NC0003433_J15050012 Report_20150902

+ DUKE Analytical Laboratory
ENERGY
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone:[phone] Fax:[phone]
Order Summary Report
Order Number: J15050012
Project Name: CAPE FEAR - AB GW ASSESSMENT SOIL
Customer Name(s): Tim Hunsucker, Chris Suttell, Kathy Webb, John Toepfer
Customer Address:
Lab Contact: Marqaret Galvin -Karr Phone: [phone]
MXG4644 (101161)
Report Authorized By: �-04'00' 2015.06.09 14:03:15 Date:
(Signature)
Margaret Galvin -Karr
Program Comments:
Please contact the Program Manager (Margaret Galvin -Karr) with any questions regarding this report.
Data Flags & Calculations:
6/8/2015
il<.ii[1Ya
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Sample ID's & Descriptions: 2 of 102
Collection
Sample ID Plant/Station Date and Time Collected By Sample Description
2015012925
Cape Fear
25-Apr-15 4:15 PM
Illegible
MW-9SB 16-17
2015012926
Cape Fear
25-Apr-15 4:10 PM
Illegible
MW-9SB 6-7
2015012927
Cape Fear
25-Apr-15 4:05 PM
Illegible
MW-9SB 2-3
2015012928
Cape Fear
25-Apr-15 4:25 PM
Illegible
MW-9SB 0-2
2015012929
Cape Fear
28-Apr-15 5:00 PM
Illegible
MW-16SB 0-2
2015012930
Cape Fear
28-Apr-15 5:10 PM
Illegible
MW-16SB 4-6
2015012931
Cape Fear
28-Apr-15 5:20 PM
Illegible
MW-16SB 13-15
2015012934
Cape Fear
25-Apr-15 8:35 AM
Illegible
ERB-20 (SONIC)
2015012935
Cape Fear
28-Apr-15 3:40 PM
Illegible
ERB-21 (SONIC)
2015012936
Cape Fear
28-Apr-15
Filter Blank
10 Total Samples

Oni 511M
Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals Yes No
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits. ❑ Yes❑ No
All laboratory QA/QC requirements are acceptable.❑ Yes ❑ No
Report Sections Included:
U Job Summary Report
❑ Sample Identification
n Technical Validation of Data Package
❑ Analytical Laboratory Certificate of Analysis
❑ Analytical Laboratory QC Report
Reviewed By: Date:
Sub -contracted Laboratory Results
❑ Customer Specific Data Sheets, Reports, & Documentation
❑ Customer Database Entries
0 Chain of Custody
[I/0] Electronic Data Deliverable (EDD) Sent Separately

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15050012
Site: MW-9SB 16-17
Collection Date: 25-Apr-15 4:15 PM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
SPLP LEACHATE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
4 of 102
Sample #: 2015012925
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15050012
Site: MW-9SB 6-7
Collection Date: 25-Apr-15 4:10 PM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
SPLP LEACHATE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
:�1111111N,
Sample #: 2015012926
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15050012
Site: MW-9SB 2-3
Collection Date: 25-Apr-15 4:05 PM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
SPLP LEACHATE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
6 of 102
Sample #: 2015012927
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15050012
Site: MW-9SB 0-2
Collection Date: 25-Apr-15 4:25 PM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
SPLP LEACHATE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
rAns 1111111N,
Sample #: 2015012928
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15050012
Site: MW-16SB 0-2
Collection Date: 28-Apr-15 5:00 PM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
SPLP LEACHATE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
8 of 102
Sample #: 2015012929
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15050012
Site: MW-16SB 4-6
Collection Date: 28-Apr-15 5:10 PM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
SPLP LEACHATE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
9 of 102
Sample #: 2015012930
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15050012
Site: MW-16SB 13-15
Collection Date: 28-Apr-15 5:20 PM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
SPLP LEACHATE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
`[IZi7i1IN
Sample #: 2015012931
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis 11 of 102
This report shall not be reproduced, except in full.
Order # J15050012
Site: ERB-20 (SONIC)
Collection Date: 25-Apr-15 8:35 AM
Analyte Result Units Qualifiers RDL DF
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Sample #: 2015012934
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE

Certificate of Laboratory Analysis 12 of 102
This report shall not be reproduced, except in full.
Order # J15050012
Site: ERB-21 (SONIC)
Collection Date: 28-Apr-15 3:40 PM
Analyte Result Units Qualifiers RDL DF
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Sample #: 2015012935
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE

Site: Filter Blank
Collection Date: 28-Apr-15
Certificate of Laboratory Analysis 13 of 102
This report shall not be reproduced, except in full.
Order # J15050012
Sample #: 2015012936
Matrix: SOIL
Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
-- Additional Information --
Sample 2015012928: RPD for TOC exceeds Pace method RPD of 40% or less between 4 determinations. RPD for
this sample was 78%. M. Galvin -Karr 6/6/2015

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980011,ir6fy011je. Suite 100
Huntersville, INC 28078
[phone]
May 28, 2015
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg.7405 MG30A2
Huntersville, NC 28078
RE: Project: J 15050012
Pace Project No.: 92247913
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on May 01, 2015. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TN standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc: Marge Galvin -Karr, Duke Energy
Program Manager, Duke Energy
Rodney Wilke, Duke Energy
p«FO
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
lqe� ��� without the written consent of Pace Analytical Services, Inc..
BRAT,
Page 1 of 88

lacmnalyfica(
www.pacelabs.com
Pace Analytical Services, Inc.
980011� y6r. Suite 100
Huntersville, NC 28078
[phone]
Project: J15050012
Pace Project No.: 92247913
Minnesota Certification IDs
1700 Elm Street SE Suite 200, Minneapolis, MN 55414
A21-A Certification #: 2926.01
Alaska Certification #: UST-078
Alaska Certification #MN00064
Alabama Certification #40770
Arizona Certification #: AZ-0014
Arkansas Certification #: 88-0680
California Certification #: 01155CA
Colorado Certification #Pace
Connecticut Certification #: PH-0256
EPA Region 8 Certification #: 8TMS-L
Florida/NELAP Certification #: E87605
Guam Certification #:14-008r
Georgia Certification #: 959
Georgia EPD #: Pace
Idaho Certification #: MN00064
Hawaii Certification #MN00064
Illinois Certification #: 200011
Indiana Certification#C-MN-01
Iowa Certification #: 368
Kansas Certification #: E-10167
Kentucky Dept of Envi. Protection - DW #90062
Kentucky Dept of Envi. Protection - WW #:90062
Louisiana DEQ Certification #: 3086
Louisiana DHH #: LA140001
Maine Certification #: 2013011
Maryland Certification #: 322
Michigan DEPH Certification #: 9909
Ormond Beach Certification IDs
8 East Tower Circle, Ormond Beach, FL 32174
Alabama Certification #: 41320
Connecticut Certification #: PH-0216
Delaware Certification: FL NELAC Reciprocity
Florida Certification #: E83079
Georgia Certification #: 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification #: 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383
Kentucky Certification #: 90050
Louisiana Certification #: FL NELAC Reciprocity
Louisiana Environmental Certificate #: 05007
Maryland Certification: #346
Massachusetts Certification #: M-FL1264
Michigan Certification #: 9911
Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236
Green Bay Certification IDs
1241 Bellevue Street, Green Bay, WI 54302
Florida/NELAP Certification #: E87948
Illinois Certification #: 200050
Kentucky Certification #: 82
Louisiana Certification #: 04168
Minnesota Certification #: 055-999-334
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
CERTIFICATIONS
Minnesota Certification #: 027-053-137
Mississippi Certification #: Pace
Montana Certification #: MT0092
Nevada Certification #: MN_00064
Nebraska Certification #: Pace
New Jersey Certification #: MN-002
New York Certification #: 11647
North Carolina Certification #: 530
North Carolina State Public Health #: 27700
North Dakota Certification #: R-036
Ohio EPA#: 4150
Ohio VAP Certification #: CL101
Oklahoma Certification #: 9507
Oregon Certification #: MN200001
Oregon Certification #: MN300001
Pennsylvania Certification #: 68-00563
Puerto Rico Certification
Saipan (CNMI) #:MP0003
South Carolina #:74003001
Texas Certification #: T104704192
Tennessee Certification #: 02818
Utah Certification #: MN000642013-4
Virginia DGS Certification #: 251
Virginia/VELAP Certification #: Pace
Washington Certification #: C486
West Virginia Certification #: 382
West Virginia DHHR #:9952C
Wisconsin Certification #: 999407970
Montana Certification #: Cert 0074
Nebraska Certification: NE-OS-28-14
Nevada Certification: FL NELAC Reciprocity
New Hampshire Certification #: 2958
New Jersey Certification #: FL765
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FLO1264
South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
Washington Certification #: C955
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
North Dakota Certification #: R-150
South Carolina Certification #: 83006001
Texas Certification #: T104704529-14-1
US Dept of Agriculture #: S-76505
Wisconsin Certification #: 405132750
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 2 of 88

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
98001�yo"Je. Suite 100
Huntersville, NC 28078
[phone]
Project: J15050012
Pace Project No.: 92247913
Asheville Certification IDs
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
CERTIFICATIONS
West Virginia Certification #: 356
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 3 of 88

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
98001�yo"Je. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE SUMMARY
Project: J15050012
Pace Project No.: 92247913
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92247913001
2015012925
Solid
04/25/1516:15
05/01/15 12:03
92247913002
2015012926
Solid
04/25/1516:10
05/01/15 12:03
92247913003
2015012927
Solid
04/25/1516:05
05/01/15 12:03
92247913004
2015012928
Solid
04/25/1516:25
05/01/15 12:03
92247913005
2015012929
Solid
04/28/1517:00
05/01/15 12:03
92247913006
2015012930
Solid
04/28/1517:10
05/01/15 12:03
92247913007
2015012931
Solid
04/28/1517:20
05/01/15 12:03
92247913008
2015012934
Water
04/25/15 08:35
05/01/15 12:03
92247913009
2015012935
Water
04/28/1515:40
05/01/15 12:03
92247913010
2015012936
Water
04/28/15 00:00
05/01/15 12:03
92247913011
2015012925 SPLP
Water
04/25/15 16:15
05/01/15 12:03
92247913012
2015012926 SPLP
Water
04/25/15 16:10
05/01/15 12:03
92247913013
2015012927 SPLP
Water
04/25/15 16:05
05/01/15 12:03
92247913014
2015012928 SPLP
Water
04/25/15 16:25
05/01/15 12:03
92247913015
2015012929 SPLP
Water
04/28/15 17:00
05/01/15 12:03
92247913016
2015012930 SPLP
Water
04/28/15 17:10
05/01/15 12:03
92247913017
2015012931 SPLP
Water
04/28/15 17:20
05/01/15 12:03
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 4 of 88

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
98001�yo"Je. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project: J15050012
Pace Project No.: 92247913
Lab ID
Sample ID
Method
Analysts
Analytes
Reported
Laboratory
92247913001
2015012925
EPA 6010
TAP
16
PASI-0
EPA 6020
DRS
8
PASI-O
EPA 7471
CKJ
1
PASI-O
ASTM D2974-87
MLO
1
PASI-O
EPA 9045
MLS
1
PASI-A
EPA 300.0
AES2
1
PASI-A
EPA 353.2
DMN
1
PASI-A
SM 4500-CI-E
SER
1
PASI-A
EPA 9056
KHC
2
PASI-O
EPA 9056
KHC
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92247913002
2015012926
EPA 6010
TAP
16
PASI-0
EPA 6020
DRS
8
PASI-O
EPA 7471
CKJ
1
PASI-O
ASTM D2974-87
MLO
1
PASI-O
EPA 9045
MLS
1
PASI-A
EPA 300.0
AES2
1
PASI-A
EPA 353.2
DMN
1
PASI-A
SM 4500-CI-E
SER
1
PASI-A
EPA 9056
KHC
2
PASI-O
EPA 9056
KHC
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92247913003
2015012927
EPA 6010
TAP
16
PASI-0
EPA 6020
DRS
8
PASI-O
EPA 7471
CKJ
1
PASI-O
ASTM D2974-87
MLO
1
PASI-O
EPA 9045
MLS
1
PASI-A
EPA 300.0
AES2
1
PASI-A
EPA 353.2
DMN
1
PASI-A
SM 4500-CI-E
SER
1
PASI-A
EPA 9056
KHC
2
PASI-O
EPA 9056
KHC
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92247913004
2015012928
EPA 6010
TAP
16
PASI-0
EPA 6020
DRS
8
PASI-O
EPA 7471
CKJ
1
PASI-O
ASTM D2974-87
MLO
1
PASI-O
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 5 of 88

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980019,6fYo"Je. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project: J15050012
Pace Project No.: 92247913
Lab ID
Sample ID
Method
Analysts
Analytes
Reported
Laboratory
EPA 9045
MLS
1
PASI-A
EPA 300.0
AES2
1
PASI-A
EPA 353.2
DMN
1
PASI-A
SM 4500-CI-E
SER
1
PASI-A
EPA 9056
KHC
2
PASI-O
EPA 9056
KHC
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92247913005
2015012929
EPA 6010
TAP
16
PASI-0
EPA 6020
DRS
8
PASI-O
EPA 7471
CKJ
1
PASI-O
ASTM D2974-87
MLO
1
PASI-O
EPA 9045
MLS
1
PASI-A
EPA 300.0
AES2
1
PASI-A
EPA 353.2
DMN
1
PASI-A
SM 4500-CI-E
SER
1
PASI-A
EPA 9056
KHC
2
PASI-O
EPA 9056
KHC
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92247913006
2015012930
EPA 6010
TAP
16
PASI-0
EPA 6020
DRS
8
PASI-O
EPA 7471
CKJ
1
PASI-O
ASTM D2974-87
MLO
1
PASI-O
EPA 9045
MLS
1
PASI-A
EPA 300.0
AES2
1
PASI-A
EPA 353.2
DMN
1
PASI-A
SM 4500-CI-E
SER
1
PASI-A
EPA 9056
KHC
2
PASI-O
EPA 9056
KHC
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92247913007
2015012931
EPA 6010
TAP
16
PASI-0
EPA 6020
DRS
8
PASI-O
EPA 7471
CKJ
1
PASI-O
ASTM D2974-87
MLO
1
PASI-O
EPA 9045
MLS
1
PASI-A
EPA 300.0
AES2
1
PASI-A
EPA 353.2
DMN
1
PASI-A
SM 4500-CI-E
SER
1
PASI-A
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 6 of 88

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800�8rpyo"Je. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
J15050012
92247913
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
EPA 9056
KHC
2
PASI-O
EPA 9056
KHC
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92247913008
2015012934
EPA 6020A
RJS
24
PASI-M
EPA 7470A
JDD
1
PASI-M
92247913009
2015012935
EPA 6020A
RJS
24
PASI-M
EPA 7470A
JDD
1
PASI-M
92247913010
2015012936
EPA 6020A
RJS
24
PASI-M
EPA 7470A
JDD
1
PASI-M
92247913011
2015012925 SPLP
EPA 6020A
RJS,TT3
24
PASI-M
EPA 7470A
DM
1
PASI-M
92247913012
2015012926 SPLP
EPA 6020A
RJS,TT3
24
PASI-M
EPA 7470A
DM
1
PASI-M
92247913013
2015012927 SPLP
EPA 6020A
RJS,TT3
24
PASI-M
EPA 7470A
DM
1
PASI-M
92247913014
2015012928 SPLP
EPA 6020A
RJS,TT3
24
PASI-M
EPA 7470A
DM
1
PASI-M
92247913015
2015012929 SPLP
EPA 6020A
RJS,TT3
24
PASI-M
EPA 7470A
DM
1
PASI-M
92247913016
2015012930 SPLP
EPA 6020A
TT3
24
PASI-M
EPA 7470A
DM
1
PASI-M
92247913017
2015012931 SPLP
EPA 6020A
RJS,TT3
24
PASI-M
EPA 7470A
DM
1
PASI-M
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 7 of 88

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
98002ISirpyo"Je. Suite 100
Huntersville, NC 28078
[phone]
Project: J15050012
Pace Project No.: 92247913
Lab Sample ID Client Sample ID
Method Parameters
SUMMARY OF DETECTION
Result Units Report Limit Analyzed
92247913001
2015012925
EPA 6010
Aluminum
9980
mg/kg
28.5
05/10/15 17:50
EPA 6010
Barium
50.6
mg/kg
2.9
05/10/15 17:50
EPA 6010
Beryllium
0.32
mg/kg
0.29
05/10/15 17:50
EPA 6010
Calcium
2950
mg/kg
143
05/10/15 17:50
EPA 6010
Chromium
5.1
mg/kg
1.4
05/10/15 17:50
EPA 6010
Copper
10.4
mg/kg
1.4
05/10/15 17:50
EPA 6010
Iron
19500
mg/kg
11.4
05/10/15 17:50
EPA 6010
Magnesium
3090
mg/kg
143
05/10/15 17:50
EPA 6010
Manganese
371
mg/kg
1.4
05/10/15 17:50
EPA 6010
Nickel
2.3
mg/kg
1.4
05/10/15 17:50
EPA 6010
Potassium
1010
mg/kg
285
05/10/15 17:50
EPA 6010
Strontium
25.6
mg/kg
2.9
05/10/15 17:50
EPA 6010
Zinc
83.3
mg/kg
5.7
05/10/15 17:50
EPA6020
Cobalt
7.3
mg/kg
5.7
05/11/1513:37
EPA6020
Lead
6.8
mg/kg
5.7
05/11/1513:37
EPA6020
Vanadium
11.0
mg/kg
5.7
05/11/1513:37
ASTM D2974-87
Percent Moisture
9.2
%
0.10
05/11/15 10:33
EPA 9045
pH at 25 Degrees C
6.7
Std. Units
0.10
05/05/15 14:25
EPA 300.0
Sulfate
4.4
mg/L
2.2
05/14/15 22:53
EPA 9060
Total Organic Carbon
339J
mg/kg
659
05/22/15 11:08
EPA 9060
RSD%
5.0
%
05/22/15 11:08
92247913002
2015012926
EPA 6010
Aluminum
9700
mg/kg
28.7
05/10/15 17:54
EPA 6010
Barium
224
mg/kg
2.9
05/10/15 17:54
EPA 6010
Beryllium
0.73
mg/kg
0.29
05/10/15 17:54
EPA 6010
Calcium
2750
mg/kg
144
05/10/15 17:54
EPA 6010
Chromium
5.0
mg/kg
1.4
05/10/15 17:54
EPA 6010
Copper
17.4
mg/kg
1.4
05/10/15 17:54
EPA 6010
Iron
24500
mg/kg
11.5
05/10/15 17:54
EPA 6010
Magnesium
3420
mg/kg
144
05/10/15 17:54
EPA 6010
Manganese
1140
mg/kg
1.4
05/10/15 17:54
EPA 6010
Nickel
5.7
mg/kg
1.4
05/10/15 17:54
EPA 6010
Potassium
427
mg/kg
287
05/10/15 17:54
EPA 6010
Sodium
338
mg/kg
287
05/10/15 17:54
EPA 6010
Strontium
35.8
mg/kg
2.9
05/10/15 17:54
EPA 6010
Zinc
154
mg/kg
5.7
05/10/15 17:54
EPA6020
Cobalt
11.4
mg/kg
5.7
05/11/1513:40
EPA6020
Lead
26.1
mg/kg
5.7
05/11/1513:40
EPA6020
Vanadium
10.8
mg/kg
5.7
05/11/1513:40
EPA 7471
Mercury
0.012
mg/kg
0.0092
05/09/15 18:07
ASTM D2974-87
Percent Moisture
13.4
%
0.10
05/11/15 10:33
EPA 9045
pH at 25 Degrees C
6.7
Std. Units
0.10
05/05/15 14:25
EPA 300.0
Sulfate
4.7
mg/L
2.3
05/14/15 23:34
EPA 9060
Total Organic Carbon
546J
mg/kg
694
05/22/15 13:41
EPA 9060
Total Organic Carbon
593J
mg/kg
698
05/22/15 13:47
EPA 9060
Total Organic Carbon
504J
mg/kg
697
05/22/15 13:52
EPA 9060
Total Organic Carbon
655J
mg/kg
697
05/22/15 13:59
REPORT OF LABORATORY ANALYSIS
B
B
Qualifiers
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 8 of 88

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800�qrpyo"Je. Suite 100
Huntersville, NC 28078
[phone]
Project: J15050012
Pace Project No.: 92247913
Lab Sample ID Client Sample ID
Method Parameters
SUMMARY OF DETECTION
Result Units Report Limit Analyzed
92247913002
2015012926
EPA 9060
Mean Total Organic Carbon
575J
mg/kg
696
05/22/15 13:41
EPA 9060
RSD%
11.2
%
05/22/15 13:41
92247913003
2015012927
EPA 6010
Aluminum
7720
mg/kg
26.7
05/10/15 17:58
EPA 6010
Barium
155
mg/kg
2.7
05/10/15 17:58
EPA 6010
Beryllium
1.2
mg/kg
0.27
05/10/15 17:58
EPA 6010
Calcium
979
mg/kg
133
05/10/15 17:58
EPA 6010
Chromium
4.3
mg/kg
1.3
05/10/15 17:58
EPA 6010
Copper
8.8
mg/kg
1.3
05/10/15 17:58
EPA 6010
Iron
20000
mg/kg
10.7
05/10/15 17:58
EPA 6010
Magnesium
2500
mg/kg
133
05/10/15 17:58
EPA 6010
Manganese
324
mg/kg
1.3
05/10/15 17:58
EPA 6010
Molybdenum
3.3
mg/kg
2.7
05/10/15 17:58
EPA 6010
Nickel
8.4
mg/kg
1.3
05/10/15 17:58
EPA 6010
Potassium
237J
mg/kg
267
05/10/15 17:58
EPA 6010
Sodium
166J
mg/kg
267
05/10/15 17:58
EPA 6010
Strontium
15.1
mg/kg
2.7
05/10/15 17:58
EPA 6010
Zinc
67.8
mg/kg
5.3
05/10/15 17:58
EPA6020
Arsenic
8.1
mg/kg
5.3
05/11/1513:43
EPA6020
Cobalt
31.9
mg/kg
5.3
05/11/1513:43
EPA6020
Lead
12.4
mg/kg
5.3
05/11/1513:43
EPA6020
Selenium
4AJ
mg/kg
5.3
05/11/1513:43
EPA6020
Vanadium
9.7
mg/kg
5.3
05/11/1513:43
EPA 7471
Mercury
0.0070J
mg/kg
0.0088
05/09/15 18:09
ASTM D2974-87
Percent Moisture
7.6
%
0.10
05/11/15 10:33
EPA 9045
pH at 25 Degrees C
5.6
Std. Units
0.10
05/05/15 14:25
EPA 300.0
Sulfate
6.6
mg/L
2.2
05/14/15 23:47 B
EPA 9060
Total Organic Carbon
743
mg/kg
648
05/22/15 14:04
EPA 9060
Total Organic Carbon
762
mg/kg
652
05/22/15 14:10
EPA 9060
Total Organic Carbon
693
mg/kg
644
05/22/15 14:16
EPA 9060
Total Organic Carbon
768
mg/kg
650
05/22/15 14:23
EPA 9060
Mean Total Organic Carbon
741
mg/kg
649
05/22/15 14:04
EPA 9060
RSD%
4.6
%
05/22/15 14:04
92247913004
2015012928
EPA 6010
Aluminum
4250
mg/kg
33.3
05/10/15 18:55
EPA 6010
Barium
18.1
mg/kg
3.3
05/10/15 18:55
EPA 6010
Chromium
4.3
mg/kg
1.7
05/10/15 18:55
EPA 6010
Copper
4.7
mg/kg
1.7
05/10/15 18:55
EPA 6010
Iron
13000
mg/kg
13.3
05/10/15 18:55
EPA 6010
Magnesium
305
mg/kg
166
05/10/15 18:55
EPA 6010
Manganese
19.4
mg/kg
1.7
05/10/15 18:55
EPA 6010
Zinc
9.4
mg/kg
6.7
05/10/15 18:55
EPA6020
Lead
6.3J
mg/kg
6.7
05/11/1513:51
EPA6020
Vanadium
10.2
mg/kg
6.7
05/11/1513:51
EPA 7471
Mercury
0.011
mg/kg
0.010
05/09/15 18:25
ASTM D2974-87
Percent Moisture
21.2
%
0.10
05/11/15 10:34
REPORT OF LABORATORY ANALYSIS
Qualifiers
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 9 of 88

