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Home My WebLink AboutNC0003433_J15060058 Report_20150902+ DUKE Analytical Laboratory 1 of60 ENERGY Order Number: Project Name: Customer Name(s): Customer Address: Lab Contact: Report Authorized By: (Signature) Program Comments: 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone:980-875-5245 Fax:980-875-4349 Order Summary Report J15060058 CAPE FEAR - AB GW ASSESSMENT SOIL Tim Hunsucker, Chris Suttell, Kathy Webb, John Toepfer Margaret Galvin -Karr Margaret Galvin -Karr MXG4644 (101 161) 2015.07.06 08:00:29 -04'00' Phone: 980-875-5219 Date: Please contact the Program Manager (Margaret Galvin -Karr) with any questions regarding this report. Data Flags & Calculations: 7/6/2015 Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Sample ID's & Descriptions: Collection Sample ID Plant/Station Date and Time Collected By Sample Description 2015016945 Cape Fear 30-May-15 3:40 PM Chris S. MW-6BRSB(0-2) 2015016949 Cape Fear 30-May-15 5:55 PM Chris S. MW-6BRSB(6-7) 2015016950 Cape Fear 30-May-15 5:15 PM Chris S. MW-6BRSB(14-16) 2015016951 Cape Fear 30-May-15 Chris S. Soil-Dup-07 4 Total Samples 2 of 60 3 of 60 Technical Validation Review Checklist: COC and .pdf report are in agreement with sample totals Yes No and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. ❑ Yes❑ No All laboratory QA/QC requirements are acceptable.❑ Yes ❑ No Report Sections Included: U Job Summary Report ❑ Sample Identification n Technical Validation of Data Package ❑ Analytical Laboratory Certificate of Analysis ❑ Analytical Laboratory QC Report Sub -contracted Laboratory Results ❑ Customer Specific Data Sheets, Reports, & Documentation ❑ Customer Database Entries 66 Chain of Custody [I/0] Electronic Data Deliverable (EDD) Sent Separately Reviewed By: Margaret Galvin -Karr Date: 7/6/2015 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060058 Site: MW-6BRSB(0-2) Collection Date: 30-May-15 3:40 PM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 4 of 60 Sample #: 2015016945 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060058 Site: MW-6BRSB(6-7) Collection Date: 30-May-15 5:55 PM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 5 of 60 Sample #: 2015016949 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060058 Site: MW-6BRSB(14-16) Collection Date: 30-May-15 5:15 PM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 6 of 60 Sample #: 2015016950 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060058 Site: Soil-Dup-07 Collection Date: 30-May-15 Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 7 of 60 Sample #: 2015016951 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kigc&y&e. Suite 100 Huntersville, INC 28078 (704)875-9092 July 03, 2015 Program Manager Duke Energy 13339 Hagers Ferry Road Bldg.7405 MG30A2 Huntersville, NC 28078 RE: Project: J 15060058 Pace Project No.: 92252541 Dear Program Manager: Enclosed are the analytical results for sample(s) received by the laboratory on June 02, 2015. The results relate only to the samples included in this report. Results reported herein conform to the most current TN standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Herring kevin.herring@pacelabs.com HORIZON Database Administrator Enclosures cc: Marge Galvin -Karr, Duke Energy Program Manager, Duke Energy Mary Ann Ogle, Duke Energy Rodney Wilke, Duke Energy p«FO REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, lqe� �� without the written consent of Pace Analytical Services, Inc.. BRAT, Page 1 of 52 lacmnalyfica( www.pacelabs.com Pace Analytical Services, Inc. 9800 Kinf&e. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15060058 Pace Project No.: 92252541 Minnesota Certification IDs 1700 Elm Street SE Suite 200, Minneapolis, MN 55414 A21-A Certification #: 2926.01 Alaska Certification #: UST-078 Alaska Certification #MN00064 Alabama Certification #40770 Arizona Certification #: AZ-0014 Arkansas Certification #: 88-0680 California Certification #: 01155CA Colorado Certification #Pace Connecticut Certification #: PH-0256 EPA Region 8 Certification #: 8TMS-L Florida/NELAP Certification #: E87605 Guam Certification #:14-008r Georgia Certification #: 959 Georgia EPD #: Pace Idaho Certification #: MN00064 Hawaii Certification #MN00064 Illinois Certification #: 200011 Indiana Certification#C-MN-01 Iowa Certification #: 368 Kansas Certification #: E-10167 Kentucky Dept of Envi. Protection - DW #90062 Kentucky Dept of Envi. 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Page 2 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ff�i�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 CERTIFICATIONS Project: J15060058 Pace Project No.: 92252541 Asheville Certification IDs West Virginia Certification #: 356 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 3 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ff�in� c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: J15060058 Pace Project No.: 92252541 Lab ID Sample ID Matrix Date Collected Date Received 92252541001 2015016945 Solid 05/30/1515:40 06/02/15 16:30 92252541002 2015016949 Solid 05/30/1517:55 06/02/15 16:30 92252541003 2015016950 Solid 05/30/1517:15 06/02/15 16:30 92252541004 2015016951 Solid 05/30/15 00:00 06/02/15 16:30 92252541005 2015016945 SPLP Water 05/30/15 15:40 06/02/15 16:30 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 4 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffli�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: J15060058 Pace Project No.: 92252541 Lab ID Sample ID Method Analysts Analytes Reported Laboratory 92252541001 2015016945 EPA 6010 CKJ 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA 7471 TAP 1 PASI-O ASTM D2974-87 MLO 1 PASI-O EPA 9045 MAB 1 PASI-A EPA 300.0 AES2 1 PASI-A EPA 353.2 DMN 1 PASI-A SM 4500-CI-E SER 1 PASI-A EPA 9056 CMB 2 PASI-O EPA 9056 CMB 1 PASI-O EPA 9060 Modified TJJ 4 PASI-G 92252541002 2015016949 EPA 6010 CKJ 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA 7471 TAP 1 PASI-O ASTM D2974-87 MLO 1 PASI-O EPA 9045 MAB 1 PASI-A EPA 9056 CMB 2 PASI-O EPA 9056 CMB 1 PASI-O EPA 9060 Modified TJJ 4 PASI-G 92252541003 2015016950 EPA 6010 CKJ 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA 7471 TAP 1 PASI-O ASTM D2974-87 MLO 1 PASI-O EPA 9045 MAB 1 PASI-A EPA 9056 CMB 2 PASI-O EPA 9056 CMB 1 PASI-O EPA 9060 Modified TJJ 4 PASI-G 92252541004 2015016951 EPA 6010 CKJ 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA 7471 TAP 1 PASI-O ASTM D2974-87 MLO 1 PASI-O EPA 9045 MAB 1 PASI-A EPA 9056 CMB 2 PASI-O EPA 9056 CMB 1 PASI-O EPA 9060 Modified TJJ 4 PASI-G 92252541005 2015016945 SPLP EPA 6020A RJS 24 PASI-M EPA 7470A LMW 1 PASI-M REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 5 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffli�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15060058 Pace Project No.: 92252541 Lab Sample ID Client Sample ID Method Parameters SUMMARY OF DETECTION Result Units Report Limit Analyzed 92252541001 2015016945 EPA 6010 Aluminum 9800 mg/kg 30.4 06/10/15 16:10 EPA 6010 Barium 100 mg/kg 3.0 06/10/15 16:10 EPA 6010 Beryllium 0.58 mg/kg 0.30 06/10/15 16:10 EPA 6010 Calcium 442 mg/kg 152 06/10/15 16:10 EPA 6010 Chromium 18.7 mg/kg 1.5 06/10/15 16:10 EPA 6010 Copper 12.7 mg/kg 1.5 06/10/15 16:10 EPA 6010 Iron 18900 mg/kg 12.2 06/10/15 16:10 EPA 6010 Magnesium 1840 mg/kg 152 06/10/15 16:10 EPA 6010 Manganese 1080 mg/kg 1.5 06/10/15 16:10 EPA 6010 Nickel 6.9 mg/kg 1.5 06/10/15 16:10 EPA 6010 Strontium 8.6 mg/kg 3.0 06/10/15 16:10 EPA 6010 Zinc 27.6 mg/kg 6.1 06/10/15 16:10 EPA 6020 Cobalt 17.5 mg/kg 6.1 06/10/15 11:09 EPA 6020 Lead 10.6 mg/kg 6.1 06/10/15 11:09 EPA 6020 Vanadium 50.2 mg/kg 6.1 06/10/15 11:09 EPA 7471 Mercury 0.050 mg/kg 0.0094 06/09/15 12:35 ASTM D2974-87 Percent Moisture 14.6 % 0.10 06/10/15 08:16 EPA 9045 pH at 25 Degrees C 5.5 Std. Units 0.10 06/08/15 15:55 EPA 300.0 Sulfate 16.4 mg/L 2.3 06/16/15 16:55 SM 4500-CI-E Chloride 5.1J