NC0003433_J15030700 Report_20150902

+ DUKE Analytical Laboratory 1 of 112
ENERGY
Order Number:
Project Name:
Customer Name(s):
Customer Address:
Lab Contact:
Report Authorized By:
(Signature)
Program Comments:
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone:[phone] Fax:[phone]
Order Summary Report
J15030700
CAPE FEAR - AB GW ASSESSMENT SOIL
Tim Hunsucker, Chris Suttell, Kathy Webb, John Toepfer
Margaret Galvin -Karr Phone: [phone]
•�w�."_ku^' MXG4644(101161)
Q 2015.05.28 07:21:33-04'00, Date:
Margaret Galvin -Karr
Please contact the Program Manager (Margaret Galvin -Karr) with any questions regarding this report.
Data Flags & Calculations:
5/26/2015
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Sample ID's & Descriptions:
Sample ID Plant/Station
Collection
Date and Time
Collected By
2 of 112
Sample Description
2015008683
Cape Fear
23-Mar-15 3:00 PM
Chris S.
Well ABMW-1S6 (39-41)
2015008684
Cape Fear
23-Mar-15 10:45 AM
Chris S.
Well ERB-08 (SONIC)
2015008685
Cape Fear
24-Mar-15 4:50 PM
Chris S.
Well ABMW-1S13 (57-59)
2015008686
Cape Fear
24-Mar-15 5:15 PM
Chris S.
Well ABMW-1S13 (69-71)
2015008687
Cape Fear
24-Mar-15 8:30 AM
Chris S.
Well ERB-09 (SONIC)
2015008688
Cape Fear
25-Mar-15 4:20 PM
Chris S.
Well ERB-10 (SONIC)
2015008689
Cape Fear
25-Mar-15 5:00 PM
Chris S.
Well ABMW-2 AB (2-3)
2015008690
Cape Fear
26-Mar-15 8:30 AM
Chris S.
Well ERB-11 (SONIC)
2015008691
Cape Fear
26-Mar-15 11:30 AM
Chris S.
Well ABMW-2SB (11-12)
2015008692
Cape Fear
26-Mar-15 8:45 AM
Chris S.
Well ABMW-2SB (5-6)
2015008693
Cape Fear
26-Mar-15 1:30 PM
Chris S.
Well A13MW-2SB (27-28)
11 Total Samples

Oni MEN
Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals Yes No
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits. ❑ Yes❑ No
All laboratory QA/QC requirements are acceptable.❑ Yes ❑ No
Report Sections Included:
U Job Summary Report
❑ Sample Identification
n Technical Validation of Data Package
❑ Analytical Laboratory Certificate of Analysis
❑ Analytical Laboratory QC Report
Reviewed By: Date:
Sub -contracted Laboratory Results
❑ Customer Specific Data Sheets, Reports, & Documentation
❑ Customer Database Entries
0 Chain of Custody
[I/0] Electronic Data Deliverable (EDD) Sent Separately

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15030700
Site: Well ABMW-1SB (39-41)
Collection Date: 23-Mar-15 3:00 PM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
SPLP LEACHATE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
4 of 112
Sample #: 2015008683
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15030700
Site: Well ERB-08 (SONIC)
Collection Date: 23-Mar-15 10:45 AM
Analyte Result Units Qualifiers RDL DF
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Sample #: 2015008684
Matrix: OTHER
5 of 112
Method Analysis Date/Time Analyst
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15030700
Site: Well ABMW-1SB (57-59)
Collection Date: 24-Mar-15 4:50 PM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
SPLP LEACHATE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
6 of 112
Sample #: 2015008685
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15030700
Site: Well ABMW-1SB (69-71)
Collection Date: 24-Mar-15 5:15 PM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
7 of 112
Sample #: 2015008686
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis 8 of 112
This report shall not be reproduced, except in full.
Order # J15030700
Site: Well ERB-09 (SONIC)
Collection Date: 24-Mar-15 8:30 AM
Analyte Result Units Qualifiers RDL DF
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Sample #: 2015008687
Matrix: OTHER
Method Analysis Date/Time Analyst
Vendor Method V_PACE

Certificate of Laboratory Analysis 9 of 112
This report shall not be reproduced, except in full.
Order # J15030700
Site: Well ERB-10 (SONIC)
Collection Date: 25-Mar-15 4:20 PM
Analyte Result Units Qualifiers RDL DF
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Sample #: 2015008688
Matrix: OTHER
Method Analysis Date/Time Analyst
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15030700
Site: Well ABMW-2 AB (2-3)
Collection Date: 25-Mar-15 5:00 PM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
SPLP LEACHATE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
1111IM4 MEN
Sample #: 2015008689
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis 11 of 112
This report shall not be reproduced, except in full.
Order # J15030700
Site: Well ERB-11 (SONIC)
Collection Date: 26-Mar-15 8:30 AM
Analyte Result Units Qualifiers RDL DF
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Sample #: 2015008690
Matrix: OTHER
Method Analysis Date/Time Analyst
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15030700
Site: Well ABMW-2SB (11-12)
Collection Date: 26-Mar-15 11:30 AM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
SPLP LEACHATE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
fLN�. MEN
Sample #: 2015008691
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15030700
Site: Well ABMW-2SB (5-6)
Collection Date: 26-Mar-15 8:45 AM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
SPLP LEACHATE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
13 of 112
Sample #: 2015008692
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15030700
Site: Well ABMW-2SB (27-28)
Collection Date: 26-Mar-15 1:30 PM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
1EHIZ$ MEN
Sample #: 2015008693
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980011ji yfy e. Suite 100
Huntersville, INC 28078
[phone]
May 11, 2015
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg.7405 MG30A2
Huntersville, NC 28078
RE: Project: J 15030700
Pace Project No.: 92243096
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on March 27, 2015. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TN standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc: Marge Galvin -Karr, Duke Energy
Program Manager, Duke Energy
Rodney Wilke, Duke Energy
p«FO
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
lqe� ��� without the written consent of Pace Analytical Services, Inc..
BRAT,
Page 1 of 97

lacmnalyfica(
www.pacelabs.com
Pace Analytical Services, Inc.
9800118r6f r. Suite 100
Huntersville, NC 28078
[phone]
Project: J15030700
Pace Project No.: 92243096
Minnesota Certification IDs
1700 Elm Street SE Suite 200, Minneapolis, MN 55414
A21-A Certification #: 2926.01
Alaska Certification #: UST-078
Alaska Certification #MN00064
Alabama Certification #40770
Arizona Certification #: AZ-0014
Arkansas Certification #: 88-0680
California Certification #: 01155CA
Colorado Certification #Pace
Connecticut Certification #: PH-0256
EPA Region 8 Certification #: 8TMS-L
Florida/NELAP Certification #: E87605
Guam Certification #:14-008r
Georgia Certification #: 959
Georgia EPD #: Pace
Idaho Certification #: MN00064
Hawaii Certification #MN00064
Illinois Certification #: 200011
Indiana Certification#C-MN-01
Iowa Certification #: 368
Kansas Certification #: E-10167
Kentucky Dept of Envi. Protection - DW #90062
Kentucky Dept of Envi. Protection - WW #:90062
Louisiana DEQ Certification #: 3086
Louisiana DHH #: LA140001
Maine Certification #: 2013011
Maryland Certification #: 322
Michigan DEPH Certification #: 9909
Ormond Beach Certification IDs
8 East Tower Circle, Ormond Beach, FL 32174
Alabama Certification #: 41320
Connecticut Certification #: PH-0216
Delaware Certification: FL NELAC Reciprocity
Florida Certification #: E83079
Georgia Certification #: 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification #: 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383
Kentucky Certification #: 90050
Louisiana Certification #: FL NELAC Reciprocity
Louisiana Environmental Certificate #: 05007
Maryland Certification: #346
Massachusetts Certification #: M-FL1264
Michigan Certification #: 9911
Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236
Green Bay Certification IDs
1241 Bellevue Street, Green Bay, WI 54302
Florida/NELAP Certification #: E87948
Illinois Certification #: 200050
Kentucky Certification #: 82
Louisiana Certification #: 04168
Minnesota Certification #: 055-999-334
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
CERTIFICATIONS
Minnesota Certification #: 027-053-137
Mississippi Certification #: Pace
Montana Certification #: MT0092
Nevada Certification #: MN_00064
Nebraska Certification #: Pace
New Jersey Certification #: MN-002
New York Certification #: 11647
North Carolina Certification #: 530
North Carolina State Public Health #: 27700
North Dakota Certification #: R-036
Ohio EPA#: 4150
Ohio VAP Certification #: CL101
Oklahoma Certification #: 9507
Oregon Certification #: MN200001
Oregon Certification #: MN300001
Pennsylvania Certification #: 68-00563
Puerto Rico Certification
Saipan (CNMI) #:MP0003
South Carolina #:74003001
Texas Certification #: T104704192
