NC0003433_J15070007report_20150902

DUE Analytical Laboratory
ENERGY
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone:[phone] Fax:[phone]
Order Summary Report
Order Number: J15070007
Project Name: CAPE FEAR - AB GW ASSESSMENT WATER
Customer Name(s): Tim Hunsucker, Chris Suttell, Kathy Webb, John Toepfer
Customer Address:
Lab Contact: Mary Ann Ogle Phone: [phone]
mary.ogle@duke-
Report Authorized By: �i i w energy Date:
�I I > 2015.07.13 .13 11:56:59-04'00'
(Signature)
Mary Ann Ogle
Program Comments:
Please contact the Program Manager (Mary Ann Ogle) with any questions regarding this report.
Data Flags & Calculations:
7/13/2015
Analytical Lab
Page 1 of 74
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Sample ID's & Descriptions:
Collection
Sample ID Plant/Station Date and Time
Collected By
Sample Description
2015021635
Cape Fear
30-Jun-15 2:08 PM
Illegible
MW-9
2015021636
Cape Fear
29-Jun-15 4:50 PM
Illegible
MW-13
2015021637
Cape Fear
30-Jun-15 10:13 AM
Illegible
MW-14
2015021638
Cape Fear
30-Jun-15 1:08 PM
Illegible
MW-16S
2015021639
Cape Fear
30-Jun-15 11:05 AM
Illegible
MW-15SL
2015021640
Cape Fear
30-Jun-15 9:30 AM
Illegible
MW-15BR
2015021641
Cape Fear
30-Jun-15 12:01 PM
Illegible
MW-6BR
2015021642
Cape Fear
30-Jun-15 3:22 PM
Illegible
MW-12
2015021643
Cape Fear
30-Jun-15
Illegible
Filter Blank
2015021644
Cape Fear
30-Jun-15
Illegible
Equipment Blank
2015021645
Cape Fear
29-Jun-15 3:55 PM
Illegible
Filter Blank
2015021646
Cape Fear
29-Jun-15 3:55 PM
Illegible
Equipment Blank
12 Total Samples
Analytical Lab
Page 2 of 74

Analytical Lab
Page 3 of 74
Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals 0 Yes ❑ No
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits. ❑ Yes 0 No
All laboratory QA/QC requirements are acceptable. 0 Yes ❑ No
Report Sections Included:
E%-'] Job Summary Report
❑� Sample Identification
Technical Validation of Data Package
❑� Analytical Laboratory Certificate of Analysis
❑ Analytical Laboratory QC Report
❑d Sub -contracted Laboratory Results
❑ Customer Specific Data Sheets, Reports, & Documentation
❑ Customer Database Entries
❑� Chain of Custody
❑� Electronic Data Deliverable (EDD) Sent Separately
Reviewed By: Mary Ann Ogle Date: 7/13/2015

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15070007
Site: MW-9
Collection Date: 30-Jun-15 2:08 PM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter
Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)
< 0.01
mg-N/L
0.01
INORGANIC IONS BY IC
Chloride
240
mg/L
5
Sulfate
41
mg/L
1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
0.006
mg/L
0.005
Barium (Ba)
0.080
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
1.13
mg/L
0.01
Manganese (Mn)
0.792
mg/L
0.005
Strontium (Sr)
0.506
mg/L
0.005
Zinc (Zn)
0.010
mg/L
0.005
UNDIGESTED METALS BY lCP
Calcium (Ca)
68.9
mg/L
0.01
Magnesium (Mg)
30.3
mg/L
0.005
Potassium (K)
0.962
mg/L
0.1
Sodium (Na)
61.4
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.016
mg/L
0.005
Barium (Ba)
0.076
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
1.80
mg/L
0.01
Manganese (Mn)
0.826
mg/L
0.005
Strontium (Sr)
0.538
mg/L
0.005
Zinc (Zn)
0.010
mg/L
0.005
Sample #: 2015021635
Matrix: GW WW
Analytical Lab
Page 4 of 74
DF Method Analysis Date/Time Analyst
Vendor Method V_SHEALY
1
EPA 353.2
07/01/2015 14:47
LSTARLI
50
EPA 300.0
07/01/2015 13:47
BGN9034
10
EPA 300.0
07/01/2015 13:47
BGN9034
1
EPA 245.1
07/01/2015 13:29
ACPAYNE
1
EPA 245.1
07/02/2015 12:07
ACPAYNE
1
EPA 200.7
07/06/2015 09:16
FCJORDA
1
EPA 200.7
07/06/2015 09:16
FCJORDA
1
EPA 200.7
07/06/2015 09:16
FCJORDA
1
EPA 200.7
07/06/2015 09:16
FCJORDA
1
EPA 200.7
07/06/2015 09:16
FCJORDA
1
EPA 200.7
07/06/2015 09:16
FCJORDA
1
EPA 200.7
07/06/2015 09:16
FCJORDA
1
EPA 200.7
07/06/2015 11:24
FCJORDA
1
EPA 200.7
07/06/2015 11:24
FCJORDA
1
EPA 200.7
07/06/2015 11:24
FCJORDA
1
EPA 200.7
07/06/2015 11:24
FCJORDA
1
EPA 200.7
07/02/2015 11:05
MHH7131
1
EPA 200.7
07/02/2015 11:05
MHH7131
1
EPA 200.7
07/02/2015 11:05
MHH7131
1
EPA 200.7
07/02/2015 11:05
MHH7131
1
EPA 200.7
07/02/2015 11:05
MHH7131
1
EPA 200.7
07/02/2015 11:05
MHH7131
1
EPA 200.7
07/02/2015 11:05
MHH7131

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15070007
Site: MW-9
Collection Date: 30-Jun-15 2:08 PM
Analyte Result Units Qualifiers RDL
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
4.56
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
2.21
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
6.70
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
1.80
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
660
mg/L
25
Total Carbon
TOC
1.3
mg/L
0.1
TOTAL SUSPENDED SOLIDS
TSS
< 5
mg/L
5
Sample #: 2015021635
Matrix: GW WW
Analytical Lab
Page 5 of 74
DF
Method
Analysis Date/Time
Analyst
1
EPA 200.8
07/06/2015 11:27
JAHERMA
1
EPA 200.8
07/06/2015 11:27
JAHERMA
1
EPA 200.8
07/06/2015 11:27
JAHERMA
1
EPA 200.8
07/06/2015 11:27
JAHERMA
1
EPA 200.8
07/06/2015 11:27
JAHERMA
1
EPA 200.8
07/06/2015 11:27
JAHERMA
1
EPA 200.8
07/06/2015 11:27
JAHERMA
1
EPA 200.8
07/06/2015 11:27
JAHERMA
1
EPA 200.8
07/06/2015 11:27
JAHERMA
1
EPA 200.8
07/06/2015 11:27
JAHERMA
1
EPA 200.8
07/06/2015 11:27
JAHERMA
1
EPA 200.8
07/06/2015 11:27
JAHERMA
1
EPA 200.8
07/06/2015 11:27
JAHERMA
1
EPA 200.8
07/01/2015 18:11
JAHERMA
1
EPA 200.8
07/01/2015 18:11
JAHERMA
1
EPA 200.8
07/01/2015 18:11
JAHERMA
1
EPA 200.8
07/01/2015 18:11
JAHERMA
1
EPA 200.8
07/01/2015 18:11
JAHERMA
1
EPA 200.8
07/01/2015 18:11
JAHERMA
1
EPA 200.8
07/01/2015 18:11
JAHERMA
1
EPA 200.8
07/01/2015 18:11
JAHERMA
1
EPA 200.8
07/01/2015 18:11
JAHERMA
1
EPA 200.8
07/01/2015 18:11
JAHERMA
1
EPA 200.8
07/01/2015 18:11
JAHERMA
1
EPA 200.8
07/01/2015 18:11
JAHERMA
1
EPA 200.8
07/01/2015 18:11
JAHERMA
Vendor Method V_SHEALY
Vendor Method V_ELE1
1 SM2540C 07/01/201514:05 AGIBBS5
1 SM5310C/EPA9060A 07/06/201513:39 TJA7067
1 SM2540D 07/02/2015 08:40 AGIBBS5

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15070007
Site: MW-13
Collection Date: 29-Jun-15 4:50 PM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter
Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)
0.094
mg-N/L
0.01
INORGANIC IONS BY IC
Chloride
28
mg/L
1
Sulfate
91
mg/L
1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
0.014
mg/L
0.005
Barium (Ba)
0.084
mg/L
0.005
Boron (B)
0.223
mg/L
0.05
Iron (Fe)
0.127
mg/L
0.01
Manganese (Mn)
0.641
mg/L
0.005
Strontium (Sr)
0.180
mg/L
0.005
Zinc (Zn)
0.204
mg/L
0.005
UNDIGESTED METALS BY lCP
Calcium (Ca)
24.1
mg/L
0.01
Magnesium (Mg)
15.1
mg/L
0.005
Potassium (K)
0.145
mg/L
0.1
Sodium (Na)
33.4
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.206
mg/L
0.005
Barium (Ba)
0.102
mg/L
0.005
Boron (B)
0.319
mg/L
0.05
Iron (Fe)
0.248
mg/L
0.01
Manganese (Mn)
0.820
mg/L
0.005
Strontium (Sr)
0.223
mg/L
0.005
Zinc (Zn)
0.011
mg/L
0.005
Sample #: 2015021636
Matrix: GW WW
Analytical Lab
Page 6 of 74
DF Method Analysis Date/Time Analyst
Vendor Method V_SHEALY
1
EPA 353.2
07/01/2015 14:50
LSTARLI
10
EPA 300.0
07/01/2015 14:37
BGN9034
10
EPA 300.0
07/01/2015 14:37
BGN9034
1
EPA 245.1
07/01/2015 13:31
ACPAYNE
1
EPA 245.1
07/02/2015 12:09
ACPAYNE
1
EPA 200.7
07/06/2015 09:27
FCJORDA
1
EPA 200.7
07/06/2015 09:27
FCJORDA
1
EPA 200.7
07/06/2015 09:27
FCJORDA
1
EPA 200.7
07/06/2015 09:27
FCJORDA
1
EPA 200.7
07/06/2015 09:27
FCJORDA
1
EPA 200.7
07/06/2015 09:27
FCJORDA
1
EPA 200.7
07/06/2015 09:27
FCJORDA
1
EPA 200.7
07/06/2015 11:35
FCJORDA
1
EPA 200.7
07/06/2015 11:35
FCJORDA
1
EPA 200.7
07/06/2015 11:35
FCJORDA
1
EPA 200.7
07/06/2015 11:35
FCJORDA
1
EPA 200.7
07/02/2015 11:16
MHH7131
1
EPA 200.7
07/02/2015 11:16
MHH7131
1
EPA 200.7
07/02/2015 11:16
MHH7131
1
EPA 200.7
07/02/2015 11:16
MHH7131
1
EPA 200.7
07/02/2015 11:16
MHH7131
1
EPA 200.7
07/02/2015 11:16
MHH7131
1
EPA 200.7
07/02/2015 11:16
MHH7131

