NC0003433_J15040620 Report_20150902

+ DUKE Analytical Laboratory 1 of92
ENERGY
Order Number:
Project Name:
Customer Name(s):
Customer Address:
Lab Contact:
Report Authorized By:
(Signature)
Program Comments:
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone:[phone] Fax:[phone]
Order Summary Report
J15040620
CAPE FEAR - AB GW ASSESSMENT SOIL
Tim Hunsucker, Chris Suttell, Kathy Webb, John Toepfer
Margaret Galvin -Karr Phone: [phone]
MXG4644(101161)
0 2015.06.0109:03:24-04'00' Date:
Margaret Galvin -Karr
Please contact the Program Manager (Margaret Galvin -Karr) with any questions regarding this report.
Data Flags & Calculations:
5/28/2015
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Sample ID's & Descriptions: 2 of 92
Collection
Sample ID Plant/Station Date and Time Collected By Sample Description
2015012031
Cape Fear
21-Apr-15 1:15 PM
Illegible
MW-21SB (0-2bgs)
2015012032
Cape Fear
21-Apr-15 1:30 PM
Illegible
MW-21SB (5-6 bgs)
2015012033
Cape Fear
21-Apr-15 1:50 PM
Illegible
MW-21SB (9-11 bgs)
2015012034
Cape Fear
23-Apr-15 12:40 PM
Illegible
ERB -19 (Sonic)
2015012035
Cape Fear
23-Apr-15 2:30 PM
Illegible
MW-513R SB (0-2)
2015012036
Cape Fear
23-Apr-15 2:50 PM
Illegible
MW-5BR SB (10-12)
2015012037
Cape Fear
23-Apr-15 3:10 PM
Illegible
MW-5BR SB (18-20)
2015012038
Cape Fear
21-Apr-15 3:50 PM
Illegible
ERB-18 (Sonic)
2015012039
Cape Fear
23-Apr-15 3:10 PM
Illegible
DUP
9 Total Samples

3 of 92
Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals Yes No
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits. ❑ Yes❑ No
All laboratory QA/QC requirements are acceptable.❑ Yes ❑ No
Report Sections Included:
U Job Summary Report
❑ Sample Identification
n Technical Validation of Data Package
❑ Analytical Laboratory Certificate of Analysis
❑ Analytical Laboratory QC Report
Reviewed By: Date:
Sub -contracted Laboratory Results
❑ Customer Specific Data Sheets, Reports, & Documentation
❑ Customer Database Entries
0 Chain of Custody
[I/0] Electronic Data Deliverable (EDD) Sent Separately

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15040620
Site: MW-21 SB (0-2bgs)
Collection Date: 21-Apr-15 1:15 PM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
4 of 92
Sample #: 2015012031
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15040620
Site: MW-21 SB (5-6 bgs)
Collection Date: 21-Apr-15 1:30 PM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
SPLP LEACHATE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
5 of 92
Sample #: 2015012032
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15040620
Site: MW-21 SB (9-11 bgs)
Collection Date: 21-Apr-15 1:50 PM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
SPLP LEACHATE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
6 of 92
Sample #: 2015012033
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15040620
Site: ERB -19 (Sonic)
Collection Date: 23-Apr-15 12:40 PM
Analyte Result Units Qualifiers RDL DF
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Sample #: 2015012034
Matrix: SOIL
7 of 92
Method Analysis Date/Time Analyst
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15040620
Site: MW-5BR SIB (0-2)
Collection Date: 23-Apr-15 2:30 PM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
SPLP LEACHATE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
8 of 92
Sample #: 2015012035
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15040620
Site: MW-5BR SB (10-12)
Collection Date: 23-Apr-15 2:50 PM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
SPLP LEACHATE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
9 of 92
Sample #: 2015012036
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15040620
Site: MW-5BR SB (18-20)
Collection Date: 23-Apr-15 3:10 PM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
10 of 92
Sample #: 2015012037
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis 11 of 92
This report shall not be reproduced, except in full.
Order # J15040620
Site: ERB-18 (Sonic)
Collection Date: 21-Apr-15 3:50 PM
Analyte Result Units Qualifiers RDL DF
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Sample #: 2015012038
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15040620
Site: DUP
Collection Date: 23-Apr-15 3:10 PM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
12 of 92
Sample #: 2015012039
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 ff�i�c&fie. Suite 100
Huntersville, INC 28078
[phone]
May 20, 2015
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg.7405 MG30A2
Huntersville, NC 28078
RE: Project: J 15040620
Pace Project No.: 92247080
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on April 24, 2015. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TN standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc: Marge Galvin -Karr, Duke Energy
Program Manager, Duke Energy
Rodney Wilke, Duke Energy
p«FO
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
lqe� ��� without the written consent of Pace Analytical Services, Inc..
BRAT,
Page 1 of 79

lacmnalyfica(
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kiincsfke. Suite 100
Huntersville, NC 28078
[phone]
Project: J15040620
Pace Project No.: 92247080
Minnesota Certification IDs
1700 Elm Street SE Suite 200, Minneapolis, MN 55414
A21-A Certification #: 2926.01
Alaska Certification #: UST-078
Alaska Certification #MN00064
Alabama Certification #40770
Arizona Certification #: AZ-0014
Arkansas Certification #: 88-0680
California Certification #: 01155CA
Colorado Certification #Pace
Connecticut Certification #: PH-0256
EPA Region 8 Certification #: 8TMS-L
Florida/NELAP Certification #: E87605
Guam Certification #:14-008r
Georgia Certification #: 959
Georgia EPD #: Pace
Idaho Certification #: MN00064
Hawaii Certification #MN00064
Illinois Certification #: 200011
Indiana Certification#C-MN-01
Iowa Certification #: 368
Kansas Certification #: E-10167
Kentucky Dept of Envi. Protection - DW #90062
Kentucky Dept of Envi. Protection - WW #:90062
Louisiana DEQ Certification #: 3086
Louisiana DHH #: LA140001
Maine Certification #: 2013011
Maryland Certification #: 322
Michigan DEPH Certification #: 9909
Ormond Beach Certification IDs
8 East Tower Circle, Ormond Beach, FL 32174
Alabama Certification #: 41320
Connecticut Certification #: PH-0216
Delaware Certification: FL NELAC Reciprocity
Florida Certification #: E83079
Georgia Certification #: 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification #: 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383
Kentucky Certification #: 90050
Louisiana Certification #: FL NELAC Reciprocity
Louisiana Environmental Certificate #: 05007
Maryland Certification: #346
Massachusetts Certification #: M-FL1264
Michigan Certification #: 9911
Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236
Green Bay Certification IDs
1241 Bellevue Street, Green Bay, WI 54302
Florida/NELAP Certification #: E87948
Illinois Certification #: 200050
Kentucky Certification #: 82
Louisiana Certification #: 04168
Minnesota Certification #: 055-999-334
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
CERTIFICATIONS
Minnesota Certification #: 027-053-137
Mississippi Certification #: Pace
Montana Certification #: MT0092
Nevada Certification #: MN_00064
Nebraska Certification #: Pace
New Jersey Certification #: MN-002
New York Certification #: 11647
North Carolina Certification #: 530
North Carolina State Public Health #: 27700
North Dakota Certification #: R-036
Ohio EPA#: 4150
Ohio VAP Certification #: CL101
Oklahoma Certification #: 9507
Oregon Certification #: MN200001
Oregon Certification #: MN300001
Pennsylvania Certification #: 68-00563
Puerto Rico Certification
Saipan (CNMI) #:MP0003
South Carolina #:74003001
Texas Certification #: T104704192
Tennessee Certification #: 02818
Utah Certification #: MN000642013-4
Virginia DGS Certification #: 251
Virginia/VELAP Certification #: Pace
Washington Certification #: C486
West Virginia Certification #: 382
West Virginia DHHR #:9952C
Wisconsin Certification #: 999407970
Montana Certification #: Cert 0074
Nebraska Certification: NE-OS-28-14
Nevada Certification: FL NELAC Reciprocity
New Hampshire Certification #: 2958
New Jersey Certification #: FL765
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FLO1264
South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
Washington Certification #: C955
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
North Dakota Certification #: R-150
South Carolina Certification #: 83006001
Texas Certification #: T104704529-14-1
US Dept of Agriculture #: S-76505
Wisconsin Certification #: 405132750
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 2 of 79

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 f igc&yq"�e. Suite 100
Huntersville, NC 28078
[phone]
Project: J15040620
Pace Project No.: 92247080
Asheville Certification IDs
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
CERTIFICATIONS
West Virginia Certification #: 356
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 3 of 79

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 ff�i�c&fie. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE SUMMARY
Project: J15040620
Pace Project No.: 92247080
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92247080001
2015012031
Solid
04/21/1513:15
04/24/15 12:54
92247080002
2015012032
Solid
04/21/1513:30
04/24/15 12:54
92247080003
2015012033
Solid
04/21/1513:50
04/24/15 12:54
92247080004
2015012035
Solid
04/23/1514:30
04/24/15 12:54
92247080005
2015012036
Solid
04/23/1514:50
04/24/15 12:54
92247080006
2015012037
Solid
04/23/1515:10
04/24/15 12:54
92247080007
2015012039
Solid
04/23/1515:10
04/24/15 12:54
92247080008
2015012034
Water
04/23/1512:40
04/24/15 12:54
92247080009
2015012038
Water
04/21/1515:50
04/24/15 12:54
92247080010
2015012032 SPLP
Water
04/21/15 13:30
04/24/15 12:54
92247080011
2015012033 SPLP
Water
04/21/15 13:50
04/24/15 12:54
92247080012
2015012035 SPLP
Water
04/23/15 14:30
04/24/15 12:54
92247080013
2015012036 SPLP
Water
04/23/15 14:50
04/24/15 12:54
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 4 of 79

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 fflic&fie. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
J15040620
92247080
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92247080001
2015012031
EPA 6010
CKJ
16
PASI-0
EPA 6020
DRS
8
PASI-O
EPA 7471
CKJ
1
PASI-O
ASTM D2974-87
MLO
1
PASI-O
EPA 9045
TEP
1
PASI-A
EPA 9056
CMB
2
PASI-O
EPA 9056
CMB
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92247080002
2015012032
EPA 6010
CKJ
16
PASI-0
EPA 6020
DRS
8
PASI-O
EPA 7471
CKJ
1
PASI-O
ASTM D2974-87
MLO
1
PASI-O
EPA 9045
TEP
1
PASI-A
EPA 300.0
AES2
1
PASI-A
EPA 353.2
DMN
1
PASI-A
SM 4500-CI-E
SER
1
PASI-A
EPA 9056
AIS
2
PASI-O
EPA 9056
CMB
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92247080003
2015012033
EPA 6010
CKJ
16
PASI-0
EPA 6020
DRS
8
PASI-O
EPA 7471
CKJ
1
PASI-O
ASTM D2974-87
MLO
1
PASI-O
EPA 9045
TEP
1
PASI-A
EPA 300.0
AES2
1
PASI-A
EPA 353.2
DMN
1
PASI-A
SM 4500-CI-E
SER
1
PASI-A
EPA 9056
AIS
2
PASI-O
EPA 9056
CMB
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92247080004
2015012035
EPA 6010
CKJ
16
PASI-0
EPA 6020
DRS
8
PASI-O
EPA 7471
CKJ
1
PASI-O
ASTM D2974-87
MLO
1
PASI-O
EPA 9045
TEP
1
PASI-A
EPA 300.0
AES2
1
PASI-A
EPA 353.2
DMN
1
PASI-A
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 5 of 79

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 ffligc&fie. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project: J15040620
Pace Project No.: 92247080
Lab ID
Sample ID
Method
Analysts
Analytes
Reported
Laboratory
SM 4500-CI-E
SER
1
PASI-A
EPA 9056
CMB
2
PASI-O
EPA 9056
CMB
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92247080005
2015012036
EPA 6010
CKJ
16
PASI-0
EPA 6020
DRS
8
PASI-O
EPA 7471
CKJ
1
PASI-O
ASTM D2974-87
MLO
1
PASI-O
EPA 9045
TEP
1
PASI-A
EPA 300.0
AES2
1
PASI-A
EPA 353.2
DMN
1
PASI-A
SM 4500-CI-E
SER
1
PASI-A
EPA 9056
CMB
2
PASI-O
EPA 9056
CMB
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92247080006
2015012037
EPA 6010
CKJ
16
PASI-0
EPA 6020
DRS
8
PASI-O
EPA 7471
CKJ
1
PASI-O
ASTM D2974-87
MLO
1
PASI-O
EPA 9045
TEP
1
PASI-A
EPA 9056
CMB
2
PASI-O
EPA 9056
CMB
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92247080007
2015012039
EPA 6010
CKJ
16
PASI-0
EPA 6020
DRS
8
PASI-O
EPA 7471
CKJ
1
PASI-O
ASTM D2974-87
MLO
1
PASI-O
EPA 9045
TEP
1
PASI-A
EPA 9056
CMB
2
PASI-O
EPA 9056
CMB
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92247080008
2015012034
EPA 6020A
TT3
24
PASI-M
EPA 7470A
JDD
1
PASI-M
92247080009
2015012038
EPA 6020A
TT3
24
PASI-M
EPA 7470A
JDD
1
PASI-M
92247080010
2015012032 SPLP
EPA 6020A
TT3
24
PASI-M
EPA 7470A
JDD
1
PASI-M
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 6 of 79

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 ffli�c&fie. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
J15040620
92247080
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92247080011
2015012033 SPLP
EPA 6020A
TT3
24
PASI-M
EPA 7470A
JDD
1
PASI-M
92247080012
2015012035 SPLP
EPA 6020A
TT3
24
PASI-M
EPA 7470A
JDD
1
PASI-M
92247080013
2015012036 SPLP
EPA 6020A
TT3
24
PASI-M
EPA 7470A
JDD
1
PASI-M
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 7 of 79

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 KP�c&fie. Suite 100
Huntersville, NC 28078
[phone]
Project: J15040620
Pace Project No.: 92247080
Lab Sample ID Client Sample ID
Method Parameters
SUMMARY OF DETECTION
Result Units Report Limit Analyzed
92247080001
2015012031
EPA 6010
Aluminum
1480
mg/kg
30.2
05/05/15 14:58
EPA 6010
Barium
66.1
mg/kg
3.0
05/05/15 14:58
EPA 6010
Calcium
93.3J
mg/kg
151
05/05/15 14:58
EPA 6010
Chromium
3.7
mg/kg
1.5
05/05/15 14:58
EPA 6010
Copper
2.2
mg/kg
1.5
05/05/15 14:58
EPA 6010
Iron
8420
mg/kg
12.1
05/05/15 14:58
EPA 6010
Magnesium
178
mg/kg
151
05/05/15 14:58
EPA 6010
Manganese
25.3
mg/kg
1.5
05/05/15 14:58
EPA 6010
Strontium
4.0
mg/kg
3.0
05/05/15 14:58
EPA 6010
Zinc
3.1J
mg/kg
6.0
05/05/15 14:58
EPA 6020
Arsenic
60.3
mg/kg
6.0
05/05/15 09:48
EPA 6020
Selenium
3.2J
mg/kg
6.0
05/05/15 09:48
EPA 6020
Vanadium
14.9
mg/kg
6.0
05/05/15 09:48
EPA 7471
Mercury
0.013
mg/kg
0.0095
05/04/15 15:47
ASTM D2974-87
Percent Moisture
13.9
%
0.10
05/05/15 10:24
EPA 9045
pH at 25 Degrees C
3.8
Std. Units
0.10
04/29/15 23:15
EPA 9060
Total Organic Carbon
921
mg/kg
696
05/14/15 11:33
EPA 9060
Total Organic Carbon
957
mg/kg
700
05/14/15 11:38
EPA 9060
Total Organic Carbon
870
mg/kg
698
05/14/15 11:44
EPA 9060
Total Organic Carbon
979
mg/kg
702
05/14/15 11:50
EPA 9060
Mean Total Organic Carbon
932
mg/kg
699
05/14/15 11:33
EPA 9060
RSD%
5.1
%
05/14/15 11:33
92247080002
2015012032
EPA 6010
Aluminum
2490
mg/kg
28.9
05/05/15 15:02
EPA 6010
Barium
50.0
mg/kg
2.9
05/05/15 15:02
EPA 6010
Calcium
92.OJ
mg/kg
144
05/05/15 15:02
EPA 6010
Chromium
5.8
mg/kg
1.4
05/05/15 15:02
EPA 6010
Copper
3.0
mg/kg
1.4
05/05/15 15:02
EPA 6010
Iron
14500
mg/kg
11.6
05/05/15 15:02
EPA 6010
Magnesium
447
mg/kg
144
05/05/15 15:02
EPA 6010
Manganese
100
mg/kg
1.4
05/05/15 15:02
EPA 6010
Nickel
0.77J
mg/kg
1.4
05/05/15 15:02
EPA 6010
Strontium
4.0
mg/kg
2.9
05/05/15 15:02
EPA 6010
Zinc
5.8
mg/kg
5.8
05/05/15 15:02
EPA 6020
Lead
3.7J
mg/kg
5.8
05/05/15 09:50
EPA 6020
Vanadium
22.0
mg/kg
5.8
05/05/15 09:50
EPA 7471
Mercury
0.0066J
mg/kg
0.0094
05/04/15 15:49
ASTM D2974-87
Percent Moisture
11.3
%
0.10
05/05/15 10:24
EPA 9045
pH at 25 Degrees C
3.6
Std. Units
0.10
04/29/15 23:15
EPA 300.0
Sulfate
11.4
mg/L
2.3
05/07/15 11:40
EPA 353.2
Nitrogen, Nitrate
0.23
mg/L
0.23
05/13/15 13:21
EPA 9056
Sulfate
194J
mg/kg
283
05/03/15 17:12
EPA 9060
Total Organic Carbon
560J
mg/kg
674
05/14/15 12:42
EPA 9060
Total Organic Carbon
523J
mg/kg
676
05/14/15 12:47
EPA 9060
Total Organic Carbon
548J
mg/kg
672
05/14/15 12:54
EPA 9060
Total Organic Carbon
531J
mg/kg
678
05/14/15 13:00
EPA 9060
Mean Total Organic Carbon
540J
mg/kg
675
05/14/15 12:42
REPORT OF LABORATORY ANALYSIS
H3
H3
B
H1
D3
Qualifiers
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 8 of 79

