NC0003433_J15040322 Report_20150902

+ DUKE Analytical Laboratory 1 of 122
ENERGY
Order Number:
Project Name:
Customer Name(s):
Customer Address:
Lab Contact:
Report Authorized By:
(Signature)
Program Comments:
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone:[phone] Fax:[phone]
Order Summary Report
J15040322
CAPE FEAR - AB GW ASSESSMENT SOIL
Tim Hunsucker, Chris Suttell, Kathy Webb, John Toepfer
Margaret Galvin -Karr Phone: [phone]
�DI"{C Vie® MXG4644(10161)
2015.06.1610:11:18-04'00- Date:
Margaret Galvin -Karr
Please contact the Program Manager (Margaret Galvin -Karr) with any questions regarding this report.
Data Flags & Calculations:
6/16/2015
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Sample ID's & Descriptions:
2 of 122
Sample ID
Plant/Station
Collection
Date and Time
Collected By
Sample Description
2015010703
Cape Fear
11-Apr-15 11:00 AM
Chris S.
Well ERB-16 (Sonic)
2015010705
Cape Fear
11-Apr-15 11:30 AM
Chris S.
Well ABMW-4AB (1-2)
2015010706
Cape Fear
11-Apr-15 11:30 AM
Chris S.
Well Soil Dup-02
2015010707
Cape Fear
11-Apr-15 3:05 PM
Chris S.
Well ABMW-4AB (21-22)
2015010708
Cape Fear
11-Apr-15 3:35 PM
Chris S.
Well ABMW-4SB (28-30)
2015010709
Cape Fear
13-Apr-15 1:25 PM
Chris S.
Well ABMW-4SB (42.5-44.5)
2015010710
Cape Fear
13-Apr-15 3:45 PM
Chris S.
Well ERB-17 (Sonic)
2015010711
Cape Fear
13-Apr-15 5:15 PM
Chris S.
Well ABB-6SB (47-48)
2015010712
Cape Fear
13-Apr-15 4:00 PM
Chris S.
Well ABB-6AB (3-5)
2015010713
Cape Fear
13-Apr-15 5:00 PM
Chris S.
Well ABB-6AB (14-15)
2015010714
Cape Fear
13-Apr-15 5:30 PM
Chris S.
Well ABB-6AB (40-44)
2015010715
Cape Fear
14-Apr-15 3:45 PM
Chris S.
Well ABMW-3AB (19-20)
2015010716
Cape Fear
14-Apr-15 3:55 PM
Chris S.
Well ABMW-3SB (25-26)
2015010717
Cape Fear
14-Apr-15 4:00 PM
Chris S.
Well Soil Dup-03
2015010718
Cape Fear
14-Apr-15 2:00 PM
Well ERB-18 (Sonic)
15 Total Samples

Cni SM
Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals Yes No
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits. ❑ Yes❑ No
All laboratory QA/QC requirements are acceptable.❑ Yes ❑ No
Report Sections Included:
U Job Summary Report
❑ Sample Identification
n Technical Validation of Data Package
❑ Analytical Laboratory Certificate of Analysis
❑ Analytical Laboratory QC Report
Reviewed By: Date:
Sub -contracted Laboratory Results
❑ Customer Specific Data Sheets, Reports, & Documentation
❑ Customer Database Entries
0 Chain of Custody
[I/0] Electronic Data Deliverable (EDD) Sent Separately

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15040322
Site: Well ERB-16 (Sonic)
Collection Date: 11-Apr-15 11:00 AM
Analyte Result Units Qualifiers RDL DF
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Sample #: 2015010703
Matrix: SOIL
4 of 122
Method Analysis Date/Time Analyst
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15040322
Site: Well ABMW-4AB (1-2)
Collection Date: 11-Apr-15 11:30 AM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
5 of 122
Sample #: 2015010705
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15040322
Site: Well Soil Dup-02
Collection Date: 11-Apr-15 11:30 AM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
6 of 122
Sample #: 2015010706
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15040322
Site: Well ABMW-4AB (21-22)
Collection Date: 11-Apr-15 3:05 PM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
SPLP LEACHATE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
7 of 122
Sample #: 2015010707
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15040322
Site: Well ABMW-4SB (28-30)
Collection Date: 11-Apr-15 3:35 PM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
SPLP LEACHATE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
8 of 122
Sample #: 2015010708
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15040322
Site: Well ABMW-4SB (42.5-44.5)
Collection Date: 13-Apr-15 1:25 PM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
SPLP LEACHATE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
9 of 122
Sample #: 2015010709
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis 10 of 122
This report shall not be reproduced, except in full.
Order # J15040322
Site: Well ERB-17 (Sonic)
Collection Date: 13-Apr-15 3:45 PM
Analyte Result Units Qualifiers RDL DF
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Sample #: 2015010710
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15040322
Site: Well ABB-6SB (47-48)
Collection Date: 13-Apr-15 5:15 PM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
11 of 122
Sample #: 2015010711
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15040322
Site: Well ABB-6AB (3-5)
Collection Date: 13-Apr-15 4:00 PM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
`e�4 EPA
Sample #: 2015010712
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15040322
Site: Well ABB-6AB (14-15)
Collection Date: 13-Apr-15 5:00 PM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
SPLP LEACHATE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
13 of 122
Sample #: 2015010713
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15040322
Site: Well ABB-6AB (40-44)
Collection Date: 13-Apr-15 5:30 PM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
1EHI4 EPA
Sample #: 2015010714
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15040322
Site: Well ABMW-3AB (19-20)
Collection Date: 14-Apr-15 3:45 PM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
SPLP LEACHATE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
15 of 122
Sample #: 2015010715
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15040322
Site: Well ABMW-3SB (25-26)
Collection Date: 14-Apr-15 3:55 PM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
SPLP LEACHATE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
16 of 122
Sample #: 2015010716
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15040322
Site: Well Soil Dup-03
Collection Date: 14-Apr-15 4:00 PM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
17 of 122
Sample #: 2015010717
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Site: Well ERB-18 (Sonic)
Collection Date: 14-Apr-15 2:00 PM
Certificate of Laboratory Analysis 18 of 122
This report shall not be reproduced, except in full.
Order # J15040322
Sample #: 2015010718
Matrix: SOIL
Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
-- Additional Information --
%RSD for TOC on sample 2015010714 greater than limit of 40% (actual RSD is 51/5). SPLP Mercury for sample
2015010715 ws analyzed out of hold time. M. Galvin -Karr 6/15/2015

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980019r6fy2b�e. Suite 100
Huntersville, INC 28078
[phone]
June 15, 2015
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg.7405 MG30A2
Huntersville, NC 28078
RE: Project: J 15040322
Pace Project No.: 92245627
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on April 15, 2015. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TN standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc: Marge Galvin -Karr, Duke Energy
Program Manager, Duke Energy
Mary Ann Ogle, Duke Energy
Rodney Wilke, Duke Energy
p«FO
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
y without the written consent of Pace Analytical Services, Inc.. Page 1 of 103

lacmnalyfica(
www.pacelabs.com
Pace Analytical Services, Inc.
980C�i Y,92e. Suite 100
Huntersville, NC 28078
[phone]
Project: J15040322
Pace Project No.: 92245627
Minnesota Certification IDs
1700 Elm Street SE Suite 200, Minneapolis, MN 55414
A21-A Certification #: 2926.01
Alaska Certification #: UST-078
Alaska Certification #MN00064
Alabama Certification #40770
Arizona Certification #: AZ-0014
Arkansas Certification #: 88-0680
California Certification #: 01155CA
Colorado Certification #Pace
Connecticut Certification #: PH-0256
EPA Region 8 Certification #: 8TMS-L
Florida/NELAP Certification #: E87605
Guam Certification #:14-008r
Georgia Certification #: 959
Georgia EPD #: Pace
Idaho Certification #: MN00064
Hawaii Certification #MN00064
Illinois Certification #: 200011
Indiana Certification#C-MN-01
Iowa Certification #: 368
Kansas Certification #: E-10167
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Kentucky Dept of Envi. Protection - WW #:90062
Louisiana DEQ Certification #: 3086
Louisiana DHH #: LA140001
Maine Certification #: 2013011
Maryland Certification #: 322
Michigan DEPH Certification #: 9909
Ormond Beach Certification IDs
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Alabama Certification #: 41320
Connecticut Certification #: PH-0216
Delaware Certification: FL NELAC Reciprocity
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Green Bay Certification IDs
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Illinois Certification #: 200050
Kentucky Certification #: 82
Louisiana Certification #: 04168
Minnesota Certification #: 055-999-334
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
CERTIFICATIONS
Minnesota Certification #: 027-053-137
Mississippi Certification #: Pace
Montana Certification #: MT0092
Nevada Certification #: MN_00064
Nebraska Certification #: Pace
New Jersey Certification #: MN-002
New York Certification #: 11647
North Carolina Certification #: 530
North Carolina State Public Health #: 27700
North Dakota Certification #: R-036
Ohio EPA#: 4150
Ohio VAP Certification #: CL101
Oklahoma Certification #: 9507
Oregon Certification #: MN200001
Oregon Certification #: MN300001
Pennsylvania Certification #: 68-00563
Puerto Rico Certification
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Wisconsin Certification #: 999407970
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Pennsylvania Certification #: 68-00547
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South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
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Virginia Environmental Certification #: 460165
Washington Certification #: C955
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Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
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Wisconsin Certification #: 405132750
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 2 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800AWM2"� e. Suite 100
Huntersville, NC 28078
[phone]
Project: J15040322
Pace Project No.: 92245627
Asheville Certification IDs
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
CERTIFICATIONS
West Virginia Certification #: 356
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 3 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800�9rWY2"�e. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE SUMMARY
Project: J15040322
Pace Project No.: 92245627
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92245627001
2015010703
Water
04/11/1511:00
04/15/15 15:30
92245627003
2015010705
Solid
04/11/1511:30
04/15/15 15:30
92245627004
2015010706
Solid
04/11/1511:30
04/15/15 15:30
92245627005
2015010707
Solid
04/11/1515:05
04/15/15 15:30
92245627006
2015010708
Solid
04/11/1515:35
04/15/15 15:30
92245627007
2015010709
Solid
04/13/1513:25
04/15/15 15:30
92245627008
2015010710
Water
04/13/1515:45
04/15/15 15:30
92245627009
2015010711
Solid
04/13/1517:15
04/15/15 15:30
92245627010
2015010712
Solid
04/13/1516:00
04/15/15 15:30
92245627011
2015010713
Solid
04/13/1517:00
04/15/15 15:30
92245627012
2015010714
Solid
04/13/1517:30
04/15/15 15:30
92245627013
2015010715
Solid
04/14/1515:45
04/15/15 15:30
92245627014
2015010716
Solid
04/14/1515:55
04/15/15 15:30
92245627015
2015010717
Solid
04/14/1516:00
04/15/15 15:30
92245627016
2015010707 SPLP
Water
04/11/15 15:05
04/15/15 15:30
92245627017
2015010708 SPLP
Water
04/11/15 15:35
04/15/15 15:30
92245627018
2015010709 SPLP
Water
04/13/15 13:25
04/15/15 15:30
92245627019
2015010712 SPLP
Water
04/13/15 16:00
04/15/15 15:30
92245627021
2015010715 SPLP
Water
04/14/15 15:45
04/15/15 15:30
92245627022
2015010718
Water
04/14/1514:00
04/15/1517:00
92245627023
2015010716 SPLP
Water
04/14/15 15:55
04/15/15 15:30
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc.. Page 4 of 103

