NC0003433_J15060669F_20150902

+ DUKE Analytical Laboratory
ENERGY
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone:[phone] Fax:[phone]
Order Summary Report
Order Number: J15060669
Project Name: CAPE FEAR - AB GW ASSESSMENT SPECIATION
Customer Name(s): Tim Hunsucker, Chris Suttell, Kathy Webb, John Toepfer
Customer Address:
Lab Contact: Peggy Kendall Phone:
peggy.kendall@d
Report Authorized By: Uke-energy.Com Date:
(Signature)
% eggy Kendall 2015.07.14
11:34:10-04'00'
Program Comments:
Please contact the Program Manager (Peggy Kendall) with any questions regarding this report.
Data Flags & Calculations:
7/14/2015
Page 1 of 30
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Sample ID's & Descriptions:
Collection
Sample ID Plant/Station Date and Time
Collected By
Sample Description
2015020242
Cape Fear
16-Jun-15 9:50 AM
Joshua Hunter
ABMW-5S
2015020243
Cape Fear
16-Jun-15 12:05 PM
Joshua Hunter
ABMW-3S
2015020244
Cape Fear
16-Jun-15 12:31 PM
Joshua Hunter
MW-10BR
2015020245
Cape Fear
16-Jun-15 10:20 AM
Joshua Hunter
ABMW-3BR
2015020246
Cape Fear
16-Jun-15 1:05 PM
Joshua Hunter
ABMW-3
2015020247
Cape Fear
16-Jun-15 4:04 PM
Joshua Hunter
CTMW-1
6 Total Samples
Page 2 of 30

Page 3 of 30
Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals Yes No
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits. ❑ Yes❑ No
All laboratory QA/QC requirements are acceptable.❑ Yes ❑ No
Report Sections Included:
U Job Summary Report
❑ Sample Identification
n Technical Validation of Data Package
❑ Analytical Laboratory Certificate of Analysis
❑ Analytical Laboratory QC Report
Sub -contracted Laboratory Results
❑ Customer Specific Data Sheets, Reports, & Documentation
❑ Customer Database Entries
66 Chain of Custody
[I/0] Electronic Data Deliverable (EDD) Sent Separately
Reviewed By: Peggy Kendall Date: 7/14/2015

Certificate of Laboratory Analysis Page 4 of 30
This report shall not be reproduced, except in full.
Order # J15060669
Site: ABMW-5S
Collection Date: 16-Jun-15 9:50 AM
Analyte Result Units Qualifiers RDL DF
Speciation of an Element - (Analysis Performed by Brooks Rand Labs LLC)
Vendor Parameter Complete
Sample #: 2015020242
Matrix: GW WW
Method Analysis Date/Time Analyst
Vendor Method V_BRAND

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060669
Site: ABMW-3S
Collection Date: 16-Jun-15 12:05 PM
Analyte Result Units Qualifiers RDL DF
Speciation of an Element - (Analysis Performed by Brooks Rand Labs LLC)
Vendor Parameter Complete
Sample #: 2015020243
Matrix: GW WW
Page 5 of 30
Method Analysis Date/Time Analyst
Vendor Method V_BRAND

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060669
Site: MW-10BR
Collection Date: 16-Jun-15 12:31 PM
Analyte Result Units Qualifiers RDL DF
Speciation of an Element - (Analysis Performed by Brooks Rand Labs LLC)
Vendor Parameter Complete
Sample #: 2015020244
Matrix: GW WW
Page 6 of 30
Method Analysis Date/Time Analyst
Vendor Method V_BRAND

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060669
Site: ABMW-3BR
Collection Date: 16-Jun-15 10:20 AM
Analyte Result Units Qualifiers RDL DF
Speciation of an Element - (Analysis Performed by Brooks Rand Labs LLC)
Vendor Parameter Complete
Sample #: 2015020245
Matrix: GW WW
Page 7 of 30
Method Analysis Date/Time Analyst
Vendor Method V_BRAND

Certificate of Laboratory Analysis Page 8 of 30
This report shall not be reproduced, except in full.
Order # J15060669
Site: ABMW-3
Collection Date: 16-Jun-15 1:05 PM
Analyte Result Units Qualifiers RDL DF
Speciation of an Element - (Analysis Performed by Brooks Rand Labs LLC)
Vendor Parameter Complete
Sample #: 2015020246
Matrix: GW WW
Method Analysis Date/Time Analyst
Vendor Method V_BRAND

