NC0003433_J15040079 Report_20150902

DUE Analytical Laboratory Page 1of95
' ENERGY
Order Number:
Project Name:
Customer Name(s):
Customer Address:
Lab Contact:
Report Authorized By:
(Signature)
Program Comments:
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone:[phone] Fax:[phone]
Order Summary Report
J15040079
CAPE FEAR - AB GW ASSESSMENT SOIL
Tim Hunsucker, Chris Suttell, Kathy Webb, John Toepfer
Margaret Galvin -Karr
Margaret Galvin -Karr
MXG4644(101161)
2015.05.1810:19:53
-04'00'
Phone: [phone]
Date:
Please contact the Program Manager (Margaret Galvin -Karr) with any questions regarding this report.
Data Flags & Calculations:
5/6/2015
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Sample ID's & Descriptions:
Collection
Sample ID Plant/Station Date and Time
Collected By
Sample Description
Page 2 of 95
2015009505
Cape Fear
30-Mar-15 3:35 PM
Chris S.
Well ERB-12 (Sonic)
2015009506
Cape Fear
30-Mar-15 4:20 PM
Chris S.
Well B-N1963 (0-2)
2015009507
Cape Fear
30-Mar-15 4:40 PM
Chris S.
Well B-N1963 (14-16)
2015009508
Cape Fear
30-Mar-15 4:50 PM
Chris S.
Well B-N1963 (22-24)
2015009509
Cape Fear
30-Mar-15 5:00 PM
Chris S.
Well B-N1963 (28-30)
2015009510
Cape Fear
01-Apr-15 9:35 AM
Chris S.
Well ERB-13 (Sonic)
2015009511
Cape Fear
01-Apr-15 2:36 PM
Chris S.
Well MW-15 SB (0-2)
2015009512
Cape Fear
01-Apr-15 4:00 PM
Chris S.
Well MW-15 SB (7-9)
2015009513
Cape Fear
01-Apr-15 4:30 PM
Chris S.
Well MW-15 SB (18-19)
9 Total Samples

Page 3 of 95
Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals Yes No
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits. ❑ Yes No
All laboratory QA/QC requirements are acceptable. (] Yes ❑ No
Report Sections Included:
L� Job Summary Report
❑ Sample Identification
n Technical Validation of Data Package
6 Analytical Laboratory Certificate of Analysis
❑ Analytical Laboratory QC Report
L-1 Sub -contracted Laboratory Results
❑ Customer Specific Data Sheets, Reports, & Documentation
❑ Customer Database Entries
6 Chain of Custody
LVI Electronic Data Deliverable (EDD) Sent Separately
Reviewed By: DBA Account Date: 5/6/2015

Certificate of Laboratory Analysis Page 4 of 95
This report shall not be reproduced, except in full.
Order # J15040079
Site: Well ERB-12 (Sonic)
Collection Date: 30-Mar-15 3:35 PM
Analyte Result Units Qualifiers RDL DF
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Sample #: 2015009505
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15040079
Site: Well B-N1963 (0-2)
Collection Date: 30-Mar-15 4:20 PM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
SPLP LEACHATE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Page 5 of 95
Sample #: 2015009506
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15040079
Site: Well B-N1963 (14-16)
Collection Date: 30-Mar-15 4:40 PM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
SPLP LEACHATE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Page 6 of 95
Sample #: 2015009507
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15040079
Site: Well B-N1963 (22-24)
Collection Date: 30-Mar-15 4:50 PM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
SPLP LEACHATE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Page 7 of 95
Sample #: 2015009508
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15040079
Site: Well B-N1963 (28-30)
Collection Date: 30-Mar-15 5:00 PM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Page 8 of 95
Sample #: 2015009509
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis Page 9 of 95
This report shall not be reproduced, except in full.
Order # J15040079
Site: Well ERB-13 (Sonic)
Collection Date: 01-Apr-15 9:35 AM
Analyte Result Units Qualifiers RDL DF
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Sample #: 2015009510
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15040079
Site: Well MW-15 SIB (0-2)
Collection Date: 01-Apr-15 2:36 PM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
SPLP LEACHATE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Page 10 of 95
Sample #: 2015009511
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15040079
Site: Well MW-15 SIB (7-9)
Collection Date: 01-Apr-15 4:00 PM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
SPLP LEACHATE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Page 11 of 95
Sample #: 2015009512
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15040079
Site: Well MW-15 SIB (18-19)
Collection Date: 01-Apr-15 4:30 PM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
SPLP LEACHATE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Page 12 of 95
Sample #: 2015009513
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
Suite 100
y Huntersville, INC 28078
[phone]
April 27, 2015
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg.7405 MG30A2
Huntersville, NC 28078
RE: Project: J 15040079
Pace Project No.: 92244130
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on April 06, 2015. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TN standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc: Marge Galvin -Karr, Duke Energy
Program Manager, Duke Energy
Rodney Wilke, Duke Energy
p«FO
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
lqe� ��� without the written consent of Pace Analytical Services, Inc..
BRAT,
Page 1 of 82