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15070007
Site: MW-13
Collection Date: 29-Jun-15 4:50 PM
Analyte Result Units Qualifiers RDL
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
1.20
ug/L
1
Copper (Cu)
1.81
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
3.41
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
0.587
ug/L
0.3
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
1.46
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
3.31
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
0.297
ug/L
0.2
Vanadium (V) Low Level
1.07
ug/L
0.3
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
270
mg/L
25
Total Carbon
TOC
0.910
mg/L
0.1
TOTAL SUSPENDED SOLIDS
TSS
< 5
mg/L
5
Sample #: 2015021636
Matrix: GW WW
Analytical Lab
Page 7 of 74
DF
Method
Analysis Date/Time
Analyst
1
EPA 200.8
07/06/2015 11:34
JAHERMA
1
EPA 200.8
07/06/2015 11:34
JAHERMA
1
EPA 200.8
07/06/2015 11:34
JAHERMA
1
EPA 200.8
07/06/2015 11:34
JAHERMA
1
EPA 200.8
07/06/2015 11:34
JAHERMA
1
EPA 200.8
07/06/2015 11:34
JAHERMA
1
EPA 200.8
07/06/2015 11:34
JAHERMA
1
EPA 200.8
07/06/2015 11:34
JAHERMA
1
EPA 200.8
07/06/2015 11:34
JAHERMA
1
EPA 200.8
07/06/2015 11:34
JAHERMA
1
EPA 200.8
07/06/2015 11:34
JAHERMA
1
EPA 200.8
07/06/2015 11:34
JAHERMA
1
EPA 200.8
07/06/2015 11:34
JAHERMA
1
EPA 200.8
07/01/2015 18:32
JAHERMA
1
EPA 200.8
07/01/2015 18:32
JAHERMA
1
EPA 200.8
07/01/2015 18:32
JAHERMA
1
EPA 200.8
07/01/2015 18:32
JAHERMA
1
EPA 200.8
07/01/2015 18:32
JAHERMA
1
EPA 200.8
07/01/2015 18:32
JAHERMA
1
EPA 200.8
07/01/2015 18:32
JAHERMA
1
EPA 200.8
07/01/2015 18:32
JAHERMA
1
EPA 200.8
07/01/2015 18:32
JAHERMA
1
EPA 200.8
07/01/2015 18:32
JAHERMA
1
EPA 200.8
07/01/2015 18:32
JAHERMA
1
EPA 200.8
07/01/2015 18:32
JAHERMA
1
EPA 200.8
07/01/2015 18:32
JAHERMA
Vendor Method V_SHEALY
Vendor Method V_ELE1
1 SM2540C 07/01/201514:05 AGIBBS5
1 SM5310C/EPA9060A 07/06/201513:39 TJA7067
1 SM2540D 07/02/2015 08:40 AGIBBS5

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15070007
Site: MW-14
Collection Date: 30-Jun-15 10:13 AM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter
Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)
< 0.01
mg-N/L
0.01
INORGANIC IONS BY IC
Chloride
40
mg/L
1
Sulfate
30
mg/L
1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
0.104
mg/L
0.005
Barium (Ba)
0.055
mg/L
0.005
Boron (B)
0.125
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
< 0.005
mg/L
0.005
Strontium (Sr)
0.260
mg/L
0.005
Zinc (Zn)
0.009
mg/L
0.005
UNDIGESTED METALS BY lCP
Calcium (Ca)
10.3
mg/L
0.01
Magnesium (Mg)
1.48
mg/L
0.005
Potassium (K)
2.92
mg/L
0.1
Sodium (Na)
81.9
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.614
mg/L
0.005
Barium (Ba)
0.064
mg/L
0.005
Boron (B)
0.132
mg/L
0.05
Iron (Fe)
0.419
mg/L
0.01
Manganese (Mn)
0.024
mg/L
0.005
Strontium (Sr)
0.278
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Sample #: 2015021637
Matrix: GW WW
Analytical Lab
Page 8 of 74
DF Method Analysis Date/Time Analyst
Vendor Method V_SHEALY
1
EPA 353.2
07/01/2015 14:51
LSTARLI
10
EPA 300.0
07/01/2015 14:53
BGN9034
10
EPA 300.0
07/01/2015 14:53
BGN9034
1
EPA 245.1
07/01/2015 13:34
ACPAYNE
1
EPA 245.1
07/02/2015 12:11
ACPAYNE
1
EPA 200.7
07/06/2015 09:31
FCJORDA
1
EPA 200.7
07/06/2015 09:31
FCJORDA
1
EPA 200.7
07/06/2015 09:31
FCJORDA
1
EPA 200.7
07/06/2015 09:31
FCJORDA
1
EPA 200.7
07/06/2015 09:31
FCJORDA
1
EPA 200.7
07/06/2015 09:31
FCJORDA
1
EPA 200.7
07/06/2015 09:31
FCJORDA
1
EPA 200.7
07/06/2015 11:39
FCJORDA
1
EPA 200.7
07/06/2015 11:39
FCJORDA
1
EPA 200.7
07/06/2015 11:39
FCJORDA
1
EPA 200.7
07/06/2015 11:39
FCJORDA
1
EPA 200.7
07/02/2015 11:20
MHH7131
1
EPA 200.7
07/02/2015 11:20
MHH7131
1
EPA 200.7
07/02/2015 11:20
MHH7131
1
EPA 200.7
07/02/2015 11:20
MHH7131
1
EPA 200.7
07/02/2015 11:20
MHH7131
1
EPA 200.7
07/02/2015 11:20
MHH7131
1
EPA 200.7
07/02/2015 11:20
MHH7131

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15070007
Site: MW-14
Collection Date: 30-Jun-15 10:13 AM
Analyte
Result
Units Qualifiers
RDL
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
1.55
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
70.9
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
1.06
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
72.0
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
1.37
ug/L
0.3
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
260
mg/L
25
Total Carbon
TOC
0.795
mg/L
0.1
TOTAL SUSPENDED SOLIDS
TSS
16
mg/L
5
Sample #: 2015021637
Matrix: GW WW
Analytical Lab
Page 9 of 74
DF
Method
Analysis Date/Time
Analyst
1
EPA 200.8
07/06/2015 11:06
JAHERMA
1
EPA 200.8
07/06/2015 11:06
JAHERMA
1
EPA 200.8
07/06/2015 11:06
JAHERMA
1
EPA 200.8
07/06/2015 11:06
JAHERMA
1
EPA 200.8
07/06/2015 11:06
JAHERMA
1
EPA 200.8
07/06/2015 11:06
JAHERMA
1
EPA 200.8
07/06/2015 11:06
JAHERMA
1
EPA 200.8
07/06/2015 11:06
JAHERMA
1
EPA 200.8
07/06/2015 11:06
JAHERMA
1
EPA 200.8
07/06/2015 11:06
JAHERMA
1
EPA 200.8
07/06/2015 11:06
JAHERMA
1
EPA 200.8
07/06/2015 11:06
JAHERMA
1
EPA 200.8
07/06/2015 11:06
JAHERMA
1
EPA 200.8
07/01/2015 18:39
JAHERMA
1
EPA 200.8
07/01/2015 18:39
JAHERMA
1
EPA 200.8
07/01/2015 18:39
JAHERMA
1
EPA 200.8
07/01/2015 18:39
JAHERMA
1
EPA 200.8
07/01/2015 18:39
JAHERMA
1
EPA 200.8
07/01/2015 18:39
JAHERMA
1
EPA 200.8
07/01/2015 18:39
JAHERMA
1
EPA 200.8
07/01/2015 18:39
JAHERMA
1
EPA 200.8
07/01/2015 18:39
JAHERMA
1
EPA 200.8
07/01/2015 18:39
JAHERMA
1
EPA 200.8
07/01/2015 18:39
JAHERMA
1
EPA 200.8
07/01/2015 18:39
JAHERMA
1
EPA 200.8
07/01/2015 18:39
JAHERMA
Vendor Method V_SHEALY
Vendor Method V_ELE1
1 SM2540C 07/01/201514:05 AGIBBS5
1 SM5310C/EPA9060A 07/06/201513:39 TJA7067
1 SM2540D 07/02/2015 08:40 AGIBBS5

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15070007
Site: MW-16S
Collection Date: 30-Jun-15 1:08 PM
Analyte Result Units Qualifiers RDL DF
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete
Sample #: 2015021638
Matrix: GW WW
Analytical Lab
Page 10 of 74
Method Analysis Date/Time Analyst
Vendor Method
v GEL

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15070007
Site: MW-15SL
Collection Date: 30-Jun-15 11:05 AM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter
Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)
0.026
mg-N/L
0.01
INORGANIC IONS BY IC
Chloride
7.6
mg/L
0.1
Sulfate
52
mg/L
1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
0.071
mg/L
0.005
Barium (Ba)
0.067
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
37.3
mg/L
0.01
Manganese (Mn)
3.80
mg/L
0.005
Strontium (Sr)
0.113
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
7.21
mg/L
0.01
Magnesium (Mg)
2.88
mg/L
0.005
Potassium (K)
1.42
mg/L
0.1
Sodium (Na)
15.5
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.161
mg/L
0.005
Barium (Ba)
0.069
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
38.4
mg/L
0.01
Manganese (Mn)
3.86
mg/L
0.005
Strontium (Sr)
0.114
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Sample #: 2015021639
Matrix: GW WW
Analytical Lab
Page 11 of 74
DF Method Analysis Date/Time Analyst
Vendor Method V_SHEALY
1
EPA 353.2
07/01/2015 14:53
LSTARLI
1
EPA 300.0
07/01/2015 17:37
BGN9034
10
EPA 300.0
07/01/2015 17:37
BGN9034
1
EPA 245.1
07/01/2015 13:36
ACPAYNE
1
EPA 245.1
07/02/2015 12:14
ACPAYNE
1
EPA 200.7
07/06/2015 09:35
FCJORDA
1
EPA 200.7
07/06/2015 09:35
FCJORDA
1
EPA 200.7
07/06/2015 09:35
FCJORDA
1
EPA 200.7
07/06/2015 09:35
FCJORDA
1
EPA 200.7
07/06/2015 09:35
FCJORDA
1
EPA 200.7
07/06/2015 09:35
FCJORDA
1
EPA 200.7
07/06/2015 09:35
FCJORDA
1
EPA 200.7
07/06/2015 11:43
FCJORDA
1
EPA 200.7
07/06/2015 11:43
FCJORDA
1
EPA 200.7
07/06/2015 11:43
FCJORDA
1
EPA 200.7
07/06/2015 11:43
FCJORDA
1
EPA 200.7
07/02/2015 11:24
MHH7131
1
EPA 200.7
07/02/2015 11:24
MHH7131
1
EPA 200.7
07/02/2015 11:24
MHH7131
1
EPA 200.7
07/02/2015 11:24
MHH7131
1
EPA 200.7
07/02/2015 11:24
MHH7131
1
EPA 200.7
07/02/2015 11:24
MHH7131
1
EPA 200.7
07/02/2015 11:24
MHH7131

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15070007
Site: MW-15SL
Collection Date: 30-Jun-15 11:05 AM
Analyte Result Units Qualifiers RDL
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
1.77
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
12.0
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
1.91
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
12.3
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
0.383
ug/L
0.3
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
190
mg/L
25
Total Carbon
TOC
1.2
mg/L
0.1
TOTAL SUSPENDED SOLIDS
TSS
30
mg/L
5
Sample #: 2015021639
Matrix: GW WW
Analytical Lab
Page 12 of 74
DF
Method
Analysis Date/Time
Analyst
1
EPA 200.8
07/06/2015 11:41
JAHERMA
1
EPA 200.8
07/06/2015 11:41
JAHERMA
1
EPA 200.8
07/06/2015 11:41
JAHERMA
1
EPA 200.8
07/06/2015 11:41
JAHERMA
1
EPA 200.8
07/06/2015 11:41
JAHERMA
1
EPA 200.8
07/06/2015 11:41
JAHERMA
1
EPA 200.8
07/06/2015 11:41
JAHERMA
1
EPA 200.8
07/06/2015 11:41
JAHERMA
1
EPA 200.8
07/06/2015 11:41
JAHERMA
1
EPA 200.8
07/06/2015 11:41
JAHERMA
1
EPA 200.8
07/06/2015 11:41
JAHERMA
1
EPA 200.8
07/06/2015 11:41
JAHERMA
1
EPA 200.8
07/06/2015 11:41
JAHERMA
1
EPA 200.8
07/01/2015 18:46
JAHERMA
1
EPA 200.8
07/01/2015 18:46
JAHERMA
1
EPA 200.8
07/01/2015 18:46
JAHERMA
1
EPA 200.8
07/01/2015 18:46
JAHERMA
1
EPA 200.8
07/01/2015 18:46
JAHERMA
1
EPA 200.8
07/01/2015 18:46
JAHERMA
1
EPA 200.8
07/01/2015 18:46
JAHERMA
1
EPA 200.8
07/01/2015 18:46
JAHERMA
1
EPA 200.8
07/01/2015 18:46
JAHERMA
1
EPA 200.8
07/01/2015 18:46
JAHERMA
1
EPA 200.8
07/01/2015 18:46
JAHERMA
1
EPA 200.8
07/01/2015 18:46
JAHERMA
1
EPA 200.8
07/01/2015 18:46
JAHERMA
Vendor Method V_SHEALY
Vendor Method V_ELE1
1 SM2540C 07/01/201514:05 AGIBBS5
1 SM5310C/EPA9060A 07/06/201513:39 TJA7067
1 SM2540D 07/02/2015 08:40 AGIBBS5