aceAnaiXical
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Pace Analytical Services, Inc.
9800�SrWY2"�e. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
J15040322
92245627
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92245627001
2015010703
EPA 6020A
RJS
24
PASI-M
EPA 7470
JDD
1
PASI-M
92245627003
2015010705
EPA 6010
CKJ
16
PASI-0
EPA 6020
DRS
8
PASI-O
EPA 7471
TAP
1
PASI-O
ASTM D2974-87
MLO
1
PASI-O
EPA 9045
MLS
1
PASI-A
EPA 9056
AIS
2
PASI-O
EPA 9056
AIS
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92245627004
2015010706
EPA 6010
CKJ
16
PASI-0
EPA 6020
DRS
8
PASI-O
EPA 7471
TAP
1
PASI-O
ASTM D2974-87
MLO
1
PASI-O
EPA 9045
MLS
1
PASI-A
EPA 9056
AIS
2
PASI-O
EPA 9056
AIS
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92245627005
2015010707
EPA 6010
CKJ
16
PASI-0
EPA 6020
DRS
8
PASI-O
EPA 7471
TAP
1
PASI-O
ASTM D2974-87
MLO
1
PASI-O
EPA 9045
MLS
1
PASI-A
EPA 300.0
AES2
1
PASI-A
EPA 353.2
DMN
1
PASI-A
SM 4500-CI-E
SER
1
PASI-A
EPA 9056
AIS
2
PASI-O
EPA 9056
AIS
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92245627006
2015010708
EPA 6010
CKJ
16
PASI-0
EPA 6020
DRS
8
PASI-O
EPA 7471
TAP
1
PASI-O
ASTM D2974-87
MLO
1
PASI-O
EPA 9045
MLS
1
PASI-A
EPA 300.0
AES2
1
PASI-A
EPA 353.2
DMN
1
PASI-A
SM 4500-CI-E
SER
1
PASI-A
REPORT OF LABORATORY ANALYSIS
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aceAnaiXical
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Pace Analytical Services, Inc.
9800AirWY2"�e. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
J15040322
92245627
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
EPA 9056
AIS
2
PASI-O
EPA 9056
AIS
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92245627007
2015010709
EPA 6010
CKJ
16
PASI-0
EPA 6020
DRS
8
PASI-O
EPA 7471
TAP
1
PASI-O
ASTM D2974-87
MLO
1
PASI-O
EPA 9045
MLS
1
PASI-A
EPA 300.0
AES2
1
PASI-A
EPA 353.2
DMN
1
PASI-A
SM 4500-CI-E
SER
1
PASI-A
EPA 9056
AIS
2
PASI-O
EPA 9056
AIS
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92245627008
2015010710
EPA 6020A
RJS
24
PASI-M
EPA 7470
JDD
1
PASI-M
92245627009
2015010711
EPA 6010
CKJ
16
PASI-0
EPA 6020
DRS
8
PASI-O
EPA 7471
TAP
1
PASI-O
ASTM D2974-87
MLO
1
PASI-O
EPA 9045
TEP
1
PASI-A
EPA 9056
AIS
2
PASI-O
EPA 9056
AIS
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92245627010
2015010712
EPA 6010
CKJ
16
PASI-0
EPA 6020
DRS
8
PASI-O
EPA 7471
TAP
1
PASI-O
ASTM D2974-87
MLO
1
PASI-O
EPA 9045
TEP
1
PASI-A
EPA 300.0
AES2
1
PASI-A
EPA 353.2
DMN
1
PASI-A
SM 4500-CI-E
SER
1
PASI-A
EPA 9056
AIS
2
PASI-O
EPA 9056
AIS
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92245627011
2015010713
EPA 6010
CKJ
16
PASI-0
EPA 6020
DRS
8
PASI-O
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc.. Page 6 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800AirWY2"�e. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
J15040322
92245627
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
EPA 7471
TAP
1
PASI-O
ASTM D2974-87
MLO
1
PASI-O
EPA 9045
TEP
1
PASI-A
EPA 9056
AIS
2
PASI-O
EPA 9056
AIS
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92245627012
2015010714
EPA 6010
CKJ
16
PASI-0
EPA 6020
DRS
8
PASI-O
EPA 7471
TAP
1
PASI-O
ASTM D2974-87
MLO
1
PASI-O
EPA 9045
TEP
1
PASI-A
EPA 9056
AIS
2
PASI-O
EPA 9056
AIS
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92245627013
2015010715
EPA 6010
CKJ
16
PASI-0
EPA 6020
DRS
8
PASI-O
EPA 7471
TAP
1
PASI-O
ASTM D2974-87
MLO
1
PASI-O
EPA 9045
TEP
1
PASI-A
EPA 300.0
AES2
1
PASI-A
EPA 353.2
DMN
1
PASI-A
SM 4500-CI-E
SER
1
PASI-A
EPA 9056
AIS
2
PASI-O
EPA 9056
AIS
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92245627014
2015010716
EPA 6010
CKJ
16
PASI-0
EPA 6020
DRS
8
PASI-O
EPA 7471
TAP
1
PASI-O
ASTM D2974-87
MLO
1
PASI-O
EPA 9045
TEP
1
PASI-A
EPA 300.0
AES2
1
PASI-A
EPA 353.2
DMN
1
PASI-A
SM 4500-CI-E
SER
1
PASI-A
EPA 9056
AIS
2
PASI-O
EPA 9056
AIS
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92245627015
2015010717
EPA 6010
CKJ
16
PASI-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 7 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 WY2"Y e. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project: J15040322
Pace Project No.: 92245627
Lab ID
Sample ID
Method
Analysts
Analytes
Reported
Laboratory
EPA 6020
DRS
8
PASI-O
EPA 7471
TAP
1
PASI-O
ASTM D2974-87
MLO
1
PASI-O
EPA 9045
TEP
1
PASI-A
EPA 9056
AIS
2
PASI-O
EPA 9056
AIS
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92245627016
2015010707 SPLP
EPA 6020A
TT3
24
PASI-M
EPA 7470A
JDD
1
PASI-M
92245627017
2015010708 SPLP
EPA 6020A
TT3
24
PASI-M
EPA 7470A
JDD
1
PASI-M
92245627018
2015010709 SPLP
EPA 6020A
TT3
24
PASI-M
EPA 7470A
JDD
1
PASI-M
92245627019
2015010712 SPLP
EPA 6020A
TT3
24
PASI-M
EPA 7470A
JDD
1
PASI-M
92245627021
2015010715 SPLP
EPA 6020A
TT3
24
PASI-M
EPA 7470A
JDD
1
PASI-M
92245627022
2015010718
EPA 6020A
RJS
24
PASI-M
EPA 7470
JDD
1
PASI-M
92245627023
2015010716 SPLP
EPA 6020A
TT3
24
PASI-M
EPA 7470A
JDD
1
PASI-M
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc.. Page 8 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800�9rWY2"�e. Suite 100
Huntersville, NC 28078
[phone]
Project: J15040322
Pace Project No.: 92245627
Lab Sample ID Client Sample ID
Method Parameters
SUMMARY OF DETECTION
Result Units Report Limit Analyzed
92245627001
2015010703
EPA 6020A
Aluminum
1140
ug/L
10.0
04/21/15 04:58
EPA 6020A
Arsenic
0.21J
ug/L
0.50
04/21/15 04:58
EPA 6020A
Barium
9.3
ug/L
0.30
04/21/15 04:58
EPA 6020A
Calcium
456
ug/L
40.0
04/23/15 01:00
EPA 6020A
Chromium
0.84
ug/L
0.50
04/21/15 04:58
EPA 6020A
Cobalt
1.2
ug/L
0.50
04/21/15 04:58
EPA 6020A
Copper
0.66J
ug/L
1.0
04/21/15 04:58
EPA 6020A
Iron
806
ug/L
50.0
04/21/15 04:58
EPA 6020A
Lead
0.59
ug/L
0.10
04/21/15 04:58
EPA 6020A
Magnesium
248
ug/L
10.0
04/21/15 04:58
EPA 6020A
Manganese
40.9
ug/L
0.50
04/21/15 04:58
EPA 6020A
Molybdenum
0.40J
ug/L
0.50
04/21/15 04:58
EPA 6020A
Nickel
0.57
ug/L
0.50
04/21/15 04:58
EPA 6020A
Potassium
395
ug/L
50.0
04/21/15 04:58
EPA 6020A
Sodium
219
ug/L
50.0
04/21/15 04:58
EPA 6020A
Strontium
2.3
ug/L
0.50
04/21/15 04:58
EPA 6020A
Vanadium
1.2
ug/L
1.0
04/21/15 04:58
EPA 6020A
Zinc
6.1
ug/L
5.0
04/21/15 04:58
92245627003
2015010705
EPA 6010
Aluminum
5200
mg/kg
42.2
04/25/15 23:01
EPA 6010
Barium
482
mg/kg
4.2
04/25/15 23:01
EPA 6010
Beryllium
1.1
mg/kg
0.42
04/25/15 23:01
EPA 6010
Calcium
1390
mg/kg
211
04/25/15 23:01
EPA 6010
Chromium
10.5
mg/kg
2.1
04/25/15 23:01
EPA 6010
Copper
19.3
mg/kg
2.1
04/25/15 23:01
EPA 6010
Iron
20500
mg/kg
16.9
04/25/15 23:01
EPA 6010
Magnesium
447
mg/kg
211
04/25/15 23:01
EPA 6010
Manganese
56.2
mg/kg
2.1
04/25/15 23:01
EPA 6010
Nickel
13.0
mg/kg
2.1
04/25/15 23:01
EPA 6010
Potassium
853
mg/kg
422
04/25/15 23:01
EPA 6010
Strontium
97.4
mg/kg
4.2
04/25/15 23:01
EPA 6010
Zinc
9.7
mg/kg
8.4
04/25/15 23:01
EPA 6020
Arsenic
21.8
mg/kg
8.4
04/26/15 10:36
EPA 6020
Cadmium
0.591
mg/kg
1.0
04/26/15 10:36
EPA 6020
Cobalt
6.9J
mg/kg
8.4
04/26/15 10:36
EPA 6020
Selenium
6.9J
mg/kg
8.4
04/26/15 10:36
EPA 6020
Vanadium
20.4
mg/kg
8.4
04/26/15 10:36
EPA 7471
Mercury
0.093
mg/kg
0.014
04/22/15 12:59
ASTM D2974-87
Percent Moisture
42.3
%
0.10
04/23/15 13:16
EPA 9045
pH at 25 Degrees C
5.4
Std. Units
0.10
04/20/15 21:25
EPA 9060
Total Organic Carbon
95600
mg/kg
9050
05/06/15 14:11
EPA 9060
Total Organic Carbon
104000
mg/kg
8900
05/06/15 14:17
EPA 9060
Total Organic Carbon
118000
mg/kg
8840
05/06/15 14:26
EPA 9060
Total Organic Carbon
98800
mg/kg
9260
05/06/15 14:33
EPA 9060
Mean Total Organic Carbon
104000
mg/kg
9010
05/06/15 14:11
EPA 9060
RSD%
9.6
%
05/06/15 14:11
REPORT OF LABORATORY ANALYSIS
M1
M1
M1
M1
I
M1
M1
M6
M6
M6
M6
M6
Qualifiers
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 9 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980GAWfYl�e. Suite 100
Huntersville, NC 28078
[phone]
Project: J15040322
Pace Project No.: 92245627
Lab Sample ID Client Sample ID
Method Parameters
SUMMARY OF DETECTION
Result Units Report Limit Analyzed
92245627004
2015010706
EPA 6010
Aluminum
6260
mg/kg
30.3
04/25/15 23:26
EPA 6010
Barium
389
mg/kg
3.0
04/25/15 23:26
EPA 6010
Beryllium
1.4
mg/kg
0.30
04/25/15 23:26
EPA 6010
Calcium
1710
mg/kg
151
04/25/15 23:26
EPA 6010
Chromium
11.5
mg/kg
1.5
04/25/15 23:26
EPA 6010
Copper
25.7
mg/kg
1.5
04/25/15 23:26
EPA 6010
Iron
16800
mg/kg
12.1
04/25/15 23:26
EPA 6010
Magnesium
523
mg/kg
151
04/25/15 23:26
EPA 6010
Manganese
55.7
mg/kg
1.5
04/25/15 23:26
EPA 6010
Molybdenum
1.8J
mg/kg
3.0
04/25/15 23:26
EPA 6010
Nickel
16.1
mg/kg
7.6
04/25/15 23:30 D3
EPA 6010
Potassium
1030
mg/kg
303
04/25/15 23:26
EPA 6010
Strontium
135
mg/kg
3.0
04/25/15 23:26
EPA 6010
Zinc
14.5
mg/kg
6.1
04/25/15 23:26
EPA 6020
Arsenic
30.4
mg/kg
6.1
04/26/15 10:50
EPA 6020
Cobalt
6.5
mg/kg
6.1
04/26/15 10:50
EPA 6020
Lead
5.5J
mg/kg
6.1
04/26/15 10:50
EPA 6020
Selenium
7.1
mg/kg
6.1
04/26/15 10:50
EPA 6020
Vanadium
25.8
mg/kg
6.1
04/26/15 10:50
EPA 7471
Mercury
0.13
mg/kg
0.010
04/22/15 13:03
ASTM D2974-87
Percent Moisture
19.0
%
0.10
04/23/15 13:16
EPA 9045
pH at 25 Degrees C
6.6
Std. Units
0.10
04/20/15 21:25
EPA 9060
Total Organic Carbon
91300
mg/kg
6420
05/06/15 15:32
EPA 9060
Total Organic Carbon
84700
mg/kg
6430
05/06/15 15:39
EPA 9060
Total Organic Carbon
85100
mg/kg
6210
05/06/15 15:46
EPA 9060
Total Organic Carbon
70700
mg/kg
6530
05/06/15 15:52
EPA 9060
Mean Total Organic Carbon
82900
mg/kg
6390
05/06/15 15:32
EPA 9060
RSD%
10.5
%
05/06/15 15:32
92245627005
2015010707
EPA 6010
Aluminum
10700
mg/kg
34.8
04/25/15 23:38
EPA 6010
Barium
603
mg/kg
3.5
04/25/15 23:38
EPA 6010
Beryllium
3.4
mg/kg
0.35
04/25/15 23:38
EPA 6010
Boron
10.1 J
mg/kg
17.4
04/25/15 23:38
EPA 6010
Calcium
3830
mg/kg
174
04/25/15 23:38
EPA 6010
Chromium
18.8
mg/kg
1.7
04/25/15 23:38
EPA 6010
Copper
34.2
mg/kg
1.7
04/25/15 23:38
EPA 6010
Iron
19100
mg/kg
13.9
04/25/15 23:38
EPA 6010
Magnesium
991
mg/kg
174
04/25/15 23:38
EPA 6010
Manganese
93.5
mg/kg
1.7
04/25/15 23:38
EPA 6010
Nickel
17.8
mg/kg
1.7
04/25/15 23:38
EPA 6010
Potassium
1990
mg/kg
348
04/25/15 23:38
EPA 6010
Sodium
352
mg/kg
348
04/25/15 23:38
EPA 6010
Strontium
251
mg/kg
3.5
04/25/15 23:38
EPA 6010
Zinc
15.1
mg/kg
7.0
04/25/15 23:38
EPA 6020
Arsenic
44.0
mg/kg
7.0
04/26/15 10:54
EPA 6020
Cobalt
9.5
mg/kg
7.0
04/26/15 10:54
EPA 6020
Lead
11.5
mg/kg
7.0
04/26/15 10:54
REPORT OF LABORATORY ANALYSIS
Qualifiers
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 10 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 WY2"Y e. Suite 100
Huntersville, NC 28078
[phone]
SUMMARY OF DETECTION
Project:
Pace Project No.:
J15040322
92245627
Lab Sample ID
Client Sample ID
Method
Parameters
Result
Units
Report Limit
Analyzed Qualifiers
92245627005
2015010707
EPA 6020
Selenium
8.8
mg/kg
7.0
04/26/15 10:54
EPA 6020
Vanadium
40.5
mg/kg
7.0
04/26/15 10:54
EPA 7471
Mercury
0.10
mg/kg
0.011
04/22/15 13:05
ASTM D2974-87
Percent Moisture
26.9
%
0.10
04/23/15 13:16
EPA 9045
pH at 25 Degrees C
7.5
Std. Units
0.10
04/20/15 21:25
EPA 300.0
Sulfate
12.6
mg/L
2.7
04/29/15 15:03 B
EPA 9056
Sulfate
209J
mg/kg
343
04/19/15 09:59 D3
EPA 9060
Total Organic Carbon
50200
mg/kg
3970
05/06/15 16:55
EPA 9060
Total Organic Carbon
72500
mg/kg
3990
05/06/15 17:02
EPA 9060
Total Organic Carbon
51200
mg/kg
3920
05/06/15 17:09
EPA 9060
Total Organic Carbon
71200
mg/kg
3940
05/06/15 17:15
EPA 9060
Mean Total Organic Carbon
61300
mg/kg
3950
05/06/15 16:55
EPA 9060
RSD%
20.0
%
05/06/15 16:55
92245627006
2015010708
EPA 6010
Aluminum
18200
mg/kg
33.6
04/25/15 23:42
EPA 6010
Barium
178
mg/kg
3.4
04/25/15 23:42
EPA 6010
Beryllium
0.89
mg/kg
0.34
04/25/15 23:42
EPA 6010
Calcium
1970
mg/kg
168
04/25/15 23:42
EPA 6010
Chromium
23.3
mg/kg
1.7
04/25/15 23:42
EPA 6010
Copper
21.9
mg/kg
1.7
04/25/15 23:42
EPA 6010
Iron
43700
mg/kg
13.5
04/25/15 23:42
EPA 6010
Magnesium
3950
mg/kg
168
04/25/15 23:42
EPA 6010
Manganese
512
mg/kg
1.7
04/25/15 23:42
EPA 6010
Nickel
14.7
mg/kg
1.7
04/25/15 23:42
EPA 6010
Potassium
250J
mg/kg
336
04/25/15 23:42
EPA 6010
Strontium
28.1
mg/kg
3.4
04/25/15 23:42
EPA 6010
Zinc
59.9
mg/kg
6.7
04/25/15 23:42
EPA 6020
Arsenic
5.1J
mg/kg
6.7
04/26/15 10:57
EPA 6020
Cobalt
11.4
mg/kg
6.7
04/26/15 10:57
EPA 6020
Lead
9.0
mg/kg
6.7
04/26/15 10:57
EPA 6020
Vanadium
62.1
mg/kg
6.7
04/26/15 10:57
EPA 7471
Mercury
0.032
mg/kg
0.010
04/22/15 13:07
ASTM D2974-87
Percent Moisture
22.9
%
0.10
04/23/15 13:16
EPA 9045
pH at 25 Degrees C
7.0
Std. Units
0.10
04/20/15 21:25
EPA 300.0
Sulfate
5.3
mg/L
2.6
04/29/15 15:43 B
SM 4500-CI-E
Chloride
15.2
mg/L
6.5
04/30/15 01:43
EPA 9060
Total Organic Carbon
1080
mg/kg
773
05/06/15 17:27
EPA 9060
Total Organic Carbon
1160
mg/kg
779
05/06/15 17:34
EPA 9060
Total Organic Carbon
977
mg/kg
779
05/06/15 17:40
EPA 9060
Total Organic Carbon
959
mg/kg
772
05/06/15 17:45
EPA 9060
Mean Total Organic Carbon
1040
mg/kg
776
05/06/15 17:27
EPA 9060
RSD%
9.1
%
05/06/15 17:27
92245627007
2015010709
EPA 6010
Aluminum
4550
mg/kg
33.0
04/25/15 23:46
EPA 6010
Barium
24.3
mg/kg
3.3
04/25/15 23:46
EPA 6010
Beryllium
0.20J
mg/kg
0.33
04/25/15 23:46
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 11 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980aq8rWY2"�e. Suite 100
Huntersville, NC 28078
[phone]
Project: J15040322
Pace Project No.: 92245627
Lab Sample ID Client Sample ID
Method Parameters
SUMMARY OF DETECTION
Result Units Report Limit Analyzed
92245627007
2015010709
EPA 6010
Calcium
633
mg/kg
165
04/25/15 23:46
EPA 6010
Chromium
9.9
mg/kg
1.6
04/25/15 23:46
EPA 6010
Copper
5.7
mg/kg
1.6
04/25/15 23:46
EPA 6010
Iron
7310
mg/kg
13.2
04/25/15 23:46
EPA 6010
Magnesium
1360
mg/kg
165
04/25/15 23:46
EPA 6010
Manganese
83.0
mg/kg
1.6
04/25/15 23:46
EPA 6010
Nickel
4.5
mg/kg
1.6
04/25/15 23:46
EPA 6010
Strontium
6.1
mg/kg
3.3
04/25/15 23:46
EPA 6010
Zinc
19.0
mg/kg
6.6
04/25/15 23:46
EPA 6020
Cobalt
4.2J
mg/kg
6.6
04/26/15 10:59
EPA 6020
Lead
4.OJ
mg/kg
6.6
04/26/15 10:59
EPA 6020
Vanadium
18.9
mg/kg
6.6
04/26/15 10:59
ASTM D2974-87
Percent Moisture
25.5
%
0.10
04/23/15 13:16
EPA 9045
pH at 25 Degrees C
6.1
Std. Units
0.10
04/20/15 21:25
EPA 300.0
Sulfate
6.3
mg/L
2.7
04/29/15 15:57 B
SM 4500-CI-E
Chloride
7.3
mg/L
6.7
04/30/15 01:44
EPA 9060
Total Organic Carbon
1800
mg/kg
804
05/06/15 18:32
EPA 9060
Total Organic Carbon
2010
mg/kg
809
05/06/15 18:38
EPA 9060
Total Organic Carbon
1660
mg/kg
799
05/06/15 18:44
EPA 9060
Total Organic Carbon
1810
mg/kg
805
05/06/15 18:51
EPA 9060
Mean Total Organic Carbon
1820
mg/kg
804
05/06/15 18:32
EPA 9060
RSD%
7.9
%
05/06/15 18:32
92245627008
2015010710
EPA 6020A
Aluminum
10500
ug/L
10.0
04/21/15 05:03
EPA 6020A
Antimony
0.16J
ug/L
0.50
04/21/15 05:03
EPA 6020A
Arsenic
4.7
ug/L
0.50
04/21/15 05:03
EPA 6020A
Barium
125
ug/L
0.30
04/21/15 05:03
EPA 6020A
Beryllium
0.69
ug/L
0.20
04/21/15 05:03
EPA 6020A
Boron
14.4
ug/L
5.0
04/21/15 05:03
EPA 6020A
Cadmium
0.076J
ug/L
0.080
04/21/15 05:03
EPA 6020A
Calcium
117000
ug/L
400
04/21/1513:06
EPA 6020A
Chromium
19.4
ug/L
0.50
04/21/15 05:03
EPA 6020A
Cobalt
5.4
ug/L
0.50
04/21/15 05:03
EPA 6020A
Copper
11.4
ug/L
1.0
04/21/15 05:03
EPA 6020A
Iron
11300
ug/L
50.0
04/21/15 05:03
EPA 6020A
Lead
6.7
ug/L
0.10
04/21/15 05:03
EPA 6020A
Magnesium
4850
ug/L
10.0
04/21/15 05:03
EPA 6020A
Manganese
382
ug/L
0.50
04/21/15 05:03
EPA 6020A
Molybdenum
1.6
ug/L
0.50
04/21/15 05:03
EPA 6020A
Nickel
12.6
ug/L
0.50
04/21/15 05:03
EPA 6020A
Potassium
2860
ug/L
50.0
04/21/15 05:03
EPA 6020A
Selenium
1.2
ug/L
0.50
04/21/15 05:03
EPA 6020A
Sodium
1430
ug/L
50.0
04/21/15 05:03
EPA 6020A
Strontium
235
ug/L
0.50
04/21/15 05:03
EPA 6020A
Thallium
0.080J
ug/L
0.10
04/21/15 05:03
EPA 6020A
Vanadium
29.4
ug/L
1.0
04/21/15 05:03
EPA 6020A
Zinc
61.6
ug/L
5.0
04/21/15 05:03
REPORT OF LABORATORY ANALYSIS
Qualifiers
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 12 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980Q3f WY2"Y e. Suite 100
Huntersville, NC 28078
[phone]
Project: J15040322
Pace Project No.: 92245627
Lab Sample ID Client Sample ID
Method Parameters
SUMMARY OF DETECTION
Result Units Report Limit Analyzed
92245627009
2015010711
EPA 6010
Aluminum
14100
mg/kg
41.2
04/25/15 23:50
EPA 6010
Barium
60.2
mg/kg
4.1
04/25/15 23:50
EPA 6010
Beryllium
0.59
mg/kg
0.41
04/25/15 23:50
EPA 6010
Calcium
382
mg/kg
206
04/25/15 23:50
EPA 6010
Chromium
28.7
mg/kg
2.1
04/25/15 23:50
EPA 6010
Copper
15.8
mg/kg
2.1
04/25/15 23:50
EPA 6010
Iron
14200
mg/kg
16.5
04/25/15 23:50
EPA 6010
Magnesium
1950
mg/kg
206
04/25/15 23:50
EPA 6010
Manganese
249
mg/kg
2.1
04/25/15 23:50
EPA 6010
Nickel
5.9
mg/kg
2.1
04/25/15 23:50
EPA 6010
Strontium
7.7
mg/kg
4.1
04/25/15 23:50
EPA 6010
Zinc
35.2
mg/kg
8.2
04/25/15 23:50
EPA 6020
Cadmium
0.54J
mg/kg
0.99
04/26/15 11:01
EPA 6020
Cobalt
7.5J
mg/kg
8.2
04/26/15 11:01
EPA 6020
Lead
6.9J
mg/kg
8.2
04/26/15 11:01
EPA 6020
Vanadium
31.8
mg/kg
8.2
04/26/15 11:01
EPA 7471
Mercury
0.038
mg/kg
0.014
04/22/15 13:12
ASTM D2974-87
Percent Moisture
40.2
%
0.10
04/23/15 13:17
EPA 9045
pH at 25 Degrees C
4.2
Std. Units
0.10
04/21/15 11:55 H1
EPA 9060
Total Organic Carbon
1530
mg/kg
1000
05/06/15 18:56
EPA 9060
Total Organic Carbon
1500
mg/kg
999
05/06/15 19:03
EPA 9060
Total Organic Carbon
1480
mg/kg
996
05/06/15 19:10
EPA 9060
Total Organic Carbon
1460
mg/kg
994
05/06/15 19:15
EPA 9060
Mean Total Organic Carbon
1490
mg/kg
998
05/06/15 18:56
EPA 9060
RSD%
2.0
%
05/06/15 18:56
92245627010
2015010712
EPA 6010
Aluminum
10700
mg/kg
31.0
04/25/15 23:54
EPA 6010
Barium
173
mg/kg
3.1
04/25/15 23:54
EPA 6010
Beryllium
2.2
mg/kg
0.31
04/25/15 23:54
EPA 6010
Boron
10.6J
mg/kg
15.5
04/25/15 23:54
EPA 6010
Calcium
2660
mg/kg
155
04/25/15 23:54
EPA 6010
Chromium
14.2
mg/kg
1.6
04/25/15 23:54
EPA 6010
Copper
26.6
mg/kg
1.6
04/25/15 23:54
EPA 6010
Iron
23600
mg/kg
12.4
04/25/15 23:54
EPA 6010
Magnesium
2250
mg/kg
155
04/25/15 23:54
EPA 6010
Manganese
220
mg/kg
1.6
04/25/15 23:54
EPA 6010
Molybdenum
9.0
mg/kg
3.1
04/25/15 23:54
EPA 6010
Nickel
19.1
mg/kg
1.6
04/25/15 23:54
EPA 6010
Potassium
1530
mg/kg
310
04/25/15 23:54
EPA 6010
Strontium
83.4
mg/kg
3.1
04/25/15 23:54
EPA 6010
Zinc
48.2
mg/kg
6.2
04/25/15 23:54
EPA 6020
Arsenic
20.5
mg/kg
6.2
04/26/15 11:03
EPA 6020
Cobalt
12.6
mg/kg
6.2
04/26/15 11:03
EPA 6020
Lead
22.6
mg/kg
6.2
04/26/15 11:03
EPA 6020
Selenium
12.0
mg/kg
6.2
04/26/15 11:03
EPA 6020
Vanadium
51.5
mg/kg
6.2
04/26/15 11:03
EPA 7471
Mercury
0.24
mg/kg
0.010
04/22/15 13:14
REPORT OF LABORATORY ANALYSIS
Qualifiers
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 13 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980aq9rWY2"�e. Suite 100
Huntersville, NC 28078
[phone]
SUMMARY OF DETECTION
Project:
Pace Project No.:
J15040322
92245627
Lab Sample ID
Client Sample ID
Method
Parameters
Result
Units
Report Limit
Analyzed Qualifiers
92245627010
2015010712
ASTM D2974-87
Percent Moisture
17.9
%
0.10
04/23/15 13:17
EPA 9045
pH at 25 Degrees C
6.3
Std. Units
0.10
04/21/15 11:55 H1
EPA 300.0
Sulfate
13.8
mg/L
2.4
04/29/15 16:11 B
EPA 9060
Total Organic Carbon
112000
mg/kg
5850
05/06/15 19:21
EPA 9060
Total Organic Carbon
114000
mg/kg
5640
05/06/15 19:31
EPA 9060
Total Organic Carbon
101000
mg/kg
5750
05/06/15 19:37
EPA 9060
Total Organic Carbon
82500
mg/kg
5550
05/06/15 19:43
EPA 9060
Mean Total Organic Carbon
102000
mg/kg
5700
05/06/15 19:21
EPA 9060
RSD%
14.1
%
05/06/15 19:21
92245627011
2015010713
EPA 6010
Aluminum
8180
mg/kg
42.8
04/25/15 23:58
EPA 6010
Barium
162
mg/kg
4.3
04/25/15 23:58
EPA 6010
Beryllium
2.7
mg/kg
0.43
04/25/15 23:58
EPA 6010
Boron
23.4
mg/kg
21.4
04/25/15 23:58
EPA 6010
Calcium
2150
mg/kg
214
04/25/15 23:58
EPA 6010
Chromium
14.2
mg/kg
2.1
04/25/15 23:58
EPA 6010
Copper
33.1
mg/kg
2.1
04/25/15 23:58
EPA 6010
Iron
5960
mg/kg
17.1
04/25/15 23:58
EPA 6010
Magnesium
581
mg/kg
214
04/25/15 23:58
EPA 6010
Manganese
26.0
mg/kg
2.1
04/25/15 23:58
EPA 6010
Molybdenum
16.1
mg/kg
4.3
04/25/15 23:58
EPA 6010
Nickel
22.2
mg/kg
2.1
04/25/15 23:58
EPA 6010
Potassium
1180
mg/kg
428
04/25/15 23:58
EPA 6010
Strontium
98.8
mg/kg
4.3
04/25/15 23:58
EPA 6010
Zinc
25.9
mg/kg
8.6
04/25/15 23:58
EPA 6020
Arsenic
37.8
mg/kg
8.6
04/26/15 11:05
EPA 6020
Cobalt
12.6
mg/kg
8.6
04/26/15 11:05
EPA 6020
Lead
14.8
mg/kg
8.6
04/26/15 11:05
EPA 6020
Selenium
18.8
mg/kg
8.6
04/26/15 11:05
EPA 6020
Vanadium
59.6
mg/kg
8.6
04/26/15 11:05
EPA 7471
Mercury
0.44
mg/kg
0.013
04/22/15 13:20
ASTM D2974-87
Percent Moisture
40.1
%
0.10
04/23/15 13:17
EPA 9045
pH at 25 Degrees C
7.7
Std. Units
0.10
04/21/15 11:55 H1
EPA 9060
Total Organic Carbon
91000
mg/kg
5200
05/06/15 19:49
EPA 9060
Total Organic Carbon
58800
mg/kg
5030
05/06/15 19:56
EPA 9060
Total Organic Carbon
83600
mg/kg
5210
05/06/15 20:01
EPA 9060
Total Organic Carbon
109000
mg/kg
5170
05/06/15 20:08
EPA 9060
Mean Total Organic Carbon
85600
mg/kg
5150
05/06/15 19:49
EPA 9060
RSD%
24.4
%
05/06/15 19:49
92245627012
2015010714
EPA 6010
Aluminum
11500
mg/kg
36.7
04/26/15 00:02
EPA 6010
Barium
159
mg/kg
3.7
04/26/15 00:02
EPA 6010
Beryllium
0.97
mg/kg
0.37
04/26/15 00:02
EPA 6010
Boron
9.3J
mg/kg
18.3
04/26/15 00:02
EPA 6010
Calcium
2160
mg/kg
183
04/26/15 00:02
EPA 6010
Chromium
19.9
mg/kg
1.8
04/26/15 00:02
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 14 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980agir6fY2"�e. Suite 100
Huntersville, NC 28078
[phone]
SUMMARY OF DETECTION
Project:
Pace Project No.:
J15040322
92245627
Lab Sample ID
Client Sample ID
Method
Parameters
Result
Units
Report Limit
Analyzed Qualifiers
92245627012
2015010714
EPA 6010
Copper
48.9
mg/kg
1.8
04/26/15 00:02
EPA 6010
Iron
22600
mg/kg
14.7
04/26/15 00:02
EPA 6010
Magnesium
1450
mg/kg
183
04/26/15 00:02
EPA 6010
Manganese
123
mg/kg
1.8
04/26/15 00:02
EPA 6010
Molybdenum
56.9
mg/kg
3.7
04/26/15 00:02
EPA 6010
Nickel
11.2
mg/kg
1.8
04/26/15 00:02
EPA 6010
Potassium
896
mg/kg
367
04/26/15 00:02
EPA 6010
Strontium
102
mg/kg
3.7
04/26/15 00:02
EPA 6010
Zinc
43.4
mg/kg
7.3
04/26/15 00:02
EPA 6020
Arsenic
95.1
mg/kg
7.3
04/26/15 11:08
EPA 6020
Cobalt
6.8J
mg/kg
7.3
04/26/15 11:08
EPA 6020
Lead
49.5
mg/kg
7.3
04/26/15 11:08
EPA 6020
Selenium
4AJ
mg/kg
7.3
04/26/15 11:08
EPA 6020
Vanadium
42.7
mg/kg
7.3
04/26/15 11:08
EPA 7471
Mercury
0.34
mg/kg
0.011
04/22/15 13:22
ASTM D2974-87
Percent Moisture
30.4
%
0.10
04/23/15 13:17
EPA 9045
pH at 25 Degrees C
7.2
Std. Units
0.10
04/21/15 11:55 H1
EPA 9060
Total Organic Carbon
141000
mg/kg
6140
05/06/15 20:16
EPA 9060
Total Organic Carbon
52000
mg/kg
5960
05/06/15 20:23
EPA 9060
Total Organic Carbon
70800
mg/kg
6110
05/06/15 20:28
EPA 9060
Total Organic Carbon
56600
mg/kg
5800
05/06/15 20:34
EPA 9060
Mean Total Organic Carbon
80000
mg/kg
6000
05/06/15 20:16
EPA 9060
RSD%
51.5
%
05/06/15 20:16 1 g
92245627013
2015010715
EPA 6010
Aluminum
9690
mg/kg
49.7
04/26/15 00:19
EPA 6010
Barium
316
mg/kg
5.0
04/26/15 00:19
EPA 6010
Beryllium
2.3
mg/kg
0.50
04/26/15 00:19
EPA 6010
Boron
29.8
mg/kg
24.9
04/26/15 00:19
EPA 6010
Calcium
4700
mg/kg
249
04/26/15 00:19
EPA 6010
Chromium
16.0
mg/kg
2.5
04/26/15 00:19
EPA 6010
Copper
29.2
mg/kg
2.5
04/26/15 00:19
EPA 6010
Iron
8410
mg/kg
19.9
04/26/15 00:19
EPA 6010
Magnesium
1130
mg/kg
249
04/26/15 00:19
EPA 6010
Manganese
59.0
mg/kg
2.5
04/26/15 00:19
EPA 6010
Nickel
12.3
mg/kg
2.5
04/26/15 00:19
EPA 6010
Potassium
1560
mg/kg
497
04/26/15 00:19
EPA 6010
Sodium
323J
mg/kg
497
04/26/15 00:19
EPA 6010
Strontium
230
mg/kg
5.0
04/26/15 00:19
EPA 6010
Zinc
13.5
mg/kg
9.9
04/26/15 00:19
EPA 6020
Arsenic
52.6
mg/kg
9.9
04/26/15 11:10
EPA 6020
Cobalt
6.2J
mg/kg
9.9
04/26/15 11:10
EPA 6020
Lead
10.8
mg/kg
9.9
04/26/15 11:10
EPA 6020
Selenium
8.5J
mg/kg
9.9
04/26/15 11:10
EPA 6020
Vanadium
33.0
mg/kg
9.9
04/26/15 11:10
EPA 7471
Mercury
0.23
mg/kg
0.017
04/22/15 13:24
ASTM D2974-87
Percent Moisture
50.6
%
0.10
04/23/15 13:17
EPA 9045
pH at 25 Degrees C
8.9
Std. Units
0.10
04/21/15 11:55 H1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 15 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980CA"WY2"�e. Suite 100
Huntersville, NC 28078
[phone]
SUMMARY OF DETECTION
Project:
Pace Project No.:
J15040322
92245627
Lab Sample ID
Client Sample ID
Method
Parameters
Result
Units
Report Limit
Analyzed
Qualifiers
92245627013
2015010715
EPA 300.0
Sulfate
24.8
mg/L
4.0
04/29/15 16:24
B
EPA 9056
Sulfate
523
mg/kg
496
04/19/15 13:12
EPA 9060
Total Organic Carbon
212000
mg/kg
7530
05/11/15 10:40
EPA 9060
Total Organic Carbon
158000
mg/kg
7320
05/11/15 10:45
EPA 9060
Total Organic Carbon
152000
mg/kg
7490
05/11/15 10:51
EPA 9060
Total Organic Carbon
179000
mg/kg
7450
05/11/15 10:58
EPA 9060
Mean Total Organic Carbon
175000
mg/kg
7440
05/11/15 10:40
EPA 9060
RSD%
15.6
%
05/11/15 10:40
92245627014
2015010716
EPA 6010
Aluminum
8850
mg/kg
33.6
04/26/15 00:23
EPA 6010
Barium
58.7
mg/kg
3.4
04/26/15 00:23
EPA 6010
Beryllium
0.32J
mg/kg
0.34
04/26/15 00:23
EPA 6010
Calcium
989
mg/kg
168
04/26/15 00:23
EPA 6010
Chromium
10.9
mg/kg
1.7
04/26/15 00:23
EPA 6010
Copper
9.9
mg/kg
1.7
04/26/15 00:23
EPA 6010
Iron
12500
mg/kg
13.4
04/26/15 00:23
EPA 6010
Magnesium
1250
mg/kg
168
04/26/15 00:23
EPA 6010
Manganese
351
mg/kg
1.7
04/26/15 00:23
EPA 6010
Nickel
5.0
mg/kg
1.7
04/26/15 00:23
EPA 6010
Potassium
342
mg/kg
336
04/26/15 00:23
EPA 6010
Strontium
19.1
mg/kg
3.4
04/26/15 00:23
EPA 6010
Zinc
16.5
mg/kg
6.7
04/26/15 00:23
EPA 6020
Cobalt
5AJ
mg/kg
6.7
04/26/15 11:19
EPA 6020
Lead
5.2J
mg/kg
6.7
04/26/15 11:19
EPA 6020
Vanadium
29.3
mg/kg
6.7
04/26/15 11:19
EPA 7471
Mercury
0.022
mg/kg
0.011
04/22/15 13:27
ASTM D2974-87
Percent Moisture
27.4
%
0.10
04/23/15 13:17
EPA 9045
pH at 25 Degrees C
6.4
Std. Units
0.10
04/21/15 11:55
H1
EPA 300.0
Sulfate
13.7
mg/L
2.8
05/06/15 08:41
B
EPA353.2
Nitrogen, Nitrate
0.74
mg/L
0.28
05/13/1513:18
H1
EPA 9056
Sulfate
209J
mg/kg
339
04/19/15 13:33
D3
EPA 9060
Total Organic Carbon
1230
mg/kg
827
05/11/15 11:52
EPA 9060
Total Organic Carbon
1210
mg/kg
827
05/11/15 11:58
EPA 9060
Total Organic Carbon
1120
mg/kg
827
05/11/15 12:03
EPA 9060
Total Organic Carbon
1120
mg/kg
828
05/11/15 12:09
EPA 9060
Mean Total Organic Carbon
1170
mg/kg
827
05/11/15 11:52
EPA 9060
RSD%
5.1
%
05/11/15 11:52
92245627015
2015010717
EPA 6010
Aluminum
12300
mg/kg
46.6
04/26/15 00:27
EPA 6010
Barium
407
mg/kg
4.7
04/26/15 00:27
EPA 6010
Beryllium
3.0
mg/kg
0.47
04/26/15 00:27
EPA 6010
Boron
35.2
mg/kg
23.3
04/26/15 00:27
EPA 6010
Calcium
6170
mg/kg
233
04/26/15 00:27
EPA 6010
Chromium
21.1
mg/kg
2.3
04/26/15 00:27
EPA 6010
Copper
36.5
mg/kg
2.3
04/26/15 00:27
EPA 6010
Iron
10000
mg/kg
18.6
04/26/15 00:27
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 16 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800AirWY2"�e. Suite 100
Huntersville, NC 28078
[phone]
Project: J15040322
Pace Project No.: 92245627
Lab Sample ID Client Sample ID
Method Parameters
SUMMARY OF DETECTION
Result Units Report Limit Analyzed Qualifiers
92245627015
2015010717
EPA 6010
Magnesium
1480
mg/kg
233
04/26/15 00:27
EPA 6010
Manganese
73.4
mg/kg
2.3
04/26/15 00:27
EPA 6010
Nickel
15.2
mg/kg
2.3
04/26/15 00:27
EPA 6010
Potassium
1870
mg/kg
466
04/26/15 00:27
EPA 6010
Sodium
353J
mg/kg
466
04/26/15 00:27
EPA 6010
Strontium
301
mg/kg
4.7
04/26/15 00:27
EPA 6010
Zinc
17.4
mg/kg
9.3
04/26/15 00:27
EPA 6020
Arsenic
72.9
mg/kg
9.3
04/26/15 11:22
EPA 6020
Cobalt
7.8J
mg/kg
9.3
04/26/15 11:22
EPA 6020
Lead
13.6
mg/kg
9.3
04/26/15 11:22
EPA 6020
Selenium
10.4
mg/kg
9.3
04/26/15 11:22
EPA 6020
Vanadium
44.8
mg/kg
9.3
04/26/15 11:22
EPA 7471
Mercury
0.24
mg/kg
0.015
04/22/15 13:29
ASTM D2974-87
Percent Moisture
43.8
%
0.10
04/23/15 13:17
EPA 9045
pH at 25 Degrees C
8.8
Std. Units
0.10
04/21/15 11:55 H1
EPA 9056
Sulfate
437J
mg/kg
444
04/19/15 13:54
EPA 9060
Total Organic Carbon
168000
mg/kg
6230
05/11/15 12:14
EPA 9060
Total Organic Carbon
165000
mg/kg
6290
05/11/15 12:20
EPA 9060
Total Organic Carbon
159000
mg/kg
6190
05/11/15 12:27
EPA 9060
Total Organic Carbon
148000
mg/kg
6260
05/11/15 12:33
EPA 9060
Mean Total Organic Carbon
160000
mg/kg
6240
05/11/15 12:14
EPA 9060
RSD%
5.4
%
05/11/15 12:14
92245627016
2015010707 SPLP
EPA 6020A
Aluminum
428
ug/L
10.0
05/15/15 14:12
EPA 6020A
Antimony
3.6
ug/L
0.50
05/15/15 14:12
EPA 6020A
Arsenic
90.5
ug/L
0.50
05/15/15 14:12
EPA 6020A
Barium
251
ug/L
0.30
05/15/15 14:12
EPA 6020A
Boron
61.5
ug/L
5.0
05/15/15 14:12
EPA 6020A
Calcium
9480
ug/L
40.0
05/15/15 14:12
EPA 6020A
Chromium
2.2
ug/L
0.50
05/15/15 14:12
EPA 6020A
Copper
0.66J
ug/L
1.0
05/15/15 14:12
EPA 6020A
Iron
18.91
ug/L
50.0
05/15/15 14:12
EPA 6020A
Lead
0.0501
ug/L
0.10
05/15/15 14:12
EPA 6020A
Magnesium
605
ug/L
10.0
05/15/15 14:12
EPA 6020A
Manganese
5.3
ug/L
0.50
05/15/15 14:12
EPA 6020A
Molybdenum
8.2
ug/L
0.50
05/15/15 14:12
EPA 6020A
Nickel
0.35J
ug/L
0.50
05/15/15 14:12
EPA 6020A
Potassium
238
ug/L
50.0
05/15/15 14:12
EPA 6020A
Selenium
58.3
ug/L
0.50
05/15/15 14:12
EPA 6020A
Sodium
2230
ug/L
50.0
05/15/15 14:12
EPA 6020A
Strontium
344
ug/L
0.50
05/15/15 14:12
EPA 6020A
Vanadium
33.5
ug/L
1.0
05/15/15 14:12
EPA 6020A
Zinc
22.4
ug/L
5.0
05/15/15 14:12
92245627017
2015010708 SPLP
EPA 6020A
Aluminum
282000
ug/L
200
05/15/15 14:15
EPA 6020A
Arsenic
17.7
ug/L
0.50
05/14/15 19:46
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 17 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800AirWY2"�e. Suite 100
Huntersville, NC 28078
[phone]
Project: J15040322
Pace Project No.: 92245627
Lab Sample ID Client Sample ID
Method Parameters
SUMMARY OF DETECTION
Result Units Report Limit Analyzed
92245627017
2015010708 SPLP
EPA 6020A
Barium
1340
ug/L
6.0
05/15/15 14:15
EPA 6020A
Beryllium
6.6
ug/L
4.0
05/15/15 14:15
EPA 6020A
Boron
181
ug/L
100
05/15/15 14:15
EPA 6020A
Cadmium
0.25
ug/L
0.080
05/14/15 19:46
EPA 6020A
Calcium
18500
ug/L
800
05/15/15 14:15
EPA 6020A
Chromium
288
ug/L
10.0
05/15/15 14:15
EPA 6020A
Cobalt
43.6
ug/L
0.50
05/14/15 19:46
EPA 6020A
Copper
155
ug/L
1.0
05/14/15 19:46
EPA 6020A
Iron
278000
ug/L
1000
05/15/15 14:15
EPA 6020A
Lead
52.6
ug/L
0.10
05/14/15 19:46
EPA 6020A
Magnesium
22100
ug/L
200
05/15/15 14:15
EPA 6020A
Manganese
2210
ug/L
10.0
05/15/15 14:15
EPA 6020A
Molybdenum
0.37J
ug/L
0.50
05/14/15 19:46
EPA 6020A
Nickel
125
ug/L
0.50
05/14/15 19:46
EPA 6020A
Potassium
3240
ug/L
1000
05/15/15 14:15
EPA 6020A
Selenium
3.9
ug/L
0.50
05/14/15 19:46
EPA 6020A
Sodium
2760
ug/L
1000
05/15/15 14:15
EPA 6020A
Strontium
274
ug/L
0.50
05/14/15 19:46
EPA 6020A
Thallium
1.0
ug/L
0.10
05/14/15 19:46
EPA 6020A
Vanadium
370
ug/L
20.0
05/15/15 14:15
EPA 6020A
Zinc
554
ug/L
100
05/15/15 14:15
EPA 7470A
Mercury
0.39
ug/L
0.20
05/14/15 21:19
92245627018
2015010709 SPLP
EPA 6020A
Aluminum
44000
ug/L
200
05/15/15 14:17
EPA 6020A
Antimony
0.47J
ug/L
0.50
05/14/15 19:48
EPA 6020A
Arsenic
7.0
ug/L
0.50
05/14/15 19:48
EPA 6020A
Barium
359
ug/L
0.30
05/14/15 19:48
EPA 6020A
Beryllium
1.8
ug/L
0.20
05/14/15 19:48
EPA 6020A
Boron
43.9
ug/L
5.0
05/14/15 19:48
EPA 6020A
Cadmium
0.21
ug/L
0.080
05/14/15 19:48
EPA 6020A
Calcium
2550
ug/L
40.0
05/14/15 19:48
EPA 6020A
Chromium
53.2
ug/L
0.50
05/14/15 19:48
EPA 6020A
Cobalt
13.5
ug/L
0.50
05/14/15 19:48
EPA 6020A
Copper
39.0
ug/L
1.0
05/14/15 19:48
EPA 6020A
Iron
22900
ug/L
1000
05/15/15 14:17
EPA 6020A
Lead
23.8
ug/L
0.10
05/14/15 19:48
EPA 6020A
Magnesium
3380
ug/L
10.0
05/14/15 19:48
EPA 6020A
Manganese
180
ug/L
0.50
05/14/15 19:48
EPA 6020A
Molybdenum
1.4
ug/L
0.50
05/14/15 19:48
EPA 6020A
Nickel
22.4
ug/L
0.50
05/14/15 19:48
EPA 6020A
Potassium
1380
ug/L
50.0
05/14/15 19:48
EPA 6020A
Selenium
0.82
ug/L
0.50
05/14/15 19:48
EPA 6020A
Sodium
2680
ug/L
1000
05/15/15 14:17
EPA 6020A
Strontium
30.2
ug/L
0.50
05/14/15 19:48
EPA 6020A
Thallium
0.18
ug/L
0.10
05/14/15 19:48
EPA 6020A
Vanadium
161
ug/L
1.0
05/14/15 19:48
EPA 6020A
Zinc
182
ug/L
5.0
05/14/15 19:48
REPORT OF LABORATORY ANALYSIS
Qualifiers
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 18 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980Q WY2"Y e. Suite 100
Huntersville, NC 28078
[phone]
Project: J15040322
Pace Project No.: 92245627
Lab Sample ID Client Sample ID
Method Parameters
SUMMARY OF DETECTION
Result Units Report Limit Analyzed Qualifiers
92245627018
2015010709 SPLP
EPA 7470A
Mercury
0.040J
ug/L
0.20
05/14/15 21:28
92245627019
2015010712 SPLP
EPA 6020A
Aluminum
24900
ug/L
50.0
05/15/15 14:20
EPA 6020A
Antimony
5.1
ug/L
0.50
05/14/15 19:54
EPA 6020A
Arsenic
24.6
ug/L
0.50
05/14/15 19:54
EPA 6020A
Barium
429
ug/L
0.30
05/14/15 19:54
EPA 6020A
Beryllium
0.94
ug/L
0.20
05/14/15 19:54
EPA 6020A
Boron
166
ug/L
5.0
05/14/15 19:54
EPA 6020A
Cadmium
0.083
ug/L
0.080
05/14/15 19:54
EPA 6020A
Calcium
6370
ug/L
40.0
05/14/15 19:54
EPA 6020A
Chromium
15.1
ug/L
0.50
05/14/15 19:54
EPA 6020A
Cobalt
6.3
ug/L
0.50
05/14/15 19:54
EPA 6020A
Copper
13.1
ug/L
1.0
05/14/15 19:54
EPA 6020A
Iron
18000
ug/L
50.0
05/14/15 19:54
EPA 6020A
Lead
8.1
ug/L
0.10
05/14/15 19:54
EPA 6020A
Magnesium
2270
ug/L
10.0
05/14/15 19:54
EPA 6020A
Manganese
117
ug/L
0.50
05/14/15 19:54
EPA 6020A
Molybdenum
129
ug/L
0.50
05/14/15 19:54
EPA 6020A
Nickel
9.0
ug/L
0.50
05/14/15 19:54
EPA 6020A
Potassium
2280
ug/L
50.0
05/14/15 19:54
EPA 6020A
Selenium
13.9
ug/L
0.50
05/14/15 19:54
EPA 6020A
Sodium
1980
ug/L
250
05/15/15 14:20
EPA 6020A
Strontium
187
ug/L
0.50
05/14/15 19:54
EPA 6020A
Thallium
0.51
ug/L
0.10
05/14/15 19:54
EPA 6020A
Vanadium
45.6
ug/L
1.0
05/14/15 19:54
EPA 6020A
Zinc
124
ug/L
5.0
05/14/15 19:54
EPA 7470A
Mercury
0.0801
ug/L
0.20
05/14/15 21:30
92245627021
2015010715 SPLP
EPA 6020A
Aluminum
1080
ug/L
10.0
05/15/15 14:23
EPA 6020A
Antimony
2.1
ug/L
0.50
05/15/15 14:23
EPA 6020A
Arsenic
131
ug/L
0.50
05/15/15 14:23
EPA 6020A
Barium
149
ug/L
0.30
05/15/15 14:23
EPA 6020A
Boron
316
ug/L
5.0
05/15/15 14:23
EPA 6020A
Calcium
9790
ug/L
40.0
05/15/15 14:23
EPA 6020A
Chromium
2.1
ug/L
0.50
05/15/15 14:23
EPA 6020A
Copper
3.0
ug/L
1.0
05/15/15 14:23
EPA 6020A
Iron
36.3J
ug/L
50.0
05/15/15 14:23
EPA 6020A
Lead
0.20
ug/L
0.10
05/15/15 14:23
EPA 6020A
Magnesium
905
ug/L
10.0
05/15/15 14:23
EPA 6020A
Manganese
3.0
ug/L
0.50
05/15/15 14:23
EPA 6020A
Molybdenum
5.5
ug/L
0.50
05/15/15 14:23
EPA 6020A
Nickel
0.89
ug/L
0.50
05/15/15 14:23
EPA 6020A
Potassium
398
ug/L
50.0
05/15/15 14:23
EPA 6020A
Selenium
37.1
ug/L
0.50
05/15/15 14:23
EPA 6020A
Sodium
1480
ug/L
50.0
05/15/15 14:23
EPA 6020A
Strontium
271
ug/L
0.50
05/15/15 14:23
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 19 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980Q WY2"Y e. Suite 100
Huntersville, NC 28078
[phone]
Project: J15040322
Pace Project No.: 92245627
Lab Sample ID Client Sample ID
Method Parameters
SUMMARY OF DETECTION
Result Units Report Limit Analyzed Qualifiers
92245627021
2015010715 SPLP
EPA 6020A
Vanadium
48.2
ug/L
1.0
05/15/15 14:23
EPA 6020A
Zinc
9.8
ug/L
5.0
05/15/15 14:23
92245627022
2015010718
EPA 6020A
Aluminum
575
ug/L
10.0
04/21/15 05:08
EPA 6020A
Arsenic
0.37J
ug/L
0.50
04/21/15 05:08
EPA 6020A
Barium
9.8
ug/L
0.30
04/21/15 05:08
EPA 6020A
Beryllium
0.077J
ug/L
0.20
04/21/15 05:08
EPA 6020A
Calcium
761
ug/L
40.0
04/23/15 01:05
EPA 6020A
Chromium
3.0
ug/L
0.50
04/21/15 05:08
EPA 6020A
Cobalt
3.3
ug/L
0.50
04/21/15 05:08
EPA 6020A
Copper
1.7
ug/L
1.0
04/21/15 05:08
EPA 6020A
Iron
1000
ug/L
50.0
04/21/15 05:08
EPA 6020A
Lead
0.42
ug/L
0.10
04/21/15 05:08
EPA 6020A
Magnesium
155
ug/L
10.0
04/21/15 05:08
EPA 6020A
Manganese
39.7
ug/L
0.50
04/21/15 05:08
EPA 6020A
Molybdenum
0.91
ug/L
0.50
04/21/15 05:08
EPA 6020A
Nickel
0.74
ug/L
0.50
04/21/15 05:08
EPA 6020A
Potassium
278
ug/L
50.0
04/21/15 05:08
EPA 6020A
Sodium
337
ug/L
50.0
04/21/15 05:08
EPA 6020A
Strontium
5.4
ug/L
0.50
04/21/15 05:08
EPA 6020A
Vanadium
1.0
ug/L
1.0
04/21/15 05:08
EPA 6020A
Zinc
6.4
ug/L
5.0
04/21/15 05:08
92245627023
2015010716 SPLP
EPA 6020A
Aluminum
54000
ug/L
50.0
05/15/15 14:26
EPA 6020A
Arsenic
3.8
ug/L
0.50
05/14/15 19:59
EPA 6020A
Barium
347
ug/L
0.30
05/14/15 19:59
EPA 6020A
Beryllium
1.1
ug/L
0.20
05/14/15 19:59
EPA 6020A
Boron
183
ug/L
5.0
05/14/15 19:59
EPA 6020A
Cadmium
0.030J
ug/L
0.080
05/14/15 19:59
EPA 6020A
Calcium
5320
ug/L
40.0
05/14/15 19:59
EPA 6020A
Chromium
42.6
ug/L
0.50
05/14/15 19:59
EPA 6020A
Cobalt
16.3
ug/L
0.50
05/14/15 19:59
EPA 6020A
Copper
46.9
ug/L
1.0
05/14/15 19:59
EPA 6020A
Iron
47400
ug/L
250
05/15/15 14:26
EPA 6020A
Lead
11.9
ug/L
0.10
05/14/15 19:59
EPA 6020A
Magnesium
4070
ug/L
10.0
05/14/15 19:59
EPA 6020A
Manganese
1340
ug/L
2.5
05/15/15 14:26
EPA 6020A
Molybdenum
0.37J
ug/L
0.50
05/14/15 19:59
EPA 6020A
Nickel
26.1
ug/L
0.50
05/14/15 19:59
EPA 6020A
Potassium
1270
ug/L
50.0
05/14/15 19:59
EPA 6020A
Selenium
0.65
ug/L
0.50
05/14/15 19:59
EPA 6020A
Sodium
2170
ug/L
250
05/15/15 14:26
EPA 6020A
Strontium
117
ug/L
0.50
05/14/15 19:59
EPA 6020A
Thallium
0.24
ug/L
0.10
05/14/15 19:59
EPA 6020A
Vanadium
86.0
ug/L
1.0
05/14/15 19:59
EPA 6020A
Zinc
133
ug/L
5.0
05/14/15 19:59
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 20 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800WWY2"�e. Suite 100
Huntersville, NC 28078
[phone]
Project: J15040322
Pace Project No.: 92245627
Lab Sample ID
Method
92245627023
EPA 7470A
Client Sample ID
Parameters
2015010716 SPLP
Mercury
SUMMARY OF DETECTION
Result UnitE
0.10J ug/L
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Report Limit Analyzed Qualifiers
0.20 05/14/15 21:36
Page 21 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980041 WY2"Y e. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15040322
Pace Project No.: 92245627
Method: EPA 6010
Description: 6010 MET ICP
Client: Duke Energy
Date: June 15, 2015
General Information:
12 samples were analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 3050 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: MPRP/23716
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92245627003
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1188469)
• Aluminum
• Barium
• Iron
• Potassium
• Strontium
• MSD (Lab ID: 1188470)
• Aluminum
• Barium
• Beryllium
• Calcium
• Copper
• Potassium
• Strontium
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 22 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
98004ff WY2"Y e. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15040322
Pace Project No.: 92245627
Method: EPA 6010
Description: 6010 MET ICP
Client: Duke Energy
Date: June 15, 2015
Batch Comments:
Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
• QC Batch: ICP / 14506
Analyte Comments:
QC Batch: MPRP/23716
D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
•2015010706 (Lab ID:92245627004)
• Nickel
P8: Analyte was detected in the method blank. All associated samples had concentrations of at least ten times greater than the blank
or were below the reporting limit.
• BLANK (Lab ID: 1188467)
• Iron
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 23 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
98004t WleYl�e. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15040322
Pace Project No.: 92245627
Method: EPA 6020
Description: 6020 MET ICPMS
Client: Duke Energy
Date: June 15, 2015
General Information:
12 samples were analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 3050 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: MPRP/23717
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92245627003
M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
• MS (Lab ID: 1188475)
• Antimony
• Arsenic
• Cadmium
• Cobalt
• Lead
• Selenium
• Thallium
• Vanadium
• MSD (Lab ID: 1188476)
• Antimony
• Arsenic
• Cadmium
• Cobalt
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 24 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
98004 WIeYl e" Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15040322
Pace Project No.: 92245627
Method: EPA 6020
Description: 6020 MET ICPMS
Client: Duke Energy
Date: June 15, 2015
QC Batch: MPRP/23717
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92245627003
M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
• Lead
• Selenium
• Thallium
• Vanadium
Additional Comments:
Batch Comments:
Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
• QC Batch: ICPM / 9649
Analyte Comments:
QC Batch: MPRP/23717
N2: The lab does not hold TNI accreditation for this parameter.
•2015010705 (Lab ID:92245627003)
• Antimony
•2015010706 (Lab ID:92245627004)
• Antimony
•2015010707 (Lab ID:92245627005)
• Antimony
•2015010708 (Lab ID:92245627006)
• Antimony
•2015010709 (Lab ID:92245627007)
• Antimony
•2015010711 (Lab ID:92245627009)
• Antimony
•2015010712 (Lab ID:92245627010)
• Antimony
•2015010713 (Lab ID:92245627011)
• Antimony
•2015010714 (Lab ID:92245627012)
• Antimony
•2015010715 (Lab ID:92245627013)
• Antimony
•2015010716 (Lab ID:92245627014)
• Antimony
•2015010717 (Lab ID:92245627015)
• Antimony
• BLANK (Lab ID: 1188473)
• Antimony
• LCS (Lab ID: 1188474)
• Antimony
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 25 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
98004t WY2"Y e. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15040322
Pace Project No.: 92245627
Method: EPA 6020
Description: 6020 MET ICPMS
Client: Duke Energy
Date: June 15, 2015
Analyte Comments:
QC Batch: MPRP/23717
N2: The lab does not hold TNI accreditation for this parameter.
• MS (Lab ID: 1188475)
• Antimony
• MSD (Lab ID: 1188476)
• Antimony
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 26 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980041 WeYlY e. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15040322
Pace Project No.: 92245627
Method: EPA 6020A
Description: 6020A MET ICPMS
Client: Duke Energy
Date: June 15, 2015
General Information:
9 samples were analyzed for EPA 6020A. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 3020 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: MPRP/53712
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92245612006
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1943026)
• Copper
• Zinc
R1: RPD value was outside control limits.
• MSD (Lab ID: 1943027)
• Copper
• Zinc
QC Batch: MPRP/54343
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92249101001
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1963687)
• Aluminum
• MSD (Lab ID: 1963688)
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 27 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800*WleYl�e. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15040322
Pace Project No.: 92245627
Method: EPA 6020A
Description: 6020A MET ICPMS
Client: Duke Energy
Date: June 15, 2015
QC Batch: MPRP/54343
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92249101001
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• Aluminum
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 28 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
98004t WeYlY e. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15040322
Pace Project No.: 92245627
Method: EPA 7470
Description: 7470 Mercury
Client: Duke Energy
Date: June 15, 2015
General Information:
3 samples were analyzed for EPA 7470. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 7470 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 29 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
98004t WeYlY e. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15040322
Pace Project No.: 92245627
Method: EPA 7470A
Description: 7470A Mercury
Client: Duke Energy
Date: June 15, 2015
General Information:
6 samples were analyzed for EPA 7470A. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
1-11: Analysis conducted outside the recognized method holding time.
• 2015010715 SPLP (Lab ID: 92245627021)
1-12: Extraction or preparation was conducted outside of the recognized method holding time.
• 2015010715 SPLP (Lab ID: 92245627021)
Sample Preparation:
The samples were prepared in accordance with EPA 7470A with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 30 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800AWIeYl�e. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15040322
Pace Project No.: 92245627
Method: EPA 7471
Description: 7471 Mercury
Client: Duke Energy
Date: June 15, 2015
General Information:
12 samples were analyzed for EPA 7471. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 7471 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: MERP/5614
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 35183605001
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1190221)
• Mercury
• MSD (Lab ID: 1190222)
• Mercury
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 31 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
98005k WY2"Y e. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15040322
Pace Project No.: 92245627
Method: EPA 9045
Description: 9045 pH Soil
Client: Duke Energy
Date: June 15, 2015
General Information:
12 samples were analyzed for EPA 9045. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
1-11: Analysis conducted outside the EPA method holding time.
•2015010711 (Lab ID:92245627009)
•2015010712 (Lab ID:92245627010)
•2015010713 (Lab ID:92245627011)
•2015010714 (Lab ID:92245627012)
•2015010715 (Lab ID:92245627013)
•2015010716 (Lab ID:92245627014)
•2015010717 (Lab ID:92245627015)
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 32 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
98005irWY2"�e. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15040322
Pace Project No.: 92245627
Method: EPA 300.0
Description: 300.0 IC Anions, SPLP
Client: Duke Energy
Date: June 15, 2015
General Information:
6 samples were analyzed for EPA 300.0. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
QC Batch: WETA/22735
B: Analyte was detected in the associated method blank.
• BLANK for HBN 261569 [WETA/227 (Lab ID: 1445696)
• Sulfate
QC Batch: WETA/22814
B: Analyte was detected in the associated method blank.
• BLANK for HBN 262461 [WETA/228 (Lab ID: 1450589)
• Sulfate
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 33 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
98005kf WY2"Y e. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15040322
Pace Project No.: 92245627
Method: EPA 353.2
Description: 353.2 Nitrogen, NO2/NO3, SPLP
Client: Duke Energy
Date: June 15, 2015
General Information:
6 samples were analyzed for EPA 353.2. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
1-11: Analysis conducted outside the EPA method holding time.
•2015010707 (Lab ID:92245627005)
•2015010708 (Lab ID:92245627006)
•2015010709 (Lab ID:92245627007)
•2015010712 (Lab ID:92245627010)
•2015010715 (Lab ID:92245627013)
•2015010716 (Lab ID:92245627014)
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 34 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
98005kf WY2"Y e. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15040322
Pace Project No.: 92245627
Method: SM 4500-CI-E
Description: 4500 Chloride, SPLP
Client: Duke Energy
Date: June 15, 2015
General Information:
6 samples were analyzed for SM 4500-CI-E. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 35 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800AWM2"�e. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15040322
Pace Project No.: 92245627
Method: EPA 9056
Description: 9056 IC Anions
Client: Duke Energy
Date: June 15, 2015
General Information:
12 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
Analyte Comments:
QC Batch: WETA/45549
DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
•2015010705 (Lab ID:92245627003)
• Chloride
• Sulfate
•2015010706 (Lab ID:92245627004)
• Chloride
• Sulfate
•2015010707 (Lab ID:92245627005)
• Chloride
• Sulfate
•2015010708 (Lab ID:92245627006)
• Chloride
• Sulfate
•2015010709 (Lab ID:92245627007)
• Chloride
• Sulfate
•2015010711 (Lab ID:92245627009)
• Chloride
• Sulfate
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 36 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
98005FWY2"� . Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15040322
Pace Project No.: 92245627
Method: EPA 9056
Description: 9056 IC Anions
Client: Duke Energy
Date: June 15, 2015
Analyte Comments:
QC Batch: WETA/45549
DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
•2015010712 (Lab ID:92245627010)
• Chloride
• Sulfate
•2015010713 (Lab ID:92245627011)
• Chloride
• Sulfate
•2015010714 (Lab ID:92245627012)
• Chloride
• Sulfate
•2015010715 (Lab ID:92245627013)
• Chloride
•2015010716 (Lab ID:92245627014)
• Chloride
• Sulfate
•2015010717 (Lab ID:92245627015)
• Chloride
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 37 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
98005WM2"�-. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15040322
Pace Project No.: 92245627
Method: EPA 9056
Description: 9056 IC Anions 48hr
Client: Duke Energy
Date: June 15, 2015
General Information:
12 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
1-11: Analysis conducted outside the EPA method holding time.
•2015010709 (Lab ID:92245627007)
1-13: Sample was received or analysis requested beyond the recognized method holding time.
•2015010705 (Lab ID:92245627003)
•2015010706 (Lab ID:92245627004)
•2015010707 (Lab ID:92245627005)
•2015010708 (Lab ID:92245627006)
•2015010711 (Lab ID:92245627009)
•2015010712 (Lab ID:92245627010)
•2015010713 (Lab ID:92245627011)
•2015010714 (Lab ID:92245627012)
•2015010715 (Lab ID:92245627013)
•2015010716 (Lab ID:92245627014)
•2015010717 (Lab ID:92245627015)
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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PROJECT NARRATIVE
Project: J15040322
Pace Project No.: 92245627
Method: EPA 9060
Description: Total Organic Carbon Quad
Client: Duke Energy
Date: June 15, 2015
General Information:
12 samples were analyzed for EPA 9060. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
Analyte Comments:
QC Batch: WETA/28320
1g: % RSD > 40
•2015010714 (Lab ID:92245627012)
• RSD%
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc.. Page 39 of 103

