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Home My WebLink AboutNC0003433_J15060005 Report_20150902+ DUKE Analytical Laboratory 1 of60 ENERGY Order Number: Project Name: Customer Name(s): Customer Address: Lab Contact: Report Authorized By: (Signature) Program Comments: 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone:980-875-5245 Fax:980-875-4349 Order Summary Report J15060005 CAPE FEAR - AB GW ASSESSMENT SOIL Tim Hunsucker, Chris Suttell, Kathy Webb, John Toepfer Margaret Galvin -Karr Margaret Galvin -Karr MXG4644 (101161) 2015.06.26 09:53:38 -04'00' Phone: 980-875-5219 Date: Please contact the Program Manager (Margaret Galvin -Karr) with any questions regarding this report. Data Flags & Calculations: 6/26/2015 Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Sample ID's & Descriptions: Collection Sample ID Plant/Station Date and Time Collected By Sample Description 2015016714 Cape Fear 28-May-15 11:40 AM Illegible SW-CFDG 2015016715 Cape Fear 28-May-15 10:20 AM Illegible SW -HAW 2015016716 Cape Fear 28-May-15 9:55 AM Illegible SW-DEEPR 2015016717 Cape Fear 28-May-15 10:55 AM Illegible S-16 4 Total Samples 2 of 60 3 of 60 Technical Validation Review Checklist: COC and .pdf report are in agreement with sample totals Yes No and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. ❑ Yes❑ No All laboratory QA/QC requirements are acceptable.❑ Yes ❑ No Report Sections Included: U Job Summary Report ❑ Sample Identification n Technical Validation of Data Package ❑ Analytical Laboratory Certificate of Analysis ❑ Analytical Laboratory QC Report Reviewed By: Date: Sub -contracted Laboratory Results ❑ Customer Specific Data Sheets, Reports, & Documentation ❑ Customer Database Entries 0 Chain of Custody [I/0] Electronic Data Deliverable (EDD) Sent Separately Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060005 Site: SW-CFDG Collection Date: 28-May-15 11:40 AM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SEDIMENT ANALYSIS - (Analysis Performed by Access Analytical) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 4 of 60 Sample #: 2015016714 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_A.Analytical Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060005 Site: SW -HAW Collection Date: 28-May-15 10:20 AM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SEDIMENT ANALYSIS - (Analysis Performed by Access Analytical) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 5 of 60 Sample #: 2015016715 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_A.Analytical Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060005 Site: SW-DEEPR Collection Date: 28-May-15 9:55 AM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SEDIMENT ANALYSIS - (Analysis Performed by Access Analytical) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 6 of 60 Sample #: 2015016716 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_A.Analytical Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060005 Site: S-16 Collection Date: 28-May-15 10:55 AM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SEDIMENT ANALYSIS - (Analysis Performed by Access Analytical) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 7 of 60 Sample #: 2015016717 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_A.Analytical Vendor Method V_PACE -- Additional Information -- Samples were received out of temperature. Temperature at receipt was 9.8 C MG-K 6/26/15 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kigc&y&e. Suite 100 Huntersville, INC 28078 (704)875-9092 June 25, 2015 Program Manager Duke Energy 13339 Hagers Ferry Road Bldg.7405 MG30A2 Huntersville, NC 28078 RE: Project: J 15060005 Pace Project No.: 92252369 Dear Program Manager: Enclosed are the analytical results for sample(s) received by the laboratory on June 01, 2015. The results relate only to the samples included in this report. Results reported herein conform to the most current TN standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Herring kevin.herring@pacelabs.com HORIZON Database Administrator Enclosures cc: Marge Galvin -Karr, Duke Energy Program Manager, Duke Energy Mary Ann Ogle, Duke Energy Rodney Wilke, Duke Energy p«FO REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, lqe� �� without the written consent of Pace Analytical Services, Inc.. BRAT, Page 1 of 38 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kig,8y&e. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15060005 Pace Project No.: 92252369 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification #: 41320 Connecticut Certification M PH-0216 Delaware Certification: FL NELAC Reciprocity Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate M 05007 Maryland Certification: #346 Massachusetts Certification #: M-FL1264 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Green Bay Certification IDs 1241 Bellevue Street, Green Bay, WI 54302 Florida/NELAP Certification #: E87948 Illinois Certification #: 200050 Kentucky Certification #: 82 Louisiana Certification #: 04168 Minnesota Certification #: 055-999-334 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification M E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 CERTIFICATIONS Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 Nevada Certification: FL NELAC Reciprocity New Hampshire Certification #: 2958 New Jersey Certification #: FL765 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 Pennsylvania Certification #: 68-00547 Puerto Rico Certification M FLO1264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 Washington Certification #: C955 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity North Dakota Certification #: R-150 South Carolina Certification #: 83006001 Texas Certification #: T104704529-14-1 US Dept of Agriculture #: S-76505 Wisconsin Certification #: 405132750 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 West Virginia Certification M 356 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 2 of 38 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ff�i�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: J15060005 Pace Project No.: 92252369 Lab ID Sample ID Matrix Date Collected Date Received 92252369001 201501614 Solid 05128/1511:40 06/01/1518:40 92252369002 201501615 Solid 05/28/1510:20 06/01/1518:40 92252369003 201501616 Solid 05/28/15 09:55 06/01/15 18:40 92252369004 201501617 Solid 05/28/1510:55 06/01/1518:40 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 3 of 38 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 fflinl c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: J15060005 92252369 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92252369001 201501614 EPA 6010 TAP 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA 7471 TAP 1 PASI-O ASTM D2974-87 MLO 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 9056 CMB 2 PASI-O EPA 9056 CMB 1 PASI-O EPA 9060 TJJ 6 PASI-G 92252369002 201501615 EPA 6010 TAP 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA 7471 TAP 1 PASI-O ASTM D2974-87 MLO 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 9056 CMB 2 PASI-O EPA 9056 CMB 1 PASI-O EPA 9060 TJJ 6 PASI-G 92252369003 201501616 EPA 6010 TAP 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA 7471 TAP 1 PASI-O ASTM D2974-87 MLO 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 9056 CMB 2 PASI-O EPA 9056 CMB 1 PASI-O EPA 9060 TJJ 6 PASI-G 92252369004 201501617 EPA 6010 CKJ, TAP 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA 7471 TAP 1 PASI-O ASTM D2974-87 MLO 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 9056 CMB 2 PASI-O EPA 9056 CMB 1 PASI-O EPA 9060 TJJ 6 PASI-G REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 4 of 38 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffli�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15060005 Pace