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Home My WebLink AboutNC0003433_J15050258 Report_20150902+ DUKE Analytical Laboratory 1 of71 ENERGY Order Number: Project Name: Customer Name(s): Customer Address: Lab Contact: Report Authorized By: (Signature) Program Comments: 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone:980-875-5245 Fax:980-875-4349 Order Summary Report J15050258 CAPE FEAR - AB GW ASSESSMENT SOIL Tim Hunsucker, Chris Suttell, Kathy Webb, John Toepfer Margaret Galvin -Karr MXG4644 (101161) 2015.06.1311:20:35 -04'00' Margaret Galvin -Karr Phone: 980-875-5219 Date: Please contact the Program Manager (Margaret Galvin -Karr) with any questions regarding this report. Data Flags & Calculations: 6/13/2015 Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Sample ID's & Descriptions: 2 of 71 Collection Sample ID Plant/Station Date and Time Collected By Sample Description 2015014094 Cape Fear 07-May-15 9:20 AM Chris S. Well ERB-22 (Sonic) 2015014095 Cape Fear 07-May-15 10:40 AM Chris S. Well ABMW-5 AB (3-5) 2015014096 Cape Fear 07-May-15 Chris S. Well Soil Dup-05 2015014097 Cape Fear 07-May-15 11:00 AM Chris S. Well ABMW-5 AB(23-24) 2015014098 Cape Fear 07-May-15 11:25 AM Chris S. Well ABMW-5SB(29-30) 5 Total Samples 3of71 Technical Validation Review Checklist: COC and .pdf report are in agreement with sample totals Yes No and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. ❑ Yes❑ No All laboratory QA/QC requirements are acceptable.❑ Yes ❑ No Report Sections Included: U Job Summary Report ❑ Sample Identification n Technical Validation of Data Package ❑ Analytical Laboratory Certificate of Analysis ❑ Analytical Laboratory QC Report Reviewed By: Date: Sub -contracted Laboratory Results ❑ Customer Specific Data Sheets, Reports, & Documentation ❑ Customer Database Entries 0 Chain of Custody [I/0] Electronic Data Deliverable (EDD) Sent Separately Certificate of Laboratory Analysis 4 of 71 This report shall not be reproduced, except in full. Order # J15050258 Site: Well ERB-22 (Sonic) Collection Date: 07-May-15 9:20 AM Analyte Result Units Qualifiers RDL DF METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Sample #: 2015014094 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050258 Site: Well ABMW-5 AB (3-5) Collection Date: 07-Mav-15 10:40 AM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 5of71 Sample #: 2015014095 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050258 Site: Well Soil Dup-05 Collection Date: 07-Mav-15 Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 6of71 Sample #: 2015014096 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050258 Site: Well ABMW-5 AB(23-24) Collection Date: 07-Mav-15 11:00 AM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 7of71 Sample #: 2015014097 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050258 Site: Well ABMW-5SB(29-30) Collection Date: 07-May-15 11:25 AM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 8of71 Sample #: 2015014098 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kigc&fte. Suite 100 Huntersville, INC 28078 (704)875-9092 June 09, 2015 Program Manager Duke Energy 13339 Hagers Ferry Road Bldg.7405 MG30A2 Huntersville, NC 28078 RE: Project: J 15050258 Pace Project No.: 92249487 Dear Program Manager: Enclosed are the analytical results for sample(s) received by the laboratory on May 12, 2015. The results relate only to the samples included in this report. Results reported herein conform to the most current TN standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Herring kevin.herring@pacelabs.com HORIZON Database Administrator Enclosures cc: Marge Galvin -Karr, Duke Energy Program Manager, Duke Energy Mary Ann Ogle, Duke Energy Rodney Wilke, Duke Energy p«FO REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, lqe� �� without the written consent of Pace Analytical Services, Inc.. BRAT, Page 1 of 62 lacmnalyfica( www.pacelabs.com Pace Analytical Services, Inc. 9800 Kiinffte. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15050258 Pace Project No.: 92249487 Minnesota Certification IDs 1700 Elm Street SE Suite 200, Minneapolis, MN 55414 A21-A Certification #: 2926.01 Alaska Certification #: UST-078 Alaska Certification #MN00064 Alabama Certification #40770 Arizona Certification #: AZ-0014 Arkansas Certification #: 88-0680 California Certification #: 01155CA Colorado Certification #Pace Connecticut Certification #: PH-0256 EPA Region 8 Certification #: 8TMS-L Florida/NELAP Certification #: E87605 Guam Certification #:14-008r Georgia Certification #: 959 Georgia EPD #: Pace Idaho Certification #: MN00064 Hawaii Certification #MN00064 Illinois Certification #: 200011 Indiana Certification#C-MN-01 Iowa Certification #: 368 Kansas Certification #: E-10167 Kentucky Dept of Envi. Protection - DW #90062 Kentucky Dept of Envi. Protection - WW #:90062 Louisiana DEQ Certification #: 3086 Louisiana DHH #: LA140001 Maine Certification #: 2013011 Maryland Certification #: 322 Michigan DEPH Certification #: 9909 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification #: 41320 Connecticut Certification #: PH-0216 Delaware Certification: FL NELAC Reciprocity Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Massachusetts Certification #: M-FL1264 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Green Bay Certification IDs 1241 Bellevue Street, Green Bay, WI 54302 Florida/NELAP Certification #: E87948 Illinois Certification #: 200050 Kentucky Certification #: 82 Louisiana Certification #: 04168 Minnesota Certification #: 055-999-334 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 CERTIFICATIONS Minnesota Certification #: 027-053-137 Mississippi Certification #: Pace Montana Certification #: MT0092 Nevada Certification #: MN_00064 Nebraska Certification #: Pace New Jersey Certification #: MN-002 New York Certification #: 11647 North Carolina Certification #: 530 North Carolina State Public Health #: 27700 North Dakota Certification #: R-036 Ohio EPA#: 4150 Ohio VAP Certification #: CL101 Oklahoma Certification #: 9507 Oregon Certification #: MN200001 Oregon Certification #: MN300001 Pennsylvania Certification #: 68-00563 Puerto Rico Certification Saipan (CNMI) #:MP0003 South Carolina #:74003001 Texas Certification #: T104704192 Tennessee Certification #: 02818 Utah Certification #: MN000642013-4 Virginia DGS Certification #: 251 Virginia/VELAP Certification #: Pace Washington Certification #: C486 West Virginia Certification #: 382 West Virginia DHHR #:9952C Wisconsin Certification #: 999407970 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 Nevada Certification: FL NELAC Reciprocity New Hampshire Certification #: 2958 New Jersey Certification #: FL765 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FLO1264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 Washington Certification #: C955 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity North Dakota Certification #: R-150 South Carolina Certification #: 83006001 Texas Certification #: T104704529-14-1 US Dept of Agriculture #: S-76505 Wisconsin Certification #: 405132750 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 2 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 )inlc&y fte. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15050258 Pace Project No.: 92249487 Asheville Certification IDs North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 CERTIFICATIONS West Virginia Certification #: 356 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 3 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 )iQg8y fte. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: J15050258 Pace Project No.: 92249487 Lab ID Sample ID Matrix Date Collected Date Received 92249487001 2015014094 Water 05/07/15 09:20 05/12/15 16:40 92249487002 2015014095 Solid 05/07/1510:40 05/12/15 16:40 92249487003 2015014096 Solid 05/07/15 00:00 05/12/15 16:40 92249487004 2015014097 Solid 05/07/1511:00 05/12/15 16:40 92249487005 2015014098 Solid 05107/1511:25 05/12/15 16:40 92249487006 2015014095 SPLP Water 05/07/15 10:40 05/12/15 16:40 92249487007 2015014096 SPLP Water 05/07/15 00:00 05/12/15 16:40 92249487008 2015014097 SPLP Water 05/07/15 11:00 05/12/15 16:40 92249487009 2015014098 SPLP Water 05/07/15 11:25 05/12/15 16:40 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 4 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 f ig'8y fte. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: J15050258 92249487 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92249487001 2015014094 EPA 6020A RJS 24 PASI-M EPA 7470A DM 1 PASI-M 92249487002 2015014095 EPA 6010 CKJ 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 MLO 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 300.0 AES2 1 PASI-A EPA 353.2 DMN 1 PASI-A SM 4500-CI-E SER 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92249487003 2015014096 EPA 6010 CKJ 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 MLO 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 300.0 AES2 1 PASI-A EPA 353.2 DMN 1 PASI-A SM 4500-CI-E SER 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92249487004 2015014097 EPA 6010 CKJ 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 MLO 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 300.0 AES2 1 PASI-A EPA 353.2 DMN 1 PASI-A SM 4500-CI-E SER 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92249487005 2015014098 EPA 6010 CKJ 16 PASI-0 EPA 6020 CRT 8 PASI-O REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 5 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffli '8ffte. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: J15050258 Pace Project No.: 92249487 Lab ID Sample ID Method Analysts Analytes Reported Laboratory EPA 7471 CKJ 1 PASI-O ASTM D2974-87 MLO 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 300.0 AES2 1 PASI-A EPA 353.2 DMN 1 PASI-A SM 4500-CI-E SER 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92249487006 2015014095 SPLP EPA 6020A TT3 24 PASI-M EPA 7470A WBS 1 PASI-M 92249487007 2015014096 SPLP EPA 6020A TT3 24 PASI-M EPA 7470A WBS 1 PASI-M 92249487008 2015014097 SPLP EPA 6020A TT3 24 PASI-M EPA 7470A WBS 1 PASI-M 92249487009 2015014098 SPLP EPA 6020A TT3 24 PASI-M EPA 7470A WBS 1 PASI-M REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 6 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kligc&yfte. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15050258 Pace Project No.: 92249487 Lab Sample ID Client Sample ID Method Parameters SUMMARY OF DETECTION Result Units Report Limit Analyzed 92249487001 2015014094 EPA 6020A Aluminum 347 ug/L 10.0 05/18/15 14:42 EPA 6020A Arsenic 0.69 ug/L 0.50 05/18/15 14:42 EPA 6020A Barium 5.9 ug/L 0.30 05/18/15 14:42 EPA 6020A Beryllium 0.10J ug/L 0.20 05/18/15 14:42 EPA 6020A Calcium 234 ug/L 40.0 05/18/15 14:42 EPA 6020A Chromium 1.0 ug/L 0.50 05/18/15 14:42 EPA 6020A Cobalt 1.2 ug/L 0.50 05/18/15 14:42 EPA 6020A Copper 1.4 ug/L 1.0 05/18/15 14:42 EPA 6020A Iron 526 ug/L 50.0 05/18/15 14:42 EPA 6020A Lead 0.43 ug/L 0.10 05/18/15 14:42 EPA 6020A Magnesium 68.9 ug/L 10.0 05/18/15 14:42 EPA 6020A Manganese 11.8 ug/L 0.50 05/18/15 14:42 EPA 6020A Molybdenum 0.24J ug/L 0.50 05/18/15 14:42 EPA 6020A Nickel 1.2 ug/L 0.50 05/18/15 14:42 EPA 6020A Potassium 95.5 ug/L 50.0 05/18/15 14:42 EPA 6020A Sodium 146 ug/L 50.0 05/18/15 14:42 EPA 6020A Strontium 3.5 ug/L 0.50 05/18/15 14:42 EPA 6020A Vanadium 0.891 ug/L 1.0 05/18/15 14:42 EPA 6020A Zinc 6.1 ug/L 5.0 05/18/15 14:42 92249487002 2015014095 EPA 6010 Aluminum 9100 mg/kg 26.8 05/22/15 20:19 EPA 6010 Barium 495 mg/kg 2.7 05/22/15 20:19 EPA 6010 Beryllium 2.4 mg/kg 0.27 05/22/15 20:19 EPA 6010 Calcium 2580 mg/kg 134 05/22/15 20:19 EPA 6010 Chromium 11.7 mg/kg 1.3 05/22/15 20:19 EPA 6010 Copper 27.2 mg/kg 1.3 05/22/15 20:19 EPA 6010 Iron 10400 mg/kg 10.7 05/22/15 20:19 EPA 6010 Magnesium 968 mg/kg 134 05/22/15 20:19 EPA 6010 Manganese 47.9 mg/kg 1.3 05/22/15 20:19 EPA 6010 Nickel 13.2 mg/kg 1.3 05/22/15 20:19 EPA 6010 Potassium 1440 mg/kg 268 05/22/15 20:19 EPA 6010 Sodium 314 mg/kg 268 05/22/15 20:19 EPA 6010 Strontium 197 mg/kg 2.7 05/22/15 20:19 EPA 6010 Zinc 10.4 mg/kg 5.4 05/22/15 20:19 EPA 6020 Arsenic 43.0 mg/kg 5.4 05/22/15 20:27 EPA 6020 Cobalt 6.8 mg/kg 5.4 05/22/15 20:27 EPA 6020 Lead 7.5 mg/kg 5.4 05/22/15 20:27 EPA 6020 Vanadium 29.7 mg/kg 5.4 05/22/15 20:27 EPA7471 Mercury 0.10 mg/kg 0.0085 05/21/1513:36 ASTM D2974-87 Percent Moisture 4.8 % 0.10 05/21/15 12:35 EPA 9045 pH at 25 Degrees C 6.8 Std. Units 0.10 05/20/15 13:20 EPA 300.0 Sulfate 6.2 mg/L 2.1 05/31/15 01:25 B EPA 9060 Total Organic Carbon 38800 mg/kg 4000 06/02/15 17:17 EPA 9060 Total Organic Carbon 36100 mg/kg 3920 06/02/15 17:23 EPA 9060 Total Organic Carbon 44200 mg/kg 4030 06/02/15 17:30 EPA 9060 Total Organic Carbon 41200 mg/kg 3960 06/02/15 17:36 EPA 9060 Mean Total Organic Carbon 40100 mg/kg 3980 06/02/15 17:17 REPORT OF LABORATORY ANALYSIS Qualifiers This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 7 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffli '8ffte. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15050258 Pace Project No.: 92249487 Lab Sample ID Client Sample ID Method Parameters SUMMARY OF DETECTION Result Units Report Limit Analyzed Qualifiers 92249487002 2015014095 EPA 9060 RSD% 8.6 % 06/02/15 17:17 92249487003 2015014096 EPA 6010 Aluminum 14700 mg/kg 39.3 05/22/15 20:23 EPA 6010 Barium 880 mg/kg 3.9 05/22/15 20:23 EPA 6010 Beryllium 3.8 mg/kg 0.39 05/22/15 20:23 EPA 6010 Boron 10.6J mg/kg 19.7 05/22/15 20:23 EPA 6010 Calcium 4120 mg/kg 197 05/22/15 20:23 EPA 6010 Chromium 19.1 mg/kg 2.0 05/22/15 20:23 EPA 6010 Copper 44.2 mg/kg 2.0 05/22/15 20:23 EPA 6010 Iron 19000 mg/kg 15.7 05/22/15 20:23 EPA 6010 Magnesium 1500 mg/kg 197 05/22/15 20:23 EPA 6010 Manganese 79.9 mg/kg 2.0 05/22/15 20:23 EPA 6010 Nickel 21.8 mg/kg 2.0 05/22/15 20:23 EPA 6010 Potassium 2220 mg/kg 393 05/22/15 20:23 EPA 6010 Sodium 514 mg/kg 393 05/22/15 20:23 EPA 6010 Strontium 333 mg/kg 3.9 05/22/15 20:23 EPA 6010 Zinc 16.6 mg/kg 7.9 05/22/15 20:23 EPA 6020 Arsenic 64.5 mg/kg 7.9 05/22/15 20:29 EPA 6020 Cobalt 11.7 mg/kg 7.9 05/22/15 20:29 EPA 6020 Lead 12.2 mg/kg 7.9 05/22/15 20:29 EPA 6020 Vanadium 50.3 mg/kg 7.9 05/22/15 20:29 EPA7471 Mercury 0.17 mg/kg 0.013 05/21/1513:38 ASTM D2974-87 Percent Moisture 35.9 % 0.10 05/21/15 12:35 EPA 9045 pH at 25 Degrees C 6.7 Std. Units 0.10 05/20/15 13:20 EPA 300.0 Sulfate 9.1 mg/L 3.1 05/31/15 01:38 B EPA 9060 Total Organic Carbon 56900 mg/kg 5970 06/02/15 17:43 EPA 9060 Total Organic Carbon 59600 mg/kg 5850 06/02/15 17:49 EPA 9060 Total Organic Carbon 61700 mg/kg 5810 06/02/15 17:55 EPA 9060 Total Organic Carbon 57400 mg/kg 5980 06/02/15 18:01 EPA 9060 Mean Total Organic Carbon 58900 mg/kg 5900 06/02/15 17:43 EPA 9060 RSD% 3.8 % 06/02/15 17:43 92249487004 2015014097 EPA 6010 Aluminum 11100 mg/kg 30.6 05/22/15 20:27 EPA 6010 Barium 645 mg/kg 3.1 05/22/15 20:27 EPA 6010 Beryllium 3.6 mg/kg 0.31 05/22/15 20:27 EPA 6010 Boron 15.7 mg/kg 15.3 05/22/15 20:27 EPA 6010 Calcium 3590 mg/kg 153 05/22/15 20:27 EPA 6010 Chromium 17.9 mg/kg 1.5 05/22/15 20:27 EPA 6010 Copper 39.2 mg/kg 1.5 05/22/15 20:27 EPA 6010 Iron 12700 mg/kg 12.2 05/22/15 20:27 EPA 6010 Magnesium 968 mg/kg 153 05/22/15 20:27 EPA 6010 Manganese 57.7 mg/kg 1.5 05/22/15 20:27 EPA 6010 Nickel 17.1 mg/kg 1.5 05/22/15 20:27 EPA 6010 Potassium 1490 mg/kg 306 05/22/15 20:27 EPA 6010 Sodium 314 mg/kg 306 05/22/15 20:27 EPA 6010 Strontium 316 mg/kg 3.1 05/22/15 20:27 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 8 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffli .8yfte. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15050258 Pace Project No.: 92249487 Lab Sample ID Client Sample ID Method Parameters SUMMARY OF DETECTION Result Units Report Limit Analyzed Qualifiers 92249487004 2015014097 EPA 6010 Zinc 16.5 mg/kg 6.1 05/22/15 20:27 EPA 6020 Arsenic 41.9 mg/kg 6.1 05/22/15 20:31 EPA 6020 Cobalt 8.2 mg/kg 6.1 05/22/15 20:31 EPA 6020 Lead 11.2 mg/kg 6.1 05/22/15 20:31 EPA 6020 Selenium 11.6 mg/kg 6.1 05/22/15 20:31 EPA 6020 Vanadium 37.5 mg/kg 6.1 05/22/15 20:31 EPA7471 Mercury 0.098 mg/kg 0.010 05/21/1513:40 ASTM D2974-87 Percent Moisture 21.4 % 0.10 05/21/15 12:35 EPA 9045 pH at 25 Degrees C 7.9 Std. Units 0.10 05/20/15 13:20 EPA 300.0 Sulfate 6.8 mg/L 2.5 05/31/15 01:52 EPA 9060 Total Organic Carbon 87000 mg/kg 5040 06/02/15 18:08 EPA 9060 Total Organic Carbon 49800 mg/kg 5180 06/02/15 18:15 EPA 9060 Total Organic Carbon 45800 mg/kg 5010 06/02/15 18:22 EPA 9060 Total Organic Carbon 52700 mg/kg 5100 06/02/15 18:29 EPA 9060 Mean Total Organic Carbon 58800 mg/kg 5080 06/02/15 18:08 EPA 9060 RSD% 32.3 % 06/02/15 18:08 92249487005 2015014098 EPA 6010 Aluminum 10900 mg/kg 31.7 05/22/15 20:31 EPA 6010 Barium 30.3 mg/kg 3.2 05/22/15 20:31 EPA 6010 Beryllium 0.43 mg/kg 0.32 05/22/15 20:31 EPA 6010 Calcium 1140 mg/kg 158 05/22/15 20:31 EPA 6010 Chromium 12.8 mg/kg 1.6 05/22/15 20:31 EPA 6010 Copper 8.1 mg/kg 1.6 05/22/15 20:31 EPA 6010 Iron 14600 mg/kg 12.7 05/22/15 20:31 EPA 6010 Magnesium 2290 mg/kg 158 05/22/15 20:31 EPA 6010 Manganese 316 mg/kg 1.6 05/22/15 20:31 EPA 6010 Nickel 5.8 mg/kg 1.6 05/22/15 20:31 EPA 6010 Potassium 607 mg/kg 317 05/22/15 20:31 EPA 6010 Strontium 16.6 mg/kg 3.2 05/22/15 20:31 EPA 6010 Zinc 23.6 mg/kg 6.3 05/22/15 20:31 EPA 6020 Cobalt 5.8J mg/kg 6.3 05/22/15 20:33 EPA 6020 Lead 3.6J mg/kg 6.3 05/22/15 20:33 EPA 6020 Vanadium 31.7 mg/kg 6.3 05/22/15 20:33 ASTM D2974-87 Percent Moisture 20.3 % 0.10 05/21/15 12:35 EPA 9045 pH at 25 Degrees C 6.0 Std. Units 0.10 05/20/15 13:20 EPA 300.0 Sulfate 12.9 mg/L 2.5 05/31/15 02:05 EPA 9056 Sulfate 243J mg/kg 314 05/17/15 15:20 EPA 9060 Total Organic Carbon 576J mg/kg 750 06/02/15 18:36 EPA 9060 Total Organic Carbon 570J mg/kg 760 06/02/15 18:41 EPA 9060 Total Organic Carbon 574J mg/kg 753 06/02/15 18:47 EPA 9060 Total Organic Carbon 562J mg/kg 759 06/02/15 18:53 EPA 9060 Mean Total Organic Carbon 571J mg/kg 755 06/02/15 18:36 EPA 9060 RSD% 1.0 % 06/02/15 18:36 92249487006 2015014095 SPLP EPA 6020A Aluminum 1210 ug/L 10.0 06/02/15 10:08 EPA6020A Antimony 1.3 ug/L 0.50 06/01/1517:35 REPORT OF LABORATORY ANALYSIS B B D3 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 9 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffli '8ffte. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15050258 Pace Project No.: 92249487 Lab Sample ID Client Sample ID Method Parameters SUMMARY OF DETECTION Result Units Report Limit Analyzed Qualifiers 92249487006 2015014095 SPLP EPA6020A Arsenic 50.4 ug/L 0.50 06/01/1517:35 EPA6020A Barium 237 ug/L 0.30 06/01/1517:35 EPA6020A Beryllium 0.42 ug/L 0.20 06/01/1517:35 EPA6020A Boron 64.6 ug/L 5.0 06/01/1517:35 EPA6020A Cadmium 0.077J ug/L 0.080 06/01/1517:35 EPA6020A Calcium 1770 ug/L 40.0 06/01/1517:35 EPA6020A Chromium 10.0 ug/L 0.50 06/01/1517:35 EPA6020A Cobalt 1.3 ug/L 0.50 06/01/1517:35 EPA6020A Copper 7.4 ug/L 1.0 06/01/1517:35 EPA6020A Iron 691 ug/L 50.0 06/01/1517:35 EPA6020A Lead 2.0 ug/L 0.10 06/01/1517:35 EPA6020A Magnesium 620 ug/L 10.0 06/01/1517:35 EPA6020A Manganese 10.9 ug/L 0.50 06/01/1517:35 EPA6020A Molybdenum 2.3 ug/L 0.50 06/01/1517:35 EPA6020A Nickel 3.4 ug/L 0.50 06/01/1517:35 EPA6020A Potassium 1400 ug/L 50.0 06/01/1517:35 EPA6020A Selenium 2.3 ug/L 0.50 06/01/1517:35 EPA6020A Sodium 1450 ug/L 50.0 06/01/1517:35 EPA6020A Strontium 100 ug/L 0.50 06/01/1517:35 EPA6020A Thallium 0.29 ug/L 0.10 06/01/1517:35 EPA6020A Vanadium 41.6 ug/L 1.0 06/01/1517:35 EPA6020A Zinc 54.3 ug/L 5.0 06/01/1517:35 EPA 7470A Mercury 0.0901 ug/L 0.20 05/30/15 17:50 92249487007 2015014096 SPLP EPA 6020A Aluminum 1300 ug/L 10.0 06/02/15 10:11 EPA6020A Antimony 1.3 ug/L 0.50 06/01/1517:37 EPA6020A Arsenic 52.6 ug/L 0.50 06/01/1517:37 EPA6020A Barium 244 ug/L 0.30 06/01/1517:37 EPA6020A Beryllium 0.42 ug/L 0.20 06/01/1517:37 EPA6020A Boron 73.2 ug/L 5.0 06/01/1517:37 EPA6020A Cadmium 0.064J ug/L 0.080 06/01/1517:37 EPA6020A Calcium 1760 ug/L 40.0 06/01/1517:37 EPA6020A Chromium 10.7 ug/L 0.50 06/01/1517:37 EPA6020A Cobalt 1.4 ug/L 0.50 06/01/1517:37 EPA6020A Copper 8.3 ug/L 1.0 06/01/1517:37 EPA6020A Iron 758 ug/L 50.0 06/01/1517:37 EPA6020A Lead 2.1 ug/L 0.10 06/01/1517:37 EPA6020A Magnesium 616 ug/L 10.0 06/01/1517:37 EPA6020A Manganese 12.2 ug/L 0.50 06/01/1517:37 EPA6020A Molybdenum 2.2 ug/L 0.50 06/01/1517:37 EPA6020A Nickel 4.3 ug/L 0.50 06/01/1517:37 EPA6020A Potassium 1390 ug/L 50.0 06/01/1517:37 EPA6020A Selenium 2.4 ug/L 0.50 06/01/1517:37 EPA6020A Sodium 1470 ug/L 50.0 06/01/1517:37 EPA6020A Strontium 102 ug/L 0.50 06/01/1517:37 EPA6020A Thallium 0.26 ug/L 0.10 06/01/1517:37 EPA6020A Vanadium 40.0 ug/L 1.0 06/01/1517:37 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 10 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffli ,8yfte. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15050258 Pace Project No.: 92249487 Lab Sample ID Client Sample ID Method Parameters SUMMARY OF DETECTION Result Units Report Limit Analyzed Qualifiers 92249487007 2015014096 SPLP EPA 6020A Zinc 56.6 ug/L 5.0 06/01/1517:37 EPA 7470A Mercury 0.0901 ug/L 0.20 05/30/15 17:52 92249487008 2015014097 SPLP EPA 6020A Aluminum 528 ug/L 10.0 06/02/15 10:13 EPA 6020A Antimony 1.9 ug/L 0.50 06/01/1517:40 EPA 6020A Arsenic 64.9 ug/L 0.50 06/01/1517:40 EPA 6020A Barium 349 ug/L 0.30 06/01/1517:40 EPA 6020A Boron 76.9 ug/L 5.0 06/01/1517:40 EPA 6020A Calcium 8310 ug/L 40.0 06/01/1517:40 EPA 6020A Chromium 1.5 ug/L 0.50 06/01/1517:40 EPA 6020A Copper 1.5 ug/L 1.0 06/01/1517:40 EPA 6020A Iron 15.3J ug/L 50.0 06/01/1517:40 EPA 6020A Lead 0.077J ug/L 0.10 06/01/1517:40 EPA 6020A Magnesium 706 ug/L 10.0 06/01/1517:40 EPA 6020A Manganese 7.2 ug/L 0.50 06/01/1517:40 EPA 6020A Molybdenum 5.0 ug/L 0.50 06/01/1517:40 EPA 6020A Nickel 0.65 ug/L 0.50 06/01/1517:40 EPA 6020A Potassium 177 ug/L 50.0 06/01/1517:40 EPA 6020A Selenium 87.7 ug/L 0.50 06/01/1517:40 EPA 6020A Sodium 1390 ug/L 50.0 06/01/1517:40 EPA 6020A Strontium 309 ug/L 0.50 06/01/1517:40 EPA 6020A Vanadium 39.8 ug/L 1.0 06/01/1517:40 EPA 6020A Zinc 33.9 ug/L 5.0 06/01/1517:40 92249487009 2015014098 SPLP EPA 6020A Aluminum 8.6J ug/L 10.0 06/02/15 10:16 EPA 6020A Barium 143 ug/L 0.30 06/01/1517:43 EPA 6020A Boron 68.6 ug/L 5.0 06/01/1517:43 EPA 6020A Calcium 2100 ug/L 40.0 06/01/1517:43 EPA 6020A Chromium 0.39J ug/L 0.50 06/01/1517:43 EPA 6020A Cobalt 2.8 ug/L 0.50 06/01/1517:43 EPA 6020A Copper 1.2 ug/L 1.0 06/01/1517:43 EPA 6020A Lead 0.046J ug/L 0.10 06/01/1517:43 EPA 6020A Magnesium 726 ug/L 10.0 06/01/1517:43 EPA 6020A Manganese 300 ug/L 0.50 06/01/1517:43 EPA 6020A Molybdenum 0.21J ug/L 0.50 06/01/1517:43 EPA 6020A Nickel 1.9 ug/L 0.50 06/01/1517:43 EPA 6020A Potassium 421 ug/L 50.0 06/01/1517:43 EPA 6020A Sodium 2420 ug/L 50.0 06/01/1517:43 EPA 6020A Strontium 50.6 ug/L 0.50 06/01/1517:43 EPA 6020A Zinc 38.0 ug/L 5.0 06/01/1517:43 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 11 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KPi ,8yfte. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15050258 Pace Project No.: 92249487 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: June 09, 2015 General Information: 4 samples were analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/24249 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92249061002 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1218699) • Aluminum • Barium • Iron • Manganese • MSD (Lab ID: 1218700) • Aluminum • Barium • Iron • Manganese Additional Comments: Batch Comments: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. • QC Batch: ICP / 14828 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 12 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 tf�nic&)rfte. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15050258 Pace Project No.: 92249487 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: June 09, 2015 General Information: 4 samples were analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/24250 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92249061002 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • MS (Lab ID: 1218705) • Antimony • Arsenic • Selenium • Vanadium • MSD (Lab ID: 1218706) • Antimony • Arsenic • Lead • Selenium • Thallium • Vanadium Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 13 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 1P2,8y ft.. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15050258 Pace Project No.: 92249487 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: June 09, 2015 Batch Comments: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. • QC Batch: ICPM / 9829 Analyte Comments: QC Batch: MPRP/24250 N2: The lab does not hold TNI accreditation for this parameter. •2015014095 (Lab ID:92249487002) • Antimony •2015014096 (Lab ID:92249487003) • Antimony •2015014097 (Lab ID:92249487004) • Antimony •2015014098 (Lab ID:92249487005) • Antimony • BLANK (Lab ID: 1218703) • Antimony • LCS (Lab ID: 1218704) • Antimony • MS (Lab ID: 1218705) • Antimony • MSD (Lab ID: 1218706) • Antimony REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 14 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KS,8y ft.. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15050258 Pace Project No.: 92249487 Method: EPA 6020A Description: 6020A MET ICPMS Client: Duke Energy Date: June 09, 2015 General Information: 5 samples were analyzed for EPA 6020A. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3020 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/54425 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92249061001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1966605) • Aluminum • MSD (Lab ID: 1966606) • Aluminum QC Batch: MPRP/54772 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 10308223006 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1980685) • Boron • Calcium • Magnesium • Potassium • Sodium REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 15 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 1P4,8y ft.. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15050258 Pace Project No.: 92249487 Method: EPA 6020A Description: 6020A MET ICPMS Client: Duke Energy Date: June 09, 2015 QC Batch: MPRP/54772 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 10308223006 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • Strontium • MSD (Lab ID: 1980686) • Aluminum • Calcium • Magnesium • Potassium • Sodium • Strontium Additional Comments: Analyte Comments: QC Batch: MPRP/54772 E: Analyte concentration exceeded the calibration range. The reported result is estimated. • MS (Lab ID: 1980685) • Calcium • Sodium • MSD (Lab ID: 1980686) • Calcium • Sodium REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 16 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KPi ,8yfte. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15050258 Pace Project No.: 92249487 Method: EPA 7470A Description: 7470A Mercury Client: Duke Energy Date: June 09, 2015 General Information: 5 samples were analyzed for EPA 7470A. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7470A with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 17 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 tf� ,8yfte. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15050258 Pace Project No.: 92249487 Method: EPA 7471 Description: 7471 Mercury Client: Duke Energy Date: June 09, 2015 General Information: 4 samples were analyzed for EPA 7471. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7471 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 18 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15050258 Pace Project No.: 92249487 Method: EPA 9045 Description: 9045 pH Soil Client: Duke Energy Date: June 09, 2015 General Information: 4 samples were analyzed for EPA 9045. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Duplicate Sample: All duplicate sample results were within method acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 19 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KPi ,8yfte. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15050258 Pace Project No.: 92249487 Method: EPA 300.0 Description: 300.0 IC Anions, SPLP Client: Duke Energy Date: June 09, 2015 General Information: 4 samples were analyzed for EPA 300.0. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. QC Batch: WETA/23110 B: Analyte was detected in the associated method blank. • BLANK for HBN 265986 [WETA/231 (Lab ID: 1471529) • Sulfate Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 20 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 tf� ,8yfte. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15050258 Pace Project No.: 92249487 Method: EPA 353.2 Description: 353.2 Nitrogen, NO2/NO3, SPLP Client: Duke Energy Date: June 09, 2015 General Information: 4 samples were analyzed for EPA 353.2. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 1-11: Analysis conducted outside the EPA method holding time. •2015014095 (Lab ID:92249487002) •2015014096 (Lab ID:92249487003) •2015014097 (Lab ID:92249487004) •2015014098 (Lab ID:92249487005) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: WETA/23177 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92249487002,92250202006 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1476702) • Nitrogen, Nitrate • MSD (Lab ID: 1476703) • Nitrogen, Nitrate Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 21 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 %,8yfte. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15050258 Pace Project No.: 92249487 Method: SM 4500-CI-E Description: 4500 Chloride, SPLP Client: Duke Energy Date: June 09, 2015 General Information: 4 samples were analyzed for SM 4500-CI-E. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: WETA/23132 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92249061003,92249703005 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1472685) • Chloride • MSD (Lab ID: 1472686) • Chloride Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 22 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 �nlc&)rfte. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15050258 Pace Project No.: 92249487 Method: EPA 9056 Description: 9056 IC Anions Client: Duke Energy Date: June 09, 2015 General Information: 4 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/46491 DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015014095 (Lab ID:92249487002) • Chloride • Sulfate •2015014096 (Lab ID:92249487003) • Chloride • Sulfate •2015014097 (Lab ID:92249487004) • Chloride • Sulfate •2015014098 (Lab ID:92249487005) • Chloride • Sulfate REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 23 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 1�2c8y ft.. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15050258 Pace Project No.: 92249487 Method: EPA 9056 Description: 9056 IC Anions 48hr Client: Duke Energy Date: June 09, 2015 General Information: 4 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 1-13: Sample was received or analysis requested beyond the recognized method holding time. •2015014095 (Lab ID:92249487002) •2015014096 (Lab ID:92249487003) •2015014097 (Lab ID:92249487004) •2015014098 (Lab ID:92249487005) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 24 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 t S,8y ft.. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15050258 Pace Project No.: 92249487 Method: EPA 9060 Description: Total Organic Carbon Quad Client: Duke Energy Date: June 09, 2015 General Information: 4 samples were analyzed for EPA 9060. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: This data package has been reviewed for quality and completeness and is approved for release. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 25 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K4'8y ft.. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15050258 Pace Project No.: 92249487 Sample: 2015014094 Lab ID: 92249487001 Collected: 05/07/15 09:20 Received: 05/12/15 16:40 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;I➢ZI7c\�i,I=11 l[99�� 6? Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470A Mercury Mercury Date: 06/09/2015 05:15 PM Analytical Method: EPA 6020A Preparation Method: EPA 3020 347 ug/L 10.0 3.0 1 05/15/1510:17 05/18/1514:42 7429-90-5 ND ug/L 0.50 0.15 1 05/15/1510:17 05/18/1514:42 7440-36-0 0.69 ug/L 0.50 0.11 1 05/15/1510:17 05/18/1514:42 7440-38-2 5.9 ug/L 0.30 0.081 1 05/15/1510:17 05/18/1514:42 7440-39-3 0.10J ug/L 0.20 0.067 1 05/15/1510:17 05/18/1514:42 7440-41-7 ND ug/L 5.0 1.1 1 05/15/1510:17 05/18/1514:42 7440-42-8 ND ug/L 0.080 0.024 1 05/15/1510:17 05/18/1514:42 7440-43-9 234 ug/L 40.0 16.0 1 05/15/1510:17 05/18/1514:42 7440-70-2 1.0 ug/L 0.50 0.17 1 05/15/1510:17 05/18/1514:42 7440-47-3 1.2 ug/L 0.50 0.13 1 05/15/1510:17 05/18/1514:42 7440-48-4 1.4 ug/L 1.0 0.21 1 05/15/1510:17 05/18/1514:42 7440-50-8 526 ug/L 50.0 13.7 1 05/15/1510:17 05/18/1514:42 7439-89-6 0.43 ug/L 0.10 0.046 1 05/15/1510:17 05/18/1514:42 7439-92-1 68.9 ug/L 10.0 3.2 1 05/15/1510:17 05/18/1514:42 7439-95-4 11.8 ug/L 0.50 0.24 1 05/15/1510:17 05/18/1514:42 7439-96-5 0.24J ug/L 0.50 0.094 1 05/15/1510:17 05/18/1514:42 7439-98-7 1.2 ug/L 0.50 0.16 1 05/15/1510:17 05/18/1514:42 7440-02-0 95.5 ug/L 50.0 11.7 1 05/15/1510:17 05/18/1514:42 7440-09-7 ND ug/L 0.50 0.20 1 05/15/1510:17 05/18/1514:42 7782-49-2 146 ug/L 50.0 16.3 1 05/15/1510:17 05/18/1514:42 7440-23-5 3.5 ug/L 0.50 0.13 1 05/15/1510:17 05/18/1514:42 7440-24-6 ND ug/L 0.10 0.015 1 05/15/1510:17 05/18/1514:42 7440-28-0 0.891 ug/L 1.0 0.28 1 05/15/1510:17 05/18/1514:42 7440-62-2 6.1 ug/L 5.0 2.4 1 05/15/1510:17 05/18/1514:42 7440-66-6 Analytical Method: EPA 7470A Preparation Method: EPA 7470A ND ug/L 0.20 0.022 1 05/15/15 09:10 05/15/15 11:22 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 26 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kai ,8ffte. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15050258 Pace Project No.: 92249487 Sample: 2015014095 Lab ID: 92249487002 Collected: 05/07/15 10:40 Received: 05/12/15 16:40 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Aluminum Barium Beryllium Boron Calcium Chromium Copper Iron Magnesium Manganese Molybdenum Nickel Potassium Sodium Strontium Zinc 6020 MET ICPMS Antimony Arsenic Cadmium Cobalt Lead Selenium Thallium Vanadium 7471 Mercury Mercury Percent Moisture Percent Moisture 9045 pH Soil pH at 25 Degrees C 300.0 IC Anions, SPLP Sulfate 353.2 Nitrogen, NO2/NO3, SPLP Nitrogen, Nitrate 4500 Chloride, SPLP Chloride Date: 06/09/2015 05:15 PM Analytical Method: EPA 6010 Preparation Method: EPA 3050 9100 mg/kg 26.8 13.4 5 05/20/15 14:45 05/22/15 20:19 7429-90-5 495 mg/kg 2.7 1.3 5 05/20/15 14:45 05/22/15 20:19 7440-39-3 2.4 mg/kg 0.27 0.13 5 05/20/15 14:45 05/22/15 20:19 7440-41-7 ND mg/kg 13.4 6.7 5 05/20/15 14:45 05/22/15 20:19 7440-42-8 2580 mg/kg 134 66.9 5 05/20/15 14:45 05/22/15 20:19 7440-70-2 11.7 mg/kg 1.3 0.67 5 05/20/15 14:45 05/22/15 20:19 7440-47-3 27.2 mg/kg 1.3 0.67 5 05/20/15 14:45 05/22/15 20:19 7440-50-8 10400 mg/kg 10.7 5.4 5 05/20/15 14:45 05/22/15 20:19 7439-89-6 968 mg/kg 134 66.9 5 05/20/15 14:45 05/22/15 20:19 7439-95-4 47.9 mg/kg 1.3 0.67 5 05/20/15 14:45 05/22/15 20:19 7439-96-5 ND mg/kg 2.7 1.3 5 05/20/15 14:45 05/22/15 20:19 7439-98-7 13.2 mg/kg 1.3 0.67 5 05/20/15 14:45 05/22/15 20:19 7440-02-0 1440 mg/kg 268 134 5 05/20/15 14:45 05/22/15 20:19 7440-09-7 314 mg/kg 268 134 5 05/20/15 14:45 05/22/15 20:19 7440-23-5 197 mg/kg 2.7 1.3 5 05/20/15 14:45 05/22/15 20:19 7440-24-6 10.4 mg/kg 5.4 2.7 5 05/20/15 14:45 05/22/15 20:19 7440-66-6 Analytical Method: EPA 6020 Preparation Method: EPA 3050 ND mg/kg 5.4 2.7 100 05/20/15 14:45 05/22/15 20:27 7440-36-0 43.0 mg/kg 5.4 2.7 100 05/20/15 14:45 05/22/15 20:27 7440-38-2 ND mg/kg 0.64 0.32 100 05/20/15 14:45 05/22/15 20:27 7440-43-9 6.8 mg/kg 5.4 2.7 100 05/20/15 14:45 05/22/15 20:27 7440-48-4 7.5 mg/kg 5.4 2.7 100 05/20/15 14:45 05/22/15 20:27 7439-92-1 ND mg/kg 5.4 2.7 100 05/20/15 14:45 05/22/15 20:27 7782-49-2 ND mg/kg 5.4 2.7 100 05/20/15 14:45 05/22/15 20:27 7440-28-0 29.7 mg/kg 5.4 2.7 100 05/20/15 14:45 05/22/15 20:27 7440-62-2 Analytical Method: EPA 7471 Preparation Method: EPA 7471 0.10 mg/kg 0.0085 0.0043 1 05/20/1514:50 05/21/1513:36 7439-97-6 Analytical Method: ASTM D2974-87 4.8 % 0.10 0.10 1 05/21/1512:35 Analytical Method: EPA 9045 6.8 Std. Units 0.10 0.10 1 05/20/15 13:20 N2 Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 05/15/15 01:35 6.2 mg/L 2.1 1.1 1 05/31 /15 01:25 14808-79-8 B Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 05/15/15 01:35 ND mg/L 0.21 0.21 1 06/09/1510:59 H1,M1 Analytical Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 05/15/15 01:35 ND mg/L 5.3 2.6 1 06/04/15 06:50 16887-00-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 27 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 %,8ffte. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15050258 Pace Project No.: 92249487 Sample: 2015014095 Lab ID: 92249487002 Collected: 05/07/15 10:40 Received: 05/12/15 16:40 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 261 130 5 05/17/1513:33 16887-00-6 D3 Sulfate ND mg/kg 261 130 5 05/17/1513:33 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 26.1 13.0 5 05/17/15 13:33 14797-55-8 H3 Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 38800 mg/kg 4000 2000 1 06/02/15 17:17 7440-44-0 Total Organic Carbon 36100 mg/kg 3920 1960 1 06/02/15 17:23 7440-44-0 Total Organic Carbon 44200 mg/kg 4030 2010 1 06/02/15 17:30 7440-44-0 Total Organic Carbon 41200 mg/kg 3960 1980 1 06/02/15 17:36 7440-44-0 Mean Total Organic Carbon 40100 mg/kg 3980 1990 1 06/02/15 17:17 7440-44-0 Surrogates RSD% 8.6 % 1 06/02/15 17:17 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/09/2015 05:15 PM without the written consent of Pace Analytical Services, Inc.. Page 28 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K3c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15050258 Pace Project No.: 92249487 Sample: 2015014096 Lab ID: 92249487003 Collected: 05/07/15 00:00 Received: 05/12/15 16:40 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Aluminum Barium Beryllium Boron Calcium Chromium Copper Iron Magnesium Manganese Molybdenum Nickel Potassium Sodium Strontium Zinc 6020 MET ICPMS Antimony Arsenic Cadmium Cobalt Lead Selenium Thallium Vanadium 7471 Mercury Mercury Percent Moisture Percent Moisture 9045 pH Soil pH at 25 Degrees C 300.0 IC Anions, SPLP Sulfate 353.2 Nitrogen, NO2/NO3, SPLP Nitrogen, Nitrate 4500 Chloride, SPLP Chloride Date: 06/09/2015 05:15 PM Analytical Method: EPA 6010 Preparation Method: EPA 3050 14700 mg/kg 39.3 19.7 5 05/20/15 14:45 05/22/15 20:23 7429-90-5 880 mg/kg 3.9 2.0 5 05/20/15 14:45 05/22/15 20:23 7440-39-3 3.8 mg/kg 0.39 0.20 5 05/20/15 14:45 05/22/15 20:23 7440-41-7 10.6J mg/kg 19.7 9.8 5 05/20/15 14:45 05/22/15 20:23 7440-42-8 4120 mg/kg 197 98.3 5 05/20/15 14:45 05/22/15 20:23 7440-70-2 19.1 mg/kg 2.0 0.98 5 05/20/15 14:45 05/22/15 20:23 7440-47-3 44.2 mg/kg 2.0 0.98 5 05/20/15 14:45 05/22/15 20:23 7440-50-8 19000 mg/kg 15.7 7.9 5 05/20/15 14:45 05/22/15 20:23 7439-89-6 1500 mg/kg 197 98.3 5 05/20/15 14:45 05/22/15 20:23 7439-95-4 79.9 mg/kg 2.0 0.98 5 05/20/15 14:45 05/22/15 20:23 7439-96-5 ND mg/kg 3.9 2.0 5 05/20/15 14:45 05/22/15 20:23 7439-98-7 21.8 mg/kg 2.0 0.98 5 05/20/15 14:45 05/22/15 20:23 7440-02-0 2220 mg/kg 393 197 5 05/20/15 14:45 05/22/15 20:23 7440-09-7 514 mg/kg 393 197 5 05/20/15 14:45 05/22/15 20:23 7440-23-5 333 mg/kg 3.9 2.0 5 05/20/15 14:45 05/22/15 20:23 7440-24-6 16.6 mg/kg 7.9 3.9 5 05/20/15 14:45 05/22/15 20:23 7440-66-6 Analytical Method: EPA 6020 Preparation Method: EPA 3050 ND mg/kg 7.9 3.9 100 05/20/15 14:45 05/22/15 20:29 7440-36-0 64.5 mg/kg 7.9 3.9 100 05/20/15 14:45 05/22/15 20:29 7440-38-2 ND mg/kg 0.94 0.47 100 05/20/15 14:45 05/22/15 20:29 7440-43-9 11.7 mg/kg 7.9 3.9 100 05/20/15 14:45 05/22/15 20:29 7440-48-4 12.2 mg/kg 7.9 3.9 100 05/20/15 14:45 05/22/15 20:29 7439-92-1 ND mg/kg 7.9 3.9 100 05/20/15 14:45 05/22/15 20:29 7782-49-2 ND mg/kg 7.9 3.9 100 05/20/15 14:45 05/22/15 20:29 7440-28-0 50.3 mg/kg 7.9 3.9 100 05/20/15 14:45 05/22/15 20:29 7440-62-2 Analytical Method: EPA 7471 Preparation Method: EPA 7471 0.17 mg/kg 0.013 0.0064 1 05/20/1514:50 05/21/1513:38 7439-97-6 Analytical Method: ASTM D2974-87 35.9 % 0.10 0.10 1 05/21/1512:35 Analytical Method: EPA 9045 6.7 Std. Units 0.10 0.10 1 05/20/15 13:20 N2 Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 05/15/15 01:35 9.1 mg/L 3.1 1.6 1 05/31 /15 01:38 14808-79-8 B Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 05/15/15 01:35 ND mg/L 0.31 0.31 1 06/09/1511:05 H1 Analytical Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 05/15/15 01:35 ND mg/L 7.8 3.9 1 06/04/15 06:50 16887-00-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 29 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 %,8f fte. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15050258 Pace Project No.: 92249487 Sample: 2015014096 Lab ID: 92249487003 Collected: 05/07/15 00:00 Received: 05/12/15 16:40 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 390 195 5 05/17/1514:37 16887-00-6 D3 Sulfate ND mg/kg 390 195 5 05/17/1514:37 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 39.0 19.5 5 05/17/15 14:37 14797-55-8 H3 Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 56900 mg/kg 5970 2990 1 06/02/15 17:43 7440-44-0 Total Organic Carbon 59600 mg/kg 5850 2920 1 06/02/15 17:49 7440-44-0 Total Organic Carbon 61700 mg/kg 5810 2900 1 06/02/15 17:55 7440-44-0 Total Organic Carbon 57400 mg/kg 5980 2990 1 06/02/15 18:01 7440-44-0 Mean Total Organic Carbon 58900 mg/kg 5900 2950 1 06/02/15 17:43 7440-44-0 Surrogates RSD% 3.8 % 1 06/02/15 17:43 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/09/2015 05:15 PM without the written consent of Pace Analytical Services, Inc.. Page 30 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kai ,8ffte. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15050258 Pace Project No.: 92249487 Sample: 2015014097 Lab ID: 92249487004 Collected: 05/07/15 11:00 Received: 05/12/15 16:40 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Aluminum Barium Beryllium Boron Calcium Chromium Copper Iron Magnesium Manganese Molybdenum Nickel Potassium Sodium Strontium Zinc 6020 MET ICPMS Antimony Arsenic Cadmium Cobalt Lead Selenium Thallium Vanadium 7471 Mercury Mercury Percent Moisture Percent Moisture 9045 pH Soil pH at 25 Degrees C 300.0 IC Anions, SPLP Sulfate 353.2 Nitrogen, NO2/NO3, SPLP Nitrogen, Nitrate 4500 Chloride, SPLP Chloride Date: 06/09/2015 05:15 PM Analytical Method: EPA 6010 Preparation Method: EPA 3050 11100 mg/kg 30.6 15.3 5 05/20/15 14:45 05/22/15 20:27 7429-90-5 645 mg/kg 3.1 1.5 5 05/20/15 14:45 05/22/15 20:27 7440-39-3 3.6 mg/kg 0.31 0.15 5 05/20/15 14:45 05/22/15 20:27 7440-41-7 15.7 mg/kg 15.3 7.6 5 05/20/15 14:45 05/22/15 20:27 7440-42-8 3590 mg/kg 153 76.4 5 05/20/15 14:45 05/22/15 20:27 7440-70-2 17.9 mg/kg 1.5 0.76 5 05/20/15 14:45 05/22/15 20:27 7440-47-3 39.2 mg/kg 1.5 0.76 5 05/20/15 14:45 05/22/15 20:27 7440-50-8 12700 mg/kg 12.2 6.1 5 05/20/15 14:45 05/22/15 20:27 7439-89-6 968 mg/kg 153 76.4 5 05/20/15 14:45 05/22/15 20:27 7439-95-4 57.7 mg/kg 1.5 0.76 5 05/20/15 14:45 05/22/15 20:27 7439-96-5 ND mg/kg 3.1 1.5 5 05/20/15 14:45 05/22/15 20:27 7439-98-7 17.1 mg/kg 1.5 0.76 5 05/20/15 14:45 05/22/15 20:27 7440-02-0 1490 mg/kg 306 153 5 05/20/15 14:45 05/22/15 20:27 7440-09-7 314 mg/kg 306 153 5 05/20/15 14:45 05/22/15 20:27 7440-23-5 316 mg/kg 3.1 1.5 5 05/20/15 14:45 05/22/15 20:27 7440-24-6 16.5 mg/kg 6.1 3.1 5 05/20/15 14:45 05/22/15 20:27 7440-66-6 Analytical Method: EPA 6020 Preparation Method: EPA 3050 ND mg/kg 6.1 3.1 100 05/20/15 14:45 05/22/15 20:31 7440-36-0 41.9 mg/kg 6.1 3.1 100 05/20/15 14:45 05/22/15 20:31 7440-38-2 ND mg/kg 0.73 0.37 100 05/20/15 14:45 05/22/15 20:31 7440-43-9 8.2 mg/kg 6.1 3.1 100 05/20/15 14:45 05/22/15 20:31 7440-48-4 11.2 mg/kg 6.1 3.1 100 05/20/15 14:45 05/22/15 20:31 7439-92-1 11.6 mg/kg 6.1 3.1 100 05/20/15 14:45 05/22/15 20:31 7782-49-2 ND mg/kg 6.1 3.1 100 05/20/15 14:45 05/22/15 20:31 7440-28-0 37.5 mg/kg 6.1 3.1 100 05/20/15 14:45 05/22/15 20:31 7440-62-2 Analytical Method: EPA 7471 Preparation Method: EPA 7471 0.098 mg/kg 0.010 0.0052 1 05/20/1514:50 05/21/1513:40 7439-97-6 Analytical Method: ASTM D2974-87 21.4 % 0.10 0.10 1 05/21/1512:35 Analytical Method: EPA 9045 7.9 Std. Units 0.10 0.10 1 05/20/15 13:20 N2 Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 05/15/15 01:35 6.8 mg/L 2.5 1.3 1 05/31 /15 01:52 14808-79-8 B Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 05/15/15 01:35 ND mg/L 0.25 0.25 1 06/09/1511:06 H1 Analytical Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 05/15/15 01:35 ND mg/L 6.4 3.2 1 06/04/15 06:51 16887-00-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 31 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 %,8ffte. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15050258 Pace Project No.: 92249487 Sample: 2015014097 Lab ID: 92249487004 Collected: 05/07/15 11:00 Received: 05/12/15 16:40 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 318 159 5 05/17/1514:58 16887-00-6 D3 Sulfate ND mg/kg 318 159 5 05/17/1514:58 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 31.8 15.9 5 05/17/15 14:58 14797-55-8 H3 Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 87000 mg/kg 5040 2520 1 06/02/15 18:08 7440-44-0 Total Organic Carbon 49800 mg/kg 5180 2590 1 06/02/15 18:15 7440-44-0 Total Organic Carbon 45800 mg/kg 5010 2500 1 06/02/15 18:22 7440-44-0 Total Organic Carbon 52700 mg/kg 5100 2550 1 06/02/15 18:29 7440-44-0 Mean Total Organic Carbon 58800 mg/kg 5080 2540 1 06/02/15 18:08 7440-44-0 Surrogates RSD% 32.3 % 1 06/02/15 18:08 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/09/2015 05:15 PM without the written consent of Pace Analytical Services, Inc.. Page 32 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 t�inic8y ft.. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15050258 Pace Project No.: 92249487 Sample: 2015014098 Lab ID: 92249487005 Collected: 05/07/15 11:25 Received: 05/12/15 16:40 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Aluminum Barium Beryllium Boron Calcium Chromium Copper Iron Magnesium Manganese Molybdenum Nickel Potassium Sodium Strontium Zinc 6020 MET ICPMS Antimony Arsenic Cadmium Cobalt Lead Selenium Thallium Vanadium 7471 Mercury Mercury Percent Moisture Percent Moisture 9045 pH Soil pH at 25 Degrees C 300.0 IC Anions, SPLP Sulfate 353.2 Nitrogen, NO2/NO3, SPLP Nitrogen, Nitrate 4500 Chloride, SPLP Chloride Date: 06/09/2015 05:15 PM Analytical Method: EPA 6010 Preparation Method: EPA 3050 10900 mg/kg 31.7 15.8 5 05/20/15 14:45 05/22/15 20:31 7429-90-5 30.3 mg/kg 3.2 1.6 5 05/20/15 14:45 05/22/15 20:31 7440-39-3 0.43 mg/kg 0.32 0.16 5 05/20/15 14:45 05/22/15 20:31 7440-41-7 ND mg/kg 15.8 7.9 5 05/20/15 14:45 05/22/15 20:31 7440-42-8 1140 mg/kg 158 79.1 5 05/20/15 14:45 05/22/15 20:31 7440-70-2 12.8 mg/kg 1.6 0.79 5 05/20/15 14:45 05/22/15 20:31 7440-47-3 8.1 mg/kg 1.6 0.79 5 05/20/15 14:45 05/22/15 20:31 7440-50-8 14600 mg/kg 12.7 6.3 5 05/20/15 14:45 05/22/15 20:31 7439-89-6 2290 mg/kg 158 79.1 5 05/20/15 14:45 05/22/15 20:31 7439-95-4 316 mg/kg 1.6 0.79 5 05/20/15 14:45 05/22/15 20:31 7439-96-5 ND mg/kg 3.2 1.6 5 05/20/15 14:45 05/22/15 20:31 7439-98-7 5.8 mg/kg 1.6 0.79 5 05/20/15 14:45 05/22/15 20:31 7440-02-0 607 mg/kg 317 158 5 05/20/15 14:45 05/22/15 20:31 7440-09-7 ND mg/kg 317 158 5 05/20/15 14:45 05/22/15 20:31 7440-23-5 16.6 mg/kg 3.2 1.6 5 05/20/15 14:45 05/22/15 20:31 7440-24-6 23.6 mg/kg 6.3 3.2 5 05/20/15 14:45 05/22/15 20:31 7440-66-6 Analytical Method: EPA 6020 Preparation Method: EPA 3050 ND mg/kg 6.3 3.2 100 05/20/15 14:45 05/22/15 20:33 7440-36-0 ND mg/kg 6.3 3.2 100 05/20/15 14:45 05/22/15 20:33 7440-38-2 ND mg/kg 0.76 0.38 100 05/20/15 14:45 05/22/15 20:33 7440-43-9 5.8J mg/kg 6.3 3.2 100 05/20/15 14:45 05/22/15 20:33 7440-48-4 3.6J mg/kg 6.3 3.2 100 05/20/15 14:45 05/22/15 20:33 7439-92-1 ND mg/kg 6.3 3.2 100 05/20/15 14:45 05/22/15 20:33 7782-49-2 ND mg/kg 6.3 3.2 100 05/20/15 14:45 05/22/15 20:33 7440-28-0 31.7 mg/kg 6.3 3.2 100 05/20/15 14:45 05/22/15 20:33 7440-62-2 Analytical Method: EPA 7471 Preparation Method: EPA 7471 ND mg/kg 0.0097 0.0049 1 05/20/1514:50 05/21/1513:46 7439-97-6 Analytical Method: ASTM D2974-87 20.3 % 0.10 0.10 1 05/21/1512:35 Analytical Method: EPA 9045 6.0 Std. Units 0.10 0.10 1 05/20/15 13:20 N2 Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 05/15/15 01:35 12.9 mg/L 2.5 1.3 1 05/31 /15 02:05 14808-79-8 B Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 05/15/15 01:35 ND mg/L 0.25 0.25 1 06/09/1511:10 H1 Analytical Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 05/15/15 01:35 ND mg/L 6.3 3.1 1 06/04/15 06:52 16887-00-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 33 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 t ,Q,8y ft.. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15050258 Pace Project No.: 92249487 Sample: 2015014098 Lab ID: 92249487005 Collected: 05/07/15 11:25 Received: 05/12/15 16:40 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 314 157 5 05/17/1515:20 16887-00-6 D3 Sulfate 243J mg/kg 314 157 5 05/17/1515:20 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 31.4 15.7 5 05/17/15 15:20 14797-55-8 H3 Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 576J mg/kg 750 375 1 06/02/15 18:36 7440-44-0 Total Organic Carbon 570J mg/kg 760 380 1 06/02/15 18:41 7440-44-0 Total Organic Carbon 574J mg/kg 753 377 1 06/02/15 18:47 7440-44-0 Total Organic Carbon 562J mg/kg 759 379 1 06/02/15 18:53 7440-44-0 Mean Total Organic Carbon 571J mg/kg 755 378 1 06/02/15 18:36 7440-44-0 Surrogates RSD% 1.0 % 1 06/02/15 18:36 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/09/2015 05:15 PM without the written consent of Pace Analytical Services, Inc.. Page 34 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 %'8ffte. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15050258 Pace Project No.: 92249487 Sample: 2015014095 SPLP Lab ID: 92249487006 Collected: 05/07/15 10:40 Received: 05/12/15 16:40 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;T➢Z17c\�iil=11 a Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470A Mercury Mercury Date: 06/09/2015 05:15 PM Analytical Method: EPA 6020A Preparation Method: EPA 3020 1210 ug/L 10.0 3.0 1 05/31/15 05:35 06/02/15 10:08 7429-90-5 1.3 ug/L 0.50 0.15 1 05/31/15 05:35 06/01/15 17:35 7440-36-0 50.4 ug/L 0.50 0.11 1 05/31/15 05:35 06/01/15 17:35 7440-38-2 237 ug/L 0.30 0.081 1 05/31/15 05:35 06/01/15 17:35 7440-39-3 0.42 ug/L 0.20 0.067 1 05/31/15 05:35 06/01/15 17:35 7440-41-7 64.6 ug/L 5.0 1.1 1 05/31/15 05:35 06/01/15 17:35 7440-42-8 0.077J ug/L 0.080 0.024 1 05/31/15 05:35 06/01/15 17:35 7440-43-9 1770 ug/L 40.0 16.0 1 05/31/15 05:35 06/01/15 17:35 7440-70-2 10.0 ug/L 0.50 0.17 1 05/31/15 05:35 06/01/15 17:35 7440-47-3 1.3 ug/L 0.50 0.13 1 05/31/15 05:35 06/01/15 17:35 7440-48-4 7.4 ug/L 1.0 0.21 1 05/31/15 05:35 06/01/15 17:35 7440-50-8 691 ug/L 50.0 13.7 1 05/31/15 05:35 06/01/15 17:35 7439-89-6 2.0 ug/L 0.10 0.046 1 05/31/15 05:35 06/01/15 17:35 7439-92-1 620 ug/L 10.0 3.2 1 05/31/15 05:35 06/01/15 17:35 7439-95-4 10.9 ug/L 0.50 0.24 1 05/31/15 05:35 06/01/15 17:35 7439-96-5 2.3 ug/L 0.50 0.094 1 05/31/15 05:35 06/01/15 17:35 7439-98-7 3.4 ug/L 0.50 0.16 1 05/31/15 05:35 06/01/15 17:35 7440-02-0 1400 ug/L 50.0 11.7 1 05/31/15 05:35 06/01/15 17:35 7440-09-7 2.3 ug/L 0.50 0.20 1 05/31/15 05:35 06/01/15 17:35 7782-49-2 1450 ug/L 50.0 16.3 1 05/31/15 05:35 06/01/15 17:35 7440-23-5 100 ug/L 0.50 0.13 1 05/31/15 05:35 06/01/15 17:35 7440-24-6 0.29 ug/L 0.10 0.015 1 05/31/15 05:35 06/01/15 17:35 7440-28-0 41.6 ug/L 1.0 0.28 1 05/31/15 05:35 06/01/15 17:35 7440-62-2 54.3 ug/L 5.0 2.4 1 05/31/15 05:35 06/01/15 17:35 7440-66-6 Analytical Method: EPA 7470A Preparation Method: EPA 7470A 0.0901 ug/L 0.20 0.022 1 05/29/1517:52 05/30/1517:50 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 35 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 %'8ffte. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15050258 Pace Project No.: 92249487 Sample: 2015014096 SPLP Lab ID: 92249487007 Collected: 05/07/15 00:00 Received: 05/12/15 16:40 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;T➢Z17c\�iil=11 a Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470A Mercury Mercury Date: 06/09/2015 05:15 PM Analytical Method: EPA 6020A Preparation Method: EPA 3020 1300 ug/L 10.0 3.0 1 05/31/15 05:35 06/02/15 10:11 7429-90-5 1.3 ug/L 0.50 0.15 1 05/31/15 05:35 06/01/15 17:37 7440-36-0 52.6 ug/L 0.50 0.11 1 05/31/15 05:35 06/01/15 17:37 7440-38-2 244 ug/L 0.30 0.081 1 05/31/15 05:35 06/01/15 17:37 7440-39-3 0.42 ug/L 0.20 0.067 1 05/31/15 05:35 06/01/15 17:37 7440-41-7 73.2 ug/L 5.0 1.1 1 05/31/15 05:35 06/01/15 17:37 7440-42-8 0.064J ug/L 0.080 0.024 1 05/31/15 05:35 06/01/15 17:37 7440-43-9 1760 ug/L 40.0 16.0 1 05/31/15 05:35 06/01/15 17:37 7440-70-2 10.7 ug/L 0.50 0.17 1 05/31/15 05:35 06/01/15 17:37 7440-47-3 1.4 ug/L 0.50 0.13 1 05/31/15 05:35 06/01/15 17:37 7440-48-4 8.3 ug/L 1.0 0.21 1 05/31/15 05:35 06/01/15 17:37 7440-50-8 758 ug/L 50.0 13.7 1 05/31/15 05:35 06/01/15 17:37 7439-89-6 2.1 ug/L 0.10 0.046 1 05/31/15 05:35 06/01/15 17:37 7439-92-1 616 ug/L 10.0 3.2 1 05/31/15 05:35 06/01/15 17:37 7439-95-4 12.2 ug/L 0.50 0.24 1 05/31/15 05:35 06/01/15 17:37 7439-96-5 2.2 ug/L 0.50 0.094 1 05/31/15 05:35 06/01/15 17:37 7439-98-7 4.3 ug/L 0.50 0.16 1 05/31/15 05:35 06/01/15 17:37 7440-02-0 1390 ug/L 50.0 11.7 1 05/31/15 05:35 06/01/15 17:37 7440-09-7 2.4 ug/L 0.50 0.20 1 05/31/15 05:35 06/01/15 17:37 7782-49-2 1470 ug/L 50.0 16.3 1 05/31/15 05:35 06/01/15 17:37 7440-23-5 102 ug/L 0.50 0.13 1 05/31/15 05:35 06/01/15 17:37 7440-24-6 0.26 ug/L 0.10 0.015 1 05/31/15 05:35 06/01/15 17:37 7440-28-0 40.0 ug/L 1.0 0.28 1 05/31/15 05:35 06/01/15 17:37 7440-62-2 56.6 ug/L 5.0 2.4 1 05/31/15 05:35 06/01/15 17:37 7440-66-6 Analytical Method: EPA 7470A Preparation Method: EPA 7470A 0.0901 ug/L 0.20 0.022 1 05/29/1517:52 05/30/1517:52 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 36 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 %'8ffte. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15050258 Pace Project No.: 92249487 Sample: 2015014097 SPLP Lab ID: 92249487008 Collected: 05/07/15 11:00 Received: 05/12/15 16:40 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;T➢Z17c\�iil=11 a Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470A Mercury Mercury Date: 06/09/2015 05:15 PM Analytical Method: EPA 6020A Preparation Method: EPA 3020 528 ug/L 10.0 3.0 1 05/31/15 05:35 06/02/15 10:13 7429-90-5 1.9 ug/L 0.50 0.15 1 05/31/15 05:35 06/01/15 17:40 7440-36-0 64.9 ug/L 0.50 0.11 1 05/31/15 05:35 06/01/15 17:40 7440-38-2 349 ug/L 0.30 0.081 1 05/31/15 05:35 06/01/15 17:40 7440-39-3 ND ug/L 0.20 0.067 1 05/31/15 05:35 06/01/15 17:40 7440-41-7 76.9 ug/L 5.0 1.1 1 05/31/15 05:35 06/01/15 17:40 7440-42-8 ND ug/L 0.080 0.024 1 05/31/15 05:35 06/01/15 17:40 7440-43-9 8310 ug/L 40.0 16.0 1 05/31/15 05:35 06/01/15 17:40 7440-70-2 1.5 ug/L 0.50 0.17 1 05/31/15 05:35 06/01/15 17:40 7440-47-3 ND ug/L 0.50 0.13 1 05/31/15 05:35 06/01/15 17:40 7440-48-4 1.5 ug/L 1.0 0.21 1 05/31/15 05:35 06/01/15 17:40 7440-50-8 15.3J ug/L 50.0 13.7 1 05/31/15 05:35 06/01/15 17:40 7439-89-6 0.077J ug/L 0.10 0.046 1 05/31/15 05:35 06/01/15 17:40 7439-92-1 706 ug/L 10.0 3.2 1 05/31/15 05:35 06/01/15 17:40 7439-95-4 7.2 ug/L 0.50 0.24 1 05/31/15 05:35 06/01/15 17:40 7439-96-5 5.0 ug/L 0.50 0.094 1 05/31/15 05:35 06/01/15 17:40 7439-98-7 0.65 ug/L 0.50 0.16 1 05/31/15 05:35 06/01/15 17:40 7440-02-0 177 ug/L 50.0 11.7 1 05/31/15 05:35 06/01/15 17:40 7440-09-7 87.7 ug/L 0.50 0.20 1 05/31/15 05:35 06/01/15 17:40 7782-49-2 1390 ug/L 50.0 16.3 1 05/31/15 05:35 06/01/15 17:40 7440-23-5 309 ug/L 0.50 0.13 1 05/31/15 05:35 06/01/15 17:40 7440-24-6 ND ug/L 0.10 0.015 1 05/31/15 05:35 06/01/15 17:40 7440-28-0 39.8 ug/L 1.0 0.28 1 05/31/15 05:35 06/01/15 17:40 7440-62-2 33.9 ug/L 5.0 2.4 1 05/31/15 05:35 06/01/15 17:40 7440-66-6 Analytical Method: EPA 7470A Preparation Method: EPA 7470A ND ug/L 0.20 0.022 1 05/29/1517:52 05/30/1517:54 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 37 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 %'8ffte. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15050258 Pace Project No.: 92249487 Sample: 2015014098 SPLP Lab ID: 92249487009 Collected: 05/07/15 11:25 Received: 05/12/15 16:40 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;T➢Z17c\�iil=11 a Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470A Mercury Mercury Date: 06/09/2015 05:15 PM Analytical Method: EPA 6020A Preparation Method: EPA 3020 8.6J ug/L 10.0 3.0 1 05/31/15 05:35 06/02/15 10:16 7429-90-5 ND ug/L 0.50 0.15 1 05/31/15 05:35 06/01/15 17:43 7440-36-0 ND ug/L 0.50 0.11 1 05/31/15 05:35 06/01/15 17:43 7440-38-2 143 ug/L 0.30 0.081 1 05/31/15 05:35 06/01/15 17:43 7440-39-3 ND ug/L 0.20 0.067 1 05/31/15 05:35 06/01/15 17:43 7440-41-7 68.6 ug/L 5.0 1.1 1 05/31/15 05:35 06/01/15 17:43 7440-42-8 ND ug/L 0.080 0.024 1 05/31/15 05:35 06/01/15 17:43 7440-43-9 2100 ug/L 40.0 16.0 1 05/31/15 05:35 06/01/15 17:43 7440-70-2 0.39J ug/L 0.50 0.17 1 05/31/15 05:35 06/01/15 17:43 7440-47-3 2.8 ug/L 0.50 0.13 1 05/31/15 05:35 06/01/15 17:43 7440-48-4 1.2 ug/L 1.0 0.21 1 05/31/15 05:35 06/01/15 17:43 7440-50-8 ND ug/L 50.0 13.7 1 05/31/15 05:35 06/01/15 17:43 7439-89-6 0.046J ug/L 0.10 0.046 1 05/31/15 05:35 06/01/15 17:43 7439-92-1 726 ug/L 10.0 3.2 1 05/31/15 05:35 06/01/15 17:43 7439-95-4 300 ug/L 0.50 0.24 1 05/31/15 05:35 06/01/15 17:43 7439-96-5 0.21J ug/L 0.50 0.094 1 05/31/15 05:35 06/01/15 17:43 7439-98-7 1.9 ug/L 0.50 0.16 1 05/31/15 05:35 06/01/15 17:43 7440-02-0 421 ug/L 50.0 11.7 1 05/31/15 05:35 06/01/15 17:43 7440-09-7 ND ug/L 0.50 0.20 1 05/31/15 05:35 06/01/15 17:43 7782-49-2 2420 ug/L 50.0 16.3 1 05/31/15 05:35 06/01/15 17:43 7440-23-5 50.6 ug/L 0.50 0.13 1 05/31/15 05:35 06/01/15 17:43 7440-24-6 ND ug/L 0.10 0.015 1 05/31/15 05:35 06/01/15 17:43 7440-28-0 ND ug/L 1.0 0.28 1 05/31/15 05:35 06/01/15 17:43 7440-62-2 38.0 ug/L 5.0 2.4 1 05/31/15 05:35 06/01/15 17:43 7440-66-6 Analytical Method: EPA 7470A Preparation Method: EPA 7470A ND ug/L 0.20 0.022 1 05/29/1517:52 05/30/1517:56 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 38 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Iic&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050258 Pace Project No.: 92249487 QC Batch: MERP/13557 Analysis Method: EPA 7470A QC Batch Method: EPA 7470A Analysis Description: 7470A Mercury Water Associated Lab Samples: 92249487001 METHOD BLANK: 1966620 Matrix: Water Associated Lab Samples: 92249487001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury ug/L ND 0.20 05/15/1510:43 LABORATORY CONTROL SAMPLE: 1966621 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 5 4.9 98 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1966707 1966708 MS MSD 92249477011 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 5 5 4.7 4.8 94 97 80-120 3 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/09/2015 05:15 PM without the written consent of Pace Analytical Services, Inc.. Page 39 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Iigc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050258 Pace Project No.: 92249487 QC Batch: MERP/13691 Analysis Method: EPA 7470A QC Batch Method: EPA 7470A Analysis Description: 7470A Mercury Water Associated Lab Samples: 92249487006, 92249487007, 92249487008, 92249487009 METHOD BLANK: 1978382 Matrix: Water Associated Lab Samples: 92249487006, 92249487007, 92249487008, 92249487009 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury ug/L ND 0.20 05/30/1517:23 LABORATORY CONTROL SAMPLE: 1978383 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 5 4.8 96 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1979809 1979810 MS MSD 10307933003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 5 5 4.8 4.6 96 93 80-120 3 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/09/2015 05:15 PM without the written consent of Pace Analytical Services, Inc.. Page 40 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050258 Pace Project No.: 92249487 QC Batch: MERP/5748 Analysis Method: EPA 7471 QC Batch Method: EPA 7471 Analysis Description: 7471 Mercury Associated Lab Samples: 92249487002, 92249487003, 92249487004, 92249487005 METHOD BLANK: 1218709 Matrix: Solid Associated Lab Samples: 92249487002, 92249487003, 92249487004, 92249487005 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury mg/kg ND 0.0081 05/21/1512:58 LABORATORY CONTROL SAMPLE: 1218710 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury mg/kg .08 0.080 100 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1218711 1218712 MS MSD 92249061002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury mg/kg 0.037 .0954 .0943 0.13 0.12 94 86 80-120 7 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/09/2015 05:15 PM without the written consent of Pace Analytical Services, Inc.. Page 41 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Iji g8yfte. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050258 Pace Project No.: 92249487 QC Batch: MPRP/24249 Analysis Method: EPA 6010 QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid Associated Lab Samples: 92249487002, 92249487003, 92249487004, 92249487005 METHOD BLANK: 1218697 Matrix: Solid Associated Lab Samples: 92249487002, 92249487003, 92249487004, 92249487005 Blank Reporting Parameter Units Result Limit Analyzed Aluminum mg/kg ND 5.1 05/22/1518:46 Barium mg/kg ND 0.51 05/22/1518:46 Beryllium mg/kg ND 0.051 05/22/1518:46 Boron mg/kg ND 2.5 05/22/1518:46 Calcium mg/kg ND 25.5 05/22/1518:46 Chromium mg/kg ND 0.25 05/22/1518:46 Copper mg/kg ND 0.25 05/22/1518:46 Iron mg/kg ND 2.0 05/22/1518:46 Magnesium mg/kg ND 25.5 05/22/1518:46 Manganese mg/kg ND 0.25 05/22/1518:46 Molybdenum mg/kg ND 0.51 05/22/1518:46 Nickel mg/kg ND 0.25 05/22/1518:46 Potassium mg/kg ND 50.9 05/22/1518:46 Sodium mg/kg ND 50.9 05/22/1518:46 Strontium mg/kg ND 0.51 05/22/1518:46 Zinc mg/kg ND 1.0 05/22/1518:46 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 1218698 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Aluminum mg/kg 130 131 101 80-120 Barium mg/kg 13 13.2 102 80-120 Beryllium mg/kg 1.3 1.3 103 80-120 Boron mg/kg 130 131 101 80-120 Calcium mg/kg 649 653 101 80-120 Chromium mg/kg 13 13.2 102 80-120 Copper mg/kg 13 12.9 100 80-120 Iron mg/kg 130 131 101 80-120 Magnesium mg/kg 649 649 100 80-120 Manganese mg/kg 13 13.1 101 80-120 Molybdenum mg/kg 13 12.8 98 80-120 Nickel mg/kg 13 13.0 101 80-120 Potassium mg/kg 649 635 98 80-120 Sodium mg/kg 649 671 104 80-120 Strontium mg/kg 13 12.8 99 80-120 Zinc mg/kg 64.9 65.7 101 80-120 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/09/2015 05:15 PM without the written consent of Pace Analytical Services, Inc.. Page 42 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 1jiT igy fte. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050258 Pace Project No.: 92249487 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1218699 1218700 MS MSD 92249061002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum mg/kg 9000 149 151 13700 13800 3150 3180 75-125 0 20 M1 Barium mg/kg 68.8 14.9 15.1 90.2 88.7 142 133 75-125 2 20 M1 Beryllium mg/kg 0.46 1.49 1.49 1.8 1.9 92 95 75-125 2 20 Boron mg/kg ND 149 151 128 132 84 87 75-125 3 20 Calcium mg/kg 301 749 751 1080 1080 104 104 75-125 0 20 Chromium mg/kg 11.4 14.9 15.1 26.1 27.9 98 110 75-125 7 20 Copper mg/kg 7.7 14.9 15.1 22.0 22.8 96 100 75-125 3 20 Iron mg/kg 9460 149 151 10000 10500 384 687 75-125 4 20 M1 Magnesium mg/kg 1110 749 751 1890 1900 104 105 75-125 0 20 Manganese mg/kg 693 14.9 15.1 665 729 -182 241 75-125 9 20 M1 Molybdenum mg/kg ND 14.9 15.1 12.1 12.7 79 82 75-125 4 20 Nickel mg/kg 4.2 14.9 15.1 19.2 19.5 100 102 75-125 2 20 Potassium mg/kg 534 749 751 1380 1410 113 116 75-125 2 20 Sodium mg/kg ND 749 751 754 704 93 87 75-125 7 20 Strontium mg/kg 5.7 14.9 15.1 21.2 21.3 103 104 75-125 0 20 Zinc mg/kg 21.4 74.9 75.1 94.7 96.7 98 100 75-125 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/09/2015 05:15 PM without the written consent of Pace Analytical Services, Inc.. Page 43 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 I Qgigyft.. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050258 Pace Project No.: 92249487 QC Batch: MPRP/24250 Analysis Method: EPA 6020 QC Batch Method: EPA 3050 Analysis Description: 6020 MET SOLID Associated Lab Samples: 92249487002, 92249487003, 92249487004, 92249487005 METHOD BLANK: 1218703 Matrix: Solid Associated Lab Samples: 92249487002, 92249487003, 92249487004, 92249487005 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Antimony mg/kg ND 0.051 05/22/1519:44 N2 Arsenic mg/kg ND 0.051 05/22/1519:44 Cadmium mg/kg ND 0.0061 05/22/1519:44 Cobalt mg/kg ND 0.051 05/22/1519:44 Lead mg/kg ND 0.051 05/22/1519:44 Selenium mg/kg ND 0.051 05/22/1519:44 Thallium mg/kg ND 0.051 05/22/1519:44 Vanadium mg/kg ND 0.051 05/22/1519:44 LABORATORY CONTROL SAMPLE: Parameter 1218704 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Antimony mg/kg 2.5 2.5 102 80-120 N2 Arsenic mg/kg 2.5 2.6 103 80-120 Cadmium mg/kg .25 0.25 100 80-120 Cobalt mg/kg 2.5 2.5 102 80-120 Lead mg/kg 2.5 2.5 101 80-120 Selenium mg/kg 2.5 2.5 101 80-120 Thallium mg/kg 2.5 2.5 103 80-120 Vanadium mg/kg 2.5 2.5 101 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1218705 1218706 MS MSD 92249061002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony mg/kg ND 2.87 2.87 ND ND 63 52 75-125 20 M6, N2 Arsenic mg/kg ND 2.87 2.87 3.3J 3.OJ 68 55 75-125 20 M6 Cadmium mg/kg ND .287 .287 ND ND 112 80 75-125 20 Cobalt mg/kg 5.9 2.87 2.87 8.8 8.2 101 79 75-125 7 20 Lead mg/kg 5AJ 2.87 2.87 8.0 7.4 93 69 75-125 8 20 M6 Selenium mg/kg ND 2.87 2.87 3.1J 3.OJ 29 27 75-125 20 M6 Thallium mg/kg ND 2.87 2.87 2.9J ND 85 74 75-125 20 M6 Vanadium mg/kg 17.6 2.87 2.87 19.7 17.9 74 11 75-125 9 20 M6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/09/2015 05:15 PM without the written consent of Pace Analytical Services, Inc.. Page 44 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 I Sgigyft.. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050258 Pace Project No.: 92249487 QC Batch: MPRP/54425 Analysis Method: EPA 6020A QC Batch Method: EPA 3020 Analysis Description: 6020A Water UPD4 Associated Lab Samples: 92249487001 METHOD BLANK: 1966603 Associated Lab Samples: 92249487001 Parameter Units Aluminum ug/L Antimony ug/L Arsenic ug/L Barium ug/L Beryllium ug/L Boron ug/L Cadmium ug/L Calcium ug/L Chromium ug/L Cobalt ug/L Copper ug/L Iron ug/L Lead ug/L Magnesium ug/L Manganese ug/L Molybdenum ug/L Nickel ug/L Potassium ug/L Selenium ug/L Sodium ug/L Strontium ug/L Thallium ug/L Vanadium ug/L Zinc ug/L Matrix: Water Blank Result Reporting Limit Analyzed ND 10.0 05/18/1513:36 ND 0.50 05/18/1513:36 ND 0.50 05/18/1513:36 ND 0.30 05/18/1513:36 ND 0.20 05/18/1513:36 ND 5.0 05/18/1513:36 ND 0.080 05/18/1513:36 ND 40.0 05/18/1513:36 ND 0.50 05/18/1513:36 ND 0.50 05/18/1513:36 ND 1.0 05/18/1513:36 ND 50.0 05/18/1513:36 ND 0.10 05/18/1513:36 ND 10.0 05/18/1513:36 ND 0.50 05/18/1513:36 ND 0.50 05/18/1513:36 ND 0.50 05/18/1513:36 ND 50.0 05/18/1513:36 ND 0.50 05/18/1513:36 ND 50.0 05/18/1513:36 ND 0.50 05/18/1513:36 ND 0.10 05/18/1513:36 ND 1.0 05/18/1513:36 ND 5.0 05/18/1513:36 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 1966604 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Aluminum ug/L 80 75.6 94 80-120 Antimony ug/L 80 77.8 97 80-120 Arsenic ug/L 80 76.4 96 80-120 Barium ug/L 80 76.0 95 80-120 Beryllium ug/L 80 76.9 96 80-120 Boron ug/L 80 73.1 91 80-120 Cadmium ug/L 80 77.0 96 80-120 Calcium ug/L 1000 1020 102 80-120 Chromium ug/L 80 77.4 97 80-120 Cobalt ug/L 80 75.8 95 80-120 Copper ug/L 80 75.6 95 80-120 Iron ug/L 1000 951 95 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/09/2015 05:15 PM without the written consent of Pace Analytical Services, Inc.. Page 45 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 14,8y ft.. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050258 Pace Project No.: 92249487 LABORATORY CONTROL SAMPLE: 1966604 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Lead ug/L 80 78.2 98 80-120 Magnesium ug/L 1000 927 93 80-120 Manganese ug/L 80 76.8 96 80-120 Molybdenum ug/L 80 77.0 96 80-120 Nickel ug/L 80 76.5 96 80-120 Potassium ug/L 1000 954 95 80-120 Selenium ug/L 80 73.8 92 80-120 Sodium ug/L 1000 926 93 80-120 Strontium ug/L 80 76.4 96 80-120 Thallium ug/L 80 80.4 100 80-120 Vanadium ug/L 80 76.9 96 80-120 Zinc ug/L 80 75.6 95 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1966605 1966606 MS MSD 92249061001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum ug/L 20.5 80 80 124 129 130 136 75-125 4 20 M1 Antimony ug/L ND 80 80 77.0 76.7 96 96 75-125 0 20 Arsenic ug/L ND 80 80 76.1 75.0 95 94 75-125 2 20 Barium ug/L 0.35 80 80 74.2 74.6 92 93 75-125 1 20 Beryllium ug/L ND 80 80 77.9 76.9 97 96 75-125 1 20 Boron ug/L ND 80 80 71.9 77.2 89 96 75-125 7 20 Cadmium ug/L ND 80 80 76.2 76.2 95 95 75-125 0 20 Calcium ug/L 337 1000 1000 1370 1330 103 99 75-125 3 20 Chromium ug/L 2.2 80 80 78.8 79.1 96 96 75-125 0 20 Cobalt ug/L ND 80 80 75.4 75.2 94 94 75-125 0 20 Copper ug/L 0.67J 80 80 76.3 76.6 95 95 75-125 0 20 Iron ug/L 105 1000 1000 1060 1060 95 95 75-125 0 20 Lead ug/L ND 80 80 77.5 77.6 97 97 75-125 0 20 Magnesium ug/L 5.91 1000 1000 994 966 99 96 75-125 3 20 Manganese ug/L 1.3 80 80 77.1 77.4 95 95 75-125 0 20 Molybdenum ug/L 19.3 80 80 95.0 94.4 95 94 75-125 1 20 Nickel ug/L 0.35J 80 80 77.0 76.8 96 96 75-125 0 20 Potassium ug/L 48.1J 1000 1000 989 974 94 93 75-125 2 20 Selenium ug/L ND 80 80 74.5 72.4 93 90 75-125 3 20 Sodium ug/L 16.9J 1000 1000 915 950 90 93 75-125 4 20 Strontium ug/L 0.68 80 80 76.0 76.8 94 95 75-125 1 20 Thallium ug/L ND 80 80 79.5 79.8 99 100 75-125 0 20 Vanadium ug/L ND 80 80 75.9 76.6 95 95 75-125 1 20 Zinc ug/L 2.5J 80 80 77.2 76.5 93 92 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/09/2015 05:15 PM without the written consent of Pace Analytical Services, Inc.. Page 46 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Ijigc&y ft.. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050258 Pace Project No.: 92249487 QC Batch: MPRP/54772 Analysis Method: EPA 6020A QC Batch Method: EPA 3020 Analysis Description: 6020A Water UPD4 Associated Lab Samples: 92249487006, 92249487007, 92249487008, 92249487009 METHOD BLANK: 1980141 Matrix: Water Associated Lab Samples: 92249487006, 92249487007, 92249487008, 92249487009 Blank Reporting Parameter Units Result Limit Analyzed Aluminum ug/L ND 10.0 06/01/1517:29 Antimony ug/L ND 0.50 06/01/1517:29 Arsenic ug/L ND 0.50 06/01/1517:29 Barium ug/L ND 0.30 06/01/1517:29 Beryllium ug/L ND 0.20 06/01/1517:29 Boron ug/L ND 5.0 06/01/1517:29 Cadmium ug/L ND 0.080 06/01/1517:29 Calcium ug/L ND 40.0 06/01/1517:29 Chromium ug/L ND 0.50 06/01/1517:29 Cobalt ug/L ND 0.50 06/01/1517:29 Copper ug/L ND 1.0 06/01/1517:29 Iron ug/L ND 50.0 06/01/1517:29 Lead ug/L ND 0.10 06/01/1517:29 Magnesium ug/L ND 10.0 06/01/1517:29 Manganese ug/L ND 0.50 06/01/1517:29 Molybdenum ug/L ND 0.50 06/01/1517:29 Nickel ug/L ND 0.50 06/01/1517:29 Potassium ug/L ND 50.0 06/01/1517:29 Selenium ug/L ND 0.50 06/01/1517:29 Sodium ug/L ND 50.0 06/01/1517:29 Strontium ug/L ND 0.50 06/01/1517:29 Thallium ug/L ND 0.10 06/01/1517:29 Vanadium ug/L ND 1.0 06/01/1517:29 Zinc ug/L ND 5.0 06/01/1517:29 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 1980142 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Aluminum ug/L 80 86.2 108 80-120 Antimony ug/L 80 84.8 106 80-120 Arsenic ug/L 80 85.4 107 80-120 Barium ug/L 80 84.3 105 80-120 Beryllium ug/L 80 88.0 110 80-120 Boron ug/L 80 80.9 101 80-120 Cadmium ug/L 80 85.7 107 80-120 Calcium ug/L 1000 999 100 80-120 Chromium ug/L 80 88.9 111 80-120 Cobalt ug/L 80 85.1 106 80-120 Copper ug/L 80 85.5 107 80-120 Iron ug/L 1000 1100 110 80-120 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/09/2015 05:15 PM without the written consent of Pace Analytical Services, Inc.. Page 47 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 16,8y ft.. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050258 Pace Project No.: 92249487 LABORATORY CONTROL SAMPLE: 1980142 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Lead ug/L 80 84.1 105 80-120 Magnesium ug/L 1000 1090 109 80-120 Manganese ug/L 80 89.5 112 80-120 Molybdenum ug/L 80 86.4 108 80-120 Nickel ug/L 80 84.9 106 80-120 Potassium ug/L 1000 1080 108 80-120 Selenium ug/L 80 83.4 104 80-120 Sodium ug/L 1000 1070 107 80-120 Strontium ug/L 80 86.9 109 80-120 Thallium ug/L 80 90.0 113 80-120 Vanadium ug/L 80 87.3 109 80-120 Zinc ug/L 80 86.3 108 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1980685 1980686 MS MSD 10308223006 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum ug/L 203 80 80 279 258 94 69 75-125 8 20 M1 Antimony ug/L <2.5 80 80 86.6 84.9 107 105 75-125 2 20 Arsenic ug/L 9.1 80 80 94.9 93.6 107 106 75-125 1 20 Barium ug/L 369 80 80 448 443 98 92 75-125 1 20 Beryllium ug/L <1.0 80 80 81.6 81.5 102 102 75-125 0 20 Boron ug/L 1010 80 80 1070 1070 74 75 75-125 0 20 M1 Cadmium ug/L <0.40 80 80 85.2 84.1 106 105 75-125 1 20 Calcium ug/L 148000 1000 1000 146000 144000 -157 -410 75-125 2 20 E,M1 Chromium ug/L <2.5 80 80 86.4 85.8 107 106 75-125 1 20 Cobalt ug/L 3.3 80 80 86.7 85.3 104 102 75-125 2 20 Copper ug/L <5.0 80 80 82.2 81.1 102 101 75-125 1 20 Iron ug/L <250 1000 1000 1200 1180 106 103 75-125 2 20 Lead ug/L <0.50 80 80 79.0 78.5 98 98 75-125 1 20 Magnesium ug/L 51800 1000 1000 52000 51300 21 -45 75-125 1 20 M1 Manganese ug/L 30.9 80 80 113 111 103 100 75-125 2 20 Molybdenum ug/L 153 80 80 239 234 107 102 75-125 2 20 Nickel ug/L 5.7 80 80 86.2 85.4 101 100 75-125 1 20 Potassium ug/L 14800 1000 1000 15500 15300 70 51 75-125 1 20 M1 Selenium ug/L 348 80 80 421 415 92 84 75-125 1 20 Sodium ug/L 372000 1000 1000 368000 362000 -396 -960 75-125 2 20 E,M1 Strontium ug/L 1430 80 80 1480 1460 62 37 75-125 1 20 M1 Thallium ug/L <0.50 80 80 83.9 82.9 105 104 75-125 1 20 Vanadium ug/L <5.0 80 80 94.0 92.7 112 111 75-125 1 20 Zinc ug/L 55.0 80 80 140 139 106 105 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/09/2015 05:15 PM without the written consent of Pace Analytical Services, Inc.. Page 48 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Ijc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050258 Pace Project No.: 92249487 QC Batch: PMST/3586 Analysis Method: ASTM D2974-87 QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture Associated Lab Samples: 92249487002, 92249487003, 92249487004, 92249487005 SAMPLE DUPLICATE: 1220300 35187349001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 0.73 1.3 56 10 D6 SAMPLE DUPLICATE: 1220301 35188096006 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 59.2 61.5 4 10 SAMPLE DUPLICATE: 1220302 35188476001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 18.5 19.5 6 10 SAMPLE DUPLICATE: 1220303 35188591001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 81.0 76.6 6 10 SAMPLE DUPLICATE: 1220304 35189234002 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 7.1 9.2 25 10 D6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/09/2015 05:15 PM without the written consent of Pace Analytical Services, Inc.. Page 49 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Iji g8yfte. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050258 Pace Project No.: 92249487 QC Batch: WET/37531 Analysis Method: EPA 9045 QC Batch Method: EPA 9045 Analysis Description: 9045 pH Associated Lab Samples: 92249487002, 92249487003, 92249487004, 92249487005 SAMPLE DUPLICATE: 1462098 92249477001 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 6.4 6.4 0 10 SAMPLE DUPLICATE: 1462099 92249477003 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 8.5 8.5 1 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/09/2015 05:15 PM without the written consent of Pace Analytical Services, Inc.. Page 50 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050258 Pace Project No.: 92249487 QC Batch: WETA/23110 Analysis Method: EPA 300.0 QC Batch Method: EPA 300.0 Analysis Description: 300.0 IC Anions Associated Lab Samples: 92249487002, 92249487003, 92249487004, 92249487005 METHOD BLANK: 1471529 Matrix: Water Associated Lab Samples: 92249487002, 92249487003, 92249487004, 92249487005 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Sulfate mg/L 3.1 2.0 05/30/15 23:22 LABORATORY CONTROL SAMPLE: 1471530 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfate mg/L 20 19.8 99 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1471531 1471532 MS MSD 92249101017 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfate mg/L 3.0 29.3 29.3 30.9 30.7 95 94 1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1471533 1471534 MS MSD 92250183011 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfate mg/L 8.3 37.2 37.2 44.0 43.9 96 96 0 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/09/2015 05:15 PM without the written consent of Pace Analytical Services, Inc.. Page 51 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 t 6,8y ft.. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050258 Pace Project No.: 92249487 QC Batch: WETA/23177 Analysis Method: EPA 353.2 QC Batch Method: EPA 353.2 Analysis Description: 353.2 Nitrate + Nitrite, Unpres. Associated Lab Samples: 92249487002, 92249487003, 92249487004, 92249487005 METHOD BLANK: 1476700 Matrix: Water Associated Lab Samples: 92249487002, 92249487003, 92249487004, 92249487005 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, Nitrate mg/L 0.15 0.020 06/09/15 10:56 Z2 LABORATORY CONTROL SAMPLE: 1476701 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Nitrate mg/L 2.5 2.4 95 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1476702 1476703 MS MSD 92249487002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Nitrate mg/L ND 2.6 2.6 2.4 2.4 89 89 90-110 1 10 H1,M1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1476704 1476705 MS MSD 92250202006 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Nitrate mg/L ND 3.1 3.1 3.1 3.2 93 94 90-110 2 10 H1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/09/2015 05:15 PM without the written consent of Pace Analytical Services, Inc.. Page 52 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 �T igy fte. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050258 Pace Project No.: 92249487 QC Batch: WETA/23132 Analysis Method: SM 4500-CI-E QC Batch Method: SM 4500-CI-E Analysis Description: 4500 Chloride Associated Lab Samples: 92249487002, 92249487003, 92249487004, 92249487005 METHOD BLANK: 1472681 Matrix: Water Associated Lab Samples: 92249487002, 92249487003, 92249487004, 92249487005 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/L ND 1.0 06/04/15 06:39 LABORATORY CONTROL SAMPLE: 1472682 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloride mg/L 20 21.0 105 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1472683 1472684 MS MSD 92249061003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride mg/L ND 24.2 24.2 27.1 27.1 109 110 90-110 0 10 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1472685 1472686 MS MSD 92249703005 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride mg/L ND 20 20 23.1 23.3 114 115 90-110 1 10 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/09/2015 05:15 PM without the written consent of Pace Analytical Services, Inc.. Page 53 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 t Qgigy ft.. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050258 Pace Project No.: 92249487 QC Batch: WETA/46491 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92249487002, 92249487003, 92249487004, 92249487005 METHOD BLANK: 1216444 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/kg ND 49.9 05/17/1512:50 Sulfate mg/kg ND 49.9 05/17/1512:50 LABORATORY CONTROL SAMPLE: 1216445 Parameter Units Chloride mg/kg Sulfate mg/kg MATRIX SPIKE SAMPLE: 1216447 Parameter Units Chloride mg/kg Sulfate mg/kg SAMPLE DUPLICATE: 1216446 Parameter Chloride Sulfate Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 491 453 92 80-120 491 454 92 80-120 92249487002 Spike MS MS % Rec Result Conc. Result % Rec Limits Qualifiers ND 526 495 94 80-120 ND 526 541 85 80-120 92249487002 Dup Units Result Result mg/kg ND ND mg/kg ND ND Max RPD RPD Qualifiers 20 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/09/2015 05:15 PM without the written consent of Pace Analytical Services, Inc.. Page 54 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 t S igy ft.. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050258 Pace Project No.: 92249487 QC Batch: WETA/46490 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92249487002, 92249487003, 92249487004, 92249487005 METHOD BLANK: 1216440 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrate as N mg/kg ND 5.0 05/17/15 12:50 LABORATORY CONTROL SAMPLE: 1216441 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg 49.1 46.0 94 80-120 MATRIX SPIKE SAMPLE: 1216443 92249487002 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg ND 52.6 51.0 95 80-120 H3 SAMPLE DUPLICATE: 1216442 92249487002 Dup Max Parameter Units Result Result RPD RPD Qualifiers Nitrate as N mg/kg ND ND 20 H3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/09/2015 05:15 PM without the written consent of Pace Analytical Services, Inc.. Page 55 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 t 4,8y ft.. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050258 Pace Project No.: 92249487 QC Batch: WETA/28762 Analysis Method: EPA 9060 QC Batch Method: EPA 9060 Analysis Description: 9060 TOC Average Associated Lab Samples: 92249487002, 92249487003, 92249487004, 92249487005 METHOD BLANK: 1167261 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mean Total Organic Carbon mg/kg ND 600 06/02/15 07:26 LABORATORY CONTROL SAMPLE: 1167262 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mean Total Organic Carbon mg/kg 120000 114000 95 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1167263 1167264 MS MSD 92249703006 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg ND 5990 6000 4820 4980 77 79 50-150 3 30 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1167265 1167266 MS MSD 92249703007 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg ND 6030 6010 5110 5550 81 89 50-150 8 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/09/2015 05:15 PM without the written consent of Pace Analytical Services, Inc.. Page 56 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 �gc&y ft.. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: J15050258 Pace Project No.: 92249487 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TN -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-G Pace Analytical Services - Green Bay PASI-M Pace Analytical Services - Minneapolis PASI-O Pace Analytical Services - Ormond Beach BATCH QUALIFIERS Batch: ICP/14828 Ill Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. Batch: ICPM/9829 III Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. ANALYTE QUALIFIERS B Analyte was detected in the associated method blank. D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. D6 The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits. E Analyte concentration exceeded the calibration range. The reported result is estimated. H1 Analysis conducted outside the EPA method holding time. H3 Sample was received or analysis requested beyond the recognized method holding time. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/09/2015 05:15 PM without the written consent of Pace Analytical Services, Inc.. Page 57 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ftc&y ft.. Suite 100 Huntersville, INC 28078 (704)875-9092 QUALIFIERS Project: J15050258 Pace Project No.: 92249487 ANALYTE QUALIFIERS M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. N2 The lab does not hold TIN accreditation for this parameter. Z2 Analyte present in the associated method blank above the detection limit. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/09/2015 05:15 PM without the written consent of Pace Analytical Services, Inc.. Page 58 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 "'8yfte. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: J15050258 Pace Project No.: 92249487 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92249487002 2015014095 EPA 3050 MPRP/24249 EPA 6010 ICP/14828 92249487003 2015014096 EPA 3050 MPRP/24249 EPA 6010 ICP/14828 92249487004 2015014097 EPA 3050 MPRP/24249 EPA 6010 ICP/14828 92249487005 2015014098 EPA 3050 MPRP/24249 EPA 6010 ICP/14828 92249487002 2015014095 EPA 3050 MPRP/24250 EPA6020 ICPM/9829 92249487003 2015014096 EPA 3050 MPRP/24250 EPA6020 ICPM/9829 92249487004 2015014097 EPA 3050 MPRP/24250 EPA 6020 ICPM/9829 92249487005 2015014098 EPA 3050 MPRP/24250 EPA6020 ICPM/9829 92249487001 2015014094 EPA 3020 MPRP/54425 EPA 6020A ICPM/24315 92249487006 2015014095 SPLP EPA 3020 MPRP/54772 EPA 6020A ICPM/24559 92249487007 2015014096 SPLP EPA 3020 MPRP/54772 EPA 6020A ICPM/24559 92249487008 2015014097 SPLP EPA 3020 MPRP/54772 EPA 6020A ICPM/24559 92249487009 2015014098 SPLP EPA 3020 MPRP/54772 EPA 6020A ICPM/24559 92249487001 2015014094 EPA 7470A MERP/13557 EPA 7470A MERC/15737 92249487006 2015014095 SPLP EPA 7470A MERP/13691 EPA 7470A MERC/15918 92249487007 2015014096 SPLP EPA 7470A MERP/13691 EPA 7470A MERC/15918 92249487008 2015014097 SPLP EPA 7470A MERP/13691 EPA 7470A MERC/15918 92249487009 2015014098 SPLP EPA 7470A MERP/13691 EPA 7470A MERC/15918 92249487002 2015014095 EPA 7471 MERP/5748 EPA 7471 MERC/5735 92249487003 2015014096 EPA 7471 MERP/5748 EPA 7471 MERC/5735 92249487004 2015014097 EPA 7471 MERP/5748 EPA 7471 MERC/5735 92249487005 2015014098 EPA 7471 MERP/5748 EPA 7471 MERC/5735 92249487002 2015014095 ASTM D2974-87 PMST/3586 92249487003 2015014096 ASTM D2974-87 PMST/3586 92249487004 2015014097 ASTM D2974-87 PMST/3586 92249487005 2015014098 ASTM D2974-87 PMST/3586 92249487002 2015014095 EPA 9045 WET/37531 92249487003 2015014096 EPA 9045 WET/37531 92249487004 2015014097 EPA 9045 WET/37531 92249487005 2015014098 EPA 9045 WET/37531 92249487002 2015014095 EPA 300.0 WETA/23110 92249487003 2015014096 EPA 300.0 WETA/23110 92249487004 2015014097 EPA 300.0 WETA/23110 92249487005 2015014098 EPA 300.0 WETA/23110 92249487002 2015014095 EPA 353.2 WETA/23177 92249487003 2015014096 EPA 353.2 WETA/23177 92249487004 2015014097 EPA 353.2 WETA/23177 92249487005 2015014098 EPA 353.2 WETA/23177 92249487002 2015014095 SM 4500-CI-E WETA/23132 92249487003 2015014096 SM 4500-CI-E WETA/23132 92249487004 2015014097 SM 4500-CI-E WETA/23132 92249487005 2015014098 SM 4500-CI-E WETA/23132 92249487002 2015014095 EPA 9056 WETA/46491 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/09/2015 05:15 PM without the written consent of Pace Analytical Services, Inc.. Page 59 of 62 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 �gc&y ft.. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: J15050258 Pace Project No.: 92249487 Lab ID Sample ID QC Batch Method QC Batch 92249487003 2015014096 EPA 9056 WETA/46491 92249487004 2015014097 EPA 9056 WETA/46491 92249487005 2015014098 EPA 9056 WETA/46491 92249487002 2015014095 EPA 9056 WETA/46490 92249487003 2015014096 EPA 9056 WETA/46490 92249487004 2015014097 EPA 9056 WETA/46490 92249487005 2015014098 EPA 9056 WETA/46490 92249487002 2015014095 EPA 9060 WETA/28762 92249487002 2015014095 EPA 9060 WETA/28763 92249487003 2015014096 EPA 9060 WETA/28762 92249487003 2015014096 EPA 9060 WETA/28763 92249487004 2015014097 EPA 9060 WETA/28762 92249487004 2015014097 EPA 9060 WETA/28763 92249487005 2015014098 EPA 9060 WETA/28762 92249487005 2015014098 EPA 9060 WETA/28763 Date: 06/09/2015 05:15 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Analytical Method Analytical Batch Page 60 of 62 F_CHR C8a003.r6v.15 face Huntersville dualk Office Client Name: 69 of 71 Courier: ❑ Fed Ex [] UPS❑ USPS❑ Client[] CommerclalElPace other Custody Seal on Cooler/Boer Present: ❑ yes a no Seats intact: ❑ yes ❑ no Tattling Material: ❑ Bubble V❑p ❑ Bubble Bags � g Q' None ❑ 0#iter Thermometer Used: IR Gun T1401 Type of lee: Wet Blue Non ElSamples on Im, cooling processhas begun Temp Correction Factor T1401 No Correction �J Corrected Cooler Temp.: °C Biological Tissue is Frozen: Yes No' NIA. oate and Initi Is o efsone amining Temp should be above freezing to 6°C contents: Y:S Comments: Chain of Custody Present: Oyes ❑No ONIA 1. Chain of Custody trilled Out: 0' es EINo DNIA 2. Chain of Custody Relinquished: Q es ONo DNIA 3, Sampler Name & Signature on COC: PYos QNo ©NIA 4. Samples Arrived within Hold Time: [etas DNo ONIA 5. Short Hold Time Analysis (<72hr): ©Yes L'1No DNIA 6. Rush Turn Around Time Requested: 0Yes ONO 0WA 7, Sufficient Volume: ClYes ©No .LVA $. Correct Containers Used: ..0Yes ©No DNIA g, -Pace Containers Used: nYes ON6 0NlA Containers Intact: -oyes ONo DNIA 10. Filtered volume received for Dissolved tests Dyes DNo Dgii 11. Sample Labels match COC: 0es DNo DNIA 12. -Includes date{time/1D1Analysis Matrix: All containers needing preservation have been checked. []yes UNo DNIA 13, All containers needing preservation are found to be in CfYes UNo C1N1A compliance with EPA recommendation. exceptions; VOA, colifonr, FOC, 0&G, W -DRO (water) Dyes ONO 14. Samples checked for dechlorination: Dyes ONO .-aNrA Heads ace in V0A Vials (y6mm): Dyes ONo ❑wA' a - Trip Blank Present: Dyes 1iNo 13N!A 6. Trip Blank Custody Seals Present Dyes []No DwA Pace Trip Blank Lot # (if purchased): Client Notification/ Resolution: Field Data Required? Y ! N Person Contacted: Datelrime: Comments] Resolution: SCURF Review: (4-V Date: 5112,tr5' SRF Review: r( Date; r30 Note: Whenever there Is a discrepancy affeoting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DBHNR Certification Office (1.e out of hold, incorrect preservative, out of temp, Incorrect containers) WO#:92249487 111111IT IIIIIIIIIIII Page 61 of 62 70 of 71 t C VD r ED CD rn . .. . ...... cal GlllaaFtvrirjhl 1�1A r It C) x S 2: 22 0 9, CL rD , F3 E > 0 3 � 0 1; - 11 -A 0 u 2. 10 U1 VI CD 0 0 m o (A C ! g Cj 0, I ct z Cn I 0 .0. N 0 Cl) to -0 i C) L------------- P,n S ............. X CL rn CL > m 4�- Nj 0 0 00 i ILI W >! r A-10 comp. A lye z 0 "Grab Rey Ire 21 Er )< X Total Metals (PACE v � 'C.mp. '61a �b Total Metals (PACE Anions (PACE) 5 C (a m PH (PACE) z V 0i -1 SPLP - Total Me tals and IN —i a 4--4 Anions (PACE) i I I f i t i l! I Sediment specific tests i i {Access Analytical) 5 ,x Organic Carbon Ixl (Access Analytical) 5 q i 56 CL fD r 22 OD Qj o 0 a C) hill m 0 —4 z z CL -20TQta1# of Containers Page 62 of 62 _ HAII_�_O_ F CUSTODY RECORD AND ANALYSIS P=_._ �Analyfical Synterra EDD j ' 'U Laboratory Services A. i _ _ _ _ _�=��I�r' i _, .,_._._._.__ _ =1�Laboral Use only tn!Vtkm MR11 Codes IAG43A2 iR,dldi*g T-00d} � Wa *,,Jtr PAP 1 Of 1 ENERGY. 153M "gers Fe" fttl f MunrenrlFde, N.C. 26078 � �% �i� � �..� � - �Inkfe �, . �ppm pn4ime" � � I 4iSTRiBuTION �1 \\ � I iCaVFp•m ®k 'Qr�S 7M�. � 'C�IEiIGIF�I.aI, IA LAB, 19@4j 8,'S-5?95 " - 6AWLE P Gedub r Waler — COPY to CLIENT 11P o1wr1 Rl�rrr� AB GW AS SlPhaNfrX ► ._. -- _ aPRE�_ GYtbr Pt4" � Capp Feara �.� rm!ft �k REV DATE 112aring ])Glfanr - J-0110 TrMl*fir, dLk M.rk McDaOa„Bynum PACE Ca IerTrm C jrF PC) 1142081 e Kathy Webb, S]+Ilti M r�sarM,:1 � Chda SUMI, Sy � i 2A-I ts 8a4one �e7 �S'Y Yr} ra7 tin ,r,. �TTyyy � ACJ-CP1402 �ttt m bl d r.Mirr® Wni t: lJAetlMir� rF .e _ IPrncxf_Ip a 7cli % 4 �a as to cam C4lPIY410.1-. (q ' � l� CC SPM - � r� i3fFf y Rl.�4l, Jam f'I i � M a4 i6 whw� Lpetiflc xeourrtilg het bbm Ga hm et d a not InalcoW aixva Preservatives when used nlue,l hu � ll1 Ig � IJ,1 69 � r i5 ww � ti•o is114,wlery: 1; E�Irir corrieci 4G "+Hull m Idl B s" Aelas ab--. or Added within 15 mit.utes of salmple Q 11:1 $ �+ 2J f�cavlgra cernreGr tcrnurlei ic.r raiino Urrt WP4 Prae®rsl ID. coIlQ tioa R {.] tS IiL 0 Ib FA ueue Owtir Malrly[ C ollertion Informall' D f1 G w i, ep I ;Sail, Sedin.m, A.N) I Sam le Desc i tiorl ur D ' 3 S7 � '� S CLL •c ® 47 L tu3 a to TYme a �' A � 'L '0 4 575 i'ie� L Mter _ r� {r� �y{'�} 4+ Sf 1'T' ] fj r•� 'j ;�/ 5- ,7l' �. Jj I i I r 1 I A 9 1 1 1 Y j '.SA 4VplN9ttyNf i + -�. So -Clyj _ D- w7kri IAc[rpmi i 5--fF hs �X 6ald'7'hne _ Metals- A], Sh, As, 13a, BE. B, Gd.Ca, Cr, Co, Cu. Fe, Pts, Nlg, mn, No, M. pH A. L, _ — TfTT _ -- Fiilr Sr. TI, V, Zn. Cl, WtUste-N, 504 22Requested Turnaroiind 14 r3wff 'T Days — 'fylf� 14I