/2015 Project Number: J15080088 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 08/08/2015 0113 JJG 81986 CAS Analytical Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 22 10 ug/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 8 of 18 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Inorganic non-metals Client: Duke Energy Laboratory ID: QH06103-003 Description: 2015025944 Matrix: Aqueous Date Sampled:08/05/2015 1212 Project Name: AB GW Assessment Water - Date Received:08/06/2015 Project Number: J15080088 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 08/08/2015 1411 HMA 81865 1 (Bicarbonate ) SM 2320B-2011 1 08/08/2015 1411 HMA 1 (Carbonate Al) SM 2320B-2011 1 08/08/2015 1411 HMA CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 310 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 310 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 9 of 18 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Methane Client: Duke Energy Laboratory ID: QH06103-003 Description: 2015025944 Matrix: Aqueous Date Sampled:08/05/2015 1212 Project Name: AB GW Assessment Water - Date Received:08/06/2015 Project Number: J15080088 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 08/08/2015 0123 JJG 81986 CAS Analytical Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 56 10 ug/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 10 of 18 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Inorganic non-metals Client: Duke Energy Laboratory ID: QH06103-004 Description: 2015025945 Matrix: Aqueous Date Sampled:08/05/2015 0915 Project Name: AB GW Assessment Water - Date Received:08/06/2015 Project Number: J15080088 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 08/08/2015 1415 HMA 81865 1 (Bicarbonate ) SM 2320B-2011 1 08/08/2015 1415 HMA 1 (Carbonate Al) SM 2320B-2011 1 08/08/2015 1415 HMA CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 28 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 28 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 11 of 18 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Methane Client: Duke Energy Laboratory ID: QH06103-004 Description: 2015025945 Matrix: Aqueous Date Sampled:08/05/2015 0915 Project Name: AB GW Assessment Water - Date Received:08/06/2015 Project Number: J15080088 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 08/08/2015 0136 JJG 81986 CAS Analytical Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 33 10 ug/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 12 of 18 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Inorganic non-metals Client: Duke Energy Laboratory ID: QH06103-005 Description: 2015025946 Matrix: Aqueous Date Sampled:08/05/2015 1448 Project Name: AB GW Assessment Water - Date Received:08/06/2015 Project Number: J15080088 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 08/08/2015 1449 HMA 81865 1 (Bicarbonate ) SM 2320B-2011 1 08/08/2015 1449 HMA 1 (Carbonate Al) SM 2320B-2011 1 08/08/2015 1449 HMA CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 150 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 140 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 13 of 18 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Methane Client: Duke Energy Laboratory ID: QH06103-005 Description: 2015025946 Matrix: Aqueous Date Sampled:08/05/2015 1448 Project Name: AB GW Assessment Water - Date Received:08/06/2015 Project Number: J15080088 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 08/08/2015 0153 JJG 81986 CAS Analytical Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 10 ug/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 14 of 18 