NC0003433_J15060060 Report_20150902

Lab
DUI E Analytical Laboratory APagel1aof34
ENERGY
Order Number:
Project Name:
Customer Name(s):
Customer Address:
Lab Contact:
Report Authorized By:
(Signature)
Program Comments:
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone:[phone] Fax:[phone]
Order Summary Report
J15060060
CAPE FEAR - AB GW ASSESSMENT WATER
Tim Hunsucker, Chris Suttell, Kathy Webb, John Toepfer
Mary Ann Ogle
Mary Ann Ogle
Phone: [phone]
Mary Ann Ogle
2015.06.18 16:5 7:20D a to :
-04'00'
Please contact the Program Manager (Mary Ann Ogle) with any questions regarding this report.
Data Flags & Calculations:
6/18/2015
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Sample ID's & Descriptions:
Collection
Sample ID Plant/Station Date and Time
Collected By
Sample Description
2015016952
Cape Fear 01-Jun-15 8:20 AM
Illegible ERB-34
2015016953
Cape Fear 01-Jun-15 10:50 AM
Illegible MW-15BR
2015017340
Cape Fear 01-Jun-15 10:50 AM
Illegible Filter Blank
3 Total Samples
Analytical Lab
Page 2 of 34

Analytical Lab
Page 3 of 34
Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals 0 Yes ❑ No
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits. ❑ Yes 0 No
All laboratory QA/QC requirements are acceptable. 0 Yes ❑ No
Report Sections Included:
E%-'] Job Summary Report
❑� Sample Identification
Technical Validation of Data Package
❑� Analytical Laboratory Certificate of Analysis
❑ Analytical Laboratory QC Report
❑d Sub -contracted Laboratory Results
❑ Customer Specific Data Sheets, Reports, & Documentation
❑ Customer Database Entries
❑� Chain of Custody
❑� Electronic Data Deliverable (EDD) Sent Separately
Reviewed By: Mary Ann Ogle Date: 6/18/2015

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060060
Site: ERB-34
Collection Date: 01-Jun-15 8:20 AM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter
Complete
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
UNDIGESTED METALS BY ICP
Calcium (Ca)
0.066
mg/L
0.01
Magnesium (Mg)
0.006
mg/L
0.005
Potassium (K)
< 0.1
mg/L
0.1
Sodium (Na)
< 0.05
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
< 0.005
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
< 0.005
mg/L
0.005
Strontium (Sr)
< 0.005
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
METHANE - (Analysis Performed by
Shealy Labs
Methane (CH4)
SULFIDE - (Analysis Performed by
Complete
Element One)
Vendor Parameter
Complete
Analytical Lab
Page 4 of 34
Sample #: 2015016952
Matrix: GW WW
DF Method Analysis Date/Time Analyst
Vendor Method V_SHEALY
1 EPA 245.1
06/04/2015 14:44
ACPAYNE
1 EPA 200.7
06/05/2015 11:28
MHALL3
1 EPA 200.7
06/05/2015 11:28
MHALL3
1 EPA 200.7
06/05/2015 11:28
MHALL3
1 EPA 200.7
06/05/2015 11:28
MHALL3
1 EPA 200.7
06/04/2015 15:53
MHALL3
1 EPA 200.7
06/04/2015 15:53
MHALL3
1 EPA 200.7
06/04/2015 15:53
MHALL3
1 EPA 200.7
06/04/2015 15:53
MHALL3
1 EPA 200.7
06/04/2015 15:53
MHALL3
1 EPA 200.7
06/04/2015 15:53
MHALL3
1 EPA 200.7
06/04/2015 15:53
MHALL3
1 EPA 200.8
06/10/2015 15:16
JAHERMA
1 EPA 200.8
06/10/2015 15:16
JAHERMA
1 EPA 200.8
06/10/2015 15:16
JAHERMA
1 EPA 200.8
06/10/2015 15:16
JAHERMA
1 EPA 200.8
06/10/2015 15:16
JAHERMA
1 EPA 200.8
06/10/2015 15:16
JAHERMA
1 EPA 200.8
06/10/2015 15:16
JAHERMA
1 EPA 200.8
06/10/2015 15:16
JAHERMA
1 EPA 200.8
06/10/2015 15:16
JAHERMA
1 EPA 200.8
06/10/2015 15:16
JAHERMA
1 EPA 200.8
06/10/2015 15:16
JAHERMA
1 EPA 200.8
06/10/2015 15:16
JAHERMA
1 EPA 200.8
06/10/2015 15:16
JAHERMA
Vendor Method V_SHEALY
Vendor Method V_ELE1

