NC0003433_J15040239 Report_20150902

DUE Analytical Laboratory Page 1of78
' ENERGY
Order Number:
Project Name:
Customer Name(s):
Customer Address:
Lab Contact:
Report Authorized By:
(Signature)
Program Comments:
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone:[phone] Fax:[phone]
Order Summary Report
J15040239
CAPE FEAR - AB GW ASSESSMENT SOIL
Tim Hunsucker, Chris Suttell, Kathy Webb, John Toepfer
Margaret Galvin -Karr
[��pJ�(� MXG4644(101161)
rcr �"^ ��Y — 015.05.18 11:07:47
U C�WiK-04'00'
Margaret Galvin -Karr
Phone: [phone]
Date:
Please contact the Program Manager (Margaret Galvin -Karr) with any questions regarding this report.
Data Flags & Calculations:
5/8/2015
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Sample ID's & Descriptions:
Collection
Sample ID Plant/Station Date and Time
2015010247
2015010252
2015010253
2015010254
2015010255
2015010256
2015010257
7 Total Samples
Collected By
Sample Description
Cape Fear
07-Apr-15 9:15 AM
Synterra
ERB-14 (Sonic)
Cape Fear
07-Apr-15 4:25 PM
Synterra
MW-15SB (35-36)
Cape Fear
08-Apr-15 3:10 PM
Synterra
ERB-15 (Sonic)
Cape Fear
08-Apr-15 3:30 PM
Synterra
MW-10BRSB (0-2)
Cape Fear
08-Apr-15 4:45 PM
Synterra
MW-10BRSB (8-9)
Cape Fear
08-Apr-15 5:00 PM
Synterra
MW-10BRSB (15-16)
Cape Fear
08-Apr-15 5:15 PM
Synterra
MW-10BRSB (26-27)
Page 2 of 78

Page 3 of 78
Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals Yes No
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits. ❑ Yes No
All laboratory QA/QC requirements are acceptable. (] Yes ❑ No
Report Sections Included:
L� Job Summary Report
❑ Sample Identification
n Technical Validation of Data Package
6 Analytical Laboratory Certificate of Analysis
❑ Analytical Laboratory QC Report
LVI Sub -contracted Laboratory Results
❑ Customer Specific Data Sheets, Reports, & Documentation
❑ Customer Database Entries
6 Chain of Custody
LVI Electronic Data Deliverable (EDD) Sent Separately
Reviewed By: DBA Account Date: 5/8/2015

Certificate of Laboratory Analysis Page 4 of 78
This report shall not be reproduced, except in full.
Order # J15040239
Site: ERB-14 (Sonic)
Collection Date: 07-Apr-15 9:15 AM
Analyte Result Units Qualifiers RDL DF
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Sample #: 2015010247
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15040239
Site: MW-15SB (35-36)
Collection Date: 07-Apr-15 4:25 PM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
SPLP LEACHATE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Page 5 of 78
Sample #: 2015010252
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis Page 6 of 78
This report shall not be reproduced, except in full.
Order # J15040239
Site: ERB-15 (Sonic)
Collection Date: 08-Apr-15 3:10 PM
Analyte Result Units Qualifiers RDL DF
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Sample #: 2015010253
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15040239
Site: MW-10BRSB (0-2)
Collection Date: 08-Apr-15 3:30 PM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
SPLP LEACHATE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Page 7 of 78
Sample #: 2015010254
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15040239
Site: MW-10BRSB (8-9)
Collection Date: 08-Apr-15 4:45 PM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
SPLP LEACHATE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Page 8 of 78
Sample #: 2015010255
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15040239
Site: MW-10BRSB (15-16)
Collection Date: 08-Apr-15 5:00 PM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Page 9 of 78
Sample #: 2015010256
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15040239
Site: MW-10BRSB (26-27)
Collection Date: 08-Apr-15 5:15 PM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Page 10 of 78
Sample #: 2015010257
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
�Q�ff�in�c&fie. Suite 100
y Huntersville, INC 28078
[phone]
April 29, 2015
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg.7405 MG30A2
Huntersville, NC 28078
RE: Project: J 15040239
Pace Project No.: 92245128
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on April 10, 2015. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TN standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc: Marge Galvin -Karr, Duke Energy
Program Manager, Duke Energy
Rodney Wilke, Duke Energy
p«FO
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
lqe� ��� without the written consent of Pace Analytical Services, Inc..
BRAT,
Page 1 of 67

lacmnalyfica(
www.pacelabs.com
Pace Analytical Services, Inc.
og8gKi2cgf fre. Suite 100
Huntersville, NC 28078
[phone]
Project: J15040239
Pace Project No.: 92245128
Minnesota Certification IDs
1700 Elm Street SE Suite 200, Minneapolis, MN 55414
A21-A Certification #: 2926.01
Alaska Certification #: UST-078
Alaska Certification #MN00064
Alabama Certification #40770
Arizona Certification #: AZ-0014
Arkansas Certification #: 88-0680
California Certification #: 01155CA
Colorado Certification #Pace
Connecticut Certification #: PH-0256
EPA Region 8 Certification #: 8TMS-L
Florida/NELAP Certification #: E87605
Guam Certification #:14-008r
Georgia Certification #: 959
Georgia EPD #: Pace
Idaho Certification #: MN00064
Hawaii Certification #MN00064
Illinois Certification #: 200011
Indiana Certification#C-MN-01
Iowa Certification #: 368
Kansas Certification #: E-10167
Kentucky Dept of Envi. Protection - DW #90062
Kentucky Dept of Envi. Protection - WW #:90062
Louisiana DEQ Certification #: 3086
Louisiana DHH #: LA140001
Maine Certification #: 2013011
Maryland Certification #: 322
Michigan DEPH Certification #: 9909
Ormond Beach Certification IDs
8 East Tower Circle, Ormond Beach, FL 32174
Alabama Certification #: 41320
Connecticut Certification #: PH-0216
Delaware Certification: FL NELAC Reciprocity
Florida Certification #: E83079
Georgia Certification #: 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification #: 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383
Kentucky Certification #: 90050
Louisiana Certification #: FL NELAC Reciprocity
Louisiana Environmental Certificate #: 05007
Maryland Certification: #346
Massachusetts Certification #: M-FL1264
Michigan Certification #: 9911
Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236
Green Bay Certification IDs
1241 Bellevue Street, Green Bay, WI 54302
Florida/NELAP Certification #: E87948
Illinois Certification #: 200050
Kentucky Certification #: 82
Louisiana Certification #: 04168
Minnesota Certification #: 055-999-334
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
CERTIFICATIONS
Minnesota Certification #: 027-053-137
Mississippi Certification #: Pace
Montana Certification #: MT0092
Nevada Certification #: MN_00064
Nebraska Certification #: Pace
New Jersey Certification #: MN-002
New York Certification #: 11647
North Carolina Certification #: 530
North Carolina State Public Health #: 27700
North Dakota Certification #: R-036
Ohio EPA#: 4150
Ohio VAP Certification #: CL101
Oklahoma Certification #: 9507
Oregon Certification #: MN200001
Oregon Certification #: MN300001
Pennsylvania Certification #: 68-00563
Puerto Rico Certification
Saipan (CNMI) #:MP0003
South Carolina #:74003001
Texas Certification #: T104704192
Tennessee Certification #: 02818
Utah Certification #: MN000642013-4
Virginia DGS Certification #: 251
Virginia/VELAP Certification #: Pace
Washington Certification #: C486
West Virginia Certification #: 382
West Virginia DHHR #:9952C
Wisconsin Certification #: 999407970
Montana Certification #: Cert 0074
Nebraska Certification: NE-OS-28-14
Nevada Certification: FL NELAC Reciprocity
New Hampshire Certification #: 2958
New Jersey Certification #: FL765
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FLO1264
South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
Washington Certification #: C955
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
North Dakota Certification #: R-150
South Carolina Certification #: 83006001
Texas Certification #: T104704529-14-1
US Dept of Agriculture #: S-76505
Wisconsin Certification #: 405132750
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 2 of 67

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
�Q�ff�i�c&fie. Suite 100
y Huntersville, NC 28078
[phone]
Project: J15040239
Pace Project No.: 92245128
Asheville Certification IDs
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
CERTIFICATIONS
West Virginia Certification #: 356
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 3 of 67

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
�Q�ff�ic&fie. Suite 100
y Huntersville, NC 28078
[phone]
SAMPLE SUMMARY
Project: J15040239
Pace Project No.: 92245128
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92245128001
2015010247
Water
04/07/15 09:15
04/10/15 16:35
92245128002
2015010253
Water
04/08/1515:10
04/10/15 16:35
92245128003
2015010252
Solid
04/07/1516:25
04/10/15 16:35
92245128004
2015010254
Solid
04/08/1515:30
04/10/15 16:35
92245128005
2015010255
Solid
04/08/1516:45
04/10/15 16:35
92245128006
2015010256
Solid
04/08/1517:00
04/10/15 16:35
92245128007
2015010257
Solid
04/08/1517:15
04/10/15 16:35
92245128008
2015010252 SPLP
Water
04/07/15 16:25
04/10/15 16:35
92245128009
2015010254 SPLP
Water
04/08/15 15:30
04/10/15 16:35
92245128010
2015010255 SPLP
Water
04/08/15 16:45
04/10/15 16:35
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 4 of 67

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
�Q�ffli�c&fie. Suite 100
y Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
J15040239
92245128
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92245128001
2015010247
EPA 6020A
TT3
24
PASI-M
EPA 7470
LMW
1
PASI-M
92245128002
2015010253
EPA 6020A
TT3
24
PASI-M
EPA 7470
LMW
1
PASI-M
92245128003
2015010252
EPA 6010
TAP
16
PASI-0
EPA 6020
CRT
8
PASI-O
EPA 7471
CKJ
1
PASI-O
ASTM D2974-87
AEM
1
PASI-O
EPA 9045
MLS
1
PASI-A
EPA 300.0
AES2
1
PASI-A
EPA 353.2
DMN
1
PASI-A
SM 4500-CI-E
SER
1
PASI-A
EPA 9056
AIS
2
PASI-O
EPA 9056
AIS
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92245128004
2015010254
EPA 6010
TAP
16
PASI-0
EPA 6020
CRT
8
PASI-O
EPA 7471
CKJ
1
PASI-O
ASTM D2974-87
AEM
1
PASI-O
EPA 9045
MLS
1
PASI-A
EPA 300.0
AES2
1
PASI-A
EPA 353.2
DMN
1
PASI-A
SM 4500-CI-E
SER
1
PASI-A
EPA 9056
AIS
2
PASI-O
EPA 9056
AIS
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92245128005
2015010255
EPA 6010
TAP
16
PASI-0
EPA 6020
CRT
8
PASI-O
EPA 7471
CKJ
1
PASI-O
ASTM D2974-87
AEM
1
PASI-O
EPA 9045
MLS
1
PASI-A
EPA 300.0
AES2
1
PASI-A
EPA 353.2
DMN
1
PASI-A
SM 4500-CI-E
SER
1
PASI-A
EPA 9056
AIS
2
PASI-O
EPA 9056
AIS
1
PASI-O
EPA 9060
TJJ
6
PASI-G
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 5 of 67

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
�Q�ffli�c&fie. Suite 100
y Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
J15040239
92245128
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92245128006
2015010256
EPA 6010
TAP
16
PASI-0
EPA 6020
CRT
8
PASI-O
EPA 7471
CKJ
1
PASI-O
ASTM D2974-87
AEM
1
PASI-O
EPA 9045
MLS
1
PASI-A
EPA 9056
AIS
2
PASI-O
EPA 9056
AIS
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92245128007
2015010257
EPA 6010
CKJ
16
PASI-0
EPA 6020
CRT
8
PASI-O
EPA 7471
CKJ
1
PASI-O
ASTM D2974-87
AEM
1
PASI-O
EPA 9045
MLS
1
PASI-A
EPA 9056
AIS
2
PASI-O
EPA 9056
AIS
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92245128008
2015010252 SPLP
EPA 6020A
TT3
24
PASI-M
EPA 7470A
DM
1
PASI-M
92245128009
2015010254 SPLP
EPA 6020A
TT3
24
PASI-M
EPA 7470A
DM
1
PASI-M
92245128010
2015010255 SPLP
EPA 6020A
TT3
24
PASI-M
EPA 7470A
DM
1
PASI-M
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 6 of 67

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
�Q�fflic&fie. Suite 100
y Huntersville, NC 28078
[phone]
Project: J15040239
Pace Project No.: 92245128
Lab Sample ID Client Sample ID
Method Parameters
SUMMARY OF DETECTION
Result Units Report Limit Analyzed Qualifiers
92245128001
2015010247
EPA 6020A
Aluminum
1360
ug/L
10.0
04/15/15 16:12
EPA 6020A
Barium
12.0
ug/L
0.30
04/15/15 16:12
EPA 6020A
Calcium
378
ug/L
40.0
04/15/15 16:12
EPA 6020A
Chromium
3.8
ug/L
0.50
04/15/15 16:12
EPA 6020A
Cobalt
6.0
ug/L
0.50
04/15/15 16:12
EPA 6020A
Copper
1.7
ug/L
1.0
04/15/15 16:12
EPA 6020A
Iron
2540
ug/L
50.0
04/15/15 16:12
EPA 6020A
Lead
0.75
ug/L
0.10
04/15/15 16:12
EPA 6020A
Magnesium
265
ug/L
10.0
04/16/15 10:41
EPA 6020A
Manganese
73.0
ug/L
0.50
04/15/15 16:12
EPA 6020A
Molybdenum
1.0
ug/L
0.50
04/15/15 16:12
EPA 6020A
Nickel
1.1
ug/L
0.50
04/15/15 16:12
EPA 6020A
Potassium
134
ug/L
50.0
04/15/15 16:12
EPA 6020A
Sodium
251
ug/L
50.0
04/15/15 16:12
EPA 6020A
Strontium
3.8
ug/L
0.50
04/15/15 16:12
EPA 6020A
Vanadium
3.4
ug/L
1.0
04/15/15 16:12
92245128002
2015010253
EPA 6020A
Aluminum
192
ug/L
10.0
04/15/15 16:18
EPA 6020A
Barium
1.6
ug/L
0.30
04/15/15 16:18
EPA 6020A
Calcium
145
ug/L
40.0
04/15/15 16:18
EPA 6020A
Chromium
0.66
ug/L
0.50
04/15/15 16:18
EPA 6020A
Cobalt
5.2
ug/L
0.50
04/15/15 16:18
EPA 6020A
Iron
269
ug/L
50.0
04/15/15 16:18
EPA 6020A
Lead
0.16
ug/L
0.10
04/16/15 10:44
EPA 6020A
Magnesium
63.3
ug/L
10.0
04/16/15 10:44
EPA 6020A
Manganese
14.0
ug/L
0.50
04/15/15 16:18
EPA 6020A
Potassium
86.7
ug/L
50.0
04/15/15 16:18
EPA 6020A
Sodium
111
ug/L
50.0
04/15/15 16:18
EPA 6020A
Strontium
1.0
ug/L
0.50
04/15/15 16:18
92245128003
2015010252
EPA 6010
Aluminum
6560
mg/kg
5.7
04/20/15 14:47
EPA 6010
Barium
30.6
mg/kg
0.57
04/20/15 14:47
EPA 6010
Beryllium
0.34
mg/kg
0.057
04/20/15 14:47
EPA 6010
Boron
7.6
mg/kg
2.8
04/20/15 14:47
EPA 6010
Calcium
1660
mg/kg
28.3
04/20/15 14:47
EPA 6010
Chromium
11.6
mg/kg
0.28
04/20/15 14:47
EPA 6010
Copper
14.4
mg/kg
0.28
04/20/15 14:47
EPA 6010
Iron
13100
mg/kg
2.3
04/20/15 14:47
EPA 6010
Magnesium
3140
mg/kg
28.3
04/20/15 14:47
EPA 6010
Manganese
220
mg/kg
0.28
04/20/15 14:47
EPA 6010
Nickel
17.3
mg/kg
0.28
04/20/15 14:47
EPA 6010
Potassium
214
mg/kg
56.7
04/20/15 14:47
EPA 6010
Strontium
13.8
mg/kg
0.57
04/20/15 14:47
EPA 6010
Zinc
55.9
mg/kg
1.1
04/20/15 14:47
EPA 6020
Cobalt
16.8
mg/kg
5.7
04/22/15 02:21
EPA 6020
Lead
6.7
mg/kg
5.7
04/22/15 02:21
REPORT OF LABORATORY ANALYSIS
D3
D3
D3
D3
D3
D3
D3
D3
D3
D3
D3
D3
D3
D3
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 7 of 67