Project No.: 92252369 Lab Sample ID Client Sample ID Method Parameters SUMMARY OF DETECTION Result Units Report Limit Analyzed 92252369001 201501614 EPA 6010 Aluminum 11700 mg/kg 66.2 06/07/15 20:16 EPA 6010 Barium 115 mg/kg 6.6 06/07/15 20:16 EPA 6010 Beryllium 0.45J mg/kg 0.66 06/07/15 20:16 EPA 6010 Boron 18.8J mg/kg 33.1 06/07/15 20:16 EPA 6010 Calcium 1510 mg/kg 331 06/07/15 20:16 EPA 6010 Chromium 21.0 mg/kg 3.3 06/07/15 20:16 EPA 6010 Copper 18.8 mg/kg 3.3 06/07/15 20:16 EPA 6010 Iron 20700 mg/kg 26.5 06/07/15 20:16 EPA 6010 Magnesium 1830 mg/kg 331 06/07/15 20:16 EPA 6010 Manganese 1020 mg/kg 3.3 06/07/15 20:16 EPA 6010 Nickel 7.9 mg/kg 3.3 06/07/15 20:16 EPA 6010 Potassium 385J mg/kg 662 06/07/15 20:16 EPA 6010 Strontium 15.1 mg/kg 6.6 06/07/15 20:16 EPA 6010 Zinc 60.8 mg/kg 13.2 06/07/15 20:16 EPA 6020 Cobalt 12AJ mg/kg 13.2 06/10/15 09:12 EPA 6020 Lead 14.1 mg/kg 13.2 06/10/15 09:12 EPA 6020 Vanadium 41.9 mg/kg 13.2 06/10/15 09:12 EPA 7471 Mercury 0.078 mg/kg 0.022 06/09/15 14:20 ASTM D2974-87 Percent Moisture 62.7 % 0.10 06/09/15 08:55 EPA 9045 pH at 25 Degrees C 6.4 Std. Units 0.10 06/07/15 14:55 EPA 9060 Total Organic Carbon 30000 mg/kg 5310 06/24/15 11:02 EPA 9060 Total Organic Carbon 26400 mg/kg 5360 06/24/15 11:07 EPA 9060 Total Organic Carbon 23400 mg/kg 5360 06/24/15 11:12 EPA 9060 Total Organic Carbon 25400 mg/kg 5420 06/24/15 11:19 EPA 9060 Mean Total Organic Carbon 26300 mg/kg 5360 06/24/15 11:02 EPA 9060 RSD% 10.5 % 06/24/15 11:02 92252369002 201501615 EPA 6010 Aluminum 3890 mg/kg 42.7 06/07/15 20:20 EPA 6010 Barium 45.3 mg/kg 4.3 06/07/15 20:20 EPA 6010 Calcium 510 mg/kg 214 06/07/15 20:20 EPA 6010 Chromium 16.6 mg/kg 2.1 06/07/15 20:20 EPA 6010 Copper 6.7 mg/kg 2.1 06/07/15 20:20 EPA 6010 Iron 10000 mg/kg 17.1 06/07/15 20:20 EPA 6010 Magnesium 726 mg/kg 214 06/07/15 20:20 EPA 6010 Manganese 731 mg/kg 2.1 06/07/15 20:20 EPA 6010 Nickel 3.0 mg/kg 2.1 06/07/15 20:20 EPA 6010 Strontium 5.4 mg/kg 4.3 06/07/15 20:20 EPA 6010 Zinc 27.8 mg/kg 8.5 06/07/15 20:20 EPA 6020 Cobalt 6.6J mg/kg 8.5 06/10/15 09:15 EPA 6020 Lead 5.9J mg/kg 8.5 06/10/15 09:15 EPA 6020 Vanadium 24.6 mg/kg 8.5 06/10/15 09:15 EPA 7471 Mercury 0.026 mg/kg 0.014 06/09/15 14:22 ASTM D2974-87 Percent Moisture 39.6 % 0.10 06/09/15 08:56 EPA 9045 pH at 25 Degrees C 7.4 Std. Units 0.10 06/07/15 14:55 EPA 9060 Total Organic Carbon 5720 mg/kg 1000 06/22/15 15:50 EPA 9060 Total Organic Carbon 4160 mg/kg 1000 06/22/15 15:55 EPA 9060 Total Organic Carbon 3860 mg/kg 984 06/22/15 16:02 REPORT OF LABORATORY ANALYSIS 1g 1g Qualifiers This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 5 of 38 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffli�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15060005 Pace Project No.: 92252369 Lab Sample ID Method Client Sample ID Parameters 92252369002 201501615 EPA 9060 Total Organic Carbon EPA 9060 Mean Total Organic Carbon EPA 9060 RSD% 92252369003 201501616 EPA 6010 Aluminum EPA 6010 Barium EPA 6010 Beryllium EPA 6010 Calcium EPA 6010 Chromium EPA 6010 Copper EPA 6010 Iron EPA 6010 Magnesium EPA 6010 Manganese EPA 6010 Nickel EPA 6010 Strontium EPA 6010 Zinc EPA 6020 Cobalt EPA 6020 Lead EPA 6020 Vanadium EPA 7471 Mercury ASTM D2974-87 Percent Moisture EPA 9045 pH at 25 Degrees C EPA 9060 Total Organic Carbon EPA 9060 Total Organic Carbon EPA 9060 Total Organic Carbon EPA 9060 Total Organic Carbon EPA 9060 Mean Total Organic Carbon EPA 9060 RSD% SUMMARY OF DETECTION Result Units Report Limit Analyzed Qualifiers 3110 mg/kg 998 06/22/1516:07 4210 mg/kg 996 06/22/1515:50 26.1 % 06/22/1515:50 6470 mg/kg 46.7 06/07/15 20:25 58.7 mg/kg 4.7 06/07/15 20:25 0.26J mg/kg 0.47 06/07/15 20:25 917 mg/kg 233 06/07/15 20:25 8.9 mg/kg 2.3 06/07/15 20:25 9.6 mg/kg 2.3 06/07/15 20:25 11200 mg/kg 18.7 06/07/15 20:25 1g 1020 mg/kg 233 06/07/15 20:25 459 mg/kg 2.3 06/07/15 20:25 4.1 mg/kg 2.3 06/07/15 20:25 8.7 mg/kg 4.7 06/07/15 20:25 25.3 mg/kg 9.3 06/07/15 20:25 7.8J mg/kg 9.3 06/10/15 09:24 7.2J mg/kg 9.3 06/10/15 09:24 23.8 mg/kg 9.3 06/10/15 09:24 0.060 mg/kg 0.015 06/09/1514:24 47.8 % 0.10 06/09/15 08:56 D6 6.4 Std. Units 0.10 06/07/15 14:55 17000 mg/kg 1140 06/22/1516:27 18200 mg/kg 1150 06/22/1516:33 14900 mg/kg 1150 06/22/1516:39 21700 mg/kg 1150 06/22/1516:44 18000 mg/kg 1150 06/22/1516:27 15.9 % 06/22/1516:27 92252369004 201501617 EPA 6010 Aluminum 2660 mg/kg 55.9 06/07/15 20:29 EPA 6010 Barium 34.4 mg/kg 5.6 06/07/15 20:29 EPA 6010 Beryllium 0.46J mg/kg 0.56 06/07/15 20:29 EPA 6010 Boron 160 mg/kg 28.0 06/07/15 20:29 EPA 6010 Calcium 647 mg/kg 280 06/07/15 20:29 EPA 6010 Chromium 2.3J mg/kg 2.8 06/07/15 20:29 EPA 6010 Copper 12.1 mg/kg 2.8 06/07/15 20:29 EPA 6010 Iron 345000 mg/kg 112 06/13/15 21:10 D4 EPA 6010 Magnesium 317 mg/kg 280 06/07/15 20:29 EPA 6010 Manganese 54.8 mg/kg 2.8 06/07/15 20:29 EPA 6010 Potassium 1190 mg/kg 559 06/07/15 20:29 EPA 6010 Strontium 16.1 mg/kg 5.6 06/07/15 20:29 EPA 6010 Zinc 20.7 mg/kg 11.2 06/07/15 20:29 EPA 6020 Arsenic 230 mg/kg 11.2 06/10/15 09:26 EPA 6020 Vanadium 25.1 mg/kg 11.2 06/10/15 09:26 EPA 7471 Mercury 0.024 mg/kg 0.019 06/09/15 14:27 ASTM D2974-87 Percent Moisture 55.5 % 0.10 06/09/15 08:56 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 6 of 38 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 fflic&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Project: J15060005 Pace Project No.: 92252369 Lab Sample ID Client Sample ID Method Parameters Result Units 92252369004 201501617 EPA 9045 pH at 25 Degrees C 2.9 Std. Units EPA 9060 Total Organic Carbon 18000 mg/kg EPA 9060 Total Organic Carbon 19600 mg/kg EPA 9060 Total Organic Carbon 20700 mg/kg EPA 9060 Total Organic Carbon 19900 mg/kg EPA 9060 Mean Total Organic Carbon 19500 mg/kg EPA 9060 RSD% 5.8 % REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Report Limit Analyzed Qualifiers 0.10 06/07/1514:55 1350 06/22/1516:50 1350 06/22/1516:56 1340 06/22/1517:01 1350 06/22/1517:07 1350 06/22/1516:50 06/22/15 16:50 Page 7 of 38 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffli�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060005 Pace Project No.: 92252369 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: June 25, 2015 General Information: 4 samples were analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. QC Batch: MPRP/24564 CH: The continuing calibration for this compound is outside of Pace Analytical acceptance limits. The results may be biased high. • MS (Lab ID: 1234522) • Iron • MSD (Lab ID: 1234523) • Iron Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/24564 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92252110014 M1: Matrix spike recovery exceeded QC limits. • MS (Lab ID: 1234522) • Aluminum • Iron • Manganese • MSD (Lab ID: 1234523) • Aluminum • Iron • Manganese Batch accepted based on laboratory control sample (LCS) recovery. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 8 of 38 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffli�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060005 Pace Project No.: 92252369 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: June 25, 2015 Additional Comments: Batch Comments: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. • QC Batch: ICP / 15002 Analyte Comments: QC Batch: MPRP/24564 1g: Analyte was detected in the continueing calibration verification low level (CCVL). All associated samples had concentrations of at least ten times greater than the CCVL or were below the reporting limit. •201501614 (Lab ID:92252369001) • Iron •201501615 (Lab ID:92252369002) • Iron •201501616 (Lab ID:92252369003) • Iron D4: Sample was diluted due to the presence of high levels of target analytes. •201501617 (Lab ID:92252369004) • Iron REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 9 of 38 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 fflic&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060005 Pace Project No.: 92252369 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: June 25, 2015 General Information: 4 samples were analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/24565 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92252110014 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • MS (Lab ID: 1234526) • Arsenic • Selenium • Vanadium • MSD (Lab ID: 1234527) • Arsenic • Vanadium Additional Comments: Batch Comments: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. • QC Batch: ICPM / 9947 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 10 of 38 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffiigc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060005 Pace Project No.: 92252369 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: June 25, 2015 Analyte Comments: QC Batch: MPRP/24565 N2: The lab does not hold TNI accreditation for this parameter. • 201501614 (Lab ID: 92252369001) • Antimony •201501615 (Lab ID:92252369002) • Antimony •201501616 (Lab ID:92252369003) • Antimony •201501617 (Lab ID:92252369004) • Antimony • BLANK (Lab ID: 1234524) • Antimony • LCS (Lab ID: 1234525) • Antimony • MS (Lab ID: 1234526) • Antimony • MSD (Lab ID: 1234527) • Antimony REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 11 of 38 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 %cigy&.. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060005 Pace Project No.: 92252369 Method: EPA 7471 Description: 7471 Mercury Client: Duke Energy Date: June 25, 2015 General Information: 4 samples were analyzed for EPA 7471. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7471 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 12 of 38 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KP�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060005 Pace Project No.: 92252369 Method: EPA 9045 Description: 9045 pH Soil Client: Duke Energy Date: June 25, 2015 General Information: 4 samples were analyzed for EPA 9045. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Duplicate Sample: All duplicate sample results were within method acceptance criteria with any exceptions noted below. QC Batch: WET/37839 D6: The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits. • DUP (Lab ID: 1473422) • pH at 25 Degrees C Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 13 of 38 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K�nic&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060005 Pace Project No.: 92252369 Method: EPA 9056 Description: 9056 IC Anions Client: Duke Energy Date: June 25, 2015 General Information: 4 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/47029 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •201501614 (Lab ID:92252369001) • Chloride • Sulfate •201501615 (Lab ID:92252369002) • Chloride • Sulfate •201501616 (Lab ID:92252369003) • Chloride • Sulfate •201501617 (Lab ID:92252369004) • Chloride • Sulfate REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 14 of 38 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KP�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060005 Pace Project No.: 92252369 Method: EPA 9056 Description: 9056 IC Anions 48hr Client: Duke Energy Date: June 25, 2015 General Information: 4 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 113: Sample was received or analysis requested beyond the recognized method holding time. • 201501614 (Lab ID: 92252369001) •201501615 (Lab ID:92252369002) •201501616 (Lab ID:92252369003) •201501617 (Lab ID:92252369004) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/47028 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •201501614 (Lab ID:92252369001) • Nitrate as N •201501615 (Lab ID:92252369002) • Nitrate as N •201501616 (Lab ID:92252369003) • Nitrate as N •201501617 (Lab ID:92252369004) • Nitrate as N REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 15 of 38 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KP�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060005 Pace Project No.: 92252369 Method: EPA 9060 Description: Total Organic Carbon Quad Client: Duke Energy Date: June 25, 2015 General Information: 4 samples were analyzed for EPA 9060. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: This data package has been reviewed for quality and completeness and is approved for release. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 16 of 38 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KPc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15060005 Pace Project No.: 92252369 Sample: 201501614 Lab ID: 92252369001 Collected: 05/28/15 11:40 Received: 06/01/15 18:40 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 11700 mg/kg 66.2 33.1 5 06/06/15 15:46 06/07/15 20:16 7429-90-5 Barium 115 mg/kg 6.6 3.3 5 06/06/15 15:46 06/07/15 20:16 7440-39-3 Beryllium 0.45J mg/kg 0.66 0.33 5 06/06/15 15:46 06/07/15 20:16 7440-41-7 Boron 18.8J mg/kg 33.1 16.5 5 06/06/15 15:46 06/07/15 20:16 7440-42-8 Calcium 1510 mg/kg 331 165 5 06/06/15 15:46 06/07/15 20:16 7440-70-2 Chromium 21.0 mg/kg 3.3 1.7 5 06/06/15 15:46 06/07/15 20:16 7440-47-3 Copper 18.8 mg/kg 3.3 1.7 5 06/06/15 15:46 06/07/15 20:16 7440-50-8 Iron 20700 mg/kg 26.5 13.2 5 06/06/15 15:46 06/07/15 20:16 7439-89-6 1g Magnesium 1830 mg/kg 331 165 5 06/06/15 15:46 06/07/15 20:16 7439-95-4 Manganese 1020 mg/kg 3.3 1.7 5 06/06/15 15:46 06/07/15 20:16 7439-96-5 Molybdenum ND mg/kg 6.6 3.3 5 06/06/15 15:46 06/07/15 20:16 7439-98-7 Nickel 7.9 mg/kg 3.3 1.7 5 06/06/15 15:46 06/07/15 20:16 7440-02-0 Potassium 385J mg/kg 662 331 5 06/06/15 15:46 06/07/15 20:16 7440-09-7 Sodium ND mg/kg 662 331 5 06/06/15 15:46 06/07/15 20:16 7440-23-5 Strontium 15.1 mg/kg 6.6 3.3 5 06/06/15 15:46 06/07/15 20:16 7440-24-6 Zinc 60.8 mg/kg 13.2 6.6 5 06/06/15 15:46 06/07/15 20:16 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 13.2 6.6 100 06/06/15 15:46 06/10/15 09:12 7440-36-0 N2 Arsenic ND mg/kg 13.2 6.6 100 06/06/15 15:46 06/10/15 09:12 7440-38-2 Cadmium ND mg/kg 1.6 0.79 100 06/06/15 15:46 06/10/15 09:12 7440-43-9 Cobalt 12AJ mg/kg 13.2 6.6 100 06/06/15 15:46 06/10/15 09:12 7440-48-4 Lead 14.1 mg/kg 13.2 6.6 100 06/06/15 15:46 06/10/15 09:12 7439-92-1 Selenium ND mg/kg 13.2 6.6 100 06/06/15 15:46 06/10/15 09:12 7782-49-2 Thallium ND mg/kg 13.2 6.6 100 06/06/15 15:46 06/10/15 09:12 7440-28-0 Vanadium 41.9 mg/kg 13.2 6.6 100 06/06/15 15:46 06/10/15 09:12 7440-62-2 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury 0.078 mg/kg 0.022 0.011 1 06/06/1516:00 06/09/1514:20 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 62.7 % 0.10 0.10 1 06/09/15 08:55 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 6.4 Std. Units 0.10 0.10 1 06/07/15 14:55 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 678 339 5 06/06/15 07:38 16887-00-6 D3,M1 Sulfate ND mg/kg 678 339 5 06/06/15 07:38 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 67.8 33.9 5 06/06/15 07:38 14797-55-8 D3,H3 Date: 06/25/2015 02:51 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 17 of 38 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KP�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15060005 Pace Project No.: 92252369 Sample: 201501614 Lab ID: 92252369001 Collected: 05/28/15 11:40 Received: 06/01/15 18:40 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 30000 mg/kg 5310 2650 1 06/24/15 11:02 7440-44-0 Total Organic Carbon 26400 mg/kg 5360 2680 1 06/24/15 11:07 7440-44-0 Total Organic Carbon 23400 mg/kg 5360 2680 1 06/24/15 11:12 7440-44-0 Total Organic Carbon 25400 mg/kg 5420 2710 1 06/24/15 11:19 7440-44-0 Mean Total Organic Carbon 26300 mg/kg 5360 2680 1 06/24/15 11:02 7440-44-0 Surrogates RSD% 10.5 % 1 06/24/15 11:02 Date: 06/25/2015 02:51 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 18 of 