lacmnalyfica(
www.pacelabs.com
Pace Analytical Services, Inc.
OQ9iiii$c8fd4ge. Suite 100
Huntersville, NC 28078
[phone]
Project: J15040079
Pace Project No.: 92244130
Minnesota Certification IDs
1700 Elm Street SE Suite 200, Minneapolis, MN 55414
A21-A Certification #: 2926.01
Alaska Certification #: UST-078
Alaska Certification #MN00064
Alabama Certification #40770
Arizona Certification #: AZ-0014
Arkansas Certification #: 88-0680
California Certification #: 01155CA
Colorado Certification #Pace
Connecticut Certification #: PH-0256
EPA Region 8 Certification #: 8TMS-L
Florida/NELAP Certification #: E87605
Guam Certification #:14-008r
Georgia Certification #: 959
Georgia EPD #: Pace
Idaho Certification #: MN00064
Hawaii Certification #MN00064
Illinois Certification #: 200011
Indiana Certification#C-MN-01
Iowa Certification #: 368
Kansas Certification #: E-10167
Kentucky Dept of Envi. Protection - DW #90062
Kentucky Dept of Envi. Protection - WW #:90062
Louisiana DEQ Certification #: 3086
Louisiana DHH #: LA140001
Maine Certification #: 2013011
Maryland Certification #: 322
Michigan DEPH Certification #: 9909
Ormond Beach Certification IDs
8 East Tower Circle, Ormond Beach, FL 32174
Alabama Certification #: 41320
Connecticut Certification #: PH-0216
Delaware Certification: FL NELAC Reciprocity
Florida Certification #: E83079
Georgia Certification #: 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification #: 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383
Kentucky Certification #: 90050
Louisiana Certification #: FL NELAC Reciprocity
Louisiana Environmental Certificate #: 05007
Maryland Certification: #346
Massachusetts Certification #: M-FL1264
Michigan Certification #: 9911
Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236
Green Bay Certification IDs
1241 Bellevue Street, Green Bay, WI 54302
Florida/NELAP Certification #: E87948
Illinois Certification #: 200050
Kentucky Certification #: 82
Louisiana Certification #: 04168
Minnesota Certification #: 055-999-334
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
CERTIFICATIONS
Minnesota Certification #: 027-053-137
Mississippi Certification #: Pace
Montana Certification #: MT0092
Nevada Certification #: MN_00064
Nebraska Certification #: Pace
New Jersey Certification #: MN-002
New York Certification #: 11647
North Carolina Certification #: 530
North Carolina State Public Health #: 27700
North Dakota Certification #: R-036
Ohio EPA#: 4150
Ohio VAP Certification #: CL101
Oklahoma Certification #: 9507
Oregon Certification #: MN200001
Oregon Certification #: MN300001
Pennsylvania Certification #: 68-00563
Puerto Rico Certification
Saipan (CNMI) #:MP0003
South Carolina #:74003001
Texas Certification #: T104704192
Tennessee Certification #: 02818
Utah Certification #: MN000642013-4
Virginia DGS Certification #: 251
Virginia/VELAP Certification #: Pace
Washington Certification #: C486
West Virginia Certification #: 382
West Virginia DHHR #:9952C
Wisconsin Certification #: 999407970
Montana Certification #: Cert 0074
Nebraska Certification: NE-OS-28-14
Nevada Certification: FL NELAC Reciprocity
New Hampshire Certification #: 2958
New Jersey Certification #: FL765
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FLO1264
South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
Washington Certification #: C955
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
North Dakota Certification #: R-150
South Carolina Certification #: 83006001
Texas Certification #: T104704529-14-1
US Dept of Agriculture #: S-76505
Wisconsin Certification #: 405132750
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 2 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
Suite 100
y Huntersville, NC 28078
[phone]
Project: J15040079
Pace Project No.: 92244130
Asheville Certification IDs
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
CERTIFICATIONS
West Virginia Certification #: 356
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 3 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
Suite 100
y Huntersville, NC 28078
[phone]
SAMPLE SUMMARY
Project: J15040079
Pace Project No.: 92244130
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92244130001
201509505
Water
03/30/1515:35
04/06/15 14:32
92244130002
201509510
Water
04/01/15 09:35
04/06/15 14:32
92244130003
201509506
Solid
03/30/1516:20
04/06/15 14:32
92244130004
201509507
Solid
03/30/1516:40
04/06/15 14:32
92244130005
201509508
Solid
03/30/1516:50
04/06/15 14:32
92244130006
201509511
Solid
04/01/1514:36
04/06/15 14:32
92244130007
201509512
Solid
04/01/1516:00
04/06/15 14:32
92244130008
201509513
Solid
04/01/1516:30
04/06/15 14:32
92244130009
201509509
Solid
03/30/1517:00
04/06/15 14:32
92244130010
201509506 SPLP
Water
04/01/15 16:20
04/06/15 14:32
92244130011
201509507 SPLP
Water
03/30/15 16:40
04/06/15 14:32
92244130012
201509508 SPLP
Water
03/30/15 16:50
04/06/15 14:32
92244130013
201509511 SPLP
Water
04/01/15 14:36
04/06/15 14:32
92244130014
201509512 SPLP
Water
04/01/15 16:00
04/06/15 14:32
92244130015
201509513 SPLP
Water
04/01/15 16:30
04/06/15 14:32
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 4 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
Suite 100
y Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
J15040079
92244130
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92244130001
201509505
EPA 6020A
RJS
24
PASI-M
EPA 7470
DM
1
PASI-M
92244130002
201509510
EPA 6020A
RJS
24
PASI-M
EPA 7470
DM
1
PASI-M
92244130003
201509506
EPA 6010
CKJ
16
PASI-0
EPA 6020
DRS
8
PASI-O
EPA 7471
CKJ
1
PASI-O
ASTM D2974-87
AIS
1
PASI-O
EPA 9045
MLS
1
PASI-A
EPA 300.0
AES2
1
PASI-A
EPA 353.2
DMN
1
PASI-A
SM 4500-CI-E
SER
1
PASI-A
EPA 9056
AIS, CMB
2
PASI-O
EPA 9056
AIS
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92244130004
201509507
EPA 6010
CKJ
16
PASI-0
EPA 6020
DRS
8
PASI-O
EPA 7471
CKJ
1
PASI-O
ASTM D2974-87
AIS
1
PASI-O
EPA 9045
MLS
1
PASI-A
EPA 300.0
AES2
1
PASI-A
EPA 353.2
DMN
1
PASI-A
SM 4500-CI-E
SER
1
PASI-A
EPA 9056
AIS
2
PASI-O
EPA 9056
AIS
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92244130005
201509508
EPA 6010
CKJ
16
PASI-0
EPA 6020
DRS
8
PASI-O
EPA 7471
CKJ
1
PASI-O
ASTM D2974-87
AIS
1
PASI-O
EPA 9045
MLS
1
PASI-A
EPA 300.0
AES2
1
PASI-A
EPA 353.2
DMN
1
PASI-A
SM 4500-CI-E
SER
1
PASI-A
EPA 9056
AIS
2
PASI-O
EPA 9056
AIS
1
PASI-O
EPA 9060
TJJ
6
PASI-G
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 5 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
�Q�ffligc&� �e. Suite 100
y Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
J15040079
92244130
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92244130006
201509511
EPA 6010
CKJ
16
PASI-0
EPA 6020
DRS
8
PASI-O
EPA 7471
CKJ
1
PASI-O
ASTM D2974-87
AIS
1
PASI-O
EPA 9045
MLS
1
PASI-A
EPA 300.0
AES2
1
PASI-A
EPA 353.2
DMN
1
PASI-A
SM 4500-CI-E
SER
1
PASI-A
EPA 9056
AIS
2
PASI-O
EPA 9056
AIS
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92244130007
201509512
EPA 6010
TAP
16
PASI-0
EPA 6020
DRS
8
PASI-O
EPA 7471
CKJ
1
PASI-O
ASTM D2974-87
AIS
1
PASI-O
EPA 9045
MLS
1
PASI-A
EPA 300.0
AES2
1
PASI-A
EPA 353.2
DMN
1
PASI-A
SM 4500-CI-E
SER
1
PASI-A
EPA 9056
AIS
2
PASI-O
EPA 9056
AIS
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92244130008
201509513
EPA 6010
TAP
16
PASI-0
EPA 6020
DRS
8
PASI-O
EPA 7471
CKJ
1
PASI-O
ASTM D2974-87
AIS
1
PASI-O
EPA 9045
MLS
1
PASI-A
EPA 300.0
AES2
1
PASI-A
EPA 353.2
DMN
1
PASI-A
SM 4500-CI-E
SER
1
PASI-A
EPA 9056
AIS
2
PASI-O
EPA 9056
AIS
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92244130009
201509509
EPA 6010
TAP
16
PASI-0
EPA 6020
DRS
8
PASI-O
EPA 7471
CKJ
1
PASI-O
ASTM D2974-87
AIS
1
PASI-O
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 6 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
Suite 100
y Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project: J15040079
Pace Project No.: 92244130
Lab ID
Sample ID
Method
Analysts
Analytes
Reported
Laboratory
EPA 9045
MLS
1
PASI-A
EPA 9056
AIS
2
PASI-O
EPA 9056
AIS
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92244130010
201509506 SPLP
EPA 6020A
TT3
24
PASI-M
EPA 7470A
LMW
1
PASI-M
92244130011
201509507 SPLP
EPA 6020A
TT3
24
PASI-M
EPA 7470A
LMW
1
PASI-M
92244130012
201509508 SPLP
EPA 6020A
TT3
24
PASI-M
EPA 7470A
LMW
1
PASI-M
92244130013
201509511 SPLP
EPA 6020A
TT3
24
PASI-M
EPA 7470A
LMW
1
PASI-M
92244130014
201509512 SPLP
EPA 6020A
TT3
24
PASI-M
EPA 7470A
LMW
1
PASI-M
92244130015
201509513 SPLP
EPA 6020A
TT3
24
PASI-M
EPA 7470A
LMW
1
PASI-M
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 7 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098g i vfte. Suite 100
Huntersville, NC 28078
[phone]
Project: J15040079
Pace Project No.: 92244130
Lab Sample ID Client Sample ID
Method Parameters
SUMMARY OF DETECTION
Result Units Report Limit Analyzed
92244130001
201509505
EPA 6020A
Aluminum
68.6
ug/L
10.0
04/13/15 16:03
EPA 6020A
Barium
0.73
ug/L
0.30
04/13/15 16:03
EPA 6020A
Calcium
278
ug/L
40.0
04/13/15 16:03
EPA 6020A
Chromium
1.0
ug/L
0.50
04/13/15 16:03
EPA 6020A
Iron
618
ug/L
50.0
04/13/15 16:03
EPA 6020A
Lead
0.19
ug/L
0.10
04/13/15 16:03
EPA 6020A
Magnesium
32.1
ug/L
10.0
04/13/15 16:03
EPA 6020A
Manganese
14.0
ug/L
0.50
04/13/15 16:03
EPA 6020A
Nickel
0.73
ug/L
0.50
04/13/15 16:03
EPA 6020A
Sodium
59.6
ug/L
50.0
04/13/15 16:03
EPA 6020A
Strontium
2.5
ug/L
0.50
04/13/15 16:03
92244130002
201509510
EPA 6020A
Aluminum
44.1
ug/L
10.0
04/13/15 16:08
EPA 6020A
Barium
1.3
ug/L
0.30
04/13/15 16:08
EPA 6020A
Calcium
329
ug/L
40.0
04/13/15 16:08
EPA 6020A
Chromium
0.55
ug/L
0.50
04/13/15 16:08
EPA 6020A
Cobalt
0.68
ug/L
0.50
04/13/15 16:08
EPA 6020A
Iron
345
ug/L
50.0
04/13/15 16:08
EPA 6020A
Lead
0.19
ug/L
0.10
04/13/15 16:08
EPA 6020A
Magnesium
18.7
ug/L
10.0
04/13/15 16:08
EPA 6020A
Manganese
7.0
ug/L
0.50
04/13/15 16:08
EPA 6020A
Potassium
51.4
ug/L
50.0
04/13/15 16:08
EPA 6020A
Strontium
1.6
ug/L
0.50
04/13/15 16:08
92244130003
201509506
EPA 6010
Aluminum
1920
mg/kg
28.3
04/15/15 08:56
EPA 6010
Barium
47.8
mg/kg
2.8
04/15/15 08:56
EPA 6010
Boron
40.0
mg/kg
14.1
04/15/15 08:56
EPA 6010
Calcium
3400
mg/kg
141
04/15/15 08:56
EPA 6010
Chromium
9.3
mg/kg
1.4
04/15/15 08:56
EPA 6010
Copper
19.0
mg/kg
1.4
04/15/15 08:56
EPA 6010
Iron
50400
mg/kg
11.3
04/15/15 08:56
EPA 6010
Magnesium
1170
mg/kg
141
04/15/15 08:56
EPA 6010
Manganese
68.8
mg/kg
1.4
04/15/15 08:56
EPA 6010
Molybdenum
1.7J
mg/kg
2.8
04/15/15 08:56
EPA 6010
Nickel
3.9
mg/kg
1.4
04/15/15 08:56
EPA 6010
Potassium
750
mg/kg
283
04/15/15 08:56
EPA 6010
Strontium
20.2
mg/kg
2.8
04/15/15 08:56
EPA 6010
Zinc
10.3
mg/kg
5.7
04/15/15 08:56
EPA 6020
Arsenic
118
mg/kg
2.8
04/16/15 22:09
EPA 6020
Cobalt
2.1J
mg/kg
2.8
04/16/15 22:09
EPA 6020
Lead
42.1
mg/kg
5.7
04/20/15 10:28
EPA 6020
Selenium
4.7
mg/kg
2.8
04/16/15 22:09
EPA 6020
Vanadium
24.9
mg/kg
2.8
04/16/15 22:09
EPA 7471
Mercury
0.13
mg/kg
0.0087
04/14/15 13:20
ASTM D2974-87
Percent Moisture
11.8
%
0.10
04/14/15 12:20
EPA 9045
pH at 25 Degrees C
3.2
Std. Units
0.10
04/13/15 23:00
REPORT OF LABORATORY ANALYSIS
D3
D3
D3
D3
D3
D3
D3
D3
D3
D3
D3
D3
D3
D3
0.
Qualifiers
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 8 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098gKinvfte. Suite 100
Huntersville, NC 28078
[phone]
Project: J15040079
Pace Project No.: 92244130
Lab Sample ID Client Sample ID
Method Parameters
SUMMARY OF DETECTION
Result Units Report Limit Analyzed
92244130003
201509506
EPA 300.0
Sulfate
275
mg/L
22.7
04/19/15 12:42
B
EPA 9056
Sulfate
5650
mg/kg
1150
04/10/15 14:27
EPA 9060
Total Organic Carbon
164000
mg/kg
4310
04/22/15 16:46
EPA 9060
Total Organic Carbon
148000
mg/kg
4480
04/22/15 16:52
EPA 9060
Total Organic Carbon
168000
mg/kg
4450
04/22/15 16:57
EPA 9060
Total Organic Carbon
167000
mg/kg
4320
04/22/15 17:04
EPA 9060
Mean Total Organic Carbon
162000
mg/kg
4390
04/22/15 16:46
EPA 9060
RSD%
5.6
%
04/22/15 16:46
92244130004
201509507
EPA 6010
Aluminum
4580
mg/kg
29.0
04/15/15 09:00
D3
EPA 6010
Barium
374
mg/kg
2.9
04/15/15 09:00
D3
EPA 6010
Beryllium
1.2
mg/kg
0.29
04/15/15 09:00
D3
EPA 6010
Boron
19.6
mg/kg
14.5
04/15/15 09:00
D3
EPA 6010
Calcium
873
mg/kg
145
04/15/15 09:00
D3
EPA 6010
Chromium
7.6
mg/kg
1.4
04/15/15 09:00
D3
EPA 6010
Copper
14.3
mg/kg
1.4
04/15/15 09:00
D3
EPA 6010
Iron
16600
mg/kg
11.6
04/15/15 09:00
D3
EPA 6010
Magnesium
449
mg/kg
145
04/15/15 09:00
D3
EPA 6010
Manganese
106
mg/kg
1.4
04/15/15 09:00
D3
EPA 6010
Nickel
17.3
mg/kg
1.4
04/15/15 09:00
D3
EPA 6010
Potassium
468
mg/kg
290
04/15/15 09:00
D3
EPA 6010
Strontium
107
mg/kg
2.9
04/15/15 09:00
D3
EPA 6010
Zinc
27.3
mg/kg
5.8
04/15/15 09:00
D3
EPA 6020
Arsenic
13.1
mg/kg
2.9
04/16/15 22:11
EPA 6020
Cobalt
6.3
mg/kg
2.9
04/16/15 22:11
EPA 6020
Lead
2.9J
mg/kg
5.8
04/20/15 10:30
EPA 6020
Selenium
4.2
mg/kg
2.9
04/16/15 22:11
EPA 6020
Vanadium
13.4
mg/kg
2.9
04/16/15 22:11
EPA 7471
Mercury
0.017
mg/kg
0.0089
04/14/15 13:22
ASTM D2974-87
Percent Moisture
13.8
%
0.10
04/14/15 12:24
EPA 9045
pH at 25 Degrees C
3.5
Std. Units
0.10
04/13/15 23:00
EPA 300.0
Sulfate
173
mg/L
11.6
04/19/15 13:22
EPA 9056
Sulfate
3330
mg/kg
291
04/10/15 03:14
EPA 9060
Total Organic Carbon
28800
mg/kg
4970
04/22/15 17:09
EPA 9060
Total Organic Carbon
28000
mg/kg
4940
04/22/15 17:16
EPA 9060
Total Organic Carbon
27400
mg/kg
4970
04/22/15 17:22
EPA 9060
Total Organic Carbon
27800
mg/kg
4960
04/22/15 17:30
EPA 9060
Mean Total Organic Carbon
28000
mg/kg
4960
04/22/15 17:09
EPA 9060
RSD%
2.1
%
04/22/15 17:09
92244130005
201509508
EPA 6010
Aluminum
4830
mg/kg
28.8
04/15/15 09:05
D3
EPA 6010
Barium
47.5
mg/kg
2.9
04/15/15 09:05
D3
EPA 6010
Beryllium
0.37
mg/kg
0.29
04/15/15 09:05
D3
EPA 6010
Calcium
180
mg/kg
144
04/15/15 09:05
D3
EPA 6010
Chromium
6.9
mg/kg
1.4
04/15/15 09:05
D3
EPA 6010
Copper
4.9
mg/kg
1.4
04/15/15 09:05
D3
REPORT OF LABORATORY ANALYSIS
Qualifiers
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 9 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098gKinyfte. Suite 100
Huntersville, NC 28078
[phone]
Project: J15040079
Pace Project No.: 92244130
Lab Sample ID Client Sample ID
Method Parameters
SUMMARY OF DETECTION
Result Units Report Limit Analyzed
92244130005
201509508
EPA 6010
Iron
8660
mg/kg
11.5
04/15/15 09:05
EPA 6010
Magnesium
402
mg/kg
144
04/15/15 09:05
EPA 6010
Manganese
596
mg/kg
1.4
04/15/15 09:05
EPA 6010
Nickel
3.1
mg/kg
1.4
04/15/15 09:05
EPA 6010
Strontium
3.0
mg/kg
2.9
04/15/15 09:05
EPA 6010
Zinc
9.5
mg/kg
5.8
04/15/15 09:05
EPA 6020
Cobalt
9.8
mg/kg
2.9
04/16/15 22:14
EPA 6020
Lead
6.9
mg/kg
5.8
04/20/15 10:33
EPA 6020
Vanadium
18.7
mg/kg
2.9
04/16/15 22:14
EPA 7471
Mercury
0.013
mg/kg
0.0094
04/14/15 13:24
ASTM D2974-87
Percent Moisture
13.5
%
0.10
04/14/15 12:25
EPA 9045
pH at 25 Degrees C
5.5
Std. Units
0.10
04/13/15 23:00
EPA 300.0
Sulfate
7.2
mg/L
2.3
04/19/15 13:36
EPA 353.2
Nitrogen, Nitrate
0.24
mg/L
0.23
04/22/15 17:27
EPA 9060
Total Organic Carbon
2240
mg/kg
697
04/22/15 17:48
EPA 9060
Total Organic Carbon
2330
mg/kg
698
04/22/15 17:54
EPA 9060
Total Organic Carbon
2060
mg/kg
691
04/22/15 17:59
EPA 9060
Total Organic Carbon
1910
mg/kg
699
04/22/15 18:05
EPA 9060
Mean Total Organic Carbon
2130
mg/kg
696
04/22/15 17:48
EPA 9060
RSD%
8.9
%
04/22/15 17:48
92244130006
201509511
EPA 6010
Aluminum
9980
mg/kg
29.2
04/15/15 09:09
EPA 6010
Barium
64.9
mg/kg
2.9
04/15/15 09:09
EPA 6010
Beryllium
0.60
mg/kg
0.29
04/15/15 09:09
EPA 6010
Boron
18.2
mg/kg
14.6
04/15/15 09:09
EPA 6010
Calcium
1120
mg/kg
146
04/15/15 09:09
EPA 6010
Chromium
15.2
mg/kg
1.5
04/15/15 09:09
EPA 6010
Copper
11.4
mg/kg
1.5
04/15/15 09:09
EPA 6010
Iron
24100
mg/kg
11.7
04/15/15 09:09
EPA 6010
Magnesium
2170
mg/kg
146
04/15/15 09:09
EPA 6010
Manganese
367
mg/kg
1.5
04/15/15 09:09
EPA 6010
Nickel
8.8
mg/kg
1.5
04/15/15 09:09
EPA 6010
Sodium
177J
mg/kg
292
04/15/15 09:09
EPA 6010
Strontium
15.9
mg/kg
2.9
04/15/15 09:09
EPA 6010
Zinc
32.8
mg/kg
5.8
04/15/15 09:09
EPA 6020
Cobalt
6.4
mg/kg
5.8
04/20/15 10:35
EPA 6020
Lead
8.5
mg/kg
5.8
04/20/15 10:35
EPA 6020
Vanadium
55.1
mg/kg
5.8
04/20/15 10:35
EPA 7471
Mercury
0.019
mg/kg
0.010
04/14/15 13:26
ASTM D2974-87
Percent Moisture
18.3
%
0.10
04/14/15 12:27
EPA 9045
pH at 25 Degrees C
5.2
Std. Units
0.10
04/13/15 23:00
EPA 300.0
Sulfate
36.6
mg/L
2.4
04/19/15 13:50
EPA 9056
Sulfate
539
mg/kg
307
04/10/15 03:57
EPA 9060
Total Organic Carbon
1340
mg/kg
735
04/22/15 18:12
EPA 9060
Total Organic Carbon
1680
mg/kg
731
04/22/15 18:18
EPA 9060
Total Organic Carbon
1580
mg/kg
733
04/22/15 18:24
EPA 9060
Total Organic Carbon
1530
mg/kg
731
04/22/15 18:30
REPORT OF LABORATORY ANALYSIS
D3
D3
D3
D3
D3
D3
B
H1
D3
D3
D3
D3
D3
D3
D3
D3
D3
D3
D3
D3
D3
D3
Qualifiers
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 10 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098gKinyfte. Suite 100
Huntersville, NC 28078
[phone]
Project: J15040079
Pace Project No.: 92244130
Lab Sample ID Client Sample ID
Method Parameters
SUMMARY OF DETECTION
Result Units Report Limit Analyzed Qualifiers
92244130006
201509511
EPA 9060
Mean Total Organic Carbon
1530
mg/kg
732
04/22/15 18:12
EPA 9060
RSD%
9.2
%
04/22/15 18:12
92244130007
201509512
EPA 6010
Aluminum
13900
mg/kg
28.5
04/16/15 08:45
EPA 6010
Barium
189
mg/kg
2.8
04/16/15 08:45
EPA 6010
Beryllium
0.44
mg/kg
0.28
04/16/15 08:45
EPA 6010
Boron
13.2J
mg/kg
14.2
04/16/15 08:45
EPA 6010
Calcium
1770
mg/kg
142
04/16/15 08:45
EPA 6010
Chromium
20.9
mg/kg
1.4
04/16/15 08:45
EPA 6010
Copper
12.0
mg/kg
1.4
04/16/15 08:45
EPA 6010
Iron
11400
mg/kg
11.4
04/16/15 08:45
EPA 6010
Magnesium
3730
mg/kg
142
04/16/15 08:45
EPA 6010
Manganese
116
mg/kg
1.4
04/16/15 08:45
EPA 6010
Nickel
8.8
mg/kg
1.4
04/16/15 08:45
EPA 6010
Potassium
426
mg/kg
285
04/16/15 08:45
EPA 6010
Sodium
709
mg/kg
285
04/16/15 08:45
EPA 6010
Strontium
27.6
mg/kg
2.8
04/16/15 08:45
EPA 6010
Zinc
32.4
mg/kg
5.7
04/16/15 08:45
EPA 6020
Cobalt
3AJ
mg/kg
5.7
04/20/15 10:37
EPA 6020
Lead
6.2
mg/kg
5.7
04/20/15 10:37
EPA 6020
Vanadium
22.3
mg/kg
5.7
04/20/15 10:37
EPA 7471
Mercury
0.042
mg/kg
0.0096
04/14/15 13:29
ASTM D2974-87
Percent Moisture
16.6
%
0.10
04/14/15 12:28
EPA 9045
pH at 25 Degrees C
8.1
Std. Units
0.10
04/13/15 16:20
EPA 300.0
Sulfate
14.3
mg/L
2.4
04/19/15 14:03 B
EPA353.2
Nitrogen, Nitrate
0.29
mg/L
0.24
04/22/1517:29 H1
SM 4500-CI-E
Chloride
3.2J
mg/L
6.0
04/17/15 05:36
EPA 9056
Sulfate
233J
mg/kg
296
04/10/15 04:18
EPA 9060
Total Organic Carbon
850
mg/kg
725
04/22/15 18:37
EPA 9060
Total Organic Carbon
871
mg/kg
724
04/22/15 18:42
EPA 9060
Total Organic Carbon
858
mg/kg
713
04/22/15 18:47
EPA 9060
Total Organic Carbon
915
mg/kg
715
04/22/15 18:53
EPA 9060
Mean Total Organic Carbon
873
mg/kg
719
04/22/15 18:37
EPA 9060
RSD%
3.3
%
04/22/15 18:37
92244130008
201509513
EPA 6010
Aluminum
5500
mg/kg
29.2
04/16/15 08:49
EPA 6010
Barium
41.3
mg/kg
2.9
04/16/15 08:49
EPA 6010
Beryllium
0.27J
mg/kg
0.29
04/16/15 08:49
EPA 6010
Boron
15.5
mg/kg
14.6
04/16/15 08:49
EPA 6010
Calcium
496
mg/kg
146
04/16/15 08:49
EPA 6010
Chromium
6.0
mg/kg
1.5
04/16/15 08:49
EPA 6010
Copper
6.6
mg/kg
1.5
04/16/15 08:49
EPA 6010
Iron
13500
mg/kg
11.7
04/16/15 08:49
EPA 6010
Magnesium
1240
mg/kg
146
04/16/15 08:49
EPA 6010
Manganese
614
mg/kg
1.5
04/16/15 08:49
EPA 6010
Nickel
4.4
mg/kg
1.5
04/16/15 08:49
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 11 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098gK4-8y fe. Suite 100
Huntersville, NC 28078
[phone]
Project: J15040079
Pace Project No.: 92244130
Lab Sample ID Client Sample ID
Method Parameters
SUMMARY OF DETECTION
Result Units Report Limit Analyzed
92244130008
201509513
EPA 6010
Potassium
322
mg/kg
292
04/16/15 08:49
EPA 6010
Strontium
6.5
mg/kg
2.9
04/16/15 08:49
EPA 6010
Zinc
15.7
mg/kg
5.8
04/16/15 08:49
EPA 6020
Cobalt
5.2
mg/kg
2.9
04/16/15 22:20
EPA 6020
Lead
4.9J
mg/kg
5.8
04/20/15 10:46
EPA 6020
Vanadium
18.4
mg/kg
2.9
04/16/15 22:20
EPA 7471
Mercury
0.0048J
mg/kg
0.0096
04/14/15 13:31
ASTM D2974-87
Percent Moisture
16.9
%
0.10
04/14/15 12:29
EPA 9045
pH at 25 Degrees C
5.5
Std. Units
0.10
04/13/15 16:20
EPA 300.0
Sulfate
4.4
mg/L
2.4
04/19/15 14:17 B
EPA 9060
Total Organic Carbon
526J
mg/kg
720
04/22/15 18:59
EPA 9060
Total Organic Carbon
536J
mg/kg
723
04/22/15 19:05
EPA 9060
Total Organic Carbon
543J
mg/kg
719
04/22/15 19:11
EPA 9060
Total Organic Carbon
512J
mg/kg
727
04/22/15 19:16
EPA 9060
Mean Total Organic Carbon
529J
mg/kg
722
04/22/15 18:59
EPA 9060
RSD%
2.5
%
04/22/15 18:59
92244130009
201509509
EPA 6010
Aluminum
10500
mg/kg
31.7
04/16/15 08:54
EPA 6010
Barium
80.2
mg/kg
3.2
04/16/15 08:54
EPA 6010
Beryllium
0.43
mg/kg
0.32
04/16/15 08:54
EPA 6010
Boron
27.1
mg/kg
15.8
04/16/15 08:54
EPA 6010
Calcium
317
mg/kg
158
04/16/15 08:54
EPA 6010
Chromium
14.4
mg/kg
1.6
04/16/15 08:54
EPA 6010
Copper
14.4
mg/kg
1.6
04/16/15 08:54
EPA 6010
Iron
25100
mg/kg
12.7
04/16/15 08:54
EPA 6010
Magnesium
1450
mg/kg
158
04/16/15 08:54
EPA 6010
Manganese
322
mg/kg
1.6
04/16/15 08:54
EPA 6010
Nickel
8.5
mg/kg
1.6
04/16/15 08:54
EPA 6010
Potassium
193J
mg/kg
317
04/16/15 08:54
EPA 6010
Strontium
5.8
mg/kg
3.2
04/16/15 08:54
EPA 6010
Zinc
28.7
mg/kg
6.3
04/16/15 08:54
EPA 6020
Arsenic
1.91
mg/kg
3.2
04/16/15 22:23
EPA 6020
Cobalt
5.3
mg/kg
3.2
04/16/15 22:23
EPA 6020
Lead
10.9
mg/kg
6.3
04/20/15 10:48
EPA 6020
Vanadium
34.9
mg/kg
3.2
04/16/15 22:23
EPA 7471
Mercury
0.033
mg/kg
0.011
04/14/15 13:37
ASTM D2974-87
Percent Moisture
23.5
%
0.10
04/14/15 12:30
EPA 9045
pH at 25 Degrees C
4.4
Std. Units
0.10
04/13/15 23:00
EPA 9056
Sulfate
364
mg/kg
322
04/10/15 05:01
EPA 9060
Total Organic Carbon
1450
mg/kg
779
04/22/15 19:23
EPA 9060
Total Organic Carbon
1300
mg/kg
786
04/22/15 19:28
EPA 9060
Total Organic Carbon
1340
mg/kg
786
04/22/15 19:35
EPA 9060
Total Organic Carbon
1320
mg/kg
788
04/22/15 19:40
EPA 9060
Mean Total Organic Carbon
1350
mg/kg
785
04/22/15 19:23
EPA 9060
RSD%
4.8
%
04/22/15 19:23
REPORT OF LABORATORY ANALYSIS
Qualifiers
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 12 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098g i vfte. Suite 100
Huntersville, NC 28078
[phone]
Project: J15040079
Pace Project No.: 92244130
Lab Sample ID Client Sample ID
Method Parameters
SUMMARY OF DETECTION
Result Units Report Limit Analyzed
92244130010
201509506 SPLP
EPA 6020A
Aluminum
969
ug/L
10.0
04/23/15 14:36
EPA 6020A
Arsenic
0.33J
ug/L
0.50
04/23/15 14:36
EPA 6020A
Barium
147
ug/L
0.30
04/23/15 14:36
EPA 6020A
Beryllium
0.21
ug/L
0.20
04/23/15 14:36
EPA 6020A
Boron
51.5
ug/L
5.0
04/23/15 14:36
EPA 6020A
Cadmium
0.19
ug/L
0.080
04/23/15 14:36
EPA 6020A
Calcium
88700
ug/L
400
04/23/15 15:24
EPA 6020A
Chromium
0.52
ug/L
0.50
04/23/15 14:36
EPA 6020A
Cobalt
2.4
ug/L
0.50
04/23/15 14:36
EPA 6020A
Copper
3.9
ug/L
1.0
04/23/15 14:36
EPA 6020A
Iron
160
ug/L
50.0
04/23/15 14:36
EPA 6020A
Lead
4.7
ug/L
0.10
04/23/15 14:36
EPA 6020A
Magnesium
546
ug/L
10.0
04/23/15 14:36
EPA 6020A
Manganese
128
ug/L
0.50
04/23/15 14:36
EPA 6020A
Nickel
6.0
ug/L
0.50
04/23/15 14:36
EPA 6020A
Potassium
1020
ug/L
50.0
04/23/15 14:36
EPA 6020A
Selenium
0.92
ug/L
0.50
04/23/15 14:36
EPA 6020A
Sodium
799
ug/L
50.0
04/23/15 14:36
EPA 6020A
Strontium
89.6
ug/L
0.50
04/23/15 14:36
EPA 6020A
Thallium
0.060J
ug/L
0.10
04/23/15 14:36
EPA 6020A
Zinc
143
ug/L
5.0
04/23/15 14:36
92244130011
201509507 SPLP
EPA 6020A
Aluminum
13600
ug/L
10.0
04/23/15 14:39
EPA 6020A
Arsenic
8.6
ug/L
0.50
04/23/15 14:39
EPA 6020A
Barium
149
ug/L
0.30
04/23/15 14:39
EPA 6020A
Beryllium
15.5
ug/L
0.20
04/23/15 14:39
EPA 6020A
Boron
168
ug/L
5.0
04/23/15 14:39
EPA 6020A
Cadmium
8.0
ug/L
0.080
04/23/15 14:39
EPA 6020A
Calcium
4940
ug/L
40.0
04/23/15 14:39
EPA 6020A
Chromium
2.1
ug/L
0.50
04/23/15 14:39
EPA 6020A
Cobalt
127
ug/L
0.50
04/23/15 14:39
EPA 6020A
Copper
88.5
ug/L
1.0
04/23/15 14:39
EPA 6020A
Iron
1950
ug/L
50.0
04/23/15 14:39
EPA 6020A
Lead
1.9
ug/L
0.10
04/23/15 14:39
EPA 6020A
Magnesium
6310
ug/L
10.0
04/23/15 14:39
EPA 6020A
Manganese
2060
ug/L
5.0
04/23/15 15:27
EPA 6020A
Nickel
320
ug/L
0.50
04/23/15 14:39
EPA 6020A
Potassium
1860
ug/L
50.0
04/23/15 14:39
EPA 6020A
Selenium
3.6
ug/L
0.50
04/23/15 14:39
EPA 6020A
Sodium
2320
ug/L
50.0
04/23/15 14:39
EPA 6020A
Strontium
398
ug/L
0.50
04/23/15 14:39
EPA 6020A
Thallium
0.77
ug/L
0.10
04/23/15 14:39
EPA 6020A
Zinc
1640
ug/L
50.0
04/23/15 15:27
92244130012
201509508 SPLP
EPA 6020A
Aluminum
6730
ug/L
10.0
04/23/15 14:41
EPA 6020A
Arsenic
1.4
ug/L
0.50
04/23/15 14:41
REPORT OF LABORATORY ANALYSIS
Qualifiers
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 13 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
09Q�K�i vfte. Suite 100
y Huntersville, NC 28078
[phone]
Project: J15040079
Pace Project No.: 92244130
Lab Sample ID Client Sample ID
Method Parameters
SUMMARY OF DETECTION
Result Units Report Limit Analyzed
92244130012
201509508 SPLP
EPA 6020A
Barium
422
ug/L
0.30
04/23/15 14:41
EPA 6020A
Beryllium
0.45
ug/L
0.20
04/23/15 14:41
EPA 6020A
Boron
161
ug/L
5.0
04/23/15 14:41
EPA 6020A
Calcium
1520
ug/L
40.0
04/23/15 14:41
EPA 6020A
Chromium
9.7
ug/L
0.50
04/23/15 14:41
EPA 6020A
Cobalt
9.6
ug/L
0.50
04/23/15 14:41
EPA 6020A
Copper
8.8
ug/L
1.0
04/23/15 14:41
EPA 6020A
Iron
8720
ug/L
50.0
04/23/15 14:41
EPA 6020A
Lead
12.8
ug/L
0.10
04/23/15 14:41
EPA 6020A
Magnesium
461
ug/L
10.0
04/23/15 14:41
EPA 6020A
Manganese
162
ug/L
0.50
04/23/15 14:41
EPA 6020A
Nickel
2.3
ug/L
0.50
04/23/15 14:41
EPA 6020A
Potassium
495
ug/L
50.0
04/23/15 14:41
EPA 6020A
Selenium
0.27J
ug/L
0.50
04/23/15 14:41
EPA 6020A
Sodium
3300
ug/L
50.0
04/23/15 14:41
EPA 6020A
Strontium
25.7
ug/L
0.50
04/23/15 14:41
EPA 6020A
Thallium
0.057J
ug/L
0.10
04/23/15 14:41
EPA 6020A
Vanadium
37.6
ug/L
1.0
04/23/15 14:41
EPA 6020A
Zinc
192
ug/L
5.0
04/23/15 14:41
EPA 7470A
Mercury
0.17J
ug/L
0.20
04/23/15 19:41
92244130013
201509511 SPLP
EPA 6020A
Aluminum
16300
ug/L
10.0
04/23/15 14:44
EPA 6020A
Arsenic
1.1
ug/L
0.50
04/23/15 14:44
EPA 6020A
Barium
248
ug/L
0.30
04/23/15 14:44
EPA 6020A
Beryllium
0.64
ug/L
0.20
04/23/15 14:44
EPA 6020A
Boron
148
ug/L
5.0
04/23/15 14:44
EPA 6020A
Cadmium
0.034J
ug/L
0.080
04/23/15 14:44
EPA 6020A
Calcium
2500
ug/L
40.0
04/23/15 14:44
EPA 6020A
Chromium
17.4
ug/L
0.50
04/23/15 14:44
EPA 6020A
Cobalt
3.1
ug/L
0.50
04/23/15 14:44
EPA 6020A
Copper
9.6
ug/L
1.0
04/23/15 14:44
EPA 6020A
Iron
14600
ug/L
50.0
04/23/15 14:44
EPA 6020A
Lead
4.5
ug/L
0.10
04/23/15 14:44
EPA 6020A
Magnesium
3100
ug/L
10.0
04/23/15 14:44
EPA 6020A
Manganese
150
ug/L
0.50
04/23/15 14:44
EPA 6020A
Nickel
8.1
ug/L
0.50
04/23/15 14:44
EPA 6020A
Potassium
604
ug/L
50.0
04/23/15 14:44
EPA 6020A
Selenium
0.42J
ug/L
0.50
04/23/15 14:44
EPA 6020A
Sodium
10100
ug/L
50.0
04/23/15 14:44
EPA 6020A
Strontium
35.6
ug/L
0.50
04/23/15 14:44
EPA 6020A
Thallium
0.10
ug/L
0.10
04/23/15 14:44
EPA 6020A
Vanadium
31.4
ug/L
1.0
04/23/15 14:44
EPA 6020A
Zinc
189
ug/L
5.0
04/23/15 14:44
EPA 7470A
Mercury
0.080J
ug/L
0.20
04/23/15 19:43
92244130014
201509512 SPLP
EPA 6020A
Aluminum
11500
ug/L
10.0
04/23/15 14:47
REPORT OF LABORATORY ANALYSIS
Qualifiers
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 14 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098v i vfte. Suite 100
Huntersville, NC 28078
[phone]
Project: J15040079
Pace Project No.: 92244130
Lab Sample ID Client Sample ID
Method Parameters
SUMMARY OF DETECTION
Result Units Report Limit Analyzed
92244130014
201509512 SPLP
EPA 6020A
Arsenic
1.3
ug/L
0.50
04/23/15 14:47
EPA 6020A
Barium
334
ug/L
0.30
04/23/15 14:47
EPA 6020A
Beryllium
0.76
ug/L
0.20
04/23/15 14:47
EPA 6020A
Boron
57.7
ug/L
5.0
04/23/15 14:47
EPA 6020A
Cadmium
0.034J
ug/L
0.080
04/23/15 14:47
EPA 6020A
Calcium
3620
ug/L
40.0
04/23/15 14:47
EPA 6020A
Chromium
10.7
ug/L
0.50
04/23/15 14:47
EPA 6020A
Cobalt
3.6
ug/L
0.50
04/23/15 14:47
EPA 6020A
Copper
11.6
ug/L
1.0
04/23/15 14:47
EPA 6020A
Iron
7510
ug/L
50.0
04/23/15 14:47
EPA 6020A
Lead
6.2
ug/L
0.10
04/23/15 14:47
EPA 6020A
Magnesium
3890
ug/L
10.0
04/23/15 14:47
EPA 6020A
Manganese
126
ug/L
0.50
04/23/15 14:47
EPA 6020A
Molybdenum
0.20J
ug/L
0.50
04/23/15 14:47
EPA 6020A
Nickel
6.2
ug/L
0.50
04/23/15 14:47
EPA 6020A
Potassium
542
ug/L
50.0
04/23/15 14:47
EPA 6020A
Selenium
0.53
ug/L
0.50
04/23/15 14:47
EPA 6020A
Sodium
10300
ug/L
50.0
04/23/15 14:47
EPA 6020A
Strontium
51.9
ug/L
0.50
04/23/15 14:47
EPA 6020A
Thallium
0.071J
ug/L
0.10
04/23/15 14:47
EPA 6020A
Vanadium
35.5
ug/L
1.0
04/23/15 14:47
EPA 6020A
Zinc
88.0
ug/L
5.0
04/23/15 14:47
EPA 7470A
Mercury
0.13J
ug/L
0.20
04/23/15 19:45
92244130015
201509513 SPLP
EPA 6020A
Aluminum
40900
ug/L
100
04/23/15 15:22
EPA 6020A
Arsenic
2.8
ug/L
0.50
04/23/15 14:50
EPA 6020A
Barium
379
ug/L
0.30
04/23/15 14:50
EPA 6020A
Beryllium
1.4
ug/L
0.20
04/23/15 14:50
EPA 6020A
Boron
80.0
ug/L
5.0
04/23/15 14:50
EPA 6020A
Cadmium
0.056J
ug/L
0.080
04/23/15 14:50
EPA 6020A
Calcium
1320
ug/L
40.0
04/23/15 14:50
EPA 6020A
Chromium
29.1
ug/L
0.50
04/23/15 14:50
EPA 6020A
Cobalt
10
ug/L
0.50
04/23/15 14:50
EPA 6020A
Copper
28.4
ug/L
1.0
04/23/15 14:50
EPA 6020A
Iron
26400
ug/L
500
04/23/15 15:22
EPA 6020A
Lead
16.3
ug/L
0.10
04/23/15 14:50
EPA 6020A
Magnesium
1930
ug/L
10.0
04/23/15 14:50
EPA 6020A
Manganese
417
ug/L
0.50
04/23/15 14:50
EPA 6020A
Molybdenum
0.18J
ug/L
0.50
04/23/15 14:50
EPA 6020A
Nickel
15.3
ug/L
0.50
04/23/15 14:50
EPA 6020A
Potassium
1420
ug/L
50.0
04/23/15 14:50
EPA 6020A
Selenium
0.35J
ug/L
0.50
04/23/15 14:50
EPA 6020A
Sodium
2310
ug/L
50.0
04/23/15 14:50
EPA 6020A
Strontium
23.4
ug/L
0.50
04/23/15 14:50
EPA 6020A
Thallium
0.19
ug/L
0.10
04/23/15 14:50
EPA 6020A
Vanadium
93.2
ug/L
1.0
04/23/15 14:50
EPA 6020A
Zinc
199
ug/L
5.0
04/23/15 14:50
REPORT OF LABORATORY ANALYSIS
Qualifiers
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 15 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098g i vfte. Suite 100
Huntersville, NC 28078
[phone]
Project: J15040079
Pace Project No.: 92244130
Lab Sample ID
Method
92244130015
EPA 7470A
Client Sample ID
Parameters
201509513 SPLP
Mercury
SUMMARY OF DETECTION
Result UnitE
0.0501 ug/L
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Report Limit Analyzed Qualifiers
0.20 04/23/1519:51
Page 16 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098g i vfte. Suite 100
�J Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15040079
Pace Project No.: 92244130
Method: EPA 6010
Description: 6010 MET ICP
Client: Duke Energy
Date: April 27, 2015
General Information:
7 samples were analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 3050 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: MPRP/23551
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92244129001
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1181557)
• Aluminum
• Barium
• Iron
• MSD (Lab ID: 1181558)
• Aluminum
• Barium
• Iron
• Manganese
R1: RPD value was outside control limits.
• MSD (Lab ID: 1181558)
• Aluminum
• Barium
• Iron
• Manganese
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 17 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098ninyfte. Suite 100
y Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15040079
Pace Project No.: 92244130
Method: EPA 6010
Description: 6010 MET ICP
Client: Duke Energy
Date: April 27, 2015
Additional Comments:
Analyte Comments:
QC Batch: MPRP/23551
D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
•201509506 (Lab ID:92244130003)
• Aluminum
• Boron
• Barium
• Beryllium
• Calcium
• Chromium
• Copper
• Iron
• Potassium
• Magnesium
• Manganese
• Molybdenum
• Sodium
• Nickel
• Strontium
• Zinc
•201509507 (Lab ID:92244130004)
• Aluminum
• Boron
• Barium
• Beryllium
• Calcium
• Chromium
• Copper
• Iron
• Potassium
• Magnesium
• Manganese
• Molybdenum
• Sodium
• Nickel
• Strontium
• Zinc
•201509508 (Lab ID:92244130005)
• Aluminum
• Boron
• Barium
• Beryllium
• Calcium
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 18 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098ninvfte. Suite 100
y Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15040079
Pace Project No.: 92244130
Method: EPA 6010
Description: 6010 MET ICP
Client: Duke Energy
Date: April 27, 2015
Analyte Comments:
QC Batch: MPRP/23551
D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
•201509508 (Lab ID:92244130005)
• Chromium
• Copper
• Iron
• Potassium
• Magnesium
• Manganese
• Molybdenum
• Sodium
• Nickel
• Strontium
• Zinc
•201509511 (Lab ID:92244130006)
• Aluminum
• Boron
• Barium
• Beryllium
• Calcium
• Chromium
• Copper
• Iron
• Potassium
• Magnesium
• Manganese
• Sodium
• Nickel
• Strontium
• Zinc
• MS (Lab ID: 1181557)
• Aluminum
• Boron
• Beryllium
• Calcium
• Chromium
• Copper
• Iron
• Potassium
• Magnesium
• Manganese
• Molybdenum
• Sodium
• Nickel
• Zinc
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc.. Page 19 of 82