mg/L 5.9 06/18/15 05:01 EPA 9056 Sulfate 145J mg/kg 287 06/06/15 12:59 EPA 9060 Modified RPD% 5.5 % 0.10 06/25/15 15:39 EPA 9060 Modified Total Organic Carbon 4660 mg/kg 699 06/25/15 15:39 EPA 9060 Modified Total Organic Carbon 4930 mg/kg 698 06/25/15 15:44 EPA 9060 Modified Mean Total Organic Carbon 4790 mg/kg 698 06/25/15 15:39 92252541002 2015016949 EPA 6010 Aluminum 9740 mg/kg 30.6 06/10/15 16:14 EPA 6010 Barium 49.7 mg/kg 3.1 06/10/15 16:14 EPA 6010 Beryllium 0.65 mg/kg 0.31 06/10/15 16:14 EPA 6010 Calcium 1040 mg/kg 153 06/10/15 16:14 EPA 6010 Chromium 15.0 mg/kg 1.5 06/10/15 16:14 EPA 6010 Copper 11.9 mg/kg 1.5 06/10/15 16:14 EPA 6010 Iron 20200 mg/kg 12.2 06/10/15 16:14 EPA 6010 Magnesium 3370 mg/kg 153 06/10/15 16:14 EPA 6010 Manganese 489 mg/kg 1.5 06/10/15 16:14 EPA 6010 Nickel 9.9 mg/kg 1.5 06/10/15 16:14 EPA 6010 Potassium 691 mg/kg 306 06/10/15 16:14 EPA 6010 Sodium 596 mg/kg 306 06/10/15 16:14 EPA 6010 Strontium 15.7 mg/kg 3.1 06/10/15 16:14 EPA 6010 Zinc 31.1 mg/kg 6.1 06/10/15 16:14 EPA 6020 Cobalt 12.8 mg/kg 6.1 06/10/15 11:12 EPA 6020 Lead 9.6 mg/kg 6.1 06/10/15 11:12 EPA 6020 Vanadium 48.0 mg/kg 6.1 06/10/15 11:12 EPA 7471 Mercury 0.013 mg/kg 0.0099 06/09/15 12:37 ASTM D2974-87 Percent Moisture 16.9 % 0.10 06/10/15 08:16 EPA 9045 pH at 25 Degrees C 8.2 Std. Units 0.10 06/08/15 15:55 EPA 9060 Modified RPD% 1.4 % 0.10 06/25/15 16:14 REPORT OF LABORATORY ANALYSIS B D3 Qualifiers This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 6 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 fflic&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15060058 Pace Project No.: 92252541 Lab Sample ID Client Sample ID Method Parameters SUMMARY OF DETECTION Result Units Report Limit Analyzed Qualifiers 92252541002 2015016949 EPA 9060 Modified Total Organic Carbon 582J mg/kg 722 06/25/15 16:14 EPA 9060 Modified Total Organic Carbon 5901 mg/kg 727 06/25/15 16:21 EPA 9060 Modified Mean Total Organic Carbon 586J mg/kg 725 06/25/15 16:14 92252541003 2015016950 EPA 6010 Aluminum 4720 mg/kg 32.0 06/10/15 16:18 EPA 6010 Barium 49.5 mg/kg 3.2 06/10/15 16:18 EPA 6010 Beryllium 0.35 mg/kg 0.32 06/10/15 16:18 EPA 6010 Calcium 937 mg/kg 160 06/10/15 16:18 EPA 6010 Chromium 8.2 mg/kg 1.6 06/10/15 16:18 EPA 6010 Copper 4.8 mg/kg 1.6 06/10/15 16:18 EPA 6010 Iron 13600 mg/kg 12.8 06/10/15 16:18 EPA 6010 Magnesium 1530 mg/kg 160 06/10/15 16:18 EPA 6010 Manganese 275 mg/kg 1.6 06/10/15 16:18 EPA 6010 Nickel 6.1 mg/kg 1.6 06/10/15 16:18 EPA 6010 Potassium 303J mg/kg 320 06/10/15 16:18 EPA 6010 Strontium 9.7 mg/kg 3.2 06/10/15 16:18 EPA 6010 Zinc 17.7 mg/kg 6.4 06/10/15 16:18 EPA 6020 Cobalt 6.7 mg/kg 6.4 06/10/15 11:14 EPA 6020 Lead 4.6J mg/kg 6.4 06/10/15 11:14 EPA 6020 Vanadium 21.3 mg/kg 6.4 06/10/15 11:14 ASTM D2974-87 Percent Moisture 22.6 % 0.10 06/10/15 08:16 EPA 9045 pH at 25 Degrees C 7.2 Std. Units 0.10 06/08/15 15:55 EPA 9060 Modified RPD% 6.9 % 0.10 06/25/15 16:26 EPA 9060 Modified Total Organic Carbon 421J mg/kg 769 06/25/15 16:26 EPA 9060 Modified Total Organic Carbon 393J mg/kg 770 06/25/15 16:35 EPA 9060 Modified Mean Total Organic Carbon 407J mg/kg 769 06/25/15 16:26 92252541004 2015016951 EPA 6010 Aluminum 9820 mg/kg 29.1 06/10/15 16:22 EPA 6010 Barium 79.8 mg/kg 2.9 06/10/15 16:22 EPA 6010 Beryllium 0.55 mg/kg 0.29 06/10/15 16:22 EPA 6010 Calcium 1060 mg/kg 145 06/10/15 16:22 EPA 6010 Chromium 15.7 mg/kg 1.5 06/10/15 16:22 EPA 6010 Copper 11.4 mg/kg 1.5 06/10/15 16:22 EPA 6010 Iron 17000 mg/kg 11.6 06/10/15 16:22 EPA 6010 Magnesium 3500 mg/kg 145 06/10/15 16:22 EPA 6010 Manganese 343 mg/kg 1.5 06/10/15 16:22 EPA 6010 Nickel 9.6 mg/kg 1.5 06/10/15 16:22 EPA 6010 Potassium 694 mg/kg 291 06/10/15 16:22 EPA 6010 Sodium 621 mg/kg 291 06/10/15 16:22 EPA 6010 Strontium 17.0 mg/kg 2.9 06/10/15 16:22 EPA 6010 Zinc 31.6 mg/kg 5.8 06/10/15 16:22 EPA 6020 Cobalt 10.8 mg/kg 5.8 06/10/15 11:21 EPA 6020 Lead 8.0 mg/kg 5.8 06/10/15 11:21 EPA 6020 Vanadium 37.9 mg/kg 5.8 06/10/15 11:21 EPA 7471 Mercury 0.011 mg/kg 0.0096 06/09/15 12:41 ASTM D2974-87 Percent Moisture 16.2 % 0.10 06/10/15 08:16 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 7 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffli�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15060058 Pace Project No.: 92252541 Lab Sample ID Method Client Sample ID Parameters 92252541004 2015016951 EPA 9045 pH at 25 Degrees C EPA 9060 Modified RPD% EPA 9060 Modified Total Organic Carbon EPA 9060 Modified Total Organic Carbon EPA 9060 Modified Mean Total Organic Carbon 92252541005 2015016945 SPLP EPA 6020A Aluminum EPA 6020A Arsenic EPA 6020A Barium EPA 6020A Beryllium EPA 6020A Boron EPA 6020A Calcium EPA 6020A Chromium EPA 6020A Cobalt EPA 6020A Copper EPA 6020A Iron EPA 6020A Lead EPA 6020A Magnesium EPA 6020A Manganese EPA 6020A Molybdenum EPA 6020A Nickel EPA 6020A Potassium EPA 6020A Selenium EPA 6020A Sodium EPA 6020A Strontium EPA 6020A Thallium EPA 6020A Vanadium EPA 6020A Zinc EPA 7470A Mercury SUMMARY OF DETECTION Result Units Report Limit Analyzed Qualifiers 8.4 Std. Units 0.10 06/08/15 15:55 13.1 % 0.10 06/25/1516:41 506J mg/kg 722 06/25/1516:41 577J mg/kg 719 06/25/1516:47 541J mg/kg 721 06/25/1516:41 12500 ug/L 10.0 07/01/15 00:51 1.7 ug/L 0.50 07/01/15 00:51 350 ug/L 0.30 07/01/15 00:51 0.85 ug/L 0.20 07/01/15 00:51 60.1 ug/L 5.0 07/01/15 00:51 979 ug/L 40.0 07/02/15 08:38 13.3 ug/L 0.50 07/01/15 00:51 6.1 ug/L 0.50 07/01/15 00:51 12.3 ug/L 1.0 07/01/15 00:51 12500 ug/L 50.0 07/01/15 00:51 8.2 ug/L 0.10 07/01/15 00:51 2380 ug/L 10.0 07/01/15 00:51 313 ug/L 0.50 07/01/15 00:51 0.13J ug/L 0.50 07/01/15 00:51 6.0 ug/L 0.50 07/01/15 00:51 394 ug/L 50.0 07/01/15 00:51 1.6 ug/L 0.50 07/01/15 00:51 9360 ug/L 50.0 07/01/15 00:51 19.9 ug/L 0.50 07/01/15 00:51 0.068J ug/L 0.10 07/01/15 00:51 40.8 ug/L 1.0 07/01/15 00:51 112 ug/L 5.0 07/01/15 00:51 0.038J ug/L 0.20 07/01/1518:01 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 8 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffli�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060058 Pace Project No.: 92252541 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: July 03, 2015 General Information: 4 samples were analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/24583 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92252534002 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1235380) • Aluminum • Barium • Iron • Manganese • MSD (Lab ID: 1235381) • Aluminum • Barium • Copper • Iron • Manganese Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 9 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ff�ic&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060058 Pace Project No.: 92252541 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: July 03, 2015 Batch Comments: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. • QC Batch: ICP / 15013 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 10 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffligc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060058 Pace Project No.: 92252541 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: July 03, 2015 General Information: 4 samples were analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/24584 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92252534002 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • MS (Lab ID: 1235384) • Antimony • Cadmium • Vanadium • MSD (Lab ID: 1235385) • Antimony • Cadmium • Cobalt • Selenium • Vanadium Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 11 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffii�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060058 Pace Project No.: 92252541 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: July 03, 2015 Batch Comments: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. • QC Batch: ICPM / 9967 Analyte Comments: QC Batch: MPRP/24584 N2: The lab does not hold TNI accreditation for this parameter. •2015016945 (Lab ID:92252541001) • Antimony •2015016949 (Lab ID:92252541002) • Antimony •2015016950 (Lab ID:92252541003) • Antimony •2015016951 (Lab ID:92252541004) • Antimony • BLANK (Lab ID: 1235382) • Antimony • LCS (Lab ID: 1235383) • Antimony • MS (Lab ID: 1235384) • Antimony • MSD (Lab ID: 1235385) • Antimony REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 12 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KP�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060058 Pace Project No.: 92252541 Method: EPA 6020A Description: 6020A MET ICPMS Client: Duke Energy Date: July 03, 2015 General Information: 1 sample was analyzed for EPA 6020A. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3020 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 13 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K�nic&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060058 Pace Project No.: 92252541 Method: EPA 7470A Description: 7470A Mercury Client: Duke Energy Date: July 03, 2015 General Information: 1 sample was analyzed for EPA 7470A. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7470A with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 14 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KP�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060058 Pace Project No.: 92252541 Method: EPA 7471 Description: 7471 Mercury Client: Duke Energy Date: July 03, 2015 General Information: 4 samples were analyzed for EPA 7471. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7471 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 15 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KP�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060058 Pace Project No.: 92252541 Method: EPA 9045 Description: 9045 pH Soil Client: Duke Energy Date: July 03, 2015 General Information: 4 samples were analyzed for EPA 9045. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Duplicate Sample: All duplicate sample results were within method acceptance criteria with any exceptions noted below. QC Batch: WET/37905 D6: The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits. • DUP (Lab ID: 1476410) • pH at 25 Degrees C Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 16 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KPc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060058 Pace Project No.: 92252541 Method: EPA 300.0 Description: 300.0 IC Anions, SPLP Client: Duke Energy Date: July 03, 2015 General Information: 1 sample was analyzed for EPA 300.0. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. QC Batch: WETA/23324 B: Analyte was detected in the associated method blank. • BLANK for HBN 268289 [WETA/233 (Lab ID: 1485896) • Sulfate Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 17 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KP�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060058 Pace Project No.: 92252541 Method: EPA 353.2 Description: 353.2 Nitrogen, NO2/NO3, SPLP Client: Duke Energy Date: July 03, 2015 General Information: 1 sample was analyzed for EPA 353.2. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 111: Analysis conducted outside the EPA method holding time. •2015016945 (Lab ID:92252541001) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 18 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K��c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060058 Pace Project No.: 92252541 Method: SM 4500-CI-E Description: 4500 Chloride, SPLP Client: Duke Energy Date: July 03, 2015 General Information: 1 sample was analyzed for SM 4500-CI-E. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: WETA/23354 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92252532003 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1487999) • Chloride • MSD (Lab ID: 1488000) • Chloride Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 19 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060058 Pace Project No.: 92252541 Method: EPA 9056 Description: 9056 IC Anions Client: Duke Energy Date: July 03, 2015 General Information: 4 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/47029 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015016945 (Lab ID:92252541001) • Chloride • Sulfate •2015016949 (Lab ID:92252541002) • Chloride • Sulfate •2015016950 (Lab ID:92252541003) • Chloride • Sulfate •2015016951 (Lab ID:92252541004) • Chloride • Sulfate REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 20 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KPgc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060058 Pace Project No.: 92252541 Method: EPA 9056 Description: 9056 IC Anions 48hr Client: Duke Energy Date: July 03, 2015 General Information: 4 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 113: Sample was received or analysis requested beyond the recognized method holding time. •2015016945 (Lab ID:92252541001) •2015016949 (Lab ID:92252541002) •2015016950 (Lab ID:92252541003) •2015016951 (Lab ID:92252541004) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/47028 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015016945 (Lab ID:92252541001) • Nitrate as N •2015016949 (Lab ID:92252541002) • Nitrate as N •2015016950 (Lab ID:92252541003) • Nitrate as N •2015016951 (Lab ID:92252541004) • Nitrate as N REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 21 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K��c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060058 Pace Project No.: 92252541 Method: EPA 9060 Modified Description: Total Organic Carbon Client: Duke Energy Date: July 03, 2015 General Information: 4 samples were analyzed for EPA 9060 Modified. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: This data package has been reviewed for quality and completeness and is approved for release. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 22 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K3�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15060058 Pace Project No.: 92252541 Sample: 2015016945 Lab ID: 92252541001 Collected: 05/30/15 15:40 Received: 06/02/15 16:30 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Aluminum Barium Beryllium Boron Calcium Chromium Copper Iron Magnesium Manganese Molybdenum Nickel Potassium Sodium Strontium Zinc 6020 MET ICPMS Antimony Arsenic Cadmium Cobalt Lead Selenium Thallium Vanadium 7471 Mercury Mercury Percent Moisture Percent Moisture 9045 pH Soil pH at 25 Degrees C 300.0 IC Anions, SPLP Sulfate 353.2 Nitrogen, NO2/NO3, SPLP Nitrogen, Nitrate 4500 Chloride, SPLP Chloride Date: 07/03/2015 08:29 AM Analytical Method: EPA 6010 Preparation Method: EPA 3050 9800 mg/kg 30.4 15.2 5 06/08/1516:08 06/10/1516:10 7429-90-5 100 mg/kg 3.0 1.5 5 06/08/1516:08 06/10/1516:10 7440-39-3 0.58 mg/kg 0.30 0.15 5 06/08/1516:08 06/10/1516:10 7440-41-7 ND mg/kg 15.2 7.6 5 06/08/1516:08 06/10/1516:10 7440-42-8 442 mg/kg 152 76.1 5 06/08/1516:08 06/10/1516:10 7440-70-2 18.7 mg/kg 1.5 0.76 5 06/08/1516:08 06/10/1516:10 7440-47-3 12.7 mg/kg 1.5 0.76 5 06/08/1516:08 06/10/1516:10 7440-50-8 18900 mg/kg 12.2 6.1 5 06/08/1516:08 06/10/1516:10 7439-89-6 1840 mg/kg 152 76.1 5 06/08/1516:08 06/10/1516:10 7439-95-4 1080 mg/kg 1.5 0.76 5 06/08/1516:08 06/10/1516:10 7439-96-5 ND mg/kg 3.0 1.5 5 06/08/1516:08 06/10/1516:10 7439-98-7 6.9 mg/kg 1.5 0.76 5 06/08/1516:08 06/10/1516:10 7440-02-0 ND mg/kg 304 152 5 06/08/1516:08 06/10/1516:10 7440-09-7 ND mg/kg 304 152 5 06/08/1516:08 06/10/1516:10 7440-23-5 8.6 mg/kg 3.0 1.5 5 06/08/1516:08 06/10/1516:10 7440-24-6 27.6 mg/kg 6.1 3.0 5 06/08/1516:08 06/10/1516:10 7440-66-6 Analytical Method: EPA 6020 Preparation Method: EPA 3050 ND mg/kg 6.1 3.0 100 06/08/1516:08 06/10/1511:09 7440-36-0 ND mg/kg 6.1 3.0 100 06/08/1516:08 06/10/1511:09 7440-38-2 ND mg/kg 0.73 0.37 100 06/08/1516:08 06/10/1511:09 7440-43-9 17.5 mg/kg 6.1 3.0 100 06/08/1516:08 06/10/1511:09 7440-48-4 10.6 mg/kg 6.1 3.0 100 06/08/1516:08 06/10/1511:09 7439-92-1 ND mg/kg 6.1 3.0 100 06/08/1516:08 06/10/1511:09 7782-49-2 ND mg/kg 6.1 