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HomeMy WebLinkAboutNC0003433_J15050605report_20150902+ DUKE Analytical Laboratory Page 1of78 ENERGY Order Number: Project Name: Customer Name(s): Customer Address: Lab Contact: Report Authorized By: (Signature) Program Comments: 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone:980-875-5245 Fax:980-875-4349 Order Summary Report J15050605 CAPE FEAR - AB GW ASSESSMENT WATER Tim Hunsucker, Chris Suttell, Kathy Webb, John Toepfer Mary Ann Ogle 'p, � Mary Ann Ogle Phone: 980-875-5274 Mary Ann Ogle 2015.06.1012:33:44 Date: -04'00' Please contact the Program Manager (Mary Ann Ogle) with any questions regarding this report. Data Flags & Calculations: 6/9/2015 Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Sample ID's & Descriptions: Collection Sample ID Plant/Station Date and Time Collected By Sample Description 2015015613 Cape Fear 19-May-15 11:50 AM Illegible ABMW-5BR 2015015614 Cape Fear 19-May-15 4:00 PM Illegible ABMW-3BR 2015015615 Cape Fear 19-May-15 4:50 PM Illegible ERB-26 2015015616 Cape Fear 20-May-15 10:55 AM Illegible MW-16S 2015015617 Cape Fear 20-May-15 12:00 PM Illegible MW-16BR 2015015618 Cape Fear 20-May-15 11:10 AM Illegible DUP 2015015619 Cape Fear 20-May-15 1:25 PM Illegible ABMW-3 2015015620 Cape Fear 20-May-15 2:45 PM Illegible ABMW-2SU 2015015621 Cape Fear 20-May-15 4:00 PM Illegible ABMW-2SL 2015015622 Cape Fear 20-May-15 4:35 PM Illegible ERB-27 2015015623 Cape Fear 19-May-15 4:50 PM Illegible Filter Blank 2015015624 Cape Fear 20-May-15 4:35 PM Illegible Filter Blank 12 Total Samples Page 2 of 78 Page 3 of 78 Technical Validation Review Checklist: COC and .pdf report are in agreement with sample totals Yes No and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. ❑ Yes❑ No All laboratory QA/QC requirements are acceptable.❑ Yes ❑ No Report Sections Included: U Job Summary Report ❑ Sample Identification n Technical Validation of Data Package ❑ Analytical Laboratory Certificate of Analysis ❑ Analytical Laboratory QC Report Sub -contracted Laboratory Results ❑ Customer Specific Data Sheets, Reports, & Documentation ❑ Customer Database Entries 66 Chain of Custody [I/0] Electronic Data Deliverable (EDD) Sent Separately Reviewed By: Peggy Kendall Date: 6/9/2015 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050605 Site: ABMW-5BR Collection Date: 19-May-15 11:50 AM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) < 0.01 mg-N/L 0.01 INORGANIC IONS BY IC Chloride 5.0 mg/L 0.1 Sulfate 15 mg/L 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) 0.013 mg/L 0.005 Barium (Ba) 0.295 mg/L 0.005 Boron (B) 0.055 mg/L 0.05 Iron (Fe) 0.021 mg/L 0.01 Manganese (Mn) 0.063 mg/L 0.005 Strontium (Sr) 0.353 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 23.5 mg/L 0.01 Magnesium (Mg) 5.49 mg/L 0.005 Potassium (K) 1.80 mg/L 0.1 Sodium (Na) 38.4 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.088 mg/L 0.005 Barium (Ba) 0.310 mg/L 0.005 Boron (B) 0.054 mg/L 0.05 Iron (Fe) 0.129 mg/L 0.01 Manganese (Mn) 0.063 mg/L 0.005 Strontium (Sr) 0.358 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 Sample #: 2015015613 Matrix: GW_WW Page 4 of 78 DF Method Analysis Date/Time Analyst Vendor Method V_SHEALY 1 EPA 353.2 05/27/2015 13:36 LSTARL1 1 EPA 300.0 05/23/2015 00:17 BGN9034 10 EPA 300.0 05/23/2015 00:17 BGN9034 1 EPA 245.1 05/28/2015 13:35 ACPAYNE 1 EPA 245.1 06/01/2015 13:31 ACPAYNE 1 EPA 200.7 05/22/2015 11:19 MHALL3 1 EPA 200.7 05/22/2015 11:19 MHALL3 1 EPA 200.7 05/22/2015 11:19 MHALL3 1 EPA 200.7 05/22/2015 11:19 MHALL3 1 EPA 200.7 05/22/2015 11:19 MHALL3 1 EPA 200.7 05/22/2015 11:19 MHALL3 1 EPA 200.7 05/22/2015 11:19 MHALL3 1 EPA 200.7 05/22/2015 14:20 MHALL3 1 EPA 200.7 05/22/2015 14:20 MHALL3 1 EPA 200.7 05/22/2015 14:20 MHALL3 1 EPA 200.7 05/22/2015 14:20 MHALL3 1 EPA 200.7 05/27/2015 13:31 MHALL3 1 EPA 200.7 05/27/2015 13:31 MHALL3 1 EPA 200.7 05/27/2015 13:31 MHALL3 1 EPA 200.7 05/27/2015 13:31 MHALL3 1 EPA 200.7 05/27/2015 13:31 MHALL3 1 EPA 200.7 05/27/2015 13:31 MHALL3 1 EPA 200.7 05/27/2015 13:31 MHALL3 Certificate of Laboratory Analysis Page 5 of 78 This report shall not be reproduced, except in full. Order # J15050605 Site: ABMW-5BR Sample #: 2015015613 Collection Date: 19-May-15 11:50 AM Matrix: GW_WW Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst DISSOLVED METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 1 EPA 200.8 06/05/2015 11:36 JAHERMA Arsenic (As) 2.76 ug/L 1 1 EPA 200.8 06/05/2015 11:36 JAHERMA Beryllium (Be) < 1 ug/L 1 1 EPA 200.8 06/05/2015 11:36 JAHERMA Cadmium (Cd) < 1 ug/L 1 1 EPA 200.8 06/05/2015 11:36 JAHERMA Chromium (Cr) < 1 ug/L 1 1 EPA 200.8 06/05/2015 11:36 JAHERMA Cobalt (Co) < 1 ug/L 1 1 EPA 200.8 06/05/2015 11:36 JAHERMA Copper (Cu) < 1 ug/L 1 1 EPA 200.8 06/05/2015 11:36 JAHERMA Lead (Pb) < 1 ug/L 1 1 EPA 200.8 06/05/2015 11:36 JAHERMA Molybdenum (Mo) 7.35 ug/L 1 1 EPA 200.8 06/05/2015 11:36 JAHERMA Nickel (Ni) < 1 ug/L 1 1 EPA 200.8 06/05/2015 11:36 JAHERMA Selenium (Se) < 1 ug/L 1 1 EPA 200.8 06/05/2015 11:36 JAHERMA Thallium (TI) Low Level < 0.2 ug/L 0.2 1 EPA 200.8 06/05/2015 11:36 JAHERMA Vanadium (V) Low Level < 0.3 ug/L 0.3 1 EPA 200.8 06/05/2015 11:36 JAHERMA TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 1 EPA 200.8 06/05/2015 15:11 SLS2560 Arsenic (As) 2.58 ug/L 1 1 EPA 200.8 06/05/2015 15:11 SLS2560 Beryllium (Be) < 1 ug/L 1 1 EPA 200.8 06/05/2015 15:11 SLS2560 Cadmium (Cd) < 1 ug/L 1 1 EPA 200.8 06/05/2015 15:11 SLS2560 Chromium (Cr) < 1 ug/L 1 1 EPA 200.8 06/05/2015 15:11 SLS2560 Cobalt (Co) < 1 ug/L 1 1 EPA 200.8 06/05/2015 15:11 SLS2560 Copper (Cu) < 1 ug/L 1 1 EPA 200.8 06/05/2015 15:11 SLS2560 Lead (Pb) < 1 ug/L 1 1 EPA 200.8 06/05/2015 15:11 SLS2560 Molybdenum (Mo) 7.25 ug/L 1 1 EPA 200.8 06/05/2015 15:11 SLS2560 Nickel (Ni) < 1 ug/L 1 1 EPA 200.8 06/05/2015 15:11 SLS2560 Selenium (Se) < 1 ug/L 1 1 EPA 200.8 06/05/2015 15:11 SLS2560 Thallium (TI) Low Level 0.359 ug/L 0.2 1 EPA 200.8 06/05/2015 15:11 SLS2560 Vanadium (V) Low Level < 0.3 ug/L 0.3 1 EPA 200.8 06/05/2015 15:11 SLS2560 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4) Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 200 mg/L 25 1 SM2540C 05/21/201514:24 AGIBBS5 Total Carbon TOC 0.471 mg/L 0.1 1 SM5310C/EPA9060A 06/01/201512:24 GHUTCHI TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 1 SM2540D 05/22/2015 10:57 AGIBBS5 Certificate of Laboratory Analysis Page 6 of 78 This report shall not be reproduced, except in full. Order # J15050605 Site: ABMW-3BR Collection Date: 19-May-15 4:00 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.018 mg-N/L 0.01 INORGANIC IONS BY IC Chloride 31 mg/L 1 Sulfate 140 mg/L 2.5 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) < 0.005 mg/L 0.005 Barium (Ba) 0.127 mg/L 0.005 Boron (B) 0.189 mg/L 0.05 Iron (Fe) 1.40 mg/L 0.01 Manganese (Mn) 1.69 mg/L 0.005 Strontium (Sr) 0.575 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 96.7 mg/L 0.01 Magnesium (Mg) 16.9 mg/L 0.005 Potassium (K) 2.01 mg/L 0.1 Sodium (Na) 62.3 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.177 mg/L 0.005 Barium (Ba) 0.129 mg/L 0.005 Boron (B) 0.188 mg/L 0.05 Iron (Fe) 1.66 mg/L 0.01 Manganese (Mn) 1.69 mg/L 0.005 Strontium (Sr) 0.573 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 Sample #: 2015015614 Matrix: GW_WW DF Method Analysis Date/Time Analyst Vendor Method V_SHEALY 1 EPA 353.2 05/27/2015 13:37 LSTARL1 10 EPA 300.0 05/26/2015 14:21 BGN9034 25 EPA 300.0 05/26/2015 14:21 BGN9034 1 EPA 245.1 05/28/2015 13:42 ACPAYNE 1 EPA 245.1 06/01/2015 13:38 ACPAYNE 1 EPA 200.7 05/22/2015 11:30 MHALL3 1 EPA 200.7 05/22/2015 11:30 MHALL3 1 EPA 200.7 05/22/2015 11:30 MHALL3 1 EPA 200.7 05/22/2015 11:30 MHALL3 1 EPA 200.7 05/22/2015 11:30 MHALL3 1 EPA 200.7 05/22/2015 11:30 MHALL3 1 EPA 200.7 05/22/2015 11:30 MHALL3 1 EPA 200.7 05/22/2015 14:24 MHALL3 1 EPA 200.7 05/22/2015 14:24 MHALL3 1 EPA 200.7 05/22/2015 14:24 MHALL3 1 EPA 200.7 05/22/2015 14:24 MHALL3 1 EPA 200.7 05/27/2015 13:42 MHALL3 1 EPA 200.7 05/27/2015 13:42 MHALL3 1 EPA 200.7 05/27/2015 13:42 MHALL3 1 EPA 200.7 05/27/2015 13:42 MHALL3 1 EPA 200.7 05/27/2015 13:42 MHALL3 1 EPA 200.7 05/27/2015 13:42 MHALL3 1 EPA 200.7 05/27/2015 13:42 MHALL3 Certificate of Laboratory Analysis Page 7 of 78 This report shall not be reproduced, except in full. Order # J15050605 Site: ABMW-3BR Sample #: 2015015614 Collection Date: 19-May-15 4:00 PM Matrix: GW_WW Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst DISSOLVED METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 1 EPA 200.8 06/05/2015 11:40 JAHERMA Arsenic (As) 1.20 ug/L 1 1 EPA 200.8 06/05/2015 11:40 JAHERMA Beryllium (Be) < 1 ug/L 1 1 EPA 200.8 06/05/2015 11:40 JAHERMA Cadmium (Cd) < 1 ug/L 1 1 EPA 200.8 06/05/2015 11:40 JAHERMA Chromium (Cr) < 1 ug/L 1 1 EPA 200.8 06/05/2015 11:40 JAHERMA Cobalt (Co) < 1 ug/L 1 1 EPA 200.8 06/05/2015 11:40 JAHERMA Copper (Cu) < 1 ug/L 1 1 EPA 200.8 06/05/2015 11:40 JAHERMA Lead (Pb) < 1 ug/L 1 1 EPA 200.8 06/05/2015 11:40 JAHERMA Molybdenum (Mo) 1.75 ug/L 1 1 EPA 200.8 06/05/2015 11:40 JAHERMA Nickel (Ni) < 1 ug/L 1 1 EPA 200.8 06/05/2015 11:40 JAHERMA Selenium (Se) < 1 ug/L 1 1 EPA 200.8 06/05/2015 11:40 JAHERMA Thallium (TI) Low Level < 0.2 ug/L 0.2 1 EPA 200.8 06/05/2015 11:40 JAHERMA Vanadium (V) Low Level < 0.3 ug/L 0.3 1 EPA 200.8 06/05/2015 11:40 JAHERMA TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 1 EPA 200.8 06/05/2015 14:58 SLS2560 Arsenic (As) 1.28 ug/L 1 1 EPA 200.8 06/05/2015 14:58 SLS2560 Beryllium (Be) < 1 ug/L 1 1 EPA 200.8 06/05/2015 14:58 SLS2560 Cadmium (Cd) < 1 ug/L 1 1 EPA 200.8 06/05/2015 14:58 SLS2560 Chromium (Cr) < 1 ug/L 1 1 EPA 200.8 06/05/2015 14:58 SLS2560 Cobalt (Co) < 1 ug/L 1 1 EPA 200.8 06/05/2015 14:58 SLS2560 Copper (Cu) < 1 ug/L 1 1 EPA 200.8 06/05/2015 14:58 SLS2560 Lead (Pb) < 1 ug/L 1 1 EPA 200.8 06/05/2015 14:58 SLS2560 Molybdenum (Mo) 1.48 ug/L 1 1 EPA 200.8 06/05/2015 14:58 SLS2560 Nickel (Ni) < 1 ug/L 1 1 EPA 200.8 06/05/2015 14:58 SLS2560 Selenium (Se) < 1 ug/L 1 1 EPA 200.8 06/05/2015 14:58 SLS2560 Thallium (TI) Low Level < 0.2 ug/L 0.2 1 EPA 200.8 06/05/2015 14:58 SLS2560 Vanadium (V) Low Level < 0.3 ug/L 0.3 1 EPA 200.8 06/05/2015 14:58 SLS2560 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4) Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 540 mg/L 25 1 SM2540C 05/21/201514:24 AGIBBS5 Total Carbon TOC 0.883 mg/L 0.1 1 SM5310C/EPA9060A 06/01/201512:24 GHUTCHI TOTAL SUSPENDED SOLIDS TSS 9.0 mg/L 5 1 SM2540D 05/22/201510:57 AGIBBS5 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050605 Site: ERB-26 Collection Date: 19-May-15 4:50 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.036 mg-N/L 0.01 INORGANIC IONS BY IC Chloride < 0.1 mg/L 0.1 Sulfate < 0.1 mg/L 