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ANALYTICAL RESULTS
Project: J15040322
Pace Project No.: 92245627
Sample: 2015010703 Lab ID: 92245627001 Collected: 04/11/15 11:00 Received: 04/15/15 15:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
;I➢ZI7c\�i,I=11 l[99�r 6?
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Sodium
Strontium
Thallium
Vanadium
Zinc
7470 Mercury
Mercury
Date: 06/15/2015 07:34 AM
Analytical Method: EPA 6020A Preparation Method: EPA 3020
1140
ug/L
10.0
3.0
1
04/20/15 06:33
04/21/15 04:58
7429-90-5
ND
ug/L
0.50
0.15
1
04/20/15 06:33
04/21/15 04:58
7440-36-0
0.21J
ug/L
0.50
0.11
1
04/20/15 06:33
04/21/15 04:58
7440-38-2
9.3
ug/L
0.30
0.081
1
04/20/15 06:33
04/21/15 04:58
7440-39-3
ND
ug/L
0.20
0.067
1
04/20/15 06:33
04/21/15 04:58
7440-41-7
ND
ug/L
5.0
1.1
1
04/20/15 06:33
04/21/15 04:58
7440-42-8
ND
ug/L
0.080
0.024
1
04/20/15 06:33
04/21/15 04:58
7440-43-9
456
ug/L
40.0
16.0
1
04/20/15 06:33
04/23/15 01:00
7440-70-2
0.84
ug/L
0.50
0.17
1
04/20/15 06:33
04/21/15 04:58
7440-47-3
1.2
ug/L
0.50
0.13
1
04/20/15 06:33
04/21/15 04:58
7440-48-4
0.66J
ug/L
1.0
0.21
1
04/20/15 06:33
04/21/15 04:58
7440-50-8
806
ug/L
50.0
13.7
1
04/20/15 06:33
04/21/15 04:58
7439-89-6
0.59
ug/L
0.10
0.046
1
04/20/15 06:33
04/21/15 04:58
7439-92-1
248
ug/L
10.0
3.2
1
04/20/15 06:33
04/21/15 04:58
7439-95-4
40.9
ug/L
0.50
0.24
1
04/20/15 06:33
04/21/15 04:58
7439-96-5
0.40J
ug/L
0.50
0.094
1
04/20/15 06:33
04/21/15 04:58
7439-98-7
0.57
ug/L
0.50
0.16
1
04/20/15 06:33
04/21/15 04:58
7440-02-0
395
ug/L
50.0
11.7
1
04/20/15 06:33
04/21/15 04:58
7440-09-7
ND
ug/L
0.50
0.20
1
04/20/15 06:33
04/21/15 04:58
7782-49-2
219
ug/L
50.0
16.3
1
04/20/15 06:33
04/21/15 04:58
7440-23-5
2.3
ug/L
0.50
0.13
1
04/20/15 06:33
04/21/15 04:58
7440-24-6
ND
ug/L
0.10
0.015
1
04/20/15 06:33
04/21/15 04:58
7440-28-0
1.2
ug/L
1.0
0.28
1
04/20/15 06:33
04/21/15 04:58
7440-62-2
6.1
ug/L
5.0
2.4
1
04/20/15 06:33
04/21/15 04:58
7440-66-6
Analytical Method: EPA 7470 Preparation Method: EPA 7470
ND ug/L 0.20 0.022 1 04/20/15 11:15 04/20/15 20:08 7439-97-6
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: J15040322
Pace Project No.: 92245627
Sample: 2015010705
Lab ID:
92245627003 Collected:
04/11/15 11:30
Received: 04/15/15 15:30 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample
size and any dilutions.
Report
Parameters
Results
Units Limit
MDL
DF
Prepared
Analyzed
CAS No.
Qual
6010 MET ICP
Analytical
Method: EPA 6010
Preparation
Method: EPA 3050
Aluminum
5200
mg/kg
42.2
21.1
5
04/21/15 14:40
04/25/15 23:01
7429-90-5
M1
Barium
482
mg/kg
4.2
2.1
5
04/21/15 14:40
04/25/15 23:01
7440-39-3
M1
Beryllium
1.1
mg/kg
0.42
0.21
5
04/21/15 14:40
04/25/15 23:01
7440-41-7
M1
Boron
ND
mg/kg
21.1
10.6
5
04/21/15 14:40
04/25/15 23:01
7440-42-8
Calcium
1390
mg/kg
211
106
5
04/21/15 14:40
04/25/15 23:01
7440-70-2
M1
Chromium
10.5
mg/kg
2.1
1.1
5
04/21/15 14:40
04/25/15 23:01
7440-47-3
Copper
19.3
mg/kg
2.1
1.1
5
04/21/15 14:40
04/25/15 23:01
7440-50-8
M1
Iron
20500
mg/kg
16.9
8.4
5
04/21/15 14:40
04/25/15 23:01
7439-89-6
M1
Magnesium
447
mg/kg
211
106
5
04/21/15 14:40
04/25/15 23:01
7439-95-4
Manganese
56.2
mg/kg
2.1
1.1
5
04/21/15 14:40
04/25/15 23:01
7439-96-5
Molybdenum
ND
mg/kg
4.2
2.1
5
04/21/15 14:40
04/25/15 23:01
7439-98-7
Nickel
13.0
mg/kg
2.1
1.1
5
04/21/15 14:40
04/25/15 23:01
7440-02-0
Potassium
853
mg/kg
422
211
5
04/21/15 14:40
04/25/15 23:01
7440-09-7
M1
Sodium
ND
mg/kg
422
211
5
04/21/15 14:40
04/25/15 23:01
7440-23-5
Strontium
97.4
mg/kg
4.2
2.1
5
04/21/15 14:40
04/25/15 23:01
7440-24-6
M1
Zinc
9.7
mg/kg
8.4
4.2
5
04/21/15 14:40
04/25/15 23:01
7440-66-6
6020 MET ICPMS
Analytical
Method: EPA 6020
Preparation
Method: EPA 3050
Antimony
ND
mg/kg
8.4
4.2
100
04/21/15 14:40
04/26/1510:36
7440-36-0
M6,N2
Arsenic
21.8
mg/kg
8.4
4.2
100
04/21/15 14:40
04/26/1510:36
7440-38-2
M6
Cadmium
0.591
mg/kg
1.0
0.51
100
04/21/15 14:40
04/26/1510:36
7440-43-9
M6
Cobalt
6.91
mg/kg
8.4
4.2
100
04/21/15 14:40
04/26/1510:36
7440-48-4
M6
Lead
ND
mg/kg
8.4
4.2
100
04/21/15 14:40
04/26/1510:36
7439-92-1
M6
Selenium
6.91
mg/kg
8.4
4.2
100
04/21/15 14:40
04/26/1510:36
7782-49-2
M6
Thallium
ND
mg/kg
8.4
4.2
100
04/21/15 14:40
04/26/1510:36
7440-28-0
M6
Vanadium
20.4
mg/kg
8.4
4.2
100
04/21/15 14:40
04/26/1510:36
7440-62-2
M6
7471 Mercury
Analytical
Method: EPA 7471
Preparation
Method: EPA 7471
Mercury
0.093
mg/kg 0.014
0.0071
1
04/21/15 21:00
04/22/15 12:59
7439-97-6
Percent Moisture
Analytical
Method: ASTM D2974-87
Percent Moisture
42.3
%
0.10
0.10
1
04/23/15 13:16
9045 pH Soil
Analytical
Method: EPA 9045
pH at 25 Degrees C
5.4
Std. Units
0.10
0.10
1
04/20/15 21:25
9056 IC Anions
Analytical
Method: EPA 9056
Chloride
ND
mg/kg
432
216
5
04/19/1515:20
16887-00-6
D3
Sulfate
ND
mg/kg
432
216
5
04/19/1515:20
14808-79-8
D3
9056 IC Anions 48hr
Analytical
Method: EPA 9056
Nitrate as N
ND
mg/kg
43.2
21.6
5
04/19/15 15:20
14797-55-8
H3
Date: 06/15/2015 07:34 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 41 of 103