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Pace Analytical Services, Inc.
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PROJECT NARRATIVE
Project: J15040079
Pace Project No.: 92244130
Method: EPA 6010
Description: 6010 MET ICP
Client: Duke Energy
Date: April 27, 2015
Analyte Comments:
QC Batch: MPRP/23551
D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
• MSD (Lab ID: 1181558)
• Aluminum
• Boron
• Barium
• Beryllium
• Calcium
• Chromium
• Copper
• Iron
• Potassium
• Magnesium
• Manganese
• Molybdenum
• Sodium
• Nickel
• Strontium
• Zinc
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc.. Page 20 of 82

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Pace Analytical Services, Inc.
098ninyfte. Suite 100
y Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15040079
Pace Project No.: 92244130
Method: EPA 6020
Description: 6020 MET ICPMS
Client: Duke Energy
Date: April 27, 2015
General Information:
7 samples were analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 3050 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: MPRP/23552
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92244129001
M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
• MS (Lab ID: 1181562)
• Arsenic
• MSD (Lab ID: 1181563)
• Arsenic
• Cadmium
R1: RPD value was outside control limits.
• MSD (Lab ID: 1181563)
• Arsenic
Additional Comments:
Batch Comments:
Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
• QC Batch: ICPM / 9583
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc.. Page 21 of 82

aceAnaiXical
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Pace Analytical Services, Inc.
09Q�K�i vfte. Suite 100
y Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15040079
Pace Project No.: 92244130
Method: EPA 6020
Description: 6020 MET ICPMS
Client: Duke Energy
Date: April 27, 2015
Analyte Comments:
QC Batch: MPRP/23552
DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
• MS (Lab ID: 1181562)
• Arsenic
• Cadmium
• Cobalt
• Lead
• Antimony
• Selenium
• Thallium
• Vanadium
• MSD (Lab ID: 1181563)
• Arsenic
• Cadmium
• Cobalt
• Lead
• Antimony
• Selenium
• Thallium
• Vanadium
N2: The lab does not hold TNI accreditation for this parameter.
•201509506 (Lab ID:92244130003)
• Antimony
•201509507 (Lab ID:92244130004)
• Antimony
•201509508 (Lab ID:92244130005)
• Antimony
•201509509 (Lab ID:92244130009)
• Antimony
•201509511 (Lab ID:92244130006)
• Antimony
•201509512 (Lab ID:92244130007)
• Antimony
•201509513 (Lab ID:92244130008)
• Antimony
• BLANK (Lab ID: 1181560)
• Antimony
• LCS (Lab ID: 1181561)
• Antimony
• MS (Lab ID: 1181562)
• Antimony
• MSD (Lab ID: 1181563)
• Antimony
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc.. Page 22 of 82

aceAnaiXical
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Pace Analytical Services, Inc.
098ninyfte. Suite 100
y Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15040079
Pace Project No.: 92244130
Method: EPA 6020A
Description: 6020A MET ICPMS
Client: Duke Energy
Date: April 27, 2015
General Information:
8 samples were analyzed for EPA 6020A. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 3020 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: MPRP/53524
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92244129006
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1936122)
• Aluminum
• MSD (Lab ID: 1936123)
• Aluminum
QC Batch: MPRP/53815
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 10303182004
M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
• MS (Lab ID: 1945266)
• Boron
• Calcium
• Magnesium
• Potassium
• Sodium
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc.. Page 23 of 82

aceAnaiXical
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Pace Analytical Services, Inc.
098ninyfte. Suite 100
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[phone]
PROJECT NARRATIVE
Project: J15040079
Pace Project No.: 92244130
Method: EPA 6020A
Description: 6020A MET ICPMS
Client: Duke Energy
Date: April 27, 2015
QC Batch: MPRP/53815
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 10303182004
M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
• Strontium
• MSD (Lab ID: 1945267)
• Boron
• Calcium
• Magnesium
• Potassium
• Sodium
• Strontium
R1: RPD value was outside control limits.
• MSD (Lab ID: 1945267)
• Selenium
Additional Comments:
Analyte Comments:
QC Batch: MPRP/53815
E: Analyte concentration exceeded the calibration range. The reported result is estimated.
• MS (Lab ID: 1945266)
• Sodium
• MSD (Lab ID: 1945267)
• Sodium
P8: Analyte was detected in the method blank. All associated samples had concentrations of at least ten times greater than the blank
or were below the reporting limit.
• BLANK (Lab ID: 1945264)
• Manganese
REPORT OF LABORATORY ANALYSIS
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PROJECT NARRATIVE
Project: J15040079
Pace Project No.: 92244130
Method: EPA 7470
Description: 7470 Mercury
Client: Duke Energy
Date: April 27, 2015
General Information:
2 samples were analyzed for EPA 7470. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 7470 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc.. Page 25 of 82

aceAnaiXical
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Pace Analytical Services, Inc.
098ninyfte. Suite 100
y Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15040079
Pace Project No.: 92244130
Method: EPA 7470A
Description: 7470A Mercury
Client: Duke Energy
Date: April 27, 2015
General Information:
6 samples were analyzed for EPA 7470A. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 7470A with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 26 of 82

aceAnaiXical
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Pace Analytical Services, Inc.
098ninyfte. Suite 100
y Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15040079
Pace Project No.: 92244130
Method: EPA 7471
Description: 7471 Mercury
Client: Duke Energy
Date: April 27, 2015
General Information:
7 samples were analyzed for EPA 7471. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 7471 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc.. Page 27 of 82

aceAnaiXical
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Pace Analytical Services, Inc.
098m.8ffte. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15040079
Pace Project No.: 92244130
Method: EPA 9045
Description: 9045 pH Soil
Client: Duke Energy
Date: April 27, 2015
General Information:
7 samples were analyzed for EPA 9045. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
QC Batch: WET/36760
D6: The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits.
• DUP (Lab ID: 1431691)
• pH at 25 Degrees C
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc.. Page 28 of 82

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Pace Analytical Services, Inc.
098gWinlc8)r fie. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15040079
Pace Project No.: 92244130
Method: EPA 300.0
Description: 300.0 IC Anions, SPLP
Client: Duke Energy
Date: April 27, 2015
General Information:
6 samples were analyzed for EPA 300.0. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
QC Batch: WETA/22607
B: Analyte was detected in the associated method blank.
• BLANK for HBN 260035 [WETA/226 (Lab ID: 1437291)
• Sulfate
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc.. Page 29 of 82

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Pace Analytical Services, Inc.
098oinffte. Suite 100
y Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15040079
Pace Project No.: 92244130
Method: EPA 353.2
Description: 353.2 Nitrogen, NO2/NO3, SPLP
Client: Duke Energy
Date: April 27, 2015
General Information:
6 samples were analyzed for EPA 353.2. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
1-11: Analysis conducted outside the EPA method holding time.
•201509506 (Lab ID:92244130003)
•201509507 (Lab ID:92244130004)
•201509508 (Lab ID:92244130005)
•201509511 (Lab ID:92244130006)
•201509512 (Lab ID:92244130007)
•201509513 (Lab ID:92244130008)
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 30 of 82

aceAnaiXical
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Pace Analytical Services, Inc.
098�t�i .8fftie. Suite 100
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[phone]
PROJECT NARRATIVE
Project: J15040079
Pace Project No.: 92244130
Method: SM 4500-CI-E
Description: 4500 Chloride, SPLP
Client: Duke Energy
Date: April 27, 2015
General Information:
6 samples were analyzed for SM 4500-CI-E. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc.. Page 31 of 82

aceAnaiXical
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Pace Analytical Services, Inc.
098g i vfte. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15040079
Pace Project No.: 92244130
Method: EPA 9056
Description: 9056 IC Anions
Client: Duke Energy
Date: April 27, 2015
General Information:
7 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
Analyte Comments:
QC Batch: WETA/45261
DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
•201509506 (Lab ID:92244130003)
• Chloride
•201509507 (Lab ID:92244130004)
• Chloride
•201509508 (Lab ID:92244130005)
• Chloride
• Sulfate
•201509509 (Lab ID:92244130009)
• Chloride
•201509511 (Lab ID:92244130006)
• Chloride
•201509512 (Lab ID:92244130007)
• Chloride
•201509513 (Lab ID:92244130008)
• Chloride
• Sulfate
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc.. Page 32 of 82

aceAnaiXical
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Pace Analytical Services, Inc.
098m.8ffte. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15040079
Pace Project No.: 92244130
Method: EPA 9056
Description: 9056 IC Anions 48hr
Client: Duke Energy
Date: April 27, 2015
General Information:
7 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
1-13: Sample was received or analysis requested beyond the recognized method holding time.
•201509506 (Lab ID:92244130003)
•201509507 (Lab ID:92244130004)
•201509508 (Lab ID:92244130005)
•201509509 (Lab ID:92244130009)
•201509511 (Lab ID:92244130006)
•201509512 (Lab ID:92244130007)
•201509513 (Lab ID:92244130008)
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 33 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098�t�i .8fftie. Suite 100
y Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15040079
Pace Project No.: 92244130
Method: EPA 9060
Description: Total Organic Carbon Quad
Client: Duke Energy
Date: April 27, 2015
General Information:
7 samples were analyzed for EPA 9060. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc.. Page 34 of 82