38 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K��c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15060005 Pace Project No.: 92252369 Sample: 201501615 Lab ID: 92252369002 Collected: 05/28/15 10:20 Received: 06/01/15 18:40 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 3890 mg/kg 42.7 21.4 5 06/06/15 15:46 06/07/15 20:20 7429-90-5 Barium 45.3 mg/kg 4.3 2.1 5 06/06/15 15:46 06/07/15 20:20 7440-39-3 Beryllium ND mg/kg 0.43 0.21 5 06/06/15 15:46 06/07/15 20:20 7440-41-7 Boron ND mg/kg 21.4 10.7 5 06/06/15 15:46 06/07/15 20:20 7440-42-8 Calcium 510 mg/kg 214 107 5 06/06/15 15:46 06/07/15 20:20 7440-70-2 Chromium 16.6 mg/kg 2.1 1.1 5 06/06/15 15:46 06/07/15 20:20 7440-47-3 Copper 6.7 mg/kg 2.1 1.1 5 06/06/15 15:46 06/07/15 20:20 7440-50-8 Iron 10000 mg/kg 17.1 8.5 5 06/06/15 15:46 06/07/15 20:20 7439-89-6 1g Magnesium 726 mg/kg 214 107 5 06/06/15 15:46 06/07/15 20:20 7439-95-4 Manganese 731 mg/kg 2.1 1.1 5 06/06/15 15:46 06/07/15 20:20 7439-96-5 Molybdenum ND mg/kg 4.3 2.1 5 06/06/15 15:46 06/07/15 20:20 7439-98-7 Nickel 3.0 mg/kg 2.1 1.1 5 06/06/15 15:46 06/07/15 20:20 7440-02-0 Potassium ND mg/kg 427 214 5 06/06/15 15:46 06/07/15 20:20 7440-09-7 Sodium ND mg/kg 427 214 5 06/06/15 15:46 06/07/15 20:20 7440-23-5 Strontium 5.4 mg/kg 4.3 2.1 5 06/06/15 15:46 06/07/15 20:20 7440-24-6 Zinc 27.8 mg/kg 8.5 4.3 5 06/06/15 15:46 06/07/15 20:20 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 8.5 4.3 100 06/06/15 15:46 06/10/15 09:15 7440-36-0 N2 Arsenic ND mg/kg 8.5 4.3 100 06/06/15 15:46 06/10/15 09:15 7440-38-2 Cadmium ND mg/kg 1.0 0.51 100 06/06/15 15:46 06/10/15 09:15 7440-43-9 Cobalt 6.6J mg/kg 8.5 4.3 100 06/06/15 15:46 06/10/15 09:15 7440-48-4 Lead 5.9J mg/kg 8.5 4.3 100 06/06/15 15:46 06/10/15 09:15 7439-92-1 Selenium ND mg/kg 8.5 4.3 100 06/06/15 15:46 06/10/15 09:15 7782-49-2 Thallium ND mg/kg 8.5 4.3 100 06/06/15 15:46 06/10/15 09:15 7440-28-0 Vanadium 24.6 mg/kg 8.5 4.3 100 06/06/15 15:46 06/10/15 09:15 7440-62-2 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury 0.026 mg/kg 0.014 0.0068 1 06/06/1516:00 06/09/1514:22 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 39.6 % 0.10 0.10 1 06/09/15 08:56 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 7.4 Std. Units 0.10 0.10 1 06/07/15 14:55 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 418 209 5 06/06/15 08:42 16887-00-6 D3 Sulfate ND mg/kg 418 209 5 06/06/15 08:42 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 41.8 20.9 5 06/06/15 08:42 14797-55-8 D3,H3 Date: 06/25/2015 02:51 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 19 of 38 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15060005 Pace Project No.: 92252369 Sample: 201501615 Lab ID: 92252369002 Collected: 05/28/15 10:20 Received: 06/01/15 18:40 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 5720 mg/kg 1000 500 1 06/22/15 15:50 7440-44-0 Total Organic Carbon 4160 mg/kg 1000 502 1 06/22/15 15:55 7440-44-0 Total Organic Carbon 3860 mg/kg 984 492 1 06/22/15 16:02 7440-44-0 Total Organic Carbon 3110 mg/kg 998 499 1 06/22/15 16:07 7440-44-0 Mean Total Organic Carbon 4210 mg/kg 996 498 1 06/22/15 15:50 7440-44-0 Surrogates RSD% 26.1 % 1 06/22/15 15:50 Date: 06/25/2015 02:51 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 20 of 38 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KPgc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15060005 Pace Project No.: 92252369 Sample: 201501616 Lab ID: 92252369003 Collected: 05/28/15 09:55 Received: 06/01/15 18:40 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 6470 mg/kg 46.7 23.3 5 06/06/15 15:46 06/07/15 20:25 7429-90-5 Barium 58.7 mg/kg 4.7 2.3 5 06/06/15 15:46 06/07/15 20:25 7440-39-3 Beryllium 0.26J mg/kg 0.47 0.23 5 06/06/15 15:46 06/07/15 20:25 7440-41-7 Boron ND mg/kg 23.3 11.7 5 06/06/15 15:46 06/07/15 20:25 7440-42-8 Calcium 917 mg/kg 233 117 5 06/06/15 15:46 06/07/15 20:25 7440-70-2 Chromium 8.9 mg/kg 2.3 1.2 5 06/06/15 15:46 06/07/15 20:25 7440-47-3 Copper 9.6 mg/kg 2.3 1.2 5 06/06/15 15:46 06/07/15 20:25 7440-50-8 Iron 11200 mg/kg 18.7 9.3 5 06/06/15 15:46 06/07/15 20:25 7439-89-6 1g Magnesium 1020 mg/kg 233 117 5 06/06/15 15:46 06/07/15 20:25 7439-95-4 Manganese 459 mg/kg 2.3 1.2 5 06/06/15 15:46 06/07/15 20:25 7439-96-5 Molybdenum ND mg/kg 4.7 2.3 5 06/06/15 15:46 06/07/15 20:25 7439-98-7 Nickel 4.1 mg/kg 2.3 1.2 5 06/06/15 15:46 06/07/15 20:25 7440-02-0 Potassium ND mg/kg 467 233 5 06/06/15 15:46 06/07/15 20:25 7440-09-7 Sodium ND mg/kg 467 233 5 06/06/15 15:46 06/07/15 20:25 7440-23-5 Strontium 8.7 mg/kg 4.7 2.3 5 06/06/15 15:46 06/07/15 20:25 7440-24-6 Zinc 25.3 mg/kg 9.3 4.7 5 06/06/15 15:46 06/07/15 20:25 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 9.3 4.7 100 06/06/15 15:46 06/10/15 09:24 7440-36-0 N2 Arsenic ND mg/kg 9.3 4.7 100 06/06/15 15:46 06/10/15 09:24 7440-38-2 Cadmium ND mg/kg 1.1 0.56 100 06/06/15 15:46 06/10/15 09:24 7440-43-9 Cobalt 7.8J mg/kg 9.3 4.7 100 06/06/15 15:46 06/10/15 09:24 7440-48-4 Lead 7.2J mg/kg 9.3 4.7 100 06/06/15 15:46 06/10/15 09:24 7439-92-1 Selenium ND mg/kg 9.3 4.7 100 06/06/15 15:46 06/10/15 09:24 7782-49-2 Thallium ND mg/kg 9.3 4.7 100 06/06/15 15:46 06/10/15 09:24 7440-28-0 Vanadium 23.8 mg/kg 9.3 4.7 100 06/06/15 15:46 06/10/15 09:24 7440-62-2 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury 0.060 mg/kg 0.015 0.0076 1 06/06/1516:00 06/09/1514:24 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 47.8 % 0.10 0.10 1 06/09/15 08:56 D6 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 6.4 Std. Units 0.10 0.10 1 06/07/15 14:55 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 470 235 5 06/06/15 09:04 16887-00-6 D3 Sulfate ND mg/kg 470 235 5 06/06/15 09:04 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 47.0 23.5 5 06/06/15 09:04 14797-55-8 D3,H3 Date: 06/25/2015 02:51 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 21 of 38 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K��c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15060005 Pace Project No.: 92252369 Sample: 201501616 Lab ID: 92252369003 Collected: 05/28/15 09:55 Received: 06/01/15 18:40 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 17000 mg/kg 1140 570 1 06/22/15 16:27 7440-44-0 Total Organic Carbon 18200 mg/kg 1150 575 1 06/22/15 16:33 7440-44-0 Total Organic Carbon 14900 mg/kg 1150 575 1 06/22/15 16:39 7440-44-0 Total Organic Carbon 21700 mg/kg 1150 574 1 06/22/15 16:44 7440-44-0 Mean Total Organic Carbon 18000 mg/kg 1150 574 1 06/22/15 16:27 7440-44-0 Surrogates RSD% 15.9 % 1 06/22/15 16:27 Date: 06/25/2015 02:51 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 22 of 38 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K��c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15060005 Pace Project No.: 92252369 Sample: 201501617 Lab ID: 92252369004 Collected: 05/28/15 10:55 Received: 06/01/15 18:40 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 2660 mg/kg 55.9 28.0 5 06/06/15 15:46 06/07/15 20:29 7429-90-5 Barium 34.4 mg/kg 5.6 2.8 5 06/06/15 15:46 06/07/15 20:29 7440-39-3 Beryllium 0.46J mg/kg 0.56 0.28 5 06/06/15 15:46 06/07/15 20:29 7440-41-7 Boron 160 mg/kg 28.0 14.0 5 06/06/15 15:46 06/07/15 20:29 7440-42-8 Calcium 647 mg/kg 280 140 5 06/06/15 15:46 06/07/15 20:29 7440-70-2 Chromium 2.3J mg/kg 2.8 1.4 5 06/06/15 15:46 06/07/15 20:29 7440-47-3 Copper 12.1 mg/kg 2.8 1.4 5 06/06/15 15:46 06/07/15 20:29 7440-50-8 Iron 345000 mg/kg 112 55.9 25 06/06/15 15:46 06/13/15 21:10 7439-89-6 D4 Magnesium 317 mg/kg 280 140 5 06/06/15 15:46 06/07/15 20:29 7439-95-4 Manganese 54.8 mg/kg 2.8 1.4 5 06/06/15 15:46 06/07/15 20:29 7439-96-5 Molybdenum ND mg/kg 5.6 2.8 5 06/06/15 15:46 06/07/15 20:29 7439-98-7 Nickel ND mg/kg 2.8 1.4 5 06/06/15 15:46 06/07/15 20:29 7440-02-0 Potassium 1190 mg/kg 559 280 5 06/06/15 15:46 06/07/15 20:29 7440-09-7 Sodium ND mg/kg 559 280 