0.1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 UNDIGESTED METALS BY ICP Calcium (Ca) 0.041 mg/L 0.01 Magnesium (Mg) < 0.005 mg/L 0.005 Potassium (K) < 0.1 mg/L 0.1 Sodium (Na) 0.103 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.019 mg/L 0.005 Barium (Ba) < 0.005 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) < 0.01 mg/L 0.01 Manganese (Mn) < 0.005 mg/L 0.005 Strontium (Sr) < 0.005 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 Page 8 of 78 Sample #: 2015015615 Matrix: GW_WW DF Method Analysis Date/Time Analyst Vendor Method V_SHEALY 1 EPA 353.2 05/27/2015 13:38 LSTARL1 1 EPA 300.0 05/23/2015 00:49 BGN9034 1 EPA 300.0 05/23/2015 00:49 BGN9034 1 EPA 245.1 05/28/2015 13:44 ACPAYNE 1 EPA 200.7 05/22/2015 14:29 MHALL3 1 EPA 200.7 05/22/2015 14:29 MHALL3 1 EPA 200.7 05/22/2015 14:29 MHALL3 1 EPA 200.7 05/22/2015 14:29 MHALL3 1 EPA 200.7 05/27/2015 13:46 MHALL3 1 EPA 200.7 05/27/2015 13:46 MHALL3 1 EPA 200.7 05/27/2015 13:46 MHALL3 1 EPA 200.7 05/27/2015 13:46 MHALL3 1 EPA 200.7 05/27/2015 13:46 MHALL3 1 EPA 200.7 05/27/2015 13:46 MHALL3 1 EPA 200.7 05/27/2015 13:46 MHALL3 1 EPA 200.8 06/05/2015 15:16 SLS2560 1 EPA 200.8 06/05/2015 15:16 SLS2560 1 EPA 200.8 06/05/2015 15:16 SLS2560 1 EPA 200.8 06/05/2015 15:16 SLS2560 1 EPA 200.8 06/05/2015 15:16 SLS2560 1 EPA 200.8 06/05/2015 15:16 SLS2560 1 EPA 200.8 06/05/2015 15:16 SLS2560 1 EPA 200.8 06/05/2015 15:16 SLS2560 1 EPA 200.8 06/05/2015 15:16 SLS2560 1 EPA 200.8 06/05/2015 15:16 SLS2560 1 EPA 200.8 06/05/2015 15:16 SLS2560 1 EPA 200.8 06/05/2015 15:16 SLS2560 1 EPA 200.8 06/05/2015 15:16 SLS2560 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4) Complete Vendor Method V_SHEALY Certificate of Laboratory Analysis Page 9 of 78 This report shall not be reproduced, except in full. Order # J15050605 Site: ERB-26 Collection Date: 19-May-15 4:50 PM Analyte Result Units Qualifiers RDL DF SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS < 25 mg/L 25 1 Total Carbon Sample #: 2015015615 Matrix: GW WW Method Analysis Date/Time Analyst Vendor Method V_ELE1 SM2540C 05/21/201514:24 AGIBBS5 TOC 0.545 mg/L 0.1 1 SM5310C/EPA9060A 06/01/201512:24 GHUTCHI TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 1 SM2540D 05/22/2015 10:57 AGIBBS5 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050605 Site: MW-16S Collection Date: 20-May-15 10:55 AM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.018 mg-N/L 0.01 INORGANIC IONS BY IC Chloride 210 mg/L 2.5 Sulfate 44 mg/L 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) < 0.005 mg/L 0.005 Barium (Ba) 0.159 mg/L 0.005 Boron (B) 0.217 mg/L 0.05 Iron (Fe) 0.035 mg/L 0.01 Manganese (Mn) 0.319 mg/L 0.005 Strontium (Sr) 0.428 mg/L 0.005 Zinc (Zn) 0.005 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 59.9 mg/L 0.01 Magnesium (Mg) 26.0 mg/L 0.005 Potassium (K) 0.992 mg/L 0.1 Sodium (Na) 83.1 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.110 mg/L 0.005 Barium (Ba) 0.160 mg/L 0.005 Boron (B) 0.140 mg/L 0.05 Iron (Fe) 0.093 mg/L 0.01 Manganese (Mn) 0.202 mg/L 0.005 Strontium (Sr) 0.624 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 Sample #: 2015015616 Matrix: GW_WW Page 10 of 78 DF Method Analysis Date/Time Analyst Vendor Method V_SHEALY 1 EPA 353.2 05/27/2015 13:39 LSTARL1 25 EPA 300.0 05/26/2015 14:37 BGN9034 10 EPA 300.0 05/26/2015 14:37 BGN9034 1 EPA 245.1 05/28/2015 13:47 ACPAYNE 1 EPA 245.1 06/01/2015 13:45 ACPAYNE 1 EPA 200.7 05/22/2015 11:34 MHALL3 1 EPA 200.7 05/22/2015 11:34 MHALL3 1 EPA 200.7 05/22/2015 11:34 MHALL3 1 EPA 200.7 05/22/2015 11:34 MHALL3 1 EPA 200.7 05/22/2015 11:34 MHALL3 1 EPA 200.7 05/22/2015 11:34 MHALL3 1 EPA 200.7 05/22/2015 11:34 MHALL3 1 EPA 200.7 05/22/2015 14:33 MHALL3 1 EPA 200.7 05/22/2015 14:33 MHALL3 1 EPA 200.7 05/22/2015 14:33 MHALL3 1 EPA 200.7 05/22/2015 14:33 MHALL3 1 EPA 200.7 05/27/2015 13:50 MHALL3 1 EPA 200.7 05/27/2015 13:50 MHALL3 1 EPA 200.7 05/27/2015 13:50 MHALL3 1 EPA 200.7 05/27/2015 13:50 MHALL3 1 EPA 200.7 05/27/2015 13:50 MHALL3 1 EPA 200.7 05/27/2015 13:50 MHALL3 1 EPA 200.7 05/27/2015 13:50 MHALL3 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050605 Site: MW-16S Collection Date: 20-May-15 10:55 AM Analyte Result DISSOLVED METALS BY ICP-MS Antimony (Sb) < 1 Arsenic (As) < 1 Beryllium (Be) < 1 Cadmium (Cd) < 1 Chromium (Cr) < 1 Cobalt (Co) 5.31 Copper (Cu) < 1 Lead (Pb) < 1 Molybdenum (Mo) < 1 Nickel (Ni) 5.14 Selenium (Se) < 1 Thallium (TI) Low Level < 0.2 Vanadium (V) Low Level 0.954 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 Arsenic (As) < 1 Beryllium (Be) < 1 Cadmium (Cd) < 1 Chromium (Cr) < 1 Cobalt (Co) 3.52 Copper (Cu) < 1 Lead (Pb) < 1 Molybdenum (Mo) < 1 Nickel (Ni) 3.14 Selenium (Se) < 1 Thallium (TI) Low Level < 0.2 Vanadium (V) Low Level 1.10 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4) Complete SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 630 Total Carbon TOC 0.706 TOTAL SUSPENDED SOLIDS TSS < 5 Page 11 of 78 Sample #: 2015015616 Matrix: GW_WW Units Qualifiers RDL DF Method Analysis Date/Time Analyst ug/L 1 1 EPA 200.8 06/05/2015 11:45 JAHERMA ug/L 1 1 EPA 200.8 06/05/2015 11:45 JAHERMA ug/L 1 1 EPA 200.8 06/05/2015 11:45 JAHERMA ug/L 1 1 EPA 200.8 06/05/2015 11:45 JAHERMA ug/L 1 1 EPA 200.8 06/05/2015 11:45 JAHERMA ug/L 1 1 EPA 200.8 06/05/2015 11:45 JAHERMA ug/L 1 1 EPA 200.8 06/05/2015 11:45 JAHERMA ug/L 1 1 EPA 200.8 06/05/2015 11:45 JAHERMA ug/L 1 1 EPA 200.8 06/05/2015 11:45 JAHERMA ug/L 1 1 EPA 200.8 06/05/2015 11:45 JAHERMA ug/L 1 1 EPA 200.8 06/05/2015 11:45 JAHERMA ug/L 0.2 1 EPA 200.8 06/05/2015 11:45 JAHERMA ug/L 0.3 1 EPA 200.8 06/05/2015 11:45 JAHERMA ug/L 1 1 EPA 200.8 06/06/2015 07:45 SLS2560 ug/L 1 1 EPA 200.8 06/06/2015 07:45 SLS2560 ug/L 1 1 EPA 200.8 06/06/2015 07:45 SLS2560 ug/L 1 1 EPA 200.8 06/06/2015 07:45 SLS2560 ug/L 1 1 EPA 200.8 06/06/2015 07:45 SLS2560 ug/L 1 1 EPA 200.8 06/06/2015 07:45 SLS2560 ug/L 1 1 EPA 200.8 06/06/2015 07:45 SLS2560 ug/L 1 1 EPA 200.8 06/06/2015 07:45 SLS2560 ug/L 1 1 EPA 200.8 06/06/2015 07:45 SLS2560 ug/L 1 1 EPA 200.8 06/06/2015 07:45 SLS2560 ug/L 1 1 EPA 200.8 06/06/2015 07:45 SLS2560 ug/L 0.2 1 EPA 200.8 06/06/2015 07:45 SLS2560 ug/L 0.3 1 EPA 200.8 06/06/2015 07:45 SLS2560 Vendor Method V SHEALY Vendor Method V_ELE1 mg/L 25 1 SM2540C 05/26/201515:35 AGIBBS5 mg/L 0.1 1 SM5310C/EPA9060A 06/01/201512:24 GHUTCHI mg/L 5 1 SM2540D 05/26/201510:27 AGIBBS5 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050605 Site: MW-16BR Collection Date: 20-May-15 12:00 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) < 0.01 mg-N/L 0.01 INORGANIC IONS BY IC Chloride 37 mg/L 1 Sulfate 41 mg/L 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) 0.006 mg/L 0.005 Barium (Ba) 0.352 mg/L 0.005 Boron (B) 0.051 mg/L 0.05 Iron (Fe) 0.187 mg/L 0.01 Manganese (Mn) 0.332 mg/L 0.005 Strontium (Sr) 0.494 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 41.1 mg/L 0.01 Magnesium (Mg) 13.9 mg/L 0.005 Potassium (K) 2.49 mg/L 0.1 Sodium (Na) 57.3 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.118 mg/L 0.005 Barium (Ba) 0.360 mg/L 0.005 Boron (B) 0.051 mg/L 0.05 Iron (Fe) 0.329 mg/L 0.01 Manganese (Mn) 0.326 mg/L 0.005 Strontium (Sr) 0.505 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 Sample #: 2015015617 Matrix: GW_WW Page 12 of 78 DF Method Analysis Date/Time Analyst Vendor Method V_SHEALY 1 EPA 353.2 05/27/2015 13:41 LSTARL1 10 EPA 300.0 05/27/2015 11:27 BGN9034 10 EPA 300.0 05/27/2015 11:27 BGN9034 1 EPA 245.1 05/28/2015 13:49 ACPAYNE 1 EPA 245.1 06/01/2015 13:47 ACPAYNE 1 EPA 200.7 05/22/2015 12:20 MHALL3 1 EPA 200.7 05/22/2015 12:20 MHALL3 1 EPA 200.7 05/22/2015 12:20 MHALL3 1 EPA 200.7 05/22/2015 12:20 MHALL3 1 EPA 200.7 05/22/2015 12:20 MHALL3 1 EPA 200.7 05/22/2015 12:20 MHALL3 1 EPA 200.7 05/22/2015 12:20 MHALL3 1 EPA 200.7 05/22/2015 14:37 MHALL3 1 EPA 200.7 05/22/2015 14:37 MHALL3 1 EPA 200.7 05/22/2015 14:37 MHALL3 1 EPA 200.7 05/22/2015 14:37 MHALL3 1 EPA 200.7 05/27/2015 13:53 MHALL3 1 EPA 200.7 05/27/2015 13:53 MHALL3 1 EPA 200.7 05/27/2015 13:53 MHALL3 1 EPA 200.7 05/27/2015 13:53 MHALL3 1 EPA 200.7 05/27/2015 13:53 MHALL3 1 EPA 200.7 05/27/2015 13:53 MHALL3 1 EPA 200.7 05/27/2015 13:53 MHALL3 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050605 Site: MW-16BR Collection Date: 20-May-15 12:00 PM Analyte Result DISSOLVED METALS BY ICP-MS Antimony (Sb) < 1 Arsenic (As) 2.59 Beryllium (Be) < 1 Cadmium (Cd) < 1 Chromium (Cr) < 1 Cobalt (Co) < 1 Copper (Cu) < 1 Lead (Pb) < 1 Molybdenum (Mo) 2.89 Nickel (Ni) < 1 Selenium (Se) < 1 Thallium (TI) Low Level < 0.2 Vanadium (V) Low Level < 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 Arsenic (As) 2.50 Beryllium (Be) < 1 Cadmium (Cd) < 1 Chromium (Cr) < 1 Cobalt (Co) < 1 Copper (Cu) 2.48 Lead (Pb) < 1 Molybdenum (Mo) 2.97 Nickel (Ni) < 1 Selenium (Se) < 1 Thallium (TI) Low Level < 0.2 Vanadium (V) Low Level < 0.3 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4) Complete SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 340 Total Carbon TOC 0.892 TOTAL SUSPENDED SOLIDS TSS < 5 Page 13 of 78 Sample #: 2015015617 Matrix: GW_WW Units Qualifiers RDL DF Method Analysis Date/Time Analyst ug/L 1 1 EPA 200.8 06/05/2015 11:50 JAHERMA ug/L 1 1 EPA 200.8 06/05/2015 11:50 JAHERMA ug/L 1 1 EPA 200.8 06/05/2015 11:50 JAHERMA ug/L 1 1 EPA 200.8 06/05/2015 11:50 JAHERMA ug/L 1 1 EPA 200.8 06/05/2015 11:50 JAHERMA ug/L 1 1 EPA 200.8 06/05/2015 11:50 JAHERMA ug/L 1 1 EPA 200.8 06/05/2015 11:50 JAHERMA ug/L 1 1 EPA 200.8 06/05/2015 11:50 JAHERMA ug/L 1 1 EPA 200.8 06/05/2015 11:50 JAHERMA ug/L 1 1 EPA 200.8 06/05/2015 11:50 JAHERMA ug/L 1 1 EPA 200.8 06/05/2015 11:50 JAHERMA ug/L 0.2 1 EPA 200.8 06/05/2015 11:50 JAHERMA ug/L 0.3 1 EPA 200.8 06/05/2015 11:50 JAHERMA ug/L 1 1 EPA 200.8 06/06/2015 07:49 SLS2560 ug/L 1 1 EPA 200.8 06/06/2015 07:49 SLS2560 ug/L 1 1 EPA 200.8 06/06/2015 07:49 SLS2560 ug/L 1 1 EPA 200.8 06/06/2015 07:49 SLS2560 ug/L 1 1 EPA 200.8 06/06/2015 07:49 SLS2560 ug/L 1 1 EPA 200.8 06/06/2015 07:49 SLS2560 ug/L 1 1 EPA 200.8 06/06/2015 07:49 SLS2560 ug/L 1 1 EPA 200.8 06/06/2015 07:49 SLS2560 ug/L 1 1 EPA 200.8 06/06/2015 07:49 SLS2560 ug/L 1 1 EPA 200.8 06/06/2015 07:49 SLS2560 ug/L 1 1 EPA 200.8 06/06/2015 07:49 SLS2560 ug/L 0.2 1 EPA 200.8 06/06/2015 07:49 SLS2560 ug/L 0.3 1 EPA 200.8 06/06/2015 07:49 SLS2560 Vendor Method V SHEALY Vendor Method V_ELE1 mg/L 25 1 SM2540C 05/26/201515:35 AGIBBS5 mg/L 0.1 1 SM5310C/EPA9060A 06/01/201512:24 GHUTCHI mg/L 5 1 SM2540D 05/26/201510:27 AGIBBS5 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050605 Site: DUP Collection Date: 20-May-15 11:10 AM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.015 mg-N/L 0.01 INORGANIC IONS BY IC Chloride 200 mg/L 2.5 Sulfate 44 mg/L 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) < 0.005 mg/L 0.005 