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
�Q�ffligc&fie. Suite 100
y Huntersville, NC 28078
[phone]
Project: J15040239
Pace Project No.: 92245128
Lab Sample ID Client Sample ID
Method Parameters
SUMMARY OF DETECTION
Result Units Report Limit Analyzed
92245128003
2015010252
EPA 6020
Vanadium
13.8
mg/kg
5.7
04/22/15 02:21
ASTM D2974-87
Percent Moisture
8.9
%
0.10
04/16/15 16:13
EPA 9045
pH at 25 Degrees C
6.7
Std. Units
0.10
04/16/15 16:00
EPA 300.0
Sulfate
3.5
mg/L
2.2
04/19/15 17:00
EPA 9060
Total Organic Carbon
461J
mg/kg
657
04/28/15 12:59
EPA 9060
Total Organic Carbon
502J
mg/kg
663
04/28/15 13:05
EPA 9060
Total Organic Carbon
5051
mg/kg
655
04/28/15 13:10
EPA 9060
Total Organic Carbon
526J
mg/kg
664
04/28/15 13:17
EPA 9060
Mean Total Organic Carbon
499J
mg/kg
660
04/28/15 12:59
EPA 9060
RSD%
5.5
%
04/28/15 12:59
92245128004
2015010254
EPA 6010
Aluminum
3300
mg/kg
5.8
04/20/15 14:51
EPA 6010
Barium
33.5
mg/kg
0.58
04/20/15 14:51
EPA 6010
Beryllium
0.21
mg/kg
0.058
04/20/15 14:51
EPA 6010
Boron
6.4
mg/kg
2.9
04/20/15 14:51
EPA 6010
Calcium
291
mg/kg
29.0
04/20/15 14:51
EPA 6010
Chromium
20.6
mg/kg
0.29
04/20/15 14:51
EPA 6010
Copper
7.1
mg/kg
0.29
04/20/15 14:51
EPA 6010
Iron
10600
mg/kg
2.3
04/20/15 14:51
EPA 6010
Magnesium
650
mg/kg
29.0
04/20/15 14:51
EPA 6010
Manganese
363
mg/kg
0.29
04/20/15 14:51
EPA 6010
Nickel
2.7
mg/kg
0.29
04/20/15 14:51
EPA 6010
Potassium
114
mg/kg
58.1
04/20/15 14:51
EPA 6010
Strontium
3.9
mg/kg
0.58
04/20/15 14:51
EPA 6010
Zinc
27.2
mg/kg
1.2
04/20/15 14:51
EPA 6020
Cobalt
9.3
mg/kg
5.8
04/22/15 02:23
EPA 6020
Lead
6.9
mg/kg
5.8
04/22/15 02:23
EPA 6020
Vanadium
31.6
mg/kg
5.8
04/22/15 02:23
EPA 7471
Mercury
0.029
mg/kg
0.0090
04/20/15 21:08
ASTM D2974-87
Percent Moisture
10
%
0.10
04/16/15 16:14
EPA 9045
pH at 25 Degrees C
5.0
Std. Units
0.10
04/16/15 16:00
EPA 300.0
Sulfate
4.0
mg/L
2.2
04/19/15 17:39
EPA 353.2
Nitrogen, Nitrate
0.26
mg/L
0.22
04/22/15 17:44
EPA 9060
Total Organic Carbon
3950
mg/kg
670
04/28/15 13:23
EPA 9060
Total Organic Carbon
3570
mg/kg
668
04/28/15 13:29
EPA 9060
Total Organic Carbon
3830
mg/kg
668
04/28/15 13:35
EPA 9060
Total Organic Carbon
3780
mg/kg
662
04/28/15 13:40
EPA 9060
Mean Total Organic Carbon
3780
mg/kg
667
04/28/15 13:23
EPA 9060
RSD%
4.1
%
04/28/15 13:23
92245128005
2015010255
EPA 6010
Aluminum
4500
mg/kg
6.3
04/20/15 14:56
EPA 6010
Barium
47.1
mg/kg
0.63
04/20/15 14:56
EPA 6010
Beryllium
0.22
mg/kg
0.063
04/20/15 14:56
EPA 6010
Boron
6.7
mg/kg
3.1
04/20/15 14:56
EPA 6010
Calcium
448
mg/kg
31.4
04/20/15 14:56
EPA 6010
Chromium
9.9
mg/kg
0.31
04/20/15 14:56
REPORT OF LABORATORY ANALYSIS
B
B
H1
Qualifiers
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 8 of 67

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
�Q�ffli�c&fie. Suite 100
y Huntersville, NC 28078
[phone]
Project: J15040239
Pace Project No.: 92245128
Lab Sample ID Client Sample ID
Method Parameters
SUMMARY OF DETECTION
Result Units Report Limit Analyzed
92245128005
2015010255
EPA 6010
Copper
8.2
mg/kg
0.31
04/20/15 14:56
EPA 6010
Iron
10600
mg/kg
2.5
04/20/15 14:56
EPA 6010
Magnesium
1060
mg/kg
31.4
04/20/15 14:56
EPA 6010
Manganese
495
mg/kg
0.31
04/20/15 14:56
EPA 6010
Nickel
3.1
mg/kg
0.31
04/20/15 14:56
EPA 6010
Potassium
171
mg/kg
62.8
04/20/15 14:56
EPA 6010
Strontium
5.6
mg/kg
0.63
04/20/15 14:56
EPA 6010
Zinc
11.2
mg/kg
1.3
04/20/15 14:56
EPA 6020
Cobalt
9.3
mg/kg
6.3
04/22/15 02:25
EPA 6020
Lead
74.3
mg/kg
6.3
04/22/15 02:25
EPA 6020
Vanadium
35.2
mg/kg
6.3
04/22/15 02:25
EPA 7471
Mercury
0.0092J
mg/kg
0.010
04/20/15 21:11
ASTM D2974-87
Percent Moisture
18.1
%
0.10
04/16/15 16:14
EPA 9045
pH at 25 Degrees C
5.9
Std. Units
0.10
04/16/15 16:00
EPA 300.0
Sulfate
5.2
mg/L
2.4
04/19/15 17:53 B
EPA 9060
Total Organic Carbon
2420
mg/kg
738
04/28/15 14:34
EPA 9060
Total Organic Carbon
2050
mg/kg
735
04/28/15 14:40
EPA 9060
Total Organic Carbon
2090
mg/kg
737
04/28/15 14:46
EPA 9060
Total Organic Carbon
2140
mg/kg
728
04/28/15 14:51
EPA 9060
Mean Total Organic Carbon
2170
mg/kg
734
04/28/15 14:34
EPA 9060
RSD%
7.6
%
04/28/15 14:34
92245128006
2015010256
EPA 6010
Aluminum
5670
mg/kg
6.8
04/20/15 15:00
EPA 6010
Barium
82.7
mg/kg
0.68
04/20/15 15:00
EPA 6010
Beryllium
0.33
mg/kg
0.068
04/20/15 15:00
EPA 6010
Boron
7.4
mg/kg
3.4
04/20/15 15:00
EPA 6010
Calcium
639
mg/kg
33.9
04/20/15 15:00
EPA 6010
Chromium
10.5
mg/kg
0.34
04/20/15 15:00
EPA 6010
Copper
7.9
mg/kg
0.34
04/20/15 15:00
EPA 6010
Iron
9870
mg/kg
2.7
04/20/15 15:00
EPA 6010
Magnesium
1100
mg/kg
33.9
04/20/15 15:00
EPA 6010
Manganese
358
mg/kg
0.34
04/20/15 15:00
EPA 6010
Nickel
3.9
mg/kg
0.34
04/20/15 15:00
EPA 6010
Potassium
111
mg/kg
67.8
04/20/15 15:00
EPA 6010
Strontium
9.1
mg/kg
0.68
04/20/15 15:00
EPA 6010
Zinc
14.1
mg/kg
1.4
04/20/15 15:00
EPA 6020
Cobalt
8.3
mg/kg
6.8
04/22/15 02:35
EPA 6020
Lead
5.2J
mg/kg
6.8
04/22/15 02:35
EPA 6020
Vanadium
35.2
mg/kg
6.8
04/22/15 02:35
EPA 7471
Mercury
0.016
mg/kg
0.011
04/20/15 21:17
ASTM D2974-87
Percent Moisture
22.3
%
0.10
04/16/15 16:15
EPA 9045
pH at 25 Degrees C
5.6
Std. Units
0.10
04/16/15 16:00
EPA 9060
Total Organic Carbon
3270
mg/kg
778
04/28/15 14:57
EPA 9060
Total Organic Carbon
2990
mg/kg
768
04/28/15 15:03
EPA 9060
Total Organic Carbon
3190
mg/kg
770
04/28/15 15:08
EPA 9060
Total Organic Carbon
2840
mg/kg
779
04/28/15 15:15
EPA 9060
Mean Total Organic Carbon
3070
mg/kg
774
04/28/15 14:57
REPORT OF LABORATORY ANALYSIS
Qualifiers
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 9 of 67

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098g i vfte. Suite 100
Huntersville, NC 28078
[phone]
Project: J15040239
Pace Project No.: 92245128
Lab Sample ID Client Sample ID
Method Parameters
SUMMARY OF DETECTION
Result Units Report Limit Analyzed Qualifiers
92245128006
2015010256
EPA 9060
RSD%
6.4
%
04/28/15 14:57
92245128007
2015010257
EPA 6010
Aluminum
27200
mg/kg
51.1
04/25/15 15:08
EPA 6010
Barium
209
mg/kg
5.1
04/25/15 15:08
EPA 6010
Beryllium
1.4
mg/kg
0.51
04/25/15 15:08
EPA 6010
Calcium
301
mg/kg
256
04/25/15 15:08
EPA 6010
Chromium
14.4
mg/kg
2.6
04/25/15 15:08
EPA 6010
Copper
24.0
mg/kg
2.6
04/25/15 15:08
EPA 6010
Iron
22900
mg/kg
20.5
04/25/15 15:08
EPA 6010
Magnesium
3570
mg/kg
256
04/25/15 15:08
EPA 6010
Manganese
457
mg/kg
2.6
04/25/15 15:08
EPA 6010
Molybdenum
3.3J
mg/kg
5.1
04/25/15 15:08
EPA 6010
Nickel
5.9
mg/kg
2.6
04/25/15 15:08
EPA 6010
Potassium
3920
mg/kg
511
04/25/15 15:08
EPA 6010
Strontium
14.3
mg/kg
5.1
04/25/15 15:08
EPA 6010
Zinc
78.0
mg/kg
10.2
04/25/15 15:08
EPA 6020
Cobalt
27.9
mg/kg
5.1
04/22/15 02:37
EPA 6020
Lead
8.3
mg/kg
5.1
04/22/15 02:37
EPA 6020
Selenium
3.3J
mg/kg
5.1
04/22/15 02:37
EPA 6020
Vanadium
30.1
mg/kg
5.1
04/22/15 02:37
ASTM D2974-87
Percent Moisture
4.0
%
0.10
04/16/15 16:15
EPA 9045
pH at 25 Degrees C
7.9
Std. Units
0.10
04/16/15 16:00
EPA 9060
RSD%
1.6
%
04/28/15 15:21
92245128008
2015010252 SPLP
EPA 6020A
Aluminum
1160
ug/L
10.0
04/27/15 10:52
EPA 6020A
Arsenic
0.87
ug/L
0.50
04/27/15 10:52
EPA 6020A
Barium
130
ug/L
0.30
04/27/15 10:52
EPA 6020A
Beryllium
0.15J
ug/L
0.20
04/27/15 10:52
EPA 6020A
Boron
32.9
ug/L
5.0
04/27/15 10:52
EPA 6020A
Calcium
1120
ug/L
40.0
04/27/15 10:52
EPA 6020A
Chromium
1.3
ug/L
0.50
04/27/15 10:52
EPA 6020A
Cobalt
1.9
ug/L
0.50
04/27/15 10:52
EPA 6020A
Copper
7.6
ug/L
1.0
04/27/15 10:52
EPA 6020A
Iron
802
ug/L
50.0
04/27/15 10:52
EPA 6020A
Lead
2.1
ug/L
0.10
04/27/15 10:52
EPA 6020A
Magnesium
503
ug/L
10.0
04/27/15 10:52
EPA 6020A
Manganese
41.8
ug/L
0.50
04/27/15 10:52
EPA 6020A
Molybdenum
0.18J
ug/L
0.50
04/27/15 10:52
EPA 6020A
Nickel
1.4
ug/L
0.50
04/27/15 10:52
EPA 6020A
Potassium
267
ug/L
50.0
04/27/15 10:52
EPA 6020A
Sodium
1770
ug/L
50.0
04/27/15 10:52
EPA 6020A
Strontium
12.6
ug/L
0.50
04/27/15 10:52
EPA 6020A
Vanadium
2.8
ug/L
1.0
04/27/15 10:52
EPA 6020A
Zinc
35.8
ug/L
5.0
04/27/15 10:52
92245128009
2015010254 SPLP
EPA 6020A
Aluminum
7460
ug/L
50.0
04/27/15 10:55
REPORT OF LABORATORY ANALYSIS
D3
D3
D3
D3
D3
D3
D3
D3
D3
D3
D3
D3
D3
D3
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 10 of 67

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098gKinvfte. Suite 100
Huntersville, NC 28078
[phone]
Project: J15040239
Pace Project No.: 92245128
Lab Sample ID Client Sample ID
Method Parameters
SUMMARY OF DETECTION
Result Units Report Limit Analyzed Qualifiers
92245128009
2015010254 SPLP
EPA 6020A
Arsenic
1.1J
ug/L
2.5
04/27/15 10:55
EPA 6020A
Barium
206
ug/L
1.5
04/27/15 10:55
EPA 6020A
Beryllium
0.40J
ug/L
1.0
04/27/15 10:55
EPA 6020A
Boron
74.0
ug/L
25.0
04/27/15 10:55
EPA 6020A
Calcium
1100
ug/L
200
04/27/15 10:55
EPA 6020A
Chromium
10.7
ug/L
2.5
04/27/15 10:55
EPA 6020A
Cobalt
4.7
ug/L
2.5
04/27/15 10:55
EPA 6020A
Copper
11.0
ug/L
5.0
04/27/15 10:55
EPA 6020A
Iron
8770
ug/L
250
04/27/15 10:55
EPA 6020A
Lead
6.7
ug/L
0.50
04/27/15 10:55
EPA 6020A
Magnesium
651
ug/L
50.0
04/27/15 10:55
EPA 6020A
Manganese
350
ug/L
2.5
04/27/15 10:55
EPA 6020A
Nickel
3.8
ug/L
2.5
04/27/15 10:55
EPA 6020A
Potassium
264
ug/L
250
04/27/15 10:55
EPA 6020A
Sodium
1570
ug/L
250
04/27/15 10:55
EPA 6020A
Strontium
15.8
ug/L
2.5
04/27/15 10:55
EPA 6020A
Vanadium
27.5
ug/L
5.0
04/27/15 10:55
EPA 6020A
Zinc
130
ug/L
25.0
04/27/15 10:55
92245128010
2015010255 SPLP
EPA 6020A
Aluminum
1720
ug/L
10.0
04/27/15 11:06
EPA 6020A
Arsenic
0.16J
ug/L
0.50
04/27/15 11:06
EPA 6020A
Barium
148
ug/L
0.30
04/27/15 11:06
EPA 6020A
Beryllium
0.075J
ug/L
0.20
04/27/15 11:06
EPA 6020A
Boron
57.9
ug/L
5.0
04/27/15 11:06
EPA 6020A
Calcium
902
ug/L
40.0
04/27/15 11:06
EPA 6020A
Chromium
1.9
ug/L
0.50
04/27/15 11:06
EPA 6020A
Cobalt
0.86
ug/L
0.50
04/27/15 11:06
EPA 6020A
Copper
3.2
ug/L
1.0
04/27/15 11:06
EPA 6020A
Iron
1520
ug/L
50.0
04/27/15 11:06
EPA 6020A
Lead
0.88
ug/L
0.10
04/27/15 11:06
EPA 6020A
Magnesium
370
ug/L
10.0
04/27/15 11:06
EPA 6020A
Manganese
64.9
ug/L
0.50
04/27/15 11:06
EPA 6020A
Nickel
1.6
ug/L
0.50
04/27/15 11:06
EPA 6020A
Potassium
91.7
ug/L
50.0
04/27/15 11:06
EPA 6020A
Sodium
1390
ug/L
50.0
04/27/15 11:06
EPA 6020A
Strontium
12.8
ug/L
0.50
04/27/15 11:06
EPA 6020A
Vanadium
5.0
ug/L
1.0
04/27/15 11:06
EPA 6020A
Zinc
46.1
ug/L
5.0
04/27/15 11:06
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 11 of 67

