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NC0003433_J15060674F_20150902
+ DUKE Analytical Laboratory Page 1of21 ENERGY Order Number: Project Name: Customer Name(s): Customer Address: 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone:980-875-5245 Fax:980-875-4349 Order Summary Report J15060674 CAPE FEAR - AB GW ASSESSMENT SPECIATION Tim Hunsucker, Chris Suttell, Kathy Webb, John Toepfer Lab Contact: Peggy Kendall Phone: peggy.kendall@du Report Authorized By: ke-energy.com Date: 8/3/2015 (Signature) 2015.0&03 rt€_ Peggy Kendall 10:15:29-04'00' Program Comments: Please contact the Program Manager (Peggy Kendall) with any questions regarding this report. Data Flags & Calculations: Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Sample ID's & Descriptions: Page 2 of 21 Sample ID Plant/Station 2015020265 Cape Fear 2015020266 Cape Fear 2 Total Samples Collection Date and Time Collected By Sample Description 17-Jun-15 1:55 PM Kyle Donovan CTMW-2 17-Jun-15 11:18 AM Kyle Donovan MW-2 Page 3 of 21 Technical Validation Review Checklist: COC and .pdf report are in agreement with sample totals Yes No and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. ❑ Yes❑ No All laboratory QA/QC requirements are acceptable.❑ Yes ❑ No Report Sections Included: U Job Summary Report ❑ Sample Identification n Technical Validation of Data Package ❑ Analytical Laboratory Certificate of Analysis ❑ Analytical Laboratory QC Report Sub -contracted Laboratory Results ❑ Customer Specific Data Sheets, Reports, & Documentation ❑ Customer Database Entries 66 Chain of Custody [I/0] Electronic Data Deliverable (EDD) Sent Separately Reviewed By: Peggy Kendall Date: 8/3/2015 Certificate of Laboratory Analysis Page 4 of 21 This report shall not be reproduced, except in full. Order # J15060674 Site: CTMW-2 Collection Date: 17-Jun-15 1:55 PM Analyte Result Units Qualifiers RDL DF Speciation of an Element - (Analysis Performed by Brooks Rand Labs LLC) Vendor Parameter Complete Sample #: 2015020265 Matrix: GW WW Method Analysis Date/Time Analyst Vendor Method V_BRAND Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060674 Site: MW-2 Collection Date: 17-Jun-15 11:18 AM Analyte Result Units Qualifiers RDL DF Speciation of an Element - (Analysis Performed by Brooks Rand Labs LLC) Vendor Parameter Complete Sample #: 2015020266 Matrix: GW WW Page 5 of 21 Method Analysis Date/Time Analyst Vendor Method V_BRAND Page 6 of 21 BRO�©KS RAND LABS MEANINGFUL METALS DATA July 31, 2015 Peggy Kendall Duke Energy Analytical Laboratory Mail Code MGO3A2 (Building 7405) 13339 Hagers Ferry Rd. Huntersville, NC 28078 980-875-5848 Project: Duke Energy Progress Cape Fear (LIMS# J15060674) Ms. Kendall, Attached is the report associated with two (2) aqueous samples submitted for hexavalent chromium, selenium speciation, arsenic speciation, iron speciation, and manganese speciation analyses on June 17, 2015. The samples were received in a sealed cooler at -0.3°C on June 18, 2015. Arsenic speciation analyses were performed via ion chromatography inductively coupled plasma collision reaction cell mass spectrometry (IC-ICP-CRC-MS). All samples requesting iron speciation analysis were analyzed by spectrophotometry. Mn(II) analysis was performed via IC-ICP-CRC-MS. Mn(IV) analysis were performed via digestion and subsequent analysis by inductively coupled plasma triple quadrupole mass spectrometry (ICP-QQQ-MS). Any issues associated with the analyses are addressed in the following report. If you have any questions, please feel free to contact me at your convenience. Sincerely, kL7S�-- Jeremy Maute Project Manager Brooks Rand Labs, LLC 3958 6th Ave NW • Seattle, WA 98107 • T: 206-632-6206 • F: 206-632-6017 • www.brooksrand.com • brl@brooksrand.com Page 7 of 21 Brooks Rand Labs, LLC Report prepared for: Peggy Kendall Duke Energy Analytical Laboratory Mail Code MGO3A2 (Building 7405) 13339 Hagers Ferry Rd. Huntersville, NC 28078 Project: Duke Energy Progress Cape Fear (LIMS# J15060674) July 31, 2015 1. Sample Reception Two (2) aqueous samples were submitted for hexavalent chromium, selenium speciation, arsenic speciation, iron speciation, and manganese speciation analyses on June 17, 2015. The samples were received in acceptable condition on June 18, 2015 in a sealed container at a temperature of-0.3°C. The client instructed Brooks Rand Labs to cancel hexavalent chromium and selenium speciation analyses for all client samples in this sampling event. The chain of custody form reflects hexavalent chromium and selenium speciation as target analytes; however, no results were reported for these parameters in accordance with the client's instructions. All samples were received in a laminar flow clean hood, void of trace metals contamination and ultra -violet radiation, and were designated discrete sample identifiers. Sample fractions requesting hexavalent chromium, selenium speciation, arsenic speciation, and iron speciation analyses were field filtered by the client. Two containers were submitted for each client sample requesting manganese speciation, one field filtered fraction and one unfiltered fraction. An aliquot of each sample submitted for arsenic speciation analysis was filtered (0.45µm) into a polypropylene centrifuge tube; all filtrates and original bottles were then stored in a secure, monitored refrigerator (maintained at a temperature of <6°C) until the analyses could be performed. The sample fractions requesting iron speciation analysis were stored in a secure, monitored refrigerator (maintained at a temperature of <6°C) until the analyses could be performed. An aliquot of each filtered sample submitted for manganese speciation analysis was decanted into a polypropylene centrifuge tube for Mn(II) analysis. These fractions were stored in a Page 8 of 21 secure, monitored refrigerator (maintained at a temperature of <6°C) until the analyses could be performed. Subsequently, the original bottles (filtered and unfiltered fractions) intended for Mn speciation were preserved to pH < 2 with concentrated HNO3 and then stored in a secure polyethylene container, known to be free from trace metals contamination, until the digestion could be performed. 2. Sample Preparation All sample preparation is performed in laminar flow clean hoods known to be free from trace metals contamination. All applied water for dilutions and sample preservatives are monitored for contamination to account for any biases associated with the sample results. Arsenic speciation Analysis by IC-ICP-CRC-MS An aliquot of each sample was filtered directly into a sealed autosampler vial. No further sample preparation was performed as a buffered EDTA solution was provided by Brooks Rand Labs for field -preservation of the submitted samples. Iron speciation Analysis by Spectrophotometry No sample preparation was required as a de - gassed HCL solution was provided by Brooks Rand Labs for field -preservation of the submitted samples. Manganese Mn(II Analysis by IC-ICP-CRC-MS An aliquot of each sample was filtered (0.45µm) directly into an autosampler vial for Mn(II) analysis. No additional sample preparation was performed as any chemical alteration of the samples may shift the equilibrium of the system resulting in changes in speciation ratios. Manganese Mn(IV) Analysis by ICP-QQQ-MS Each filtered and unfiltered sample submitted for Mn speciation analysis was preserved with 1% HNO3 (v/v) upon sample receipt. Each sample fraction was then further digested on a hotblock apparatus with aliquots of 50% HNO3 (v/v) and 50% HCl (v/v), in accordance with the digestion procedure specified in EPA Method 200.8. All resulting sample digests were analyzed for total manganese via inductively coupled plasma triple quadrupole mass spectrometry (ICP-QQQ-MS). 