Barium (Ba) 0.156 mg/L 0.005 Boron (B) 0.202 mg/L 0.05 Iron (Fe) 0.033 mg/L 0.01 Manganese (Mn) 0.305 mg/L 0.005 Strontium (Sr) 0.445 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 59.7 mg/L 0.01 Magnesium (Mg) 26.0 mg/L 0.005 Potassium (K) 0.943 mg/L 0.1 Sodium (Na) 82.2 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.064 mg/L 0.005 Barium (Ba) 0.162 mg/L 0.005 Boron (B) 0.140 mg/L 0.05 Iron (Fe) 0.072 mg/L 0.01 Manganese (Mn) 0.207 mg/L 0.005 Strontium (Sr) 0.627 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 Sample #: 2015015618 Matrix: GW_WW Page 14 of 78 DF Method Analysis Date/Time Analyst Vendor Method V_SHEALY 1 EPA 353.2 05/27/2015 13:42 LSTARL1 25 EPA 300.0 05/27/2015 13:38 BGN9034 10 EPA 300.0 05/27/2015 13:38 BGN9034 1 EPA 245.1 05/28/2015 13:51 ACPAYNE 1 EPA 245.1 06/01/2015 13:50 ACPAYNE 1 EPA 200.7 05/22/2015 11:38 MHALL3 1 EPA 200.7 05/22/2015 11:38 MHALL3 1 EPA 200.7 05/22/2015 11:38 MHALL3 1 EPA 200.7 05/22/2015 11:38 MHALL3 1 EPA 200.7 05/22/2015 11:38 MHALL3 1 EPA 200.7 05/22/2015 11:38 MHALL3 1 EPA 200.7 05/22/2015 11:38 MHALL3 1 EPA 200.7 05/22/2015 14:41 MHALL3 1 EPA 200.7 05/22/2015 14:41 MHALL3 1 EPA 200.7 05/22/2015 14:41 MHALL3 1 EPA 200.7 05/22/2015 14:41 MHALL3 1 EPA 200.7 05/27/2015 13:57 MHALL3 1 EPA 200.7 05/27/2015 13:57 MHALL3 1 EPA 200.7 05/27/2015 13:57 MHALL3 1 EPA 200.7 05/27/2015 13:57 MHALL3 1 EPA 200.7 05/27/2015 13:57 MHALL3 1 EPA 200.7 05/27/2015 13:57 MHALL3 1 EPA 200.7 05/27/2015 13:57 MHALL3 Certificate of Laboratory Analysis Page 15 of 78 This report shall not be reproduced, except in full. Order # J15050605 Site: DUP Sample #: 2015015618 Collection Date: 20-May-15 11:10 AM Matrix: GW_WW Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst DISSOLVED METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 1 EPA 200.8 06/05/2015 11:54 JAHERMA Arsenic (As) < 1 ug/L 1 1 EPA 200.8 06/05/2015 11:54 JAHERMA Beryllium (Be) < 1 ug/L 1 1 EPA 200.8 06/05/2015 11:54 JAHERMA Cadmium (Cd) < 1 ug/L 1 1 EPA 200.8 06/05/2015 11:54 JAHERMA Chromium (Cr) < 1 ug/L 1 1 EPA 200.8 06/05/2015 11:54 JAHERMA Cobalt (Co) 5.19 ug/L 1 1 EPA 200.8 06/05/2015 11:54 JAHERMA Copper (Cu) < 1 ug/L 1 1 EPA 200.8 06/05/2015 11:54 JAHERMA Lead (Pb) < 1 ug/L 1 1 EPA 200.8 06/05/2015 11:54 JAHERMA Molybdenum (Mo) < 1 ug/L 1 1 EPA 200.8 06/05/2015 11:54 JAHERMA Nickel (Ni) 4.59 ug/L 1 1 EPA 200.8 06/05/2015 11:54 JAHERMA Selenium (Se) < 1 ug/L 1 1 EPA 200.8 06/05/2015 11:54 JAHERMA Thallium (TI) Low Level < 0.2 ug/L 0.2 1 EPA 200.8 06/05/2015 11:54 JAHERMA Vanadium (V) Low Level 0.827 ug/L 0.3 1 EPA 200.8 06/05/2015 11:54 JAHERMA TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 1 EPA 200.8 06/06/2015 07:54 SLS2560 Arsenic (As) < 1 ug/L 1 1 EPA 200.8 06/06/2015 07:54 SLS2560 Beryllium (Be) < 1 ug/L 1 1 EPA 200.8 06/06/2015 07:54 SLS2560 Cadmium (Cd) < 1 ug/L 1 1 EPA 200.8 06/06/2015 07:54 SLS2560 Chromium (Cr) < 1 ug/L 1 1 EPA 200.8 06/06/2015 07:54 SLS2560 Cobalt (Co) 3.90 ug/L 1 1 EPA 200.8 06/06/2015 07:54 SLS2560 Copper (Cu) < 1 ug/L 1 1 EPA 200.8 06/06/2015 07:54 SLS2560 Lead (Pb) < 1 ug/L 1 1 EPA 200.8 06/06/2015 07:54 SLS2560 Molybdenum (Mo) < 1 ug/L 1 1 EPA 200.8 06/06/2015 07:54 SLS2560 Nickel (Ni) 2.95 ug/L 1 1 EPA 200.8 06/06/2015 07:54 SLS2560 Selenium (Se) < 1 ug/L 1 1 EPA 200.8 06/06/2015 07:54 SLS2560 Thallium (TI) Low Level < 0.2 ug/L 0.2 1 EPA 200.8 06/06/2015 07:54 SLS2560 Vanadium (V) Low Level 1.05 ug/L 0.3 1 EPA 200.8 06/06/2015 07:54 SLS2560 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4) Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 620 mg/L 25 1 SM2540C 05/26/201515:35 AGIBBS5 Total Carbon TOC 0.747 mg/L 0.1 1 SM5310C/EPA9060A 06/01/201512:24 GHUTCHI TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 1 SM2540D 05/26/2015 10:27 AGIBBS5 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050605 Site: ABMW-3 Collection Date: 20-May-15 1:25 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.016 mg-N/L 0.01 INORGANIC IONS BY IC Chloride 6.7 mg/L 0.1 Sulfate 410 mg/L 10 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) 0.215 mg/L 0.005 Barium (Ba) 0.133 mg/L 0.005 Boron (B) 6.25 mg/L 0.05 Iron (Fe) 0.070 mg/L 0.01 Manganese (Mn) 0.124 mg/L 0.005 Strontium (Sr) 4.37 mg/L 0.005 Zinc (Zn) 0.005 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 120 mg/L 0.1 Magnesium (Mg) 67.4 mg/L 0.005 Potassium (K) 19.7 mg/L 0.1 Sodium (Na) 23.4 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.232 mg/L 0.005 Barium (Ba) 0.137 mg/L 0.005 Boron (B) 6.36 mg/L 0.05 Iron (Fe) 0.091 mg/L 0.01 Manganese (Mn) 0.124 mg/L 0.005 Strontium (Sr) 4.45 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 Page 16 of 78 Sample #: 2015015619 Matrix: GW_WW DF Method Analysis Date/Time Analyst Vendor Method V_SHEALY 1 EPA 353.2 05/27/2015 13:48 LSTARL1 1 EPA 300.0 05/27/2015 14:11 BGN9034 100 EPA 300.0 05/27/2015 14:11 BGN9034 1 EPA 245.1 05/28/2015 13:54 ACPAYNE 1 EPA 245.1 06/01/2015 13:52 ACPAYNE 1 EPA 200.7 05/22/2015 12:51 MHALL3 1 EPA 200.7 05/22/2015 12:51 MHALL3 1 EPA 200.7 05/22/2015 12:51 MHALL3 1 EPA 200.7 05/22/2015 12:51 MHALL3 1 EPA 200.7 05/22/2015 12:51 MHALL3 1 EPA 200.7 05/22/2015 12:51 MHALL3 1 EPA 200.7 05/22/2015 12:51 MHALL3 10 EPA 200.7 05/22/2015 14:53 MHALL3 1 EPA 200.7 05/22/2015 14:53 MHALL3 1 EPA 200.7 05/22/2015 14:53 MHALL3 1 EPA 200.7 05/22/2015 14:53 MHALL3 1 EPA 200.7 05/27/2015 14:01 MHALL3 1 EPA 200.7 05/27/2015 14:01 MHALL3 1 EPA 200.7 05/27/2015 14:01 MHALL3 1 EPA 200.7 05/27/2015 14:01 MHALL3 1 EPA 200.7 05/27/2015 14:01 MHALL3 1 EPA 200.7 05/27/2015 14:01 MHALL3 1 EPA 200.7 05/27/2015 14:01 MHALL3 Certificate of Laboratory Analysis Page 17 of 78 This report shall not be reproduced, except in full. Order # J15050605 Site: ABMW-3 Sample #: 2015015619 Collection Date: 20-May-15 1:25 PM Matrix: GW_WW Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst DISSOLVED METALS BY ICP-MS Antimony (Sb) 3.10 ug/L 1 1 EPA 200.8 06/05/2015 11:59 JAHERMA Arsenic (As) 361 ug/L 1 1 EPA 200.8 06/05/2015 11:59 JAHERMA Beryllium (Be) < 1 ug/L 1 1 EPA 200.8 06/05/2015 11:59 JAHERMA Cadmium (Cd) < 1 ug/L 1 1 EPA 200.8 06/05/2015 11:59 JAHERMA Chromium (Cr) < 1 ug/L 1 1 EPA 200.8 06/05/2015 11:59 JAHERMA Cobalt (Co) < 1 ug/L 1 1 EPA 200.8 06/05/2015 11:59 JAHERMA Copper (Cu) < 1 ug/L 1 1 EPA 200.8 06/05/2015 11:59 JAHERMA Lead (Pb) < 1 ug/L 1 1 EPA 200.8 06/05/2015 11:59 JAHERMA Molybdenum (Mo) 261 ug/L 1 1 EPA 200.8 06/05/2015 11:59 JAHERMA Nickel (Ni) 5.10 ug/L 1 1 EPA 200.8 06/05/2015 11:59 JAHERMA Selenium (Se) 1.92 ug/L 1 1 EPA 200.8 06/05/2015 11:59 JAHERMA Thallium (TI) Low Level 0.442 ug/L 0.2 1 EPA 200.8 06/05/2015 11:59 JAHERMA Vanadium (V) Low Level 22.3 ug/L 0.3 1 EPA 200.8 06/05/2015 11:59 JAHERMA TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) 3.59 ug/L 1 1 EPA 200.8 06/06/2015 07:58 SLS2560 Arsenic (As) 341 ug/L 1 1 EPA 200.8 06/06/2015 07:58 SLS2560 Beryllium (Be) < 1 ug/L 1 1 EPA 200.8 06/06/2015 07:58 SLS2560 Cadmium (Cd) < 1 ug/L 1 1 EPA 200.8 06/06/2015 07:58 SLS2560 Chromium (Cr) < 1 ug/L 1 1 EPA 200.8 06/06/2015 07:58 SLS2560 Cobalt (Co) < 1 ug/L 1 1 EPA 200.8 06/06/2015 07:58 SLS2560 Copper (Cu) < 1 ug/L 1 1 EPA 200.8 06/06/2015 07:58 SLS2560 Lead (Pb) < 1 ug/L 1 1 EPA 200.8 06/06/2015 07:58 SLS2560 Molybdenum (Mo) 239 ug/L 1 1 EPA 200.8 06/06/2015 07:58 SLS2560 Nickel (Ni) 5.45 ug/L 1 1 EPA 200.8 06/06/2015 07:58 SLS2560 Selenium (Se) 2.32 ug/L 1 1 EPA 200.8 06/06/2015 07:58 SLS2560 Thallium (TI) Low Level 0.422 ug/L 0.2 1 EPA 200.8 06/06/2015 07:58 SLS2560 Vanadium (V) Low Level 22.1 ug/L 0.3 1 EPA 200.8 06/06/2015 07:58 SLS2560 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4) Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 820 mg/L 25 1 SM2540C 05/26/201515:35 AGIBBS5 Total Carbon TOC 1.2 mg/L 0.1 1 SM5310C/EPA9060A 06/01/201512:24 GHUTCHI TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 1 SM2540D 05/26/2015 10:27 AGIBBS5 Certificate of Laboratory Analysis Page 18 of 78 This report shall not be reproduced, except in full. Order # J15050605 Site: ABMW-2SU Collection Date: 20-May-15 2:45 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.030 mg-N/L 0.01 INORGANIC IONS BY IC Chloride 39 mg/L 1 Sulfate 270 mg/L 5 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) 1.98 mg/L 0.005 Barium (Ba) 0.027 mg/L 0.005 Boron (B) 0.200 mg/L 0.05 Iron (Fe) 16.8 mg/L 0.01 Manganese (Mn) 1.56 mg/L 0.005 Strontium (Sr) 0.552 mg/L 0.005 Zinc (Zn) 0.036 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 21.0 mg/L 0.01 Magnesium (Mg) 8.71 mg/L 0.005 Potassium (K) 3.66 mg/L 0.1 Sodium (Na) 79.9 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 2.09 mg/L 0.005 Barium (Ba) 0.028 mg/L 0.005 Boron (B) 0.198 mg/L 0.05 Iron (Fe) 15.9 mg/L 0.01 Manganese (Mn) 1.54 mg/L 0.005 Strontium (Sr) 0.549 mg/L 0.005 Zinc (Zn) 0.037 mg/L 0.005 Sample #: 2015015620 Matrix: GW_WW DF Method Analysis Date/Time Analyst Vendor Method V_SHEALY 1 EPA 353.2 05/27/2015 13:51 LSTARL1 10 EPA 300.0 05/28/2015 09:54 BGN9034 50 EPA 300.0 05/28/2015 09:54 BGN9034 1 EPA 245.1 05/28/2015 13:56 ACPAYNE 1 EPA 245.1 06/01/2015 13:54 ACPAYNE 1 EPA 200.7 05/22/2015 11:45 MHALL3 1 EPA 200.7 05/22/2015 11:45 MHALL3 1 EPA 200.7 05/22/2015 11:45 MHALL3 1 EPA 200.7 05/22/2015 11:45 MHALL3 1 EPA 200.7 05/22/2015 11:45 MHALL3 1 EPA 200.7 05/22/2015 11:45 MHALL3 1 EPA 200.7 05/22/2015 11:45 MHALL3 1 EPA 200.7 05/22/2015 15:31 MHALL3 1 EPA 200.7 05/22/2015 15:31 MHALL3 1 EPA 200.7 05/22/2015 15:31 MHALL3 1 EPA 200.7 05/22/2015 15:31 MHALL3 1 EPA 200.7 05/27/2015 14:05 MHALL3 1 EPA 200.7 05/27/2015 14:05 MHALL3 1 EPA 200.7 05/27/2015 14:05 MHALL3 1 EPA 200.7 05/27/2015 14:05 MHALL3 1 EPA 200.7 05/27/2015 14:05 MHALL3 1 EPA 200.7 05/27/2015 14:05 MHALL3 1 EPA 200.7 05/27/2015 14:05 MHALL3 Certificate of Laboratory Analysis Page 19 of 78 This report shall not be reproduced, except in full. Order # J15050605 Site: ABMW-2SU Sample #: 2015015620 Collection Date: 20-May-15 2:45 PM Matrix: GW_WW Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst DISSOLVED METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 1 EPA 200.8 06/05/2015 12:04 JAHERMA Arsenic (As) < 1 ug/L 1 1 EPA 200.8 06/05/2015 12:04 JAHERMA Beryllium (Be) < 1 ug/L 1 1 EPA 200.8 06/05/2015 12:04 JAHERMA Cadmium (Cd) < 1 ug/L 1 1 EPA 200.8 06/05/2015 12:04 JAHERMA Chromium (Cr) < 1 ug/L 1 1 EPA 200.8 06/05/2015 12:04 JAHERMA Cobalt (Co) 18.0 ug/L 1 1 EPA 200.8 06/05/2015 12:04 JAHERMA Copper (Cu) 2.37 ug/L B2 1 1 EPA 200.8 06/05/2015 12:04 JAHERMA Lead (Pb) 6.16 ug/L 1 1 EPA 200.8 06/05/2015 12:04 JAHERMA Molybdenum (Mo) < 1 ug/L 1 1 EPA 200.8 06/05/2015 12:04 JAHERMA Nickel (Ni) 14.4 ug/L 1 1 EPA 200.8 06/05/2015 12:04 JAHERMA Selenium (Se) < 1 ug/L 1 1 EPA 200.8 06/05/2015 12:04 JAHERMA Thallium (TI) Low Level < 0.2 ug/L 0.2 1 