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098gKinyfte. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15040239
Pace Project No.: 92245128
Method: EPA 6010
Description: 6010 MET ICP
Client: Duke Energy
Date: April 29, 2015
General Information:
5 samples were analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 3050 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: MPRP/23696
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92245094011
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1188077)
• Aluminum
• Barium
• Chromium
• Iron
• Magnesium
• Manganese
• Nickel
• Potassium
• Strontium
• Zinc
• MSD (Lab ID: 1188078)
• Aluminum
• Barium
• Chromium
• Copper
• Iron
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 12 of 67

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098gKinyfte. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15040239
Pace Project No.: 92245128
Method: EPA 6010
Description: 6010 MET ICP
Client: Duke Energy
Date: April 29, 2015
QC Batch: MPRP/23696
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92245094011
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• Magnesium
• Manganese
• Nickel
• Potassium
• Strontium
• Zinc
Additional Comments:
Analyte Comments:
QC Batch: MPRP/23696
D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
•2015010252 (Lab ID:92245128003)
• Aluminum
• Boron
• Barium
• Beryllium
• Calcium
• Chromium
• Copper
• Iron
• Potassium
• Magnesium
• Manganese
• Molybdenum
• Sodium
• Nickel
• Strontium
• Zinc
•2015010257 (Lab ID:92245128007)
• Aluminum
• Boron
• Barium
• Beryllium
• Calcium
• Chromium
• Copper
• Iron
• Potassium
• Magnesium
• Manganese
• Molybdenum
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc.. Page 13 of 67

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PROJECT NARRATIVE
Project: J15040239
Pace Project No.: 92245128
Method: EPA 6010
Description: 6010 MET ICP
Client: Duke Energy
Date: April 29, 2015
Analyte Comments:
QC Batch: MPRP/23696
D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
•2015010257 (Lab ID:92245128007)
• Sodium
• Nickel
• Strontium
• Zinc
• MS (Lab ID: 1188077)
• Aluminum
• Boron
• Barium
• Beryllium
• Calcium
• Chromium
• Copper
• Iron
• Potassium
• Magnesium
• Manganese
• Molybdenum
• Sodium
• Nickel
• Strontium
• Zinc
• MSD (Lab ID: 1188078)
• Aluminum
• Boron
• Barium
• Beryllium
• Calcium
• Chromium
• Copper
• Iron
• Potassium
• Magnesium
• Manganese
• Molybdenum
• Sodium
• Nickel
• Strontium
• Zinc
P8: Analyte was detected in the method blank. All associated samples had concentrations of at least ten times greater than the blank
or were below the reporting limit.
• BLANK (Lab ID: 1188075)
• Iron
REPORT OF LABORATORY ANALYSIS
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PROJECT NARRATIVE
Project: J15040239
Pace Project No.: 92245128
Method: EPA 6020
Description: 6020 MET ICPMS
Client: Duke Energy
Date: April 29, 2015
General Information:
5 samples were analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 3050 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: MPRP/23697
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92245094012
M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
• MS (Lab ID: 1188081)
• Antimony
• Cobalt
• Lead
• MSD (Lab ID: 1188082)
• Antimony
• Cobalt
• Lead
• Vanadium
R1: RPD value was outside control limits.
• MSD (Lab ID: 1188082)
• Cobalt
• Vanadium
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 15 of 67

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Pace Analytical Services, Inc.
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[phone]
PROJECT NARRATIVE
Project: J15040239
Pace Project No.: 92245128
Method: EPA 6020
Description: 6020 MET ICPMS
Client: Duke Energy
Date: April 29, 2015
Additional Comments:
Batch Comments:
Batch was diluted due to the presence of high levels of non -target analytes or other matrix interference.
• QC Batch: ICPM / 9631
Analyte Comments:
QC Batch: MPRP/23697
N2: The lab does not hold TNI accreditation for this parameter.
•2015010252 (Lab ID:92245128003)
• Antimony
•2015010254 (Lab ID:92245128004)
• Antimony
•2015010255 (Lab ID:92245128005)
• Antimony
•2015010256 (Lab ID:92245128006)
• Antimony
•2015010257 (Lab ID:92245128007)
• Antimony
• BLANK (Lab ID: 1188079)
• Antimony
• LCS (Lab ID: 1188080)
• Antimony
• MS (Lab ID: 1188081)
• Antimony
• MSD (Lab ID: 1188082)
• Antimony
REPORT OF LABORATORY ANALYSIS
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[phone]
PROJECT NARRATIVE
Project: J15040239
Pace Project No.: 92245128
Method: EPA 6020A
Description: 6020A MET ICPMS
Client: Duke Energy
Date: April 29, 2015
General Information:
5 samples were analyzed for EPA 6020A. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 3020 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: MPRP/53618
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 10302295001
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1938833)
• Calcium
• Magnesium
• MSD (Lab ID: 1938834)
• Magnesium
QC Batch: MPRP/53885
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92245143004
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1948832)
• Aluminum
• Calcium
• Iron
• Magnesium
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc.. Page 17 of 67

aceAnaiXical
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Pace Analytical Services, Inc.
098g i vfte. Suite 100
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[phone]
PROJECT NARRATIVE
Project: J15040239
Pace Project No.: 92245128
Method: EPA 6020A
Description: 6020A MET ICPMS
Client: Duke Energy
Date: April 29, 2015
QC Batch: MPRP/53885
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92245143004
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MSD (Lab ID: 1948833)
• Aluminum
• Calcium
• Copper
• Iron
• Magnesium
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 18 of 67

aceAnaiXical
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Pace Analytical Services, Inc.
098g i�vfte. Suite 100
�J Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15040239
Pace Project No.: 92245128
Method: EPA 7470
Description: 7470 Mercury
Client: Duke Energy
Date: April 29, 2015
General Information:
2 samples were analyzed for EPA 7470. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 7470 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 19 of 67

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Pace Analytical Services, Inc.
098ninyfte. Suite 100
y Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15040239
Pace Project No.: 92245128
Method: EPA 7470A
Description: 7470A Mercury
Client: Duke Energy
Date: April 29, 2015
General Information:
3 samples were analyzed for EPA 7470A. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 7470A with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc.. Page 20 of 67

aceAnaiXical
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Pace Analytical Services, Inc.
098ninivfte. Suite 100
y Huntersville, NC 28078
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PROJECT NARRATIVE
Project: J15040239
Pace Project No.: 92245128
Method: EPA 7471
Description: 7471 Mercury
Client: Duke Energy
Date: April 29, 2015
General Information:
5 samples were analyzed for EPA 7471. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 7471 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc.. Page 21 of 67

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Pace Analytical Services, Inc.
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PROJECT NARRATIVE
Project: J15040239
Pace Project No.: 92245128
Method: EPA 9045
Description: 9045 pH Soil
Client: Duke Energy
Date: April 29, 2015
General Information:
5 samples were analyzed for EPA 9045. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
QC Batch: WET/36863
D6: The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits.
• DUP (Lab ID: 1436064)
• pH at 25 Degrees C
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc.. Page 22 of 67

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Pace Analytical Services, Inc.
098ninyfte. Suite 100
y Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15040239
Pace Project No.: 92245128
Method: EPA 300.0
Description: 300.0 IC Anions, SPLP
Client: Duke Energy
Date: April 29, 2015
General Information:
3 samples were analyzed for EPA 300.0. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
QC Batch: WETA/22607
B: Analyte was detected in the associated method blank.
• BLANK for HBN 260035 [WETA/226 (Lab ID: 1437291)
• Sulfate
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc.. Page 23 of 67

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Pace Analytical Services, Inc.
09Q�K�i�vfte. Suite 100
y Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15040239
Pace Project No.: 92245128
Method: EPA 353.2
Description: 353.2 Nitrogen, NO2/NO3, SPLP
Client: Duke Energy
Date: April 29, 2015
General Information:
3 samples were analyzed for EPA 353.2. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
1-11: Analysis conducted outside the EPA method holding time.
•2015010252 (Lab ID:92245128003)
•2015010254 (Lab ID:92245128004)
•2015010255 (Lab ID:92245128005)
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 24 of 67

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Pace Analytical Services, Inc.
098ninyfte. Suite 100
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[phone]
PROJECT NARRATIVE
Project: J15040239
Pace Project No.: 92245128
Method: SM 4500-CI-E
Description: 4500 Chloride, SPLP
Client: Duke Energy
Date: April 29, 2015
General Information:
3 samples were analyzed for SM 4500-CI-E. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc.. Page 25 of 67

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Pace Analytical Services, Inc.
098ninyfte. Suite 100
y Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15040239
Pace Project No.: 92245128
Method: EPA 9056
Description: 9056 IC Anions
Client: Duke Energy
Date: April 29, 2015
General Information:
5 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
Analyte Comments:
QC Batch: WETA/45424
DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
•2015010252 (Lab ID:92245128003)
• Chloride
• Sulfate
•2015010254 (Lab ID:92245128004)
• Chloride
• Sulfate
•2015010255 (Lab ID:92245128005)
• Chloride
• Sulfate
•2015010256 (Lab ID:92245128006)
• Chloride
• Sulfate
•2015010257 (Lab ID:92245128007)
• Chloride
• Sulfate
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc.. Page 26 of 67

aceAnaiXical
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Pace Analytical Services, Inc.
098v�vfte. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15040239
Pace Project No.: 92245128
Method: EPA 9056
Description: 9056 IC Anions 48hr
Client: Duke Energy
Date: April 29, 2015
General Information:
5 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
1-13: Sample was received or analysis requested beyond the recognized method holding time.
•2015010252 (Lab ID:92245128003)
•2015010254 (Lab ID:92245128004)
•2015010255 (Lab ID:92245128005)
•2015010256 (Lab ID:92245128006)
•2015010257 (Lab ID:92245128007)
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc.. Page 27 of 67

aceAnaiXical
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Pace Analytical Services, Inc.
098ninyfte. Suite 100
y Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15040239
Pace Project No.: 92245128
Method: EPA 9060
Description: Total Organic Carbon Quad
Client: Duke Energy
Date: April 29, 2015
General Information:
5 samples were analyzed for EPA 9060. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc.. Page 28 of 67

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ANALYTICAL RESULTS
Project: J15040239
Pace Project No.: 92245128
Sample: 2015010247 Lab ID: 92245128001 Collected: 04/07/15 09:15 Received: 04/10/15 16:35 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
;I➢ZI7c\�i,I=11a 99�r6?
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Sodium
Strontium
Thallium
Vanadium
Zinc
7470 Mercury
Mercury
Date: 04/29/2015 02:22 PM
Analytical Method: EPA 6020A Preparation Method: EPA 3020
1360
ug/L
10.0
3.0
1
04/15/15 08:27
04/15/15 16:12
7429-90-5
ND
ug/L
0.50
0.15
1
04/15/15 08:27
04/15/15 16:12
7440-36-0
ND
ug/L
0.50
0.11
1
04/15/15 08:27
04/15/15 16:12
7440-38-2
12.0
ug/L
0.30
0.081
1
04/15/15 08:27
04/15/15 16:12
7440-39-3
ND
ug/L
0.20
0.067
1
04/15/15 08:27
04/16/15 10:41
7440-41-7
ND
ug/L
5.0
1.1
1
04/15/15 08:27
04/16/15 10:41
7440-42-8
ND
ug/L
0.080
0.024
1
04/15/15 08:27
04/15/15 16:12
7440-43-9
378
ug/L
40.0
16.0
1
04/15/15 08:27
04/15/15 16:12
7440-70-2
3.8
ug/L
0.50
0.17
1
04/15/15 08:27
04/15/15 16:12
7440-47-3
6.0
ug/L
0.50
0.13
1
04/15/15 08:27
04/15/15 16:12
7440-48-4
1.7
ug/L
1.0
0.21
1
04/15/15 08:27
04/15/15 16:12
7440-50-8
2540
ug/L
50.0
13.7
1
04/15/15 08:27
04/15/15 16:12
7439-89-6
0.75
ug/L
0.10
0.046
1
04/15/15 08:27
04/15/15 16:12
7439-92-1
265
ug/L
10.0
3.2
1
04/15/15 08:27
04/16/15 10:41
7439-95-4
73.0
ug/L
0.50
0.24
1
04/15/15 08:27
04/15/15 16:12
7439-96-5
1.0
ug/L
0.50
0.094
1
04/15/15 08:27
04/15/15 16:12
7439-98-7
1.1
ug/L
0.50
0.16
1
04/15/15 08:27
04/15/15 16:12
7440-02-0
134
ug/L
50.0
11.7
1
04/15/15 08:27
04/15/15 16:12
7440-09-7
ND
ug/L
0.50
0.20
1
04/15/15 08:27
04/15/15 16:12
7782-49-2
251
ug/L
50.0
16.3
1
04/15/15 08:27
04/15/15 16:12
7440-23-5
3.8
ug/L
0.50
0.13
1
04/15/15 08:27
04/15/15 16:12
7440-24-6
ND
ug/L
0.10
0.015
1
04/15/15 08:27
04/15/15 16:12
7440-28-0
3.4
ug/L
1.0
0.28
1
04/15/15 08:27
04/15/15 16:12
7440-62-2
ND
ug/L
5.0
2.4
1
04/15/15 08:27
04/15/15 16:12
7440-66-6
Analytical Method: EPA 7470 Preparation Method: EPA 7470
ND ug/L 0.20 0.022 1 04/15/1510:10 04/15/1518:14 7439-97-6
REPORT OF LABORATORY ANALYSIS
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Page 29 of 67

aceAnaiXical
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Pace Analytical Services, Inc.
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Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040239
Pace Project No.: 92245128
Sample: 2015010253 Lab ID: 92245128002 Collected: 04/08/15 15:10 Received: 04/10/15 16:35 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
;I➢ZI7c\�i,I=11 l[99�r 6?
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Sodium
Strontium
Thallium
Vanadium
Zinc
7470 Mercury
Mercury
Date: 04/29/2015 02:22 PM
Analytical Method: EPA 6020A Preparation Method: EPA 3020
192
ug/L
10.0
3.0
1
04/15/15 08:27
04/15/15 16:18
7429-90-5
ND
ug/L
0.50
0.15
1
04/15/15 08:27
04/15/15 16:18
7440-36-0
ND
ug/L
0.50
0.11
1
04/15/15 08:27
04/15/15 16:18
7440-38-2
1.6
ug/L
0.30
0.081
1
04/15/15 08:27
04/15/15 16:18
7440-39-3
ND
ug/L
0.20
0.067
1
04/15/15 08:27
04/16/15 10:44
7440-41-7
ND
ug/L
5.0
1.1
1
04/15/15 08:27
04/16/15 10:44
7440-42-8
ND
ug/L
0.080
0.024
1
04/15/15 08:27
04/15/15 16:18
7440-43-9
145
ug/L
40.0
16.0
1
04/15/15 08:27
04/15/15 16:18
7440-70-2
0.66
ug/L
0.50
0.17
1
04/15/15 08:27
04/15/15 16:18
7440-47-3
5.2
ug/L
0.50
0.13
1
04/15/15 08:27
04/15/15 16:18
7440-48-4
ND
ug/L
1.0
0.21
1
04/15/15 08:27
04/15/15 16:18
7440-50-8
269
ug/L
50.0
13.7
1
04/15/15 08:27
04/15/15 16:18
7439-89-6
0.16
ug/L
0.10
0.046
1
04/15/15 08:27
04/16/15 10:44
7439-92-1
63.3
ug/L
10.0
3.2
1
04/15/15 08:27
04/16/15 10:44
7439-95-4
14.0
ug/L
0.50
0.24
1
04/15/15 08:27
04/15/15 16:18
7439-96-5
ND
ug/L
0.50
0.094
1
04/15/15 08:27
04/15/15 16:18
7439-98-7
ND
ug/L
0.50
0.16
1
04/15/15 08:27
04/15/15 16:18
7440-02-0
86.7
ug/L
50.0
11.7
1
04/15/15 08:27
04/15/15 16:18
7440-09-7
ND
ug/L
0.50
0.20
1
04/15/15 08:27
04/15/15 16:18
7782-49-2
111
ug/L
50.0
16.3
1
04/15/15 08:27
04/15/15 16:18
7440-23-5
1.0
ug/L
0.50
0.13
1
04/15/15 08:27
04/15/15 16:18
7440-24-6
ND
ug/L
0.10
0.015
1
04/15/15 08:27
04/15/15 16:18
7440-28-0
ND
ug/L
1.0
0.28
1
04/15/15 08:27
04/15/15 16:18
7440-62-2
ND
ug/L
5.0
2.4
1
04/15/15 08:27
04/15/15 16:18
7440-66-6
Analytical Method: EPA 7470 Preparation Method: EPA 7470
ND ug/L 0.20 0.022 1 04/15/1510:10 04/15/1518:20 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 30 of 67