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 K�n�c&fie. Suite 100
Huntersville, NC 28078
[phone]
Project: J15040620
Pace Project No.: 92247080
Lab Sample ID Client Sample ID
Method Parameters
SUMMARY OF DETECTION
Result Units Report Limit Analyzed Qualifiers
92247080002
2015012032
EPA 9060
RSD%
3.1
%
05/14/15 12:42
92247080003
2015012033
EPA 6010
Aluminum
7520
mg/kg
29.3
05/05/15 15:06
EPA 6010
Barium
52.2
mg/kg
2.9
05/05/15 15:06
EPA 6010
Beryllium
0.35
mg/kg
0.29
05/05/15 15:06
EPA 6010
Calcium
263
mg/kg
147
05/05/15 15:06
EPA 6010
Chromium
10.7
mg/kg
1.5
05/05/15 15:06
EPA 6010
Copper
9.4
mg/kg
1.5
05/05/15 15:06
EPA 6010
Iron
15700
mg/kg
11.7
05/05/15 15:06
EPA 6010
Magnesium
1670
mg/kg
147
05/05/15 15:06
EPA 6010
Manganese
231
mg/kg
1.5
05/05/15 15:06
EPA 6010
Nickel
4.0
mg/kg
1.5
05/05/15 15:06
EPA 6010
Potassium
150J
mg/kg
293
05/05/15 15:06
EPA 6010
Strontium
7.4
mg/kg
2.9
05/05/15 15:06
EPA 6010
Zinc
20.6
mg/kg
5.9
05/05/15 15:06
EPA 6020
Arsenic
3.2J
mg/kg
5.9
05/05/15 10:00
EPA 6020
Cobalt
5.2J
mg/kg
5.9
05/05/15 10:00
EPA 6020
Lead
6.9
mg/kg
5.9
05/05/15 10:00
EPA 6020
Vanadium
41.3
mg/kg
5.9
05/05/15 10:00
EPA 7471
Mercury
0.0086J
mg/kg
0.0096
05/04/15 15:51
ASTM D2974-87
Percent Moisture
13.0
%
0.10
05/05/15 10:24
EPA 9045
pH at 25 Degrees C
4.0
Std. Units
0.10
04/29/15 23:15
H3
EPA 300.0
Sulfate
14.3
mg/L
2.3
05/07/15 12:21
B
EPA353.2
Nitrogen, Nitrate
0.26
mg/L
0.23
05/13/15 13:30
H1
EPA 9056
Sulfate
1991
mg/kg
280
05/03/15 17:34
D3
EPA 9060
Total Organic Carbon
785
mg/kg
687
05/14/15 13:06
EPA 9060
Total Organic Carbon
792
mg/kg
689
05/14/15 13:13
EPA 9060
Total Organic Carbon
829
mg/kg
692
05/14/15 13:19
EPA 9060
Total Organic Carbon
802
mg/kg
689
05/14/15 13:25
EPA 9060
Mean Total Organic Carbon
802
mg/kg
689
05/14/15 13:06
EPA 9060
RSD%
2.4
%
05/14/15 13:06
92247080004
2015012035
EPA 6010
Aluminum
11500
mg/kg
30.4
05/05/15 15:10
EPA 6010
Barium
62.8
mg/kg
3.0
05/05/15 15:10
EPA 6010
Beryllium
0.21J
mg/kg
0.30
05/05/15 15:10
EPA 6010
Calcium
1230
mg/kg
152
05/05/15 15:10
EPA 6010
Chromium
24.7
mg/kg
1.5
05/05/15 15:10
EPA 6010
Copper
8.2
mg/kg
1.5
05/05/15 15:10
EPA 6010
Iron
26200
mg/kg
12.2
05/05/15 15:10
EPA 6010
Magnesium
905
mg/kg
152
05/05/15 15:10
EPA 6010
Manganese
78.0
mg/kg
1.5
05/05/15 15:10
EPA 6010
Nickel
1.3J
mg/kg
1.5
05/05/15 15:10
EPA 6010
Strontium
17.5
mg/kg
3.0
05/05/15 15:10
EPA 6010
Zinc
11.6
mg/kg
6.1
05/05/15 15:10
EPA 6020
Cobalt
3.7J
mg/kg
6.1
05/05/15 10:03
EPA 6020
Lead
7.4
mg/kg
6.1
05/05/15 10:03
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 9 of 79

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 KP�c&fie. Suite 100
Huntersville, NC 28078
[phone]
Project: J15040620
Pace Project No.: 92247080
Lab Sample ID Client Sample ID
Method Parameters
SUMMARY OF DETECTION
Result Units Report Limit Analyzed
92247080004
2015012035
EPA 6020
Vanadium
89.6
mg/kg
6.1
05/05/15 10:03
EPA 7471
Mercury
0.037
mg/kg
0.0098
05/04/15 15:53
ASTM D2974-87
Percent Moisture
19.8
%
0.10
05/05/15 10:25
EPA 9045
pH at 25 Degrees C
5.6
Std. Units
0.10
04/29/15 23:15
EPA 300.0
Sulfate
6.0
mg/L
2.5
05/07/15 12:34
EPA 353.2
Nitrogen, Nitrate
0.31
mg/L
0.25
05/13/15 13:31
EPA 9060
Total Organic Carbon
1270
mg/kg
742
05/18/15 17:09
EPA 9060
Total Organic Carbon
1730
mg/kg
742
05/18/15 17:14
EPA 9060
Total Organic Carbon
1210
mg/kg
744
05/18/15 17:20
EPA 9060
Total Organic Carbon
1690
mg/kg
750
05/18/15 17:26
EPA 9060
Mean Total Organic Carbon
1480
mg/kg
744
05/18/15 17:09
EPA 9060
RSD%
18.7
%
05/18/15 17:09
92247080005
2015012036
EPA 6010
Aluminum
5400
mg/kg
30.1
05/05/15 15:26
EPA 6010
Barium
98.4
mg/kg
3.0
05/05/15 15:26
EPA 6010
Beryllium
0.70
mg/kg
0.30
05/05/15 15:26
EPA 6010
Calcium
1470
mg/kg
150
05/05/15 15:26
EPA 6010
Chromium
18.2
mg/kg
1.5
05/05/15 15:26
EPA 6010
Copper
12.5
mg/kg
1.5
05/05/15 15:26
EPA 6010
Iron
16100
mg/kg
12.0
05/05/15 15:26
EPA 6010
Magnesium
2440
mg/kg
150
05/05/15 15:26
EPA 6010
Manganese
479
mg/kg
1.5
05/05/15 15:26
EPA 6010
Nickel
7.3
mg/kg
1.5
05/05/15 15:26
EPA 6010
Potassium
187J
mg/kg
301
05/05/15 15:26
EPA 6010
Strontium
20.3
mg/kg
3.0
05/05/15 15:26
EPA 6010
Zinc
22.9
mg/kg
6.0
05/05/15 15:26
EPA 6020
Cobalt
13.6
mg/kg
6.0
05/05/15 10:05
EPA 6020
Lead
5.91
mg/kg
6.0
05/05/15 10:05
EPA 6020
Vanadium
50.9
mg/kg
6.0
05/05/15 10:05
ASTM D2974-87
Percent Moisture
18.1
%
0.10
05/05/15 10:25
EPA 9045
pH at 25 Degrees C
7.5
Std. Units
0.10
04/29/15 23:15
EPA 300.0
Sulfate
6.3
mg/L
2.4
05/07/15 12:48
SM 4500-CI-E
Chloride
16.6
mg/L
6.1
05/09/15 03:39
EPA 9060
Total Organic Carbon
515J
mg/kg
728
05/18/15 17:33
EPA 9060
Total Organic Carbon
502J
mg/kg
727
05/18/15 17:38
EPA 9060
Total Organic Carbon
511 J
mg/kg
736
05/18/15 17:44
EPA 9060
Total Organic Carbon
499J
mg/kg
734
05/18/15 17:50
EPA 9060
Mean Total Organic Carbon
507J
mg/kg
731
05/18/15 17:33
EPA 9060
RSD%
1.5
%
05/18/15 17:33
92247080006
2015012037
EPA 6010
Aluminum
4760
mg/kg
32.4
05/05/15 15:30
EPA 6010
Barium
49.1
mg/kg
3.2
05/05/15 15:30
EPA 6010
Beryllium
0.31 J
mg/kg
0.32
05/05/15 15:30
EPA 6010
Calcium
881
mg/kg
162
05/05/15 15:30
EPA 6010
Chromium
4.7
mg/kg
1.6
05/05/15 15:30
EPA 6010
Copper
4.7
mg/kg
1.6
05/05/15 15:30
REPORT OF LABORATORY ANALYSIS
H1
B
H1
H1
B
Qualifiers
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 10 of 79

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 KP�c&fie. Suite 100
Huntersville, NC 28078
[phone]
Project: J15040620
Pace Project No.: 92247080
Lab Sample ID Client Sample ID
Method Parameters
SUMMARY OF DETECTION
Result Units Report Limit Analyzed
92247080006
2015012037
EPA 6010
Iron
9300
mg/kg
13.0
05/05/15 15:30
EPA 6010
Magnesium
1720
mg/kg
162
05/05/15 15:30
EPA 6010
Manganese
439
mg/kg
1.6
05/05/15 15:30
EPA 6010
Nickel
4.0
mg/kg
1.6
05/05/15 15:30
EPA 6010
Potassium
330
mg/kg
324
05/05/15 15:30
EPA 6010
Strontium
11.2
mg/kg
3.2
05/05/15 15:30
EPA 6010
Zinc
17.9
mg/kg
6.5
05/05/15 15:30
EPA 6020
Cobalt
8.9
mg/kg
6.5
05/05/15 10:07
EPA 6020
Lead
3.6J
mg/kg
6.5
05/05/15 10:07
EPA 6020
Vanadium
21.0
mg/kg
6.5
05/05/15 10:07
ASTM D2974-87
Percent Moisture
22.0
%
0.10
05/05/15 10:25
EPA 9045
pH at 25 Degrees C
6.4
Std. Units
0.10
04/29/15 23:15
EPA 9060
Total Organic Carbon
521J
mg/kg
771
05/18/15 17:57
EPA 9060
Total Organic Carbon
528J
mg/kg
772
05/18/15 18:03
EPA 9060
Total Organic Carbon
510J
mg/kg
774
05/18/15 18:08
EPA 9060
Total Organic Carbon
496J
mg/kg
764
05/18/15 18:14
EPA 9060
Mean Total Organic Carbon
514J
mg/kg
770
05/18/15 17:57
EPA 9060
RSD%
2.7
%
05/18/15 17:57
92247080007
2015012039
EPA 6010
Aluminum
6360
mg/kg
32.2
05/05/15 15:34
EPA 6010
Barium
65.3
mg/kg
3.2
05/05/15 15:34
EPA 6010
Beryllium
0.52
mg/kg
0.32
05/05/15 15:34
EPA 6010
Calcium
1380
mg/kg
161
05/05/15 15:34
EPA 6010
Chromium
7.5
mg/kg
1.6
05/05/15 15:34
EPA 6010
Copper
8.0
mg/kg
1.6
05/05/15 15:34
EPA 6010
Iron
14900
mg/kg
12.9
05/05/15 15:34
EPA 6010
Magnesium
2170
mg/kg
161
05/05/15 15:34
EPA 6010
Manganese
695
mg/kg
1.6
05/05/15 15:34
EPA 6010
Nickel
6.2
mg/kg
1.6
05/05/15 15:34
EPA 6010
Potassium
355
mg/kg
322
05/05/15 15:34
EPA 6010
Strontium
17.6
mg/kg
3.2
05/05/15 15:34
EPA 6010
Zinc
24.5
mg/kg
6.4
05/05/15 15:34
EPA 6020
Cobalt
11.7
mg/kg
6.4
05/05/15 10:10
EPA 6020
Lead
6.5
mg/kg
6.4
05/05/15 10:10
EPA 6020
Vanadium
38.2
mg/kg
6.4
05/05/15 10:10
ASTM D2974-87
Percent Moisture
20.9
%
0.10
05/05/15 10:25
EPA 9045
pH at 25 Degrees C
6.2
Std. Units
0.10
04/29/15 23:15
EPA 9060
Total Organic Carbon
493J
mg/kg
757
05/18/15 18:19
EPA 9060
Total Organic Carbon
511J
mg/kg
755
05/18/15 18:26
EPA 9060
Total Organic Carbon
499J
mg/kg
762
05/18/15 18:31
EPA 9060
Total Organic Carbon
467J
mg/kg
757
05/18/15 18:38
EPA 9060
Mean Total Organic Carbon
492J
mg/kg
757
05/18/15 18:19
EPA 9060
RSD%
3.8
%
05/18/15 18:19
92247080008
2015012034
EPA 6020A
Aluminum
10.7
ug/L
10.0
04/30/15 11:26
EPA 6020A
Arsenic
0.14J
ug/L
0.50
04/30/15 11:26
REPORT OF LABORATORY ANALYSIS
H1
I:f
Qualifiers
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 11 of 79

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 KPc&fie. Suite 100
Huntersville, NC 28078
[phone]
Project: J15040620
Pace Project No.: 92247080
Lab Sample ID Client Sample ID
Method Parameters
SUMMARY OF DETECTION
Result Units Report Limit Analyzed Qualifiers
92247080008
2015012034
EPA 6020A
Barium
0.73
ug/L
0.30
04/30/15 11:26
EPA 6020A
Calcium
167
ug/L
40.0
04/30/15 11:26
EPA 6020A
Chromium
0.20J
ug/L
0.50
04/30/15 11:26
EPA 6020A
Iron
31.8J
ug/L
50.0
04/30/15 11:26
EPA 6020A
Magnesium
24.3
ug/L
10.0
04/30/15 11:26
EPA 6020A
Manganese
2.4
ug/L
0.50
04/30/15 11:26
EPA 6020A
Potassium
28.5J
ug/L
50.0
04/30/15 11:26
EPA 6020A
Sodium
70.8
ug/L
50.0
04/30/15 11:26
EPA 6020A
Strontium
1.3
ug/L
0.50
04/30/15 11:26
92247080009
2015012038
EPA 6020A
Aluminum
27.9
ug/L
10.0
04/30/15 11:28
EPA 6020A
Arsenic
0.13J
ug/L
0.50
04/30/15 11:28
EPA 6020A
Barium
2.3
ug/L
0.30
04/30/15 11:28
EPA 6020A
Boron
35.1
ug/L
5.0
04/30/15 11:28
EPA 6020A
Calcium
211
ug/L
40.0
04/30/15 11:28
EPA 6020A
Chromium
8.8
ug/L
0.50
04/30/15 11:28
EPA 6020A
Cobalt
2.0
ug/L
0.50
04/30/15 11:28
EPA 6020A
Copper
17.2
ug/L
1.0
04/30/15 11:28
EPA 6020A
Iron
1100
ug/L
50.0
04/30/15 11:28
EPA 6020A
Lead
14.7
ug/L
0.10
04/30/15 11:28
EPA 6020A
Magnesium
19.4
ug/L
10.0
04/30/15 11:28
EPA 6020A
Manganese
36.6
ug/L
0.50
04/30/15 11:28
EPA 6020A
Molybdenum
1.0
ug/L
0.50
04/30/15 11:28
EPA 6020A
Nickel
1.4
ug/L
0.50
04/30/15 11:28
EPA 6020A
Potassium
38AJ
ug/L
50.0
04/30/15 11:28
EPA 6020A
Sodium
49.3J
ug/L
50.0
04/30/15 11:28
EPA 6020A
Strontium
0.72
ug/L
0.50
04/30/15 11:28
EPA 6020A
Zinc
33.8
ug/L
5.0
04/30/15 11:28
92247080010
2015012032 SPLP
EPA 6020A
Aluminum
116
ug/L
10.0
05/14/15 18:41
EPA 6020A
Barium
278
ug/L
0.30
05/14/15 18:41
EPA 6020A
Beryllium
0.13J
ug/L
0.20
05/14/15 18:41
EPA 6020A
Boron
57.0
ug/L
5.0
05/15/15 09:37
EPA 6020A
Calcium
1560
ug/L
40.0
05/14/15 18:41
EPA 6020A
Chromium
0.33J
ug/L
0.50
05/14/15 18:41
EPA 6020A
Cobalt
3.2
ug/L
0.50
05/14/15 18:41
EPA 6020A
Copper
1.7
ug/L
1.0
05/14/15 18:41
EPA 6020A
Iron
16.5J
ug/L
50.0
05/14/15 18:41
EPA 6020A
Lead
0.26
ug/L
0.10
05/14/15 18:41
EPA 6020A
Magnesium
234
ug/L
10.0
05/14/15 18:41
EPA 6020A
Manganese
255
ug/L
0.50
05/14/15 18:41
EPA 6020A
Nickel
1.8
ug/L
0.50
05/14/15 18:41
EPA 6020A
Potassium
602
ug/L
50.0
05/14/15 18:41
EPA 6020A
Sodium
424
ug/L
50.0
05/14/15 18:41
EPA 6020A
Strontium
43.2
ug/L
0.50
05/14/15 18:41
EPA 6020A
Zinc
77.8
ug/L
5.0
05/14/15 18:41
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 12 of 79

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 KP�c&fie. Suite 100
Huntersville, NC 28078
[phone]
Project: J15040620
Pace Project No.: 92247080
Lab Sample ID Client Sample ID
Method Parameters
SUMMARY OF DETECTION
Result Units Report Limit Analyzed
92247080011
2015012033 SPLP
EPA 6020A
Aluminum
49.2
ug/L
10.0
05/14/15 18:44
EPA 6020A
Barium
204
ug/L
0.30
05/14/15 18:44
EPA 6020A
Beryllium
0.22
ug/L
0.20
05/14/15 18:44
EPA 6020A
Boron
108
ug/L
25.0
05/15/15 09:43
EPA 6020A
Cadmium
0.056J
ug/L
0.080
05/14/15 18:44
EPA 6020A
Calcium
2020
ug/L
40.0
05/14/15 18:44
EPA 6020A
Chromium
0.39J
ug/L
0.50
05/14/15 18:44
EPA 6020A
Cobalt
10.9
ug/L
0.50
05/14/15 18:44
EPA 6020A
Copper
3.0
ug/L
1.0
05/14/15 18:44
EPA 6020A
Iron
15.2J
ug/L
50.0
05/14/15 18:44
EPA 6020A
Lead
0.078J
ug/L
0.10
05/14/15 18:44
EPA 6020A
Magnesium
806
ug/L
10.0
05/14/15 18:44
EPA 6020A
Manganese
554
ug/L
2.5
05/15/15 09:43
EPA 6020A
Nickel
2.5
ug/L
0.50
05/14/15 18:44
EPA 6020A
Potassium
497
ug/L
50.0
05/14/15 18:44
EPA 6020A
Sodium
1970
ug/L
50.0
05/14/15 18:44
EPA 6020A
Strontium
51.7
ug/L
0.50
05/14/15 18:44
EPA 6020A
Zinc
127
ug/L
5.0
05/14/15 18:44
92247080012
2015012035 SPLP
EPA 6020A
Aluminum
17400
ug/L
10.0
05/14/15 18:46
EPA 6020A
Arsenic
0.82
ug/L
0.50
05/14/15 18:46
EPA 6020A
Barium
166
ug/L
0.30
05/14/15 18:46
EPA 6020A
Beryllium
0.20
ug/L
0.20
05/14/15 18:46
EPA 6020A
Boron
43.4
ug/L
5.0
05/15/15 09:40
EPA 6020A
Calcium
1370
ug/L
40.0
05/14/15 18:46
EPA 6020A
Chromium
15.8
ug/L
0.50
05/14/15 18:46
EPA 6020A
Cobalt
2.1
ug/L
0.50
05/14/15 18:46
EPA 6020A
Copper
8.7
ug/L
1.0
05/14/15 18:46
EPA 6020A
Iron
15400
ug/L
50.0
05/14/15 18:46
EPA 6020A
Lead
3.3
ug/L
0.10
05/14/15 18:46
EPA 6020A
Magnesium
1180
ug/L
10.0
05/14/15 18:46
EPA 6020A
Manganese
31.5
ug/L
0.50
05/14/15 18:46
EPA 6020A
Nickel
4.9
ug/L
0.50
05/14/15 18:46
EPA 6020A
Potassium
290
ug/L
50.0
05/14/15 18:46
EPA 6020A
Selenium
0.25J
ug/L
0.50
05/14/15 18:46
EPA 6020A
Sodium
2400
ug/L
50.0
05/15/15 09:40
EPA 6020A
Strontium
19.6
ug/L
0.50
05/14/15 18:46
EPA 6020A
Thallium
0.0911
ug/L
0.10
05/14/15 18:46
EPA 6020A
Vanadium
40.1
ug/L
1.0
05/14/15 18:46
EPA 6020A
Zinc
85.2
ug/L
5.0
05/14/15 18:46
92247080013
2015012036 SPLP
EPA 6020A
Aluminum
108000
ug/L
50.0
05/15/15 12:46
EPA 6020A
Arsenic
7.6
ug/L
0.50
05/14/15 18:49
EPA 6020A
Barium
854
ug/L
1.5
05/15/15 12:46
EPA 6020A
Beryllium
7.4
ug/L
1.0
05/15/15 12:46
EPA 6020A
Boron
52.4
ug/L
25.0
05/15/15 12:46
REPORT OF LABORATORY ANALYSIS
Qualifiers
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 13 of 79