3.0 100 06/08/1516:08 06/10/1511:09 7440-28-0 50.2 mg/kg 6.1 3.0 100 06/08/1516:08 06/10/1511:09 7440-62-2 Analytical Method: EPA 7471 Preparation Method: EPA 7471 0.050 mg/kg 0.0094 0.0047 1 06/08/1516:22 06/09/1512:35 7439-97-6 Analytical Method: ASTM D2974-87 14.6 % 0.10 0.10 1 06/10/15 08:16 Analytical Method: EPA 9045 5.5 Std. Units 0.10 0.10 1 06/08/15 15:55 N2 Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 06/04/15 02:10 16.4 mg/L 2.3 1.2 1 06/16/1516:55 14808-79-8 B Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 06/04/15 02:10 ND mg/L 0.23 0.23 1 06/18/1517:15 H1 Analytical Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 06/04/15 02:10 5.1J mg/L 5.9 2.9 1 06/18/15 05:01 16887-00-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 23 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K�n�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15060058 Pace Project No.: 92252541 Sample: 2015016945 Lab ID: 92252541001 Collected: 05/30/15 15:40 Received: 06/02/15 16:30 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 287 144 5 06/06/1512:59 16887-00-6 D3 Sulfate 145J mg/kg 287 144 5 06/06/1512:59 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 28.7 14.4 5 06/06/15 12:59 14797-55-8 D3,1-13 Total Organic Carbon Analytical Method: EPA 9060 Modified Surrogates RPD% 5.5 % 0.10 0.10 1 06/25/15 15:39 Total Organic Carbon 4660 mg/kg 699 349 1 06/25/15 15:39 7440-44-0 Total Organic Carbon 4930 mg/kg 698 349 1 06/25/15 15:44 7440-44-0 Mean Total Organic Carbon 4790 mg/kg 698 349 1 06/25/15 15:39 7440-44-0 Date: 07/03/2015 08:29 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 24 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K��c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15060058 Pace Project No.: 92252541 Sample: 2015016949 Lab ID: 92252541002 Collected: 05/30/15 17:55 Received: 06/02/15 16:30 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 9740 mg/kg 30.6 15.3 5 06/08/1516:08 06/10/1516:14 7429-90-5 Barium 49.7 mg/kg 3.1 1.5 5 06/08/1516:08 06/10/1516:14 7440-39-3 Beryllium 0.65 mg/kg 0.31 0.15 5 06/08/1516:08 06/10/1516:14 7440-41-7 Boron ND mg/kg 15.3 7.7 5 06/08/1516:08 06/10/1516:14 7440-42-8 Calcium 1040 mg/kg 153 76.6 5 06/08/1516:08 06/10/1516:14 7440-70-2 Chromium 15.0 mg/kg 1.5 0.77 5 06/08/1516:08 06/10/1516:14 7440-47-3 Copper 11.9 mg/kg 1.5 0.77 5 06/08/1516:08 06/10/1516:14 7440-50-8 Iron 20200 mg/kg 12.2 6.1 5 06/08/1516:08 06/10/1516:14 7439-89-6 Magnesium 3370 mg/kg 153 76.6 5 06/08/1516:08 06/10/1516:14 7439-95-4 Manganese 489 mg/kg 1.5 0.77 5 06/08/1516:08 06/10/1516:14 7439-96-5 Molybdenum ND mg/kg 3.1 1.5 5 06/08/1516:08 06/10/1516:14 7439-98-7 Nickel 9.9 mg/kg 1.5 0.77 5 06/08/1516:08 06/10/1516:14 7440-02-0 Potassium 691 mg/kg 306 153 5 06/08/1516:08 06/10/1516:14 7440-09-7 Sodium 596 mg/kg 306 153 5 06/08/1516:08 06/10/1516:14 7440-23-5 Strontium 15.7 mg/kg 3.1 1.5 5 06/08/1516:08 06/10/1516:14 7440-24-6 Zinc 31.1 mg/kg 6.1 3.1 5 06/08/1516:08 06/10/1516:14 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 6.1 3.1 100 06/08/1516:08 06/10/1511:12 7440-36-0 N2 Arsenic ND mg/kg 6.1 3.1 100 06/08/1516:08 06/10/1511:12 7440-38-2 Cadmium ND mg/kg 0.73 0.37 100 06/08/1516:08 06/10/1511:12 7440-43-9 Cobalt 12.8 mg/kg 6.1 3.1 100 06/08/1516:08 06/10/1511:12 7440-48-4 Lead 9.6 mg/kg 6.1 3.1 100 06/08/1516:08 06/10/1511:12 7439-92-1 Selenium ND mg/kg 6.1 3.1 100 06/08/1516:08 06/10/1511:12 7782-49-2 Thallium ND mg/kg 6.1 3.1 100 06/08/1516:08 06/10/1511:12 7440-28-0 Vanadium 48.0 mg/kg 6.1 3.1 100 06/08/1516:08 06/10/1511:12 7440-62-2 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury 0.013 mg/kg 0.0099 0.0049 1 06/08/1516:22 06/09/1512:37 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 16.9 % 0.10 0.10 1 06/10/15 08:16 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 8.2 Std. Units 0.10 0.10 1 06/08/15 15:55 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 298 149 5 06/06/1513:21 16887-00-6 D3 Sulfate ND mg/kg 298 149 5 06/06/1513:21 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 29.8 14.9 5 06/06/15 13:21 14797-55-8 D3,H3 Date: 07/03/2015 08:29 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 25 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15060058 Pace Project No.: 92252541 Sample: 2015016949 Lab ID: 92252541002 Collected: 05/30/15 17:55 Received: 06/02/15 16:30 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Analytical Method: EPA 9060 Modified Surrogates RPD% 1.4 % 0.10 0.10 1 06/25/15 16:14 Total Organic Carbon 582J mg/kg 722 361 1 06/25/15 16:14 7440-44-0 Total Organic Carbon 590J mg/kg 727 364 1 06/25/15 16:21 7440-44-0 Mean Total Organic Carbon 586J mg/kg 725 362 1 06/25/15 16:14 7440-44-0 Date: 07/03/2015 08:29 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 26 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15060058 Pace Project No.: 92252541 Sample: 2015016950 Lab ID: 92252541003 Collected: 05/30/15 17:15 Received: 06/02/15 16:30 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 4720 mg/kg 32.0 16.0 5 06/08/1516:08 06/10/1516:18 7429-90-5 Barium 49.5 mg/kg 3.2 1.6 5 06/08/1516:08 06/10/1516:18 7440-39-3 Beryllium 0.35 mg/kg 0.32 0.16 5 06/08/1516:08 06/10/1516:18 7440-41-7 Boron ND mg/kg 16.0 8.0 5 06/08/1516:08 06/10/1516:18 7440-42-8 Calcium 937 mg/kg 160 80.0 5 06/08/1516:08 06/10/1516:18 7440-70-2 Chromium 8.2 mg/kg 1.6 0.80 5 06/08/1516:08 06/10/1516:18 7440-47-3 Copper 4.8 mg/kg 1.6 0.80 5 06/08/1516:08 06/10/1516:18 7440-50-8 Iron 13600 mg/kg 12.8 6.4 5 06/08/1516:08 06/10/1516:18 7439-89-6 Magnesium 1530 mg/kg 160 80.0 5 06/08/1516:08 06/10/1516:18 7439-95-4 Manganese 275 mg/kg 1.6 0.80 5 06/08/1516:08 06/10/1516:18 7439-96-5 Molybdenum ND mg/kg 3.2 1.6 5 06/08/1516:08 06/10/1516:18 7439-98-7 Nickel 6.1 mg/kg 1.6 0.80 5 06/08/1516:08 06/10/1516:18 7440-02-0 Potassium 303J mg/kg 320 160 5 06/08/1516:08 06/10/1516:18 7440-09-7 Sodium ND mg/kg 320 160 5 06/08/1516:08 06/10/1516:18 7440-23-5 Strontium 9.7 mg/kg 3.2 1.6 5 06/08/1516:08 06/10/1516:18 7440-24-6 Zinc 17.7 mg/kg 6.4 3.2 5 06/08/1516:08 06/10/1516:18 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 6.4 3.2 100 06/08/1516:08 06/10/1511:14 7440-36-0 N2 Arsenic ND mg/kg 6.4 3.2 100 06/08/1516:08 06/10/1511:14 7440-38-2 Cadmium ND mg/kg 0.77 0.38 100 06/08/1516:08 06/10/1511:14 7440-43-9 Cobalt 6.7 mg/kg 6.4 3.2 100 06/08/1516:08 06/10/1511:14 7440-48-4 Lead 4.6J mg/kg 6.4 3.2 100 06/08/1516:08 06/10/1511:14 7439-92-1 Selenium ND mg/kg 6.4 3.2 100 06/08/1516:08 06/10/1511:14 7782-49-2 Thallium ND mg/kg 6.4 3.2 100 06/08/1516:08 06/10/1511:14 7440-28-0 Vanadium 21.3 mg/kg 6.4 3.2 100 06/08/1516:08 06/10/1511:14 7440-62-2 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury ND mg/kg 0.010 0.0050 1 06/08/1516:22 06/09/1512:39 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 22.6 % 0.10 0.10 1 06/10/15 08:16 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 7.2 Std. Units 0.10 0.10 1 06/08/15 15:55 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 322 161 5 06/06/1513:42 16887-00-6 D3 Sulfate ND mg/kg 322 161 5 06/06/1513:42 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 32.2 16.1 5 06/06/15 13:42 14797-55-8 D3,H3 Date: 07/03/2015 08:29 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 27 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K��c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15060058 Pace Project No.: 92252541 Sample: 2015016950 Lab ID: 92252541003 Collected: 05/30/15 17:15 Received: 06/02/15 16:30 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Analytical Method: EPA 9060 Modified Surrogates RPD% 6.9 % 0.10 0.10 1 06/25/15 16:26 Total Organic Carbon 421J mg/kg 769 384 1 06/25/15 16:26 7440-44-0 Total Organic Carbon 393J mg/kg 770 385 1 06/25/15 16:35 7440-44-0 Mean Total Organic Carbon 407J mg/kg 769 385 1 06/25/15 16:26 7440-44-0 Date: 07/03/2015 08:29 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 28 