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098gWinic8f fie. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040239
Pace Project No.: 92245128
Sample: 2015010252 Lab ID: 92245128003 Collected: 04/07/15 16:25 Received: 04/10/15 16:35 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Aluminum
Barium
Beryllium
Boron
Calcium
Chromium
Copper
Iron
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Sodium
Strontium
Zinc
6020 MET ICPMS
Antimony
Arsenic
Cadmium
Cobalt
Lead
Selenium
Thallium
Vanadium
7471 Mercury
Mercury
Percent Moisture
Percent Moisture
9045 pH Soil
pH at 25 Degrees C
300.0 IC Anions, SPLP
Sulfate
353.2 Nitrogen, NO2/NO3, SPLP
Nitrogen, Nitrate
4500 Chloride, SPLP
Chloride
Date: 04/29/2015 02:22 PM
Analytical Method: EPA 6010 Preparation Method: EPA 3050
6560
mg/kg
5.7
2.8
1
04/19/15 05:38
04/20/15 14:47
7429-90-5
30.6
mg/kg
0.57
0.28
1
04/19/15 05:38
04/20/15 14:47
7440-39-3
0.34
mg/kg
0.057
0.028
1
04/19/15 05:38
04/20/15 14:47
7440-41-7
7.6
mg/kg
2.8
1.4
1
04/19/15 05:38
04/20/15 14:47
7440-42-8
1660
mg/kg
28.3
14.2
1
04/19/15 05:38
04/20/15 14:47
7440-70-2
11.6
mg/kg
0.28
0.14
1
04/19/15 05:38
04/20/15 14:47
7440-47-3
14.4
mg/kg
0.28
0.14
1
04/19/15 05:38
04/20/15 14:47
7440-50-8
13100
mg/kg
2.3
1.1
1
04/19/15 05:38
04/20/15 14:47
7439-89-6
3140
mg/kg
28.3
14.2
1
04/19/15 05:38
04/20/15 14:47
7439-95-4
220
mg/kg
0.28
0.14
1
04/19/15 05:38
04/20/15 14:47
7439-96-5
ND
mg/kg
0.57
0.28
1
04/19/15 05:38
04/20/15 14:47
7439-98-7
17.3
mg/kg
0.28
0.14
1
04/19/15 05:38
04/20/15 14:47
7440-02-0
214
mg/kg
56.7
28.3
1
04/19/15 05:38
04/20/15 14:47
7440-09-7
ND
mg/kg
56.7
28.3
1
04/19/15 05:38
04/20/15 14:47
7440-23-5
13.8
mg/kg
0.57
0.28
1
04/19/15 05:38
04/20/15 14:47
7440-24-6
55.9
mg/kg
1.1
0.57
1
04/19/15 05:38
04/20/15 14:47
7440-66-6
Analytical
Method: EPA
6020 Preparation Method: EPA 3050
ND
mg/kg
5.7
2.8
100
04/19/15 05:38
04/22/15 02:21
7440-36-0
ND
mg/kg
5.7
2.8
100
04/19/15 05:38
04/22/15 02:21
7440-38-2
ND
mg/kg
0.68
0.34
100
04/19/15 05:38
04/22/15 02:21
7440-43-9
16.8
mg/kg
5.7
2.8
100
04/19/15 05:38
04/22/15 02:21
7440-48-4
6.7
mg/kg
5.7
2.8
100
04/19/15 05:38
04/22/15 02:21
7439-92-1
ND
mg/kg
5.7
2.8
100
04/19/15 05:38
04/22/15 02:21
7782-49-2
ND
mg/kg
5.7
2.8
100
04/19/15 05:38
04/22/15 02:21
7440-28-0
13.8
mg/kg
5.7
2.8
100
04/19/15 05:38
04/22/15 02:21
7440-62-2
Analytical Method: EPA 7471 Preparation Method: EPA 7471
ND mg/kg 0.0087 0.0044 1 04/19/15 05:30 04/20/15 21:06 7439-97-6
Analytical Method: ASTM D2974-87
8.9 % 0.10 0.10 1 04/16/1516:13
Analytical Method: EPA 9045
6.7 Std. Units 0.10 0.10 1 04/16/15 16:00
D3
D3
D3
D3
D3
D3
D3
D3
D3
D3
D3
D3
D3
D3
D3
D3
N2
Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 04/15/15 00:55
3.5 mg/L 2.2 1.1 1 04/19/1517:00 14808-79-8 B
Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 04/15/15 00:55
ND mg/L 0.22 0.22 1 04/22/1517:43 H1
Analytical Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 04/15/15 00:55
ND mg/L 5.5 2.7 1 04/17/15 05:42 16887-00-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 31 of 67

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098oinffte. Suite 100
y Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040239
Pace Project No.: 92245128
Sample: 2015010252 Lab ID: 92245128003 Collected: 04/07/15 16:25 Received: 04/10/15 16:35 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
9056 IC Anions Analytical Method: EPA 9056
Chloride
ND mg/kg
269
135
5
04/15/1518:04
16887-00-6 D3
Sulfate
ND mg/kg
269
135
5
04/15/1518:04
14808-79-8 D3
9056 IC Anions 48hr
Analytical Method: EPA 9056
Nitrate as N
ND mg/kg
26.9
13.5
5
04/15/15 18:04
14797-55-8 H3
Total Organic Carbon Quad
Analytical Method: EPA 9060
Total Organic Carbon
461J mg/kg
657
328
1
04/28/15 12:59
7440-44-0
Total Organic Carbon
502J mg/kg
663
332
1
04/28/15 13:05
7440-44-0
Total Organic Carbon
505J mg/kg
655
328
1
04/28/15 13:10
7440-44-0
Total Organic Carbon
526J mg/kg
664
332
1
04/28/15 13:17
7440-44-0
Mean Total Organic Carbon
499J mg/kg
660
330
1
04/28/15 12:59
7440-44-0
Surrogates
RSD%
5.5 %
1
04/28/15 12:59
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/29/2015 02:22 PM without the written consent of Pace Analytical Services, Inc..
Page 32 of 67

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098�t�i .8fftie. Suite 100
y Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040239
Pace Project No.: 92245128
Sample: 2015010254 Lab ID: 92245128004 Collected: 04/08/15 15:30 Received: 04/10/15 16:35 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Aluminum
Barium
Beryllium
Boron
Calcium
Chromium
Copper
Iron
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Sodium
Strontium
Zinc
6020 MET ICPMS
Antimony
Arsenic
Cadmium
Cobalt
Lead
Selenium
Thallium
Vanadium
7471 Mercury
Mercury
Percent Moisture
Percent Moisture
9045 pH Soil
pH at 25 Degrees C
300.0 IC Anions, SPLP
Sulfate
353.2 Nitrogen, NO2/NO3, SPLP
Nitrogen, Nitrate
4500 Chloride, SPLP
Chloride
Date: 04/29/2015 02:22 PM
Analytical Method: EPA 6010 Preparation Method: EPA 3050
3300
mg/kg
5.8
2.9
1
04/19/15 05:38
04/20/15 14:51
7429-90-5
33.5
mg/kg
0.58
0.29
1
04/19/15 05:38
04/20/15 14:51
7440-39-3
0.21
mg/kg
0.058
0.029
1
04/19/15 05:38
04/20/15 14:51
7440-41-7
6.4
mg/kg
2.9
1.5
1
04/19/15 05:38
04/20/15 14:51
7440-42-8
291
mg/kg
29.0
14.5
1
04/19/15 05:38
04/20/15 14:51
7440-70-2
20.6
mg/kg
0.29
0.15
1
04/19/15 05:38
04/20/15 14:51
7440-47-3
7.1
mg/kg
0.29
0.15
1
04/19/15 05:38
04/20/15 14:51
7440-50-8
10600
mg/kg
2.3
1.2
1
04/19/15 05:38
04/20/15 14:51
7439-89-6
650
mg/kg
29.0
14.5
1
04/19/15 05:38
04/20/15 14:51
7439-95-4
363
mg/kg
0.29
0.15
1
04/19/15 05:38
04/20/15 14:51
7439-96-5
ND
mg/kg
0.58
0.29
1
04/19/15 05:38
04/20/15 14:51
7439-98-7
2.7
mg/kg
0.29
0.15
1
04/19/15 05:38
04/20/15 14:51
7440-02-0
114
mg/kg
58.1
29.0
1
04/19/15 05:38
04/20/15 14:51
7440-09-7
ND
mg/kg
58.1
29.0
1
04/19/15 05:38
04/20/15 14:51
7440-23-5
3.9
mg/kg
0.58
0.29
1
04/19/15 05:38
04/20/15 14:51
7440-24-6
27.2
mg/kg
1.2
0.58
1
04/19/15 05:38
04/20/15 14:51
7440-66-6
Analytical
Method: EPA
6020 Preparation Method: EPA 3050
ND
mg/kg
5.8
2.9
100
04/19/15 05:38
04/22/15 02:23
7440-36-0
ND
mg/kg
5.8
2.9
100
04/19/15 05:38
04/22/15 02:23
7440-38-2
ND
mg/kg
0.70
0.35
100
04/19/15 05:38
04/22/15 02:23
7440-43-9
9.3
mg/kg
5.8
2.9
100
04/19/15 05:38
04/22/15 02:23
7440-48-4
6.9
mg/kg
5.8
2.9
100
04/19/15 05:38
04/22/15 02:23
7439-92-1
ND
mg/kg
5.8
2.9
100
04/19/15 05:38
04/22/15 02:23
7782-49-2
ND
mg/kg
5.8
2.9
100
04/19/15 05:38
04/22/15 02:23
7440-28-0
31.6
mg/kg
5.8
2.9
100
04/19/15 05:38
04/22/15 02:23
7440-62-2
Analytical Method: EPA 7471 Preparation Method: EPA 7471
0.029 mg/kg 0.0090 0.0045 1 04/19/15 05:30 04/20/15 21:08 7439-97-6
Analytical Method: ASTM D2974-87
10 % 0.10 0.10 1 04/16/1516:14
Analytical Method: EPA 9045
5.0 Std. Units 0.10 0.10 1 04/16/15 16:00
N2
Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 04/15/15 00:55
4.0 mg/L 2.2 1.1 1 04/19/1517:39 14808-79-8 B
Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 04/15/15 00:55
0.26 mg/L 0.22 0.22 1 04/22/1517:44 H1
Analytical Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 04/15/15 00:55
ND mg/L 5.6 2.8 1 04/17/15 05:44 16887-00-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 33 of 67

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098g%vfte. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040239
Pace Project No.: 92245128
Sample: 2015010254 Lab ID: 92245128004 Collected: 04/08/15 15:30 Received: 04/10/15 16:35 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
9056 IC Anions Analytical Method: EPA 9056
Chloride
ND mg/kg
272
136
5
04/15/1518:25
16887-00-6 D3
Sulfate
ND mg/kg
272
136
5
04/15/1518:25
14808-79-8 D3
9056 IC Anions 48hr
Analytical Method: EPA 9056
Nitrate as N
ND mg/kg
27.2
13.6
5
04/15/15 18:25
14797-55-8 H3
Total Organic Carbon Quad
Analytical Method: EPA 9060
Total Organic Carbon
3950 mg/kg
670
335
1
04/28/15 13:23
7440-44-0
Total Organic Carbon
3570 mg/kg
668
334
1
04/28/15 13:29
7440-44-0
Total Organic Carbon
3830 mg/kg
668
334
1
04/28/15 13:35
7440-44-0
Total Organic Carbon
3780 mg/kg
662
331
1
04/28/15 13:40
7440-44-0
Mean Total Organic Carbon
3780 mg/kg
667
334
1
04/28/15 13:23
7440-44-0
Surrogates
RSD%
4.1 %
1
04/28/15 13:23
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/29/2015 02:22 PM without the written consent of Pace Analytical Services, Inc..
Page 34 of 67

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098�t�i .8fftie. Suite 100
y Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040239
Pace Project No.: 92245128
Sample: 2015010255 Lab ID: 92245128005 Collected: 04/08/15 16:45 Received: 04/10/15 16:35 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Aluminum
Barium
Beryllium
Boron
Calcium
Chromium
Copper
Iron
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Sodium
Strontium
Zinc
6020 MET ICPMS
Antimony
Arsenic
Cadmium
Cobalt
Lead
Selenium
Thallium
Vanadium
7471 Mercury
Mercury
Percent Moisture
Percent Moisture
9045 pH Soil
pH at 25 Degrees C
300.0 IC Anions, SPLP
Sulfate
353.2 Nitrogen, NO2/NO3, SPLP
Nitrogen, Nitrate
4500 Chloride, SPLP
Chloride
Date: 04/29/2015 02:22 PM
Analytical Method: EPA 6010 Preparation Method: EPA 3050
4500
mg/kg
6.3
3.1
1
04/19/15 05:38
04/20/15 14:56
7429-90-5
47.1
mg/kg
0.63
0.31
1
04/19/15 05:38
04/20/15 14:56
7440-39-3
0.22
mg/kg
0.063
0.031
1
04/19/15 05:38
04/20/15 14:56
7440-41-7
6.7
mg/kg
3.1
1.6
1
04/19/15 05:38
04/20/15 14:56
7440-42-8
448
mg/kg
31.4
15.7
1
04/19/15 05:38
04/20/15 14:56
7440-70-2
9.9
mg/kg
0.31
0.16
1
04/19/15 05:38
04/20/15 14:56
7440-47-3
8.2
mg/kg
0.31
0.16
1
04/19/15 05:38
04/20/15 14:56
7440-50-8
10600
mg/kg
2.5
1.3
1
04/19/15 05:38
04/20/15 14:56
7439-89-6
1060
mg/kg
31.4
15.7
1
04/19/15 05:38
04/20/15 14:56
7439-95-4
495
mg/kg
0.31
0.16
1
04/19/15 05:38
04/20/15 14:56
7439-96-5
ND
mg/kg
0.63
0.31
1
04/19/15 05:38
04/20/15 14:56
7439-98-7
3.1
mg/kg
0.31
0.16
1
04/19/15 05:38
04/20/15 14:56
7440-02-0
171
mg/kg
62.8
31.4
1
04/19/15 05:38
04/20/15 14:56
7440-09-7
ND
mg/kg
62.8
31.4
1
04/19/15 05:38
04/20/15 14:56
7440-23-5
5.6
mg/kg
0.63
0.31
1
04/19/15 05:38
04/20/15 14:56
7440-24-6
11.2
mg/kg
1.3
0.63
1
04/19/15 05:38
04/20/15 14:56
7440-66-6
Analytical
Method: EPA
6020 Preparation Method: EPA 3050
ND
mg/kg
6.3
3.1
100
04/19/15 05:38
04/22/15 02:25
7440-36-0
ND
mg/kg
6.3
3.1
100
04/19/15 05:38
04/22/15 02:25
7440-38-2
ND
mg/kg
0.75
0.38
100
04/19/15 05:38
04/22/15 02:25
7440-43-9
9.3
mg/kg
6.3
3.1
100
04/19/15 05:38
04/22/15 02:25
7440-48-4
74.3
mg/kg
6.3
3.1
100
04/19/15 05:38
04/22/15 02:25
7439-92-1
ND
mg/kg
6.3
3.1
100
04/19/15 05:38
04/22/15 02:25
7782-49-2
ND
mg/kg
6.3
3.1
100
04/19/15 05:38
04/22/15 02:25
7440-28-0
35.2
mg/kg
6.3
3.1
100
04/19/15 05:38
04/22/15 02:25
7440-62-2
Analytical Method: EPA 7471 Preparation Method: EPA 7471
0.0092J mg/kg 0.010 0.0051 1 04/19/15 05:30 04/20/15 21:11 7439-97-6
Analytical Method: ASTM D2974-87
18.1 % 0.10 0.10 1 04/16/1516:14
Analytical Method: EPA 9045
5.9 Std. Units 0.10 0.10 1 04/16/15 16:00
N2
Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 04/15/15 00:55
5.2 mg/L 2.4 1.2 1 04/19/1517:53 14808-79-8 B
Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 04/15/15 00:55
ND mg/L 0.24 0.24 1 04/22/1517:45 H1
Analytical Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 04/15/15 00:55
ND mg/L 6.1 3.1 1 04/17/15 05:45 16887-00-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 35 of 67