Certificate of Laboratory Analysis Page 9 of 30
This report shall not be reproduced, except in full.
Order # J15060669
Site: CTMW-1
Collection Date: 16-Jun-15 4:04 PM
Analyte Result Units Qualifiers RDL DF
Speciation of an Element - (Analysis Performed by Brooks Rand Labs LLC)
Vendor Parameter Complete
Sample #: 2015020247
Matrix: GW WW
Method Analysis Date/Time Analyst
Vendor Method V_BRAND

Page 10 of 30
BRO�©KS
RAND
LABS
MEANINGFUL METALS DATA
July 13, 2015
Peggy Kendall
Duke Energy Analytical Laboratory
Mail Code MGO3A2 (Building 7405)
13339 Hagers Ferry Rd.
Huntersville, NC 28078
[phone]
Project: Duke Cape Fear Plant (LIMS# J15060669)
Ms. Kendall,
Attached is the report associated with six (6) aqueous samples submitted for chromium
speciation, arsenic speciation, iron speciation, and manganese speciation analyses on June 16,
2015. The samples were received in a sealed cooler at 0.0°C on June 17, 2015. Hexavalent
chromium analysis was performed by ion chromatography inductively coupled plasma dynamic
reaction cell mass spectrometry (IC-ICP-DRC-MS). All samples requesting iron speciation
analysis were analyzed by spectrophotometry. Mn (II) and arsenic speciation analyses were
performed via IC-ICP-CRC-MS. Mn(IV) analysis were performed via digestion and subsequent
analysis by inductively coupled plasma triple quadrupole mass spectrometry (ICP-QQQ-MS).
Any issues associated with the analyses are addressed in the following report.
If you have any questions, please feel free to contact me at your convenience.
Sincerely,
Russell Gerads
Business Development Director
Brooks Rand Labs, LLC
3958 6th Ave NW • Seattle, WA 98107 • T: 206-632-6206 • F: 206-632-6017 • www.brooksrand.com • [e-mail]

Page 11 of 30
Brooks Rand Labs, LLC
Report prepared for:
Peggy Kendall
Duke Energy Analytical Laboratory
Mail Code MGO3A2 (Building 7405)
13339 Hagers Ferry Rd.
Huntersville, NC 28078
Project: Duke Cape Fear Plant (LIMS# J15060669)
July 13, 2015
1. Sample Reception
Six (6) aqueous samples were submitted for chromium speciation arsenic speciation, iron
speciation, and manganese speciation analyses on June 16, 2015. All samples were received
in acceptable condition on June 17, 2015 in a sealed container at 0.0°C.
All samples were received in a laminar flow clean hood, void of trace metals contamination
and ultra -violet radiation, and were designated discrete sample identifiers. An aliquot of
each sample submitted for hexavalent chromium analysis was decanted into a clean
polypropylene tube. All hexavalent chromium sample fractions were stored in a secure
refrigerator maintained at a temperature of 4°C, until the analyses could be performed.
An aliquot of each sample submitted for arsenic speciation analysis was filtered (0.45µm)
into a polypropylene centrifuge tube; all filtrates and original bottles were then stored in a
secure, monitored refrigerator (maintained at a temperature of <6°C) until the analyses could
be performed.
The sample fractions requesting iron speciation analysis were stored in a secure, monitored
refrigerator (maintained at a temperature of <6°C) until the analyses could be performed.
An aliquot of each filtered sample submitted for manganese speciation analysis was decanted
into a polypropylene centrifuge tube for Mn(II) analysis. These fractions were stored in a
secure, monitored refrigerator (maintained at a temperature of <6°C) until the analyses could
be performed. Subsequently, the original bottles (filtered and unfiltered fractions) intended
for Mn speciation were preserved to pH < 2 with concentrated HNO3 and then stored in a
secure polyethylene container, known to be free from trace metals contamination, until the
digestion could be performed.