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098m.8ffte. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040079
Pace Project No.: 92244130
Sample: 201509505 Lab ID: 92244130001 Collected: 03/30/15 15:35 Received: 04/06/15 14:32 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
;I➢ZI7c\�i,I=11 l[99�r 6?
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Sodium
Strontium
Thallium
Vanadium
Zinc
7470 Mercury
Mercury
Date: 04/27/2015 03:40 PM
Analytical Method: EPA 6020A Preparation Method: EPA 3020
68.6
ug/L
10.0
3.0
1
04/09/1516:35
04/13/1516:03
7429-90-5
ND
ug/L
0.50
0.15
1
04/09/1516:35
04/13/1516:03
7440-36-0
ND
ug/L
0.50
0.11
1
04/09/1516:35
04/13/1516:03
7440-38-2
0.73
ug/L
0.30
0.081
1
04/09/1516:35
04/13/1516:03
7440-39-3
ND
ug/L
0.20
0.067
1
04/09/1516:35
04/13/1516:03
7440-41-7
ND
ug/L
5.0
1.1
1
04/09/1516:35
04/13/1516:03
7440-42-8
ND
ug/L
0.080
0.024
1
04/09/1516:35
04/13/1516:03
7440-43-9
278
ug/L
40.0
16.0
1
04/09/1516:35
04/13/1516:03
7440-70-2
1.0
ug/L
0.50
0.17
1
04/09/1516:35
04/13/1516:03
7440-47-3
ND
ug/L
0.50
0.13
1
04/09/1516:35
04/13/1516:03
7440-48-4
ND
ug/L
1.0
0.21
1
04/09/1516:35
04/13/1516:03
7440-50-8
618
ug/L
50.0
13.7
1
04/09/1516:35
04/13/1516:03
7439-89-6
0.19
ug/L
0.10
0.046
1
04/09/1516:35
04/13/1516:03
7439-92-1
32.1
ug/L
10.0
3.2
1
04/09/1516:35
04/13/1516:03
7439-95-4
14.0
ug/L
0.50
0.24
1
04/09/1516:35
04/13/1516:03
7439-96-5
ND
ug/L
0.50
0.094
1
04/09/1516:35
04/13/1516:03
7439-98-7
0.73
ug/L
0.50
0.16
1
04/09/1516:35
04/13/1516:03
7440-02-0
ND
ug/L
50.0
11.7
1
04/09/1516:35
04/13/1516:03
7440-09-7
ND
ug/L
0.50
0.20
1
04/09/1516:35
04/13/1516:03
7782-49-2
59.6
ug/L
50.0
16.3
1
04/09/1516:35
04/13/1516:03
7440-23-5
2.5
ug/L
0.50
0.13
1
04/09/1516:35
04/13/1516:03
7440-24-6
ND
ug/L
0.10
0.015
1
04/09/1516:35
04/13/1516:03
7440-28-0
ND
ug/L
1.0
0.28
1
04/09/1516:35
04/13/1516:03
7440-62-2
ND
ug/L
5.0
2.4
1
04/09/1516:35
04/13/1516:03
7440-66-6
Analytical Method: EPA 7470 Preparation Method: EPA 7470
ND ug/L 0.20 0.022 1 04/12/1519:00 04/13/1511:35 7439-97-6
REPORT OF LABORATORY ANALYSIS
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www.pacelabs.com
Pace Analytical Services, Inc.
098m.8ffte. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040079
Pace Project No.: 92244130
Sample: 201509510 Lab ID: 92244130002 Collected: 04/01/15 09:35 Received: 04/06/15 14:32 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
;I➢ZI7c\�i,I=11 l[99�r 6?
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Sodium
Strontium
Thallium
Vanadium
Zinc
7470 Mercury
Mercury
Date: 04/27/2015 03:40 PM
Analytical Method: EPA 6020A Preparation Method: EPA 3020
44.1
ug/L
10.0
3.0
1
04/09/1516:35
04/13/1516:08
7429-90-5
ND
ug/L
0.50
0.15
1
04/09/1516:35
04/13/1516:08
7440-36-0
ND
ug/L
0.50
0.11
1
04/09/1516:35
04/13/1516:08
7440-38-2
1.3
ug/L
0.30
0.081
1
04/09/1516:35
04/13/1516:08
7440-39-3
ND
ug/L
0.20
0.067
1
04/09/1516:35
04/13/1516:08
7440-41-7
ND
ug/L
5.0
1.1
1
04/09/1516:35
04/13/1516:08
7440-42-8
ND
ug/L
0.080
0.024
1
04/09/1516:35
04/13/1516:08
7440-43-9
329
ug/L
40.0
16.0
1
04/09/1516:35
04/13/1516:08
7440-70-2
0.55
ug/L
0.50
0.17
1
04/09/1516:35
04/13/1516:08
7440-47-3
0.68
ug/L
0.50
0.13
1
04/09/1516:35
04/13/1516:08
7440-48-4
ND
ug/L
1.0
0.21
1
04/09/1516:35
04/13/1516:08
7440-50-8
345
ug/L
50.0
13.7
1
04/09/1516:35
04/13/1516:08
7439-89-6
0.19
ug/L
0.10
0.046
1
04/09/1516:35
04/13/1516:08
7439-92-1
18.7
ug/L
10.0
3.2
1
04/09/1516:35
04/13/1516:08
7439-95-4
7.0
ug/L
0.50
0.24
1
04/09/1516:35
04/13/1516:08
7439-96-5
ND
ug/L
0.50
0.094
1
04/09/1516:35
04/13/1516:08
7439-98-7
ND
ug/L
0.50
0.16
1
04/09/1516:35
04/13/1516:08
7440-02-0
51.4
ug/L
50.0
11.7
1
04/09/1516:35
04/13/1516:08
7440-09-7
ND
ug/L
0.50
0.20
1
04/09/1516:35
04/13/1516:08
7782-49-2
ND
ug/L
50.0
16.3
1
04/09/1516:35
04/13/1516:08
7440-23-5
1.6
ug/L
0.50
0.13
1
04/09/1516:35
04/13/1516:08
7440-24-6
ND
ug/L
0.10
0.015
1
04/09/1516:35
04/13/1516:08
7440-28-0
ND
ug/L
1.0
0.28
1
04/09/1516:35
04/13/1516:08
7440-62-2
ND
ug/L
5.0
2.4
1
04/09/1516:35
04/13/1516:08
7440-66-6
Analytical Method: EPA 7470 Preparation Method: EPA 7470
ND ug/L 0.20 0.022 1 04/12/1519:00 04/13/1511:37 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 36 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098m.8ffte. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040079
Pace Project No.: 92244130
Sample: 201509506 Lab ID: 92244130003 Collected: 03/30/15 16:20 Received: 04/06/15 14:32 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Aluminum
Barium
Beryllium
Boron
Calcium
Chromium
Copper
Iron
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Sodium
Strontium
Zinc
6020 MET ICPMS
Antimony
Arsenic
Cadmium
Cobalt
Lead
Selenium
Thallium
Vanadium
7471 Mercury
Mercury
Percent Moisture
Percent Moisture
9045 pH Soil
pH at 25 Degrees C
300.0 IC Anions, SPLP
Sulfate
353.2 Nitrogen, NO2/NO3, SPLP
Nitrogen, Nitrate
4500 Chloride, SPLP
Chloride
Date: 04/27/2015 03:40 PM
Analytical Method: EPA 6010 Preparation Method: EPA 3050
1920
mg/kg
28.3
14.1
5
04/13/15 15:00
04/15/15 08:56
7429-90-5
47.8
mg/kg
2.8
1.4
5
04/13/15 15:00
04/15/15 08:56
7440-39-3
ND
mg/kg
0.28
0.14
5
04/13/15 15:00
04/15/15 08:56
7440-41-7
40.0
mg/kg
14.1
7.1
5
04/13/15 15:00
04/15/15 08:56
7440-42-8
3400
mg/kg
141
70.7
5
04/13/15 15:00
04/15/15 08:56
7440-70-2
9.3
mg/kg
1.4
0.71
5
04/13/15 15:00
04/15/15 08:56
7440-47-3
19.0
mg/kg
1.4
0.71
5
04/13/15 15:00
04/15/15 08:56
7440-50-8
50400
mg/kg
11.3
5.7
5
04/13/15 15:00
04/15/15 08:56
7439-89-6
1170
mg/kg
141
70.7
5
04/13/15 15:00
04/15/15 08:56
7439-95-4
68.8
mg/kg
1.4
0.71
5
04/13/15 15:00
04/15/15 08:56
7439-96-5
1.7J
mg/kg
2.8
1.4
5
04/13/15 15:00
04/15/15 08:56
7439-98-7
3.9
mg/kg
1.4
0.71
5
04/13/15 15:00
04/15/15 08:56
7440-02-0
750
mg/kg
283
141
5
04/13/15 15:00
04/15/15 08:56
7440-09-7
ND
mg/kg
283
141
5
04/13/15 15:00
04/15/15 08:56
7440-23-5
20.2
mg/kg
2.8
1.4
5
04/13/15 15:00
04/15/15 08:56
7440-24-6
10.3
mg/kg
5.7
2.8
5
04/13/15 15:00
04/15/15 08:56
7440-66-6
Analytical
Method: EPA 6020 Preparation
Method: EPA 3050
ND
mg/kg
2.8
1.4
50
04/13/15 15:00
04/16/15 22:09
7440-36-0
118
mg/kg
2.8
1.4
50
04/13/15 15:00
04/16/15 22:09
7440-38-2
ND
mg/kg
0.34
0.17
50
04/13/15 15:00
04/16/15 22:09
7440-43-9
2.1J
mg/kg
2.8
1.4
50
04/13/15 15:00
04/16/15 22:09
7440-48-4
42.1
mg/kg
5.7
2.8
100
04/13/15 15:00
04/20/1510:28
7439-92-1
4.7
mg/kg
2.8
1.4
50
04/13/15 15:00
04/16/15 22:09
7782-49-2
ND
mg/kg
2.8
1.4
50
04/13/15 15:00
04/16/15 22:09
7440-28-0
24.9
mg/kg
2.8
1.4
50
04/13/15 15:00
04/16/15 22:09
7440-62-2
D3
D3
D3
D3
D3
D3
D3
D3
D3
D3
D3
D3
D3
D3
D3
D3
N2
Analytical Method: EPA 7471 Preparation Method: EPA 7471
0.13 mg/kg 0.0087 0.0044 1 04/13/1515:32 04/14/1513:20 7439-97-6
Analytical Method: ASTM D2974-87
11.8 % 0.10 0.10 1 04/14/1512:20 D6
Analytical Method: EPA 9045
3.2 Std. Units 0.10 0.10 1 04/13/15 23:00
Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 04/15/15 00:55
275 mg/L 22.7 11.3 10 04/19/1512:42 14808-79-8 B
Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 04/15/15 00:55
ND mg/L 0.23 0.23 1 04/22/1517:12 H1
Analytical Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 04/15/15 00:55
ND mg/L 5.7 2.8 1 04/17/15 05:29 16887-00-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 37 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098onyfte. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040079
Pace Project No.: 92244130
Sample: 201509506 Lab ID: 92244130003 Collected: 03/30/15 16:20 Received: 04/06/15 14:32 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
9056 IC Anions Analytical Method: EPA 9056
Chloride
ND mg/kg
288
144
5
04/10/15 02:53
16887-00-6 D3
Sulfate
5650 mg/kg
1150
576
20
04/10/1514:27
14808-79-8
9056 IC Anions 48hr
Analytical Method: EPA 9056
Nitrate as N
ND mg/kg
28.8
14.4
5
04/10/15 02:53
14797-55-8 H3
Total Organic Carbon Quad
Analytical Method: EPA 9060
Total Organic Carbon
164000 mg/kg
4310
2150
1
04/22/15 16:46
7440-44-0
Total Organic Carbon
148000 mg/kg
4480
2240
1
04/22/15 16:52
7440-44-0
Total Organic Carbon
168000 mg/kg
4450
2220
1
04/22/15 16:57
7440-44-0
Total Organic Carbon
167000 mg/kg
4320
2160
1
04/22/15 17:04
7440-44-0
Mean Total Organic Carbon
162000 mg/kg
4390
2190
1
04/22/15 16:46
7440-44-0
Surrogates
RSD%
5.6 %
1
04/22/15 16:46
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/27/2015 03:40 PM without the written consent of Pace Analytical Services, Inc..
Page 38 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098onvfte. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040079
Pace Project No.: 92244130
Sample: 201509507
Lab ID:
92244130004
Collected:
03/30/15 16:40
Received: 04/06/15 14:32 Matrix: Solid
Results reported on a "dry weight"
basis and are adjusted for percent moisture, sample
size and any dilutions.
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared
Analyzed
CAS No.
Qual
6010 MET ICP
Analytical Method: EPA 6010 Preparation Method: EPA
3050
Aluminum
4580
mg/kg
29.0
14.5
5
04/13/15 15:00
04/15/15 09:00
7429-90-5
D3
Barium
374
mg/kg
2.9
1.4
5
04/13/15 15:00
04/15/15 09:00
7440-39-3
D3
Beryllium
1.2
mg/kg
0.29
0.14
5
04/13/15 15:00
04/15/15 09:00
7440-41-7
D3
Boron
19.6
mg/kg
14.5
7.2
5
04/13/15 15:00
04/15/15 09:00
7440-42-8
D3
Calcium
873
mg/kg
145
72.5
5
04/13/15 15:00
04/15/15 09:00
7440-70-2
D3
Chromium
7.6
mg/kg
1.4
0.72
5
04/13/15 15:00
04/15/15 09:00
7440-47-3
D3
Copper
14.3
mg/kg
1.4
0.72
5
04/13/15 15:00
04/15/15 09:00
7440-50-8
D3
Iron
16600
mg/kg
11.6
5.8
5
04/13/15 15:00
04/15/15 09:00
7439-89-6
D3
Magnesium
449
mg/kg
145
72.5
5
04/13/15 15:00
04/15/15 09:00
7439-95-4
D3
Manganese
106
mg/kg
1.4
0.72
5
04/13/15 15:00
04/15/15 09:00
7439-96-5
D3
Molybdenum
ND
mg/kg
2.9
1.4
5
04/13/15 15:00
04/15/15 09:00
7439-98-7
D3
Nickel
17.3
mg/kg
1.4
0.72
5
04/13/15 15:00
04/15/15 09:00
7440-02-0
D3
Potassium
468
mg/kg
290
145
5
04/13/15 15:00
04/15/15 09:00
7440-09-7
D3
Sodium
ND
mg/kg
290
145
5
04/13/15 15:00
04/15/15 09:00
7440-23-5
D3
Strontium
107
mg/kg
2.9
1.4
5
04/13/15 15:00
04/15/15 09:00
7440-24-6
D3
Zinc
27.3
mg/kg
5.8
2.9
5
04/13/15 15:00
04/15/15 09:00
7440-66-6
D3
6020 MET ICPMS
Analytical
Method: EPA 6020
Preparation
Method: EPA
3050
Antimony
ND
mg/kg
5.8
2.9
100
04/13/15 15:00
04/20/1510:30
7440-36-0
N2
Arsenic
13.1
mg/kg
2.9
1.4
50
04/13/15 15:00
04/16/15 22:11
7440-38-2
Cadmium
ND
mg/kg
0.70
0.35
100
04/13/15 15:00
04/20/1510:30
7440-43-9
Cobalt
6.3
mg/kg
2.9
1.4
50
04/13/15 15:00
04/16/15 22:11
7440-48-4
Lead
2.9J
mg/kg
5.8
2.9
100
04/13/15 15:00
04/20/1510:30
7439-92-1
Selenium
4.2
mg/kg
2.9
1.4
50
04/13/15 15:00
04/16/15 22:11
7782-49-2
Thallium
ND
mg/kg
5.8
2.9
100
04/13/15 15:00
04/20/1510:30
7440-28-0
Vanadium
13.4
mg/kg
2.9
1.4
50
04/13/15 15:00
04/16/15 22:11
7440-62-2
7471 Mercury
Analytical
Method: EPA 7471 Preparation
Method: EPA
7471
Mercury
0.017
mg/kg
0.0089
0.0044
1
04/13/1515:32
04/14/1513:22
7439-97-6
Percent Moisture
Analytical
Method: ASTM
D2974-87
Percent Moisture
13.8
%
0.10
0.10
1
04/14/15 12:24
9045 pH Soil
Analytical
Method: EPA 9045
pH at 25 Degrees C
3.5
Std. Units
0.10
0.10
1
04/13/15 23:00
300.0 IC Anions, SPLP
Analytical
Method: EPA 300.0
Leachate
Method/Date:
EPA 1312; 04/15/15
00:55
Sulfate
173
mg/L
11.6
5.8
5
04/19/1513:22
14808-79-8
353.2 Nitrogen, NO2/NO3, SPLP
Analytical
Method: EPA 353.2
Leachate
Method/Date:
EPA 1312; 04/15/15
00:55
Nitrogen, Nitrate
ND
mg/L
0.23
0.23
1
04/22/15 17:18
H1
4500 Chloride, SPLP
Analytical
Method: SM 4500-CI-E Leachate
Method/Date: EPA 1312; 04/15/15 00:55
Chloride
ND
mg/L
5.8
2.9
1
04/17/15 05:31
16887-00-6
REPORT OF LABORATORY
ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/27/2015 03:40 PM
without the written
consent of Pace Analytical Services, Inc..
Page
39 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098onyfte. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040079
Pace Project No.: 92244130
Sample: 201509507 Lab ID: 92244130004 Collected: 03/30/15 16:40 Received: 04/06/15 14:32 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
9056 IC Anions Analytical Method: EPA 9056
Chloride
ND mg/kg
291
145
5
04/10/15 03:14
16887-00-6 D3
Sulfate
3330 mg/kg
291
145
5
04/10/15 03:14
14808-79-8
9056 IC Anions 48hr
Analytical Method: EPA 9056
Nitrate as N
ND mg/kg
29.1
14.5
5
04/10/15 03:14
14797-55-8 H3
Total Organic Carbon Quad
Analytical Method: EPA 9060
Total Organic Carbon
28800 mg/kg
4970
2490
1
04/22/15 17:09
7440-44-0
Total Organic Carbon
28000 mg/kg
4940
2470
1
04/22/15 17:16
7440-44-0
Total Organic Carbon
27400 mg/kg
4970
2480
1
04/22/15 17:22
7440-44-0
Total Organic Carbon
27800 mg/kg
4960
2480
1
04/22/15 17:30
7440-44-0
Mean Total Organic Carbon
28000 mg/kg
4960
2480
1
04/22/15 17:09
7440-44-0
Surrogates
RSD%
2.1 %
1
04/22/15 17:09
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/27/2015 03:40 PM without the written consent of Pace Analytical Services, Inc..
Page 40 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098nnyfte. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040079
Pace Project No.: 92244130
Sample: 201509508 Lab ID: 92244130005 Collected: 03/30/15 16:50 Received: 04/06/15 14:32 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Aluminum
Barium
Beryllium
Boron
Calcium
Chromium
Copper
Iron
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Sodium
Strontium
Zinc
6020 MET ICPMS
Antimony
Arsenic
Cadmium
Cobalt
Lead
Selenium
Thallium
Vanadium
7471 Mercury
Mercury
Percent Moisture
Percent Moisture
9045 pH Soil
pH at 25 Degrees C
300.0 IC Anions, SPLP
Sulfate
353.2 Nitrogen, NO2/NO3, SPLP
Nitrogen, Nitrate
4500 Chloride, SPLP
Chloride
Date: 04/27/2015 03:40 PM
Analytical Method: EPA 6010 Preparation Method: EPA 3050
4830
mg/kg
28.8
14.4
5
04/13/15 15:00
04/15/15 09:05
7429-90-5
47.5
mg/kg
2.9
1.4
5
04/13/15 15:00
04/15/15 09:05
7440-39-3
0.37
mg/kg
0.29
0.14
5
04/13/15 15:00
04/15/15 09:05
7440-41-7
ND
mg/kg
14.4
7.2
5
04/13/15 15:00
04/15/15 09:05
7440-42-8
180
mg/kg
144
72.0
5
04/13/15 15:00
04/15/15 09:05
7440-70-2
6.9
mg/kg
1.4
0.72
5
04/13/15 15:00
04/15/15 09:05
7440-47-3
4.9
mg/kg
1.4
0.72
5
04/13/15 15:00
04/15/15 09:05
7440-50-8
8660
mg/kg
11.5
5.8
5
04/13/15 15:00
04/15/15 09:05
7439-89-6
402
mg/kg
144
72.0
5
04/13/15 15:00
04/15/15 09:05
7439-95-4
596
mg/kg
1.4
0.72
5
04/13/15 15:00
04/15/15 09:05
7439-96-5
ND
mg/kg
2.9
1.4
5
04/13/15 15:00
04/15/15 09:05
7439-98-7
3.1
mg/kg
1.4
0.72
5
04/13/15 15:00
04/15/15 09:05
7440-02-0
ND
mg/kg
288
144
5
04/13/15 15:00
04/15/15 09:05
7440-09-7
ND
mg/kg
288
144
5
04/13/15 15:00
04/15/15 09:05
7440-23-5
3.0
mg/kg
2.9
1.4
5
04/13/15 15:00
04/15/15 09:05
7440-24-6
9.5
mg/kg
5.8
2.9
5
04/13/15 15:00
04/15/15 09:05
7440-66-6
Analytical
Method: EPA 6020 Preparation
Method: EPA 3050
ND
mg/kg
2.9
1.4
50
04/13/15 15:00
04/16/15 22:14
7440-36-0
ND
mg/kg
2.9
1.4
50
04/13/15 15:00
04/16/15 22:14
7440-38-2
ND
mg/kg
0.35
0.17
50
04/13/15 15:00
04/16/15 22:14
7440-43-9
9.8
mg/kg
2.9
1.4
50
04/13/15 15:00
04/16/15 22:14
7440-48-4
6.9
mg/kg
5.8
2.9
100
04/13/15 15:00
04/20/1510:33
7439-92-1
ND
mg/kg
2.9
1.4
50
04/13/15 15:00
04/16/15 22:14
7782-49-2
ND
mg/kg
5.8
2.9
100
04/13/15 15:00
04/20/1510:33
7440-28-0
18.7
mg/kg
2.9
1.4
50
04/13/15 15:00
04/16/15 22:14
7440-62-2
Analytical Method: EPA 7471 Preparation Method: EPA 7471
0.013 mg/kg 0.0094 0.0047 1 04/13/1515:32 04/14/1513:24 7439-97-6
Analytical Method: ASTM D2974-87
13.5 % 0.10 0.10 1 04/14/1512:25
Analytical Method: EPA 9045
5.5 Std. Units 0.10 0.10 1 04/13/15 23:00
D3
D3
D3
D3
D3
D3
D3
D3
D3
D3
D3
D3
D3
D3
D3
D3
N2
Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 04/15/15 00:55
7.2 mg/L 2.3 1.2 1 04/19/1513:36 14808-79-8 B
Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 04/15/15 00:55
0.24 mg/L 0.23 0.23 1 04/22/1517:27 H1
Analytical Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 04/15/15 00:55
ND mg/L 5.8 2.9 1 04/17/15 05:33 16887-00-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 41 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098mvfte. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040079
Pace Project No.: 92244130
Sample: 201509508 Lab ID: 92244130005 Collected: 03/30/15 16:50 Received: 04/06/15 14:32 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
9056 IC Anions Analytical Method: EPA 9056
Chloride
ND mg/kg
286
143
5
04/10/15 03:36
16887-00-6 D3
Sulfate
ND mg/kg
286
143
5
04/10/15 03:36
14808-79-8 D3
9056 IC Anions 48hr
Analytical Method: EPA 9056
Nitrate as N
ND mg/kg
28.6
14.3
5
04/10/15 03:36
14797-55-8 H3
Total Organic Carbon Quad
Analytical Method: EPA 9060
Total Organic Carbon
2240 mg/kg
697
348
1
04/22/15 17:48
7440-44-0
Total Organic Carbon
2330 mg/kg
698
349
1
04/22/15 17:54
7440-44-0
Total Organic Carbon
2060 mg/kg
691
346
1
04/22/15 17:59
7440-44-0
Total Organic Carbon
1910 mg/kg
699
349
1
04/22/15 18:05
7440-44-0
Mean Total Organic Carbon
2130 mg/kg
696
348
1
04/22/15 17:48
7440-44-0
Surrogates
RSD%
8.9 %
1
04/22/15 17:48
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/27/2015 03:40 PM without the written consent of Pace Analytical Services, Inc..
Page 42 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098nnyfte. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040079
Pace Project No.: 92244130
Sample: 201509511
Lab ID:
92244130006
Collected:
04/01/15 14:36
Received: 04/06/15 14:32 Matrix: Solid
Results reported on a "dry weight"
basis and are adjusted for percent moisture, sample
size and any dilutions.
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared
Analyzed
CAS No.
Qual
6010 MET ICP
Analytical Method: EPA 6010 Preparation Method: EPA
3050
Aluminum
9980
mg/kg
29.2
14.6
5
04/13/15 15:00
04/15/15 09:09
7429-90-5
D3
Barium
64.9
mg/kg
2.9
1.5
5
04/13/15 15:00
04/15/15 09:09
7440-39-3
D3
Beryllium
0.60
mg/kg
0.29
0.15
5
04/13/15 15:00
04/15/15 09:09
7440-41-7
D3
Boron
18.2
mg/kg
14.6
7.3
5
04/13/15 15:00
04/15/15 09:09
7440-42-8
D3
Calcium
1120
mg/kg
146
73.0
5
04/13/15 15:00
04/15/15 09:09
7440-70-2
D3
Chromium
15.2
mg/kg
1.5
0.73
5
04/13/15 15:00
04/15/15 09:09
7440-47-3
D3
Copper
11.4
mg/kg
1.5
0.73
5
04/13/15 15:00
04/15/15 09:09
7440-50-8
D3
Iron
24100
mg/kg
11.7
5.8
5
04/13/15 15:00
04/15/15 09:09
7439-89-6
D3
Magnesium
2170
mg/kg
146
73.0
5
04/13/15 15:00
04/15/15 09:09
7439-95-4
D3
Manganese
367
mg/kg
1.5
0.73
5
04/13/15 15:00
04/15/15 09:09
7439-96-5
D3
Molybdenum
ND
mg/kg
2.9
1.5
5
04/13/15 15:00
04/15/15 09:09
7439-98-7
Nickel
8.8
mg/kg
1.5
0.73
5
04/13/15 15:00
04/15/15 09:09
7440-02-0
D3
Potassium
ND
mg/kg
292
146
5
04/13/15 15:00
04/15/15 09:09
7440-09-7
D3
Sodium
177J
mg/kg
292
146
5
04/13/15 15:00
04/15/15 09:09
7440-23-5
D3
Strontium
15.9
mg/kg
2.9
1.5
5
04/13/15 15:00
04/15/15 09:09
7440-24-6
D3
Zinc
32.8
mg/kg
5.8
2.9
5
04/13/15 15:00
04/15/15 09:09
7440-66-6
D3
6020 MET ICPMS
Analytical
Method: EPA 6020
Preparation
Method: EPA
3050
Antimony
ND
mg/kg
2.9
1.5
50
04/13/15 15:00
04/16/15 22:16
7440-36-0
N2
Arsenic
ND
mg/kg
5.8
2.9
100
04/13/15 15:00
04/20/1510:35
7440-38-2
Cadmium
ND
mg/kg
0.35
0.18
50
04/13/15 15:00
04/16/15 22:16
7440-43-9
Cobalt
6.4
mg/kg
5.8
2.9
100
04/13/15 15:00
04/20/1510:35
7440-48-4
Lead
8.5
mg/kg
5.8
2.9
100
04/13/15 15:00
04/20/1510:35
7439-92-1
Selenium
ND
mg/kg
5.8
2.9
100
04/13/15 15:00
04/20/1510:35
7782-49-2
Thallium
ND
mg/kg
5.8
2.9
100
04/13/15 15:00
04/20/1510:35
7440-28-0
Vanadium
55.1
mg/kg
5.8
2.9
100
04/13/15 15:00
04/20/1510:35
7440-62-2
7471 Mercury
Analytical
Method: EPA 7471 Preparation
Method: EPA
7471
Mercury
0.019
mg/kg
0.010
0.0050
1
04/13/1515:32
04/14/1513:26
7439-97-6
Percent Moisture
Analytical
Method: ASTM
D2974-87
Percent Moisture
18.3
%
0.10
0.10
1
04/14/15 12:27
9045 pH Soil
Analytical
Method: EPA 9045
pH at 25 Degrees C
5.2
Std. Units
0.10
0.10
1
04/13/15 23:00
300.0 IC Anions, SPLP
Analytical
Method: EPA 300.0
Leachate
Method/Date:
EPA 1312; 04/15/15
00:55
Sulfate
36.6
mg/L
2.4
1.2
1
04/19/1513:50
14808-79-8
353.2 Nitrogen, NO2/NO3, SPLP
Analytical
Method: EPA 353.2
Leachate
Method/Date:
EPA 1312; 04/15/15
00:55
Nitrogen, Nitrate
ND
mg/L
0.24
0.24
1
04/22/15 17:28
H1
4500 Chloride, SPLP
Analytical
Method: SM 4500-CI-E Leachate
Method/Date: EPA 1312; 04/15/15 00:55
Chloride
ND
mg/L
6.1
3.1
1
04/17/15 05:34
16887-00-6
REPORT OF LABORATORY
ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/27/2015 03:40 PM
without the written
consent of Pace Analytical Services, Inc..
Page
43 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098onyfte. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040079
Pace Project No.: 92244130
Sample: 201509511 Lab ID: 92244130006 Collected: 04/01/15 14:36 Received: 04/06/15 14:32 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
9056 IC Anions Analytical Method: EPA 9056
Chloride
ND mg/kg
307
153
5
04/10/15 03:57
16887-00-6 D3
Sulfate
539 mg/kg
307
153
5
04/10/15 03:57
14808-79-8
9056 IC Anions 48hr
Analytical Method: EPA 9056
Nitrate as N
ND mg/kg
30.7
15.3
5
04/10/15 03:57
14797-55-8 H3
Total Organic Carbon Quad
Analytical Method: EPA 9060
Total Organic Carbon
1340 mg/kg
735
368
1
04/22/15 18:12
7440-44-0
Total Organic Carbon
1680 mg/kg
731
366
1
04/22/15 18:18
7440-44-0
Total Organic Carbon
1580 mg/kg
733
366
1
04/22/15 18:24
7440-44-0
Total Organic Carbon
1530 mg/kg
731
366
1
04/22/15 18:30
7440-44-0
Mean Total Organic Carbon
1530 mg/kg
732
366
1
04/22/15 18:12
7440-44-0
Surrogates
RSD%
9.2 %
1
04/22/15 18:12
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/27/2015 03:40 PM without the written consent of Pace Analytical Services, Inc..
Page 44 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098g i vfte. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040079
Pace Project No.: 92244130
Sample: 201509512 Lab ID: 92244130007 Collected: 04/01/15 16:00 Received: 04/06/15 14:32 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Aluminum
Barium
Beryllium
Boron
Calcium
Chromium
Copper
Iron
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Sodium
Strontium
Zinc
6020 MET ICPMS
Antimony
Arsenic
Cadmium
Cobalt
Lead
Selenium
Thallium
Vanadium
7471 Mercury
Mercury
Percent Moisture
Percent Moisture
9045 pH Soil
pH at 25 Degrees C
300.0 IC Anions, SPLP
Sulfate
353.2 Nitrogen, NO2/NO3, SPLP
Nitrogen, Nitrate
4500 Chloride, SPLP
Chloride
Date: 04/27/2015 03:40 PM
Analytical Method: EPA 6010 Preparation Method: EPA 3050
13900
mg/kg
28.5
14.2
5
04/13/15 15:00
04/16/15 08:45
7429-90-5
189
mg/kg
2.8
1.4
5
04/13/15 15:00
04/16/15 08:45
7440-39-3
0.44
mg/kg
0.28
0.14
5
04/13/15 15:00
04/16/15 08:45
7440-41-7
13.2J
mg/kg
14.2
7.1
5
04/13/15 15:00
04/16/15 08:45
7440-42-8
1770
mg/kg
142
71.2
5
04/13/15 15:00
04/16/15 08:45
7440-70-2
20.9
mg/kg
1.4
0.71
5
04/13/15 15:00
04/16/15 08:45
7440-47-3
12.0
mg/kg
1.4
0.71
5
04/13/15 15:00
04/16/15 08:45
7440-50-8
11400
mg/kg
11.4
5.7
5
04/13/15 15:00
04/16/15 08:45
7439-89-6
3730
mg/kg
142
71.2
5
04/13/15 15:00
04/16/15 08:45
7439-95-4
116
mg/kg
1.4
0.71
5
04/13/15 15:00
04/16/15 08:45
7439-96-5
ND
mg/kg
2.8
1.4
5
04/13/15 15:00
04/16/15 08:45
7439-98-7
8.8
mg/kg
1.4
0.71
5
04/13/15 15:00
04/16/15 08:45
7440-02-0
426
mg/kg
285
142
5
04/13/15 15:00
04/16/15 08:45
7440-09-7
709
mg/kg
285
142
5
04/13/15 15:00
04/16/15 08:45
7440-23-5
27.6
mg/kg
2.8
1.4
5
04/13/15 15:00
04/16/15 08:45
7440-24-6
32.4
mg/kg
5.7
2.8
5
04/13/15 15:00
04/16/15 08:45
7440-66-6
Analytical
Method: EPA 6020 Preparation
Method: EPA 3050
ND
mg/kg
2.8
1.4
50
04/13/15 15:00
04/16/15 22:18
7440-36-0
ND
mg/kg
5.7
2.8
100
04/13/15 15:00
04/20/1510:37
7440-38-2
ND
mg/kg
0.34
0.17
50
04/13/15 15:00
04/16/15 22:18
7440-43-9
3AJ
mg/kg
5.7
2.8
100
04/13/15 15:00
04/20/1510:37
7440-48-4
6.2
mg/kg
5.7
2.8
100
04/13/15 15:00
04/20/1510:37
7439-92-1
ND
mg/kg
5.7
2.8
100
04/13/15 15:00
04/20/1510:37
7782-49-2
ND
mg/kg
2.8
1.4
50
04/13/15 15:00
04/16/15 22:18
7440-28-0
22.3
mg/kg
5.7
2.8
100
04/13/15 15:00
04/20/1510:37
7440-62-2
Analytical Method: EPA 7471 Preparation Method: EPA 7471
0.042 mg/kg 0.0096 0.0048 1 04/13/1515:32 04/14/1513:29 7439-97-6
Analytical Method: ASTM D2974-87
16.6 % 0.10 0.10 1 04/14/1512:28
Analytical Method: EPA 9045
8.1 Std. Units 0.10 0.10 1 04/13/15 16:20
N2
Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 04/15/15 00:55
14.3 mg/L 2.4 1.2 1 04/19/1514:03 14808-79-8 B
Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 04/15/15 00:55
0.29 mg/L 0.24 0.24 1 04/22/1517:29 H1
Analytical Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 04/15/15 00:55
3.2J mg/L 6.0 3.0 1 04/17/15 05:36 16887-00-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 45 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098onyfte. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040079
Pace Project No.: 92244130
Sample: 201509512 Lab ID: 92244130007 Collected: 04/01/15 16:00 Received: 04/06/15 14:32 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
9056 IC Anions Analytical Method: EPA 9056
Chloride
ND mg/kg
296
148
5
04/10/15 04:18
16887-00-6 D3
Sulfate
233J mg/kg
296
148
5
04/10/15 04:18
14808-79-8
9056 IC Anions 48hr
Analytical Method: EPA 9056
Nitrate as N
ND mg/kg
29.6
14.8
5
04/10/15 04:18
14797-55-8 H3
Total Organic Carbon Quad
Analytical Method: EPA 9060
Total Organic Carbon
850 mg/kg
725
362
1
04/22/15 18:37
7440-44-0
Total Organic Carbon
871 mg/kg
724
362
1
04/22/15 18:42
7440-44-0
Total Organic Carbon
858 mg/kg
713
357
1
04/22/15 18:47
7440-44-0
Total Organic Carbon
915 mg/kg
715
358
1
04/22/15 18:53
7440-44-0
Mean Total Organic Carbon
873 mg/kg
719
360
1
04/22/15 18:37
7440-44-0
Surrogates
RSD%
3.3 %
1
04/22/15 18:37
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/27/2015 03:40 PM without the written consent of Pace Analytical Services, Inc..
Page 46 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098onyfte. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040079
Pace Project No.: 92244130
Sample: 201509513 Lab ID: 92244130008 Collected: 04/01/15 16:30 Received: 04/06/15 14:32 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Aluminum
Barium
Beryllium
Boron
Calcium
Chromium
Copper
Iron
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Sodium
Strontium
Zinc
6020 MET ICPMS
Antimony
Arsenic
Cadmium
Cobalt
Lead
Selenium
Thallium
Vanadium
7471 Mercury
Mercury
Percent Moisture
Percent Moisture
9045 pH Soil
pH at 25 Degrees C
300.0 IC Anions, SPLP
Sulfate
353.2 Nitrogen, NO2/NO3, SPLP
Nitrogen, Nitrate
4500 Chloride, SPLP
Chloride
Date: 04/27/2015 03:40 PM
Analytical Method: EPA 6010 Preparation Method: EPA 3050
5500
mg/kg
29.2
14.6
5
04/13/15 15:00
04/16/15 08:49
7429-90-5
41.3
mg/kg
2.9
1.5
5
04/13/15 15:00
04/16/15 08:49
7440-39-3
0.27J
mg/kg
0.29
0.15
5
04/13/15 15:00
04/16/15 08:49
7440-41-7
15.5
mg/kg
14.6
7.3
5
04/13/15 15:00
04/16/15 08:49
7440-42-8
496
mg/kg
146
73.0
5
04/13/15 15:00
04/16/15 08:49
7440-70-2
6.0
mg/kg
1.5
0.73
5
04/13/15 15:00
04/16/15 08:49
7440-47-3
6.6
mg/kg
1.5
0.73
5
04/13/15 15:00
04/16/15 08:49
7440-50-8
13500
mg/kg
11.7
5.8
5
04/13/15 15:00
04/16/15 08:49
7439-89-6
1240
mg/kg
146
73.0
5
04/13/15 15:00
04/16/15 08:49
7439-95-4
614
mg/kg
1.5
0.73
5
04/13/15 15:00
04/16/15 08:49
7439-96-5
ND
mg/kg
2.9
1.5
5
04/13/15 15:00
04/16/15 08:49
7439-98-7
4.4
mg/kg
1.5
0.73
5
04/13/15 15:00
04/16/15 08:49
7440-02-0
322
mg/kg
292
146
5
04/13/15 15:00
04/16/15 08:49
7440-09-7
ND
mg/kg
292
146
5
04/13/15 15:00
04/16/15 08:49
7440-23-5
6.5
mg/kg
2.9
1.5
5
04/13/15 15:00
04/16/15 08:49
7440-24-6
15.7
mg/kg
5.8
2.9
5
04/13/15 15:00
04/16/15 08:49
7440-66-6
Analytical
Method: EPA 6020 Preparation
Method: EPA 3050
ND
mg/kg
2.9
1.5
50
04/13/15 15:00
04/16/15 22:20
7440-36-0
ND
mg/kg
2.9
1.5
50
04/13/15 15:00
04/16/15 22:20
7440-38-2
ND
mg/kg
0.35
0.18
50
04/13/15 15:00
04/16/15 22:20
7440-43-9
5.2
mg/kg
2.9
1.5
50
04/13/15 15:00
04/16/15 22:20
7440-48-4
4.9J
mg/kg
5.8
2.9
100
04/13/15 15:00
04/20/1510:46
7439-92-1
ND
mg/kg
2.9
1.5
50
04/13/15 15:00
04/16/15 22:20
7782-49-2
ND
mg/kg
2.9
1.5
50
04/13/15 15:00
04/16/15 22:20
7440-28-0
18.4
mg/kg
2.9
1.5
50
04/13/15 15:00
04/16/15 22:20
7440-62-2
Analytical Method: EPA 7471 Preparation Method: EPA 7471
0.0048J mg/kg 0.0096 0.0048 1 04/13/1515:32 04/14/1513:31 7439-97-6
Analytical Method: ASTM D2974-87
16.9 % 0.10 0.10 1 04/14/1512:29
Analytical Method: EPA 9045
5.5 Std. Units 0.10 0.10 1 04/13/15 16:20
N2
Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 04/15/15 00:55
4.4 mg/L 2.4 1.2 1 04/19/1514:17 14808-79-8 B
Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 04/15/15 00:55
ND mg/L 0.24 0.24 1 04/22/1517:30 H1
Analytical Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 04/15/15 00:55
ND mg/L 6.0 3.0 1 04/17/15 05:37 16887-00-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 47 of 82