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098�t�i .8fftie. Suite 100
y Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040239
Pace Project No.: 92245128
Sample: 2015010255 Lab ID: 92245128005 Collected: 04/08/15 16:45 Received: 04/10/15 16:35 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
9056 IC Anions Analytical Method: EPA 9056
Chloride
ND mg/kg
299
150
5
04/15/1519:29
16887-00-6 D3
Sulfate
ND mg/kg
299
150
5
04/15/1519:29
14808-79-8 D3
9056 IC Anions 48hr
Analytical Method: EPA 9056
Nitrate as N
ND mg/kg
29.9
15.0
5
04/15/15 19:29
14797-55-8 H3
Total Organic Carbon Quad
Analytical Method: EPA 9060
Total Organic Carbon
2420 mg/kg
738
369
1
04/28/15 14:34
7440-44-0
Total Organic Carbon
2050 mg/kg
735
367
1
04/28/15 14:40
7440-44-0
Total Organic Carbon
2090 mg/kg
737
368
1
04/28/15 14:46
7440-44-0
Total Organic Carbon
2140 mg/kg
728
364
1
04/28/15 14:51
7440-44-0
Mean Total Organic Carbon
2170 mg/kg
734
367
1
04/28/15 14:34
7440-44-0
Surrogates
RSD%
7.6 %
1
04/28/15 14:34
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/29/2015 02:22 PM without the written consent of Pace Analytical Services, Inc..
Page 36 of 67

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098�t�i .8fftie. Suite 100
y Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040239
Pace Project No.: 92245128
Sample: 2015010256
Lab ID:
92245128006 Collected:
04/08/15 17:00
Received: 04/10/15 16:35 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample
size and any dilutions.
Report
Parameters
Results
Units Limit
MDL
DF
Prepared
Analyzed
CAS No.
Qual
6010 MET ICP
Analytical
Method: EPA 6010
Preparation
Method: EPA
3050
Aluminum
5670
mg/kg
6.8
3.4
1
04/19/15 05:38
04/20/15 15:00
7429-90-5
Barium
82.7
mg/kg
0.68
0.34
1
04/19/15 05:38
04/20/15 15:00
7440-39-3
Beryllium
0.33
mg/kg 0.068
0.034
1
04/19/15 05:38
04/20/15 15:00
7440-41-7
Boron
7.4
mg/kg
3.4
1.7
1
04/19/15 05:38
04/20/15 15:00
7440-42-8
Calcium
639
mg/kg
33.9
16.9
1
04/19/15 05:38
04/20/15 15:00
7440-70-2
Chromium
10.5
mg/kg
0.34
0.17
1
04/19/15 05:38
04/20/15 15:00
7440-47-3
Copper
7.9
mg/kg
0.34
0.17
1
04/19/15 05:38
04/20/15 15:00
7440-50-8
Iron
9870
mg/kg
2.7
1.4
1
04/19/15 05:38
04/20/15 15:00
7439-89-6
Magnesium
1100
mg/kg
33.9
16.9
1
04/19/15 05:38
04/20/15 15:00
7439-95-4
Manganese
358
mg/kg
0.34
0.17
1
04/19/15 05:38
04/20/15 15:00
7439-96-5
Molybdenum
ND
mg/kg
0.68
0.34
1
04/19/15 05:38
04/20/15 15:00
7439-98-7
Nickel
3.9
mg/kg
0.34
0.17
1
04/19/15 05:38
04/20/15 15:00
7440-02-0
Potassium
111
mg/kg
67.8
33.9
1
04/19/15 05:38
04/20/15 15:00
7440-09-7
Sodium
ND
mg/kg
67.8
33.9
1
04/19/15 05:38
04/20/15 15:00
7440-23-5
Strontium
9.1
mg/kg
0.68
0.34
1
04/19/15 05:38
04/20/15 15:00
7440-24-6
Zinc
14.1
mg/kg
1.4
0.68
1
04/19/15 05:38
04/20/15 15:00
7440-66-6
6020 MET ICPMS
Analytical
Method: EPA 6020
Preparation
Method: EPA
3050
Antimony
ND
mg/kg
6.8
3.4
100
04/19/15 05:38
04/22/15 02:35
7440-36-0
N2
Arsenic
ND
mg/kg
6.8
3.4
100
04/19/15 05:38
04/22/15 02:35
7440-38-2
Cadmium
ND
mg/kg
0.81
0.41
100
04/19/15 05:38
04/22/15 02:35
7440-43-9
Cobalt
8.3
mg/kg
6.8
3.4
100
04/19/15 05:38
04/22/15 02:35
7440-48-4
Lead
5.2J
mg/kg
6.8
3.4
100
04/19/15 05:38
04/22/15 02:35
7439-92-1
Selenium
ND
mg/kg
6.8
3.4
100
04/19/15 05:38
04/22/15 02:35
7782-49-2
Thallium
ND
mg/kg
6.8
3.4
100
04/19/15 05:38
04/22/15 02:35
7440-28-0
Vanadium
35.2
mg/kg
6.8
3.4
100
04/19/15 05:38
04/22/15 02:35
7440-62-2
7471 Mercury
Analytical
Method: EPA 7471
Preparation
Method: EPA
7471
Mercury
0.016
mg/kg
0.011
0.0054
1
04/19/15 05:30
04/20/15 21:17
7439-97-6
Percent Moisture
Analytical
Method: ASTM D2974-87
Percent Moisture
22.3
%
0.10
0.10
1
04/16/15 16:15
9045 pH Soil
Analytical
Method: EPA 9045
pH at 25 Degrees C
5.6
Std. Units
0.10
0.10
1
04/16/15 16:00
9056 IC Anions
Analytical
Method: EPA 9056
Chloride
ND
mg/kg
323
162
5
04/15/1519:51
16887-00-6
D3
Sulfate
ND
mg/kg
323
162
5
04/15/1519:51
14808-79-8
D3
9056 IC Anions 48hr
Analytical
Method: EPA 9056
Nitrate as N
ND
mg/kg
32.3
16.2
5
04/15/15 19:51
14797-55-8
H3
Date: 04/29/2015 02:22 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 37 of 67

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098�t�i .8fftie. Suite 100
y Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040239
Pace Project No.: 92245128
Sample: 2015010256
Lab ID:
92245128006
Collected:
04/08/15 17:00
Received: 04/10/15 16:35 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample
size and any dilutions.
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared Analyzed
CAS No. Qual
Total Organic Carbon Quad
Analytical
Method: EPA 9060
Total Organic Carbon
3270
mg/kg
778
389
1
04/28/15 14:57
7440-44-0
Total Organic Carbon
2990
mg/kg
768
384
1
04/28/15 15:03
7440-44-0
Total Organic Carbon
3190
mg/kg
770
385
1
04/28/15 15:08
7440-44-0
Total Organic Carbon
2840
mg/kg
779
390
1
04/28/15 15:15
7440-44-0
Mean Total Organic Carbon
3070
mg/kg
774
387
1
04/28/15 14:57
7440-44-0
Surrogates
RSD%
6.4
%
1
04/28/15 14:57
Date: 04/29/2015 02:22 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 38 of 67

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098�t�i .8fftie. Suite 100
y Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040239
Pace Project No.: 92245128
Sample: 2015010257
Lab ID:
92245128007 Collected:
04/08/15 17:15
Received: 04/10/15 16:35 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample
size and any dilutions.
Report
Parameters
Results
Units Limit
MDL
DF
Prepared
Analyzed
CAS No.
Qual
6010 MET ICP
Analytical
Method: EPA 6010
Preparation
Method: EPA
3050
Aluminum
27200
mg/kg
51.1
25.6
10
04/19/15 05:38
04/25/15 15:08
7429-90-5
D3
Barium
209
mg/kg
5.1
2.6
10
04/19/15 05:38
04/25/15 15:08
7440-39-3
D3
Beryllium
1.4
mg/kg
0.51
0.26
10
04/19/15 05:38
04/25/15 15:08
7440-41-7
D3
Boron
ND
mg/kg
25.6
12.8
10
04/19/15 05:38
04/25/15 15:08
7440-42-8
D3
Calcium
301
mg/kg
256
128
10
04/19/15 05:38
04/25/15 15:08
7440-70-2
D3
Chromium
14.4
mg/kg
2.6
1.3
10
04/19/15 05:38
04/25/15 15:08
7440-47-3
D3
Copper
24.0
mg/kg
2.6
1.3
10
04/19/15 05:38
04/25/15 15:08
7440-50-8
D3
Iron
22900
mg/kg
20.5
10.2
10
04/19/15 05:38
04/25/15 15:08
7439-89-6
D3
Magnesium
3570
mg/kg
256
128
10
04/19/15 05:38
04/25/15 15:08
7439-95-4
D3
Manganese
457
mg/kg
2.6
1.3
10
04/19/15 05:38
04/25/15 15:08
7439-96-5
D3
Molybdenum
3.3J
mg/kg
5.1
2.6
10
04/19/15 05:38
04/25/15 15:08
7439-98-7
D3
Nickel
5.9
mg/kg
2.6
1.3
10
04/19/15 05:38
04/25/15 15:08
7440-02-0
D3
Potassium
3920
mg/kg
511
256
10
04/19/15 05:38
04/25/15 15:08
7440-09-7
D3
Sodium
ND
mg/kg
511
256
10
04/19/15 05:38
04/25/15 15:08
7440-23-5
D3
Strontium
14.3
mg/kg
5.1
2.6
10
04/19/15 05:38
04/25/15 15:08
7440-24-6
D3
Zinc
78.0
mg/kg
10.2
5.1
10
04/19/15 05:38
04/25/15 15:08
7440-66-6
D3
6020 MET ICPMS
Analytical
Method: EPA 6020
Preparation
Method: EPA
3050
Antimony
ND
mg/kg
5.1
2.6
100
04/19/15 05:38
04/22/15 02:37
7440-36-0
N2
Arsenic
ND
mg/kg
5.1
2.6
100
04/19/15 05:38
04/22/15 02:37
7440-38-2
Cadmium
ND
mg/kg
0.61
0.31
100
04/19/15 05:38
04/22/15 02:37
7440-43-9
Cobalt
27.9
mg/kg
5.1
2.6
100
04/19/15 05:38
04/22/15 02:37
7440-48-4
Lead
8.3
mg/kg
5.1
2.6
100
04/19/15 05:38
04/22/15 02:37
7439-92-1
Selenium
3.3.11
mg/kg
5.1
2.6
100
04/19/15 05:38
04/22/15 02:37
7782-49-2
Thallium
ND
mg/kg
5.1
2.6
100
04/19/15 05:38
04/22/15 02:37
7440-28-0
Vanadium
30.1
mg/kg
5.1
2.6
100
04/19/15 05:38
04/22/15 02:37
7440-62-2
7471 Mercury
Analytical
Method: EPA 7471
Preparation
Method: EPA
7471
Mercury
ND
mg/kg 0.0082
0.0041
1
04/19/15 05:30
04/20/15 21:19
7439-97-6
Percent Moisture
Analytical
Method: ASTM D2974-87
Percent Moisture
4.0
%
0.10
0.10
1
04/16/15 16:15
9045 pH Soil
Analytical
Method: EPA 9045
pH at 25 Degrees C
7.9
Std. Units
0.10
0.10
1
04/16/15 16:00
9056 IC Anions
Analytical
Method: EPA 9056
Chloride
ND
mg/kg
256
128
5
04/15/15 20:12
16887-00-6
D3
Sulfate
ND
mg/kg
256
128
5
04/15/15 20:12
14808-79-8
D3
9056 IC Anions 48hr
Analytical
Method: EPA 9056
Nitrate as N
ND
mg/kg
25.6
12.8
5
04/15/15 20:12
14797-55-8
H3
Date: 04/29/2015 02:22 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 39 of 67

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098onyfte. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040239
Pace Project No.: 92245128
Sample: 2015010257
Lab ID:
92245128007
Collected:
04/08/15 17:15
Received: 04/10/15 16:35 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample
size and any dilutions.
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared Analyzed
CAS No. Qual
Total Organic Carbon Quad
Analytical
Method: EPA 9060
Total Organic Carbon
ND
mg/kg
630
315
1
04/28/15 15:21
7440-44-0
Total Organic Carbon
ND
mg/kg
621
310
1
04/28/15 15:26
7440-44-0
Total Organic Carbon
ND
mg/kg
626
313
1
04/28/15 15:32
7440-44-0
Total Organic Carbon
ND
mg/kg
624
312
1
04/28/15 15:37
7440-44-0
Mean Total Organic Carbon
ND
mg/kg
625
313
1
04/28/15 15:21
7440-44-0
Surrogates
RSD%
1.6
%
1
04/28/15 15:21
Date: 04/29/2015 02:22 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 40 of 67

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098onvfte. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040239
Pace Project No.: 92245128
Sample: 2015010252 SPLP Lab ID: 92245128008 Collected: 04/07/15 16:25 Received: 04/10/15 16:35 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
;T➢Z17c\�iil=11 a
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Sodium
Strontium
Thallium
Vanadium
Zinc
7470A Mercury
Mercury
Date: 04/29/2015 02:22 PM
Analytical Method: EPA 6020A Preparation Method: EPA 3020
1160
ug/L
10.0
3.0
1
04/26/15 22:15
04/27/15 10:52
7429-90-5
ND
ug/L
0.50
0.15
1
04/26/15 22:15
04/27/15 10:52
7440-36-0
0.87
ug/L
0.50
0.11
1
04/26/15 22:15
04/27/15 10:52
7440-38-2
130
ug/L
0.30
0.081
1
04/26/15 22:15
04/27/15 10:52
7440-39-3
0.15J
ug/L
0.20
0.067
1
04/26/15 22:15
04/27/15 10:52
7440-41-7
32.9
ug/L
5.0
1.1
1
04/26/15 22:15
04/27/15 10:52
7440-42-8
ND
ug/L
0.080
0.024
1
04/26/15 22:15
04/27/15 10:52
7440-43-9
1120
ug/L
40.0
16.0
1
04/26/15 22:15
04/27/15 10:52
7440-70-2
1.3
ug/L
0.50
0.17
1
04/26/15 22:15
04/27/15 10:52
7440-47-3
1.9
ug/L
0.50
0.13
1
04/26/15 22:15
04/27/15 10:52
7440-48-4
7.6
ug/L
1.0
0.21
1
04/26/15 22:15
04/27/15 10:52
7440-50-8
802
ug/L
50.0
13.7
1
04/26/15 22:15
04/27/15 10:52
7439-89-6
2.1
ug/L
0.10
0.046
1
04/26/15 22:15
04/27/15 10:52
7439-92-1
503
ug/L
10.0
3.2
1
04/26/15 22:15
04/27/15 10:52
7439-95-4
41.8
ug/L
0.50
0.24
1
04/26/15 22:15
04/27/15 10:52
7439-96-5
0.181
ug/L
0.50
0.094
1
04/26/15 22:15
04/27/15 10:52
7439-98-7
1.4
ug/L
0.50
0.16
1
04/26/15 22:15
04/27/15 10:52
7440-02-0
267
ug/L
50.0
11.7
1
04/26/15 22:15
04/27/15 10:52
7440-09-7
ND
ug/L
0.50
0.20
1
04/26/15 22:15
04/27/15 10:52
7782-49-2
1770
ug/L
50.0
16.3
1
04/26/15 22:15
04/27/15 10:52
7440-23-5
12.6
ug/L
0.50
0.13
1
04/26/15 22:15
04/27/15 10:52
7440-24-6
ND
ug/L
0.10
0.015
1
04/26/15 22:15
04/27/15 10:52
7440-28-0
2.8
ug/L
1.0
0.28
1
04/26/15 22:15
04/27/15 10:52
7440-62-2
35.8
ug/L
5.0
2.4
1
04/26/15 22:15
04/27/15 10:52
7440-66-6
Analytical Method: EPA 7470A Preparation Method: EPA 7470A
ND ug/L 0.60 0.065 1 04/26/15 18:20 04/27/15 09:56 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 41 of 67