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15070007
Site: MW-15BR
Collection Date: 30-Jun-15 9:30 AM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter
Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)
2.7
mg-N/L
0.02
INORGANIC IONS BY IC
Chloride
13
mg/L
1
Sulfate
37
mg/L
1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
0.015
mg/L
0.005
Barium (Ba)
0.369
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.015
mg/L
0.01
Manganese (Mn)
0.065
mg/L
0.005
Strontium (Sr)
0.469
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
31.9
mg/L
0.01
Magnesium (Mg)
8.24
mg/L
0.005
Potassium (K)
1.69
mg/L
0.1
Sodium (Na)
42.9
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.030
mg/L
0.005
Barium (Ba)
0.398
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.031
mg/L
0.01
Manganese (Mn)
0.069
mg/L
0.005
Strontium (Sr)
0.493
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Sample #: 2015021640
Matrix: GW WW
Analytical Lab
Page 13 of 74
DF Method Analysis Date/Time Analyst
Vendor Method V_SHEALY
2
EPA 353.2
07/01/2015 15:02
LSTARLI
10
EPA 300.0
07/01/2015 15:26
BGN9034
10
EPA 300.0
07/01/2015 15:26
BGN9034
1
EPA 245.1
07/01/2015 13:50
ACPAYNE
1
EPA 245.1
07/02/2015 12:00
ACPAYNE
1
EPA 200.7
07/06/2015 09:38
FCJORDA
1
EPA 200.7
07/06/2015 09:38
FCJORDA
1
EPA 200.7
07/06/2015 09:38
FCJORDA
1
EPA 200.7
07/06/2015 09:38
FCJORDA
1
EPA 200.7
07/06/2015 09:38
FCJORDA
1
EPA 200.7
07/06/2015 09:38
FCJORDA
1
EPA 200.7
07/06/2015 09:38
FCJORDA
1
EPA 200.7
07/06/2015 11:46
FCJORDA
1
EPA 200.7
07/06/2015 11:46
FCJORDA
1
EPA 200.7
07/06/2015 11:46
FCJORDA
1
EPA 200.7
07/06/2015 11:46
FCJORDA
1
EPA 200.7
07/02/2015 11:27
MHH7131
1
EPA 200.7
07/02/2015 11:27
MHH7131
1
EPA 200.7
07/02/2015 11:27
MHH7131
1
EPA 200.7
07/02/2015 11:27
MHH7131
1
EPA 200.7
07/02/2015 11:27
MHH7131
1
EPA 200.7
07/02/2015 11:27
MHH7131
1
EPA 200.7
07/02/2015 11:27
MHH7131

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15070007
Site: MW-15BR
Collection Date: 30-Jun-15 9:30 AM
Analyte
Result
Units Qualifiers
RDL
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
6.60
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
11.8
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
1.95
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
2.00
ug/L
0.3
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
6.07
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
11.5
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
1.98
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
1.82
ug/L
0.3
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
260
mg/L
25
Total Carbon
TOC
0.371
mg/L
0.1
TOTAL SUSPENDED SOLIDS
TSS
< 5
mg/L
5
Sample #: 2015021640
Matrix: GW WW
Analytical Lab
Page 14 of 74
DF
Method
Analysis Date/Time
Analyst
1
EPA 200.8
07/06/2015 11:48
JAHERMA
1
EPA 200.8
07/06/2015 11:48
JAHERMA
1
EPA 200.8
07/06/2015 11:48
JAHERMA
1
EPA 200.8
07/06/2015 11:48
JAHERMA
1
EPA 200.8
07/06/2015 11:48
JAHERMA
1
EPA 200.8
07/06/2015 11:48
JAHERMA
1
EPA 200.8
07/06/2015 11:48
JAHERMA
1
EPA 200.8
07/06/2015 11:48
JAHERMA
1
EPA 200.8
07/06/2015 11:48
JAHERMA
1
EPA 200.8
07/06/2015 11:48
JAHERMA
1
EPA 200.8
07/06/2015 11:48
JAHERMA
1
EPA 200.8
07/06/2015 11:48
JAHERMA
1
EPA 200.8
07/06/2015 11:48
JAHERMA
1
EPA 200.8
07/01/2015 18:53
JAHERMA
1
EPA 200.8
07/01/2015 18:53
JAHERMA
1
EPA 200.8
07/01/2015 18:53
JAHERMA
1
EPA 200.8
07/01/2015 18:53
JAHERMA
1
EPA 200.8
07/01/2015 18:53
JAHERMA
1
EPA 200.8
07/01/2015 18:53
JAHERMA
1
EPA 200.8
07/01/2015 18:53
JAHERMA
1
EPA 200.8
07/01/2015 18:53
JAHERMA
1
EPA 200.8
07/01/2015 18:53
JAHERMA
1
EPA 200.8
07/01/2015 18:53
JAHERMA
1
EPA 200.8
07/01/2015 18:53
JAHERMA
1
EPA 200.8
07/01/2015 18:53
JAHERMA
1
EPA 200.8
07/01/2015 18:53
JAHERMA
Vendor Method V_SHEALY
Vendor Method V_ELE1
1 SM2540C 07/01/201514:05 AGIBBS5
1 SM5310C/EPA9060A 07/06/201513:39 TJA7067
1 SM2540D 07/02/2015 08:40 AGIBBS5

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15070007
Site: MW-6BR
Collection Date: 30-Jun-15 12:01 PM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter
Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)
0.018
mg-N/L
0.01
INORGANIC IONS BY IC
Chloride
250
mg/L
2.5
Sulfate
42
mg/L
1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
0.006
mg/L
0.005
Barium (Ba)
0.826
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.157
mg/L
0.01
Manganese (Mn)
0.748
mg/L
0.005
Strontium (Sr)
0.951
mg/L
0.005
Zinc (Zn)
0.013
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
97.6
mg/L
0.01
Magnesium (Mg)
29.2
mg/L
0.005
Potassium (K)
3.89
mg/L
0.1
Sodium (Na)
89.6
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.010
mg/L
0.005
Barium (Ba)
0.842
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.178
mg/L
0.01
Manganese (Mn)
0.743
mg/L
0.005
Strontium (Sr)
0.946
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Sample #: 2015021641
Matrix: GW WW
Analytical Lab
Page 15 of 74
DF Method Analysis Date/Time Analyst
Vendor Method V_SHEALY
1
EPA 353.2
07/01/2015 14:55
LSTARLI
25
EPA 300.0
07/02/2015 11:14
BGN9034
10
EPA 300.0
07/02/2015 11:14
BGN9034
1
EPA 245.1
07/01/2015 13:53
ACPAYNE
1
EPA 245.1
07/02/2015 12:16
ACPAYNE
1
EPA 200.7
07/06/2015 09:42
FCJORDA
1
EPA 200.7
07/06/2015 09:42
FCJORDA
1
EPA 200.7
07/06/2015 09:42
FCJORDA
1
EPA 200.7
07/06/2015 09:42
FCJORDA
1
EPA 200.7
07/06/2015 09:42
FCJORDA
1
EPA 200.7
07/06/2015 09:42
FCJORDA
1
EPA 200.7
07/06/2015 09:42
FCJORDA
1
EPA 200.7
07/06/2015 11:50
FCJORDA
1
EPA 200.7
07/06/2015 11:50
FCJORDA
1
EPA 200.7
07/06/2015 11:50
FCJORDA
1
EPA 200.7
07/06/2015 11:50
FCJORDA
1
EPA 200.7
07/02/2015 11:31
MHH7131
1
EPA 200.7
07/02/2015 11:31
MHH7131
1
EPA 200.7
07/02/2015 11:31
MHH7131
1
EPA 200.7
07/02/2015 11:31
MHH7131
1
EPA 200.7
07/02/2015 11:31
MHH7131
1
EPA 200.7
07/02/2015 11:31
MHH7131
1
EPA 200.7
07/02/2015 11:31
MHH7131

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15070007
Site: MW-6BR
Collection Date: 30-Jun-15 12:01 PM
Analyte Result Units Qualifiers RDL
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
3.47
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
0.530
ug/L
0.3
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
3.17
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
0.659
ug/L
0.3
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
770
mg/L
25
Total Carbon
TOC
0.683
mg/L
0.1
TOTAL SUSPENDED SOLIDS
TSS
< 5
mg/L
5
Sample #: 2015021641
Matrix: GW WW
Analytical Lab
Page 16 of 74
DF
Method
Analysis Date/Time
Analyst
1
EPA 200.8
07/06/2015 11:55
JAHERMA
1
EPA 200.8
07/06/2015 11:55
JAHERMA
1
EPA 200.8
07/06/2015 11:55
JAHERMA
1
EPA 200.8
07/06/2015 11:55
JAHERMA
1
EPA 200.8
07/06/2015 11:55
JAHERMA
1
EPA 200.8
07/06/2015 11:55
JAHERMA
1
EPA 200.8
07/06/2015 11:55
JAHERMA
1
EPA 200.8
07/06/2015 11:55
JAHERMA
1
EPA 200.8
07/06/2015 11:55
JAHERMA
1
EPA 200.8
07/06/2015 11:55
JAHERMA
1
EPA 200.8
07/06/2015 11:55
JAHERMA
1
EPA 200.8
07/06/2015 11:55
JAHERMA
1
EPA 200.8
07/06/2015 11:55
JAHERMA
1
EPA 200.8
07/01/2015 19:00
JAHERMA
1
EPA 200.8
07/01/2015 19:00
JAHERMA
1
EPA 200.8
07/01/2015 19:00
JAHERMA
1
EPA 200.8
07/01/2015 19:00
JAHERMA
1
EPA 200.8
07/01/2015 19:00
JAHERMA
1
EPA 200.8
07/01/2015 19:00
JAHERMA
1
EPA 200.8
07/01/2015 19:00
JAHERMA
1
EPA 200.8
07/01/2015 19:00
JAHERMA
1
EPA 200.8
07/01/2015 19:00
JAHERMA
1
EPA 200.8
07/01/2015 19:00
JAHERMA
1
EPA 200.8
07/01/2015 19:00
JAHERMA
1
EPA 200.8
07/01/2015 19:00
JAHERMA
1
EPA 200.8
07/01/2015 19:00
JAHERMA
Vendor Method V_SHEALY
Vendor Method V_ELE1
1 SM2540C 07/01/201514:05 AGIBBS5
1 SM5310C/EPA9060A 07/06/201513:39 TJA7067
1 SM2540D 07/02/2015 08:40 AGIBBS5

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15070007
Site: MW-12
Collection Date: 30-Jun-15 3:22 PM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter
Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)
0.090
mg-N/L
0.01
INORGANIC IONS BY IC
Chloride
59
mg/L
1
Sulfate
260
mg/L
5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
0.054
mg/L
0.005
Boron (B)
0.465
mg/L
0.05
Iron (Fe)
0.414
mg/L
0.01
Manganese (Mn)
0.842
mg/L
0.005
Strontium (Sr)
0.258
mg/L
0.005
Zinc (Zn)
0.008
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
35.3
mg/L
0.01
Magnesium (Mg)
26.5
mg/L
0.005
Potassium (K)
0.136
mg/L
0.1
Sodium (Na)
165
mg/L
0.5
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
0.055
mg/L
0.005
Boron (B)
0.448
mg/L
0.05
Iron (Fe)
0.456
mg/L
0.01
Manganese (Mn)
0.843
mg/L
0.005
Strontium (Sr)
0.257
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Sample #: 2015021642
Matrix: GW WW
Analytical Lab
Page 17 of 74
DF Method Analysis Date/Time Analyst
Vendor Method V_SHEALY
1
EPA 353.2
07/01/2015 15:00
LSTARLI
10
EPA 300.0
07/07/2015 18:35
BGN9034
50
EPA 300.0
07/07/2015 18:35
BGN9034
1
EPA 245.1
07/01/2015 13:43
ACPAYNE
1
EPA 245.1
07/02/2015 12:19
ACPAYNE
1
EPA 200.7
07/06/2015 09:46
FCJORDA
1
EPA 200.7
07/06/2015 09:46
FCJORDA
1
EPA 200.7
07/06/2015 09:46
FCJORDA
1
EPA 200.7
07/06/2015 09:46
FCJORDA
1
EPA 200.7
07/06/2015 09:46
FCJORDA
1
EPA 200.7
07/06/2015 09:46
FCJORDA
1
EPA 200.7
07/06/2015 09:46
FCJORDA
1
EPA 200.7
07/06/2015 11:54
FCJORDA
1
EPA 200.7
07/06/2015 11:54
FCJORDA
1
EPA 200.7
07/06/2015 11:54
FCJORDA
10
EPA 200.7
07/06/2015 11:54
FCJORDA
1
EPA 200.7
07/02/2015 11:35
MHH7131
1
EPA 200.7
07/02/2015 11:35
MHH7131
1
EPA 200.7
07/02/2015 11:35
MHH7131
1
EPA 200.7
07/02/2015 11:35
MHH7131
1
EPA 200.7
07/02/2015 11:35
MHH7131
1
EPA 200.7
07/02/2015 11:35
MHH7131
1
EPA 200.7
07/02/2015 11:35
MHH7131