3. Sample Analysis All sample analysis is preceded by a minimum of a five -point calibration curve spanning the entire concentration range of interest. Calibration curves are performed at the beginning of each analytical day. All calibration curves, associated with each species of interest, are standardized by linear regression resulting in a response factor. All sample results are instrument blank corrected to account for any operational biases associated with the analytical platform. Prior to sample analysis, all calibration curves are verified using second source standards which are identified as initial calibration verification standards (ICV). Page 9 of 21 Ongoing instrument performance is identified by the analysis of continuing calibration verification standards (CCV) and continuing calibration blanks (CCB) at a minimum interval of every ten analytical runs. Arsenic Speciation Analysis by IC-ICP-CRC-MS Each sample was analyzed for arsenic speciation via ion chromatography inductively coupled plasma collision reaction cell mass spectrometry (IC-ICP-CRC-MS) on July 14, 2015. Aliquots of each sample are injected onto an anion exchange column and eluted isocratically. The eluting arsenic species are then introduced into a radio frequency (RF) plasma where energy -transfer processes cause desolvation, atomization, and ionization. The ions are extracted from the plasma through a differentially -pumped vacuum interface and travel through a pressurized chamber (CRC) containing a specific collision gas. Polyatomic interferences, due to their inherently larger size, collide more frequently with the collision gas and therefore may be separated from the analyte of interest via kinetic energy discrimination (KED). A solid-state detector detects ions transmitted through the mass analyzer on the basis of their mass -to -charge ratio (m/z), and the resulting current is processed by a data handling system. Retention times for each eluting species are compared to known standards for species identification. Iron Speciation Analysis by Spectrophotometry All samples submitted were analyzed for Fe(II) quantification on June 18, 2015. The samples were analyzed for total recoverable Fe on July 14, 2015. All samples were analyzed for Fe speciation in accordance with the scientifically accepted method outlined by: Stookey, L.L., (1970). "Ferrozine - A new spectrophotometric reagent for iron", Anal.Chem., 42:779-81. Manganese Mn(II) Analysis by IC-ICP-CRC-MS All samples for Mn(II) analysis were analyzed by ion chromatography inductively coupled plasma collision reaction cell mass spectrometry (IC-ICP-CRC-MS) on June 29, 2015. Aliquots of each sample are injected onto an anion exchange column and mobilized by an acidic (pH < 7) gradient. An ion pairing agent provides a dynamic ion exchange mechanism for the cationic manganese species on the chromatographic column. The differences in the affinity of manganese species towards the ion pair agent and the column results in separation. The eluting selenium species are then introduced into a radio frequency (RF) plasma where energy -transfer processes cause desolvation, atomization, and ionization. The ions are extracted from the plasma through a differentially -pumped vacuum interface and travel through a pressurized chamber (CRC) containing a reaction gas which preferentially reacts with interfering ions of the same target mass to charge ratios (m/z). A solid-state detector detects ions transmitted through the mass analyzer and the resulting current is processed by a data handling system. Retention times for each eluting species are compared to known standards for