EPA 200.8 06/05/2015 12:04 JAHERMA Vanadium (V) Low Level < 0.3 ug/L 0.3 1 EPA 200.8 06/05/2015 12:04 JAHERMA TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 1 EPA 200.8 06/06/2015 08:03 SLS2560 Arsenic (As) < 1 ug/L 1 1 EPA 200.8 06/06/2015 08:03 SLS2560 Beryllium (Be) < 1 ug/L 1 1 EPA 200.8 06/06/2015 08:03 SLS2560 Cadmium (Cd) < 1 ug/L 1 1 EPA 200.8 06/06/2015 08:03 SLS2560 Chromium (Cr) < 1 ug/L 1 1 EPA 200.8 06/06/2015 08:03 SLS2560 Cobalt (Co) 19.0 ug/L 1 1 EPA 200.8 06/06/2015 08:03 SLS2560 Copper (Cu) 2.41 ug/L 1 1 EPA 200.8 06/06/2015 08:03 SLS2560 Lead (Pb) 6.24 ug/L 1 1 EPA 200.8 06/06/2015 08:03 SLS2560 Molybdenum (Mo) < 1 ug/L 1 1 EPA 200.8 06/06/2015 08:03 SLS2560 Nickel (Ni) 14.8 ug/L 1 1 EPA 200.8 06/06/2015 08:03 SLS2560 Selenium (Se) < 1 ug/L 1 1 EPA 200.8 06/06/2015 08:03 SLS2560 Thallium (TI) Low Level < 0.2 ug/L 0.2 1 EPA 200.8 06/06/2015 08:03 SLS2560 Vanadium (V) Low Level < 0.3 ug/L 0.3 1 EPA 200.8 06/06/2015 08:03 SLS2560 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4) Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 440 mg/L 25 1 SM2540C 05/26/201515:35 AGIBBS5 Total Carbon TOC 2.5 mg/L 0.1 1 SM5310C/EPA9060A 06/01/201512:24 GHUTCHI TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 1 SM2540D 05/26/2015 10:27 AGIBBS5 Certificate of Laboratory Analysis Page 20 of 78 This report shall not be reproduced, except in full. Order # J15050605 Site: ABMW-2SL Collection Date: 20-May-15 4:00 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.271 mg-N/L 0.01 INORGANIC IONS BY IC Chloride 6.6 mg/L 0.1 Sulfate 14 mg/L 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) 0.008 mg/L 0.005 Barium (Ba) 0.014 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 3.26 mg/L 0.01 Manganese (Mn) 0.493 mg/L 0.005 Strontium (Sr) 0.028 mg/L 0.005 Zinc (Zn) 0.053 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 8.72 mg/L 0.01 Magnesium (Mg) 4.25 mg/L 0.005 Potassium (K) 1.09 mg/L 0.1 Sodium (Na) 9.47 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.069 mg/L 0.005 Barium (Ba) 0.015 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 3.45 mg/L 0.01 Manganese (Mn) 0.519 mg/L 0.005 Strontium (Sr) 0.030 mg/L 0.005 Zinc (Zn) 0.638 mg/L 0.005 Sample #: 2015015621 Matrix: GW_WW DF Method Analysis Date/Time Analyst Vendor Method V_SHEALY 1 EPA 353.2 05/27/2015 13:53 LSTARL1 1 EPA 300.0 05/27/2015 19:07 BGN9034 10 EPA 300.0 05/27/2015 19:07 BGN9034 1 EPA 245.1 05/28/2015 13:59 ACPAYNE 1 EPA 245.1 06/01/2015 13:57 ACPAYNE 1 EPA 200.7 05/22/2015 11:49 MHALL3 1 EPA 200.7 05/22/2015 11:49 MHALL3 1 EPA 200.7 05/22/2015 11:49 MHALL3 1 EPA 200.7 05/22/2015 11:49 MHALL3 1 EPA 200.7 05/22/2015 11:49 MHALL3 1 EPA 200.7 05/22/2015 11:49 MHALL3 1 EPA 200.7 05/22/2015 11:49 MHALL3 1 EPA 200.7 05/22/2015 14:08 MHALL3 1 EPA 200.7 05/22/2015 14:08 MHALL3 1 EPA 200.7 05/22/2015 14:08 MHALL3 1 EPA 200.7 05/22/2015 14:08 MHALL3 1 EPA 200.7 05/27/2015 14:09 MHALL3 1 EPA 200.7 05/27/2015 14:09 MHALL3 1 EPA 200.7 05/27/2015 14:09 MHALL3 1 EPA 200.7 05/27/2015 14:09 MHALL3 1 EPA 200.7 05/27/2015 14:09 MHALL3 1 EPA 200.7 05/27/2015 14:09 MHALL3 1 EPA 200.7 05/27/2015 14:09 MHALL3 Certificate of Laboratory Analysis Page 21 of 78 This report shall not be reproduced, except in full. Order # J15050605 Site: ABMW-2SL Sample #: 2015015621 Collection Date: 20-May-15 4:00 PM Matrix: GW_WW Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst DISSOLVED METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 1 EPA 200.8 06/04/2015 18:06 JAHERMA Arsenic (As) 1.18 ug/L 1 1 EPA 200.8 06/04/2015 18:06 JAHERMA Beryllium (Be) < 1 ug/L 1 1 EPA 200.8 06/04/2015 18:06 JAHERMA Cadmium (Cd) < 1 ug/L 1 1 EPA 200.8 06/04/2015 18:06 JAHERMA Chromium (Cr) < 1 ug/L 1 1 EPA 200.8 06/04/2015 18:06 JAHERMA Cobalt (Co) 4.17 ug/L 1 1 EPA 200.8 06/04/2015 18:06 JAHERMA Copper (Cu) < 1 ug/L 1 1 EPA 200.8 06/04/2015 18:06 JAHERMA Lead (Pb) < 1 ug/L 1 1 EPA 200.8 06/04/2015 18:06 JAHERMA Molybdenum (Mo) < 1 ug/L 1 1 EPA 200.8 06/04/2015 18:06 JAHERMA Nickel (Ni) 6.83 ug/L 1 1 EPA 200.8 06/04/2015 18:06 JAHERMA Selenium (Se) < 1 ug/L 1 1 EPA 200.8 06/04/2015 18:06 JAHERMA Thallium (TI) Low Level < 0.2 ug/L 0.2 1 EPA 200.8 06/04/2015 18:06 JAHERMA Vanadium (V) Low Level < 0.3 ug/L 0.3 1 EPA 200.8 06/04/2015 18:06 JAHERMA TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 10 ug/L 10 10 EPA 200.8 06/06/2015 08:07 SLS2560 Arsenic (As) < 10 ug/L 10 10 EPA 200.8 06/06/2015 08:07 SLS2560 Beryllium (Be) < 10 ug/L 10 10 EPA 200.8 06/06/2015 08:07 SLS2560 Cadmium (Cd) < 10 ug/L 10 10 EPA 200.8 06/06/2015 08:07 SLS2560 Chromium (Cr) < 10 ug/L 10 10 EPA 200.8 06/06/2015 08:07 SLS2560 Cobalt (Co) < 10 ug/L 10 10 EPA 200.8 06/06/2015 08:07 SLS2560 Copper (Cu) < 10 ug/L 10 10 EPA 200.8 06/06/2015 08:07 SLS2560 Lead (Pb) < 10 ug/L 10 10 EPA 200.8 06/06/2015 08:07 SLS2560 Molybdenum (Mo) < 10 ug/L 10 10 EPA 200.8 06/06/2015 08:07 SLS2560 Nickel (Ni) < 10 ug/L 10 10 EPA 200.8 06/06/2015 08:07 SLS2560 Selenium (Se) < 10 ug/L 10 10 EPA 200.8 06/06/2015 08:07 SLS2560 Thallium (TI) Low Level < 2 ug/L 2 10 EPA 200.8 06/06/2015 08:07 SLS2560 Vanadium (V) Low Level < 3 ug/L 3 10 EPA 200.8 06/06/2015 08:07 SLS2560 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4) Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 100 mg/L 25 1 SM2540C 05/26/201515:35 AGIBBS5 Total Carbon TOC 0.898 mg/L 0.1 1 SM5310C/EPA9060A 06/01/201512:24 GHUTCHI TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 1 SM2540D 05/26/2015 10:27 AGIBBS5 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050605 Site: ERB-27 Collection Date: 20-May-15 4:35 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.015 mg-N/L 0.01 INORGANIC IONS BY IC Chloride < 0.1 mg/L 0.1 Sulfate 0.50 mg/L 0.1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 UNDIGESTED METALS BY ICP Calcium (Ca) 0.040 mg/L 0.01 Magnesium (Mg) < 0.005 mg/L 0.005 Potassium (K) < 0.1 mg/L 0.1 Sodium (Na) 0.140 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.011 mg/L 0.005 Barium (Ba) < 0.005 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) < 0.01 mg/L 0.01 Manganese (Mn) < 0.005 mg/L 0.005 Strontium (Sr) < 0.005 mg/L 0.005 Zinc (Zn) 0.018 mg/L 0.005 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 Page 22 of 78 Sample #: 2015015622 Matrix: GW_WW DF Method Analysis Date/Time Analyst Vendor Method V_SHEALY 1 EPA 353.2 05/27/2015 13:54 LSTARL1 1 EPA 300.0 05/27/2015 19:23 BGN9034 1 EPA 300.0 05/27/2015 19:23 BGN9034 1 EPA 245.1 05/28/2015 14:01 ACPAYNE 1 EPA 200.7 05/22/2015 14:45 MHALL3 1 EPA 200.7 05/22/2015 14:45 MHALL3 1 EPA 200.7 05/22/2015 14:45 MHALL3 1 EPA 200.7 05/22/2015 14:45 MHALL3 1 EPA 200.7 05/27/2015 14:12 MHALL3 1 EPA 200.7 05/27/2015 14:12 MHALL3 1 EPA 200.7 05/27/2015 14:12 MHALL3 1 EPA 200.7 05/27/2015 14:12 MHALL3 1 EPA 200.7 05/27/2015 14:12 MHALL3 1 EPA 200.7 05/27/2015 14:12 MHALL3 1 EPA 200.7 05/27/2015 14:12 MHALL3 1 EPA 200.8 06/06/2015 08:12 SLS2560 1 EPA 200.8 06/06/2015 08:12 SLS2560 1 EPA 200.8 06/06/2015 08:12 SLS2560 1 EPA 200.8 06/06/2015 08:12 SLS2560 1 EPA 200.8 06/06/2015 08:12 SLS2560 1 EPA 200.8 06/06/2015 08:12 SLS2560 1 EPA 200.8 06/06/2015 08:12 SLS2560 1 EPA 200.8 06/06/2015 08:12 SLS2560 1 EPA 200.8 06/06/2015 08:12 SLS2560 1 EPA 200.8 06/06/2015 08:12 SLS2560 1 EPA 200.8 06/06/2015 08:12 SLS2560 1 EPA 200.8 06/06/2015 08:12 SLS2560 1 EPA 200.8 06/06/2015 08:12 SLS2560 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4) Complete Vendor Method V_SHEALY Certificate of Laboratory Analysis Page 23 of 78 This report shall not be reproduced, except in full. Order # J15050605 Site: ERB-27 Collection Date: 20-May-15 4:35 PM Analyte Result Units Qualifiers RDL DF SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS < 25 mg/L 25 1 Total Carbon Sample #: 2015015622 Matrix: GW WW Method Analysis Date/Time Analyst Vendor Method V_ELE1 SM2540C 05/26/201515:35 AGIBBS5 TOC 0.248 mg/L 0.1 1 SM5310C/EPA9060A 06/01/201512:24 GHUTCHI TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 1 SM2540D 05/26/2015 10:27 AGIBBS5 Certificate of Laboratory Analysis Page 24 of 78 This report shall not be reproduced, except in full. Order # J15050605 Site: Filter Blank Collection Date: 19-May-15 4:50 PM Analyte Result Units Qualifiers RDL Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) < 0.005 mg/L 0.005 Barium (Ba) < 0.005 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) < 0.01 mg/L 0.01 Manganese (Mn) < 0.005 mg/L 0.005 Strontium (Sr) < 0.005 mg/L 0.005 Zinc (Zn) 0.014 mg/L 0.005 DISSOLVED METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 Sample #: 2015015623 Matrix: GW_WW DF Method Analysis Date/Time Analyst 1 EPA 245.1 06/01/2015 13:59 ACPAYNE 1 EPA 200.7 05/22/2015 11:53 MHALL3 1 EPA 200.7 05/22/2015 11:53 MHALL3 1 EPA 200.7 05/22/2015 11:53 MHALL3 1 EPA 200.7 05/22/2015 11:53 MHALL3 1 EPA 200.7 05/22/2015 11:53 MHALL3 1 EPA 200.7 05/22/2015 11:53 MHALL3 1 EPA 200.7 05/22/2015 11:53 MHALL3 1 EPA 200.8 06/04/2015 18:19 JAHERMA 1 EPA 200.8 06/04/2015 18:19 JAHERMA 1 EPA 200.8 06/04/2015 18:19 JAHERMA 1 EPA 200.8 06/04/2015 18:19 JAHERMA 1 EPA 200.8 06/04/2015 18:19 JAHERMA 1 EPA 200.8 06/04/2015 18:19 JAHERMA 1 EPA 200.8 06/04/2015 18:19 JAHERMA 1 EPA 200.8 06/04/2015 18:19 JAHERMA 1 EPA 200.8 06/04/2015 18:19 JAHERMA 1 EPA 200.8 06/04/2015 18:19 JAHERMA 1 EPA 200.8 06/04/2015 18:19 JAHERMA 1 EPA 200.8 06/04/2015 18:19 JAHERMA 1 EPA 200.8 06/04/2015 18:19 JAHERMA Certificate of Laboratory Analysis Page 25 of 78 This report shall not be reproduced, except in full. Order # J15050605 Site: Filter Blank Collection Date: 20-May-15 4:35 PM Analyte Result Units Qualifiers RDL Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) < 0.005 mg/L 0.005 Barium (Ba) < 0.005 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) < 0.01 mg/L 0.01 Manganese (Mn) < 0.005 mg/L 0.005 Strontium (Sr) < 0.005 mg/L 0.005 Zinc (Zn) 0.027 mg/L 0.005 DISSOLVED METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 Sample #: 2015015624 Matrix: GW_WW DF Method Analysis Date/Time Analyst 1 EPA 245.1 06/01/2015 14:01 ACPAYNE 1 EPA 200.7 05/22/2015 11:57 MHALL3 1 EPA 200.7 05/22/2015 11:57 MHALL3 1 EPA 200.7 05/22/2015 11:57 MHALL3 1 EPA 200.7 05/22/2015 11:57 MHALL3 1 EPA 200.7 05/22/2015 11:57 MHALL3 1 EPA 200.7 05/22/2015 11:57 MHALL3 1 EPA 200.7 05/22/2015 11:57 MHALL3 1 EPA 200.8 06/04/2015 18:24 JAHERMA 1 EPA 200.8 06/04/2015 18:24 JAHERMA 1 EPA 200.8 06/04/2015 18:24 JAHERMA 1 EPA 200.8 06/04/2015 18:24 JAHERMA 1 EPA 200.8 06/04/2015 18:24 JAHERMA 1 EPA 200.8 06/04/2015 18:24 JAHERMA 1 EPA 200.8 06/04/2015 18:24 JAHERMA 1 EPA 200.8 06/04/2015 18:24 JAHERMA 1 EPA 200.8 06/04/2015 18:24 JAHERMA 1 EPA 200.8 06/04/2015 18:24 JAHERMA 1 EPA 200.8 06/04/2015 18:24 JAHERMA 1 EPA 200.8 06/04/2015 18:24 JAHERMA 1 EPA 200.8 06/04/2015 