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 K��c&fie. Suite 100
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[phone]
SUMMARY OF DETECTION
Project: J15040620
Pace Project No.: 92247080
Lab Sample ID
Client Sample ID
Method
Parameters
Result
92247080013
2015012036 SPLP
EPA 6020A
Cadmium
0.080
EPA 6020A
Calcium
12800
EPA 6020A
Chromium
162
EPA 6020A
Cobalt
52.0
EPA 6020A
Copper
117
EPA 6020A
Iron
161000
EPA 6020A
Lead
37.0
EPA 6020A
Magnesium
13900
EPA 6020A
Manganese
1980
EPA 6020A
Molybdenum
0.24J
EPA 6020A
Nickel
61.6
EPA 6020A
Potassium
1500
EPA 6020A
Selenium
1.8
EPA 6020A
Sodium
5310
EPA 6020A
Strontium
193
EPA 6020A
Thallium
0.34
EPA 6020A
Vanadium
411
EPA 6020A
Zinc
255
EPA 7470A
Mercury
0.0901
Units Report Limit Analyzed Qualifiers
ug/L
0.080
05/14/1518:49
ug/L
200
05/15/1512:46
ug/L
2.5
05/15/1512:46
ug/L
0.50
05/14/1518:49
ug/L
1.0
05/14/1518:49
ug/L
2500
05/15/1512:48
ug/L
0.10
05/14/1518:49
ug/L
50.0
05/15/1512:46
ug/L
2.5
05/15/1512:46
ug/L
0.50
05/14/1518:49
ug/L
0.50
05/14/1518:49
ug/L
250
05/15/1512:46
ug/L
0.50
05/14/1518:49
ug/L
250
05/15/1512:46
ug/L
0.50
05/14/1518:49
ug/L
0.10
05/14/1518:49
ug/L
5.0
05/15/1512:46
ug/L
5.0
05/14/1518:49
ug/L
0.20
05/14/15 21:56
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 14 of 79

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 K�c&)e. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15040620
Pace Project No.: 92247080
Method: EPA 6010
Description: 6010 MET ICP
Client: Duke Energy
Date: May 20, 2015
General Information:
7 samples were analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 3050 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: MPRP/23928
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92247054001
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1202030)
• Aluminum
• Iron
• MSD (Lab ID: 1202031)
• Aluminum
• Iron
R1: RPD value was outside control limits.
• MSD (Lab ID: 1202031)
• Aluminum
Additional Comments:
Batch Comments:
Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
• QC Batch: ICP / 14625
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 15 of 79

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 KPgc&)e. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15040620
Pace Project No.: 92247080
Method: EPA 6020
Description: 6020 MET ICPMS
Client: Duke Energy
Date: May 20, 2015
General Information:
7 samples were analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 3050 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: MPRP/23929
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92247054001
M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
• MS (Lab ID: 1202034)
• Lead
• Selenium
• Vanadium
• MSD (Lab ID: 1202035)
• Cadmium
• Lead
• Selenium
• Vanadium
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 16 of 79

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 K��c&fie. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15040620
Pace Project No.: 92247080
Method: EPA 6020
Description: 6020 MET ICPMS
Client: Duke Energy
Date: May 20, 2015
Analyte Comments:
QC Batch: MPRP/23929
N2: The lab does not hold TNI accreditation for this parameter.
•2015012031 (Lab ID:92247080001)
• Antimony
•2015012032 (Lab ID:92247080002)
• Antimony
•2015012033 (Lab ID:92247080003)
• Antimony
•2015012035 (Lab ID:92247080004)
• Antimony
•2015012036 (Lab ID:92247080005)
• Antimony
•2015012037 (Lab ID:92247080006)
• Antimony
•2015012039 (Lab ID:92247080007)
• Antimony
• BLANK (Lab ID: 1202032)
• Antimony
• LCS (Lab ID: 1202033)
• Antimony
• MS (Lab ID: 1202034)
• Antimony
• MSD (Lab ID: 1202035)
• Antimony
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 17 of 79

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 K��c&)e. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15040620
Pace Project No.: 92247080
Method: EPA 6020A
Description: 6020A MET ICPMS
Client: Duke Energy
Date: May 20, 2015
General Information:
6 samples were analyzed for EPA 6020A. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 3020 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: MPRP/53983
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92247052008
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1950243)
• Aluminum
• MSD (Lab ID: 1950244)
• Aluminum
R1: RPD value was outside control limits.
• MSD (Lab ID: 1950244)
• Aluminum
QC Batch: MPRP/54376
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 10305831001
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1965129)
• Aluminum
• Calcium
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 18 of 79

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 �nlc&yq"�e. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15040620
Pace Project No.: 92247080
Method: EPA 6020A
Description: 6020A MET ICPMS
Client: Duke Energy
Date: May 20, 2015
QC Batch: MPRP/54376
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 10305831001
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• Magnesium
• Potassium
• MSD (Lab ID: 1965130)
• Aluminum
• Calcium
• Magnesium
• Potassium
M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
• MS (Lab ID: 1965129)
• Sodium
• MSD (Lab ID: 1965130)
• Sodium
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 19 of 79

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 K��c&)e. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15040620
Pace Project No.: 92247080
Method: EPA 7470A
Description: 7470A Mercury
Client: Duke Energy
Date: May 20, 2015
General Information:
6 samples were analyzed for EPA 7470A. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 7470A with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 20 of 79

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 K�c&)e. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15040620
Pace Project No.: 92247080
Method: EPA 7471
Description: 7471 Mercury
Client: Duke Energy
Date: May 20, 2015
General Information:
7 samples were analyzed for EPA 7471. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 7471 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 21 of 79

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 K�c&fie. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15040620
Pace Project No.: 92247080
Method: EPA 9045
Description: 9045 pH Soil
Client: Duke Energy
Date: May 20, 2015
General Information:
7 samples were analyzed for EPA 9045. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
1-11: Analysis conducted outside the EPA method holding time.
•2015012035 (Lab ID:92247080004)
•2015012036 (Lab ID:92247080005)
•2015012037 (Lab ID:92247080006)
•2015012039 (Lab ID:92247080007)
1-13: Sample was received or analysis requested beyond the recognized method holding time.
•2015012031 (Lab ID:92247080001)
•2015012032 (Lab ID:92247080002)
•2015012033 (Lab ID:92247080003)
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 22 of 79

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 K��c&fie. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15040620
Pace Project No.: 92247080
Method: EPA 300.0
Description: 300.0 IC Anions, SPLP
Client: Duke Energy
Date: May 20, 2015
General Information:
4 samples were analyzed for EPA 300.0. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
QC Batch: WETA/22837
B: Analyte was detected in the associated method blank.
• BLANK for HBN 262746 [WETA/228 (Lab ID: 1452663)
• Sulfate
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 23 of 79

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 K��c&)e. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15040620
Pace Project No.: 92247080
Method: EPA 353.2
Description: 353.2 Nitrogen, NO2/NO3, SPLP
Client: Duke Energy
Date: May 20, 2015
General Information:
4 samples were analyzed for EPA 353.2. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
1-11: Analysis conducted outside the EPA method holding time.
•2015012032 (Lab ID:92247080002)
•2015012033 (Lab ID:92247080003)
•2015012035 (Lab ID:92247080004)
•2015012036 (Lab ID:92247080005)
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 24 of 79

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 K�c&fie. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15040620
Pace Project No.: 92247080
Method: SM 4500-CI-E
Description: 4500 Chloride, SPLP
Client: Duke Energy
Date: May 20, 2015
General Information:
4 samples were analyzed for SM 4500-CI-E. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 25 of 79

aceAnaiXical
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Pace Analytical Services, Inc.
9800 K�gc&fie. Suite 100
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[phone]
PROJECT NARRATIVE
Project: J15040620
Pace Project No.: 92247080
Method: EPA 9056
Description: 9056 IC Anions
Client: Duke Energy
Date: May 20, 2015
General Information:
7 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
Analyte Comments:
QC Batch: WETA/45962
DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
•2015012031 (Lab ID:92247080001)
• Chloride
• Sulfate
•2015012035 (Lab ID:92247080004)
• Chloride
• Sulfate
QC Batch: WETA/45964
DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
•2015012036 (Lab ID:92247080005)
• Chloride
• Sulfate
•2015012037 (Lab ID:92247080006)
• Chloride
• Sulfate
•2015012039 (Lab ID:92247080007)
• Chloride
• Sulfate
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 26 of 79

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 K��c&fie. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15040620
Pace Project No.: 92247080
Method: EPA 9056
Description: 9056 IC Anions
Client: Duke Energy
Date: May 20, 2015
Analyte Comments:
QC Batch: WETA/46023
DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
•2015012032 (Lab ID:92247080002)
• Chloride
• Sulfate
•2015012033 (Lab ID:92247080003)
• Chloride
• Sulfate
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 27 of 79

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15040620
Pace Project No.: 92247080
Method: EPA 9056
Description: 9056 IC Anions 48hr
Client: Duke Energy
Date: May 20, 2015
General Information:
7 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
1­13: Sample was received or analysis requested beyond the recognized method holding time.
•2015012031 (Lab ID:92247080001)
•2015012032 (Lab ID:92247080002)
•2015012033 (Lab ID:92247080003)
•2015012035 (Lab ID:92247080004)
•2015012036 (Lab ID:92247080005)
•2015012037 (Lab ID:92247080006)
•2015012039 (Lab ID:92247080007)
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
Analyte Comments:
QC Batch: WETA/45963
DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
•2015012031 (Lab ID:92247080001)
• Nitrate as N
•2015012032 (Lab ID:92247080002)
• Nitrate as N
•2015012033 (Lab ID:92247080003)
• Nitrate as N
•2015012035 (Lab ID:92247080004)
• Nitrate as N
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 28 of 79

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 1in�c&fie. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15040620
Pace Project No.: 92247080
Method: EPA 9056
Description: 9056 IC Anions 48hr
Client: Duke Energy
Date: May 20, 2015
Analyte Comments:
QC Batch: WETA/45965
DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
•2015012036 (Lab ID:92247080005)
• Nitrate as N
•2015012037 (Lab ID:92247080006)
• Nitrate as N
•2015012039 (Lab ID:92247080007)
• Nitrate as N
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 29 of 79

aceAnaiXical
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Pace Analytical Services, Inc.
9800 Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15040620
Pace Project No.: 92247080
Method: EPA 9060
Description: Total Organic Carbon Quad
Client: Duke Energy
Date: May 20, 2015
General Information:
7 samples were analyzed for EPA 9060. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 30 of 79

aceAnaiXical
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Pace Analytical Services, Inc.
9800 Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040620
Pace Project No.: 92247080
Sample: 2015012031 Lab ID: 92247080001 Collected: 04/21/15 13:15 Received: 04/24/15 12:54 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Aluminum
Barium
Beryllium
Boron
Calcium
Chromium
Copper
Iron
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Sodium
Strontium
Zinc
6020 MET ICPMS
Antimony
Arsenic
Cadmium
Cobalt
Lead
Selenium
Thallium
Vanadium
7471 Mercury
Mercury
Percent Moisture
Percent Moisture
9045 pH Soil
pH at 25 Degrees C
9056 IC Anions
Chloride
Sulfate
9056 IC Anions 48hr
Nitrate as N
Date: 05/20/2015 08:27 AM
Analytical Method: EPA 6010 Preparation Method: EPA 3050
1480
mg/kg
30.2
15.1
5
05/04/15 04:15
05/05/15 14:58
7429-90-5
66.1
mg/kg
3.0
1.5
5
05/04/15 04:15
05/05/15 14:58
7440-39-3
ND
mg/kg
0.30
0.15
5
05/04/15 04:15
05/05/15 14:58
7440-41-7
ND
mg/kg
15.1
7.5
5
05/04/15 04:15
05/05/15 14:58
7440-42-8
93.3J
mg/kg
151
75.5
5
05/04/15 04:15
05/05/15 14:58
7440-70-2
3.7
mg/kg
1.5
0.75
5
05/04/15 04:15
05/05/15 14:58
7440-47-3
2.2
mg/kg
1.5
0.75
5
05/04/15 04:15
05/05/15 14:58
7440-50-8
8420
mg/kg
12.1
6.0
5
05/04/15 04:15
05/05/15 14:58
7439-89-6
178
mg/kg
151
75.5
5
05/04/15 04:15
05/05/15 14:58
7439-95-4
25.3
mg/kg
1.5
0.75
5
05/04/15 04:15
05/05/15 14:58
7439-96-5
ND
mg/kg
3.0
1.5
5
05/04/15 04:15
05/05/15 14:58
7439-98-7
ND
mg/kg
1.5
0.75
5
05/04/15 04:15
05/05/15 14:58
7440-02-0
ND
mg/kg
302
151
5
05/04/15 04:15
05/05/15 14:58
7440-09-7
ND
mg/kg
302
151
5
05/04/15 04:15
05/05/15 14:58
7440-23-5
4.0
mg/kg
3.0
1.5
5
05/04/15 04:15
05/05/15 14:58
7440-24-6
3.1J
mg/kg
6.0
3.0
5
05/04/15 04:15
05/05/15 14:58
7440-66-6
Analytical
Method: EPA 6020 Preparation
Method: EPA 3050
ND
mg/kg
6.0
3.0
100
05/04/15 04:15
05/05/15 09:48
7440-36-0
60.3
mg/kg
6.0
3.0
100
05/04/15 04:15
05/05/15 09:48
7440-38-2
ND
mg/kg
0.72
0.36
100
05/04/15 04:15
05/05/15 09:48
7440-43-9
ND
mg/kg
6.0
3.0
100
05/04/15 04:15
05/05/15 09:48
7440-48-4
ND
mg/kg
6.0
3.0
100
05/04/15 04:15
05/05/15 09:48
7439-92-1
3.2J
mg/kg
6.0
3.0
100
05/04/15 04:15
05/05/15 09:48
7782-49-2
ND
mg/kg
6.0
3.0
100
05/04/15 04:15
05/05/15 09:48
7440-28-0
14.9
mg/kg
6.0
3.0
100
05/04/15 04:15
05/05/15 09:48
7440-62-2
Analytical Method: EPA 7471 Preparation Method: EPA 7471
0.013 mg/kg 0.0095 0.0047 1 05/04/15 05:06 05/04/15 15:47 7439-97-6
Analytical Method: ASTM D2974-87
13.9 % 0.10 0.10 1 05/05/1510:24
Analytical Method: EPA 9045
3.8 Std. Units 0.10 0.10 1
Analytical Method: EPA 9056
ND mg/kg 281 141 5
ND mg/kg 281 141 5
Analytical Method: EPA 9056
ND mg/kg 28.1 14.1 5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
[8DX-11f61KCAR
CU
N2
04/30/15 23:38 16887-00-6 D3
04/30/15 23:38 14808-79-8 D3
04/30/15 23:38 14797-55-8 D3,H3
Page 31 of 79

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Iic&fie. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040620
Pace Project No.: 92247080
Sample: 2015012031
Lab ID:
92247080001
Collected:
04/21/15 13:15
Received: 04/24/15 12:54 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample
size and any dilutions.
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared Analyzed
CAS No. Qual
Total Organic Carbon Quad
Analytical
Method: EPA 9060
Total Organic Carbon
921
mg/kg
696
348
1
05/14/15 11:33
7440-44-0
Total Organic Carbon
957
mg/kg
700
350
1
05/14/15 11:38
7440-44-0
Total Organic Carbon
870
mg/kg
698
349
1
05/14/15 11:44
7440-44-0
Total Organic Carbon
979
mg/kg
702
351
1
05/14/15 11:50
7440-44-0
Mean Total Organic Carbon
932
mg/kg
699
349
1
05/14/15 11:33
7440-44-0
Surrogates
RSD%
5.1
%
1
05/14/15 11:33
Date: 05/20/2015 08:27 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 32 of 79

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040620
Pace Project No.: 92247080
Sample: 2015012032 Lab ID: 92247080002 Collected: 04/21/15 13:30 Received: 04/24/15 12:54 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Aluminum
Barium
Beryllium
Boron
Calcium
Chromium
Copper
Iron
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Sodium
Strontium
Zinc
6020 MET ICPMS
Antimony
Arsenic
Cadmium
Cobalt
Lead
Selenium
Thallium
Vanadium
7471 Mercury
Mercury
Percent Moisture
Percent Moisture
9045 pH Soil
pH at 25 Degrees C
300.0 IC Anions, SPLP
Sulfate
353.2 Nitrogen, NO2/NO3, SPLP
Nitrogen, Nitrate
4500 Chloride, SPLP
Chloride
Date: 05/20/2015 08:27 AM
Analytical Method: EPA 6010 Preparation Method: EPA 3050
2490
mg/kg
28.9
14.4
5
05/04/15 04:15
05/05/15 15:02
7429-90-5
50.0
mg/kg
2.9
1.4
5
05/04/15 04:15
05/05/15 15:02
7440-39-3
ND
mg/kg
0.29
0.14
5
05/04/15 04:15
05/05/15 15:02
7440-41-7
ND
mg/kg
14.4
7.2
5
05/04/15 04:15
05/05/15 15:02
7440-42-8
92.OJ
mg/kg
144
72.2
5
05/04/15 04:15
05/05/15 15:02
7440-70-2
5.8
mg/kg
1.4
0.72
5
05/04/15 04:15
05/05/15 15:02
7440-47-3
3.0
mg/kg
1.4
0.72
5
05/04/15 04:15
05/05/15 15:02
7440-50-8
14500
mg/kg
11.6
5.8
5
05/04/15 04:15
05/05/15 15:02
7439-89-6
447
mg/kg
144
72.2
5
05/04/15 04:15
05/05/15 15:02
7439-95-4
100
mg/kg
1.4
0.72
5
05/04/15 04:15
05/05/15 15:02
7439-96-5
ND
mg/kg
2.9
1.4
5
05/04/15 04:15
05/05/15 15:02
7439-98-7
0.77J
mg/kg
1.4
0.72
5
05/04/15 04:15
05/05/15 15:02
7440-02-0
ND
mg/kg
289
144
5
05/04/15 04:15
05/05/15 15:02
7440-09-7
ND
mg/kg
289
144
5
05/04/15 04:15
05/05/15 15:02
7440-23-5
4.0
mg/kg
2.9
1.4
5
05/04/15 04:15
05/05/15 15:02
7440-24-6
5.8
mg/kg
5.8
2.9
5
05/04/15 04:15
05/05/15 15:02
7440-66-6
Analytical
Method: EPA 6020 Preparation
Method: EPA 3050
ND
mg/kg
5.8
2.9
100
05/04/15 04:15
05/05/15 09:50
7440-36-0
ND
mg/kg
5.8
2.9
100
05/04/15 04:15
05/05/15 09:50
7440-38-2
ND
mg/kg
0.69
0.35
100
05/04/15 04:15
05/05/15 09:50
7440-43-9
ND
mg/kg
5.8
2.9
100
05/04/15 04:15
05/05/15 09:50
7440-48-4
3.7J
mg/kg
5.8
2.9
100
05/04/15 04:15
05/05/15 09:50
7439-92-1
ND
mg/kg
5.8
2.9
100
05/04/15 04:15
05/05/15 09:50
7782-49-2
ND
mg/kg
5.8
2.9
100
05/04/15 04:15
05/05/15 09:50
7440-28-0
22.0
mg/kg
5.8
2.9
100
05/04/15 04:15
05/05/15 09:50
7440-62-2
Analytical Method: EPA 7471 Preparation Method: EPA 7471
0.0066J mg/kg 0.0094 0.0047 1 05/04/15 05:06 05/04/15 15:49 7439-97-6
Analytical Method: ASTM D2974-87
11.3 % 0.10 0.10 1 05/05/1510:24
Analytical Method: EPA 9045
3.6 Std. Units 0.10 0.10 1 04/29/15 23:15
CU
N2
Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 04/30/15 04:20
11.4 mg/L 2.3 1.1 1 05/07/1511:40 14808-79-8 B
Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 04/30/15 04:20
0.23 mg/L 0.23 0.23 1 05/13/1513:21 H1
Analytical Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 04/30/15 04:20
ND mg/L 5.6 2.8 1 05/09/15 03:36 16887-00-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 33 of 79

