The URL can be used to link to this page

Home My WebLink AboutNC0003433_J15060659 Report_20150902+ DUKE Analytical Laboratory 1 of55 ENERGY Order Number: Project Name: Customer Name(s): Customer Address: Lab Contact: Report Authorized By: (Signature) Program Comments: 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone:980-875-5245 Fax:980-875-4349 Order Summary Report J15060659 CAPE FEAR - AB GW ASSESSMENT SOIL Tim Hunsucker, Chris Suttell, Kathy Webb, John Toepfer Margaret Galvin -Karr Margaret Galvin -Karr MXG4644 (101161) 2015.07.15 08:28:50 -04'00' Phone: 980-875-5219 Date: Please contact the Program Manager (Margaret Galvin -Karr) with any questions regarding this report. Data Flags & Calculations: 7/15/2015 Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Sample ID's & Descriptions: 2 of 55 Sample ID Plant/Station Collection Date and Time Collected By Sample Description 2015020192 Cape Fear 18-Jun-15 9:15 AM Illegible MW-21SB (0-2) 2015020193 Cape Fear 18-Jun-15 9:35 AM Illegible ERB-37 2 Total Samples 3 of 55 Technical Validation Review Checklist: COC and .pdf report are in agreement with sample totals Yes No and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. ❑ Yes❑ No All laboratory QA/QC requirements are acceptable.❑ Yes ❑ No Report Sections Included: U Job Summary Report ❑ Sample Identification n Technical Validation of Data Package ❑ Analytical Laboratory Certificate of Analysis ❑ Analytical Laboratory QC Report Sub -contracted Laboratory Results ❑ Customer Specific Data Sheets, Reports, & Documentation ❑ Customer Database Entries 66 Chain of Custody [I/0] Electronic Data Deliverable (EDD) Sent Separately Reviewed By: Margaret Galvin -Karr Date: 7/15/2015 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060659 Site: MW-21 SB (0-2) Collection Date: 18-Jun-15 9:15 AM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 4 of 55 Sample #: 2015020192 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Site: ERB-37 Collection Date: 18-Jun-15 9:35 AM Certificate of Laboratory Analysis 5 of 55 This report shall not be reproduced, except in full. Order # J15060659 Sample #: 2015020193 Matrix: SOIL Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE -- Additional Information -- Associated sample concentration for boron is less than 5 times the concentration in the blank and the result is suspect. The associated sample concentration for the sodium is above 5 times the blank concentration but less than 10 times so the result should be considered an upper limit of the true concentration. MG-K 7/15/2015 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kigc&y&ie. Suite 100 Huntersville, INC 28078 (704)875-9092 July 14, 2015 Marge Galvin -Karr RE: Project: J 15060659 Pace Project No.: 92255296 Dear Marge Galvin -Karr: Enclosed are the analytical results for sample(s) received by the laboratory on June 19, 2015. The results relate only to the samples included in this report. Results reported herein conform to the most current TN standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Herring kevin.herring@pacelabs.com HORIZON Database Administrator Enclosures cc: Marge Galvin -Karr, Duke Energy Program Manager, Duke Energy Mary Ann Ogle, Duke Energy Rodney Wilke, Duke Energy �e PIC REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. BRAT, Page 1 of 49 lacmnalyfica( www.pacelabs.com Pace Analytical Services, Inc. 9800 Kinfb6ge. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15060659 Pace Project No.: 92255296 Minnesota Certification IDs 1700 Elm Street SE Suite 200, Minneapolis, MN 55414 A21-A Certification #: 2926.01 Alaska Certification #: UST-078 Alaska Certification #MN00064 Alabama Certification #40770 Arizona Certification #: AZ-0014 Arkansas Certification #: 88-0680 California Certification #: 01155CA Colorado Certification #Pace Connecticut Certification #: PH-0256 EPA Region 8 Certification #: 8TMS-L Florida/NELAP Certification #: E87605 Guam Certification #:14-008r Georgia Certification #: 959 Georgia EPD #: Pace Idaho Certification #: MN00064 Hawaii Certification #MN00064 Illinois Certification #: 200011 Indiana Certification#C-MN-01 Iowa Certification #: 368 Kansas Certification #: E-10167 Kentucky Dept of Envi. Protection - DW #90062 Kentucky Dept of Envi. Protection - WW #:90062 Louisiana DEQ Certification #: 3086 Louisiana DHH #: LA140001 Maine Certification #: 2013011 Maryland Certification #: 322 Michigan DEPH Certification #: 9909 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification #: 41320 Connecticut Certification #: PH-0216 Delaware Certification: FL NELAC Reciprocity Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Green Bay Certification IDs 1241 Bellevue Street, Green Bay, WI 54302 Florida/NELAP Certification #: E87948 Illinois Certification #: 200050 Kentucky Certification #: 82 Louisiana Certification #: 04168 Minnesota Certification #: 055-999-334 CERTIFICATIONS Minnesota Certification #: 027-053-137 Mississippi Certification #: Pace Montana Certification #: MT0092 Nevada Certification #: MN_00064 Nebraska Certification #: Pace New Jersey Certification #: MN-002 New York Certification #: 11647 North Carolina Certification #: 530 North Carolina State Public Health #: 27700 North Dakota Certification #: R-036 Ohio EPA#: 4150 Ohio VAP Certification #: CL101 Oklahoma Certification #: 9507 Oregon Certification #: MN200001 Oregon Certification #: MN300001 Pennsylvania Certification #: 68-00563 Puerto Rico Certification Saipan (CNMI) #:MP0003 South Carolina #:74003001 Texas Certification #: T104704192 Tennessee Certification #: 02818 Utah Certification #: MN000642013-4 Virginia DGS Certification #: 251 Virginia/VELAP Certification #: Pace Washington Certification #: C486 West Virginia Certification #: 382 West Virginia DHHR #:9952C Wisconsin Certification #: 999407970 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 Nevada Certification: FL NELAC Reciprocity New Hampshire Certification #: 2958 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 North Carolina Certification #: 12710 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FLO1264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity North Dakota Certification #: R-150 South Carolina Certification #: 83006001 Texas Certification #: T104704529-14-1 US Dept of Agriculture #: S-76505 Wisconsin Certification #: 405132750 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 North Carolina Drinking Water Certification #: 37712 Florida/NELAP Certification #: E87648 North Carolina Wastewater Certification #: 40 Massachusetts Certification #: M-NC030 South Carolina Certification #: 99030001 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 2 of 49 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kigg8y&&e. Suite 100 Huntersville, NC 28078 (704)875-9092 CERTIFICATIONS Project: J15060659 Pace Project No.: 92255296 Asheville Certification IDs West Virginia Certification #: 356 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 3 of 49 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kigc&y&ie. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: J15060659 Pace Project No.: 92255296 Lab ID Sample ID Matrix Date Collected Date Received 92255296001 92255296002 2015020192 2015020193 Solid Water 06/18/15 09:15 06/18/15 09:35 06/19/15 13:00 06/19/15 13:00 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 4 of 49 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffli�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: J15060659 Pace Project No.: 92255296 Lab ID Sample ID Method Analysts Analytes Reported Laboratory 92255296001 2015020192 EPA 6010 TAP 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA 6020A TT3 24 PASI-M EPA 7470A JDD 1 PASI-M EPA 7471 CKJ 1 PASI-O ASTM D2974-87 MLO 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 300.0 AES2 1 PASI-A EPA 353.2 DMN 1 PASI-A SM 4500-CI-E SER 1 PASI-A EPA 9056 KHC 2 PASI-O EPA 9056 KHC 1 PASI-O EPA 9060 Modified TJJ 4 PASI-G 92255296002 2015020193 EPA 6020A TT3 24 PASI-M EPA 7470A LMW 1 PASI-M REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 5 of 49 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 fflini c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15060659 Pace Project No.: 92255296 Lab Sample ID Client Sample ID Method Parameters SUMMARY OF DETECTION Result Units Report Limit Analyzed 92255296001 2015020192 EPA 6010 Aluminum 1610 mg/kg 41.0 07/14/15 12:28 EPA 6010 Barium 87.5 mg/kg 4.1 07/14/15 12:28 EPA 6010 Calcium 2490 mg/kg 205 07/14/15 12:28 EPA 6010 Chromium 3.1 mg/kg 2.0 07/14/15 12:28 EPA 6010 Copper 8.3 mg/kg 2.0 07/14/15 12:28 EPA 6010 Iron 5980 mg/kg 16.4 07/14/15 12:28 EPA 6010 Magnesium 393 mg/kg 205 07/14/15 12:28 EPA 6010 Manganese 781 mg/kg 2.0 07/14/15 12:28 EPA 6010 Nickel 1.8J mg/kg 2.0 07/14/15 12:28 EPA 6010 Potassium 338J mg/kg 410 07/14/15 12:28 EPA 6010 Strontium 25.0 mg/kg 4.1 07/14/15 12:28 EPA 6010 Zinc 20.6 mg/kg 8.2 07/14/15 12:28 EPA 6020 Arsenic 40.1 mg/kg 8.2 07/14/15 13:09 EPA 6020 Lead 13.1 mg/kg 8.2 07/14/15 13:09 EPA 6020 Selenium 5.7J mg/kg 8.2 07/14/15 13:09 EPA 6020 Vanadium 8.8 mg/kg 8.2 07/14/15 13:09 EPA 6020A Aluminum 406 ug/L 100 07/08/15 07:59 EPA 6020A Arsenic 10.9 ug/L 5.0 07/08/15 07:59 EPA 6020A Barium 11.8J ug/L 100 07/08/15 07:59 EPA 6020A Boron 75.5 ug/L 50.0 07/08/15 07:59 EPA 6020A Calcium 1880 ug/L 400 07/08/15 07:59 EPA 6020A Copper 3.2J ug/L 10.0 07/08/15 07:59 EPA 6020A Iron 724 ug/L 500 07/08/15 07:59 EPA 6020A Lead 2.5 ug/L 1.0 07/08/15 07:59 EPA 6020A Magnesium 370 ug/L 100 07/08/15 07:59 EPA 6020A Manganese 45.8 ug/L 5.0 07/08/15 07:59 EPA 6020A Potassium 1000 ug/L 500 07/08/15 07:59 EPA 6020A Selenium 2.5J ug/L 5.0 07/08/15 07:59 EPA 6020A Sodium 5440 ug/L 500 07/08/15 07:59 EPA 6020A Strontium 12.2 ug/L 5.0 07/08/15 07:59 EPA 6020A Thallium 0.30J ug/L 1.0 07/08/15 07:59 EPA 7470A Mercury 0.14J ug/L 0.20 07/07/15 21:45 EPA7471 Mercury 0.75 mg/kg 0.064 07/11/1517:22 ASTM D2974-87 Percent Moisture 36.6 % 0.10 07/14/15 07:57 EPA 9045 pH at 25 Degrees C 5.2 Std. Units 0.10 06/22/15 15:35 EPA 300.0 Sulfate 16.4 mg/L 3.2 07/02/15 12:34 EPA 353.2 Nitrogen, Nitrate 1.1 mg/L 0.32 07/06/15 15:40 EPA 9056 Sulfate 285J mg/kg 382 07/12/15 21:38 EPA 9060 Modified RPD% 1.9 % 0.10 07/07/15 16:50 EPA 9060 Modified Total Organic Carbon 43100 mg/kg 4470 07/07/15 16:50 EPA 9060 Modified Total Organic Carbon 42300 mg/kg 4580 07/07/15 16:56 EPA 9060 Modified Mean Total Organic Carbon 42700 mg/kg 4520 07/07/15 16:50 92255296002 2015020193 EPA 6020A Aluminum 4.2J ug/L 10.0 07/06/15 16:12 EPA 6020A Barium 3.0 ug/L 0.30 07/06/15 16:12 EPA 6020A Iron 14.5J ug/L 50.0 07/06/15 16:12 EPA 6020A Manganese 0.41J ug/L 0.50 07/06/15 16:12 REPORT OF LABORATORY ANALYSIS 1g D4 B H1 D3 Qualifiers This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 6 of 49 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffli�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060659 Pace Project No.: 92255296 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: July 14, 2015 General Information: 1 sample was analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/25192 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92257635001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1266959) • Aluminum • Iron • MSD (Lab ID: 1266960) • Aluminum • Barium • Iron • Manganese Additional Comments: Batch Comments: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. • QC Batch: ICP / 15328 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 7 of 49 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffli�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060659 Pace Project No.: 92255296 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: July 14, 2015 General Information: 1 sample was analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/25193 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92257635001 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • MS (Lab ID: 1266963) • Antimony • Cadmium • Cobalt • Vanadium • MSD (Lab ID: 1266964) • Antimony • Cobalt • Vanadium Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 8 of 49 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffiic&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060659 Pace Project No.: 92255296 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: July 14, 2015 Batch Comments: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. • QC Batch: ICPM / 10219 Analyte Comments: QC Batch: MPRP/25193 N2: The lab does not hold TNI accreditation for this parameter. •2015020192 (Lab ID:92255296001) • Antimony • BLANK (Lab ID: 1266961) • Antimony • LCS (Lab ID: 1266962) • Antimony • MS (Lab ID: 1266963) • Antimony • MSD (Lab ID: 1266964) • Antimony REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 9 of 49 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffli�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060659 Pace Project No.: 92255296 Method: EPA 6020A Description: 6020A MET ICPMS Client: Duke Energy Date: July 14, 2015 General Information: 1 sample was analyzed for EPA 6020A. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3020 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/55795 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92256907011 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 2014210) • Aluminum • MSD (Lab ID: 2014211) • Aluminum Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 10 of 49 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffli�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060659 Pace Project No.: 92255296 Method: EPA 6020A Description: 6020A MET ICPMS, SPLP Client: Duke Energy Date: July 14, 2015 General Information: 1 sample was analyzed for EPA 6020A. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3020 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 11 of 49 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 fflic&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060659 Pace Project No.: 92255296 Method: EPA 7470A Description: 7470A Mercury, SPLP Client: Duke Energy Date: July 14, 2015 General Information: 1 sample was analyzed for EPA 7470A. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7470A with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: MERP/14127 1g: The temperature in the TCLP/ZHE extraction area was outside the method required range of 21-25 degrees C. •2015020192 (Lab ID:92255296001) • Mercury REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 12 of 49 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffligc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060659 Pace Project No.: 92255296 Method: EPA 7470A Description: 7470A Mercury Client: Duke Energy Date: July 14, 2015 General Information: 1 sample was analyzed for EPA 7470A. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7470A with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 13 of 49 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffli�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060659 Pace Project No.: 92255296 Method: EPA 7471 Description: 7471 Mercury Client: Duke Energy Date: July 14, 2015 General Information: 1 sample was analyzed for EPA 7471. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7471 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MERP/5972 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 35196569001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1266968) • Mercury • MSD (Lab ID: 1266969) • Mercury Additional Comments: Analyte Comments: QC Batch: MERP/5972 D4: Sample was diluted due to the presence of high levels of target analytes. •2015020192 (Lab ID:92255296001) • Mercury REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 14 of 49 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KP�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060659 Pace Project No.: 92255296 Method: EPA 9045 Description: 9045 pH Soil Client: Duke Energy Date: July 14, 2015 General Information: 1 sample was analyzed for EPA 9045. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Duplicate Sample: All duplicate sample results were within method acceptance criteria with any exceptions noted below. QC Batch: WET/38288 D6: The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits. • DUP (Lab ID: 1490817) • pH at 25 Degrees C Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 15 of 49 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K�nic&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060659 Pace Project No.: 92255296 Method: EPA 300.0 Description: 300.0 IC Anions, SPLP Client: Duke Energy Date: July 14, 2015 General Information: 1 sample was analyzed for EPA 300.0. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. QC Batch: WETA/23569 B: Analyte was detected in the associated method blank. • BLANK for HBN 270836 [WETA/235 (Lab ID: 1500538) • Sulfate Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 16 of 49 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KP�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060659 Pace Project No.: 92255296 Method: EPA 353.2 Description: 353.2 Nitrogen, NO2/NO3, SPLP Client: Duke Energy Date: July 14, 2015 General Information: 1 sample was analyzed for EPA 353.2. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 111: Analysis conducted outside the EPA method holding time. •2015020192 (Lab ID:92255296001) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 17 of 49 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KP�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060659 Pace Project No.: 92255296 Method: SM 4500-CI-E Description: 4500 Chloride, SPLP Client: Duke Energy Date: July 14, 2015 General Information: 1 sample was analyzed for SM 4500-CI-E. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 18 of 49 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KPc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060659 Pace Project No.: 92255296 Method: EPA 9056 Description: 9056 IC Anions Client: Duke Energy Date: July 14, 2015 General Information: 1 sample was analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/48094 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015020192 (Lab ID:92255296001) • Chloride • Sulfate REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 19 of 49 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KP�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060659 Pace Project No.: 92255296 Method: EPA 9056 Description: 9056 IC Anions 48hr Client: Duke Energy Date: July 14, 2015 General Information: 1 sample was analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 113: Sample was received or analysis requested beyond the recognized method holding time. •2015020192 (Lab ID:92255296001) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 20 of 49 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K��c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060659 Pace Project No.: 92255296 Method: EPA 9060 Modified Description: Total Organic Carbon Client: Duke Energy Date: July 14, 2015 General Information: 1 sample was analyzed for EPA 9060 Modified. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: This data package has been reviewed for quality and completeness and is approved for release. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 21 of 49 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15060659 Pace Project No.: 92255296 Sample: 2015020192 Lab ID: 92255296001 Collected: 06/18/15 09:15 Received: 06/19/15 13:00 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 1610 mg/kg 41.0 20.5 5 07/11/1510:25 07/14/1512:28 7429-90-5 Barium 87.5 mg/kg 4.1 2.0 5 07/11/1510:25 07/14/1512:28 7440-39-3 Beryllium ND mg/kg 0.41 0.20 5 07/11/1510:25 07/14/1512:28 7440-41-7 Boron ND mg/kg 20.5 10.2 5 07/11/1510:25 07/14/1512:28 7440-42-8 Calcium 2490 mg/kg 205 102 5 07/11/1510:25 07/14/1512:28 7440-70-2 Chromium 3.1 mg/kg 2.0 1.0 5 07/11/1510:25 07/14/1512:28 7440-47-3 Copper 8.3 mg/kg 2.0 1.0 5 07/11/1510:25 07/14/1512:28 7440-50-8 Iron 5980 mg/kg 16.4 8.2 5 07/11/1510:25 07/14/1512:28 7439-89-6 Magnesium 393 mg/kg 205 102 5 07/11/1510:25 07/14/1512:28 7439-95-4 Manganese 781 mg/kg 2.0 1.0 5 07/11/1510:25 07/14/1512:28 7439-96-5 Molybdenum ND mg/kg 4.1 2.0 5 07/11/1510:25 07/14/1512:28 7439-98-7 Nickel 1.8J mg/kg 2.0 1.0 5 07/11/1510:25 07/14/1512:28 7440-02-0 Potassium 338J mg/kg 410 205 5 07/11/1510:25 07/14/1512:28 7440-09-7 Sodium ND mg/kg 410 205 5 07/11/1510:25 07/14/1512:28 7440-23-5 Strontium 25.0 mg/kg 4.1 2.0 5 07/11/1510:25 07/14/1512:28 7440-24-6 Zinc 20.6 mg/kg 8.2 4.1 5 07/11/1510:25 07/14/1512:28 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 8.2 4.1 100 07/11/1510:25 07/14/1513:09 7440-36-0 Arsenic 40.1 mg/kg 8.2 4.1 100 07/11/1510:25 07/14/1513:09 7440-38-2 Cadmium ND mg/kg 0.98 0.49 100 07/11/1510:25 07/14/1513:09 7440-43-9 Cobalt ND mg/kg 8.2 4.1 100 07/11/1510:25 07/14/1513:09 7440-48-4 Lead 13.1 mg/kg 8.2 4.1 100 07/11/1510:25 07/14/1513:09 7439-92-1 Selenium 5.7J mg/kg 8.2 4.1 100 07/11/1510:25 07/14/1513:09 7782-49-2 Thallium ND mg/kg 8.2 4.1 100 07/11/1510:25 07/14/1513:09 7440-28-0 Vanadium 8.8 mg/kg 8.2 4.1 100 07/11/1510:25 07/14/1513:09 7440-62-2 6020A MET ICPMS, SPLP Analytical Method: EPA 6020A Preparation Method: EPA 3020 Leachate Method/Date: EPA 1312; 07/07/15 12:31 Initial pH: ; Final pH: 6.65 Aluminum 406 ug/L 100 29.8 1 07/07/15 14:04 07/08/15 07:59 7429-90-5 Antimony ND ug/L 5.0 1.5 1 07/07/15 14:04 07/08/15 07:59 7440-36-0 Arsenic 10.9 ug/L 5.0 1.1 1 07/07/15 14:04 07/08/15 07:59 7440-38-2 Barium 11.81 ug/L 100 0.81 1 07/07/15 14:04 07/08/15 07:59 7440-39-3 Beryllium ND ug/L 2.0 0.67 1 07/07/15 14:04 07/08/15 07:59 7440-41-7 Boron 75.5 ug/L 50.0 11.1 1 07/07/15 14:04 07/08/15 07:59 7440-42-8 Cadmium ND ug/L 0.80 0.24 1 07/07/15 14:04 07/08/15 07:59 7440-43-9 Calcium 1880 ug/L 400 160 1 07/07/15 14:04 07/08/15 07:59 7440-70-2 Chromium ND ug/L 5.0 1.7 1 07/07/15 14:04 07/08/15 07:59 7440-47-3 Cobalt ND ug/L 5.0 1.3 1 07/07/15 14:04 07/08/15 07:59 7440-48-4 Copper 3.2J ug/L 10.0 2.1 1 07/07/15 14:04 07/08/15 07:59 7440-50-8 Iron 724 ug/L 500 137 1 07/07/15 14:04 07/08/15 07:59 7439-89-6 Lead 