5 06/06/15 15:46 06/07/15 20:29 7440-23-5 Strontium 16.1 mg/kg 5.6 2.8 5 06/06/15 15:46 06/07/15 20:29 7440-24-6 Zinc 20.7 mg/kg 11.2 5.6 5 06/06/15 15:46 06/07/15 20:29 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 11.2 5.6 100 06/06/15 15:46 06/10/15 09:26 7440-36-0 N2 Arsenic 230 mg/kg 11.2 5.6 100 06/06/15 15:46 06/10/15 09:26 7440-38-2 Cadmium ND mg/kg 1.3 0.67 100 06/06/15 15:46 06/10/15 09:26 7440-43-9 Cobalt ND mg/kg 11.2 5.6 100 06/06/15 15:46 06/10/15 09:26 7440-48-4 Lead ND mg/kg 11.2 5.6 100 06/06/15 15:46 06/10/15 09:26 7439-92-1 Selenium ND mg/kg 11.2 5.6 100 06/06/15 15:46 06/10/15 09:26 7782-49-2 Thallium ND mg/kg 11.2 5.6 100 06/06/15 15:46 06/10/15 09:26 7440-28-0 Vanadium 25.1 mg/kg 11.2 5.6 100 06/06/15 15:46 06/10/15 09:26 7440-62-2 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury 0.024 mg/kg 0.019 0.0093 1 06/06/1516:00 06/09/1514:27 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 55.5 % 0.10 0.10 1 06/09/15 08:56 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 2.9 Std. Units 0.10 0.10 1 06/07/15 14:55 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 567 283 5 06/06/15 09:25 16887-00-6 D3 Sulfate ND mg/kg 567 283 5 06/06/15 09:25 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 56.7 28.3 5 06/06/15 09:25 14797-55-8 D3,H3 Date: 06/25/2015 02:51 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 23 of 38 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K�n�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15060005 Pace Project No.: 92252369 Sample: 201501617 Lab ID: 92252369004 Collected: 05/28/15 10:55 Received: 06/01/15 18:40 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 18000 mg/kg 1350 673 1 06/22/15 16:50 7440-44-0 Total Organic Carbon 19600 mg/kg 1350 675 1 06/22/15 16:56 7440-44-0 Total Organic Carbon 20700 mg/kg 1340 671 1 06/22/15 17:01 7440-44-0 Total Organic Carbon 19900 mg/kg 1350 676 1 06/22/15 17:07 7440-44-0 Mean Total Organic Carbon 19500 mg/kg 1350 674 1 06/22/15 16:50 7440-44-0 Surrogates RSD% 5.8 % 1 06/22/15 16:50 Date: 06/25/2015 02:51 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 24 of 38 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K��c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060005 Pace Project No.: 92252369 QC Batch: MERP/5823 Analysis Method: EPA 7471 QC Batch Method: EPA 7471 Analysis Description: 7471 Mercury Associated Lab Samples: 92252369001, 92252369002, 92252369003, 92252369004 METHOD BLANK: 1234528 Matrix: Solid Associated Lab Samples: 92252369001, 92252369002, 92252369003, 92252369004 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury mg/kg ND 0.0081 06/09/1513:50 LABORATORY CONTROL SAMPLE: 1234529 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury mg/kg .082 0.089 108 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1234530 1234531 MS MSD 92252110014 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury mg/kg ND .102 .0987 0.097 0.087 93 87 80-120 11 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/25/2015 02:51 PM without the written consent of Pace Analytical Services, Inc.. Page 25 of 38 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060005 Pace Project No.: 92252369 QC Batch: MPRP/24564 Analysis Method: EPA 6010 QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid Associated Lab Samples: 92252369001, 92252369002, 92252369003, 92252369004 METHOD BLANK: 1234520 Matrix: Solid Associated Lab Samples: 92252369001, 92252369002, 92252369003, 92252369004 Blank Reporting Parameter Units Result Limit Analyzed Aluminum mg/kg ND 5.2 06/07/1518:49 Barium mg/kg ND 0.52 06/07/1518:49 Beryllium mg/kg ND 0.052 06/07/1518:49 Boron mg/kg ND 2.6 06/07/1518:49 Calcium mg/kg ND 25.8 06/07/1518:49 Chromium mg/kg ND 0.26 06/07/1518:49 Copper mg/kg ND 0.26 06/07/1518:49 Iron mg/kg ND 2.1 06/07/1518:49 Magnesium mg/kg ND 25.8 06/07/1518:49 Manganese mg/kg ND 0.26 06/07/1518:49 Molybdenum mg/kg ND 0.52 06/07/1518:49 Nickel mg/kg ND 0.26 06/07/1518:49 Potassium mg/kg ND 51.5 06/07/1518:49 Sodium mg/kg ND 51.5 06/07/1518:49 Strontium mg/kg ND 0.52 06/07/1518:49 Zinc mg/kg ND 1.0 06/07/1518:49 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 1234521 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Aluminum mg/kg 126 118 93 80-120 Barium mg/kg 12.6 11.8 94 80-120 Beryllium mg/kg 1.3 1.2 92 80-120 Boron mg/kg 126 117 93 80-120 Calcium mg/kg 629 594 94 80-120 Chromium mg/kg 12.6 11.5 92 80-120 Copper mg/kg 12.6 11.5 91 80-120 Iron mg/kg 126 115 91 80-120 Magnesium mg/kg 629 583 93 80-120 Manganese mg/kg 12.6 11.7 93 80-120 Molybdenum mg/kg 12.6 11.5 92 80-120 Nickel mg/kg 12.6 11.7 93 80-120 Potassium mg/kg 629 574 91 80-120 Sodium mg/kg 629 594 94 80-120 Strontium mg/kg 12.6 11.6 92 80-120 Zinc mg/kg 62.9 57.9 92 80-120 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/25/2015 02:51 PM without the written consent of Pace Analytical Services, Inc.. Page 26 of 38 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060005 Pace Project No.: 92252369 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1234522 1234523 MS MSD 92252110014 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum mg/kg 3080 157 149 4100 3850 650 518 75-125 6 20 M1 Barium mg/kg 13.4 15.7 14.9 27.2 26.9 88 91 75-125 1 20 Beryllium mg/kg 0.43 1.52 1.52 1.8 1.8 90 90 75-125 4 20 Boron mg/kg 9.6J 157 149 151 145 90 91 75-125 4 20 Calcium mg/kg 239 787 748 1010 961 98 97 75-125 5 20 Chromium mg/kg 5.5 15.7 14.9 20.0 18.8 92 89 75-125 6 20 Copper mg/kg 1.9 15.7 14.9 16.2 15.5 90 91 75-125 4 20 Iron mg/kg 10400 157 149 9260 8860 -729 -1040 75-125 4 20 CH,M1 Magnesium mg/kg 500 787 748 1190 1190 88 92 75-125 0 20 Manganese mg/kg 90.9 15.7 14.9 96.0 83.6 32 -49 75-125 14 20 M1 Molybdenum mg/kg 4.5 15.7 14.9 18.5 17.9 89 89 75-125 4 20 Nickel mg/kg 1.8 15.7 14.9 17.5 16.7 100 100 75-125 5 20 Potassium mg/kg 338 787 748 999 1000 84 89 75-125 0 20 Sodium mg/kg ND 787 748 784 717 100 96 75-125 9 20 Strontium mg/kg 4.5 15.7 14.9 19.6 18.4 95 93 75-125 6 20 Zinc mg/kg 5.9J 78.7 74.8 79.4 77.3 93 95 75-125 3 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/25/2015 02:51 PM without the written consent of Pace Analytical Services, Inc.. Page 27 of 38 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K3�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060005 Pace Project No.: 92252369 QC Batch: MPRP/24565 Analysis Method: EPA 6020 QC Batch Method: EPA 3050 Analysis Description: 6020 MET SOLID Associated Lab Samples: 92252369001, 92252369002, 92252369003, 92252369004 METHOD BLANK: 1234524 Matrix: Solid Associated Lab Samples: 92252369001, 92252369002, 92252369003, 92252369004 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Antimony mg/kg ND 0.051 06/10/15 08:38 N2 Arsenic mg/kg ND 0.051 06/10/15 08:38 Cadmium mg/kg ND 0.0061 06/10/15 08:38 Cobalt mg/kg ND 0.051 06/10/15 08:38 Lead mg/kg ND 0.051 06/10/15 08:38 Selenium mg/kg ND 0.051 06/10/15 08:38 Thallium mg/kg ND 0.051 06/10/15 08:38 Vanadium mg/kg ND 0.051 06/10/15 08:38 LABORATORY CONTROL SAMPLE: Parameter 1234525 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Antimony mg/kg 2.5 2.6 102 80-120 N2 Arsenic mg/kg 2.5 2.6 102 80-120 Cadmium mg/kg .25 0.26 102 80-120 Cobalt mg/kg 2.5 2.6 103 80-120 Lead mg/kg 2.5 2.6 104 80-120 Selenium mg/kg 2.5 2.6 103 80-120 Thallium mg/kg 2.5 2.7 105 80-120 Vanadium mg/kg 2.5 2.6 103 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1234526 1234527 MS MSD 92252110014 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony mg/kg ND 3.29 3.16 ND ND 90 78 75-125 20 N2 Arsenic mg/kg 49.5 3.29 3.16 47.8 42.3 -53 -225 75-125 12 20 M6 Cadmium mg/kg ND .329 .316 ND ND 84 82 75-125 20 Cobalt mg/kg ND 3.29 3.16 5.5J 5.3J 82 78 75-125 20 Lead mg/kg ND 3.29 3.16 4.5J 4.3J 87 83 75-125 20 Selenium mg/kg ND 3.29 3.16 4.6J 3.6J 132 103 75-125 20 M6 Thallium