Tennessee Certification #: 02818
Utah Certification #: MN000642013-4
Virginia DGS Certification #: 251
Virginia/VELAP Certification #: Pace
Washington Certification #: C486
West Virginia Certification #: 382
West Virginia DHHR #:9952C
Wisconsin Certification #: 999407970
Montana Certification #: Cert 0074
Nebraska Certification: NE-OS-28-14
Nevada Certification: FL NELAC Reciprocity
New Hampshire Certification #: 2958
New Jersey Certification #: FL765
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FLO1264
South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
Washington Certification #: C955
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
North Dakota Certification #: R-150
South Carolina Certification #: 83006001
Texas Certification #: T104704529-14-1
US Dept of Agriculture #: S-76505
Wisconsin Certification #: 405132750
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 2 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
98001�yfy e. Suite 100
Huntersville, NC 28078
[phone]
Project: J15030700
Pace Project No.: 92243096
Asheville Certification IDs
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
CERTIFICATIONS
West Virginia Certification #: 356
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 3 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
98001lgi yf�e. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE SUMMARY
Project: J15030700
Pace Project No.: 92243096
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92243096001
2015008683
Solid
03/23/1515:00
03/27/15 15:45
92243096002
2015008685
Solid
03/24/1516:50
03/27/15 15:45
92243096003
2015008689
Solid
03/25/1517:00
03/27/15 15:45
92243096004
2015008691
Solid
03/26/1511:30
03/27/15 15:45
92243096005
2015008692
Solid
03/26/15 08:45
03/27/15 15:45
92243096006
2015008686
Solid
03/24/1517:15
03/27/15 15:45
92243096007
2015008693
Solid
03/26/1513:30
03/27/15 15:45
92243096008
2015008683 SPLP
Water
03/23/15 15:00
03/27/15 15:45
92243096009
2015008685 SPLP
Water
03/24/15 16:50
03/27/15 15:45
92243096010
2015008689 SPLP
Water
03/25/15 17:00
03/27/15 15:45
92243096011
2015008691 SPLP
Water
03/26/15 11:30
03/27/15 15:45
92243096012
2015008692 SPLP
Water
03/26/15 08:45
03/27/15 15:45
92243096013
2015008684
Water
03/23/1510:45
03/27/15 15:45
92243096014
2015008687
Water
03/24/15 08:30
03/27/15 15:45
92243096015
2015008688
Water
03/25/1516:26
03/27/15 15:45
92243096016
2015008690
Water
03/26/15 08:30
03/27/15 15:45
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 4 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980019'6fyf�e. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project: J15030700
Pace Project No.: 92243096
Lab ID
Sample ID
Method
Analysts
Analytes
Reported
Laboratory
92243096001
2015008683
EPA 6010
TAP
16
PASI-0
EPA 6020
CRT
8
PASI-O
EPA 7471
CKJ
1
PASI-O
ASTM D2974-87
CRT
1
PASI-O
EPA 9045
MAB
1
PASI-A
EPA 300.0
AES2
1
PASI-A
EPA 353.2
DMN
1
PASI-A
SM 4500-CI-E
SER
1
PASI-A
EPA 9056
AIS
2
PASI-O
EPA 9056
AIS
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92243096002
2015008685
EPA 6010
TAP
16
PASI-0
EPA 6020
CRT
8
PASI-O
EPA 7471
CKJ
1
PASI-O
ASTM D2974-87
CRT
1
PASI-O
EPA 9045
MAB
1
PASI-A
EPA 300.0
AES2
1
PASI-A
EPA 353.2
DMN
1
PASI-A
SM 4500-CI-E
SER
1
PASI-A
EPA 9056
AIS
2
PASI-O
EPA 9056
AIS
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92243096003
2015008689
EPA 6010
TAP
16
PASI-0
EPA 6020
CRT
8
PASI-O
EPA 7471
CKJ
1
PASI-O
ASTM D2974-87
CRT
1
PASI-O
EPA 9045
MAB
1
PASI-A
EPA 300.0
AES2
1
PASI-A
EPA 353.2
DMN
1
PASI-A
SM 4500-CI-E
SER
1
PASI-A
EPA 9056
AIS
2
PASI-O
EPA 9056
AIS
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92243096004
2015008691
EPA 6010
TAP
16
PASI-0
EPA 6020
CRT
8
PASI-O
EPA 7471
CKJ
1
PASI-O
ASTM D2974-87
CRT
1
PASI-O
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 5 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800�8rpyf�e. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
J15030700
92243096
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
EPA 9045
MLS
1
PASI-A
EPA 300.0
AES2
1
PASI-A
EPA 353.2
DMN
1
PASI-A
SM 4500-CI-E
SER
1
PASI-A
EPA 9056
AIS
2
PASI-O
EPA 9056
AIS
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92243096005
2015008692
EPA 6010
TAP
16
PASI-0
EPA 6020
CRT
8
PASI-O
EPA 7471
CKJ
1
PASI-O
ASTM D2974-87
CRT
1
PASI-O
EPA 9045
MLS
1
PASI-A
EPA 300.0
AES2
1
PASI-A
EPA 353.2
DMN
1
PASI-A
SM 4500-CI-E
SER
1
PASI-A
EPA 9056
AIS
2
PASI-O
EPA 9056
AIS
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92243096006
2015008686
EPA 6010
TAP
16
PASI-0
EPA 6020
CRT
8
PASI-O
EPA 7471
CKJ
1
PASI-O
ASTM D2974-87
CRT
1
PASI-O
EPA 9045
MAB
1
PASI-A
EPA 9056
AIS
2
PASI-O
EPA 9056
AIS
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92243096007
2015008693
EPA 6010
TAP
16
PASI-0
EPA 6020
CRT
8
PASI-O
EPA 7471
CKJ
1
PASI-O
ASTM D2974-87
CRT
1
PASI-O
EPA 9045
MLS
1
PASI-A
EPA 9056
AIS
2
PASI-O
EPA 9056
AIS
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92243096008
2015008683 SPLP
EPA 6020A
RJS
24
PASI-M
EPA 7470A
LMW
1
PASI-M
92243096009
2015008685 SPLP
EPA 6020A
RJS
24
PASI-M
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 6 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
98002ISirpyf�e. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project:
J15030700
Pace Project No.:
92243096
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
EPA 7470A
LMW
1
PASI-M
92243096010
2015008689 SPLP
EPA 6020A
RJS
24
PASI-M
EPA 7470A
LMW
1
PASI-M
92243096011
2015008691 SPLP
EPA 6020A
RJS
24
PASI-M
EPA 7470A
LMW
1
PASI-M
92243096012
2015008692 SPLP
EPA 6020A
RJS
24
PASI-M
EPA 7470A
LMW
1
PASI-M
92243096013
2015008684
EPA 6020A
TT3
24
PASI-M
EPA 7470
LMW
1
PASI-M
92243096014
2015008687
EPA 6020A
TT3
24
PASI-M
EPA 7470
LMW
1
PASI-M
92243096015
2015008688
EPA 6020A
TT3
24
PASI-M
EPA 7470
LMW
1
PASI-M
92243096016
2015008690
EPA 6020A
TT3
24
PASI-M
EPA 7470
LMW
1
PASI-M
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 7 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800�qrpyf�e. Suite 100
Huntersville, NC 28078
[phone]
SUMMARY OF DETECTION
Project:
Pace Project No.:
J15030700
92243096
Lab Sample ID
Client Sample ID
Method
Parameters
Result
Units
Report Limit
Analyzed
Qualifiers
92243096001
2015008683
EPA 6010
Aluminum
3650
mg/kg
28.3
04/09/15 06:03
D3
EPA 6010
Barium
37.0
mg/kg
2.8
04/09/15 06:03
D3
EPA 6010
Beryllium
0.25J
mg/kg
0.28
04/09/15 06:03
D3
EPA 6010
Calcium
999
mg/kg
142
04/09/15 06:03
D3
EPA 6010
Chromium
7.4
mg/kg
1.4
04/09/15 06:03
D3
EPA 6010
Copper
4.6
mg/kg
1.4
04/09/15 06:03
D3
EPA 6010
Iron
4280
mg/kg
11.3
04/09/15 06:03
D3
EPA 6010
Magnesium
1090
mg/kg
142
04/09/15 06:03
D3
EPA 6010
Manganese
81.6
mg/kg
1.4
04/09/15 06:03
D3
EPA 6010
Molybdenum
2.9
mg/kg
2.8
04/09/15 06:03
D3
EPA 6010
Nickel
3.6
mg/kg
1.4
04/09/15 06:03
D3
EPA 6010
Potassium
215J
mg/kg
283
04/09/15 06:03
D3
EPA 6010
Strontium
20.1
mg/kg
2.8
04/09/15 06:03
D3
EPA 6010
Zinc
13.8
mg/kg
5.7
04/09/15 06:03
B,D3
EPA 6020
Cobalt
3.9
mg/kg
2.8
04/06/15 11:52
EPA 6020
Lead
4.0
mg/kg
2.8
04/06/15 11:52
EPA 6020
Vanadium
16.1
mg/kg
2.8
04/06/15 11:52
EPA 7471
Mercury
0.0073J
mg/kg
0.0091
04/04/15 21:01
ASTM D2974-87
Percent Moisture
11.7
%
0.10
04/04/15 20:05
EPA 9045
pH at 25 Degrees C
6.9
Std. Units
0.10
04/01/15 13:55
EPA 300.0
Sulfate
5.5
mg/L
2.3
04/07/15 20:48
B
EPA353.2
Nitrogen, Nitrate
0.23
mg/L
0.23
04/09/15 19:39
H1
EPA 9060
Total Organic Carbon
624J
mg/kg
685
04/10/15 15:32
EPA 9060
Total Organic Carbon
593J
mg/kg
677
04/10/15 15:39
EPA 9060
Total Organic Carbon
626J
mg/kg
680
04/10/15 15:44
EPA 9060
Total Organic Carbon
670J
mg/kg
681
04/10/15 15:51
EPA 9060
Mean Total Organic Carbon
628J
mg/kg
680
04/10/15 15:32
EPA 9060
RSD%
5.1
%
04/10/15 15:32
92243096002
2015008685
EPA 6010
Aluminum
2560
mg/kg
25.0
04/09/15 06:07
D3
EPA 6010
Barium
65.3
mg/kg
2.5
04/09/15 06:07
D3
EPA 6010
Beryllium
0.18J
mg/kg
0.25
04/09/15 06:07
D3
EPA 6010
Calcium
56100
mg/kg
125
04/09/15 06:07
D4
EPA 6010
Chromium
1.2J
mg/kg
1.3
04/09/15 06:07
D3
EPA 6010
Copper
3.1
mg/kg
1.3
04/09/15 06:07
D3
EPA 6010
Iron
3620
mg/kg
10.0
04/09/15 06:07
D3
EPA 6010
Magnesium
1900
mg/kg
125
04/09/15 06:07
D3
EPA 6010
Manganese
2210
mg/kg
1.3
04/09/15 06:07
D3
EPA 6010
Nickel
1.3
mg/kg
1.3
04/09/15 06:07
D3
EPA 6010
Potassium
434
mg/kg
250
04/09/15 06:07
D3
EPA 6010
Sodium
134J
mg/kg
250
04/09/15 06:07
D3
EPA 6010
Strontium
90.1
mg/kg
2.5
04/09/15 06:07
D3
EPA 6010
Zinc
9.6
mg/kg
5.0
04/09/15 06:07
B,D3
EPA 6020
Cadmium
0.40
mg/kg
0.30
04/06/15 11:55
EPA 6020
Cobalt
1.3J
mg/kg
2.5
04/06/15 11:55
EPA 6020
Lead
4.4
mg/kg
2.5
04/06/15 11:55
EPA 6020
Vanadium
6.7
mg/kg
2.5
04/06/15 11:55
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 8 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800�Srpyf�e. Suite 100
Huntersville, NC 28078
[phone]
Project: J15030700
Pace Project No.: 92243096
Lab Sample ID Client Sample ID
Method Parameters