2.5 ug/L 1.0 0.46 1 07/07/15 14:04 07/08/15 07:59 7439-92-1 Magnesium 370 ug/L 100 31.7 1 07/07/15 14:04 07/08/15 07:59 7439-95-4 Manganese 45.8 ug/L 5.0 2.4 1 07/07/15 14:04 07/08/15 07:59 7439-96-5 Molybdenum ND ug/L 5.0 0.94 1 07/07/15 14:04 07/08/15 07:59 7439-98-7 REPORT OF LABORATORY ANALYSIS N2 This report shall not be reproduced, except in full, Date: 07/14/2015 03:17 PM without the written consent of Pace Analytical Services, Inc.. Page 22 of 49 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KPgc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15060659 Pace Project No.: 92255296 Sample: 2015020192 Lab ID: 92255296001 Collected: 06/18/15 09:15 Received: 06/19/15 13:00 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6020A MET ICPMS, SPLP Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470A Mercury, SPLP Mercury 7471 Mercury Mercury Percent Moisture Percent Moisture 9045 pH Soil pH at 25 Degrees C 300.0 IC Anions, SPLP Sulfate 353.2 Nitrogen, N021NO3, SPLP Nitrogen, Nitrate 4500 Chloride, SPLP Chloride 9056 IC Anions Chloride Sulfate 9056 IC Anions 48hr Nitrate as N Total Organic Carbon Surrogates RPD% Total Organic Carbon Total Organic Carbon Date: 07/14/2015 03:17 PM Analytical Method: EPA 6020A Preparation Method: EPA 3020 Leachate Method/Date: EPA 1312; 07/07/15 12:31 Initial pH: ; Final pH: 6.65 ND ug/L 5.0 1.6 1 07/07/15 14:04 07/08/15 07:59 7440-02-0 1000 ug/L 500 117 1 07/07/15 14:04 07/08/15 07:59 7440-09-7 2.5J ug/L 5.0 2.0 1 07/07/15 14:04 07/08/15 07:59 7782-49-2 5440 ug/L 500 163 1 07/07/15 14:04 07/08/15 07:59 7440-23-5 12.2 ug/L 5.0 1.3 1 07/07/15 14:04 07/08/15 07:59 7440-24-6 0.30J ug/L 1.0 0.15 1 07/07/15 14:04 07/08/15 07:59 7440-28-0 ND ug/L 10.0 2.8 1 07/07/15 14:04 07/08/15 07:59 7440-62-2 ND ug/L 50.0 24.1 1 07/07/15 14:04 07/08/15 07:59 7440-66-6 Analytical Method: EPA 7470A Preparation Method: EPA 7470A Leachate Method/Date: EPA 1312; 07/07/15 12:31 Initial pH: ; Final pH: 6.65 0.14J ug/L 0.20 0.022 1 07/07/15 16:45 07/07/15 21:45 7439-97-6 1g Analytical Method: EPA 7471 Preparation Method: EPA 7471 0.75 mg/kg 0.064 0.032 5 07/11/1510:40 07/11/1517:22 7439-97-6 D4 Analytical Method: ASTM D2974-87 36.6 % 0.10 0.10 1 07/14/15 07:57 Analytical Method: EPA 9045 5.2 Std. Units 0.10 0.10 1 06/22/15 15:35 Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 06/20/15 16:00 16.4 mg/L 3.2 1.6 1 07/02/1512:34 14808-79-8 B Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 06/20/15 16:00 1.1 mg/L 0.32 0.32 1 07/06/1515:40 H1 Analytical Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 06/20/15 16:00 ND mg/L 7.9 3.9 1 06/30/15 00:37 16887-00-6 Analytical Method: EPA 9056 ND mg/kg 382 191 5 07/12/15 21:38 16887-00-6 D3,M1 285J mg/kg 382 191 5 07/12/15 21:38 14808-79-8 D3 Analytical Method: EPA 9056 ND mg/kg 38.2 19.1 5 07/12/15 21:38 14797-55-8 H3 Analytical Method: EPA 9060 Modified 1.9 % 0.10 0.10 1 07/07/1516:50 43100 mg/kg 4470 2240 1 07/07/1516:50 7440-44-0 42300 mg/kg 4580 2290 1 07/07/1516:56 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 23 of 49 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K��c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15060659 Pace Project No.: 92255296 Sample: 2015020192 Lab ID: 92255296001 Collected: 06/18/15 09:15 Received: 06/19/15 13:00 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Analytical Method: EPA 9060 Modified Mean Total Organic Carbon 42700 mg/kg 4520 2260 1 07/07/15 16:50 7440-44-0 Date: 07/14/2015 03:17 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 24 of 49 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K3�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15060659 Pace Project No.: 92255296 Sample: 2015020193 Lab ID: 92255296002 Collected: 06/18/15 09:35 Received: 06/19/15 13:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;I➢ZI7c\�i,I=11 l[99�� 6? Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470A Mercury Mercury Date: 07/14/2015 03:17 PM Analytical Method: EPA 6020A Preparation Method: EPA 3020 4.2J ug/L 10.0 3.0 1 07/05/1511:18 07/06/1516:12 7429-90-5 ND ug/L 0.50 0.15 1 07/05/1511:18 07/06/1516:12 7440-36-0 ND ug/L 0.50 0.11 1 07/05/1511:18 07/06/1516:12 7440-38-2 3.0 ug/L 0.30 0.081 1 07/05/1511:18 07/06/1516:12 7440-39-3 ND ug/L 0.20 0.067 1 07/05/1511:18 07/06/1516:12 7440-41-7 ND ug/L 5.0 1.1 1 07/05/1511:18 07/06/1516:12 7440-42-8 ND ug/L 0.080 0.024 1 07/05/1511:18 07/06/1516:12 7440-43-9 ND ug/L 40.0 16.0 1 07/05/1511:18 07/06/1516:12 7440-70-2 ND ug/L 0.50 0.17 1 07/05/1511:18 07/06/1516:12 7440-47-3 ND ug/L 0.50 0.13 1 07/05/1511:18 07/06/1516:12 7440-48-4 ND ug/L 1.0 0.21 1 07/05/1511:18 07/06/1516:12 7440-50-8 14.5J ug/L 50.0 13.7 1 07/05/1511:18 07/06/1516:12 7439-89-6 ND ug/L 0.10 0.046 1 07/05/1511:18 07/06/1516:12 7439-92-1 ND ug/L 10.0 3.2 1 07/05/1511:18 07/06/1516:12 7439-95-4 0.41J ug/L 0.50 0.24 1 07/05/1511:18 07/06/1516:12 7439-96-5 ND ug/L 0.50 0.094 1 07/05/1511:18 07/06/1516:12 7439-98-7 ND ug/L 0.50 0.16 1 07/05/1511:18 07/06/1516:12 7440-02-0 ND ug/L 50.0 11.7 1 07/05/1511:18 07/06/1516:12 7440-09-7 ND ug/L 0.50 0.20 1 07/05/1511:18 07/06/1516:12 7782-49-2 ND ug/L 50.0 16.3 1 07/05/1511:18 07/06/1516:12 7440-23-5 ND ug/L 0.50 0.13 1 07/05/1511:18 07/06/1516:12 7440-24-6 ND ug/L 0.10 0.015 1 07/05/1511:18 07/06/1516:12 7440-28-0 ND ug/L 1.0 0.28 1 07/05/1511:18 07/06/1516:12 7440-62-2 ND ug/L 5.0 2.4 1 07/05/1511:18 07/06/1516:12 7440-66-6 Analytical Method: EPA 7470A Preparation Method: EPA 7470A ND ug/L 0.20 0.022 1 07/05/15 09:25 07/05/15 20:54 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 25 of 49 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K�nic&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060659 Pace Project No.: 92255296 QC Batch: MERP/14127 Analysis Method: EPA 7470A QC Batch Method: EPA 7470A Analysis Description: 7470A Mercury SPLP Associated Lab Samples: 92255296001 METHOD BLANK: 2015543 Matrix: Water Associated Lab Samples: 92255296001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury ug/L ND 0.20 07/07/15 21:16 METHOD BLANK: 2014527 Matrix: Solid Associated Lab Samples: 92255296001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury ug/L ND 0.20 07/07/15 21:50 LABORATORY CONTROL SAMPLE: 2015544 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 5 5.4 108 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2015545 2015546 MS MSD 92256693002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qua] Mercury ug/L ND 5 5 5.4 5.4 107 108 80-120 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/14/2015 03:17 PM without the written consent of Pace Analytical Services, Inc.. Page 26 of 49 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K��c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060659 Pace Project No.: 92255296 QC Batch: MERP/14103 Analysis Method: EPA 7470A QC Batch Method: EPA 7470A Analysis Description: 7470A Mercury Water Associated Lab Samples: 92255296002 METHOD BLANK: 2014212 Matrix: Water Associated Lab Samples: 92255296002 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury ug/L ND 0.20 07/05/15 20:42 LABORATORY CONTROL SAMPLE: 2014213 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 5 4.7 94 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2014214 2014215 MS MSD 92256907010 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 5 5 4.9 4.8 98 96 80-120 