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800�Srpyo"Je. Suite 100
Huntersville, NC 28078
[phone]
Project: J15050012
Pace Project No.: 92247913
Lab Sample ID Client Sample ID
Method Parameters
SUMMARY OF DETECTION
Result Units Report Limit Analyzed Qualifiers
92247913004
2015012928
EPA 9045
pH at 25 Degrees C
4.1
Std. Units
0.10
05/05/15 14:25
EPA 300.0
Sulfate
7.7
mg/L
2.5
05/15/15 00:01
EPA 9060
Total Organic Carbon
14100
mg/kg
759
05/22/15 14:30
EPA 9060
Total Organic Carbon
4540
mg/kg
762
05/22/15 14:36
EPA 9060
Total Organic Carbon
2820
mg/kg
768
05/22/15 14:43
EPA 9060
Total Organic Carbon
4720
mg/kg
757
05/22/15 14:48
EPA 9060
Mean Total Organic Carbon
6550
mg/kg
761
05/22/15 14:30
EPA 9060
RSD%
78.2
%
05/22/15 14:30
92247913005
2015012929
EPA 6010
Aluminum
4130
mg/kg
33.7
05/10/15 19:12
EPA 6010
Barium
69.2
mg/kg
3.4
05/10/15 19:12
EPA 6010
Beryllium
0.26J
mg/kg
0.34
05/10/15 19:12
EPA 6010
Calcium
642
mg/kg
168
05/10/15 19:12
EPA 6010
Chromium
3.8
mg/kg
1.7
05/10/15 19:12
EPA 6010
Copper
4.0
mg/kg
1.7
05/10/15 19:12
EPA 6010
Iron
7250
mg/kg
13.5
05/10/15 19:12
EPA 6010
Magnesium
1380
mg/kg
168
05/10/15 19:12
EPA 6010
Manganese
392
mg/kg
1.7
05/10/15 19:12
EPA 6010
Nickel
3.9
mg/kg
1.7
05/10/15 19:12
EPA 6010
Potassium
227J
mg/kg
337
05/10/15 19:12
EPA 6010
Strontium
9.5
mg/kg
3.4
05/10/15 19:12
EPA 6010
Zinc
18.9
mg/kg
6.7
05/10/15 19:12
EPA6020
Cobalt
4.3J
mg/kg
6.7
05/11/1514:07
EPA 6020
Lead
8.1
mg/kg
6.7
05/11 /15 14:07
EPA6020
Vanadium
12.1
mg/kg
6.7
05/11/1514:07
EPA 7471
Mercury
0.018
mg/kg
0.011
05/09/15 18:31
ASTM D2974-87
Percent Moisture
29.3
%
0.10
05/11/15 10:34
EPA 9045
pH at 25 Degrees C
5.0
Std. Units
0.10
05/06/15 13:00
EPA 300.0
Sulfate
7.1
mg/L
2.8
05/15/15 00:15
EPA 9060
Total Organic Carbon
12700
mg/kg
846
05/26/15 13:27
EPA 9060
Total Organic Carbon
13900
mg/kg
852
05/26/15 13:33
EPA 9060
Total Organic Carbon
12400
mg/kg
843
05/26/15 13:39
EPA 9060
Total Organic Carbon
14600
mg/kg
852
05/26/15 13:44
EPA 9060
Mean Total Organic Carbon
13400
mg/kg
848
05/26/15 13:27
EPA 9060
RSD%
7.5
%
05/26/15 13:27
92247913006
2015012930
EPA 6010
Aluminum
4480
mg/kg
31.3
05/10/15 19:16
EPA 6010
Barium
130
mg/kg
3.1
05/10/15 19:16
EPA 6010
Beryllium
0.30J
mg/kg
0.31
05/10/15 19:16
EPA 6010
Calcium
1190
mg/kg
157
05/10/15 19:16
EPA 6010
Chromium
3.8
mg/kg
1.6
05/10/15 19:16
EPA 6010
Copper
2.6
mg/kg
1.6
05/10/15 19:16
EPA 6010
Iron
3100
mg/kg
12.5
05/10/15 19:16
EPA 6010
Magnesium
1400
mg/kg
157
05/10/15 19:16
EPA 6010
Manganese
47.7
mg/kg
1.6
05/10/15 19:16
EPA 6010
Nickel
4.6
mg/kg
1.6
05/10/15 19:16
REPORT OF LABORATORY ANALYSIS
B
1g
D6
B
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 10 of 88

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800Airpyo"Je. Suite 100
Huntersville, NC 28078
[phone]
Project: J15050012
Pace Project No.: 92247913
Lab Sample ID Client Sample ID
Method Parameters
SUMMARY OF DETECTION
Result Units Report Limit Analyzed
92247913006
2015012930
EPA 6010
Sodium
957
mg/kg
313
05/10/15 19:16
EPA 6010
Strontium
19.4
mg/kg
3.1
05/10/15 19:16
EPA 6010
Zinc
10.5
mg/kg
6.3
05/10/15 19:16
EPA6020
Lead
5.9J
mg/kg
6.3
05/11/1514:12
EPA6020
Vanadium
13.6
mg/kg
6.3
05/11/1514:12
EPA 7471
Mercury
0.034
mg/kg
0.0098
05/09/15 18:35
ASTM D2974-87
Percent Moisture
18.0
%
0.10
05/11/15 10:34
EPA 9045
pH at 25 Degrees C
6.9
Std. Units
0.10
05/06/15 13:00
EPA 300.0
Sulfate
9.1
mg/L
2.4
05/15/15 00:28
SM 4500-CI-E
Chloride
14.0
mg/L
6.1
05/14/15 06:06
EPA 9060
Total Organic Carbon
1260
mg/kg
736
05/26/15 13:50
EPA 9060
Total Organic Carbon
1210
mg/kg
738
05/26/15 13:56
EPA 9060
Total Organic Carbon
1150
mg/kg
737
05/26/15 14:03
EPA 9060
Total Organic Carbon
1120
mg/kg
727
05/26/15 14:09
EPA 9060
Mean Total Organic Carbon
1190
mg/kg
734
05/26/15 13:50
EPA 9060
RSD%
5.2
%
05/26/15 13:50
92247913007
2015012931
EPA 6010
Aluminum
1970
mg/kg
33.5
05/10/15 19:20
EPA 6010
Barium
14.3
mg/kg
3.3
05/10/15 19:20
EPA 6010
Beryllium
0.17J
mg/kg
0.33
05/10/15 19:20
EPA 6010
Calcium
283
mg/kg
167
05/10/15 19:20
EPA 6010
Chromium
1.9
mg/kg
1.7
05/10/15 19:20
EPA 6010
Copper
2.1
mg/kg
1.7
05/10/15 19:20
EPA 6010
Iron
1390
mg/kg
13.4
05/10/15 19:20
EPA 6010
Magnesium
321
mg/kg
167
05/10/15 19:20
EPA 6010
Manganese
48.0
mg/kg
1.7
05/10/15 19:20
EPA 6010
Nickel
1 AJ
mg/kg
1.7
05/10/15 19:20
EPA 6010
Strontium
3.5
mg/kg
3.3
05/10/15 19:20
EPA 6010
Zinc
7.2
mg/kg
6.7
05/10/15 19:20
EPA6020
Cobalt
6.OJ
mg/kg
6.7
05/11/15 14:15
EPA6020
Vanadium
7.6
mg/kg
6.7
05/11/15 14:15
ASTM D2974-87
Percent Moisture
22.2
%
0.10
05/11/15 10:34
EPA 9045
pH at 25 Degrees C
6.6
Std. Units
0.10
05/06/15 13:00
EPA 300.0
Sulfate
6.1
mg/L
2.6
05/15/15 00:42
EPA 9060
Total Organic Carbon
441J
mg/kg
766
05/26/15 14:20
EPA 9060
Total Organic Carbon
452J
mg/kg
774
05/26/15 14:26
EPA 9060
Total Organic Carbon
465J
mg/kg
773
05/26/15 14:31
EPA 9060
Mean Total Organic Carbon
435J
mg/kg
772
05/26/15 14:15
EPA 9060
RSD%
8.4
%
05/26/15 14:15
92247913008
2015012934
EPA 6020A
Aluminum
127
ug/L
10.0
05/12/15 02:33
EPA 6020A
Antimony
0.32J
ug/L
0.50
05/12/15 02:33
EPA 6020A
Barium
1.5
ug/L
0.30
05/12/15 02:33
EPA 6020A
Calcium
346
ug/L
40.0
05/12/15 02:33
EPA 6020A
Chromium
0.94
ug/L
0.50
05/12/15 02:33
EPA 6020A
Cobalt
0.16J
ug/L
0.50
05/12/15 02:33
REPORT OF LABORATORY ANALYSIS
B
B
Qualifiers
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 11 of 88

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800Airpyo"Je. Suite 100
Huntersville, NC 28078
[phone]
Project: J15050012
Pace Project No.: 92247913
Lab Sample ID Client Sample ID
Method Parameters
SUMMARY OF DETECTION
Result Units Report Limit Analyzed
92247913008
2015012934
EPA 6020A
Copper
0.45J
ug/L
1.0
05/12/15 02:33
EPA 6020A
Iron
260
ug/L
50.0
05/12/15 02:33
EPA 6020A
Lead
0.11
ug/L
0.10
05/12/15 02:33
EPA 6020A
Magnesium
48.6
ug/L
10.0
05/12/15 02:33
EPA 6020A
Manganese
6.3
ug/L
0.50
05/12/15 02:33
EPA 6020A
Molybdenum
0.20J
ug/L
0.50
05/12/15 02:33
EPA 6020A
Potassium
42.3J
ug/L
50.0
05/12/15 02:33
EPA 6020A
Sodium
55.5
ug/L
50.0
05/12/15 02:33
EPA 6020A
Strontium
0.80
ug/L
0.50
05/12/15 02:33
92247913009
2015012935
EPA 6020A
Aluminum
8080
ug/L
10.0
05/12/15 02:09
EPA 6020A
Antimony
0.29J
ug/L
0.50
05/12/15 02:09
EPA 6020A
Arsenic
0.57
ug/L
0.50
05/12/15 02:09
EPA 6020A
Barium
91.9
ug/L
0.30
05/12/15 02:09
EPA 6020A
Beryllium
0.28
ug/L
0.20
05/12/15 02:09
EPA 6020A
Boron
1.91
ug/L
5.0
05/12/15 02:09
EPA 6020A
Cadmium
0.028J
ug/L
0.080
05/12/15 02:09
EPA 6020A
Calcium
1840
ug/L
40.0
05/12/15 02:09
EPA 6020A
Chromium
6.8
ug/L
0.50
05/12/15 02:09
EPA 6020A
Cobalt
7.4
ug/L
0.50
05/12/15 02:09
EPA 6020A
Copper
5.9
ug/L
1.0
05/12/15 02:09
EPA 6020A
Iron
12800
ug/L
50.0
05/12/15 02:09
EPA 6020A
Lead
3.8
ug/L
0.10
05/12/15 02:09
EPA 6020A
Magnesium
2330
ug/L
10.0
05/12/15 02:09
EPA 6020A
Manganese
355
ug/L
0.50
05/12/15 02:09
EPA 6020A
Molybdenum
0.59
ug/L
0.50
05/12/15 02:09
EPA 6020A
Nickel
3.4
ug/L
0.50
05/12/15 02:09
EPA 6020A
Potassium
1820
ug/L
50.0
05/12/15 02:09
EPA 6020A
Selenium
0.31 J
ug/L
0.50
05/12/15 02:09
EPA 6020A
Sodium
1020
ug/L
50.0
05/12/15 02:09
EPA 6020A
Strontium
16.2
ug/L
0.50
05/12/15 02:09
EPA 6020A
Thallium
0.058J
ug/L
0.10
05/12/15 02:09
EPA 6020A
Vanadium
10.3
ug/L
1.0
05/12/15 16:20
EPA 6020A
Zinc
52.4
ug/L
5.0
05/12/15 02:09
92247913011
2015012925 SPLP
EPA 6020A
Aluminum
10200
ug/L
10.0
05/20/15 13:52
EPA 6020A
Arsenic
0.32J
ug/L
0.50
05/20/15 13:52
EPA 6020A
Barium
189
ug/L
0.30
05/20/15 13:52
EPA 6020A
Beryllium
0.22
ug/L
0.20
05/20/15 13:52
EPA 6020A
Boron
61.7
ug/L
5.0
05/20/15 13:52
EPA 6020A
Calcium
889
ug/L
40.0
05/20/15 13:52
EPA 6020A
Chromium
4.7
ug/L
0.50
05/20/15 13:52
EPA 6020A
Cobalt
0.88
ug/L
0.50
05/20/15 13:52
EPA 6020A
Copper
3.6
ug/L
1.0
05/20/15 13:52
EPA 6020A
Iron
8210
ug/L
50.0
05/20/15 13:52
EPA 6020A
Lead
1.7
ug/L
0.10
05/20/15 13:52
REPORT OF LABORATORY ANALYSIS
Qualifiers
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 12 of 88

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800Airpyo"Je. Suite 100
Huntersville, NC 28078
[phone]
Project: J15050012
Pace Project No.: 92247913
Lab Sample ID Client Sample ID
Method Parameters
SUMMARY OF DETECTION
Result Units Report Limit Analyzed
92247913011
2015012925 SPLP
EPA 6020A
Magnesium
802
ug/L
10.0
05/20/15 13:52
EPA 6020A
Manganese
36.3
ug/L
0.50
05/20/15 13:52
EPA 6020A
Molybdenum
0.28J
ug/L
0.50
05/20/15 13:52
EPA 6020A
Nickel
2.1
ug/L
0.50
05/20/15 13:52
EPA 6020A
Potassium
1440
ug/L
50.0
05/20/15 13:52
EPA 6020A
Sodium
3050
ug/L
50.0
05/20/15 13:52
EPA 6020A
Strontium
11.5
ug/L
0.50
05/20/15 13:52
EPA 6020A
Thallium
0.032J
ug/L
0.10
05/22/15 13:33
EPA 6020A
Vanadium
9.0
ug/L
1.0
05/20/15 13:52
EPA 6020A
Zinc
50.9
ug/L
5.0
05/20/15 13:52
92247913012
2015012926 SPLP
EPA 6020A
Aluminum
11600
ug/L
10.0
05/20/15 13:55
EPA 6020A
Arsenic
0.93
ug/L
0.50
05/20/15 13:55
EPA 6020A
Barium
228
ug/L
0.30
05/20/15 13:55
EPA 6020A
Beryllium
0.40
ug/L
0.20
05/20/15 13:55
EPA 6020A
Boron
72.4
ug/L
5.0
05/20/15 13:55
EPA 6020A
Cadmium
0.053J
ug/L
0.080
05/20/15 13:55
EPA 6020A
Calcium
1020
ug/L
40.0
05/20/15 13:55
EPA 6020A
Chromium
6.3
ug/L
0.50
05/20/15 13:55
EPA 6020A
Cobalt
2.0
ug/L
0.50
05/20/15 13:55
EPA 6020A
Copper
5.9
ug/L
1.0
05/20/15 13:55
EPA 6020A
Iron
10100
ug/L
50.0
05/20/15 13:55
EPA 6020A
Lead
6.3
ug/L
0.10
05/20/15 13:55
EPA 6020A
Magnesium
1470
ug/L
10.0
05/20/15 13:55
EPA 6020A
Manganese
175
ug/L
0.50
05/20/15 13:55
EPA 6020A
Molybdenum
3.5
ug/L
0.50
05/20/15 13:55
EPA 6020A
Nickel
2.8
ug/L
0.50
05/20/15 13:55
EPA 6020A
Potassium
1920
ug/L
50.0
05/20/15 13:55
EPA 6020A
Sodium
4900
ug/L
50.0
05/20/15 13:55
EPA 6020A
Strontium
19.2
ug/L
0.50
05/20/15 13:55
EPA 6020A
Thallium
0.045J
ug/L
0.10
05/22/15 13:37
EPA 6020A
Vanadium
10.8
ug/L
1.0
05/20/15 13:55
EPA 6020A
Zinc
74.7
ug/L
5.0
05/20/15 13:55
92247913013
2015012927 SPLP
EPA 6020A
Aluminum
9070
ug/L
10.0
05/20/15 13:58
EPA 6020A
Antimony
0.27J
ug/L
0.50
05/20/15 13:58
EPA 6020A
Arsenic
4.3
ug/L
0.50
05/20/15 13:58
EPA 6020A
Barium
241
ug/L
0.30
05/20/15 13:58
EPA 6020A
Beryllium
0.73
ug/L
0.20
05/20/15 13:58
EPA 6020A
Boron
88.9
ug/L
5.0
05/20/15 13:58
EPA 6020A
Cadmium
0.032J
ug/L
0.080
05/20/15 13:58
EPA 6020A
Calcium
496
ug/L
40.0
05/20/15 13:58
EPA 6020A
Chromium
3.9
ug/L
0.50
05/20/15 13:58
EPA 6020A
Cobalt
15.9
ug/L
0.50
05/20/15 13:58
EPA 6020A
Copper
4.7
ug/L
1.0
05/20/15 13:58
EPA 6020A
Iron
10800
ug/L
50.0
05/20/15 13:58
REPORT OF LABORATORY ANALYSIS
Qualifiers
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 13 of 88

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980c&pyo"Je. Suite 100
Huntersville, NC 28078
[phone]
Project: J15050012
Pace Project No.: 92247913
Lab Sample ID Client Sample ID
Method Parameters
SUMMARY OF DETECTION
Result Units Report Limit Analyzed Qualifiers
92247913013
2015012927 SPLP
EPA 6020A
Lead
5.5
ug/L
0.10
05/20/15 13:58
EPA 6020A
Magnesium
1010
ug/L
10.0
05/20/15 13:58
EPA 6020A
Manganese
173
ug/L
0.50
05/20/15 13:58
EPA 6020A
Molybdenum
2.1
ug/L
0.50
05/20/15 13:58
EPA 6020A
Nickel
5.5
ug/L
0.50
05/20/15 13:58
EPA 6020A
Potassium
1230
ug/L
50.0
05/20/15 13:58
EPA 6020A
Selenium
0.42J
ug/L
0.50
05/20/15 13:58
EPA 6020A
Sodium
4910
ug/L
50.0
05/20/15 13:58
EPA 6020A
Strontium
10
ug/L
0.50
05/20/15 13:58
EPA 6020A
Thallium
0.049J
ug/L
0.10
05/22/15 13:42
EPA 6020A
Vanadium
10.2
ug/L
1.0
05/20/15 13:58
EPA 6020A
Zinc
88.8
ug/L
5.0
05/20/15 13:58
92247913014
2015012928 SPLP
EPA 6020A
Aluminum
16400
ug/L
10.0
05/20/15 14:06
EPA 6020A
Antimony
0.21J
ug/L
0.50
05/20/15 14:06
EPA 6020A
Arsenic
3.6
ug/L
0.50
05/20/15 14:06
EPA 6020A
Barium
532
ug/L
3.0
05/20/15 14:45
EPA 6020A
Beryllium
0.29
ug/L
0.20
05/20/15 14:06
EPA 6020A
Boron
266
ug/L
5.0
05/20/15 14:06
EPA 6020A
Cadmium
0.028J
ug/L
0.080
05/20/15 14:06
EPA 6020A
Calcium
483
ug/L
40.0
05/20/15 14:06
EPA 6020A
Chromium
12.1
ug/L
0.50
05/20/15 14:06
EPA 6020A
Cobalt
3.1
ug/L
0.50
05/20/15 14:06
EPA 6020A
Copper
10.7
ug/L
1.0
05/20/15 14:06
EPA 6020A
Iron
26000
ug/L
500
05/20/15 14:45
EPA 6020A
Lead
8.3
ug/L
0.10
05/20/15 14:06
EPA 6020A
Magnesium
953
ug/L
10.0
05/20/15 14:06
EPA 6020A
Manganese
42.7
ug/L
0.50
05/20/15 14:06
EPA 6020A
Molybdenum
0.51
ug/L
0.50
05/20/15 14:06
EPA 6020A
Nickel
4.0
ug/L
0.50
05/20/15 14:06
EPA 6020A
Potassium
1270
ug/L
50.0
05/20/15 14:06
EPA 6020A
Selenium
0.32J
ug/L
0.50
05/20/15 14:06
EPA 6020A
Sodium
3540
ug/L
50.0
05/20/15 14:06
EPA 6020A
Strontium
12.7
ug/L
0.50
05/20/15 14:06
EPA 6020A
Thallium
0.14
ug/L
0.10
05/22/15 13:46
EPA 6020A
Vanadium
25.6
ug/L
1.0
05/20/15 14:06
EPA 6020A
Zinc
328
ug/L
5.0
05/20/15 14:06
92247913015
2015012929 SPLP
EPA 6020A
Aluminum
31900
ug/L
100
05/20/15 14:47
EPA 6020A
Arsenic
2.3
ug/L
0.50
05/20/15 14:08
EPA 6020A
Barium
425
ug/L
0.30
05/20/15 14:08
EPA 6020A
Beryllium
0.59
ug/L
0.20
05/20/15 14:08
EPA 6020A
Boron
129
ug/L
5.0
05/20/15 14:08
EPA 6020A
Cadmium
0.52
ug/L
0.080
05/20/15 14:08
EPA 6020A
Calcium
1350
ug/L
40.0
05/20/15 14:08
EPA 6020A
Chromium
14.9
ug/L
0.50
05/20/15 14:08
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 14 of 88