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060060
Site: MW-15BR
Collection Date: 01-Jun-15 10:50 AM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter
Complete
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY lCP
Aluminum (AI)
0.051
mg/L
0.005
Barium (Ba)
0.424
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
0.072
mg/L
0.005
Strontium (Sr)
0.498
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
UNDIGESTED METALS BY lCP
Calcium (Ca)
34.4
mg/L
0.01
Magnesium (Mg)
8.49
mg/L
0.005
Potassium (K)
1.48
mg/L
0.1
Sodium (Na)
36.7
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.007
mg/L
0.005
Barium (Ba)
0.429
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
0.072
mg/L
0.005
Strontium (Sr)
0.501
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Sample #: 2015016953
Matrix: GW WW
Analytical Lab
Page 5 of 34
DF Method Analysis Date/Time Analyst
Vendor Method
V_SHEALY
1 EPA 245.1
06/04/2015 14:46
ACPAYNE
1 EPA 245.1
06/10/2015 15:02
ACPAYNE
1 EPA 200.7
06/04/2015 12:16
MHALL3
1 EPA 200.7
06/04/2015 12:16
MHALL3
1 EPA 200.7
06/04/2015 12:16
MHALL3
1 EPA 200.7
06/04/2015 12:16
MHALL3
1 EPA 200.7
06/04/2015 12:16
MHALL3
1 EPA 200.7
06/04/2015 12:16
MHALL3
1 EPA 200.7
06/04/2015 12:16
MHALL3
1 EPA 200.7
06/05/2015 11:32
MHALL3
1 EPA 200.7
06/05/2015 11:32
MHALL3
1 EPA 200.7
06/05/2015 11:32
MHALL3
1 EPA 200.7
06/05/2015 11:32
MHALL3
1 EPA 200.7
06/04/2015 16:04
MHALL3
1 EPA 200.7
06/04/2015 16:04
MHALL3
1 EPA 200.7
06/04/2015 16:04
MHALL3
1 EPA 200.7
06/04/2015 16:04
MHALL3
1 EPA 200.7
06/04/2015 16:04
MHALL3
1 EPA 200.7
06/04/2015 16:04
MHALL3
1 EPA 200.7
06/04/2015 16:04
MHALL3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060060
Site: MW-15BR
Collection Date: 01-Jun-15 10:50 AM
Analyte
Result
DISSOLVED METALS BY ICP-MS
Antimony (Sb)
< 5
Arsenic (As)
6.44
Beryllium (Be)
< 5
Cadmium (Cd)
< 5
Chromium (Cr)
< 5
Cobalt (Co)
< 5
Copper (Cu)
< 5
Lead (Pb)
< 5
Molybdenum (Mo)
16.9
Nickel (Ni)
< 5
Selenium (Se)
< 5
Thallium (TI) Low Level
< 1
Vanadium (V) Low Level
1.81
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
Arsenic (As)
6.76
Beryllium (Be)
< 1
Cadmium (Cd)
< 1
Chromium (Cr)
< 1
Cobalt (Co)
< 1
Copper (Cu)
< 1
Lead (Pb)
< 1
Molybdenum (Mo)
17.0
Nickel (Ni)
< 1
Selenium (Se)
2.02
Thallium (TI) Low Level
< 0.2
Vanadium (V) Low Level
1.73
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
SULFIDE - (Analvsis Performed by
Element One)
Sample #: 2015016953
Matrix: GW WW
Analytical Lab
Page 6 of 34
Units Qualifiers
RDL
DF
Method
Analysis Date/Time
Analyst
ug/L
5
5
EPA 200.8
06/16/2015 19:36
JAHERMA
ug/L
5
5
EPA 200.8
06/16/2015 19:36
JAHERMA
ug/L
5
5
EPA 200.8
06/16/2015 19:36
JAHERMA
ug/L
5
5
EPA 200.8
06/16/2015 19:36
JAHERMA
ug/L
5
5
EPA 200.8
06/16/2015 19:36
JAHERMA
ug/L
5
5
EPA 200.8
06/16/2015 19:36
JAHERMA
ug/L
5
5
EPA 200.8
06/16/2015 19:36
JAHERMA
ug/L
5
5
EPA 200.8
06/16/2015 19:36
JAHERMA
ug/L
5
5
EPA 200.8
06/16/2015 19:36
JAHERMA
ug/L
5
5
EPA 200.8
06/16/2015 19:36
JAHERMA
ug/L
5
5
EPA 200.8
06/16/2015 19:36
JAHERMA
ug/L
1
5
EPA 200.8
06/16/2015 19:36
JAHERMA
ug/L
1.5
5
EPA 200.8
06/16/2015 19:36
JAHERMA
ug/L
1
1
EPA 200.8
06/10/2015 14:58
JAHERMA
ug/L
1
1
EPA 200.8
06/10/2015 14:58
JAHERMA
ug/L
1
1
EPA 200.8
06/10/2015 14:58
JAHERMA
ug/L
1
1
EPA 200.8
06/10/2015 14:58
JAHERMA
ug/L
1
1
EPA 200.8
06/10/2015 14:58
JAHERMA
ug/L
1
1
EPA 200.8
06/10/2015 14:58
JAHERMA
ug/L
1
1
EPA 200.8
06/10/2015 14:58
JAHERMA
ug/L
1
1
EPA 200.8
06/10/2015 14:58
JAHERMA
ug/L
1
1
EPA 200.8
06/10/2015 14:58
JAHERMA
ug/L
1
1
EPA 200.8
06/10/2015 14:58
JAHERMA
ug/L
1
1
EPA 200.8
06/10/2015 14:58
JAHERMA
ug/L
0.2
1
EPA 200.8
06/10/2015 14:58
JAHERMA
ug/L
0.3
1
EPA 200.8
06/10/2015 14:58
JAHERMA
Vendor Method V_SHEALY
Vendor Parameter Complete Vendor Method V_ELE1