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Inorganic non-metals Client: Duke Energy Laboratory ID: QH06103-006 Description: 2015025947 Matrix: Aqueous Date Sampled:08/05/2015 1648 Project Name: AB GW Assessment Water - Date Received:08/06/2015 Project Number: J15080088 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 08/08/2015 1457 HMA 81865 1 (Bicarbonate ) SM 2320B-2011 1 08/08/2015 1457 HMA 1 (Carbonate Al) SM 2320B-2011 1 08/08/2015 1457 HMA CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 190 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 190 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 15 of 18 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Methane Client: Duke Energy Laboratory ID: QH06103-006 Description: 2015025947 Matrix: Aqueous Date Sampled:08/05/2015 1648 Project Name: AB GW Assessment Water - Date Received:08/06/2015 Project Number: J15080088 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 08/08/2015 0203 JJG 81986 CAS Analytical Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 10 ug/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 16 of 18 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Inorganic non-metals Client: Duke Energy Laboratory ID: QH06103-007 Description: 2015025949 Matrix: Aqueous Date Sampled:08/05/2015 0730 Project Name: AB GW Assessment Water - Date Received:08/06/2015 Project Number: J15080088 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 08/08/2015 1501 HMA 81865 1 (Bicarbonate ) SM 2320B-2011 1 08/08/2015 1501 HMA 1 (Carbonate Al) SM 2320B-2011 1 08/08/2015 1501 HMA CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 ND 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 17 of 18 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Methane Client: Duke Energy Laboratory ID: QH06103-007 Description: 2015025949 Matrix: Aqueous Date Sampled:08/05/2015 0730 Project Name: AB GW Assessment Water - Date Received:08/06/2015 Project Number: J15080088 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 08/08/2015 0213 JJG 81986 CAS Analytical Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 10 ug/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 18 of 18 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com QC Summary Shealy Environmental Services, Inc. QC Data for Lot Number: QH06103 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Inorganic non-metals - MB Sample ID: QQ81865-001 Matrix: Aqueous Batchg1865 Analytical Method: SM 2320B-2011 Parameter Result Q Dil PQL Units Analysis Date Alkalinity ND 1 10 mg/L 08/08/20151328 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QH06103 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Inorganic non-metals - LCS Sample ID: QQ81865-002 Matrix: Aqueous Batchg1865 Analytical Method: SM 2320B-2011 Spike Amount Result % Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Alkalinity 100 99 1 99 90-110 08/08/20151334 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QH06103 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Inorganic non-metals - MS Sample ID: QH06103-001 MS Matrix: Aqueous Batch81865 Analytical Method: SM 2320B-2011 Sample Spike Amount Amount Result % Rec Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Alkalinity 130 100 210 1 83 70-130 08/08/20151348 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QH06103 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Inorganic non-metals - MSD Sample ID: QH06103-001MD Matrix: Aqueous Batch81865 Analytical Method: SM 2320B-2011 Sample Spike Amount Amount Result % Rec % RPD Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date Alkalinity 130 100 210 1 87 2.0 70-130 20 08/08/20151355 