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800Airpyo"Je. Suite 100
Huntersville, NC 28078
[phone]
Project: J15050012
Pace Project No.: 92247913
Lab Sample ID Client Sample ID
Method Parameters
SUMMARY OF DETECTION
Result Units Report Limit Analyzed Qualifiers
92247913015
2015012929 SPLP
EPA 6020A
Cobalt
5.5
ug/L
0.50
05/20/15 14:08
EPA 6020A
Copper
9.8
ug/L
1.0
05/20/15 14:08
EPA 6020A
Iron
19600
ug/L
50.0
05/20/15 14:08
EPA 6020A
Lead
8.3
ug/L
0.10
05/20/15 14:08
EPA 6020A
Magnesium
2520
ug/L
10.0
05/20/15 14:08
EPA 6020A
Manganese
405
ug/L
0.50
05/20/15 14:08
EPA 6020A
Molybdenum
0.14J
ug/L
0.50
05/20/15 14:08
EPA 6020A
Nickel
9.6
ug/L
0.50
05/20/15 14:08
EPA 6020A
Potassium
1310
ug/L
50.0
05/20/15 14:08
EPA 6020A
Selenium
0.40J
ug/L
0.50
05/20/15 14:08
EPA 6020A
Sodium
3110
ug/L
50.0
05/20/15 14:08
EPA 6020A
Strontium
20.9
ug/L
0.50
05/20/15 14:08
EPA 6020A
Thallium
0.20
ug/L
0.10
05/22/15 13:51
EPA 6020A
Vanadium
41.2
ug/L
1.0
05/20/15 14:08
EPA 6020A
Zinc
180
ug/L
5.0
05/20/15 14:08
92247913016
2015012930 SPLP
EPA 6020A
Aluminum
205000
ug/L
100
05/20/15 14:50
EPA 6020A
Arsenic
6.7
ug/L
0.50
05/20/15 14:31
EPA 6020A
Barium
2350
ug/L
3.0
05/20/15 14:50
EPA 6020A
Beryllium
4.0
ug/L
0.20
05/20/15 14:31
EPA 6020A
Boron
79.9
ug/L
5.0
05/20/15 14:31
EPA 6020A
Cadmium
0.11
ug/L
0.080
05/20/15 14:31
EPA 6020A
Calcium
10300
ug/L
40.0
05/20/15 14:31
EPA 6020A
Chromium
96.7
ug/L
0.50
05/20/15 14:31
EPA 6020A
Cobalt
38.2
ug/L
0.50
05/20/15 14:31
EPA 6020A
Copper
51.9
ug/L
1.0
05/20/15 14:31
EPA 6020A
Iron
160000
ug/L
500
05/20/15 14:50
EPA 6020A
Lead
84.2
ug/L
0.10
05/20/15 14:31
EPA 6020A
Magnesium
24600
ug/L
100
05/20/15 14:50
EPA 6020A
Manganese
427
ug/L
0.50
05/20/15 14:31
EPA 6020A
Molybdenum
0.11J
ug/L
0.50
05/20/15 14:31
EPA 6020A
Nickel
73.7
ug/L
0.50
05/20/15 14:31
EPA 6020A
Potassium
2660
ug/L
50.0
05/20/15 14:31
EPA 6020A
Selenium
1.6
ug/L
0.50
05/20/15 14:31
EPA 6020A
Sodium
25000
ug/L
500
05/20/15 14:50
EPA 6020A
Strontium
191
ug/L
0.50
05/20/15 14:31
EPA 6020A
Thallium
1.2
ug/L
0.10
05/20/15 14:31
EPA 6020A
Vanadium
275
ug/L
1.0
05/20/15 14:31
EPA 6020A
Zinc
388
ug/L
5.0
05/20/15 14:31
EPA7470A
Mercury
0.21
ug/L
0.20
05/21/1512:22
92247913017
2015012931 SPLP
EPA 6020A
Aluminum
28200
ug/L
100
05/20/15 14:53
EPA 6020A
Arsenic
2.2
ug/L
0.50
05/20/15 14:11
EPA 6020A
Barium
256
ug/L
0.30
05/20/15 14:11
EPA 6020A
Beryllium
1.3
ug/L
0.20
05/20/15 14:11
EPA 6020A
Boron
58.5
ug/L
5.0
05/20/15 14:11
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 15 of 88

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800hrpyo"Je. Suite 100
Huntersville, NC 28078
[phone]
Project: J15050012
Pace Project No.: 92247913
Lab Sample ID
Method
92247913017
EPA 6020A
EPA 6020A
EPA 6020A
EPA 6020A
EPA 6020A
EPA 6020A
EPA 6020A
EPA 6020A
EPA 6020A
EPA 6020A
EPA 6020A
EPA 6020A
EPA 6020A
EPA 6020A
EPA 6020A
EPA 6020A
Client Sample ID
Parameters
2015012931 SPLP
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Nickel
Potassium
Selenium
Sodium
Strontium
Thallium
Vanadium
Zinc
SUMMARY OF DETECTION
Result
UnitE
2040
ug/L
19.6
ug/L
7.2
ug/L
13.2
ug/L
13300
ug/L
7.7
ug/L
1710
ug/L
66.1
ug/L
11.5
ug/L
969
ug/L
0.28J
ug/L
2710
ug/L
29.3
ug/L
0.076J
ug/L
60.8
ug/L
94.1
ug/L
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Report Limit Analyzed Qualifiers
40.0
05/20/1514:11
0.50
05/20/1514:11
0.50
05/20/1514:11
1.0
05/20/1514:11
50.0
05/20/1514:11
0.10
05/20/1514:11
10.0
05/20/1514:11
0.50
05/20/1514:11
0.50
05/20/1514:11
50.0
05/20/1514:11
0.50
05/20/1514:11
50.0
05/20/1514:11
0.50
05/20/1514:11
0.10
05/22/1513:55
1.0
05/20/1514:11
5.0
05/20/1514:11
Page 16 of 88

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980aq8r6fy0"Je. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15050012
Pace Project No.: 92247913
Method: EPA 6010
Description: 6010 MET ICP
Client: Duke Energy
Date: May 28, 2015
General Information:
7 samples were analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 3050 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: MPRP/24040
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92247834001
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1208607)
• Aluminum
• Iron
• MSD (Lab ID: 1208608)
• Aluminum
• Iron
• Manganese
QC Batch: MPRP/24042
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 35186628008
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1208652)
• Aluminum
• Beryllium
• Boron
• Calcium
• Copper
REPORT OF LABORATORY ANALYSIS
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[phone]
PROJECT NARRATIVE
Project: J15050012
Pace Project No.: 92247913
Method: EPA 6010
Description: 6010 MET ICP
Client: Duke Energy
Date: May 28, 2015
QC Batch: MPRP/24042
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 35186628008
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• Iron
• Manganese
• Molybdenum
• Zinc
• MSD (Lab ID: 1208653)
• Aluminum
• Barium
• Boron
• Calcium
• Copper
• Iron
• Magnesium
• Manganese
• Molybdenum
• Strontium
R1: RPD value was outside control limits.
• MSD (Lab ID: 1208653)
• Iron
• Zinc
Additional Comments:
Batch Comments:
Samples in this batch were diluted due to the presence of high levels of non -target analytes or other matrix interference.
• QC Batch: ICP / 14693
• QC Batch: ICP / 14694
Analyte Comments:
QC Batch: MPRP/24042
E: Analyte concentration exceeded the calibration range. The reported result is estimated.
• MS (Lab ID: 1208652)
• Calcium
• MSD (Lab ID: 1208653)
• Calcium
REPORT OF LABORATORY ANALYSIS
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Pace Analytical Services, Inc.
980aq9r6fy0"Je. Suite 100
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[phone]
PROJECT NARRATIVE
Project: J15050012
Pace Project No.: 92247913
Method: EPA 6020
Description: 6020 MET ICPMS
Client: Duke Energy
Date: May 28, 2015
General Information:
7 samples were analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 3050 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: MPRP/24041
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92247834001
M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
• MS (Lab ID: 1208613)
• Antimony
• Cadmium
• Cobalt
• Vanadium
• MSD (Lab ID: 1208614)
• Antimony
• Cobalt
• Lead
• Selenium
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc.. Page 19 of 88

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Pace Analytical Services, Inc.
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[phone]
PROJECT NARRATIVE
Project: J15050012
Pace Project No.: 92247913
Method: EPA 6020
Description: 6020 MET ICPMS
Client: Duke Energy
Date: May 28, 2015
QC Batch: MPRP/24043
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92247913004
M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
• MS (Lab ID: 1208656)
• Antimony
• Arsenic
• Selenium
• Thallium
• MSD (Lab ID: 1208657)
• Antimony
• Arsenic
• Selenium
Additional Comments:
Batch Comments:
Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
• QC Batch: ICPM / 9756
• QC Batch: ICPM / 9757
Analyte Comments:
QC Batch: MPRP/24041
N2: The lab does not hold TNI accreditation for this parameter.
•2015012925 (Lab ID:92247913001)
• Antimony
•2015012926 (Lab ID:92247913002)
• Antimony
•2015012927 (Lab ID:92247913003)
• Antimony
• BLANK (Lab ID: 1208611)
• Antimony
• LCS (Lab ID: 1208612)
• Antimony
• MS (Lab ID: 1208613)
• Antimony
• MSD (Lab ID: 1208614)
• Antimony
QC Batch: MPRP/24043
N2: The lab does not hold TNI accreditation for this parameter.
•2015012928 (Lab ID:92247913004)
• Antimony
•2015012929 (Lab ID:92247913005)
• Antimony
•2015012930 (Lab ID:92247913006)
• Antimony
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc.. Page 20 of 88

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Pace Analytical Services, Inc.
9800Airpyo"Je. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15050012
Pace Project No.: 92247913
Method: EPA 6020
Description: 6020 MET ICPMS
Client: Duke Energy
Date: May 28, 2015
Analyte Comments:
QC Batch: MPRP/24043
N2: The lab does not hold TNI accreditation for this parameter.
•2015012931 (Lab ID:92247913007)
• Antimony
• BLANK (Lab ID: 1208654)
• Antimony
• LCS (Lab ID: 1208655)
• Antimony
• MS (Lab ID: 1208656)
• Antimony
• MSD (Lab ID: 1208657)
• Antimony
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 21 of 88

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Pace Analytical Services, Inc.
980agir6fy0"Je. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15050012
Pace Project No.: 92247913
Method: EPA 6020A
Description: 6020A MET ICPMS
Client: Duke Energy
Date: May 28, 2015
General Information:
10 samples were analyzed for EPA 6020A. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 3020 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: MPRP/54160
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92247913008
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1956666)
• Aluminum
• MSD (Lab ID: 1956667)
• Aluminum
QC Batch: MPRP/54474
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92249710021
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1968215)
• Aluminum
• Calcium
• Iron
• Zinc
• MSD (Lab ID: 1968216)
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc.. Page 22 of 88

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Pace Analytical Services, Inc.
980aq8r6fy0"Je. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15050012
Pace Project No.: 92247913
Method: EPA 6020A
Description: 6020A MET ICPMS
Client: Duke Energy
Date: May 28, 2015
QC Batch: MPRP/54474
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92249710021
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• Aluminum
R1: RPD value was outside control limits.
• MSD (Lab ID: 1968216)
• Aluminum
• Zinc
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc.. Page 23 of 88

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Pace Analytical Services, Inc.
9800*r6fy0"Je. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15050012
Pace Project No.: 92247913
Method: EPA 7470A
Description: 7470A Mercury
Client: Duke Energy
Date: May 28, 2015
General Information:
10 samples were analyzed for EPA 7470A. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 7470A with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc.. Page 24 of 88

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Pace Analytical Services, Inc.
980a�grpyo"Je. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15050012
Pace Project No.: 92247913
Method: EPA 7471
Description: 7471 Mercury
Client: Duke Energy
Date: May 28, 2015
General Information:
7 samples were analyzed for EPA 7471. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 7471 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc.. Page 25 of 88

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Pace Analytical Services, Inc.
980agir6fy0"Je. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15050012
Pace Project No.: 92247913
Method: EPA 9045
Description: 9045 pH Soil
Client: Duke Energy
Date: May 28, 2015
General Information:
7 samples were analyzed for EPA 9045. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
QC Batch: WET/37238
D6: The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits.
• DUP (Lab ID: 1450002)
• pH at 25 Degrees C
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc.. Page 26 of 88

aceAnaiXical
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Pace Analytical Services, Inc.
98004tbirWY051e. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15050012
Pace Project No.: 92247913
Method: EPA 300.0
Description: 300.0 IC Anions, SPLP
Client: Duke Energy
Date: May 28, 2015
General Information:
7 samples were analyzed for EPA 300.0. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
QC Batch: WETA/22924
B: Analyte was detected in the associated method blank.
• BLANK for HBN 263861 [WETA/229 (Lab ID: 1459398)
• Sulfate
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: WETA/22924
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92247374003,92247911005
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1459402)
• Sulfate
• MSD (Lab ID: 1459403)
• Sulfate
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc.. Page 27 of 88

aceAnaiXical
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Pace Analytical Services, Inc.
98004irWY051e. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15050012
Pace Project No.: 92247913
Method: EPA 353.2
Description: 353.2 Nitrogen, NO2/NO3, SPLP
Client: Duke Energy
Date: May 28, 2015
General Information:
7 samples were analyzed for EPA 353.2. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
1-11: Analysis conducted outside the EPA method holding time.
•2015012925 (Lab ID:92247913001)
•2015012926 (Lab ID:92247913002)
•2015012927 (Lab ID:92247913003)
•2015012928 (Lab ID:92247913004)
•2015012929 (Lab ID:92247913005)
•2015012930 (Lab ID:92247913006)
•2015012931 (Lab ID:92247913007)
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc.. Page 28 of 88

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Pace Analytical Services, Inc.
98004t WeYdle. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15050012
Pace Project No.: 92247913
Method: SM 4500-CI-E
Description: 4500 Chloride, SPLP
Client: Duke Energy
Date: May 28, 2015
General Information:
7 samples were analyzed for SM 4500-CI-E. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 29 of 88

aceAnaiXical
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Pace Analytical Services, Inc.
98004WeY051e. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15050012
Pace Project No.: 92247913
Method: EPA 9056
Description: 9056 IC Anions
Client: Duke Energy
Date: May 28, 2015
General Information:
7 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
Analyte Comments:
QC Batch: WETA/46118
DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
•2015012925 (Lab ID:92247913001)
• Chloride
• Sulfate
•2015012926 (Lab ID:92247913002)
• Chloride
• Sulfate
•2015012927 (Lab ID:92247913003)
• Chloride
• Sulfate
•2015012928 (Lab ID:92247913004)
• Chloride
• Sulfate
•2015012929 (Lab ID:92247913005)
• Chloride
• Sulfate
•2015012930 (Lab ID:92247913006)
• Chloride
• Sulfate
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc.. Page 30 of 88

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
98004t�ir6fY051e. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15050012
Pace Project No.: 92247913
Method: EPA 9056
Description: 9056 IC Anions
Client: Duke Energy
Date: May 28, 2015
Analyte Comments:
QC Batch: WETA/46118
DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
•2015012931 (Lab ID:92247913007)
• Chloride
• Sulfate
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc.. Page 31 of 88

aceAnaiXical
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Pace Analytical Services, Inc.
980041 WeY051e. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15050012
Pace Project No.: 92247913
Method: EPA 9056
Description: 9056 IC Anions 48hr
Client: Duke Energy
Date: May 28, 2015
General Information:
7 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
1-13: Sample was received or analysis requested beyond the recognized method holding time.
•2015012925 (Lab ID:92247913001)
•2015012926 (Lab ID:92247913002)
•2015012927 (Lab ID:92247913003)
•2015012928 (Lab ID:92247913004)
•2015012929 (Lab ID:92247913005)
•2015012930 (Lab ID:92247913006)
•2015012931 (Lab ID:92247913007)
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 32 of 88

aceAnaiXical
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Pace Analytical Services, Inc.
98004t WeY051e. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15050012
Pace Project No.: 92247913
Method: EPA 9060
Description: Total Organic Carbon Quad
Client: Duke Energy
Date: May 28, 2015
General Information:
7 samples were analyzed for EPA 9060. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
Analyte Comments:
QC Batch: WETA/28572
1g: % RSD > 40
•2015012928 (Lab ID:92247913004)
• RSD%
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc.. Page 33 of 88

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Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15050012
Pace Project No.: 92247913
Sample: 2015012925 Lab ID: 92247913001 Collected: 04/25/15 16:15 Received: 05/01/15 12:03 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Aluminum
Barium
Beryllium
Boron
Calcium
Chromium
Copper
Iron
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Sodium
Strontium
Zinc
6020 MET ICPMS
Antimony
Arsenic
Cadmium
Cobalt
Lead
Selenium
Thallium
Vanadium
7471 Mercury
Mercury
Percent Moisture
Percent Moisture
9045 pH Soil
pH at 25 Degrees C
300.0 IC Anions, SPLP
Sulfate
353.2 Nitrogen, NO2/NO3, SPLP
Nitrogen, Nitrate
4500 Chloride, SPLP
Chloride
Date: 05/28/2015 07:43 AM
Analytical Method: EPA 6010 Preparation Method: EPA 3050
9980
mg/kg
28.5
14.3
5
05/09/15 09:34
05/10/15 17:50
7429-90-5
50.6
mg/kg
2.9
1.4
5
05/09/15 09:34
05/10/15 17:50
7440-39-3
0.32
mg/kg
0.29
0.14
5
05/09/15 09:34
05/10/15 17:50
7440-41-7
ND
mg/kg
14.3
7.1
5
05/09/15 09:34
05/10/15 17:50
7440-42-8
2950
mg/kg
143
71.3
5
05/09/15 09:34
05/10/15 17:50
7440-70-2
5.1
mg/kg
1.4
0.71
5
05/09/15 09:34
05/10/15 17:50
7440-47-3
10.4
mg/kg
1.4
0.71
5
05/09/15 09:34
05/10/15 17:50
7440-50-8
19500
mg/kg
11.4
5.7
5
05/09/15 09:34
05/10/15 17:50
7439-89-6
3090
mg/kg
143
71.3
5
05/09/15 09:34
05/10/15 17:50
7439-95-4
371
mg/kg
1.4
0.71
5
05/09/15 09:34
05/10/15 17:50
7439-96-5
ND
mg/kg
2.9
1.4
5
05/09/15 09:34
05/10/15 17:50
7439-98-7
2.3
mg/kg
1.4
0.71
5
05/09/15 09:34
05/10/15 17:50
7440-02-0
1010
mg/kg
285
143
5
05/09/15 09:34
05/10/15 17:50
7440-09-7
ND
mg/kg
285
143
5
05/09/15 09:34
05/10/15 17:50
7440-23-5
25.6
mg/kg
2.9
1.4
5
05/09/15 09:34
05/10/15 17:50
7440-24-6
83.3
mg/kg
5.7
2.9
5
05/09/15 09:34
05/10/15 17:50
7440-66-6
Analytical
Method: EPA 6020 Preparation
Method: EPA 3050
ND
mg/kg
5.7
2.9
100
05/09/15 09:34
05/11/15 13:37
7440-36-0
ND
mg/kg
5.7
2.9
100
05/09/15 09:34
05/11/15 13:37
7440-38-2
ND
mg/kg
0.68
0.34
100
05/09/15 09:34
05/11/15 13:37
7440-43-9
7.3
mg/kg
5.7
2.9
100
05/09/15 09:34
05/11/15 13:37
7440-48-4
6.8
mg/kg
5.7
2.9
100
05/09/15 09:34
05/11/15 13:37
7439-92-1
ND
mg/kg
5.7
2.9
100
05/09/15 09:34
05/11/15 13:37
7782-49-2
ND
mg/kg
5.7
2.9
100
05/09/15 09:34
05/11/15 13:37
7440-28-0
11.0
mg/kg
5.7
2.9
100
05/09/15 09:34
05/11/15 13:37
7440-62-2
Analytical Method: EPA 7471 Preparation Method: EPA 7471
ND mg/kg 0.0090 0.0045 1 05/09/15 09:41 05/09/15 18:05 7439-97-6
Analytical Method: ASTM D2974-87
9.2 % 0.10 0.10 1 05/11/1510:33
Analytical Method: EPA 9045
6.7 Std. Units 0.10 0.10 1 05/05/15 14:25
N2
Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 05/11/15 03:30
4.4 mg/L 2.2 1.1 1 05/14/15 22:53 14808-79-8 B
Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 05/11/15 03:30
ND mg/L 0.22 0.22 1 05/15/15 21:23 H1
Analytical Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 05/11/15 03:30
ND mg/L 5.5 2.8 1 05/14/15 06:01 16887-00-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 34 of 88

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800AWleY051e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15050012
Pace Project No.: 92247913
Sample: 2015012925 Lab ID: 92247913001 Collected: 04/25/15 16:15 Received: 05/01/15 12:03 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
9056 IC Anions Analytical Method: EPA 9056
Chloride
ND mg/kg
274
137
5
05/06/1516:48
16887-00-6 D3
Sulfate
ND mg/kg
274
137
5
05/06/1516:48
14808-79-8 D3
9056 IC Anions 48hr
Analytical Method: EPA 9056
Nitrate as N
ND mg/kg
27.4
13.7
5
05/06/15 16:48
14797-55-8 H3
Total Organic Carbon Quad
Analytical Method: EPA 9060
Total Organic Carbon
339J mg/kg
659
330
1
05/22/15 11:08
7440-44-0
Total Organic Carbon
ND mg/kg
664
332
1
05/22/15 11:14
7440-44-0
Total Organic Carbon
ND mg/kg
660
330
1
05/22/15 11:20
7440-44-0
Total Organic Carbon
ND mg/kg
657
328
1
05/22/15 11:27
7440-44-0
Mean Total Organic Carbon
ND mg/kg
660
330
1
05/22/15 11:08
7440-44-0
Surrogates
RSD%
5.0 %
1
05/22/15 11:08
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/28/2015 07:43 AM without the written consent of Pace Analytical Services, Inc..
Page 35 of 88