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98006Jbir6fYl�e. Suite 100
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[phone]
ANALYTICAL RESULTS
Project: J15040322
Pace Project No.: 92245627
Sample: 2015010705
Lab ID:
92245627003
Collected:
04/11/15 11:30
Received: 04/15/15 15:30 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample
size and any dilutions.
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared Analyzed
CAS No. Qual
Total Organic Carbon Quad
Analytical
Method: EPA 9060
Total Organic Carbon
95600
mg/kg
9050
4530
1
05/06/15 14:11
7440-44-0
Total Organic Carbon
104000
mg/kg
8900
4450
1
05/06/15 14:17
7440-44-0
Total Organic Carbon
118000
mg/kg
8840
4420
1
05/06/15 14:26
7440-44-0
Total Organic Carbon
98800
mg/kg
9260
4630
1
05/06/15 14:33
7440-44-0
Mean Total Organic Carbon
104000
mg/kg
9010
4510
1
05/06/15 14:11
7440-44-0
Surrogates
RSD%
9.6
%
1
05/06/15 14:11
Date: 06/15/2015 07:34 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 42 of 103

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Pace Analytical Services, Inc.
980%EWWY2"�e. Suite 100
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[phone]
ANALYTICAL RESULTS
Project: J15040322
Pace Project No.: 92245627
Sample: 2015010706
Lab ID:
92245627004 Collected:
04/11/15 11:30
Received: 04/15/15 15:30 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample
size and any dilutions.
Report
Parameters
Results
Units Limit
MDL
DF
Prepared
Analyzed
CAS No.
Qual
6010 MET ICP
Analytical
Method: EPA 6010
Preparation
Method: EPA 3050
Aluminum
6260
mg/kg
30.3
15.1
5
04/21/15 14:40
04/25/15 23:26
7429-90-5
Barium
389
mg/kg
3.0
1.5
5
04/21/15 14:40
04/25/15 23:26
7440-39-3
Beryllium
1.4
mg/kg
0.30
0.15
5
04/21/15 14:40
04/25/15 23:26
7440-41-7
Boron
ND
mg/kg
15.1
7.6
5
04/21/15 14:40
04/25/15 23:26
7440-42-8
Calcium
1710
mg/kg
151
75.7
5
04/21/15 14:40
04/25/15 23:26
7440-70-2
Chromium
11.5
mg/kg
1.5
0.76
5
04/21/15 14:40
04/25/15 23:26
7440-47-3
Copper
25.7
mg/kg
1.5
0.76
5
04/21/15 14:40
04/25/15 23:26
7440-50-8
Iron
16800
mg/kg
12.1
6.1
5
04/21/15 14:40
04/25/15 23:26
7439-89-6
Magnesium
523
mg/kg
151
75.7
5
04/21/15 14:40
04/25/15 23:26
7439-95-4
Manganese
55.7
mg/kg
1.5
0.76
5
04/21/15 14:40
04/25/15 23:26
7439-96-5
Molybdenum
1.8J
mg/kg
3.0
1.5
5
04/21/15 14:40
04/25/15 23:26
7439-98-7
Nickel
16.1
mg/kg
7.6
3.8
25
04/21/15 14:40
04/25/1523:30
7440-02-0
D3
Potassium
1030
mg/kg
303
151
5
04/21/15 14:40
04/25/15 23:26
7440-09-7
Sodium
ND
mg/kg
303
151
5
04/21/15 14:40
04/25/15 23:26
7440-23-5
Strontium
135
mg/kg
3.0
1.5
5
04/21/15 14:40
04/25/15 23:26
7440-24-6
Zinc
14.5
mg/kg
6.1
3.0
5
04/21/15 14:40
04/25/15 23:26
7440-66-6
6020 MET ICPMS
Analytical
Method: EPA 6020
Preparation
Method: EPA 3050
Antimony
ND
mg/kg
6.1
3.0
100
04/21/15 14:40
04/26/1510:50
7440-36-0
N2
Arsenic
30.4
mg/kg
6.1
3.0
100
04/21/15 14:40
04/26/1510:50
7440-38-2
Cadmium
ND
mg/kg
0.73
0.36
100
04/21/15 14:40
04/26/1510:50
7440-43-9
Cobalt
6.5
mg/kg
6.1
3.0
100
04/21/15 14:40
04/26/1510:50
7440-48-4
Lead
5.5J
mg/kg
6.1
3.0
100
04/21/15 14:40
04/26/1510:50
7439-92-1
Selenium
7.1
mg/kg
6.1
3.0
100
04/21/15 14:40
04/26/1510:50
7782-49-2
Thallium
ND
mg/kg
6.1
3.0
100
04/21/15 14:40
04/26/1510:50
7440-28-0
Vanadium
25.8
mg/kg
6.1
3.0
100
04/21/15 14:40
04/26/1510:50
7440-62-2
7471 Mercury
Analytical
Method: EPA 7471
Preparation
Method: EPA 7471
Mercury
0.13
mg/kg 0.010
0.0050
1
04/21/15 21:00
04/22/15 13:03
7439-97-6
Percent Moisture
Analytical
Method: ASTM D2974-87
Percent Moisture
19.0
%
0.10
0.10
1
04/23/15 13:16
9045 pH Soil
Analytical
Method: EPA 9045
pH at 25 Degrees C
6.6
Std. Units
0.10
0.10
1
04/20/15 21:25
9056 IC Anions
Analytical
Method: EPA 9056
Chloride
ND
mg/kg
308
154
5
04/19/1515:41
16887-00-6
D3
Sulfate
ND
mg/kg
308
154
5
04/19/1515:41
14808-79-8
D3
9056 IC Anions 48hr
Analytical
Method: EPA 9056
Nitrate as N
ND
mg/kg
30.8
15.4
5
04/19/15 15:41
14797-55-8
H3
Date: 06/15/2015 07:34 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 43 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
98006Jf WYIW e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040322
Pace Project No.: 92245627
Sample: 2015010706
Lab ID:
92245627004
Collected:
04/11/15 11:30
Received: 04/15/15 15:30 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample
size and any dilutions.
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared Analyzed
CAS No. Qual
Total Organic Carbon Quad
Analytical
Method: EPA 9060
Total Organic Carbon
91300
mg/kg
6420
3210
1
05/06/15 15:32
7440-44-0
Total Organic Carbon
84700
mg/kg
6430
3210
1
05/06/15 15:39
7440-44-0
Total Organic Carbon
85100
mg/kg
6210
3100
1
05/06/15 15:46
7440-44-0
Total Organic Carbon
70700
mg/kg
6530
3260
1
05/06/15 15:52
7440-44-0
Mean Total Organic Carbon
82900
mg/kg
6390
3200
1
05/06/15 15:32
7440-44-0
Surrogates
RSD%
10.5
%
1
05/06/15 15:32
Date: 06/15/2015 07:34 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 44 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
98006Jf WYIW e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040322
Pace Project No.: 92245627
Sample: 2015010707 Lab ID: 92245627005 Collected: 04/11/15 15:05 Received: 04/15/15 15:30 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Aluminum
Barium
Beryllium
Boron
Calcium
Chromium
Copper
Iron
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Sodium
Strontium
Zinc
6020 MET ICPMS
Antimony
Arsenic
Cadmium
Cobalt
Lead
Selenium
Thallium
Vanadium
7471 Mercury
Mercury
Percent Moisture
Percent Moisture
9045 pH Soil
pH at 25 Degrees C
300.0 IC Anions, SPLP
Sulfate
353.2 Nitrogen, NO2/NO3, SPLP
Nitrogen, Nitrate
4500 Chloride, SPLP
Chloride
Date: 06/15/2015 07:34 AM
Analytical Method: EPA 6010 Preparation Method: EPA 3050
10700
mg/kg
34.8
17.4
5
04/21/15 14:40
04/25/15 23:38
7429-90-5
603
mg/kg
3.5
1.7
5
04/21/15 14:40
04/25/15 23:38
7440-39-3
3.4
mg/kg
0.35
0.17
5
04/21/15 14:40
04/25/15 23:38
7440-41-7
10.1J
mg/kg
17.4
8.7
5
04/21/15 14:40
04/25/15 23:38
7440-42-8
3830
mg/kg
174
87.1
5
04/21/15 14:40
04/25/15 23:38
7440-70-2
18.8
mg/kg
1.7
0.87
5
04/21/15 14:40
04/25/15 23:38
7440-47-3
34.2
mg/kg
1.7
0.87
5
04/21/15 14:40
04/25/15 23:38
7440-50-8
19100
mg/kg
13.9
7.0
5
04/21/15 14:40
04/25/15 23:38
7439-89-6
991
mg/kg
174
87.1
5
04/21/15 14:40
04/25/15 23:38
7439-95-4
93.5
mg/kg
1.7
0.87
5
04/21/15 14:40
04/25/15 23:38
7439-96-5
ND
mg/kg
3.5
1.7
5
04/21/15 14:40
04/25/15 23:38
7439-98-7
17.8
mg/kg
1.7
0.87
5
04/21/15 14:40
04/25/15 23:38
7440-02-0
1990
mg/kg
348
174
5
04/21/15 14:40
04/25/15 23:38
7440-09-7
352
mg/kg
348
174
5
04/21/15 14:40
04/25/15 23:38
7440-23-5
251
mg/kg
3.5
1.7
5
04/21/15 14:40
04/25/15 23:38
7440-24-6
15.1
mg/kg
7.0
3.5
5
04/21/15 14:40
04/25/15 23:38
7440-66-6
Analytical
Method: EPA 6020 Preparation
Method: EPA 3050
ND
mg/kg
7.0
3.5
100
04/21/15 14:40
04/26/1510:54
7440-36-0
44.0
mg/kg
7.0
3.5
100
04/21/15 14:40
04/26/1510:54
7440-38-2
ND
mg/kg
0.84
0.42
100
04/21/15 14:40
04/26/1510:54
7440-43-9
9.5
mg/kg
7.0
3.5
100
04/21/15 14:40
04/26/1510:54
7440-48-4
11.5
mg/kg
7.0
3.5
100
04/21/15 14:40
04/26/1510:54
7439-92-1
8.8
mg/kg
7.0
3.5
100
04/21/15 14:40
04/26/1510:54
7782-49-2
ND
mg/kg
7.0
3.5
100
04/21/15 14:40
04/26/1510:54
7440-28-0
40.5
mg/kg
7.0
3.5
100
04/21/15 14:40
04/26/15 10:54
7440-62-2
Analytical Method: EPA 7471 Preparation Method: EPA 7471
0.10 mg/kg 0.011 0.0056 1 04/21/15 21:00 04/22/15 13:05 7439-97-6
Analytical Method: ASTM D2974-87
26.9 % 0.10 0.10 1 04/23/1513:16
Analytical Method: EPA 9045
7.5 Std. Units 0.10 0.10 1 04/20/15 21:25
N2
Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 04/16/15 03:15
12.6 mg/L 2.7 1.4 1 04/29/1515:03 14808-79-8 B
Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 04/16/15 03:15
ND mg/L 0.27 0.27 1 04/29/15 20:58 H1
Analytical Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 04/16/15 03:15
ND mg/L 6.8 3.4 1 04/30/15 01:43 16887-00-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 45 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
98006} WMI� e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040322
Pace Project No.: 92245627
Sample: 2015010707 Lab ID: 92245627005 Collected: 04/11/15 15:05 Received: 04/15/15 15:30 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
9056 IC Anions Analytical Method: EPA 9056
Chloride
ND mg/kg
343
171
5
04/19/15 09:59
16887-00-6 D3
Sulfate
209J mg/kg
343
171
5
04/19/15 09:59
14808-79-8 D3
9056 IC Anions 48hr
Analytical Method: EPA 9056
Nitrate as N
ND mg/kg
34.3
17.1
5
04/19/15 09:59
14797-55-8 H3
Total Organic Carbon Quad
Analytical Method: EPA 9060
Total Organic Carbon
50200 mg/kg
3970
1980
1
05/06/15 16:55
7440-44-0
Total Organic Carbon
72500 mg/kg
3990
1990
1
05/06/15 17:02
7440-44-0
Total Organic Carbon
51200 mg/kg
3920
1960
1
05/06/15 17:09
7440-44-0
Total Organic Carbon
71200 mg/kg
3940
1970
1
05/06/15 17:15
7440-44-0
Mean Total Organic Carbon
61300 mg/kg
3950
1980
1
05/06/15 16:55
7440-44-0
Surrogates
RSD%
20.0 %
1
05/06/15 16:55
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2015 07:34 AM without the written consent of Pace Analytical Services, Inc..
Page 46 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980%&WYI�e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040322
Pace Project No.: 92245627
Sample: 2015010708 Lab ID: 92245627006 Collected: 04/11/15 15:35 Received: 04/15/15 15:30 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Aluminum
Barium
Beryllium
Boron
Calcium
Chromium
Copper
Iron
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Sodium
Strontium
Zinc
6020 MET ICPMS
Antimony
Arsenic
Cadmium
Cobalt
Lead
Selenium
Thallium
Vanadium
7471 Mercury
Mercury
Percent Moisture
Percent Moisture
9045 pH Soil
pH at 25 Degrees C
300.0 IC Anions, SPLP
Sulfate
353.2 Nitrogen, NO2/NO3, SPLP
Nitrogen, Nitrate
4500 Chloride, SPLP
Chloride
Date: 06/15/2015 07:34 AM
Analytical Method: EPA 6010 Preparation Method: EPA 3050
18200
mg/kg
33.6
16.8
5
04/21/15 14:40
04/25/15 23:42
7429-90-5
178
mg/kg
3.4
1.7
5
04/21/15 14:40
04/25/15 23:42
7440-39-3
0.89
mg/kg
0.34
0.17
5
04/21/15 14:40
04/25/15 23:42
7440-41-7
ND
mg/kg
16.8
8.4
5
04/21/15 14:40
04/25/15 23:42
7440-42-8
1970
mg/kg
168
84.1
5
04/21/15 14:40
04/25/15 23:42
7440-70-2
23.3
mg/kg
1.7
0.84
5
04/21/15 14:40
04/25/15 23:42
7440-47-3
21.9
mg/kg
1.7
0.84
5
04/21/15 14:40
04/25/15 23:42
7440-50-8
43700
mg/kg
13.5
6.7
5
04/21/15 14:40
04/25/15 23:42
7439-89-6
3950
mg/kg
168
84.1
5
04/21/15 14:40
04/25/15 23:42
7439-95-4
512
mg/kg
1.7
0.84
5
04/21/15 14:40
04/25/15 23:42
7439-96-5
ND
mg/kg
3.4
1.7
5
04/21/15 14:40
04/25/15 23:42
7439-98-7
14.7
mg/kg
1.7
0.84
5
04/21/15 14:40
04/25/15 23:42
7440-02-0
250J
mg/kg
336
168
5
04/21/15 14:40
04/25/15 23:42
7440-09-7
ND
mg/kg
336
168
5
04/21/15 14:40
04/25/15 23:42
7440-23-5
28.1
mg/kg
3.4
1.7
5
04/21/15 14:40
04/25/15 23:42
7440-24-6
59.9
mg/kg
6.7
3.4
5
04/21/15 14:40
04/25/15 23:42
7440-66-6
Analytical
Method: EPA 6020 Preparation
Method: EPA 3050
ND
mg/kg
6.7
3.4
100
04/21/15 14:40
04/26/1510:57
7440-36-0
5.1J
mg/kg
6.7
3.4
100
04/21/15 14:40
04/26/1510:57
7440-38-2
ND
mg/kg
0.81
0.40
100
04/21/15 14:40
04/26/1510:57
7440-43-9
11.4
mg/kg
6.7
3.4
100
04/21/15 14:40
04/26/1510:57
7440-48-4
9.0
mg/kg
6.7
3.4
100
04/21/15 14:40
04/26/1510:57
7439-92-1
ND
mg/kg
6.7
3.4
100
04/21/15 14:40
04/26/1510:57
7782-49-2
ND
mg/kg
6.7
3.4
100
04/21/15 14:40
04/26/1510:57
7440-28-0
62.1
mg/kg
6.7
3.4
100
04/21/15 14:40
04/26/15 10:57
7440-62-2
Analytical Method: EPA 7471 Preparation Method: EPA 7471
0.032 mg/kg 0.010 0.0052 1 04/21/15 21:00 04/22/15 13:07 7439-97-6
Analytical Method: ASTM D2974-87
22.9 % 0.10 0.10 1 04/23/1513:16
Analytical Method: EPA 9045
7.0 Std. Units 0.10 0.10 1 04/20/15 21:25
N2
Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 04/16/15 03:15
5.3 mg/L 2.6 1.3 1 04/29/1515:43 14808-79-8 B
Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 04/16/15 03:15
ND mg/L 0.26 0.26 1 04/29/15 21:02 H1
Analytical Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 04/16/15 03:15
15.2 mg/L 6.5 3.2 1 04/30/15 01:43 16887-00-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 47 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
98406MI6 e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040322
Pace Project No.: 92245627
Sample: 2015010708 Lab ID: 92245627006 Collected: 04/11/15 15:35 Received: 04/15/15 15:30 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
9056 IC Anions Analytical Method: EPA 9056
Chloride
ND mg/kg
322
161
5
04/19/1510:20
16887-00-6 D3
Sulfate
ND mg/kg
322
161
5
04/19/1510:20
14808-79-8 D3
9056 IC Anions 48hr
Analytical Method: EPA 9056
Nitrate as N
ND mg/kg
32.2
16.1
5
04/19/15 10:20
14797-55-8 H3
Total Organic Carbon Quad
Analytical Method: EPA 9060
Total Organic Carbon
1080 mg/kg
773
386
1
05/06/15 17:27
7440-44-0
Total Organic Carbon
1160 mg/kg
779
389
1
05/06/15 17:34
7440-44-0
Total Organic Carbon
977 mg/kg
779
389
1
05/06/15 17:40
7440-44-0
Total Organic Carbon
959 mg/kg
772
386
1
05/06/15 17:45
7440-44-0
Mean Total Organic Carbon
1040 mg/kg
776
388
1
05/06/15 17:27
7440-44-0
Surrogates
RSD%
9.1 %
1
05/06/15 17:27
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2015 07:34 AM without the written consent of Pace Analytical Services, Inc..
Page 48 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
98006J WYIW e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040322
Pace Project No.: 92245627
Sample: 2015010709 Lab ID: 92245627007 Collected: 04/13/15 13:25 Received: 04/15/15 15:30 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Aluminum
Barium
Beryllium
Boron
Calcium
Chromium
Copper
Iron
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Sodium
Strontium
Zinc
6020 MET ICPMS
Antimony
Arsenic
Cadmium
Cobalt
Lead
Selenium
Thallium
Vanadium
7471 Mercury
Mercury
Percent Moisture
Percent Moisture
9045 pH Soil
pH at 25 Degrees C
300.0 IC Anions, SPLP
Sulfate
353.2 Nitrogen, NO2/NO3, SPLP
Nitrogen, Nitrate
4500 Chloride, SPLP
Chloride
Date: 06/15/2015 07:34 AM
Analytical Method: EPA 6010 Preparation Method: EPA 3050
4550
mg/kg
33.0
16.5
5
04/21/15 14:40
04/25/15 23:46
7429-90-5
24.3
mg/kg
3.3
1.6
5
04/21/15 14:40
04/25/15 23:46
7440-39-3
0.20J
mg/kg
0.33
0.16
5
04/21/15 14:40
04/25/15 23:46
7440-41-7
ND
mg/kg
16.5
8.2
5
04/21/15 14:40
04/25/15 23:46
7440-42-8
633
mg/kg
165
82.5
5
04/21/15 14:40
04/25/15 23:46
7440-70-2
9.9
mg/kg
1.6
0.82
5
04/21/15 14:40
04/25/15 23:46
7440-47-3
5.7
mg/kg
1.6
0.82
5
04/21/15 14:40
04/25/15 23:46
7440-50-8
7310
mg/kg
13.2
6.6
5
04/21/15 14:40
04/25/15 23:46
7439-89-6
1360
mg/kg
165
82.5
5
04/21/15 14:40
04/25/15 23:46
7439-95-4
83.0
mg/kg
1.6
0.82
5
04/21/15 14:40
04/25/15 23:46
7439-96-5
ND
mg/kg
3.3
1.6
5
04/21/15 14:40
04/25/15 23:46
7439-98-7
4.5
mg/kg
1.6
0.82
5
04/21/15 14:40
04/25/15 23:46
7440-02-0
ND
mg/kg
330
165
5
04/21/15 14:40
04/25/15 23:46
7440-09-7
ND
mg/kg
330
165
5
04/21/15 14:40
04/25/15 23:46
7440-23-5
6.1
mg/kg
3.3
1.6
5
04/21/15 14:40
04/25/15 23:46
7440-24-6
19.0
mg/kg
6.6
3.3
5
04/21/15 14:40
04/25/15 23:46
7440-66-6
Analytical
Method: EPA 6020 Preparation
Method: EPA 3050
ND
mg/kg
6.6
3.3
100
04/21/15 14:40
04/26/1510:59
7440-36-0
ND
mg/kg
6.6
3.3
100
04/21/15 14:40
04/26/1510:59
7440-38-2
ND
mg/kg
0.79
0.40
100
04/21/15 14:40
04/26/1510:59
7440-43-9
4.2J
mg/kg
6.6
3.3
100
04/21/15 14:40
04/26/1510:59
7440-48-4
4.OJ
mg/kg
6.6
3.3
100
04/21/15 14:40
04/26/1510:59
7439-92-1
ND
mg/kg
6.6
3.3
100
04/21/15 14:40
04/26/1510:59
7782-49-2
ND
mg/kg
6.6
3.3
100
04/21/15 14:40
04/26/1510:59
7440-28-0
18.9
mg/kg
6.6
3.3
100
04/21/15 14:40
04/26/15 10:59
7440-62-2
Analytical Method: EPA 7471 Preparation Method: EPA 7471
ND mg/kg 0.011 0.0053 1 04/21/15 21:00 04/22/15 13:09 7439-97-6
Analytical Method: ASTM D2974-87
25.5 % 0.10 0.10 1 04/23/1513:16
Analytical Method: EPA 9045
6.1 Std. Units 0.10 0.10 1 04/20/15 21:25
N2
Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 04/16/15 03:15
6.3 mg/L 2.7 1.3 1 04/29/1515:57 14808-79-8 B
Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 04/16/15 03:15
ND mg/L 0.27 0.27 1 04/29/15 21:03 H1
Analytical Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 04/16/15 03:15
7.3 mg/L 6.7 3.4 1 04/30/15 01:44 16887-00-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 49 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800649WMI�e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040322
Pace Project No.: 92245627
Sample: 2015010709 Lab ID: 92245627007 Collected: 04/13/15 13:25 Received: 04/15/15 15:30 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
9056 IC Anions Analytical Method: EPA 9056
Chloride
ND mg/kg
336
168
5
04/19/1510:41
16887-00-6 D3
Sulfate
ND mg/kg
336
168
5
04/19/1510:41
14808-79-8 D3
9056 IC Anions 48hr
Analytical Method: EPA 9056
Nitrate as N
ND mg/kg
33.6
16.8
5
04/19/15 10:41
14797-55-8 H1
Total Organic Carbon Quad
Analytical Method: EPA 9060
Total Organic Carbon
1800 mg/kg
804
402
1
05/06/15 18:32
7440-44-0
Total Organic Carbon
2010 mg/kg
809
404
1
05/06/15 18:38
7440-44-0
Total Organic Carbon
1660 mg/kg
799
399
1
05/06/15 18:44
7440-44-0
Total Organic Carbon
1810 mg/kg
805
403
1
05/06/15 18:51
7440-44-0
Mean Total Organic Carbon
1820 mg/kg
804
402
1
05/06/15 18:32
7440-44-0
Surrogates
RSD%
7.9 %
1
05/06/15 18:32
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2015 07:34 AM without the written consent of Pace Analytical Services, Inc..
Page 50 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 WY2"Y e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040322
Pace Project No.: 92245627
Sample: 2015010710 Lab ID: 92245627008 Collected: 04/13/15 15:45 Received: 04/15/15 15:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
;I➢ZI7c\�i,I=11 l[99�r 6?
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Sodium
Strontium
Thallium
Vanadium
Zinc
7470 Mercury
Mercury
Date: 06/15/2015 07:34 AM
Analytical Method: EPA 6020A Preparation Method: EPA 3020
10500
ug/L
10.0
3.0
1
04/20/15 06:33
04/21/15 05:03
7429-90-5
0.16J
ug/L
0.50
0.15
1
04/20/15 06:33
04/21/15 05:03
7440-36-0
4.7
ug/L
0.50
0.11
1
04/20/15 06:33
04/21/15 05:03
7440-38-2
125
ug/L
0.30
0.081
1
04/20/15 06:33
04/21/15 05:03
7440-39-3
0.69
ug/L
0.20
0.067
1
04/20/15 06:33
04/21/15 05:03
7440-41-7
14.4
ug/L
5.0
1.1
1
04/20/15 06:33
04/21/15 05:03
7440-42-8
0.076J
ug/L
0.080
0.024
1
04/20/15 06:33
04/21/15 05:03
7440-43-9
117000
ug/L
400
160
10
04/20/15 06:33
04/21/15 13:06
7440-70-2
19.4
ug/L
0.50
0.17
1
04/20/15 06:33
04/21/15 05:03
7440-47-3
5.4
ug/L
0.50
0.13
1
04/20/15 06:33
04/21/15 05:03
7440-48-4
11.4
ug/L
1.0
0.21
1
04/20/15 06:33
04/21/15 05:03
7440-50-8
11300
ug/L
50.0
13.7
1
04/20/15 06:33
04/21/15 05:03
7439-89-6
6.7
ug/L
0.10
0.046
1
04/20/15 06:33
04/21/15 05:03
7439-92-1
4850
ug/L
10.0
3.2
1
04/20/15 06:33
04/21/15 05:03
7439-95-4
382
ug/L
0.50
0.24
1
04/20/15 06:33
04/21/15 05:03
7439-96-5
1.6
ug/L
0.50
0.094
1
04/20/15 06:33
04/21/15 05:03
7439-98-7
12.6
ug/L
0.50
0.16
1
04/20/15 06:33
04/21/15 05:03
7440-02-0
2860
ug/L
50.0
11.7
1
04/20/15 06:33
04/21/15 05:03
7440-09-7
1.2
ug/L
0.50
0.20
1
04/20/15 06:33
04/21/15 05:03
7782-49-2
1430
ug/L
50.0
16.3
1
04/20/15 06:33
04/21/15 05:03
7440-23-5
235
ug/L
0.50
0.13
1
04/20/15 06:33
04/21/15 05:03
7440-24-6
0.0801
ug/L
0.10
0.015
1
04/20/15 06:33
04/21/15 05:03
7440-28-0
29.4
ug/L
1.0
0.28
1
04/20/15 06:33
04/21/15 05:03
7440-62-2
61.6
ug/L
5.0
2.4
1
04/20/15 06:33
04/21/15 05:03
7440-66-6
Analytical Method: EPA 7470 Preparation Method: EPA 7470
ND ug/L 0.20 0.022 1 04/20/15 11:15 04/20/15 20:11 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 51 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
98007t WYIW e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040322
Pace Project No.: 92245627
Sample: 2015010711 Lab ID: 92245627009 Collected: 04/13/15 17:15 Received: 04/15/15 15:30 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Aluminum
Barium
Beryllium
Boron
Calcium
Chromium
Copper
Iron
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Sodium
Strontium
Zinc
6020 MET ICPMS
Antimony
Arsenic
Cadmium
Cobalt
Lead
Selenium
Thallium
Vanadium
7471 Mercury
Mercury
Percent Moisture
Percent Moisture
9045 pH Soil
pH at 25 Degrees C
9056 IC Anions
Chloride
Sulfate
9056 IC Anions 48hr
Nitrate as N
Date: 06/15/2015 07:34 AM
Analytical Method: EPA 6010 Preparation Method: EPA 3050
14100
mg/kg
41.2
20.6
5
04/21/15 14:40
04/25/15 23:50
7429-90-5
60.2
mg/kg
4.1
2.1
5
04/21/15 14:40
04/25/15 23:50
7440-39-3
0.59
mg/kg
0.41
0.21
5
04/21/15 14:40
04/25/15 23:50
7440-41-7
ND
mg/kg
20.6
10.3
5
04/21/15 14:40
04/25/15 23:50
7440-42-8
382
mg/kg
206
103
5
04/21/15 14:40
04/25/15 23:50
7440-70-2
28.7
mg/kg
2.1
1.0
5
04/21/15 14:40
04/25/15 23:50
7440-47-3
15.8
mg/kg
2.1
1.0
5
04/21/15 14:40
04/25/15 23:50
7440-50-8
14200
mg/kg
16.5
8.2
5
04/21/15 14:40
04/25/15 23:50
7439-89-6
1950
mg/kg
206
103
5
04/21/15 14:40
04/25/15 23:50
7439-95-4
249
mg/kg
2.1
1.0
5
04/21/15 14:40
04/25/15 23:50
7439-96-5
ND
mg/kg
4.1
2.1
5
04/21/15 14:40
04/25/15 23:50
7439-98-7
5.9
mg/kg
2.1
1.0
5
04/21/15 14:40
04/25/15 23:50
7440-02-0
ND
mg/kg
412
206
5
04/21/15 14:40
04/25/15 23:50
7440-09-7
ND
mg/kg
412
206
5
04/21/15 14:40
04/25/15 23:50
7440-23-5
7.7
mg/kg
4.1
2.1
5
04/21/15 14:40
04/25/15 23:50
7440-24-6
35.2
mg/kg
8.2
4.1
5
04/21/15 14:40
04/25/15 23:50
7440-66-6
Analytical
Method: EPA 6020 Preparation
Method: EPA 3050
ND
mg/kg
8.2
4.1
100
04/21/15 14:40
04/26/1511:01
7440-36-0
ND
mg/kg
8.2
4.1
100
04/21/15 14:40
04/26/1511:01
7440-38-2
0.54J
mg/kg
0.99
0.49
100
04/21/15 14:40
04/26/1511:01
7440-43-9
7.5J
mg/kg
8.2
4.1
100
04/21/15 14:40
04/26/1511:01
7440-48-4
6.9J
mg/kg
8.2
4.1
100
04/21/15 14:40
04/26/1511:01
7439-92-1
ND
mg/kg
8.2
4.1
100
04/21/15 14:40
04/26/1511:01
7782-49-2
ND
mg/kg
8.2
4.1
100
04/21/15 14:40
04/26/1511:01
7440-28-0
31.8
mg/kg
8.2
4.1
100
04/21/15 14:40
04/26/15 11:01
7440-62-2
Analytical Method: EPA 7471 Preparation Method: EPA 7471
0.038 mg/kg 0.014 0.0068 1 04/21/15 21:00 04/22/15 13:12 7439-97-6
Analytical Method: ASTM D2974-87
40.2 % 0.10 0.10 1 04/23/1513:17
Analytical Method: EPA 9045
4.2 Std. Units
0.10
0.10 1
Analytical Method: EPA 9056
ND mg/kg
409
204 5
ND mg/kg
409
204 5
Analytical Method: EPA 9056
ND mg/kg
40.9
20.4 5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
,81APIi1f601111.7
N2
I:fl
04/19/1511:03 16887-00-6 D3
04/19/1511:03 14808-79-8 D3
04/19/1511:03 14797-55-8 H3
Page 52 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800AIMI� e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040322
Pace Project No.: 92245627
Sample: 2015010711
Lab ID:
92245627009
Collected:
04/13/15 17:15
Received: 04/15/15 15:30 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample
size and any dilutions.
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared Analyzed
CAS No. Qual
Total Organic Carbon Quad
Analytical
Method: EPA 9060
Total Organic Carbon
1530
mg/kg
1000
502
1
05/06/15 18:56
7440-44-0
Total Organic Carbon
1500
mg/kg
999
500
1
05/06/15 19:03
7440-44-0
Total Organic Carbon
1480
mg/kg
996
498
1
05/06/15 19:10
7440-44-0
Total Organic Carbon
1460
mg/kg
994
497
1
05/06/15 19:15
7440-44-0
Mean Total Organic Carbon
1490
mg/kg
998
499
1
05/06/15 18:56
7440-44-0
Surrogates
RSD%
2.0
%
1
05/06/15 18:56
Date: 06/15/2015 07:34 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 53 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 WYIW e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040322
Pace Project No.: 92245627
Sample: 2015010712 Lab ID: 92245627010 Collected: 04/13/15 16:00 Received: 04/15/15 15:30 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Aluminum
Barium
Beryllium
Boron
Calcium
Chromium
Copper
Iron
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Sodium
Strontium
Zinc
6020 MET ICPMS
Antimony
Arsenic
Cadmium
Cobalt
Lead
Selenium
Thallium
Vanadium
7471 Mercury
Mercury
Percent Moisture
Percent Moisture
9045 pH Soil
pH at 25 Degrees C
300.0 IC Anions, SPLP
Sulfate
353.2 Nitrogen, NO2/NO3, SPLP
Nitrogen, Nitrate
4500 Chloride, SPLP
Chloride
Date: 06/15/2015 07:34 AM
Analytical Method: EPA 6010 Preparation Method: EPA 3050
10700
mg/kg
31.0
15.5
5
04/21/15 14:40
04/25/15 23:54
7429-90-5
173
mg/kg
3.1
1.6
5
04/21/15 14:40
04/25/15 23:54
7440-39-3
2.2
mg/kg
0.31
0.16
5
04/21/15 14:40
04/25/15 23:54
7440-41-7
10.6J
mg/kg
15.5
7.8
5
04/21/15 14:40
04/25/15 23:54
7440-42-8
2660
mg/kg
155
77.6
5
04/21/15 14:40
04/25/15 23:54
7440-70-2
14.2
mg/kg
1.6
0.78
5
04/21/15 14:40
04/25/15 23:54
7440-47-3
26.6
mg/kg
1.6
0.78
5
04/21/15 14:40
04/25/15 23:54
7440-50-8
23600
mg/kg
12.4
6.2
5
04/21/15 14:40
04/25/15 23:54
7439-89-6
2250
mg/kg
155
77.6
5
04/21/15 14:40
04/25/15 23:54
7439-95-4
220
mg/kg
1.6
0.78
5
04/21/15 14:40
04/25/15 23:54
7439-96-5
9.0
mg/kg
3.1
1.6
5
04/21/15 14:40
04/25/15 23:54
7439-98-7
19.1
mg/kg
1.6
0.78
5
04/21/15 14:40
04/25/15 23:54
7440-02-0
1530
mg/kg
310
155
5
04/21/15 14:40
04/25/15 23:54
7440-09-7
ND
mg/kg
310
155
5
04/21/15 14:40
04/25/15 23:54
7440-23-5
83.4
mg/kg
3.1
1.6
5
04/21/15 14:40
04/25/15 23:54
7440-24-6
48.2
mg/kg
6.2
3.1
5
04/21/15 14:40
04/25/15 23:54
7440-66-6
Analytical
Method: EPA 6020
Preparation Method: EPA 3050
ND
mg/kg
6.2
3.1
100
04/21/15 14:40
04/26/1511:03
7440-36-0
N2
20.5
mg/kg
6.2
3.1
100
04/21/15 14:40
04/26/1511:03
7440-38-2
ND
mg/kg
0.74
0.37
100
04/21/15 14:40
04/26/1511:03
7440-43-9
12.6
mg/kg
6.2
3.1
100
04/21/15 14:40
04/26/1511:03
7440-48-4
22.6
mg/kg
6.2
3.1
100
04/21/15 14:40
04/26/1511:03
7439-92-1
12.0
mg/kg
6.2
3.1
100
04/21/15 14:40
04/26/1511:03
7782-49-2
ND
mg/kg
6.2
3.1
100
04/21/15 14:40
04/26/1511:03
7440-28-0
51.5
mg/kg
6.2
3.1
100
04/21/15 14:40
04/26/15 11:03
7440-62-2
Analytical
Method: EPA 7471
Preparation Method: EPA 7471
0.24
mg/kg 0.010
0.0050
1
04/21/15 21:00
04/22/15 13:14
7439-97-6
Analytical
Method: ASTM D2974-87
17.9
%
0.10
0.10
1
04/23/1513:17
Analytical
Method: EPA 9045
6.3
Std. Units
0.10
0.10
1
04/21/15 11:55
H1
Analytical
Method: EPA 300.0 Leachate Method/Date:
EPA 1312; 04/16/15
03:15
13.8
mg/L
2.4
1.2
1
04/29/1516:11
14808-79-8
B
Analytical
Method: EPA 353.2 Leachate Method/Date:
EPA 1312; 04/16/15
03:15
ND
mg/L
0.24
0.24
1
04/29/15 21:04
H1
Analytical
Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 04/16/15 03:15
ND
mg/L
6.1
3.0
1
04/30/15 01:46
16887-00-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 54 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980WWYIW e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040322
Pace Project No.: 92245627
Sample: 2015010712 Lab ID: 92245627010 Collected: 04/13/15 16:00 Received: 04/15/15 15:30 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
9056 IC Anions Analytical Method: EPA 9056
Chloride
ND mg/kg
305
152
5
04/19/1511:25
16887-00-6 D3
Sulfate
ND mg/kg
305
152
5
04/19/1511:25
14808-79-8 D3
9056 IC Anions 48hr
Analytical Method: EPA 9056
Nitrate as N
ND mg/kg
30.5
15.2
5
04/19/15 11:25
14797-55-8 H3
Total Organic Carbon Quad
Analytical Method: EPA 9060
Total Organic Carbon
112000 mg/kg
5850
2930
1
05/06/15 19:21
7440-44-0
Total Organic Carbon
114000 mg/kg
5640
2820
1
05/06/15 19:31
7440-44-0
Total Organic Carbon
101000 mg/kg
5750
2870
1
05/06/15 19:37
7440-44-0
Total Organic Carbon
82500 mg/kg
5550
2780
1
05/06/15 19:43
7440-44-0
Mean Total Organic Carbon
102000 mg/kg
5700
2850
1
05/06/15 19:21
7440-44-0
Surrogates
RSD%
14.1 %
1
05/06/15 19:21
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2015 07:34 AM without the written consent of Pace Analytical Services, Inc..
Page 55 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
98007VWYI�e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040322
Pace Project No.: 92245627
Sample: 2015010713 Lab ID: 92245627011 Collected: 04/13/15 17:00 Received: 04/15/15 15:30 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Aluminum
Barium
Beryllium
Boron
Calcium
Chromium
Copper
Iron
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Sodium
Strontium
Zinc
6020 MET ICPMS
Antimony
Arsenic
Cadmium
Cobalt
Lead
Selenium
Thallium
Vanadium
7471 Mercury
Mercury
Percent Moisture
Percent Moisture
9045 pH Soil
pH at 25 Degrees C
9056 IC Anions
Chloride
Sulfate
9056 IC Anions 48hr
Nitrate as N
Date: 06/15/2015 07:34 AM
Analytical Method: EPA 6010 Preparation Method: EPA 3050
8180
mg/kg
42.8
21.4
5
04/21/15 14:40
04/25/15 23:58
7429-90-5
162
mg/kg
4.3
2.1
5
04/21/15 14:40
04/25/15 23:58
7440-39-3
2.7
mg/kg
0.43
0.21
5
04/21/15 14:40
04/25/15 23:58
7440-41-7
23.4
mg/kg
21.4
10.7
5
04/21/15 14:40
04/25/15 23:58
7440-42-8
2150
mg/kg
214
107
5
04/21/15 14:40
04/25/15 23:58
7440-70-2
14.2
mg/kg
2.1
1.1
5
04/21/15 14:40
04/25/15 23:58
7440-47-3
33.1
mg/kg
2.1
1.1
5
04/21/15 14:40
04/25/15 23:58
7440-50-8
5960
mg/kg
17.1
8.6
5
04/21/15 14:40
04/25/15 23:58
7439-89-6
581
mg/kg
214
107
5
04/21/15 14:40
04/25/15 23:58
7439-95-4
26.0
mg/kg
2.1
1.1
5
04/21/15 14:40
04/25/15 23:58
7439-96-5
16.1
mg/kg
4.3
2.1
5
04/21/15 14:40
04/25/15 23:58
7439-98-7
22.2
mg/kg
2.1
1.1
5
04/21/15 14:40
04/25/15 23:58
7440-02-0
1180
mg/kg
428
214
5