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QH06103 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Methane - MB Sample ID: QQ81986-001 Matrix: Aqueous Batchg1986 Analytical Method: RSK - 175 Parameter Result Q Dil PQL Units Analysis Date Methane ND 1 10 ug/L 08/08/2015 0050 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QH06103 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Methane - LCS Sample ID: QQ81986-002 Matrix: Aqueous Batchg1986 Analytical Method: RSK - 175 Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Methane 50 47 1 93 70-130 08/08/2015 0018 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QH06103 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Methane - LCSD Sample ID: QQ81986-003 Matrix: Aqueous Batchg1986 Analytical Method: RSK - 175 Spike Amount Result % Rec % RPD Parameter (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date Methane 50 43 1 86 7.2 70-130 30 08/08/2015 0029 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QH06103 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com SHEALY ENVIRONMENTAL SERVICES, INC. _. E im F j I I QC I Cx' i 4 1` i j el �a dMI IrI I F9 LLJ ; �I Z. i Uq h If s i� L�Zlpkj"f l r'4Gh=Al � �PI�IAB :11 .- MMMA" -911IN'D01 IDW 110 4.,4 �qnww-A [fit .,-m2o aannm � 6E i 4 a 001 I qrqpp }}} em C5 4 PUnWnum *k omlFul marold -luR,ndw!'MUM*RU - I 3 S le ar V PIE � E LU wau W� Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com SHEALY ENVIRONMENTAL SERVICES, INC. Shandy 1-4vjronment8l Services, Inc. ppwuimuh'uober F-p.D--016 Rn-ision Nu mbu: 17 PW1&1 keplarees Dew: 1 IM114 r4mo- iwe fiats' W30115 'ample Receipt Checklist (SR C Ciiarl#- Dj&VJ fe1Cr in speed by�'datc:1 ]deans of receipt: srnSI ❑ client ❑ ups ❑ P dl;x ❑ Airlaome ap Q Other Yes No 1. Were cu seals present on the cooler"? Ye:s ❑ I No ❑ NA kj 17. If eustat SCW s went prcscnt, wcrc the " intact and u11k}re_ekelt? Cooler IDMriginatl temperature tlpotl rmciptfl7erived (corrmtcd) temperature upon receipt: fl.1 f I ! aC °C l f 6C Method. cmperamm lank El Asanst Botdcs IR Qw ICI: _ ER Gem Correction Factor: ! °C Method of coolant: IhIct ice ❑ Eluv. Ice ❑ DTry Ice- Lj Nonc Y,,� ❑ No ❑ NA [ 3. Vtemperature of any cooler excevdcd 6.0`°C, ww P"roject Manager notified? PM (notified by SRC" phone, riot+: (circle one), other: (For coolers received via commercial courieer. PhVis are go be nmtifred irnmcciiatt•I .} Yes No ❑ NA 4. Is the commercial courier's packing shp attadied to this fonn? Yes No [] 5. Were proper custody Ntlures (rel tlishe dlreeived fnlicweeil`? Yes ❑ No ❑ NA Sa Were samples reli uished by client to commmial courier? Yes No 6, Were sample IDs listed on the COC? yC5 No ❑ 7, Were zem 1G 1lDs IiNtrd on all sale k rontaineu? Yes No ❑ 8, Was collection date & time listed on the COC? Yes No ❑ 9. Was cull tiun elute & bane listed an all sample ct,-ntainars? Yes NTO ❑ 10, Laid all container label infbrtnation ID date, time) apx1ft with the Yes Nn ❑ I I _ Were tests to be perfortned listeed on the C Yea No ® 1.2_ Did all sam les arrive in the proW containers for each text'? Yes Nc [� 13. Did all cvntainm� arrive in 1good condition unbroken lids on, etc:, � o. Yea 1 14. Was adequate sample volume available? Yes No ❑ 15_ Were all samples rec,civrd within '1x the holding time or 48 hours, whichever tames first? Yes NQ I G. Were any sarnp les containers missirr .