Page 12 of 30
2. Sample Preparation
All sample preparation is performed in laminar flow clean hoods known to be free from trace
metals contamination. All applied water for dilutions and sample preservatives are
monitored for contamination to account for any biases associated with the sample results.
Hexavalent Chromium Analysis by IC-ICP-DRC-MS Prior to analysis, an aliquot of each
sample was filtered with a syringe filter (0.45µm) and injected directly into a sealed
autosampler vial. No further sample preparation was performed as any chemical alteration of
a sample may shift the equilibrium of the system, resulting in changes in speciation ratios.
Arsenic Speciation Analysis by IC-ICP-CRC-MS An aliquot of each sample was filtered
directly into a sealed autosampler vial. No further sample preparation was performed as a
buffered EDTA solution was provided by Brooks Rand Labs for field -preservation of the
submitted samples.
Iron Speciation Analysis by Spectrophotometry No sample preparation was required as a de -
gassed HCL solution was provided by Brooks Rand Labs for field -preservation of the
submitted samples.
Manganese Mn(II Analysis by IC-ICP-CRC-MS An aliquot of each sample was filtered
(0.45µm) directly into an autosampler vial for Mn(II) analysis. No additional sample
preparation was performed as any chemical alteration of the samples may shift the
equilibrium of the system resulting in changes in speciation ratios.
Manganese Mn(IV) Analysis by ICP-QQQ-MS Each filtered and unfiltered sample submitted
for Mn speciation analysis was preserved with 1% HNO3 (v/v) upon sample receipt. Each
sample fraction was then further digested on a hotblock apparatus with aliquots of 50%
HNO3 (v/v) and 50% HCl (v/v), in accordance with the digestion procedure specified in EPA
Method 200.8. All resulting sample digests were analyzed for total manganese via
inductively coupled plasma triple quadrupole mass spectrometry (ICP-QQQ-MS).
3. Sample Analysis
All sample analysis is preceded by a minimum of a five -point calibration curve spanning the
entire concentration range of interest. Calibration curves are performed at the beginning of
each analytical day. All calibration curves, associated with each species of interest, are
standardized by linear regression resulting in a response factor. All sample results are
instrument blank corrected to account for any operational biases associated with the
analytical platform.
Prior to sample analysis, all calibration curves are verified using second source standards
which are identified as initial calibration verification standards (ICV).
Ongoing instrument performance is identified by the analysis of continuing calibration
verification standards (CCV) and continuing calibration blanks (CCB) at a minimum interval
of every ten analytical runs.

Page 13 of 30
Hexavalent Chromium Analysis by IC-ICP-DRC-MS Each sample for hexavalent chromium
analysis was analyzed by ion chromatography inductively coupled plasma dynamic reaction
cell mass spectrometry (IC-ICP-DRC-MS) on June 22, 2015. An aliquot of each sample is
injected onto an anion exchange column and mobilized by a basic (pH > 7) gradient. The
eluting chromium species are then introduced into a radio frequency (RF) plasma where
energy -transfer processes cause desolvation, atomization, and ionization. The ions are
extracted from the plasma through a differentially -pumped vacuum interface and travel
through a pressurized chamber (DRC) containing a reaction gas which preferentially reacts
with interfering ions of the same target mass to charge ratios (m/z). A solid-state detector
detects ions transmitted through the mass analyzer and the resulting current is processed by a
data handling system.
Retention times for each eluting species are compared to known standards for species
identification.
Arsenic Speciation Analysis by IC-ICP-CRC-MS Each sample was analyzed for arsenic
speciation via ion chromatography inductively coupled plasma collision reaction cell mass
spectrometry (IC-ICP-CRC-MS) on June 26, 2015. Aliquots of each sample are injected
onto an anion exchange column and eluted isocratically. The eluting arsenic species are then
introduced into a radio frequency (RF) plasma where energy -transfer processes cause
desolvation, atomization, and ionization. The ions are extracted from the plasma through a
differentially -pumped vacuum interface and travel through a pressurized chamber (CRC)
containing a specific collision gas. Polyatomic interferences, due to their inherently larger
size, collide more frequently with the collision gas and therefore may be separated from the
analyte of interest via kinetic energy discrimination (KED). A solid-state detector detects
ions transmitted through the mass analyzer on the basis of their mass -to -charge ratio (m/z),
and the resulting current is processed by a data handling system.
Retention times for each eluting species are compared to known standards for species
identification.
Iron Speciation Analysis by SpectrophotometrX All samples submitted for Fe speciation
quantification were analyzed on June 17, 2015, and in accordance with the scientifically
accepted method outlined by:
Stookey, L.L., (1970). "Ferrozine - A new spectrophotometric reagent for iron",
Anal.Chem., 42:779-81.
Manganese Mn(I) Analysis by IC-ICP-CRC-MS All samples for Mn(II) analysis were
analyzed by ion chromatography inductively coupled plasma collision reaction cell mass
spectrometry (IC-ICP-CRC-MS) on June 29, 2015. Aliquots of each sample are injected
onto an anion exchange column and mobilized by an acidic (pH < 7) gradient. An ion
pairing agent provides a dynamic ion exchange mechanism for the cationic manganese
species on the chromatographic column. The differences in the affinity of manganese species
towards the ion pair agent and the column results in separation. The eluting selenium species