mg/kg ND 3.29 3.16 3.6J 3.3J 101 92 75-125 20 Vanadium mg/kg 10.4 3.29 3.16 12.4 12.3 62 58 75-125 1 20 M6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/25/2015 02:51 PM without the written consent of Pace Analytical Services, Inc.. Page 28 of 38 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K��c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060005 Pace Project No.: 92252369 QC Batch: PMST/3626 Analysis Method: ASTM D2974-87 QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture Associated Lab Samples: 92252369001, 92252369002, 92252369003, 92252369004 SAMPLE DUPLICATE: 1236448 35190638001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 23.8 22.8 5 10 SAMPLE DUPLICATE: 1236449 92252369003 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 47.8 54.2 13 10 D6 SAMPLE DUPLICATE: 1236450 35191113002 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 15.9 15.2 5 10 SAMPLE DUPLICATE: 1236451 35191437001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 15.1 16.3 8 10 SAMPLE DUPLICATE: 1236452 35191894001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 10.2 10.6 3 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/25/2015 02:51 PM without the written consent of Pace Analytical Services, Inc.. Page 29 of 38 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K3c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060005 Pace Project No.: 92252369 QC Batch: WET/37839 Analysis Method: EPA 9045 QC Batch Method: EPA 9045 Analysis Description: 9045 pH Associated Lab Samples: 92252369001, 92252369002, 92252369003, 92252369004 SAMPLE DUPLICATE: 1473421 92252023001 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 8.0 8.1 1 10 SAMPLE DUPLICATE: 1473422 92252110007 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 6.4 6.5 2 10 D6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/25/2015 02:51 PM without the written consent of Pace Analytical Services, Inc.. Page 30 of 38 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K�gc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060005 Pace Project No.: 92252369 QC Batch: WETA/47029 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92252369001, 92252369002, 92252369003, 92252369004 METHOD BLANK: 1233607 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/kg ND 49.8 06/06/15 06:55 Sulfate mg/kg ND 49.8 06/06/15 06:55 LABORATORY CONTROL SAMPLE: 1233608 Parameter Units Chloride mg/kg Sulfate mg/kg MATRIX SPIKE SAMPLE: 1233610 Parameter Units Chloride mg/kg Sulfate mg/kg SAMPLE DUPLICATE: 1233609 Parameter Chloride Sulfate Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 496 510 103 80-120 496 507 102 80-120 92252369001 Spike MS MS % Rec Result Conc. Result % Rec Limits Qualifiers ND 1310 1240 76 80-120 M 1 ND 1310 1300 84 80-120 92252369001 Dup Units Result Result mg/kg ND ND mg/kg ND ND Max RPD RPD Qualifiers 20 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/25/2015 02:51 PM without the written consent of Pace Analytical Services, Inc.. Page 31 of 38 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K��c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060005 Pace Project No.: 92252369 QC Batch: WETA/47028 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92252369001, 92252369002, 92252369003, 92252369004 METHOD BLANK: 1233603 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrate as N mg/kg ND 5.0 06/06/15 06:55 LABORATORY CONTROL SAMPLE: 1233604 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg 49.6 52.7 106 80-120 MATRIX SPIKE SAMPLE: 1233606 92252369001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg ND 131 123 92 80-120 H3 SAMPLE DUPLICATE: 1233605 92252369001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Nitrate as N mg/kg ND ND 20 H3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/25/2015 02:51 PM without the written consent of Pace Analytical Services, Inc.. Page 32 of 38 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060005 Pace Project No.: 92252369 QC Batch: WETA/29118 Analysis Method: EPA 9060 QC Batch Method: EPA 9060 Analysis Description: 9060 TOC Average Associated Lab Samples: 92252369001, 92252369002, 92252369003, 92252369004 METHOD BLANK: 1179207 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mean Total Organic Carbon mg/kg ND 600 06/22/15 12:40 LABORATORY CONTROL SAMPLE: 1179208 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mean Total Organic Carbon mg/kg 120000 127000 106 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1179209 1179210 MS MSD 92253352001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg ND 8010 7970 8470 7940 102 96 50-150 6 30 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1179211 1179212 MS MSD 92252369001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg 26300 53000 53000 79000 83700 99 108 50-150 6 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/25/2015 02:51 PM without the written consent of Pace Analytical Services, Inc.. Page 33 of 38 Pace Analytical Services, Inc aceAnalXical ® 9800 t c&rr�e. Suite 100 Huntersville, NC 28078078 www.pacelabs.com (704)875-9092 QUALIFIERS Project: J15060005 Pace Project No.: 92252369 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TN -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-G Pace Analytical Services - Green Bay PASI-O Pace Analytical Services - Ormond Beach BATCH QUALIFIERS Batch: ICP/15002 Ill Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. Batch: ICPM/9947 Ill Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. ANALYTE QUALIFIERS 1g Analyte was detected in the continueing calibration verification low level (CCVL). All associated samples had concentrations of at least ten times greater than the CCVL or were below the reporting limit. CH The continuing calibration for this compound is outside of Pace Analytical acceptance limits. The results may be biased high. D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. D4 Sample was diluted due to the presence of high levels of target analytes. D6 The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits. H3 Sample was received or analysis requested beyond the recognized method holding time. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/25/2015 02:51 PM without the written consent of Pace Analytical Services, Inc.. Page 34 of 38 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, INC 28078 (704)875-9092 QUALIFIERS Project: J15060005 Pace Project No.: 92252369 ANALYTE QUALIFIERS M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. N2 The lab does not hold TIN accreditation for this parameter. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/25/2015 02:51 PM without the written consent of Pace Analytical Services, Inc.. Page 35 of 38 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 I� %fir&e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: J15060005 Pace Project No.: 92252369 Lab ID Sample ID QC Batch Method QC Batch Analytical Method 92252369001 201501614 EPA 3050 MPRP/24564 EPA 6010 92252369002 201501615 EPA 3050 MPRP/24564 EPA 6010 92252369003 201501616 EPA 3050 MPRP/24564 EPA 6010 92252369004 201501617 EPA 3050 MPRP/24564 EPA 6010 92252369001 201501614 EPA 3050 MPRP/24565 EPA 6020 92252369002 201501615 EPA 3050 MPRP/24565 EPA 6020 92252369003 201501616 EPA 3050 MPRP/24565 EPA 6020 92252369004 201501617 EPA 3050 MPRP/24565 EPA 6020 92252369001 201501614 EPA 7471 MERP/5823 EPA 7471 92252369002 201501615 EPA 7471 MERP/5823 EPA 7471 92252369003 201501616 EPA 7471 MERP/5823 EPA 7471 92252369004 201501617 EPA 7471 MERP/5823 EPA 7471 92252369001 201501614 ASTM D2974-87 PMST/3626 92252369002 201501615 ASTM D2974-87 PMST/3626 92252369003 201501616 ASTM D2974-87 PMST/3626 92252369004 201501617 ASTM D2974-87 PMST/3626 92252369001 201501614 EPA 9045 WET/37839 92252369002 201501615 EPA 9045 WET/37839 92252369003 201501616 EPA 9045 WET/37839 92252369004 201501617 EPA 9045 WET/37839 92252369001 201501614 EPA 9056 WETA/47029 92252369002 201501615 EPA 9056 WETA/47029 92252369003 201501616 EPA 9056 WETA/47029 92252369004 201501617 EPA 9056 WETA/47029 92252369001 201501614 EPA 9056 WETA/47028 92252369002 201501615 EPA 9056 WETA/47028 92252369003 201501616 EPA 9056 WETA/47028 92252369004 201501617 EPA 9056 WETA/47028 92252369001 201501614 EPA 9060 WETA/29118 92252369001 201501614 EPA 9060 WETA/29123 92252369002 201501615 EPA 9060 WETA/29118 92252369002 201501615 EPA 9060 WETA/29123 92252369003 201501616 EPA 9060 WETA/29118 92252369003 201501616 EPA 9060 WETA/29123 92252369004 201501617 EPA 9060 WETA/29118 92252369004 201501617 EPA 9060 WETA/29123 Date: 06/25/2015 02:51 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Analytical Batch ICP/15002 ICP/15002 ICP/15002 ICP/15002 ICPM/9947 ICPM/9947 ICPM/9947 ICPM/9947 MERC/5810 MERC/5810 MERC/5810 MERC/5810 Page 36 of 38 � ��ceArrF�lyPica!