aceAnaiXical
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Pace Analytical Services, Inc.
098oinyfte. Suite 100
y Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040079
Pace Project No.: 92244130
Sample: 201509513 Lab ID: 92244130008 Collected: 04/01/15 16:30 Received: 04/06/15 14:32 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
9056 IC Anions Analytical Method: EPA 9056
Chloride
ND mg/kg
306
153
5
04/10/15 04:40
16887-00-6 D3
Sulfate
ND mg/kg
306
153
5
04/10/15 04:40
14808-79-8 D3
9056 IC Anions 48hr
Analytical Method: EPA 9056
Nitrate as N
ND mg/kg
30.6
15.3
5
04/10/15 04:40
14797-55-8 H3
Total Organic Carbon Quad
Analytical Method: EPA 9060
Total Organic Carbon
526J mg/kg
720
360
1
04/22/15 18:59
7440-44-0
Total Organic Carbon
536J mg/kg
723
361
1
04/22/15 19:05
7440-44-0
Total Organic Carbon
543J mg/kg
719
360
1
04/22/15 19:11
7440-44-0
Total Organic Carbon
512J mg/kg
727
364
1
04/22/15 19:16
7440-44-0
Mean Total Organic Carbon
529J mg/kg
722
361
1
04/22/15 18:59
7440-44-0
Surrogates
RSD%
2.5 %
1
04/22/15 18:59
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/27/2015 03:40 PM without the written consent of Pace Analytical Services, Inc..
Page 48 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098oinvfte. Suite 100
y Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040079
Pace Project No.: 92244130
Sample: 201509509
Lab ID:
92244130009 Collected:
03/30/15 17:00
Received: 04/06/15 14:32 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample
size and any dilutions.
Report
Parameters
Results
Units Limit
MDL
DF
Prepared
Analyzed
CAS No. Qual
6010 MET ICP
Analytical
Method: EPA 6010
Preparation
Method: EPA
3050
Aluminum
10500
mg/kg
31.7
15.8
5
04/13/15 15:00
04/16/15 08:54
7429-90-5
Barium
80.2
mg/kg
3.2
1.6
5
04/13/15 15:00
04/16/15 08:54
7440-39-3
Beryllium
0.43
mg/kg
0.32
0.16
5
04/13/15 15:00
04/16/15 08:54
7440-41-7
Boron
27.1
mg/kg
15.8
7.9
5
04/13/15 15:00
04/16/15 08:54
7440-42-8
Calcium
317
mg/kg
158
79.2
5
04/13/15 15:00
04/16/15 08:54
7440-70-2
Chromium
14.4
mg/kg
1.6
0.79
5
04/13/15 15:00
04/16/15 08:54
7440-47-3
Copper
14.4
mg/kg
1.6
0.79
5
04/13/15 15:00
04/16/15 08:54
7440-50-8
Iron
25100
mg/kg
12.7
6.3
5
04/13/15 15:00
04/16/15 08:54
7439-89-6
Magnesium
1450
mg/kg
158
79.2
5
04/13/15 15:00
04/16/15 08:54
7439-95-4
Manganese
322
mg/kg
1.6
0.79
5
04/13/15 15:00
04/16/15 08:54
7439-96-5
Molybdenum
ND
mg/kg
3.2
1.6
5
04/13/15 15:00
04/16/15 08:54
7439-98-7
Nickel
8.5
mg/kg
1.6
0.79
5
04/13/15 15:00
04/16/15 08:54
7440-02-0
Potassium
193J
mg/kg
317
158
5
04/13/15 15:00
04/16/15 08:54
7440-09-7
Sodium
ND
mg/kg
317
158
5
04/13/15 15:00
04/16/15 08:54
7440-23-5
Strontium
5.8
mg/kg
3.2
1.6
5
04/13/15 15:00
04/16/15 08:54
7440-24-6
Zinc
28.7
mg/kg
6.3
3.2
5
04/13/15 15:00
04/16/15 08:54
7440-66-6
6020 MET ICPMS
Analytical
Method: EPA 6020
Preparation
Method: EPA
3050
Antimony
ND
mg/kg
3.2
1.6
50
04/13/15 15:00
04/16/15 22:23
7440-36-0 N2
Arsenic
1.91
mg/kg
3.2
1.6
50
04/13/15 15:00
04/16/15 22:23
7440-38-2
Cadmium
ND
mg/kg
0.38
0.19
50
04/13/15 15:00
04/16/15 22:23
7440-43-9
Cobalt
5.3
mg/kg
3.2
1.6
50
04/13/15 15:00
04/16/15 22:23
7440-48-4
Lead
10.9
mg/kg
6.3
3.2
100
04/13/15 15:00
04/20/1510:48
7439-92-1
Selenium
ND
mg/kg
3.2
1.6
50
04/13/15 15:00
04/16/15 22:23
7782-49-2
Thallium
ND
mg/kg
3.2
1.6
50
04/13/15 15:00
04/16/15 22:23
7440-28-0
Vanadium
34.9
mg/kg
3.2
1.6
50
04/13/15 15:00
04/16/15 22:23
7440-62-2
7471 Mercury
Analytical
Method: EPA 7471
Preparation
Method: EPA
7471
Mercury
0.033
mg/kg
0.011
0.0053
1
04/13/1515:32
04/14/1513:37
7439-97-6
Percent Moisture
Analytical
Method: ASTM D2974-87
Percent Moisture
23.5
%
0.10
0.10
1
04/14/15 12:30
9045 pH Soil
Analytical
Method: EPA 9045
pH at 25 Degrees C
4.4
Std. Units
0.10
0.10
1
04/13/15 23:00
9056 IC Anions
Analytical
Method: EPA 9056
Chloride
ND
mg/kg
322
161
5
04/10/15 05:01
16887-00-6 D3
Sulfate
364
mg/kg
322
161
5
04/10/15 05:01
14808-79-8
9056 IC Anions 48hr
Analytical
Method: EPA 9056
Nitrate as N
ND
mg/kg
32.2
16.1
5
04/10/15 05:01
14797-55-8 H3
Date: 04/27/2015 03:40 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 49 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098oinyfte. Suite 100
y Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040079
Pace Project No.: 92244130
Sample: 201509509
Lab ID:
92244130009
Collected:
03/30/15 17:00
Received: 04/06/15 14:32 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample
size and any dilutions.
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared Analyzed
CAS No. Qual
Total Organic Carbon Quad
Analytical
Method: EPA 9060
Total Organic Carbon
1450
mg/kg
779
390
1
04/22/15 19:23
7440-44-0
Total Organic Carbon
1300
mg/kg
786
393
1
04/22/15 19:28
7440-44-0
Total Organic Carbon
1340
mg/kg
786
393
1
04/22/15 19:35
7440-44-0
Total Organic Carbon
1320
mg/kg
788
394
1
04/22/15 19:40
7440-44-0
Mean Total Organic Carbon
1350
mg/kg
785
392
1
04/22/15 19:23
7440-44-0
Surrogates
RSD%
4.8
%
1
04/22/15 19:23
Date: 04/27/2015 03:40 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 50 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098oinyfte. Suite 100
y Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040079
Pace Project No.: 92244130
Sample: 201509506 SPLP Lab ID: 92244130010 Collected: 04/01/15 16:20 Received: 04/06/15 14:32 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
;T➢Z17c\�iil=11 a
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Sodium
Strontium
Thallium
Vanadium
Zinc
7470A Mercury
Mercury
Date: 04/27/2015 03:40 PM
Analytical Method: EPA 6020A Preparation Method: EPA 3020
969
ug/L
10.0
3.0
1
04/22/1514:54
04/23/1514:36
7429-90-5
ND
ug/L
0.50
0.15
1
04/22/1514:54
04/23/1514:36
7440-36-0
0.33J
ug/L
0.50
0.11
1
04/22/1514:54
04/23/1514:36
7440-38-2
147
ug/L
0.30
0.081
1
04/22/1514:54
04/23/1514:36
7440-39-3
0.21
ug/L
0.20
0.067
1
04/22/1514:54
04/23/1514:36
7440-41-7
51.5
ug/L
5.0
1.1
1
04/22/1514:54
04/23/1514:36
7440-42-8
0.19
ug/L
0.080
0.024
1
04/22/1514:54
04/23/1514:36
7440-43-9
88700
ug/L
400
160
10
04/22/1514:54
04/23/1515:24
7440-70-2
0.52
ug/L
0.50
0.17
1
04/22/1514:54
04/23/1514:36
7440-47-3
2.4
ug/L
0.50
0.13
1
04/22/1514:54
04/23/1514:36
7440-48-4
3.9
ug/L
1.0
0.21
1
04/22/1514:54
04/23/1514:36
7440-50-8
160
ug/L
50.0
13.7
1
04/22/1514:54
04/23/1514:36
7439-89-6
4.7
ug/L
0.10
0.046
1
04/22/1514:54
04/23/1514:36
7439-92-1
546
ug/L
10.0
3.2
1
04/22/1514:54
04/23/1514:36
7439-95-4
128
ug/L
0.50
0.24
1
04/22/1514:54
04/23/1514:36
7439-96-5
ND
ug/L
0.50
0.094
1
04/22/1514:54
04/23/1514:36
7439-98-7
6.0
ug/L
0.50
0.16
1
04/22/1514:54
04/23/1514:36
7440-02-0
1020
ug/L
50.0
11.7
1
04/22/1514:54
04/23/1514:36
7440-09-7
0.92
ug/L
0.50
0.20
1
04/22/1514:54
04/23/1514:36
7782-49-2
799
ug/L
50.0
16.3
1
04/22/1514:54
04/23/1514:36
7440-23-5
89.6
ug/L
0.50
0.13
1
04/22/1514:54
04/23/1514:36
7440-24-6
0.060J
ug/L
0.10
0.015
1
04/22/1514:54
04/23/1514:36
7440-28-0
ND
ug/L
1.0
0.28
1
04/22/1514:54
04/23/1514:36
7440-62-2
143
ug/L
5.0
2.4
1
04/22/1514:54
04/23/1514:36
7440-66-6
Analytical Method: EPA 7470A Preparation Method: EPA 7470A
ND ug/L 0.20 0.022 1 04/22/1517:55 04/23/1519:36 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 51 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098mvfte. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040079
Pace Project No.: 92244130
Sample: 201509507 SPLP Lab ID: 92244130011 Collected: 03/30/15 16:40 Received: 04/06/15 14:32 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
;T➢Z17c\�iil=11 a
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Sodium
Strontium
Thallium
Vanadium
Zinc
7470A Mercury
Mercury
Date: 04/27/2015 03:40 PM
Analytical Method: EPA 6020A Preparation Method: EPA 3020
13600
ug/L
10.0
3.0
1
04/22/1514:54
04/23/1514:39
7429-90-5
ND
ug/L
0.50
0.15
1
04/22/1514:54
04/23/1514:39
7440-36-0
8.6
ug/L
0.50
0.11
1
04/22/1514:54
04/23/1514:39
7440-38-2
149
ug/L
0.30
0.081
1
04/22/1514:54
04/23/1514:39
7440-39-3
15.5
ug/L
0.20
0.067
1
04/22/1514:54
04/23/1514:39
7440-41-7
168
ug/L
5.0
1.1
1
04/22/1514:54
04/23/1514:39
7440-42-8
8.0
ug/L
0.080
0.024
1
04/22/1514:54
04/23/1514:39
7440-43-9
4940
ug/L
40.0
16.0
1
04/22/1514:54
04/23/1514:39
7440-70-2
2.1
ug/L
0.50
0.17
1
04/22/1514:54
04/23/1514:39
7440-47-3
127
ug/L
0.50
0.13
1
04/22/1514:54
04/23/1514:39
7440-48-4
88.5
ug/L
1.0
0.21
1
04/22/1514:54
04/23/1514:39
7440-50-8
1950
ug/L
50.0
13.7
1
04/22/1514:54
04/23/1514:39
7439-89-6
1.9
ug/L
0.10
0.046
1
04/22/1514:54
04/23/1514:39
7439-92-1
6310
ug/L
10.0
3.2
1
04/22/1514:54
04/23/1514:39
7439-95-4
2060
ug/L
5.0
2.4
10
04/22/1514:54
04/23/1515:27
7439-96-5
ND
ug/L
0.50
0.094
1
04/22/1514:54
04/23/1514:39
7439-98-7
320
ug/L
0.50
0.16
1
04/22/1514:54
04/23/1514:39
7440-02-0
1860
ug/L
50.0
11.7
1
04/22/1514:54
04/23/1514:39
7440-09-7
3.6
ug/L
0.50
0.20
1
04/22/1514:54
04/23/1514:39
7782-49-2
2320
ug/L
50.0
16.3
1
04/22/1514:54
04/23/1514:39
7440-23-5
398
ug/L
0.50
0.13
1
04/22/1514:54
04/23/1514:39
7440-24-6
0.77
ug/L
0.10
0.015
1
04/22/1514:54
04/23/1514:39
7440-28-0
ND
ug/L
1.0
0.28
1
04/22/1514:54
04/23/1514:39
7440-62-2
1640
ug/L
50.0
24.1
10
04/22/1514:54
04/23/1515:27
7440-66-6
Analytical Method: EPA 7470A Preparation Method: EPA 7470A
ND ug/L 0.20 0.022 1 04/22/1517:55 04/23/1519:38 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 52 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098oinyfte. Suite 100
y Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040079
Pace Project No.: 92244130
Sample: 201509508 SPLP Lab ID: 92244130012 Collected: 03/30/15 16:50 Received: 04/06/15 14:32 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
;T➢Z17c\�iil=11 a
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Sodium
Strontium
Thallium
Vanadium
Zinc
7470A Mercury
Mercury
Date: 04/27/2015 03:40 PM
Analytical Method: EPA 6020A Preparation Method: EPA 3020
6730
ug/L
10.0
3.0
1
04/22/1514:54
04/23/1514:41
7429-90-5
ND
ug/L
0.50
0.15
1
04/22/1514:54
04/23/1514:41
7440-36-0
1.4
ug/L
0.50
0.11
1
04/22/1514:54
04/23/1514:41
7440-38-2
422
ug/L
0.30
0.081
1
04/22/1514:54
04/23/1514:41
7440-39-3
0.45
ug/L
0.20
0.067
1
04/22/1514:54
04/23/1514:41
7440-41-7
161
ug/L
5.0
1.1
1
04/22/1514:54
04/23/1514:41
7440-42-8
ND
ug/L
0.080
0.024
1
04/22/1514:54
04/23/1514:41
7440-43-9
1520
ug/L
40.0
16.0
1
04/22/1514:54
04/23/1514:41
7440-70-2
9.7
ug/L
0.50
0.17
1
04/22/1514:54
04/23/1514:41
7440-47-3
9.6
ug/L
0.50
0.13
1
04/22/1514:54
04/23/1514:41
7440-48-4
8.8
ug/L
1.0
0.21
1
04/22/1514:54
04/23/1514:41
7440-50-8
8720
ug/L
50.0
13.7
1
04/22/1514:54
04/23/1514:41
7439-89-6
12.8
ug/L
0.10
0.046
1
04/22/1514:54
04/23/1514:41
7439-92-1
461
ug/L
10.0
3.2
1
04/22/1514:54
04/23/1514:41
7439-95-4
162
ug/L
0.50
0.24
1
04/22/1514:54
04/23/1514:41
7439-96-5
ND
ug/L
0.50
0.094
1
04/22/1514:54
04/23/1514:41
7439-98-7
2.3
ug/L
0.50
0.16
1
04/22/1514:54
04/23/1514:41
7440-02-0
495
ug/L
50.0
11.7
1
04/22/1514:54
04/23/1514:41
7440-09-7
0.27J
ug/L
0.50
0.20
1
04/22/1514:54
04/23/1514:41
7782-49-2
3300
ug/L
50.0
16.3
1
04/22/1514:54
04/23/1514:41
7440-23-5
25.7
ug/L
0.50
0.13
1
04/22/1514:54
04/23/1514:41
7440-24-6
0.057J
ug/L
0.10
0.015
1
04/22/1514:54
04/23/1514:41
7440-28-0
37.6
ug/L
1.0
0.28
1
04/22/1514:54
04/23/1514:41
7440-62-2
192
ug/L
5.0
2.4
1
04/22/1514:54
04/23/1514:41
7440-66-6
Analytical Method: EPA 7470A Preparation Method: EPA 7470A
0.17J ug/L 0.20 0.022 1 04/22/1517:55 04/23/1519:41 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 53 of 82