Page 14 of 30
are then introduced into a radio frequency (RF) plasma where energy -transfer processes
cause desolvation, atomization, and ionization. The ions are extracted from the plasma
through a differentially -pumped vacuum interface and travel through a pressurized chamber
(CRC) containing a reaction gas which preferentially reacts with interfering ions of the same
target mass to charge ratios (m/z). A solid-state detector detects ions transmitted through the
mass analyzer and the resulting current is processed by a data handling system.
Retention times for each eluting species are compared to known standards for species
identification.
Manganese Mn(IV) Analysis by ICP-000-MS All samples submitted for Mn speciation
quantitation were analyzed by inductively coupled plasma triple quadrupole mass
spectrometry (ICP-QQQ-MS) on July 1, 2015. Aliquots of each sample digest are introduced
into a radio frequency (RF) plasma where energy -transfer processes cause desolvation,
atomization, and ionization. The ions are extracted from the plasma through a differentially -
pumped vacuum interface and travel through an initial quadrupole (Q 1), which filters the
target masses prior to their entrance into a second chamber. The second chamber contains
specific reactive gasses or collision gasses that preferentially react either with interfering ions
of the same target mass to charge ratios (m/z) or with the target analyte, producing an
entirely different mass to charge ratio (m/z) which can then be differentiated from the initial
interferences. The ions then exit the collision/reaction cell into and additional quadrupole
(Q2). A solid-state detector detects ions transmitted through the mass analyzer, on the basis
of their mass -to -charge ratio (m/z), and the resulting current is processed by a data handling
system.
4. Analytical Issues
No significant analytical issues were encountered. All quality control parameters associated
with the samples were within acceptance limits.
Unknown arsenic species were present in various samples associated with the arsenic
speciation analysis resulting in late elution into following sample injections. The late eluting
peaks did not affect the target arsenic species; however, differentiation between late eluting
peaks and other unknown arsenic species for a given sample could not be accomplished.
Mn(IV) is quantified by analyzing the water samples for total Mn and dissolved Mn. Mn(IV)
is operationally defined as the difference between the filtered and unfiltered total Mn
concentrations, since it is thermodynamically favored to be in the form of a precipitate.
The estimated method detection limit (eMDL) for hexavalent chromium is generated from
replicate analyses of the lowest standard in the calibration curve.
The eMDL values for arsenite, arsenate, and dimethylarsinic acid are generated using the
standard deviation of replicate analyses of the lowest standard in the calibration curve. The
eMDL for monomethylarsonic acid is calculated from the average eMDL of the three arsenic

Page 15 of 30
species contained in the calibration (i.e., arsenite, arsenate, and dimethylarsinic acid); the
calibration and CCVs do not contain monomethylarsonic acid due to impurities in this
standard which would bias the results for other arsenic species.
The eMDL value for Fe(II) and total recoverable Fe was set at 5 based on the sensitivity of
the instrument.
The eMDL for Mn(II) has been generated from replicate analyses of the lowest standard in
the calibration curve.
The eMDL values for Mn(IV) been calculated using the standard deviation of the method
blanks prepared and analyzed concurrently with the submitted samples.
If you have any questions or concerns regarding this report, please feel free to contact me.
Sincerely,
Russell Gerads
Business Development Director
Brooks Rand Labs, LLC

Page 16 of 30
Speciation Results for Duke Energy
Project Name: Duke Cape Fear Plant
Contact: Jay Perkins
LIMS# J15060669
Date: July 13, 2015
Report Generated by: Russell Gerads
Brooks Rand Labs, LLC
Sample Results (6)
Sample ID Cr(VI)
ABMW-5S ND (<0.005)
ABMW-3S
MW-10BR
ABMW-3BR
ABMW-3
CTMW-1
8.31
0.023
ND (<0.005)
0.015
ND (<0.005)
All results reflect the applied dilution and are reported in pg/L
ND = Not detected at the applied dilution