04/21/15 14:40
04/25/15 23:58
7440-09-7
ND
mg/kg
428
214
5
04/21/15 14:40
04/25/15 23:58
7440-23-5
98.8
mg/kg
4.3
2.1
5
04/21/15 14:40
04/25/15 23:58
7440-24-6
25.9
mg/kg
8.6
4.3
5
04/21/15 14:40
04/25/15 23:58
7440-66-6
Analytical
Method: EPA 6020 Preparation
Method: EPA 3050
ND
mg/kg
8.6
4.3
100
04/21/15 14:40
04/26/1511:05
7440-36-0
37.8
mg/kg
8.6
4.3
100
04/21/15 14:40
04/26/1511:05
7440-38-2
ND
mg/kg
1.0
0.51
100
04/21/15 14:40
04/26/1511:05
7440-43-9
12.6
mg/kg
8.6
4.3
100
04/21/15 14:40
04/26/1511:05
7440-48-4
14.8
mg/kg
8.6
4.3
100
04/21/15 14:40
04/26/1511:05
7439-92-1
18.8
mg/kg
8.6
4.3
100
04/21/15 14:40
04/26/1511:05
7782-49-2
ND
mg/kg
8.6
4.3
100
04/21/15 14:40
04/26/1511:05
7440-28-0
59.6
mg/kg
8.6
4.3
100
04/21/15 14:40
04/26/15 11:05
7440-62-2
Analytical Method: EPA 7471 Preparation Method: EPA 7471
0.44 mg/kg 0.013 0.0066 1 04/21/15 21:00 04/22/15 13:20 7439-97-6
Analytical Method: ASTM D2974-87
40.1 % 0.10 0.10 1 04/23/1513:17
Analytical Method: EPA 9045
7.7 Std. Units
0.10
0.10 1
Analytical Method: EPA 9056
ND mg/kg
417
208 5
ND mg/kg
417
208 5
Analytical Method: EPA 9056
ND mg/kg
41.7
20.8 5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
,81APIi1f601111.7
N2
I:fl
04/19/1511:46 16887-00-6 D3
04/19/1511:46 14808-79-8 D3
04/19/1511:46 14797-55-8 H3
Page 56 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
98008WMI� e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040322
Pace Project No.: 92245627
Sample: 2015010713
Lab ID:
92245627011
Collected:
04/13/15 17:00
Received: 04/15/15 15:30 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample
size and any dilutions.
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared Analyzed
CAS No. Qual
Total Organic Carbon Quad
Analytical
Method: EPA 9060
Total Organic Carbon
91000
mg/kg
5200
2600
1
05/06/15 19:49
7440-44-0
Total Organic Carbon
58800
mg/kg
5030
2520
1
05/06/15 19:56
7440-44-0
Total Organic Carbon
83600
mg/kg
5210
2600
1
05/06/15 20:01
7440-44-0
Total Organic Carbon
109000
mg/kg
5170
2590
1
05/06/15 20:08
7440-44-0
Mean Total Organic Carbon
85600
mg/kg
5150
2580
1
05/06/15 19:49
7440-44-0
Surrogates
RSD%
24.4
%
1
05/06/15 19:49
Date: 06/15/2015 07:34 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 57 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980WWYIW e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040322
Pace Project No.: 92245627
Sample: 2015010714 Lab ID: 92245627012 Collected: 04/13/15 17:30 Received: 04/15/15 15:30 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Aluminum
Barium
Beryllium
Boron
Calcium
Chromium
Copper
Iron
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Sodium
Strontium
Zinc
6020 MET ICPMS
Antimony
Arsenic
Cadmium
Cobalt
Lead
Selenium
Thallium
Vanadium
7471 Mercury
Mercury
Percent Moisture
Percent Moisture
9045 pH Soil
pH at 25 Degrees C
9056 IC Anions
Chloride
Sulfate
9056 IC Anions 48hr
Nitrate as N
Date: 06/15/2015 07:34 AM
Analytical Method: EPA 6010 Preparation Method: EPA 3050
11500
mg/kg
36.7
18.3
5
04/21/15 14:40
04/26/15 00:02
7429-90-5
159
mg/kg
3.7
1.8
5
04/21/15 14:40
04/26/15 00:02
7440-39-3
0.97
mg/kg
0.37
0.18
5
04/21/15 14:40
04/26/15 00:02
7440-41-7
9.3J
mg/kg
18.3
9.2
5
04/21/15 14:40
04/26/15 00:02
7440-42-8
2160
mg/kg
183
91.7
5
04/21/15 14:40
04/26/15 00:02
7440-70-2
19.9
mg/kg
1.8
0.92
5
04/21/15 14:40
04/26/15 00:02
7440-47-3
48.9
mg/kg
1.8
0.92
5
04/21/15 14:40
04/26/15 00:02
7440-50-8
22600
mg/kg
14.7
7.3
5
04/21/15 14:40
04/26/15 00:02
7439-89-6
1450
mg/kg
183
91.7
5
04/21/15 14:40
04/26/15 00:02
7439-95-4
123
mg/kg
1.8
0.92
5
04/21/15 14:40
04/26/15 00:02
7439-96-5
56.9
mg/kg
3.7
1.8
5
04/21/15 14:40
04/26/15 00:02
7439-98-7
11.2
mg/kg
1.8
0.92
5
04/21/15 14:40
04/26/15 00:02
7440-02-0
896
mg/kg
367
183
5
04/21/15 14:40
04/26/15 00:02
7440-09-7
ND
mg/kg
367
183
5
04/21/15 14:40
04/26/15 00:02
7440-23-5
102
mg/kg
3.7
1.8
5
04/21/15 14:40
04/26/15 00:02
7440-24-6
43.4
mg/kg
7.3
3.7
5
04/21/15 14:40
04/26/15 00:02
7440-66-6
Analytical
Method: EPA 6020 Preparation
Method: EPA 3050
ND
mg/kg
7.3
3.7
100
04/21/15 14:40
04/26/1511:08
7440-36-0
95.1
mg/kg
7.3
3.7
100
04/21/15 14:40
04/26/1511:08
7440-38-2
ND
mg/kg
0.88
0.44
100
04/21/15 14:40
04/26/1511:08
7440-43-9
6.8J
mg/kg
7.3
3.7
100
04/21/15 14:40
04/26/1511:08
7440-48-4
49.5
mg/kg
7.3
3.7
100
04/21/15 14:40
04/26/1511:08
7439-92-1
4AJ
mg/kg
7.3
3.7
100
04/21/15 14:40
04/26/1511:08
7782-49-2
ND
mg/kg
7.3
3.7
100
04/21/15 14:40
04/26/1511:08
7440-28-0
42.7
mg/kg
7.3
3.7
100
04/21/15 14:40
04/26/15 11:08
7440-62-2
Analytical Method: EPA 7471 Preparation Method: EPA 7471
0.34 mg/kg 0.011 0.0055 1 04/21/15 21:00 04/22/15 13:22 7439-97-6
Analytical Method: ASTM D2974-87
30.4 % 0.10 0.10 1 04/23/1513:17
Analytical Method: EPA 9045
7.2 Std. Units
0.10
0.10 1
Analytical Method: EPA 9056
ND mg/kg
354
177 5
ND mg/kg
354
177 5
Analytical Method: EPA 9056
ND mg/kg
35.4
17.7 5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
,81APIi1f601111.7
N2
I:fl
04/19/1512:50 16887-00-6 D3
04/19/1512:50 14808-79-8 D3
04/19/1512:50 14797-55-8 H3
Page 58 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800&WYIY e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040322
Pace Project No.: 92245627
Sample: 2015010714
Lab ID:
92245627012
Collected:
04/13/15
17:30
Received: 04/15/15 15:30 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample
size and any dilutions.
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared Analyzed
CAS No. Qual
Total Organic Carbon Quad
Analytical Method: EPA 9060
Total Organic Carbon
141000
mg/kg
6140
3070
1
05/06/15 20:16
7440-44-0
Total Organic Carbon
52000
mg/kg
5960
2980
1
05/06/15 20:23
7440-44-0
Total Organic Carbon
70800
mg/kg
6110
3060
1
05/06/15 20:28
7440-44-0
Total Organic Carbon
56600
mg/kg
5800
2900
1
05/06/15 20:34
7440-44-0
Mean Total Organic Carbon
80000
mg/kg
6000
3000
1
05/06/15 20:16
7440-44-0
Surrogates
RSD%
51.5
%
1
05/06/15 20:16
1g
Date: 06/15/2015 07:34 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 59 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980WWYIW e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040322
Pace Project No.: 92245627
Sample: 2015010715 Lab ID: 92245627013 Collected: 04/14/15 15:45 Received: 04/15/15 15:30 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Aluminum
Barium
Beryllium
Boron
Calcium
Chromium
Copper
Iron
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Sodium
Strontium
Zinc
6020 MET ICPMS
Antimony
Arsenic
Cadmium
Cobalt
Lead
Selenium
Thallium
Vanadium
7471 Mercury
Mercury
Percent Moisture
Percent Moisture
9045 pH Soil
pH at 25 Degrees C
300.0 IC Anions, SPLP
Sulfate
353.2 Nitrogen, NO2/NO3, SPLP
Nitrogen, Nitrate
4500 Chloride, SPLP
Chloride
Date: 06/15/2015 07:34 AM
Analytical Method: EPA 6010 Preparation Method: EPA 3050
9690
mg/kg
49.7
24.9
5
04/21/15 14:40
04/26/15 00:19
7429-90-5
316
mg/kg
5.0
2.5
5
04/21/15 14:40
04/26/15 00:19
7440-39-3
2.3
mg/kg
0.50
0.25
5
04/21/15 14:40
04/26/15 00:19
7440-41-7
29.8
mg/kg
24.9
12.4
5
04/21/15 14:40
04/26/15 00:19
7440-42-8
4700
mg/kg
249
124
5
04/21/15 14:40
04/26/15 00:19
7440-70-2
16.0
mg/kg
2.5
1.2
5
04/21/15 14:40
04/26/15 00:19
7440-47-3
29.2
mg/kg
2.5
1.2
5
04/21/15 14:40
04/26/15 00:19
7440-50-8
8410
mg/kg
19.9
9.9
5
04/21/15 14:40
04/26/15 00:19
7439-89-6
1130
mg/kg
249
124
5
04/21/15 14:40
04/26/15 00:19
7439-95-4
59.0
mg/kg
2.5
1.2
5
04/21/15 14:40
04/26/15 00:19
7439-96-5
ND
mg/kg
5.0
2.5
5
04/21/15 14:40
04/26/15 00:19
7439-98-7
12.3
mg/kg
2.5
1.2
5
04/21/15 14:40
04/26/15 00:19
7440-02-0
1560
mg/kg
497
249
5
04/21/15 14:40
04/26/15 00:19
7440-09-7
323J
mg/kg
497
249
5
04/21/15 14:40
04/26/15 00:19
7440-23-5
230
mg/kg
5.0
2.5
5
04/21/15 14:40
04/26/15 00:19
7440-24-6
13.5
mg/kg
9.9
5.0
5
04/21/15 14:40
04/26/15 00:19
7440-66-6
Analytical
Method: EPA 6020
Preparation Method: EPA 3050
ND
mg/kg
9.9
5.0
100
04/21/15 14:40
04/26/1511:10
7440-36-0
N2
52.6
mg/kg
9.9
5.0
100
04/21/15 14:40
04/26/1511:10
7440-38-2
ND
mg/kg
1.2
0.60
100
04/21/15 14:40
04/26/1511:10
7440-43-9
6.2J
mg/kg
9.9
5.0
100
04/21/15 14:40
04/26/1511:10
7440-48-4
10.8
mg/kg
9.9
5.0
100
04/21/15 14:40
04/26/1511:10
7439-92-1
8.5J
mg/kg
9.9
5.0
100
04/21/15 14:40
04/26/1511:10
7782-49-2
ND
mg/kg
9.9
5.0
100
04/21/15 14:40
04/26/1511:10
7440-28-0
33.0
mg/kg
9.9
5.0
100
04/21/15 14:40
04/26/15 11:10
7440-62-2
Analytical
Method: EPA 7471
Preparation Method: EPA 7471
0.23
mg/kg 0.017
0.0083
1
04/21/15 21:00
04/22/15 13:24
7439-97-6
Analytical
Method: ASTM D2974-87
50.6
%
0.10
0.10
1
04/23/1513:17
Analytical
Method: EPA 9045
8.9
Std. Units
0.10
0.10
1
04/21/15 11:55
H1
Analytical
Method: EPA 300.0 Leachate Method/Date:
EPA 1312; 04/16/15
03:15
24.8
mg/L
4.0
2.0
1
04/29/1516:24
14808-79-8
B
Analytical
Method: EPA 353.2 Leachate Method/Date:
EPA 1312; 04/16/15
03:15
ND
mg/L
0.40
0.40
1
04/29/15 21:05
H1
Analytical
Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 04/16/15 03:15
ND
mg/L
10.1
5.1
1
04/30/15 01:47
16887-00-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 60 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980079WMI� e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040322
Pace Project No.: 92245627
Sample: 2015010715 Lab ID: 92245627013 Collected: 04/14/15 15:45 Received: 04/15/15 15:30 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
9056 IC Anions Analytical Method: EPA 9056
Chloride
ND mg/kg
496
248
5
04/19/1513:12
16887-00-6 D3
Sulfate
523 mg/kg
496
248
5
04/19/1513:12
14808-79-8
9056 IC Anions 48hr
Analytical Method: EPA 9056
Nitrate as N
ND mg/kg
49.6
24.8
5
04/19/15 13:12
14797-55-8 H3
Total Organic Carbon Quad
Analytical Method: EPA 9060
Total Organic Carbon
212000 mg/kg
7530
3760
1
05/11/15 10:40
7440-44-0
Total Organic Carbon
158000 mg/kg
7320
3660
1
05/11/15 10:45
7440-44-0
Total Organic Carbon
152000 mg/kg
7490
3740
1
05/11/15 10:51
7440-44-0
Total Organic Carbon
179000 mg/kg
7450
3720
1
05/11/15 10:58
7440-44-0
Mean Total Organic Carbon
175000 mg/kg
7440
3720
1
05/11/15 10:40
7440-44-0
Surrogates
RSD%
15.6 %
1
05/11/15 10:40
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2015 07:34 AM without the written consent of Pace Analytical Services, Inc..
Page 61 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 WYIW e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040322
Pace Project No.: 92245627
Sample: 2015010716 Lab ID: 92245627014 Collected: 04/14/15 15:55 Received: 04/15/15 15:30 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Aluminum
Barium
Beryllium
Boron
Calcium
Chromium
Copper
Iron
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Sodium
Strontium
Zinc
6020 MET ICPMS
Antimony
Arsenic
Cadmium
Cobalt
Lead
Selenium
Thallium
Vanadium
7471 Mercury
Mercury
Percent Moisture
Percent Moisture
9045 pH Soil
pH at 25 Degrees C
300.0 IC Anions, SPLP
Sulfate
353.2 Nitrogen, NO2/NO3, SPLP
Nitrogen, Nitrate
4500 Chloride, SPLP
Chloride
Date: 06/15/2015 07:34 AM
Analytical Method: EPA 6010 Preparation Method: EPA 3050
8850
mg/kg
33.6
16.8
5
04/21/15 14:40
04/26/15 00:23
7429-90-5
58.7
mg/kg
3.4
1.7
5
04/21/15 14:40
04/26/15 00:23
7440-39-3
0.32J
mg/kg
0.34
0.17
5
04/21/15 14:40
04/26/15 00:23
7440-41-7
ND
mg/kg
16.8
8.4
5
04/21/15 14:40
04/26/15 00:23
7440-42-8
989
mg/kg
168
84.0
5
04/21/15 14:40
04/26/15 00:23
7440-70-2
10.9
mg/kg
1.7
0.84
5
04/21/15 14:40
04/26/15 00:23
7440-47-3
9.9
mg/kg
1.7
0.84
5
04/21/15 14:40
04/26/15 00:23
7440-50-8
12500
mg/kg
13.4
6.7
5
04/21/15 14:40
04/26/15 00:23
7439-89-6
1250
mg/kg
168
84.0
5
04/21/15 14:40
04/26/15 00:23
7439-95-4
351
mg/kg
1.7
0.84
5
04/21/15 14:40
04/26/15 00:23
7439-96-5
ND
mg/kg
3.4
1.7
5
04/21/15 14:40
04/26/15 00:23
7439-98-7
5.0
mg/kg
1.7
0.84
5
04/21/15 14:40
04/26/15 00:23
7440-02-0
342
mg/kg
336
168
5
04/21/15 14:40
04/26/15 00:23
7440-09-7
ND
mg/kg
336
168
5
04/21/15 14:40
04/26/15 00:23
7440-23-5
19.1
mg/kg
3.4
1.7
5
04/21/15 14:40
04/26/15 00:23
7440-24-6
16.5
mg/kg
6.7
3.4
5
04/21/15 14:40
04/26/15 00:23
7440-66-6
Analytical
Method: EPA 6020
Preparation Method: EPA 3050
ND
mg/kg
6.7
3.4
100
04/21/15 14:40
04/26/1511:19
7440-36-0
N2
ND
mg/kg
6.7
3.4
100
04/21/15 14:40
04/26/1511:19
7440-38-2
ND
mg/kg
0.81
0.40
100
04/21/15 14:40
04/26/1511:19
7440-43-9
5AJ
mg/kg
6.7
3.4
100
04/21/15 14:40
04/26/1511:19
7440-48-4
5.2J
mg/kg
6.7
3.4
100
04/21/15 14:40
04/26/1511:19
7439-92-1
ND
mg/kg
6.7
3.4
100
04/21/15 14:40
04/26/1511:19
7782-49-2
ND
mg/kg
6.7
3.4
100
04/21/15 14:40
04/26/1511:19
7440-28-0
29.3
mg/kg
6.7
3.4
100
04/21/15 14:40
04/26/15 11:19
7440-62-2
Analytical
Method: EPA 7471
Preparation Method: EPA 7471
0.022
mg/kg
0.011
0.0055
1
04/21/15 21:00
04/22/15 13:27
7439-97-6
Analytical
Method: ASTM D2974-87
27.4
%
0.10
0.10
1
04/23/1513:17
Analytical
Method: EPA 9045
6.4
Std. Units
0.10
0.10
1
04/21/15 11:55
H1
Analytical
Method: EPA 300.0 Leachate Method/Date:
EPA 1312; 04/27/15
23:05
13.7
mg/L
2.8
1.4
1
05/06/15 08:41
14808-79-8
B
Analytical
Method: EPA 353.2 Leachate Method/Date:
EPA 1312; 04/27/15
23:05
0.74
mg/L
0.28
0.28
1
05/13/1513:18
H1
Analytical
Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 04/27/15 23:05
ND
mg/L
6.9
3.4
1
05/09/15 03:32
16887-00-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 62 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980WWYIW e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040322
Pace Project No.: 92245627
Sample: 2015010716 Lab ID: 92245627014 Collected: 04/14/15 15:55 Received: 04/15/15 15:30 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
9056 IC Anions Analytical Method: EPA 9056
Chloride
ND mg/kg
339
169
5
04/19/1513:33
16887-00-6 D3
Sulfate
209J mg/kg
339
169
5
04/19/1513:33
14808-79-8 D3
9056 IC Anions 48hr
Analytical Method: EPA 9056
Nitrate as N
ND mg/kg
33.9
16.9
5
04/19/15 13:33
14797-55-8 H3
Total Organic Carbon Quad
Analytical Method: EPA 9060
Total Organic Carbon
1230 mg/kg
827
413
1
05/11/15 11:52
7440-44-0
Total Organic Carbon
1210 mg/kg
827
414
1
05/11/15 11:58
7440-44-0
Total Organic Carbon
1120 mg/kg
827
413
1
05/11/15 12:03
7440-44-0
Total Organic Carbon
1120 mg/kg
828
414
1
05/11/15 12:09
7440-44-0
Mean Total Organic Carbon
1170 mg/kg
827
414
1
05/11/15 11:52
7440-44-0
Surrogates
RSD%
5.1 %
1
05/11/15 11:52
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2015 07:34 AM without the written consent of Pace Analytical Services, Inc..
Page 63 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 WY2"Y e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040322
Pace Project No.: 92245627
Sample: 2015010717 Lab ID: 92245627015 Collected: 04/14/15 16:00 Received: 04/15/15 15:30 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Aluminum
Barium
Beryllium
Boron
Calcium
Chromium
Copper
Iron
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Sodium
Strontium
Zinc
6020 MET ICPMS
Antimony
Arsenic
Cadmium
Cobalt
Lead
Selenium
Thallium
Vanadium
7471 Mercury
Mercury
Percent Moisture
Percent Moisture
9045 pH Soil
pH at 25 Degrees C
9056 IC Anions
Chloride
Sulfate
9056 IC Anions 48hr
Nitrate as N
Date: 06/15/2015 07:34 AM
Analytical Method: EPA 6010 Preparation Method: EPA 3050
12300
mg/kg
46.6
23.3
5
04/21/15 14:40
04/26/15 00:27
7429-90-5
407
mg/kg
4.7
2.3
5
04/21/15 14:40
04/26/15 00:27
7440-39-3
3.0
mg/kg
0.47
0.23
5
04/21/15 14:40
04/26/15 00:27
7440-41-7
35.2
mg/kg
23.3
11.6
5
04/21/15 14:40
04/26/15 00:27
7440-42-8
6170
mg/kg
233
116
5
04/21/15 14:40
04/26/15 00:27
7440-70-2
21.1
mg/kg
2.3
1.2
5
04/21/15 14:40
04/26/15 00:27
7440-47-3
36.5
mg/kg
2.3
1.2
5
04/21/15 14:40
04/26/15 00:27
7440-50-8
10000
mg/kg
18.6
9.3
5
04/21/15 14:40
04/26/15 00:27
7439-89-6
1480
mg/kg
233
116
5
04/21/15 14:40
04/26/15 00:27
7439-95-4
73.4
mg/kg
2.3
1.2
5
04/21/15 14:40
04/26/15 00:27
7439-96-5
ND
mg/kg
4.7
2.3
5
04/21/15 14:40
04/26/15 00:27
7439-98-7
15.2
mg/kg
2.3
1.2
5
04/21/15 14:40
04/26/15 00:27
7440-02-0
1870
mg/kg
466
233
5
04/21/15 14:40
04/26/15 00:27
7440-09-7
353J
mg/kg
466
233
5
04/21/15 14:40
04/26/15 00:27
7440-23-5
301
mg/kg
4.7
2.3
5
04/21/15 14:40
04/26/15 00:27
7440-24-6
17.4
mg/kg
9.3
4.7
5
04/21/15 14:40
04/26/15 00:27
7440-66-6
Analytical
Method: EPA 6020 Preparation
Method: EPA 3050
ND
mg/kg
9.3
4.7
100
04/21/15 14:40
04/26/1511:22
7440-36-0
72.9
mg/kg
9.3
4.7
100
04/21/15 14:40
04/26/1511:22
7440-38-2
ND
mg/kg
1.1
0.56
100
04/21/15 14:40
04/26/1511:22
7440-43-9
7.8J
mg/kg
9.3
4.7
100
04/21/15 14:40
04/26/1511:22
7440-48-4
13.6
mg/kg
9.3
4.7
100
04/21/15 14:40
04/26/1511:22
7439-92-1
10.4
mg/kg
9.3
4.7
100
04/21/15 14:40
04/26/1511:22
7782-49-2
ND
mg/kg
9.3
4.7
100
04/21/15 14:40
04/26/1511:22
7440-28-0
44.8
mg/kg
9.3
4.7
100
04/21/15 14:40
04/26/15 11:22
7440-62-2
Analytical Method: EPA 7471 Preparation Method: EPA 7471
0.24 mg/kg 0.015 0.0073 1 04/21/15 21:00 04/22/15 13:29 7439-97-6
Analytical Method: ASTM D2974-87
43.8 % 0.10 0.10 1 04/23/1513:17
Analytical Method: EPA 9045
8.8 Std. Units
0.10
0.10 1
Analytical Method: EPA 9056
ND mg/kg
444
222 5
437J mg/kg
444
222 5
Analytical Method: EPA 9056
ND mg/kg
44.4
22.2 5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
,81APIi1f601111.7
N2
I:fl
04/19/1513:54 16887-00-6 D3
04/ 19/ 15 13:54 14808-79-8
04/19/1513:54 14797-55-8 H3
Page 64 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800AWMI� e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040322
Pace Project No.: 92245627
Sample: 2015010717
Lab ID:
92245627015
Collected:
04/14/15 16:00
Received: 04/15/15 15:30 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample
size and any dilutions.
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared Analyzed
CAS No. Qual
Total Organic Carbon Quad
Analytical
Method: EPA 9060
Total Organic Carbon
168000
mg/kg
6230
3120
1
05/11/15 12:14
7440-44-0
Total Organic Carbon
165000
mg/kg
6290
3140
1
05/11/15 12:20
7440-44-0
Total Organic Carbon
159000
mg/kg
6190
3100
1
05/11/15 12:27
7440-44-0
Total Organic Carbon
148000
mg/kg
6260
3130
1
05/11/15 12:33
7440-44-0
Mean Total Organic Carbon
160000
mg/kg
6240
3120
1
05/11/15 12:14
7440-44-0
Surrogates
RSD%
5.4
%
1
05/11/15 12:14
Date: 06/15/2015 07:34 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 65 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800AirWY2"�e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040322
Pace Project No.: 92245627
Sample: 2015010707 SPLP Lab ID: 92245627016 Collected: 04/11/15 15:05 Received: 04/15/15 15:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
;T➢Z17c\riil=11 a
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Sodium
Strontium
Thallium
Vanadium
Zinc
7470A Mercury
Mercury
Date: 06/15/2015 07:34 AM
Analytical Method: EPA 6020A Preparation Method: EPA 3020
428
ug/L
10.0
3.0
1
05/14/15 07:47
05/15/15 14:12
7429-90-5
3.6
ug/L
0.50
0.15
1
05/14/15 07:47
05/15/15 14:12
7440-36-0
90.5
ug/L
0.50
0.11
1
05/14/15 07:47
05/15/15 14:12
7440-38-2
251
ug/L
0.30
0.081
1
05/14/15 07:47
05/15/15 14:12
7440-39-3
ND
ug/L
0.20
0.067
1
05/14/15 07:47
05/15/15 14:12
7440-41-7
61.5
ug/L
5.0
1.1
1
05/14/15 07:47
05/15/15 14:12
7440-42-8
ND
ug/L
0.080
0.024
1
05/14/15 07:47
05/15/15 14:12
7440-43-9
9480
ug/L
40.0
16.0
1
05/14/15 07:47
05/15/15 14:12
7440-70-2
2.2
ug/L
0.50
0.17
1
05/14/15 07:47
05/15/15 14:12
7440-47-3
ND
ug/L
0.50
0.13
1
05/14/15 07:47
05/15/15 14:12
7440-48-4
0.66J
ug/L
1.0
0.21
1
05/14/15 07:47
05/15/15 14:12
7440-50-8
18.91
ug/L
50.0
13.7
1
05/14/15 07:47
05/15/15 14:12
7439-89-6
0.050J
ug/L
0.10
0.046
1
05/14/15 07:47
05/15/15 14:12
7439-92-1
605
ug/L
10.0
3.2
1
05/14/15 07:47
05/15/15 14:12
7439-95-4
5.3
ug/L
0.50
0.24
1
05/14/15 07:47
05/15/15 14:12
7439-96-5
8.2
ug/L
0.50
0.094
1
05/14/15 07:47
05/15/15 14:12
7439-98-7
0.35J
ug/L
0.50
0.16
1
05/14/15 07:47
05/15/15 14:12
7440-02-0
238
ug/L
50.0
11.7
1
05/14/15 07:47
05/15/15 14:12
7440-09-7
58.3
ug/L
0.50
0.20
1
05/14/15 07:47
05/15/15 14:12
7782-49-2
2230
ug/L
50.0
16.3
1
05/14/15 07:47
05/15/15 14:12
7440-23-5
344
ug/L
0.50
0.13
1
05/14/15 07:47
05/15/15 14:12
7440-24-6
ND
ug/L
0.10
0.015
1
05/14/15 07:47
05/15/15 14:12
7440-28-0
33.5
ug/L
1.0
0.28
1
05/14/15 07:47
05/15/15 14:12
7440-62-2
22.4
ug/L
5.0
2.4
1
05/14/15 07:47
05/15/15 14:12
7440-66-6
Analytical Method: EPA 7470A Preparation Method: EPA 7470A
ND ug/L 0.20 0.022 1 05/14/15 11:05 05/14/15 21:17 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 66 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 WY2"Y e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040322
Pace Project No.: 92245627
Sample: 2015010708 SPLP Lab ID: 92245627017 Collected: 04/11/15 15:35 Received: 04/15/15 15:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
;T➢Z17c\��il=11 a � 6?
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Sodium
Strontium
Thallium
Vanadium
Zinc
7470A Mercury
Mercury
Date: 06/15/2015 07:34 AM
Analytical Method: EPA 6020A Preparation Method: EPA 3020
282000
ug/L
200
59.6
20
05/14/15 07:47
05/15/15 14:15
7429-90-5
ND
ug/L
0.50
0.15
1
05/14/15 07:47
05/14/15 19:46
7440-36-0
17.7
ug/L
0.50
0.11
1
05/14/15 07:47
05/14/15 19:46
7440-38-2
1340
ug/L
6.0
1.6
20
05/14/15 07:47
05/15/15 14:15
7440-39-3
6.6
ug/L
4.0
1.3
20
05/14/15 07:47
05/15/15 14:15
7440-41-7
181
ug/L
100
22.2
20
05/14/15 07:47
05/15/15 14:15
7440-42-8
0.25
ug/L
0.080
0.024
1
05/14/15 07:47
05/14/15 19:46
7440-43-9
18500
ug/L
800
320
20
05/14/15 07:47
05/15/15 14:15
7440-70-2
288
ug/L
10.0
3.4
20
05/14/15 07:47
05/15/15 14:15
7440-47-3
43.6
ug/L
0.50
0.13
1
05/14/15 07:47
05/14/15 19:46
7440-48-4
155
ug/L
1.0
0.21
1
05/14/15 07:47
05/14/15 19:46
7440-50-8
278000
ug/L
1000
274
20
05/14/15 07:47
05/15/15 14:15
7439-89-6
52.6
ug/L
0.10
0.046
1
05/14/15 07:47
05/14/15 19:46
7439-92-1
22100
ug/L
200
63.4
20
05/14/15 07:47
05/15/15 14:15
7439-95-4
2210
ug/L
10.0
4.8
20
05/14/15 07:47
05/15/15 14:15
7439-96-5
0.37J
ug/L
0.50
0.094
1
05/14/15 07:47
05/14/15 19:46
7439-98-7
125
ug/L
0.50
0.16
1
05/14/15 07:47
05/14/15 19:46
7440-02-0
3240
ug/L
1000
235
20
05/14/15 07:47
05/15/15 14:15
7440-09-7
3.9
ug/L
0.50
0.20
1
05/14/15 07:47
05/14/15 19:46
7782-49-2
2760
ug/L
1000
326
20
05/14/15 07:47
05/15/15 14:15
7440-23-5
274
ug/L
0.50
0.13
1
05/14/15 07:47
05/14/15 19:46
7440-24-6
1.0
ug/L
0.10
0.015
1
05/14/15 07:47
05/14/15 19:46
7440-28-0
370
ug/L
20.0
5.6
20
05/14/15 07:47
05/15/15 14:15
7440-62-2
554
ug/L
100
48.2
20
05/14/15 07:47
05/15/15 14:15
7440-66-6
Analytical Method: EPA 7470A Preparation Method: EPA 7470A
0.39 ug/L 0.20 0.022 1 05/14/15 11:05 05/14/15 21:19 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 67 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 WY2"Y e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040322
Pace Project No.: 92245627
Sample: 2015010709 SPLP Lab ID: 92245627018 Collected: 04/13/15 13:25 Received: 04/15/15 15:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
;T➢Z17c\��il=11 a � 6?
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Sodium
Strontium
Thallium
Vanadium
Zinc
7470A Mercury
Mercury
Date: 06/15/2015 07:34 AM
Analytical Method: EPA 6020A Preparation Method: EPA 3020
44000
ug/L
200
59.6
20
05/14/15 07:47
05/15/15 14:17
7429-90-5
0.47J
ug/L
0.50
0.15
1
05/14/15 07:47
05/14/15 19:48
7440-36-0
7.0
ug/L
0.50
0.11
1
05/14/15 07:47
05/14/15 19:48
7440-38-2
359
ug/L
0.30
0.081
1
05/14/15 07:47
05/14/15 19:48
7440-39-3
1.8
ug/L
0.20
0.067
1
05/14/15 07:47
05/14/15 19:48
7440-41-7
43.9
ug/L
5.0
1.1
1
05/14/15 07:47
05/14/15 19:48
7440-42-8
0.21
ug/L
0.080
0.024
1
05/14/15 07:47
05/14/15 19:48
7440-43-9
2550
ug/L
40.0
16.0
1
05/14/15 07:47
05/14/15 19:48
7440-70-2
53.2
ug/L
0.50
0.17
1
05/14/15 07:47
05/14/15 19:48
7440-47-3
13.5
ug/L
0.50
0.13
1
05/14/15 07:47
05/14/15 19:48
7440-48-4
39.0
ug/L
1.0
0.21
1
05/14/15 07:47
05/14/15 19:48
7440-50-8
22900
ug/L
1000
274
20
05/14/15 07:47
05/15/15 14:17
7439-89-6
23.8
ug/L
0.10
0.046
1
05/14/15 07:47
05/14/15 19:48
7439-92-1
3380
ug/L
10.0
3.2
1
05/14/15 07:47
05/14/15 19:48
7439-95-4
180
ug/L
0.50
0.24
1
05/14/15 07:47
05/14/15 19:48
7439-96-5
1.4
ug/L
0.50
0.094
1
05/14/15 07:47
05/14/15 19:48
7439-98-7
22.4
ug/L
0.50
0.16
1
05/14/15 07:47
05/14/15 19:48
7440-02-0
1380
ug/L
50.0
11.7
1
05/14/15 07:47
05/14/15 19:48
7440-09-7
0.82
ug/L
0.50
0.20
1
05/14/15 07:47
05/14/15 19:48
7782-49-2
2680
ug/L
1000
326
20
05/14/15 07:47
05/15/15 14:17
7440-23-5
30.2
ug/L
0.50
0.13
1
05/14/15 07:47
05/14/15 19:48
7440-24-6
0.18
ug/L
0.10
0.015
1
05/14/15 07:47
05/14/15 19:48
7440-28-0
161
ug/L
1.0
0.28
1
05/14/15 07:47
05/14/15 19:48
7440-62-2
182
ug/L
5.0
2.4
1
05/14/15 07:47
05/14/15 19:48
7440-66-6
Analytical Method: EPA 7470A Preparation Method: EPA 7470A
0.040J ug/L 0.20 0.022 1 05/14/15 11:05 05/14/15 21:28 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 68 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 WY2"Y e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040322
Pace Project No.: 92245627
Sample: 2015010712 SPLP Lab ID: 92245627019 Collected: 04/13/15 16:00 Received: 04/15/15 15:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
;T➢Z17c\��il=11 a � 6?
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Sodium
Strontium
Thallium
Vanadium
Zinc
7470A Mercury
Mercury
Date: 06/15/2015 07:34 AM
Analytical Method: EPA 6020A Preparation Method: EPA 3020
24900
ug/L
50.0
14.9
5
05/14/15 07:47
05/15/15 14:20
7429-90-5
5.1
ug/L
0.50
0.15
1
05/14/15 07:47
05/14/15 19:54
7440-36-0
24.6
ug/L
0.50
0.11
1
05/14/15 07:47
05/14/15 19:54
7440-38-2
429
ug/L
0.30
0.081
1
05/14/15 07:47
05/14/15 19:54
7440-39-3
0.94
ug/L
0.20
0.067
1
05/14/15 07:47
05/14/15 19:54
7440-41-7
166
ug/L
5.0
1.1
1
05/14/15 07:47
05/14/15 19:54
7440-42-8
0.083
ug/L
0.080
0.024
1
05/14/15 07:47
05/14/15 19:54
7440-43-9
6370
ug/L
40.0
16.0
1
05/14/15 07:47
05/14/15 19:54
7440-70-2
15.1
ug/L
0.50
0.17
1
05/14/15 07:47
05/14/15 19:54
7440-47-3
6.3
ug/L
0.50
0.13
1
05/14/15 07:47
05/14/15 19:54
7440-48-4
13.1
ug/L
1.0
0.21
1
05/14/15 07:47
05/14/15 19:54
7440-50-8
18000
ug/L
50.0
13.7
1
05/14/15 07:47
05/14/15 19:54
7439-89-6
8.1
ug/L
0.10
0.046
1
05/14/15 07:47
05/14/15 19:54
7439-92-1
2270
ug/L
10.0
3.2
1
05/14/15 07:47
05/14/15 19:54
7439-95-4
117
ug/L
0.50
0.24
1
05/14/15 07:47
05/14/15 19:54
7439-96-5
129
ug/L
0.50
0.094
1
05/14/15 07:47
05/14/15 19:54
7439-98-7
9.0
ug/L
0.50
0.16
1
05/14/15 07:47
05/14/15 19:54
7440-02-0
2280
ug/L
50.0
11.7
1
05/14/15 07:47
05/14/15 19:54
7440-09-7
13.9
ug/L
0.50
0.20
1
05/14/15 07:47
05/14/15 19:54
7782-49-2
1980
ug/L
250
81.5
5
05/14/15 07:47
05/15/15 14:20
7440-23-5
187
ug/L
0.50
0.13
1
05/14/15 07:47
05/14/15 19:54
7440-24-6
0.51
ug/L
0.10
0.015
1
05/14/15 07:47
05/14/15 19:54
7440-28-0
45.6
ug/L
1.0
0.28
1
05/14/15 07:47
05/14/15 19:54
7440-62-2
124
ug/L
5.0
2.4
1
05/14/15 07:47
05/14/15 19:54
7440-66-6
Analytical Method: EPA 7470A Preparation Method: EPA 7470A
0.0801 ug/L 0.20 0.022 1 05/14/15 11:05 05/14/15 21:30 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 69 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 WY2"Y e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040322
Pace Project No.: 92245627
Sample: 2015010715 SPLP Lab ID: 92245627021 Collected: 04/14/15 15:45 Received: 04/15/15 15:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
;T➢Z17c\�iil=11 a
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Sodium
Strontium
Thallium
Vanadium
Zinc
7470A Mercury
Mercury
Date: 06/15/2015 07:34 AM
Analytical Method: EPA 6020A Preparation Method: EPA 3020
1080
ug/L
10.0
3.0
1
05/14/15 07:47
05/15/15 14:23
7429-90-5
2.1
ug/L
0.50
0.15
1
05/14/15 07:47
05/15/15 14:23
7440-36-0
131
ug/L
0.50
0.11
1
05/14/15 07:47
05/15/15 14:23
7440-38-2
149
ug/L
0.30
0.081
1
05/14/15 07:47
05/15/15 14:23
7440-39-3
ND
ug/L
0.20
0.067
1
05/14/15 07:47
05/15/15 14:23
7440-41-7
316
ug/L
5.0
1.1
1
05/14/15 07:47
05/15/15 14:23
7440-42-8
ND
ug/L
0.080
0.024
1
05/14/15 07:47
05/15/15 14:23
7440-43-9
9790
ug/L
40.0
16.0
1
05/14/15 07:47
05/15/15 14:23
7440-70-2
2.1
ug/L
0.50
0.17
1
05/14/15 07:47
05/15/15 14:23
7440-47-3
ND
ug/L
0.50
0.13
1
05/14/15 07:47
05/15/15 14:23
7440-48-4
3.0
ug/L
1.0
0.21
1
05/14/15 07:47
05/15/15 14:23
7440-50-8
36.3J
ug/L
50.0
13.7
1
05/14/15 07:47
05/15/15 14:23
7439-89-6
0.20
ug/L
0.10
0.046
1
05/14/15 07:47
05/15/15 14:23
7439-92-1
905
ug/L
10.0
3.2
1
05/14/15 07:47
05/15/15 14:23
7439-95-4
3.0
ug/L
0.50
0.24
1
05/14/15 07:47
05/15/15 14:23
7439-96-5
5.5
ug/L
0.50
0.094
1
05/14/15 07:47
05/15/15 14:23
7439-98-7
0.89
ug/L
0.50
0.16
1
05/14/15 07:47
05/15/15 14:23
7440-02-0
398
ug/L
50.0
11.7
1
05/14/15 07:47
05/15/15 14:23
7440-09-7
37.1
ug/L
0.50
0.20
1
05/14/15 07:47
05/15/15 14:23
7782-49-2
1480
ug/L
50.0
16.3
1
05/14/15 07:47
05/15/15 14:23
7440-23-5
271
ug/L
0.50
0.13
1
05/14/15 07:47
05/15/15 14:23
7440-24-6
ND
ug/L
0.10
0.015
1
05/14/15 07:47
05/15/15 14:23
7440-28-0
48.2
ug/L
1.0
0.28
1
05/14/15 07:47
05/15/15 14:23
7440-62-2
9.8
ug/L
5.0
2.4
1
05/14/15 07:47
05/15/15 14:23
7440-66-6
Analytical Method: EPA 7470A Preparation Method: EPA 7470A
ND ug/L 0.20 0.022 1 05/14/15 11:05 05/14/15 21:34 7439-97-6 H1,H2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 70 of 103