aceAnaiXical
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Pace Analytical Services, Inc.
098oinyfte. Suite 100
y Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040079
Pace Project No.: 92244130
Sample: 201509511 SPLP Lab ID: 92244130013 Collected: 04/01/15 14:36 Received: 04/06/15 14:32 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
;T➢Z17c\�iil=11 a
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Sodium
Strontium
Thallium
Vanadium
Zinc
7470A Mercury
Mercury
Date: 04/27/2015 03:40 PM
Analytical Method: EPA 6020A Preparation Method: EPA 3020
16300
ug/L
10.0
3.0
1
04/22/1514:54
04/23/1514:44
7429-90-5
ND
ug/L
0.50
0.15
1
04/22/1514:54
04/23/1514:44
7440-36-0
1.1
ug/L
0.50
0.11
1
04/22/1514:54
04/23/1514:44
7440-38-2
248
ug/L
0.30
0.081
1
04/22/1514:54
04/23/1514:44
7440-39-3
0.64
ug/L
0.20
0.067
1
04/22/1514:54
04/23/1514:44
7440-41-7
148
ug/L
5.0
1.1
1
04/22/1514:54
04/23/1514:44
7440-42-8
0.034J
ug/L
0.080
0.024
1
04/22/1514:54
04/23/1514:44
7440-43-9
2500
ug/L
40.0
16.0
1
04/22/1514:54
04/23/1514:44
7440-70-2
17.4
ug/L
0.50
0.17
1
04/22/1514:54
04/23/1514:44
7440-47-3
3.1
ug/L
0.50
0.13
1
04/22/1514:54
04/23/1514:44
7440-48-4
9.6
ug/L
1.0
0.21
1
04/22/1514:54
04/23/1514:44
7440-50-8
14600
ug/L
50.0
13.7
1
04/22/1514:54
04/23/1514:44
7439-89-6
4.5
ug/L
0.10
0.046
1
04/22/1514:54
04/23/1514:44
7439-92-1
3100
ug/L
10.0
3.2
1
04/22/1514:54
04/23/1514:44
7439-95-4
150
ug/L
0.50
0.24
1
04/22/1514:54
04/23/1514:44
7439-96-5
ND
ug/L
0.50
0.094
1
04/22/1514:54
04/23/1514:44
7439-98-7
8.1
ug/L
0.50
0.16
1
04/22/1514:54
04/23/1514:44
7440-02-0
604
ug/L
50.0
11.7
1
04/22/1514:54
04/23/1514:44
7440-09-7
0.42J
ug/L
0.50
0.20
1
04/22/1514:54
04/23/1514:44
7782-49-2
10100
ug/L
50.0
16.3
1
04/22/1514:54
04/23/1514:44
7440-23-5
35.6
ug/L
0.50
0.13
1
04/22/1514:54
04/23/1514:44
7440-24-6
0.10
ug/L
0.10
0.015
1
04/22/1514:54
04/23/1514:44
7440-28-0
31.4
ug/L
1.0
0.28
1
04/22/1514:54
04/23/1514:44
7440-62-2
189
ug/L
5.0
2.4
1
04/22/1514:54
04/23/1514:44
7440-66-6
Analytical Method: EPA 7470A Preparation Method: EPA 7470A
0.0801 ug/L 0.20 0.022 1 04/22/1517:55 04/23/1519:43 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 54 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098g i vfte. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040079
Pace Project No.: 92244130
Sample: 201509512 SPLP Lab ID: 92244130014 Collected: 04/01/15 16:00 Received: 04/06/15 14:32 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
;T➢Z17c\�iil=11 a
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Sodium
Strontium
Thallium
Vanadium
Zinc
7470A Mercury
Mercury
Date: 04/27/2015 03:40 PM
Analytical Method: EPA 6020A Preparation Method: EPA 3020
11500
ug/L
10.0
3.0
1
04/22/1514:54
04/23/1514:47
7429-90-5
ND
ug/L
0.50
0.15
1
04/22/1514:54
04/23/1514:47
7440-36-0
1.3
ug/L
0.50
0.11
1
04/22/1514:54
04/23/1514:47
7440-38-2
334
ug/L
0.30
0.081
1
04/22/1514:54
04/23/1514:47
7440-39-3
0.76
ug/L
0.20
0.067
1
04/22/1514:54
04/23/1514:47
7440-41-7
57.7
ug/L
5.0
1.1
1
04/22/1514:54
04/23/1514:47
7440-42-8
0.034J
ug/L
0.080
0.024
1
04/22/1514:54
04/23/1514:47
7440-43-9
3620
ug/L
40.0
16.0
1
04/22/1514:54
04/23/1514:47
7440-70-2
10.7
ug/L
0.50
0.17
1
04/22/1514:54
04/23/1514:47
7440-47-3
3.6
ug/L
0.50
0.13
1
04/22/1514:54
04/23/1514:47
7440-48-4
11.6
ug/L
1.0
0.21
1
04/22/1514:54
04/23/1514:47
7440-50-8
7510
ug/L
50.0
13.7
1
04/22/1514:54
04/23/1514:47
7439-89-6
6.2
ug/L
0.10
0.046
1
04/22/1514:54
04/23/1514:47
7439-92-1
3890
ug/L
10.0
3.2
1
04/22/1514:54
04/23/1514:47
7439-95-4
126
ug/L
0.50
0.24
1
04/22/1514:54
04/23/1514:47
7439-96-5
0.20J
ug/L
0.50
0.094
1
04/22/1514:54
04/23/1514:47
7439-98-7
6.2
ug/L
0.50
0.16
1
04/22/1514:54
04/23/1514:47
7440-02-0
542
ug/L
50.0
11.7
1
04/22/1514:54
04/23/1514:47
7440-09-7
0.53
ug/L
0.50
0.20
1
04/22/1514:54
04/23/1514:47
7782-49-2
10300
ug/L
50.0
16.3
1
04/22/1514:54
04/23/1514:47
7440-23-5
51.9
ug/L
0.50
0.13
1
04/22/1514:54
04/23/1514:47
7440-24-6
0.071J
ug/L
0.10
0.015
1
04/22/1514:54
04/23/1514:47
7440-28-0
35.5
ug/L
1.0
0.28
1
04/22/1514:54
04/23/1514:47
7440-62-2
88.0
ug/L
5.0
2.4
1
04/22/1514:54
04/23/1514:47
7440-66-6
Analytical Method: EPA 7470A Preparation Method: EPA 7470A
0.13J ug/L 0.20 0.022 1 04/22/1517:55 04/23/1519:45 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 55 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098oinyfte. Suite 100
y Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15040079
Pace Project No.: 92244130
Sample: 201509513 SPLP Lab ID: 92244130015 Collected: 04/01/15 16:30 Received: 04/06/15 14:32 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
;T➢Z17c\��il=11 a � 6?
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Sodium
Strontium
Thallium
Vanadium
Zinc
7470A Mercury
Mercury
Date: 04/27/2015 03:40 PM
Analytical Method: EPA 6020A Preparation Method: EPA 3020
40900
ug/L
100
29.8
10
04/22/1514:54
04/23/1515:22
7429-90-5
ND
ug/L
0.50
0.15
1
04/22/1514:54
04/23/1514:50
7440-36-0
2.8
ug/L
0.50
0.11
1
04/22/1514:54
04/23/1514:50
7440-38-2
379
ug/L
0.30
0.081
1
04/22/1514:54
04/23/1514:50
7440-39-3
1.4
ug/L
0.20
0.067
1
04/22/1514:54
04/23/1514:50
7440-41-7
80.0
ug/L
5.0
1.1
1
04/22/1514:54
04/23/1514:50
7440-42-8
0.056J
ug/L
0.080
0.024
1
04/22/1514:54
04/23/1514:50
7440-43-9
1320
ug/L
40.0
16.0
1
04/22/1514:54
04/23/1514:50
7440-70-2
29.1
ug/L
0.50
0.17
1
04/22/1514:54
04/23/1514:50
7440-47-3
10
ug/L
0.50
0.13
1
04/22/1514:54
04/23/1514:50
7440-48-4
28.4
ug/L
1.0
0.21
1
04/22/1514:54
04/23/1514:50
7440-50-8
26400
ug/L
500
137
10
04/22/1514:54
04/23/1515:22
7439-89-6
16.3
ug/L
0.10
0.046
1
04/22/1514:54
04/23/1514:50
7439-92-1
1930
ug/L
10.0
3.2
1
04/22/1514:54
04/23/1514:50
7439-95-4
417
ug/L
0.50
0.24
1
04/22/1514:54
04/23/1514:50
7439-96-5
0.181
ug/L
0.50
0.094
1
04/22/1514:54
04/23/1514:50
7439-98-7
15.3
ug/L
0.50
0.16
1
04/22/1514:54
04/23/1514:50
7440-02-0
1420
ug/L
50.0
11.7
1
04/22/1514:54
04/23/1514:50
7440-09-7
0.35J
ug/L
0.50
0.20
1
04/22/1514:54
04/23/1514:50
7782-49-2
2310
ug/L
50.0
16.3
1
04/22/1514:54
04/23/1514:50
7440-23-5
23.4
ug/L
0.50
0.13
1
04/22/1514:54
04/23/1514:50
7440-24-6
0.19
ug/L
0.10
0.015
1
04/22/1514:54
04/23/1514:50
7440-28-0
93.2
ug/L
1.0
0.28
1
04/22/1514:54
04/23/1514:50
7440-62-2
199
ug/L
5.0
2.4
1
04/22/1514:54
04/23/1514:50
7440-66-6
Analytical Method: EPA 7470A Preparation Method: EPA 7470A
0.0501 ug/L 0.20 0.022 1 04/22/1517:55 04/23/1519:51 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 56 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098oinyfte. Suite 100
y Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040079
Pace Project No.: 92244130
QC Batch: MERP/13175
Analysis Method: EPA 7470
QC Batch Method: EPA 7470
Analysis Description: 7470 Mercury
Associated Lab Samples: 92244130001, 92244130002
METHOD BLANK: 1935443
Matrix: Water
Associated Lab Samples: 92244130001, 92244130002
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Mercury ug/L
ND 0.20
04/13/1510:36
LABORATORY CONTROL SAMPLE: 1935444
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Mercury ug/L
5 5.2
105 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1935445 1935446
MS MSD
10301355001
Spike Spike MS
MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec Limits RPD RPD Qual
Mercury ug/L <0.20
5 5 5.2
4.7 104 94 75-125 9 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/27/2015 03:40 PM without the written consent of Pace Analytical Services, Inc..
Page 57 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098onyfte. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040079
Pace Project No.: 92244130
QC Batch: MERP/13312 Analysis Method: EPA 7470A
QC Batch Method: EPA 7470A Analysis Description: 7470A Mercury Water
Associated Lab Samples: 92244130010, 92244130011, 92244130012, 92244130013, 92244130014, 92244130015
METHOD BLANK: 1945562 Matrix: Water
Associated Lab Samples: 92244130010, 92244130011, 92244130012, 92244130013, 92244130014, 92244130015
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Mercury ug/L ND 0.20 04/23/1519:26
LABORATORY CONTROL SAMPLE: 1945563
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Mercury ug/L 5 5.2 104 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1945564 1945565
MS MSD
92246088001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Mercury ug/L ND 5 5 5.0 5.1 100 102 80-120 2 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/27/2015 03:40 PM without the written consent of Pace Analytical Services, Inc..
Page 58 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098onvfte. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040079
Pace Project No.: 92244130
QC Batch: MERP/5584
Analysis Method: EPA 7471
QC Batch Method: EPA 7471
Analysis Description: 7471 Mercury
Associated Lab Samples: 92244130003,92244130004,92244130005,92244130006,92244130007,92244130008,92244130009
METHOD BLANK: 1181576
Matrix: Solid
Associated Lab Samples: 92244130003, 92244130004,
92244130005, 92244130006, 92244130007, 92244130008, 92244130009
Blank Reporting
Parameter Units
Result Limit Analyzed Qualifiers
Mercury mg/kg
ND 0.0081 04/14/1512:48
LABORATORY CONTROL SAMPLE: 1181577
Spike LCS LCS % Rec
Parameter Units
Conc. Result % Rec Limits Qualifiers
Mercury mg/kg
.08 0.076 95 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1181578 1181579
MS MSD
35182748001
Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Mercury mg/kg 0.0083
.0845 .0815 0.085 0.082 90 90 80-120 3 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/27/2015 03:40 PM without the written consent of Pace Analytical Services, Inc..
Page 59 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098onyfte. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040079
Pace Project No.: 92244130
QC Batch: MPRP/23551 Analysis Method: EPA 6010
QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid
Associated Lab Samples: 92244130003, 92244130004, 92244130005, 92244130006, 92244130007, 92244130008, 92244130009
METHOD BLANK: 1181555 Matrix: Solid
Associated Lab Samples: 92244130003, 92244130004, 92244130005, 92244130006, 92244130007, 92244130008, 92244130009
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Aluminum
mg/kg
ND
5.0
04/15/1511:44
Barium
mg/kg
ND
0.50
04/15/1511:44
Beryllium
mg/kg
ND
0.050
04/15/1511:44
Boron
mg/kg
ND
2.5
04/15/1511:44
Calcium
mg/kg
ND
25.2
04/15/1511:44
Chromium
mg/kg
ND
0.25
04/15/1511:44
Copper
mg/kg
ND
0.25
04/15/1511:44
Iron
mg/kg
ND
2.0
04/15/15 07:39
Magnesium
mg/kg
ND
25.2
04/15/15 07:39
Manganese
mg/kg
ND
0.25
04/15/1511:44
Molybdenum
mg/kg
ND
0.50
04/15/15 07:39
Nickel
mg/kg
ND
0.25
04/15/1511:44
Potassium
mg/kg
ND
50.4
04/15/1511:44
Sodium
mg/kg
ND
50.4
04/15/15 07:39
Strontium
mg/kg
ND
0.50
04/15/1511:44
Zinc
mg/kg
ND
1.0
04/15/1511:44
LABORATORY CONTROL SAMPLE:
Parameter
1181556
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
Aluminum
mg/kg
128
134
105
80-120
Barium
mg/kg
12.8
13.2
104
80-120
Beryllium
mg/kg
1.3
1.3
105
80-120
Boron
mg/kg
128
132
104
80-120
Calcium
mg/kg
638
677
106
80-120
Chromium
mg/kg
12.8
12.9
101
80-120
Copper
mg/kg
12.8
12.8
101
80-120
Iron
mg/kg
128
130
102
80-120
Magnesium
mg/kg
638
658
103
80-120
Manganese
mg/kg
12.8
13.4
105
80-120
Molybdenum
mg/kg
12.8
12.8
100
80-120
Nickel
mg/kg
12.8
13.1
103
80-120
Potassium
mg/kg
638
633
99
80-120
Sodium
mg/kg
638
671
105
80-120
Strontium
mg/kg
12.8
13.4
105
80-120
Zinc
mg/kg
63.8
66.1
104
80-120
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/27/2015 03:40 PM without the written consent of Pace Analytical Services, Inc.. Page 60 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098g i vfte. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040079
Pace Project No.: 92244130
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
1181557
1181558
MS
MSD
92244129001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Aluminum
mg/kg
595
126
128
1200
965
480
288
75-125
22
20 D3,M1,
R1
Barium
mg/kg
40.6
12.6
12.8
60.3
43.2
156
20
75-125
33
20 D3,M1,
R1
Beryllium
mg/kg
0.14J
1.3
1.3
1.4
1.4
103
100
75-125
1
20 D3
Boron
mg/kg
ND
126
128
122
125
95
96
75-125
2
20 D3
Calcium
mg/kg
106J
632
642
790
774
108
104
75-125
2
20 D3
Chromium
mg/kg
2.3
12.6
12.8
17.8
14.7
123
97
75-125
19
20 D3
Copper
mg/kg
2.8
12.6
12.8
15.5
14.5
100
91
75-125
6
20 D3
Iron
mg/kg
1820
126
128
2300
1530
376
-228
75-125
40
20 D3,M1,
R1
Magnesium
mg/kg
1081
632
642
763
743
104
99
75-125
3
20 D3
Manganese
mg/kg
25.5
12.6
12.8
36.7
28.6
88
24
75-125
25
20 D3,M1,
R1
Molybdenum
mg/kg
ND
12.6
12.8
12.7
12.3
99
94
75-125
3
20 D3
Nickel
mg/kg
2.3
12.6
12.8
16.1
15.6
110
103
75-125
4
20 D3
Potassium
mg/kg
173J
632
642
768
717
94
85
75-125
7
20 D3
Sodium
mg/kg
ND
632
642
637
624
99
95
75-125
2
20 D3
Strontium
mg/kg
3.6
12.6
12.8
17.5
17.2
110
106
75-125
1
20 D3
Zinc
mg/kg
ND
63.2
64.2
65.4
65.7
101
100
75-125
0
20 D3
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/27/2015 03:40 PM without the written consent of Pace Analytical Services, Inc..
Page 61 of 82