Page 17 of 30
Speciation Results for Duke Energy
Project Name: Duke Cape Fear Plant
Contact: Jay Perkins
LIMS# J15060669
Date: July 13, 2015
Report Generated by: Russell Gerads
Brooks Rand Labs, LLC
Sample Results (6)
Sample ID
As(III)
As(V)
MMAs
ABMW-5S
0.561
0.262
ND (<0.053)
ABMW-3S
ND (<0.049)
0.224
0.100
MW-10BR
1.36
0.228
ND (<0.053)
ABMW-3BR
0.772
ND (<0.028)
ND (<0.053)
ABMW-3
62.0
235
ND (<0.053)
CTMW-1
ND (<0.049)
0.244
ND (<0.053)
All results reflect the applied dilution and are reported in pg/L
MMAs = monomethylarsonic acid
DMAs = dimethylarsinic acid
Unknown As Species = Total concentration of all unknown As species observed by
NA = Not available. Please see narrative.

Page 18 of 30
Speciation Results for Duke Energy
Project Name: Duke Cape Fear Plant
Contact: Jay Perkins
LIMS# J15060669
Date: July 13, 2015
Report Generated by: Russell Gerads
Brooks Rand Labs, LLC
Sample Results (2
Sample ID
Fe(II)
Fe(III)*
Mn (II)
Mn(IV)**
ABMW-5S
111000
3220
33000
60.8
ABMW-3S
14.0
33.5
ND (<0.26)
ND (<0.07)
MW-10BR
ND (< 5.0)
ND (<5.0)
212
ND (<0.07)
ABMW-3BR
805
123
391
110
ABMW-3
21.0
17.2
114
6.08
CTMW-1
98.0
70.7
148
175
All results reflect the applied dilution and are reported in pg/L
ND = Not detected at the applied dilution
NR = Analysis not requested
*Fe(III) operationally defined as the difference between total recoverable Fe and Fe(II)
*Mn(IV) operationally defined as the difference between total and dissolved Mn

Page 19 of 30
Speciation Results for Duke Energy
Project Name: Duke Cape Fear Plant
Contact: Jay Perkins
LIMS# J15060669
Date: July 13, 2015
Report Generated by: Russell Gerads
Brooks Rand Labs, LLC
Quality Control Summary - Preparation Blank Summary (1)
Analyte (Ng/L) PBW1 PBW2 PBW3 PBW4 Mean StdDev eMDL* eMDL 5x RL 5x
Cr(VI) -0.001 0.000 0.001 0.002 0.001 0.001 0.001 0.005 0.050
eMDL = Estimated Method Detection Limit; RL = Reporting Limit
*Please see narrative regarding eMDL calculations
Quality Control Summary - Preparation Blank Summary (2)
Analyte (Ng/L)
PBW1
PBW2
PBW3
PBW4
Mean
StdDev
eMDL*
eMDL 10x
RL 10x
As(III)
0.000
0.000
0.000
0.000
0.000
0.000
0.005
0.049
0.20
As(V)
0.000
0.000
0.000
0.000
0.000
0.000
0.003
0.028
0.20
MMAs
0.000
0.000
0.000
0.000
0.000
0.000
0.005
0.053
0.20
DMAs
0.000
0.000
0.000
0.000
0.000
0.000
0.008
0.083
0.21
eMDL = Estimated Method Detection Limit; RL = Reporting Limit
*Please see narrative regarding eMDL calculations

Page 20 of 30
Speciation Results for Duke Energy
Project Name: Duke Cape Fear Plant
Contact: Jay Perkins
LIMS# J15060669
Date: July 13, 2015
Report Generated by: Russell Gerads
Brooks Rand Labs, LLC
Qualitv Control Summary - Preparation Blank Summary (3
Analyte (lag/L) PBW1 PBW2 PBW3 PBW4 Mean StdDev eMDL** eMDL 1x RL 1x
Fe(II) 0.0 0.0 0.0 0.0 0.0 0.0 5.0 5.0 20
Total Fe -5.0 -5.0 -5.0 -5.0 -5.0 0.0 5.0 5.0 20
eMDL = Estimated Method Detection Limit; RL = Reporting Limit
**Please see narrative regarding eMDL calculations
Quality Control Summary - Preparation Blank Summary (3)
Analyte (lag/L)
PBW1
PBW2
PBW3
PBW4
Mean
StdDev
eMDL* eMDL 10x RL 10x eMDL 25x RL 25x
Mn (II)
-0.23
0.21
0.00
-0.27
-0.01
0.22
0.026 0.26 5.0 - -
Total Mn
0.110
0.068
0.074
0.070
0.084
0.020
0.002 - - 0.06 1.0
Diss Mn
0.020
0.076
0.040
0.056
0.045
0.024
0.003 - - 0.07 1.0
eMDL = Estimated Method Detection Limit; RL = Reporting Limit
*Please see narrative regarding eMDL calculations