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060060
Site: Filter Blank
Collection Date: 01-Jun-15 10:50 AM
Analyte
Result
Units
Qualifiers RDL
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
< 0.005
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
< 0.005
mg/L
0.005
Strontium (Sr)
< 0.005
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
DISSOLVED METALS BY ICP-MS
Antimony (Sb)
< 5
ug/L
5
Arsenic (As)
< 5
ug/L
5
Beryllium (Be)
< 5
ug/L
5
Cadmium (Cd)
< 5
ug/L
5
Chromium (Cr)
< 5
ug/L
5
Cobalt (Co)
< 5
ug/L
5
Copper (Cu)
< 5
ug/L
5
Lead (Pb)
< 5
ug/L
5
Molybdenum (Mo)
< 5
ug/L
5
Nickel (Ni)
< 5
ug/L
5
Selenium (Se)
< 5
ug/L
5
Thallium (TI) Low Level
< 1
ug/L
1
Vanadium (V) Low Level
< 1.5
ug/L
1.5
Sample #: 2015017340
Matrix: GW WW
Analytical Lab
Page 7 of 34
DF
Method
Analysis Date/Time
Analyst
1
EPA 245.1
06/10/2015 15:04
ACPAYNE
1
EPA 200.7
06/04/2015 12:20
MHALL3
1
EPA 200.7
06/04/2015 12:20
MHALL3
1
EPA 200.7
06/04/2015 12:20
MHALL3
1
EPA 200.7
06/04/2015 12:20
MHALL3
1
EPA 200.7
06/04/2015 12:20
MHALL3
1
EPA 200.7
06/04/2015 12:20
MHALL3
1
EPA 200.7
06/04/2015 12:20
MHALL3
5
EPA 200.8
06/16/2015 19:29
JAHERMA
5
EPA 200.8
06/16/2015 19:29
JAHERMA
5
EPA 200.8
06/16/2015 19:29
JAHERMA
5
EPA 200.8
06/16/2015 19:29
JAHERMA
5
EPA 200.8
06/16/2015 19:29
JAHERMA
5
EPA 200.8
06/16/2015 19:29
JAHERMA
5
EPA 200.8
06/16/2015 19:29
JAHERMA
5
EPA 200.8
06/16/2015 19:29
JAHERMA
5
EPA 200.8
06/16/2015 19:29
JAHERMA
5
EPA 200.8
06/16/2015 19:29
JAHERMA
5
EPA 200.8
06/16/2015 19:29
JAHERMA
5
EPA 200.8
06/16/2015 19:29
JAHERMA
5
EPA 200.8
06/16/2015 19:29
JAHERMA

Analytical Lab
Page 8 of 34
Element One Inc.
6319-D Carolina Beach Rd.
Wilmington, NC 284112
Phone: [phone]
Fax: [phone]
[e-mail]
REPORT OF ANALYSES
Duke Energy June 11, 2015
Laboratory Services Client Project Name AB GW Assessment water Asheville
13339 Hagers Ferry Road Bld. MG03A Client Project Number J15060060
Huntersville, NC 28078 PO Number
Sample Matrix GW WW Sample Type Grab Date Received 06/03/2015
Date Analyzed 06/04/2015 Method SM 4500 S2- D Time Received 1420
Delivered by FedEx
eOne ID Duke Energy ID Parameter Result Unit Dil
24948-1 ERB-34 (GW)
24948-2 MW-15 BR
Sulfide < 0.1 mg/L 1
Received by JRC
DL Date Time
Sampled Sampled
0.1 06/01/15 0820
Sulfide < 0.1 mg/L 1 0.1 06/01/15 1050
�76
Ken Smith, Laboratory Director
24948 Duke Report Packet Compiled by
NC Certifications: DW 37788 and DWQ DENR 604

Analytical Lab
Page 9 of 34
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elementOne SAMPLE SUBMISSION FORM
TAT 7 BD
Hold Time Expiration 06.08.15 @ 8:20
Client: Duke Energy
LIMS No J15060060
Project ID Asheville
pH >9
If No, Record
No Temps 60C Yes
If No, Record
Sample Identification & Collection Information
Analytical Lab
LatrlVo 024948
Analysis Due Date 06.05.15
Report Due Date 06.12.15
Date Rec: 06.03.15
Time Rec: 1420
Rec By J RC
No Ref. Method:
SM4500 S2 D
Lab ID Client ID Collection Date Collection Time Anal sis Requested
1 ERB-34 (GW) 06/01/15 0820
2 MW-15 BR 06/01/15 1050 Sulfide
NOTE for Sulfide The MS/MSD spike should approximate 2 to 3 times the sample concentration. If no sulfide detected
at 100 pg/L spike the sample to render the final spike concentration at — 500 pg/L
Lab Communications
All AB Groundwater Assessment jobs need a RL of 0.1
SS Page 1 of Prep By /Date 6 911 S
SS by Labeled By / Dates
6/11/201 12:56.42 PM ID Verification By/Date