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098onyfte. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040239
Pace Project No.: 92245128
Sample: 2015010254 SPLP Lab ID: 92245128009 Collected: 04/08/15 15:30 Received: 04/10/15 16:35 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
;T➢Z17c\�iil=11 a
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Sodium
Strontium
Thallium
Vanadium
Zinc
7470A Mercury
Mercury
Date: 04/29/2015 02:22 PM
Analytical Method: EPA 6020A Preparation Method: EPA 3020
7460
ug/L
50.0
14.9
1
04/26/15 22:15
04/27/15 10:55
7429-90-5
ND
ug/L
2.5
0.74
1
04/26/15 22:15
04/27/15 10:55
7440-36-0
1.1J
ug/L
2.5
0.56
1
04/26/15 22:15
04/27/15 10:55
7440-38-2
206
ug/L
1.5
0.40
1
04/26/15 22:15
04/27/15 10:55
7440-39-3
0.40J
ug/L
1.0
0.34
1
04/26/15 22:15
04/27/15 10:55
7440-41-7
74.0
ug/L
25.0
5.6
1
04/26/15 22:15
04/27/15 10:55
7440-42-8
ND
ug/L
0.40
0.12
1
04/26/15 22:15
04/27/15 10:55
7440-43-9
1100
ug/L
200
80.0
1
04/26/15 22:15
04/27/15 10:55
7440-70-2
10.7
ug/L
2.5
0.84
1
04/26/15 22:15
04/27/15 10:55
7440-47-3
4.7
ug/L
2.5
0.63
1
04/26/15 22:15
04/27/15 10:55
7440-48-4
11.0
ug/L
5.0
1.1
1
04/26/15 22:15
04/27/15 10:55
7440-50-8
8770
ug/L
250
68.5
1
04/26/15 22:15
04/27/15 10:55
7439-89-6
6.7
ug/L
0.50
0.23
1
04/26/15 22:15
04/27/15 10:55
7439-92-1
651
ug/L
50.0
15.8
1
04/26/15 22:15
04/27/15 10:55
7439-95-4
350
ug/L
2.5
1.2
1
04/26/15 22:15
04/27/15 10:55
7439-96-5
ND
ug/L
2.5
0.47
1
04/26/15 22:15
04/27/15 10:55
7439-98-7
3.8
ug/L
2.5
0.81
1
04/26/15 22:15
04/27/15 10:55
7440-02-0
264
ug/L
250
58.7
1
04/26/15 22:15
04/27/15 10:55
7440-09-7
ND
ug/L
2.5
1.0
1
04/26/15 22:15
04/27/15 10:55
7782-49-2
1570
ug/L
250
81.5
1
04/26/15 22:15
04/27/15 10:55
7440-23-5
15.8
ug/L
2.5
0.66
1
04/26/15 22:15
04/27/15 10:55
7440-24-6
ND
ug/L
0.50
0.077
1
04/26/15 22:15
04/27/15 10:55
7440-28-0
27.5
ug/L
5.0
1.4
1
04/26/15 22:15
04/27/15 10:55
7440-62-2
130
ug/L
25.0
12.0
1
04/26/15 22:15
04/27/15 10:55
7440-66-6
Analytical Method: EPA 7470A Preparation Method: EPA 7470A
ND ug/L 0.60 0.065 1 04/26/15 18:20 04/27/15 09:58 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 42 of 67

aceAnaiXical
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Pace Analytical Services, Inc.
098nnyfte. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040239
Pace Project No.: 92245128
Sample: 2015010255 SPLP Lab ID: 92245128010 Collected: 04/08/15 16:45 Received: 04/10/15 16:35 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
;T➢Z17c\�iil=11 a
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Sodium
Strontium
Thallium
Vanadium
Zinc
7470A Mercury
Mercury
Date: 04/29/2015 02:22 PM
Analytical Method: EPA 6020A Preparation Method: EPA 3020
1720
ug/L
10.0
3.0
1
04/26/15 22:15
04/27/15 11:06
7429-90-5
ND
ug/L
0.50
0.15
1
04/26/15 22:15
04/27/15 11:06
7440-36-0
0.16J
ug/L
0.50
0.11
1
04/26/15 22:15
04/27/15 11:06
7440-38-2
148
ug/L
0.30
0.081
1
04/26/15 22:15
04/27/15 11:06
7440-39-3
0.075J
ug/L
0.20
0.067
1
04/26/15 22:15
04/27/15 11:06
7440-41-7
57.9
ug/L
5.0
1.1
1
04/26/15 22:15
04/27/15 11:06
7440-42-8
ND
ug/L
0.080
0.024
1
04/26/15 22:15
04/27/15 11:06
7440-43-9
902
ug/L
40.0
16.0
1
04/26/15 22:15
04/27/15 11:06
7440-70-2
1.9
ug/L
0.50
0.17
1
04/26/15 22:15
04/27/15 11:06
7440-47-3
0.86
ug/L
0.50
0.13
1
04/26/15 22:15
04/27/15 11:06
7440-48-4
3.2
ug/L
1.0
0.21
1
04/26/15 22:15
04/27/15 11:06
7440-50-8
1520
ug/L
50.0
13.7
1
04/26/15 22:15
04/27/15 11:06
7439-89-6
0.88
ug/L
0.10
0.046
1
04/26/15 22:15
04/27/15 11:06
7439-92-1
370
ug/L
10.0
3.2
1
04/26/15 22:15
04/27/15 11:06
7439-95-4
64.9
ug/L
0.50
0.24
1
04/26/15 22:15
04/27/15 11:06
7439-96-5
ND
ug/L
0.50
0.094
1
04/26/15 22:15
04/27/15 11:06
7439-98-7
1.6
ug/L
0.50
0.16
1
04/26/15 22:15
04/27/15 11:06
7440-02-0
91.7
ug/L
50.0
11.7
1
04/26/15 22:15
04/27/15 11:06
7440-09-7
ND
ug/L
0.50
0.20
1
04/26/15 22:15
04/27/15 11:06
7782-49-2
1390
ug/L
50.0
16.3
1
04/26/15 22:15
04/27/15 11:06
7440-23-5
12.8
ug/L
0.50
0.13
1
04/26/15 22:15
04/27/15 11:06
7440-24-6
ND
ug/L
0.10
0.015
1
04/26/15 22:15
04/27/15 11:06
7440-28-0
5.0
ug/L
1.0
0.28
1
04/26/15 22:15
04/27/15 11:06
7440-62-2
46.1
ug/L
5.0
2.4
1
04/26/15 22:15
04/27/15 11:06
7440-66-6
Analytical Method: EPA 7470A Preparation Method: EPA 7470A
ND ug/L 0.60 0.065 1 04/26/1518:20 04/27/1510:00 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 43 of 67

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098mvfte. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040239
Pace Project No.: 92245128
QC Batch: MERP/13223 Analysis Method: EPA 7470
QC Batch Method: EPA 7470 Analysis Description: 7470 Mercury
Associated Lab Samples: 92245128001, 92245128002
METHOD BLANK: 1938836 Matrix: Water
Associated Lab Samples: 92245128001, 92245128002
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Mercury ug/L ND 0.20 04/15/1518:09
LABORATORY CONTROL SAMPLE: 1938837
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Mercury ug/L 5 4.7 95 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1938838 1938839
MS MSD
92245128001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Mercury ug/L ND 5 5 4.7 4.7 94 94 75-125 0 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/29/2015 02:22 PM without the written consent of Pace Analytical Services, Inc..
Page 44 of 67

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098nnyfte. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040239
Pace Project No.: 92245128
QC Batch: MERP/13346
Analysis Method: EPA 7470A
QC Batch Method: EPA 7470A
Analysis Description: 7470A Mercury Water
Associated Lab Samples: 92245128008, 92245128009,
92245128010
METHOD BLANK: 1948052
Matrix: Water
Associated Lab Samples: 92245128008, 92245128009,
92245128010
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Mercury ug/L
ND 0.20
04/27/15 09:48
LABORATORY CONTROL SAMPLE: 1948053
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Mercury ug/L
5 5.1
101 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1948822 1948823
MS MSD
10303813001
Spike Spike MS
MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec Limits RPD RPD Qual
Mercury ug/L 0.20 U
5 5 4.8
4.6 97 93 80-120 4 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/29/2015 02:22 PM without the written consent of Pace Analytical Services, Inc..
Page 45 of 67

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098onyfte. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040239
Pace Project No.: 92245128
QC Batch: MERP/5604
Analysis Method: EPA 7471
QC Batch Method: EPA 7471
Analysis Description: 7471 Mercury
Associated Lab Samples: 92245128003, 92245128004,
92245128005, 92245128006, 92245128007
METHOD BLANK: 1188083
Matrix: Solid
Associated Lab Samples: 92245128003, 92245128004,
92245128005, 92245128006, 92245128007
Blank Reporting
Parameter Units
Result Limit Analyzed Qualifiers
Mercury mg/kg
ND 0.0081 04/20/15 20:38
LABORATORY CONTROL SAMPLE: 1188084
Spike LCS LCS % Rec
Parameter Units
Conc. Result % Rec Limits Qualifiers
Mercury mg/kg
.082 0.066 81 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1188085 1188086
MS MSD
92245094011
Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Mercury mg/kg ND
.12 .117 0.11 0.10 89 86 80-120 6 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/29/2015 02:22 PM without the written consent of Pace Analytical Services, Inc..
Page 46 of 67

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098g"vfte. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040239
Pace Project No.: 92245128
QC Batch: MPRP/23696 Analysis Method: EPA 6010
QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid
Associated Lab Samples: 92245128003, 92245128004, 92245128005, 92245128006, 92245128007
METHOD BLANK: 1188075 Matrix: Solid
Associated Lab Samples: 92245128003, 92245128004, 92245128005, 92245128006, 92245128007
Blank Reporting
Parameter Units Result Limit Analyzed
Aluminum
mg/kg
ND
5.2
04/25/1514:10
Barium
mg/kg
ND
0.52
04/25/1514:10
Beryllium
mg/kg
ND
0.052
04/25/1514:10
Boron
mg/kg
ND
2.6
04/25/1514:10
Calcium
mg/kg
ND
25.8
04/25/1514:10
Chromium
mg/kg
ND
0.26
04/25/1514:10
Copper
mg/kg
ND
0.26
04/25/1514:10
Iron
mg/kg
1 AJ
2.1
04/25/15 14:10 P8
Magnesium
mg/kg
ND
25.8
04/25/1514:10
Manganese
mg/kg
ND
0.26
04/25/1514:10
Molybdenum
mg/kg
ND
0.52
04/25/1514:10
Nickel
mg/kg
ND
0.26
04/25/1514:10
Potassium
mg/kg
ND
51.7
04/25/1514:10
Sodium
mg/kg
ND
51.7
04/25/1514:10
Strontium
mg/kg
ND
0.52
04/25/1514:10
Zinc
mg/kg
ND
1.0
04/25/1514:10
Qualifiers
LABORATORY CONTROL SAMPLE:
Parameter
1188076
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
Aluminum
mg/kg
122
126
103
80-120
Barium
mg/kg
12.2
12.6
103
80-120
Beryllium
mg/kg
1.2
1.3
105
80-120
Boron
mg/kg
122
122
100
80-120
Calcium
mg/kg
608
644
106
80-120
Chromium
mg/kg
12.2
12.1
100
80-120
Copper
mg/kg
12.2
11.9
98
80-120
Iron
mg/kg
122
127
105
80-120
Magnesium
mg/kg
608
627
103
80-120
Manganese
mg/kg
12.2
12.5
103
80-120
Molybdenum
mg/kg
12.2
12.2
101
80-120
Nickel
mg/kg
12.2
12.7
104
80-120
Potassium
mg/kg
608
626
103
80-120
Sodium
mg/kg
608
640
105
80-120
Strontium
mg/kg
12.2
12.5
103
80-120
Zinc
mg/kg
60.8
63.3
104
80-120
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/29/2015 02:22 PM without the written consent of Pace Analytical Services, Inc.. Page 47 of 67

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098onyfte. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040239
Pace Project No.: 92245128
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
1188077
1188078
MS
MSD
92245094011
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qua]
Aluminum
mg/kg
20700
186
174
31300
33500
5680
7350
75-125
7
20 D3,M1
Barium
mg/kg
149
18.6
17.4
269
274
643
715
75-125
2
20 D3,M1
Beryllium
mg/kg
2.3
1.86
1.72
4.1
4.3
97
116
75-125
5
20 D3
Boron
mg/kg
ND
186
174
144
136
77
78
75-125
6
20 D3
Calcium
mg/kg
525
929
872
1560
1500
111
112
75-125
4
20 D3
Chromium
mg/kg
47.5
18.6
17.4
122
119
401
412
75-125
2
20 D3,M1
Copper
mg/kg
37.5
18.6
17.4
55.6
61.2
98
136
75-125
10
20 D3,M1
Iron
mg/kg
60700
186
174
64600
63300
2070
1460
75-125
2
20 D3,M1
Magnesium
mg/kg
5520
929
872
11300
12100
616
749
75-125
7
20 D3,M1
Manganese
mg/kg
942
18.6
17.4
1120
1040
975
538
75-125
8
20 D3,M1
Molybdenum
mg/kg
44.6
18.6
17.4
62.9
65.7
98
121
75-125
4
20 D3
Nickel
mg/kg
30.2
18.6
17.4
74.8
81.5
240
294
75-125
8
20 D3,M1
Potassium
mg/kg
4200
929
872
8300
9180
441
571
75-125
10
20 D3,M1
Sodium
mg/kg
ND
929
872
943
886
101
102
75-125
6
20 D3
Strontium
mg/kg
27.4
18.6
17.4
51.2
49.6
128
128
75-125
3
20 D3,M1
Zinc
mg/kg
83.5
92.9
87.2
202
201
128
135
75-125
0
20 D3,M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/29/2015 02:22 PM without the written consent of Pace Analytical Services, Inc..
Page 48 of 67