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040620
Pace Project No.: 92247080
Sample: 2015012032 Lab ID: 92247080002 Collected: 04/21/15 13:30 Received: 04/24/15 12:54 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
9056 IC Anions Analytical Method: EPA 9056
Chloride
ND mg/kg
283
142
5
05/03/1517:12
16887-00-6 D3
Sulfate
194J mg/kg
283
142
5
05/03/1517:12
14808-79-8 D3
9056 IC Anions 48hr
Analytical Method: EPA 9056
Nitrate as N
ND mg/kg
28.3
14.2
5
05/01/15 00:00
14797-55-8 D3,1-13
Total Organic Carbon Quad
Analytical Method: EPA 9060
Total Organic Carbon
560J mg/kg
674
337
1
05/14/15 12:42
7440-44-0
Total Organic Carbon
523J mg/kg
676
338
1
05/14/15 12:47
7440-44-0
Total Organic Carbon
548J mg/kg
672
336
1
05/14/15 12:54
7440-44-0
Total Organic Carbon
531J mg/kg
678
339
1
05/14/15 13:00
7440-44-0
Mean Total Organic Carbon
540J mg/kg
675
338
1
05/14/15 12:42
7440-44-0
Surrogates
RSD%
3.1 %
1
05/14/15 12:42
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/20/2015 08:27 AM without the written consent of Pace Analytical Services, Inc..
Page 34 of 79

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Iic&fie. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040620
Pace Project No.: 92247080
Sample: 2015012033 Lab ID: 92247080003 Collected: 04/21/15 13:50 Received: 04/24/15 12:54 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Aluminum
Barium
Beryllium
Boron
Calcium
Chromium
Copper
Iron
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Sodium
Strontium
Zinc
6020 MET ICPMS
Antimony
Arsenic
Cadmium
Cobalt
Lead
Selenium
Thallium
Vanadium
7471 Mercury
Mercury
Percent Moisture
Percent Moisture
9045 pH Soil
pH at 25 Degrees C
300.0 IC Anions, SPLP
Sulfate
353.2 Nitrogen, NO2/NO3, SPLP
Nitrogen, Nitrate
4500 Chloride, SPLP
Chloride
Date: 05/20/2015 08:27 AM
Analytical Method: EPA 6010 Preparation Method: EPA 3050
7520
mg/kg
29.3
14.7
5
05/04/15 04:15
05/05/15 15:06
7429-90-5
52.2
mg/kg
2.9
1.5
5
05/04/15 04:15
05/05/15 15:06
7440-39-3
0.35
mg/kg
0.29
0.15
5
05/04/15 04:15
05/05/15 15:06
7440-41-7
ND
mg/kg
14.7
7.3
5
05/04/15 04:15
05/05/15 15:06
7440-42-8
263
mg/kg
147
73.4
5
05/04/15 04:15
05/05/15 15:06
7440-70-2
10.7
mg/kg
1.5
0.73
5
05/04/15 04:15
05/05/15 15:06
7440-47-3
9.4
mg/kg
1.5
0.73
5
05/04/15 04:15
05/05/15 15:06
7440-50-8
15700
mg/kg
11.7
5.9
5
05/04/15 04:15
05/05/15 15:06
7439-89-6
1670
mg/kg
147
73.4
5
05/04/15 04:15
05/05/15 15:06
7439-95-4
231
mg/kg
1.5
0.73
5
05/04/15 04:15
05/05/15 15:06
7439-96-5
ND
mg/kg
2.9
1.5
5
05/04/15 04:15
05/05/15 15:06
7439-98-7
4.0
mg/kg
1.5
0.73
5
05/04/15 04:15
05/05/15 15:06
7440-02-0
150J
mg/kg
293
147
5
05/04/15 04:15
05/05/15 15:06
7440-09-7
ND
mg/kg
293
147
5
05/04/15 04:15
05/05/15 15:06
7440-23-5
7.4
mg/kg
2.9
1.5
5
05/04/15 04:15
05/05/15 15:06
7440-24-6
20.6
mg/kg
5.9
2.9
5
05/04/15 04:15
05/05/15 15:06
7440-66-6
Analytical
Method: EPA 6020 Preparation
Method: EPA 3050
ND
mg/kg
5.9
2.9
100
05/04/15 04:15
05/05/15 10:00
7440-36-0
3.2J
mg/kg
5.9
2.9
100
05/04/15 04:15
05/05/15 10:00
7440-38-2
ND
mg/kg
0.70
0.35
100
05/04/15 04:15
05/05/15 10:00
7440-43-9
5.2J
mg/kg
5.9
2.9
100
05/04/15 04:15
05/05/15 10:00
7440-48-4
6.9
mg/kg
5.9
2.9
100
05/04/15 04:15
05/05/15 10:00
7439-92-1
ND
mg/kg
5.9
2.9
100
05/04/15 04:15
05/05/15 10:00
7782-49-2
ND
mg/kg
5.9
2.9
100
05/04/15 04:15
05/05/15 10:00
7440-28-0
41.3
mg/kg
5.9
2.9
100
05/04/15 04:15
05/05/15 10:00
7440-62-2
Analytical Method: EPA 7471 Preparation Method: EPA 7471
0.0086J mg/kg 0.0096 0.0048 1 05/04/15 05:06 05/04/15 15:51 7439-97-6
Analytical Method: ASTM D2974-87
13.0 % 0.10 0.10 1 05/05/1510:24
Analytical Method: EPA 9045
4.0 Std. Units 0.10 0.10 1 04/29/15 23:15
CU
N2
Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 04/30/15 04:20
14.3 mg/L 2.3 1.1 1 05/07/1512:21 14808-79-8 B
Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 04/30/15 04:20
0.26 mg/L 0.23 0.23 1 05/13/1513:30 H1
Analytical Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 04/30/15 04:20
ND mg/L 5.7 2.9 1 05/09/15 03:37 16887-00-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 35 of 79

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Iigc&fie. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040620
Pace Project No.: 92247080
Sample: 2015012033 Lab ID: 92247080003 Collected: 04/21/15 13:50 Received: 04/24/15 12:54 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
9056 IC Anions Analytical Method: EPA 9056
Chloride
ND mg/kg
280
140
5
05/03/1517:34
16887-00-6 D3
Sulfate
1991 mg/kg
280
140
5
05/03/1517:34
14808-79-8 D3
9056 IC Anions 48hr
Analytical Method: EPA 9056
Nitrate as N
ND mg/kg
28.0
14.0
5
05/01/15 00:21
14797-55-8 D3,1-13
Total Organic Carbon Quad
Analytical Method: EPA 9060
Total Organic Carbon
785 mg/kg
687
343
1
05/14/15 13:06
7440-44-0
Total Organic Carbon
792 mg/kg
689
344
1
05/14/15 13:13
7440-44-0
Total Organic Carbon
829 mg/kg
692
346
1
05/14/15 13:19
7440-44-0
Total Organic Carbon
802 mg/kg
689
344
1
05/14/15 13:25
7440-44-0
Mean Total Organic Carbon
802 mg/kg
689
345
1
05/14/15 13:06
7440-44-0
Surrogates
RSD%
2.4 %
1
05/14/15 13:06
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/20/2015 08:27 AM without the written consent of Pace Analytical Services, Inc..
Page 36 of 79

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040620
Pace Project No.: 92247080
Sample: 2015012035 Lab ID: 92247080004 Collected: 04/23/15 14:30 Received: 04/24/15 12:54 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Aluminum
Barium
Beryllium
Boron
Calcium
Chromium
Copper
Iron
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Sodium
Strontium
Zinc
6020 MET ICPMS
Antimony
Arsenic
Cadmium
Cobalt
Lead
Selenium
Thallium
Vanadium
7471 Mercury
Mercury
Percent Moisture
Percent Moisture
9045 pH Soil
pH at 25 Degrees C
300.0 IC Anions, SPLP
Sulfate
353.2 Nitrogen, NO2/NO3, SPLP
Nitrogen, Nitrate
4500 Chloride, SPLP
Chloride
Date: 05/20/2015 08:27 AM
Analytical Method: EPA 6010 Preparation Method: EPA 3050
11500
mg/kg
30.4
15.2
5
05/04/15 04:15
05/05/15 15:10
7429-90-5
62.8
mg/kg
3.0
1.5
5
05/04/15 04:15
05/05/15 15:10
7440-39-3
0.21J
mg/kg
0.30
0.15
5
05/04/15 04:15
05/05/15 15:10
7440-41-7
ND
mg/kg
15.2
7.6
5
05/04/15 04:15
05/05/15 15:10
7440-42-8
1230
mg/kg
152
76.0
5
05/04/15 04:15
05/05/15 15:10
7440-70-2
24.7
mg/kg
1.5
0.76
5
05/04/15 04:15
05/05/15 15:10
7440-47-3
8.2
mg/kg
1.5
0.76
5
05/04/15 04:15
05/05/15 15:10
7440-50-8
26200
mg/kg
12.2
6.1
5
05/04/15 04:15
05/05/15 15:10
7439-89-6
905
mg/kg
152
76.0
5
05/04/15 04:15
05/05/15 15:10
7439-95-4
78.0
mg/kg
1.5
0.76
5
05/04/15 04:15
05/05/15 15:10
7439-96-5
ND
mg/kg
3.0
1.5
5
05/04/15 04:15
05/05/15 15:10
7439-98-7
1.3J
mg/kg
1.5
0.76
5
05/04/15 04:15
05/05/15 15:10
7440-02-0
ND
mg/kg
304
152
5
05/04/15 04:15
05/05/15 15:10
7440-09-7
ND
mg/kg
304
152
5
05/04/15 04:15
05/05/15 15:10
7440-23-5
CU
17.5
mg/kg
3.0
1.5
5
05/04/15 04:15
05/05/15 15:10
7440-24-6
11.6
mg/kg
6.1
3.0
5
05/04/15 04:15
05/05/15 15:10
7440-66-6
Analytical
Method: EPA 6020
Preparation Method: EPA 3050
ND
mg/kg
6.1
3.0
100
05/04/15 04:15
05/05/15 10:03
7440-36-0
N2
ND
mg/kg
6.1
3.0
100
05/04/15 04:15
05/05/15 10:03
7440-38-2
ND
mg/kg
0.73
0.36
100
05/04/15 04:15
05/05/15 10:03
7440-43-9
3.7J
mg/kg
6.1
3.0
100
05/04/15 04:15
05/05/15 10:03
7440-48-4
7.4
mg/kg
6.1
3.0
100
05/04/15 04:15
05/05/15 10:03
7439-92-1
ND
mg/kg
6.1
3.0
100
05/04/15 04:15
05/05/15 10:03
7782-49-2
ND
mg/kg
6.1
3.0
100
05/04/15 04:15
05/05/15 10:03
7440-28-0
89.6
mg/kg
6.1
3.0
100
05/04/15 04:15
05/05/15 10:03
7440-62-2
Analytical
Method: EPA 7471
Preparation Method: EPA 7471
0.037
mg/kg 0.0098
0.0049
1
05/04/15 05:06
05/04/15 15:53
7439-97-6
Analytical
Method: ASTM D2974-87
19.8
%
0.10
0.10
1
05/05/1510:25
Analytical
Method: EPA 9045
5.6
Std. Units
0.10
0.10
1
04/29/15 23:15
H1
Analytical
Method: EPA 300.0 Leachate Method/Date:
EPA 1312; 04/30/15
04:20
6.0
mg/L
2.5
1.2
1
05/07/1512:34
14808-79-8
B
Analytical
Method: EPA 353.2 Leachate Method/Date:
EPA 1312; 04/30/15
04:20
0.31
mg/L
0.25
0.25
1
05/13/1513:31
H1
Analytical
Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 04/30/15 04:20
ND
mg/L
6.2
3.1
1
05/09/15 03:37
16887-00-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 37 of 79

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040620
Pace Project No.: 92247080
Sample: 2015012035 Lab ID: 92247080004 Collected: 04/23/15 14:30 Received: 04/24/15 12:54 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
9056 IC Anions Analytical Method: EPA 9056
Chloride
ND mg/kg
312
156
5
05/01/15 00:42
16887-00-6 D3
Sulfate
ND mg/kg
312
156
5
05/01/15 00:42
14808-79-8 D3
9056 IC Anions 48hr
Analytical Method: EPA 9056
Nitrate as N
ND mg/kg
31.2
15.6
5
05/01/15 00:42
14797-55-8 D3,1-13
Total Organic Carbon Quad
Analytical Method: EPA 9060
Total Organic Carbon
1270 mg/kg
742
371
1
05/18/15 17:09
7440-44-0
Total Organic Carbon
1730 mg/kg
742
371
1
05/18/15 17:14
7440-44-0
Total Organic Carbon
1210 mg/kg
744
372
1
05/18/15 17:20
7440-44-0
Total Organic Carbon
1690 mg/kg
750
375
1
05/18/15 17:26
7440-44-0
Mean Total Organic Carbon
1480 mg/kg
744
372
1
05/18/15 17:09
7440-44-0
Surrogates
RSD%
18.7 %
1
05/18/15 17:09
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/20/2015 08:27 AM without the written consent of Pace Analytical Services, Inc..
Page 38 of 79

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 1j ni c&fie. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040620
Pace Project No.: 92247080
Sample: 2015012036 Lab ID: 92247080005 Collected: 04/23/15 14:50 Received: 04/24/15 12:54 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Aluminum
Barium
Beryllium
Boron
Calcium
Chromium
Copper
Iron
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Sodium
Strontium
Zinc
6020 MET ICPMS
Antimony
Arsenic
Cadmium
Cobalt
Lead
Selenium
Thallium
Vanadium
7471 Mercury
Mercury
Percent Moisture
Percent Moisture
9045 pH Soil
pH at 25 Degrees C
300.0 IC Anions, SPLP
Sulfate
353.2 Nitrogen, NO2/NO3, SPLP
Nitrogen, Nitrate
4500 Chloride, SPLP
Chloride
Date: 05/20/2015 08:27 AM
Analytical Method: EPA 6010 Preparation Method: EPA 3050
5400
mg/kg
30.1
15.0
5
05/04/15 04:15
05/05/15 15:26
7429-90-5
98.4
mg/kg
3.0
1.5
5
05/04/15 04:15
05/05/15 15:26
7440-39-3
0.70
mg/kg
0.30
0.15
5
05/04/15 04:15
05/05/15 15:26
7440-41-7
ND
mg/kg
15.0
7.5
5
05/04/15 04:15
05/05/15 15:26
7440-42-8
1470
mg/kg
150
75.2
5
05/04/15 04:15
05/05/15 15:26
7440-70-2
18.2
mg/kg
1.5
0.75
5
05/04/15 04:15
05/05/15 15:26
7440-47-3
12.5
mg/kg
1.5
0.75
5
05/04/15 04:15
05/05/15 15:26
7440-50-8
16100
mg/kg
12.0
6.0
5
05/04/15 04:15
05/05/15 15:26
7439-89-6
2440
mg/kg
150
75.2
5
05/04/15 04:15
05/05/15 15:26
7439-95-4
479
mg/kg
1.5
0.75
5
05/04/15 04:15
05/05/15 15:26
7439-96-5
ND
mg/kg
3.0
1.5
5
05/04/15 04:15
05/05/15 15:26
7439-98-7
7.3
mg/kg
1.5
0.75
5
05/04/15 04:15
05/05/15 15:26
7440-02-0
187J
mg/kg
301
150
5
05/04/15 04:15
05/05/15 15:26
7440-09-7
ND
mg/kg
301
150
5
05/04/15 04:15
05/05/15 15:26
7440-23-5
CU
20.3
mg/kg
3.0
1.5
5
05/04/15 04:15
05/05/15 15:26
7440-24-6
22.9
mg/kg
6.0
3.0
5
05/04/15 04:15
05/05/15 15:26
7440-66-6
Analytical
Method: EPA 6020
Preparation Method: EPA 3050
ND
mg/kg
6.0
3.0
100
05/04/15 04:15
05/05/15 10:05
7440-36-0
N2
ND
mg/kg
6.0
3.0
100
05/04/15 04:15
05/05/15 10:05
7440-38-2
ND
mg/kg
0.72
0.36
100
05/04/15 04:15
05/05/15 10:05
7440-43-9
13.6
mg/kg
6.0
3.0
100
05/04/15 04:15
05/05/15 10:05
7440-48-4
5.9J
mg/kg
6.0
3.0
100
05/04/15 04:15
05/05/15 10:05
7439-92-1
ND
mg/kg
6.0
3.0
100
05/04/15 04:15
05/05/15 10:05
7782-49-2
ND
mg/kg
6.0
3.0
100
05/04/15 04:15
05/05/15 10:05
7440-28-0
50.9
mg/kg
6.0
3.0
100
05/04/15 04:15
05/05/15 10:05
7440-62-2
Analytical
Method: EPA 7471
Preparation Method: EPA 7471
ND
mg/kg 0.0096
0.0048
1
05/04/15 05:06
05/04/15 15:55
7439-97-6
Analytical
Method: ASTM D2974-87
18.1
%
0.10
0.10
1
05/05/1510:25
Analytical
Method: EPA 9045
7.5
Std. Units
0.10
0.10
1
04/29/15 23:15
H1
Analytical
Method: EPA 300.0 Leachate Method/Date:
EPA 1312; 04/30/15
04:20
6.3
mg/L
2.4
1.2
1
05/07/1512:48
14808-79-8
B
Analytical
Method: EPA 353.2 Leachate Method/Date:
EPA 1312; 04/30/15
04:20
ND
mg/L
0.24
0.24
1
05/13/1513:32
H1
Analytical
Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 04/30/15 04:20
16.6
mg/L
6.1
3.1
1
05/09/15 03:39
16887-00-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 39 of 79