18:24 JAHERMA Qualifiers: B2 Target analyte was detected in blank(s) at a concentration greater than'/z the reporting limit but less than the reporting limit. Analyte concentration in sample is valid and may be used for compliance purposes. Page 26 of 78 �'�O�9�l�i1t• - REPORT OF ANALYSES E�ernent One lnc. 63119-D Carolina Beach Rd. Wilmington, NC 28412 Phone: 910 793-01128 Fax: 910 792-6853 el1ab@ellab.com Duke Energy June 2, 2015 Laboratory Services Client Project Name AB GW Assessment water Cape Fear 13339 Hagers Ferry Road Bld. MG03A Client Project Number J15050605 Huntersville, NC 28078 PO Number Sample Matrix Sample Type Grab Date Received 05/22/2015 Date Analyzed 05/22/2015 Method SM 4500 S2- D Time Received 1205 Delivered by FedEx Received by JRC eOne ID Duke Energy ID Parameter Result Unit Dil DL Date Time Sampled Sampled 24836-1 ABMW-5BR Sulfide < 0.1 mg/L 1 0.1 05/19/15 1150 24836-2 ABMW-3BR Sulfide < 0.1 mg/L 1 0.1 05/19/15 1600 24836-3 ERB-26 Sulfide < 0.1 mg/L 1 0.1 05/19/15 1650 24836-4 MW-16S Sulfide < 0.1 mg/L 1 0.1 05/20/15 1055 24836-5 MW-16BR Sulfide < 0.1 mg/L 1 0.1 05/20/15 1200 24836-6 Dup Sulfide < 0.1 mg/L 1 0.1 05/20/15 1110 24836-7* ABMW-DI-3 Sulfide < 0.2 mg/L 2 0.1 05/20/15 1325 24836-8* ABMW-2SU Sulfide < 0.5 mg/L 5 0.1 05/20/15 1445 *Sample spike recovery outside of QA limits of 85-115%; dilution necessary to meet laboratory QA limits. Ken Smith, Laboratory Director 24836 Duke Report Packet Compiled byVLLS NC Certifications: DW 37788 and DWQ DENR 604 Page 27 of 78 Ell e31 e 1 t • - Element One Duce 6319-D Carolina Beach Rd. VVHmin¢gton, NC 28412 Tone: 910 793-0128 Fax: 910 792-6853 ellab@ellab.com REPORT OF ANALYSES Duke Energy June 2, 2015 Laboratory Services Client Project Name AB GW Assessment water Cape Fear 13339 Hagers Ferry Road Bid. MG03A Client Project Number J15050605 Huntersville, NC 28078 PO Number Sample Matrix Sample Type Grab Date Received 05/22/2015 Date Analyzed 05/22/2015 Method SM 4500 S2- D Time Received 1205 Delivered by FedEx eOne ID Duke Energy ID Parameter Result Unit Dil 24836-9 ABMW-2SL 24836-10 ERB-27 (GW) Sulfide < 0.1 mg/L 1 Received by JRC DL Date Time Sampled Sampled 0.1 05/20/15 1600 Sulfide < 0.1 mg/L 1 0.1 05/20/15 1635 Ken Smith, Laboratory Director 24836 Duke Report Packet Compiled by)[AA— NC Certifications: DW 37788 and DWQ DENR 604 po c NFTITT-.-T l'S U �Iz W. N �` _ >. o PeAlosslp Molaq of ct W g Im f aas) sielew __------- - ---- O ° > b I O 4 + I i j i A—Q ��1 tr S e zIN�� c o � $ yins e46 @ieuogiep� A -*---r—�- uoqjvole taG' �� 3 -)3 s 'Aijujj@MIV ellJliN ~ i a1111 '001Lao - - LLJ wig N% �---•---i V yt 34SU)eue448 Z'� Q G ! a j 6`•�-�ap ' I <. I V! G w ; {�y Ii.e V C Q G: YL� Q e--I w O d Q C --,-r I I ! I O o T@ YI j� E _ C l `\V1'• cr Page 28 of 78 punojeuinjpausap ejvojpujosuajd :juej�odwj'JDlUOj51lj z u U N elementOne SAMPLE SUBMISSION FORM Lab Ibge 2Y4936 TAT 7 131) Hold Time Expiration 05.26.15 @ 1150 Client: Duke Energy LIMS No J15050605 Project ID Cape Fear Analysis Due Date 05.22.15 Report Due Date 06.02.15 Date Rec: 05.22.15 Time Rec: 1205 Rec By JRC H >9 Y No Temps 60C Ye No Ref. Method: SM4500 S2 D If No, Record I If No, Record Sample Identification & Collection Information Lab ID Client ID Collection Date Collection Time Analysis Requested 1 ABMW-5BR 05/19/15 1150 e VI 2 3 4 ABMW-3BR ERB-26 MW-16S 05/19/15 05/19/15 05/20/15 1600 1650 1055 u i 5 MW-16BR 05/20/15 1200 u i 6 Dup 05/20/15 1110 u i 7 ABMW-3 05/20/15 1325 u i e) 8 ABMW-2SU 05/20/15 1445 ulfide 9 ABMW-2SL 05/20/15� 1600 _ ulfid___ 10 ERB-27 05/20/15 1635 u fid __, NOTE for Sulfide The MS/MSD spike should approximate 2 to 3 times the sample concentration. If no sulfide detected at 100 pg/L spike the sample to render the final spike concentration at - 500 pg/L Lab Communications All AB Groundwater Assessment SS Page 1 of 1 SS by 5/22/2015 .32:05 PM need a RL of 0.1 Prep By / Date I � 5 �)4 \' 1� Labeled By / Date r w -2-- ID Verification By /D a ____ Y,A5- Page 30 of 78 METHOD: SM 4500 S2- D ELEMENT ASSAY: Sulfide CLIENT: Duke Lab ID# 24832/833/834/835/836/837/€ Date: 5.22.1' 5 Time Analysis Begun 1400 Time Analysis Ended 1817 Analyst: KAM` 0900 ug STD STD SOLUTION ABS 0.00 0.000 1.00 0.098 2.50 0.226 5.00 0.426 7.50 0.607 10.00 0.778 ! ELEMENT ONE Wave Length 664 VC'rl- "Ury L11V11j_LUM I.UUU SPK LEVEL u 5 MAX ALIQUOT 10.00 Na2S•9H20 Lot # STANDARD conc(ppm) X 40721 Cal Std Lot: WC2-82-2 10 QC Std Lot: WC2-82-3 10 Page 1 of 8 lSTD ABSORPTION Y 0.800 0.700 0.800 -----"--'--- 0.800 Y D. .428 0.200 28 0.100 D.D00 000 ��BOU 8A0 8.00 woo 12W x Correlation 0.998667979 SAMPLE I.D. SAMP ABS ug PER ALIQUOT ALI in mL ANALYZED PREP VOL in mL ALI in mL TAKEN RESULTS ug/mL LESS THAN % SPK REC SPIKE LEVEL Std. B. 0.00 0 0.0000 10 10 10 < Std. B. 1.00 0.096 0.8053 10 10 10 < 81 % 1 Std. B. 2.50 0.225 2.5569 10 10 10 0.256 102% 2.5 Std. B. 5.00 0.441 1 5.4897 10 10 10 0.549 110% 5 Std. B. 7.50 0.61 7.7844 10 10 10 0.778 104% 7.5 Std. B. 10.00 0.772 9.9840 10 10 10 0.998 100% 10 LRB 0.00 0.0000 10 10 10 < LRB SPK 0.437 5.4354 10 10 10 0.544 109% 5.0 QC 0.434 5.3947 10 10 10 0.539 108% 5.0 24832 0.004 -0.4438 10 10 10 U:M. 24832 dup 0.004 -0.4438 10 10 10 < 0: ,.., NA 24832 spk 0.442 5.5033 10 10 10 0.550 110% 5.0 24833-1 0.009 -0.3759 10 10 10 24833-1 s k 0.434 5.3947 10 10 10 0.539 108% 5.0 24833-2 0.039 0.0314 10 10 10 24833-2 spk 0.433 5.3811 10 10 10 0.538 108% 5.0 24833-3 0.009 -0.3759 10 10 10 < 24833-3 spk 0.346 4.1998 10 10 10 0.420 84% 5.0 24833-4 0.005 -0.4302 10 10 10.O.1 24833-4 spk 0.354 4.3084 10 10 10 0.431 86% 5.0 24833-5 0.013 -0.3216 10 10 10 <.Q; 24833-5 spk 0.383 1 4.7022 10 10 10 0.470 94% 5.0 24833-6 0.031 -0.0772 10 10 10 < 24833-6 spk 0.329 3.9690 10 10 10 0.397 79% 5.0 24833-7 0.012 -0.3352 10 10 10;' 24833-7 spk 0.399 14.9194 10 10 10 0.492 98% 5.0 24833-8 0.003 -0.4574 10 10 10 24833-8 spk 0.433 5.3811 10 10 10 0.538 108% 5.0 Blank 0 0.0000 10 10 10 < QC 0.435 Submitted for QA/QC- 5.4082 10 Date: 5.22.15 10 By: (Print) 10 0.541 KAM 108% 5.0 (sign): Page 31 of 78 METHOD: SM 4500 S2- D ELEMENT ASSAY: Sulfide CLIENT: Duke Lab ID# 24832/833/834/835/836/837/83 Date: 15.22.15 Time Analysis Begun 11400 Time Analysis Ended 11817 X Y ug STD STD SOLUTION ABS 0.00 0.000 1.00 0.098 2.50 0.226 5.00 0.426 7.50 0.607 10.00 0.778 ELEMENT ONE Spectrophotometer UNITS OF ANSWER ug/mL Wave Length 664 DETECTION LIMIT u 1,000 SPK LEVEL u 5 MAX ALIQUOT 10.00 Na2S•9H2O Lot # STANDARD conc(ppm) X 40721 Cal Std Lot: WC2-82-2 10 QC Std Lot: WC2-82-3 10 Page 2 of 8 STD ABSORPTION Y i 0. 0.7W 0.800 --_--------- -- 0500 Y 0.400 26 0.200 .22 0.,00 0.000 �� 1000 i 2.00 4.00 6.00 800 low 12A0 x SAMPLE I.D. SAMP ABS ug PER ALIQUOT .. x ALI in mL PREP ANALYZED VOL in mL Sloe 0.077457143 Correlation 0.998667979 ALI in mL TAKEN RESULTS ug/mL LESS THAN % SPK REC SPIKE LEVEL Std. B. 0.00 0 0.0000 10 10 10 < Std. B. 1.00 0.096 0.8053 10 10 10 < 81 % 1 Std. B. 2.50 0.225 2.5569 10 10 10 0.256 102% 2.5 Std. B. 5.00 0.441 5.4897 10 10 10 0.549 110% 5 Std. B. 7.50 0.61 7.7844 10 10 10 0.778 104% 7.5 Std. B. 10.00 0.772 9.9840 10 10 10 0.998 100% 10 LRB 0.00 0.0000 10 10 10 < LRB SPK 0.437 5.4354 10 10 10 0.544 109% 5.0 QC 0.434 5.3947 10 10 10 0.539 108% 5.0 24834-1 0.009 -0.3759 10 10 10� 24834-1 s k 0.386 4.7429 10 10 10 0.474 95% 5.0 24834-2 0,016 -0.2809 10 10 10 < 24834-2 dup 0.019 -0.2402 10 10 10 < NA 24834-2 s k 0.330 3.9826 10 10 10 0.398 80% 5.0 24834-3 0.014 -0.3080 10 10 10 < Q:. - 24834-3 s k 0.378 4.6343 10 10 10 0.463 93% 5.0 24834-4 0.017 -0.2673 10 10 10 24834-4 s k 0.414 5.1231 10 10 10 0.512 102% 5.0 24834-5 0.009 -0.3759 10 10 10 777, ' 24834-5 s k 0.432 5.3675 10 10 10 0.537 107% 5.0 24834-6 0.003 -0.4574 10 10 10: t f,=� 24834-6 s k 0.432 5.3675 10 10 10 0.537 107% 5.0 24835-1 0.007 1 -0.4031 10 10 10 <101 24835-1 s k 0.404 4.9873 10 10 10 0.499 100% 5.0 24835-2 0.003 -0.4574 10 10 10 24835-2 s k 0.431 5.3539 10 10 10 0.535 107% 5.0 24835-3 0.005 -0.4302 10 10 10p 1; 24835-3 s k 0.433 5.3811 10 10 10 0.538 108% 5.0 Blank 0 0.0000 10 10 10 < QC 0.435 5.4082 10 10 10 0.541 108% 5.0 Submiffed for QA/QC- Date: 5.22.15 By: (Print) KAM (sign): r- Page 32 of 78 METHOD: SM 4500 S2- D ELEMENT ASSAY: Sulfide CLIENT: Duke Lab ID# 24832/833/834/835/836/837/838 Date: 5.22.15 Time Analysis Begun 1400 Time Analysis Ended 1817 X Y ug STD STD )LUTION ABS 0.00 0.000 1.00 0.098 2.50 0.226 5.00 0.426 7.50 0.607 10.00 0.778 ELEMENT ONE Wave Length 664 uG' F-1✓ I "-"vu u -i.uuu SPK LEVELLuM 5 MAX ALIQUOT 10.00 Na2S•9H2O Lot # STANDARD conc(ppm) X 40721 Cal Std Lot: WC2-82-2 10 QC Std Lot: WC2-82-3 10 Page 3 of 8 STD ABSORPTION Y U.300 0.fi00 ---- _-_ 0.500 D.a00 a D.300 0.200 -.-___- ___ 2 0.100 D.00D m ,M -4 6.00 0.00 1000 1200 I�! X �7-7- 07 PREP VOL in mL 10 Sloe 0.077457143 ALI in mL RESULTS TAKEN u /mL 10 < Correlation 0.998667979 LESS THAN SPIKE % SPK REC LEVEL SAMPLE I.D. Std. B. 0.00 SAMP ABS 0 ug PER ALIQUOT 0.0000 ALI in mL ANALYZED 10 Std. B. 1.00 Std. B. 2.50 Std. B. 5.00 Std. B. 7.50 Std. B. 10.00 0.096 0.225 0.441 0.61 0.772 0.8053 2.5569 5.4897 7.7844 9.9840 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 < 0.256 0.549 0.778 0.998 81 % 102% 110% 104% 100% 1 2.5 5 7.5 10 LRB 0.00 0.0000 10 10 10 < LRB SPK 0.437 5.4354 10 10 10 0.544 109% 5.0 QC 0.434 5.3947 10 10 10 0.539 108% 5.0 24835-4 0.005 -0.4302 10 10 10 24835-4 s k 0.435 5.4082 10 10 10 0.541 108% 5.0 4835-5 0.042 0.0721 10 10 10 �. 24835-5 s k 0.442 5.5033 10 10 10 0.550 110% 5.0 24835-6 0.008 -0.3895 10 10 10 < 24835-6 du 0.006 -0.4167 10 10 10 < NA 24835-6 s k 0.307 3.6703 10 10 10 0.367 73% 5.0 24835-7 0.01 -0.3624 10 10 10 24835-7 s k 0.377 1 4.6207 10 10 10 0.462 92% 5.0 24835-8 0.0041 -0.4438 10 10 10 < 24835-8 s k 0.317 3.8061 10 10 10 0.381 76% 5.0 24835-9 0.002 -0.4710 10 10 10� < p1F 24835-9 s k 0.445 5.5440 10 10 10 0.554 111 % 5.0 24836-1 0.011 -0.3488 10 10 10 24836-1 s k 0.413 5.1095 10 10 10 0.511 102% 5.0 24836-2 0.008 -0.3895 10 10 10 24836-2 s k 0.355 4.3220 10 10 10 0.432 86% 5.0 24836-3 0.006 -0.4167 10 10 10 24836-3 s k 0.452 5.6391 10 1 10 10 0.564 113% 5.0 Blank 0 0.0000 10 10 10 < QC 0.435 Submitted fOr QA/QC- 5.4082 10 Date: 5.22.15 10 By: (Print) 10 0.541 KAM 108% 5.0 (sign): Page 33 of 78 METHOD: SM 4500 S2- D ELEMENT ONE ELEMENT ASSAY: Sulfide Spectrophotometer Wave Length 664 UNITS OF ANSWER ug/mL DETECTION LIMIT u 1.000 CLIENT: Duke SPK LEVELLuM 5 Lab ID# 24832/833/834/835/836/837/838 MAX ALIQUOT _ 5.22.15 Na2S•9H2O Lot # STANDARD conc(ppm) 1400 40721 Cal Std Lot: WC2-82-2 1817 QC Std Lot: WC2-82-3 KAM Page 4 of 8 _ STD ABSORPTION Y 6.900 10.00 Date: X Time Analysis Begun 10 Time Analysis Ended 10 Analyst: Y X ug STD SOLUTION STD o.000 ABS 0.100 ---- - - - '- -- - -- -- - - - - -- -- - --- __o� 0.00 1.00 2.50 5.00 7.50 10.00 0.000 0800 oaoo 0.098 °°°° °� -..