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15070007
Site: MW-12
Collection Date: 30-Jun-15 3:22 PM
Analyte
Result
Units Qualifiers
RDL
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
2.64
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
1.42
ug/L
1
Nickel (Ni)
1.28
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
2.43
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
1.57
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
740
mg/L
25
Total Carbon
TOC
1.2
mg/L
0.1
TOTAL SUSPENDED SOLIDS
TSS
< 5
mg/L
5
Sample #: 2015021642
Matrix: GW WW
Analytical Lab
Page 18 of 74
DF
Method
Analysis Date/Time
Analyst
1
EPA 200.8
07/06/2015 12:02
JAHERMA
1
EPA 200.8
07/06/2015 12:02
JAHERMA
1
EPA 200.8
07/06/2015 12:02
JAHERMA
1
EPA 200.8
07/06/2015 12:02
JAHERMA
1
EPA 200.8
07/06/2015 12:02
JAHERMA
1
EPA 200.8
07/06/2015 12:02
JAHERMA
1
EPA 200.8
07/06/2015 12:02
JAHERMA
1
EPA 200.8
07/06/2015 12:02
JAHERMA
1
EPA 200.8
07/06/2015 12:02
JAHERMA
1
EPA 200.8
07/06/2015 12:02
JAHERMA
1
EPA 200.8
07/06/2015 12:02
JAHERMA
1
EPA 200.8
07/06/2015 12:02
JAHERMA
1
EPA 200.8
07/06/2015 12:02
JAHERMA
1
EPA 200.8
07/01/2015 19:07
JAHERMA
1
EPA 200.8
07/01/2015 19:07
JAHERMA
1
EPA 200.8
07/01/2015 19:07
JAHERMA
1
EPA 200.8
07/01/2015 19:07
JAHERMA
1
EPA 200.8
07/01/2015 19:07
JAHERMA
1
EPA 200.8
07/01/2015 19:07
JAHERMA
1
EPA 200.8
07/01/2015 19:07
JAHERMA
1
EPA 200.8
07/01/2015 19:07
JAHERMA
1
EPA 200.8
07/01/2015 19:07
JAHERMA
1
EPA 200.8
07/01/2015 19:07
JAHERMA
1
EPA 200.8
07/01/2015 19:07
JAHERMA
1
EPA 200.8
07/01/2015 19:07
JAHERMA
1
EPA 200.8
07/01/2015 19:07
JAHERMA
Vendor Method V_SHEALY
Vendor Method V_ELE1
1 SM2540C 07/01/201514:05 AGIBBS5
1 SM5310C/EPA9060A 07/06/201513:39 TJA7067
1 SM2540D 07/02/2015 08:40 AGIBBS5

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15070007
Site: Filter Blank
Collection Date: 30-Jun-15
Analyte
Result
Units
Qualifiers RDL
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
< 0.005
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
< 0.005
mg/L
0.005
Strontium (Sr)
< 0.005
mg/L
0.005
Zinc (Zn)
0.033
mg/L
0.005
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
1.47
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
Sample #: 2015021643
Matrix: GW WW
Analytical Lab
Page 19 of 74
DF
Method
Analysis Date/Time
Analyst
1
EPA 245.1
07/02/2015 12:21
ACPAYNE
1
EPA 200.7
07/06/2015 09:50
FCJORDA
1
EPA 200.7
07/06/2015 09:50
FCJORDA
1
EPA 200.7
07/06/2015 09:50
FCJORDA
1
EPA 200.7
07/06/2015 09:50
FCJORDA
1
EPA 200.7
07/06/2015 09:50
FCJORDA
1
EPA 200.7
07/06/2015 09:50
FCJORDA
1
EPA 200.7
07/06/2015 09:50
FCJORDA
1
EPA 200.8
07/06/2015 12:09
JAHERMA
1
EPA 200.8
07/06/2015 12:09
JAHERMA
1
EPA 200.8
07/06/2015 12:09
JAHERMA
1
EPA 200.8
07/06/2015 12:09
JAHERMA
1
EPA 200.8
07/06/2015 12:09
JAHERMA
1
EPA 200.8
07/06/2015 12:09
JAHERMA
1
EPA 200.8
07/06/2015 12:09
JAHERMA
1
EPA 200.8
07/06/2015 12:09
JAHERMA
1
EPA 200.8
07/06/2015 12:09
JAHERMA
1
EPA 200.8
07/06/2015 12:09
JAHERMA
1
EPA 200.8
07/06/2015 12:09
JAHERMA
1
EPA 200.8
07/06/2015 12:09
JAHERMA
1
EPA 200.8
07/06/2015 12:09
JAHERMA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15070007
Site: Equipment Blank
Collection Date: 30-Jun-15
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy
Labs)
Vendor Parameter
Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)
0.059
mg-N/L
0.01
INORGANIC IONS BY IC
Chloride
< 0.1
mg/L
0.1
Sulfate
< 0.1
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
UNDIGESTED METALS BY lCP
Calcium (Ca)
0.026
mg/L
0.01
Magnesium (Mg)
< 0.005
mg/L
0.005
Potassium (K)
< 0.1
mg/L
0.1
Sodium (Na)
< 0.05
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
< 0.005
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
< 0.005
mg/L
0.005
Strontium (Sr)
< 0.005
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
0.310
ug/L
0.3
Sample #: 2015021644
Matrix: GW WW
Analytical Lab
Page 20 of 74
DF Method Analysis Date/Time Analyst
Vendor Method V_SHEALY
1 EPA 353.2
07/01/2015 14:56
LSTARLI
1 EPA 300.0
07/01/2015 16:15
BGN9034
1 EPA 300.0
07/01/2015 16:15
BGN9034
1 EPA 245.1
07/02/2015 13:03
ACPAYNE
1 EPA 200.7
07/06/2015 12:02
FCJORDA
1 EPA 200.7
07/06/2015 12:02
FCJORDA
1 EPA 200.7
07/06/2015 12:02
FCJORDA
1 EPA 200.7
07/06/2015 12:02
FCJORDA
1 EPA 200.7
07/02/2015 11:39
MHH7131
1 EPA 200.7
07/02/2015 11:39
MHH7131
1 EPA 200.7
07/02/2015 11:39
MHH7131
1 EPA 200.7
07/02/2015 11:39
MHH7131
1 EPA 200.7
07/02/2015 11:39
MHH7131
1 EPA 200.7
07/02/2015 11:39
MHH7131
1 EPA 200.7
07/02/2015 11:39
MHH7131
1 EPA 200.8
07/01/2015 19:14
JAHERMA
1 EPA 200.8
07/01/2015 19:14
JAHERMA
1 EPA 200.8
07/01/2015 19:14
JAHERMA
1 EPA 200.8
07/01/2015 19:14
JAHERMA
1 EPA 200.8
07/01/2015 19:14
JAHERMA
1 EPA 200.8
07/01/2015 19:14
JAHERMA
1 EPA 200.8
07/01/2015 19:14
JAHERMA
1 EPA 200.8
07/01/2015 19:14
JAHERMA
1 EPA 200.8
07/01/2015 19:14
JAHERMA
1 EPA 200.8
07/01/2015 19:14
JAHERMA
1 EPA 200.8
07/01/2015 19:14
JAHERMA
1 EPA 200.8
07/01/2015 19:14
JAHERMA
1 EPA 200.8
07/01/2015 19:14
JAHERMA
METHANE - (Analysis Performed by Shealy Labs
Methane (CH4) Complete
Vendor Method V_SHEALY

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15070007
Site: Equipment Blank
Collection Date: 30-Jun-15
Analyte Result Units Qualifiers RDL DF
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete
TOTAL DISSOLVED SOLIDS
TDS < 25 mg/L 25 1
Total Carbon
Sample #: 2015021644
Matrix: GW WW
Analytical Lab
Page 21 of 74
Method Analysis Date/Time Analyst
Vendor Method
V_ELE1
SM2540C 07/01/201514:05 AGIBBS5
TOC 1.0 mg/L 0.1 1 SM5310C/EPA9060A 07/06/201513:39 TJA7067
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L 5 1 SM2540D 07/02/2015 08:40 AGIBBS5

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15070007
Site: Filter Blank
Collection Date: 29-Jun-15 3:55 PM
Analyte
Result
Units
Qualifiers RDL
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
< 0.005
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
< 0.005
mg/L
0.005
Strontium (Sr)
< 0.005
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
Sample #: 2015021645
Matrix: GW WW
Analytical Lab
Page 22 of 74
DF
Method
Analysis Date/Time
Analyst
1
EPA 245.1
07/02/2015 12:23
ACPAYNE
1
EPA 200.7
07/06/2015 09:54
FCJORDA
1
EPA 200.7
07/06/2015 09:54
FCJORDA
1
EPA 200.7
07/06/2015 09:54
FCJORDA
1
EPA 200.7
07/06/2015 09:54
FCJORDA
1
EPA 200.7
07/06/2015 09:54
FCJORDA
1
EPA 200.7
07/06/2015 09:54
FCJORDA
1
EPA 200.7
07/06/2015 09:54
FCJORDA
1
EPA 200.8
07/06/2015 12:16
JAHERMA
1
EPA 200.8
07/06/2015 12:16
JAHERMA
1
EPA 200.8
07/06/2015 12:16
JAHERMA
1
EPA 200.8
07/06/2015 12:16
JAHERMA
1
EPA 200.8
07/06/2015 12:16
JAHERMA
1
EPA 200.8
07/06/2015 12:16
JAHERMA
1
EPA 200.8
07/06/2015 12:16
JAHERMA
1
EPA 200.8
07/06/2015 12:16
JAHERMA
1
EPA 200.8
07/06/2015 12:16
JAHERMA
1
EPA 200.8
07/06/2015 12:16
JAHERMA
1
EPA 200.8
07/06/2015 12:16
JAHERMA
1
EPA 200.8
07/06/2015 12:16
JAHERMA
1
EPA 200.8
07/06/2015 12:16
JAHERMA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15070007
Site: Equipment Blank
Collection Date: 29-Jun-15 3:55 PM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy
Labs)
Vendor Parameter
Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)
< 0.01
mg-N/L
0.01
INORGANIC IONS BY IC
Chloride
< 0.1
mg/L
0.1
Sulfate
< 0.1
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
UNDIGESTED METALS BY lCP
Calcium (Ca)
0.015
mg/L
0.01
Magnesium (Mg)
< 0.005
mg/L
0.005
Potassium (K)
< 0.1
mg/L
0.1
Sodium (Na)
< 0.05
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
< 0.005
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
< 0.005
mg/L
0.005
Strontium (Sr)
< 0.005
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
Sample #: 2015021646
Matrix: GW WW
Analytical Lab
Page 23 of 74
DF Method Analysis Date/Time Analyst
Vendor Method V_SHEALY
1 EPA 353.2
07/01/2015 15:01
LSTARLI
1 EPA 300.0
07/01/2015 16:31
BGN9034
1 EPA 300.0
07/01/2015 16:31
BGN9034
1 EPA 245.1
07/01/2015 13:55
ACPAYNE
1 EPA 200.7
07/06/2015 12:06
FCJORDA
1 EPA 200.7
07/06/2015 12:06
FCJORDA
1 EPA 200.7
07/06/2015 12:06
FCJORDA
1 EPA 200.7
07/06/2015 12:06
FCJORDA
1 EPA 200.7
07/02/2015 11:43
MHH7131
1 EPA 200.7
07/02/2015 11:43
MHH7131
1 EPA 200.7
07/02/2015 11:43
MHH7131
1 EPA 200.7
07/02/2015 11:43
MHH7131
1 EPA 200.7
07/02/2015 11:43
MHH7131
1 EPA 200.7
07/02/2015 11:43
MHH7131
1 EPA 200.7
07/02/2015 11:43
MHH7131
1 EPA 200.8
07/01/2015 19:21
JAHERMA
1 EPA 200.8
07/01/2015 19:21
JAHERMA
1 EPA 200.8
07/01/2015 19:21
JAHERMA
1 EPA 200.8
07/01/2015 19:21
JAHERMA
1 EPA 200.8
07/01/2015 19:21
JAHERMA
1 EPA 200.8
07/01/2015 19:21
JAHERMA
1 EPA 200.8
07/01/2015 19:21
JAHERMA
1 EPA 200.8
07/01/2015 19:21
JAHERMA
1 EPA 200.8
07/01/2015 19:21
JAHERMA
1 EPA 200.8
07/01/2015 19:21
JAHERMA
1 EPA 200.8
07/01/2015 19:21
JAHERMA
1 EPA 200.8
07/01/2015 19:21
JAHERMA
1 EPA 200.8
07/01/2015 19:21
JAHERMA
METHANE - (Analysis Performed by Shealy Labs
Methane (CH4) Complete
Vendor Method V_SHEALY