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040620
Pace Project No.: 92247080
Sample: 2015012036 Lab ID: 92247080005 Collected: 04/23/15 14:50 Received: 04/24/15 12:54 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
9056 IC Anions Analytical Method: EPA 9056
Chloride
ND mg/kg
308
154
5
05/01/15 02:30
16887-00-6 D3,M1
Sulfate
ND mg/kg
308
154
5
05/01/15 02:30
14808-79-8 D3
9056 IC Anions 48hr
Analytical Method: EPA 9056
Nitrate as N
ND mg/kg
30.8
15.4
5
05/01/15 02:30
14797-55-8 D3,1-13
Total Organic Carbon Quad
Analytical Method: EPA 9060
Total Organic Carbon
515J mg/kg
728
364
1
05/18/15 17:33
7440-44-0
Total Organic Carbon
502J mg/kg
727
364
1
05/18/15 17:38
7440-44-0
Total Organic Carbon
511J mg/kg
736
368
1
05/18/15 17:44
7440-44-0
Total Organic Carbon
499J mg/kg
734
367
1
05/18/15 17:50
7440-44-0
Mean Total Organic Carbon
507J mg/kg
731
366
1
05/18/15 17:33
7440-44-0
Surrogates
RSD%
1.5 %
1
05/18/15 17:33
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/20/2015 08:27 AM without the written consent of Pace Analytical Services, Inc..
Page 40 of 79

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040620
Pace Project No.: 92247080
Sample: 2015012037 Lab ID: 92247080006 Collected: 04/23/15 15:10 Received: 04/24/15 12:54 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Aluminum
Barium
Beryllium
Boron
Calcium
Chromium
Copper
Iron
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Sodium
Strontium
Zinc
6020 MET ICPMS
Antimony
Arsenic
Cadmium
Cobalt
Lead
Selenium
Thallium
Vanadium
7471 Mercury
Mercury
Percent Moisture
Percent Moisture
9045 pH Soil
pH at 25 Degrees C
9056 IC Anions
Chloride
Sulfate
9056 IC Anions 48hr
Nitrate as N
Date: 05/20/2015 08:27 AM
Analytical Method: EPA 6010 Preparation Method: EPA 3050
4760
mg/kg
32.4
16.2
5
05/04/15 04:15
05/05/15 15:30
7429-90-5
49.1
mg/kg
3.2
1.6
5
05/04/15 04:15
05/05/15 15:30
7440-39-3
0.31J
mg/kg
0.32
0.16
5
05/04/15 04:15
05/05/15 15:30
7440-41-7
ND
mg/kg
16.2
8.1
5
05/04/15 04:15
05/05/15 15:30
7440-42-8
881
mg/kg
162
81.1
5
05/04/15 04:15
05/05/15 15:30
7440-70-2
4.7
mg/kg
1.6
0.81
5
05/04/15 04:15
05/05/15 15:30
7440-47-3
4.7
mg/kg
1.6
0.81
5
05/04/15 04:15
05/05/15 15:30
7440-50-8
9300
mg/kg
13.0
6.5
5
05/04/15 04:15
05/05/15 15:30
7439-89-6
1720
mg/kg
162
81.1
5
05/04/15 04:15
05/05/15 15:30
7439-95-4
439
mg/kg
1.6
0.81
5
05/04/15 04:15
05/05/15 15:30
7439-96-5
ND
mg/kg
3.2
1.6
5
05/04/15 04:15
05/05/15 15:30
7439-98-7
4.0
mg/kg
1.6
0.81
5
05/04/15 04:15
05/05/15 15:30
7440-02-0
330
mg/kg
324
162
5
05/04/15 04:15
05/05/15 15:30
7440-09-7
ND
mg/kg
324
162
5
05/04/15 04:15
05/05/15 15:30
7440-23-5
11.2
mg/kg
3.2
1.6
5
05/04/15 04:15
05/05/15 15:30
7440-24-6
17.9
mg/kg
6.5
3.2
5
05/04/15 04:15
05/05/15 15:30
7440-66-6
Analytical
Method: EPA 6020 Preparation
Method: EPA 3050
ND
mg/kg
6.5
3.2
100
05/04/15 04:15
05/05/15 10:07
7440-36-0
ND
mg/kg
6.5
3.2
100
05/04/15 04:15
05/05/15 10:07
7440-38-2
ND
mg/kg
0.78
0.39
100
05/04/15 04:15
05/05/15 10:07
7440-43-9
8.9
mg/kg
6.5
3.2
100
05/04/15 04:15
05/05/15 10:07
7440-48-4
3.6J
mg/kg
6.5
3.2
100
05/04/15 04:15
05/05/15 10:07
7439-92-1
ND
mg/kg
6.5
3.2
100
05/04/15 04:15
05/05/15 10:07
7782-49-2
ND
mg/kg
6.5
3.2
100
05/04/15 04:15
05/05/15 10:07
7440-28-0
21.0
mg/kg
6.5
3.2
100
05/04/15 04:15
05/05/15 10:07
7440-62-2
Analytical Method: EPA 7471 Preparation Method: EPA 7471
ND mg/kg 0.010 0.0052 1 05/04/15 05:06 05/04/15 15:58 7439-97-6
Analytical Method: ASTM D2974-87
22.0 % 0.10 0.10 1 05/05/1510:25
Analytical Method: EPA 9045
6.4 Std. Units
0.10
0.10 1
Analytical Method: EPA 9056
ND mg/kg
316
158 5
ND mg/kg
316
158 5
Analytical Method: EPA 9056
ND mg/kg
31.6
15.8 5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
[8DX-11f61KCAR
CU
N2
I:fl
05/01/15 03:34 16887-00-6 D3
05/01/15 03:34 14808-79-8 D3
05/01/15 03:34 14797-55-8 D3,H3
Page 41 of 79

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Ijc&fie. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040620
Pace Project No.: 92247080
Sample: 2015012037
Lab ID:
92247080006
Collected:
04/23/15 15:10
Received: 04/24/15 12:54 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample
size and any dilutions.
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared Analyzed
CAS No. Qual
Total Organic Carbon Quad
Analytical
Method: EPA 9060
Total Organic Carbon
521J
mg/kg
771
386
1
05/18/15 17:57
7440-44-0
Total Organic Carbon
528J
mg/kg
772
386
1
05/18/15 18:03
7440-44-0
Total Organic Carbon
5101
mg/kg
774
387
1
05/18/15 18:08
7440-44-0
Total Organic Carbon
496J
mg/kg
764
382
1
05/18/15 18:14
7440-44-0
Mean Total Organic Carbon
514J
mg/kg
770
385
1
05/18/15 17:57
7440-44-0
Surrogates
RSD%
2.7
%
1
05/18/15 17:57
Date: 05/20/2015 08:27 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 42 of 79

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040620
Pace Project No.: 92247080
Sample: 2015012039 Lab ID: 92247080007 Collected: 04/23/15 15:10 Received: 04/24/15 12:54 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Aluminum
Barium
Beryllium
Boron
Calcium
Chromium
Copper
Iron
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Sodium
Strontium
Zinc
6020 MET ICPMS
Antimony
Arsenic
Cadmium
Cobalt
Lead
Selenium
Thallium
Vanadium
7471 Mercury
Mercury
Percent Moisture
Percent Moisture
9045 pH Soil
pH at 25 Degrees C
9056 IC Anions
Chloride
Sulfate
9056 IC Anions 48hr
Nitrate as N
Date: 05/20/2015 08:27 AM
Analytical Method: EPA 6010 Preparation Method: EPA 3050
6360
mg/kg
32.2
16.1
5
05/04/15 04:15
05/05/15 15:34
7429-90-5
65.3
mg/kg
3.2
1.6
5
05/04/15 04:15
05/05/15 15:34
7440-39-3
0.52
mg/kg
0.32
0.16
5
05/04/15 04:15
05/05/15 15:34
7440-41-7
ND
mg/kg
16.1
8.1
5
05/04/15 04:15
05/05/15 15:34
7440-42-8
1380
mg/kg
161
80.5
5
05/04/15 04:15
05/05/15 15:34
7440-70-2
7.5
mg/kg
1.6
0.81
5
05/04/15 04:15
05/05/15 15:34
7440-47-3
8.0
mg/kg
1.6
0.81
5
05/04/15 04:15
05/05/15 15:34
7440-50-8
14900
mg/kg
12.9
6.4
5
05/04/15 04:15
05/05/15 15:34
7439-89-6
2170
mg/kg
161
80.5
5
05/04/15 04:15
05/05/15 15:34
7439-95-4
695
mg/kg
1.6
0.81
5
05/04/15 04:15
05/05/15 15:34
7439-96-5
ND
mg/kg
3.2
1.6
5
05/04/15 04:15
05/05/15 15:34
7439-98-7
6.2
mg/kg
1.6
0.81
5
05/04/15 04:15
05/05/15 15:34
7440-02-0
355
mg/kg
322
161
5
05/04/15 04:15
05/05/15 15:34
7440-09-7
ND
mg/kg
322
161
5
05/04/15 04:15
05/05/15 15:34
7440-23-5
17.6
mg/kg
3.2
1.6
5
05/04/15 04:15
05/05/15 15:34
7440-24-6
24.5
mg/kg
6.4
3.2
5
05/04/15 04:15
05/05/15 15:34
7440-66-6
Analytical
Method: EPA 6020 Preparation
Method: EPA 3050
ND
mg/kg
6.4
3.2
100
05/04/15 04:15
05/05/15 10:10
7440-36-0
ND
mg/kg
6.4
3.2
100
05/04/15 04:15
05/05/15 10:10
7440-38-2
ND
mg/kg
0.77
0.39
100
05/04/15 04:15
05/05/15 10:10
7440-43-9
11.7
mg/kg
6.4
3.2
100
05/04/15 04:15
05/05/15 10:10
7440-48-4
6.5
mg/kg
6.4
3.2
100
05/04/15 04:15
05/05/15 10:10
7439-92-1
ND
mg/kg
6.4
3.2
100
05/04/15 04:15
05/05/15 10:10
7782-49-2
ND
mg/kg
6.4
3.2
100
05/04/15 04:15
05/05/15 10:10
7440-28-0
38.2
mg/kg
6.4
3.2
100
05/04/15 04:15
05/05/15 10:10
7440-62-2
Analytical Method: EPA 7471 Preparation Method: EPA 7471
ND mg/kg 0.010 0.0052 1 05/04/15 05:06 05/04/15 16:00 7439-97-6
Analytical Method: ASTM D2974-87
20.9 % 0.10 0.10 1 05/05/1510:25
Analytical Method: EPA 9045
6.2 Std. Units
0.10
0.10 1
Analytical Method: EPA 9056
ND mg/kg
317
159 5
ND mg/kg
317
159 5
Analytical Method: EPA 9056
ND mg/kg
31.7
15.9 5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
[8DX-11f61KCAR
CU
N2
I:fl
05/01/15 03:55 16887-00-6 D3
05/01/15 03:55 14808-79-8 D3
05/01/15 03:55 14797-55-8 D3,H3
Page 43 of 79

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Ijigc&yqll�e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040620
Pace Project No.: 92247080
Sample: 2015012039
Lab ID:
92247080007
Collected:
04/23/15 15:10
Received: 04/24/15 12:54 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample
size and any dilutions.
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared Analyzed
CAS No. Qual
Total Organic Carbon Quad
Analytical
Method: EPA 9060
Total Organic Carbon
493J
mg/kg
757
378
1
05/18/15 18:19
7440-44-0
Total Organic Carbon
511J
mg/kg
755
377
1
05/18/15 18:26
7440-44-0
Total Organic Carbon
499J
mg/kg
762
381
1
05/18/15 18:31
7440-44-0
Total Organic Carbon
467J
mg/kg
757
378
1
05/18/15 18:38
7440-44-0
Mean Total Organic Carbon
492J
mg/kg
757
379
1
05/18/15 18:19
7440-44-0
Surrogates
RSD%
3.8
%
1
05/18/15 18:19
Date: 05/20/2015 08:27 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 44 of 79

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Ijc&fie. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040620
Pace Project No.: 92247080
Sample: 2015012034 Lab ID: 92247080008 Collected: 04/23/15 12:40 Received: 04/24/15 12:54 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
;I➢ZI7c\��,I=11a
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Sodium
Strontium
Thallium
Vanadium
Zinc
7470A Mercury
Mercury
Date: 05/20/2015 08:27 AM
Analytical Method: EPA 6020A Preparation Method: EPA 3020
10.7
ug/L
10.0
3.0
1
04/28/15 20:17
04/30/15 11:26
7429-90-5
ND
ug/L
0.50
0.15
1
04/28/15 20:17
04/30/15 11:26
7440-36-0
0.14J
ug/L
0.50
0.11
1
04/28/15 20:17
04/30/15 11:26
7440-38-2
0.73
ug/L
0.30
0.081
1
04/28/15 20:17
04/30/15 11:26
7440-39-3
ND
ug/L
0.20
0.067
1
04/28/15 20:17
04/30/15 11:26
7440-41-7
ND
ug/L
5.0
1.1
1
04/28/15 20:17
04/30/15 11:26
7440-42-8
ND
ug/L
0.080
0.024
1
04/28/15 20:17
04/30/15 11:26
7440-43-9
167
ug/L
40.0
16.0
1
04/28/15 20:17
04/30/15 11:26
7440-70-2
0.20J
ug/L
0.50
0.17
1
04/28/15 20:17
04/30/15 11:26
7440-47-3
ND
ug/L
0.50
0.13
1
04/28/15 20:17
04/30/15 11:26
7440-48-4
ND
ug/L
1.0
0.21
1
04/28/15 20:17
04/30/15 11:26
7440-50-8
31.8J
ug/L
50.0
13.7
1
04/28/15 20:17
04/30/15 11:26
7439-89-6
ND
ug/L
0.10
0.046
1
04/28/15 20:17
04/30/15 11:26
7439-92-1
24.3
ug/L
10.0
3.2
1
04/28/15 20:17
04/30/15 11:26
7439-95-4
2.4
ug/L
0.50
0.24
1
04/28/15 20:17
04/30/15 11:26
7439-96-5
ND
ug/L
0.50
0.094
1
04/28/15 20:17
04/30/15 11:26
7439-98-7
ND
ug/L
0.50
0.16
1
04/28/15 20:17
04/30/15 11:26
7440-02-0
28.5J
ug/L
50.0
11.7
1
04/28/15 20:17
04/30/15 11:26
7440-09-7
ND
ug/L
0.50
0.20
1
04/28/15 20:17
04/30/15 11:26
7782-49-2
70.8
ug/L
50.0
16.3
1
04/28/15 20:17
04/30/15 11:26
7440-23-5
1.3
ug/L
0.50
0.13
1
04/28/15 20:17
04/30/15 11:26
7440-24-6
ND
ug/L
0.10
0.015
1
04/28/15 20:17
04/30/15 11:26
7440-28-0
ND
ug/L
1.0
0.28
1
04/28/15 20:17
04/30/15 11:26
7440-62-2
ND
ug/L
5.0
2.4
1
04/28/15 20:17
04/30/15 11:26
7440-66-6
Analytical Method: EPA 7470A Preparation Method: EPA 7470A
ND ug/L 0.20 0.022 1 04/28/15 20:40 04/30/15 18:06 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 45 of 79

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Ijgc&fie. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040620
Pace Project No.: 92247080
Sample: 2015012038 Lab ID: 92247080009 Collected: 04/21/15 15:50 Received: 04/24/15 12:54 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
;I➢ZI7c\�i,I=11 l[99�� 6?
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Sodium
Strontium
Thallium
Vanadium
Zinc
7470A Mercury
Mercury
Date: 05/20/2015 08:27 AM
Analytical Method: EPA 6020A Preparation Method: EPA 3020
27.9
ug/L
10.0
3.0
1
04/28/15 20:17
04/30/15 11:28
7429-90-5
ND
ug/L
0.50
0.15
1
04/28/15 20:17
04/30/15 11:28
7440-36-0
0.13J
ug/L
0.50
0.11
1
04/28/15 20:17
04/30/15 11:28
7440-38-2
2.3
ug/L
0.30
0.081
1
04/28/15 20:17
04/30/15 11:28
7440-39-3
ND
ug/L
0.20
0.067
1
04/28/15 20:17
04/30/15 11:28
7440-41-7
35.1
ug/L
5.0
1.1
1
04/28/15 20:17
04/30/15 11:28
7440-42-8
ND
ug/L
0.080
0.024
1
04/28/15 20:17
04/30/15 11:28
7440-43-9
211
ug/L
40.0
16.0
1
04/28/15 20:17
04/30/15 11:28
7440-70-2
8.8
ug/L
0.50
0.17
1
04/28/15 20:17
04/30/15 11:28
7440-47-3
2.0
ug/L
0.50
0.13
1
04/28/15 20:17
04/30/15 11:28
7440-48-4
17.2
ug/L
1.0
0.21
1
04/28/15 20:17
04/30/15 11:28
7440-50-8
1100
ug/L
50.0
13.7
1
04/28/15 20:17
04/30/15 11:28
7439-89-6
14.7
ug/L
0.10
0.046
1
04/28/15 20:17
04/30/15 11:28
7439-92-1
19.4
ug/L
10.0
3.2
1
04/28/15 20:17
04/30/15 11:28
7439-95-4
36.6
ug/L
0.50
0.24
1
04/28/15 20:17
04/30/15 11:28
7439-96-5
1.0
ug/L
0.50
0.094
1
04/28/15 20:17
04/30/15 11:28
7439-98-7
1.4
ug/L
0.50
0.16
1
04/28/15 20:17
04/30/15 11:28
7440-02-0
38AJ
ug/L
50.0
11.7
1
04/28/15 20:17
04/30/15 11:28
7440-09-7
ND
ug/L
0.50
0.20
1
04/28/15 20:17
04/30/15 11:28
7782-49-2
49.3J
ug/L
50.0
16.3
1
04/28/15 20:17
04/30/15 11:28
7440-23-5
0.72
ug/L
0.50
0.13
1
04/28/15 20:17
04/30/15 11:28
7440-24-6
ND
ug/L
0.10
0.015
1
04/28/15 20:17
04/30/15 11:28
7440-28-0
ND
ug/L
1.0
0.28
1
04/28/15 20:17
04/30/15 11:28
7440-62-2
33.8
ug/L
5.0
2.4
1
04/28/15 20:17
04/30/15 11:28
7440-66-6
Analytical Method: EPA 7470A Preparation Method: EPA 7470A
ND ug/L 0.20 0.022 1 04/28/15 20:40 04/30/15 18:13 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 46 of 79