-z.en ---sao 0.226 0.426 6.+� 0.607 0.778 °°°° 0.00 2.00 400 6.00 Boo loon 12.00 X Sloe 0.077457143 Correlation 0.998667979 SAMPLE I.D. SAMP ABS ug PER ALIQUOT ALI in mL ANALYZED PREP VOL in mL ALI in mL TAKEN RESULTS ug/mL LESS THAN % SPK REC SPIKE LEVEL Std. B. 0.00 0 0.0000 10 10 10 < Std. B. 1.00 0.096 0.8053 10 10 10 < 81 % 1 Std. B. 2.50 0.225 2.5569 10 10 10 0.256 102% 2.5 Std. B. 5.00 0.441 5.4897 10 10 10 0.549 110% 5 Std. B. 7.50 0.61 7.7844 10 10 10 0.778 104% 7.5 Std. B. 10.00 0.772 9.9840 10 10 10 0.998 100% 10 LRB 0.00 0.0000 10 10 10 < LRB SPK 0.437 5.4354 10 10 10 0.544 109% 5.0 QC 0.434 5.3947 10 10 10 0.539 108% 5.0 24836-4 0.006 -0.4167 10 10 10 < O 24836-4 s k 0.408 5.0416 10 10 10 0.504 101 % 5.0 24836-5 0.011 -0.3488 10 10 10 < (� 24836-5 s k 0.43 5.3404 10 10 10 0.534 107% 5.0 24836-6 0.002 -0.4710 10 10 10 74�0� 24836-6 s k 0.419 5.1910 10 10 10 0.519 104% 5.0 24836-7 0.005 -0.4302 10 10 10 < 24836-7 dup 0.006 -0.4167 10 10 10 < NA 24836-7 s k 0.469 5.8699 10 10 10 0.587 117% 5.0 24836-8 0.005 -0.4302 10 10 10 < 24836-8 s k 0.326 3.9283 10 10 10 0.393 79% 5.0 24836-9 0.006 -0.4167 10 10 10 24836-9 spk 0.443 5.5169 10 10 10 0.552 110% 5.0 24836-10 0.011 -0.3488 10 10 10 24836-10 s k 0.442 5.5033 10 10 10 0.550 110% 5.0 24837-1 0.03 -0.0908 10 10 10 24837-1 s k 0.391 4.8108 10 10 10 0.481 96% 5.0 24837-2 0.045 0.1129 10 10 10 < 24837-2 s k 0.24 2.7606 10 10 10 0.276 55% 5.0 Blank 0 0.0000 10 10 10 < QC 0.432 5.3675 10 10 10 0.537 107% 5.0 Submitted for QA/QC- Date: 5.22.15 By: (Print) K:AM 04 (sign): Page 34 of 78 METHOD: SM 4500 S2- D ELEMENT ASSAY: Sulfide CLIENT: Duke Lab 1D# 24832/833/834/835/836/837/8, Date: 15.22.15 Time Analysis Begun 11400 Time AnaIvsIs Ended 11817 x Y ug STD STD SOLUTION ABS 0.00 0.000 1.00 0.098 2.50 0.226 5.00 0.426 7.50 0.607 10.00 0.778 ELEMENT ONE pectrophotometer Wave Length 664 UNITS OF ANSVY DETECTION LIMI SPK LEVEL,(gM Na2S.9H2O Lot # 40721 - --Page 5 of 8- MAX ALIQUOT STANDARD conc Cal Std Lot: QC Std Lot: STD ABSORPTIC 3pm) x WC2-82-2 10 WC2-82-3 10 -y ONO 0 70D U00 ------- 0,500 y 0. 0. 0.200 226 0100 0.000 0.00 2.00 4.00 800 sm 10 12M x 0, SAMPLE SAMP I.D. ABS F N ug PER ALIQUOT W ALI in mL ANALYZED PREP VOL in mL Sloe 0.077457143 p Correlation 0.998667979 ALI in mL TAKEN RESULTS ug/mL LESS THAN % SPK REC SPIKE LEVEL Std. B. 0.00 0 0.0000 10 10 10 Std. B. 1.00 0.096 0.8053 10 10 10 < 81% 1 Std. B. 2.50 0.225 2.5569 10 10 10 0.256 102% 2.5 Std. B. 5.00 0.441 5.4897 10 10 10 0.549 110% Std. B. 7.50 0.61 7.7844 10 10 10 0.778 104% 7.5 Std. B. 10.00 0.772 9.9840 10 10 10 0.998 100% 10 LRB 0.00 0.0000 10 10 10 < LRB SPK 0.437 5.4354 10 10 10 0.544 109% 5.0 QC 0.434 5.3947 10 10 10 0.539 108% 5.0 24837-3 0.01 -0.3624 10 10 10 24837-3 spk 0.376 4.6072 10 10 10 0.461 92% 5.0 24837-4 0.05 0.1808 10 10 10 < 24837-4 spk 0.229 2.6112 10 10 10 0.261 52% 5.0 24837-5 0,053 0.2215 10 10 10 < 24837-5 spk 0.212 2.3804 .10 10 10 0.238 48% 5.0 24837-6 0.005 -0.4302 10 10 10 24837-6 spk 0.42 5.2046 10 10 10 0.520 104% 5.0 24837-7 0.012 -0.3352 10 10 10 24837-7 du p 0.015 -0.2945 10 10 10 NA 24837-7 spk 0.385 4.7294 10 10 10 0.473 95% 5.0 24837-8 0.39 4.7972 10 10 10 0.480 24837-8 spk 0.686 8.8163 10 10 10 0.882 80% 5.0 24837-9 0.022 -0.1994 10 10 10 24837-9spk 0.352 4.2813 10 10 10 0.428 86% 5.0 24837-10 0.005 -0.4302 10 10 10 < 24837-10 spk 0.335 4.0505 10 10 10 0.405 81% 5.0 24838 0.009 -0.3759 10 10 10 < 24838 spk 0.012 -0.3352 .10 10 10 < -7% 5.0 1 Blank 0 0.0000 10 10 10 < QC 0.435 5.4082 10 10 10 0.541 108% 5.0 Submitted for QAIQC - Date: 5.22.15 By: (Print) KAM sign): Page 35 of 78 METHOD: SM 4500 S2- D ELEMENT ONE ELEMENT ASSAY: Sulfide Spectrophotometer Wave Length 664 UNITS OF ANSWER u /mL DETECTION LIMIT u 1.000 CLIENT: Duke SPK LEVEL u 5 Lab ID# 24832/833/834/835/836/837/838 MAX ALIQUOT 5.22.15 Na2S•9H2O Lot # STANDARD conc(ppm) 1400 40721 Cal Std Lot: WC2-82-2 1817 QC Std Lot: WC2-82-3 KAM Page 6 of 8 STD ABSORPTION 10.00 Date: X Time Analysis Begun 10 Time Analysis Ended 10 Analyst: Y - ug STD SOLUTION STD °600 j ABS 0.7W 0BM0. 0.00 1.00 2.50 5.00 7.50 10.00 0.000 0.098 o� 0.600 - - - -- -- -- - ----- - ----� = - - -z� - _°° -- - - -- ---- - - --- - -- - --- 0.226 0.426 0.200 0100 °°°° ---- - _ -- --- -- - - -- --- - --- - - - ---- - - , - - --- - 0.607 0.778 OUO 200 4,00 6.00 6.00 10.00 12M x ' ALI in mL PREP ANALYZED VOL in mL Sloe 0.077457143 Correlation 0.998667979 SAMPLE I.D. SAMP ABS ug PER ALIQUOT ALI in mL TAKEN RESULTS u /mL LESS THAN % SPK REC SPIKE LEVEL Std. B. 0.00 0 0.0000 10 10 10 < Std. B. 1.00 0.096 0.8053 10 10 10 < 81 % 1 Std. B. 2.50 0.225 2.5569 10 10 10 0.256 102% 2.5 Std. B. 5.00 0.441 5.4897 10 10 10 0.549 110% 5 Std. B. 7.50 0.61 7.7844 10 10 10 0.778 104% 7.5 Std. B. 10.00 0.772 9.9840 10 10 10 0.998 100% 10 LRB 0.00 0.0000 10 10 10 < LRB SPK 0.437 5.4354 10 10 10 0.544 109% 5.0 QC 0.434 5.3947 10 10 10 0.539 108% 5.0 24833-3 0.005 -0.4302 10 10 5 < 24833-3 spk 0.338 4.0912 10 10 5 0.818 82% 5.0 24833-6 0.006 -0.4167 10 10 5 < 24833-6 s k 0.333 4.0233 10 10 5 0.805 80% 5.0 24834-2 0.015 -0.2945 10 10 5:� 24834-2 s k 0.362 4.4171 10 10 5 0.883 88% 5.0 24835-6 0.002 -0.4710 10 10 5 < 24835-6 s k 0.286 3.3851 10 10 5 0.677 68% 5.0 24835-8 0 0.0000 10 10 5 < 24835-8 s k 0.321 3.8604 10 10 5 0.772 77% 5.0 24836-7 0.004 -0.4438 10 10 5 24836-7 dup 0.002 -0.4710 10 10 5 < 02` NA 24836-7 s k 0.371 4.5393 10 10 5 0.908 91 % 5.0 24836-8 0 0.0000 10 10 5 < 24836-8 s k 0.3 3.5752 10 10 5 0.715 72% 5.0 24837-2 0.034 -0.0365 10 10 5 < 24837-2 s k 0.271 3.1815 10 10 5 0.636 64% 5.0 24837-4 0.052 0.2079 10 10 5 < 24837-4 s k 0.162 1.7015 10 10 5 0.340 34% 5.0 24837-5 0.031 -0.0772 10 10 5 < 24837-5 s k 0.28 3.3037 10 10 5 0.661 66% 5.0 Blank 0 0.0000 10 10 10 < QC 0.435 Submitted for QA/QC- 5.4082 10 Date: 5.22.15 10 By: (Print) 10 0.541 K:AM 108% 5.0 (sign): Page 36 of 78 METHOD: SM 4500 S2- D ELEMENT ASSAY: Sulfide CLIENT: Duke Lab ID# 24832/833/834/835/836/837/838 Date: 15.22.15 Time Analysis Begun 1_1400 Time AnaIvsIs Ended 11817 x y ug STD STD SOLUTION ABS 0.00 0.000 1.00 0.098 2.50 0.226 5.00 0.426 7.50 0.607 10.00 0.778 ELEMENT ONE pectrophotometer Wave Length 664 UNITS OF ANSWER DETECTION LIMIT (ug) SPK LEVEL (u Na2S-9H2O Lot # 40721 -- Page-7 of 8_ MAX ALIQUOT STANDARD conc(ppm) Cal Std Lot: WC2-82-2 QC Std Lot: WC2-82-3 STD ABSORPTION .00 F-U77F- 0 50D y 0. 00 .42 0200 226 DAW O,ODO�� 0 is 7 50 DD 600 8.00 10.00 12M x SAMPLE 1. D. SAMP ABS ug PER ALI in mL PREP ALIQUOT ANALYZED VOL in mL -0.0000 Slope 0.077457143 Correlation '0.998667979 ALI in mL TAKEN RESULTS ug/mL LESS THAN % SPK REC SPIKE LEVEL Std. B. 0.00 0 10 10 10 < Std. B. 1.00 0.096 0.8053 10 10 10 < 81% 1 Std. B. 2.50 0.225 2.5569 10 10 10 0.256 102% 2.5 Std. B. 5.00 0.441 5.4897 10 10 10 0.549 110% Std. B. 7.50 0.61 7.7844 10 10 lb 0.778 104% 7.5 Std. B. 10.00 0.772 9.9840 10 10 10 0.998 100% 10 LRB 0.00 0.0000 10 10 10 < LRB SPK 0.437 5.4354 10 10 10 0.544 109% 5.0 QC 0.434 5.3947 10 10 10 0.539 108% 5.0 24837-8 0.26 3.0321 10 10 5- 0.606 24837-8 spk 0.556 7.0512 10 10 5 1.410 80% 5.0 24837-10 0.006 -0.4167 10 10 5 < 24837-10 spk 0.337 4.0776 10 10 5 0.816 82% 5.0 24838 0.003 -0.4574 10 10 1 < 24838 spk 0.249 2.8828 10 10 1 2.883 58% 5.0 24833-3 0.002 -0.4710 10 10 2 24833-3 spk 0.419 5.1910 10 10 2 2.596 104% 5.0 24833-6 0.005 -0.4302 10 10 2 24833-6spk 0.409 5.0552 10 10 2 2.528 101% 5.0 24835-6 0.002 -0.4710 10 10 2 24835-6 spk 0.375 4.5936 10 10 2 2.297 92% 5.0 24835-8 0 0.0000 10 10 2 < 24835-8 spk 0.411 5.0824 10 10 2 2.541 102% 5.0 24836-8 0.011 -0.3488 10 10 2 24836-8 spk 0.395 4.8651 10 10 2 2.433 97% 5.0 24837-2 0.008 -0.3895 10 10 2 24837-2 spk 0.396 4.8787 10 10 2 2.439 98% 5.0 24837-4 0.028 -0.1179 10 10 2 24837-4 spk 0.308 3.6839 1 10 10 2 1.842 74% 5.0 Blank 0.00 0.0000 =10 10 10 < QC 0.435 5.4082 1 10 10 10 1 0.541 108% 5.0 Submitted for ;-Q-AlQc - Date: 5.22.15 By: (Print) 1 KAM i(sign):77�77= Page 37 of 78 METHOD: SM 4500 S2- D ELEMENT ASSAY: Sulfide CLIENT: Duke Lab ID# 24832/833/834/835/836/837/83 Date: 5.22.15 Time Analysis Begun 1400 Time Analysis Ended 1817 Analyst: KAM ug STD 7 STD SOLUTION ABS 0.00 0.000 1.00 0.098 2.50 0.226 5.00 0.426 7.50 0.607 10.00 0.778 ELEMENT ONE Spectrophotometer UNITS OF ANSW Wave Length 664 DETECTION LIMI SPK LEVEL u MAX ALIQUOT Na2S•9H2O Lot # STANDARD conc 40721 lCal Std Lot: QC Std Lot: Page 8 of 8 ASTID ABSORPTIC o.w Boo ,0 °0 1200 x X 10 10 Y �000 ug PER ALI in mL ALIQUOT ANALYZED 0.0000 10 Sloe 0.077457143 Correlation 0.9986679791 SAMPLE I.D. Std. B. 0.00 SAMP ABS 0 PREP VOL in mL 10 ALI in mL TAKEN 10 RESULTS ug/mL < LESS THAN % SPK REC SPIKE LEVEL Std. B. 1.00 Std. B. 2.50 Std. B. 5.00 Std. B. 7.50 Std. B. 10.00 0.096 0.225 0.441 0.61 0.772 0.8053 2.5569 5.4897 7.7844 9.9840 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 < 0.256 0.549 0.778 0.998 81 % 102% 110% 104% 100% 1 2.5 5 7.5 10 LRB 0.00 0.0000 10 10 10 < LRB SPK 0.437 5.4354 10 1 10 10 0.544 109% 5.0 QC 0.434 5.3947 10 10 10 0.539 108% 5.0 24837-5 0.015 -0.2945 10 10 2 < p 24837-5 s k 0.389 4.7837 10 10 2 2.392 96% 5.0 24837-8 0.112 1.0226 10 10 2� 0 51,E 24837-8 s k 0.481 6.0328 10 10 2 3.016 100% 5.0 24837-10 0.005 -0.4302 10 10 2 24837-10 s k 0.383 4.7022 10 10 2 2.351 94% 5.0 24838 0.004 -0.4438 10 10 0.5 <:2b 24838 spk 0.302 3.6024 10 10 0.5 7.205 72% 5.0 24837 47777-7 0.017 -0.2673 10 10 1 24837-4 s k 0.385 4.7294 10 10 1 4.729 95% 5.0 Blank 0.000 0.0000 10 10 10 < QC 0.434 Submitted for QA/QC- 5.3947 10 Date: 5.22.15 10 By: (Print) 10 0.539 KAM 108% 5.0 (sign): �-- SHEALY ENVIRONMENTAL SERVICES, INC. Report of Analysis Duke Energy 13339 Hagers Ferry Rd Bldg 7405 Huntersville, NC 28078 Attention: Mary Ann Ogle Project Name: AB GW Assessment Water Project Number:J15050605 Lot Number:QE22018 Date Completed:06/02/2015 Grant Wilton Project Manager This report shall not be reproduced, except in its entirety, without the written approval of Shealy Environmental Services, Inc. The following non -paginated documents are considered part of this report: Chain of Custody Record and Sample Receipt Checklist. * QE2201 8* Shealy Environmental Services, Inc. Page: 1 of 24 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. SC DHEC No: 32010 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative Duke Energy Lot Number: QE22018 Project Name: AB GW Assessment Water Project Number: J15050605 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the Shealy Environmental Services, Inc. ("Shealy") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPS), and Shealy policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below. If you have any questions regarding this report please contact the Shealy Project Manager listed on the cover page Shealy Environmental