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15070007
Site: Equipment Blank
Collection Date: 29-Jun-15 3:55 PM
Analyte Result Units Qualifiers RDL DF
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete
TOTAL DISSOLVED SOLIDS
TDS < 25 mg/L 25 1
Total Carbon
Sample #: 2015021646
Matrix: GW WW
Analytical Lab
Page 24 of 74
Method Analysis Date/Time Analyst
Vendor Method
V_ELE1
SM2540C 07/01/201514:05 AGIBBS5
TOC 0.190 mg/L 0.1 1 SM5310C/EPA9060A 07/06/201513:39 TJA7067
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L 5 1 SM2540D 07/02/2015 08:40 AGIBBS5

min
Analytical Lab
Page 25 of 74
Element One 9nc.
6319-D Carolina [Beach Rai.
Wilmington, NC 28412
Phone: [phone]
Fax: [phone]
1l b 1l Ib
e a @e a AM
e�8,n-, m (B�,n One
REPORT OF ANALYSES
Duke Energy
July 8, 2015
Laboratory Services
Client Project Name AB GW Assessment
water (wells) Cape Fear
13339 Hagers Ferry Road Bld.
MG03A Client Project Number J15070007
Huntersville, NC 28078
PO Number
Sample Matrix GW WW
Sample Type Grab
Date Received
07/01/2015
Date Analyzed 07/03/2015
Method SM 4500 S2- D
Time Received
1615
Delivered by FedEx
Received by
LLB
eOne ID Duke Energy ID
Parameter Result Unit
Dil
DL Date
Time
Sampled
Sampled
25227-1 MW-9
Sulfide < 0.1 mg/L
1
0.1 06/30/15
1408
25227-2` MW-13
Sulfide < 0.2 mg/L
2
0.1 06/29/15
1650
25227-3 MW-14
Sulfide 0.282 mg/L
1
0.1 06/30/15
1013
25227-4 MW-15SL
Sulfide < 0.1 mg/L
1
0.1 06/30/15
1105
25227-5 MW-15BR
Sulfide < 0.1 mg/L
1
0.1 06/30/15
0930
25227-6 MW-6BR
Sulfide < 0.1 mg/L
1
0.1 06/30/15
1201
25227-7* MW-12
Sulfide < 0.2 mg/L
2
0.1 06/30/15
1522
25227-8 Equipment Blank
Sulfide < 0.1 mg/L
1
0.1 06/30/15
----
'Sample spike recovery outside of QA limits of 85-115%; dilution necessary to meet laboratory QA limits.
Ken Smith, Laboratory Director
25227 Duke Report Packet Compiled byl�—
NC Certifications: DW 37788 and DWQ DENR 604

Analytical Lab
Page 26 of 74
IEVement One Inc,
6319-D Carolina Beach Rd.
Wilmington, VAC 284112
Phone: [phone]
Fax: [phone]
[e-mail]
REPORT OF ANALYSES
Duke Energy
July 8, 2015
Laboratory Services
Client Project Name AB GW Assessment water (wells) Cape Fear
13339 Hagers Ferry Road Bld.
MG03A Client Project Number J15070007
Huntersville, NC 28078
PO Number
Sample Matrix GW WW
Sample Type Grab
Date Received
07/01/2015
Date Analyzed 07/03/2015
Method SM 4500 S2_ D
Time Received
1615
Delivered by FedEx
Received by
LLB
eOne ID Duke Energy ID
Parameter Result Unit Dil
DL Date
Time
Sampled
Sampled
25227-9 Equipment Blank Sulfide < 0.1 mg/L 1 0.1 06/29/15 1555
Y!� C�
Ken Smith, La oratory Director
25227 Duke Report Packet Compiled by
NC Certifications: DW 37788 and DWQ DENR 604

Analytical Lab
Page 27 of 74
Q
Q
w
m
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to
W
J
U
1 0
iF o
Im U
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0
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e JJ 9 o,,yJ �'7 J
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ag

eernentOne SAMPLE SUBMISSION FORM
TAT 7 BD
Hold Time Expiration 07.06.15 @ 1665
Client: Duke Energy
LIMS No J15070007
Project ID Cape Fear
Analytical
Lab
Lab 1[3age 29!W
Analysis Due Date 07.03.15
Report Due Date 07.08.15
Date Rec:
07.01.15
Time Rec:
1615
Rec By
LLB
H >9 No
Tem <_ 6°C � No
Ref. Method:
SM4500 S2 D
If No, Record
If No, Record
04111JAW IUCHUIRAALIV11 oc VVIICGLIVII II11WIIIMIUfI
Lab ID
Client ID
Collection Date
Collection Time
Analysis Requested
1
MW-9
06.30.15
1408
Sufi
2
MW-13
06.29.15
1650
u id
3
MW-14
06.30.15
1013
Sul id
4
MW-15SL
06.30.15
1105
Sulfid
5
M_W-15BR
06.30.15
0_930_
u . e
__-- 6
MW-66R �._..__._..__06.30.15�
- _ � ---
1201 __ ---
-Sul i.
��. 7
MW-12
06.30.1.5
8
Equipment Blank
06.30.15
0800
Sulfid
9
Equipment Blank
06.29.15
1555
Sulfi
NOTE for Sulfide I The MS/MSD spike should approximate 2 to 3 times the sample concentration. If no sulfide detected
at 100 pg/L spike the sample to render the final spike concentration at - 500 pg/L
Lab Communications
All AB Groundwater Assessment lobs need a RL of 0.1
SS Page 1 Prep By / Date �J '
SS by Labeled By / Date
7/2/2015 8:54:44 AM ID Verification By /Date K4... 77- 2 -IS'

Analytical Lab
Page 29 of 74
METHOD:
SM 4500 S2- D
ELEMENT ONE
ELEMENT ASSAY:
Sulfide
Spectrophotometer
Wave Length 664
UNITS OF ANSWER
DETECTION LIMIT u
CLIENT:
Duke
SPK LEVELLugj
Lab ID#
25227 / 228 / 229
Na2S•9H2O Lot #
40721
MAX ALIQUOT
Date:
07/03/15
STANDARD conc(ppm)
Time Analysis Begun
08:20
ICal Std Lot: SD-11
Time Analysis Ended
12:10
10C Std Lot: SD-11
Analyst:
KAM
STD ABSORPTION
X
Y
ug STD
STD
SOLUTION
ABS
0.00
0.000
1.00
0.093
2.50
0.223
5.00
0.431
7.50
0619'
10.00
0.832
X
10
10
Y
��355
+505
+, 55
+�1D05
2.00 900 6.OD 8.00 10.OD 12.00
X
SAMPLE SAMP
I.D. ABS
ug PER
ALIQUOT
Tm
Sloe 0.08232967
Correlation 0.999696878
ALI in mL
TAKEN
RESULTS
u /mL
LESS THAN
%O SPK REC
SPIKE
LEVEL
Std. B. 0.00
0.000
0.0000
10
<
0.0Std.
B. 1.00
0.093
0.9348
10
<
93%
1.0
Std. B. 2.50
0.227
2.6009
10
0.260
104%
2.5
Std. B. 5.00
0.430
5.1249
10
10
10
0.512
102%
5.0
Std. B. 7.50
0.618
7.4625
10
10
10
0.746
990/0
7.5
Std. B. 10.00
0.795
9.6633
10
10
10
0.966
97%
10.0
LRB
0.003
-0.1843
10
10
10
<
0.0
LRB SPK
0.416
4.9509
10
10
10
0.495
99%
5.0
QC
0.423
5.0379
10
10
10
0,504
101%
5.0
25227-1
0.003
-0.1843
10
10
10
i 0
25227-1 s k
0.377
4.4660
10
10
10
0.447
89%
5.0
25227-2
0.005
-0.1594
10
10
10
<
25227-2 dup
0.006
-0.1470
10
10
10
<
25227-2 s k
0.348
4.1054
10
10
10
0.411
82%
5.0
25227-3
0.245
2.8247
10
10
10
25227-3 spk
0.633
1 7.6490
10
10
10
0.765
96%
5.0
25227-4
0.012
-0.0724
10
10
10
25227-4 s k
0,384
4,5530
10
10
10
0.455
91%
5.0
25227-5
0.004
-0.1718
10
10
25227-5 s k
0.413
4.9136
10
10
10
0.491
98%
5.0
25227-6
0.024
0.0768
10
10
10
25227-6 s k
0.410
4.8763
10
10
10
0.488
98%
5.0
25227-7
0.009
-0.1097
10
10
10
<
25227-7 s k
0.323
3.7945
10
10
10
0.379
76%
5.0
25227-8
0.006
-0.1470
10
10
10"
25227-8 s k
0.439
5.2369
10
10
10
0.524
105%
5.0
25227-9
0.002
-0.1967
10
10
10
25227-9 s k
0.438
5.2244
10
10
10
0.522
104%
5.0
Blank
-0.001
0.0000
10
10
10
<
QC 0.422 5.0255 10
Submitted fOr Q QC- Date: 07/03/15
10
By: (Print)
10 0.503
KAM
101 %O 5.0
(sign):IV-
Page 1 of 3 � /