species identification. Page 10 of 21 Manganese Mn(IV) Analysis by ICP-QQQ-MS All samples submitted for Mn speciation quantitation were analyzed by inductively coupled plasma triple quadrupole mass spectrometry (ICP-QQQ-MS) on July 3, 2015. Aliquots of each sample digest are introduced into a radio frequency (RF) plasma where energy -transfer processes cause desolvation, atomization, and ionization. The ions are extracted from the plasma through a differentially - pumped vacuum interface and travel through an initial quadrupole (Q1), which filters the target masses prior to their entrance into a second chamber. The second chamber contains specific reactive gasses or collision gasses that preferentially react either with interfering ions of the same target mass to charge ratios (m/z) or with the target analyte, producing an entirely different mass to charge ratio (m/z) which can then be differentiated from the initial interferences. The ions then exit the collision/reaction cell into and additional quadrupole (Q2). A solid-state detector detects ions transmitted through the mass analyzer, on the basis of their mass -to -charge ratio (m/z), and the resulting current is processed by a data handling system. 4. Analytical Issues No significant analytical issues were encountered. With the exceptions noted below, all quality control parameters associated with the samples were within acceptance limits. Mn(IV) is quantified by analyzing the water samples for total Mn and dissolved Mn. Mn(IV) is operationally defined as the difference between the filtered and unfiltered total Mn concentrations, since it is thermodynamically favored to be in the form of a precipitate. Total and dissolved manganese results for the client sample, identified as MW-2, were greater than the value of the associated high calibration standard. A linear range verification standard was analyzed at 2000 µg/L. The manganese recovery for the linear range verification standard was acceptable, at 99.5%, demonstrating that the linear range of the analytical platform extended to 2000 µg/L for manganese. Manganese results for MW-2 were less than 2000 µg/L with the dilutions at the instrument factored in, and thus were within the linear range demonstrated by the linear range verification standard. No qualification of data was necessary. The eMDL values for arsenite, arsenate, and dimethylarsinic acid are generated using the standard deviation of replicate analyses of the lowest standard in the calibration curve. The eMDL for monomethylarsonic acid is calculated from the average eMDL of the three arsenic species contained in the calibration (i.e., arsenite, arsenate, and dimethylarsinic acid); the calibration and CCVs do not contain monomethylarsonic acid due to impurities in this standard which would bias the results for other arsenic species. The eMDL values for Fe(II) and total recoverable Fe were set at 5.0 based on the sensitivity of the instrument. Page 11 of 21 The eMDL for Mn(II) has been generated from replicate analyses of the lowest standard in the calibration curve. The eMDL values for Mn(IV) been calculated using the standard deviation of the method blanks prepared and analyzed concurrently with the submitted samples. The dissolved manganese result for the fourth preparation blank, identified as PBW4, is a statistical outlier according to the Grubb's Test. The value for this sample was omitted from calculations used to determine the eMDL associated with manganese results. If you have any questions or concerns regarding this report, please feel free to contact me. Sincerely, Jeremy Maute Project Manager Brooks Rand Labs, LLC Page 12 of 21 Speciation Results for Duke Energy Project Name: Duke Energy Progress Cape Fear Contact: Peggy Kendall LIMS# J15060674 Date: July 31, 2015 Report