Page 21 of 30
Speciation Results for Duke Energy
Project Name: Duke Cape Fear Plant
Contact: Jay Perkins
LIMS# J15060669
Date: July 13, 2015
Report Generated by: Russell Gerads
Brooks Rand Labs, LLC
Quality Control Summary - Certified Reference Materials (1)
Analyte (lag/L) CRM True Value Result Recovery
Cr(VI) LCS 2.002 1.967 98.2
Quality Control Summary - Certified Reference Materials (2)
Analyte (lag/L)
CRM
True Value
Result
Recovery
As(III)
LCS
5.00
5.04
100.9
As(V)
LCS
5.00
4.58
91.6
MMAs
LCS
5.07
5.73
113.0
DMAs
LCS
3.63
3.51
96.8
Quality Control Summary - Certified Reference Materials (3
Analyte (lag/L)
CRM
True Value
Result
Recovery
Fe(II)
ICV
500.0
519.1
103.8
Total Fe
TMDA-70
369.0
400.2
108.5
Mn (II)
LCS
10.00
10.26
102.6
Total Mn
TMDA-70.2
312
295
94.5
Diss Mn
TMDA-70.2
312
301
96.6

Page 22 of 30
Speciation Results for Duke Energy
Project Name: Duke Cape Fear Plant
Contact: Jay Perkins
LIMS# J15060669
Date: July 13, 2015
Report Generated by: Russell Gerads
Brooks Rand Labs, LLC
Quality Control Summary - Matrix Duplicates (1)
Analyte (pg/L) Sample ID Rep 1 Rep 2 Mean RPD
Cr(VI) Batch QC 0.006 0.005 0.005 13.9
ND = Not detected at the applied dilution
NC = Value was not calculated due to one or more concentrations below the eMDL
Quality Control Summary - Matrix Duplicates (2)
Analyte (pg/L)
Sample ID
Rep 1
Rep 2
Mean
RPD
As(III)
Batch QC
0.135
0.075
0.105
56.9*
As(V)
Batch QC
ND (<0.028)
ND (<0.028)
NC
NC
MMAs
Batch QC
ND (<0.053)
ND (<0.053)
NC
NC
DMAs
Batch QC
ND (<0.083)
ND (<0.083)
NC
NC
ND = Not detected at the applied dilution
NC = Value was not calculated due to one or more concentrations below the eMDL

Page 23 of 30
Speciation Results for Duke Energy
Project Name: Duke Cape Fear Plant
Contact: Jay Perkins
LIMS# J15060669
Date: July 13, 2015
Report Generated by: Russell Gerads
Brooks Rand Labs, LLC
Qualitv Control Summary - Matrix Duplicates (2
Analyte (pg/L)
Sample ID
Rep 1
Rep 2
Mean
RPD
Fe(II)
ABMW-5S
110500
111400
110950
0.8
Total Fe
ABMW-5S
113700
113700
113700
0.0
Mn (II)
Batch QC
1792
1843
1817
2.8
Total Mn
Batch QC
170.0
189.3
179.6
10.8
Diss Mn
Batch QC
178.2
171.6
174.9
3.8