SUMMARY OF DETECTION
Result Units Report Limit Analyzed Qualifiers
92243096002
2015008685
ASTM D2974-87
Percent Moisture
2.8
%
0.10
04/04/15 20:05
EPA 9045
pH at 25 Degrees C
8.4
Std. Units
0.10
04/02/15 09:35
EPA 300.0
Sulfate
3.9
mg/L
2.1
04/09/15 17:09
B
SM 4500-CI-E
Chloride
3.9J
mg/L
5.1
04/09/15 04:55
M1
EPA 9060
RSD%
2.0
%
04/10/15 19:44
92243096003
2015008689
EPA 6010
Aluminum
12700
mg/kg
37.9
04/09/15 06:12
D3
EPA 6010
Barium
217
mg/kg
3.8
04/09/15 06:12
D3
EPA 6010
Beryllium
2.9
mg/kg
0.38
04/09/15 06:12
D3
EPA 6010
Boron
27.8
mg/kg
18.9
04/09/15 06:12
D3
EPA 6010
Calcium
1700
mg/kg
189
04/09/15 06:12
D3
EPA 6010
Chromium
15.4
mg/kg
1.9
04/09/15 06:12
D3
EPA 6010
Copper
48.8
mg/kg
1.9
04/09/15 06:12
D3
EPA 6010
Iron
7270
mg/kg
15.2
04/09/15 06:12
D3
EPA 6010
Magnesium
947
mg/kg
189
04/09/15 06:12
D3
EPA 6010
Manganese
49.6
mg/kg
1.9
04/09/15 06:12
D3
EPA 6010
Molybdenum
5.4
mg/kg
3.8
04/09/15 06:12
D3
EPA 6010
Nickel
21.4
mg/kg
1.9
04/09/15 06:12
D3
EPA 6010
Potassium
2350
mg/kg
379
04/09/15 06:12
D3
EPA 6010
Sodium
304J
mg/kg
379
04/09/15 06:12
D3
EPA 6010
Strontium
139
mg/kg
3.8
04/09/15 06:12
D3
EPA 6010
Zinc
43.5
mg/kg
7.6
04/09/15 06:12
D3
EPA 6020
Arsenic
115
mg/kg
3.8
04/06/15 11:57
EPA 6020
Cadmium
0.37J
mg/kg
0.45
04/06/15 11:57
EPA 6020
Cobalt
9.4
mg/kg
3.8
04/06/15 11:57
EPA 6020
Lead
18.3
mg/kg
3.8
04/06/15 11:57
EPA 6020
Selenium
14.9
mg/kg
3.8
04/06/15 11:57
EPA 6020
Vanadium
51.2
mg/kg
3.8
04/06/15 11:57
EPA 7471
Mercury
0.14
mg/kg
0.012
04/04/15 21:06
ASTM D2974-87
Percent Moisture
31.3
%
0.10
04/04/15 20:05
EPA 9045
pH at 25 Degrees C
5.7
Std. Units
0.10
04/03/15 10:15
EPA 300.0
Sulfate
18.9
mg/L
2.9
04/09/15 17:50
B
EPA 9056
Sulfate
244J
mg/kg
362
04/03/15 03:52
EPA 9060
Total Organic Carbon
56000
mg/kg
7970
04/10/15 16:19
EPA 9060
Total Organic Carbon
43900
mg/kg
7890
04/10/15 16:25
EPA 9060
Total Organic Carbon
46100
mg/kg
7920
04/10/15 16:31
EPA 9060
Total Organic Carbon
49300
mg/kg
7560
04/10/15 16:37
EPA 9060
Mean Total Organic Carbon
48800
mg/kg
7830
04/10/15 16:19
EPA 9060
RSD%
10.8
%
04/10/15 16:19
92243096004
2015008691
EPA 6010
Aluminum
5450
mg/kg
33.5
04/09/15 06:16
D3
EPA 6010
Barium
38.5
mg/kg
3.4
04/09/15 06:16
D3
EPA 6010
Beryllium
0.44
mg/kg
0.34
04/09/15 06:16
D3
EPA 6010
Boron
46.5
mg/kg
16.8
04/09/15 06:16
D3
EPA 6010
Chromium
7.2
mg/kg
1.7
04/09/15 06:16
D3
EPA 6010
Copper
26.1
mg/kg
1.7
04/09/15 06:16
D3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 9 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800A'irpyf�e. Suite 100
Huntersville, NC 28078
[phone]
Project: J15030700
Pace Project No.: 92243096
Lab Sample ID Client Sample ID
Method Parameters
SUMMARY OF DETECTION
Result Units Report Limit Analyzed
92243096004
2015008691
EPA 6010
Iron
50400
mg/kg
13.4
04/09/15 06:16
D4
EPA 6010
Magnesium
234
mg/kg
168
04/09/15 06:16
D3
EPA 6010
Manganese
348
mg/kg
1.7
04/09/15 06:16
D3
EPA 6010
Nickel
2.8
mg/kg
1.7
04/09/15 06:16
D3
EPA 6010
Zinc
18.1
mg/kg
6.7
04/09/15 06:16
D3
EPA 6020
Arsenic
3.6
mg/kg
3.4
04/06/15 11:59
EPA 6020
Cobalt
3.9
mg/kg
3.4
04/06/15 11:59
EPA 6020
Lead
9.8
mg/kg
3.4
04/06/15 11:59
EPA 6020
Vanadium
14.9
mg/kg
3.4
04/06/15 11:59
EPA 7471
Mercury
0.037
mg/kg
0.010
04/04/15 21:12
ASTM D2974-87
Percent Moisture
22.9
%
0.10
04/04/15 20:05
EPA 9045
pH at 25 Degrees C
4.8
Std. Units
0.10
04/08/15 22:00
EPA 300.0
Sulfate
7.8
mg/L
2.6
04/09/15 18:03
B
EPA 9060
Total Organic Carbon
552J
mg/kg
777
04/10/15 16:43
EPA 9060
Total Organic Carbon
526J
mg/kg
779
04/10/15 16:48
EPA 9060
Total Organic Carbon
529J
mg/kg
771
04/10/15 16:54
EPA 9060
Total Organic Carbon
563J
mg/kg
784
04/10/15 16:59
EPA 9060
Mean Total Organic Carbon
542J
mg/kg
778
04/10/15 16:43
EPA 9060
RSD%
3.3
%
04/10/15 16:43
92243096005
2015008692
EPA 6010
Aluminum
11000
mg/kg
30.8
04/09/15 06:20
D3
EPA 6010
Barium
8.8
mg/kg
3.1
04/09/15 06:20
D3
EPA 6010
Boron
34.4
mg/kg
15.4
04/09/15 06:20
D3
EPA 6010
Chromium
22.5
mg/kg
1.5
04/09/15 06:20
D3
EPA 6010
Copper
9.2
mg/kg
1.5
04/09/15 06:20
D3
EPA 6010
Iron
35600
mg/kg
12.3
04/09/15 06:20
D4
EPA 6010
Magnesium
94.OJ
mg/kg
154
04/09/15 06:20
D3
EPA 6010
Manganese
13.9
mg/kg
1.5
04/09/15 06:20
D3
EPA 6020
Lead
8.9
mg/kg
3.1
04/06/15 12:01
EPA 6020
Vanadium
74.5
mg/kg
3.1
04/06/15 12:01
EPA 7471
Mercury
0.030
mg/kg
0.0098
04/04/15 21:14
ASTM D2974-87
Percent Moisture
21.7
%
0.10
04/04/15 20:05
EPA 9045
pH at 25 Degrees C
4.0
Std. Units
0.10
04/08/15 22:00
EPA 300.0
Sulfate
19.0
mg/L
2.6
04/09/15 18:17
B
EPA 9056
Sulfate
1811
mg/kg
323
04/03/15 04:35
EPA 9060
Total Organic Carbon
899
mg/kg
765
04/10/15 17:18
EPA 9060
Total Organic Carbon
855
mg/kg
772
04/10/15 17:23
EPA 9060
Total Organic Carbon
906
mg/kg
759
04/10/15 17:30
EPA 9060
Total Organic Carbon
939
mg/kg
766
04/10/15 17:36
EPA 9060
Mean Total Organic Carbon
900
mg/kg
766
04/10/15 17:18
EPA 9060
RSD%
3.8
%
04/10/15 17:18
92243096006
2015008686
EPA 6010
Aluminum
6810
mg/kg
5.1
04/05/15 02:45
M1
EPA 6010
Barium
81.6
mg/kg
0.51
04/05/15 02:45
M1
EPA 6010
Beryllium
0.42
mg/kg
0.25
04/09/15 04:20
D3
EPA 6010
Boron
14.7
mg/kg
12.7
04/09/15 04:20
D3
REPORT OF LABORATORY ANALYSIS
Qualifiers
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 10 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800Airpyf�e. Suite 100
Huntersville, NC 28078
[phone]
SUMMARY OF DETECTION
Project:
Pace Project No.:
J15030700
92243096
Lab Sample ID
Client Sample ID
Method
Parameters
Result
Units
Report Limit
Analyzed
Qualifiers
92243096006
2015008686
EPA 6010
Calcium
2750
mg/kg
25.4
04/05/15 02:45
M1
EPA 6010
Chromium
8.9
mg/kg
1.3
04/09/15 04:20
D3
EPA 6010
Copper
9.0
mg/kg
1.3
04/09/15 04:20
D3
EPA 6010
Iron
10200
mg/kg
2.0
04/05/15 02:45
M1
EPA 6010
Magnesium
4940
mg/kg
25.4
04/05/15 02:45
M1
EPA 6010
Manganese
386
mg/kg
1.3
04/09/15 04:20
D3,M1
EPA 6010
Nickel
6.3
mg/kg
0.25
04/05/15 02:45
EPA 6010
Potassium
1180
mg/kg
50.8
04/05/15 02:45
EPA 6010
Sodium
95.7
mg/kg
50.8
04/05/15 02:45
EPA 6010
Strontium
21.9
mg/kg
0.51
04/05/15 02:45
EPA 6010
Zinc
50.7
mg/kg
1.0
04/05/15 02:45
EPA 6020
Arsenic
2.9
mg/kg
2.5
04/06/15 12:08
EPA 6020
Cobalt
8.1
mg/kg
2.5
04/06/15 12:08
EPA 6020
Lead
5.2
mg/kg
2.5
04/06/15 12:08
EPA 6020
Selenium
2AJ
mg/kg
2.5
04/06/15 12:08
EPA 6020
Vanadium
12.3
mg/kg
2.5
04/06/15 12:08
ASTM D2974-87
Percent Moisture
4.9
%
0.10
04/04/15 20:06
EPA 9045
pH at 25 Degrees C
8.6
Std. Units
0.10
04/02/15 09:35
EPA 9060
RSD%
5.0
%
04/13/15 09:58
92243096007
2015008693
EPA 6010
Aluminum
3830
mg/kg
5.5
04/05/15 02:58
EPA 6010
Barium
19.0
mg/kg
0.55
04/05/15 02:58
EPA 6010
Beryllium
0.79
mg/kg
0.27
04/09/15 04:33
D3
EPA 6010
Boron
53.2
mg/kg
13.7
04/09/15 04:33
D3
EPA 6010
Calcium
544
mg/kg
27.4
04/05/15 02:58
EPA 6010
Chromium
27.3
mg/kg
1.4
04/09/15 04:33
D3
EPA 6010
Copper
75.1
mg/kg
1.4
04/09/15 04:33
D3
EPA 6010
Iron
60400
mg/kg
11.0
04/09/15 04:33
D4
EPA 6010
Magnesium
762
mg/kg
27.4
04/05/15 02:58
EPA 6010
Manganese
72.6
mg/kg
1.4
04/09/15 04:33
EPA 6010
Molybdenum
0.62
mg/kg
0.55
04/05/15 02:58
EPA 6010
Nickel
20.3
mg/kg
0.27
04/05/15 02:58
EPA 6010
Potassium
262
mg/kg
54.8
04/05/15 02:58
EPA 6010
Strontium
5.5
mg/kg
0.55
04/05/15 02:58
EPA 6010
Zinc
56.8
mg/kg
1.1
04/05/15 02:58
EPA 6020
Arsenic
7.7
mg/kg
2.7
04/06/15 12:24
M6
EPA 6020
Cobalt
8.4
mg/kg
2.7
04/06/15 12:24
M6
EPA 6020
Lead
15.6
mg/kg
2.7
04/06/15 12:24
M6, R1
EPA 6020
Vanadium
18.5
mg/kg
2.7
04/06/15 12:24
M6, R1
EPA 7471
Mercury
0.058
mg/kg
0.0094
04/07/15 09:22
ASTM D2974-87
Percent Moisture
11.5
%
0.10
04/04/15 20:06
EPA 9045
pH at 25 Degrees C
4.6
Std. Units
0.10
04/08/15 22:00
EPA 9060
Total Organic Carbon
118000
mg/kg
7910
04/10/15 18:08
EPA 9060
Total Organic Carbon
91000
mg/kg
8080
04/10/15 18:14
EPA 9060
Total Organic Carbon
89500
mg/kg
7600
04/10/15 18:21
EPA 9060
Total Organic Carbon
102000
mg/kg
7410
04/10/15 18:27
EPA 9060
Mean Total Organic Carbon
100000
mg/kg
7750
04/10/15 18:08
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 11 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800Arpyf�e. Suite 100
Huntersville, NC 28078
[phone]
Project: J15030700
Pace Project No.: 92243096
Lab Sample ID Client Sample ID
Method Parameters
SUMMARY OF DETECTION
Result Units Report Limit Analyzed Qualifiers
92243096007
2015008693
EPA 9060
RSD%
13.3
%
04/10/15 18:08
92243096008
2015008683 SPLP
EPA 6020A
Aluminum
91800
ug/L
50.0
04/28/15 05:15
EPA 6020A
Arsenic
23.6
ug/L
0.50
04/28/15 05:10
EPA 6020A
Barium
606
ug/L
1.5
04/28/15 05:15
EPA 6020A
Beryllium
4.1
ug/L
0.20
04/28/15 05:10
EPA 6020A
Boron
97.3
ug/L
5.0
04/28/15 05:10
EPA 6020A
Cadmium
0.11
ug/L
0.080
04/28/15 05:10
EPA 6020A
Calcium
11800
ug/L
40.0
04/28/15 05:10
EPA 6020A
Chromium
110
ug/L
0.50
04/28/15 05:10
EPA 6020A
Cobalt
34.4
ug/L
0.50
04/28/15 05:10
EPA 6020A
Copper
62.5
ug/L
1.0
04/28/15 05:10
EPA 6020A
Iron
56500
ug/L
250
04/28/15 05:15
EPA 6020A
Lead
36.5
ug/L
0.10
04/28/15 05:10
EPA 6020A
Magnesium
5970
ug/L
10.0