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040620
Pace Project No.: 92247080
Sample: 2015012032 SPLP Lab ID: 92247080010 Collected: 04/21/15 13:30 Received: 04/24/15 12:54 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
;T➢Z17c\��il=11 a � 6?
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Sodium
Strontium
Thallium
Vanadium
Zinc
7470A Mercury
Mercury
Date: 05/20/2015 08:27 AM
Analytical Method: EPA 6020A Preparation Method: EPA 3020
116
ug/L
10.0
3.0
1
05/14/15 09:52
05/14/15 18:41
7429-90-5
ND
ug/L
0.50
0.15
1
05/14/15 09:52
05/14/15 18:41
7440-36-0
ND
ug/L
0.50
0.11
1
05/14/15 09:52
05/14/15 18:41
7440-38-2
278
ug/L
0.30
0.081
1
05/14/15 09:52
05/14/15 18:41
7440-39-3
0.13J
ug/L
0.20
0.067
1
05/14/15 09:52
05/14/15 18:41
7440-41-7
57.0
ug/L
5.0
1.1
1
05/14/15 09:52
05/15/15 09:37
7440-42-8
ND
ug/L
0.080
0.024
1
05/14/15 09:52
05/14/15 18:41
7440-43-9
1560
ug/L
40.0
16.0
1
05/14/15 09:52
05/14/15 18:41
7440-70-2
0.33J
ug/L
0.50
0.17
1
05/14/15 09:52
05/14/15 18:41
7440-47-3
3.2
ug/L
0.50
0.13
1
05/14/15 09:52
05/14/15 18:41
7440-48-4
1.7
ug/L
1.0
0.21
1
05/14/15 09:52
05/14/15 18:41
7440-50-8
16.5J
ug/L
50.0
13.7
1
05/14/15 09:52
05/14/15 18:41
7439-89-6
0.26
ug/L
0.10
0.046
1
05/14/15 09:52
05/14/15 18:41
7439-92-1
234
ug/L
10.0
3.2
1
05/14/15 09:52
05/14/15 18:41
7439-95-4
255
ug/L
0.50
0.24
1
05/14/15 09:52
05/14/15 18:41
7439-96-5
ND
ug/L
0.50
0.094
1
05/14/15 09:52
05/14/15 18:41
7439-98-7
1.8
ug/L
0.50
0.16
1
05/14/15 09:52
05/14/15 18:41
7440-02-0
602
ug/L
50.0
11.7
1
05/14/15 09:52
05/14/15 18:41
7440-09-7
ND
ug/L
0.50
0.20
1
05/14/15 09:52
05/14/15 18:41
7782-49-2
424
ug/L
50.0
16.3
1
05/14/15 09:52
05/14/15 18:41
7440-23-5
43.2
ug/L
0.50
0.13
1
05/14/15 09:52
05/14/15 18:41
7440-24-6
ND
ug/L
0.10
0.015
1
05/14/15 09:52
05/14/15 18:41
7440-28-0
ND
ug/L
1.0
0.28
1
05/14/15 09:52
05/14/15 18:41
7440-62-2
77.8
ug/L
5.0
2.4
1
05/14/15 09:52
05/14/15 18:41
7440-66-6
Analytical Method: EPA 7470A Preparation Method: EPA 7470A
ND ug/L 0.20 0.022 1 05/14/15 11:05 05/14/15 21:50 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 47 of 79

aceAnaiXical
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Pace Analytical Services, Inc.
9800 Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040620
Pace Project No.: 92247080
Sample: 2015012033 SPLP Lab ID: 92247080011 Collected: 04/21/15 13:50 Received: 04/24/15 12:54 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
;T➢Z17c\�iil=11 a
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Sodium
Strontium
Thallium
Vanadium
Zinc
7470A Mercury
Mercury
Date: 05/20/2015 08:27 AM
Analytical Method: EPA 6020A Preparation Method: EPA 3020
49.2
ug/L
10.0
3.0
1
05/14/15 09:52
05/14/15 18:44
7429-90-5
ND
ug/L
0.50
0.15
1
05/14/15 09:52
05/14/15 18:44
7440-36-0
ND
ug/L
0.50
0.11
1
05/14/15 09:52
05/14/15 18:44
7440-38-2
204
ug/L
0.30
0.081
1
05/14/15 09:52
05/14/15 18:44
7440-39-3
0.22
ug/L
0.20
0.067
1
05/14/15 09:52
05/14/15 18:44
7440-41-7
108
ug/L
25.0
5.6
5
05/14/15 09:52
05/15/15 09:43
7440-42-8
0.056J
ug/L
0.080
0.024
1
05/14/15 09:52
05/14/15 18:44
7440-43-9
2020
ug/L
40.0
16.0
1
05/14/15 09:52
05/14/15 18:44
7440-70-2
0.39J
ug/L
0.50
0.17
1
05/14/15 09:52
05/14/15 18:44
7440-47-3
10.9
ug/L
0.50
0.13
1
05/14/15 09:52
05/14/15 18:44
7440-48-4
3.0
ug/L
1.0
0.21
1
05/14/15 09:52
05/14/15 18:44
7440-50-8
15.2J
ug/L
50.0
13.7
1
05/14/15 09:52
05/14/15 18:44
7439-89-6
0.078J
ug/L
0.10
0.046
1
05/14/15 09:52
05/14/15 18:44
7439-92-1
806
ug/L
10.0
3.2
1
05/14/15 09:52
05/14/15 18:44
7439-95-4
554
ug/L
2.5
1.2
5
05/14/15 09:52
05/15/15 09:43
7439-96-5
ND
ug/L
0.50
0.094
1
05/14/15 09:52
05/14/15 18:44
7439-98-7
2.5
ug/L
0.50
0.16
1
05/14/15 09:52
05/14/15 18:44
7440-02-0
497
ug/L
50.0
11.7
1
05/14/15 09:52
05/14/15 18:44
7440-09-7
ND
ug/L
0.50
0.20
1
05/14/15 09:52
05/14/15 18:44
7782-49-2
1970
ug/L
50.0
16.3
1
05/14/15 09:52
05/14/15 18:44
7440-23-5
51.7
ug/L
0.50
0.13
1
05/14/15 09:52
05/14/15 18:44
7440-24-6
ND
ug/L
0.10
0.015
1
05/14/15 09:52
05/14/15 18:44
7440-28-0
ND
ug/L
1.0
0.28
1
05/14/15 09:52
05/14/15 18:44
7440-62-2
127
ug/L
5.0
2.4
1
05/14/15 09:52
05/14/15 18:44
7440-66-6
Analytical Method: EPA 7470A Preparation Method: EPA 7470A
ND ug/L 0.20 0.022 1 05/14/15 11:05 05/14/15 21:52 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 48 of 79

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 1�nlc&fie. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040620
Pace Project No.: 92247080
Sample: 2015012035 SPLP Lab ID: 92247080012 Collected: 04/23/15 14:30 Received: 04/24/15 12:54 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
;T➢Z17c\�iil=11 a
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Sodium
Strontium
Thallium
Vanadium
Zinc
7470A Mercury
Mercury
Date: 05/20/2015 08:27 AM
Analytical Method: EPA 6020A Preparation Method: EPA 3020
17400
ug/L
10.0
3.0
1
05/14/15 09:52
05/14/15 18:46
7429-90-5
ND
ug/L
0.50
0.15
1
05/14/15 09:52
05/14/15 18:46
7440-36-0
0.82
ug/L
0.50
0.11
1
05/14/15 09:52
05/14/15 18:46
7440-38-2
166
ug/L
0.30
0.081
1
05/14/15 09:52
05/14/15 18:46
7440-39-3
0.20
ug/L
0.20
0.067
1
05/14/15 09:52
05/14/15 18:46
7440-41-7
43.4
ug/L
5.0
1.1
1
05/14/15 09:52
05/15/15 09:40
7440-42-8
ND
ug/L
0.080
0.024
1
05/14/15 09:52
05/14/15 18:46
7440-43-9
1370
ug/L
40.0
16.0
1
05/14/15 09:52
05/14/15 18:46
7440-70-2
15.8
ug/L
0.50
0.17
1
05/14/15 09:52
05/14/15 18:46
7440-47-3
2.1
ug/L
0.50
0.13
1
05/14/15 09:52
05/14/15 18:46
7440-48-4
8.7
ug/L
1.0
0.21
1
05/14/15 09:52
05/14/15 18:46
7440-50-8
15400
ug/L
50.0
13.7
1
05/14/15 09:52
05/14/15 18:46
7439-89-6
3.3
ug/L
0.10
0.046
1
05/14/15 09:52
05/14/15 18:46
7439-92-1
1180
ug/L
10.0
3.2
1
05/14/15 09:52
05/14/15 18:46
7439-95-4
31.5
ug/L
0.50
0.24
1
05/14/15 09:52
05/14/15 18:46
7439-96-5
ND
ug/L
0.50
0.094
1
05/14/15 09:52
05/14/15 18:46
7439-98-7
4.9
ug/L
0.50
0.16
1
05/14/15 09:52
05/14/15 18:46
7440-02-0
290
ug/L
50.0
11.7
1
05/14/15 09:52
05/14/15 18:46
7440-09-7
0.25J
ug/L
0.50
0.20
1
05/14/15 09:52
05/14/15 18:46
7782-49-2
2400
ug/L
50.0
16.3
1
05/14/15 09:52
05/15/15 09:40
7440-23-5
19.6
ug/L
0.50
0.13
1
05/14/15 09:52
05/14/15 18:46
7440-24-6
0.0911
ug/L
0.10
0.015
1
05/14/15 09:52
05/14/15 18:46
7440-28-0
40.1
ug/L
1.0
0.28
1
05/14/15 09:52
05/14/15 18:46
7440-62-2
85.2
ug/L
5.0
2.4
1
05/14/15 09:52
05/14/15 18:46
7440-66-6
Analytical Method: EPA 7470A Preparation Method: EPA 7470A
ND ug/L 0.20 0.022 1 05/14/15 11:05 05/14/15 21:54 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 49 of 79

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040620
Pace Project No.: 92247080
Sample: 2015012036 SPLP Lab ID: 92247080013 Collected: 04/23/15 14:50 Received: 04/24/15 12:54 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
;T➢Z17c\��il=11 a � 6?
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Sodium
Strontium
Thallium
Vanadium
Zinc
7470A Mercury
Mercury
Date: 05/20/2015 08:27 AM
Analytical Method: EPA 6020A Preparation Method: EPA 3020
108000
ug/L
50.0
14.9
5
05/14/15 09:52
05/15/15 12:46
7429-90-5
ND
ug/L
0.50
0.15
1
05/14/15 09:52
05/14/15 18:49
7440-36-0
7.6
ug/L
0.50
0.11
1
05/14/15 09:52
05/14/15 18:49
7440-38-2
854
ug/L
1.5
0.40
5
05/14/15 09:52
05/15/15 12:46
7440-39-3
7.4
ug/L
1.0
0.34
5
05/14/15 09:52
05/15/15 12:46
7440-41-7
52.4
ug/L
25.0
5.6
5
05/14/15 09:52
05/15/15 12:46
7440-42-8
0.080
ug/L
0.080
0.024
1
05/14/15 09:52
05/14/15 18:49
7440-43-9
12800
ug/L
200
80.0
5
05/14/15 09:52
05/15/15 12:46
7440-70-2
162
ug/L
2.5
0.84
5
05/14/15 09:52
05/15/15 12:46
7440-47-3
52.0
ug/L
0.50
0.13
1
05/14/15 09:52
05/14/15 18:49
7440-48-4
117
ug/L
1.0
0.21
1
05/14/15 09:52
05/14/15 18:49
7440-50-8
161000
ug/L
2500
685
50
05/14/15 09:52
05/15/15 12:48
7439-89-6
37.0
ug/L
0.10
0.046
1
05/14/15 09:52
05/14/15 18:49
7439-92-1
13900
ug/L
50.0
15.8
5
05/14/15 09:52
05/15/15 12:46
7439-95-4
1980
ug/L
2.5
1.2
5
05/14/15 09:52
05/15/15 12:46
7439-96-5
0.24J
ug/L
0.50
0.094
1
05/14/15 09:52
05/14/15 18:49
7439-98-7
61.6
ug/L
0.50
0.16
1
05/14/15 09:52
05/14/15 18:49
7440-02-0
1500
ug/L
250
58.7
5
05/14/15 09:52
05/15/15 12:46
7440-09-7
1.8
ug/L
0.50
0.20
1
05/14/15 09:52
05/14/15 18:49
7782-49-2
5310
ug/L
250
81.5
5
05/14/15 09:52
05/15/15 12:46
7440-23-5
193
ug/L
0.50
0.13
1
05/14/15 09:52
05/14/15 18:49
7440-24-6
0.34
ug/L
0.10
0.015
1
05/14/15 09:52
05/14/15 18:49
7440-28-0
411
ug/L
5.0
1.4
5
05/14/15 09:52
05/15/15 12:46
7440-62-2
255
ug/L
5.0
2.4
1
05/14/15 09:52
05/14/15 18:49
7440-66-6
Analytical Method: EPA 7470A Preparation Method: EPA 7470A
0.0901 ug/L 0.20 0.022 1 05/14/15 11:05 05/14/15 21:56 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 50 of 79

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040620
Pace Project No.: 92247080
QC Batch: MERP/13380
Analysis Method: EPA 7470A
QC Batch Method: EPA 7470A
Analysis Description: 7470A Mercury Water
Associated Lab Samples: 92247080008, 92247080009
METHOD BLANK: 1950361
Matrix: Water
Associated Lab Samples: 92247080008, 92247080009
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Mercury ug/L
ND 0.20
04/30/1517:44
LABORATORY CONTROL SAMPLE: 1950362
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Mercury ug/L
5 5.2
105 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1950363 1950364
MS MSD
92247052009
Spike Spike MS
MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec Limits RPD RPD Qual
Mercury ug/L ND
5 5 5.4
5.6 107 111 80-120 4 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/20/2015 08:27 AM without the written consent of Pace Analytical Services, Inc..
Page 51 of 79

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040620
Pace Project No.: 92247080
QC Batch: MERP/13538
Analysis Method: EPA 7470A
QC Batch Method: EPA 7470A
Analysis Description: 7470A Mercury Water
Associated Lab Samples: 92247080010, 92247080011,
92247080012, 92247080013
METHOD BLANK: 1965167
Matrix: Water
Associated Lab Samples: 92247080010, 92247080011,
92247080012, 92247080013
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Mercury ug/L
ND 0.20
05/14/15 21:03
LABORATORY CONTROL SAMPLE: 1965168
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Mercury ug/L
5 4.7
94 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1965262 1965263
MS MSD
10306022003
Spike Spike MS
MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec Limits RPD RPD Qual
Mercury ug/L ND
5 5 4.7
4.8 93 95 80-120 2 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/20/2015 08:27 AM without the written consent of Pace Analytical Services, Inc..
Page 52 of 79

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040620
Pace Project No.: 92247080
QC Batch: MERP/5669
Analysis Method: EPA 7471
QC Batch Method: EPA 7471
Analysis Description: 7471 Mercury
Associated Lab Samples: 92247080001,92247080002,92247080003,92247080004,92247080005,92247080006,92247080007
METHOD BLANK: 1202036
Matrix: Solid
Associated Lab Samples: 92247080001, 92247080002,
92247080003, 92247080004, 92247080005, 92247080006, 92247080007
Blank Reporting
Parameter Units
Result Limit Analyzed Qualifiers
Mercury mg/kg
ND 0.0077 05/04/1515:17
LABORATORY CONTROL SAMPLE: 1202037
Spike LCS LCS % Rec
Parameter Units
Conc. Result % Rec Limits Qualifiers
Mercury mg/kg
.081 0.079 98 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1202038 1202039
MS MSD
92247054001
Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Mercury mg/kg ND
.107 .107 0.11 0.12 103 106 80-120 3 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/20/2015 08:27 AM without the written consent of Pace Analytical Services, Inc..
Page 53 of 79

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040620
Pace Project No.: 92247080
QC Batch: MPRP/23928 Analysis Method: EPA 6010
QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid
Associated Lab Samples: 92247080001, 92247080002, 92247080003, 92247080004, 92247080005, 92247080006, 92247080007
METHOD BLANK: 1202028 Matrix: Solid
Associated Lab Samples: 92247080001, 92247080002, 92247080003, 92247080004, 92247080005, 92247080006, 92247080007
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Aluminum
mg/kg
ND
4.9
05/05/1513:40
Barium
mg/kg
ND
0.49
05/05/1513:40
Beryllium
mg/kg
ND
0.049
05/05/1513:40
Boron
mg/kg
ND
2.4
05/05/1513:40
Calcium
mg/kg
ND
24.5
05/05/1513:40
Chromium
mg/kg
ND
0.24
05/05/1513:40
Copper
mg/kg
ND
0.24
05/05/1513:40
Iron
mg/kg
ND
2.0
05/05/1513:40
Magnesium
mg/kg
ND
24.5
05/05/1513:40
Manganese
mg/kg
ND
0.24
05/05/1513:40
Molybdenum
mg/kg
ND
0.49
05/05/1513:40
Nickel
mg/kg
ND
0.24
05/05/1513:40
Potassium
mg/kg
ND
49.0
05/05/1513:40
Sodium
mg/kg
ND
49.0
05/05/1513:40
Strontium
mg/kg
ND
0.49
05/05/1513:40
Zinc
mg/kg
ND
0.98
05/05/1513:40
LABORATORY CONTROL SAMPLE:
Parameter
1202029
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
Aluminum
mg/kg
127
134
106
80-120
Barium
mg/kg
12.7
13.5
106
80-120
Beryllium
mg/kg
1.3
1.3
103
80-120
Boron
mg/kg
127
127
100
80-120
Calcium
mg/kg
635
685
108
80-120
Chromium
mg/kg
12.7
12.5
99
80-120
Copper
mg/kg
12.7
12.5
98
80-120
Iron
mg/kg
127
133
104
80-120
Magnesium
mg/kg
635
655
103
80-120
Manganese
mg/kg
12.7
12.9
101
80-120
Molybdenum
mg/kg
12.7
13.0
102
80-120
Nickel
mg/kg
12.7
13.2
104
80-120
Potassium
mg/kg
635
675
106
80-120
Sodium
mg/kg
635
707
111
80-120
Strontium
mg/kg
12.7
13.5
106
80-120
Zinc
mg/kg
63.5
67.2
106
80-120
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/20/2015 08:27 AM without the written consent of Pace Analytical Services, Inc.. Page 54 of 79