aceAnaiXical
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Pace Analytical Services, Inc.
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[phone]
ANALYTICAL RESULTS
Project: J15040322
Pace Project No.: 92245627
Sample: 2015010718 Lab ID: 92245627022 Collected: 04/14/15 14:00 Received: 04/15/15 17:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
;I➢ZI7c\�i,I=11 l[99�r 6?
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Sodium
Strontium
Thallium
Vanadium
Zinc
7470 Mercury
Mercury
Date: 06/15/2015 07:34 AM
Analytical Method: EPA 6020A Preparation Method: EPA 3020
575
ug/L
10.0
3.0
1
04/20/15 06:33
04/21/15 05:08
7429-90-5
ND
ug/L
0.50
0.15
1
04/20/15 06:33
04/21/15 05:08
7440-36-0
0.37J
ug/L
0.50
0.11
1
04/20/15 06:33
04/21/15 05:08
7440-38-2
9.8
ug/L
0.30
0.081
1
04/20/15 06:33
04/21/15 05:08
7440-39-3
0.077J
ug/L
0.20
0.067
1
04/20/15 06:33
04/21/15 05:08
7440-41-7
ND
ug/L
5.0
1.1
1
04/20/15 06:33
04/21/15 05:08
7440-42-8
ND
ug/L
0.080
0.024
1
04/20/15 06:33
04/21/15 05:08
7440-43-9
761
ug/L
40.0
16.0
1
04/20/15 06:33
04/23/15 01:05
7440-70-2
3.0
ug/L
0.50
0.17
1
04/20/15 06:33
04/21/15 05:08
7440-47-3
3.3
ug/L
0.50
0.13
1
04/20/15 06:33
04/21/15 05:08
7440-48-4
1.7
ug/L
1.0
0.21
1
04/20/15 06:33
04/21/15 05:08
7440-50-8
1000
ug/L
50.0
13.7
1
04/20/15 06:33
04/21/15 05:08
7439-89-6
0.42
ug/L
0.10
0.046
1
04/20/15 06:33
04/21/15 05:08
7439-92-1
155
ug/L
10.0
3.2
1
04/20/15 06:33
04/21/15 05:08
7439-95-4
39.7
ug/L
0.50
0.24
1
04/20/15 06:33
04/21/15 05:08
7439-96-5
0.91
ug/L
0.50
0.094
1
04/20/15 06:33
04/21/15 05:08
7439-98-7
0.74
ug/L
0.50
0.16
1
04/20/15 06:33
04/21/15 05:08
7440-02-0
278
ug/L
50.0
11.7
1
04/20/15 06:33
04/21/15 05:08
7440-09-7
ND
ug/L
0.50
0.20
1
04/20/15 06:33
04/21/15 05:08
7782-49-2
337
ug/L
50.0
16.3
1
04/20/15 06:33
04/21/15 05:08
7440-23-5
5.4
ug/L
0.50
0.13
1
04/20/15 06:33
04/21/15 05:08
7440-24-6
ND
ug/L
0.10
0.015
1
04/20/15 06:33
04/21/15 05:08
7440-28-0
1.0
ug/L
1.0
0.28
1
04/20/15 06:33
04/21/15 05:08
7440-62-2
6.4
ug/L
5.0
2.4
1
04/20/15 06:33
04/21/15 05:08
7440-66-6
Analytical Method: EPA 7470 Preparation Method: EPA 7470
ND ug/L 0.20 0.022 1 04/20/15 11:15 04/20/15 20:13 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 71 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 WY2"e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040322
Pace Project No.: 92245627
Sample: 2015010716 SPLP Lab ID: 92245627023 Collected: 04/14/15 15:55 Received: 04/15/15 15:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
;T➢Z17c\��il=11 a � 6?
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Sodium
Strontium
Thallium
Vanadium
Zinc
7470A Mercury
Mercury
Date: 06/15/2015 07:34 AM
Analytical Method: EPA 6020A Preparation Method: EPA 3020
54000
ug/L
50.0
14.9
5
05/14/15 07:47
05/15/15 14:26
7429-90-5
ND
ug/L
0.50
0.15
1
05/14/15 07:47
05/14/15 19:59
7440-36-0
3.8
ug/L
0.50
0.11
1
05/14/15 07:47
05/14/15 19:59
7440-38-2
347
ug/L
0.30
0.081
1
05/14/15 07:47
05/14/15 19:59
7440-39-3
1.1
ug/L
0.20
0.067
1
05/14/15 07:47
05/14/15 19:59
7440-41-7
183
ug/L
5.0
1.1
1
05/14/15 07:47
05/14/15 19:59
7440-42-8
0.030J
ug/L
0.080
0.024
1
05/14/15 07:47
05/14/15 19:59
7440-43-9
5320
ug/L
40.0
16.0
1
05/14/15 07:47
05/14/15 19:59
7440-70-2
42.6
ug/L
0.50
0.17
1
05/14/15 07:47
05/14/15 19:59
7440-47-3
16.3
ug/L
0.50
0.13
1
05/14/15 07:47
05/14/15 19:59
7440-48-4
46.9
ug/L
1.0
0.21
1
05/14/15 07:47
05/14/15 19:59
7440-50-8
47400
ug/L
250
68.5
5
05/14/15 07:47
05/15/15 14:26
7439-89-6
11.9
ug/L
0.10
0.046
1
05/14/15 07:47
05/14/15 19:59
7439-92-1
4070
ug/L
10.0
3.2
1
05/14/15 07:47
05/14/15 19:59
7439-95-4
1340
ug/L
2.5
1.2
5
05/14/15 07:47
05/15/15 14:26
7439-96-5
0.37J
ug/L
0.50
0.094
1
05/14/15 07:47
05/14/15 19:59
7439-98-7
26.1
ug/L
0.50
0.16
1
05/14/15 07:47
05/14/15 19:59
7440-02-0
1270
ug/L
50.0
11.7
1
05/14/15 07:47
05/14/15 19:59
7440-09-7
0.65
ug/L
0.50
0.20
1
05/14/15 07:47
05/14/15 19:59
7782-49-2
2170
ug/L
250
81.5
5
05/14/15 07:47
05/15/15 14:26
7440-23-5
117
ug/L
0.50
0.13
1
05/14/15 07:47
05/14/15 19:59
7440-24-6
0.24
ug/L
0.10
0.015
1
05/14/15 07:47
05/14/15 19:59
7440-28-0
86.0
ug/L
1.0
0.28
1
05/14/15 07:47
05/14/15 19:59
7440-62-2
133
ug/L
5.0
2.4
1
05/14/15 07:47
05/14/15 19:59
7440-66-6
Analytical Method: EPA 7470A Preparation Method: EPA 7470A
0.10J ug/L 0.20 0.022 1 05/14/15 11:05 05/14/15 21:36 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 72 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980WWYIW e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040322
Pace Project No.: 92245627
QC Batch: MERP/13265 Analysis Method: EPA 7470
QC Batch Method: EPA 7470 Analysis Description: 7470 Mercury
Associated Lab Samples: 92245627001, 92245627008, 92245627022
METHOD BLANK: 1942361 Matrix: Water
Associated Lab Samples: 92245627001, 92245627008, 92245627022
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Mercury ug/L ND 0.20 04/20/1519:41
LABORATORY CONTROL SAMPLE: 1942362
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Mercury ug/L 5 5.1 102 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1942363 1942364
MS MSD
92243757012 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Mercury ug/L ND 5 5 5.2 5.0 103 100 75-125 3 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2015 07:34 AM without the written consent of Pace Analytical Services, Inc..
Page 73 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980CdYWY2"�e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040322
Pace Project No.: 92245627
QC Batch: MERP/13538 Analysis Method: EPA 7470A
QC Batch Method: EPA 7470A Analysis Description: 7470A Mercury Water
Associated Lab Samples: 92245627016, 92245627017, 92245627018, 92245627019, 92245627021, 92245627023
METHOD BLANK: 1965167 Matrix: Water
Associated Lab Samples: 92245627016, 92245627017, 92245627018, 92245627019, 92245627021, 92245627023
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Mercury ug/L ND 0.20 05/14/15 21:03
LABORATORY CONTROL SAMPLE: 1965168
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Mercury ug/L 5 4.7 94 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1965262 1965263
MS MSD
10306022003 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Mercury ug/L ND 5 5 4.7 4.8 93 95 80-120 2 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2015 07:34 AM without the written consent of Pace Analytical Services, Inc..
Page 74 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
98006WMI� e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040322
Pace Project No.: 92245627
QC Batch: MERP/5614 Analysis Method: EPA 7471
QC Batch Method: EPA 7471 Analysis Description: 7471 Mercury
Associated Lab Samples: 92245627003, 92245627004, 92245627005, 92245627006, 92245627007, 92245627009, 92245627010,
92245627011,92245627012,92245627013,92245627014,92245627015
METHOD BLANK: 1190219 Matrix: Solid
Associated Lab Samples: 92245627003, 92245627004, 92245627005, 92245627006, 92245627007, 92245627009, 92245627010,
92245627011,92245627012,92245627013,92245627014,92245627015
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Mercury mg/kg ND 0.0079 04/22/1512:44
LABORATORY CONTROL SAMPLE: 1190220
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Mercury mg/kg .081 0.080 99 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1190221 1190222
MS MSD
35183605001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qua]
Mercury mg/kg 0.65 .506 .5 0.92 0.79 54 28 80-120 15 20 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2015 07:34 AM without the written consent of Pace Analytical Services, Inc..
Page 75 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980C�ir6fY2"�e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040322
Pace Project No.: 92245627
QC Batch: MPRP/23716 Analysis Method: EPA 6010
QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid
Associated Lab Samples: 92245627003, 92245627004, 92245627005, 92245627006, 92245627007, 92245627009, 92245627010,
92245627011,92245627012,92245627013,92245627014,92245627015
METHOD BLANK: 1188467 Matrix: Solid
Associated Lab Samples: 92245627003, 92245627004, 92245627005, 92245627006, 92245627007, 92245627009, 92245627010,
92245627011,92245627012,92245627013,92245627014,92245627015
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Aluminum
mg/kg
ND
5.2
04/25/15 22:53
Barium
mg/kg
ND
0.52
04/25/15 22:53
Beryllium
mg/kg
ND
0.052
04/25/15 22:53
Boron
mg/kg
ND
2.6
04/25/15 22:53
Calcium
mg/kg
ND
25.9
04/25/15 22:53
Chromium
mg/kg
ND
0.26
04/25/15 22:53
Copper
mg/kg
ND
0.26
04/25/15 22:53
Iron
mg/kg
1.8J
2.1
04/25/15 22:53 P8
Magnesium
mg/kg
ND
25.9
04/25/15 22:53
Manganese
mg/kg
ND
0.26
04/25/15 22:53
Molybdenum
mg/kg
ND
0.52
04/25/15 22:53
Nickel
mg/kg
ND
0.26
04/25/15 22:53
Potassium
mg/kg
ND
51.8
04/25/15 22:53
Sodium
mg/kg
ND
51.8
04/25/15 22:53
Strontium
mg/kg
ND
0.52
04/25/15 22:53
Zinc
mg/kg
ND
1.0
04/25/15 22:53
LABORATORY CONTROL SAMPLE:
Parameter
1188468
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
Aluminum
mg/kg
129
131
102
80-120
Barium
mg/kg
12.9
13.2
103
80-120
Beryllium
mg/kg
1.3
1.3
101
80-120
Boron
mg/kg
129
126
98
80-120
Calcium
mg/kg
645
665
103
80-120
Chromium
mg/kg
12.9
12.5
97
80-120
Copper
mg/kg
12.9
12.5
97
80-120
Iron
mg/kg
129
131
101
80-120
Magnesium
mg/kg
645
646
100
80-120
Manganese
mg/kg
12.9
12.8
99
80-120
Molybdenum
mg/kg
12.9
12.7
98
80-120
Nickel
mg/kg
12.9
13.1
102
80-120
Potassium
mg/kg
645
646
100
80-120
Sodium
mg/kg
645
673
104
80-120
Strontium
mg/kg
12.9
13.1
101
80-120
Zinc
mg/kg
64.5
65.1
101
80-120
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2015 07:34 AM without the written consent of Pace Analytical Services, Inc.. Page 76 of 103