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800AWleY051e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15050012
Pace Project No.: 92247913
Sample: 2015012926 Lab ID: 92247913002 Collected: 04/25/15 16:10 Received: 05/01/15 12:03 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Aluminum
Barium
Beryllium
Boron
Calcium
Chromium
Copper
Iron
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Sodium
Strontium
Zinc
6020 MET ICPMS
Antimony
Arsenic
Cadmium
Cobalt
Lead
Selenium
Thallium
Vanadium
7471 Mercury
Mercury
Percent Moisture
Percent Moisture
9045 pH Soil
pH at 25 Degrees C
300.0 IC Anions, SPLP
Sulfate
353.2 Nitrogen, NO2/NO3, SPLP
Nitrogen, Nitrate
4500 Chloride, SPLP
Chloride
Date: 05/28/2015 07:43 AM
Analytical Method: EPA 6010 Preparation Method: EPA 3050
9700
mg/kg
28.7
14.4
5
05/09/15 09:34
05/10/15 17:54
7429-90-5
224
mg/kg
2.9
1.4
5
05/09/15 09:34
05/10/15 17:54
7440-39-3
0.73
mg/kg
0.29
0.14
5
05/09/15 09:34
05/10/15 17:54
7440-41-7
ND
mg/kg
14.4
7.2
5
05/09/15 09:34
05/10/15 17:54
7440-42-8
2750
mg/kg
144
71.8
5
05/09/15 09:34
05/10/15 17:54
7440-70-2
5.0
mg/kg
1.4
0.72
5
05/09/15 09:34
05/10/15 17:54
7440-47-3
17.4
mg/kg
1.4
0.72
5
05/09/15 09:34
05/10/15 17:54
7440-50-8
24500
mg/kg
11.5
5.7
5
05/09/15 09:34
05/10/15 17:54
7439-89-6
3420
mg/kg
144
71.8
5
05/09/15 09:34
05/10/15 17:54
7439-95-4
1140
mg/kg
1.4
0.72
5
05/09/15 09:34
05/10/15 17:54
7439-96-5
ND
mg/kg
2.9
1.4
5
05/09/15 09:34
05/10/15 17:54
7439-98-7
5.7
mg/kg
1.4
0.72
5
05/09/15 09:34
05/10/15 17:54
7440-02-0
427
mg/kg
287
144
5
05/09/15 09:34
05/10/15 17:54
7440-09-7
338
mg/kg
287
144
5
05/09/15 09:34
05/10/15 17:54
7440-23-5
35.8
mg/kg
2.9
1.4
5
05/09/15 09:34
05/10/15 17:54
7440-24-6
154
mg/kg
5.7
2.9
5
05/09/15 09:34
05/10/15 17:54
7440-66-6
Analytical
Method: EPA 6020 Preparation
Method: EPA 3050
ND
mg/kg
5.7
2.9
100
05/09/15 09:34
05/11/15 13:40
7440-36-0
ND
mg/kg
5.7
2.9
100
05/09/15 09:34
05/11/15 13:40
7440-38-2
ND
mg/kg
0.69
0.34
100
05/09/15 09:34
05/11/15 13:40
7440-43-9
11.4
mg/kg
5.7
2.9
100
05/09/15 09:34
05/11/15 13:40
7440-48-4
26.1
mg/kg
5.7
2.9
100
05/09/15 09:34
05/11/15 13:40
7439-92-1
ND
mg/kg
5.7
2.9
100
05/09/15 09:34
05/11/15 13:40
7782-49-2
ND
mg/kg
5.7
2.9
100
05/09/15 09:34
05/11/15 13:40
7440-28-0
10.8
mg/kg
5.7
2.9
100
05/09/15 09:34
05/11/15 13:40
7440-62-2
Analytical Method: EPA 7471 Preparation Method: EPA 7471
0.012 mg/kg 0.0092 0.0046 1 05/09/15 09:41 05/09/15 18:07 7439-97-6
Analytical Method: ASTM D2974-87
13.4 % 0.10 0.10 1 05/11/1510:33
Analytical Method: EPA 9045
6.7 Std. Units 0.10 0.10 1 05/05/15 14:25
N2
Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 05/11/15 03:30
4.7 mg/L 2.3 1.2 1 05/14/15 23:34 14808-79-8 B
Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 05/11/15 03:30
ND mg/L 0.23 0.23 1 05/15/15 21:24 H1
Analytical Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 05/11/15 03:30
ND mg/L 5.8 2.9 1 05/14/15 06:03 16887-00-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 36 of 88

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
98005k8r6fy0"Je. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15050012
Pace Project No.: 92247913
Sample: 2015012926 Lab ID: 92247913002 Collected: 04/25/15 16:10 Received: 05/01/15 12:03 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
9056 IC Anions Analytical Method: EPA 9056
Chloride
ND mg/kg
291
145
5
05/06/1517:10
16887-00-6 D3
Sulfate
ND mg/kg
291
145
5
05/06/1517:10
14808-79-8 D3
9056 IC Anions 48hr
Analytical Method: EPA 9056
Nitrate as N
ND mg/kg
29.1
14.5
5
05/06/15 17:10
14797-55-8 H3
Total Organic Carbon Quad
Analytical Method: EPA 9060
Total Organic Carbon
546J mg/kg
694
347
1
05/22/15 13:41
7440-44-0
Total Organic Carbon
593J mg/kg
698
349
1
05/22/15 13:47
7440-44-0
Total Organic Carbon
504J mg/kg
697
348
1
05/22/15 13:52
7440-44-0
Total Organic Carbon
655J mg/kg
697
348
1
05/22/15 13:59
7440-44-0
Mean Total Organic Carbon
575J mg/kg
696
348
1
05/22/15 13:41
7440-44-0
Surrogates
RSD%
11.2 %
1
05/22/15 13:41
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/28/2015 07:43 AM without the written consent of Pace Analytical Services, Inc..
Page 37 of 88

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800q�irpyo"Je. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15050012
Pace Project No.: 92247913
Sample: 2015012927 Lab ID: 92247913003 Collected: 04/25/15 16:05 Received: 05/01/15 12:03 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Aluminum
Barium
Beryllium
Boron
Calcium
Chromium
Copper
Iron
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Sodium
Strontium
Zinc
6020 MET ICPMS
Antimony
Arsenic
Cadmium
Cobalt
Lead
Selenium
Thallium
Vanadium
7471 Mercury
Mercury
Percent Moisture
Percent Moisture
9045 pH Soil
pH at 25 Degrees C
300.0 IC Anions, SPLP
Sulfate
353.2 Nitrogen, NO2/NO3, SPLP
Nitrogen, Nitrate
4500 Chloride, SPLP
Chloride
Date: 05/28/2015 07:43 AM
Analytical Method: EPA 6010 Preparation Method: EPA 3050
7720
mg/kg
26.7
13.3
5
05/09/15 09:34
05/10/15 17:58
7429-90-5
155
mg/kg
2.7
1.3
5
05/09/15 09:34
05/10/15 17:58
7440-39-3
1.2
mg/kg
0.27
0.13
5
05/09/15 09:34
05/10/15 17:58
7440-41-7
ND
mg/kg
13.3
6.7
5
05/09/15 09:34
05/10/15 17:58
7440-42-8
979
mg/kg
133
66.7
5
05/09/15 09:34
05/10/15 17:58
7440-70-2
4.3
mg/kg
1.3
0.67
5
05/09/15 09:34
05/10/15 17:58
7440-47-3
8.8
mg/kg
1.3
0.67
5
05/09/15 09:34
05/10/15 17:58
7440-50-8
20000
mg/kg
10.7
5.3
5
05/09/15 09:34
05/10/15 17:58
7439-89-6
2500
mg/kg
133
66.7
5
05/09/15 09:34
05/10/15 17:58
7439-95-4
324
mg/kg
1.3
0.67
5
05/09/15 09:34
05/10/15 17:58
7439-96-5
3.3
mg/kg
2.7
1.3
5
05/09/15 09:34
05/10/15 17:58
7439-98-7
8.4
mg/kg
1.3
0.67
5
05/09/15 09:34
05/10/15 17:58
7440-02-0
237J
mg/kg
267
133
5
05/09/15 09:34
05/10/15 17:58
7440-09-7
166J
mg/kg
267
133
5
05/09/15 09:34
05/10/15 17:58
7440-23-5
15.1
mg/kg
2.7
1.3
5
05/09/15 09:34
05/10/15 17:58
7440-24-6
67.8
mg/kg
5.3
2.7
5
05/09/15 09:34
05/10/15 17:58
7440-66-6
Analytical
Method: EPA 6020 Preparation
Method: EPA 3050
ND
mg/kg
5.3
2.7
100
05/09/15 09:34
05/11/15 13:43
7440-36-0
8.1
mg/kg
5.3
2.7
100
05/09/15 09:34
05/11/15 13:43
7440-38-2
ND
mg/kg
0.64
0.32
100
05/09/15 09:34
05/11/15 13:43
7440-43-9
31.9
mg/kg
5.3
2.7
100
05/09/15 09:34
05/11/15 13:43
7440-48-4
12.4
mg/kg
5.3
2.7
100
05/09/15 09:34
05/11/15 13:43
7439-92-1
4AJ
mg/kg
5.3
2.7
100
05/09/15 09:34
05/11/15 13:43
7782-49-2
ND
mg/kg
5.3
2.7
100
05/09/15 09:34
05/11/15 13:43
7440-28-0
9.7
mg/kg
5.3
2.7
100
05/09/15 09:34
05/11/15 13:43
7440-62-2
Analytical Method: EPA 7471 Preparation Method: EPA 7471
0.0070J mg/kg 0.0088 0.0044 1 05/09/15 09:41 05/09/15 18:09 7439-97-6
Analytical Method: ASTM D2974-87
7.6 % 0.10 0.10 1 05/11/1510:33
Analytical Method: EPA 9045
5.6 Std. Units 0.10 0.10 1 05/05/15 14:25
N2
Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 05/11/15 03:30
6.6 mg/L 2.2 1.1 1 05/14/15 23:47 14808-79-8 B
Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 05/11/15 03:30
ND mg/L 0.22 0.22 1 05/15/15 21:26 H1
Analytical Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 05/11/15 03:30
ND mg/L 5.4 2.7 1 05/14/15 06:04 16887-00-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 38 of 88

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
98005kf pyo"Je. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15050012
Pace Project No.: 92247913
Sample: 2015012927 Lab ID: 92247913003 Collected: 04/25/15 16:05 Received: 05/01/15 12:03 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
9056 IC Anions Analytical Method: EPA 9056
Chloride
ND mg/kg
265
133
5
05/06/1517:31
16887-00-6 D3
Sulfate
ND mg/kg
265
133
5
05/06/1517:31
14808-79-8 D3
9056 IC Anions 48hr
Analytical Method: EPA 9056
Nitrate as N
ND mg/kg
26.5
13.3
5
05/06/15 17:31
14797-55-8 H3
Total Organic Carbon Quad
Analytical Method: EPA 9060
Total Organic Carbon
743 mg/kg
648
324
1
05/22/15 14:04
7440-44-0
Total Organic Carbon
762 mg/kg
652
326
1
05/22/15 14:10
7440-44-0
Total Organic Carbon
693 mg/kg
644
322
1
05/22/15 14:16
7440-44-0
Total Organic Carbon
768 mg/kg
650
325
1
05/22/15 14:23
7440-44-0
Mean Total Organic Carbon
741 mg/kg
649
324
1
05/22/15 14:04
7440-44-0
Surrogates
RSD%
4.6 %
1
05/22/15 14:04
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/28/2015 07:43 AM without the written consent of Pace Analytical Services, Inc..
Page 39 of 88

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
98005k rpyo"Je. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15050012
Pace Project No.: 92247913
Sample: 2015012928 Lab ID: 92247913004 Collected: 04/25/15 16:25 Received: 05/01/15 12:03 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Aluminum
Barium
Beryllium
Boron
Calcium
Chromium
Copper
Iron
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Sodium
Strontium
Zinc
6020 MET ICPMS
Antimony
Arsenic
Cadmium
Cobalt
Lead
Selenium
Thallium
Vanadium
7471 Mercury
Mercury
Percent Moisture
Percent Moisture
9045 pH Soil
pH at 25 Degrees C
300.0 IC Anions, SPLP
Sulfate
353.2 Nitrogen, NO2/NO3, SPLP
Nitrogen, Nitrate
4500 Chloride, SPLP
Chloride
Date: 05/28/2015 07:43 AM
Analytical Method: EPA 6010 Preparation Method: EPA 3050
4250
mg/kg
33.3
16.6
5
05/09/1510:20
05/10/1518:55
7429-90-5
18.1
mg/kg
3.3
1.7
5
05/09/1510:20
05/10/1518:55
7440-39-3
ND
mg/kg
0.33
0.17
5
05/09/1510:20
05/10/1518:55
7440-41-7
ND
mg/kg
16.6
8.3
5
05/09/1510:20
05/10/1518:55
7440-42-8
ND
mg/kg
166
83.2
5
05/09/1510:20
05/10/1518:55
7440-70-2
4.3
mg/kg
1.7
0.83
5
05/09/1510:20
05/10/1518:55
7440-47-3
4.7
mg/kg
1.7
0.83
5
05/09/1510:20
05/10/1518:55
7440-50-8
13000
mg/kg
13.3
6.7
5
05/09/1510:20
05/10/1518:55
7439-89-6
305
mg/kg
166
83.2
5
05/09/1510:20
05/10/1518:55
7439-95-4
19.4
mg/kg
1.7
0.83
5
05/09/1510:20
05/10/1518:55
7439-96-5
ND
mg/kg
3.3
1.7
5
05/09/1510:20
05/10/1518:55
7439-98-7
ND
mg/kg
1.7
0.83
5
05/09/1510:20
05/10/1518:55
7440-02-0
ND
mg/kg
333
166
5
05/09/1510:20
05/10/1518:55
7440-09-7
ND
mg/kg
333
166
5
05/09/1510:20
05/10/1518:55
7440-23-5
ND
mg/kg
3.3
1.7
5
05/09/1510:20
05/10/1518:55
7440-24-6
9.4
mg/kg
6.7
3.3
5
05/09/1510:20
05/10/1518:55
7440-66-6
Analytical
Method: EPA 6020 Preparation
Method: EPA 3050
ND
mg/kg
6.7
3.3
100
05/09/1510:20
05/11/1513:51
7440-36-0
ND
mg/kg
6.7
3.3
100
05/09/1510:20
05/11/1513:51
7440-38-2
ND
mg/kg
0.80
0.40
100
05/09/1510:20
05/11/1513:51
7440-43-9
ND
mg/kg
6.7
3.3
100
05/09/1510:20
05/11/1513:51
7440-48-4
6.3J
mg/kg
6.7
3.3
100
05/09/1510:20
05/11/1513:51
7439-92-1
ND
mg/kg
6.7
3.3
100
05/09/1510:20
05/11/1513:51
7782-49-2
ND
mg/kg
6.7
3.3
100
05/09/1510:20
05/11/1513:51
7440-28-0
10.2
mg/kg
6.7
3.3
100
05/09/1510:20
05/11/1513:51
7440-62-2
Analytical Method: EPA 7471 Preparation Method: EPA 7471
0.011 mg/kg 0.010 0.0052 1 05/09/1510:25 05/09/1518:25 7439-97-6
Analytical Method: ASTM D2974-87
21.2 % 0.10 0.10 1 05/11/1510:34
Analytical Method: EPA 9045
4.1 Std. Units 0.10 0.10 1 05/05/15 14:25
M6, N2
M6
M6
M6
Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 05/11/15 03:30
7.7 mg/L 2.5 1.3 1 05/15/15 00:01 14808-79-8 B
Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 05/11/15 03:30
ND mg/L 0.25 0.25 1 05/15/15 21:27 H1
Analytical Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 05/11/15 03:30
ND mg/L 6.3 3.2 1 05/14/15 06:05 16887-00-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 40 of 88

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800�ir6fy0"Je. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15050012
Pace Project No.: 92247913
Sample: 2015012928
Lab ID: 92247913004 Collected:
04/25/15 16:25
Received: 05/01/15 12:03 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters
Results Units Limit
MDL DF
Prepared Analyzed
CAS No. Qual
9056 IC Anions
Analytical Method: EPA 9056
Chloride
ND mg/kg 309
155 5
05/06/1517:52
16887-00-6 D3
Sulfate
ND mg/kg 309
155 5
05/06/1517:52
14808-79-8 D3
9056 IC Anions 48hr
Analytical Method: EPA 9056
Nitrate as N
ND mg/kg 30.9
15.5 5
05/06/15 17:52
14797-55-8 H3
Total Organic Carbon Quad Analytical Method: EPA 9060
Total Organic Carbon
14100
mg/kg
759
380
1
05/22/15 14:30
7440-44-0
Total Organic Carbon
4540
mg/kg
762
381
1
05/22/15 14:36
7440-44-0
Total Organic Carbon
2820
mg/kg
768
384
1
05/22/15 14:43
7440-44-0
Total Organic Carbon
4720
mg/kg
757
379
1
05/22/15 14:48
7440-44-0
Mean Total Organic Carbon
6550
mg/kg
761
381
1
05/22/15 14:30
7440-44-0
Surrogates
RSD%
78.2
%
1
05/22/15 14:30
1g
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/28/2015 07:43 AM without the written consent of Pace Analytical Services, Inc..
Page 41 of 88

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980%ppyo"Je. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15050012
Pace Project No.: 92247913
Sample: 2015012929 Lab ID: 92247913005 Collected: 04/28/15 17:00 Received: 05/01/15 12:03 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Aluminum
Barium
Beryllium
Boron
Calcium
Chromium
Copper
Iron
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Sodium
Strontium
Zinc
6020 MET ICPMS
Antimony
Arsenic
Cadmium
Cobalt
Lead
Selenium
Thallium
Vanadium
7471 Mercury
Mercury
Percent Moisture
Percent Moisture
9045 pH Soil
pH at 25 Degrees C
300.0 IC Anions, SPLP
Sulfate
353.2 Nitrogen, NO2/NO3, SPLP
Nitrogen, Nitrate
4500 Chloride, SPLP
Chloride
Date: 05/28/2015 07:43 AM
Analytical Method: EPA 6010 Preparation Method: EPA 3050
4130
mg/kg
33.7
16.8
5
05/09/1510:20
05/10/1519:12
7429-90-5
69.2
mg/kg
3.4
1.7
5
05/09/1510:20
05/10/1519:12
7440-39-3
0.26J
mg/kg
0.34
0.17
5
05/09/1510:20
05/10/1519:12
7440-41-7
ND
mg/kg
16.8
8.4
5
05/09/1510:20
05/10/1519:12
7440-42-8
642
mg/kg
168
84.2
5
05/09/1510:20
05/10/1519:12
7440-70-2
3.8
mg/kg
1.7
0.84
5
05/09/1510:20
05/10/1519:12
7440-47-3
4.0
mg/kg
1.7
0.84
5
05/09/1510:20
05/10/1519:12
7440-50-8
7250
mg/kg
13.5
6.7
5
05/09/1510:20
05/10/1519:12
7439-89-6
1380
mg/kg
168
84.2
5
05/09/1510:20
05/10/1519:12
7439-95-4
392
mg/kg
1.7
0.84
5
05/09/1510:20
05/10/1519:12
7439-96-5
ND
mg/kg
3.4
1.7
5
05/09/1510:20
05/10/1519:12
7439-98-7
3.9
mg/kg
1.7
0.84
5
05/09/1510:20
05/10/1519:12
7440-02-0
227J
mg/kg
337
168
5
05/09/1510:20
05/10/1519:12
7440-09-7
ND
mg/kg
337
168
5
05/09/1510:20
05/10/1519:12
7440-23-5
9.5
mg/kg
3.4
1.7
5
05/09/1510:20
05/10/1519:12
7440-24-6
18.9
mg/kg
6.7
3.4
5
05/09/1510:20
05/10/1519:12
7440-66-6
Analytical
Method: EPA 6020
Preparation Method: EPA 3050
ND
mg/kg
6.7
3.4
100
05/09/1510:20
05/11/1514:07
7440-36-0
N2
ND
mg/kg
6.7
3.4
100
05/09/1510:20
05/11/1514:07
7440-38-2
ND
mg/kg
0.81
0.40
100
05/09/1510:20
05/11/1514:07
7440-43-9
4.3J
mg/kg
6.7
3.4
100
05/09/1510:20
05/11/1514:07
7440-48-4
8.1
mg/kg
6.7
3.4
100
05/09/1510:20
05/11/1514:07
7439-92-1
ND
mg/kg
6.7
3.4
100
05/09/1510:20
05/11/1514:07
7782-49-2
ND
mg/kg
6.7
3.4
100
05/09/1510:20
05/11/1514:07
7440-28-0
12.1
mg/kg
6.7
3.4
100
05/09/1510:20
05/11/1514:07
7440-62-2
Analytical
Method: EPA 7471
Preparation Method: EPA 7471
0.018
mg/kg
0.011
0.0055
1
05/09/1510:25
05/09/1518:31
7439-97-6
Analytical
Method: ASTM D2974-87
29.3
%
0.10
0.10
1
05/11/1510:34
Analytical
Method: EPA 9045
5.0
Std. Units
0.10
0.10
1
05/06/15 13:00
D6
Analytical
Method: EPA 300.0 Leachate Method/Date:
EPA 1312; 05/11/15
03:30
7.1
mg/L
2.8
1.4
1
05/15/15 00:15
14808-79-8
B
Analytical
Method: EPA 353.2 Leachate Method/Date:
EPA 1312; 05/11/15
03:30
ND
mg/L
0.28
0.28
1
05/15/15 21:28
H1
Analytical
Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 05/11/15 03:30
ND
mg/L
7.1
3.5
1
05/14/15 06:05
16887-00-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 42 of 88

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980%�rpyo"Je. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15050012
Pace Project No.: 92247913
Sample: 2015012929 Lab ID: 92247913005 Collected: 04/28/15 17:00 Received: 05/01/15 12:03 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
9056 IC Anions Analytical Method: EPA 9056
Chloride
ND mg/kg
360
180
5
05/06/1518:14
16887-00-6 D3
Sulfate
ND mg/kg
360
180
5
05/06/1518:14
14808-79-8 D3
9056 IC Anions 48hr
Analytical Method: EPA 9056
Nitrate as N
ND mg/kg
36.0
18.0
5
05/06/15 18:14
14797-55-8 H3
Total Organic Carbon Quad
Analytical Method: EPA 9060
Total Organic Carbon
12700 mg/kg
846
423
1
05/26/15 13:27
7440-44-0
Total Organic Carbon
13900 mg/kg
852
426
1
05/26/15 13:33
7440-44-0
Total Organic Carbon
12400 mg/kg
843
421
1
05/26/15 13:39
7440-44-0
Total Organic Carbon
14600 mg/kg
852
426
1
05/26/15 13:44
7440-44-0
Mean Total Organic Carbon
13400 mg/kg
848
424
1
05/26/15 13:27
7440-44-0
Surrogates
RSD%
7.5 %
1
05/26/15 13:27
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/28/2015 07:43 AM without the written consent of Pace Analytical Services, Inc..
Page 43 of 88