04/28/15 05:10
EPA 6020A
Manganese
694
ug/L
2.5
04/28/15 05:15
EPA 6020A
Molybdenum
64.9
ug/L
0.50
04/28/15 05:10
EPA 6020A
Nickel
39.6
ug/L
0.50
04/28/15 05:10
EPA 6020A
Potassium
2060
ug/L
50.0
04/28/15 05:10
EPA 6020A
Selenium
6.1
ug/L
0.50
04/28/15 05:10
EPA 6020A
Sodium
1630
ug/L
50.0
04/28/15 05:10
EPA 6020A
Strontium
276
ug/L
0.50
04/28/15 05:10
EPA 6020A
Thallium
0.37
ug/L
0.10
04/28/15 05:10
EPA 6020A
Vanadium
313
ug/L
5.0
04/29/15 11:19
EPA 6020A
Zinc
196
ug/L
5.0
04/28/15 05:10
EPA 7470A
Mercury
0.23
ug/L
0.20
04/23/15 21:18
92243096009
2015008685 SPLP
EPA 6020A
Aluminum
6300
ug/L
10.0
04/30/15 11:15
EPA 6020A
Antimony
0.16J
ug/L
0.50
04/30/15 11:15
EPA 6020A
Arsenic
5.0
ug/L
0.50
04/30/15 11:15
EPA 6020A
Barium
265
ug/L
0.30
04/30/15 11:15
EPA 6020A
Beryllium
0.24
ug/L
0.20
04/30/15 11:15
EPA 6020A
Boron
47.6
ug/L
5.0
04/30/15 11:15
EPA 6020A
Cadmium
0.035J
ug/L
0.080
04/30/15 11:15
EPA 6020A
Calcium
8710
ug/L
40.0
04/30/15 11:15
EPA 6020A
Chromium
4.1
ug/L
0.50
04/30/15 11:15
EPA 6020A
Cobalt
1.8
ug/L
0.50
04/30/15 11:15
EPA 6020A
Copper
3.3
ug/L
1.0
04/30/15 11:15
EPA 6020A
Iron
6490
ug/L
50.0
04/30/15 11:15
EPA 6020A
Lead
3.5
ug/L
0.10
04/30/15 11:15
EPA 6020A
Magnesium
2360
ug/L
10.0
04/30/15 11:15
EPA 6020A
Manganese
182
ug/L
0.50
04/30/15 11:15
EPA 6020A
Molybdenum
4.6
ug/L
0.50
04/30/15 11:15
EPA 6020A
Nickel
2.0
ug/L
0.50
04/30/15 11:15
EPA 6020A
Potassium
2640
ug/L
50.0
04/30/15 11:15
EPA 6020A
Selenium
0.42J
ug/L
0.50
04/30/15 11:15
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 12 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800�qrpyf�e. Suite 100
Huntersville, NC 28078
[phone]
Project: J15030700
Pace Project No.: 92243096
Lab Sample ID Client Sample ID
Method Parameters
SUMMARY OF DETECTION
Result Units Report Limit Analyzed
92243096009
2015008685 SPLP
EPA 6020A
Sodium
3050
ug/L
50.0
04/30/15 11:15
EPA 6020A
Strontium
49.9
ug/L
0.50
04/30/15 11:15
EPA 6020A
Thallium
0.044J
ug/L
0.10
04/30/15 11:15
EPA 6020A
Vanadium
25.2
ug/L
1.0
04/30/15 11:15
EPA 6020A
Zinc
38.7
ug/L
5.0
04/30/15 11:15
EPA 7470A
Mercury
0.030J
ug/L
0.20
04/23/15 21:20
92243096010
2015008689 SPLP
EPA 6020A
Aluminum
16.2
ug/L
10.0
04/30/15 10:42
EPA 6020A
Antimony
4.3
ug/L
0.50
04/30/15 10:42
EPA 6020A
Arsenic
3.9
ug/L
0.50
04/30/15 10:42
EPA 6020A
Barium
292
ug/L
0.30
04/30/15 10:42
EPA 6020A
Boron
81.5
ug/L
5.0
04/30/15 10:42
EPA 6020A
Cadmium
0.18
ug/L
0.080
04/30/15 10:42
EPA 6020A
Calcium
3450
ug/L
40.0
04/30/15 10:42
EPA 6020A
Chromium
0.46J
ug/L
0.50
04/30/15 10:42
EPA 6020A
Cobalt
4.7
ug/L
0.50
04/30/15 10:42
EPA 6020A
Copper
0.80J
ug/L
1.0
04/30/15 10:42
EPA 6020A
Magnesium
593
ug/L
10.0
04/30/15 10:42
EPA 6020A
Manganese
26.6
ug/L
0.50
04/30/15 10:42
EPA 6020A
Molybdenum
14.3
ug/L
0.50
04/30/15 10:42
EPA 6020A
Nickel
13.5
ug/L
0.50
04/30/15 10:42
EPA 6020A
Potassium
450
ug/L
50.0
04/30/15 10:42
EPA 6020A
Selenium
14.8
ug/L
0.50
04/30/15 10:42
EPA 6020A
Sodium
2400
ug/L
50.0
04/30/15 10:42
EPA 6020A
Strontium
267
ug/L
0.50
04/30/15 10:42
EPA 6020A
Vanadium
9.9
ug/L
1.0
04/30/15 10:42
EPA 6020A
Zinc
66.6
ug/L
5.0
04/30/15 10:42
92243096011
2015008691 SPLP
EPA 6020A
Aluminum
7.7J
ug/L
10.0
04/30/15 10:51
EPA 6020A
Barium
182
ug/L
0.30
04/30/15 10:51
EPA 6020A
Boron
97.0
ug/L
5.0
04/30/15 10:51
EPA 6020A
Cadmium
0.031J
ug/L
0.080
04/30/15 10:51
EPA 6020A
Calcium
598
ug/L
40.0
04/30/15 10:51
EPA 6020A
Chromium
0.84
ug/L
0.50
04/30/15 10:51
EPA 6020A
Cobalt
5.6
ug/L
0.50
04/30/15 10:51
EPA 6020A
Copper
0.79J
ug/L
1.0
04/30/15 10:51
EPA 6020A
Lead
0.11
ug/L
0.10
04/30/15 10:51
EPA 6020A
Magnesium
383
ug/L
10.0
04/30/15 10:51
EPA 6020A
Manganese
152
ug/L
0.50
04/30/15 10:51
EPA 6020A
Nickel
1.9
ug/L
0.50
04/30/15 10:51
EPA 6020A
Potassium
326
ug/L
50.0
04/30/15 10:51
EPA 6020A
Sodium
2030
ug/L
50.0
04/30/15 10:51
EPA 6020A
Strontium
10.4
ug/L
0.50
04/30/15 10:51
EPA 6020A
Zinc
128
ug/L
5.0
04/30/15 10:51
EPA 7470A
Mercury
0.030J
ug/L
0.20
04/23/15 21:33
REPORT OF LABORATORY ANALYSIS
Qualifiers
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 13 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800Airpyf�e. Suite 100
Huntersville, NC 28078
[phone]
Project: J15030700
Pace Project No.: 92243096
Lab Sample ID Client Sample ID
Method Parameters
SUMMARY OF DETECTION
Result Units Report Limit Analyzed
92243096012
2015008692 SPLP
EPA 6020A
Aluminum
145
ug/L
10.0
04/30/15 11:10
EPA 6020A
Barium
168
ug/L
0.30
04/30/15 11:10
EPA 6020A
Boron
95.5
ug/L
5.0
04/30/15 11:10
EPA 6020A
Cadmium
0.063J
ug/L
0.080
04/30/15 11:10
EPA 6020A
Calcium
1350
ug/L
40.0
04/30/15 11:10
EPA 6020A
Chromium
0.40J
ug/L
0.50
04/30/15 11:10
EPA 6020A
Cobalt
1.8
ug/L
0.50
04/30/15 11:10
EPA 6020A
Copper
1.3
ug/L
1.0
04/30/15 11:10
EPA 6020A
Iron
1560
ug/L
50.0
04/30/15 11:10
EPA 6020A
Lead
0.21
ug/L
0.10
04/30/15 11:10
EPA 6020A
Magnesium
823
ug/L
10.0
04/30/15 11:10
EPA 6020A
Manganese
150
ug/L
0.50
04/30/15 11:10
EPA 6020A
Nickel
1.8
ug/L
0.50
04/30/15 11:10
EPA 6020A
Potassium
696
ug/L
50.0
04/30/15 11:10
EPA 6020A
Sodium
2570
ug/L
50.0
04/30/15 11:10
EPA 6020A
Strontium
22.7
ug/L
0.50
04/30/15 11:10
EPA 6020A
Zinc
160
ug/L
5.0
04/30/15 11:10
92243096013
2015008684
EPA 6020A
Aluminum
123
ug/L
10.0
04/02/15 19:08
EPA 6020A
Barium
2.6
ug/L
0.30
04/02/15 19:08
EPA 6020A
Calcium
373
ug/L
40.0
04/02/15 19:08
EPA 6020A
Chromium
0.50
ug/L
0.50
04/02/15 19:08
EPA 6020A
Iron
1030
ug/L
50.0
04/02/15 19:08
EPA 6020A
Lead
0.27
ug/L
0.10
04/02/15 19:08
EPA 6020A
Magnesium
79.0
ug/L
10.0
04/02/15 19:08
EPA 6020A
Manganese
19.8
ug/L
0.50
04/02/15 19:08
EPA 6020A
Molybdenum
0.73
ug/L
0.50
04/02/15 19:08
EPA 6020A
Nickel
0.78
ug/L
0.50
04/02/15 19:08
EPA 6020A
Potassium
129
ug/L
50.0
04/02/15 19:08
EPA 6020A
Sodium
259
ug/L
50.0
04/02/15 19:08
EPA 6020A
Strontium
2.5
ug/L
0.50
04/02/15 19:08
92243096014
2015008687
EPA 6020A
Aluminum
59.9
ug/L
10.0
04/02/15 19:11
EPA 6020A
Barium
1.0
ug/L
0.30
04/02/15 19:11
EPA 6020A
Calcium
141
ug/L
40.0
04/02/15 19:11
EPA 6020A
Chromium
1.1
ug/L
0.50
04/02/15 19:11
EPA 6020A
Iron
814
ug/L
50.0
04/02/15 19:11
EPA 6020A
Lead
0.11
ug/L
0.10
04/02/15 19:11
EPA 6020A
Magnesium
35.7
ug/L
10.0
04/02/15 19:11
EPA 6020A
Manganese
10.3
ug/L
0.50
04/02/15 19:11
EPA 6020A
Molybdenum
0.74
ug/L
0.50
04/02/15 19:11
EPA 6020A
Potassium
67.1
ug/L
50.0
04/02/15 19:11
EPA 6020A
Sodium
135
ug/L
50.0
04/02/15 19:11
EPA 6020A
Strontium
1.1
ug/L
0.50
04/02/15 19:11
EPA 6020A
Zinc
7.3
ug/L
5.0
04/02/15 19:11
REPORT OF LABORATORY ANALYSIS
Qualifiers
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 14 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800hrpyf�e. Suite 100
Huntersville, NC 28078
[phone]
Project: J15030700
Pace Project No.: 92243096
Lab Sample ID Client Sample ID
Method Parameters
SUMMARY OF DETECTION
Result Units Report Limit Analyzed
92243096015
2015008688
EPA 6020A
Aluminum
567
ug/L
10.0
04/02/15 19:14
EPA 6020A
Barium
6.6
ug/L
0.30
04/02/15 19:14
EPA 6020A
Calcium
155
ug/L
40.0
04/02/15 19:14
EPA 6020A
Chromium
3.1
ug/L
0.50
04/02/15 19:14
EPA 6020A
Cobalt
0.66
ug/L
0.50
04/02/15 19:14
EPA 6020A
Iron
1570
ug/L
50.0
04/02/15 19:14
EPA 6020A
Lead
0.35
ug/L
0.10
04/02/15 19:14
EPA 6020A
Magnesium
201
ug/L
10.0
04/02/15 19:14
EPA 6020A
Manganese
22.0
ug/L
0.50
04/02/15 19:14
EPA 6020A
Molybdenum
1.3
ug/L
0.50
04/02/15 19:14
EPA 6020A
Nickel
1.1
ug/L
0.50
04/02/15 19:14
EPA 6020A
Potassium
201
ug/L
50.0
04/02/15 19:14
EPA 6020A
Sodium
442
ug/L
50.0
04/02/15 19:14
EPA 6020A
Strontium
1.3
ug/L
0.50
04/02/15 19:14
EPA 6020A
Vanadium
1.3
ug/L
1.0
04/02/15 19:14
EPA 6020A
Zinc
10
ug/L
5.0
04/02/15 19:14
92243096016
2015008690
EPA 6020A
Aluminum
236
ug/L
10.0
04/02/15 19:17
EPA 6020A
Barium
2.8
ug/L
0.30
04/02/15 19:17
EPA 6020A
Calcium
505
ug/L
40.0
04/02/15 19:17
EPA 6020A
Chromium
2.7
ug/L
0.50
04/02/15 19:17
EPA 6020A
Cobalt
3.5
ug/L
0.50
04/02/15 19:17
EPA 6020A
Copper
2.8
ug/L
1.0
04/02/15 19:17
EPA 6020A
Iron
479
ug/L
50.0
04/02/15 19:17
EPA 6020A
Lead
0.44
ug/L
0.10
04/02/15 19:17
EPA 6020A
Magnesium
55.7
ug/L
10.0
04/02/15 19:17
EPA 6020A
Manganese
7.1
ug/L
0.50
04/02/15 19:17
EPA 6020A
Nickel
0.57
ug/L
0.50
04/02/15 19:17
EPA 6020A
Potassium
125
ug/L
50.0
04/02/15 19:17
EPA 6020A
Sodium
67.7
ug/L
50.0
04/02/15 19:17
EPA 6020A
Strontium
2.5
ug/L
0.50
04/02/15 19:17
EPA 6020A
Zinc
5.4
ug/L
5.0
04/02/15 19:17
REPORT OF LABORATORY ANALYSIS
Qualifiers
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 15 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980aq8rpyf�e. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15030700
Pace Project No.: 92243096
Method: EPA 6010
Description: 6010 MET ICP
Client: Duke Energy
Date: May 11, 2015
General Information:
7 samples were analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 3050 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
QC Batch: MPRP/23407
B: Analyte was detected in the associated method blank.