aceAnaiXical
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Pace Analytical Services, Inc.
098g i vfte. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040079
Pace Project No.: 92244130
QC Batch: MPRP/23552 Analysis Method: EPA 6020
QC Batch Method: EPA 3050 Analysis Description: 6020 MET SOLID
Associated Lab Samples: 92244130003,92244130004,92244130005,92244130006,92244130007,92244130008,92244130009
METHOD BLANK: 1181560
Matrix:
Solid
Associated Lab Samples:
92244130003, 92244130004,
92244130005, 92244130006, 92244130007,
92244130008, 92244130009
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Antimony
mg/kg
ND
0.049
04/16/15 21:14 N2
Arsenic
mg/kg
ND
0.049
04/16/15 21:14
Cadmium
mg/kg
ND
0.0059
04/16/15 21:14
Cobalt
mg/kg
ND
0.049
04/16/15 21:14
Lead
mg/kg
ND
0.049
04/16/15 21:14
Selenium
mg/kg
ND
0.049
04/16/15 21:14
Thallium
mg/kg
ND
0.049
04/16/15 21:14
Vanadium
mg/kg
ND
0.049
04/16/15 21:14
LABORATORY CONTROL SAMPLE: 1181561
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits
Qualifiers
Antimony
mg/kg
2.5
2.4
96
80-120
N2
Arsenic
mg/kg
2.5
2.5
101
80-120
Cadmium
mg/kg
.25
0.25
102
80-120
Cobalt
mg/kg
2.5
2.5
101
80-120
Lead
mg/kg
2.5
2.4
95
80-120
Selenium
mg/kg
2.5
2.5
101
80-120
Thallium
mg/kg
2.5
2.5
99
80-120
Vanadium
mg/kg
2.5
2.5
101
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1181562
1181563
MS
MSD
92244129001
Spike
Spike
MS
MSD
MS MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec % Rec
Limits
RPD
RPD Qual
Antimony
mg/kg
ND
2.5
2.5
2.2J
2.2J
88
88
75-125
20 D3,N2
Arsenic
mg/kg
4.8
2.5
2.5
6.1
8.7
53
154
75-125
34
20 D3,M6,
R1
Cadmium
mg/kg
ND
.25
.25
0.24J
0.33
97
131
75-125
20 D3,M6
Cobalt
mg/kg
ND
2.5
2.5
3.4
3.5
108
107
75-125
1
20 D3
Lead
mg/kg
ND
2.5
2.5
3.3
3.3
93
92
75-125
0
20 D3
Selenium
mg/kg
ND
2.5
2.5
2.5
2.5J
84
81
75-125
20 D3
Thallium
mg/kg
ND
2.5
2.5
2.3J
2AJ
84
87
75-125
20 D3
Vanadium
mg/kg
2.5
2.5
2.5
5.4
5.2
119
108
75-125
4
20 D3
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/27/2015 03:40 PM without the written consent of Pace Analytical Services, Inc..
Page 62 of 82

aceAnaiXical
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Pace Analytical Services, Inc.
098onyfte. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040079
Pace Project No.: 92244130
QC Batch: MPRP/53524 Analysis Method: EPA 6020A
QC Batch Method: EPA 3020 Analysis Description: 6020A Water UPD4
Associated Lab Samples: 92244130001, 92244130002
METHOD BLANK: 1936120
Associated Lab Samples: 92244130001, 92244130002
Parameter
Units
Aluminum
ug/L
Antimony
ug/L
Arsenic
ug/L
Barium
ug/L
Beryllium
ug/L
Boron
ug/L
Cadmium
ug/L
Calcium
ug/L
Chromium
ug/L
Cobalt
ug/L
Copper
ug/L
Iron
ug/L
Lead
ug/L
Magnesium
ug/L
Manganese
ug/L
Molybdenum
ug/L
Nickel
ug/L
Potassium
ug/L
Selenium
ug/L
Sodium
ug/L
Strontium
ug/L
Thallium
ug/L
Vanadium
ug/L
Zinc
ug/L
Matrix: Water
Blank
Result
Reporting
Limit
Analyzed
ND
10.0
04/13/1515:11
ND
0.50
04/13/1515:11
ND
0.50
04/13/1515:11
ND
0.30
04/13/1515:11
ND
0.20
04/13/1515:11
ND
5.0
04/13/1515:11
ND
0.080
04/13/1515:11
ND
40.0
04/13/1515:11
ND
0.50
04/13/1515:11
ND
0.50
04/13/1515:11
ND
1.0
04/13/1515:11
ND
50.0
04/13/1515:11
ND
0.10
04/13/1515:11
ND
10.0
04/13/1515:11
ND
0.50
04/13/1515:11
ND
0.50
04/13/1515:11
ND
0.50
04/13/1515:11
ND
50.0
04/13/1515:11
ND
0.50
04/13/1515:11
ND
50.0
04/13/1515:11
ND
0.50
04/13/1515:11
ND
0.10
04/13/1515:11
ND
1.0
04/13/1515:11
ND
5.0
04/13/1515:11
Qualifiers
LABORATORY CONTROL SAMPLE:
Parameter
1936121
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
Aluminum
ug/L
80
87.8
110
80-120
Antimony
ug/L
80
80.7
101
80-120
Arsenic
ug/L
80
83.6
104
80-120
Barium
ug/L
80
84.0
105
80-120
Beryllium
ug/L
80
88.3
110
80-120
Boron
ug/L
80
84.7
106
80-120
Cadmium
ug/L
80
85.3
107
80-120
Calcium
ug/L
1000
1020
102
80-120
Chromium
ug/L
80
82.9
104
80-120
Cobalt
ug/L
80
86.4
108
80-120
Copper
ug/L
80
84.1
105
80-120
Iron
ug/L
1000
1060
106
80-120
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/27/2015 03:40 PM without the written consent of Pace Analytical Services, Inc..
Page 63 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098onyfte. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040079
Pace Project No.: 92244130
LABORATORY CONTROL SAMPLE:
1936121
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits
Qualifiers
Lead
ug/L
80
86.3
108
80-120
Magnesium
ug/L
1000
1100
110
80-120
Manganese
ug/L
80
86.2
108
80-120
Molybdenum
ug/L
80
80.2
100
80-120
Nickel
ug/L
80
87.6
109
80-120
Potassium
ug/L
1000
1100
110
80-120
Selenium
ug/L
80
90.5
113
80-120
Sodium
ug/L
1000
1100
110
80-120
Strontium
ug/L
80
83.4
104
80-120
Thallium
ug/L
80
81.2
102
80-120
Vanadium
ug/L
80
82.8
104
80-120
Zinc
ug/L
80
88.4
110
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
1936122
1936123
MS
MSD
92244129006
Spike
Spike
MS
MSD
MS MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec % Rec
Limits
RPD
RPD Qual
Aluminum
ug/L
24.4
80
80
154
137
162
140
75-125
12
20 M1
Antimony
ug/L
ND
80
80
82.1
80.6
103
101
75-125
2
20
Arsenic
ug/L
ND
80
80
84.4
83.0
106
104
75-125
2
20
Barium
ug/L
0.43
80
80
83.8
82.5
104
103
75-125
2
20
Beryllium
ug/L
ND
80
80
85.8
84.8
107
106
75-125
1
20
Boron
ug/L
ND
80
80
90.6
86.8
111
106
75-125
4
20
Cadmium
ug/L
ND
80
80
85.5
84.8
107
106
75-125
1
20
Calcium
ug/L
110
1000
1000
1130
1170
102
106
75-125
3
20
Chromium
ug/L
0.53
80
80
83.5
83.0
104
103
75-125
1
20
Cobalt
ug/L
ND
80
80
86.6
85.8
108
107
75-125
1
20
Copper
ug/L
ND
80
80
85.6
85.4
106
106
75-125
0
20
Iron
ug/L
116
1000
1000
1190
1180
107
106
75-125
1
20
Lead
ug/L
0.11
80
80
86.4
86.5
108
108
75-125
0
20
Magnesium
ug/L
33.3
1000
1000
1140
1120
111
109
75-125
1
20
Manganese
ug/L
3.0
80
80
90.5
89.0
109
108
75-125
2
20
Molybdenum
ug/L
ND
80
80
80.5
79.9
100
99
75-125
1
20
Nickel
ug/L
ND
80
80
88.1
86.9
110
108
75-125
1
20
Potassium
ug/L
ND
1000
1000
1140
1130
110
108
75-125
1
20
Selenium
ug/L
ND
80
80
86.6
90.0
108
112
75-125
4
20
Sodium
ug/L
ND
1000
1000
1150
1140
110
109
75-125
1
20
Strontium
ug/L
0.58
80
80
83.8
82.8
104
103
75-125
1
20
Thallium
ug/L
ND
80
80
81.0
82.1
101
103
75-125
1
20
Vanadium
ug/L
ND
80
80
84.2
83.6
105
104
75-125
1
20
Zinc
ug/L
ND
80
80
90.6
90.9
110
111
75-125
0
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/27/2015 03:40 PM without the written consent of Pace Analytical Services, Inc..
Page 64 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098g i vfte. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040079
Pace Project No.: 92244130
QC Batch: MPRP/53815 Analysis Method: EPA 6020A
QC Batch Method: EPA 3020 Analysis Description: 6020A Water UPD4
Associated Lab Samples: 92244130010, 92244130011, 92244130012, 92244130013, 92244130014, 92244130015
METHOD BLANK: 1945264 Matrix: Water
Associated Lab Samples: 92244130010, 92244130011, 92244130012, 92244130013, 92244130014, 92244130015
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Aluminum
ug/L
4.7J
10.0
04/24/1511:23
Antimony
ug/L
ND
0.50
04/24/1511:23
Arsenic
ug/L
ND
0.50
04/24/1511:23
Barium
ug/L
ND
0.30
04/24/1511:23
Beryllium
ug/L
ND
0.20
04/24/1511:23
Boron
ug/L
ND
5.0
04/24/1511:23
Cadmium
ug/L
ND
0.080
04/24/1511:23
Calcium
ug/L
ND
40.0
04/24/1511:23
Chromium
ug/L
ND
0.50
04/24/1511:23
Cobalt
ug/L
ND
0.50
04/24/1511:23
Copper
ug/L
ND
1.0
04/24/1511:23
Iron
ug/L
ND
50.0
04/24/1511:23
Lead
ug/L
ND
0.10
04/24/1511:23
Magnesium
ug/L
4.2J
10.0
04/24/1511:23
Manganese
ug/L
0.67
0.50
04/24/1511:23 P8
Molybdenum
ug/L
ND
0.50
04/24/1511:23
Nickel
ug/L
ND
0.50
04/24/1511:23
Potassium
ug/L
ND
50.0
04/24/1511:23
Selenium
ug/L
ND
0.50
04/24/1511:23
Sodium
ug/L
ND
50.0
04/24/1511:23
Strontium
ug/L
ND
0.50
04/24/1511:23
Thallium
ug/L
ND
0.10
04/24/1511:23
Vanadium
ug/L
ND
1.0
04/24/1511:23
Zinc
ug/L
ND
5.0
04/24/1511:23
LABORATORY CONTROL SAMPLE:
Parameter
1945265
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
Aluminum
ug/L
80
89.9
112
80-120
Antimony
ug/L
80
82.0
102
80-120
Arsenic
ug/L
80
80.0
100
80-120
Barium
ug/L
80
82.2
103
80-120
Beryllium
ug/L
80
81.5
102
80-120
Boron
ug/L
80
84.7
106
80-120
Cadmium
ug/L
80
82.4
103
80-120
Calcium
ug/L
1000
991
99
80-120
Chromium
ug/L
80
81.7
102
80-120
Cobalt
ug/L
80
83.5
104
80-120
Copper
ug/L
80
82.1
103
80-120
Iron
ug/L
1000
1030
103
80-120
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/27/2015 03:40 PM without the written consent of Pace Analytical Services, Inc.. Page 65 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098onyfte. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040079
Pace Project No.: 92244130
LABORATORY CONTROL SAMPLE:
Parameter
1945265
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
Lead
ug/L
80
78.2
98
80-120
Magnesium
ug/L
1000
1010
101
80-120
Manganese
ug/L
80
81.5
102
80-120
Molybdenum
ug/L
80
80.0
100
80-120
Nickel
ug/L
80
84.3
105
80-120
Potassium
ug/L
1000
1010
101
80-120
Selenium
ug/L
80
80.3
100
80-120
Sodium
ug/L
1000
1050
105
80-120
Strontium
ug/L
80
78.4
98
80-120
Thallium
ug/L
80
83.3
104
80-120
Vanadium
ug/L
80
79.6
100
80-120
Zinc
ug/L
80
82.9
104
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1945266 1945267
Qualifiers
MS
MSD
10303182004
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Aluminum
ug/L
<59.6
80
80
ND
ND
108
86
75-125
20
Antimony
ug/L
<2.9
80
80
85.8
74.4
107
93
75-125
14
20
Arsenic
ug/L
<2.3
80
80
82.5
72.6
101
89
75-125
13
20
Barium
ug/L
7.8
80
80
93.2
79.4
107
90
75-125
16
20
Beryllium
ug/L
<1.3
80
80
84.0
70.8
105
89
75-125
17
20
Boron
ug/L
2730
80
80
3340
2940
760
267
75-125
13
20 M6
Cadmium
ug/L
<0.49
80
80
75.0
65.4
94
82
75-125
14
20
Calcium
ug/L
300000
1000
1000
316000
273000
1520
-2740
75-125
14
20 M6
Chromium
ug/L
<0.0034
80
80
85.4
74.1
105
90
75-125
14
20
mg/L
Cobalt
ug/L
3.5J
80
80
87.8
76.6
105
91
75-125
14
20
Copper
ug/L
0.0053J
80
80
84.4
72.0
99
83
75-125
16
20
mg/L
Iron
ug/L
0.63J
1000
1000
1700J
1480J
107
85
75-125
20
mg/L
Lead
ug/L
<0.00092
80
80
72.2
63.2
90
79
75-125
13
20
mg/L
Magnesium
ug/L
793000
1000
1000
978000
856000
18500
6270
75-125
13
20 M6
Manganese
ug/L
54.4
80
80
139
120
106
81
75-125
15
20
Molybdenum
ug/L
10.5
80
80
95.9
80.6
107
88
75-125
17
20
Nickel
ug/L
0.020
80
80
106
88.6
107
86
75-125
18
20
mg/L
Potassium
ug/L
289000
1000
1000
300000
264000
1070
-2520
75-125
13
20 M6
Selenium
ug/L
<4.0
80
80
85.8
68.9
106
85
75-125
22
20 R1
Sodium
ug/L
6790000
1000
1000
8250000
7260000
145000
46300
75-125
13
20 E,M6
Strontium
ug/L
4640
80
80
5540
4860
1120
278
75-125
13
20 M6
Thallium
ug/L
<0.31
80
80
79.9
68.4
100
85
75-125
16
20
Vanadium
ug/L
<5.6
80
80
90.0
81.5
110
99
75-125
10
20
Zinc
ug/L
<0.048
80
80
ND
ND
92
76
75-125
20
mg/L
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
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aceAnaiXical
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[phone]
QUALITY CONTROL DATA
Project: J15040079
Pace Project No.: 92244130
QC Batch: PMST/3438
Analysis Method:
ASTM D2974-87
QC Batch Method: ASTM D2974-87
Analysis Description:
Dry Weight/Percent Moisture
Associated Lab Samples: 92244130003,92244130004,92244130005,92244130006,92244130007,92244130008,92244130009
SAMPLE DUPLICATE: 1182602
35181339032
Dup
Max
Parameter
Units
Result
Result RPD
RPD
Qualifiers
Percent Moisture
%
4.3
6.2 37
10 D6
SAMPLE DUPLICATE: 1182603
35182856003
Dup
Max
Parameter
Units
Result
Result RPD
RPD
Qualifiers
Percent Moisture
%
10.5
10.1 3
10
SAMPLE DUPLICATE: 1182604
92244130003
Dup
Max
Parameter
Units
Result
Result RPD
RPD
Qualifiers
Percent Moisture
%
11.8
14.3 19
10 D6
SAMPLE DUPLICATE: 1182605
92244464003
Dup
Max
Parameter
Units
Result
Result RPD
RPD
Qualifiers
Percent Moisture
%
21.8
21.3 2
10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Pace Analytical Services, Inc.
098ninyfte. Suite 100
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[phone]
QUALITY CONTROL DATA
Project: J15040079
Pace Project No.: 92244130
QC Batch: WET/36760 Analysis Method: EPA 9045
QC Batch Method: EPA 9045 Analysis Description: 9045 pH
Associated Lab Samples: 92244130003, 92244130004, 92244130005, 92244130006, 92244130009
SAMPLE DUPLICATE: 1431690
92243926014 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
pH at 25 Degrees C Std. Units 7.9 7.9 0 10
SAMPLE DUPLICATE: 1431691
92244129001 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
pH at 25 Degrees C Std. Units 5.9 5.9 1 10 D6
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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aceAnaiXical
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Pace Analytical Services, Inc.
098oinvfte. Suite 100
y Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040079
Pace Project No.: 92244130
QC Batch: WET/36789 Analysis Method: EPA 9045
QC Batch Method: EPA 9045 Analysis Description: 9045 pH
Associated Lab Samples: 92244130007, 92244130008
SAMPLE DUPLICATE: 1432813
92244052001 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
pH at 25 Degrees C Std. Units 8.6 8.6 0 10
SAMPLE DUPLICATE: 1432814
92244371005 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
pH at 25 Degrees C Std. Units 6.1 6.1 0 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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aceAnaiXical
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Pace Analytical Services, Inc.
098ninyfte. Suite 100
y Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040079
Pace Project No.: 92244130
QC Batch: WETA/22607
Analysis Method: EPA 300.0
QC Batch Method: EPA 300.0
Analysis Description: 300.0 IC Anions
Associated Lab Samples: 92244130003, 92244130004,
92244130005, 92244130006, 92244130007, 92244130008
METHOD BLANK: 1437291
Matrix: Water
Associated Lab Samples: 92244130003, 92244130004,
92244130005, 92244130006, 92244130007, 92244130008
Blank Reporting
Parameter Units
Result Limit Analyzed Qualifiers
Sulfate mg/L
3.1 2.0 04/19/1512:14
LABORATORY CONTROL SAMPLE: 1437292
Spike LCS LCS % Rec
Parameter Units
Conc. Result % Rec Limits Qualifiers
Sulfate mg/L
20 18.9 94 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1437293 1437294
MS MSD
92244130003
Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfate mg/L 275
22.7 22.7 294 295 83 85 0
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1437295 1437296
MS MSD
92245087001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfate mg/L 4.0 26.6 26.6 26.5 26.2 85 83 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Page 70 of 82