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980vrpyo"Je. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15050012
Pace Project No.: 92247913
Sample: 2015012930 Lab ID: 92247913006 Collected: 04/28/15 17:10 Received: 05/01/15 12:03 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Aluminum
Barium
Beryllium
Boron
Calcium
Chromium
Copper
Iron
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Sodium
Strontium
Zinc
6020 MET ICPMS
Antimony
Arsenic
Cadmium
Cobalt
Lead
Selenium
Thallium
Vanadium
7471 Mercury
Mercury
Percent Moisture
Percent Moisture
9045 pH Soil
pH at 25 Degrees C
300.0 IC Anions, SPLP
Sulfate
353.2 Nitrogen, NO2/NO3, SPLP
Nitrogen, Nitrate
4500 Chloride, SPLP
Chloride
Date: 05/28/2015 07:43 AM
Analytical Method: EPA 6010 Preparation Method: EPA 3050
4480
mg/kg
31.3
15.7
5
05/09/1510:20
05/10/1519:16
7429-90-5
130
mg/kg
3.1
1.6
5
05/09/1510:20
05/10/1519:16
7440-39-3
0.30J
mg/kg
0.31
0.16
5
05/09/1510:20
05/10/1519:16
7440-41-7
ND
mg/kg
15.7
7.8
5
05/09/1510:20
05/10/1519:16
7440-42-8
1190
mg/kg
157
78.3
5
05/09/1510:20
05/10/1519:16
7440-70-2
3.8
mg/kg
1.6
0.78
5
05/09/1510:20
05/10/1519:16
7440-47-3
2.6
mg/kg
1.6
0.78
5
05/09/1510:20
05/10/1519:16
7440-50-8
3100
mg/kg
12.5
6.3
5
05/09/1510:20
05/10/1519:16
7439-89-6
1400
mg/kg
157
78.3
5
05/09/1510:20
05/10/1519:16
7439-95-4
47.7
mg/kg
1.6
0.78
5
05/09/1510:20
05/10/1519:16
7439-96-5
ND
mg/kg
3.1
1.6
5
05/09/1510:20
05/10/1519:16
7439-98-7
4.6
mg/kg
1.6
0.78
5
05/09/1510:20
05/10/1519:16
7440-02-0
ND
mg/kg
313
157
5
05/09/1510:20
05/10/1519:16
7440-09-7
957
mg/kg
313
157
5
05/09/1510:20
05/10/1519:16
7440-23-5
19.4
mg/kg
3.1
1.6
5
05/09/1510:20
05/10/1519:16
7440-24-6
10.5
mg/kg
6.3
3.1
5
05/09/1510:20
05/10/1519:16
7440-66-6
Analytical
Method: EPA 6020 Preparation
Method: EPA 3050
ND
mg/kg
6.3
3.1
100
05/09/1510:20
05/11/1514:12
7440-36-0
ND
mg/kg
6.3
3.1
100
05/09/1510:20
05/11/1514:12
7440-38-2
ND
mg/kg
0.75
0.38
100
05/09/1510:20
05/11/1514:12
7440-43-9
ND
mg/kg
6.3
3.1
100
05/09/1510:20
05/11/1514:12
7440-48-4
5.9J
mg/kg
6.3
3.1
100
05/09/1510:20
05/11/1514:12
7439-92-1
ND
mg/kg
6.3
3.1
100
05/09/1510:20
05/11/1514:12
7782-49-2
ND
mg/kg
6.3
3.1
100
05/09/1510:20
05/11/1514:12
7440-28-0
13.6
mg/kg
6.3
3.1
100
05/09/1510:20
05/11/1514:12
7440-62-2
Analytical Method: EPA 7471 Preparation Method: EPA 7471
0.034 mg/kg 0.0098 0.0049 1 05/09/1510:25 05/09/1518:35 7439-97-6
Analytical Method: ASTM D2974-87
18.0 % 0.10 0.10 1 05/11/1510:34
Analytical Method: EPA 9045
6.9 Std. Units 0.10 0.10 1 05/06/15 13:00
N2
Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 05/11/15 03:30
9.1 mg/L 2.4 1.2 1 05/15/15 00:28 14808-79-8 B
Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 05/11/15 03:30
ND mg/L 0.24 0.24 1 05/15/15 21:32 H1
Analytical Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 05/11/15 03:30
14.0 mg/L 6.1 3.0 1 05/14/15 06:06 16887-00-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 44 of 88

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980%5 rpyo"Je. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15050012
Pace Project No.: 92247913
Sample: 2015012930 Lab ID: 92247913006 Collected: 04/28/15 17:10 Received: 05/01/15 12:03 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
9056 IC Anions Analytical Method: EPA 9056
Chloride
ND mg/kg
307
154
5
05/06/1518:35
16887-00-6 D3
Sulfate
ND mg/kg
307
154
5
05/06/1518:35
14808-79-8 D3
9056 IC Anions 48hr
Analytical Method: EPA 9056
Nitrate as N
ND mg/kg
30.7
15.4
5
05/06/15 18:35
14797-55-8 H3
Total Organic Carbon Quad
Analytical Method: EPA 9060
Total Organic Carbon
1260 mg/kg
736
368
1
05/26/15 13:50
7440-44-0
Total Organic Carbon
1210 mg/kg
738
369
1
05/26/15 13:56
7440-44-0
Total Organic Carbon
1150 mg/kg
737
368
1
05/26/15 14:03
7440-44-0
Total Organic Carbon
1120 mg/kg
727
363
1
05/26/15 14:09
7440-44-0
Mean Total Organic Carbon
1190 mg/kg
734
367
1
05/26/15 13:50
7440-44-0
Surrogates
RSD%
5.2 %
1
05/26/15 13:50
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/28/2015 07:43 AM without the written consent of Pace Analytical Services, Inc..
Page 45 of 88

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980%�rpyo"Je. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15050012
Pace Project No.: 92247913
Sample: 2015012931 Lab ID: 92247913007 Collected: 04/28/15 17:20 Received: 05/01/15 12:03 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Aluminum
Barium
Beryllium
Boron
Calcium
Chromium
Copper
Iron
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Sodium
Strontium
Zinc
6020 MET ICPMS
Antimony
Arsenic
Cadmium
Cobalt
Lead
Selenium
Thallium
Vanadium
7471 Mercury
Mercury
Percent Moisture
Percent Moisture
9045 pH Soil
pH at 25 Degrees C
300.0 IC Anions, SPLP
Sulfate
353.2 Nitrogen, NO2/NO3, SPLP
Nitrogen, Nitrate
4500 Chloride, SPLP
Chloride
Date: 05/28/2015 07:43 AM
Analytical Method: EPA 6010 Preparation Method: EPA 3050
1970
mg/kg
33.5
16.7
5
05/09/1510:20
05/10/1519:20
7429-90-5
14.3
mg/kg
3.3
1.7
5
05/09/1510:20
05/10/1519:20
7440-39-3
0.17J
mg/kg
0.33
0.17
5
05/09/1510:20
05/10/1519:20
7440-41-7
ND
mg/kg
16.7
8.4
5
05/09/1510:20
05/10/1519:20
7440-42-8
283
mg/kg
167
83.7
5
05/09/1510:20
05/10/1519:20
7440-70-2
1.9
mg/kg
1.7
0.84
5
05/09/1510:20
05/10/1519:20
7440-47-3
2.1
mg/kg
1.7
0.84
5
05/09/1510:20
05/10/1519:20
7440-50-8
1390
mg/kg
13.4
6.7
5
05/09/1510:20
05/10/1519:20
7439-89-6
321
mg/kg
167
83.7
5
05/09/1510:20
05/10/1519:20
7439-95-4
48.0
mg/kg
1.7
0.84
5
05/09/1510:20
05/10/1519:20
7439-96-5
ND
mg/kg
3.3
1.7
5
05/09/1510:20
05/10/1519:20
7439-98-7
1.4J
mg/kg
1.7
0.84
5
05/09/1510:20
05/10/1519:20
7440-02-0
ND
mg/kg
335
167
5
05/09/1510:20
05/10/1519:20
7440-09-7
ND
mg/kg
335
167
5
05/09/1510:20
05/10/1519:20
7440-23-5
3.5
mg/kg
3.3
1.7
5
05/09/1510:20
05/10/1519:20
7440-24-6
7.2
mg/kg
6.7
3.3
5
05/09/1510:20
05/10/1519:20
7440-66-6
Analytical
Method: EPA 6020 Preparation
Method: EPA 3050
ND
mg/kg
6.7
3.3
100
05/09/1510:20
05/11/1514:15
7440-36-0
ND
mg/kg
6.7
3.3
100
05/09/1510:20
05/11/1514:15
7440-38-2
ND
mg/kg
0.80
0.40
100
05/09/1510:20
05/11/1514:15
7440-43-9
6.01
mg/kg
6.7
3.3
100
05/09/1510:20
05/11/1514:15
7440-48-4
ND
mg/kg
6.7
3.3
100
05/09/1510:20
05/11/1514:15
7439-92-1
ND
mg/kg
6.7
3.3
100
05/09/1510:20
05/11/1514:15
7782-49-2
ND
mg/kg
6.7
3.3
100
05/09/1510:20
05/11/1514:15
7440-28-0
7.6
mg/kg
6.7
3.3
100
05/09/1510:20
05/11/1514:15
7440-62-2
Analytical Method: EPA 7471 Preparation Method: EPA 7471
ND mg/kg 0.011 0.0053 1 05/09/1510:25 05/09/1518:37 7439-97-6
Analytical Method: ASTM D2974-87
22.2 % 0.10 0.10 1 05/11/1510:34
Analytical Method: EPA 9045
6.6 Std. Units 0.10 0.10 1 05/06/15 13:00
N2
Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 05/11/15 03:30
6.1 mg/L 2.6 1.3 1 05/15/15 00:42 14808-79-8 B
Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 05/11/15 03:30
ND mg/L 0.26 0.26 1 05/15/15 21:33 H1
Analytical Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 05/11/15 03:30
ND mg/L 6.4 3.2 1 05/14/15 06:07 16887-00-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 46 of 88

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980%48r6fYo"Je. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15050012
Pace Project No.: 92247913
Sample: 2015012931 Lab ID: 92247913007 Collected: 04/28/15 17:20 Received: 05/01/15 12:03 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
9056 IC Anions Analytical Method: EPA 9056
Chloride
ND mg/kg
313
157
5
05/06/1518:57
16887-00-6 D3
Sulfate
ND mg/kg
313
157
5
05/06/1518:57
14808-79-8 D3
9056 IC Anions 48hr
Analytical Method: EPA 9056
Nitrate as N
ND mg/kg
31.3
15.7
5
05/06/15 18:57
14797-55-8 H3
Total Organic Carbon Quad
Analytical Method: EPA 9060
Total Organic Carbon
ND mg/kg
777
388
1
05/26/15 14:15
7440-44-0
Total Organic Carbon
441J mg/kg
766
383
1
05/26/15 14:20
7440-44-0
Total Organic Carbon
452J mg/kg
774
387
1
05/26/15 14:26
7440-44-0
Total Organic Carbon
465J mg/kg
773
386
1
05/26/15 14:31
7440-44-0
Mean Total Organic Carbon
435J mg/kg
772
386
1
05/26/15 14:15
7440-44-0
Surrogates
RSD%
8.4 %
1
05/26/15 14:15
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/28/2015 07:43 AM without the written consent of Pace Analytical Services, Inc..
Page 47 of 88

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980%-)ir6fy0"Je. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15050012
Pace Project No.: 92247913
Sample: 2015012934 Lab ID: 92247913008 Collected: 04/25/15 08:35 Received: 05/01/15 12:03 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
;I➢ZI7c\ri,I=11 l[99�� 6?
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Sodium
Strontium
Thallium
Vanadium
Zinc
7470A Mercury
Mercury
Date: 05/28/2015 07:43 AM
Analytical Method: EPA 6020A Preparation Method: EPA 3020
127
ug/L
10.0
3.0
1
05/06/15 10:16
05/12/15 02:33
7429-90-5
0.32J
ug/L
0.50
0.15
1
05/06/15 10:16
05/12/15 02:33
7440-36-0
ND
ug/L
0.50
0.11
1
05/06/15 10:16
05/12/15 02:33
7440-38-2
1.5
ug/L
0.30
0.081
1
05/06/15 10:16
05/12/15 02:33
7440-39-3
ND
ug/L
0.20
0.067
1
05/06/15 10:16
05/12/15 02:33
7440-41-7
ND
ug/L
5.0
1.1
1
05/06/15 10:16
05/12/15 02:33
7440-42-8
ND
ug/L
0.080
0.024
1
05/06/15 10:16
05/12/15 02:33
7440-43-9
346
ug/L
40.0
16.0
1
05/06/15 10:16
05/12/15 02:33
7440-70-2
0.94
ug/L
0.50
0.17
1
05/06/15 10:16
05/12/15 02:33
7440-47-3
0.16J
ug/L
0.50
0.13
1
05/06/15 10:16
05/12/15 02:33
7440-48-4
0.45J
ug/L
1.0
0.21
1
05/06/15 10:16
05/12/15 02:33
7440-50-8
260
ug/L
50.0
13.7
1
05/06/15 10:16
05/12/15 02:33
7439-89-6
0.11
ug/L
0.10
0.046
1
05/06/15 10:16
05/12/15 02:33
7439-92-1
48.6
ug/L
10.0
3.2
1
05/06/15 10:16
05/12/15 02:33
7439-95-4
6.3
ug/L
0.50
0.24
1
05/06/15 10:16
05/12/15 02:33
7439-96-5
0.20J
ug/L
0.50
0.094
1
05/06/15 10:16
05/12/15 02:33
7439-98-7
ND
ug/L
0.50
0.16
1
05/06/15 10:16
05/12/15 02:33
7440-02-0
42.3J
ug/L
50.0
11.7
1
05/06/15 10:16
05/12/15 02:33
7440-09-7
ND
ug/L
0.50
0.20
1
05/06/15 10:16
05/12/15 02:33
7782-49-2
55.5
ug/L
50.0
16.3
1
05/06/15 10:16
05/12/15 02:33
7440-23-5
0.80
ug/L
0.50
0.13
1
05/06/15 10:16
05/12/15 02:33
7440-24-6
ND
ug/L
0.10
0.015
1
05/06/15 10:16
05/12/15 02:33
7440-28-0
ND
ug/L
1.0
0.28
1
05/06/15 10:16
05/12/1516:29
7440-62-2
ND
ug/L
5.0
2.4
1
05/06/15 10:16
05/12/15 02:33
7440-66-6
Analytical Method: EPA 7470A Preparation Method: EPA 7470A
ND ug/L 0.20 0.022 1 05/06/15 09:00 05/06/15 17:35 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 48 of 88

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
98006Jf pyo"Je. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15050012
Pace Project No.: 92247913
Sample: 2015012935 Lab ID: 92247913009 Collected: 04/28/15 15:40 Received: 05/01/15 12:03 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
;I➢ZI7c\�i,I=11 l[99�� 6?
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Sodium
Strontium
Thallium
Vanadium
Zinc
7470A Mercury
Mercury
Date: 05/28/2015 07:43 AM
Analytical Method: EPA 6020A Preparation Method: EPA 3020
8080
ug/L
10.0
3.0
1
05/06/15 10:16
05/12/15 02:09
7429-90-5
0.29J
ug/L
0.50
0.15
1
05/06/15 10:16
05/12/15 02:09
7440-36-0
0.57
ug/L
0.50
0.11
1
05/06/15 10:16
05/12/15 02:09
7440-38-2
91.9
ug/L
0.30
0.081
1
05/06/15 10:16
05/12/15 02:09
7440-39-3
0.28
ug/L
0.20
0.067
1
05/06/15 10:16
05/12/15 02:09
7440-41-7
1.91
ug/L
5.0
1.1
1
05/06/15 10:16
05/12/15 02:09
7440-42-8
0.028J
ug/L
0.080
0.024
1
05/06/15 10:16
05/12/15 02:09
7440-43-9
1840
ug/L
40.0
16.0
1
05/06/15 10:16
05/12/15 02:09
7440-70-2
6.8
ug/L
0.50
0.17
1
05/06/15 10:16
05/12/15 02:09
7440-47-3
7.4
ug/L
0.50
0.13
1
05/06/15 10:16
05/12/15 02:09
7440-48-4
5.9
ug/L
1.0
0.21
1
05/06/15 10:16
05/12/15 02:09
7440-50-8
12800
ug/L
50.0
13.7
1
05/06/15 10:16
05/12/15 02:09
7439-89-6
3.8
ug/L
0.10
0.046
1
05/06/15 10:16
05/12/15 02:09
7439-92-1
2330
ug/L
10.0
3.2
1
05/06/15 10:16
05/12/15 02:09
7439-95-4
355
ug/L
0.50
0.24
1
05/06/15 10:16
05/12/15 02:09
7439-96-5
0.59
ug/L
0.50
0.094
1
05/06/15 10:16
05/12/15 02:09
7439-98-7
3.4
ug/L
0.50
0.16
1
05/06/15 10:16
05/12/15 02:09
7440-02-0
1820
ug/L
50.0
11.7
1
05/06/15 10:16
05/12/15 02:09
7440-09-7
0.31J
ug/L
0.50
0.20
1
05/06/15 10:16
05/12/15 02:09
7782-49-2
1020
ug/L
50.0
16.3
1
05/06/15 10:16
05/12/15 02:09
7440-23-5
16.2
ug/L
0.50
0.13
1
05/06/15 10:16
05/12/15 02:09
7440-24-6
0.058J
ug/L
0.10
0.015
1
05/06/15 10:16
05/12/15 02:09
7440-28-0
10.3
ug/L
1.0
0.28
1
05/06/15 10:16
05/12/1516:20
7440-62-2
52.4
ug/L
5.0
2.4
1
05/06/15 10:16
05/12/15 02:09
7440-66-6
Analytical Method: EPA 7470A Preparation Method: EPA 7470A
ND ug/L 0.20 0.022 1 05/06/15 09:00 05/06/15 17:42 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 49 of 88

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 iirpyo"Je. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15050012
Pace Project No.: 92247913
Sample: 2015012936 Lab ID: 92247913010 Collected: 04/28/15 00:00 Received: 05/01/15 12:03 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
;I➢ZI7c\ri,I=11 l[99�� 6?
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Sodium
Strontium
Thallium
Vanadium
Zinc
7470A Mercury
Mercury
Date: 05/28/2015 07:43 AM
Analytical Method: EPA 6020A Preparation Method: EPA 3020
ND
ug/L
10.0
3.0
1
05/06/15 10:16
05/12/15 02:28
7429-90-5
ND
ug/L
0.50
0.15
1
05/06/15 10:16
05/12/15 02:28
7440-36-0
ND
ug/L
0.50
0.11
1
05/06/15 10:16
05/12/15 02:28
7440-38-2
ND
ug/L
0.30
0.081
1
05/06/15 10:16
05/12/15 02:28
7440-39-3
ND
ug/L
0.20
0.067
1
05/06/15 10:16
05/12/15 02:28
7440-41-7
ND
ug/L
5.0
1.1
1
05/06/15 10:16
05/12/15 02:28
7440-42-8
ND
ug/L
0.080
0.024
1
05/06/15 10:16
05/12/15 02:28
7440-43-9
ND
ug/L
40.0
16.0
1
05/06/15 10:16
05/12/15 02:28
7440-70-2
ND
ug/L
0.50
0.17
1
05/06/15 10:16
05/12/15 02:28
7440-47-3
ND
ug/L
0.50
0.13
1
05/06/15 10:16
05/12/15 02:28
7440-48-4
ND
ug/L
1.0
0.21
1
05/06/15 10:16
05/12/15 02:28
7440-50-8
ND
ug/L
50.0
13.7
1
05/06/15 10:16
05/12/15 02:28
7439-89-6
ND
ug/L
0.10
0.046
1
05/06/15 10:16
05/12/15 02:28
7439-92-1
ND
ug/L
10.0
3.2
1
05/06/15 10:16
05/12/15 02:28
7439-95-4
ND
ug/L
0.50
0.24
1
05/06/15 10:16
05/12/15 02:28
7439-96-5
ND
ug/L
0.50
0.094
1
05/06/15 10:16
05/12/15 02:28
7439-98-7
ND
ug/L
0.50
0.16
1
05/06/15 10:16
05/12/15 02:28
7440-02-0
ND
ug/L
50.0
11.7
1
05/06/15 10:16
05/12/15 02:28
7440-09-7
ND
ug/L
0.50
0.20
1
05/06/15 10:16
05/12/15 02:28
7782-49-2
ND
ug/L
50.0
16.3
1
05/06/15 10:16
05/12/15 02:28
7440-23-5
ND
ug/L
0.50
0.13
1
05/06/15 10:16
05/12/15 02:28
7440-24-6
ND
ug/L
0.10
0.015
1
05/06/15 10:16
05/12/15 02:28
7440-28-0
ND
ug/L
1.0
0.28
1
05/06/15 10:16
05/12/1516:24
7440-62-2
ND
ug/L
5.0
2.4
1
05/06/15 10:16
05/12/15 02:28
7440-66-6
Analytical Method: EPA 7470A Preparation Method: EPA 7470A
ND ug/L 0.20 0.022 1 05/06/15 09:00 05/06/15 17:44 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 50 of 88

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
98006}�ir6fYo"Je. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15050012
Pace Project No.: 92247913
Sample: 2015012925 SPLP Lab ID: 92247913011 Collected: 04/25/15 16:15 Received: 05/01/15 12:03 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
;T➢Z17c\riil=11 a
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Sodium
Strontium
Thallium
Vanadium
Zinc
7470A Mercury
Mercury
Date: 05/28/2015 07:43 AM
Analytical Method: EPA 6020A Preparation Method: EPA 3020
10200
ug/L
10.0
3.0
1
05/20/1510:10
05/20/1513:52
7429-90-5
ND
ug/L
0.50
0.15
1
05/20/1510:10
05/20/1513:52
7440-36-0
0.32J
ug/L
0.50
0.11
1
05/20/1510:10
05/20/1513:52
7440-38-2
189
ug/L
0.30
0.081
1
05/20/1510:10
05/20/1513:52
7440-39-3
0.22
ug/L
0.20
0.067
1
05/20/1510:10
05/20/1513:52
7440-41-7
61.7
ug/L
5.0
1.1
1
05/20/1510:10
05/20/1513:52
7440-42-8
ND
ug/L
0.080
0.024
1
05/20/1510:10
05/20/1513:52
7440-43-9
889
ug/L
40.0
16.0
1
05/20/1510:10
05/20/1513:52
7440-70-2
4.7
ug/L
0.50
0.17
1
05/20/1510:10
05/20/1513:52
7440-47-3
0.88
ug/L
0.50
0.13
1
05/20/1510:10
05/20/1513:52
7440-48-4
3.6
ug/L
1.0
0.21
1
05/20/1510:10
05/20/1513:52
7440-50-8
8210
ug/L
50.0
13.7
1
05/20/1510:10
05/20/1513:52
7439-89-6
1.7
ug/L
0.10
0.046
1
05/20/1510:10
05/20/1513:52
7439-92-1
802
ug/L
10.0
3.2
1
05/20/1510:10
05/20/1513:52
7439-95-4
36.3
ug/L
0.50
0.24
1
05/20/1510:10
05/20/1513:52
7439-96-5
0.28J
ug/L
0.50
0.094
1
05/20/1510:10
05/20/1513:52
7439-98-7
2.1
ug/L
0.50
0.16
1
05/20/1510:10
05/20/1513:52
7440-02-0
1440
ug/L
50.0
11.7
1
05/20/1510:10
05/20/1513:52
7440-09-7
ND
ug/L
0.50
0.20
1
05/20/1510:10
05/20/1513:52
7782-49-2
3050
ug/L
50.0
16.3
1
05/20/1510:10
05/20/1513:52
7440-23-5
11.5
ug/L
0.50
0.13
1
05/20/1510:10
05/20/1513:52
7440-24-6
0.032J
ug/L
0.10
0.015
1
05/20/1510:10
05/22/1513:33
7440-28-0
9.0
ug/L
1.0
0.28
1
05/20/1510:10
05/20/1513:52
7440-62-2
50.9
ug/L
5.0
2.4
1
05/20/1510:10
05/20/1513:52
7440-66-6
Analytical Method: EPA 7470A Preparation Method: EPA 7470A
ND ug/L 0.20 0.022 1 05/20/1517:25 05/21/1512:05 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 51 of 88