• BLANK for HBN 225655 [MPRP/234 (Lab ID: 1173242)
• Zinc
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: MPRP/23407
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92242976001
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1173244)
• Aluminum
• Copper
• Iron
• Strontium
• MSD (Lab ID: 1173245)
• Aluminum
• Barium
• Beryllium
• Calcium
• Copper
• Iron
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 16 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980mirpyf�e. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15030700
Pace Project No.: 92243096
Method: EPA 6010
Description: 6010 MET ICP
Client: Duke Energy
Date: May 11, 2015
QC Batch: MPRP/23407
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92242976001
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• Strontium
QC Batch: MPRP/23414
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92243096006
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1173681)
• Aluminum
• Barium
• Calcium
• Iron
• Magnesium
• Manganese
• Molybdenum
• MSD (Lab ID: 1173682)
• Aluminum
• Barium
• Iron
• Magnesium
• Manganese
• Molybdenum
Additional Comments:
Analyte Comments:
QC Batch: MPRP/23407
D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
•2015008683 (Lab ID:92243096001)
• Aluminum
• Boron
• Barium
• Beryllium
• Calcium
• Chromium
• Copper
• Iron
• Potassium
• Magnesium
• Manganese
• Molybdenum
• Sodium
• Nickel
• Strontium
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 17 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980agirpyf�e. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15030700
Pace Project No.: 92243096
Method: EPA 6010
Description: 6010 MET ICP
Client: Duke Energy
Date: May 11, 2015
Analyte Comments:
QC Batch: MPRP/23407
D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
•2015008683 (Lab ID:92243096001)
• Zinc
•2015008685 (Lab ID:92243096002)
• Aluminum
• Boron
• Barium
• Beryllium
• Chromium
• Copper
• Iron
• Potassium
• Magnesium
• Manganese
• Molybdenum
• Sodium
• Nickel
• Strontium
• Zinc
•2015008689 (Lab ID:92243096003)
• Aluminum
• Boron
• Barium
• Beryllium
• Calcium
• Chromium
• Copper
• Iron
• Potassium
• Magnesium
• Manganese
• Molybdenum
• Sodium
• Nickel
• Strontium
• Zinc
•2015008691 (Lab ID:92243096004)
• Aluminum
• Boron
• Barium
• Beryllium
• Calcium
• Chromium
• Copper
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 18 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980agirpyf�e. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15030700
Pace Project No.: 92243096
Method: EPA 6010
Description: 6010 MET ICP
Client: Duke Energy
Date: May 11, 2015
Analyte Comments:
QC Batch: MPRP/23407
D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
•2015008691 (Lab ID:92243096004)
• Potassium
• Magnesium
• Manganese
• Molybdenum
• Sodium
• Nickel
• Strontium
• Zinc
•2015008692 (Lab ID:92243096005)
• Aluminum
• Boron
• Barium
• Beryllium
• Calcium
• Chromium
• Copper
• Potassium
• Magnesium
• Manganese
• Molybdenum
• Sodium
• Nickel
• Strontium
• Zinc
D4: Sample was diluted due to the presence of high levels of target analytes.
•2015008685 (Lab ID:92243096002)
• Calcium
•2015008691 (Lab ID:92243096004)
• Iron
•2015008692 (Lab ID:92243096005)
• Iron
QC Batch: MPRP/23414
D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
•2015008686 (Lab ID:92243096006)
• Boron
• Beryllium
• Chromium
• Copper
• Manganese
•2015008693 (Lab ID:92243096007)
• Boron
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 19 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800A'irpyf�e. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15030700
Pace Project No.: 92243096
Method: EPA 6010
Description: 6010 MET ICP
Client: Duke Energy
Date: May 11, 2015
Analyte Comments:
QC Batch: MPRP/23414
D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
•2015008693 (Lab ID:92243096007)
• Beryllium
• Chromium
• Copper
• MS (Lab ID: 1173681)
• Boron
• Beryllium
• Chromium
• Copper
• Manganese
• MSD (Lab ID: 1173682)
• Boron
• Beryllium
• Chromium
• Copper
• Manganese
D4: Sample was diluted due to the presence of high levels of target analytes.
•2015008693 (Lab ID:92243096007)
• Iron
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 20 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980agirpyf�e. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15030700
Pace Project No.: 92243096
Method: EPA 6020
Description: 6020 MET ICPMS
Client: Duke Energy
Date: May 11, 2015
General Information:
7 samples were analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 3050 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: MPRP/23408
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92242976002
M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
• MS (Lab ID: 1173248)
• Antimony
• Arsenic
• Cobalt
• Lead
• Selenium
• Thallium
• Vanadium
• MSD (Lab ID: 1173249)
• Antimony
• Arsenic
• Cobalt
• Lead
• Selenium
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 21 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980aq8rpyf�e. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15030700
Pace Project No.: 92243096
Method: EPA 6020
Description: 6020 MET ICPMS
Client: Duke Energy
Date: May 11, 2015
QC Batch: MPRP/23408
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92242976002
M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
• Thallium
• Vanadium
QC Batch: MPRP/23415
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92243096007
M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
• MS (Lab ID: 1173685)
• Antimony
• Arsenic
• Cobalt
• Lead
• Thallium
• Vanadium
• MSD (Lab ID: 1173686)
• Antimony
• Arsenic
• Cobalt
• Lead
• Selenium
• Thallium
• Vanadium
R1: RPD value was outside control limits.
• MSD (Lab ID: 1173686)
• Lead
• Selenium
• Vanadium
Additional Comments:
Analyte Comments:
QC Batch: MPRP/23408
N2: The lab does not hold TNI accreditation for this parameter.
•2015008683 (Lab ID:92243096001)
• Antimony
•2015008685 (Lab ID:92243096002)
• Antimony
•2015008689 (Lab ID:92243096003)
• Antimony
•2015008691 (Lab ID:92243096004)
• Antimony
•2015008692 (Lab ID:92243096005)
• Antimony
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 22 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800*rpyf�e. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15030700
Pace Project No.: 92243096
Method: EPA 6020
Description: 6020 MET ICPMS
Client: Duke Energy
Date: May 11, 2015
Analyte Comments:
QC Batch: MPRP/23408
N2: The lab does not hold TNI accreditation for this parameter.
• BLANK (Lab ID: 1173246)
• Antimony
• LCS (Lab ID: 1173247)
• Antimony
• MS (Lab ID: 1173248)
• Antimony
• MSD (Lab ID: 1173249)
• Antimony
QC Batch: MPRP/23415
N2: The lab does not hold TNI accreditation for this parameter.
•2015008686 (Lab ID:92243096006)
• Antimony
•2015008693 (Lab ID:92243096007)
• Antimony
• BLANK (Lab ID: 1173683)
• Antimony
• LCS (Lab ID: 1173684)
• Antimony
• MS (Lab ID: 1173685)
• Antimony
• MSD (Lab ID: 1173686)
• Antimony
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc.. Page 23 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980a�grpyf�e. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15030700
Pace Project No.: 92243096
Method: EPA 6020A
Description: 6020A MET ICPMS
Client: Duke Energy
Date: May 11, 2015
General Information:
9 samples were analyzed for EPA 6020A. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 3020 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: MPRP/53956
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 10304468001
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1949383)
• Aluminum
QC Batch: MPRP/54015
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92243096009
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1951297)
• Aluminum
• Magnesium
• Potassium
• MSD (Lab ID: 1951298)
• Aluminum
• Barium
• Iron
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 24 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980agirpyf�e. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15030700
Pace Project No.: 92243096
Method: EPA 6020A
Description: 6020A MET ICPMS
Client: Duke Energy
Date: May 11, 2015
QC Batch: MPRP/54015
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92243096009
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• Magnesium
• Potassium
R1: RPD value was outside control limits.
• MSD (Lab ID: 1951298)
• Iron
Additional Comments:
Analyte Comments:
QC Batch: MPRP/53956
P8: Analyte was detected in the method blank. All associated samples had concentrations of at least ten times greater than the blank
or were below the reporting limit.
• BLANK (Lab ID: 1949352)
• Barium
• Chromium
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 25 of 97

aceAnaiXical
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Pace Analytical Services, Inc.
980041 W �e. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15030700
Pace Project No.: 92243096
Method: EPA 7470
Description: 7470 Mercury
Client: Duke Energy
Date: May 11, 2015
General Information:
4 samples were analyzed for EPA 7470. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 7470 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 26 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
98004ff W �e. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15030700
Pace Project No.: 92243096
Method: EPA 7470A
Description: 7470A Mercury
Client: Duke Energy
Date: May 11, 2015
General Information:
5 samples were analyzed for EPA 7470A. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 7470A with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 27 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
98004K Wee f�e. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15030700
Pace Project No.: 92243096
Method: EPA 7471
Description: 7471 Mercury
Client: Duke Energy
Date: May 11, 2015
General Information:
7 samples were analyzed for EPA 7471. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 7471 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 28 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
98004WeYf. e. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15030700
Pace Project No.: 92243096
Method: EPA 9045
Description: 9045 pH Soil
Client: Duke Energy
Date: May 11, 2015
General Information:
7 samples were analyzed for EPA 9045. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
Analyte Comments:
QC Batch: WET/36660
• DUP (Lab ID: 1427812)
• pH at 25 Degrees C
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc.. Page 29 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
98004WW �e. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15030700
Pace Project No.: 92243096
Method: EPA 300.0
Description: 300.0 IC Anions, SPLP
Client: Duke Energy
Date: May 11, 2015
General Information:
5 samples were analyzed for EPA 300.0. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
QC Batch: WETA/22469
B: Analyte was detected in the associated method blank.
• BLANK for HBN 258521 [WETA/224 (Lab ID: 1428206)
• Sulfate
QC Batch: WETA/22495
B: Analyte was detected in the associated method blank.
• BLANK for HBN 258853 [WETA/224 (Lab ID: 1430392)
• Sulfate
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 30 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980041j WeYf. e. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15030700
Pace Project No.: 92243096
Method: EPA 353.2
Description: 353.2 Nitrogen, NO2/NO3, SPLP
Client: Duke Energy
Date: May 11, 2015
General Information:
5 samples were analyzed for EPA 353.2. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
1-11: Analysis conducted outside the EPA method holding time.