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K��c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15060058 Pace Project No.: 92252541 Sample: 2015016951 Lab ID: 92252541004 Collected: 05/30/15 00:00 Received: 06/02/15 16:30 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 9820 mg/kg 29.1 14.5 5 06/08/1516:08 06/10/1516:22 7429-90-5 Barium 79.8 mg/kg 2.9 1.5 5 06/08/1516:08 06/10/1516:22 7440-39-3 Beryllium 0.55 mg/kg 0.29 0.15 5 06/08/1516:08 06/10/1516:22 7440-41-7 Boron ND mg/kg 14.5 7.3 5 06/08/1516:08 06/10/1516:22 7440-42-8 Calcium 1060 mg/kg 145 72.7 5 06/08/1516:08 06/10/1516:22 7440-70-2 Chromium 15.7 mg/kg 1.5 0.73 5 06/08/1516:08 06/10/1516:22 7440-47-3 Copper 11.4 mg/kg 1.5 0.73 5 06/08/1516:08 06/10/1516:22 7440-50-8 Iron 17000 mg/kg 11.6 5.8 5 06/08/1516:08 06/10/1516:22 7439-89-6 Magnesium 3500 mg/kg 145 72.7 5 06/08/1516:08 06/10/1516:22 7439-95-4 Manganese 343 mg/kg 1.5 0.73 5 06/08/1516:08 06/10/1516:22 7439-96-5 Molybdenum ND mg/kg 2.9 1.5 5 06/08/1516:08 06/10/1516:22 7439-98-7 Nickel 9.6 mg/kg 1.5 0.73 5 06/08/1516:08 06/10/1516:22 7440-02-0 Potassium 694 mg/kg 291 145 5 06/08/1516:08 06/10/1516:22 7440-09-7 Sodium 621 mg/kg 291 145 5 06/08/1516:08 06/10/1516:22 7440-23-5 Strontium 17.0 mg/kg 2.9 1.5 5 06/08/1516:08 06/10/1516:22 7440-24-6 Zinc 31.6 mg/kg 5.8 2.9 5 06/08/1516:08 06/10/1516:22 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 5.8 2.9 100 06/08/1516:08 06/10/1511:21 7440-36-0 N2 Arsenic ND mg/kg 5.8 2.9 100 06/08/1516:08 06/10/1511:21 7440-38-2 Cadmium ND mg/kg 0.70 0.35 100 06/08/1516:08 06/10/1511:21 7440-43-9 Cobalt 10.8 mg/kg 5.8 2.9 100 06/08/1516:08 06/10/1511:21 7440-48-4 Lead 8.0 mg/kg 5.8 2.9 100 06/08/1516:08 06/10/1511:21 7439-92-1 Selenium ND mg/kg 5.8 2.9 100 06/08/1516:08 06/10/1511:21 7782-49-2 Thallium ND mg/kg 5.8 2.9 100 06/08/1516:08 06/10/1511:21 7440-28-0 Vanadium 37.9 mg/kg 5.8 2.9 100 06/08/1516:08 06/10/1511:21 7440-62-2 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury 0.011 mg/kg 0.0096 0.0048 1 06/08/1516:22 06/09/1512:41 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 16.2 % 0.10 0.10 1 06/10/15 08:16 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 8.4 Std. Units 0.10 0.10 1 06/08/15 15:55 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 300 150 5 06/06/1514:03 16887-00-6 D3 Sulfate ND mg/kg 300 150 5 06/06/1514:03 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 30.0 15.0 5 06/06/15 14:03 14797-55-8 D3,H3 Date: 07/03/2015 08:29 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 29 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K3c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15060058 Pace Project No.: 92252541 Sample: 2015016951 Lab ID: 92252541004 Collected: 05/30/15 00:00 Received: 06/02/15 16:30 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Analytical Method: EPA 9060 Modified Surrogates RPD% 13.1 % 0.10 0.10 1 06/25/15 16:41 Total Organic Carbon 506J mg/kg 722 361 1 06/25/15 16:41 7440-44-0 Total Organic Carbon 577J mg/kg 719 360 1 06/25/15 16:47 7440-44-0 Mean Total Organic Carbon 541J mg/kg 721 360 1 06/25/15 16:41 7440-44-0 Date: 07/03/2015 08:29 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 30 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K3gc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15060058 Pace Project No.: 92252541 Sample: 2015016945 SPLP Lab ID: 92252541005 Collected: 05/30/15 15:40 Received: 06/02/15 16:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;T➢Z17c\�iil=11 a Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470A Mercury Mercury Date: 07/03/2015 08:29 AM Analytical Method: EPA 6020A Preparation Method: EPA 3020 12500 ug/L 10.0 3.0 1 06/29/15 10:21 07/01/15 00:51 7429-90-5 ND ug/L 0.50 0.15 1 06/29/15 10:21 07/01/15 00:51 7440-36-0 1.7 ug/L 0.50 0.11 1 06/29/15 10:21 07/01/15 00:51 7440-38-2 350 ug/L 0.30 0.081 1 06/29/15 10:21 07/01/15 00:51 7440-39-3 0.85 ug/L 0.20 0.067 1 06/29/15 10:21 07/01/15 00:51 7440-41-7 60.1 ug/L 5.0 1.1 1 06/29/15 10:21 07/01/15 00:51 7440-42-8 ND ug/L 0.080 0.024 1 06/29/15 10:21 07/01/15 00:51 7440-43-9 979 ug/L 40.0 16.0 1 06/29/15 10:21 07/02/15 08:38 7440-70-2 13.3 ug/L 0.50 0.17 1 06/29/15 10:21 07/01/15 00:51 7440-47-3 6.1 ug/L 0.50 0.13 1 06/29/15 10:21 07/01/15 00:51 7440-48-4 12.3 ug/L 1.0 0.21 1 06/29/15 10:21 07/01/15 00:51 7440-50-8 12500 ug/L 50.0 13.7 1 06/29/15 10:21 07/01/15 00:51 7439-89-6 8.2 ug/L 0.10 0.046 1 06/29/15 10:21 07/01/15 00:51 7439-92-1 2380 ug/L 10.0 3.2 1 06/29/15 10:21 07/01/15 00:51 7439-95-4 313 ug/L 0.50 0.24 1 06/29/15 10:21 07/01/15 00:51 7439-96-5 0.13J ug/L 0.50 0.094 1 06/29/15 10:21 07/01/15 00:51 7439-98-7 6.0 ug/L 0.50 0.16 1 06/29/15 10:21 07/01/15 00:51 7440-02-0 394 ug/L 50.0 11.7 1 06/29/15 10:21 07/01/15 00:51 7440-09-7 1.6 ug/L 0.50 0.20 1 06/29/15 10:21 07/01/15 00:51 7782-49-2 9360 ug/L 50.0 16.3 1 06/29/15 10:21 07/01/15 00:51 7440-23-5 19.9 ug/L 0.50 0.13 1 06/29/15 10:21 07/01/15 00:51 7440-24-6 0.068J ug/L 0.10 0.015 1 06/29/15 10:21 07/01/15 00:51 7440-28-0 40.8 ug/L 1.0 0.28 1 06/29/15 10:21 07/01/15 00:51 7440-62-2 112 ug/L 5.0 2.4 1 06/29/15 10:21 07/01/15 00:51 7440-66-6 Analytical Method: EPA 7470A Preparation Method: EPA 7470A 0.038J ug/L 0.20 0.022 1 06/29/1514:30 07/01/1518:01 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 31 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K��c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060058 Pace Project No.: 92252541 QC Batch: MERP/14018 Analysis Method: EPA 7470A QC Batch Method: EPA 7470A Analysis Description: 7470A Mercury Water Associated Lab Samples: 92252541005 METHOD BLANK: 2006739 Matrix: Water Associated Lab Samples: 92252541005 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury ug/L ND 0.20 07/01/1517:33 LABORATORY CONTROL SAMPLE: 2006740 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 5 4.9 97 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2007452 2007453 MS MSD 92255755005 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 5 5 5.2 5.3 103 105 80-120 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/03/2015 08:29 AM without the written consent of Pace Analytical Services, Inc.. Page 32 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060058 Pace Project No.: 92252541 QC Batch: MERP/5828 Analysis Method: EPA 7471 QC Batch Method: EPA 7471 Analysis Description: 7471 Mercury Associated Lab Samples: 92252541001, 92252541002, 92252541003, 92252541004 METHOD BLANK: 1235386 Matrix: Solid Associated Lab Samples: 92252541001, 92252541002, 92252541003, 92252541004 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury mg/kg ND 0.0078 06/09/1512:15 LABORATORY CONTROL SAMPLE: 1235387 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury mg/kg .079 0.080 102 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1235388 1235389 MS MSD 92252534002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury mg/kg ND .0932 .0944 0.092 0.093 97 96 80-120 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/03/2015 08:29 AM without the written consent of Pace Analytical Services, Inc.. Page 33 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 1inlc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060058 Pace Project No.: 92252541 QC Batch: MPRP/24583 Analysis Method: EPA 6010 QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid Associated Lab Samples: 92252541001, 92252541002, 92252541003, 92252541004 METHOD BLANK: 1235378 Matrix: Solid Associated Lab Samples: 92252541001, 92252541002, 92252541003, 92252541004 Blank Reporting Parameter Units Result Limit Analyzed Aluminum mg/kg ND 5.2 06/10/1515:10 Barium mg/kg ND 0.52 06/10/1515:10 Beryllium mg/kg ND 0.052 06/10/1515:10 Boron mg/kg ND 2.6 06/10/1515:10 Calcium mg/kg ND 26.0 06/10/1515:10 Chromium mg/kg ND 0.26 06/10/1515:10 Copper mg/kg ND 0.26 06/10/1515:10 Iron mg/kg ND 2.1 06/10/1515:10 Magnesium mg/kg ND 26.0 06/10/1515:10 Manganese mg/kg ND 0.26 06/10/1515:10 Molybdenum mg/kg ND 0.52 06/10/1515:10 Nickel mg/kg ND 0.26 