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098onyfte. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040239
Pace Project No.: 92245128
QC Batch: MPRP/23697 Analysis Method: EPA 6020
QC Batch Method: EPA 3050 Analysis Description: 6020 MET SOLID
Associated Lab Samples: 92245128003, 92245128004, 92245128005, 92245128006, 92245128007
METHOD BLANK: 1188079
Matrix:
Solid
Associated Lab Samples:
92245128003, 92245128004,
92245128005, 92245128006, 92245128007
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Antimony
mg/kg
ND
0.052
04/22/15 01:45 N2
Arsenic
mg/kg
ND
0.052
04/22/15 01:45
Cadmium
mg/kg
ND
0.0063
04/22/15 01:45
Cobalt
mg/kg
ND
0.052
04/22/15 01:45
Lead
mg/kg
ND
0.052
04/22/15 01:45
Selenium
mg/kg
ND
0.052
04/22/15 01:45
Thallium
mg/kg
ND
0.052
04/22/15 01:45
Vanadium
mg/kg
ND
0.052
04/22/15 01:45
LABORATORY CONTROL SAMPLE:
Parameter
1188080
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
Antimony
mg/kg
2.5
2.5
101
80-120 N2
Arsenic
mg/kg
2.5
2.6
106
80-120
Cadmium
mg/kg
.25
0.26
104
80-120
Cobalt
mg/kg
2.5
2.6
106
80-120
Lead
mg/kg
2.5
2.5
101
80-120
Selenium
mg/kg
2.5
2.5
103
80-120
Thallium
mg/kg
2.5
2.6
103
80-120
Vanadium
mg/kg
2.5
2.6
106
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
1188081
1188082
MS
MSD
92245094012
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD RPD Qual
Antimony
mg/kg
ND
3.59
3.89
ND
ND
51
71
75-125
20 M6,N2
Arsenic
mg/kg
ND
3.59
3.89
5.1J
4.7J
107
92
75-125
20
Cadmium
mg/kg
ND
.359
.389
ND
ND
88
76
75-125
20
Cobalt
mg/kg
17.2
3.59
3.89
23.3
35.9
166
487
75-125
43 20 M6,R1
Lead
mg/kg
7.6J
3.59
3.89
12.7
14.7
139
183
75-125
14 20 M6
Selenium
mg/kg
ND
3.59
3.89
6.OJ
5.9J
90
84
75-125
20
Thallium
mg/kg
ND
3.59
3.89
4.5J
4.6J
106
103
75-125
20
Vanadium
mg/kg
29.1
3.59
3.89
33.5
57.3
119
732
75-125
52 20 M6,R1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/29/2015 02:22 PM without the written consent of Pace Analytical Services, Inc..
Page 49 of 67

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098oinyfte. Suite 100
y Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040239
Pace Project No.: 92245128
QC Batch: MPRP/53618 Analysis Method: EPA 6020A
QC Batch Method: EPA 3020 Analysis Description: 6020A Water UPD4
Associated Lab Samples: 92245128001, 92245128002
METHOD BLANK: 1938831
Associated Lab Samples: 92245128001, 92245128002
Parameter
Units
Aluminum
ug/L
Antimony
ug/L
Arsenic
ug/L
Barium
ug/L
Beryllium
ug/L
Boron
ug/L
Cadmium
ug/L
Calcium
ug/L
Chromium
ug/L
Cobalt
ug/L
Copper
ug/L
Iron
ug/L
Lead
ug/L
Magnesium
ug/L
Manganese
ug/L
Molybdenum
ug/L
Nickel
ug/L
Potassium
ug/L
Selenium
ug/L
Sodium
ug/L
Strontium
ug/L
Thallium
ug/L
Vanadium
ug/L
Zinc
ug/L
Matrix: Water
Blank
Result
Reporting
Limit
Analyzed
ND
10.0
04/15/1515:27
ND
0.50
04/15/1515:27
ND
0.50
04/15/1515:27
ND
0.30
04/15/1515:27
ND
0.20
04/15/1515:27
ND
5.0
04/15/1515:27
ND
0.080
04/15/1515:27
ND
40.0
04/15/1515:27
ND
0.50
04/15/1515:27
ND
0.50
04/15/1515:27
ND
1.0
04/15/1515:27
ND
50.0
04/15/1515:27
ND
0.10
04/15/1515:27
ND
10.0
04/15/1515:27
ND
0.50
04/15/1515:27
ND
0.50
04/15/1515:27
ND
0.50
04/15/1515:27
ND
50.0
04/15/1515:27
ND
0.50
04/15/1515:27
ND
50.0
04/15/1515:27
ND
0.50
04/15/1515:27
ND
0.10
04/15/1515:27
ND
1.0
04/15/1515:27
ND
5.0
04/15/1515:27
Qualifiers
LABORATORY CONTROL SAMPLE:
Parameter
1938832
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
Aluminum
ug/L
80
82.5
103
80-120
Antimony
ug/L
80
75.0
94
80-120
Arsenic
ug/L
80
76.1
95
80-120
Barium
ug/L
80
78.4
98
80-120
Beryllium
ug/L
80
77.1
96
80-120
Boron
ug/L
80
80.0
100
80-120
Cadmium
ug/L
80
81.3
102
80-120
Calcium
ug/L
1000
1040
104
80-120
Chromium
ug/L
80
79.9
100
80-120
Cobalt
ug/L
80
78.4
98
80-120
Copper
ug/L
80
80.9
101
80-120
Iron
ug/L
1000
1030
103
80-120
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/29/2015 02:22 PM without the written consent of Pace Analytical Services, Inc..
Page 50 of 67

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098oinvfte. Suite 100
y Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040239
Pace Project No.: 92245128
LABORATORY CONTROL SAMPLE:
1938832
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits
Qualifiers
Lead
ug/L
80
79.1
99
80-120
Magnesium
ug/L
1000
991
99
80-120
Manganese
ug/L
80
81.6
102
80-120
Molybdenum
ug/L
80
77.9
97
80-120
Nickel
ug/L
80
78.7
98
80-120
Potassium
ug/L
1000
1010
101
80-120
Selenium
ug/L
80
79.1
99
80-120
Sodium
ug/L
1000
1020
102
80-120
Strontium
ug/L
80
78.1
98
80-120
Thallium
ug/L
80
80.1
100
80-120
Vanadium
ug/L
80
78.8
98
80-120
Zinc
ug/L
80
79.6
99
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1938833
1938834
MS
MSD
10302295001
Spike
Spike
MS
MSD
MS MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec % Rec
Limits
RPD
RPD Qual
Aluminum
ug/L
ND
80
80
93.5
89.0
111
105
75-125
5
20
Antimony
ug/L
ND
80
80
77.1
75.6
96
94
75-125
2
20
Arsenic
ug/L
3.4
80
80
80.9
79.3
97
95
75-125
2
20
Barium
ug/L
36.4
80
80
117
115
101
98
75-125
2
20
Beryllium
ug/L
ND
80
80
75.6
77.0
94
96
75-125
2
20
Boron
ug/L
25.0
80
80
101
108
95
103
75-125
7
20
Cadmium
ug/L
ND
80
80
83.7
83.1
105
104
75-125
1
20
Calcium
ug/L
43.4 mg/L
1000
1000
44800
44300
140
94
75-125
1
20 M1
Chromium
ug/L
ND
80
80
81.8
79.7
102
99
75-125
3
20
Cobalt
ug/L
ND
80
80
78.7
76.8
98
96
75-125
2
20
Copper
ug/L
ND
80
80
79.6
78.2
99
98
75-125
2
20
Iron
ug/L
273
1000
1000
1310
1280
104
100
75-125
2
20
Lead
ug/L
ND
80
80
79.2
77.1
99
96
75-125
3
20
Magnesium
ug/L
21.4 mg/L
1000
1000
23600
23700
225
235
75-125
0
20 M1
Manganese
ug/L
197
80
80
285
280
110
103
75-125
2
20
Molybdenum
ug/L
1.7
80
80
81.8
80.5
100
98
75-125
2
20
Nickel
ug/L
ND
80
80
78.2
76.6
98
95
75-125
2
20
Potassium
ug/L
1.5 mg/L
1000
1000
2540
2500
108
103
75-125
2
20
Selenium
ug/L
ND
80
80
78.2
78.7
98
98
75-125
1
20
Sodium
ug/L
7.4 mg/L
1000
1000
8440
8320
101
88
75-125
1
20
Strontium
ug/L
166
80
80
250
246
105
100
75-125
2
20
Thallium
ug/L
ND
80
80
80.4
78.0
101
98
75-125
3
20
Vanadium
ug/L
ND
80
80
80.8
79.0
101
98
75-125
2
20
Zinc
ug/L
ND
80
80
79.8
79.0
98
97
75-125
1
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/29/2015 02:22 PM without the written consent of Pace Analytical Services, Inc..
Page 51 of 67

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098oinyfte. Suite 100
y Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040239
Pace Project No.: 92245128
QC Batch: MPRP/53885 Analysis Method: EPA 6020A
QC Batch Method: EPA 3020 Analysis Description: 6020A Water UPD4
Associated Lab Samples: 92245128008, 92245128009, 92245128010
METHOD BLANK: 1947519 Matrix:
Associated Lab Samples: 92245128008, 92245128009, 92245128010
Blank
Parameter Units Result
Water
Reporting
Limit
Analyzed
Aluminum
ug/L
ND
10.0
04/27/1510:10
Antimony
ug/L
ND
0.50
04/27/1510:10
Arsenic
ug/L
ND
0.50
04/27/1510:10
Barium
ug/L
ND
0.30
04/27/1510:10
Beryllium
ug/L
ND
0.20
04/27/1510:10
Boron
ug/L
ND
5.0
04/27/1510:10
Cadmium
ug/L
ND
0.080
04/27/1510:10
Calcium
ug/L
ND
40.0
04/27/1510:10
Chromium
ug/L
ND
0.50
04/27/1510:10
Cobalt
ug/L
ND
0.50
04/27/1510:10
Copper
ug/L
ND
1.0
04/27/1510:10
Iron
ug/L
ND
50.0
04/27/1510:10
Lead
ug/L
ND
0.10
04/27/1510:10
Magnesium
ug/L
ND
10.0
04/27/1510:10
Manganese
ug/L
ND
0.50
04/27/1510:10
Molybdenum
ug/L
ND
0.50
04/27/1510:10
Nickel
ug/L
ND
0.50
04/27/1510:10
Potassium
ug/L
ND
50.0
04/27/1510:10
Selenium
ug/L
ND
0.50
04/27/1510:10
Sodium
ug/L
ND
50.0
04/27/1510:10
Strontium
ug/L
ND
0.50
04/27/1510:10
Thallium
ug/L
ND
0.10
04/27/1510:10
Vanadium
ug/L
ND
1.0
04/27/1510:10
Zinc
ug/L
ND
5.0
04/27/1510:10
Qualifiers
LABORATORY CONTROL SAMPLE:
Parameter
1947520
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
Aluminum
ug/L
80
82.2
103
80-120
Antimony
ug/L
80
83.4
104
80-120
Arsenic
ug/L
80
80.3
100
80-120
Barium
ug/L
80
83.4
104
80-120
Beryllium
ug/L
80
84.2
105
80-120
Boron
ug/L
80
85.2
106
80-120
Cadmium
ug/L
80
83.1
104
80-120
Calcium
ug/L
1000
978
98
80-120
Chromium
ug/L
80
85.4
107
80-120
Cobalt
ug/L
80
83.9
105
80-120
Copper
ug/L
80
87.1
109
80-120
Iron
ug/L
1000
1030
103
80-120
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/29/2015 02:22 PM without the written consent of Pace Analytical Services, Inc.. Page 52 of 67

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098oinyfte. Suite 100
y Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040239
Pace Project No.: 92245128
LABORATORY CONTROL SAMPLE:
1947520
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits
Qualifiers
Lead
ug/L
80
84.4
106
80-120
Magnesium
ug/L
1000
1010
101
80-120
Manganese
ug/L
80
82.3
103
80-120
Molybdenum
ug/L
80
81.4
102
80-120
Nickel
ug/L
80
84.8
106
80-120
Potassium
ug/L
1000
1050
105
80-120
Selenium
ug/L
80
81.5
102
80-120
Sodium
ug/L
1000
1060
106
80-120
Strontium
ug/L
80
80.6
101
80-120
Thallium
ug/L
80
84.9
106
80-120
Vanadium
ug/L
80
83.7
105
80-120
Zinc
ug/L
80
84.4
106
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1948832
1948833
MS
MSD
92245143004
Spike
Spike
MS
MSD
MS MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec % Rec
Limits
RPD
RPD Qual
Aluminum
ug/L
19200
400
400
25500
26600
1550
1840
75-125
4
20 M1
Antimony
ug/L
ND
400
400
420
414
105
103
75-125
1
20
Arsenic
ug/L
0.72J
400
400
402
407
100
102
75-125
1
20
Barium
ug/L
349
400
400
746
769
99
105
75-125
3
20
Beryllium
ug/L
ND
400
400
425
431
106
108
75-125
1
20
Boron
ug/L
42.6
400
400
488
485
111
111
75-125
1
20
Cadmium
ug/L
ND
400
400
429
428
107
107
75-125
0
20
Calcium
ug/L
12100
5000
5000
19500
20300
147
163
75-125
4
20 M1
Chromium
ug/L
24.7
400
400
459
465
108
110
75-125
1
20
Cobalt
ug/L
45.2
400
400
470
474
106
107
75-125
1
20
Copper
ug/L
260
400
400
741
765
120
126
75-125
3
20 M1
Iron
ug/L
29000
5000
5000
40700
42400
234
266
75-125
4
20 M1
Lead
ug/L
1.9
400
400
430
429
107
107
75-125
0
20
Magnesium
ug/L
9900
5000
5000
16900
17400
139
150
75-125
3
20 M1
Manganese
ug/L
643
400
400
1070
1110
106
116
75-125
4
20
Molybdenum
ug/L
0.501
400
400
410
416
102
104
75-125
1
20
Nickel
ug/L
22.5
400
400
455
459
108
109
75-125
1
20
Potassium
ug/L
1520
5000
5000
7010
7170
110
113
75-125
2
20
Selenium
ug/L
ND
400
400
416
419
104
105
75-125
1
20
Sodium
ug/L
6550
5000
5000
12300
12700
114
123
75-125
3
20
Strontium
ug/L
114
400
400
532
539
105
106
75-125
1
20
Thallium
ug/L
ND
400
400
432
433
108
108
75-125
0
20
Vanadium
ug/L
114
400
400
545
559
108
111
75-125
3
20
Zinc
ug/L
80.6
400
400
506
520
106
110
75-125
3
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/29/2015 02:22 PM without the written consent of Pace Analytical Services, Inc..
Page 53 of 67

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098mvfte. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040239
Pace Project No.: 92245128
QC Batch: PMST/3452
Analysis Method:
ASTM D2974-87
QC Batch Method: ASTM D2974-87
Analysis Description:
Dry Weight/Percent Moisture
Associated Lab Samples: 92245128003,
92245128004, 92245128005, 92245128006,
92245128007
SAMPLE DUPLICATE: 1185592
35183639002
Dup
Max
Parameter
Units
Result
Result RPD
RPD
Qualifiers
Percent Moisture
%
13.8
14.2 3
10
SAMPLE DUPLICATE: 1185593
92245092006
Dup
Max
Parameter
Units
Result
Result RPD
RPD
Qualifiers
Percent Moisture
%
15.8
16.1 2
10
SAMPLE DUPLICATE: 1185594
92245094007
Dup
Max
Parameter
Units
Result
Result RPD
RPD
Qualifiers
Percent Moisture
%
34.6
35.1 1
10
SAMPLE DUPLICATE: 1185595
92245118003
Dup
Max
Parameter
Units
Result
Result RPD
RPD
Qualifiers
Percent Moisture
%
38.1
38.1 0
10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/29/2015 02:22 PM without the written consent of Pace Analytical Services, Inc.. Page 54 of 67

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098oinyfte. Suite 100
y Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040239
Pace Project No.: 92245128
QC Batch: WET/36863 Analysis Method: EPA 9045
QC Batch Method: EPA 9045 Analysis Description: 9045 pH
Associated Lab Samples: 92245128003, 92245128004, 92245128005, 92245128006, 92245128007
SAMPLE DUPLICATE: 1436063
92245128003 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
pH at 25 Degrees C Std. Units 6.7 6.7 0 10
SAMPLE DUPLICATE: 1436064
Parameter
pH at 25 Degrees C
92245352003 Dup
Units Result Result
Std. Units 5.8 6.0
Max
RPD RPD Qualifiers
4 10 D6
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/29/2015 02:22 PM without the written consent of Pace Analytical Services, Inc.. Page 55 of 67

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098oinyfte. Suite 100
y Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040239
Pace Project No.: 92245128
QC Batch: WETA/22607
Analysis Method: EPA 300.0
QC Batch Method: EPA 300.0
Analysis Description: 300.0 IC Anions
Associated Lab Samples: 92245128003, 92245128004,
92245128005
METHOD BLANK: 1437291
Matrix: Water
Associated Lab Samples: 92245128003, 92245128004,
92245128005
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Sulfate mg/L
3.1 2.0
04/19/1512:14
LABORATORY CONTROL SAMPLE: 1437292
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Sulfate mg/L
20 18.9
94 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1437293 1437294
MS MSD
92244130003
Spike Spike MS
MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec Limits RPD RPD Qual
Sulfate mg/L 275
22.7 22.7 294
295 83 85 0
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1437295 1437296
MS MSD
92245087001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfate mg/L 4.0 26.6 26.6 26.5 26.2 85 83 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/29/2015 02:22 PM without the written consent of Pace Analytical Services, Inc..
Page 56 of 67