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980%48r6fy0"Je. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15050012
Pace Project No.: 92247913
Sample: 2015012926 SPLP Lab ID: 92247913012 Collected: 04/25/15 16:10 Received: 05/01/15 12:03 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
;T➢Z17c\riil=11 a
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Sodium
Strontium
Thallium
Vanadium
Zinc
7470A Mercury
Mercury
Date: 05/28/2015 07:43 AM
Analytical Method: EPA 6020A Preparation Method: EPA 3020
11600
ug/L
10.0
3.0
1
05/20/1510:10
05/20/1513:55
7429-90-5
ND
ug/L
0.50
0.15
1
05/20/1510:10
05/20/1513:55
7440-36-0
0.93
ug/L
0.50
0.11
1
05/20/1510:10
05/20/1513:55
7440-38-2
228
ug/L
0.30
0.081
1
05/20/1510:10
05/20/1513:55
7440-39-3
0.40
ug/L
0.20
0.067
1
05/20/1510:10
05/20/1513:55
7440-41-7
72.4
ug/L
5.0
1.1
1
05/20/1510:10
05/20/1513:55
7440-42-8
0.053J
ug/L
0.080
0.024
1
05/20/1510:10
05/20/1513:55
7440-43-9
1020
ug/L
40.0
16.0
1
05/20/1510:10
05/20/1513:55
7440-70-2
6.3
ug/L
0.50
0.17
1
05/20/1510:10
05/20/1513:55
7440-47-3
2.0
ug/L
0.50
0.13
1
05/20/1510:10
05/20/1513:55
7440-48-4
5.9
ug/L
1.0
0.21
1
05/20/1510:10
05/20/1513:55
7440-50-8
10100
ug/L
50.0
13.7
1
05/20/1510:10
05/20/1513:55
7439-89-6
6.3
ug/L
0.10
0.046
1
05/20/1510:10
05/20/1513:55
7439-92-1
1470
ug/L
10.0
3.2
1
05/20/1510:10
05/20/1513:55
7439-95-4
175
ug/L
0.50
0.24
1
05/20/1510:10
05/20/1513:55
7439-96-5
3.5
ug/L
0.50
0.094
1
05/20/1510:10
05/20/1513:55
7439-98-7
2.8
ug/L
0.50
0.16
1
05/20/1510:10
05/20/1513:55
7440-02-0
1920
ug/L
50.0
11.7
1
05/20/1510:10
05/20/1513:55
7440-09-7
ND
ug/L
0.50
0.20
1
05/20/1510:10
05/20/1513:55
7782-49-2
4900
ug/L
50.0
16.3
1
05/20/1510:10
05/20/1513:55
7440-23-5
19.2
ug/L
0.50
0.13
1
05/20/1510:10
05/20/1513:55
7440-24-6
0.045J
ug/L
0.10
0.015
1
05/20/1510:10
05/22/1513:37
7440-28-0
10.8
ug/L
1.0
0.28
1
05/20/1510:10
05/20/1513:55
7440-62-2
74.7
ug/L
5.0
2.4
1
05/20/1510:10
05/20/1513:55
7440-66-6
Analytical Method: EPA 7470A Preparation Method: EPA 7470A
ND ug/L 0.20 0.022 1 05/20/1517:25 05/21/1512:07 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 52 of 88

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980%48r6fy0"Je. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15050012
Pace Project No.: 92247913
Sample: 2015012927 SPLP Lab ID: 92247913013 Collected: 04/25/15 16:05 Received: 05/01/15 12:03 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
;T➢Z17c\riil=11 a
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Sodium
Strontium
Thallium
Vanadium
Zinc
7470A Mercury
Mercury
Date: 05/28/2015 07:43 AM
Analytical Method: EPA 6020A Preparation Method: EPA 3020
9070
ug/L
10.0
3.0
1
05/20/1510:10
05/20/1513:58
7429-90-5
0.27J
ug/L
0.50
0.15
1
05/20/1510:10
05/20/1513:58
7440-36-0
4.3
ug/L
0.50
0.11
1
05/20/1510:10
05/20/1513:58
7440-38-2
241
ug/L
0.30
0.081
1
05/20/1510:10
05/20/1513:58
7440-39-3
0.73
ug/L
0.20
0.067
1
05/20/1510:10
05/20/1513:58
7440-41-7
88.9
ug/L
5.0
1.1
1
05/20/1510:10
05/20/1513:58
7440-42-8
0.032J
ug/L
0.080
0.024
1
05/20/1510:10
05/20/1513:58
7440-43-9
496
ug/L
40.0
16.0
1
05/20/1510:10
05/20/1513:58
7440-70-2
3.9
ug/L
0.50
0.17
1
05/20/1510:10
05/20/1513:58
7440-47-3
15.9
ug/L
0.50
0.13
1
05/20/1510:10
05/20/1513:58
7440-48-4
4.7
ug/L
1.0
0.21
1
05/20/1510:10
05/20/1513:58
7440-50-8
10800
ug/L
50.0
13.7
1
05/20/1510:10
05/20/1513:58
7439-89-6
5.5
ug/L
0.10
0.046
1
05/20/1510:10
05/20/1513:58
7439-92-1
1010
ug/L
10.0
3.2
1
05/20/1510:10
05/20/1513:58
7439-95-4
173
ug/L
0.50
0.24
1
05/20/1510:10
05/20/1513:58
7439-96-5
2.1
ug/L
0.50
0.094
1
05/20/1510:10
05/20/1513:58
7439-98-7
5.5
ug/L
0.50
0.16
1
05/20/1510:10
05/20/1513:58
7440-02-0
1230
ug/L
50.0
11.7
1
05/20/1510:10
05/20/1513:58
7440-09-7
0.42J
ug/L
0.50
0.20
1
05/20/1510:10
05/20/1513:58
7782-49-2
4910
ug/L
50.0
16.3
1
05/20/1510:10
05/20/1513:58
7440-23-5
10
ug/L
0.50
0.13
1
05/20/1510:10
05/20/1513:58
7440-24-6
0.049J
ug/L
0.10
0.015
1
05/20/1510:10
05/22/1513:42
7440-28-0
10.2
ug/L
1.0
0.28
1
05/20/1510:10
05/20/1513:58
7440-62-2
88.8
ug/L
5.0
2.4
1
05/20/1510:10
05/20/1513:58
7440-66-6
Analytical Method: EPA 7470A Preparation Method: EPA 7470A
ND ug/L 0.20 0.022 1 05/20/1517:25 05/21/1512:10 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 53 of 88

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980%4?r6fy0"Je. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15050012
Pace Project No.: 92247913
Sample: 2015012928 SPLP Lab ID: 92247913014 Collected: 04/25/15 16:25 Received: 05/01/15 12:03 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
;T➢Z17c\riil=11 a
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Sodium
Strontium
Thallium
Vanadium
Zinc
7470A Mercury
Mercury
Date: 05/28/2015 07:43 AM
Analytical Method: EPA 6020A Preparation Method: EPA 3020
16400
ug/L
10.0
3.0
1
05/20/1510:10
05/20/1514:06
7429-90-5
0.21J
ug/L
0.50
0.15
1
05/20/1510:10
05/20/1514:06
7440-36-0
3.6
ug/L
0.50
0.11
1
05/20/1510:10
05/20/1514:06
7440-38-2
532
ug/L
3.0
0.81
10
05/20/1510:10
05/20/1514:45
7440-39-3
0.29
ug/L
0.20
0.067
1
05/20/1510:10
05/20/1514:06
7440-41-7
266
ug/L
5.0
1.1
1
05/20/1510:10
05/20/1514:06
7440-42-8
0.028J
ug/L
0.080
0.024
1
05/20/1510:10
05/20/1514:06
7440-43-9
483
ug/L
40.0
16.0
1
05/20/1510:10
05/20/1514:06
7440-70-2
12.1
ug/L
0.50
0.17
1
05/20/1510:10
05/20/1514:06
7440-47-3
3.1
ug/L
0.50
0.13
1
05/20/1510:10
05/20/1514:06
7440-48-4
10.7
ug/L
1.0
0.21
1
05/20/1510:10
05/20/1514:06
7440-50-8
26000
ug/L
500
137
10
05/20/1510:10
05/20/1514:45
7439-89-6
8.3
ug/L
0.10
0.046
1
05/20/1510:10
05/20/1514:06
7439-92-1
953
ug/L
10.0
3.2
1
05/20/1510:10
05/20/1514:06
7439-95-4
42.7
ug/L
0.50
0.24
1
05/20/1510:10
05/20/1514:06
7439-96-5
0.51
ug/L
0.50
0.094
1
05/20/1510:10
05/20/1514:06
7439-98-7
4.0
ug/L
0.50
0.16
1
05/20/1510:10
05/20/1514:06
7440-02-0
1270
ug/L
50.0
11.7
1
05/20/1510:10
05/20/1514:06
7440-09-7
0.32J
ug/L
0.50
0.20
1
05/20/1510:10
05/20/1514:06
7782-49-2
3540
ug/L
50.0
16.3
1
05/20/1510:10
05/20/1514:06
7440-23-5
12.7
ug/L
0.50
0.13
1
05/20/1510:10
05/20/1514:06
7440-24-6
0.14
ug/L
0.10
0.015
1
05/20/1510:10
05/22/1513:46
7440-28-0
25.6
ug/L
1.0
0.28
1
05/20/1510:10
05/20/1514:06
7440-62-2
328
ug/L
5.0
2.4
1
05/20/1510:10
05/20/1514:06
7440-66-6
Analytical Method: EPA 7470A Preparation Method: EPA 7470A
ND ug/L 0.20 0.022 1 05/20/1517:25 05/21/1512:17 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 54 of 88

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980ygrpyo"Je. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15050012
Pace Project No.: 92247913
Sample: 2015012929 SPLP Lab ID: 92247913015 Collected: 04/28/15 17:00 Received: 05/01/15 12:03 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
;T➢Z17c\r�il=11 a � 6?
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Sodium
Strontium
Thallium
Vanadium
Zinc
7470A Mercury
Mercury
Date: 05/28/2015 07:43 AM
Analytical Method: EPA 6020A Preparation Method: EPA 3020
31900
ug/L
100
29.8
10
05/20/1510:10
05/20/1514:47
7429-90-5
ND
ug/L
0.50
0.15
1
05/20/1510:10
05/20/1514:08
7440-36-0
2.3
ug/L
0.50
0.11
1
05/20/1510:10
05/20/1514:08
7440-38-2
425
ug/L
0.30
0.081
1
05/20/1510:10
05/20/1514:08
7440-39-3
0.59
ug/L
0.20
0.067
1
05/20/1510:10
05/20/1514:08
7440-41-7
129
ug/L
5.0
1.1
1
05/20/1510:10
05/20/1514:08
7440-42-8
0.52
ug/L
0.080
0.024
1
05/20/1510:10
05/20/1514:08
7440-43-9
1350
ug/L
40.0
16.0
1
05/20/1510:10
05/20/1514:08
7440-70-2
14.9
ug/L
0.50
0.17
1
05/20/1510:10
05/20/1514:08
7440-47-3
5.5
ug/L
0.50
0.13
1
05/20/1510:10
05/20/1514:08
7440-48-4
9.8
ug/L
1.0
0.21
1
05/20/1510:10
05/20/1514:08
7440-50-8
19600
ug/L
50.0
13.7
1
05/20/1510:10
05/20/1514:08
7439-89-6
8.3
ug/L
0.10
0.046
1
05/20/1510:10
05/20/1514:08
7439-92-1
2520
ug/L
10.0
3.2
1
05/20/1510:10
05/20/1514:08
7439-95-4
405
ug/L
0.50
0.24
1
05/20/1510:10
05/20/1514:08
7439-96-5
0.14J
ug/L
0.50
0.094
1
05/20/1510:10
05/20/1514:08
7439-98-7
9.6
ug/L
0.50
0.16
1
05/20/1510:10
05/20/1514:08
7440-02-0
1310
ug/L
50.0
11.7
1
05/20/1510:10
05/20/1514:08
7440-09-7
0.40J
ug/L
0.50
0.20
1
05/20/1510:10
05/20/1514:08
7782-49-2
3110
ug/L
50.0
16.3
1
05/20/1510:10
05/20/1514:08
7440-23-5
20.9
ug/L
0.50
0.13
1
05/20/1510:10
05/20/1514:08
7440-24-6
0.20
ug/L
0.10
0.015
1
05/20/1510:10
05/22/1513:51
7440-28-0
41.2
ug/L
1.0
0.28
1
05/20/1510:10
05/20/1514:08
7440-62-2
180
ug/L
5.0
2.4
1
05/20/1510:10
05/20/1514:08
7440-66-6
Analytical Method: EPA 7470A Preparation Method: EPA 7470A
ND ug/L 0.20 0.022 1 05/20/1517:25 05/21/1512:20 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 55 of 88

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
98006rpyo"Je. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15050012
Pace Project No.: 92247913
Sample: 2015012930 SPLP Lab ID: 92247913016 Collected: 04/28/15 17:10 Received: 05/01/15 12:03 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
;T➢Z17c\��il=11 a � 6?
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Sodium
Strontium
Thallium
Vanadium
Zinc
7470A Mercury
Mercury
Date: 05/28/2015 07:43 AM
Analytical Method: EPA 6020A Preparation Method: EPA 3020
205000
ug/L
100
29.8
10
05/20/1510:10
05/20/1514:50
7429-90-5
ND
ug/L
0.50
0.15
1
05/20/1510:10
05/20/1514:31
7440-36-0
6.7
ug/L
0.50
0.11
1
05/20/1510:10
05/20/1514:31
7440-38-2
2350
ug/L
3.0
0.81
10
05/20/1510:10
05/20/1514:50
7440-39-3
4.0
ug/L
0.20
0.067
1
05/20/1510:10
05/20/1514:31
7440-41-7
79.9
ug/L
5.0
1.1
1
05/20/1510:10
05/20/1514:31
7440-42-8
0.11
ug/L
0.080
0.024
1
05/20/1510:10
05/20/1514:31
7440-43-9
10300
ug/L
40.0
16.0
1
05/20/1510:10
05/20/1514:31
7440-70-2
96.7
ug/L
0.50
0.17
1
05/20/1510:10
05/20/1514:31
7440-47-3
38.2
ug/L
0.50
0.13
1
05/20/1510:10
05/20/1514:31
7440-48-4
51.9
ug/L
1.0
0.21
1
05/20/1510:10
05/20/1514:31
7440-50-8
160000
ug/L
500
137
10
05/20/1510:10
05/20/1514:50
7439-89-6
84.2
ug/L
0.10
0.046
1
05/20/1510:10
05/20/1514:31
7439-92-1
24600
ug/L
100
31.7
10
05/20/1510:10
05/20/1514:50
7439-95-4
427
ug/L
0.50
0.24
1
05/20/1510:10
05/20/1514:31
7439-96-5
0.11J
ug/L
0.50
0.094
1
05/20/1510:10
05/20/1514:31
7439-98-7
73.7
ug/L
0.50
0.16
1
05/20/1510:10
05/20/1514:31
7440-02-0
2660
ug/L
50.0
11.7
1
05/20/1510:10
05/20/1514:31
7440-09-7
1.6
ug/L
0.50
0.20
1
05/20/1510:10
05/20/1514:31
7782-49-2
25000
ug/L
500
163
10
05/20/1510:10
05/20/1514:50
7440-23-5
191
ug/L
0.50
0.13
1
05/20/1510:10
05/20/1514:31
7440-24-6
1.2
ug/L
0.10
0.015
1
05/20/1510:10
05/20/1514:31
7440-28-0
275
ug/L
1.0
0.28
1
05/20/1510:10
05/20/1514:31
7440-62-2
388
ug/L
5.0
2.4
1
05/20/1510:10
05/20/1514:31
7440-66-6
Analytical Method: EPA 7470A Preparation Method: EPA 7470A
0.21 ug/L 0.20 0.022 1 05/20/1517:25 05/21/1512:22 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 56 of 88

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
98007tbirpyo"Je. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15050012
Pace Project No.: 92247913
Sample: 2015012931 SPLP Lab ID: 92247913017 Collected: 04/28/15 17:20 Received: 05/01/15 12:03 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
;T➢Z17c\��il=11 a � 6?
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Sodium
Strontium
Thallium
Vanadium
Zinc
7470A Mercury
Mercury
Date: 05/28/2015 07:43 AM
Analytical Method: EPA 6020A Preparation Method: EPA 3020
28200
ug/L
100
29.8
10
05/20/1510:10
05/20/1514:53
7429-90-5
ND
ug/L
0.50
0.15
1
05/20/1510:10
05/20/1514:11
7440-36-0
2.2
ug/L
0.50
0.11
1
05/20/1510:10
05/20/1514:11
7440-38-2
256
ug/L
0.30
0.081
1
05/20/1510:10
05/20/1514:11
7440-39-3
1.3
ug/L
0.20
0.067
1
05/20/1510:10
05/20/1514:11
7440-41-7
58.5
ug/L
5.0
1.1
1
05/20/1510:10
05/20/1514:11
7440-42-8
ND
ug/L
0.080
0.024
1
05/20/1510:10
05/20/1514:11
7440-43-9
2040
ug/L
40.0
16.0
1
05/20/1510:10
05/20/1514:11
7440-70-2
19.6
ug/L
0.50
0.17
1
05/20/1510:10
05/20/1514:11
7440-47-3
7.2
ug/L
0.50
0.13
1
05/20/1510:10
05/20/1514:11
7440-48-4
13.2
ug/L
1.0
0.21
1
05/20/1510:10
05/20/1514:11
7440-50-8
13300
ug/L
50.0
13.7
1
05/20/1510:10
05/20/1514:11
7439-89-6
7.7
ug/L
0.10
0.046
1
05/20/1510:10
05/20/1514:11
7439-92-1
1710
ug/L
10.0
3.2
1
05/20/1510:10
05/20/1514:11
7439-95-4
66.1
ug/L
0.50
0.24
1
05/20/1510:10
05/20/1514:11
7439-96-5
ND
ug/L
0.50
0.094
1
05/20/1510:10
05/20/1514:11
7439-98-7
11.5
ug/L
0.50
0.16
1
05/20/1510:10
05/20/1514:11
7440-02-0
969
ug/L
50.0
11.7
1
05/20/1510:10
05/20/1514:11
7440-09-7
0.28J
ug/L
0.50
0.20
1
05/20/1510:10
05/20/1514:11
7782-49-2
2710
ug/L
50.0
16.3
1
05/20/1510:10
05/20/1514:11
7440-23-5
29.3
ug/L
0.50
0.13
1
05/20/1510:10
05/20/1514:11
7440-24-6
0.076J
ug/L
0.10
0.015
1
05/20/1510:10
05/22/1513:55
7440-28-0
60.8
ug/L
1.0
0.28
1
05/20/1510:10
05/20/1514:11
7440-62-2
94.1
ug/L
5.0
2.4
1
05/20/1510:10
05/20/1514:11
7440-66-6
Analytical Method: EPA 7470A Preparation Method: EPA 7470A
ND ug/L 0.20 0.022 1 05/20/1517:25 05/21/1512:25 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 57 of 88

aceAnaiXical
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Pace Analytical Services, Inc.
9800Airpyo"Je. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15050012
Pace Project No.: 92247913
QC Batch: MERP/13434 Analysis Method: EPA 7470A
QC Batch Method: EPA 7470A Analysis Description: 7470A Mercury Water
Associated Lab Samples: 92247913008, 92247913009, 92247913010
METHOD BLANK: 1956672 Matrix: Water
Associated Lab Samples: 92247913008, 92247913009, 92247913010
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Mercury ug/L ND 0.20 05/06/1517:10
LABORATORY CONTROL SAMPLE: 1956673
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Mercury ug/L 5 5.3 106 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1956674 1956675
MS MSD
92247913008 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Mercury ug/L ND 5 5 5.1 5.0 102 101 80-120 1 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/28/2015 07:43 AM without the written consent of Pace Analytical Services, Inc..
Page 58 of 88

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800hirpyo"Je. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15050012
Pace Project No.: 92247913
QC Batch: MERP/13580
Analysis Method: EPA 7470A
QC Batch Method: EPA 7470A
Analysis Description: 7470A Mercury Water
Associated Lab Samples: 92247913011,92247913012,92247913013,92247913014,92247913015,92247913016,92247913017
METHOD BLANK: 1968349
Matrix: Water
Associated Lab Samples: 92247913011, 92247913012,
92247913013, 92247913014, 92247913015, 92247913016, 92247913017
Blank Reporting
Parameter Units
Result Limit Analyzed Qualifiers
Mercury ug/L
ND 0.20 05/21/1511:33
LABORATORY CONTROL SAMPLE: 1968350
Spike LCS LCS % Rec
Parameter Units
Conc. Result % Rec Limits Qualifiers
Mercury ug/L
5 5.1 102 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1971062 1971063
MS MSD
92249710021
Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Mercury ug/L ND
5 5 4.9 4.9 98 98 80-120 0 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/28/2015 07:43 AM without the written consent of Pace Analytical Services, Inc..
Page 59 of 88

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800h,pyo"Je. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15050012
Pace Project No.: 92247913
QC Batch: MERP/5697
Analysis Method: EPA 7471
QC Batch Method: EPA 7471
Analysis Description: 7471 Mercury
Associated Lab Samples: 92247913001, 92247913002,
92247913003
METHOD BLANK: 1208617
Matrix: Solid
Associated Lab Samples: 92247913001, 92247913002,
92247913003
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Mercury mg/kg
ND 0.0082
05/09/1517:09
LABORATORY CONTROL SAMPLE: 1208618
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Mercury mg/kg
.083 0.083
100 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1208619 1208620
MS MSD
92247834001
Spike Spike MS
MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec Limits RPD RPD Qual
Mercury mg/kg 0.018
.079 .077 0.098
0.097 101 102 80-120 2 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/28/2015 07:43 AM without the written consent of Pace Analytical Services, Inc..
Page 60 of 88

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
98007VWYO"�-. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15050012
Pace Project No.: 92247913
QC Batch: MERP/5698
Analysis Method: EPA 7471
QC Batch Method: EPA 7471
Analysis Description: 7471 Mercury
Associated Lab Samples: 92247913004, 92247913005,
92247913006, 92247913007
METHOD BLANK: 1208646
Matrix: Solid
Associated Lab Samples: 92247913004, 92247913005,
92247913006, 92247913007
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Mercury mg/kg
ND 0.0080
05/09/1518:12
LABORATORY CONTROL SAMPLE: 1208647
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Mercury mg/kg
.078 0.083
106 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1208648 1208649
MS MSD
92247913004
Spike Spike MS
MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec Limits RPD RPD Qual
Mercury mg/kg 0.011
.104 .0965 0.12
0.11 101 103 80-120 5 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/28/2015 07:43 AM without the written consent of Pace Analytical Services, Inc..
Page 61 of 88