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/14/2015 03:17 PM without the written consent of Pace Analytical Services, Inc.. Page 27 of 49 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060659 Pace Project No.: 92255296 QC Batch: MERP/5972 Analysis Method: EPA 7471 QC Batch Method: EPA 7471 Analysis Description: 7471 Mercury Associated Lab Samples: 92255296001 METHOD BLANK: 1266966 Matrix: Solid Associated Lab Samples: 92255296001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury mg/kg ND 0.0083 07/11/1516:10 LABORATORY CONTROL SAMPLE: 1266967 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury mg/kg .083 0.098 118 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1266968 1266969 MS MSD 35196569001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury mg/kg 0.87 .318 .31 1.0 0.97 44 30 80-120 5 20 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/14/2015 03:17 PM without the written consent of Pace Analytical Services, Inc.. Page 28 of 49 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060659 Pace Project No.: 92255296 QC Batch: MPRP/25192 Analysis Method: EPA 6010 QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid Associated Lab Samples: 92255296001 METHOD BLANK: 1266957 Associated Lab Samples: 92255296001 Parameter Units Aluminum mg/kg Barium mg/kg Beryllium mg/kg Boron mg/kg Calcium mg/kg Chromium mg/kg Copper mg/kg Iron mg/kg Magnesium mg/kg Manganese mg/kg Molybdenum mg/kg Nickel mg/kg Potassium mg/kg Sodium mg/kg Strontium mg/kg Zinc mg/kg Matrix: Solid Blank Result Reporting Limit Analyzed ND 5.0 07/14/1510:34 ND 0.50 07/14/1510:34 ND 0.050 07/14/1510:34 ND 2.5 07/14/1510:34 ND 25.2 07/14/1510:34 ND 0.25 07/14/1510:34 ND 0.25 07/14/1510:34 ND 2.0 07/14/1510:34 ND 25.2 07/14/1510:34 ND 0.25 07/14/1510:34 ND 0.50 07/14/1510:34 ND 0.25 07/14/1510:34 ND 50.4 07/14/1510:34 ND 50.4 07/14/1510:34 ND 0.50 07/14/1510:34 ND 1.0 07/14/1510:34 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 1266958 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Aluminum mg/kg 131 121 93 80-120 Barium mg/kg 13.1 12.7 97 80-120 Beryllium mg/kg 1.3 1.3 96 80-120 Boron mg/kg 131 128 98 80-120 Calcium mg/kg 653 616 94 80-120 Chromium mg/kg 13.1 12.6 96 80-120 Copper mg/kg 13.1 12.2 93 80-120 Iron mg/kg 131 120 92 80-120 Magnesium mg/kg 653 627 96 80-120 Manganese mg/kg 13.1 12.6 96 80-120 Molybdenum mg/kg 13.1 12.0 92 80-120 Nickel mg/kg 13.1 12.2 93 80-120 Potassium mg/kg 653 602 92 80-120 Sodium mg/kg 653 618 95 80-120 Strontium mg/kg 13.1 12.1 93 80-120 Zinc mg/kg 65.3 62.0 95 80-120 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/14/2015 03:17 PM without the written consent of Pace Analytical Services, Inc.. Page 29 of 49 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K��c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060659 Pace Project No.: 92255296 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1266959 1266960 MS MSD 92257635001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum mg/kg 6100 297 304 11700 11500 1880 1780 75-125 2 20 M1 Barium mg/kg 52.0 29.7 30.4 83.5 91.5 106 130 75-125 9 20 M1 Beryllium mg/kg 0.40J 2.87 3.11 3.2 3.3 93 95 75-125 4 20 Boron mg/kg ND 297 304 273 286 90 92 75-125 5 20 Calcium mg/kg 433 1490 1520 1810 1980 93 102 75-125 9 20 Chromium mg/kg 10.2 29.7 30.4 38.4 39.6 95 97 75-125 3 20 Copper mg/kg 16.8 29.7 30.4 43.6 45.7 90 95 75-125 5 20 Iron mg/kg 30900 297 304 31500 35000 187 1330 75-125 10 20 M1 Magnesium mg/kg 702 1490 1520 2200 2270 101 104 75-125 3 20 Manganese mg/kg 155 29.7 30.4 184 197 100 141 75-125 7 20 M1 Molybdenum mg/kg ND 29.7 30.4 25.3 26.6 80 83 75-125 5 20 Nickel mg/kg 2.OJ 29.7 30.4 30.1 31.2 94 96 75-125 4 20 Potassium mg/kg ND 1490 1520 1640 1690 92 94 75-125 3 20 Sodium mg/kg ND 1490 1520 1440 1450 97 95 75-125 1 20 Strontium mg/kg 6.2J 29.7 30.4 34.3 36.5 95 100 75-125 6 20 Zinc mg/kg 18.2 149 152 159 174 95 103 75-125 9 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/14/2015 03:17 PM without the written consent of Pace Analytical Services, Inc.. Page 30 of 49 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K��c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060659 Pace Project No.: 92255296 QC Batch: MPRP/25193 Analysis Method: EPA 6020 QC Batch Method: EPA 3050 Analysis Description: 6020 MET SOLID Associated Lab Samples: 92255296001 METHOD BLANK: 1266961 Matrix: Solid Associated Lab Samples: 92255296001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Antimony mg/kg ND 0.052 07/14/1512:05 N2 Arsenic mg/kg ND 0.052 07/14/1512:05 Cadmium mg/kg ND 0.0062 07/14/1512:05 Cobalt mg/kg ND 0.052 07/14/1512:05 Lead mg/kg ND 0.052 07/14/1512:05 Selenium mg/kg ND 0.052 07/14/1512:05 Thallium mg/kg ND 0.052 07/14/1512:05 Vanadium mg/kg ND 0.052 07/14/1512:05 LABORATORY CONTROL SAMPLE: 1266962 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Antimony mg/kg 2.5 2.5 98 80-120 N2 Arsenic mg/kg 2.5 2.5 100 80-120 Cadmium mg/kg .25 0.26 103 80-120 Cobalt mg/kg 2.5 2.6 101 80-120 Lead mg/kg 2.5 2.5 100 80-120 Selenium mg/kg 2.5 2.7 104 80-120 Thallium mg/kg 2.5 2.5 98 80-120 Vanadium mg/kg 2.5 2.6 101 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1266963 1266964 MS MSD 92257635001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony mg/kg ND 5.99 6.23 ND ND 64 63 75-125 20 M6, N2 Arsenic mg/kg ND 5.99 6.23 11.6J 12.3J 116 122 75-125 20 Cadmium mg/kg ND .599 .623 ND ND 60 78 75-125 20 M6 Cobalt mg/kg 7.5J 5.99 6.23 ND ND -125 -120 75-125 20 M6 Lead mg/kg 6AJ 5.99 6.23 11.51 11AJ 84 80 75-125 20 Selenium mg/kg ND 5.99 6.23 8.7J 7.2J 111 83 75-125 20 Thallium mg/kg ND 5.99 6.23 ND ND 81 87 75-125 20 Vanadium mg/kg 59.4 5.99 6.23 53.2 51.0 -103 -134 75-125 4 20 M6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/14/2015 03:17 PM without the written consent of Pace Analytical Services, Inc.. Page 31 of 49 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060659 Pace Project No.: 92255296 QC Batch: MPRP/55795 Analysis Method: EPA 6020A QC Batch Method: EPA 3020 Analysis Description: 6020A Water UPD4 Associated Lab Samples: 92255296002 METHOD BLANK: 2014208 Associated Lab Samples: 92255296002 Parameter Units Aluminum ug/L Antimony ug/L Arsenic ug/L Barium ug/L Beryllium ug/L Boron ug/L Cadmium ug/L Calcium ug/L Chromium ug/L Cobalt ug/L Copper ug/L Iron ug/L Lead ug/L Magnesium ug/L Manganese ug/L Molybdenum ug/L Nickel ug/L Potassium ug/L Selenium ug/L Sodium ug/L Strontium ug/L Thallium ug/L Vanadium ug/L Zinc ug/L Matrix: Water Blank Result Reporting Limit Analyzed ND 10.0 07/06/1516:02 ND 0.50 07/06/1516:02 ND 0.50 07/06/1516:02 ND 0.30 07/06/1516:02 ND 0.20 07/06/1516:02 ND 5.0 07/06/1516:02 ND 0.080 07/06/1516:02 ND 40.0 07/06/1516:02 ND 0.50 07/06/1516:02 ND 0.50 07/06/1516:02 ND 1.0 07/06/1516:02 ND 50.0 07/06/1516:02 ND 0.10 07/06/1516:02 ND 10.0 07/06/1516:02 ND 0.50 07/06/1516:02 ND 0.50 07/06/1516:02 ND 0.50 07/06/1516:02 ND 50.0 07/06/1516:02 ND 0.50 07/06/1516:02 ND 50.0 07/06/1516:02 ND 0.50 07/06/1516:02 ND 0.10 07/06/1516:02 ND 1.0 07/06/1516:02 ND 5.0 07/06/1516:02 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 2014209 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Aluminum ug/L 80 87.2 109 80-120 Antimony ug/L 80 84.2 105 80-120 Arsenic ug/L 80 83.2 104 80-120 Barium ug/L 80 85.7 107 80-120 Beryllium ug/L 80 90.5 113 80-120 Boron ug/L 80 88.2 110 80-120 Cadmium ug/L 80 85.0 106 80-120 Calcium ug/L 1000 1110 111 