` I vvcurnern tvame: le Condition Upon Recei Document Number: F-CHR-CS-003-rev.16 uocument meviseta: may iu, Eu to Page 1 of 2* Issuing Authority: 44 of 60 Pace Huntersville Qualitv Office Client Name: IeYo * Page 2 of 2 is for Internal Use Only Courier: ❑ Fed Ex ❑ UPS❑ LISPS❑ Client❑ Commercial®" Pace Other Custody Seal on Cooler/Box Present: ❑ yes 1 {Zno Seals intact: ❑ yes ❑ no Packing Material: ❑ Bubble V❑p ❑ B/u6bfe Bags ❑ None ❑ Other Thermometer Used: IR Gun T1401 Type of Ice: We Blue None �-S�amples on ice, cooling process has begun Temp Correction Factor T1401 No Correction Corrected Cooler Temp.: `C Temp should be above freezing to 6*C Biological Tissue is Frozen: Yes No NIA Date and Intl! VTr on amining g contents:I Comments: Chain of Custody Present: YI s ON. ONIA 1, Chain of Custody Filled Out: l es ONO ONIA 2. Chain of Custody Relinquished: 2' es ONO ONIA 3, Sampler Name & Signature on COC: ElYes ONO ❑NIA 4. Samples Arrived within Hold Time: ❑Y s ®No ❑NIA 5. Short Hold Time Analysis (<72hr): ❑Yes ❑No ONIA 6. Rush Turn Around Time Requested: ❑Yes [A ONIA 7. Sufficient Volume: ❑Yes ❑No ❑NIA 8. Correct Containers Used: -Pace Containers Used: Dyes ONO Dyes &No ONIA C1NIA 9. Containers Intact: IJYes ❑No ❑NIA 10. Filtered volume received for Dissolved tests ❑Yes ONO 0NIA 11. Sample Labels match COC: -Includes date/time/ID/Analysis Matrix: ,E Yes ONO ❑NrA 12, All containers needing preservation have been checked. All containers needing preservation are found to be in compliance with EPA recommendation. exceptions: VOA, colilorm, TOC, O&G, W-DRO (water) ❑Yes ❑Now ❑Yes ONO Oyes ❑No ❑NIA ONIA 13. Samples checked for dechlorination: ❑Yes ONO ONIA 14. Headspace in VOA Vials (>6mm): Oyes ❑No NIA 15. Trip Blank Present: Trip Blank Custody Seals Present Pace Trip Blank Lot # (if purchased ❑Yes ONO ❑Yes ❑No ONIA ONIA 16. Client Notification/ Resolution: Field Data Required? Y 1 N Person Contacted: DatelTime: Comments/ Resolution: SCURF Review: a Dater SRF Review: Date: ! 0 Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office ( Le out of hold, incorrect preservative, out of temp, incorrect containers) WOii : 92252369 1111111111111111111111111 Page 37 of 38 45 of 60 Custonurawst Compl-t- C— ti+ c+ c C I � Cuslamer to Complote appeoprlate columns to right 0 D � � m c LA 3W M Q\ I I N z 0 3. y � 3 rn O nl I I I I I I 1 I I I III111 I I I I I I° N 9 CL I ? y O S A� b >W n 'A] o 1 n ® M a O �} n o O o i ti7 P V Y �1 C ^ c 7 2 0 7 G 0 N b an h m a a� l a °c a ¢ s a a o n H `u` o w 4 0. R O f N q r? i `-oil � Q m O. °1 N 6 3 a a 0 14Camp. -r•- y VA -' io Zr(o 0� C7 3 !M > � �I �to! fi to teA lys s I °o ] � iz � ! Req Ire c� to i�q Q Total Metals , Anions, yJ 1 -, —1—L — pH CE 5 n cr i IM 1 -a oz jar (PA ) 0im TOC 1- 4 oz jar 4 0 0 f (PACE) CD ; U1� D o _'Ill Q I -"1 10 SPLP - Total Metals and Anions 2-8 oz jars (PACE) 5 Sediment specific tests OF H 2 - 8 oz jar (ACCESS ANALYTICAL) -- 5 g b m I' h ---- �1 m Iq �' - ._I^ _._. ._. A- - --- - - - - - - - - - - - xl O 0 — m ° r W -I L n m r. C ppA, 3. m Zw Z. "Total # of Containers ZA u Page 38 of 38 MX:111 Acass ANALYTICAL, INC, ANALYTICAL REPORT CLIENT Duke Energy 13339 Hagers Ferry Rd. Huntersville NC 28078 ATTENTION Marge Galvin -Karr PROJECT ID J15060005 LABORATORY REPORT NUMBER 1506304 DATE June 15, 2015 Primary Data Review By Secondary Data Review By Ashley Amick Chantelle Kanhai Project Manager, Access Analytical Project Manager, AES aamick@axs-inc.com PLEASE NOTE: - Unless otherwise noted, all analysis on this report performed at Analytical Environmental Services Inc. (AES Inc), 3080 Presidential Drive, Atlanta, GA 30340. - AES is SCDHEC certified laboratory # 98016, NCDENR certified lab # 562, GA certified lab # FL-E87582, NELAP certified laboratory # E87582 - Local support services for this project are provided by Access Analytical, Inc. Access Analytical is a representative of AES serving client in the SC/NC/GA areas. All questions regarding this report should be directed to your local Access Analytical representative at 803.781.4243 or toll fee at 883.315.4243 Page 1 of 8 Sy&06DD 50E --------------- ------------------ -------- ----------- ----------- ------------------------- ------ services ! AnalVt1cal Laboratory Use Only I Werk Order DUKE rwi Colo MG03A2 (Building 705) mwtw SOIL DISTRIBUTION OH— ORIGINAL to LAS, 13339 Hagers F*rry Rd I.j t" Orial"d From i I A. COPY to CLIENT Huritersvillo, N. 0. 28078 jL9".d By Date I lM ENERGY 1,, (980) 376-5246 i 5 -T 7--1 SAMPIr; PROGRAM GreurwO Water L mant NPDES 1)Pro}K, Name pphono No: q b $ AB Grovndwcter Assessment - SoA I Pace p 30-.016Tom 4�Fax No: U )CHo t PO 1142081 =H ryjH A GWAc )S"Iness V"tt 7)M011 00do: 6_ p (Cl 1 - - -* e - r- 1� Po Number 1142051. (D Imporlwar w..." Specific accountIng or [-Ali WE ONLY Matrix (3011, sedi("04 Ash) "Sample Description or ID Sediment Z'F 0 ---------------- WATER EQUIPMENT BLANK 11 PER DA —(,UVAA J-1K pre,er,rativea when used must be added within 16 minutes of sample collection "Collection Information Vo-,Wi, K, So, Na, Sr, Tl, V, Z11, M: CEC, particle Size Distrib % Y) V-U S� aV-CA,�--L < -Z 0 L -'j . 2 4 IL = 'L 0 14 co 2 .71 N 72l%equosted Turnaround 14. Day& '7 Days_ 48 Rr— com"n" Metals: Al,'gl,, As, —(3a, se, 6, Cd, Ca, Cr, Co, Cu, Fe, PI Anions: Cl, Nitrate-N, $04 Sediment Specific Par yl >n, Redox Potential Lt 180 C) z 0M Analytical Environmental Services, Inc Date: 15-Jun-1548 of 60 Client: Duke Energy Project: J15060005 Case Narrative Lab ID: 1506304 REDOX POTENTIAL 1506304-001 210.0 mV 214.6 mV 211.7 mV 1506304-002 151.3 mV 123.5 mV 100.2 mV 1506304-003 115.6 mV 114.4 mV 103.7 mV 1506304-004 173.8 mV 197.6 mV 213.5 mV Page 3 of 8 Analytical Environmental Services, Inc Date: 15-Jun-15 Client: Duke Energy Client Sample ID: SW-CFDG Project Name: J15060005 Collection Date: 5/28/2015 11:40:00 AM Lab ID: 1506304-001 Matrix: Sediment Reporting Dilution Analyses Result Qual Units BatchID Date Analyzed Analyst Limit Factor CEC of Soils (Na Saturation) SW9081 Cation Exchange Capacity Qualifiers: r Value exceeds maximum contaminant level BRL Below reporting limit H Holding times for preparation or analysis exceeded N Analyte not NELAC certified B Analyte detected in the associated method blank > Greater than Result value (SW9081) 8.0 1.0 meq/100g 208358 1 06/09/2015 00:45 TA E Estimated (value above quantitation range) S Spike Recovery outside limits due to matrix Nan See case narrative NC Not confirmed < Less than Result value J Estimated value detected below Reporting Limit Page 4 of 8 71MON Analytical Environmental Services, Inc Date: 15-Jun-15 Client: Duke Energy Client Sample ID: SW -HAW Project Name: J15060005 Collection Date: 5/28/2015 10:20:00 AM Lab ID: 1506304-002 Matrix: Sediment Reporting Dilution Analyses Result Qual Units BatcbID Date Analyzed Analyst Limit