aceAnaiXical
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Pace Analytical Services, Inc.
098m.8fftie. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040079
Pace Project No.: 92244130
QC Batch: WETA/22655
Analysis Method: EPA 353.2
QC Batch Method: EPA 353.2
Analysis Description: 353.2 Nitrate + Nitrite, Unpres.
Associated Lab Samples: 92244130003, 92244130004,
92244130005, 92244130006, 92244130007, 92244130008
METHOD BLANK: 1440999
Matrix: Water
Associated Lab Samples: 92244130003, 92244130004,
92244130005, 92244130006, 92244130007, 92244130008
Blank Reporting
Parameter Units
Result Limit Analyzed Qualifiers
Nitrogen, Nitrate mg/L
0.16 0.020 04/22/15 17:09 Z2
LABORATORY CONTROL SAMPLE: 1441000
Spike LCS LCS % Rec
Parameter Units
Conc. Result % Rec Limits Qualifiers
Nitrogen, Nitrate mg/L
2.5 2.5 101 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1441001 1441002
MS MSD
92244130003
Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Nitrogen, Nitrate mg/L ND
2.8 2.8 3.1 3.1 104 104 90-110 0 10 H1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1441003 1441004
MS MSD
92244130004 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Nitrogen, Nitrate mg/L ND 2.9 2.9 3.1 3.1 100 100 90-110 0 10 H1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Page 71 of 82

aceAnaiXical
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Pace Analytical Services, Inc.
098g i vfte. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040079
Pace Project No.: 92244130
QC Batch: WETA/22603 Analysis Method: SM 4500-CI-E
QC Batch Method: SM 4500-CI-E Analysis Description: 4500 Chloride
Associated Lab Samples: 92244130003, 92244130004, 92244130005, 92244130006, 92244130007, 92244130008
METHOD BLANK: 1437036 Matrix: Water
Associated Lab Samples: 92244130003, 92244130004, 92244130005, 92244130006, 92244130007, 92244130008
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Chloride mg/L ND 1.0 04/17/15 05:27
LABORATORY CONTROL SAMPLE: 1437037
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Chloride mg/L 20 20.3 101 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1437038 1437039
MS MSD
92244130003 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Chloride mg/L ND 22.7 22.7 23.0 23.4 101 102 90-110 1 10
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1437040 1437041
MS MSD
92244130004 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Chloride mg/L ND 23.2 23.2 23.9 23.5 103 101 90-110 2 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Page 72 of 82

aceAnaiXical
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Pace Analytical Services, Inc.
098ninyfte. Suite 100
y Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040079
Pace Project No.: 92244130
QC Batch: WETA/45261 Analysis Method: EPA 9056
QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions
Associated Lab Samples: 92244130003,92244130004,92244130005,92244130006,92244130007,92244130008,92244130009
METHOD BLANK: 1178902 Matrix: Solid
Associated Lab Samples:
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Chloride mg/kg ND 50.1 04/09/15 20:27
Sulfate mg/kg ND 50.1 04/09/15 20:27
LABORATORY CONTROL SAMPLE:
1178903
Parameter
Units
Chloride
mg/kg
Sulfate
mg/kg
MATRIX SPIKE SAMPLE:
1178905
Parameter
Units
Chloride
mg/kg
Sulfate
mg/kg
SAMPLE DUPLICATE: 1178904
Parameter
Chloride
Sulfate
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
500 480 96 80-120
500 483 97 80-120
92244083001 Spike MS MS % Rec
Result Conc. Result % Rec Limits Qualifiers
ND 1130 1020 72 80-120 M 1
508J 1130 1470 86 80-120
92244083001 Dup
Units Result Result
mg/kg ND ND
mg/kg 508J 475J
Max
RPD RPD Qualifiers
20
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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aceAnaiXical
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Pace Analytical Services, Inc.
098ninyfte. Suite 100
y Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040079
Pace Project No.: 92244130
QC Batch: WETA/45262
Analysis Method: EPA 9056
QC Batch Method: EPA 9056
Analysis Description: 9056 IC Anions
Associated Lab Samples: 92244130003,92244130004,92244130005,92244130006,92244130007,92244130008,92244130009
METHOD BLANK: 1178906
Matrix: Solid
Associated Lab Samples:
Blank Reporting
Parameter
Units
Result Limit Analyzed
Qualifiers
Nitrate as N
mg/kg
ND 5.0 04/09/15 20:27
LABORATORY CONTROL SAMPLE:
1178907
Spike LCS LCS
% Rec
Parameter
Units
Conc. Result % Rec
Limits Qualifiers
Nitrate as N
mg/kg
50 49.6 99
80-120
MATRIX SPIKE SAMPLE:
1178909
92244083001 Spike MS
MS % Rec
Parameter
Units
Result Conc. Result
% Rec Limits Qualifiers
Nitrate as N
mg/kg
ND 113 98.7
88 80-120 H3
SAMPLE DUPLICATE: 1178908
92244083001 Dup
Max
Parameter
Units
Result Result RPD
RPD Qualifiers
Nitrate as N
mg/kg
ND ND
20 H3
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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aceAnaiXical
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Pace Analytical Services, Inc.
098g i .8ffte. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15040079
Pace Project No.: 92244130
QC Batch: WETA/28128
Analysis Method: EPA 9060
QC Batch Method: EPA 9060
Analysis Description: 9060 TOC Average
Associated Lab Samples: 92244130003,92244130004,92244130005,92244130006,92244130007,92244130008,92244130009
METHOD BLANK: 1144490
Matrix: Solid
Associated Lab Samples:
Blank Reporting
Parameter Units
Result Limit Analyzed Qualifiers
Mean Total Organic Carbon mg/kg
ND 600 04/22/15 08:24
LABORATORY CONTROL SAMPLE: 1144491
Spike LCS LCS % Rec
Parameter Units
Conc. Result % Rec Limits Qualifiers
Mean Total Organic Carbon mg/kg
120000 119000 99 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1144492 1144493
MS MSD
92243926010
Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Mean Total Organic Carbon mg/kg 20900
50100 50300 68100 67500 94 93 50-150 1 30
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1144494 1144495
MS MSD
92243920001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Mean Total Organic Carbon mg/kg 86000 56100 55500 128000 131000 74 80 50-150 2 30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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aceAnaiXical
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Pace Analytical Services, Inc.
098ninyfte. Suite 100
y Huntersville, NC 28078
[phone]
QUALIFIERS
Project: J15040079
Pace Project No.: 92244130
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
LABORATORIES
PASI-A
Pace Analytical Services - Asheville
PASI-G
Pace Analytical Services - Green Bay
PASI-M
Pace Analytical Services - Minneapolis
PASI-O
Pace Analytical Services - Ormond Beach
BATCH QUALIFIERS
Batch: ICPM/9583
Ill Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
ANALYTE QUALIFIERS
B Analyte was detected in the associated method blank.
D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
D6 The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits.
E Analyte concentration exceeded the calibration range. The reported result is estimated.
H1 Analysis conducted outside the EPA method holding time.
H3 Sample was received or analysis requested beyond the recognized method holding time.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
REPORT OF LABORATORY ANALYSIS
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Pace Analytical Services, Inc
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Huntersville, INC 28078078
www.pacelabs.com [phone]
QUALIFIERS
Project: J15040079
Pace Project No.: 92244130
ANALYTE QUALIFIERS
N2 The lab does not hold TIN accreditation for this parameter.
P8 Analyte was detected in the method blank. All associated samples had concentrations of at least ten times greater than
the blank or were below the reporting limit.
R1 RPD value was outside control limits.
Z2 Analyte present in the associated method blank above the detection limit
REPORT OF LABORATORY ANALYSIS
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aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098m.8ffte. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
J15040079
Pace Project No.:
92244130
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92244130003
201509506
EPA 3050
MPRP/23551
EPA 6010
ICP/14401
92244130004
201509507
EPA 3050
MPRP/23551
EPA 6010
ICP/14401
92244130005
201509508
EPA 3050
MPRP/23551
EPA 6010
ICP/14401
92244130006
201509511
EPA 3050
MPRP/23551
EPA 6010
ICP/14401
92244130007
201509512
EPA 3050
MPRP/23551
EPA 6010
ICP/14401
92244130008
201509513
EPA 3050
MPRP/23551
EPA6010
ICP/14401
92244130009
201509509
EPA 3050
MPRP/23551
EPA 6010
ICP/14401
92244130003
201509506
EPA 3050
MPRP/23552
EPA 6020
ICPM/9583
92244130004
201509507
EPA 3050
MPRP/23552
EPA 6020
ICPM/9583
92244130005
201509508
EPA 3050
MPRP/23552
EPA 6020
ICPM/9583
92244130006
201509511
EPA 3050
MPRP/23552
EPA 6020
ICPM/9583
92244130007
201509512
EPA 3050
MPRP/23552
EPA 6020
ICPM/9583
92244130008
201509513
EPA 3050
MPRP/23552
EPA 6020
ICPM/9583
92244130009
201509509
EPA 3050
MPRP/23552
EPA 6020
ICPM/9583
92244130001
201509505
EPA 3020
MPRP/53524
EPA 6020A
ICPM/23732
92244130002
201509510
EPA 3020
MPRP/53524
EPA 6020A
ICPM/23732
92244130010
201509506 SPLP
EPA 3020
MPRP/53815
EPA 6020A
ICPM/23916
92244130011
201509507 SPLP
EPA 3020
MPRP/53815
EPA 6020A
ICPM/23916
92244130012
201509508 SPLP
EPA 3020
MPRP/53815
EPA 6020A
ICPM/23916
92244130013
201509511 SPLP
EPA 3020
MPRP/53815
EPA 6020A
ICPM/23916
92244130014
201509512 SPLP
EPA 3020
MPRP/53815
EPA 6020A
ICPM/23916
92244130015
201509513 SPLP
EPA 3020
MPRP/53815
EPA 6020A
ICPM/23916
92244130001
201509505
EPA 7470
MERP/13175
EPA 7470
MERC/15344
92244130002
201509510
EPA 7470
MERP/13175
EPA 7470
MERC/15344
92244130010
201509506 SPLP
EPA 7470A
MERP/13312
EPA 7470A
MERC/15482
92244130011
201509507 SPLP
EPA 7470A
MERP/13312
EPA 7470A
MERC/15482
92244130012
201509508 SPLP
EPA 7470A
MERP/13312
EPA 7470A
MERC/15482
92244130013
201509511 SPLP
EPA 7470A
MERP/13312
EPA 7470A
MERC/15482
92244130014
201509512 SPLP
EPA 7470A
MERP/13312
EPA 7470A
MERC/15482
92244130015
201509513 SPLP
EPA 7470A
MERP/13312
EPA 7470A
MERC/15482
92244130003
201509506
EPA 7471
MERP/5584
EPA 7471
MERC/5574
92244130004
201509507
EPA 7471
MERP/5584
EPA 7471
MERC/5574
92244130005
201509508
EPA 7471
MERP/5584
EPA 7471
MERC/5574
92244130006
201509511
EPA 7471
MERP/5584
EPA 7471
MERC/5574
92244130007
201509512
EPA 7471
MERP/5584
EPA 7471
MERC/5574
92244130008
201509513
EPA 7471
MERP/5584
EPA 7471
MERC/5574
92244130009
201509509
EPA 7471
MERP/5584
EPA 7471
MERC/5574
92244130003
201509506
ASTM D2974-87
PMST/3438
92244130004
201509507
ASTM D2974-87
PMST/3438
92244130005
201509508
ASTM D2974-87
PMST/3438
92244130006
201509511
ASTM D2974-87
PMST/3438
92244130007
201509512
ASTM D2974-87
PMST/3438
92244130008
201509513
ASTM D2974-87
PMST/3438
92244130009
201509509
ASTM D2974-87
PMST/3438
92244130003
201509506
EPA 9045
WET/36760
REPORT OF LABORATORY ANALYSIS
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acmnalytical
www.pacelabs.com
Pace Analytical Services, Inc.
ogpginlc&f'ke. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: J15040079
Pace Project No.: 92244130
Lab ID Sample ID QC Batch Method QC Batch
92244130004
201509507
EPA 9045
WET/36760
92244130005
201509508
EPA 9045
WET/36760
92244130006
201509511
EPA 9045
WET/36760
92244130007
201509512
EPA 9045
WET/36789
92244130008
201509513
EPA 9045
WET/36789
92244130009
201509509
EPA 9045
WET/36760
92244130003
201509506
EPA 300.0
WETA/22607
92244130004
201509507
EPA 300.0
WETA/22607
92244130005
201509508
EPA 300.0
WETA/22607
92244130006
201509511
EPA 300.0
WETA/22607
92244130007
201509512
EPA 300.0
WETA/22607
92244130008
201509513
EPA 300.0
WETA/22607
92244130003
201509506
EPA 353.2
WETA/22655
92244130004
201509507
EPA 353.2
WETA/22655
92244130005
201509508
EPA 353.2
WETA/22655
92244130006
201509511
EPA 353.2
WETA/22655
92244130007
201509512
EPA 353.2
WETA/22655
92244130008
201509513
EPA 353.2
WETA/22655
92244130003
201509506
SM 4500-CI-E
WETA/22603
92244130004
201509507
SM 4500-CI-E
WETA/22603
92244130005
201509508
SM 4500-CI-E
WETA/22603
92244130006
201509511
SM 4500-CI-E
WETA/22603
92244130007
201509512
SM 4500-CI-E
WETA/22603
92244130008
201509513
SM 4500-CI-E
WETA/22603
92244130003
201509506
EPA 9056
WETA/45261
92244130004
201509507
EPA 9056
WETA/45261
92244130005
201509508
EPA 9056
WETA/45261
92244130006
201509511
EPA 9056
WETA/45261
92244130007
201509512
EPA 9056
WETA/45261
92244130008
201509513
EPA 9056
WETA/45261
92244130009
201509509
EPA 9056
WETA/45261
92244130003
201509506
EPA 9056
WETA/45262
92244130004
201509507
EPA 9056
WETA/45262
92244130005
201509508
EPA 9056
WETA/45262
92244130006
201509511
EPA 9056
WETA/45262
92244130007
201509512
EPA 9056
WETA/45262
92244130008
201509513
EPA 9056
WETA/45262
92244130009
201509509
EPA 9056
WETA/45262
92244130003 201509506 EPA 9060 WETA/28128
92244130003 201509506 EPA 9060 WETA/28129
92244130004 201509507 EPA 9060 WETA/28128
92244130004 201509507 EPA 9060 WETA/28129
92244130005 201509508 EPA 9060 WETA/28128
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/27/2015 03:40 PM without the written consent of Pace Analytical Services, Inc..
Analytical
Analytical Method Batch
Page 79 of 82

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098m.8ffte. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: J15040079
Pace Project No.: 92244130
Lab ID
Sample ID
QC Batch Method
QC Batch
92244130005
201509508
EPA 9060
WETA/28129
92244130006
201509511
EPA 9060
WETA/28128
92244130006
201509511
EPA 9060
WETA/28129
92244130007
201509512
EPA 9060
WETA/28128
92244130007
201509512
EPA 9060
WETA/28129
92244130008
201509513
EPA 9060
WETA/28128
92244130008
201509513
EPA 9060
WETA/28129
92244130009
201509509
EPA 9060
WETA/28128
92244130009
201509509
EPA 9060
WETA/28129
Date: 04/27/2015 03:40 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Analytical Method
Analytical
Batch
Page 80 of 82

uocument Name: uocument Kevisea: aepremoer �z, `u i4
2eAwlytical' Sample Condition Upon Receipt SCUR) Page 1 of 2
Document Number: Issuing AL06gitZ of 95
F-CHR-CS-003-rev.16 Pace Huntersville Quality Office
Client Name:
Courier: ❑ Fed Ex ❑ UPS❑ uSPS❑ Client❑ Commercial❑ ---race—O her
Custody Seal on Cooler/Box Present: El yes D no Seals in t yes ❑ no
Packing Material: ❑ Bubble VDp ❑ Bubble Bags None` Other
Thermometer Used: IR Gu T1401 Type of Ic Wet Blue None Samples on ice, cool process has begun
Temn Correction Factor T9401 No Correction /
Corrected Cooler Temp.:_ •C
Temp should be above freezing to VC
Biological Tissue is Frozen: Yes No A!
Comments:
Date and Initial of rs n e4amining
contents: ,j { '7
Chain of Custody Present:
Yes ONO
0N1A
1.
Chain of Custody Filled Out:
Yes ONO
❑NIA
2.
Chain of Custody Relinquished:
es ONO
❑NIA
3.
Sampler Name & Signature on COG:
Yes ONO
❑NIA
4.
Samples Arrived within Hold Time:
Yes ONO
El NIA
5.
Short Hold Time Analysis (a72hr):
❑Yes No ; ❑NIA
6.
Rush Turn Around Time Requested:
❑Yes,. o
❑NIA
7,
Sufficient Volume:
jz6s ONO
❑N1A
8.
Correct Containers Used:
-Pace Containers Used:
Yes ONO
❑Yes No
❑NIA
❑NIA
9.
Containers Intact:
As ONO
❑NIA
10.
Filtered volume received for Dissolved tests
❑Yes ONO
IA
11.
Sample Labels match COG:
-Includes date/time/ID/Analysis Matrix:
Yes ONO
❑NIA
12,
All containers needing preservation have been checked.
All containers needing preservation are found to be in
compliance with EPA recommendation.
exceptions: VOA, coliform, TOC, O&G, VVI-DRO (water)
Ye❑No
s ❑No
A
❑Yes No
❑NIA
❑N/A
13.
Samples checked for dechlorination:
❑Yes ❑No
IA
14.
Headspace in VOA Vials (>6mm):
❑Yes ONO
NI .
15.
Trip Blank Present:
Trip Blank Custody Seals Present
Pace Trip Blank Lot # (if purchased):
❑Yes ONO
❑Yes ONO
NIA,
A
Client Notification/ Resolution: Field Data Required? Y I N
Person Contacted: Date/Time:
Comments/ Resolution:
SCURF Review:
Place label here
W4#:92244130
Note: Whenever there is a discrepancy affecting. North Carolina compliance fill
111111111111
samples, a copy of this form will be sent to the North Carolina DEHNRf
Certification Office ( i.e out of hold, incorrect preservative, out of temp,
incorrect containers) 82244130
Page 81 of 82

Page 94 of 95
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Page 82 of 82

CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM
I'---. — —---------•-------------•_•_-_•_•_•_•_•_•-----------------------------------
Analyticall�l 1 Laboratory Services i i Analytical Laborato
DUKEore Order
Use Onl i
p,ge o P.
Maffl= SOIL
Mall Code MG03A2 (Building 74D5) ' SO
rater Hlle, N. C. Rd j I -
Huntersvflle, N. C. 28078
V' ENERGY,.
Samples originMing SC ND— _ i DISTRIBUTION
ORIGINAL to LAB,
,a j hogged By Date t: Time
(9110) 87s sz46 /+
I 1 /' � G
Fax_L9801874.4}49_.---•-•-•-•� CL -f� U
COPY to CLIENT
SAMPLE PROGRAM Ground Water _ I
1)Projw Non* _ _ _ _ — 2)Phone No: :Vendor z
AB GW Assessment - Soil
NPOES _ Other i
Plant
Cape Fear PACE Cooler Tenrio IC
RCRA .__x_ 1 REV DATE 1/23,2015
s)ellene John Toepfer, fluke 4)Fax No:
Mark McDade, Synterra PO 1142081 ',Pr sexy j=-H L
Kathy Webb, Synterra 2=H2 4 = Or
Chris Suttel, Synterra 1 4 Ice S=Nana
+�
6)Business Unit: 6jPmject ID: r)Mail Code:
ACLCP'i402
8) Operating Unit: 9)Activhy 10: 1 g)Process ID ?. W
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to
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we need .ha following. 1) Enter Carr - t a"wt,nti ay ;n ail ;a auowalu,y lielris augur;, Or added within 15 minutes of sample 3
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241Comrnents Metals: Al, Sb, As, Ba, Be, B, Cd, Ca, Cr, Co, Cu, Fe, Pb, Mg, Mn, Mo, Ni, K, Se, No, Sr, TI, V, Zn, Mercury
pH Anions: Cl, Nitrate-N, SO4
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