Page 24 of 30
Speciation Results for Duke Energy
Project Name: Duke Cape Fear Plant
Contact: Jay Perkins
LIMS# J15060669
Date: July 13, 2015
Report Generated by: Russell Gerads
Brooks Rand Labs, LLC
Qualitv Control Summary - Matrix Spike/Matrix Spike Duplicate 0
Analyte (lag/L)
Sample ID
Spike Conc
MS Result
Recovery
Spike Conc
MSD Result
Recovery
RPD
Cr(VI)
Batch QC
5.000
4.523
90.3
5.000
4.552
90.9
0.6
Quality Control Summary - Matrix Spike/Matrix
Spike Duplicate
(2)
Analyte (lag/L)
Sample ID
Spike Conc
MS Result
Recovery
Spike Conc
MSD Result
Recovery
RPD
As(III)
As(V)
DMAs
Batch QC
Batch QC
Batch QC
20.00
20.00
20.98
18.53
18.22
18.31
92.1
91.1
87.3
20.00
20.00
20.98
18.34
18.71
17.58
91.2
93.5
83.8
1.1
2.7
4.1
Quality Control Summary - Matrix Spike/Matrix
Spike Duplicate
(3)
Analyte (lag/L)
Sample ID
Spike Conc
MS Result
Recovery
Spike Conc
MSD Result
Recovery
RPD
Fe(II)
Total Fe
ABMW-5S
ABMW-5S
100000
100000
199500
201000
88.6
87.3
100000
100000
200000
191900
89.1
78.2
0.3
4.6
Mn (II)
Total Mn
Diss Mn
Batch QC
Batch QC
Batch QC
500.0
1000
1000
2290
1195
1188
94.7
101.6
101.3
500.0
1000
1000
2288
1116
1131
94.1
93.6
95.7
0.8
6.9
4.9

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t •� 1880-1 "orthcreek : arkvvay Phone (4. ,) 183-3300
Bothell, WA 98011 — Fax [phone]
Comi and Name: � � err _ BRL Pru'zctr. crcr+^t• >\Q�iire
Contact Person: .� , By submitting of samples the client agrees to all terms and conditions set forth
Address:
Phone Number, - 72� 7c?
Fax Number:
Email Address:
r-
Project Name:
Project Number:
PO Number:
Sample ID -26!15b1114AL'
A;', S5
A, = <�
Relinquished by: (sign
Received by: (s!gn)Z
in the quotation provided by the BRL project manager. If you are not familiar
with the term and conditions associated with your project, please contact your
BRL re resentativc as soon as ossible 425 483-3300.
Requested Turn Around Time:
Method of Sample Delivery:
1217608
: rw-
Courier Tracking Number:
Confirmation of Sample Reception: Yes NO
Bottle ID
Date and Time
Matrix
Volume
Preservative
Initials
Requested Analytes and Methods
Comments
field filtered
EDTA - 1
NH40HiNH4SO4
De assed HCI
None —
None
None
1Z
E�
K 3,
As Spec;
Cr(VQ
Fe Spec —
Mn Spec
Mn Spec_.—
Se Spec
field filtered _
field filtered
field filtered
unfiltered
field filtered
3
(^� ; y
5.
rs' o�y
, 1 115
/bpi �;q�c
77, - 7- 115
EDTA- 1
As Spec
field filtered
NH40H/NH4SO4
Cr(VI)
field filtered
-
De assed HCI
Fe Spec
field filtered
None
Mn S ec
field filtered
11
^3
None
. Ninnee
Mn Spec
Sec
unfiltered
field filtered
f ✓ (print) (� D�ate(Time: f�
aL—(print)Z Dateffime:—�,-F�-..�e� �'t; V
Comments:
A.
Temp: " U C
Comments:
Relinquished by: (sign) (print) Date/Time:
Received by: (sign) (print) DaterTime:
Please account for each sample be do as a seperate line item for verification purposes.
Matrix: Air, Freshwater (I71OV), seawater (SW), groundwater (Gn wastewater (WVV), soil (SL), sediment (SD), tissue (fS), product (I'), oilier (0)
�Ob�t41�
1'ev i.I (April M05)