•2015008683 (Lab ID:92243096001)
•2015008685 (Lab ID:92243096002)
•2015008689 (Lab ID:92243096003)
•2015008691 (Lab ID:92243096004)
•2015008692 (Lab ID:92243096005)
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 31 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800*WeYf. e. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15030700
Pace Project No.: 92243096
Method: SM 4500-CI-E
Description: 4500 Chloride, SPLP
Client: Duke Energy
Date: May 11, 2015
General Information:
5 samples were analyzed for SM 4500-CI-E. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: WETA/22491
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92243096002,92243393001
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MSD (Lab ID: 1430200)
• Chloride
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 32 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800*WeYf. e. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15030700
Pace Project No.: 92243096
Method: EPA 9056
Description: 9056 IC Anions
Client: Duke Energy
Date: May 11, 2015
General Information:
7 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
Analyte Comments:
QC Batch: WETA/45049
DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
•2015008683 (Lab ID:92243096001)
• Chloride
• Sulfate
•2015008685 (Lab ID:92243096002)
• Chloride
• Sulfate
•2015008686 (Lab ID:92243096006)
• Chloride
• Sulfate
•2015008689 (Lab ID:92243096003)
• Chloride
•2015008691 (Lab ID:92243096004)
• Chloride
• Sulfate
•2015008692 (Lab ID:92243096005)
• Chloride
•2015008693 (Lab ID:92243096007)
• Chloride
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 33 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800AWeYf. e. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15030700
Pace Project No.: 92243096
Method: EPA 9056
Description: 9056 IC Anions
Client: Duke Energy
Date: May 11, 2015
Analyte Comments:
QC Batch: WETA/45049
DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
•2015008693 (Lab ID:92243096007)
• Sulfate
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 34 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800AWeYf. e. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15030700
Pace Project No.: 92243096
Method: EPA 9056
Description: 9056 IC Anions 48hr
Client: Duke Energy
Date: May 11, 2015
General Information:
7 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
1-13: Sample was received or analysis requested beyond the recognized method holding time.
•2015008683 (Lab ID:92243096001)
•2015008685 (Lab ID:92243096002)
•2015008686 (Lab ID:92243096006)
•2015008689 (Lab ID:92243096003)
•2015008691 (Lab ID:92243096004)
•2015008692 (Lab ID:92243096005)
•2015008693 (Lab ID:92243096007)
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 35 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
98005k8rpyf�e. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15030700
Pace Project No.: 92243096
Method: EPA 9060
Description: Total Organic Carbon Quad
Client: Duke Energy
Date: May 11, 2015
General Information:
7 samples were analyzed for EPA 9060. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 36 of 97

aceAnaiXical
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Pace Analytical Services, Inc.
9800q�irpyf�e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15030700
Pace Project No.: 92243096
Sample: 2015008683 Lab ID: 92243096001 Collected: 03/23/15 15:00 Received: 03/27/15 15:45 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Aluminum
Barium
Beryllium
Boron
Calcium
Chromium
Copper
Iron
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Sodium
Strontium
Zinc
6020 MET ICPMS
Antimony
Arsenic
Cadmium
Cobalt
Lead
Selenium
Thallium
Vanadium
7471 Mercury
Mercury
Percent Moisture
Percent Moisture
9045 pH Soil
pH at 25 Degrees C
300.0 IC Anions, SPLP
Sulfate
353.2 Nitrogen, NO2/NO3, SPLP
Nitrogen, Nitrate
4500 Chloride, SPLP
Chloride
Date: 05/11/2015 07:56 AM
Analytical Method: EPA 6010 Preparation Method: EPA 3050
3650
mg/kg
28.3
14.2
5
04/04/15 13:50
04/09/15 06:03
7429-90-5
37.0
mg/kg
2.8
1.4
5
04/04/15 13:50
04/09/15 06:03
7440-39-3
0.25J
mg/kg
0.28
0.14
5
04/04/15 13:50
04/09/15 06:03
7440-41-7
ND
mg/kg
14.2
7.1
5
04/04/15 13:50
04/09/15 06:03
7440-42-8
999
mg/kg
142
70.8
5
04/04/15 13:50
04/09/15 06:03
7440-70-2
7.4
mg/kg
1.4
0.71
5
04/04/15 13:50
04/09/15 06:03
7440-47-3
4.6
mg/kg
1.4
0.71
5
04/04/15 13:50
04/09/15 06:03
7440-50-8
4280
mg/kg
11.3
5.7
5
04/04/15 13:50
04/09/15 06:03
7439-89-6
1090
mg/kg
142
70.8
5
04/04/15 13:50
04/09/15 06:03
7439-95-4
81.6
mg/kg
1.4
0.71
5
04/04/15 13:50
04/09/15 06:03
7439-96-5
2.9
mg/kg
2.8
1.4
5
04/04/15 13:50
04/09/15 06:03
7439-98-7
3.6
mg/kg
1.4
0.71
5
04/04/15 13:50
04/09/15 06:03
7440-02-0
215J
mg/kg
283
142
5
04/04/15 13:50
04/09/15 06:03
7440-09-7
ND
mg/kg
283
142
5
04/04/15 13:50
04/09/15 06:03
7440-23-5
20.1
mg/kg
2.8
1.4
5
04/04/15 13:50
04/09/15 06:03
7440-24-6
13.8
mg/kg
5.7
2.8
5
04/04/15 13:50
04/09/15 06:03
7440-66-6
Analytical
Method: EPA 6020 Preparation
Method: EPA 3050
ND
mg/kg
2.8
1.4
50
04/04/15 13:50
04/06/1511:52
7440-36-0
ND
mg/kg
2.8
1.4
50
04/04/15 13:50
04/06/1511:52
7440-38-2
ND
mg/kg
0.34
0.17
50
04/04/15 13:50
04/06/1511:52
7440-43-9
3.9
mg/kg
2.8
1.4
50
04/04/15 13:50
04/06/1511:52
7440-48-4
4.0
mg/kg
2.8
1.4
50
04/04/15 13:50
04/06/1511:52
7439-92-1
ND
mg/kg
2.8
1.4
50
04/04/15 13:50
04/06/1511:52
7782-49-2
ND
mg/kg
2.8
1.4
50
04/04/15 13:50
04/06/1511:52
7440-28-0
16.1
mg/kg
2.8
1.4
50
04/04/15 13:50
04/06/1511:52
7440-62-2
Analytical Method: EPA 7471 Preparation Method: EPA 7471
0.0073J mg/kg 0.0091 0.0045 1 04/04/15 14:55 04/04/15 21:01 7439-97-6
Analytical Method: ASTM D2974-87
11.7 % 0.10 0.10 1 04/04/15 20:05
Analytical Method: EPA 9045
6.9 Std. Units 0.10 0.10 1 04/01/15 13:55
D3
D3
D3
D3
D3
D3
D3
D3
D3
D3
D3
D3
D3
D3
D3
B,D3
N2
Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 04/02/15 18:00
5.5 mg/L 2.3 1.1 1 04/07/15 20:48 14808-79-8 B
Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 04/02/15 18:00
0.23 mg/L 0.23 0.23 1 04/09/1519:39 H1
Analytical Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 04/02/15 18:00
ND mg/L 5.7 2.8 1 04/08/15 02:38 16887-00-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 37 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
98005kf� pyfy e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15030700
Pace Project No.: 92243096
Sample: 2015008683 Lab ID: 92243096001 Collected: 03/23/15 15:00 Received: 03/27/15 15:45 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
9056 IC Anions Analytical Method: EPA 9056
Chloride
ND mg/kg
284
142
5
04/03/15 03:10
16887-00-6 D3
Sulfate
ND mg/kg
284
142
5
04/03/15 03:10
14808-79-8 D3
9056 IC Anions 48hr
Analytical Method: EPA 9056
Nitrate as N
ND mg/kg
28.4
14.2
5
04/03/15 03:10
14797-55-8 H3
Total Organic Carbon Quad
Analytical Method: EPA 9060
Total Organic Carbon
624J mg/kg
685
342
1
04/10/15 15:32
7440-44-0
Total Organic Carbon
593J mg/kg
677
338
1
04/10/15 15:39
7440-44-0
Total Organic Carbon
626J mg/kg
680
340
1
04/10/15 15:44
7440-44-0
Total Organic Carbon
670J mg/kg
681
341
1
04/10/15 15:51
7440-44-0
Mean Total Organic Carbon
628J mg/kg
680
340
1
04/10/15 15:32
7440-44-0
Surrogates
RSD%
5.1 %
1
04/10/15 15:32
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/11/2015 07:56 AM without the written consent of Pace Analytical Services, Inc..
Page 38 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
98005kf3 pyfy e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15030700
Pace Project No.: 92243096
Sample: 2015008685 Lab ID: 92243096002 Collected: 03/24/15 16:50 Received: 03/27/15 15:45 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Aluminum
Barium
Beryllium
Boron
Calcium
Chromium
Copper
Iron
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Sodium
Strontium
Zinc
6020 MET ICPMS
Antimony
Arsenic
Cadmium
Cobalt
Lead
Selenium
Thallium
Vanadium
7471 Mercury
Mercury
Percent Moisture
Percent Moisture
9045 pH Soil
pH at 25 Degrees C
300.0 IC Anions, SPLP
Sulfate
353.2 Nitrogen, NO2/NO3, SPLP
Nitrogen, Nitrate
4500 Chloride, SPLP
Chloride
Date: 05/11/2015 07:56 AM
Analytical Method: EPA 6010 Preparation Method: EPA 3050
2560
mg/kg
25.0
12.5
5
04/04/15 13:50
04/09/15 06:07
7429-90-5
65.3
mg/kg
2.5
1.3
5
04/04/15 13:50
04/09/15 06:07
7440-39-3
0.18J
mg/kg
0.25
0.13
5
04/04/15 13:50
04/09/15 06:07
7440-41-7
ND
mg/kg
12.5
6.3
5
04/04/15 13:50
04/09/15 06:07
7440-42-8
56100
mg/kg
125
62.6
5
04/04/15 13:50
04/09/15 06:07
7440-70-2
1.2J
mg/kg
1.3
0.63
5
04/04/15 13:50
04/09/15 06:07
7440-47-3
3.1
mg/kg
1.3
0.63
5
04/04/15 13:50
04/09/15 06:07
7440-50-8
3620
mg/kg
10.0
5.0
5
04/04/15 13:50
04/09/15 06:07
7439-89-6
1900
mg/kg
125
62.6
5
04/04/15 13:50
04/09/15 06:07
7439-95-4
2210
mg/kg
1.3
0.63
5
04/04/15 13:50
04/09/15 06:07
7439-96-5
ND
mg/kg
2.5
1.3
5
04/04/15 13:50
04/09/15 06:07
7439-98-7
1.3
mg/kg
1.3
0.63
5
04/04/15 13:50
04/09/15 06:07
7440-02-0
434
mg/kg
250
125
5
04/04/15 13:50
04/09/15 06:07
7440-09-7
134J
mg/kg
250
125
5
04/04/15 13:50
04/09/15 06:07
7440-23-5
90.1
mg/kg
2.5
1.3
5
04/04/15 13:50
04/09/15 06:07
7440-24-6
9.6
mg/kg
5.0
2.5
5
04/04/15 13:50
04/09/15 06:07
7440-66-6
Analytical
Method: EPA 6020 Preparation
Method: EPA 3050
ND
mg/kg
2.5
1.3
50
04/04/15 13:50
04/06/1511:55
7440-36-0
ND
mg/kg
2.5
1.3
50
04/04/15 13:50
04/06/1511:55
7440-38-2
0.40
mg/kg
0.30
0.15
50
04/04/15 13:50
04/06/1511:55
7440-43-9
1.3J
mg/kg
2.5
1.3
50
04/04/15 13:50
04/06/1511:55
7440-48-4
4.4
mg/kg
2.5
1.3
50
04/04/15 13:50
04/06/1511:55
7439-92-1
ND
mg/kg
2.5
1.3
50
04/04/15 13:50
04/06/1511:55
7782-49-2
ND
mg/kg
2.5
1.3
50
04/04/15 13:50
04/06/1511:55
7440-28-0
6.7
mg/kg
2.5
1.3
50
04/04/15 13:50
04/06/1511:55
7440-62-2
Analytical Method: EPA 7471 Preparation Method: EPA 7471
ND mg/kg 0.0083 0.0042 1 04/04/15 14:55 04/04/15 21:04 7439-97-6
Analytical Method: ASTM D2974-87
2.8 % 0.10 0.10 1 04/04/15 20:05
Analytical Method: EPA 9045
8.4 Std. Units 0.10 0.10 1 04/02/15 09:35
D3
D3
D3
D3
D4
D3
D3
D3
D3
D3
D3
D3
D3
D3
D3
B,D3
N2
Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 04/06/15 18:30
3.9 mg/L 2.1 1.0 1 04/09/1517:09 14808-79-8 B
Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 04/06/15 18:30
ND mg/L 0.21 0.21 1 04/09/1519:40 H1
Analytical Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 04/06/15 18:30
3.9J mg/L 5.1 2.6 1 04/09/15 04:55 16887-00-6 M1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 39 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800t4,6fy f�e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15030700
Pace Project No.: 92243096
Sample: 2015008685 Lab ID: 92243096002 Collected: 03/24/15 16:50 Received: 03/27/15 15:45 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
9056 IC Anions Analytical Method: EPA 9056
Chloride
ND mg/kg
258
129
5
04/03/15 03:31
16887-00-6 D3
Sulfate
ND mg/kg
258
129
5
04/03/15 03:31
14808-79-8 D3
9056 IC Anions 48hr
Analytical Method: EPA 9056
Nitrate as N
ND mg/kg
25.8
12.9
5
04/03/15 03:31
14797-55-8 H3
Total Organic Carbon Quad
Analytical Method: EPA 9060
Total Organic Carbon
ND mg/kg
613
307
1
04/10/15 19:44
7440-44-0
Total Organic Carbon
ND mg/kg
612
306
1
04/10/15 19:51
7440-44-0
Total Organic Carbon
ND mg/kg
620
310
1
04/10/15 19:56
7440-44-0
Total Organic Carbon
ND mg/kg
614
307
1
04/10/15 20:02
7440-44-0
Mean Total Organic Carbon
ND mg/kg
615
308
1
04/10/15 19:44
7440-44-0
Surrogates
RSD%
2.0 %
1
04/10/15 19:44
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/11/2015 07:56 AM without the written consent of Pace Analytical Services, Inc..