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098g"vfte. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040239
Pace Project No.: 92245128
QC Batch: WETA/22655
Analysis Method: EPA 353.2
QC Batch Method: EPA 353.2
Analysis Description: 353.2 Nitrate + Nitrite, Unpres.
Associated Lab Samples: 92245128003, 92245128004,
92245128005
METHOD BLANK: 1440999
Matrix: Water
Associated Lab Samples: 92245128003, 92245128004,
92245128005
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Nitrogen, Nitrate mg/L
0.16 0.020
04/22/15 17:09 Z2
LABORATORY CONTROL SAMPLE: 1441000
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Nitrogen, Nitrate mg/L
2.5 2.5
101 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1441001 1441002
MS MSD
92244130003
Spike Spike MS
MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec Limits RPD RPD Qual
Nitrogen, Nitrate mg/L ND
2.8 2.8 3.1
3.1 104 104 90-110 0 10 H1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1441003 1441004
MS MSD
92244130004 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Nitrogen, Nitrate mg/L ND 2.9 2.9 3.1 3.1 100 100 90-110 0 10 H1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/29/2015 02:22 PM without the written consent of Pace Analytical Services, Inc..
Page 57 of 67

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098oinyfte. Suite 100
y Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040239
Pace Project No.: 92245128
QC Batch: WETA/22603
Analysis Method: SM 4500-CI-E
QC Batch Method: SM 4500-CI-E
Analysis Description: 4500 Chloride
Associated Lab Samples: 92245128003, 92245128004,
92245128005
METHOD BLANK: 1437036
Matrix: Water
Associated Lab Samples: 92245128003, 92245128004,
92245128005
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Chloride mg/L
ND 1.0
04/17/15 05:27
LABORATORY CONTROL SAMPLE: 1437037
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Chloride mg/L
20 20.3
101 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1437038 1437039
MS MSD
92244130003
Spike Spike MS
MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec Limits RPD RPD Qual
Chloride mg/L ND
22.7 22.7 23.0
23.4 101 102 90-110 1 10
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1437040 1437041
MS MSD
92244130004 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Chloride mg/L ND 23.2 23.2 23.9 23.5 103 101 90-110 2 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/29/2015 02:22 PM without the written consent of Pace Analytical Services, Inc..
Page 58 of 67

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098oinyfte. Suite 100
y Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040239
Pace Project No.: 92245128
QC Batch: WETA/45424 Analysis Method: EPA 9056
QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions
Associated Lab Samples: 92245128003, 92245128004, 92245128005, 92245128006, 92245128007
METHOD BLANK: 1183723 Matrix: Solid
Associated Lab Samples:
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Chloride mg/kg ND 49.5 04/15/1513:47
Sulfate mg/kg ND 49.5 04/15/1513:47
LABORATORY CONTROL SAMPLE:
1183724
Parameter
Units
Chloride
mg/kg
Sulfate
mg/kg
MATRIX SPIKE SAMPLE:
1183726
Parameter
Units
Chloride
mg/kg
Sulfate
mg/kg
SAMPLE DUPLICATE: 1183725
Parameter
Chloride
Sulfate
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
502 471 94 80-120
502 472 94 80-120
92245084011 Spike MS MS % Rec
Result Conc. Result % Rec Limits Qualifiers
ND 662 584 68 80-120 M 1
ND 662 635 75 80-120 M 1
92245084011 Dup
Units Result Result
mg/kg ND ND
mg/kg ND ND
Max
RPD RPD Qualifiers
20
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/29/2015 02:22 PM without the written consent of Pace Analytical Services, Inc.. Page 59 of 67

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098onyfte. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040239
Pace Project No.: 92245128
QC Batch: WETA/45425
Analysis Method: EPA 9056
QC Batch Method: EPA 9056
Analysis Description: 9056 IC Anions
Associated Lab Samples: 92245128003, 92245128004, 92245128005, 92245128006, 92245128007
METHOD BLANK: 1183727
Matrix: Solid
Associated Lab Samples:
Blank Reporting
Parameter
Units
Result Limit Analyzed
Qualifiers
Nitrate as N
mg/kg
ND 5.0 04/15/15 13:47
LABORATORY CONTROL SAMPLE:
1183728
Spike LCS LCS
% Rec
Parameter
Units
Conc. Result % Rec
Limits
Qualifiers
Nitrate as N
mg/kg
50.2 48.8 97
80-120
MATRIX SPIKE SAMPLE:
1183730
92245084011 Spike MS
MS
% Rec
Parameter
Units
Result Conc. Result
% Rec
Limits Qualifiers
Nitrate as N
mg/kg
ND 331 54.3
16 80-120 H3,M1
SAMPLE DUPLICATE: 1183729
92245084011 Dup
Max
Parameter
Units
Result Result RPD
RPD
Qualifiers
Nitrate as N
mg/kg
ND ND
20 H3
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/29/2015 02:22 PM without the written consent of Pace Analytical Services, Inc.. Page 60 of 67

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098onlvfte. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040239
Pace Project No.: 92245128
QC Batch: WETA/28220
Analysis Method: EPA 9060
QC Batch Method: EPA 9060
Analysis Description: 9060 TOC Average
Associated Lab Samples: 92245128003, 92245128004,
92245128005, 92245128006, 92245128007
METHOD BLANK: 1147912
Matrix: Solid
Associated Lab Samples:
Blank Reporting
Parameter Units
Result Limit Analyzed Qualifiers
Mean Total Organic Carbon mg/kg
ND 600 04/28/15 08:25
LABORATORY CONTROL SAMPLE: 1147913
Spike LCS LCS % Rec
Parameter Units
Conc. Result % Rec Limits Qualifiers
Mean Total Organic Carbon mg/kg
120000 127000 105 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1147914 1147915
MS MSD
92245084005
Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Mean Total Organic Carbon mg/kg 87800
65000 64800 154000 138000 102 78 50-150 11 30
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1147916 1147917
MS MSD
92245128004 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Mean Total Organic Carbon mg/kg 3780 6660 6670 11400 11800 114 119 50-150 3 30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/29/2015 02:22 PM without the written consent of Pace Analytical Services, Inc..
Page 61 of 67

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098onyfte. Suite 100
Huntersville, NC 28078
[phone]
QUALIFIERS
Project: J15040239
Pace Project No.: 92245128
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
LABORATORIES
PASI-A
Pace Analytical Services - Asheville
PASI-G
Pace Analytical Services - Green Bay
PASI-M
Pace Analytical Services - Minneapolis
PASI-O
Pace Analytical Services - Ormond Beach
BATCH QUALIFIERS
Batch: ICPM/9631
Ill Batch was diluted due to the presence of high levels of non -target analytes or other matrix interference.
ANALYTE QUALIFIERS
B Analyte was detected in the associated method blank.
D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
D6 The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits.
H1 Analysis conducted outside the EPA method holding time.
H3 Sample was received or analysis requested beyond the recognized method holding time.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
N2 The lab does not hold TN accreditation for this parameter.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/29/2015 02:22 PM without the written consent of Pace Analytical Services, Inc.. Page 62 of 67

Pace Analytical Services, Inc
aceAnalXical ® � ��t��c&rr�ie. Suite100
Huntersville, INC 28078078
www.pacelabs.com [phone]
QUALIFIERS
Project: J15040239
Pace Project No.: 92245128
ANALYTE QUALIFIERS
P8 Analyte was detected in the method blank. All associated samples had concentrations of at least ten times greater than
the blank or were below the reporting limit.
R1 RPD value was outside control limits.
Z2 Analyte present in the associated method blank above the detection limit.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/29/2015 02:22 PM without the written consent of Pace Analytical Services, Inc.. Page 63 of 67

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098g i vfte. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
Pace Project No.:
J15040239
92245128
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92245128003
2015010252
EPA 3050
MPRP/23696
EPA 6010
ICP/14483
92245128004
2015010254
EPA 3050
MPRP/23696
EPA 6010
ICP/14483
92245128005
2015010255
EPA 3050
MPRP/23696
EPA 6010
ICP/14483
92245128006
2015010256
EPA 3050
MPRP/23696
EPA 6010
ICP/14483
92245128007
2015010257
EPA 3050
MPRP/23696
EPA 6010
ICP/14483
92245128003
2015010252
EPA 3050
MPRP/23697
EPA 6020
ICPM/9631
92245128004
2015010254
EPA 3050
MPRP/23697
EPA 6020
ICPM/9631
92245128005
2015010255
EPA 3050
MPRP/23697
EPA 6020
ICPM/9631
92245128006
2015010256
EPA 3050
MPRP/23697
EPA 6020
ICPM/9631
92245128007
2015010257
EPA 3050
MPRP/23697
EPA 6020
ICPM/9631
92245128001
2015010247
EPA 3020
MPRP/53618
EPA 6020A
ICPM/23802
92245128002
2015010253
EPA 3020
MPRP/53618
EPA 6020A
ICPM/23802
92245128008
2015010252 SPLP
EPA 3020
MPRP/53885
EPA 6020A
ICPM/23957
92245128009
2015010254 SPLP
EPA 3020
MPRP/53885
EPA 6020A
ICPM/23957
92245128010
2015010255 SPLP
EPA 3020
MPRP/53885
EPA 6020A
ICPM/23957
92245128001
2015010247
EPA 7470
MERP/13223
EPA 7470
MERC/15377
92245128002
2015010253
EPA 7470
MERP/13223
EPA 7470
MERC/15377
92245128008
2015010252 SPLP
EPA 7470A
MERP/13346
EPA 7470A
MERC/15521
92245128009
2015010254 SPLP
EPA 7470A
MERP/13346
EPA 7470A
MERC/15521
92245128010
2015010255 SPLP
EPA 7470A
MERP/13346
EPA 7470A
MERC/15521
92245128003
2015010252
EPA 7471
MERP/5604
EPA 7471
MERC/5594
92245128004
2015010254
EPA 7471
MERP/5604
EPA 7471
MERC/5594
92245128005
2015010255
EPA 7471
MERP/5604
EPA 7471
MERC/5594
92245128006
2015010256
EPA 7471
MERP/5604
EPA 7471
MERC/5594
92245128007
2015010257
EPA 7471
MERP/5604
EPA 7471
MERC/5594
92245128003
2015010252
ASTM D2974-87
PMST/3452
92245128004
2015010254
ASTM D2974-87
PMST/3452
92245128005
2015010255
ASTM D2974-87
PMST/3452
92245128006
2015010256
ASTM D2974-87
PMST/3452
92245128007
2015010257
ASTM D2974-87
PMST/3452
92245128003
2015010252
EPA 9045
WET/36863
92245128004
2015010254
EPA 9045
WET/36863
92245128005
2015010255
EPA 9045
WET/36863
92245128006
2015010256
EPA 9045
WET/36863
92245128007
2015010257
EPA 9045
WET/36863
92245128003
2015010252
EPA 300.0
WETA/22607
92245128004
2015010254
EPA 300.0
WETA/22607
92245128005
2015010255
EPA 300.0
WETA/22607
92245128003
2015010252
EPA 353.2
WETA/22655
92245128004
2015010254
EPA 353.2
WETA/22655
92245128005
2015010255
EPA 353.2
WETA/22655
92245128003
2015010252
SM 4500-CI-E
WETA/22603
92245128004
2015010254
SM 4500-CI-E
WETA/22603
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/29/2015 02:22 PM without the written consent of Pace Analytical Services, Inc.. Page 64 of 67

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098onyfte. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: J15040239
Pace Project No.: 92245128
Lab ID
Sample ID
QC Batch Method
QC Batch
92245128005
2015010255
SM 4500-CI-E
WETA/22603
92245128003
2015010252
EPA 9056
WETA/45424
92245128004
2015010254
EPA 9056
WETA/45424
92245128005
2015010255
EPA 9056
WETA/45424
92245128006
2015010256
EPA 9056
WETA/45424
92245128007
2015010257
EPA 9056
WETA/45424
92245128003
2015010252
EPA 9056
WETA/45425
92245128004
2015010254
EPA 9056
WETA/45425
92245128005
2015010255
EPA 9056
WETA/45425
92245128006
2015010256
EPA 9056
WETA/45425
92245128007
2015010257
EPA 9056
WETA/45425
92245128003
2015010252
EPA 9060
WETA/28220
92245128003
2015010252
EPA 9060
WETA/28221
92245128004
2015010254
EPA 9060
WETA/28220
92245128004
2015010254
EPA 9060
WETA/28221
92245128005
2015010255
EPA 9060
WETA/28220
92245128005
2015010255
EPA 9060
WETA/28221
92245128006
2015010256
EPA 9060
WETA/28220
92245128006
2015010256
EPA 9060
WETA/28221
92245128007
2015010257
EPA 9060
WETA/28220
92245128007
2015010257
EPA 9060
WETA/28221
Date: 04/29/2015 02:22 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Analytical Method
Analytical
Batch
Page 65 of 67

Document Name:
Document Revised: September 22. ZU14
ceAnal3ftal'
Sample
Condition Upon Receipt (SCUR)
Pa e 1 of 2
Issuing AiRhovit�6 of 78
Document Number:
F-CHR-CS-003-rev.15
Pace Huntersville Quality Office
Client Name: P (A
Courier: ❑ Fed Ex ❑ UPS❑ LISPS❑
Client❑ poyrmercialn ce Other
Custody Seal on Cooler/Box Present: ❑
yes no Seals intact: ❑ yes
❑ no
Packing Material: ❑ Bubble VDp Bubble Bags ❑ None ❑ Other
Thermometer Used: IR Gun 144Y
Type of Ice: et Blue None
Samples on ice, cooling process has begun
Temp Correction Factor T1 1 No Correction
'C
Biological Tissue is Frozen: Yes. No
A
ate and Initials of rs,9 exar�rining�
Corrected Cooler Temp.:
contents: 4
Temp should be above freezing to 6°C
Comments:
Chain of Custody Present:
es o ❑NIA 1.
Chain of Custody Filled Out:
Yes No ❑NIA 2.
Chain of Custody Relinquished:
Yes ❑ o ❑NIA 3.
Sampler Name & Signature on COC:
Samples Arrived within Hold Time:
Short Hold Time Analysis (a72hr):
s o
es El No
❑Yes o
❑NIA 4.
NIA 5.
❑ 6.
Rush Turn Around Time Requested:
❑Yes o
❑NIA 7.
Sufficient Volume:
0463NO
❑NIA 8.
Correct Containers Used:
Yes ❑No
IA 9.
-Pace Containers Used:
❑Yes -
❑NIA
Containers intact:
GWe. ❑No
❑NIA 10
Filtered volume received for Dissolved tests
❑Yes
A 11.
Sample Labels match COC:
Dles ONO
ONrA 12.
-Includes date/time/ID/Analysis Matrix:
All containers needing preservation have been checked.
es
❑NIA 13.
All containers needing preservation are found to be in
DYe' S ❑No
❑NIA
compliance with EPA recommendation.
❑Yes rvo
exceptions: VOA, coliform, TOC, O&G, W-DR0 (water)
Samples checked for dechlorination:
❑Yes ❑No
NIA
Headspace in VOA Vials (>6mm):
[]Yes ONO
IA
Trip Blank Present: ❑Yes ❑No I 16.
Trip Blank Custody Seals Present ❑Yes ONO NIA
Pace Trip Blank Lot # (if purchased):
Client Notification/ Resolution: Field Data Required? Y 1 N
Person Contacted: DatelTime:
Comments/ Resolution:
SCURF Review: Date:
SRF Review: Date: i3 t
Note: Whenever there is a discrepancy affecting North Carolina compliance
samples, a copy of this form will be sent to the North Carolina DEHNR
Certification Office ( 1.e out of hold, incorrect preservative, out of temp,
incorrect containers)
WOp:92245128
1111111111111111111111111
92245128
Page 66 of 67

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