Analytical Lab
Page 11 of 34
METHOD:
SM 4500 S2-'1)
ELEMENT ASSAY:
Sulfide
CLIENT:
Duke
Lab ID#
24946 / 947 / 948 /'949 / 950 / G
Date:
06/04/1.5
Time Analysis Begun
9:30
Time Analysis Ended
1140
Analyst:
KAM
X
Y -
ug STD
STD
SOLUTION
ABS
0.00
0.000
1.00
0.104
2.50
0.232
5.00
0,446
7.50
0.637
10.00 n AAn
ELEMENT ONE
Spectrophotometer
Wave Length 664
UNITS OF ANS1N
DETECTION LIMI
SPK LEVEL Lu
Na2S•9H2O Lot #
40721
MAX ALIQUOT
STANDARD conc
Cal Std Lot:
QC Std Lot:
5
X
X
�seo i
800 low 12M
x
ky� b iiy'�"
e?
,... S
AY 4
' ��
PREP
VOL in mL
10
10
10
10
10
10
Slopa 0.082362637_
Correlation 0.999221856
SAMPLE
I.D.
Std. B. 0.00
Std. & 1 AO
Std. B. 2.50
Std. B. 5.00
Std. B. 7.50
Std. B. 10.00
SAMP
ABS
0.000
0.100
0.236
0.446
0.634
0.807
ug PER
ALIQUOT
0.0000
0.8544
2.5759
5.2342
7.6139
9.8038
ALI in mL
ANALYZED
10
10
10
10
10
10
ALI in mL
TAKEN
10
10
10
10
10
10
RESULTS
ug/mL
<
<
0.258
0.523
0.761
0.980
LESS THAN
% SPK REC
85.44%
103.04%
104.68%
101.52%
98.04%
SPIKE
LEVEL
0.0
1.0
2.5
5.00
7.5
10.00
LRB
0.000
0.0000
10
10
10
<
0
LRB SPK
0.445
5.2215
10
10
10
0.522
105%
5.0
QC
0.447
5.2468
10
10
10
0.525
105%
5.0
24946-1
0.077
0,5633
10
10
10
<
24946-1 s k
0.087
0.6899
10
10
10
<
14%
5.0
24946-2
0.006
-0.3354
10
10
10
24946-2 dup
0.003
70.3734
10
10
10
< 0.1
24946-2 s k
0.440
5.1582
10
10
10
0.516
103%
5.0
24946-3
0.022
-0.1329
10
10
10
24946-3 s k
0.421
4.9177
10
10
10
0.492
98%
5.0
24947-1
0.005
-0.3481
10
10
10
24947-1 s k
0.436
5.1076
10
10
10
0.511
102%
5.0
24947-2
0.003
-0.3734
10
10
10
24947-2 s k
0.447
5.2468
10
10
10
0.525
105%
5.0
24948-1
0.001
-0.3987
10
10
10
tkw
24948-1 s k
0.463
5.4494
10
10
0.545
109%
5.0
24948-2
0.004
-0.3608
10
10
c,
24948-2 s k
0.408
4.7532
F10
10
10
0.475
95%
5.0
24949-1
0.093
0.7658
10
10
<
24949-1 s k
0.269
2.9937
10
10
0.299
60%
5.0
5.0
24949-2
0.024
-0.1076
10
10
10
0"
91 %
24949-2 s k
0.393
4.5633
10
10
10
0.456
Blank
0.000
0.0000
10
10
10 1
<
QC 0.448 5.2595 10 1
Submitted for QA/QC- Date: 06/04/15
10
By: (Print)
10 0.526
KAM
105% 5.0
(sign):
Page 1 of 4

Analytical Lab
Page 12 of 34
METHOD:
SM 4500 S2-`D.
ELEMENT ONE
ELEMENT ASSAY:
Sulfide
Spectrophotometer
Wave Length 664
UNITS OF ANSWER
ug/mL
DETECTION u
LIMITSPK
1.000
CLIENT:
Duke
LEVEL u
5
Lab ID#
24946 / 947 / 948 /' 949 / 950 / 951
Na2S•9H2O Lot #
40721
MAX ALIQUOT
10.00
Date:
06/04/15
STANDARD conc(ppm)
X
Time Analysis Begun
9:30
Cal Std Lot: WC2-86-1
10
Time Analysis Ended
11:40
QC Std Lot: WC2-86-2
10
Analyst:
KAM
ISTID ABSORPTION
Y
X
Y
0.600
ug STD
SOLUTION
STD
ABS
om
0.80
01
---
-
--
--- ----
---
---------
_..
-o�
0.00
1.00
2.50
5.00
7.50
10.00
0.000
0.104
0.232
0.446
0.637
0.830
O' 0
°°°°
0.300
_
-__---..
-
-
-----------
-,�
6.2W
.232
°°°°
0.00 2.00 4,00 6.00 &00 10.00 12.60
x
i
Sloe 0.082362637
Correlation 0.909221866
SAMPLE
I.D.
SAMP
ABS
ug PER
ALIQUOT
ALI in mL
ANALYZED
PREP
VOL in mL
ALI in mL
TAKEN
RESULTS
ug/mL
LESS THAN
% SPK REC
SPIKE
LEVEL
Std. B. 0.00
0,000
0.0000
10
10
10
<
0.0
Std. B. 1.00
0.100
0.8544
10
10
10
<
85.44%
1.0
Std. B. 2.50
0.236
2.5759
10
10
10
0.258
103.04%
2.5
Std. B. 5.00
0.446
5.2342
10
10
10
0.523
104.68%
5.00
Std. B. 7.50
0.634
7.6139
10
10
10
0.761
101.52%
7.5
Std. B. 10.00
0.807
9.8038
10
10
10
0.980
98.04%
10.00
LRB
0.000
0.0000
10
10
10
<
0
LRB SPK
0.445
5.2215
10
10
10
0.522
105%
5.0
QC
0.447
5.2468
10
10
10
0.525
5.0
24949-3
0.003
-0.3734
10
10
10
s g
24949-3 spk
0.461
5.4241
10
10
10
0.542
108%
5.0
24950-1
0.020
-0.1582
10
10
10
s �,
24950-1 dup
0.014
-0.2342
10
10
10
< 0.1
24950-1 s k
0.407
4.7405
10
10
10
0.474
95%
5.0
24950-2
0.005
-0.3481
10
10
10
24950-2 spk
0.397
4.6139
10
10
10
0.461
92%
5.0
24950-3
0.083
0.6392
10
10
10
0.530
24950-3 spk
0.451
5.2975
10
10
10
106%
5.0
24950-4
0.006
-0.3354
10
10
10
<
24950-4 s k
0.216
2.3228
10
10
10
0.232
46%
5.0
24950-5
0.004
-0.3608
10
10
10,.9
i`,k=
24950-5 s k
0.402
4.6772
10
10
10
0.468
94%
5.0
24950-6
0.004
-0.3608
10
10
10
<
24950-6 spk
0.230
2.5000
10
10
10
0.250
50%
5.0
24950-7
0.017
-0.1962
10
10
10
24950-7 spk
0.383
4.4367
10
10
10
0.444
89%
5.0
24950-8
0.013
-0.2468
10
10
10
s a 1
24950-8 spk
0.378
4.3734
10
10
10
0.437
87%
5.0
Blank
-0.001
0.0000
10
10
10
<
QC
0.447
5.2468
10
10
10
0.525
105%
5.0
Submitted for QA/QC- Date: 06/04/15
By: (Print)
KAM (sign):
P
Page 2 of 4