- . Yes 0 Naaj 17. Were therc_a_ny° €x ss Llxpplcs +sat lusted an COM IS. WeFea bubbles resent �` ea slza°° '/,'oF 6niId 1O diameter) Ii7 any VOA vials'? Yee No NA ❑ YES ❑ Ye;i ❑ No ❑ No ❑ NA 19. Were adz metulOO&{flHENi nutrienit samples received al a pK of <2? NA 20. Were all cyanide and/or sulfide samples recelved at a pH >12 t Yes ❑ No ❑ NA 21. Were all applicable NM/TKN,lcyanidefpkenoi (<0.2mg[L.) mmples free of residual chlor ue°'x Yes ❑ No NA 22. Were; collection tem leratwxn documeMed on the COC for NC swri les? Yea No liA [ 23. Wore -Beni remarltstregdlests (i,e. requested dilubims, [viSIMST) desipations, etc..,,) ckvreetty tram9cribed from the COC into the comment section in LTMq? Yes ❑ No 24. Was the quote number used taken from the container labei7 Sample Prdeservaden {Must be cornpleted for any samlple(s) incorrectly preserved or with headspace.) sample(s) —ware received incorrectly preserved and v`'ere adjuYsud aguwdjagly in sam .Ic receiving with SO4 HNC3 I l Nat=1H usinS SR # Sarn l s) vrwre received with bubblcs>6 rnrn in diameter. Sallnp1e(5 __ were received with TRC >0 2 m If #21 is N SC Drinking Water Project Sample(s) pH vk:riFtvd 1es be > 2 by Date: Samnldsl were slot received at a pH of<2 &td were aditrsted accrardinizly usiJtllt SR Sample labels applied Common ' Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com aceAnalyical www.pacelabs.com Pa�nl iJ tifri tervices, Inc. gVI i a a Suite 100 Huntersville, INC 28078 (704)875-9092 August 07, 2015 Program Manager Duke Energy 13339 Hagers Ferry Road Bldg.7405 MG30A2 Huntersville, NC 28078 RE: Project: J 15080088 Pace Project No.: 92262289 Dear Program Manager: Enclosed are the analytical results for sample(s) received by the laboratory on August 06, 2015. The results relate only to the samples included in this report. Results reported herein conform to the most current TN standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Herring kevin.herring@pacelabs.com HORIZON Database Administrator Enclosures cc: Program Manager, Duke Energy Rodney Wilke, Duke Energy p«FO l9eORO, 00// REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 1 of 17 aceAnalyical www.pacelabs.com Pa�nl iJ tifri tervices, Inc. gVI i a a Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15080088 Pace Project No.: 92262289 Asheville Certification IDs 2225 Riverside Drive, Asheville, INC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 CERTIFICATIONS North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 West Virginia Certification #: 356 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 2 of 17 aceAnalyical www.pacelabs.com Pa�nl iJ tifri tervices, Inc. gVI i a a Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: J15080088 Pace Project No.: 92262289 Lab ID Sample ID Matrix Date Collected Date Received 92262289001 2015025942 Water 08/05/1510:21 08/06/15 17:40 92262289002 2015025943 Water 08/05/1513:35 08/06/15 17:40 92262289003 2015025944 Water 08/05/1512:12 08/06/15 17:40 92262289004 2015025945 Water 08/05/15 09:15 08/06/15 17:40 92262289005 2015025946 Water 08/05/1514:48 08/06/15 17:40 92262289006 2015025947 Water 08/05/1516:48 08/06/15 17:40 92262289007 2015025949 Water 08/05/15 07:30 08/06/15 17:40 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 3 of 17 aceAnalyical www.pacelabs.com Pa e 1 ti I ervices, Inc. Ana ,1i�tifr 098 `8699y&e. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: J15080088 92262289 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92262289001 2015025942 SM 4500-S2D MJP 1 PASI-A 92262289002 2015025943 SM 4500-S2D MJP 1 PASI-A 92262289003 2015025944 SM 4500-S2D MJP 1 PASI-A 92262289004 2015025945 SM 4500-S2D MJP 1 PASI-A 92262289005 2015025946 SM 4500-S2D MJP 1 PASI-A 92262289006 2015025947 SM 4500-S2D MJP 1 PASI-A 92262289007 2015025949 SM 4500-S2D MJP 1 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 4 of 17 aceAnalyical www.pacelabs.com Pa e 1 ti I ervices, Inc. Ana ,1i�tifr 098 18ni99Y&e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15080088 Pace Project No.: 92262289 Method: SM 4500-S213 Description: 4500S2D Sulfide Water Client: Duke Energy Date: August 07, 2015 General Information: 7 samples were analyzed for SM 4500-S2D. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: This data package has been reviewed for quality and completeness and is approved for release. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 5 of 17 aceAnalyical www.pacelabs.com Pa e 1 ti I ervices, Inc. Ana ,1i�tifr 098 18299Y&e. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15080088 Pace Project No.: 92262289 Sample: 2015025942 Lab ID: 92262289001 Collected: 08/05/15 10:21 Received: 08/06/15 17:40 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 4500S2D Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 08/07/1511:00 18496-25-8 Date: 08/07/2015 01:35 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 6 of 17 aceAnalyical www.pacelabs.com Pa e 1 ti I ervices, Inc. Ana ,1i�tifr 098 18999Y&e. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15080088 Pace Project No.: 92262289 Sample: 2015025943 Lab ID: 92262289002 Collected: 08/05/15 13:35 Received: 08/06/15 17:40 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 4500S2D Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 08/07/1511:00 18496-25-8 Date: 08/07/2015 01:35 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 7 of 17 aceAnalyical www.pacelabs.com Pa e 1 ti I ervices, Inc. Ana ,1i�tifr 098 18499Y&e. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15080088 Pace Project No.: 92262289 Sample: 2015025944 Lab ID: 92262289003 Collected: 08/05/15 12:12 Received: 08/06/15 17:40 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 4500S2D Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 08/07/1511:00 18496-25-8 Date: 08/07/2015 01:35 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 8 of 17 aceAnalyical www.pacelabs.com Pa e 1 ti I ervices, Inc. Ana ,1i�tifrl 09Q�I�i�c&fir&e. Suite 100 y Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15080088 Pace Project No.: 92262289 Sample: 2015025945 Lab ID: 92262289004 Collected: 08/05/15 09:15 Received: 08/06/15 17:40 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 4500S2D Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 08/07/1511:00 18496-25-8 Date: 08/07/2015 01:35 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 9 of 17 aceAnalyical www.pacelabs.com Pa e 1 ti I ervices, Inc. Ana ,1i�tifr 098 18699Y&e. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15080088 Pace Project No.: 92262289 Sample: 2015025946 Lab ID: 92262289005 Collected: 08/05/15 14:48 Received: 08/06/15 17:40 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 4500S2D Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 08/07/1511:00 18496-25-8 Date: 08/07/2015 01:35 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 10 of 17 aceAnalyical www.pacelabs.com Pa e 1 ti I ervices, Inc. Ana ,1i�alfra 098 1899y&e. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15080088 Pace Project No.: 92262289 Sample: 2015025947 Lab ID: 92262289006 Collected: 08/05/15 16:48 Received: 08/06/15 17:40 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 4500S2D Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 08/07/1511:00 18496-25-8 Date: 08/07/2015 01:35 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 11 of 17 aceAnalyical www.pacelabs.com Pa e 1 ti I ervices, Inc. Ana ,1i�tifr 098 18899Y&e. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15080088 Pace Project No.: 92262289 Sample: 2015025949 Lab ID: 92262289007 Collected: 08/05/15 07:30 Received: 08/06/15 17:40 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 4500S2D Sulfide Water Analytical Method: SM 4500-S21D Sulfide ND mg/L 0.10 1 08/07/1511:00 18496-25-8 Date: 08/07/2015 01:35 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 12 of 17 aceAnaiXical www.pacelabs.com Paca alytical ervices, Inc. Hna ilcal La 098 18999y1 ft Suite 100 y Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15080088 Pace Project No.: 92262289 QC Batch: WET/39351 Analysis Method: SM 4500-S2D QC Batch Method: SM 4500-S2D Analysis Description: 4500S2D Sulfide Water Associated Lab Samples: 92262289001,92262289002,92262289003,92262289004,92262289005,92262289006,92262289007 METHOD BLANK: 1528431 Matrix: Water Associated Lab Samples: 92262289001, 92262289002, 92262289003, 92262289004, 92262289005, 92262289006, 92262289007 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Sulfide mg/L ND 0.10 08/07/1511:00 LABORATORY CONTROL SAMPLE: 1528432 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfide mg/L .5 0.45 90 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1528433 1528434 MS MSD 92262283001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfide mg/L ND .5 .5 0.50 0.50 100 100 90-110 0 10 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1528435 1528436 MS MSD 92262215012 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfide mg/L ND .5 .5 0.52 0.52 103 103 90-110 0 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/07/2015 01:35 PM without the written consent of Pace Analytical Services, Inc.. Page 13 of 17 aceAnalyical www.pacelabs.com Pa e 1 ti I ervices, Inc. Ana ,Ii�alora 098 W&fir&e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: J15080088 Pace Project No.: 92262289 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TN -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/07/2015 01:35 PM without the written consent of Pace Analytical Services, Inc.. Page 14 of 17 aceAnalyical www.pacelabs.com Pa e 1 ti I ervices, Inc. Ana ,1i�tifr 098 �nlc&fir&e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: J15080088 Pace Project No.: 92262289 Lab ID Sample ID QC Batch Method QC Batch 92262289001 2015025942 SM 4500-S2D WET/39351 92262289002 2015025943 SM 4500-S2D WET/39351 92262289003 2015025944 SM 4500-S2D WET/39351 92262289004 2015025945 SM 4500-S2D WET/39351 92262289005 2015025946 SM 4500-S2D WET/39351 92262289006 2015025947 SM 4500-S2D WET/39351 92262289007 2015025949 SM 4500-S2D WET/39351 Date: 08/07/2015 01:35 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Analytical Method Analytical Batch Page 15 of 17 �, �tc�.4rralytics?I d I Document Name: Condition Upon Recei Document Number: F-CHR-CS-003-rev.16 Document Revised: May 18, 2016 Page 1 of 2*naiytical Lab Issuing Auth&ftyy 62 of 64 Pace Huntersville Quality Office Client Name: n C---1 YU, Courier: ❑ Fed Ex ❑ UPS[:] USPS❑ Client[] C mr-hercial❑ ac Other Custody Seal on Cooler/Box Present: ❑ yes no Se Is intact: ❑ yes Packing Material: ❑ Bubble V❑ ❑ Bubble Bags . None Lj Other Thermometer Used: IR G r�14 Type of ice:6W� Blue None Temp Correction Factor T1401 No Correction * Page 2 of 2 is for Internal Use Only ❑ no ❑ Sa" mples on ice, cooling process has begun Corrected Cooler Temp.:°C Temp should be above freezing to 6°C Biological Tissue is Frozen: Yes N NIA Comments: Date and Initialf person examinin s contents: Chain of Custody Present: ❑ o• ❑NIA 1. Chain of Custody Filled Out: es ❑No NIA 2, Chain of Custody Relinquished: Y a" ❑NIA 3. Sampler Name & Signature on COC: es ❑ ❑NIA 4, Samples Arrived within Hold Time: es ❑No ENX 6, Short Hold Time Analysis ({72hr): ❑Yes - o ❑ 6. Rush Turn Around Time Requested: ❑Yes NIA 7, Sufficient Volume: es pi No ❑NIA $. Correct