06/10/1515:10 Potassium mg/kg ND 52.0 06/10/1515:10 Sodium mg/kg ND 52.0 06/10/1515:10 Strontium mg/kg ND 0.52 06/10/1515:10 Zinc mg/kg ND 1.0 06/10/1515:10 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 1235379 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Aluminum mg/kg 128 135 105 80-120 Barium mg/kg 12.8 13.8 107 80-120 Beryllium mg/kg 1.3 1.4 105 80-120 Boron mg/kg 128 134 105 80-120 Calcium mg/kg 641 686 107 80-120 Chromium mg/kg 12.8 13.4 104 80-120 Copper mg/kg 12.8 13.3 104 80-120 Iron mg/kg 128 135 105 80-120 Magnesium mg/kg 641 680 106 80-120 Manganese mg/kg 12.8 13.7 107 80-120 Molybdenum mg/kg 12.8 13.0 102 80-120 Nickel mg/kg 12.8 13.5 105 80-120 Potassium mg/kg 641 685 107 80-120 Sodium mg/kg 641 709 111 80-120 Strontium mg/kg 12.8 13.5 106 80-120 Zinc mg/kg 64.1 67.3 105 80-120 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/03/2015 08:29 AM without the written consent of Pace Analytical Services, Inc.. Page 34 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060058 Pace Project No.: 92252541 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1235380 1235381 MS MSD 92252534002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum mg/kg 6900 148 141 8160 8260 852 964 75-125 1 20 M1 Barium mg/kg 92.2 14.8 14.1 92.6 92.4 3 2 75-125 0 20 M1 Beryllium mg/kg 0.44 1.52 1.4 1.8 1.8 92 96 75-125 1 20 Boron mg/kg ND 148 141 136 130 92 93 75-125 5 20 Calcium mg/kg 1640 740 704 2330 2200 93 79 75-125 6 20 Chromium mg/kg 8.0 14.8 14.1 20.6 21.5 85 96 75-125 4 20 Copper mg/kg 72.7 14.8 14.1 86.9 90.7 96 129 75-125 4 20 M1 Iron mg/kg 18300 148 141 17400 18500 -605 133 75-125 6 20 M1 Magnesium mg/kg 4170 740 704 4840 4710 91 77 75-125 3 20 Manganese mg/kg 579 14.8 14.1 496 507 -558 -509 75-125 2 20 M1 Molybdenum mg/kg ND 14.8 14.1 13.2 12.7 88 89 75-125 4 20 Nickel mg/kg 4.8 14.8 14.1 19.2 19.0 97 101 75-125 1 20 Potassium mg/kg 329 740 704 1010 1010 92 97 75-125 1 20 Sodium mg/kg 353 740 704 1070 1090 96 104 75-125 2 20 Strontium mg/kg 23.2 14.8 14.1 36.9 36.3 93 93 75-125 2 20 Zinc mg/kg 39.8 74 70.4 112 108 97 97 75-125 3 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/03/2015 08:29 AM without the written consent of Pace Analytical Services, Inc.. Page 35 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 I� %fir&e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060058 Pace Project No.: 92252541 QC Batch: MPRP/24584 Analysis Method: EPA 6020 QC Batch Method: EPA 3050 Analysis Description: 6020 MET SOLID Associated Lab Samples: 92252541001, 92252541002, 92252541003, 92252541004 METHOD BLANK: 1235382 Matrix: Solid Associated Lab Samples: 92252541001, 92252541002, 92252541003, 92252541004 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Antimony mg/kg ND 0.050 06/10/1510:54 N2 Arsenic mg/kg ND 0.050 06/10/1510:54 Cadmium mg/kg ND 0.0060 06/10/1510:54 Cobalt mg/kg ND 0.050 06/10/1510:54 Lead mg/kg ND 0.050 06/10/1510:54 Selenium mg/kg ND 0.050 06/10/1510:54 Thallium mg/kg ND 0.050 06/10/1510:54 Vanadium mg/kg ND 0.050 06/10/1510:54 LABORATORY CONTROL SAMPLE: Parameter 1235383 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Antimony mg/kg 2.5 2.7 108 80-120 N2 Arsenic mg/kg 2.5 2.7 105 80-120 Cadmium mg/kg .25 0.27 106 80-120 Cobalt mg/kg 2.5 2.7 106 80-120 Lead mg/kg 2.5 2.7 107 80-120 Selenium mg/kg 2.5 2.7 107 80-120 Thallium mg/kg 2.5 2.7 107 80-120 Vanadium mg/kg 2.5 2.7 106 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1235384 1235385 MS MSD 92252534002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony mg/kg ND 2.8 2.8 ND ND 64 56 75-125 20 M6, N2 Arsenic mg/kg ND 2.8 2.8 3.9J 4.OJ 94 95 75-125 20 Cadmium mg/kg ND .28 .28 ND ND 61 55 75-125 20 M6 Cobalt mg/kg 6.OJ 2.8 2.8 8.8 7.9 101 69 75-125 11 20 M6 Lead mg/kg 3.1J 2.8 2.8 5AJ 5.3J 82 77 75-125 20 Selenium mg/kg ND 2.8 2.8 4.3J 3.9J 86 70 75-125 20 M6 Thallium mg/kg ND 2.8 2.8 2.8J ND 95 93 75-125 20 Vanadium mg/kg 30.3 2.8 2.8 34.3 31.8 140 53 75-125 7 20 M6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/03/2015 08:29 AM without the written consent of Pace Analytical Services, Inc.. Page 36 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Iic&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060058 Pace Project No.: 92252541 QC Batch: MPRP/55571 Analysis Method: EPA 6020A QC Batch Method: EPA 3020 Analysis Description: 6020A Water UPD4 Associated Lab Samples: 92252541005 METHOD BLANK: 2006731 Associated Lab Samples: 92252541005 Parameter Units Aluminum ug/L Antimony ug/L Arsenic ug/L Barium ug/L Beryllium ug/L Boron ug/L Cadmium ug/L Calcium ug/L Chromium ug/L Cobalt ug/L Copper ug/L Iron ug/L Lead ug/L Magnesium ug/L Manganese ug/L Molybdenum ug/L Nickel ug/L Potassium ug/L Selenium ug/L Sodium ug/L Strontium ug/L Thallium ug/L Vanadium ug/L Zinc ug/L Matrix: Water Blank Result Reporting Limit Analyzed ND 10.0 07/01/15 00:15 ND 0.50 07/01/15 00:15 ND 0.50 07/01/15 00:15 ND 0.30 07/01/15 00:15 ND 0.20 07/01/15 00:15 ND 5.0 07/01/15 00:15 ND 0.080 07/01/15 00:15 ND 40.0 07/02/15 07:11 ND 0.50 07/01/15 00:15 ND 0.50 07/01/15 00:15 ND 1.0 07/02/15 07:11 ND 50.0 07/01/15 00:15 ND 0.10 07/01/15 00:15 ND 10.0 07/01/15 00:15 ND 0.50 07/01/15 00:15 ND 0.50 07/01/15 00:15 ND 0.50 07/01/15 00:15 ND 50.0 07/01/15 00:15 ND 0.50 07/01/15 00:15 ND 50.0 07/01/15 00:15 ND 0.50 07/01/15 00:15 ND 0.10 07/01/15 00:15 ND 1.0 07/01/15 00:15 ND 5.0 07/01/15 00:15 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 2006732 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Aluminum ug/L 80 76.1 95 80-120 Antimony ug/L 80 76.2 95 80-120 Arsenic ug/L 80 77.5 97 80-120 Barium ug/L 80 79.1 99 80-120 Beryllium ug/L 80 82.0 103 80-120 Boron ug/L 80 87.1 109 80-120 Cadmium ug/L 80 77.9 97 80-120 Calcium ug/L 1000 1030 103 80-120 Chromium ug/L 80 78.1 98 80-120 Cobalt ug/L 80 78.4 98 80-120 Copper ug/L 80 77.4 97 80-120 Iron ug/L 1000 976 98 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/03/2015 08:29 AM without the written consent of Pace Analytical Services, Inc.. Page 37 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060058 Pace Project No.: 92252541 LABORATORY CONTROL SAMPLE: 2006732 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Lead ug/L 80 77.0 96 80-120 Magnesium ug/L 1000 964 96 80-120 Manganese ug/L 80 78.4 98 80-120 Molybdenum ug/L 80 76.8 96 80-120 Nickel ug/L 80 78.2 98 80-120 Potassium ug/L 1000 979 98 80-120 Selenium ug/L 80 78.2 98 80-120 Sodium ug/L 1000 994 99 80-120 Strontium ug/L 80 77.3 97 80-120 Thallium ug/L 80 76.6 96 80-120 Vanadium ug/L 80 78.6 98 80-120 Zinc ug/L 80 77.2 97 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2007450 2007451 MS MSD 92255755020 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum ug/L 5.6J 80 80 94.1 93.8 111 110 75-125 0 20 Antimony ug/L ND 80 80 78.5 76.7 98 96 75-125 2 20 Arsenic ug/L ND 80 80 81.1 77.9 101 97 75-125 4 20 Barium ug/L 0.26J 80 80 80.8 79.3 101 99 75-125 2 20 Beryllium ug/L ND 80 80 79.8 80.6 100 101 75-125 1 20 Boron ug/L ND 80 80 84.4 81.9 104 101 75-125 3 20 Cadmium ug/L ND 80 80 80.7 79.4 101 99 75-125 2 20 Calcium ug/L 76.6 1000 1000 1100 1090 103 101 75-125 2 20 Chromium ug/L ND 80 80 81.2 79.1 101 99 75-125 3 20 Cobalt ug/L ND 80 80 82.2 78.6 103 98 75-125 4 20 Copper ug/L 0.32J 80 80 81.9 78.9 102 98 75-125 4 20 Iron ug/L 14.7J 1000 1000 1030 996 101 98 75-125 3 20 Lead ug/L ND 80 80 79.3 77.2 99 97 75-125 3 20 Magnesium ug/L 7.9J 1000 1000 1030 1000 102 99 75-125 3 20 Manganese ug/L 0.42J 80 80 81.6 80.2 102 100 75-125 2 20 Molybdenum ug/L ND 80 80 80.0 78.7 100 98 75-125 2 20 Nickel ug/L ND 80 80 84.0 80.4 105 100 75-125 4 20 Potassium ug/L 18.5J 1000 1000 1050 1030 104 101 75-125 3 20 Selenium ug/L ND 80 80 82.1 78.6 103 98 75-125 4 20 Sodium ug/L 31.9J 1000 1000 1070 1010 104 97 75-125 6 20 Strontium ug/L 0.50 80 80 80.6 79.8 100 99 75-125 1 20 Thallium ug/L ND 80 80 81.1 79.2 101 99 75-125 2 20 Vanadium ug/L ND 80 80 82.0 79.4 102 99 75-125 3 20 Zinc ug/L 8.0 80 80 92.6 83.4 106 94 75-125 10 