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
98008rpyo"Je. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15050012
Pace Project No.: 92247913
QC Batch: MPRP/24040 Analysis Method: EPA 6010
QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid
Associated Lab Samples: 92247913001, 92247913002, 92247913003
METHOD BLANK: 1208605 Matrix:
Associated Lab Samples: 92247913001, 92247913002, 92247913003
Blank
Parameter Units Result
Solid
Reporting
Limit
Analyzed
Aluminum
mg/kg
ND
5.1
05/10/1515:56
Barium
mg/kg
ND
0.51
05/10/1515:56
Beryllium
mg/kg
ND
0.051
05/10/1515:56
Boron
mg/kg
ND
2.6
05/10/1515:56
Calcium
mg/kg
ND
25.6
05/10/1515:56
Chromium
mg/kg
ND
0.26
05/10/1515:56
Copper
mg/kg
ND
0.26
05/10/1515:56
Iron
mg/kg
ND
2.0
05/10/1515:56
Magnesium
mg/kg
ND
25.6
05/10/1515:56
Manganese
mg/kg
ND
0.26
05/10/1515:56
Molybdenum
mg/kg
ND
0.51
05/10/1515:56
Nickel
mg/kg
ND
0.26
05/10/1515:56
Potassium
mg/kg
ND
51.1
05/10/1515:56
Sodium
mg/kg
ND
51.1
05/10/1515:56
Strontium
mg/kg
ND
0.51
05/10/1515:56
Zinc
mg/kg
ND
1.0
05/10/1515:56
Qualifiers
LABORATORY CONTROL SAMPLE:
Parameter
1208606
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
Aluminum
mg/kg
130
139
107
80-120
Barium
mg/kg
13
13.9
106
80-120
Beryllium
mg/kg
1.3
1.4
105
80-120
Boron
mg/kg
130
133
102
80-120
Calcium
mg/kg
651
699
107
80-120
Chromium
mg/kg
13
13.1
101
80-120
Copper
mg/kg
13
13.0
100
80-120
Iron
mg/kg
130
138
106
80-120
Magnesium
mg/kg
651
682
105
80-120
Manganese
mg/kg
13
13.5
103
80-120
Molybdenum
mg/kg
13
13.3
102
80-120
Nickel
mg/kg
13
13.7
105
80-120
Potassium
mg/kg
651
675
104
80-120
Sodium
mg/kg
651
708
109
80-120
Strontium
mg/kg
13
13.7
105
80-120
Zinc
mg/kg
65.1
68.9
106
80-120
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/28/2015 07:43 AM without the written consent of Pace Analytical Services, Inc.. Page 62 of 88

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800M,pyo"Je. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15050012
Pace Project No.: 92247913
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
1208607
1208608
MS
MSD
92247834001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Aluminum
mg/kg
2530
119
130
3690
4030
969
1150
75-125
9
20 M1
Barium
mg/kg
27.2
11.9
13
40.6
42.9
112
120
75-125
5
20
Beryllium
mg/kg
0.181
1.2
1.3
1.4
1.4
99
92
75-125
1
20
Boron
mg/kg
ND
119
130
110
109
90
83
75-125
0
20
Calcium
mg/kg
470
595
649
1100
1140
106
104
75-125
4
20
Chromium
mg/kg
4.3
11.9
13
16.2
16.5
100
94
75-125
2
20
Copper
mg/kg
3.4
11.9
13
15.0
15.5
98
93
75-125
3
20
Iron
mg/kg
4750
119
130
4950
5440
161
527
75-125
9
20 M1
Magnesium
mg/kg
349
595
649
975
1010
105
101
75-125
3
20
Manganese
mg/kg
180
11.9
13
195
206
122
195
75-125
5
20 M1
Molybdenum
mg/kg
ND
11.9
13
10.9
11.0
88
81
75-125
1
20
Nickel
mg/kg
1.7
11.9
13
13.8
14.0
102
95
75-125
2
20
Potassium
mg/kg
135J
595
649
706
717
96
90
75-125
2
20
Sodium
mg/kg
ND
595
649
644
672
99
95
75-125
4
20
Strontium
mg/kg
4.2
11.9
13
16.4
16.9
102
97
75-125
3
20
Zinc
mg/kg
22.0
59.5
64.9
87.1
87.0
109
100
75-125
0
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/28/2015 07:43 AM without the written consent of Pace Analytical Services, Inc..
Page 63 of 88

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800firpyo"Je. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15050012
Pace Project No.: 92247913
QC Batch: MPRP/24042 Analysis Method: EPA 6010
QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid
Associated Lab Samples: 92247913004, 92247913005, 92247913006, 92247913007
METHOD BLANK: 1208650 Matrix: Solid
Associated Lab Samples: 92247913004, 92247913005, 92247913006, 92247913007
Blank Reporting
Parameter Units Result Limit
Analyzed
Aluminum
mg/kg
ND
5.2
05/10/1518:02
Barium
mg/kg
ND
0.52
05/10/1518:02
Beryllium
mg/kg
ND
0.052
05/10/1518:02
Boron
mg/kg
ND
2.6
05/10/1518:02
Calcium
mg/kg
ND
26.1
05/10/1518:02
Chromium
mg/kg
ND
0.26
05/10/1518:02
Copper
mg/kg
ND
0.26
05/10/1518:02
Iron
mg/kg
1.6J
2.1
05/10/1518:02
Magnesium
mg/kg
ND
26.1
05/10/1518:02
Manganese
mg/kg
ND
0.26
05/10/1518:02
Molybdenum
mg/kg
ND
0.52
05/10/1518:02
Nickel
mg/kg
ND
0.26
05/10/1518:02
Potassium
mg/kg
ND
52.2
05/10/1518:02
Sodium
mg/kg
ND
52.2
05/10/1518:02
Strontium
mg/kg
ND
0.52
05/10/1518:02
Zinc
mg/kg
ND
1.0
05/10/1518:02
Qualifiers
LABORATORY CONTROL SAMPLE:
Parameter
1208651
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
Aluminum
mg/kg
129
128
99
80-120
Barium
mg/kg
12.9
12.7
98
80-120
Beryllium
mg/kg
1.3
1.3
98
80-120
Boron
mg/kg
129
124
96
80-120
Calcium
mg/kg
647
648
100
80-120
Chromium
mg/kg
12.9
12.3
95
80-120
Copper
mg/kg
12.9
11.9
92
80-120
Iron
mg/kg
129
127
99
80-120
Magnesium
mg/kg
647
633
98
80-120
Manganese
mg/kg
12.9
12.6
97
80-120
Molybdenum
mg/kg
12.9
12.3
95
80-120
Nickel
mg/kg
12.9
12.8
99
80-120
Potassium
mg/kg
647
628
97
80-120
Sodium
mg/kg
647
644
100
80-120
Strontium
mg/kg
12.9
12.5
97
80-120
Zinc
mg/kg
64.7
64.1
99
80-120
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/28/2015 07:43 AM without the written consent of Pace Analytical Services, Inc.. Page 64 of 88

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800mrpyo"Je. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15050012
Pace Project No.: 92247913
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1208652
MS
35186628008 Spike
Parameter Units Result Conc.
MSD
Spike
Conc.
1208653
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
Max
RPD RPD Qual
Aluminum
mg/kg
3480
148
153
4670
5420
804
1270
75-125
15
20 M1
Barium
mg/kg
30.9
14.8
15.3
43.9
51.6
87
136
75-125
16
20 M1
Beryllium
mg/kg
0.036J
1.54
1.54
1.1
1.2
69
75
75-125
11
20 M1
Boron
mg/kg
2.OJ
148
153
107
115
71
74
75-125
7
20 M1
Calcium
mg/kg
171000
744
765
145000
122000
-3540
-6370
75-125
17
20 E,M1
Chromium
mg/kg
7.7
14.8
15.3
23.6
19.8
107
79
75-125
18
20
Copper
mg/kg
58.5
14.8
15.3
87.2
82.8
194
159
75-125
5
20 M1
Iron
mg/kg
8450
148
153
15300
9540
4620
714
75-125
47
20 M1,R1
Magnesium
mg/kg
2660
744
765
3350
3140
93
62
75-125
7
20 M1
Manganese
mg/kg
356
14.8
15.3
289
331
-451
-161
75-125
14
20 M1
Molybdenum
mg/kg
1.6
14.8
15.3
11.2
11.8
65
67
75-125
5
20 M1
Nickel
mg/kg
6.8
14.8
15.3
20.8
19.1
94
81
75-125
8
20
Potassium
mg/kg
113
744
765
750
798
86
90
75-125
6
20
Sodium
mg/kg
105
744
765
724
763
83
86
75-125
5
20
Strontium
mg/kg
114
14.8
15.3
127
109
88
-33
75-125
15
20 M1
Zinc
mg/kg
91.5
74.4
76.5
220
175
173
110
75-125
23
20 M1,R1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/28/2015 07:43 AM without the written consent of Pace Analytical Services, Inc..
Page 65 of 88

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980079rpyo"Je. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15050012
Pace Project No.: 92247913
QC Batch: MPRP/24041 Analysis Method: EPA 6020
QC Batch Method: EPA 3050 Analysis Description: 6020 MET SOLID
Associated Lab Samples: 92247913001, 92247913002, 92247913003
METHOD BLANK: 1208611
Matrix:
Solid
Associated Lab Samples:
92247913001, 92247913002,
92247913003
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Antimony
mg/kg
ND
0.053
05/11/1512:09 N2
Arsenic
mg/kg
ND
0.053
05/11/1512:09
Cadmium
mg/kg
ND
0.0063
05/11/1512:09
Cobalt
mg/kg
ND
0.053
05/11/1512:09
Lead
mg/kg
ND
0.053
05/11/1512:09
Selenium
mg/kg
ND
0.053
05/11/1512:09
Thallium
mg/kg
ND
0.053
05/11/1512:09
Vanadium
mg/kg
ND
0.053
05/12/1517:01 CU
LABORATORY CONTROL SAMPLE:
Parameter
1208612
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
Antimony
mg/kg
2.6
2.7
101
80-120 N2
Arsenic
mg/kg
2.6
2.7
102
80-120
Cadmium
mg/kg
.26
0.27
101
80-120
Cobalt
mg/kg
2.6
2.7
104
80-120
Lead
mg/kg
2.6
2.7
104
80-120
Selenium
mg/kg
2.6
2.7
101
80-120
Thallium
mg/kg
2.6
2.7
104
80-120
Vanadium
mg/kg
2.6
2.6
100
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
1208613
1208614
MS
MSD
92247834001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD RPD Qual
Antimony
mg/kg
ND
2.6
2.6
ND
ND
60
61
75-125
20 M6, N2
Arsenic
mg/kg
ND
2.6
2.6
3.5J
3.3J
88
87
75-125
20
Cadmium
mg/kg
ND
.26
.26
ND
ND
60
83
75-125
20 M6
Cobalt
mg/kg
3.3J
2.6
2.6
6.7
6.6
130
129
75-125
2 20 M6
Lead
mg/kg
3.6J
2.6
2.6
6.9
6.9
125
128
75-125
1 20 M6
Selenium
mg/kg
ND
2.6
2.6
3.2J
ND
92
55
75-125
20 M6
Thallium
mg/kg
ND
2.6
2.6
ND
ND
91
93
75-125
20
Vanadium
mg/kg
8.5
2.6
2.6
12.1
11.5
136
119
75-125
5 20 M6
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/28/2015 07:43 AM without the written consent of Pace Analytical Services, Inc..
Page 66 of 88

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980vrpyo"Je. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15050012
Pace Project No.: 92247913
QC Batch: MPRP/24043 Analysis Method: EPA 6020
QC Batch Method: EPA 3050 Analysis Description: 6020 MET SOLID
Associated Lab Samples: 92247913004, 92247913005, 92247913006, 92247913007
METHOD BLANK: 1208654
Matrix:
Solid
Associated Lab Samples:
92247913004, 92247913005,
92247913006, 92247913007
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Antimony
mg/kg
ND
0.051
05/11/1513:45 N2
Arsenic
mg/kg
ND
0.051
05/11/1513:45
Cadmium
mg/kg
ND
0.0061
05/11/1513:45
Cobalt
mg/kg
ND
0.051
05/11/1513:45
Lead
mg/kg
ND
0.051
05/11/1513:45
Selenium
mg/kg
ND
0.051
05/11/1513:45
Thallium
mg/kg
ND
0.051
05/11/1513:45
Vanadium
mg/kg
ND
0.051
05/12/1516:58 CU
LABORATORY CONTROL SAMPLE:
Parameter
1208655
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
Antimony
mg/kg
2.6
2.5
97
80-120 N2
Arsenic
mg/kg
2.6
2.7
104
80-120
Cadmium
mg/kg
.26
0.26
101
80-120
Cobalt
mg/kg
2.6
2.8
107
80-120
Lead
mg/kg
2.6
2.7
104
80-120
Selenium
mg/kg
2.6
2.6
100
80-120
Thallium
mg/kg
2.6
2.7
104
80-120
Vanadium
mg/kg
2.6
2.7
102
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
1208656
1208657
MS
MSD
92247913004
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD RPD Qual
Antimony
mg/kg
ND
3.17
3.3
ND
ND
29
31
75-125
20 M6, N2
Arsenic
mg/kg
ND
3.17
3.3
3.7J
3.7J
42
42
75-125
20 M6
Cadmium
mg/kg
ND
.317
.33
ND
ND
76
82
75-125
20
Cobalt
mg/kg
ND
3.17
3.3
4.6J
4AJ
108
97
75-125
20
Lead
mg/kg
6.3J
3.17
3.3
9.8
10.2
111
118
75-125
3 20
Selenium
mg/kg
ND
3.17
3.3
ND
ND
0
-18
75-125
20 M6
Thallium
mg/kg
ND
3.17
3.3
ND
ND
69
75
75-125
20 M6
Vanadium
mg/kg
10.2
3.17
3.3
13.8
14.0
115
118
75-125
1 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/28/2015 07:43 AM without the written consent of Pace Analytical Services, Inc..
Page 67 of 88

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980mirpyo"Je. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15050012
Pace Project No.: 92247913
QC Batch: MPRP/54160 Analysis Method: EPA 6020A
QC Batch Method: EPA 3020 Analysis Description: 6020A Water UPD4
Associated Lab Samples: 92247913008, 92247913009, 92247913010
METHOD BLANK: 1956664 Matrix:
Associated Lab Samples: 92247913008, 92247913009, 92247913010
Blank
Parameter Units Result
Water
Reporting
Limit
Analyzed
Aluminum
ug/L
ND
10.0
05/12/15 01:36
Antimony
ug/L
ND
0.50
05/12/15 01:36
Arsenic
ug/L
ND
0.50
05/12/15 01:36
Barium
ug/L
ND
0.30
05/12/15 01:36
Beryllium
ug/L
ND
0.20
05/12/15 01:36
Boron
ug/L
ND
5.0
05/12/15 01:36
Cadmium
ug/L
ND
0.080
05/12/15 01:36
Calcium
ug/L
ND
40.0
05/12/15 01:36
Chromium
ug/L
ND
0.50
05/12/15 01:36
Cobalt
ug/L
ND
0.50
05/12/15 01:36
Copper
ug/L
ND
1.0
05/12/15 01:36
Iron
ug/L
ND
50.0
05/12/15 01:36
Lead
ug/L
ND
0.10
05/12/15 01:36
Magnesium
ug/L
ND
10.0
05/12/15 01:36
Manganese
ug/L
ND
0.50
05/12/15 01:36
Molybdenum
ug/L
ND
0.50
05/12/15 01:36
Nickel
ug/L
ND
0.50
05/12/15 01:36
Potassium
ug/L
ND
50.0
05/12/15 01:36
Selenium
ug/L
ND
0.50
05/12/15 01:36
Sodium
ug/L
ND
50.0
05/12/15 01:36
Strontium
ug/L
ND
0.50
05/12/15 01:36
Thallium
ug/L
ND
0.10
05/12/15 01:36
Vanadium
ug/L
ND
1.0
05/12/1515:16
Zinc
ug/L
ND
5.0
05/12/15 01:36
Qualifiers
LABORATORY CONTROL SAMPLE:
Parameter
1956665
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
Aluminum
ug/L
80
81.6
102
80-120
Antimony
ug/L
80
83.6
105
80-120
Arsenic
ug/L
80
81.8
102
80-120
Barium
ug/L
80
81.4
102
80-120
Beryllium
ug/L
80
83.1
104
80-120
Boron
ug/L
80
82.2
103
80-120
Cadmium
ug/L
80
80.6
101
80-120
Calcium
ug/L
1000
980
98
80-120
Chromium
ug/L
80
82.7
103
80-120
Cobalt
ug/L
80
80.7
101
80-120
Copper
ug/L
80
82.4
103
80-120
Iron
ug/L
1000
1100
110
80-120
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/28/2015 07:43 AM without the written consent of Pace Analytical Services, Inc.. Page 68 of 88

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980%ypyo"Je. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15050012
Pace Project No.: 92247913
LABORATORY CONTROL SAMPLE:
1956665
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits
Qualifiers
Lead
ug/L
80
83.5
104
80-120
Magnesium
ug/L
1000
1000
100
80-120
Manganese
ug/L
80
82.1
103
80-120
Molybdenum
ug/L
80
79.6
100
80-120
Nickel
ug/L
80
81.6
102
80-120
Potassium
ug/L
1000
1020
102
80-120
Selenium
ug/L
80
81.2
102
80-120
Sodium
ug/L
1000
932
93
80-120
Strontium
ug/L
80
78.3
98
80-120
Thallium
ug/L
80
79.0
99
80-120
Vanadium
ug/L
80
81.5
102
80-120
Zinc
ug/L
80
82.5
103
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
1956666
1956667
MS
MSD
92247913008
Spike
Spike
MS
MSD
MS MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec % Rec
Limits
RPD
RPD Qual
Aluminum
ug/L
127
80
80
246
252
148
155
75-125
2
20 M1
Antimony
ug/L
0.32J
80
80
82.0
82.6
102
103
75-125
1
20
Arsenic
ug/L
ND
80
80
80.9
81.4
101
102
75-125
1
20
Barium
ug/L
1.5
80
80
81.4
82.2
100
101
75-125
1
20
Beryllium
ug/L
ND
80
80
78.9
81.8
99
102
75-125
4
20
Boron
ug/L
ND
80
80
74.6
79.0
93
99
75-125
6
20
Cadmium
ug/L
ND
80
80
79.7
81.0
100
101
75-125
2
20
Calcium
ug/L
346
1000
1000
1210
1340
87
100
75-125
10
20
Chromium
ug/L
0.94
80
80
82.9
82.4
102
102
75-125
1
20
Cobalt
ug/L
0.16J
80
80
79.5
80.0
99
100
75-125
1
20
Copper
ug/L
0.45J
80
80
81.5
82.2
101
102
75-125
1
20
Iron
ug/L
260
1000
1000
1320
1340
106
108
75-125
1
20
Lead
ug/L
0.11
80
80
82.0
82.1
102
103
75-125
0
20
Magnesium
ug/L
48.6
1000
1000
1050
1070
101
102
75-125
1
20
Manganese
ug/L
6.3
80
80
87.0
88.7
101
103
75-125
2
20
Molybdenum
ug/L
0.20J
80
80
79.5
78.2
99
98
75-125
2
20
Nickel
ug/L
ND
80
80
79.5
81.4
99
102
75-125
2
20
Potassium
ug/L
42.3J
1000
1000
985
1010
94
96
75-125
2
20
Selenium
ug/L
ND
80
80
79.3
79.0
99
99
75-125
0
20
Sodium
ug/L
55.5
1000
1000
953
973
90
92
75-125
2
20
Strontium
ug/L
0.80
80
80
78.9
78.4
98
97
75-125
1
20
Thallium
ug/L
ND
80
80
80.5
80.2
101
100
75-125
0
20
Vanadium
ug/L
ND
80
80
81.8
81.0
102
101
75-125
1
20
Zinc
ug/L
ND
80
80
82.9
80.6
102
99
75-125
3
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/28/2015 07:43 AM without the written consent of Pace Analytical Services, Inc..
Page 69 of 88

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800Air6fy0"Je. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15050012
Pace Project No.: 92247913
QC Batch: MPRP/54474 Analysis Method: EPA 6020A
QC Batch Method: EPA 3020 Analysis Description: 6020A Water UPD4
Associated Lab Samples: 92247913011, 92247913012, 92247913013, 92247913014, 92247913015, 92247913016, 92247913017
METHOD BLANK: 1968213 Matrix: Water
Associated Lab Samples: 92247913011, 92247913012, 92247913013, 92247913014, 92247913015, 92247913016, 92247913017
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Aluminum
ug/L
ND
10.0
05/20/1512:35
Antimony
ug/L
ND
0.50
05/20/1512:35
Arsenic
ug/L
ND
0.50
05/20/1512:35
Barium
ug/L
ND
0.30
05/20/1512:35
Beryllium
ug/L
ND
0.20
05/20/1512:35
Boron
ug/L
1.3J
5.0
05/20/1512:35
Cadmium
ug/L
ND
0.080
05/20/1512:35
Calcium
ug/L
ND
40.0
05/20/1512:35
Chromium
ug/L
ND
0.50
05/20/1512:35
Cobalt
ug/L
ND
0.50
05/20/1512:35
Copper
ug/L
ND
1.0
05/20/1512:35
Iron
ug/L
ND
50.0
05/20/1512:35
Lead
ug/L
ND
0.10
05/20/1512:35
Magnesium
ug/L
ND
10.0
05/20/1512:35
Manganese
ug/L
ND
0.50
05/20/1512:35
Molybdenum
ug/L
ND
0.50
05/20/1512:35
Nickel
ug/L
ND
0.50
05/20/1512:35
Potassium
ug/L
ND
50.0
05/20/1512:35
Selenium
ug/L
ND
0.50
05/20/1512:35
Sodium
ug/L
ND
50.0
05/20/1512:35
Strontium
ug/L
ND
0.50
05/20/1512:35
Thallium
ug/L
ND
0.10
05/20/1512:35
Vanadium
ug/L
ND
1.0
05/20/1512:35
Zinc
ug/L
ND
5.0
05/20/1512:35
LABORATORY CONTROL SAMPLE:
Parameter
1968214
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
Aluminum
ug/L
80
89.0
111
80-120
Antimony
ug/L
80
76.3
95
80-120
Arsenic
ug/L
80
75.6
95
80-120
Barium
ug/L
80
81.9
102
80-120
Beryllium
ug/L
80
74.9
94
80-120
Boron
ug/L
80
75.1
94
80-120
Cadmium
ug/L
80
76.7
96
80-120
Calcium
ug/L
1000
1050
105
80-120
Chromium
ug/L
80
79.0
99
80-120
Cobalt
ug/L
80
84.8
106
80-120
Copper
ug/L
80
73.5
92
80-120
Iron
ug/L
1000
1090
109
80-120
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/28/2015 07:43 AM without the written consent of Pace Analytical Services, Inc.. Page 70 of 88