Generated by: Jeremy Maute Brooks Rand Labs, LLC Sample Results (1) Unknown As Sample ID As(III) As(V) MMAs DMAs Species CTMW-2 0.285 6.38 ND (<0.061) ND (<0.064) ND (<0.061) MW-2 0.076 ND (<0.076) ND (<0.061) ND (<0.064) ND (<0.061) All results reflect the applied dilution and are reported in pg/L ND = Not detected at the applied dilution MMAs = monomethylarsonic acid DMAs = dimethylarsinic acid Unknown As Species = Total concentration of all unknown As species observed by IC-ICP-MS Page 13 of 21 Speciation Results for Duke Energy Project Name: Duke Energy Progress Cape Fear Contact: Peggy Kendall LIMS# J15060674 Date: July 31, 2015 Report Generated by: Jeremy Maute Brooks Rand Labs, LLC Sample Results (2) Sample ID Fe(II) Fe(III)* Mn (II) Mn(IV)** CTMW-2 ND (<5.0) ND (<5.0) ND (<0.26) 1.74 MW-2 943 19.3 7090 260 All results reflect the applied dilution and are reported in pg/L ND = Not detected at the applied dilution *Fe(III) operationally defined as the difference between total recoverable Fe and Fe(II) **Mn(IV) operationally defined as the difference between total and dissolved Mn Page 14 of 21 Speciation Results for Duke Energy Project Name: Duke Energy Progress Cape Fear Contact: Peggy Kendall LIMS# J15060674 Date: July 31, 2015 Report Generated by: Jeremy Maute Brooks Rand Labs, LLC Qualitv Control Summary - Preparation Blank Summary 0 Analyte (Ng/L) PBW1 PBW2 PBW3 PBW4 Mean StdDev eMDL* eMDL 10x RL 10x As(III) 0.000 0.000 0.000 0.000 0.000 0.000 0.004 0.042 0.20 As(V) 0.000 0.000 0.000 0.000 0.000 0.000 0.008 0.076 0.20 MMAs 0.000 0.000 0.000 0.000 0.000 0.000 0.006 0.061 0.20 DMAs 0.000 0.000 0.000 0.000 0.000 0.000 0.006 0.064 0.21 eMDL = Estimated Method Detection Limit; RL = Reporting Limit *Please see narrative regarding eMDL calculations Page 15 of 21 Speciation Results for Duke Energy Project Name: Duke Energy Progress Cape Fear Contact: Peggy Kendall LIMS# J15060674 Date: July 31, 2015 Report Generated by: Jeremy Maute Brooks Rand Labs, LLC Quality Control Summary - Preparation Blank Summary (2 Analyte (Ng/L) PBW1 PBW2 PBW3 PBW4 Mean StdDev eMDL** eMDL 1x RL 1x eMDL 2x RL 2x Fe(II) 0.0 0.0 0.0 0.0 0.0 0.0 5.0 5.0 20 10 40 Total Fe 0.0 0.0 0.0 0.0 0.0 0.0 5.0 5.0 20 10 40 eMDL = Estimated Method Detection Limit; RL = Reporting Limit **Please see narrative regarding eMDL calculations Quality Control Summary - Preparation Blank Summary (2) Analyte (pg/L) PBW1 PBW2 PBW3 PBW4 Mean StdDev eMDL* eMDL 10x RL 10x eMDL 25x RL 25x eMDL 100x RL 100x Mn (II) -0.23 0.21 -0.14 -0.27 -0.06 0.22 0.026 0.26 5.0 - - 2.6 50 Total Mn 0.06 0.07 0.14 0.07 0.09 0.04 0.005 - - 0.11 1.0 - - Diss Mn 0.099 0.116 0.065 1.320** 0.094 0.026 0.003 - - 0.077 1.0 - - eMDL = Estimated Method Detection Limit; RL = Reporting Limit *Please see narrative regarding eMDL calculations ***Preparation blank is a statistical outlier according to the Grubb's Test. Please see narrative. Page 16 of 21 Speciation Results for Duke Energy Project Name: Duke Energy Progress Cape Fear Contact: Peggy Kendall LIMS# J15060674 Date: July 31, 2015 Report Generated by: Jeremy Maute Brooks Rand Labs, LLC Quality Control Summary - Certified Reference Materials (1) Analyte (lag/L) CRM True Value Result Recovery As(III) LCS 5.000 4.752 95.0 As(V) LCS 5.000 4.805 96.1 MMAs LCS 5.073 4.990 98.4 DMAs LCS 3.625 3.519 97.1 Quality Control Summary - Certified Reference Materials (2) Analyte (lag/L) CRM True Value Result Recovery Fe(II) ICV 500 514.3 102.9 Total Fe TMDA-70.2 376 401.7 106.8 Mn (II) LCS 10.00 10.26 102.6 Total Mn TMDA-70.2 312 318.9 102.2 Page 17 of 21 Speciation Results for Duke Energy Project Name: Duke Energy Progress Cape Fear Contact: Peggy Kendall LIMS# J15060674 Date: July 31, 2015 Report Generated by: Jeremy Maute Brooks Rand Labs, LLC Quality Control Summary - Matrix Duplicates (1) Analyte (pg/L) Sample ID Rep 1 Rep 2 Mean RPD As(III) Batch QC 0.304 0.305 0.305 0.3 As(V) Batch QC ND (<0.076) ND (<0.076) NC NC MMAs Batch QC ND (<0.061) ND (<0.061) NC NC DMAs Batch QC ND (<0.064) ND (<0.064) NC NC ND = Not detected at the applied dilution NC = Value was not calculated due to one or more concentrations below the eMDL Page 18 of 21 Speciation Results for Duke Energy Project Name: Duke Energy Progress Cape Fear Contact: Peggy Kendall LIMS# J15060674 Date: July 31, 2015 Report Generated by: Jeremy Maute Brooks Rand Labs, LLC Qualitv Control Summary - Matrix Duplicates (2 Analyte (pg/L) Sample ID Rep 1 Rep 2 Mean RPD Fe(II) Batch QC 185.7 195.2 190.5 5.0 Total Fe Batch QC 247.3 247.3 247.3 0.0 Mn (II) Batch QC 1792 1843 1817 2.8 Total Mn MW-2 7311 7140 7225 2.4 ND = Not detected at the applied dilution NC = Value was not calculated due to one or more concentrations below the eMDL Page 19 of 21 Speciation Results for Duke Energy Project Name: Duke Energy Progress Cape Fear Contact: Peggy Kendall LIMS# J15060674 Date: July 31, 2015 Report Generated by: Jeremy Maute Brooks Rand Labs, LLC Quality Control Summary - Matrix Spike/Matrix Spike Duplicate (1) Analyte (lag/L) Sample ID Spike Conc MS Result Recovery Spike Conc MSD Result Recovery RPD As(III) Batch QC 20.00 19.29 94.9 20.00 19.07 93.8 1.2 As(V) Batch QC 20.00 18.85 94.2 20.00 18.50 92.5 1.9 DMAs Batch QC 20.98 19.69 93.9 20.98 19.65 93.7 0.2 Qualitv Control Summary - Matrix Spike/Matrix Spike Duplicate (2 Analyte (lag/L) Sample ID Spike Conc MS Result Recovery Spike Conc MSD Result Recovery RPD Fe(II) Batch QC 500.0 714.3 104.8 500.0 721.4 106.2 1.0 Total Fe Batch QC 500.0 717.1 93.9 500.0 719.4 94.4 0.3 Mn (II) Batch QC 500.0 2290 94.7 500.0 2288 94.1 0.8 Total Mn MW-2 1000 8401 117.6 1000 8197 97.2 2.5 0 00 L N W 0400 �y F H N 0 0 6J N m c V 4) U C E CD a)m a-).0 o 0 >. d O V � L) U > U U CO m aV.i N (/) :n :fi Vi i) �° ase as O O ai .p a0i' in C N U C Q LL g N LL G� u ON '3 0 O rl o Z Zc 16 v C4 00 00 O 5y O A ""` W.0 O Cyr /5 u 2 _ C Q Z U C C C ~= C COOO N Z Z Z G1 = M Z Z Z LU LU W O �, Z 0 k) J t n -00 J cq R� y �l F.C• � � Z H � � ^y❑� \ fie,,\. I- k REdh 1� O O b �,1,�.1"'01�--I�tI\,-, N 41 NO r-3 Page 10 of 21 .el-) -<7 .oTpa.�—= iontact Pcrson: kddress: Phone Number: Lax Number. pivuw� V)2483-3300 18804 Northereek Parkway f;ax (425) 483-9818 Bothell, WA 98011 1 Pro ect Nlsn2iter submitting of samples the client agrees to all terms and conditions ns set forth the quotation provided by the BRI, project manager. I f you are not familiar th the term and conditions associated with your Project, Please contact your ZL representative as soon as ssible 425 483-3300. nested Turn Around Time: ethod of Sam IS Deliv ouner Trackin Number: ® No Ismail Address: Confirmation of Sample Reception: Ica Pro ect Narrte: Pro ect Number: 1217608 Initials Requested Anal tes and Methods Comments PCB Number' 5 Bottle ID Date and Time Matrix Volume Preservative 1 As S field filtered Sample ID EDTA - Cr field filtered . t �, _ NH4OH/NH4SO4 Fe Spec field filtered r � '� " ��" assed HCI � � Mn S c field filtered ` None Mn S c unfiltered - None Se S field filtered None As S - field filtered . v - .. EDTA- 1 1- Cr VI field filtered NH4OHINH4SO4 Fe S c field filtered De ssed HCl Mn S c Feld filtered C. None Mn S ec unfiltered None Se S field filtered n None t: - Date/Time:_- - Wi`tU G C� Relinquished by' of C; (si9ni ,ram O"fe ! (prinq ( T Received by: (sign Comments: DaterTime: (Print) Temp: Relinquished by: (sign) Dawime: Received b : (sign) (print) Please account for each sample bottle as a seperate line item for verification purposes- soil (p,sediment (SID), tissue US' product (�}+ other (0) Matrix: Air, Freshwater (I , srawater (SW), groundwater (GVi�, wastewater (VUW), 5 Itcr 1.1 (Aped 2W5)