Containers Used: -Pace Containers Used: es ❑Yes ONO n ❑NIA ❑NIA 9. Containers Intact: Yes ONO ❑NIA 10. Filtered volume received for Dissolved tests Dyes o�0 A 11. Sample Labels match COG: -Includes date/time/ID/Analysis Matrix: ElYes U/ L ON ❑NIA 12. All containers needing preservation have been checked. All containers needing preservation are found to be in compliance with EPA recommendation. exceptions: VOA, colirorm, TOG, O&G, 4NI-DRO (water) ❑Yes ❑Yes ❑Yes ONO ONO l IA I 13. Samples checked for dechlorination: Dyes ONO ❑ Headspace in VOA Vials(>6mm): ❑Yes ONO NIA $, Trip Blank Present: Trip Blank Custody Seals Present Pace Trip Blank Lot # (if purchased): Dyes ❑Yes ONO ❑No ❑NI eNIA 16. Client Notification/ Resolution: Field Data Required? Y 1 N Person Contacted: Comments/ Resolution: SCURF Review: SRF Review: Date: 'W Date: I I Daterrime: Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office ( Le out of hold, incorrect preservative, out of temp, incorrect containers) WO#:92262288 yimiiuuNnu1iii Page 16 of 17 Analytical Lab Page 63 of 64 n 4 GL � � m \ � r } 0 Q t r z� Z� l d r to O p 1 N � N C rDCL O �� 1 Cr 7 N 7 mar, imp runt: please indicate ?� dosir d turnaround G N � r G n r -i Cb a H ! .a i MME W Mudl Complete n a i I d t7 C C ! d (D ro m cr i� 0 i k i i Ca Ca 339 O i j I y OI d I i n 1 r( � T $3 I Uzi :Si i i` M t.1i a �1 11 aCi o Lam` ll1 a i-7 upie 3 G) 6 �! 0- 1 u W N c 6 tv N 041i r (n i o O rb 00 U m I A SOL01 11 0/� I al 6 j 1 •�.- O I X 11> .Q � -n 0I Wit+ n i f# iC i� C I 1 8 i g 0 Im I' n 1 m 3 -" d p , d I 7 Et 2x a ;D >•Z Comp. eD m ds _ 4. ly . X crab 0 b z. O f TSS,TDS c F O !LA aa 55 [' 4� Methane (RSK N m a i ¢ ! In CZ! f" 175) V_Sheaty N A 1 ;U 9• d� Q 0!t�t i�� C1, SO4, m o — ti o i 'n C TOC, Nitrate- j 13 d !m ! Cn Nitrite o Sa im Alkalinity, j I I 10 Bicarbonate, Carbonal V She"al ! I Ja 0 i n n Sulfide POCe a Ir _7y z @ ! C: ! ! y n Ot6lemonLij `i' o I i N I i 1 i 1 d_0 0 tciG O Iv t n 5 7Jls ` Metals {see below x o m mI Dissolved ,4 o N U 0l° o zl metals N _ m 0 r a a ev V) Total p Containers p E CA ' E Sri, ! Page97 of 117 CHAIN OF CUSTODY RECORD AND ANA�.YSIS R'EQU:E_ST_F0.RM............... ---, r..____.....----- _------- - - t�uka En@rgy ATIAWNCAl LAb*ft�ory i -- �'aq,r 1 nl i. Syf4te r2 VDU pukeE€l �gjp' -1-- f.9s i ii7 Maul Gy4f_iM1Nf ,.wu ,y,rd ''— — - _ _-QU $ I vsw rwx�'F r �•y i - - bRMP6 . PROGRAM -� � C1F2tCaINAI. to LAB COPY iq CLL Chem dP (^atit 3' n rtnti.11M N c 2we L�d4'p umvie1 'Pyjjoajat5i47A i i '''�' &0"V4plrr_ DES:_ ---- ' A _._._.. - L ---- --- -- '- - e Nr fS�GYY Rbs4 me nt wavrf ;Pt .No + �ItCRA W"td T 1 1J �i2AM`J _.. C�I'r►uPg� - -- ._....,.�.._.. --- �pflsl ruNti` (Lou - - Client ago-5rs-5032 rS7p�yy 4 �J�y 1 r {] Fillr0on {0.45 um� 4nain$rel amra� F -. Pis,: iGoilY To: Pa114Ly;`89 Preaarr81j" lea I# Ma �� le4OtWimeas ksm.�. �„ ••• w crec Cgnlalns€ Volwn(t (mL) 341NJ � ml AD i N all$ 5013 300 250 i MG03AI _ — :" r ": pne Canllrinar Type 4'Et glass PLT PET - PEt PET , _ , MfSf'IF HOPE PC 1142081 Sa r"010 D' OSCIl'iption or IV CJ stamar 1v eumPrate an apWv Prt&M? 4h � - - ._.. ,_,. Cell■colon lnlnrmat4en — in c!5 4} I w q! o i f GP5 LocaUdin f d. oah T4ma SI natu _ 4 1 it w - 19 JR44I49udl id BY Filter Blank _Eui ent Blank a 2 1 1 1 1 1 1 1 To TcTAL u brts,'tlnm Arrceptad By, me red - DA4 lane 'a ELEMENTS by ICPMS {TRM)! All, Ba, Cd, Cn, Gr, C.u, Mr7, Nl. Ph. Slr %i!. T L i Y {LLl E _ ELEMENTS byICP (3iiMp: Al,Ba, I, Fe, MM, Sr, in ICP_Uj)dagisled rvs Mg, K, NA Hg by 245 Relinquished by Dillksglvwd ni"S : all metals ICP, IMS,klg fr r - o0 Requested Turnaround total Due Y� VA `i4uays-` q fj z tea. Hr n t I 8�i1� I �) Received by Q Date Time