Analytical Lab
Page 30 of 74
METHOD:
SM 4500 S2- D
ELEMENT ONE
ELEMENT ASSAY:
Sulfide
Spectrophotometer
Wave Length 664
UNITS OF ANSWER
u /mL
DETECTION LIMIT u
1.000
CLIENT:
Duke
SPK LEVELLuM
5
Lab ID#
25227 / 228 / 229
Na2S'9H2O Lot #
40721
MAX ALIQUOT
10.00
Date:
07/03/15
_
STANDARD conc(ppm)
X
Time Analysis Begun
08:20
Cal Std Lot: SD-16-1
10
Time Analysis Ended
12:10
QC Std Lot: SD-16-2
10
Analyst:
KAM
JSTD ABSORPTION
Y
X
Y
ug STD
STD
SOLUTION
ABS
0.00
T000
1.00
0,093
2.50
0.223
5.00
0.431
750
0619
2.00 4,00 6.00 800 10.00 12W
10.00 0.832 x
,0 , ..N� *, Ac
SAMPLE
I.D.
� ,,k;
SAMP
ABS
ug PER
ALIQUOT
ALI in mL
ANALYZED
-
PREP
VOL in mL
Sloe 0.08232967
Correlation 0.999696878
ALI in mL
TAKEN
RESULTS
u /ml-
LESS THAN
% SPK REC
SPIKE
LEVEL
Std. B. 0.00
0.000
0.0000
10
10
10
<
0.0
Std. B. 1.00
0.093
0.9348
10
10
10
<
93%
1.0
Std. B. 2.50
0.227
2.6009
10
10
10
0.260
104%
2.5
Std. B. 5.00
0.430
5.1249
10
10
10
0.512
102%
5.0
Std. B. 7.50
0.618
7.4625
10
16
10
0.746
99%
7.5
Std. B. 10.00
0.795
9.6633
10
10
10
0.966
97%
10.0
LRB
0.003
-0.1843
10
10
10
<
0.0
LRB SPK
0.416
4.9509
10
10
10
0.495
99%
5.0
QC
0.423
5.0379
10
10
10
0.504
101 %
5.0
25228-1
0.002
-0.1967
10
10
10'„
77�-
25228-1 s k
0.364
4.3043
10
10
10
0.430
86%
5.0
25228-2
0.003
-0.1843
10
10
1077
77,
<{);P
25228-2 dup
0.004
-0.1718
10
10
10
< 0.1
25228-2 s k
0.425
5.0628
10
10
10
0.506
101 %
5.0
25228-3
0.009
-0.1097
10
10
10
<
25228-3 s k
0.264
3.0609
10
10
10
0.306
61 %
5.0
25228-4
0.019
0.0147
10
10
10
25228-4 s k
0.453
5.4109
10
10
10
0.541
108%
5.0
25228-5
0.001
-0.2091
10
10
10
25228-5 s k
0.429
5.1125
10
10
10
0.511
102%
5.0
25229
0.008
-0.1221
10
10
10
<
25229 s k
0.026
0.1017
10
10
10
<
2%
5.0
25227-2
0.005
-0.1594
10
10
5
<
25227-2 dup
0.005
-0.1594
10
10
5
< p
25227-2 spk
0.369
4.3665
10
10
5
0.873
87%
5.0
25227-7
0.000
0.0000
10
10
5
25227-7 s k
0.378
4.4784
10
10
5
0.896
90%
5.0
25228-3
0.005
-0.1594
10
10
5
<
25228-3 s k
0.355
4.1924
10
10
5
0.838
84%
5.0
Blank
-0.001
0.0000
10
10
10
<
QC
0.423
5.0379
10
10
10
0.504
101 %
5.0
Submlffed for QA/QC- Date: 07/03/15
By: (Print)
KAM I
(sign):
Page 2 of 3

Analytical Lab
Page 31 of 74
METHOD:
SM 4500 S2- D
ELEMENT ONE
ELEMENT ASSAY:
Sulfide
Spectrophotometer UNITS OF ANSWER
Duke
Wave Length 664 DETECTION LIMIT u
CLIENT:
Lab ID#
25227/228J229
07/03/15
SPK LEVEL u
MAX ALIQUOT
Na2S•91-120 Lot # STANDARD conc(ppm)
Date:
Time Analysis
Begun
08:20
12:10
KAM
40721 Cal Std Lot: SD-16-1
QC Std Lot: SD-16-2
Time Analysis Ended
Analyst:
XY
STD ABSORPTION
-- - - -- -- - ---
ug STD
STD
SOLUTION
ABS
0.00
0.000
1.00
0.093
2.50
0.223
5.00
0.431
7.50
0.619
10.00
I. D.
'td. B. 0.00
;td. B. 1.00
'td. B. 2.50
;td. B. 5.00
;td. B. 7.50
td. B. 10.0(
LRB
LRB SPK
25229 s,
25228-3
25228-3
25229
25229
Blank
QC
0.832
x
Sloe 0.082
SAMP ug PER ALI in mL PREP ALI in mL RESUL
ABS ALIQUOT ANALYZED VOL in mL TAKEN u /ml
0.000 0.0000 10 10 10 <
0.093 0.9348 10 10 10 <
0.227 2.6009 10 10 10 0.260
0.430 5.1249 10 10 10 0.512
0.618 7.4625 10 10 10 0.746
0.795 9.6633 10 10 10 0.966
0.003-0.1843 10 10 10 <
0.416 4.9509 10 10 10 0.495
0.423 5.0379 10 10 10 0.504
0.009-0.1097 10 10 5 <
0.122 1.2954 10 10 5 0.259
0.004-0.1718 10 10
2
0.408 4.8514 10 10 2 2.426
0.004-0.1718 10 10 2 <
0.223 2.5512 10 10 2 1.276
0.003-0.1843 10 10 1 <
0.305 3.5707 10 10 1 3.571
0.001-0.2091 10 10 0.5 <
0.343 4.0432 10 10 0.5 8.086
0.006-0.1470 10 10 0.25.; < °0"
0.380 4.5033 10 10 0.25 18.013
-0.001 0.0000 10 10 10 <
0.423 5.0379 10 10 10 0.504
Date: 07/03/15 By: (Print) KAM
Page 3 of 3
X
10
10
Y
aao ill
--ioo
_�000
10.00 12 M
SPK REC I LEVEL
0.0
y7%
-0.001 0.0000 10 10 10 <
0.423 5.0379 10 10 10 0.504
Date: 07/03/15 By: (Print) KAM
Page 3 of 3
X
10
10
Y
aao ill
--ioo
_�000
10.00 12 M
SPK REC I LEVEL
0.0
y7%
10.(
0.0
99%
5.0
101%
5.0
26%
5.0
97%
5.0
51 %
5.0
71 %
5.0
81 %
6.0
90%
5.0
101% 5.0
n): �� A

® Laboratories LLc
al t iI Lab
a member of The GEL Group IN'.
July 08, 2015
Mary Ann Ogle
Duke Energy Analytical Laboratory
13339 Hagers Ferry Road
Mail Code: MG03A2
Huntersville, North Carolina 28078
Re: AB GW Assessment Water
Work Order: 376063
SDG: J15070007
Dear Mary:
PO BOX 30712 Charleston, SC 29417
2040 Savage Road Charlestan. SC 25407
F 843.556.8171
F 843.766.1178
GEL Laboratories, LLC (GEL) appreciates the opportunity to provide the enclosed analytical results for the
sample(s) we received on July 01, 2015. This original data report has been prepared and reviewed in accordance
with GEL's standard operating procedures.
Our policy is to provide high quality, personalized analytical services to enable you to meet your analytical needs
on time every time. We trust that you will find everything in order and to your satisfaction. If you have any
questions, please do not hesitate to call me at [phone], ext. 4443.
Sincerely,
Lindsay Fabra
Project Manager
Purchase Order: 1142110
Enclosures
gel.com

Analytical Lab
Page 33 of 74
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis Report
for
DUP0002 Duke Energy
Client SDG: J15070007 GEL Work Order: 376063
The Qualifiers in this report are defined as follows:
* A quality control analyte recovery is outside of specified acceptance criteria
** Analyte is a Tracer compound
** Analyte is a surrogate compound
J Value is estimated
U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless qualified on the Certificate of Analysis.
The designation ND, if present, appears in the result column when the analyte concentration is not detected above
the limit as defined in the 'U' qualifier above.
This data report has been prepared and reviewed in accordance with GEL Laboratories LLC
standard operating procedures. Please direct any questions to your Project Manager, Lindsay Fabra.
Reviewed by
JU,&Y ,
Page 2 of 10

Analytical Lab
GEL LABORATORIES LLC Page 34 of 74
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company:
Duke Energy Analytical Laboratory
Address :
13339 Hagers Ferry Road
Mail Code: MG03A2
Huntersville, North Carolina 28078
Contact:
Mary Ann Ogle
Project:
AB GW Assessment Water
Client Sample ID:
Sample ID:
Matrix:
Collect Date:
Receive Date:
Collector:
2015021638
376063001
Water
30-JUN-15 13:08
01-JUL-15
Client
Report Date: July 8, 2015
Project: DUKE00225
Client ID: DUP0002
Parameter Qualifier Result DL RL Units DF Analyst Date Time Batch Method
Metals Analysis-ICP-MS
SW846 3010A/6020A Liquid "As Received"
Uranium-238 0.000209
0.000067
0.0002
ug/mL
1
PRB 07/08/15
1255 1489648 1
Uranium-233 U 0.00
0.00001
0.00005
ug/mL
1
SKJ 07/08/15
1312 1489648 2
Uranium-234 U 0.00
0.00001
0.00005
ug/mL
1
Uranium-236 U 0.00
0.00001
0.00005
ug/mL
1
Rad Gas Flow Proportional Counting
GFPC, Ra228, Liquid "As Received"
Radium-228 U 0.583
1.24
3.00
pCi/L
AXM6 07/08/15
1157 1489766 3
Rad Radium-226
Lucas Cell, Ra226, liquid "As Received"
Radium-226 3.00
0.563
1.00
pCi/L
CXP3 07/07/15
0840 1489741 4
The following Prep Methods were performed:
Method Description
Analyst
Date
Time Prep Batch
SW846 3010A SW 846 3010 Acid Digestion
JXM5
07/02/15
0800
1489647
The following Analytical Methods were performed:
Method Description Analyst Comments
1 SW846 3010A/6020A
2 SW846 3010A/6020A
3 EPA 904,0/SW846 9320 Modified
4 EPA 903.1 Modified
Surrogate/Tracer Recovery Test Result Nominal Recovery% Acceptable Limits
Barium-133 Tracer GFPC, Ra228, Liquid "As Received" 87.6 (15%-125%)
Notes:
Page 3 of 10

Analytical Lab
Page 35 of 74
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
QC Summary
Duke Energy Analytical Laboratory
13339 Hagers Ferry Road
Mail Code: MG03A2
Huntersville, North Carolina
Contact: Mary Ann Ogle
Workorder: 376063
Report Date: July 8, 2015
Page 1 of 3
Parmname
NOM
Sample
Qual
QC
Units
RPD%o
REC%
Range
Anlst
Date Time
Metals Analysis - ICPMS
Batch 1489648
QC1203347032
376056001
DUP
Uranium-233
U
ND
U
ND
ug/mL
N/A
SKJ
07/08/1512:51
Uranium-234
U
ND
U
ND
ug/mL
N/A
Uranium-236
U
ND
U
ND
ug/mL
N/A
Uranium-238
0.000449
0.000422
ug/mL
6.20 ^
(+/-0.0002)
PRB
07/08/1512:35
QC1203347031
LCS
Uranium-238
0.0496
0.052
ug/mL
105
(80%-120%)
07/08/1512:32
QC1203347068
LCS
Uranium-233
0.0005
0.00053
ug/mL
106
(80%-120%)
SKJ
07/08/1512:48
Uranium-234
0.00055
0.000553
ug/mL
101
(80%-120%)
Uranium-236
0.005
0.00587
ug/mL
117
(80%-120%)
QC1203347030
MB
Uranium-233
U
ND
ug/mL
07/08/1512:46
Uranium-234
U
ND
ug/mL
Uranium-236
U
ND
ug/mL
Uranium-238
U
ND
ug/mL
PRB
07/08/1512:30
QC1203347033
376056001
MS
Uranium-238
0.0496
0.000449
0.0515
ug/mL
103
(75%-125%)
07/08/1512:37
QC1203347069
376056001
MS
Uranium-233
0.0005
U
ND
0.000515
ug/mL
103
(75%-125%)
SKJ
07/08/1512:52
Uranium-234
0.00055
U
ND
0.000541
ug/mL
98.4
(75%-125%)
Uranium-236
0.005
U
ND
0.00572
ug/mL
114
(75%-125%)
QC1203347034
376056001
SDILT
Uranium-233
U
ND
U
ND
ug/L
N/A
07/08/1512:53
Page 4 of 10