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800Airpyo"Je. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15050012
Pace Project No.: 92247913
LABORATORY CONTROL SAMPLE:
1968214
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits
Qualifiers
Lead
ug/L
80
78.7
98
80-120
Magnesium
ug/L
1000
976
98
80-120
Manganese
ug/L
80
77.9
97
80-120
Molybdenum
ug/L
80
76.8
96
80-120
Nickel
ug/L
80
77.8
97
80-120
Potassium
ug/L
1000
1110
111
80-120
Selenium
ug/L
80
76.5
96
80-120
Sodium
ug/L
1000
1070
107
80-120
Strontium
ug/L
80
76.7
96
80-120
Thallium
ug/L
80
85.1
106
80-120
Vanadium
ug/L
80
77.4
97
80-120
Zinc
ug/L
80
86.0
108
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
1968215
1968216
MS
MSD
92249710021
Spike
Spike
MS
MSD
MS MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec % Rec
Limits
RPD
RPD Qual
Aluminum
ug/L
103
80
80
399
298
370
244
75-125
29
20 M1,R1
Antimony
ug/L
ND
80
80
78.4
77.4
98
97
75-125
1
20
Arsenic
ug/L
ND
80
80
79.5
78.7
99
98
75-125
1
20
Barium
ug/L
1.1
80
80
80.9
79.2
100
98
75-125
2
20
Beryllium
ug/L
ND
80
80
77.8
77.7
97
97
75-125
0
20
Boron
ug/L
1.3J
80
80
84.6
81.5
104
100
75-125
4
20
Cadmium
ug/L
ND
80
80
79.3
78.7
99
98
75-125
1
20
Calcium
ug/L
110
1000
1000
1580
1360
147
125
75-125
14
20 M1
Chromium
ug/L
0.76
80
80
81.9
81.5
101
101
75-125
0
20
Cobalt
ug/L
ND
80
80
80.4
78.9
100
98
75-125
2
20
Copper
ug/L
6.9
80
80
82.0
80.9
94
92
75-125
1
20
Iron
ug/L
397
1000
1000
1690
1600
130
120
75-125
6
20 M1
Lead
ug/L
1.6
80
80
81.1
80.3
99
98
75-125
1
20
Magnesium
ug/L
38.6
1000
1000
1170
1050
113
101
75-125
11
20
Manganese
ug/L
8.5
80
80
88.0
87.9
99
99
75-125
0
20
Molybdenum
ug/L
0.151
80
80
81.0
78.8
101
98
75-125
3
20
Nickel
ug/L
0.75
80
80
82.3
79.6
102
99
75-125
3
20
Potassium
ug/L
62.7
1000
1000
1160
1090
110
103
75-125
6
20
Selenium
ug/L
ND
80
80
79.5
79.2
99
99
75-125
0
20
Sodium
ug/L
73.1
1000
1000
1250
1100
118
102
75-125
13
20
Strontium
ug/L
0.64
80
80
81.4
80.5
101
100
75-125
1
20
Thallium
ug/L
ND
80
80
86.0
86.3
108
108
75-125
0
20
Vanadium
ug/L
ND
80
80
78.7
78.5
98
98
75-125
0
20
Zinc
ug/L
2.8J
80
80
120
95.7
147
116
75-125
23
20 M1,R1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/28/2015 07:43 AM without the written consent of Pace Analytical Services, Inc..
Page 71 of 88

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980%�rpyo"Je. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15050012
Pace Project No.: 92247913
QC Batch: PMST/3544
Analysis Method:
ASTM D2974-87
QC Batch Method: ASTM D2974-87
Analysis Description:
Dry Weight/Percent Moisture
Associated Lab Samples: 92247913001,92247913002,92247913003,92247913004,92247913005,92247913006,92247913007
SAMPLE DUPLICATE: 1209474
35185070001
Dup
Max
Parameter
Units
Result
Result RPD
RPD
Qualifiers
Percent Moisture
%
99.5
99.2 0
10
SAMPLE DUPLICATE: 1209476
92247911001
Dup
Max
Parameter
Units
Result
Result RPD
RPD
Qualifiers
Percent Moisture
%
25.9
26.6 2
10
SAMPLE DUPLICATE: 1209477
92247911010
Dup
Max
Parameter
Units
Result
Result RPD
RPD
Qualifiers
Percent Moisture
%
28.8
29.0 1
10
SAMPLE DUPLICATE: 1209478
35186853004
Dup
Max
Parameter
Units
Result
Result RPD
RPD
Qualifiers
Percent Moisture
%
18.1
19.0 5
10
SAMPLE DUPLICATE: 1209479
35187478002
Dup
Max
Parameter
Units
Result
Result RPD
RPD
Qualifiers
Percent Moisture
%
8.1
8.5 5
10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
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aceAnaiXical
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Pace Analytical Services, Inc.
980Vrpyo"Je. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15050012
Pace Project No.: 92247913
QC Batch: WET/37207 Analysis Method: EPA 9045
QC Batch Method: EPA 9045 Analysis Description: 9045 pH
Associated Lab Samples: 92247913001, 92247913002, 92247913003, 92247913004
SAMPLE DUPLICATE: 1449090
92246570001 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
pH at 25 Degrees C Std. Units 13.0 13.0 0 10
SAMPLE DUPLICATE: 1449091
92247911003 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
pH at 25 Degrees C Std. Units 7.3 7.3 0 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
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aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980Vrpyo"Je. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15050012
Pace Project No.: 92247913
QC Batch: WET/37238 Analysis Method: EPA 9045
QC Batch Method: EPA 9045 Analysis Description: 9045 pH
Associated Lab Samples: 92247913005, 92247913006, 92247913007
SAMPLE DUPLICATE: 1450001
92248135013 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
pH at 25 Degrees C Std. Units 7.1 7.2 0 10
SAMPLE DUPLICATE: 1450002
92247913005 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
pH at 25 Degrees C Std. Units 5.0 5.0 2 10 D6
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
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aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980%�'pyo"Je. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15050012
Pace Project No.: 92247913
QC Batch: WETA/22924 Analysis Method: EPA 300.0
QC Batch Method: EPA 300.0 Analysis Description: 300.0 IC Anions
Associated Lab Samples: 92247913001,92247913002,92247913003,92247913004,92247913005,92247913006,92247913007
METHOD BLANK: 1459398 Matrix: Water
Associated Lab Samples: 92247913001, 92247913002, 92247913003, 92247913004, 92247913005, 92247913006, 92247913007
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Sulfate mg/L 3.4 2.0 05/14/1518:08
LABORATORY CONTROL SAMPLE: 1459399
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Sulfate mg/L 20 19.3 96 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1459400 1459401
MS MSD
92247374003 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfate mg/L 7.1 22.5 22.5 28.3 28.3 94 94 0
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1459402 1459403
MS MSD
92247911005 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfate mg/L 27.6 23 23 47.7 48.2 87 90 1 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 05/28/2015 07:43 AM without the written consent of Pace Analytical Services, Inc..
Page 75 of 88

aceAnaiXical
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Pace Analytical Services, Inc.
98006r6fyo"Je. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15050012
Pace Project No.: 92247913
QC Batch: WETA/22957
Analysis Method: EPA 353.2
QC Batch Method: EPA 353.2
Analysis Description: 353.2 Nitrate + Nitrite, Unpres.
Associated Lab Samples: 92247913001,92247913002,92247913003,92247913004,92247913005,92247913006,92247913007
METHOD BLANK: 1461218
Matrix: Water
Associated Lab Samples: 92247913001, 92247913002,
92247913003, 92247913004, 92247913005, 92247913006, 92247913007
Blank Reporting
Parameter Units
Result Limit Analyzed Qualifiers
Nitrogen, Nitrate mg/L
0.18 0.020 05/15/15 20:50 Z2
LABORATORY CONTROL SAMPLE: 1461219
Spike LCS LCS % Rec
Parameter Units
Conc. Result % Rec Limits Qualifiers
Nitrogen, Nitrate mg/L
2.5 2.5 99 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1461220 1461221
MS MSD
92247374003
Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Nitrogen, Nitrate mg/L 0.26
2.8 2.8 2.9 2.9 93 93 90-110 0 10 H1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1461222 1461223
MS MSD
92247374005 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Nitrogen, Nitrate mg/L 0.75 2.9 2.9 3.5 3.5 94 93 90-110 0 10 H1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 05/28/2015 07:43 AM without the written consent of Pace Analytical Services, Inc..
Page 76 of 88

aceAnaiXical
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Pace Analytical Services, Inc.
980Vrpyo"Je. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15050012
Pace Project No.: 92247913
QC Batch: WETA/22916
Analysis Method: SM 4500-CI-E
QC Batch Method: SM 4500-CI-E
Analysis Description: 4500 Chloride
Associated Lab Samples: 92247913001,92247913002,92247913003,92247913004,92247913005,92247913006,92247913007
METHOD BLANK: 1458586
Matrix: Water
Associated Lab Samples: 92247913001, 92247913002,
92247913003, 92247913004, 92247913005, 92247913006, 92247913007
Blank Reporting
Parameter Units
Result Limit Analyzed Qualifiers
Chloride mg/L
ND 1.0 05/14/15 05:46
LABORATORY CONTROL SAMPLE: 1458587
Spike LCS LCS % Rec
Parameter Units
Conc. Result % Rec Limits Qualifiers
Chloride mg/L
20 19.9 100 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1458588 1458589
MS MSD
92247374003
Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Chloride mg/L ND
22.5 22.5 23.9 23.3 105 102 90-110 3 10
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1458590 1458591
MS MSD
92247911005 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Chloride mg/L ND 23 23 24.1 23.9 103 102 90-110 1 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 05/28/2015 07:43 AM without the written consent of Pace Analytical Services, Inc..
Page 77 of 88

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980mirpyo"Je. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15050012
Pace Project No.: 92247913
QC Batch: WETA/46118 Analysis Method: EPA 9056
QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions
Associated Lab Samples: 92247913001,92247913002,92247913003,92247913004,92247913005,92247913006,92247913007
METHOD BLANK: 1204695 Matrix: Solid
Associated Lab Samples:
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Chloride mg/kg ND 50.0 05/06/1510:44
Sulfate mg/kg ND 50.0 05/06/1510:44
LABORATORY CONTROL SAMPLE:
1204696
Parameter
Units
Chloride
mg/kg
Sulfate
mg/kg
MATRIX SPIKE SAMPLE:
1204698
Parameter
Units
Chloride
mg/kg
Sulfate
mg/kg
SAMPLE DUPLICATE: 1204697
Parameter
Chloride
Sulfate
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
491 453 92 80-120
491 450 92 80-120
92247909001 Spike MS MS % Rec
Result Conc. Result % Rec Limits Qualifiers
ND 561 492 88 80-120
ND 561 513 92 80-120
92247909001 Dup
Units Result Result
mg/kg ND ND
mg/kg ND ND
Max
RPD RPD Qualifiers
20 D3
20 D3
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980cbypyo"Je. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15050012
Pace Project No.: 92247913
QC Batch: WETA/46117
Analysis Method: EPA 9056
QC Batch Method: EPA 9056
Analysis Description: 9056 IC Anions
Associated Lab Samples: 92247913001,92247913002,92247913003,92247913004,92247913005,92247913006,92247913007
METHOD BLANK: 1204691
Matrix: Solid
Associated Lab Samples:
Blank Reporting
Parameter
Units
Result Limit Analyzed
Qualifiers
Nitrate as N
mg/kg
ND 5.0 05/06/15 10:44
LABORATORY CONTROL SAMPLE:
1204692
Spike LCS LCS
% Rec
Parameter
Units
Conc. Result % Rec
Limits Qualifiers
Nitrate as N
mg/kg
49.1 46.2 94
80-120
MATRIX SPIKE SAMPLE:
1204694
92247909001 Spike MS
MS % Rec
Parameter
Units
Result Conc. Result
% Rec Limits Qualifiers
Nitrate as N
mg/kg
ND 56.1 49.9
89 80-120 H3
SAMPLE DUPLICATE: 1204693
92247909001 Dup
Max
Parameter
Units
Result Result RPD
RPD Qualifiers
Nitrate as N
mg/kg
ND ND
20 H3
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
98006rpyo"Je. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15050012
Pace Project No.: 92247913
QC Batch: WETA/28572
Analysis Method: EPA 9060
QC Batch Method: EPA 9060
Analysis Description: 9060 TOC Average
Associated Lab Samples: 92247913001, 92247913002,
92247913003, 92247913004
METHOD BLANK: 1160051
Matrix: Solid
Associated Lab Samples:
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Mean Total Organic Carbon mg/kg
ND 600
05/22/15 08:19
LABORATORY CONTROL SAMPLE: 1160052
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Mean Total Organic Carbon mg/kg
120000 136000
114 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1160053 1160054
MS MSD
92247374002
Spike Spike MS
MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec Limits RPD RPD Qual
Mean Total Organic Carbon mg/kg 2470
7300 7350 10100
9990 104 102 50-150 1 30
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1160055 1160056
MS MSD
92247913001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Mean Total Organic Carbon mg/kg ND 6580 6620 6330 6460 91 93 50-150 2 30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 05/28/2015 07:43 AM without the written consent of Pace Analytical Services, Inc..
Page 80 of 88

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980C�ir6fy0"Je. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15050012
Pace Project No.: 92247913
QC Batch: WETA/28613
Analysis Method: EPA 9060
QC Batch Method: EPA 9060
Analysis Description: 9060 TOC Average
Associated Lab Samples: 92247913005, 92247913006,
92247913007
METHOD BLANK: 1161513
Matrix: Solid
Associated Lab Samples:
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Mean Total Organic Carbon mg/kg
ND 600
05/26/15 08:34
LABORATORY CONTROL SAMPLE: 1161514
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Mean Total Organic Carbon mg/kg
120000 130000
108 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1161515 1161516
MS MSD
92247835016
Spike Spike MS
MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec Limits RPD RPD Qual
Mean Total Organic Carbon mg/kg 2750
7410 7410 10300
10900 101 110 50-150 6 30
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1161527 1161528
MS MSD
92248424001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Mean Total Organic Carbon mg/kg 50700 60900 60900 113000 106000 102 91 50-150 6 30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 05/28/2015 07:43 AM without the written consent of Pace Analytical Services, Inc..
Page 81 of 88

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
98004rpyo"Je. Suite 100
Huntersville, NC 28078
[phone]
QUALIFIERS
Project: J15050012
Pace Project No.: 92247913
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
LABORATORIES
PASI-A
Pace Analytical Services - Asheville
PASI-G
Pace Analytical Services - Green Bay
PASI-M
Pace Analytical Services - Minneapolis
PASI-O
Pace Analytical Services - Ormond Beach
BATCH QUALIFIERS
Batch: ICP/14693
Ill Samples in this batch were diluted due to the presence of high levels of non -target analytes or other matrix interference.
Batch: ICPM/9756
[1j Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
Batch: ICP/14694
Ill Samples in this batch were diluted due to the presence of high levels of non -target analytes or other matrix interference.
Batch: ICPM/9757
Ill Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
ANALYTE QUALIFIERS
1g %RSD>40
B Analyte was detected in the associated method blank.
REPORT OF LABORATORY ANALYSIS
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aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800Airpyo"Je. Suite 100
Huntersville, INC 28078
[phone]
QUALIFIERS
Project: J15050012
Pace Project No.: 92247913
ANALYTE QUALIFIERS
Cu The continuing calibration for this compound is outside of Pace Analytical acceptance limits. Analyte presence below
reporting limits in associated samples. Results unaffected by high bias.
D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
D6 The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits.
E Analyte concentration exceeded the calibration range. The reported result is estimated.
H1 Analysis conducted outside the EPA method holding time.
H3 Sample was received or analysis requested beyond the recognized method holding time.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
N2 The lab does not hold TIN accreditation for this parameter.
R1 RPD value was outside control limits.
Z2 Analyte present in the associated method blank above the detection limit.
REPORT OF LABORATORY ANALYSIS
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aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800*rpyo"Je. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
Pace Project No.:
J15050012
92247913
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92247913001
2015012925
EPA 3050
MPRP/24040
EPA 6010
ICP/14693
92247913002
2015012926
EPA 3050
MPRP/24040
EPA 6010
ICP/14693
92247913003
2015012927
EPA 3050
MPRP/24040
EPA 6010
ICP/14693
92247913004
2015012928
EPA 3050
MPRP/24042
EPA 6010
ICP/14694
92247913005
2015012929
EPA 3050
MPRP/24042
EPA 6010
ICP/14694
92247913006
2015012930
EPA 3050
MPRP/24042
EPA6010
ICP/14694
92247913007
2015012931
EPA 3050
MPRP/24042
EPA 6010
ICP/14694
92247913001
2015012925
EPA 3050
MPRP/24041
EPA 6020
ICPM/9756
92247913002
2015012926
EPA 3050
MPRP/24041
EPA 6020
ICPM/9756
92247913003
2015012927
EPA 3050
MPRP/24041
EPA 6020
ICPM/9756
92247913004
2015012928
EPA 3050
MPRP/24043
EPA 6020
ICPM/9757
92247913005
2015012929
EPA 3050
MPRP/24043
EPA 6020
ICPM/9757
92247913006
2015012930
EPA 3050
MPRP/24043
EPA 6020
ICPM/9757
92247913007
2015012931
EPA 3050
MPRP/24043
EPA 6020
ICPM/9757
92247913008
2015012934
EPA 3020
MPRP/54160
EPA 6020A
ICPM/24182
92247913009
2015012935
EPA 3020
MPRP/54160
EPA 6020A
ICPM/24182
92247913010
2015012936
EPA 3020
MPRP/54160
EPA 6020A
ICPM/24182
92247913011
2015012925 SPLP
EPA 3020
MPRP/54474
EPA 6020A
ICPM/24375
92247913012
2015012926 SPLP
EPA 3020
MPRP/54474
EPA 6020A
ICPM/24375
92247913013
2015012927 SPLP
EPA 3020
MPRP/54474
EPA 6020A
ICPM/24375
92247913014
2015012928 SPLP
EPA 3020
MPRP/54474
EPA 6020A
ICPM/24375
92247913015
2015012929 SPLP
EPA 3020
MPRP/54474
EPA 6020A
ICPM/24375
92247913016
2015012930 SPLP
EPA 3020
MPRP/54474
EPA 6020A
ICPM/24375
92247913017
2015012931 SPLP
EPA 3020
MPRP/54474
EPA 6020A
ICPM/24375
92247913008
2015012934
EPA 7470A
MERP/13434
EPA 7470A
MERC/15625
92247913009
2015012935
EPA 7470A
MERP/13434
EPA 7470A
MERC/15625
92247913010
2015012936
EPA 7470A
MERP/13434
EPA 7470A
MERC/15625
92247913011
2015012925 SPLP
EPA 7470A
MERP/13580
EPA 7470A
MERC/15808
92247913012
2015012926 SPLP
EPA 7470A
MERP/13580
EPA 7470A
MERC/15808
92247913013
2015012927 SPLP
EPA 7470A
MERP/13580
EPA 7470A
MERC/15808
92247913014
2015012928 SPLP
EPA 7470A
MERP/13580
EPA 7470A
MERC/15808
92247913015
2015012929 SPLP
EPA 7470A
MERP/13580
EPA 7470A
MERC/15808
92247913016
2015012930 SPLP
EPA 7470A
MERP/13580
EPA 7470A
MERC/15808
92247913017
2015012931 SPLP
EPA 7470A
MERP/13580
EPA 7470A
MERC/15808
92247913001
2015012925
EPA 7471
MERP/5697
EPA 7471
MERC/5684
92247913002
2015012926
EPA 7471
MERP/5697
EPA 7471
MERC/5684
92247913003
2015012927
EPA 7471
MERP/5697
EPA 7471
MERC/5684
92247913004
2015012928
EPA 7471
MERP/5698
EPA 7471
MERC/5685
92247913005
2015012929
EPA 7471
MERP/5698
EPA 7471
MERC/5685
92247913006
2015012930
EPA 7471
MERP/5698
EPA 7471
MERC/5685
92247913007
2015012931
EPA 7471
MERP/5698
EPA 7471
MERC/5685
92247913001
2015012925
ASTM D2974-87
PMST/3544
92247913002
2015012926
ASTM D2974-87
PMST/3544
92247913003
2015012927
ASTM D2974-87
PMST/3544
REPORT OF LABORATORY ANALYSIS
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aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800Iirpyo"Je. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: J15050012
Pace Project No.: 92247913
Lab ID Sample ID QC Batch Method QC Batch
92247913004
2015012928
ASTM D2974-87
PMST/3544
92247913005
2015012929
ASTM D2974-87
PMST/3544
92247913006
2015012930
ASTM D2974-87
PMST/3544
92247913007
2015012931
ASTM D2974-87
PMST/3544
92247913001
2015012925
EPA 9045
WET/37207
92247913002
2015012926
EPA 9045
WET/37207
92247913003
2015012927
EPA 9045
WET/37207
92247913004
2015012928
EPA 9045
WET/37207
92247913005
2015012929
EPA 9045
WET/37238
92247913006
2015012930
EPA 9045
WET/37238
92247913007
2015012931
EPA 9045
WET/37238
92247913001
2015012925
EPA 300.0
WETA/22924
92247913002
2015012926
EPA 300.0
WETA/22924
92247913003
2015012927
EPA 300.0
WETA/22924
92247913004
2015012928
EPA 300.0
WETA/22924
92247913005
2015012929
EPA 300.0
WETA/22924
92247913006
2015012930
EPA 300.0
WETA/22924
92247913007
2015012931
EPA 300.0
WETA/22924
92247913001
2015012925
EPA 353.2
WETA/22957
92247913002
2015012926
EPA 353.2
WETA/22957
92247913003
2015012927
EPA 353.2
WETA/22957
92247913004
2015012928
EPA 353.2
WETA/22957
92247913005
2015012929
EPA 353.2
WETA/22957
92247913006
2015012930
EPA 353.2
WETA/22957
92247913007
2015012931
EPA 353.2
WETA/22957
92247913001
2015012925
SM 4500-CI-E
WETA/22916
92247913002
2015012926
SM 4500-CI-E
WETA/22916
92247913003
2015012927
SM 4500-CI-E
WETA/22916
92247913004
2015012928
SM 4500-CI-E
WETA/22916
92247913005
2015012929
SM 4500-CI-E
WETA/22916
92247913006
2015012930
SM 4500-CI-E
WETA/22916
92247913007
2015012931
SM 4500-CI-E
WETA/22916
92247913001
2015012925
EPA 9056
WETA/46118
92247913002
2015012926
EPA 9056
WETA/46118
92247913003
2015012927
EPA 9056
WETA/46118
92247913004
2015012928
EPA 9056
WETA/46118
92247913005
2015012929
EPA 9056
WETA/46118
92247913006
2015012930
EPA 9056
WETA/46118
92247913007
2015012931
EPA 9056
WETA/46118
92247913001
2015012925
EPA 9056
WETA/46117
92247913002
2015012926
EPA 9056
WETA/46117
92247913003
2015012927
EPA 9056
WETA/46117
92247913004
2015012928
EPA 9056
WETA/46117
92247913005
2015012929
EPA 9056
WETA/46117
92247913006
2015012930
EPA 9056
WETA/46117
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/28/2015 07:43 AM without the written consent of Pace Analytical Services, Inc..
Analytical
Analytical Method Batch
Page 85 of 88

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800q6r6fy0"Je. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: J15050012
Pace Project No.: 92247913
Lab ID
Sample ID
QC Batch Method
QC Batch
92247913007
2015012931
EPA 9056
WETA/46117
92247913001
2015012925
EPA 9060
WETA/28572
92247913001
2015012925
EPA 9060
WETA/28573
92247913002
2015012926
EPA 9060
WETA/28572
92247913002
2015012926
EPA 9060
WETA/28573
92247913003
2015012927
EPA 9060
WETA/28572
92247913003
2015012927
EPA 9060
WETA/28573
92247913004
2015012928
EPA 9060
WETA/28572
92247913004
2015012928
EPA 9060
WETA/28573
92247913005
2015012929
EPA 9060
WETA/28613
92247913005
2015012929
EPA 9060
WETA/28614
92247913006
2015012930
EPA 9060
WETA/28613
92247913006
2015012930
EPA 9060
WETA/28614
92247913007
2015012931
EPA 9060
WETA/28613
92247913007
2015012931
EPA 9060
WETA/28614
Date: 05/28/2015 07:43 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Analytical Method
Analytical
Batch
Page 86 of 88

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