Page 40 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980%ppyf�e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15030700
Pace Project No.: 92243096
Sample: 2015008689 Lab ID: 92243096003 Collected: 03/25/15 17:00 Received: 03/27/15 15:45 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Aluminum
Barium
Beryllium
Boron
Calcium
Chromium
Copper
Iron
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Sodium
Strontium
Zinc
6020 MET ICPMS
Antimony
Arsenic
Cadmium
Cobalt
Lead
Selenium
Thallium
Vanadium
7471 Mercury
Mercury
Percent Moisture
Percent Moisture
9045 pH Soil
pH at 25 Degrees C
300.0 IC Anions, SPLP
Sulfate
353.2 Nitrogen, NO2/NO3, SPLP
Nitrogen, Nitrate
4500 Chloride, SPLP
Chloride
Date: 05/11/2015 07:56 AM
Analytical Method: EPA 6010 Preparation Method: EPA 3050
12700
mg/kg
37.9
18.9
5
04/04/15 13:50
04/09/15 06:12
7429-90-5
217
mg/kg
3.8
1.9
5
04/04/15 13:50
04/09/15 06:12
7440-39-3
2.9
mg/kg
0.38
0.19
5
04/04/15 13:50
04/09/15 06:12
7440-41-7
27.8
mg/kg
18.9
9.5
5
04/04/15 13:50
04/09/15 06:12
7440-42-8
1700
mg/kg
189
94.7
5
04/04/15 13:50
04/09/15 06:12
7440-70-2
15.4
mg/kg
1.9
0.95
5
04/04/15 13:50
04/09/15 06:12
7440-47-3
48.8
mg/kg
1.9
0.95
5
04/04/15 13:50
04/09/15 06:12
7440-50-8
7270
mg/kg
15.2
7.6
5
04/04/15 13:50
04/09/15 06:12
7439-89-6
947
mg/kg
189
94.7
5
04/04/15 13:50
04/09/15 06:12
7439-95-4
49.6
mg/kg
1.9
0.95
5
04/04/15 13:50
04/09/15 06:12
7439-96-5
5.4
mg/kg
3.8
1.9
5
04/04/15 13:50
04/09/15 06:12
7439-98-7
21.4
mg/kg
1.9
0.95
5
04/04/15 13:50
04/09/15 06:12
7440-02-0
2350
mg/kg
379
189
5
04/04/15 13:50
04/09/15 06:12
7440-09-7
304J
mg/kg
379
189
5
04/04/15 13:50
04/09/15 06:12
7440-23-5
139
mg/kg
3.8
1.9
5
04/04/15 13:50
04/09/15 06:12
7440-24-6
43.5
mg/kg
7.6
3.8
5
04/04/15 13:50
04/09/15 06:12
7440-66-6
Analytical
Method: EPA 6020 Preparation
Method: EPA 3050
ND
mg/kg
3.8
1.9
50
04/04/15 13:50
04/06/1511:57
7440-36-0
115
mg/kg
3.8
1.9
50
04/04/15 13:50
04/06/1511:57
7440-38-2
0.37J
mg/kg
0.45
0.23
50
04/04/15 13:50
04/06/1511:57
7440-43-9
9.4
mg/kg
3.8
1.9
50
04/04/15 13:50
04/06/1511:57
7440-48-4
18.3
mg/kg
3.8
1.9
50
04/04/15 13:50
04/06/1511:57
7439-92-1
14.9
mg/kg
3.8
1.9
50
04/04/15 13:50
04/06/1511:57
7782-49-2
ND
mg/kg
3.8
1.9
50
04/04/15 13:50
04/06/1511:57
7440-28-0
51.2
mg/kg
3.8
1.9
50
04/04/15 13:50
04/06/1511:57
7440-62-2
Analytical Method: EPA 7471 Preparation Method: EPA 7471
0.14 mg/kg 0.012 0.0058 1 04/04/15 14:55 04/04/15 21:06 7439-97-6
Analytical Method: ASTM D2974-87
31.3 % 0.10 0.10 1 04/04/15 20:05
Analytical Method: EPA 9045
5.7 Std. Units 0.10 0.10 1 04/03/15 10:15
D3
D3
D3
D3
D3
D3
D3
D3
D3
D3
D3
D3
D3
D3
D3
D3
N2
Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 04/06/15 18:30
18.9 mg/L 2.9 1.5 1 04/09/1517:50 14808-79-8 B
Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 04/06/15 18:30
ND mg/L 0.29 0.29 1 04/09/1519:41 H1
Analytical Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 04/06/15 18:30
ND mg/L 7.3 3.6 1 04/09/15 04:59 16887-00-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 41 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980%�rpyf�e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15030700
Pace Project No.: 92243096
Sample: 2015008689 Lab ID: 92243096003 Collected: 03/25/15 17:00 Received: 03/27/15 15:45 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
9056 IC Anions Analytical Method: EPA 9056
Chloride
ND mg/kg
362
181
5
04/03/15 03:52
16887-00-6 D3
Sulfate
244J mg/kg
362
181
5
04/03/15 03:52
14808-79-8
9056 IC Anions 48hr
Analytical Method: EPA 9056
Nitrate as N
ND mg/kg
36.2
18.1
5
04/03/15 03:52
14797-55-8 H3
Total Organic Carbon Quad
Analytical Method: EPA 9060
Total Organic Carbon
56000 mg/kg
7970
3980
1
04/10/15 16:19
7440-44-0
Total Organic Carbon
43900 mg/kg
7890
3950
1
04/10/15 16:25
7440-44-0
Total Organic Carbon
46100 mg/kg
7920
3960
1
04/10/15 16:31
7440-44-0
Total Organic Carbon
49300 mg/kg
7560
3780
1
04/10/15 16:37
7440-44-0
Mean Total Organic Carbon
48800 mg/kg
7830
3920
1
04/10/15 16:19
7440-44-0
Surrogates
RSD%
10.8 %
1
04/10/15 16:19
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/11/2015 07:56 AM without the written consent of Pace Analytical Services, Inc..
Page 42 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800*rpyf�e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15030700
Pace Project No.: 92243096
Sample: 2015008691 Lab ID: 92243096004 Collected: 03/26/15 11:30 Received: 03/27/15 15:45 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Aluminum
Barium
Beryllium
Boron
Calcium
Chromium
Copper
Iron
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Sodium
Strontium
Zinc
6020 MET ICPMS
Antimony
Arsenic
Cadmium
Cobalt
Lead
Selenium
Thallium
Vanadium
7471 Mercury
Mercury
Percent Moisture
Percent Moisture
9045 pH Soil
pH at 25 Degrees C
300.0 IC Anions, SPLP
Sulfate
353.2 Nitrogen, NO2/NO3, SPLP
Nitrogen, Nitrate
4500 Chloride, SPLP
Chloride
Date: 05/11/2015 07:56 AM
Analytical Method: EPA 6010 Preparation Method: EPA 3050
5450
mg/kg
33.5
16.8
5
04/04/15 13:50
04/09/15 06:16
7429-90-5
38.5
mg/kg
3.4
1.7
5
04/04/15 13:50
04/09/15 06:16
7440-39-3
0.44
mg/kg
0.34
0.17
5
04/04/15 13:50
04/09/15 06:16
7440-41-7
46.5
mg/kg
16.8
8.4
5
04/04/15 13:50
04/09/15 06:16
7440-42-8
ND
mg/kg
168
83.9
5
04/04/15 13:50
04/09/15 06:16
7440-70-2
7.2
mg/kg
1.7
0.84
5
04/04/15 13:50
04/09/15 06:16
7440-47-3
26.1
mg/kg
1.7
0.84
5
04/04/15 13:50
04/09/15 06:16
7440-50-8
50400
mg/kg
13.4
6.7
5
04/04/15 13:50
04/09/15 06:16
7439-89-6
234
mg/kg
168
83.9
5
04/04/15 13:50
04/09/15 06:16
7439-95-4
348
mg/kg
1.7
0.84
5
04/04/15 13:50
04/09/15 06:16
7439-96-5
ND
mg/kg
3.4
1.7
5
04/04/15 13:50
04/09/15 06:16
7439-98-7
2.8
mg/kg
1.7
0.84
5
04/04/15 13:50
04/09/15 06:16
7440-02-0
ND
mg/kg
335
168
5
04/04/15 13:50
04/09/15 06:16
7440-09-7
ND
mg/kg
335
168
5
04/04/15 13:50
04/09/15 06:16
7440-23-5
ND
mg/kg
3.4
1.7
5
04/04/15 13:50
04/09/15 06:16
7440-24-6
18.1
mg/kg
6.7
3.4
5
04/04/15 13:50
04/09/15 06:16
7440-66-6
Analytical
Method: EPA 6020 Preparation
Method: EPA 3050
ND
mg/kg
3.4
1.7
50
04/04/15 13:50
04/06/1511:59
7440-36-0
3.6
mg/kg
3.4
1.7
50
04/04/15 13:50
04/06/1511:59
7440-38-2
ND
mg/kg
0.40
0.20
50
04/04/15 13:50
04/06/1511:59
7440-43-9
3.9
mg/kg
3.4
1.7
50
04/04/15 13:50
04/06/1511:59
7440-48-4
9.8
mg/kg
3.4
1.7
50
04/04/15 13:50
04/06/1511:59
7439-92-1
ND
mg/kg
3.4
1.7
50
04/04/15 13:50
04/06/1511:59
7782-49-2
ND
mg/kg
3.4
1.7
50
04/04/15 13:50
04/06/1511:59
7440-28-0
14.9
mg/kg
3.4
1.7
50
04/04/15 13:50
04/06/1511:59
7440-62-2
Analytical Method: EPA 7471 Preparation Method: EPA 7471
0.037 mg/kg 0.010 0.0052 1 04/04/15 14:55 04/04/15 21:12 7439-97-6
Analytical Method: ASTM D2974-87
22.9 % 0.10 0.10 1 04/04/15 20:05
Analytical Method: EPA 9045
4.8 Std. Units 0.10 0.10 1 04/08/15 22:00
D3
D3
D3
D3
D3
D3
D3
D4
D3
D3
D3
D3
D3
D3
D3
D3
N2
Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 04/06/15 18:30
7.8 mg/L 2.6 1.3 1 04/09/1518:03 14808-79-8 B
Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 04/06/15 18:30
ND mg/L 0.26 0.26 1 04/09/1519:45 H1
Analytical Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 04/06/15 18:30
ND mg/L 6.5 3.2 1 04/09/15 04:59 16887-00-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 43 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980%5 rpyf�e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15030700
Pace Project No.: 92243096
Sample: 2015008691 Lab ID: 92243096004 Collected: 03/26/15 11:30 Received: 03/27/15 15:45 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
9056 IC Anions Analytical Method: EPA 9056
Chloride
ND mg/kg
323
161
5
04/03/15 04:14
16887-00-6 D3
Sulfate
ND mg/kg
323
161
5
04/03/15 04:14
14808-79-8 D3
9056 IC Anions 48hr
Analytical Method: EPA 9056
Nitrate as N
ND mg/kg
32.3
16.1
5
04/03/15 04:14
14797-55-8 H3
Total Organic Carbon Quad
Analytical Method: EPA 9060
Total Organic Carbon
552J mg/kg
777
389
1
04/10/15 16:43
7440-44-0
Total Organic Carbon
526J mg/kg
779
390
1
04/10/15 16:48
7440-44-0
Total Organic Carbon
529J mg/kg
771
386
1
04/10/15 16:54
7440-44-0
Total Organic Carbon
563J mg/kg
784
392
1
04/10/15 16:59
7440-44-0
Mean Total Organic Carbon
542J mg/kg
778
389
1
04/10/15 16:43
7440-44-0
Surrogates
RSD%
3.3 %
1
04/10/15 16:43
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/11/2015 07:56 AM without the written consent of Pace Analytical Services, Inc..