Analytical Lab
Page 36 of 74
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
QC Summary
Workorder: 376063
Page 2 of 3
Parmname
NOM
Sample
Qual
QC
Units
RPD%
REC%
Range
Anlst
Date Time
Metals Analysis - ICPMS
Batch 1489648
Uranium-234
U
ND
U
ND
ug/L
N/A
Uranium-236
U
ND
U
ND
ug/L
N/A
(0%-10%)
SKJ
07/08/1512:53
Uranium-238
0.449
J
0.097
ug/L
8.02
(0%-10%)
PRB
07/08/1512:38
Rad Gas Flow
Batch 1489766
QC1203347317 376063001 DUP
Radium-228
U
0.583
U
-0.571
pCi/L
N/A
N/AAXM6
07/08/1511:58
QC1203347318 LCS
Radium-228
30.6
33.3
pCi/L
109
(75%-125%)
07/08/1511:58
QC1203347316 MB
Radium-228
U
1.02
pCi/L
07/08/1511:58
Rad Ra-226
Batch 1489741
QC1203347262 376063001 DUP
Radium-226
3.00
2.56
pCi/L
15.6
(0%-20%)
CXP3
07/07/15 08:40
QC1203347264 LCS
Radium-226
24.7
19.9
pCi/L
80.7
(75%-125%)
07/07/15 09:15
QC1203347261 MB
Radium-226
U
0.455
pCi/L
07/07/15 08:40
QC1203347263 376063001 MS
Radium-226
124
3.00
120
DCi/L
94.3
(75%-125%)
07/07/15 09:15
Notes:
The Qualifiers in this report are defined as follows:
** Analyte is a Tracer compound
< Result is less than value reported
> Result is greater than value reported
BD Results are either below the MDC or tracer recovery is low
E %difference of sample and SD is >10%. Sample concentration must meet flagging criteria
FA Failed analysis.
FB Mercury was found present at quantifiable concentrations in field blanks received with these samples. Data associated with the blank are deemed
invalid for reporting to regulatory agencies
H Analytical holding time was exceeded
Page 5 of 10

Analytical Lab
Page 37 of 74
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
QC Summary
Workorder: 376063
Parmname NOM Sample Qual QC Units RPD% REC'% Range Anlst
J Value is estimated
K Analyte present. Reported value may be biased high. Actual value is expected to be lower.
L Analyte present. Reported value may be biased low. Actual value is expected to be higher.
M M if above MDC and less than LLD
M REMP Result > MDC/CL and < RDL
N Metals --The Matrix spike sample recovery is not within specified control limits
N/A RPD or %Recovery limits do not apply.
N1 See case narrative
ND Analyte concentration is not detected above the detection limit
NJ Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
Q One or more quality control criteria have not been met. Refer to the applicable narrative or DER.
R Sample results are rejected
U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
UI Gamma Spectroscopy --Uncertain identification
UJ Gamma Spectroscopy --Uncertain identification
UL Not considered detected. The associated number is the reported concentration, which may be inaccurate due to a low bias.
X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
Y Other specific qualifiers were required to properly define the results. Consult case narrative.
^ RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL. Qualifier Not Applicable for Radiochemistry.
h Preparation or preservation holding time was exceeded
Page 3 of 3
Date Time
N/A indicates that spike recovery limits do not apply when sample concentration exceeds spike cone. by a factor of 4 or more or %RPD not applicable.
^ The Relative Percent Difference (RPD) obtained from the sample duplicate (DUP) is evaluated against the acceptance criteria when the sample is greater than
five times (5X) the contract required detection limit (RL). In cases where either the sample or duplicate value is less than 5X the RL, a control limit of +/- the
RL is used to evaluate the DUP result.
* Indicates that a Quality Control parameter was not within specifications.
For PS, PSD, and SDILT results, the values listed are the measured amounts, not final concentrations.
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless qualified on the QC Summary.
Page 6of10

C'i
0
w
Analytical Lab
Page 38 of 74
a r
m 'Z
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Page 7 of 10

Analytical Lab
Page 39 of 74
Laboratories
SAMPLE RECEIPT &REVIEW FORM
Client: "'
SDG/AR/COC/Work Order:
Received By: s _ 4
i
Date Received: 1
'"If Net Counts > 100cpm on samples not marked "radioactive", contact the Radiation Safety Group for further
Suspected Hazard Information
�^
z investigation.
COC/Samples marked as radioactive?
uellvlaximum Net Counts Observed* (Observed Counts - Area Background Counts): ,, t
Classified Radioactive II or III by RSO?
ujTf yes, Were swipes taken of sample contatiners < action levels?
COC/Samples marked containing PCBs?
Package, COC, and/or Samples marked as
beryllium or asbestos containing?
If yes, samples are to be segregated as Safety Controlled Samples, and opened by the GEL Safety Group.
Shipped as a DOT Hazardous?
1,,, flazard Class Shipped: UN#:
Sam les identified as Foreign Soil'?
Sample Receipt Criteria
z z
Comments/Qualifiers (Required for Non -Conforming Items)
I
Shipping containers received intact
4
1
Circle Applicable:
Seals broken Damaged container Leaking container Other (describe)
and sealed?
1
Samples requiting COId preservation
Preservation Method: Ice bags Blue ice Dry ice Non Other (describe)
*all
2
1.
temperatures are recorded in c . as
within (0 < 6 deg. C)?*
2a
Daily check performed and passed on
Temperature Device Serial #:
Secondary Temperature Device Serial # (If Applicable): ( oc,1 e
IR temperature gun'?
Chain of custody documents included
3
with shipment?
Circle Applicable:
4
Sample containers intact and sealed?
Seals broken Damaged container Leaking container Other (describe)
Samples requiring chemical
Sample ID's, containers affected and observed pit:
5
preservation at proper pH?
PreservationIf e ILot i .
Do Low Level Perchlorate samples
Sample ID's and containers affected:
6
(EPA 6850) have headspaee as
I
"
I
required?
VOA vials free of headspaee (defined
Sample ID's and containers affected:
?
as < 6mm bubble)?
(If yes, immediately deliver to Volatiles laboratory)
8
Are Encore containers present?
Samples received within holding
ID's and tests affected:
9
time?
Sample ID's on COC match ID's on
Sample ID's and containers affected:
10
bottles?
Date & time on COC match date &
Sample ID's affected:
11
time on bottles?
Number of containers received [Hatch
Sample ID's affected:
12
number indicated on COC?
Are sample containers identifiable as
13
GEL provided?
COC form is properly signed in
14
relinquished/received sections?
Circle Applicable:.
FedEx Air FedEx Ground UPS Field Services Courier Other
15
Carrier and tracking number.
Comments (Use Continuation Form if needed):
PM (or PMA) review: Initials ram" "0 Date _�_ �_a __ Page _I_ of _t_ UL-Ur1L-0n-UV I nev t
Page 8 of 10

Analytical Lab
Page 40 of 74
List of current GEL Certifications as of 08 July 2015
State
Certification
Alaska
UST-110
Arkansas
88-0651
CLIA
42DO904046
California
2940 Interim
Colorado
SC00012
Connecticut
PH-0169
Delaware
SC000122013-10
DoD ELAP/ ISO17025 A2LA
2567.01
Florida NELAP
E87156
Foreign Soils Permit
P330-12-00283, P330-12-00284
Georgia
SC00012
Georgia SDWA
967
Hawaii
SC000122013-10
Idaho Chemistry
SC00012
Idaho Radiochemistry
SC00012
Illinois NELAP
200029
Indiana
C—SC-01
Kansas NELAP
E-10332
Kentucky SDWA
90129
Kentucky Wastewater
90129
Louisiana NELAP
03046 (AI33904)
Louisiana SDWA
LA150001
Maryland
270
Massachusetts
M—SCO 12
Michigan
9976
Mississippi
SC000122013-10
Nebraska
NE—OS-26-13
Nevada
SC000122014-1
New Hampshire NELAP
2054
New Jersey NELAP
SCO02
New Mexico
SC00012
New York NELAP
11501
North Carolina
233
North Carolina SDWA
45709
Oklahoma
9904
Pennsylvania NELAP
68-00485
Plant Material Permit
PDEP-12-00260
S.Carolina Radchem
10120002
South Carolina Chemistry
10120001
Tennessee
TN 02934
Texas NELAP
T104704235-15-10
Utah NELAP
SC000122015-17
Vermont
VT87156
Virginia NELAP
460202
Washington
C780
West Virginia
997404
Page 9 of 10

Analytical Lab
There are no "Data Exception Reports" associated with this analytical rePAO.41 of 74
Page 10 of 10

SHEALY ENVIRONMENTAL SERVICES, INC.
Report of Analysis
Duke Energy
13339 Hagers Ferry Rd
Bldg 7405
Huntersville, NC 28078
Attention: Mary Ann Ogle
Project Name: AB GW Assessment Water - Cape Fear
Project Number:J15070007
Lot Number:QG01036
Date Completed:07/08/2015
Grant Wilton
Project Manager
This report shall not be reproduced, except in its entirety, without the written approval of Shealy Environmental Services, Inc.
The following non -paginated documents are considered part of this report: Chain of Custody Record and Sample Receipt Checklist.
Shealy Environmental Services, Inc. Page: 1 of 22
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

SHEALY ENVIRONMENTAL SERVICES, INC.
SC DHEC No: 32010 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
Case Narrative
Duke Energy
Lot Number: QG01036
Project Name: AB GW Assessment Water - Cape Fear
Project Number: J15070007
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample
receiving date is documented in the header information associated with each sample.
All results listed in this report relate only to the samples that are contained within this report.
Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the
Shealy Environmental Services, Inc. ("Shealy") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPS), and Shealy
policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below.
If you have any questions regarding this report please contact the Shealy Project Manager listed on the cover page
Shealy Environmental Services, Inc. Page: 2 of 22
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

SHEALY ENVIRONMENTAL SERVICES, INC.
Sample Summary
Duke Energy
Lot Number: QG01036
Project Name: AB GW Assessment Water - Cape Fear
Project Number: J15070007
Sample Number
Sample ID
Matrix
Date Sampled
Date Received
001
2015021635
Aqueous
06/30/20151408
07/01/2015
002
2015021636
Aqueous
06/29/20151650
07/01/2015
003
2015021637
Aqueous
06/30/20151013
07/01/2015
004
2015021639
Aqueous
06/30/20151105
07/01/2015
005
2015021640
Aqueous
06/30/2015 0930
07/01/2015
006
2015021641
Aqueous
06/30/20151201
07/01/2015
007
2015021642
Aqueous
06/30/20151522
07/01/2015
008
2015021644
Aqueous
06/30/2015
07/01/2015
009
2015021646
Aqueous
06/29/20151555
07/01/2015
(9 samples)
Shealy Environmental Services, Inc. Page: 3 of 22
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