Services, Inc. Page: 2 of 24 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. Sample Summary Duke Energy Lot Number: QE22018 Project Name: AB GW Assessment Water Project Number: J15050605 Sample Number Sample ID Matrix Date Sampled Date Received 001 2015015613 Aqueous 05/19/20151150 05/22/2015 002 2015015614 Aqueous 05/19/20151600 05/22/2015 003 2015015615 Aqueous 05/19/20151650 05/22/2015 004 2015015616 Aqueous 05/20/20151055 05/22/2015 005 2015015617 Aqueous 05/20/20151200 05/22/2015 006 2015015618 Aqueous 05/20/20151110 05/22/2015 007 2015015619 Aqueous 05/20/20151325 05/22/2015 008 2015015620 Aqueous 05/20/20151445 05/22/2015 009 2015015621 Aqueous 05/20/20151600 05/22/2015 010 2015015622 Aqueous 05/20/20151635 05/22/2015 (10 samples) Shealy Environmental Services, Inc. Page: 3 of 24 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. Executive Summary Duke Energy Lot Number: QE22018 Project Name: AB GW Assessment Water Project Number: J15050605 Sample Sample ID Matrix Parameter Method Result Q Units Page 001 2015015613 Aqueous Alkalinity SM 2320B- 140 mg/L 5 001 2015015613 Aqueous Bicarbonate Alkalinity SM 2320B- 140 mg/L 5 002 2015015614 Aqueous Alkalinity SM 2320B- 250 mg/L 7 002 2015015614 Aqueous Bicarbonate Alkalinity SM 2320B- 240 mg/L 7 004 2015015616 Aqueous Alkalinity SM 2320B- 84 mg/L 11 004 2015015616 Aqueous Bicarbonate Alkalinity SM 2320B- 84 mg/L 11 005 2015015617 Aqueous Alkalinity SM 2320B- 180 mg/L 13 005 2015015617 Aqueous Bicarbonate Alkalinity SM 2320B- 170 mg/L 13 005 2015015617 Aqueous Methane RSK - 175 11 ug/L 14 006 2015015618 Aqueous Alkalinity SM 2320B- 83 mg/L 15 006 2015015618 Aqueous Bicarbonate Alkalinity SM 2320B- 83 mg/L 15 007 2015015619 Aqueous Alkalinity SM 2320B- 170 mg/L 17 007 2015015619 Aqueous Bicarbonate Alkalinity SM 2320B- 160 mg/L 17 007 2015015619 Aqueous Methane RSK - 175 940 ug/L 18 008 2015015620 Aqueous Methane RSK - 175 30 ug/L 20 009 2015015621 Aqueous Alkalinity SM 2320B- 39 mg/L 21 009 2015015621 Aqueous Bicarbonate Alkalinity SM 2320B- 39 mg/L 21 (17 detections) Shealy Environmental Services, Inc. Page: 4 of 24 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals Client: Duke Energy Laboratory ID: QE22018-001 Description: 2015015613 Matrix: Aqueous Date Sampled:05/19/2015 1150 Project Name: AB GW Assessment Water Date Received:05/22/2015 Project Number: J15050605 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 05/29/2015 0117 HMA 76015 1 (Bicarbonate ) SM 2320B-2011 1 05/28/2015 0117 HMA 1 (Carbonate Al) SM 2320B-2011 1 05/28/2015 0117 HMA CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 140 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 140 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 5 of 24 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane Client: Duke Energy Laboratory ID: QE22018-001 Description: 2015015613 Matrix: Aqueous Date Sampled:05/19/2015 1150 Project Name: AB GW Assessment Water Date Received:05/22/2015 Project Number: J15050605 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 06/01/2015 1851 JJG 76279 CAS Analytical Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 10 ug/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 6 of 24 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals Client: Duke Energy Laboratory ID: QE22018-002 Description: 2015015614 Matrix: Aqueous Date Sampled:05/19/2015 1600 Project Name: AB GW Assessment Water Date Received:05/22/2015 Project Number: J15050605 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 05/29/2015 0125 HMA 76015 1 (Bicarbonate ) SM 2320B-2011 1 05/28/2015 0125 HMA 1 (Carbonate Al) SM 2320B-2011 1 05/28/2015 0125 HMA CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 250 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 240 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 7 of 24 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane Client: Duke Energy Laboratory ID: QE22018-002 Description: 2015015614 Matrix: Aqueous Date Sampled:05/19/2015 1600 Project Name: AB GW Assessment Water Date Received:05/22/2015 Project Number: J15050605 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 06/01/2015 1906 JJG 76279 CAS Analytical Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 10 ug/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 8 of 24 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals Client: Duke Energy Laboratory ID: QE22018-003 Description: 2015015615 Matrix: Aqueous Date Sampled:05/19/2015 1650 Project Name: AB GW Assessment Water Date Received:05/22/2015 Project Number: J15050605 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 05/30/2015 1554 HMA 76111 1 (Bicarbonate ) SM 2320B-2011 1 05/30/2015 1554 HMA 1 (Carbonate Al) SM 2320B-2011 1 05/30/2015 1554 HMA CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 ND 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 9 of 24 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane Client: Duke Energy Laboratory ID: QE22018-003 Description: 2015015615 Matrix: Aqueous Date Sampled:05/19/2015 1650 Project Name: AB GW Assessment Water Date Received:05/22/2015 Project Number: J15050605 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 06/01/2015 1917 JJG 76279 CAS Analytical Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 10 ug/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 10 of 24 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals Client: Duke Energy Laboratory ID: QE22018-004 Description: 2015015616 Matrix: Aqueous Date Sampled:05/20/2015 1055 Project Name: AB GW Assessment Water Date Received:05/22/2015 Project Number: J15050605 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 05/30/2015 1559 HMA 76111 1 (Bicarbonate ) SM 2320B-2011 1 05/30/2015 1559 HMA 1 (Carbonate Al) SM 2320B-2011 1 05/30/2015 1559 HMA CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 84 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 84 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 11 of 24 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane Client: Duke Energy Laboratory ID: QE22018-004 Description: 2015015616 Matrix: Aqueous Date Sampled:05/20/2015 1055 Project Name: AB GW Assessment Water Date Received:05/22/2015 Project Number: J15050605 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 06/01/2015 1931 JJG 76279 CAS Analytical Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 10 ug/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 12 of 24 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals Client: Duke Energy Laboratory ID: QE22018-005 Description: 2015015617 Matrix: Aqueous Date Sampled:05/20/2015 1200 Project Name: AB GW Assessment Water Date Received:05/22/2015 Project Number: J15050605 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 05/30/2015 1619 HMA 76111 1 (Bicarbonate ) SM 2320B-2011 1 05/30/2015 1619 HMA 1 (Carbonate Al) SM 2320B-2011 1 05/30/2015 1619 HMA CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 180 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 170 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 13 of 24 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane Client: Duke Energy Laboratory ID: QE22018-005 Description: 2015015617 Matrix: Aqueous Date Sampled:05/20/2015 1200 Project Name: AB GW Assessment Water Date Received:05/22/2015 Project Number: J15050605 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 06/01/2015 1942 JJG 76279 CAS Analytical Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 11 10 ug/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 14 of 24 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals Client: Duke Energy Laboratory ID: QE22018-006 Description: 2015015618 Matrix: Aqueous Date Sampled:05/20/2015 1110 Project Name: AB GW Assessment Water Date Received:05/22/2015 Project Number: J15050605 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 05/30/2015 1624 HMA 76111 1 (Bicarbonate ) SM 2320B-2011 1 05/30/2015 1624 HMA 1 (Carbonate Al) SM 2320B-2011 1 05/30/2015 1624 HMA CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 83 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 83 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 15 of 24 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane Client: Duke Energy Laboratory ID: QE22018-006 Description: 2015015618 Matrix: Aqueous Date Sampled:05/20/2015 1110 Project Name: AB GW Assessment Water Date Received:05/22/2015 Project Number: J15050605 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 06/01/2015 1956 JJG 76279 CAS Analytical Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 10 ug/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 16 of 24 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals Client: Duke Energy Laboratory ID: QE22018-007 Description: 2015015619 Matrix: Aqueous Date Sampled:05/20/2015 1325 Project Name: AB GW Assessment Water Date Received:05/22/2015 Project Number: J15050605 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 05/30/2015 1630 HMA 76111 1 (Bicarbonate ) SM 2320B-2011 1 05/30/2015 1630 HMA 1 (Carbonate Al) SM 2320B-2011 1 05/30/2015 1630 HMA CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 170 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 160 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 17 of 24 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane Client: Duke Energy Laboratory ID: QE22018-007 Description: 2015015619 Matrix: Aqueous Date Sampled:05/20/2015 1325 Project Name: AB GW Assessment Water Date Received:05/22/2015 Project Number: J15050605 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 2 RSK - 175 5 06/01/2015 2224 JJG 76279 CAS Analytical Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 940 50 ug/L 2 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 18 of 24 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals Client: Duke Energy Laboratory ID: QE22018-008 Description: 2015015620 Matrix: Aqueous Date Sampled:05/20/2015 1445 Project Name: AB GW Assessment Water Date Received:05/22/2015 Project Number: J15050605 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 05/30/2015 1633 HMA 76111 1 (Bicarbonate ) SM 2320B-2011 1 05/30/2015 1633 HMA 1 (Carbonate Al) SM 2320B-2011 1 05/30/2015 1633 HMA CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 ND 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 19 of 24 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane Client: Duke Energy Laboratory ID: QE22018-008 Description: 2015015620 Matrix: Aqueous Date Sampled:05/20/2015 1445 Project Name: AB GW Assessment Water Date Received:05/22/2015 Project Number: J15050605 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 06/01/2015 2024 JJG 76279 CAS Analytical Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 