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040620
Pace Project No.: 92247080
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
1202030
1202031
MS
MSD
92247054001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Aluminum
mg/kg
2870
167
167
4750
3780
1130
550
75-125
23
20 M1,R1
Barium
mg/kg
9.2
16.7
16.7
26.7
25.7
105
99
75-125
4
20
Beryllium
mg/kg
0.13J
1.69
1.69
1.8
1.9
101
105
75-125
3
20
Boron
mg/kg
ND
167
167
154
166
92
99
75-125
7
20
Calcium
mg/kg
ND
833
832
893
949
106
113
75-125
6
20
Chromium
mg/kg
1.9
16.7
16.7
18.4
18.7
99
101
75-125
2
20
Copper
mg/kg
ND
16.7
16.7
16.4
17.2
96
100
75-125
4
20
Iron
mg/kg
343
167
167
748
629
243
172
75-125
17
20 M1
Magnesium
mg/kg
ND
833
832
961
991
108
112
75-125
3
20
Manganese
mg/kg
2.1
16.7
16.7
19.9
20.0
107
108
75-125
1
20
Molybdenum
mg/kg
ND
16.7
16.7
15.7
16.7
94
100
75-125
6
20
Nickel
mg/kg
ND
16.7
16.7
18.2
19.0
107
111
75-125
4
20
Potassium
mg/kg
ND
833
832
915
963
104
110
75-125
5
20
Sodium
mg/kg
ND
833
832
887
889
107
107
75-125
0
20
Strontium
mg/kg
ND
16.7
16.7
18.2
19.2
108
114
75-125
5
20
Zinc
mg/kg
ND
83.3
83.2
87.9
91.7
105
109
75-125
4
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/20/2015 08:27 AM without the written consent of Pace Analytical Services, Inc..
Page 55 of 79

aceAnaiXical
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Pace Analytical Services, Inc.
9800 Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040620
Pace Project No.: 92247080
QC Batch: MPRP/23929 Analysis Method: EPA 6020
QC Batch Method: EPA 3050 Analysis Description: 6020 MET SOLID
Associated Lab Samples: 92247080001, 92247080002, 92247080003, 92247080004, 92247080005, 92247080006, 92247080007
METHOD BLANK: 1202032
Matrix:
Solid
Associated Lab Samples:
92247080001, 92247080002,
92247080003, 92247080004, 92247080005,
92247080006, 92247080007
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Antimony
mg/kg
ND
0.048
05/05/15 09:11 N2
Arsenic
mg/kg
ND
0.048
05/05/15 09:11
Cadmium
mg/kg
ND
0.0058
05/05/15 09:11
Cobalt
mg/kg
ND
0.048
05/05/15 09:11
Lead
mg/kg
ND
0.048
05/05/15 09:11
Selenium
mg/kg
ND
0.048
05/05/15 09:11
Thallium
mg/kg
ND
0.048
05/05/15 09:11
Vanadium
mg/kg
ND
0.048
05/05/15 09:11
LABORATORY CONTROL SAMPLE: 1202033
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits
Qualifiers
Antimony
mg/kg
2.5
2.5
100
80-120
N2
Arsenic
mg/kg
2.5
2.7
109
80-120
Cadmium
mg/kg
.25
0.26
103
80-120
Cobalt
mg/kg
2.5
2.7
107
80-120
Lead
mg/kg
2.5
2.5
102
80-120
Selenium
mg/kg
2.5
2.6
104
80-120
Thallium
mg/kg
2.5
2.5
101
80-120
Vanadium
mg/kg
2.5
2.6
107
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1202034
1202035
MS
MSD
92247054001
Spike
Spike
MS
MSD
MS MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec % Rec
Limits
RPD RPD Qual
Antimony
mg/kg
ND
3.12
3.25
ND
ND
75
82
75-125
20 N2
Arsenic
mg/kg
ND
3.12
3.25
3.6J
3.8J
83
86
75-125
20
Cadmium
mg/kg
ND
.312
.325
ND
0.45J
106
140
75-125
20 M6
Cobalt
mg/kg
ND
3.12
3.25
3.5J
3.8J
102
109
75-125
20
Lead
mg/kg
ND
3.12
3.25
4.5J
5.OJ
54
68
75-125
20 M6
Selenium
mg/kg
ND
3.12
3.25
3.6J
3.8J
66
69
75-125
20 M6
Thallium
mg/kg
ND
3.12
3.25
3.3J
3.3J
78
77
75-125
20
Vanadium
mg/kg
4AJ
3.12
3.25
6.6
6.3J
70
60
75-125
20 M6
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/20/2015 08:27 AM without the written consent of Pace Analytical Services, Inc..
Page 56 of 79

aceAnaiXical
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Pace Analytical Services, Inc.
9800 Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040620
Pace Project No.: 92247080
QC Batch: MPRP/53983 Analysis Method: EPA 6020A
QC Batch Method: EPA 3020 Analysis Description: 6020A Water UPD4
Associated Lab Samples: 92247080008, 92247080009
METHOD BLANK: 1950241
Associated Lab Samples: 92247080008, 92247080009
Parameter
Units
Aluminum
ug/L
Antimony
ug/L
Arsenic
ug/L
Barium
ug/L
Beryllium
ug/L
Boron
ug/L
Cadmium
ug/L
Calcium
ug/L
Chromium
ug/L
Cobalt
ug/L
Copper
ug/L
Iron
ug/L
Lead
ug/L
Magnesium
ug/L
Manganese
ug/L
Molybdenum
ug/L
Nickel
ug/L
Potassium
ug/L
Selenium
ug/L
Sodium
ug/L
Strontium
ug/L
Thallium
ug/L
Vanadium
ug/L
Zinc
ug/L
Matrix: Water
Blank
Result
Reporting
Limit
Analyzed
ND
10.0
04/30/1510:39
ND
0.50
04/30/1510:39
ND
0.50
04/30/1510:39
ND
0.30
04/30/1510:39
ND
0.20
04/30/1510:39
ND
5.0
04/30/1510:39
ND
0.080
04/30/1510:39
ND
40.0
04/30/1510:39
ND
0.50
04/30/1510:39
ND
0.50
04/30/1510:39
ND
1.0
04/30/1510:39
ND
50.0
04/30/1510:39
ND
0.10
04/30/1510:39
ND
10.0
04/30/1510:39
ND
0.50
04/30/1510:39
ND
0.50
04/30/1510:39
ND
0.50
04/30/1510:39
ND
50.0
04/30/1510:39
ND
0.50
04/30/1510:39
ND
50.0
04/30/1510:39
ND
0.50
04/30/1510:39
ND
0.10
04/30/1510:39
ND
1.0
04/30/1510:39
ND
5.0
04/30/1510:39
Qualifiers
LABORATORY CONTROL SAMPLE:
Parameter
1950242
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
Aluminum
ug/L
80
80.2
100
80-120
Antimony
ug/L
80
82.7
103
80-120
Arsenic
ug/L
80
84.7
106
80-120
Barium
ug/L
80
87.4
109
80-120
Beryllium
ug/L
80
83.0
104
80-120
Boron
ug/L
80
82.5
103
80-120
Cadmium
ug/L
80
82.1
103
80-120
Calcium
ug/L
1000
1060
106
80-120
Chromium
ug/L
80
89.0
111
80-120
Cobalt
ug/L
80
88.8
111
80-120
Copper
ug/L
80
88.2
110
80-120
Iron
ug/L
1000
1110
111
80-120
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/20/2015 08:27 AM without the written consent of Pace Analytical Services, Inc..
Page 57 of 79

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040620
Pace Project No.: 92247080
LABORATORY CONTROL SAMPLE:
1950242
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits
Qualifiers
Lead
ug/L
80
86.5
108
80-120
Magnesium
ug/L
1000
1100
110
80-120
Manganese
ug/L
80
83.9
105
80-120
Molybdenum
ug/L
80
84.2
105
80-120
Nickel
ug/L
80
86.1
108
80-120
Potassium
ug/L
1000
1140
114
80-120
Selenium
ug/L
80
86.1
108
80-120
Sodium
ug/L
1000
1140
114
80-120
Strontium
ug/L
80
77.7
97
80-120
Thallium
ug/L
80
91.5
114
80-120
Vanadium
ug/L
80
91.6
114
80-120
Zinc
ug/L
80
81.7
102
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
1950243
1950244
MS
MSD
92247052008
Spike
Spike
MS
MSD
MS MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec % Rec
Limits
RPD
RPD Qual
Aluminum
ug/L
31.1
80
80
142
186
138
193
75-125
27
20 M1,R1
Antimony
ug/L
ND
80
80
89.2
82.2
111
103
75-125
8
20
Arsenic
ug/L
ND
80
80
92.1
86.2
115
108
75-125
7
20
Barium
ug/L
0.79
80
80
90.1
84.5
112
105
75-125
6
20
Beryllium
ug/L
ND
80
80
83.0
83.4
104
104
75-125
0
20
Boron
ug/L
ND
80
80
86.1
87.2
106
108
75-125
1
20
Cadmium
ug/L
ND
80
80
90.3
84.8
113
106
75-125
6
20
Calcium
ug/L
40.5
1000
1000
1180
1100
114
106
75-125
7
20
Chromium
ug/L
0.73
80
80
89.4
83.8
111
104
75-125
6
20
Cobalt
ug/L
0.191
80
80
90.5
84.9
113
106
75-125
6
20
Copper
ug/L
0.56J
80
80
89.2
83.9
111
104
75-125
6
20
Iron
ug/L
169
1000
1000
1410
1380
124
121
75-125
3
20
Lead
ug/L
ND
80
80
91.0
84.7
114
106
75-125
7
20
Magnesium
ug/L
12.8
1000
1000
1130
1060
112
105
75-125
6
20
Manganese
ug/L
10.3
80
80
102
95.0
115
106
75-125
7
20
Molybdenum
ug/L
ND
80
80
90.8
84.8
113
106
75-125
7
20
Nickel
ug/L
0.25J
80
80
93.7
88.2
117
110
75-125
6
20
Potassium
ug/L
20.5J
1000
1000
1110
1040
109
102
75-125
7
20
Selenium
ug/L
ND
80
80
86.0
85.8
108
107
75-125
0
20
Sodium
ug/L
20.OJ
1000
1000
1170
1080
115
106
75-125
8
20
Strontium
ug/L
0.24J
80
80
85.3
79.3
106
99
75-125
7
20
Thallium
ug/L
ND
80
80
99.1
91.1
124
114
75-125
8
20
Vanadium
ug/L
ND
80
80
90.7
85.3
113
106
75-125
6
20
Zinc
ug/L
ND
80
80
85.7
79.6
107
99
75-125
7
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/20/2015 08:27 AM without the written consent of Pace Analytical Services, Inc..
Page 58 of 79

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 �nic&yqll�e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040620
Pace Project No.: 92247080
QC Batch: MPRP/54376 Analysis Method: EPA 6020A
QC Batch Method: EPA 3020 Analysis Description: 6020A Water UPD4
Associated Lab Samples: 92247080010, 92247080011, 92247080012, 92247080013
METHOD BLANK: 1965127 Matrix: Water
Associated Lab Samples: 92247080010, 92247080011, 92247080012, 92247080013
Blank Reporting
Parameter Units Result Limit
Analyzed
Aluminum
ug/L
ND
10.0
05/14/1518:38
Antimony
ug/L
ND
0.50
05/14/1518:38
Arsenic
ug/L
ND
0.50
05/14/1518:38
Barium
ug/L
ND
0.30
05/14/1518:38
Beryllium
ug/L
ND
0.20
05/14/1518:38
Boron
ug/L
ND
5.0
05/14/1518:38
Cadmium
ug/L
ND
0.080
05/14/1518:38
Calcium
ug/L
ND
40.0
05/14/1518:38
Chromium
ug/L
ND
0.50
05/14/1518:38
Cobalt
ug/L
ND
0.50
05/14/1518:38
Copper
ug/L
ND
1.0
05/14/1518:38
Iron
ug/L
ND
50.0
05/14/1518:38
Lead
ug/L
ND
0.10
05/14/1518:38
Magnesium
ug/L
ND
10.0
05/14/1518:38
Manganese
ug/L
ND
0.50
05/14/1518:38
Molybdenum
ug/L
ND
0.50
05/14/1518:38
Nickel
ug/L
ND
0.50
05/14/1518:38
Potassium
ug/L
ND
50.0
05/14/1518:38
Selenium
ug/L
ND
0.50
05/14/1518:38
Sodium
ug/L
ND
50.0
05/14/1518:38
Strontium
ug/L
ND
0.50
05/14/1518:38
Thallium
ug/L
ND
0.10
05/14/1518:38
Vanadium
ug/L
ND
1.0
05/14/1518:38
Zinc
ug/L
ND
5.0
05/14/1518:38
Qualifiers
LABORATORY CONTROL SAMPLE:
Parameter
1965128
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
Aluminum
ug/L
80
76.2
95
80-120
Antimony
ug/L
80
75.8
95
80-120
Arsenic
ug/L
80
79.0
99
80-120
Barium
ug/L
80
84.8
106
80-120
Beryllium
ug/L
80
81.2
102
80-120
Boron
ug/L
80
80.9
101
80-120
Cadmium
ug/L
80
79.9
100
80-120
Calcium
ug/L
1000
1030
103
80-120
Chromium
ug/L
80
81.1
101
80-120
Cobalt
ug/L
80
79.1
99
80-120
Copper
ug/L
80
82.4
103
80-120
Iron
ug/L
1000
1000
100
80-120
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/20/2015 08:27 AM without the written consent of Pace Analytical Services, Inc.. Page 59 of 79

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040620
Pace Project No.: 92247080
LABORATORY CONTROL SAMPLE:
1965128
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits
Qualifiers
Lead
ug/L
80
82.1
103
80-120
Magnesium
ug/L
1000
927
93
80-120
Manganese
ug/L
80
78.3
98
80-120
Molybdenum
ug/L
80
77.8
97
80-120
Nickel
ug/L
80
79.3
99
80-120
Potassium
ug/L
1000
934
93
80-120
Selenium
ug/L
80
81.3
102
80-120
Sodium
ug/L
1000
1080
108
80-120
Strontium
ug/L
80
74.7
93
80-120
Thallium
ug/L
80
87.7
110
80-120
Vanadium
ug/L
80
79.5
99
80-120
Zinc
ug/L
80
82.5
103
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
1965129
1965130
MS
MSD
10305831001
Spike
Spike
MS
MSD
MS MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec % Rec
Limits
RPD
RPD Qual
Aluminum
ug/L
93.4
80
80
125
128
39
43
75-125
2
20 M1
Antimony
ug/L
ND
80
80
78.5
79.3
98
99
75-125
1
20
Arsenic
ug/L
0.96
80
80
83.1
82.7
103
102
75-125
0
20
Barium
ug/L
69.5
80
80
146
149
96
99
75-125
2
20
Beryllium
ug/L
ND
80
80
82.1
86.7
103
108
75-125
5
20
Boron
ug/L
38.5
80
80
129
121
114
103
75-125
7
20
Cadmium
ug/L
ND
80
80
83.7
85.7
105
107
75-125
2
20
Calcium
ug/L
57900
1000
1000
52000
52300
-591
-562
75-125
1
20 M1
Chromium
ug/L
1.3
80
80
83.2
85.0
102
105
75-125
2
20
Cobalt
ug/L
ND
80
80
82.1
83.0
102
103
75-125
1
20
Copper
ug/L
1.8
80
80
86.1
86.9
105
106
75-125
1
20
Iron
ug/L
833
1000
1000
1830
1870
100
103
75-125
2
20
Lead
ug/L
0.30
80
80
80.9
81.2
101
101
75-125
0
20
Magnesium
ug/L
10100
1000
1000
12100
12400
201
229
75-125
2
20 M1
Manganese
ug/L
265
80
80
327
329
77
79
75-125
1
20
Molybdenum
ug/L
0.76
80
80
84.0
85.2
104
106
75-125
1
20
Nickel
ug/L
1.3
80
80
81.9
83.3
101
103
75-125
2
20
Potassium
ug/L
3360
1000
1000
4050
4060
69
70
75-125
0
20 M1
Selenium
ug/L
ND
80
80
83.0
83.6
104
104
75-125
1
20
Sodium
ug/L
119000
1000
1000
122000
125000
304
558
75-125
2
20 M6
Strontium
ug/L
98.7
80
80
181
183
102
106
75-125
2
20
Thallium
ug/L
ND
80
80
86.7
86.8
108
109
75-125
0
20
Vanadium
ug/L
ND
80
80
83.1
84.4
103
105
75-125
2
20
Zinc
ug/L
5.2
80
80
87.9
88.8
103
105
75-125
1
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/20/2015 08:27 AM without the written consent of Pace Analytical Services, Inc..
Page 60 of 79

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040620
Pace Project No.: 92247080
QC Batch: PMST/3532
Analysis Method:
ASTM D2974-87
QC Batch Method: ASTM
D2974-87
Analysis Description:
Dry Weight/Percent Moisture
Associated Lab Samples:
92247080001,92247080002,92247080003,92247080004,92247080005,92247080006,92247080007
SAMPLE DUPLICATE:
1203207
35185354001
Dup
Max
Parameter
Units
Result
Result RPD
RPD
Qualifiers
Percent Moisture
%
87.2
78.3 11
10 D6
SAMPLE DUPLICATE:
1203208
35185835006
Dup
Max
Parameter
Units
Result
Result RPD
RPD
Qualifiers
Percent Moisture
%
2.3
2.4 5
10
SAMPLE DUPLICATE:
1203209
35185835016
Dup
Max
Parameter
Units
Result
Result RPD
RPD
Qualifiers
Percent Moisture
%
4.9
4.8 2
10
SAMPLE DUPLICATE:
1203210
92247054001
Dup
Max
Parameter
Units
Result
Result RPD
RPD
Qualifiers
Percent Moisture
%
23.2
20.7 11
10 D6
SAMPLE DUPLICATE:
1203211
92247080003
Dup
Max
Parameter
Units
Result
Result RPD
RPD
Qualifiers
Percent Moisture
%
13.0
12.3 6
10
SAMPLE DUPLICATE:
1203212
92247052006
Dup
Max
Parameter
Units
Result
Result RPD
RPD
Qualifiers
Percent Moisture
%
28.0
27.5 2
10
SAMPLE DUPLICATE:
1203213
92247091008
Dup
Max
Parameter
Units
Result
Result RPD
RPD
Qualifiers
Percent Moisture
%
11.1
12.3 11
10 D6
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 %gigyqll�e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040620
Pace Project No.: 92247080
QC Batch: WET/37104 Analysis Method: EPA 9045
QC Batch Method: EPA 9045 Analysis Description: 9045 pH
Associated Lab Samples: 92247080001,92247080002,92247080003,92247080004,92247080005,92247080006,92247080007
SAMPLE DUPLICATE: 1444898
92247091009 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
pH at 25 Degrees C Std. Units 8.4 8.4 0 10 H3
SAMPLE DUPLICATE: 1444899
92247068003 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
pH at 25 Degrees C Std. Units 6.4 6.4 0 10 H3
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
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aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040620
Pace Project No.: 92247080
QC Batch: WETA/22837
Analysis Method: EPA 300.0
QC Batch Method: EPA 300.0
Analysis Description: 300.0 IC Anions
Associated Lab Samples: 92247080002, 92247080003,
92247080004, 92247080005
METHOD BLANK: 1452663
Matrix: Water
Associated Lab Samples: 92247080002, 92247080003,
92247080004, 92247080005
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Sulfate mg/L
4.0 2.0
05/07/1511:13
LABORATORY CONTROL SAMPLE: 1452664
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Sulfate mg/L
20 20.0
100 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1452665 1452666
MS MSD
92247080002
Spike Spike MS
MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec Limits RPD RPD Qual
Sulfate mg/L 11.4
22.5 22.5 34.3
34.4 102 102 0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Page 63 of 79

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040620
Pace Project No.: 92247080
QC Batch: WETA/22905
Analysis Method: EPA 353.2
QC Batch Method: EPA 353.2
Analysis Description: 353.2 Nitrate + Nitrite, Unpres.
Associated Lab Samples: 92247080002, 92247080003,
92247080004, 92247080005
METHOD BLANK: 1457411
Matrix: Water
Associated Lab Samples: 92247080002, 92247080003,
92247080004, 92247080005
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Nitrogen, Nitrate mg/L
0.16 0.020
05/13/15 13:14 Z2
LABORATORY CONTROL SAMPLE: 1457412
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Nitrogen, Nitrate mg/L
2.5 2.5
101 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1457413 1457414
MS MSD
92247080002
Spike Spike MS
MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec Limits RPD RPD Qual
Nitrogen, Nitrate mg/L 0.23
2.8 2.8 3.1
3.1 103 103 90-110 1 10 H1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1457545 1457546
MS MSD
92247233008 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Nitrogen, Nitrate mg/L 0.24 3 3 3.3 3.3 103 104 90-110 0 10 H1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 05/20/2015 08:27 AM without the written consent of Pace Analytical Services, Inc..
Page 64 of 79

aceAnaiXical
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Pace Analytical Services, Inc.
9800 Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040620
Pace Project No.: 92247080
QC Batch: WETA/22862
Analysis Method: SM 4500-CI-E
QC Batch Method: SM 4500-CI-E
Analysis Description: 4500 Chloride
Associated Lab Samples: 92247080002, 92247080003,
92247080004, 92247080005
METHOD BLANK: 1454397
Matrix: Water
Associated Lab Samples: 92247080002, 92247080003,
92247080004, 92247080005
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Chloride mg/L
ND 1.0
05/09/15 03:31
LABORATORY CONTROL SAMPLE: 1454398
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Chloride mg/L
20 20.2
101 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1454399 1454400
MS MSD
92245627014
Spike Spike MS
MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec Limits RPD RPD Qual
Chloride mg/L ND
27.5 27.5 29.0
28.7 103 103 90-110 1 10
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1454401 1454402
MS MSD
92247233008 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Chloride mg/L ND 23.9 23.9 24.8 24.6 101 100 90-110 1 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 05/20/2015 08:27 AM without the written consent of Pace Analytical Services, Inc..
Page 65 of 79