Analytical Lab
Page 13 of 34
METHOD:
SM 4500 S2- D
ELEMENT ONE
ELEMENT ASSAY:
Sulfide
Spectrophotometer
Wave Length 664
Na2S•9H2O Lot #
40721
------------
UNITS OF ANSWER
ug/mL
DETECTION LIMIT u
1.000
CLIENT:
Lab ID#
Duke
24946 / 947 / 948 / 949 / 950 / 951
SPK LEVEL (ug.
MAX ALIQUOT
5
10.00
Date:
06104/15
STANDARD conc(ppm)
X
Time Analysis Begun
9:30
Cal Std Lot: WC2-86-1
10
Time Analysis Ended
11:40
QC Std Lot: WC2-86-2
10
Analyst:
KAM
STD ABSORPTION-----
Y
X
Y
-------,--STD
- - - - - - -_ --
0..9m
ug STD
SOLUTION
STD
ABS
0.eo0
0.
0.700
------
-- ----
0.eo0
---
---------
- --- ---
_off
0.00
1.00
2.50
5.00
7.50
10.00
0.000
0.104
0.232
0.446
0.637
0.830
0s
°°
-zso
0.300
------
---
-----
-,�
0.2
.232
- --
0.1w
0.0w
0.00 2.00 4.00 0.00 am M00 12.o0
x
Slope 0.082362637 Correlation 0.999221856
SAMPLE SAMP
I.D. ABS
Std. B. 0.00 0.000
Std. B. 1.00 0.100
Std. B. 2.50 0.236
Std. B. 5.00 0.446
Std. B. 7.50 0.634
Std. B. 10.00 0.807
ug PER
ALIQUOT
0.0000
0.8544
2.5759
5.2342
7.6139
9.8038
ALI in mL
ANALYZED
10
10
10
10
10
10
PREP
VOL in mL
10
10
10
10
10
10
ALI in mL
TAKEN
10
10
10
10
10
10
RESULTS
u /ml-
<
<
0.258
0.523
0.761
0.980
LESS THAN
% SPK REC
85.44%
103.04%
104.68%
101.52%
98.04%
SPIKE
LEVEL
0.0
1.0
2.5
5.00
7.5
10.00
LRB
0.000
0.0000
10
10
10
<
0
LRB SPK
0.445
5.2215
10
10
10
0.522
105%
5.0
QC
0.447
5.2468
10
10
10
0.525
5.0
24950-9
0.008
-0.3101
10
10
10-
s0
24950-9 s k
0.376
4.3481
10
10
10
0.435
87%
5.0
24950-10
0.208
2.2215
10
10
10
p2
0.717
24950-10 s k
0.599
7.1709
10
10
10
99%
5.0
24950-11
0.002
-0.3861
10
10
10I
24950-11 dup
0.002
-0.3861
10
10
10
< 0.1
24950-11 s k
0.444
5.2089
10
10
10
0.521
104%
5.0
24950-12
0.004
-0.3608
10
10
10
24950-12 s k
0.450
5.2848
10
10
10
0.528
106%
5.0
24951
0.003
-0.3734
10
10
10
�01
24951 s k
0.441
5.1709
10
10
10
0.517
103%
5.0
24946-1
0.046
0.1709
10
10
5
<
24946-1 s k
0.178
1.8418
10
10
5
0.368
37%
5.0
24949-1
0.062
0.3734
10
10
5,Q
24949-1 s k
0.375
4.3354
10
10
5
0.867
87%
5.0
24950-4
0.009
-0.2975
10
10
5
<
24950-4 s k
0.303
3.4241
10
10
5
0.685
68%
5.0
24950-6
0.004
-0.3608
10
10
5
<
24950-6 s k
0.317
3.6013
10
10
5
0.720
72%
5.0
Blank
-0.001
0.0000
10
10
10
<
QC 0.444 5.2089 10
SUbmiffed for QA/QC- Date: 06/04/15
10
By: (Print)
10 0.521
KAM
104% 5.0
(sign):
//
Page 3 of 4