SHEALY ENVIRONMENTAL SERVICES, INC.
Executive Summary
Duke Energy
Lot Number: QG01036
Project Name:
AB GW Assessment Water - Cape Fear
Project Number: J15070007
Sample Sample ID
Matrix
Parameter Method Result Q
Units
Page
001
2015021635
Aqueous
Alkalinity SM 2320B-
83
mg/L
5
001
2015021635
Aqueous
Bicarbonate Alkalinity SM 2320B-
82
mg/L
5
001
2015021635
Aqueous
Methane RSK - 175
25
ug/L
6
002
2015021636
Aqueous
Alkalinity SM 2320B-
60
mg/L
7
002
2015021636
Aqueous
Bicarbonate Alkalinity SM 2320B-
60
mg/L
7
003
2015021637
Aqueous
Alkalinity SM 2320B-
110
mg/L
9
003
2015021637
Aqueous
Bicarbonate Alkalinity SM 2320B-
100
mg/L
9
003
2015021637
Aqueous
Methane RSK - 175
53
ug/L
10
004
2015021639
Aqueous
Alkalinity SM 2320B-
58
mg/L
11
004
2015021639
Aqueous
Bicarbonate Alkalinity SM 2320B-
58
mg/L
11
005
2015021640
Aqueous
Alkalinity SM 2320B-
130
mg/L
13
005
2015021640
Aqueous
Bicarbonate Alkalinity SM 2320B-
130
mg/L
13
006
2015021641
Aqueous
Alkalinity SM 2320B-
180
mg/L
15
006
2015021641
Aqueous
Bicarbonate Alkalinity SM 2320B-
180
mg/L
15
006
2015021641
Aqueous
Methane RSK - 175
11
ug/L
16
007
2015021642
Aqueous
Alkalinity SM 2320B-
210
mg/L
17
007
2015021642
Aqueous
Bicarbonate Alkalinity SM 2320B-
210
mg/L
17
007
2015021642
Aqueous
Methane RSK - 175
11
ug/L
18
(18 detections)
Shealy Environmental Services, Inc. Page: 4 of 22
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Inorganic non-metals
Client: Duke Energy Laboratory ID: QG01036-001
Description: 2015021635 Matrix: Aqueous
Date Sampled:06/30/2015 1408 Project Name: AB GW Assessment Water -
Date Received:07/01/2015 Project Number: J15070007
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 07/02/2015 1401 HMA 78664
1 (Bicarbonate ) SM 2320B-2011 1 07/02/2015 1401 HMA
1 (Carbonate Al) SM 2320B-2011 1 07/02/2015 1401 HMA
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
83
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
82
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 5 of 22
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Methane
Client: Duke Energy Laboratory ID: QG01036-001
Description: 2015021635 Matrix: Aqueous
Date Sampled:06/30/2015 1408 Project Name: AB GW Assessment Water -
Date Received:07/01/2015 Project Number: J15070007
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 07/07/2015 2033 JJG 79023
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 25 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 6 of 22
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Inorganic non-metals
Client: Duke Energy Laboratory ID: QG01036-002
Description: 2015021636 Matrix: Aqueous
Date Sampled:06/29/2015 1650 Project Name: AB GW Assessment Water -
Date Received:07/01/2015 Project Number: J15070007
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 07/02/2015 1407 HMA 78664
1 (Bicarbonate ) SM 2320B-2011 1 07/02/2015 1407 HMA
1 (Carbonate Al) SM 2320B-2011 1 07/02/2015 1407 HMA
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
60
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
60
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 7 of 22
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Methane
Client: Duke Energy Laboratory ID: QG01036-002
Description: 2015021636 Matrix: Aqueous
Date Sampled:06/29/2015 1650 Project Name: AB GW Assessment Water -
Date Received:07/01/2015 Project Number: J15070007
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 07/07/2015 2046 JJG 79023
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 8 of 22
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Inorganic non-metals
Client: Duke Energy Laboratory ID: QG01036-003
Description: 2015021637 Matrix: Aqueous
Date Sampled:06/30/2015 1013 Project Name: AB GW Assessment Water -
Date Received:07/01/2015 Project Number: J15070007
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 07/02/2015 1412 HMA 78664
1 (Bicarbonate ) SM 2320B-2011 1 07/02/2015 1412 HMA
1 (Carbonate Al) SM 2320B-2011 1 07/02/2015 1412 HMA
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
110
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
100
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 9 of 22
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Methane
Client: Duke Energy Laboratory ID: QG01036-003
Description: 2015021637 Matrix: Aqueous
Date Sampled:06/30/2015 1013 Project Name: AB GW Assessment Water -
Date Received:07/01/2015 Project Number: J15070007
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 07/07/2015 2059 JJG 79023
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 53 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 10 of 22
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Inorganic non-metals
Client: Duke Energy Laboratory ID: QG01036-004
Description: 2015021639 Matrix: Aqueous
Date Sampled:06/30/2015 1105 Project Name: AB GW Assessment Water -
Date Received:07/01/2015 Project Number: J15070007
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 07/02/2015 1418 HMA 78664
1 (Bicarbonate ) SM 2320B-2011 1 07/02/2015 1418 HMA
1 (Carbonate Al) SM 2320B-2011 1 07/02/2015 1418 HMA
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
58
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
58
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 11 of 22
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Methane
Client: Duke Energy Laboratory ID: QG01036-004
Description: 2015021639 Matrix: Aqueous
Date Sampled:06/30/2015 1105 Project Name: AB GW Assessment Water -
Date Received:07/01/2015 Project Number: J15070007
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 07/08/2015 0022 JJG 79023
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 12 of 22
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Inorganic non-metals
Client: Duke Energy Laboratory ID: QG01036-005
Description: 2015021640 Matrix: Aqueous
Date Sampled:06/30/2015 0930 Project Name: AB GW Assessment Water -
Date Received:07/01/2015 Project Number: J15070007
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 07/02/2015 1424 HMA 78664
1 (Bicarbonate ) SM 2320B-2011 1 07/02/2015 1424 HMA
1 (Carbonate Al) SM 2320B-2011 1 07/02/2015 1424 HMA
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
130
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
130
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 13 of 22
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Methane
Client: Duke Energy Laboratory ID: QG01036-005
Description: 2015021640 Matrix: Aqueous
Date Sampled:06/30/2015 0930 Project Name: AB GW Assessment Water -
Date Received:07/01/2015 Project Number: J15070007
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 07/07/2015 2310 JJG 79023
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 14 of 22
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Inorganic non-metals
Client: Duke Energy Laboratory ID: QG01036-006
Description: 2015021641 Matrix: Aqueous
Date Sampled:06/30/2015 1201 Project Name: AB GW Assessment Water -
Date Received:07/01/2015 Project Number: J15070007
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 07/02/2015 1431 HMA 78664
1 (Bicarbonate ) SM 2320B-2011 1 07/02/2015 1431 HMA
1 (Carbonate Al) SM 2320B-2011 1 07/02/2015 1431 HMA
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
180
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
180
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 15 of 22
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Methane
Client: Duke Energy Laboratory ID: QG01036-006
Description: 2015021641 Matrix: Aqueous
Date Sampled:06/30/2015 1201 Project Name: AB GW Assessment Water -
Date Received:07/01/2015 Project Number: J15070007
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 07/07/2015 2320 JJG 79023
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 11 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 16 of 22
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Inorganic non-metals
Client: Duke Energy Laboratory ID: QG01036-007
Description: 2015021642 Matrix: Aqueous
Date Sampled:06/30/2015 1522 Project Name: AB GW Assessment Water -
Date Received:07/01/2015 Project Number: J15070007
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 07/02/2015 1438 HMA 78664
1 (Bicarbonate ) SM 2320B-2011 1 07/02/2015 1438 HMA
1 (Carbonate Al) SM 2320B-2011 1 07/02/2015 1438 HMA
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
210
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
210
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 17 of 22
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Methane
Client: Duke Energy Laboratory ID: QG01036-007
Description: 2015021642 Matrix: Aqueous
Date Sampled:06/30/2015 1522 Project Name: AB GW Assessment Water -
Date Received:07/01/2015 Project Number: J15070007
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 07/07/2015 2330 JJG 79023
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 11 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 18 of 22
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Inorganic non-metals
Client: Duke Energy Laboratory ID: QG01036-008
Description: 2015021644 Matrix: Aqueous
Date Sampled:06/30/2015 Project Name: AB GW Assessment Water -
Date Received:07/01/2015 Project Number: J15070007
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 07/02/2015 1442 HMA 78664
1 (Bicarbonate ) SM 2320B-2011 1 07/02/2015 1442 HMA
1 (Carbonate Al) SM 2320B-2011 1 07/02/2015 1442 HMA
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
ND
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 19 of 22
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Methane
Client: Duke Energy Laboratory ID: QG01036-008
Description: 2015021644 Matrix: Aqueous
Date Sampled:06/30/2015 Project Name: AB GW Assessment Water -
Date Received:07/01/2015 Project Number: J15070007
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 07/07/2015 2354 JJG 79023
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 20 of 22
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Inorganic non-metals
Client: Duke Energy Laboratory ID: QG01036-009
Description: 2015021646 Matrix: Aqueous
Date Sampled:06/29/2015 1555 Project Name: AB GW Assessment Water -
Date Received:07/01/2015 Project Number: J15070007
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 07/02/2015 1447 HMA 78664
1 (Bicarbonate ) SM 2320B-2011 1 07/02/2015 1447 HMA
1 (Carbonate Al) SM 2320B-2011 1 07/02/2015 1447 HMA
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
ND
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 21 of 22
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Methane
Client: Duke Energy Laboratory ID: QG01036-009
Description: 2015021646 Matrix: Aqueous
Date Sampled:06/29/2015 1555 Project Name: AB GW Assessment Water -
Date Received:07/01/2015 Project Number: J15070007
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 07/08/2015 0005 JJG 79023
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 22 of 22
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

QC Summary
Shealy Environmental Services, Inc. QC Data for Lot Number: QG01036
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Inorganic non-metals - MB
Sample ID: QQ78664-001 Matrix: Aqueous
Batch:78664
Analytical Method: SM 2320B-2011
Parameter Result Q Dil PQL Units Analysis Date
Alkalinity ND 1 10 mg/L 07/02/20151256
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QG01036
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Inorganic non-metals - LCS
Sample ID: QQ78664-002 Matrix: Aqueous
Batch:78664
Analytical Method: SM 2320B-2011
Spike
Amount Result % Rec
Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Alkalinity 100 98 1 98 90-110 07/02/20151302
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QG01036
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Inorganic non-metals - MS
Sample ID: QG01036-003MS Matrix: Aqueous
Batch:78664
Analytical Method: SM 2320B-2011
Sample Spike
Amount Amount Result % Rec
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Alkalinity 110 100 200 1 90 70-130 07/02/20151315
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QG01036
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Inorganic non-metals - MSD
Sample ID: QG01036-003MD Matrix: Aqueous
Batch:78664
Analytical Method: SM 2320B-2011
Sample Spike
Amount Amount Result % Rec % RPD
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date
Alkalinity 110 100 200 1 90 0.020 70-130 20 07/02/20151309
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QG01036
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Methane - MB
Sample ID: QQ79023-001 Matrix: Aqueous
Batch:79023
Analytical Method: RSK - 175
Parameter Result Q Dil PQL Units Analysis Date
Methane ND 1 10 ug/L 07/07/20151711
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QG01036
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Methane - LCS
Sample ID: QQ79023-002 Matrix: Aqueous
Batch:79023
Analytical Method: RSK - 175
Spike
Amount Result % Rec
Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date
Methane 150 110 1 73 70-130 07/07/20151639
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QG01036
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Methane - LCSD
Sample ID: QQ79023-003 Matrix: Aqueous
Batch:79023
Analytical Method: RSK - 175
Spike
Amount Result % Rec % RPD
Parameter (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date
Methane 150 110 1 76 3.0 70-130 30 07/07/20151654
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QG01036
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

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106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

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lbieans of r°e ipt: qE I ❑ Crliew [J []PS ❑ Fed& [] Aiftme EV 210ther
Y+-S ❑� Noa 1 1. Were custody seals resort on the Goole e?
cs ❑ Na NA 2. If custody 9cals were +t tent, were in ialact aad unkoken?
Cooler TDe'O igmsl tcmPerature upan receipt+Doyived (corrected) tc'79i,perahne upon rat:
-IA Li_`i C f 11C r 1 ° fir. J .0C
Method- ❑ Temperatute Against Battles ]R Gem ID: SJLR Crun rr=tiou. Factor; °C
Ucthc d of coolant: wet toe ❑ Blue Ice Dry Toe LI None
3- if temperature of any coDlr r exceeded &O C, was Projcct Manager notified?
v,m ❑ too Ej Paid testified by 'SRC, phone, note (circle one), u&cr-
(For coolers received via commcreial courier, PNIs are to be notifies
Yes ❑
❑
NA
4. Ts the oam =jal courier's cking slip an&;hcd to this form?
Y cs
No ❑
_
5. Wen CU51 ruccdures Orel' uishe�dfree�tiur�d fvllow+ed'r
Yet 0
N.
I NAZ
5a Were sam lut5 rcl shed !IX cllcot w co mmial courier?
Yes .
o ❑
a. Wm sample Ms listed on the Cox_'?
Yes.
a ❑
7, W2fC Sample II]s listed on all le contaillers?
Yrs
o C]
S. '9` ns collection date & tune listed on the COO?
Yes
o
9. 'Was oc lle uticn date & tints Limed on all sample, at2inars'
Yes
0 Li
1 Dk [did all cuotaimrlabel iuformMion date, tune atrw with, the l OC7
Yes
o ❑
11, Were tests to be performed listed on the C.00?
Ycs
No Lj
12, Did all s.amles arrive. in the lIrk4wr uxitawe3 s for ewh nest?
Yee
o ❑
13. Did all cmtainm arriVe ilk ood condition unbroken, Hds oa et+c. $
Yc�
t+ra p
14, Was ad uMe sate le volume available:'
Ye
No D
I S. Wore all sampiat received withi the holding time or 48 houes, which
comes fint?
Yee
t.
16. Wcrc any &offlVles containers missing?
Yes Fj
No
17, Were there my excess sap! les not listed on CGG2
Yes
ND If
NA El
18, 'rem bubbles sent > ea-szzc" ( "oar 6mm in diameter) inpy V0A
V.-A n
K, F1
A'd UT 1
1 0 ILIF._..,1 ....,s..,..rn u.� A�---._r _ : _ - , - -- - --

CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM
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