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/03/2015 08:29 AM without the written consent of Pace Analytical Services, Inc.. Page 38 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060058 Pace Project No.: 92252541 QC Batch: PMST/3629 Analysis Method: ASTM D2974-87 QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture Associated Lab Samples: 92252541001, 92252541002, 92252541003, 92252541004 SAMPLE DUPLICATE: 1237772 35190066001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 5.1 4.0 23 10 D6 SAMPLE DUPLICATE: 1237773 35191549001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 21.5 20.1 7 10 SAMPLE DUPLICATE: 1237774 35191958002 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 20.2 20.2 0 10 SAMPLE DUPLICATE: 1237775 35192020007 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 24.1 22.6 6 10 SAMPLE DUPLICATE: 1237776 35192120002 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 12.4 10.2 19 10 D6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/03/2015 08:29 AM without the written consent of Pace Analytical Services, Inc.. Page 39 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Iic&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060058 Pace Project No.: 92252541 QC Batch: WET/37905 Analysis Method: EPA 9045 QC Batch Method: EPA 9045 Analysis Description: 9045 pH Associated Lab Samples: 92252541001, 92252541002, 92252541003, 92252541004 SAMPLE DUPLICATE: 1476410 92252908001 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 5.1 4.9 3 10 D6 SAMPLE DUPLICATE: 1476411 92252908010 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 6.0 6.1 2 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/03/2015 08:29 AM without the written consent of Pace Analytical Services, Inc.. Page 40 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Iigc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060058 Pace Project No.: 92252541 QC Batch: WETA/23324 Analysis Method: EPA 300.0 QC Batch Method: EPA 300.0 Analysis Description: 300.0 IC Anions Associated Lab Samples: 92252541001 METHOD BLANK: 1485896 Matrix: Water Associated Lab Samples: 92252541001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Sulfate mg/L 2.3 2.0 06/16/1515:20 LABORATORY CONTROL SAMPLE: 1485897 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfate mg/L 20 19.6 98 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1485898 1485899 MS MSD 92252532003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfate mg/L 6.3 20 20 26.0 26.2 98 99 1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/03/2015 08:29 AM without the written consent of Pace Analytical Services, Inc.. Page 41 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060058 Pace Project No.: 92252541 QC Batch: WETA/23372 Analysis Method: EPA 353.2 QC Batch Method: EPA 353.2 Analysis Description: 353.2 Nitrate + Nitrite, Unpres. Associated Lab Samples: 92252541001 METHOD BLANK: 1488925 Matrix: Water Associated Lab Samples: 92252541001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, Nitrate mg/L 0.14 0.020 06/18/15 17:00 Z2 LABORATORY CONTROL SAMPLE: 1488926 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Nitrate mg/L 2.5 2.5 102 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1488927 1488928 MS MSD 92252532003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Nitrate mg/L ND 2.5 2.5 2.6 2.6 98 97 90-110 1 10 H1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/03/2015 08:29 AM without the written consent of Pace Analytical Services, Inc.. Page 42 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060058 Pace Project No.: 92252541 QC Batch: WETA/23354 Analysis Method: SM 4500-CI-E QC Batch Method: SM 4500-CI-E Analysis Description: 4500 Chloride Associated Lab Samples: 92252541001 METHOD BLANK: 1487997 Matrix: Water Associated Lab Samples: 92252541001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/L ND 1.0 06/18/15 04:51 LABORATORY CONTROL SAMPLE: 1487998 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloride mg/L 20 19.8 99 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1487999 1488000 MS MSD 92252532003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride mg/L ND 20 20 17.3 17.4 86 86 90-110 0 10 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/03/2015 08:29 AM without the written consent of Pace Analytical Services, Inc.. Page 43 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 1j ni c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060058 Pace Project No.: 92252541 QC Batch: WETA/47029 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92252541001, 92252541002, 92252541003, 92252541004 METHOD BLANK: 1233607 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/kg ND 49.8 06/06/15 06:55 Sulfate mg/kg ND 49.8 06/06/15 06:55 LABORATORY CONTROL SAMPLE: 1233608 Parameter Units Chloride mg/kg Sulfate mg/kg MATRIX SPIKE SAMPLE: 1233610 Parameter Units Chloride mg/kg Sulfate mg/kg SAMPLE DUPLICATE: 1233609 Parameter Chloride Sulfate Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 496 510 103 80-120 496 507 102 80-120 92252369001 Spike MS MS % Rec Result Conc. Result % Rec Limits Qualifiers ND 1310 1240 76 80-120 M 1 ND 1310 1300 84 80-120 92252369001 Dup Units Result Result mg/kg ND ND mg/kg ND ND Max RPD RPD Qualifiers 20 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/03/2015 08:29 AM without the written consent of Pace Analytical Services, Inc.. Page 44 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060058 Pace Project No.: 92252541 QC Batch: WETA/47028 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92252541001, 92252541002, 92252541003, 92252541004 METHOD BLANK: 1233603 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrate as N mg/kg ND 5.0 06/06/15 06:55 LABORATORY CONTROL SAMPLE: 1233604 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg 49.6 52.7 106 80-120 MATRIX SPIKE SAMPLE: 1233606 92252369001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg ND 131 123 92 80-120 H3 SAMPLE DUPLICATE: 1233605 92252369001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Nitrate as N mg/kg ND ND 20 H3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/03/2015 08:29 AM without the written consent of Pace Analytical Services, Inc.. Page 45 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060058 Pace Project No.: 92252541 QC Batch: WETA/29200 Analysis Method: EPA 9060 Modified QC Batch Method: EPA 9060 Modified Analysis Description: 9060 TOC Average Associated Lab Samples: 92252541001, 92252541002, 92252541003, 92252541004 METHOD BLANK: 1182186 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mean Total Organic Carbon mg/kg ND 600 06/25/15 15:17 LABORATORY CONTROL SAMPLE: 1182187 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mean Total Organic Carbon mg/kg 120000 131000 109 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1182188 1182189 MS MSD 92252541001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg 4790 7040 7030 12400 11900 108 100 50-150 4 30 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1182190 1182191 MS MSD 92253161001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg ND 10200 10200 9530 9550 90 90 50-150 0 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/03/2015 08:29 AM without the written consent of Pace Analytical Services, Inc.. Page 46 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Ijc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: J15060058 Pace Project No.: 92252541 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TN -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-G Pace Analytical Services - Green Bay PASI-M Pace Analytical Services - Minneapolis PASI-O Pace Analytical Services - Ormond Beach BATCH QUALIFIERS Batch: ICP/15013 Ill Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. Batch: ICPM/9967 III Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. ANALYTE QUALIFIERS B Analyte was detected in the associated method blank. D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. D6 The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits. H1 Analysis conducted outside the EPA method holding time. H3 Sample was received or analysis requested beyond the recognized method holding time. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/03/2015 08:29 AM without the written consent of Pace Analytical Services, Inc.. Page 47 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, INC 28078 (704)875-9092 QUALIFIERS Project: J15060058 Pace Project No.: 92252541 ANALYTE QUALIFIERS M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. N2 The lab does not hold TIN accreditation for this parameter. Z2 Analyte present in the associated method blank above the detection limit. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/03/2015 08:29 AM without the written consent of Pace Analytical Services, Inc.. Page 48 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: J15060058 92252541 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92252541001 2015016945 EPA 3050 MPRP/24583 EPA 6010 ICP/15013 92252541002 2015016949 EPA 3050 MPRP/24583 EPA 6010 ICP/15013 92252541003 2015016950 EPA 3050 MPRP/24583 EPA 6010 1CP/15013 92252541004 2015016951 EPA 3050 MPRP/24583 EPA 6010 ICP/15013 92252541001 2015016945 EPA 3050 MPRP/24584 EPA6020 ICPM/9967 92252541002 2015016949 EPA 3050 MPRP/24584 EPA6020 ICPM/9967 92252541003 2015016950 EPA 3050 MPRP/24584 EPA 6020 ICPM/9967 92252541004 2015016951 EPA 3050 MPRP/24584 EPA6020 ICPM/9967 92252541005 2015016945 SPLP EPA 3020 MPRP/55571 EPA 6020A ICPM/25109 92252541005 2015016945 SPLP EPA 7470A MERP/14018 EPA 7470A MERC/16364 92252541001 2015016945 EPA 7471 MERP/5828 EPA 7471 MERC/5813 92252541002 2015016949 EPA 7471 MERP/5828 EPA 7471 MERC/5813 92252541003 2015016950 EPA 7471 MERP/5828 EPA 7471 MERC/5813 92252541004 2015016951 EPA 7471 MERP/5828 EPA 7471 MERC/5813 92252541001 2015016945 ASTM D2974-87 PMST/3629 92252541002 2015016949 ASTM D2974-87 PMST/3629 92252541003 2015016950 ASTM D2974-87 PMST/3629 92252541004 2015016951 ASTM D2974-87 PMST/3629 92252541001 2015016945 EPA 9045 WET/37905 92252541002 2015016949 EPA 9045 WET/37905 92252541003 2015016950 EPA 9045 WET/37905 92252541004 2015016951 EPA 9045 WET/37905 92252541001 2015016945 EPA 300.0 WETA/23324 92252541001 2015016945 EPA 353.2 WETA/23372 92252541001 2015016945 SM 4500-CI-E WETA/23354 92252541001 2015016945 EPA 9056 WETA/47029 92252541002 2015016949 EPA 9056 WETA/47029 92252541003 2015016950 EPA 9056 WETA/47029 92252541004 2015016951 EPA 9056 WETA/47029 92252541001 2015016945 EPA 9056 WETA/47028 92252541002 2015016949 EPA 9056 WETA/47028 92252541003 2015016950 EPA 9056 WETA/47028 92252541004 2015016951 EPA 9056 WETA/47028 92252541001 2015016945 EPA 9060 Modified WETA/29200 92252541001 2015016945 EPA 9060 Modified WETA/29201 92252541002 2015016949 EPA 9060 Modified WETA/29200 92252541002 2015016949 EPA 9060 Modified WETA/29201 92252541003 2015016950 EPA 9060 Modified WETA/29200 92252541003 2015016950 EPA 9060 Modified WETA/29201 92252541004 2015016951 EPA 9060 Modified WETA/29200 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/03/2015 08:29 AM without the written consent of Pace Analytical Services, Inc.. Page 49 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Ijc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: J15060058 Pace Project No.: 92252541 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92252541004 2015016951 EPA 9060 Modified WETA/29201 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/03/2015 08:29 AM without the written consent of Pace Analytical Services, Inc.. Page 50 of 52 r ��ceAlk�lyifcal ° r vUUu111U11L Warne: Sample Condition Upon Receil Document Number: F-CHR-CS-003-rev.16 uUL:urr1UF1L rieV1bUU- Ivrdy jo, GV ICJ Page 1 of 2* Issuing Authority: 58 of 60 Pace Huntersville Quality Office Client Name: Courier: ❑ Fed Ex ❑ UPS[] USPS❑ Client❑ Commercial * Page 2 of 2 is for Internal Use Only Pace Other Custody Seal on Cooler/Box Present: ❑ yes W no Seals intact: ❑ yes ❑ no Packing Material: ❑ Bubble VDp Ef Bubble Bags ❑ None ❑ Other Thermometer Used: IR Gun T1401 Type of Ice(W)t Blue None El Samples on ice, cooling process has begun Temp Correction Factor T1401 No Correction 1��'J/ , Corrected Cooler Tem 1` -C p Biological Tissue is Frozen: Yes No NIA Date and Initials of Pe on examining contend§ Temp should be above freezing to 6°C Comments: Chain of Custody Present: 12dep [IN. ❑NIA 1. Chain of Custody Filled Out: E Yes ❑No ❑NIA 2. Chain of Custody Relinquished: Yes ❑No ❑MIA 3. Sampler Name & Signature on COC: es ❑No ❑NIA 4. Samples Arrived within Hold Time: ❑ es 0No ❑NIA 5. Short Hold Time Analysis (<72hr): ❑Yes 12 o El N/A 6. Rush Turn Around Time Requested: Dyes t No ❑NIA 7. Sufficient. Volume: ❑Yes [IN. ❑NIA 8. Correct Containers Used: Cayes ❑No ❑NIA 9. -Pace Containers Used: es 4d ❑NIA Containers Intact: Yes ❑No ❑D�NIA 10. Filtered volume received for Dissolved tests []Yes ❑No IQNIA 11. Sample Labels match COC: Vies ❑No ❑NIA 12, -Includes date/time/ID/Analysis Matrix: All containers needing preservation have been checked. ❑Yes ❑No ,_.,' �INIA 13. All containers needing preservation are found to be in ❑Yes ❑No L�]NIA compliance with EPA recommendation. exceptions: VOA, co%form, TOC, 0&G, VVI-DRO (water) ❑Yes ❑No Samples checked for dechlorination: ❑Yes ❑No ®IA 14. Headspace in VOA Vials (>6mm): ❑Yes ❑No P NIA 15. Trip Blank Present: ❑Yes [-]No PN/A 16, Trip Blank Custody Seals Present ❑Yes ❑No ❑NIA Pace Trip Blank Lot # (if purchased): Client Notification/ Resolution: Field Data Required? Y I N Person Contacted: Comments/ Resolution: Date/Time: SCURF Review:1 K& Date: [2 is SRF Review: Date: ! Note, Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office ( i.e out of hold, Incorrect preservative, out of temp, incorrect containers) WOp:92252541 111111311111111111111111JI Page 51 of 52 Customer must Complete w - j 3 0 n Y 33 3 M - G N n m 3 re '� C tea_ QV n t'4 Po n (? ro 0 t\? 3�3 gg 0 'M m � r ` 4 re 3 //11 U V O aR " m to now$ ro �� n0i G ao A � 1 _ Cr l / c N rs 0 A J m m i a t7 O C = � A N 3 m 6 7 0. customer to cnmpioto appropriato coromna to right N i3 $Q� m 7S v a c nIs g iS D0 a n 0 C � � O CL o O LIU rrt w 7 ; m o o 56 N C6 3 a 7 (r d w n 6 N w p n 0, °� tt O N d O o S 59 0 6 M Z G R M (v rM Page 52 of 52 CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM Synterra ODD -Analyticad Lalxxat+}rySBrrrielet i a -.-._,v,a._.-.-.,-Ana...... lyticaf Laboratory Use Only UV t Nail Code MG03A2 { Building 74M) l kFb ardor M — - , -, 1 OF 1 II�V� FF'�� DTI 1333g Ragem Farry Rd 6 50 5q U wl■o-la 131L a. �.. or♦ I.a41 From *H_ fSISTRI[tL171C}N I i y 'p l{,e.ea.svIj[4, m e. ZM7. ' _.� - l �. _ u � � 'OR IGINAL to LAO, 19e5}a7a axe � aau a T7i [ `COPY to CLIENT F�sI S�4 biQal34�_- ---i i V 'P I a SAMPLE P14OL; M Gra,r}i 1Na9er _ — WIVES I,tPrejla lNama• A Groundrwaler Asse#smaro - Soil X�IRkanaMe; _ �w"e8tl 1 1 ,Tarr, worn _ 1 _ CAPE f 1 All � E'. tar Tom iG l +� GATE +�i 1'f r2�15 41FOX$w Pare aLf3 GW ` PID 114208 � k aolrs -Tic n u7 v u'r u7 I i F 4111enM1� Unit BlFreied Fla: 7R" Code; 6' iipar■Nry LWrjp 1"" iP: 9+oler'asf■M lA L When ypocill[ acr<pupting has boon aclabNshotl and to rat lnillcmtod abown we need the fulWming: 10 Enlar CotTmt Acontutbing In oil 5 secoun1mrg fieldo above, Of I LAa USE OWL' 1 Mork I 1 i "Lan rll {5on. Sesli�rtn[,A■Fri I la I 1 ++ l 11 N 1� I 1 1 r P 1 Y i 1_ I � 1 ill WATER By ,5saMple Pq$ cri tian or ID .10.. c BR - EQUIPMENT KANK 11 PER DA O Metals; Al. Sh, As. F3a, Fie, 8, Cd, Ca, Cr, Co, Cu, Fo. Pt% Mg, Mn, LoQK .. 41 � aai iarC'FPFP�#414�a -1 C 1 7 - Proser ativeic when used must be 0 (L j N _ a(Mad wil iIn 15 1T11a.ut" of sam13le rollection a N r C.1 � ra CL < J fia. ir3 t�colleclion lofr7rmation Q os to TirSi aura. C- CL fA tb SV dam] '�yy s r�-T TI QprarT G sr, 5 V, im Merrlrry, pH Parllele Site Dis-trill„ llon. Red4x 22RNLlented Tumsraund 1.4 Gaya �£ `7 DNS 3 • 48 Hr mL'16W Add CD5I.. VNSr.' ly