80-120 Chromium ug/L 80 89.7 112 80-120 Cobalt ug/L 80 87.4 109 80-120 Copper ug/L 80 91.5 114 80-120 Iron ug/L 1000 1130 113 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/14/2015 03:17 PM without the written consent of Pace Analytical Services, Inc.. Page 32 of 49 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K�gc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060659 Pace Project No.: 92255296 LABORATORY CONTROL SAMPLE: 2014209 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Lead ug/L 80 84.4 105 80-120 Magnesium ug/L 1000 1040 104 80-120 Manganese ug/L 80 89.9 112 80-120 Molybdenum ug/L 80 85.4 107 80-120 Nickel ug/L 80 89.3 112 80-120 Potassium ug/L 1000 1060 106 80-120 Selenium ug/L 80 85.8 107 80-120 Sodium ug/L 1000 1020 102 80-120 Strontium ug/L 80 84.7 106 80-120 Thallium ug/L 80 88.0 110 80-120 Vanadium ug/L 80 87.1 109 80-120 Zinc ug/L 80 86.7 108 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2014210 2014211 MS MSD 92256907011 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum ug/L 420 80 80 655 655 295 294 75-125 0 20 M1 Antimony ug/L 0.21J 80 80 83.4 84.5 104 105 75-125 1 20 Arsenic ug/L 1.1 80 80 82.5 83.7 102 103 75-125 1 20 Barium ug/L 9.6 80 80 96.8 97.6 109 110 75-125 1 20 Beryllium ug/L 0.077J 80 80 90.0 88.6 112 111 75-125 2 20 Boron ug/L 18.3 80 80 103 105 106 109 75-125 2 20 Cadmium ug/L ND 80 80 84.5 85.3 106 107 75-125 1 20 Calcium ug/L 705 1000 1000 1840 1840 113 113 75-125 0 20 Chromium ug/L 4.8 80 80 93.3 93.3 111 111 75-125 0 20 Cobalt ug/L 0.57 80 80 88.2 88.9 110 110 75-125 1 20 Copper ug/L 17.2 80 80 107 110 113 116 75-125 3 20 Iron ug/L 3500 1000 1000 4430 4530 94 103 75-125 2 20 Lead ug/L 0.52 80 80 85.7 86.1 106 107 75-125 0 20 Magnesium ug/L 123 1000 1000 1160 1180 104 106 75-125 1 20 Manganese ug/L 35.7 80 80 123 124 109 110 75-125 1 20 Molybdenum ug/L 4.2 80 80 87.7 88.1 104 105 75-125 0 20 Nickel ug/L 6.4 80 80 95.1 96.6 111 113 75-125 2 20 Potassium ug/L 151 1000 1000 1210 1230 105 108 75-125 2 20 Selenium ug/L ND 80 80 84.8 82.9 106 103 75-125 2 20 Sodium ug/L 539 1000 1000 1510 1530 97 99 75-125 1 20 Strontium ug/L 5.3 80 80 89.2 90.5 105 106 75-125 1 20 Thallium ug/L 0.024J 80 80 87.3 88.2 109 110 75-125 1 20 Vanadium ug/L 1.6 80 80 87.6 88.2 108 108 75-125 1 20 Zinc ug/L 298 80 80 375 380 96 102 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/14/2015 03:17 PM without the written consent of Pace Analytical Services, Inc.. Page 33 of 49 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K��c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060659 Pace Project No.: 92255296 QC Batch: MPRP/55850 Analysis Method: EPA 6020A QC Batch Method: EPA 3020 Analysis Description: 6020A SPLP UPD4 Associated Lab Samples: 92255296001 METHOD BLANK: 2015529 Associated Lab Samples: 92255296001 Parameter Units Aluminum ug/L Antimony ug/L Arsenic ug/L Barium ug/L Beryllium ug/L Boron ug/L Cadmium ug/L Calcium ug/L Chromium ug/L Cobalt ug/L Copper ug/L Iron ug/L Lead ug/L Magnesium ug/L Manganese ug/L Molybdenum ug/L Nickel ug/L Potassium ug/L Selenium ug/L Sodium ug/L Strontium ug/L Thallium ug/L Vanadium ug/L Zinc ug/L METHOD BLANK: 2014527 Associated Lab Samples: 92255296001 Parameter Units Aluminum ug/L Antimony ug/L Arsenic ug/L Barium ug/L Beryllium ug/L Boron ug/L Cadmium ug/L Calcium ug/L Chromium ug/L Cobalt ug/L Matrix: Water Blank Result Reporting Limit Analyzed ND 100 07/08/15 07:21 ND 5.0 07/08/15 07:21 ND 5.0 07/08/15 07:21 ND 100 07/08/15 07:21 ND 2.0 07/08/15 07:21 ND 50.0 07/08/15 07:21 ND 0.80 07/08/15 07:21 ND 400 07/08/15 07:21 ND 5.0 07/08/15 07:21 ND 5.0 07/08/15 07:21 ND 10.0 07/08/15 07:21 ND 500 07/08/15 07:21 ND 1.0 07/08/15 07:21 ND 100 07/08/15 07:21 ND 5.0 07/08/15 07:21 ND 5.0 07/08/15 07:21 ND 5.0 07/08/15 07:21 ND 500 07/08/15 07:21 ND 5.0 07/08/15 07:21 ND 500 07/08/15 07:21 ND 5.0 07/08/15 07:21 ND 1.0 07/08/15 07:21 ND 10.0 07/08/15 07:21 ND 50.0 07/08/15 07:21 Matrix: Solid Blank Result Reporting Limit Analyzed ND 100 07/08/15 08:09 ND 5.0 07/08/15 08:09 ND 5.0 07/08/15 08:09 ND 100 07/08/15 08:09 ND 2.0 07/08/15 08:09 54.1 50.0 07/08/15 08:09 ND 0.80 07/08/15 08:09 ND 400 07/08/15 08:09 ND 5.0 07/08/15 08:09 ND 5.0 07/08/15 08:09 Qualifiers Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/14/2015 03:17 PM without the written consent of Pace Analytical Services, Inc.. Page 34 of 49 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060659 Pace Project No.: 92255296 METHOD BLANK: 2014527 Associated Lab Samples: 92255296001 Parameter Units Matrix: Blank Result Solid Reporting Limit Analyzed Copper ug/L ND 10.0 07/08/15 08:09 Iron ug/L ND 500 07/08/15 08:09 Lead ug/L 0.73J 1.0 07/08/15 08:09 Magnesium ug/L ND 100 07/08/15 08:09 Manganese ug/L ND 5.0 07/08/15 08:09 Molybdenum ug/L ND 5.0 07/08/15 08:09 Nickel ug/L ND 5.0 07/08/15 08:09 Potassium ug/L ND 500 07/08/15 08:09 Selenium ug/L ND 5.0 07/08/15 08:09 Sodium ug/L 874 500 07/08/15 08:09 Strontium ug/L ND 5.0 07/08/15 08:09 Thallium ug/L ND 1.0 07/08/15 08:09 Vanadium ug/L ND 10.0 07/08/15 08:09 Zinc ug/L ND 50.0 07/08/15 08:09 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 2015530 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Aluminum ug/L 80 86.9J 109 80-120 Antimony ug/L 80 86.3 108 80-120 Arsenic ug/L 80 84.3 105 80-120 Barium ug/L 80 84AJ 106 80-120 Beryllium ug/L 80 81.3 102 80-120 Boron ug/L 80 78.8 98 80-120 Cadmium ug/L 80 88.8 111 80-120 Calcium ug/L 1000 1110 111 80-120 Chromium ug/L 80 87.4 109 80-120 Cobalt ug/L 80 89.4 112 80-120 Copper ug/L 80 92.0 115 80-120 Iron ug/L 1000 1110 111 80-120 Lead ug/L 80 86.1 108 80-120 Magnesium ug/L 1000 1160 116 80-120 Manganese ug/L 80 85.7 107 80-120 Molybdenum ug/L 80 84.6 106 80-120 Nickel ug/L 80 91.9 115 80-120 Potassium ug/L 1000 1130 113 80-120 Selenium ug/L 80 83.8 105 80-120 Sodium ug/L 1000 1170 117 80-120 Strontium ug/L 80 82.1 103 80-120 Thallium ug/L 80 91.3 114 80-120 Vanadium ug/L 80 89.7 112 80-120 Zinc ug/L 80 89.7 112 80-120 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/14/2015 03:17 PM without the written consent of Pace Analytical Services, Inc.. Page 35 of 49 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 1in�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060659 Pace Project No.: 92255296 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2015531 2015532 MS MSD 92256693001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum ug/L ND 80 80 ND ND 109 114 75-125 20 Antimony ug/L ND 80 80 84.2 85.9 105 107 75-125 2 20 Arsenic ug/L ND 80 80 84.1 85.1 105 106 75-125 1 20 Barium ug/L 1.2J 80 80 84.3J 85.2J 104 105 75-125 20 Beryllium ug/L ND 80 80 81.9 82.9 102 104 75-125 1 20 Boron ug/L 16.7J 80 80 96.7J 99.2J 100 103 75-125 20 Cadmium ug/L ND 80 80 87.9 90.5 110 113 75-125 3 20 Calcium ug/L 185J 1000 1000 1290J 1230J 111 105 75-125 20 Chromium ug/L ND 80 80 87.0 87.7 109 110 75-125 1 20 Cobalt ug/L ND 80 80 90.0 91.5 112 114 75-125 2 20 Copper ug/L ND 80 80 91.6 92.8 114 116 75-125 1 20 Iron ug/L ND 1000 1000 11101 1120J 110 112 75-125 20 Lead ug/L ND 80 80 87.1 87.9 109 110 75-125 1 20 Magnesium ug/L 106 1000 1000 1240 1260 113 115 75-125 1 20 Manganese ug/L 12.3 80 80 99.3 101 109 111 75-125 2 20 Molybdenum ug/L ND 80 80 83.9 85.2 105 107 75-125 2 20 Nickel ug/L ND 80 80 93.1 93.1 116 116 75-125 0 20 Potassium ug/L ND 1000 1000 1140J 1160J 109 111 75-125 20 Selenium ug/L ND 80 80 