Analytical Lab
Page 14 of 34
METHOD:
SM 4500 S2- D
ELEMENT ONE
ELEMENT ASSAY:
Sulfide Spectrophotometer
Duke Wave Length 664
24946 / 947 / 9481949 1950 / 951
06/04/15 Na2S•9H2O Lot #
9:30 40721
11:40
KAM
- - - -- - -
UNITS OF ANSW
DETECTION LIMI
CLIENT:
Lab ID#
SPK LEVEL u
Date:
MAX ALIQUOT
STANDARD conc
Time Analysis Begun
Time Analysis Ended
Cal Std Lot:
Analyst:
QC Std Lot:
STD ABSORPTIO
--- - -----
XY
ug STD
STD
SOLUTION
ABS
0.00
0.000
1.00
0,104
2.50
0.232
5.00
0.446
7.50
0.637
X
!-86-1 10
!-86-2 7
Y
10.00
0:830
ug PER
ALIQUOT
0.0000
0.8544
2.5759
5.2342
7.6139
9.8038
ALI in mL
ANALYZED
10
10
10
10
10
10
PREP P
VOL in mL
10
10
10
10
10
10
x
Soa
ALI in mL
TAKEN
10
10
10
10
10
10
8.00 10.00
0.082362637 Correlation
RESULTS LESS THAN
u /mL %SPK REC
<
< 85.44%
0.258 103.04%
0.523 104.68%
0.761 101.52%
0.980 98.04%
Q
0.998221855
SPIKE
LEVEL
0.0
1.0
2.5
5.00
7.5
10.00
777,7
SAMPLE
I.D.
Std. B. 0.00
Std. B. 1.00
Std. B. 2.50
Std. B. 5.00
Std. B. 7.50
Std. B. 10.00
SAMP
ABS
0.000
0.100
0.236
0.446
0.634
0.807
LRB
0.000
0.0000
10
10
10
<
0
LRB SPK
0.445
5.2215
10
10
10
0.522
105%
5.0
5.0
QC
0,447
5.2468
10
10
10
0.525
105%
24946-1
0.020
-0.1582
10
10
2
<
24946-1 s k
0.310
3.5127
10
10
2
1.756
70%
5.0
24950-4
0.006
-0.3354
10
10
2
0
24950-4 s k
0.381
4.4114
10
10
2
2.206
88%
5.0
24950-6
24950-6 s k
24946-1
24946-1 spk
0.002
0.385
0.011
0.371
-0.3861
4.4620
-0.2722
4.2848
10
10
10
10
10
10
10
10
2
2
1
1
k °_
2.231
n; <
4.285
89%
5.0
F86%
5.0
Blank 0.000 0.0000 10 10 10 <
QC 0.448 5.2595 10 10 110 0.526
fed for QAX C- Date: 06/04/15 By: (Print) KAM
Page 4 of 4
105% J 5.0

SHEALY ENVIRONMENTAL SERVICES, INC.
Report of Analysis
Duke Energy
13339 Hagers Ferry Rd
Bldg 7405
Huntersville, NC 28078
Attention: Mary Ann Ogle
Project Name: AB GW Assessment Water - Cape Fear
Project Number:J15060060
Lot Number:QF03021
Date Completed:06/09/2015
Grant Wilton
Project Manager
This report shall not be reproduced, except in its entirety, without the written approval of Shealy Environmental Services, Inc.
The following non -paginated documents are considered part of this report: Chain of Custody Record and Sample Receipt Checklist.
*QF03021*
Shealy Environmental Services, Inc. Page: 1 of 8
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