aceAnaiXical
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Pace Analytical Services, Inc.
9800AWMI� e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040322
Pace Project No.: 92245627
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
1188469
1188470
MS
MSD
92245627003
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Aluminum
mg/kg
5200
224
220
8480
9980
1470
2170
75-125
16
20 M1
Barium
mg/kg
482
22.4
22
558
617
340
615
75-125
10
20 M1
Beryllium
mg/kg
1.1
2.25
2.25
3.6
4.1
112
135
75-125
12
20 M1
Boron
mg/kg
ND
224
220
189
200
83
89
75-125
6
20
Calcium
mg/kg
1390
1110
1100
2790
3070
125
152
75-125
10
20 M1
Chromium
mg/kg
10.5
22.4
22
29.7
33.3
86
104
75-125
11
20
Copper
mg/kg
19.3
22.4
22
44.9
51.1
115
145
75-125
13
20 M1
Iron
mg/kg
20500
224
220
18000
20700
-1110
84
75-125
14
20 M1
Magnesium
mg/kg
447
1110
1100
1630
1780
106
121
75-125
9
20
Manganese
mg/kg
56.2
22.4
22
79.0
82.8
102
121
75-125
5
20
Molybdenum
mg/kg
ND
22.4
22
20.3
21.7
84
91
75-125
6
20
Nickel
mg/kg
13.0
22.4
22
35.1
39.2
99
119
75-125
11
20
Potassium
mg/kg
853
1110
1100
2540
2840
151
181
75-125
11
20 M1
Sodium
mg/kg
ND
1110
1100
1170
1230
99
106
75-125
5
20
Strontium
mg/kg
97.4
22.4
22
159
184
276
395
75-125
15
20 M1
Zinc
mg/kg
9.7
111
110
113
121
92
101
75-125
7
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2015 07:34 AM without the written consent of Pace Analytical Services, Inc..
Page 77 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800AWMI� e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040322
Pace Project No.: 92245627
QC Batch: MPRP/23717 Analysis Method: EPA 6020
QC Batch Method: EPA 3050 Analysis Description: 6020 MET SOLID
Associated Lab Samples: 92245627003, 92245627004, 92245627005, 92245627006, 92245627007, 92245627009, 92245627010,
92245627011,92245627012,92245627013,92245627014,92245627015
METHOD BLANK: 1188473
Matrix:
Solid
Associated Lab Samples:
92245627003, 92245627004,
92245627005, 92245627006, 92245627007,
92245627009, 92245627010,
92245627011,92245627012,92245627013,92245627014,92245627015
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Antimony
mg/kg
ND
0.051
04/26/1510:31 N2
Arsenic
mg/kg
ND
0.051
04/26/1510:31
Cadmium
mg/kg
ND
0.0062
04/26/1510:31
Cobalt
mg/kg
ND
0.051
04/26/1510:31
Lead
mg/kg
ND
0.051
04/26/1510:31
Selenium
mg/kg
ND
0.051
04/26/1510:31
Thallium
mg/kg
ND
0.051
04/26/1510:31
Vanadium
mg/kg
ND
0.051
04/26/1510:31
LABORATORY CONTROL SAMPLE:
Parameter
1188474
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
Antimony
mg/kg
2.6
2.6
99
80-120 N2
Arsenic
mg/kg
2.6
2.7
103
80-120
Cadmium
mg/kg
.26
0.26
99
80-120
Cobalt
mg/kg
2.6
2.7
104
80-120
Lead
mg/kg
2.6
2.6
100
80-120
Selenium
mg/kg
2.6
2.6
99
80-120
Thallium
mg/kg
2.6
2.6
101
80-120
Vanadium
mg/kg
2.6
2.7
103
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
1188475
1188476
MS
MSD
92245627003
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Antimony
mg/kg
ND
4.51
4.16
17.2
14.8
381
351
75-125
15
20 M6, N2
Arsenic
mg/kg
21.8
4.51
4.16
51.2
55.5
661
816
75-125
8
20 M6
Cadmium
mg/kg
0.59J
.451
.416
2.4
2.2
411
397
75-125
8
20 M6
Cobalt
mg/kg
6.9J
4.51
4.16
29.1
30.3
500
567
75-125
4
20 M6
Lead
mg/kg
ND
4.51
4.16
27.4
28.6
525
594
75-125
4
20 M6
Selenium
mg/kg
6.9J
4.51
4.16
29.5
29.0
507
533
75-125
2
20 M6
Thallium
mg/kg
ND
4.51
4.16
20.6
19.4
444
450
75-125
6
20 M6
Vanadium
mg/kg
20.4
4.51
4.16
49.4
54.1
650
816
75-125
9
20 M6
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2015 07:34 AM without the written consent of Pace Analytical Services, Inc..
Page 78 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800 WYIW e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040322
Pace Project No.: 92245627
QC Batch: MPRP/53712 Analysis Method: EPA 6020A
QC Batch Method: EPA 3020 Analysis Description: 6020A Water UPD4
Associated Lab Samples: 92245627001, 92245627008, 92245627022
METHOD BLANK: 1942408 Matrix:
Associated Lab Samples: 92245627001, 92245627008, 92245627022
Blank
Parameter Units Result
Water
Reporting
Limit
Analyzed
Aluminum
ug/L
ND
10.0
04/21/15 03:54
Antimony
ug/L
ND
0.50
04/21/15 03:54
Arsenic
ug/L
ND
0.50
04/21/15 03:54
Barium
ug/L
ND
0.30
04/21/15 03:54
Beryllium
ug/L
ND
0.20
04/21/15 03:54
Boron
ug/L
ND
5.0
04/21/15 03:54
Cadmium
ug/L
ND
0.080
04/21/15 03:54
Calcium
ug/L
ND
40.0
04/21/15 03:54
Chromium
ug/L
ND
0.50
04/21/15 03:54
Cobalt
ug/L
ND
0.50
04/21/15 03:54
Copper
ug/L
ND
1.0
04/21/15 03:54
Iron
ug/L
ND
50.0
04/21/15 03:54
Lead
ug/L
ND
0.10
04/21/15 03:54
Magnesium
ug/L
ND
10.0
04/21/15 03:54
Manganese
ug/L
ND
0.50
04/21/15 03:54
Molybdenum
ug/L
ND
0.50
04/21/15 03:54
Nickel
ug/L
ND
0.50
04/21/15 03:54
Potassium
ug/L
ND
50.0
04/21/15 03:54
Selenium
ug/L
ND
0.50
04/21/15 03:54
Sodium
ug/L
ND
50.0
04/21/15 03:54
Strontium
ug/L
ND
0.50
04/21/15 03:54
Thallium
ug/L
ND
0.10
04/21/15 03:54
Vanadium
ug/L
ND
1.0
04/21/15 03:54
Zinc
ug/L
ND
5.0
04/21/15 03:54
Qualifiers
LABORATORY CONTROL SAMPLE:
Parameter
1942409
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
Aluminum
ug/L
80
75.1
94
80-120
Antimony
ug/L
80
79.8
100
80-120
Arsenic
ug/L
80
78.9
99
80-120
Barium
ug/L
80
78.9
99
80-120
Beryllium
ug/L
80
76.6
96
80-120
Boron
ug/L
80
78.1
98
80-120
Cadmium
ug/L
80
78.4
98
80-120
Calcium
ug/L
1000
908
91
80-120
Chromium
ug/L
80
78.7
98
80-120
Cobalt
ug/L
80
77.4
97
80-120
Copper
ug/L
80
76.8
96
80-120
Iron
ug/L
1000
983
98
80-120
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2015 07:34 AM without the written consent of Pace Analytical Services, Inc.. Page 79 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
98000WWYI�e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040322
Pace Project No.: 92245627
LABORATORY CONTROL SAMPLE:
1942409
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits
Qualifiers
Lead
ug/L
80
79.1
99
80-120
Magnesium
ug/L
1000
960
96
80-120
Manganese
ug/L
80
78.6
98
80-120
Molybdenum
ug/L
80
75.6
95
80-120
Nickel
ug/L
80
80.3
100
80-120
Potassium
ug/L
1000
985
98
80-120
Selenium
ug/L
80
79.2
99
80-120
Sodium
ug/L
1000
958
96
80-120
Strontium
ug/L
80
77.4
97
80-120
Thallium
ug/L
80
77.3
97
80-120
Vanadium
ug/L
80
78.8
99
80-120
Zinc
ug/L
80
79.9
100
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
1943026
1943027
MS
MSD
92245612006
Spike
Spike
MS
MSD
MS MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec % Rec
Limits
RPD
RPD Qual
Aluminum
ug/L
ND
80
80
83.9
76.5
105
95
75-125
9
20
Antimony
ug/L
ND
80
80
79.9
79.8
100
100
75-125
0
20
Arsenic
ug/L
ND
80
80
78.9
80.7
99
101
75-125
2
20
Barium
ug/L
ND
80
80
79.7
77.8
100
97
75-125
2
20
Beryllium
ug/L
ND
80
80
75.7
75.9
95
95
75-125
0
20
Boron
ug/L
ND
80
80
78.4
75.1
98
94
75-125
4
20
Cadmium
ug/L
ND
80
80
78.2
78.2
98
98
75-125
0
20
Calcium
ug/L
ND
1000
1000
956
1050
95
104
75-125
9
20
Chromium
ug/L
ND
80
80
78.6
78.1
98
98
75-125
1
20
Cobalt
ug/L
ND
80
80
78.4
78.3
98
98
75-125
0
20
Copper
ug/L
ND
80
80
130
78.9
162
98
75-125
49
20 M1,R1
Iron
ug/L
ND
1000
1000
970
987
97
99
75-125
2
20
Lead
ug/L
ND
80
80
82.6
79.2
103
99
75-125
4
20
Magnesium
ug/L
ND
1000
1000
966
977
96
98
75-125
1
20
Manganese
ug/L
ND
80
80
79.1
78.8
99
98
75-125
0
20
Molybdenum
ug/L
ND
80
80
76.2
75.6
95
94
75-125
1
20
Nickel
ug/L
ND
80
80
81.8
81.0
102
101
75-125
1
20
Potassium
ug/L
ND
1000
1000
973
975
97
97
75-125
0
20
Selenium
ug/L
ND
80
80
80.5
79.0
101
99
75-125
2
20
Sodium
ug/L
ND
1000
1000
980
951
98
95
75-125
3
20
Strontium
ug/L
ND
80
80
77.5
77.4
97
97
75-125
0
20
Thallium
ug/L
ND
80
80
79.4
79.1
99
99
75-125
0
20
Vanadium
ug/L
ND
80
80
79.0
79.6
99
99
75-125
1
20
Zinc
ug/L
ND
80
80
118
79.7
146
98
75-125
39
20 M1,R1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2015 07:34 AM without the written consent of Pace Analytical Services, Inc..
Page 80 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800�rWY2"�e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040322
Pace Project No.: 92245627
QC Batch: MPRP/54343 Analysis Method: EPA 6020A
QC Batch Method: EPA 3020 Analysis Description: 6020A Water UPD4
Associated Lab Samples: 92245627016, 92245627017, 92245627018, 92245627019, 92245627021, 92245627023
METHOD BLANK: 1963685 Matrix: Water
Associated Lab Samples: 92245627016, 92245627017, 92245627018, 92245627019, 92245627021, 92245627023
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Aluminum
ug/L
ND
10.0
05/15/1513:22
Antimony
ug/L
ND
0.50
05/14/15 20:15
Arsenic
ug/L
ND
0.50
05/14/15 20:15
Barium
ug/L
ND
0.30
05/14/15 20:15
Beryllium
ug/L
ND
0.20
05/14/15 20:15
Boron
ug/L
1.8J
5.0
05/14/15 20:15
Cadmium
ug/L
ND
0.080
05/14/15 20:15
Calcium
ug/L
ND
40.0
05/14/15 20:15
Chromium
ug/L
ND
0.50
05/14/15 20:15
Cobalt
ug/L
ND
0.50
05/14/15 20:15
Copper
ug/L
ND
1.0
05/14/15 20:15
Iron
ug/L
ND
50.0
05/14/15 20:15
Lead
ug/L
ND
0.10
05/14/15 20:15
Magnesium
ug/L
ND
10.0
05/14/15 20:15
Manganese
ug/L
ND
0.50
05/14/15 20:15
Molybdenum
ug/L
ND
0.50
05/14/15 20:15
Nickel
ug/L
ND
0.50
05/14/15 20:15
Potassium
ug/L
ND
50.0
05/14/15 20:15
Selenium
ug/L
ND
0.50
05/14/15 20:15
Sodium
ug/L
ND
50.0
05/14/15 20:15
Strontium
ug/L
ND
0.50
05/14/15 20:15
Thallium
ug/L
ND
0.10
05/14/15 20:15
Vanadium
ug/L
ND
1.0
05/14/15 20:15
Zinc
ug/L
ND
5.0
05/14/15 20:15
LABORATORY CONTROL SAMPLE:
Parameter
1963686
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
Aluminum
ug/L
80
81.6
102
80-120
Antimony
ug/L
80
75.9
95
80-120
Arsenic
ug/L
80
80.1
100
80-120
Barium
ug/L
80
85.2
106
80-120
Beryllium
ug/L
80
77.7
97
80-120
Boron
ug/L
80
78.7
98
80-120
Cadmium
ug/L
80
84.0
105
80-120
Calcium
ug/L
1000
1020
102
80-120
Chromium
ug/L
80
83.0
104
80-120
Cobalt
ug/L
80
81.5
102
80-120
Copper
ug/L
80
84.6
106
80-120
Iron
ug/L
1000
1030
103
80-120
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2015 07:34 AM without the written consent of Pace Analytical Services, Inc.. Page 81 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980M'6fY2"1e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040322
Pace Project No.: 92245627
LABORATORY CONTROL SAMPLE:
1963686
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits
Qualifiers
Lead
ug/L
80
83.9
105
80-120
Magnesium
ug/L
1000
934
93
80-120
Manganese
ug/L
80
79.9
100
80-120
Molybdenum
ug/L
80
81.5
102
80-120
Nickel
ug/L
80
81.8
102
80-120
Potassium
ug/L
1000
950
95
80-120
Selenium
ug/L
80
79.8
100
80-120
Sodium
ug/L
1000
1010
101
80-120
Strontium
ug/L
80
77.1
96
80-120
Thallium
ug/L
80
89.1
111
80-120
Vanadium
ug/L
80
81.0
101
80-120
Zinc
ug/L
80
83.8
105
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
1963687
1963688
MS
MSD
92249101001
Spike
Spike
MS
MSD
MS MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec % Rec
Limits
RPD
RPD Qual
Aluminum
ug/L
643
80
80
1200
1210
694
713
75-125
1
20 M1
Antimony
ug/L
ND
80
80
76.8
77.4
96
97
75-125
1
20
Arsenic
ug/L
0.60
80
80
82.3
83.8
102
104
75-125
2
20
Barium
ug/L
11.3
80
80
92.0
91.9
101
101
75-125
0
20
Beryllium
ug/L
ND
80
80
79.8
82.8
100
104
75-125
4
20
Boron
ug/L
2.2J
80
80
82.5
86.0
100
105
75-125
4
20
Cadmium
ug/L
ND
80
80
85.9
85.7
107
107
75-125
0
20
Calcium
ug/L
1150
1000
1000
2170
2050
102
90
75-125
6
20
Chromium
ug/L
3.5
80
80
86.1
86.1
103
103
75-125
0
20
Cobalt
ug/L
0.65
80
80
82.6
82.3
102
102
75-125
0
20
Copper
ug/L
2.5
80
80
88.3
88.0
107
107
75-125
0
20
Iron
ug/L
2690
1000
1000
3780
3740
109
105
75-125
1
20
Lead
ug/L
0.44
80
80
81.6
82.0
101
102
75-125
0
20
Magnesium
ug/L
214
1000
1000
1160
1150
94
94
75-125
0
20
Manganese
ug/L
37.8
80
80
117
116
99
98
75-125
0
20
Molybdenum
ug/L
2.4
80
80
85.3
84.7
104
103
75-125
1
20
Nickel
ug/L
3.2
80
80
85.1
85.7
102
103
75-125
1
20
Potassium
ug/L
468
1000
1000
1350
1390
89
92
75-125
2
20
Selenium
ug/L
0.32J
80
80
81.1
83.4
101
104
75-125
3
20
Sodium
ug/L
364
1000
1000
1370
1390
101
103
75-125
1
20
Strontium
ug/L
4.4
80
80
84.6
85.0
100
101
75-125
0
20
Thallium
ug/L
0.018J
80
80
87.1
88.1
109
110
75-125
1
20
Vanadium
ug/L
2.5
80
80
83.5
82.9
101
100
75-125
1
20
Zinc
ug/L
4.5J
80
80
87.6
89.1
104
106
75-125
2
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2015 07:34 AM without the written consent of Pace Analytical Services, Inc..
Page 82 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
98Q0ir6fY2"1e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040322
Pace Project No.: 92245627
QC Batch: PMST/3479
Analysis Method:
ASTM D2974-87
QC Batch Method: ASTM
D2974-87
Analysis Description:
Dry Weight/Percent Moisture
Associated Lab Samples:
92245627003,
92245627004, 92245627005, 92245627006,
92245627007, 92245627009,
92245627010,
92245627011,92245627012,92245627013,92245627014,92245627015
SAMPLE DUPLICATE:
1192377
92245394016
Dup
Max
Parameter
Units
Result
Result RPD
RPD
Qualifiers
Percent Moisture
%
19.3
20.4 5
10
SAMPLE DUPLICATE:
1192394
35184321009
Dup
Max
Parameter
Units
Result
Result RPD
RPD
Qualifiers
Percent Moisture
%
2.3
2.8 19
10 D6
SAMPLE DUPLICATE:
1192395
92245627011
Dup
Max
Parameter
Units
Result
Result RPD
RPD
Qualifiers
Percent Moisture
%
40.1
42.5 6
10
SAMPLE DUPLICATE:
1192396
35184455005
Dup
Max
Parameter
Units
Result
Result RPD
RPD
Qualifiers
Percent Moisture
%
6.2
6.7 8
10
SAMPLE DUPLICATE:
1192397
35184857004
Dup
Max
Parameter
Units
Result
Result RPD
RPD
Qualifiers
Percent Moisture
%
21.5
20.8 3
10
SAMPLE DUPLICATE:
1192398
35184857008
Dup
Max
Parameter
Units
Result
Result RPD
RPD
Qualifiers
Percent Moisture
%
19.0
19.9 5
10
SAMPLE DUPLICATE:
1192399
35184308001
Dup
Max
Parameter
Units
Result
Result RPD
RPD
Qualifiers
Percent Moisture
%
74.6
75.8 2
10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2015 07:34 AM without the written consent of Pace Analytical Services, Inc.. Page 83 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
98"rWY11" Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040322
Pace Project No.: 92245627
QC Batch: WET/36942 Analysis Method: EPA 9045
QC Batch Method: EPA 9045 Analysis Description: 9045 pH
Associated Lab Samples: 92245627003, 92245627004, 92245627005, 92245627006, 92245627007
SAMPLE DUPLICATE: 1438600
92245612013 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
pH at 25 Degrees C Std. Units 6.6 6.6 0 10
SAMPLE DUPLICATE: 1438601
92245627004 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
pH at 25 Degrees C Std. Units 6.6 6.6 0 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2015 07:34 AM without the written consent of Pace Analytical Services, Inc.. Page 84 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980Mr6fY2"1e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040322
Pace Project No.: 92245627
QC Batch: WET/36947 Analysis Method: EPA 9045
QC Batch Method: EPA 9045 Analysis Description: 9045 pH
Associated Lab Samples: 92245627009,92245627010,92245627011,92245627012,92245627013,92245627014,92245627015
SAMPLE DUPLICATE: 1438913
92246075013 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
pH at 25 Degrees C Std. Units 6.4 6.3 2 10 H3
SAMPLE DUPLICATE: 1438914
92245627010 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
pH at 25 Degrees C Std. Units 6.3 6.5 4 10 H1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2015 07:34 AM without the written consent of Pace Analytical Services, Inc.. Page 85 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980�ir6fY2"1e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040322
Pace Project No.: 92245627
QC Batch: WETA/22735
Analysis Method: EPA 300.0
QC Batch Method: EPA 300.0
Analysis Description: 300.0 IC Anions
Associated Lab Samples: 92245627005, 92245627006,
92245627007, 92245627010, 92245627013
METHOD BLANK: 1445696
Matrix: Water
Associated Lab Samples: 92245627005, 92245627006,
92245627007, 92245627010, 92245627013
Blank Reporting
Parameter Units
Result Limit Analyzed Qualifiers
Sulfate mg/L
3.4 2.0 04/29/1513:00
LABORATORY CONTROL SAMPLE: 1445697
Spike LCS LCS % Rec
Parameter Units
Conc. Result % Rec Limits Qualifiers
Sulfate mg/L
20 19.4 97 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1445698 1445699
MS MSD
92245352011
Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfate mg/L 1.7J
23.9 23.9 23.5 23.2 91 90 1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1445700 1445701
MS MSD
92245637002 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfate mg/L 11.0 20 20 31.2 31.3 101 102 0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2015 07:34 AM without the written consent of Pace Analytical Services, Inc..
Page 86 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980Mr6fY2"1e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040322
Pace Project No.: 92245627
QC Batch: WETA/22814 Analysis Method: EPA 300.0
QC Batch Method: EPA 300.0 Analysis Description: 300.0 IC Anions
Associated Lab Samples: 92245627014
METHOD BLANK: 1450589 Matrix: Water
Associated Lab Samples: 92245627014
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Sulfate mg/L 3.4 2.0 05/05/1517:27
LABORATORY CONTROL SAMPLE: 1450590
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Sulfate mg/L 20 19.8 99 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1450591 1450592
MS MSD
92245627014 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfate mg/L 13.7 27.5 27.5 40.3 40.6 97 98 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2015 07:34 AM without the written consent of Pace Analytical Services, Inc..
Page 87 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980Mr6fY2"1e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040322
Pace Project No.: 92245627
QC Batch: WETA/22748
Analysis Method: EPA 353.2
QC Batch Method: EPA 353.2
Analysis Description: 353.2 Nitrate + Nitrite, Unpres.
Associated Lab Samples: 92245627005, 92245627006,
92245627007, 92245627010, 92245627013
METHOD BLANK: 1446743
Matrix: Water
Associated Lab Samples: 92245627005, 92245627006,
92245627007, 92245627010, 92245627013
Blank Reporting
Parameter Units
Result Limit Analyzed Qualifiers
Nitrogen, Nitrate mg/L
0.15 0.020 04/29/15 20:34 Z2
LABORATORY CONTROL SAMPLE: 1446744
Spike LCS LCS % Rec
Parameter Units
Conc. Result % Rec Limits Qualifiers
Nitrogen, Nitrate mg/L
2.5 2.6 102 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1446745 1446746
MS MSD
92245352011
Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Nitrogen, Nitrate mg/L ND
3 3 3.3 3.3 103 103 90-110 0 10 H1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1446747 1446748
MS MSD
92245352012 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Nitrogen, Nitrate mg/L ND 3.2 3.2 3.5 3.4 102 102 90-110 0 10 H1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2015 07:34 AM without the written consent of Pace Analytical Services, Inc..
Page 88 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
98"'WY11e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040322
Pace Project No.: 92245627
QC Batch: WETA/22905
Analysis Method: EPA 353.2
QC Batch Method: EPA 353.2
Analysis Description: 353.2 Nitrate + Nitrite, Unpres.
Associated Lab Samples: 92245627014
METHOD BLANK: 1457411
Matrix: Water
Associated Lab Samples: 92245627014
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Nitrogen, Nitrate mg/L
0.16 0.020
05/13/15 13:14 Z2
LABORATORY CONTROL SAMPLE: 1457412
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Nitrogen, Nitrate mg/L
2.5 2.5
101 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1457413 1457414
MS MSD
92247080002
Spike Spike MS
MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec Limits RPD RPD Qual
Nitrogen, Nitrate mg/L 0.23
2.8 2.8 3.1
3.1 103 103 90-110 1 10 H1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1457545 1457546
MS MSD
92247233008 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Nitrogen, Nitrate mg/L 0.24 3 3 3.3 3.3 103 104 90-110 0 10 H1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2015 07:34 AM without the written consent of Pace Analytical Services, Inc..
Page 89 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
98"WieYlle. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040322
Pace Project No.: 92245627
QC Batch: WETA/22743
Analysis Method: SM 4500-CI-E
QC Batch Method: SM 4500-CI-E
Analysis Description: 4500 Chloride
Associated Lab Samples: 92245627005, 92245627006,
92245627007, 92245627010, 92245627013
METHOD BLANK: 1446034
Matrix: Water
Associated Lab Samples: 92245627005, 92245627006,
92245627007, 92245627010, 92245627013
Blank Reporting
Parameter Units
Result Limit Analyzed Qualifiers
Chloride mg/L
ND 1.0 04/30/15 01:35
LABORATORY CONTROL SAMPLE: 1446035
Spike LCS LCS % Rec
Parameter Units
Conc. Result % Rec Limits Qualifiers
Chloride mg/L
20 21.1 106 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1446036 1446037
MS MSD
92245352011
Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Chloride mg/L ND
23.9 23.9 24.6 24.4 102 101 90-110 1 10
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1446038 1446039
MS MSD
92245637002 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Chloride mg/L ND 20 20 22.3 22.0 103 101 90-110 1 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2015 07:34 AM without the written consent of Pace Analytical Services, Inc..
Page 90 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
98"rWY11" Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040322
Pace Project No.: 92245627
QC Batch: WETA/22862
Analysis Method: SM 4500-CI-E
QC Batch Method: SM 4500-CI-E
Analysis Description: 4500 Chloride
Associated Lab Samples: 92245627014
METHOD BLANK: 1454397
Matrix: Water
Associated Lab Samples: 92245627014
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Chloride mg/L
ND 1.0
05/09/15 03:31
LABORATORY CONTROL SAMPLE: 1454398
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Chloride mg/L
20 20.2
101 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1454399 1454400
MS MSD
92245627014
Spike Spike MS
MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec Limits RPD RPD Qual
Chloride mg/L ND
27.5 27.5 29.0
28.7 103 103 90-110 1 10
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1454401 1454402
MS MSD
92247233008 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Chloride mg/L ND 23.9 23.9 24.8 24.6 101 100 90-110 1 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2015 07:34 AM without the written consent of Pace Analytical Services, Inc..
Page 91 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
98QQ11blr6fY2"1e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040322
Pace Project No.: 92245627
QC Batch: WETA/45549 Analysis Method: EPA 9056
QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions
Associated Lab Samples: 92245627003, 92245627004, 92245627005, 92245627006, 92245627007, 92245627009, 92245627010,
92245627011,92245627012,92245627013,92245627014,92245627015
METHOD BLANK: 1187892 Matrix: Solid
Associated Lab Samples:
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Chloride mg/kg ND 49.9 04/18/15 20:52
Sulfate mg/kg ND 49.9 04/18/15 20:52
LABORATORY CONTROL SAMPLE:
1187893
Parameter
Units
Chloride
mg/kg
Sulfate
mg/kg
MATRIX SPIKE SAMPLE:
1187895
Parameter
Units
Chloride
mg/kg
Sulfate
mg/kg
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
500 485 97 80-120
500 484 97 80-120
92245417003 Spike MS MS % Rec
Result Conc. Result % Rec Limits Qualifiers
ND 590 556 94 80-120
ND 590 578 98 80-120
SAMPLE DUPLICATE: 1187894
92245417003 Dup
Parameter Units Result Result
Chloride mg/kg ND ND
Sulfate mg/kg ND ND
Max
RPD RPD Qualifiers
20
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2015 07:34 AM without the written consent of Pace Analytical Services, Inc.. Page 92 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
98QQ1KIir6fY2"1e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040322
Pace Project No.: 92245627
QC Batch: WETA/45548
Analysis Method: EPA 9056
QC Batch Method: EPA 9056
Analysis Description: 9056 IC Anions
Associated Lab Samples: 92245627003, 92245627004, 92245627005, 92245627006, 92245627007, 92245627009, 92245627010,
92245627011,92245627012,92245627013,92245627014,92245627015
METHOD BLANK: 1187887
Matrix: Solid
Associated Lab Samples:
Blank Reporting
Parameter
Units
Result Limit Analyzed
Qualifiers
Nitrate as N
mg/kg
ND 5.0 04/18/15 20:52
LABORATORY CONTROL SAMPLE:
1187888
Spike LCS LCS
% Rec
Parameter
Units
Conc. Result % Rec
Limits Qualifiers
Nitrate as N
mg/kg
50 50.3 101
80-120
MATRIX SPIKE SAMPLE:
1187890
92245417003 Spike MS
MS % Rec
Parameter
Units
Result Conc. Result
% Rec Limits Qualifiers
Nitrate as N
mg/kg
ND 59 55.5
94 80-120 H3
SAMPLE DUPLICATE: 1187889
92245417003 Dup
Max
Parameter
Units
Result Result RPD
RPD Qualifiers
Nitrate as N
mg/kg
ND ND
20 H3
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2015 07:34 AM without the written consent of Pace Analytical Services, Inc.. Page 93 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
98QM7WeY2"1e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040322
Pace Project No.: 92245627
QC Batch: WETA/28320
Analysis Method: EPA 9060
QC Batch Method: EPA 9060
Analysis Description: 9060 TOC Average
Associated Lab Samples: 92245627003, 92245627004,
92245627005,
92245627006, 92245627007, 92245627009, 92245627010,
92245627011,92245627012
METHOD BLANK: 1151702
Matrix: Solid
Associated Lab Samples:
Blank
Reporting
Parameter Units
Result
Limit
Analyzed Qualifiers
Mean Total Organic Carbon mg/kg
ND 600
05/06/15 13:21
LABORATORY CONTROL SAMPLE: 1151703
Spike
LCS
LCS % Rec
Parameter Units
Conc.
Result
% Rec Limits Qualifiers
Mean Total Organic Carbon mg/kg
120000
125000
104 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1151704
1151705
MS
MSD
92245627003
Spike
Spike MS
MSD MS MSD
% Rec
Max
Parameter Units Result
Conc.
Conc. Result
Result % Rec % Rec
Limits
RPD RPD Qual
Mean Total Organic Carbon mg/kg 104000
91000
91700 208000
206000 114 111
50-150
1 30
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1151706
1151707
MS
MSD
92245627004
Spike
Spike MS
MSD MS MSD
% Rec
Max
Parameter Units Result
Conc.
Conc. Result
Result % Rec % Rec
Limits
RPD RPD Qual
Mean Total Organic Carbon mg/kg 82900
65500
64400 160000
141000 118 90
50-150
13 30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2015 07:34 AM without the written consent of Pace Analytical Services, Inc..
Page 94 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
98QQ1K5reY2"1e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040322
Pace Project No.: 92245627
QC Batch: WETA/28413
Analysis Method: EPA 9060
QC Batch Method: EPA 9060
Analysis Description: 9060 TOC Average
Associated Lab Samples: 92245627013, 92245627014,
92245627015
METHOD BLANK: 1154316
Matrix: Solid
Associated Lab Samples:
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Mean Total Organic Carbon mg/kg
ND 600
05/11/15 09:53
LABORATORY CONTROL SAMPLE: 1154317
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Mean Total Organic Carbon mg/kg
120000 118000
99 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1154318 1154319
MS MSD
92245627013
Spike Spike MS
MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec Limits RPD RPD Qual
Mean Total Organic Carbon mg/kg 175000
74100 74500 234000
263000 79 118 50-150 12 30
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1154320 1154321
MS MSD
92247019006 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Mean Total Organic Carbon mg/kg 524J 6950 6920 6130 6060 81 80 50-150 1 30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2015 07:34 AM without the written consent of Pace Analytical Services, Inc..
Page 95 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
98QQ11'ir6fY2"1e. Suite 100
Huntersville, NC 28078
[phone]
QUALIFIERS
Project: J15040322
Pace Project No.: 92245627
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
LABORATORIES
PASI-A
Pace Analytical Services - Asheville
PASI-G
Pace Analytical Services - Green Bay
PASI-M
Pace Analytical Services - Minneapolis
PASI-O
Pace Analytical Services - Ormond Beach
BATCH QUALIFIERS
Batch: ICP/14506
Ill Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
Batch: ICPM/9649
III Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
ANALYTE QUALIFIERS
1g %RSD>40
B Analyte was detected in the associated method blank.
D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
D6 The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits.
H1 Analysis conducted outside the EPA method holding time.
H1 Analysis conducted outside the recognized method holding time.
REPORT OF LABORATORY ANALYSIS
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Date: 06/15/2015 07:34 AM without the written consent of Pace Analytical Services, Inc.. Page 96 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
98QP WleY2"1e. Suite 100
Huntersville, INC 28078
[phone]
QUALIFIERS
Project: J15040322
Pace Project No.: 92245627
ANALYTE QUALIFIERS
H2 Extraction or preparation was conducted outside of the recognized method holding time.
H3 Sample was received or analysis requested beyond the recognized method holding time.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
N2 The lab does not hold TIN accreditation for this parameter.
P8 Analyte was detected in the method blank. All associated samples had concentrations of at least ten times greater than
the blank or were below the reporting limit.
R1 RPD value was outside control limits.
Z2 Analyte present in the associated method blank above the detection limit.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2015 07:34 AM without the written consent of Pace Analytical Services, Inc.. Page 97 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
98QPAWleY2"1e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
Pace Project No.:
J15040322
92245627
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92245627003
2015010705
EPA 3050
MPRP/23716
EPA 6010
ICP/14506
92245627004
2015010706
EPA 3050
MPRP/23716
EPA 6010
ICP/14506
92245627005
2015010707
EPA 3050
MPRP/23716
EPA 6010
ICP/14506
92245627006
2015010708
EPA 3050
MPRP/23716
EPA 6010
ICP/14506
92245627007
2015010709
EPA 3050
MPRP/23716
EPA 6010
ICP/14506
92245627009
2015010711
EPA 3050
MPRP/23716
EPA6010
ICP/14506
92245627010
2015010712
EPA 3050
MPRP/23716
EPA 6010
ICP/14506
92245627011
2015010713
EPA 3050
MPRP/23716
EPA 6010
ICP/14506
92245627012
2015010714
EPA 3050
MPRP/23716
EPA 6010
ICP/14506
92245627013
2015010715
EPA 3050
MPRP/23716
EPA 6010
ICP/14506
92245627014
2015010716
EPA 3050
MPRP/23716
EPA 6010
ICP/14506
92245627015
2015010717
EPA 3050
MPRP/23716
EPA 6010
ICP/14506
92245627003
2015010705
EPA 3050
MPRP/23717
EPA 6020
ICPM/9649
92245627004
2015010706
EPA 3050
MPRP/23717
EPA 6020
ICPM/9649
92245627005
2015010707
EPA 3050
MPRP/23717
EPA 6020
ICPM/9649
92245627006
2015010708
EPA 3050
MPRP/23717
EPA 6020
ICPM/9649
92245627007
2015010709
EPA 3050
MPRP/23717
EPA 6020
ICPM/9649
92245627009
2015010711
EPA 3050
MPRP/23717
EPA 6020
ICPM/9649
92245627010
2015010712
EPA 3050
MPRP/23717
EPA 6020
ICPM/9649
92245627011
2015010713
EPA 3050
MPRP/23717
EPA 6020
ICPM/9649
92245627012
2015010714
EPA 3050
MPRP/23717
EPA 6020
ICPM/9649
92245627013
2015010715
EPA 3050
MPRP/23717
EPA 6020
ICPM/9649
92245627014
2015010716
EPA 3050
MPRP/23717
EPA 6020
ICPM/9649
92245627015
2015010717
EPA 3050
MPRP/23717
EPA 6020
ICPM/9649
92245627001
2015010703
EPA 3020
MPRP/53712
EPA 6020A
ICPM/23855
92245627008
2015010710
EPA 3020
MPRP/53712
EPA 6020A
ICPM/23855
92245627016
2015010707 SPLP
EPA 3020
MPRP/54343
EPA 6020A
ICPM/24273
92245627017
2015010708 SPLP
EPA 3020
MPRP/54343
EPA 6020A
ICPM/24273
92245627018
2015010709 SPLP
EPA 3020
MPRP/54343
EPA 6020A
ICPM/24273
92245627019
2015010712 SPLP
EPA 3020
MPRP/54343
EPA 6020A
ICPM/24273
92245627021
2015010715 SPLP
EPA 3020
MPRP/54343
EPA 6020A
ICPM/24273
92245627022
2015010718
EPA 3020
MPRP/53712
EPA 6020A
ICPM/23855
92245627023
2015010716 SPLP
EPA 3020
MPRP/54343
EPA 6020A
ICPM/24273
92245627001
2015010703
EPA 7470
MERP/13265
EPA 7470
MERC/15439
92245627008
2015010710
EPA 7470
MERP/13265
EPA 7470
MERC/15439
92245627022
2015010718
EPA 7470
MERP/13265
EPA 7470
MERC/15439
92245627016
2015010707 SPLP
EPA 7470A
MERP/13538
EPA 7470A
MERC/15723
92245627017
2015010708 SPLP
EPA 7470A
MERP/13538
EPA 7470A
MERC/15723
92245627018
2015010709 SPLP
EPA 7470A
MERP/13538
EPA 7470A
MERC/15723
92245627019
2015010712 SPLP
EPA 7470A
MERP/13538
EPA 7470A
MERC/15723
92245627021
2015010715 SPLP
EPA 7470A
MERP/13538
EPA 7470A
MERC/15723
92245627023
2015010716 SPLP
EPA 7470A
MERP/13538
EPA 7470A
MERC/15723
92245627003
2015010705
EPA 7471
MERP/5614
EPA 7471
MERC/5602
92245627004
2015010706
EPA 7471
MERP/5614
EPA 7471
MERC/5602
92245627005
2015010707
EPA 7471
MERP/5614
EPA 7471
MERC/5602
REPORT OF LABORATORY
ANALYSIS
This report shall not be reproduced, except
in full,
Date: 06/15/2015
07:34 AM
without the written consent of Pace Analytical Services, Inc..
Page 98 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980P*WleY2"1e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
J15040322
Pace Project No.:
92245627
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method Batch
92245627006
2015010708
EPA 7471
MERP/5614
EPA 7471 MERC/5602
92245627007
2015010709
EPA 7471
MERP/5614
EPA 7471 MERC/5602
92245627009
2015010711
EPA 7471
MERP/5614
EPA 7471 MERC/5602
92245627010
2015010712
EPA 7471
MERP/5614
EPA 7471 MERC/5602
92245627011
2015010713
EPA 7471
MERP/5614
EPA 7471 MERC/5602
92245627012
2015010714
EPA 7471
MERP/5614
EPA 7471 MERC/5602
92245627013
2015010715
EPA 7471
MERP/5614
EPA 7471 MERC/5602
92245627014
2015010716
EPA 7471
MERP/5614
EPA 7471 MERC/5602
92245627015
2015010717
EPA 7471
MERP/5614
EPA 7471 MERC/5602
92245627003
2015010705
ASTM D2974-87
PMST/3479
92245627004
2015010706
ASTM D2974-87
PMST/3479
92245627005
2015010707
ASTM D2974-87
PMST/3479
92245627006
2015010708
ASTM D2974-87
PMST/3479
92245627007
2015010709
ASTM D2974-87
PMST/3479
92245627009
2015010711
ASTM D2974-87
PMST/3479
92245627010
2015010712
ASTM D2974-87
PMST/3479
92245627011
2015010713
ASTM D2974-87
PMST/3479
92245627012
2015010714
ASTM D2974-87
PMST/3479
92245627013
2015010715
ASTM D2974-87
PMST/3479
92245627014
2015010716
ASTM D2974-87
PMST/3479
92245627015
2015010717
ASTM D2974-87
PMST/3479
92245627003
2015010705
EPA 9045
WET/36942
92245627004
2015010706
EPA 9045
WET/36942
92245627005
2015010707
EPA 9045
WET/36942
92245627006
2015010708
EPA 9045
WET/36942
92245627007
2015010709
EPA 9045
WET/36942
92245627009
2015010711
EPA 9045
WET/36947
92245627010
2015010712
EPA 9045
WET/36947
92245627011
2015010713
EPA 9045
WET/36947
92245627012
2015010714
EPA 9045
WET/36947
92245627013
2015010715
EPA 9045
WET/36947
92245627014
2015010716
EPA 9045
WET/36947
92245627015
2015010717
EPA 9045
WET/36947
92245627005
2015010707
EPA 300.0
WETA/22735
92245627006
2015010708
EPA 300.0
WETA/22735
92245627007
2015010709
EPA 300.0
WETA/22735
92245627010
2015010712
EPA 300.0
WETA/22735
92245627013
2015010715
EPA 300.0
WETA/22735
92245627014
2015010716
EPA 300.0
WETA/22814
92245627005
2015010707
EPA 353.2
WETA/22748
92245627006
2015010708
EPA 353.2
WETA/22748
92245627007
2015010709
EPA 353.2
WETA/22748
92245627010
2015010712
EPA 353.2
WETA/22748
92245627013
2015010715
EPA 353.2
WETA/22748
92245627014
2015010716
EPA 353.2
WETA/22905
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2015 07:34 AM without the written consent of Pace Analytical Services, Inc.. Page 99 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980PAWleYlle. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: J15040322
Pace Project No.: 92245627
Lab ID Sample ID QC Batch Method QC Batch
92245627005
2015010707
SM 4500-CI-E
WETA/22743
92245627006
2015010708
SM 4500-CI-E
WETA/22743
92245627007
2015010709
SM 4500-CI-E
WETA/22743
92245627010
2015010712
SM 4500-CI-E
WETA/22743
92245627013
2015010715
SM 4500-CI-E
WETA/22743
92245627014
2015010716
SM 4500-CI-E
WETA/22862
92245627003
2015010705
EPA 9056
WETA/45549
92245627004
2015010706
EPA 9056
WETA/45549
92245627005
2015010707
EPA 9056
WETA/45549
92245627006
2015010708
EPA 9056
WETA/45549
92245627007
2015010709
EPA 9056
WETA/45549
92245627009
2015010711
EPA 9056
WETA/45549
92245627010
2015010712
EPA 9056
WETA/45549
92245627011
2015010713
EPA 9056
WETA/45549
92245627012
2015010714
EPA 9056
WETA/45549
92245627013
2015010715
EPA 9056
WETA/45549
92245627014
2015010716
EPA 9056
WETA/45549
92245627015
2015010717
EPA 9056
WETA/45549
92245627003
2015010705
EPA 9056
WETA/45548
92245627004
2015010706
EPA 9056
WETA/45548
92245627005
2015010707
EPA 9056
WETA/45548
92245627006
2015010708
EPA 9056
WETA/45548
92245627007
2015010709
EPA 9056
WETA/45548
92245627009
2015010711
EPA 9056
WETA/45548
92245627010
2015010712
EPA 9056
WETA/45548
92245627011
2015010713
EPA 9056
WETA/45548
92245627012
2015010714
EPA 9056
WETA/45548
92245627013
2015010715
EPA 9056
WETA/45548
92245627014
2015010716
EPA 9056
WETA/45548
92245627015
2015010717
EPA 9056
WETA/45548
92245627003
2015010705
EPA
9060
WETA/28320
92245627003
2015010705
EPA
9060
WETA/28321
92245627004
2015010706
EPA
9060
WETA/28320
92245627004
2015010706
EPA
9060
WETA/28321
92245627005
2015010707
EPA
9060
WETA/28320
92245627005
2015010707
EPA
9060
WETA/28321
92245627006
2015010708
EPA
9060
WETA/28320
92245627006
2015010708
EPA
9060
WETA/28321
92245627007
2015010709
EPA
9060
WETA/28320
92245627007
2015010709
EPA
9060
WETA/28321
92245627009
2015010711
EPA
9060
WETA/28320
Date: 06/15/2015 07:34 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Analytical Method
Analytical
Batch
Page 100 of 103