Factor CEC of Soils (Na Saturation) SW9081 Cation Exchange Capacity Qualifiers: r Value exceeds maximum contaminant level BRL Below reporting limit H Holding times for preparation or analysis exceeded N Analyte not NELAC certified B Analyte detected in the associated method blank > Greater than Result value (SW9081) 5.5 1.0 meq/100g 208358 1 06/09/2015 00:48 TA E Estimated (value above quantitation range) S Spike Recovery outside limits due to matrix Nan See case narrative NC Not confirmed < Less than Result value J Estimated value detected below Reporting Limit Page 5 of 8 51 of 60 Analytical Environmental Services, Inc Date: 15-Jun-15 Client: Duke Energy Client Sample ID: SW-DEEPR Project Name: J15060005 Collection Date: 5/28/2015 9:55:00 AM Lab ID: 1506304-003 Matrix: Sediment Reporting Dilution Analyses Result Qual Units BatcbID Date Analyzed Analyst Limit Factor CEC of Soils (Na Saturation) SW9081 Cation Exchange Capacity Qualifiers: r Value exceeds maximum contaminant level BRL Below reporting limit H Holding times for preparation or analysis exceeded N Analyte not NELAC certified B Analyte detected in the associated method blank > Greater than Result value (SW9081) BRL 1.0 meq/100g 208358 1 06/09/2015 00:57 TA E Estimated (value above quantitation range) S Spike Recovery outside limits due to matrix Nan See case narrative NC Not confirmed < Less than Result value J Estimated value detected below Reporting Limit Page 6 of 8 52 of 60 Analytical Environmental Services, Inc Date: 15-Jun-15 Client: Duke Energy Client Sample ID: S-16 Project Name: J15060005 Collection Date: 5/28/2015 10:55:00 AM Lab ID: 1506304-004 Matrix: Sediment Reporting Dilution Analyses Result Qual Units BatcbID Date Analyzed Analyst Limit Factor CEC of Soils (Na Saturation) SW9081 Cation Exchange Capacity Qualifiers: r Value exceeds maximum contaminant level BRL Below reporting limit H Holding times for preparation or analysis exceeded N Analyte not NELAC certified B Analyte detected in the associated method blank > Greater than Result value (SW9081) 9.6 1.0 meq/100g 208358 1 06/09/2015 01:00 TA E Estimated (value above quantitation range) S Spike Recovery outside limits due to matrix Nan See case narrative NC Not confirmed < Less than Result value J Estimated value detected below Reporting Limit Page 7 of 8 iMI.111 Analytical Environmental Services, Inc, Sample/Cooler Receipt Checklist Client ABC c c `York Order Number Checklist completed by Signature Date Carrier name: FedEx ✓ UPS Courier Client US iviail Other Shipping container/cooler in good condition? Yes No `. Custody seals intact on shipping container/cooler? Yes _ No ^ Custody seals intact on sample bottles? Yes �No _ Container/Temp Blank temperature in compliance? (0°<6°C)* Yes (/ No — Not Present Not Present 1 Not Present Cooler 91 3 V Cooler #2 Cooler #3 Cooler #4 Cooler#5 Cooler 46 Chain of custody present? Yes No Chain of custody signed when relinquished and received? Yes / No Chain of custody agrees with sample labels? Yes No — Samples in proper coatainer/bottle? Yes No Sample containers intact? Yes ' No — Sufficient sample volume for indicated test? Yes No _ All samples received within holding time? Yes No _ Was TAT marked on the COC? Yes / No Proceed with Standard TAT as per project history? Yes ` No Water - VOA vials have zero headspace? No VOA vials submitted Yes Water - pH acceptable upon receipt? Yes No Adjusted? Sample Condition: Good f Other(Explain) (For diffusive samples or AIHA lead) Is a known blank included? See Case Narrative for resolution of the Non -Conformance. Checked by Not Applicable f No Not Applicable Yes No Samples do not have to comply Nvith the given range for certain parameters. 11Aes scrver111Sample Receiptlivly Documents\COCs and pH Adjustment ShecMample_Cooler Recipt Cliecklist_Revl.rtf Page 8 of 8 54 of 60 June 15, 2015 Access Analytical 7478 Carlisle Street Irmo, South Carolina 29063 Attn: Mr. Ashley Amick Re: Summary of Laboratory Testing AB Groundwater Assessment Terracon Project No. 73075016 (WOJ15060005) Dear Mr. Amick: Irerracon Terracon has performed the requested laboratory testing program indicated by your Chain of Custody Record, dated 06/04/15. The correspondence indicated hydrometer testing for Samples SW-CFDG, SW -HAW, SW-DEEPR, and S-16. The results have been electronically forwarded to you in PDF format at aamick@accessanalyticalinc.com, as instructed. If there are any questions regarding the results or if we can be of additional service, please contact us. Sincerely, Terracon Consultants, Inc. Rebecca Simms, CET Laboratory Manager Attachments Copies: 1xc: Above (PDF via email) 1xc: File RS/PM Phillip . Mor son P.E. Geo chnic D artment Manager Terracon Consultants, Inc. 521 Clemson Road Columbia, South Carolina 29229 P [803] 741 9000 F [803] 741 9900 terracon.com GRAIN SIZE DISTRIBUTION 55 of 60 ASTM D422 U.S. SIEVE OPENING IN INCHES U.S. SIEVE NUMBERS I HYDROMETER 6 4 3 2 1.5 1 3/4 1/23/8 3 6 810 1416 20 30 40 50 60 100 140 200 100 95 - 90 85 - 80 75 70 65 w 60 >- 55 m w - 50 z LL - I- 45 z 40 w d 35 30 25 20 15 - 10 - 5 0 - 100 10 1 0.1 0.01 0.001 GRAIN SIZE IN MILLIMETERS LCOBBLES GRAVEL SAND SILT OR CLAY coarse fine coarse medium fine GRAIN SIZE DISTRIBUTION 56 of 60 ASTM D422 U.S. SIEVE OPENING IN INCHES U.S. SIEVE NUMBERS I HYDROMETER 6 4 3 2 1.5 1 3/4 1/23/8 3 4 6 810 1416 20 30 40 50 60 100 140 200 100 95 - 90 85 - 80 75 70 65 w 60 >- 55 m w - 50 z LL - I- 45 z 40 w d 35 30 25 20 15 - 10 - 5 0 - 100 10 1 0.1 0.01 0.001 GRAIN SIZE IN MILLIMETERS LCOBBLES GRAVEL SAND SILT OR CLAY coarse fine coarse medium fine GRAIN SIZE DISTRIBUTION 57 of 60 ASTM D422 U.S. SIEVE OPENING IN INCHES U.S. SIEVE NUMBERS I HYDROMETER 6 4 3 2 1.5 1 3/4 1/23/8 3 4 6 810 1416 20 30 40 50 60 100 140 200 100 95 90 - 85 - 80 75 70 65 w 60 >- 55 m w - 50 z LL - I- 45 z 40 w d 35 30 25 20 15 - 10 - 5 0 - 100 10 1 0.1 0.01 0.001 GRAIN SIZE IN MILLIMETERS LCOBBLES GRAVEL SAND SILT OR CLAY coarse fine coarse medium fine GRAIN SIZE DISTRIBUTION 58 of 60 ASTM D422 U.S. SIEVE OPENING IN INCHES U.S. SIEVE NUMBERS I HYDROMETER 6 4 3 2 1.5 1 3/4 1/23/8 3 6 810 1416 20 30 40 50 60 100 140 200 100 95 - 90 85 - 80 75 70 65 w 60 >- 55 m w - 50 z LL - I— 45 z 40 w o_ 35 30 25 20 15 - 10 - 5 0 - 100 10 1 0.1 0.01 0.001 GRAIN SIZE IN MILLIMETERS L Boring ID Depth (ft) USCS Classification ILL PL PI Cc Cu • SW -HAW 0 1.53 14.26 Boring ID Depth (ft) D,00 Dso D, D,o % Gravel % Sand % Silt % Clay • SW -HAW 0 4.75 0.338 0.111 0.024 0.0 84.6 10.6 4.7 PROJECT: AB GW Assessment - Asheville Sediment Irerracon 521 Clemson Road Columbia, South Carolina PROJECT NUMBER: 73075016 SITE: Asheville, North Carolina CLIENT: Access Analytical COBBLES GRAVEL SAND SILT OR CLAY coarse fine coarse medium fine M M � z.+ r C 4 f*b my as q M1 �dYo a � 11 �2 s �w J 0 '4;�Z ma 3 m Eiz a Q , E nO aN tra J J Z = u A oa�'m CT- 3 r a 42 ma otZ5_ m ans r G1 O _ cv Q -� D is a �_ co � MO It — ' OZ2 LOxp ty1I 11 61 3J 4 �aU) O @ 4p lG I C VY _ - i117� L t, V 0 d - O N `� p tU U C a V Q V v %'vela sieA�eue sisd�eunk srcA�eue s7ae�aue ws5�cue 9J .r. 4Tdl.Siall® LdulEllHq Y p V Ell 4 Q ;;v of 40 d Q Cpppp d nU i 3U m ee CL > j ti u ='ti I C7Fi 40 } r } n b G)F _ w Wli 51 Q a Q) ir 6TP,V'�6lie, ' dE56JelIF; 4ryYAfsta PPR�Ii°a P�11lCO i°�"IK' Tdoaw4l0a sr,�aeirYn 6UIIIH�.IYll rj J m Z1 L N CT cz ] v v a `Q v a a x� cd 0 ° ro i U�� I Q u" G chi DUKE.,.., E V 1 a. v i CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM _._.- ------- - - - - -.. y cal Laboraio y u only . -- ,4n lykiCal Labaratoq SOrvic0sVigo fw4w — 3 SOIL . SaeIQp1R 43r IM1— 1.3" HN -S Fwy HwiiNr�++RMe N-Cmra LaQynd64 pitr■1 [ Isrral -e s a 6 i A I I, 6 WWR r Cimnd waral —fir ^ rox; isaal aTf _._• ,- - _ _ i ' 7 l r r. �NPUES— Pace I PO 1142081 ,Access AnalVtical ' PC) Number 114205-1 Synterra EDD