85.4 85.6 107 107 75-125 0 20 Sodium ug/L 861 1000 1000 1960J 2010J 110 115 75-125 20 Strontium ug/L ND 80 80 83.4 84.5 103 105 75-125 1 20 Thallium ug/L ND 80 80 91.0 92.4 114 116 75-125 2 20 Vanadium ug/L ND 80 80 89.6 90.8 112 113 75-125 1 20 Zinc ug/L ND 80 80 ND ND 111 114 75-125 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/14/2015 03:17 PM without the written consent of Pace Analytical Services, Inc.. Page 36 of 49 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060659 Pace Project No.: 92255296 QC Batch: PMST/3726 Analysis Method: ASTM D2974-87 QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture Associated Lab Samples: 92255296001 SAMPLE DUPLICATE: 1269128 35195836001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 46.1 47.9 4 10 SAMPLE DUPLICATE: 1269129 35195978016 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 24.0 24.6 2 10 SAMPLE DUPLICATE: 1269130 35196456002 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 21.1 20.2 4 10 SAMPLE DUPLICATE: 1269131 35196557007 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 5.5 5.4 1 10 SAMPLE DUPLICATE: 1269132 35196557016 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 6.9 7.6 9 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/14/2015 03:17 PM without the written consent of Pace Analytical Services, Inc.. Page 37 of 49 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060659 Pace Project No.: 92255296 QC Batch: WET/38288 Analysis Method: EPA 9045 QC Batch Method: EPA 9045 Analysis Description: 9045 pH Associated Lab Samples: 92255296001 SAMPLE DUPLICATE: 1490817 Parameter pH at 25 Degrees C SAMPLE DUPLICATE: 1490818 Parameter pH at 25 Degrees C 92255286001 Dup Max Units Result Result RPD RPD Qualifiers Std. Units 7.1 7.1 1 10 D6 92254629009 Dup Max Units Result Result RPD RPD Qualifiers Std. Units 6.5 6.4 1 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/14/2015 03:17 PM without the written consent of Pace Analytical Services, Inc.. Page 38 of 49 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Iic&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060659 Pace Project No.: 92255296 QC Batch: WETA/23569 Analysis Method: EPA 300.0 QC Batch Method: EPA 300.0 Analysis Description: 300.0 IC Anions Associated Lab Samples: 92255296001 METHOD BLANK: 1500538 Matrix: Water Associated Lab Samples: 92255296001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Sulfate mg/L 1.6J 2.0 07/02/1512:07 LABORATORY CONTROL SAMPLE: 1500539 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfate mg/L 20 20.2 101 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1500540 1500541 MS MSD 92255296001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfate mg/L 16.4 31.5 31.5 44.8 44.6 90 90 0 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/14/2015 03:17 PM without the written consent of Pace Analytical Services, Inc.. Page 39 of 49 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060659 Pace Project No.: 92255296 QC Batch: WETA/23607 Analysis Method: EPA 353.2 QC Batch Method: EPA 353.2 Analysis Description: 353.2 Nitrate + Nitrite, Unpres. Associated Lab Samples: 92255296001 METHOD BLANK: 1502287 Matrix: Water Associated Lab Samples: 92255296001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, Nitrate mg/L 0.11 0.020 07/06/15 15:37 Z2 LABORATORY CONTROL SAMPLE: 1502288 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Nitrate mg/L 2.5 2.4 96 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1502289 1502290 MS MSD 92255305004 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Nitrate mg/L 0.43 3.1 3.1 3.5 3.5 97 97 90-110 0 10 H1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/14/2015 03:17 PM without the written consent of Pace Analytical Services, Inc.. Page 40 of 49 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060659 Pace Project No.: 92255296 QC Batch: WETA/23526 Analysis Method: SM 4500-CI-E QC Batch Method: SM 4500-CI-E Analysis Description: 4500 Chloride Associated Lab Samples: 92255296001 METHOD BLANK: 1497697 Matrix: Water Associated Lab Samples: 92255296001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/L ND 1.0 06/30/15 00:35 LABORATORY CONTROL SAMPLE: 1497698 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloride mg/L 20 20.2 101 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1497699 1497700 MS MSD 92255296001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride mg/L ND 31.5 31.5 36.1 36.5 105 106 90-110 1 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/14/2015 03:17 PM without the written consent of Pace Analytical Services, Inc.. Page 41 of 49 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Iic&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060659 Pace Project No.: 92255296 QC Batch: WETA/48094 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92255296001 METHOD BLANK: 1267851 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/kg ND 50.0 07/12/15 20:54 Sulfate mg/kg ND 50.0 07/12/15 20:54 LABORATORY CONTROL SAMPLE: 1267852 Parameter Units Chloride mg/kg Sulfate mg/kg MATRIX SPIKE SAMPLE: 1267854 Parameter Units Chloride mg/kg Sulfate mg/kg SAMPLE DUPLICATE: 1267853 Parameter Chloride Sulfate Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 493 485 98 80-120 493 488 99 80-120 92255296001 Spike MS MS % Rec Result Conc. Result % Rec Limits Qualifiers ND 788 673 69 80-120 M 1 285J 788 923 81 80-120 92255296001 Dup Units Result Result mg/kg ND ND mg/kg 285J 236J Max RPD RPD Qualifiers 20 D3 20 D3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/14/2015 03:17 PM without the written consent of Pace Analytical Services, Inc.. Page 42 of 49 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Iigc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060659 Pace Project No.: 92255296 QC Batch: WETA/48093 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92255296001 METHOD BLANK: 1267847 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrate as N mg/kg ND 5.0 07/12/15 20:54 LABORATORY CONTROL SAMPLE: 1267848 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg 49.3 50.6 103 80-120 MATRIX SPIKE SAMPLE: 1267850 92255296001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg ND 78.8 77.7 90 80-120 H3 SAMPLE DUPLICATE: 1267849 92255296001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Nitrate as N mg/kg ND ND 20 H3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/14/2015 03:17 PM without the written consent of Pace Analytical Services, Inc.. Page 43 of 49 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060659 Pace Project No.: 92255296 QC Batch: WETA/29382 Analysis Method: EPA 9060 Modified QC Batch Method: EPA 9060 Modified Analysis Description: 9060 TOC Average Associated Lab Samples: 92255296001 METHOD BLANK: 1188393 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mean Total Organic Carbon mg/kg ND 600 07/07/15 14:24 LABORATORY CONTROL SAMPLE: 1188394 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mean Total Organic Carbon mg/kg 120000 125000 104 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1188395 1188396 MS MSD 92255965005 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg 11000 26400 26300 38000 36000 102 95 50-150 5 30 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1188397 1188398 MS MSD 92255965006 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg ND 6950 7000 7320 7180 102 100 50-150 2 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/14/2015 03:17 PM without the written consent of Pace Analytical Services, Inc.. Page 44 of 49 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: J15060659 Pace Project No.: 92255296 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TN -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-G Pace Analytical Services - Green Bay PASI-M Pace Analytical Services - Minneapolis PASI-O Pace Analytical Services - Ormond Beach BATCH QUALIFIERS Batch: ICP/15328 Ill Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. Batch: ICPM/10219 III Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. ANALYTE QUALIFIERS 1g The temperature in the TCLP/ZHE extraction area was outside the method required range of 21-25 degrees C. B Analyte was detected in the associated method blank. D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. D4 Sample was diluted due to the presence of high levels of target analytes. D6 The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits. H1 Analysis conducted outside the EPA method holding time. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/14/2015 03:17 PM without the written consent of Pace Analytical Services, Inc.. Page 45 of 49 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 1j nl c&fie. Suite 100 Huntersville, INC 28078 (704)875-9092 QUALIFIERS Project: J15060659 Pace Project No.: 92255296 ANALYTE QUALIFIERS H3 Sample was received or analysis requested beyond the recognized method holding time. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. N2 The lab does not hold TNI accreditation for this parameter. Z2 Analyte present in the associated method blank above the detection limit. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/14/2015 03:17 PM without the written consent of Pace Analytical Services, Inc.. Page 46 of 49 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: J15060659 Pace Project No.: 92255296 Lab ID Sample ID QC Batch Method QC Batch Analytical Method 92255296001 2015020192 EPA 3050 MPRP/25192 EPA 6010 92255296001 2015020192 EPA 3050 MPRP/25193 EPA 6020 92255296002 2015020193 EPA 3020 MPRP/55795 EPA 6020A 92255296001 2015020192 EPA 3020 MPRP/55850 EPA 6020A 92255296001 2015020192 EPA 7470A MERP/14127 EPA 7470A 92255296002 2015020193 EPA 7470A MERP/14103 EPA 7470A 92255296001 2015020192 EPA 7471 MERP/5972 EPA 7471 92255296001 2015020192 ASTM D2974-87 PMST/3726 92255296001 2015020192 EPA 9045 WET/38288 92255296001 2015020192 EPA 300.0 WETA/23569 92255296001 2015020192 EPA 353.2 WETA/23607 92255296001 2015020192 SM 4500-CI-E WETA/23526 92255296001 2015020192 EPA 9056 WETA/48094 92255296001 2015020192 EPA 9056 WETA/48093 92255296001 2015020192 EPA 9060 Modified WETA/29382 92255296001 2015020192 EPA 9060 Modified WETA/29383 Date: 07/14/2015 03:17 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Analytical Batch ICP/15328 ICPM/10219 ICPM/25198 ICPM/25240 MERC/16456 MERC/16431 MERC/5953 Page 47 of 49 �1'iZC@/{rk7l�/flCclf ' Document Number: Issuing Authority: F-CHR-CS-003-rev.16 Pace Huntersville Quality Office 5s or 55 Client Name. Do k -e— Ems' v.Y o, , ` Page 2 of 2 is for Internal Use Only Courier: ❑ Fed Ex ❑ UPS❑ LISPS❑ Client[] Commercial❑ ace Other Rjygj Custody Seal on Cooler/Box Present: es ❑ no Seals intact: ',,G` yes ❑ no Packing Material: Q Bubble V[)p ❑ Bubble Bag" None . Other Thermometer Used: IR Gun T7401 Type of Ice° Wet lue None ❑ Samples on ice, cooling process has begun Tpmn Cnrraetinn Factor T1401 No Correction • Corrected Cooler Temp.: r C Biological Tissue is Frozen; Yes N NJ g ate and Initi Is of person e: amining contents: Temp should be above freezing to 6°C Comments: Chain of Custody Present: Yes .❑No ©NIA ,, Chain of Custody Filled Out: Yes Callo ❑NIA 2. Chain of Custody Relinquished: Yes ©No ❑NIA 3. Sampler Name & Signature on COC: es ❑No I-INIA 4. Samples Arrived within Hold Time: P.Yes ❑No ❑NIA 5. Short Hold Time Analysis (<72hr): Dyes o ❑NIA 6,. Rush Turn Around Time Requested: ®Yes o ❑NIA 7. Sufficient Volume: RYes ❑No ❑NIA 8, Correct Containers Used: ,�Yes ❑No ❑NIA 9. -Pace Containers Used: PYes.. ❑No ❑NIA Containers Intact: Yes ❑No ❑NIA 10. Filtered volume received for Dissolved tests es DNo El N/A 11, Sample Labels match COC: Yes ❑No t ❑NIA 12, -includes date/time/ID/Analysis Matrix: `z t tJ All containers needing preservation have been checked. A:&s ❑No El N/A 13. All containers needing preservation are found to be in compliance with EPA recommendation. ,.6Yes ❑No El NIA exceptions: VOA, ooliform, TOC, O&G, VN•DRO (water) ❑Yes o Samples checked for dechlorination: ❑Yes ❑Na NIA 14. Headspace in VOA Vials (>6mm): ❑Yes ❑No NIA 15. Trip Blank Present: ©Yes ❑No 2(�' 16. Trip Blank Custody Seals Present Dyes ❑No x7NIA Pace Trip Blank Lot # jif purchased): Client Notification/ Resolution: Person Contacted: Comments/ Resolution: DatefTime: SCURF Review: Date: 0!f !K- SRF Review: Date: 20IS— Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office ( Le out of hold, incorrect preservative, out of temp, incorrect containers) Field Data Required? WO#:92255296 I1111111111111111111111�� Y 1 N Page 48 of 49 'f N s e s m n_n��py z ` L' w 3 o 0 SO o O r11 O s t d m � N � n � 3 4 � a 0 0 4 6 Z w a 7S co w N- N C EVA cr o o E VIE x a x o m s G y' W \ ° 4 ,y fD A x m 1 O A C rL "0 E � III m 1 l_.. ....... I._ - E {' .I O u L) e u n � u 2 z • a C a u � v m Q o � N I + N O o' g 0 z o r'rr 0 Page 49 9 49 55 of 55 Synterra EDD CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM �DUKEI _-lknakyta sl LalaoraxOry Ser me-5-,_._l Mail Code MG6�LA� (flulldhp 7405l � . �...a.,, ,e,r - - - - - -.R _ -Ary Use Only _ --._._._. _ nal ical Laboratory - - - - - rlc _x_ 1 nt i yYwlr Order 1 $-MV Haflere Ferry Rd 1 � � rwM= SIB IL � �=— 1 CMSTRIBtJiliStl CM— ENERGYM I Munlererdlla, N.C, 2130M I � ILappdRp OeeraT ea�Ne 4rlplaretinp From I ORIGINAL 10 LAR I 1sMQ) 075,5246 FBx9eQ 876�3!19 I l� � # Ct71�YloCLIEfJs _ _ -�., , ._._-_._-_-_I - : .p SAMPLE aFfaGRAM Gr�1UItl W81Fi" NPQES[ �Jf+t el Mlrne {� rar4lill lrli7ltr ik##rB3#mprlf - SON3[Prw,r r,P: IY�w ,r Cnrner _ Plam _. Htv�,aT 201r3015 I Gape Fear l lei T,am G - - I L %ft �E. r+rb,.. �i Pace - 3JPI�IIsaati IJxil° - Rlprgjrcl [B: sIM311 Cn.l,. al r3Frroune urel: I01Proc..ese Id F[t: Wlrell specific accounting hea been eelabllehed end a not ladle&ted ab ve ws nsedl ph■ owWU7 11 Efw w eonwl aeoow; rating Irl all 5 accounting wd% AtKl too, or PrvYldr carnet acopwnll for 0 brad Unit and Proles 16- ;.'• LAB I Hatrli. a *x.�IB 15a11,5rdr nKAnh[ Sample Desc i tlfyn car ID I I I — 9 I _ i I L_ I 1 I I I_ I I I L [= i � I - P I WATER Eq [lPllifl` AIT-M lNK 1 PER 1 AY -Pl rw Tirvw�/�/� _ 7'- 271w.x.nyu[eNed=yri- Rallntl�rthee ®� DaINTime Raw,y.,rch®a9 Sawn. 5raled'�Lotked 4�+� QateJlime Po 11 420, , 2=11 . Q,r 3-W 4-ki V one LO v 6n , r ;irNl, I m 1 C '0 ao- Q rt P C) i--) ` to 3 Preservatives when used must he O i 14 ]+ { added within 15 minutes of sample . °� i2 C C collection ,.., F 7FJ N ifl '"C 0llect[on lnffrwrrTlation C) [L Q — ;R t] tXrlp� T}nla CDf� cl H c0 �� U) rc eu ru IlJ .�, Vr AlWUl 'T1S-- - I h R�JMNIWWN R 241Co.nrnonra ideulw Al, Sb, As, Ra, Be. B. Cd, Ca. Cr, Co, Cu, Fr, Pb, Mg. Fll1h Mo. Fill_ r5. l' a, SeTt 1i, T' lac ny.. pH` Anloniv Cl, NIICrate-N, 504 Sediment S ific Pivarnetm: %5olide- GEG, Piartlew S�IxA-C} stl lb}ut[on, Rmox Potential "Requested Turnaround �a f{