30 10 ug/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 20 of 24 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals Client: Duke Energy Laboratory ID: QE22018-009 Description: 2015015621 Matrix: Aqueous Date Sampled:05/20/2015 1600 Project Name: AB GW Assessment Water Date Received:05/22/2015 Project Number: J15050605 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 05/30/2015 1701 HMA 76111 1 (Bicarbonate ) SM 2320B-2011 1 05/30/2015 1701 HMA 1 (Carbonate Al) SM 2320B-2011 1 05/30/2015 1701 HMA CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 39 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 39 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 21 of 24 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane Client: Duke Energy Laboratory ID: QE22018-009 Description: 2015015621 Matrix: Aqueous Date Sampled:05/20/2015 1600 Project Name: AB GW Assessment Water Date Received:05/22/2015 Project Number: J15050605 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 06/01/2015 2034 JJG 76279 CAS Analytical Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 10 ug/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 22 of 24 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals Client: Duke Energy Laboratory ID: QE22018-010 Description: 2015015622 Matrix: Aqueous Date Sampled:05/20/2015 1635 Project Name: AB GW Assessment Water Date Received:05/22/2015 Project Number: J15050605 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 05/30/2015 1708 HMA 76111 1 (Bicarbonate ) SM 2320B-2011 1 05/30/2015 1708 HMA 1 (Carbonate Al) SM 2320B-2011 1 05/30/2015 1708 HMA CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 ND 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 23 of 24 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane Client: Duke Energy Laboratory ID: QE22018-010 Description: 2015015622 Matrix: Aqueous Date Sampled:05/20/2015 1635 Project Name: AB GW Assessment Water Date Received:05/22/2015 Project Number: J15050605 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 06/01/2015 2044 JJG 76279 CAS Analytical Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 10 ug/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 24 of 24 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 QC Summary Shealy Environmental Services, Inc. QC Data for Lot Number: QE22018 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals - Ii Sample ID: QQ76015-001 Matrix: Aqueous Batch: 76015 Analytical Method: SM 2320B-2011 Parameter Result Q Dil PQL Units Analysis Date Alkalinity ND 1 10 mg/L 05/28/2015 2226 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QE22018 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals - LCS Sample ID: QQ76015-002 Matrix: Aqueous Batch: 76015 Analytical Method: SM 2320B-2011 Spike Amount Result % Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Alkalinity 100 99 1 99 90-110 05/28/2015 2233 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QE22018 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals - MS Sample ID: QE22018-002MS Matrix: Aqueous Batch: 76015 Analytical Method: SM 2320B-2011 Sample Spike Amount Amount Result % Rec Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Alkalinity 250 100 290 N 1 47 70-130 05/29/2015 0132 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QE22018 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals - MSD Sample ID: QE22018-002MD Matrix: Aqueous Batch: 76015 Analytical Method: SM 2320B-2011 Sample Spike Amount Amount Result % Rec % RPD Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date Alkalinity 250 100 290 N 1 48 0.26 70-130 20 05/29/2015 0139 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QE22018 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals - Ii Sample ID: QQ76111-001 Matrix: Aqueous Batch:76111 Analytical Method: SM 2320B-2011 Parameter Result Q Dil PQL Units Analysis Date Alkalinity ND 1 10 mg/L 05/30/20151542 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QE22018 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals - LCS Sample ID: QQ76111-002 Matrix: Aqueous Batch:76111 Analytical Method: SM 2320B-2011 Spike Amount Result % Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Alkalinity 100 95 1 95 90-110 05/30/20151548 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QE22018 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals - MS Sample ID: QE22018-004MS Matrix: Aqueous Batch:76111 Analytical Method: SM 2320B-2011 Sample Spike Amount Amount Result % Rec Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Alkalinity 84 100 170 1 85 70-130 05/30/20151606 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QE22018 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals - MSD Sample ID: QE22018-004MD Matrix: Aqueous Batch:76111 Analytical Method: SM 2320B-2011 Sample Spike Amount Amount Result % Rec % RPD Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date Alkalinity 84 100 170 1 84 0.55 70-130 20 05/30/20151613 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QE22018 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals - MS Sample ID: QE22018-008MS Matrix: Aqueous Batch:76111 Analytical Method: SM 2320B-2011 Sample Spike Amount Amount Result % Rec Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Alkalinity ND 100 64 N 1 64 70-130 05/30/20151639 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QE22018 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals - MSD Sample ID: QE22018-008MD Matrix: Aqueous Batch:76111 Analytical Method: SM 2320B-2011 Sample Spike Amount Amount Result % Rec % RPD Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date Alkalinity ND 100 63 N 1 63 1.6 70-130 20 05/30/20151657 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QE22018 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane - MB Sample ID: QQ76279-001 Matrix: Aqueous Batch: 76279 Analytical Method: RSK - 175 Parameter Result Q Dil PQL Units Analysis Date Methane ND 1 10 ug/L 06/01/20151840 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QE22018 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane - LCS Sample ID: QQ76279-002 Matrix: Aqueous Batch: 76279 Analytical Method: RSK - 175 Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Methane 150 160 1 106 70-130 06/01/20151734 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QE22018 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane - LCSD Sample ID: QQ76279-003 Matrix: Aqueous Batch: 76279 Analytical Method: RSK - 175 Spike Amount Result % Rec % RPD Parameter (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date Methane 150 160 1 109 2.7 70-130 30 06/01/20151748 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QE22018 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. LU -wo Q, Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. Shasly Envimnu=1al Scrviccs, Inc. Documenc N%m*cr_ F-Anil ] 6 Icvizian Number 17 Pam I vF I R*aun Lble: I LAD7114 Mwitive Date.. )4!3LM1 Sample Receipt Checklist (SRC) Client: i CQoler b6pected by/datrn Lot N' }'EQ9Q tears ofreeeipt: BEST Clienl ❑ UPS C] FedUx Airborne 1-xp ❑ <) hor 'fie3 Q No 1. Were t,ustody seals present gil the woler? Yes 0 No 0 1 NA 1 if cmtody seals were wesent, were they intact and nabroken? Cooler ID/Original temperature upon receiptUerived (corrected) tear, lure upon r ipt: Dc Ur f or Niel hod, ❑ Temperature I k Against Bottles !lt Gun LI7 Mothod of coolant: ct Ioc ❑ Blue Ice El Dry Ice ?wle+rae Yes Lj Yes ❑ No Ll Iq If temperature of nny nooler exceeded 6.0$C, ,r A4 Project Mamffer notified? Pllr1 notified by SRC, phone, note (circle one), other_ (For c€ okra roccived via coruttrercip.l ccuricr, Plwls arc to be notified imrrrediately,) NA 4, b the coal nercial courier`s ackin s1i attached to this f +rrn? Yes-0 -L10 ❑ El [3' y5, -W, = pro custody cedulres re]in uishedlreceived follri,WeR Yes Elc Sa Were samples re[irsquished by clic It to commercial courim-9 Yes 12r❑ d. Were sample UN, IiPrecl on the COC? Yes ❑ 7. Were sample IDs listed on al spun le conWnm? Yes o ❑ Was 0011miion date & timc listod on the. CXX"? Yes o ❑ 9_ Was cckilEecttion date & titue. Batted on all sam le containers' Yes 9 ❑ 10, Did all container label in forrrlation , date, tiT=) allce widi the CUC? Yes o ❑ 11 _ Were tuts to k. ptrformcd listed on the, CX? Yesalla arrive ifl the er e<rntiiztcrs for each test Yes 13_ Did all containers arrive in good oondition tuibrok Lids o`n, etc')? Yes No 14, Weis adequate sample v+olumc available? Yes ❑ rklo Na(_] 15. Were all sgmples received 1withiti G2 the holding time ,or 48 hours, whIchrver come3 ftr.0 Yes No lb, Wei an s les containm ntissiit 7 YM © Yes P! 17. WvTv 4ht= any CXUU55 yarn lea not listed cm COC?- Were bubbles resent :� ea-szae'r -!a"or 6mm in dlamete to any VUA viols? No NA ❑ NA NA ' Y cs ❑ No ❑ �. Were ,all inet&1a*&G;HENUnutricn_t sate lcs rcc6ved at a ITof <2? Yes ❑ No Q 0. Were all cyanide andior sulfide sanVles received a1 it pR �,12? Yes ❑ No ❑ NA 21. W= all applicable NH3rTKMcyanidc,'phcuol (e0.2rn&1.) samples tree of S=dtia14hlonne? Yes hto ❑ NA 22 W= collectors tem1nemtures documented on the COC for NC saris les? Yes [3 two -::] 23. Were client reinatkVrequests (Le- requestorl dilutlotts, MS/MSD {dC3lgnanons, etc.. -)Co ciltranscribed flan the COC into the comment ser~tton in LIMS? Yes ❑ No 24_ Was the quote number used taken from the ceDtainer label? Sample Pre-5ervatiun (Mmt be complecod for any sampic(s) incorrectly preserved or with, headspace,j Samplc(s) were received incorr oily preserved and were adj ustrd accardin in sample mcG ,M2& with ?SO4AN03,,KC 1,NaOM2 ij SLIR SR # sample(s) were received x1ijth bubbles >6 mm in diarneter_ Saanple(s) were reccivod with TRC _0.2 rn If #21 is i fo SC Drinking Water Project Sampie ss) pH venfied to be r 2 by Mie., to !e 5 Wrrc nol roc uived at a pH of and were adjusted accoTdiriglX usLn& SKN ana le labels Applied bV' ''eril`ied key° Date. 57 Cotnmertts: Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 CRAM OF CUSTODY RECORD AND ANALYSIS REQ'UES`� FORM— .. _--i p Sy�T4#erl'a Ei�D _ .._.......�_. ��- —T— . a„k„ Fnarw "IAGal L*Daruv V i IilitRR LiSSt WiM' — p MIROL"ION DukipEra''pT WY{�YW]Iw11�WY'419rt .I F* j°y, — _ _.. �-- &I,�I ei i.abomtr9ly' �n r fr Y R? 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Tall 1.1 gel.l�raahad al' ' / P ,r1h ��Irr ,//r f �r a'9 ..} /4•'T _ 7 ' - %ime •%4 Days, " 7 0WjI ac+d Fhellr+q�ah+d �y f ray G -r)tt ' _ASAP — As, TENTS top 1GP, MS fTRMI k&. B+F, iC4 Ca, S[, [du., Me. WI. PG.. fit, 5 T1 ILL.I.. u' I P � • Add. Gnsl Vy'm APPly- IaLEM1ENTy by ICP {T1R.M1' Al. Ba. E, Fa_ Mel, Sty ZR ICP_utwitg a ad Ca. Mg, ' . Na N by 2U-1 Dlgeynlvetl IP9A.2ft ail metals lcpI IM*S.Hu U —