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
98QPAWleY2"1e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: J15040322
Pace Project No.: 92245627
Lab ID
Sample ID
QC Batch Method
QC Batch
92245627009
2015010711
EPA
9060
WETA/28321
92245627010
2015010712
EPA
9060
WETA/28320
92245627010
2015010712
EPA
9060
WETA/28321
92245627011
2015010713
EPA
9060
WETA/28320
92245627011
2015010713
EPA
9060
WETA/28321
92245627012
2015010714
EPA
9060
WETA/28320
92245627012
2015010714
EPA
9060
WETA/28321
92245627013
2015010715
EPA
9060
WETA/28413
92245627013
2015010715
EPA
9060
WETA/28414
92245627014
2015010716
EPA
9060
WETA/28413
92245627014
2015010716
EPA
9060
WETA/28414
92245627015
2015010717
EPA
9060
WETA/28413
92245627015
2015010717
EPA
9060
WETA/28414
Date: 06/15/2015 07:34 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Analytical Method
Analytical
Batch
Page 101 of 103

Document Name: Document Revised: September 22. 2U14
e�Analytreal Sample Condition Upon Receipt SCUR Page I of 2 122
Document Number: Issuing Authorit .
i F-CHR-CS-003-rev.15 Pace Huntersville Quality Office
Client Name:
Courier., ❑ Fed Ex [IUPS❑ USPS❑ Client[] mercial❑ Pee- Other
Custody Seat on CoolerlBox Present: ❑ yes' no Seals intact: ❑ yes ❑ no
Packing Material: ❑ Bubble VI D ❑ Bubble Bags ❑ None ❑ Other
Thermometer Used: IR Gun T1 �
Type of Ice: Wet Blue
None Sampies on ice, cooling process has begun
Temp Correction Factor 441 No Correction
-C Biological Tissue is Frozen: Yes No Date and Initial Piersan examining
Corrected Cooler Temp.: contents:
Temp should be alcove freezing to 6°C
Comments:
Chain of Custody Present:
© ❑NIA 1.
Chain of Custody Filled Out:
❑Y s
❑ ❑NIA 2.
Chain of Custody Relinquished:
El es
6 ❑NIA 3,
Sampler Name & Signature on COC:
❑N s
o El NIA 4.
Samples Arrived within Hold Time:
es
ONO ONIA 5.
Short Hold Time Analysis (<72hr):
Oyes
C1 0 ❑NIA 6.
Rush Turn Around Time Requested:
❑Yes
o ❑NIA 7.
Sufficient Volume:
es
o ❑NIA 8,
Correct Containers Used:
❑ es
❑No r 9.
-Pace Containers Used:
❑Yes
br- ❑NIA
Containers Intact:
❑ es
❑No ❑NIA 10.
Filtered volume received for Dissolved tests
Sample Labels match COC:
-includes date/time/ID/Analysis Matrix:
Dyes
❑ " s
❑N 11.
tL ❑NIA 12,
All containers needing preservation have been checked.
❑ es e' ❑NIA 13.
- -ram
Ali containers needing preservation are found to be in
compliance with EPA recommendation.
❑Yes
❑No IA
G 1!
exceptions: VOA, coliform, TOG, O&G, VA-DRO (water) ❑Yes ❑No
Samples checked for dechlorination: ❑Yes ONO ❑ IA 1
Headspace in VOA Vials (>6mm): ❑Yes ❑No ®IA
Trip Blank Present: ❑Yes ONO �NIA
I 6.
Trip Blank Custody Seals Present ❑Yes ONO
Pace Trip Blank Lot # (if purchased):
Client Notification/ Resolution: Field Data Required? Y 1 N
Person Contacted: Date/Time:
Comments/ Resolution:
SCURF Review: PA Date:{5�15 W0# • 92245627
SRF Review: Date:
Note: Whenever there is a discrepancy affecting North Carolina compliance
samples, a copy of this form will be sent to the North Carolina DEHNR 92245627 1
Certification Office (i.e out of hold, incorrect preservative, out of temp,
incorrect containers)
Page 102 of 103

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Page 103 of 103

CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM 122 of 122
DUKE
®M
ENERGY
Analytical Laboratory Services i
I
Mail Code MG03A2 (Building 7405)
I
unter Hagere Ferry Rd
Huntereville, N. C. 28078
j
[phone]
Fax-a88018754349 --_ _ _ - _i
i Anal ical Laborato
Use Onl SYN ! E�?��D
rn:_x_ Page 1 Of 1
�— I DISTRIBUTION
Samples OriginatingFrom OH_ I
ORIGINAL to LAB,
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SAMPLE PROGRAM Ground Water_ NPDES;
Other _ Plant
Work Order
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Matrix: SOIL
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Date 8 Tlme
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1)Project Name AB Groundwater Assessment -Soil
Cape Fear
2)Phone No:
3.3
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Pp0 1142081
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Important: When specific accounting has been established and is not indicated above
we need the following:1 Enter correct accounting
) gin all 5 accounting fields above, Or
2 Provide correct accountingfor Operating Unit and Process ID.
Preservatives when used must be
added Within 15 minutes of aamPie
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