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 %c&yqll�e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040620
Pace Project No.: 92247080
QC Batch: WETA/45962 Analysis Method: EPA 9056
QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions
Associated Lab Samples: 92247080001, 92247080004
METHOD BLANK: 1199898 Matrix: Solid
Associated Lab Samples:
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Chloride mg/kg ND 49.8 04/30/1515:47
Sulfate mg/kg 117 49.8 04/30/1515:47
LABORATORY CONTROL SAMPLE:
1199899
Parameter
Units
Chloride
mg/kg
Sulfate
mg/kg
MATRIX SPIKE SAMPLE:
1199901
Parameter
Units
Chloride
mg/kg
Sulfate
mg/kg
SAMPLE DUPLICATE: 1199900
Parameter
Chloride
Sulfate
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
500 467 93 80-120
500 470 94 80-120
92247052001 Spike MS MS % Rec
Result Conc. Result % Rec Limits Qualifiers
ND 685 592 69 80-120 M 1
ND 685 611 89 80-120
92247052001 Dup
Units Result Result
mg/kg ND ND
mg/kg ND ND
Max
RPD RPD Qualifiers
20
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 05/20/2015 08:27 AM without the written consent of Pace Analytical Services, Inc.. Page 66 of 79

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 %gigyqll�e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040620
Pace Project No.: 92247080
QC Batch: WETA/45964 Analysis Method: EPA 9056
QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions
Associated Lab Samples: 92247080005, 92247080006, 92247080007
METHOD BLANK: 1199913 Matrix: Solid
Associated Lab Samples:
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Chloride mg/kg ND 50.6 05/01/15 01:47
Sulfate mg/kg ND 50.6 05/01/15 01:47
LABORATORY CONTROL SAMPLE:
1199914
Parameter
Units
Chloride
mg/kg
Sulfate
mg/kg
MATRIX SPIKE SAMPLE:
1199916
Parameter
Units
Chloride
mg/kg
Sulfate
mg/kg
SAMPLE DUPLICATE: 1199915
Parameter
Chloride
Sulfate
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
495 471 95 80-120
495 468 95 80-120
92247080005 Spike MS MS % Rec
Result Conc. Result % Rec Limits Qualifiers
ND 593 519 70 80-120 M 1
ND 593 543 92 80-120
92247080005 Dup
Units Result Result
mg/kg ND ND
mg/kg ND ND
Max
RPD RPD Qualifiers
20
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 %gigyqll�e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040620
Pace Project No.: 92247080
QC Batch: WETA/46023 Analysis Method: EPA 9056
QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions
Associated Lab Samples: 92247080002, 92247080003
METHOD BLANK: 1202084 Matrix: Solid
Associated Lab Samples:
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Chloride mg/kg ND 49.7 05/03/15 05:05
Sulfate mg/kg ND 49.7 05/03/15 05:05
LABORATORY CONTROL SAMPLE:
1202085
Parameter
Units
Chloride
mg/kg
Sulfate
mg/kg
MATRIX SPIKE SAMPLE:
1202087
Parameter
Units
Chloride
mg/kg
Sulfate
mg/kg
SAMPLE DUPLICATE: 1202086
Parameter
Chloride
Sulfate
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
499 506 101 80-120
499 502 101 80-120
92247383007 Spike MS MS % Rec
Result Conc. Result % Rec Limits Qualifiers
ND 496 469 77 80-120 M 1
ND 496 493 99 80-120
92247383007 Dup
Units Result Result
mg/kg ND ND
mg/kg ND ND
Max
RPD RPD Qualifiers
20
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 05/20/2015 08:27 AM without the written consent of Pace Analytical Services, Inc.. Page 68 of 79

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 1�nlc&fie. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040620
Pace Project No.: 92247080
QC Batch: WETA/45963
Analysis Method:
EPA 9056
QC Batch Method: EPA 9056
Analysis Description:
9056 IC Anions
Associated Lab Samples: 92247080001, 92247080002, 92247080003, 92247080004
METHOD BLANK: 1199903
Matrix: Solid
Associated Lab Samples:
Blank Reporting
Parameter
Units
Result Limit
Analyzed
Qualifiers
Nitrate as N
mg/kg
ND 5.0
04/30/15 15:47
LABORATORY CONTROL SAMPLE:
1199904
Spike LCS
LCS
% Rec
Parameter
Units
Conc. Result
% Rec
Limits
Qualifiers
Nitrate as N
mg/kg
50 47.9
96
80-120
MATRIX SPIKE SAMPLE:
1199906
92247052001 Spike
MS
MS
% Rec
Parameter
Units
Result Conc.
Result
% Rec
Limits Qualifiers
Nitrate as N
mg/kg
ND 68.5
61.0
87 80-120 H3
SAMPLE DUPLICATE: 1199905
92247052001 Dup
Max
Parameter
Units
Result Result
RPD
RPD
Qualifiers
Nitrate as N
mg/kg
ND ND
20 H3
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 05/20/2015 08:27 AM without the written consent of Pace Analytical Services, Inc.. Page 69 of 79

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040620
Pace Project No.: 92247080
QC Batch: WETA/45965
Analysis Method:
EPA 9056
QC Batch Method: EPA 9056
Analysis Description:
9056 IC Anions
Associated Lab Samples: 92247080005, 92247080006, 92247080007
METHOD BLANK: 1199920
Matrix: Solid
Associated Lab Samples:
Blank Reporting
Parameter
Units
Result Limit
Analyzed
Qualifiers
Nitrate as N
mg/kg
ND 5.1
05/01/15 01:47
LABORATORY CONTROL SAMPLE:
1199921
Spike LCS
LCS
% Rec
Parameter
Units
Conc. Result
% Rec
Limits
Qualifiers
Nitrate as N
mg/kg
49.5 48.4
98
80-120
MATRIX SPIKE SAMPLE:
1199923
92247080005 Spike
MS
MS
% Rec
Parameter
Units
Result Conc.
Result
% Rec
Limits Qualifiers
Nitrate as N
mg/kg
ND 59.3
52.4
88 80-120 H3
SAMPLE DUPLICATE: 1199922
92247080005 Dup
Max
Parameter
Units
Result Result
RPD
RPD
Qualifiers
Nitrate as N
mg/kg
ND ND
20 H3
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040620
Pace Project No.: 92247080
QC Batch: WETA/28457
Analysis Method: EPA 9060
QC Batch Method: EPA 9060
Analysis Description: 9060 TOC Average
Associated Lab Samples: 92247080001, 92247080002,
92247080003
METHOD BLANK: 1155940
Matrix: Solid
Associated Lab Samples:
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Mean Total Organic Carbon mg/kg
ND 600
05/14/15 07:20
LABORATORY CONTROL SAMPLE: 1155941
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Mean Total Organic Carbon mg/kg
120000 118000
98 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1155942 1155943
MS MSD
92247068001
Spike Spike MS
MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec Limits RPD RPD Qual
Mean Total Organic Carbon mg/kg ND
8580 8510 8380
7830 94 89 50-150 7 30
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1155944 1155945
MS MSD
92247080001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Mean Total Organic Carbon mg/kg 932 6990 6960 7150 7530 89 95 50-150 5 30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Page 71 of 79

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040620
Pace Project No.: 92247080
QC Batch: WETA/28520
Analysis Method: EPA 9060
QC Batch Method: EPA 9060
Analysis Description: 9060 TOC Average
Associated Lab Samples: 92247080004, 92247080005,
92247080006, 92247080007
METHOD BLANK: 1158740
Matrix: Solid
Associated Lab Samples:
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Mean Total Organic Carbon mg/kg
ND 600
05/18/15 08:42
LABORATORY CONTROL SAMPLE: 1158741
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Mean Total Organic Carbon mg/kg
120000 135000
112 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1158742 1158743
MS MSD
92247383002
Spike Spike MS
MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec Limits RPD RPD Qual
Mean Total Organic Carbon mg/kg 420J
6150 6150 6640
6780 101 103 50-150 2 30
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1158744 1158745
MS MSD
92247835007 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Mean Total Organic Carbon mg/kg 108000 73800 73100 162000 153000 73 62 50-150 6 30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 05/20/2015 08:27 AM without the written consent of Pace Analytical Services, Inc..
Page 72 of 79

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Suite 100
Huntersville, NC 28078
[phone]
QUALIFIERS
Project: J15040620
Pace Project No.: 92247080
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
LABORATORIES
PASI-A
Pace Analytical Services - Asheville
PASI-G
Pace Analytical Services - Green Bay
PASI-M
Pace Analytical Services - Minneapolis
PASI-O
Pace Analytical Services - Ormond Beach
BATCH QUALIFIERS
Batch: ICP/14625
Ill Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
ANALYTE QUALIFIERS
B Analyte was detected in the associated method blank.
CU The continuing calibration for this compound is outside of Pace Analytical acceptance limits. Analyte presence below
reporting limits in associated samples. Results unaffected by high bias.
D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
D6 The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits.
H1 Analysis conducted outside the EPA method holding time.
H3 Sample was received or analysis requested beyond the recognized method holding time.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
REPORT OF LABORATORY ANALYSIS
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aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Suite 100
Huntersville, INC 28078
[phone]
QUALIFIERS
Project: J15040620
Pace Project No.: 92247080
ANALYTE QUALIFIERS
N2 The lab does not hold TIN accreditation for this parameter.
R1 RPD value was outside control limits.
Z2 Analyte present in the associated method blank above the detection limit.
REPORT OF LABORATORY ANALYSIS
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acmnalytical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 I gcgfo'\ye. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
Pace Project No.:
J15040620
92247080
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical
Method
Batch
92247080001
2015012031
EPA 3050
MPRP/23928
EPA
6010
ICP/14625
92247080002
2015012032
EPA 3050
MPRP/23928
EPA
6010
ICP/14625
92247080003
2015012033
EPA 3050
MPRP/23928
EPA
6010
ICP/14625
92247080004
2015012035
EPA 3050
MPRP/23928
EPA
6010
ICP/14625
92247080005
2015012036
EPA 3050
MPRP/23928
EPA
6010
ICP/14625
92247080006
2015012037
EPA 3050
MPRP/23928
EPA
6010
ICP/14625
92247080007
2015012039
EPA 3050
MPRP/23928
EPA
6010
ICP/14625
92247080001
2015012031
EPA 3050
MPRP/23929
EPA
6020
ICPM/9721
92247080002
2015012032
EPA 3050
MPRP/23929
EPA
6020
ICPM/9721
92247080003
2015012033
EPA 3050
MPRP/23929
EPA
6020
ICPM/9721
92247080004
2015012035
EPA 3050
MPRP/23929
EPA
6020
ICPM/9721
92247080005
2015012036
EPA 3050
MPRP/23929
EPA
6020
ICPM/9721
92247080006
2015012037
EPA 3050
MPRP/23929
EPA
6020
ICPM/9721
92247080007
2015012039
EPA 3050
MPRP/23929
EPA
6020
ICPM/9721
92247080008
2015012034
EPA 3020
MPRP/53983
EPA
6020A
ICPM/24001
92247080009
2015012038
EPA 3020
MPRP/53983
EPA
6020A
ICPM/24001
92247080010
2015012032 SPLP
EPA 3020
MPRP/54376
EPA
6020A
ICPM/24274
92247080011
2015012033 SPLP
EPA 3020
MPRP/54376
EPA
6020A
ICPM/24274
92247080012
2015012035 SPLP
EPA 3020
MPRP/54376
EPA
6020A
ICPM/24274
92247080013
2015012036 SPLP
EPA 3020
MPRP/54376
EPA
6020A
ICPM/24274
92247080008
2015012034
EPA 7470A
MERP/13380
EPA
7470A
MERC/15555
92247080009
2015012038
EPA 7470A
MERP/13380
EPA
7470A
MERC/15555
92247080010
2015012032 SPLP
EPA 7470A
MERP/13538
EPA
7470A
MERC/15723
92247080011
2015012033 SPLP
EPA 7470A
MERP/13538
EPA
7470A
MERC/15723
92247080012
2015012035 SPLP
EPA 7470A
MERP/13538
EPA
7470A
MERC/15723
92247080013
2015012036 SPLP
EPA 7470A
MERP/13538
EPA
7470A
MERC/15723
92247080001
2015012031
EPA 7471
MERP/5669
EPA
7471
MERC/5659
92247080002
2015012032
EPA 7471
MERP/5669
EPA
7471
MERC/5659
92247080003
2015012033
EPA 7471
MERP/5669
EPA
7471
MERC/5659
92247080004
2015012035
EPA 7471
MERP/5669
EPA
7471
MERC/5659
92247080005
2015012036
EPA 7471
MERP/5669
EPA
7471
MERC/5659
92247080006
2015012037
EPA 7471
MERP/5669
EPA
7471
MERC/5659
92247080007
2015012039
EPA 7471
MERP/5669
EPA
7471
MERC/5659
92247080001
2015012031
ASTM D2974-87
PMST/3532
92247080002
2015012032
ASTM D2974-87
PMST/3532
92247080003
2015012033
ASTM D2974-87
PMST/3532
92247080004
2015012035
ASTM D2974-87
PMST/3532
92247080005
2015012036
ASTM D2974-87
PMST/3532
92247080006
2015012037
ASTM D2974-87
PMST/3532
92247080007
2015012039
ASTM D2974-87
PMST/3532
92247080001
2015012031
EPA 9045
WET/37104
92247080002
2015012032
EPA 9045
WET/37104
92247080003
2015012033
EPA 9045
WET/37104
92247080004
2015012035
EPA 9045
WET/37104
92247080005
2015012036
EPA 9045
WET/37104
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/20/2015 08:27 AM without the written consent of Pace Analytical Services, Inc.. Page 75 of 79

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 lglgc&yq"�e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: J15040620
Pace Project No.: 92247080
Lab ID Sample ID QC Batch Method QC Batch
92247080006
2015012037
EPA 9045
WET/37104
92247080007
2015012039
EPA 9045
WET/37104
92247080002
2015012032
EPA 300.0
WETA/22837
92247080003
2015012033
EPA 300.0
WETA/22837
92247080004
2015012035
EPA 300.0
WETA/22837
92247080005
2015012036
EPA 300.0
WETA/22837
92247080002
2015012032
EPA 353.2
WETA/22905
92247080003
2015012033
EPA 353.2
WETA/22905
92247080004
2015012035
EPA 353.2
WETA/22905
92247080005
2015012036
EPA 353.2
WETA/22905
92247080002
2015012032
SM 4500-CI-E
WETA/22862
92247080003
2015012033
SM 4500-CI-E
WETA/22862
92247080004
2015012035
SM 4500-CI-E
WETA/22862
92247080005
2015012036
SM 4500-CI-E
WETA/22862
92247080001
2015012031
EPA 9056
WETA/45962
92247080002
2015012032
EPA 9056
WETA/46023
92247080003
2015012033
EPA 9056
WETA/46023
92247080004
2015012035
EPA 9056
WETA/45962
92247080005
2015012036
EPA 9056
WETA/45964
92247080006
2015012037
EPA 9056
WETA/45964
92247080007
2015012039
EPA 9056
WETA/45964
92247080001
2015012031
EPA 9056
WETA/45963
92247080002
2015012032
EPA 9056
WETA/45963
92247080003
2015012033
EPA 9056
WETA/45963
92247080004
2015012035
EPA 9056
WETA/45963
92247080005
2015012036
EPA 9056
WETA/45965
92247080006
2015012037
EPA 9056
WETA/45965
92247080007
2015012039
EPA 9056
WETA/45965
92247080001
2015012031
EPA 9060
WETA/28457
92247080001
2015012031
EPA 9060
WETA/28458
92247080002
2015012032
EPA 9060
WETA/28457
92247080002
2015012032
EPA 9060
WETA/28458
92247080003
2015012033
EPA 9060
WETA/28457
92247080003
2015012033
EPA 9060
WETA/28458
92247080004
2015012035
EPA 9060
WETA/28520
92247080004
2015012035
EPA 9060
WETA/28521
92247080005
2015012036
EPA 9060
WETA/28520
92247080005
2015012036
EPA 9060
WETA/28521
92247080006
2015012037
EPA 9060
WETA/28520
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/20/2015 08:27 AM without the written consent of Pace Analytical Services, Inc..
Analytical
Analytical Method Batch
Page 76 of 79

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: J15040620
Pace Project No.: 92247080
Lab ID
Sample ID
QC Batch Method
QC Batch
92247080006
2015012037
EPA 9060
WETA/28521
92247080007
2015012039
EPA 9060
WETA/28520
92247080007
2015012039
EPA 9060
WETA/28521
Date: 05/20/2015 08:27 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Analytical Method
Analytical
Batch
Page 77 of 79

ceAmlytical. Sample Condition Upon Recei
Document Number:
F-CHR-CS-403-rev.15
rain I UI G
pace Huntersville
Office
92
ient Name: 0 ,A
Trier: ❑ Fed Ex ❑ UPS❑ LISPS❑ Client Vno
ommercial❑ Pace Other_
t d S I CoolerlBox Present: El ye - Seals intact: El Yes [
o y ea on
king Material: ❑ Bubble V[3 _ Bubble Bags ❑ None ElOther
�rmometer Used: IR Gun 14 Type of Ice: Qt Iue None
tip Correction Factor T1401 No Correction
rected Cooler Temp.: Q s ; •C Biological Tissue is Frozen: Yes ND
ip should be above freezing to 6°C Comments:
tin of Custody Present:
tin of Custody Filled Out:
tin of Custody Relinquished:
npler Name & Signature on COC:
npies Arrived within Hold Time:
srt Hold Time Analysis (a72hr):
sh Turn Around Time Requests
ficient Volume:
rrect Containers Used:
-Pace Containers Used:
Infant -
erect .volume received for
mple Labels match COC:
-includes dateltirnellDlAr
Qys PKo
❑NIA 1.
0 es No
❑NIA 2.
BY. PtCo
❑NIA 3.
CK es ❑ ie— ❑NIA 4.
G{ es ❑No
ON1A 5.
Oyes 0a
PNIA 6.
❑Yes ❑W-11,❑NIA
7.
❑ N/IA 8.
es ❑No
NIA 9.
Dyes ❑
❑NIA
es ❑No
❑NIA
tests ❑Yes �❑
A 11.
es ❑No
❑NIA 12.
been
containers needing preservation are found to be in
npliance with EPA recommendation.
W-DRO
❑'des ❑ NIA 13.
❑Yes ONO C3NI
[]Yes ❑C(O
on ice, cooling process has begun
,adspace in VOA Vials (>6mm): []Yes ONO ❑KIA .16.
ip Blank Present: ❑Yes ONO NIA 16.
ip Blank Custody Seals Present ❑Yes ONO NIA
ace Trip Blank Lot# (if purchased):
lient Notification! Resolution: Field Data Required? Y I N
Person Contacted: Daterrime:
Comments/ Resolution:
,CURF Review: Date: rd] ji5 WOE . 9224708®
SRF Review: Date: I aLd—IEj
Note: Whenever there is a discrepancy affecting North Carolina compliance
samples, a copy of this form will be sent to the North Carolina DEHNR
Certification Office (Le out of hold, incorrect preservative, out of temp, 92247080
incorrect containers) _
��
Page 78 of 79

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