SarC�i9�J'7�.
R A!'ti J
18864 Nor-thaeek Park way
Bothell, WA 98011
Phone (4. Q 83. 3 irk
Fax [phone]
Company Name. ` ; n Tyr
t 4:1stt r: eremy Ms»tr
Contact Person: 40. PK
1 h
By submitting of samples the client agrees to all terms and conditions set forth
in the quotation provided by the BRL project manager. If you are not familiar
with the tenet and conditions associated with your project, please contact your
BRL representative as soon as possible 425 483-3300.
Address;
Phone Number. ,_ 7 ' -2>7C ' 0 & `'t 3,
Fax Number.
Requested Turn Around Time:
Email Address: K,1
6L>c0. Cates''
Method of Sam le Delivery
Project Nana:.
s �� Cyr_.
--
Courier Tracking Number:
Project Number:
PO Number:
1217608
Con6.:nation of Sample Reception: Yes
No
Sample ID
Bottle ID
Date and Time
Matrix
Volume
Preservative.
Inivals
Requested Analytes and Methods
Comments
EDTA - 1
As Spec
field filtered
NH40HiNH4SO4
Cr VI
field filtered _
Degassed HCl
Fe Spec
field filtered
1 w -- to 6 �`
, i
`!
None
Mn Spec
field filtered
�, to&z
None
Mn Spec
unfiltered
to fSr.
!
< <-" r
None
Se Spec
field filtered
JOS
A
( ems' to +Z
isw
i �
EDTA - 1
As Spec
field filtered —
3
NH40H/NH4SO4
Cr VI
field filtered
leis tc a.c:
Degassed HCI
Fe S' ec
field filtered
V - -S (sl:
g 6 31
�4644- 3
None
Mn Spec
field filtered _ T
sew - ty C'
0 >a b Ito
' —
None
Mn Spec
unfiltered
Se Spec
Field filtered
Relinquished by: (sign)
by: (sig
j(print)
(print) u
laf/v �^
r Date/Time:..&46 t!
Date/Time: I I
j (
Comments:
Temp:
�
, ,(
LReceived
elinquished by: (sign)
[Received by: (sign)
(print)
(print)
Date/Time:
Date/Time: _
Comments:
Temp:
Please account for each sample boadc as a seperate line item for verification purposes.
Matrix: Air, Freshwater OzW), seawater (SW), groundwater (GW), wastewater (WW), soil (SL), sediment (SD), tissue M), product (I'), ot4er (0)
1'ev i.l (April 2005)

Page so of
A�
Qt
1880,1 1`!orthereck'Parkv,ay Phone (4.- q �ts�-»•,�
Bothell, WA 98011 Fax [phone]
Mg4NtMMI7Il McT�4.l•Yt'I'�
Company Name:
�•
BRL Pr •t .:ia u er: tercmr Moore
By of samples the client agrees to all terms and conditions set forth
Contact Person:
submitting
in the quotation provided by the BRL project manager. If you are not familiarr
with the term and conditions associated with your project, please contact your
BRL representative as soon as possible 425 483-3300.
Address: 1 � k a ; - 't-" t eT
Phone Number: '!'? ' 37t+ ""t 7
TurnRe nested Turn Around Time:
Fax Number.
Email Address: `� `t "" Q '� "
, `_ " "
'
Method of Sample Delivery
Project Name: i Cr.c
'' rv� "
'c �'es� r
Courier Tracking Number.
Sample Reception: No
Project Number: I t s b - !G
__
Confu-:nation of Yes :3
PO Number. 1217608
Sam le ID,?rslSc,2-0Z`/49
Bottle ID
Date and Time
Matnx
Volume
Preservative
Initials
Re nested Anal tes and Methods
Comments
. ,— )
EDTA - 1
�, �.. �
A& S G
field filtered
` w �j
�� s
r4wF
�tjj5 ice,
NH40HiNH4SO4
COW
field filtered i
A1�,+.w - 3
De assed HCl
Fe Spec _field
filtered
_
None
Mn Spec
field filtered
None
Mn Spec
unfiltered
ff $, -
None
Se Spec
field filtered
TM w . l
'
I
EDTA - 1
' `'
As Spec.
field filtered
13`376 i�
NH40H/NH4SO4
Cr(VI)
field filtered
C' %v -
( TM I
9.( y
4
Degas HC
Fe Specfield
filtered
T w _
Y(�
None
Mn Spec_
field filtered
None
Mn Spec
unfiltered
NoneSe
S e~c
field filtered
(print) ux, µn. r
Date/Time: 6 (a 1`�
Comments:
Relinquished by: (sign)
Received by: (si
aj.L
rint �-,:yC� �.1
(p ) �` �^" `'
Dateffime: (! 0
^
V L
_
Temp:
Comments:
[Relinquished by: (sign)
(print)
DatefTime:......:,.,,w
ti.I• �et.,.,u
forintl
Date/Time:
i emp:
Please account for each sample bode as a seperate line item for veriEuation purposes.
Matrix: Air, f ceshwater (FVt ), seawater (SW), groundwater (GWt wastewater (WVt7, soil (SL), sediment (Sll), tissue (I S), product (I'), other (0)
11ev iA (Ap,il2(N)5)