SHEALY ENVIRONMENTAL SERVICES, INC.
SC DHEC No: 32010 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
Case Narrative
Duke Energy
Lot Number: QF03021
Project Name: AB GW Assessment Water - Cape Fear
Project Number: J15060060
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample
receiving date is documented in the header information associated with each sample.
All results listed in this report relate only to the samples that are contained within this report.
Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the
Shealy Environmental Services, Inc. ("Shealy") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPS), and Shealy
policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below.
If you have any questions regarding this report please contact the Shealy Project Manager listed on the cover page
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SHEALY ENVIRONMENTAL SERVICES, INC.
Sample Summary
Duke Energy
Lot Number: QF03021
Project Name: AB GW Assessment Water - Cape Fear
Project Number: J15060060
Sample Number Sample ID Matrix Date Sampled Date Received
001 2015016952 Aqueous 06/01/2015 0820 06/03/2015
002 2015016953 Aqueous 06/01/20151050 06/03/2015
(2 samples)
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SHEALY ENVIRONMENTAL SERVICES, INC.
Executive Summary
Duke Energy
Lot Number: QF03021
Project Name: AB GW Assessment Water - Cape Fear
Project Number: J15060060
Sample Sample ID
Matrix Parameter Method Result Q
Units
Page
002 2015016953
Aqueous Alkalinity SM 2320B- 150
mg/L
7
002 2015016953
Aqueous Bicarbonate Alkalinity SM 2320B- 150
mg/L
7
002 2015016953
Aqueous Methane RSK - 175 14
ug/L
8
(3 detections)
Shealy Environmental Services, Inc. Page: 4 of 8
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Inorganic non-metals
Client: Duke Energy Laboratory ID: QF03021-001
Description: 2015016952 Matrix: Aqueous
Date Sampled:06/01/2015 0820 Project Name: AB GW Assessment Water -
Date Received:06/03/2015 Project Number: J15060060
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 2320B-2011
1 06/04/2015 2320
HMA 76563
1
(Bicarbonate ) SM 2320B-2011
1 06/04/2015 2320
HMA
1
(Carbonate Al) SM 2320B-2011
1 06/04/2015 2320
HMA
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
ND
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Methane
Client: Duke Energy Laboratory ID: QF03021-001
Description: 2015016952 Matrix: Aqueous
Date Sampled:06/01/2015 0820 Project Name: AB GW Assessment Water -
Date Received:06/03/2015 Project Number: J15060060
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 06/04/2015 2318 JJG 76593
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Inorganic non-metals
Client: Duke Energy Laboratory ID: QF03021-002
Description: 2015016953 Matrix: Aqueous
Date Sampled:06/01/2015 1050 Project Name: AB GW Assessment Water -
Date Received:06/03/2015 Project Number: J15060060
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 2320B-2011
1 06/04/2015 2326
HMA 76563
1
(Bicarbonate ) SM 2320B-2011
1 06/04/2015 2326
HMA
1
(Carbonate Al) SM 2320B-2011
1 06/04/2015 2326
HMA
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
150
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
150
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Methane
Client: Duke Energy Laboratory ID: QF03021-002
Description: 2015016953 Matrix: Aqueous
Date Sampled:06/01/2015 1050 Project Name: AB GW Assessment Water -
Date Received:06/03/2015 Project Number: J15060060
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 06/05/2015 1307 DCS 76634
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 14 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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QC Summary
Shealy Environmental Services, Inc. QC Data for Lot Number: QF03021
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals - Ii
Sample ID: QQ76563-001 Matrix: Aqueous
Batch: 76563
Analytical Method: SM 2320B-2011
Parameter Result Q Dil PQL Units Analysis Date
Alkalinity ND 1 10 mg/L 06/04/2015 2153
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QF03021
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Inorganic non-metals - LCS
Sample ID: QQ76563-002 Matrix: Aqueous
Batch: 76563
Analytical Method: SM 2320B-2011
Spike
Amount Result % Rec
Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Alkalinity 100 98 1 98 90-110 06/04/2015 2159
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QF03021
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane - MB
Sample ID: QQ76593-001 Matrix: Aqueous
Batch: 76593
Analytical Method: RSK - 175
Parameter Result Q Dil PQL Units Analysis Date
Methane ND 1 10 ug/L 06/04/2015 2042
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QF03021
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane - LCS
Sample ID: QQ76593-002 Matrix: Aqueous
Batch: 76593
Analytical Method: RSK - 175
Spike
Amount Result % Rec
Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date
Methane 50 48 1 94 70-130 06/04/2015 2015
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QF03021
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane - LCSD
Sample ID: QQ76593-003 Matrix: Aqueous
Batch: 76593
Analytical Method: RSK - 175
Spike
Amount Result % Rec % RPD
Parameter (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date
Methane 50 44 1 88 6.7 70-130 30 06/04/2015 2031
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QF03021
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane - MB
Sample ID: QQ76634-001 Matrix: Aqueous
Batch:76634
Analytical Method: RSK - 175
Parameter Result Q Dil PQL Units Analysis Date
Methane ND 1 10 ug/L 06/05/2015 0944
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QF03021
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane - LCS
Sample ID: QQ76634-002 Matrix: Aqueous
Batch:76634
Analytical Method: RSK - 175
Spike
Amount Result % Rec
Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date
Methane 50 50 1 100 70-130 06/05/2015 0921
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QF03021
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane - LCSD
Sample ID: QQ76634-003 Matrix: Aqueous
Batch:76634
Analytical Method: RSK - 175
Spike
Amount Result % Rec % RPD
Parameter (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date
Methane 50 50 1 99 1.1 70-130 30 06/05/2015 0934
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QF03021
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

SHEALY ENVIRONMENTAL SERVICES, INC.
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Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

SHEALY ENVIRONMENTAL SERVICES, INC.
SheatyEnvimwnerital15mviecE, 1W. Pale 1 orl
fWurwnr +Tumbw: F-A -01-6 Kcpha:- s Mw 11.10M4
RLvNk )ri Neii9bu: 17 15ON w: Paw. r1VJWl J
IC
am le Receipt Checklist (SRC)
Client- a lm Inspcctal by.'date; : f V-;A-; Lot A: 0.11
I
hl °.ans of receipt: ❑ SESl L]
licnl UPS ❑ redF.x © Airbornc Exp ()thcr
yrs
QJNo
1, we'
. ad , seals presont on the cooler?
U I NTO L1 I 2, if c
Cooler UXO`,,rigital temperature upon
lviebod� ❑ Temperature > lank [
Method of coolant: [ Wet Ice
sto
seals w prx erl# were t11e intact and unbroken?
t{Lie veri (eorrected) temperslure upon rorxipl:
1# otdas IR Gun ID: YR Gun C rreerinn Fac arr_ D OC
Slut Ire lee LJ No=
m
gain
F
Yes ❑
No ❑
CIA
3. If temperatilike
PM nol
(F-rr cap
i mimed
of any coolcr cxeccdod 6.0'C, was Project l+ Mager reotit ed7
iicd Py SRC, phunc, ijol[e (circle one), [ikllel"-
]crs Tcceived via commercial courier, Phis are to be nvtiRed
atel )
Yes
No ❑
NA
4_ is the c
omn=ial courier's pad:inj s4 attached to this fo n?
Yew
Na ❑
5. W=u
etlstald ' rocedures rclin uishcdAuceived) folluwcd?
Yes. ❑
No
A
.Sa
x _ ks Telinquighed by client to corarnereial courier?
Ycs
No ❑
b. V4'erc s
in2 il)s listed on the C7
YeS
No
T Wore s
unple. Ws listed on all sample contairl=s7 '
Yc%�
'a ❑
8. 'Nas 1~ .11cclkun
date & time lined QU the i C?
Yes.
NO
9, Was cc
l leetxon date &. time listed on all sampic contaium?
Y'-s
N' ❑
10. Nd al
container label intormaiti,tiri (II}, date time) agree with the C 7
Yes
149 ❑
�J l- Were
csASt..0 tw, perrOMcd IitilcNl iFTI the COC"?
Ye-;
NO ❑
12_ Did al
arrive. iu the pxopex containers. for each tea?
Ycs 9,No
13, Did al
c&n airlers arrive iu good c€ndihon LLntcken, lids o-n etcJ;"
Yes
No ❑
14. Was a
1equate sayer le volume available?
yag
No
15. Were
co
L11 sajnples received within V:s the holding time or 48 hours, wbichurver
5 pies containers naismi
ym ❑
mo
16. Were
Yes
N.
l"�_ Were
ere umc_ss samples not listed on COC:�
ubb s t >`' a -sine" (14"or 6mm in diameter) in any VOA Kraals?
Yes
No
1'A ❑
18. Wye
Y cs ❑
No ❑
NA
199_ crc
ll m�hdl JO&GlHENL'nutrient samples received at a of<2?
Yea ❑
Nn 0
NA
20, Were
all cyanide an&or sulfide sarrr l" received at a PH >l2'?
applicable NH3e'T1C Icy�lnide}phenal (r--0.-mg,'L) samples free of
Yes C]
No ❑
NA
21, Wcrc
residel-01krstle?
Yes
No []
NA
22. Were
plLection ecru eratures doeumcrtrnd on the CIAO for NC sum les7
Yes ❑
No ❑,;bHe
NA
Were
etc---o
liens rcmarles requests (i_e_ rcc} rr uls:,liluticxns A1Sr`[4iSD designations,
ectly tramseribcd from the C inLo the oclmmcrtt scctioa in LIly1S
Yes
No
246
x
e number used taken from the eo�ntainex iahcl?
Sawple Preservation (Mast
plet
for any sa les) inwrii ec ly preserved or with headspace. )
S ,upl�(s
aeeure3iT1 itr vam ie'receivin with
were reotived i=orro tly preserved and were adjusted
(H2S0,t BN03,BCI NaQH) using SR 1
Sa1m !e s
were rcccivcd with bubbics >6 mm in di;:mcter_
le
w= rcccivc€1 with TRC >0,2 m if #21 is No
SC Drinking Watzr Project Sarnplc(s)
S to s Wry nol
pH V: eHfred Lo be > 2 by -- - Dalu:
cxl Ut a PH ul =2 al_l(l w aeljuslc;l iK'rQrJift9lX Basin g SR4
Samplc labels a iced by:
Verif W- by: DaltG-
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Ci-iAit: u, ..,;STORY RLCORD E.. IS REQUEST FORM
I Duke Energy Analytlwlltborttory
Duke Energy
Analytical Laboratory
Mali Code MGoMZ IBmldlea 7495)
13339 Hyce Ferry Rd
Chain of Custody &
He WSVIIW N C. MOTI
Sample Log
U"`I $T6-521S
F.s:J7M, B75da]. ..............
AS GW Assessment'JUR'rlCr Pn"ne N`
Willem
Fa Ne
880-876-803Z
Business Unit:
^"°""'
a"`P'c"t.T".
-
Pretest M: - -
Axlhft 1e:
Met Cuter
MG03A3
amrlwdr: - -
3.a"n: Cape Fear
Analytical LaborittDIV
Uwe
Orderp
MatrIK GW_4VW
rw„w.o,n,M,MeF,om
NC x—
0
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,L02g0dBy III" d'Time 1-7
;- '+� ��!_y v
SAMPLE
Ground MNatar_
PROGRAM
NPDES
�Verldor `r
DrinklrV WaterT
UST_
I
element 1
RCRA Waste
._.._.._.._.._.._..
n (0.45 um)
Unfiltered
n 133
ct
TO 112
u,C
'reservative
Ice
Ice
Ice
N39�W
Ice
W,w
'olume (nnL)
2000
40 ml
300
to
500
500
AO mL
SHEALY )ntainer Type
PET
glass
PET
PET
PET
PET
glass
Page _1_ ot_1_
DISTRIBUTION
ORIGINAL to LAB, COPY to CLIENT
.CGC REV DATE 1/2212015
6irercd-_-
P© 1142089
m
0Y
Sample Description or ID
�'
.ale
`$
d 0
N R
Collection Information
GPS Location
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tq
to
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Yz
V
V
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1
t
ay
Ln Cu
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Date Time
Y
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Filter Blank
JAW— By: ,4
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DatelTi
DatelTir
EL EMFN-. 7, by iGs Ia5 (TRM): sag. Be. C-4, C... C:, Co. go, N1. I"v, Sb. Se, 'LL". `:
ELEMENTS by ICP (TRM): Al, Ba, B. Fs, Mn, Sr, Zn ICP_Undigested Ca, Mg, K`Na Mg by L46.1
Dissolved metals: all metals ICP, l MS,Hq
0
1 g
l 0
1 1
I 2
I 0'
14
Total' 14
Requested Turnaround
*14 Days r
7 Days
49 Hr
'Other ASAP
'Add. Cost Will Apply
Analytical Lab
Page 34 of 34