Page 44 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980%�rpyf�e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15030700
Pace Project No.: 92243096
Sample: 2015008692 Lab ID: 92243096005 Collected: 03/26/15 08:45 Received: 03/27/15 15:45 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Aluminum
Barium
Beryllium
Boron
Calcium
Chromium
Copper
Iron
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Sodium
Strontium
Zinc
6020 MET ICPMS
Antimony
Arsenic
Cadmium
Cobalt
Lead
Selenium
Thallium
Vanadium
7471 Mercury
Mercury
Percent Moisture
Percent Moisture
9045 pH Soil
pH at 25 Degrees C
300.0 IC Anions, SPLP
Sulfate
353.2 Nitrogen, NO2/NO3, SPLP
Nitrogen, Nitrate
4500 Chloride, SPLP
Chloride
Date: 05/11/2015 07:56 AM
Analytical Method: EPA 6010 Preparation Method: EPA 3050
11000
mg/kg
30.8
15.4
5
04/04/15 13:50
04/09/15 06:20
7429-90-5
8.8
mg/kg
3.1
1.5
5
04/04/15 13:50
04/09/15 06:20
7440-39-3
ND
mg/kg
0.31
0.15
5
04/04/15 13:50
04/09/15 06:20
7440-41-7
34.4
mg/kg
15.4
7.7
5
04/04/15 13:50
04/09/15 06:20
7440-42-8
ND
mg/kg
154
77.1
5
04/04/15 13:50
04/09/15 06:20
7440-70-2
22.5
mg/kg
1.5
0.77
5
04/04/15 13:50
04/09/15 06:20
7440-47-3
9.2
mg/kg
1.5
0.77
5
04/04/15 13:50
04/09/15 06:20
7440-50-8
35600
mg/kg
12.3
6.2
5
04/04/15 13:50
04/09/15 06:20
7439-89-6
94.OJ
mg/kg
154
77.1
5
04/04/15 13:50
04/09/15 06:20
7439-95-4
13.9
mg/kg
1.5
0.77
5
04/04/15 13:50
04/09/15 06:20
7439-96-5
ND
mg/kg
3.1
1.5
5
04/04/15 13:50
04/09/15 06:20
7439-98-7
ND
mg/kg
1.5
0.77
5
04/04/15 13:50
04/09/15 06:20
7440-02-0
ND
mg/kg
308
154
5
04/04/15 13:50
04/09/15 06:20
7440-09-7
ND
mg/kg
308
154
5
04/04/15 13:50
04/09/15 06:20
7440-23-5
ND
mg/kg
3.1
1.5
5
04/04/15 13:50
04/09/15 06:20
7440-24-6
ND
mg/kg
6.2
3.1
5
04/04/15 13:50
04/09/15 06:20
7440-66-6
Analytical
Method: EPA 6020 Preparation
Method: EPA 3050
ND
mg/kg
3.1
1.5
50
04/04/15 13:50
04/06/1512:01
7440-36-0
ND
mg/kg
3.1
1.5
50
04/04/15 13:50
04/06/1512:01
7440-38-2
ND
mg/kg
0.37
0.18
50
04/04/15 13:50
04/06/1512:01
7440-43-9
ND
mg/kg
3.1
1.5
50
04/04/15 13:50
04/06/1512:01
7440-48-4
8.9
mg/kg
3.1
1.5
50
04/04/15 13:50
04/06/1512:01
7439-92-1
ND
mg/kg
3.1
1.5
50
04/04/15 13:50
04/06/1512:01
7782-49-2
ND
mg/kg
3.1
1.5
50
04/04/15 13:50
04/06/1512:01
7440-28-0
74.5
mg/kg
3.1
1.5
50
04/04/15 13:50
04/06/1512:01
7440-62-2
Analytical Method: EPA 7471 Preparation Method: EPA 7471
0.030 mg/kg 0.0098 0.0049 1 04/04/15 14:55 04/04/15 21:14 7439-97-6
Analytical Method: ASTM D2974-87
21.7 % 0.10 0.10 1 04/04/15 20:05
Analytical Method: EPA 9045
4.0 Std. Units 0.10 0.10 1 04/08/15 22:00
D3
D3
D3
D3
D3
D3
D3
D4
D3
D3
D3
D3
D3
D3
D3
D3
N2
Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 04/06/15 18:30
19.0 mg/L 2.6 1.3 1 04/09/1518:17 14808-79-8 B
Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 04/06/15 18:30
ND mg/L 0.26 0.26 1 04/09/1519:50 H1
Analytical Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 04/06/15 18:30
ND mg/L 6.4 3.2 1 04/09/15 05:00 16887-00-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 45 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980%48rpyf�e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15030700
Pace Project No.: 92243096
Sample: 2015008692 Lab ID: 92243096005 Collected: 03/26/15 08:45 Received: 03/27/15 15:45 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
9056 IC Anions Analytical Method: EPA 9056
Chloride
ND mg/kg
323
162
5
04/03/15 04:35
16887-00-6 D3
Sulfate
181J mg/kg
323
162
5
04/03/15 04:35
14808-79-8
9056 IC Anions 48hr
Analytical Method: EPA 9056
Nitrate as N
ND mg/kg
32.3
16.2
5
04/03/15 04:35
14797-55-8 H3
Total Organic Carbon Quad
Analytical Method: EPA 9060
Total Organic Carbon
899 mg/kg
765
383
1
04/10/15 17:18
7440-44-0
Total Organic Carbon
855 mg/kg
772
386
1
04/10/15 17:23
7440-44-0
Total Organic Carbon
906 mg/kg
759
380
1
04/10/15 17:30
7440-44-0
Total Organic Carbon
939 mg/kg
766
383
1
04/10/15 17:36
7440-44-0
Mean Total Organic Carbon
900 mg/kg
766
383
1
04/10/15 17:18
7440-44-0
Surrogates
RSD%
3.8 %
1
04/10/15 17:18
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/11/2015 07:56 AM without the written consent of Pace Analytical Services, Inc..
Page 46 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980%-)irpyf�e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15030700
Pace Project No.: 92243096
Sample: 2015008686
Lab ID:
92243096006 Collected:
03/24/15 17:15
Received: 03/27/15 15:45 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample
size and any dilutions.
Report
Parameters
Results
Units Limit
MDL
DF
Prepared
Analyzed
CAS No.
Qual
6010 MET ICP
Analytical
Method: EPA 6010
Preparation
Method: EPA
3050
Aluminum
6810
mg/kg
5.1
2.5
1
04/03/15 12:24
04/05/15 02:45
7429-90-5
M1
Barium
81.6
mg/kg
0.51
0.25
1
04/03/15 12:24
04/05/15 02:45
7440-39-3
M1
Beryllium
0.42
mg/kg
0.25
0.13
5
04/03/15 12:24
04/09/15 04:20
7440-41-7
D3
Boron
14.7
mg/kg
12.7
6.3
5
04/03/15 12:24
04/09/15 04:20
7440-42-8
D3
Calcium
2750
mg/kg
25.4
12.7
1
04/03/15 12:24
04/05/15 02:45
7440-70-2
M1
Chromium
8.9
mg/kg
1.3
0.63
5
04/03/15 12:24
04/09/15 04:20
7440-47-3
D3
Copper
9.0
mg/kg
1.3
0.63
5
04/03/15 12:24
04/09/15 04:20
7440-50-8
D3
Iron
10200
mg/kg
2.0
1.0
1
04/03/15 12:24
04/05/15 02:45
7439-89-6
M1
Magnesium
4940
mg/kg
25.4
12.7
1
04/03/15 12:24
04/05/15 02:45
7439-95-4
M1
Manganese
386
mg/kg
1.3
0.63
5
04/03/15 12:24
04/09/15 04:20
7439-96-5
D3,M1
Molybdenum
ND
mg/kg
0.51
0.25
1
04/03/15 12:24
04/05/15 02:45
7439-98-7
M1
Nickel
6.3
mg/kg
0.25
0.13
1
04/03/15 12:24
04/05/15 02:45
7440-02-0
Potassium
1180
mg/kg
50.8
25.4
1
04/03/15 12:24
04/05/15 02:45
7440-09-7
Sodium
95.7
mg/kg
50.8
25.4
1
04/03/15 12:24
04/05/15 02:45
7440-23-5
Strontium
21.9
mg/kg
0.51
0.25
1
04/03/15 12:24
04/05/15 02:45
7440-24-6
Zinc
50.7
mg/kg
1.0
0.51
1
04/03/15 12:24
04/05/15 02:45
7440-66-6
6020 MET ICPMS
Analytical
Method: EPA 6020
Preparation
Method: EPA
3050
Antimony
ND
mg/kg
2.5
1.3
50
04/03/15 12:24
04/06/1512:08
7440-36-0
N2
Arsenic
2.9
mg/kg
2.5
1.3
50
04/03/15 12:24
04/06/1512:08
7440-38-2
Cadmium
ND
mg/kg
0.30
0.15
50
04/03/15 12:24
04/06/1512:08
7440-43-9
Cobalt
8.1
mg/kg
2.5
1.3
50
04/03/15 12:24
04/06/1512:08
7440-48-4
Lead
5.2
mg/kg
2.5
1.3
50
04/03/15 12:24
04/06/1512:08
7439-92-1
Selenium
2AJ
mg/kg
2.5
1.3
50
04/03/15 12:24
04/06/1512:08
7782-49-2
Thallium
ND
mg/kg
2.5
1.3
50
04/03/15 12:24
04/06/1512:08
7440-28-0
Vanadium
12.3
mg/kg
2.5
1.3
50
04/03/15 12:24
04/06/1512:08
7440-62-2
7471 Mercury
Analytical
Method: EPA 7471
Preparation
Method: EPA
7471
Mercury
ND
mg/kg 0.0085
0.0043
1
04/04/15 19:50
04/07/15 09:20
7439-97-6
Percent Moisture
Analytical
Method: ASTM D2974-87
Percent Moisture
4.9
%
0.10
0.10
1
04/04/15 20:06
9045 pH Soil
Analytical
Method: EPA 9045
pH at 25 Degrees C
8.6
Std. Units
0.10
0.10
1
04/02/15 09:35
9056 IC Anions
Analytical
Method: EPA 9056
Chloride
ND
mg/kg
260
130
5
04/03/15 05:39
16887-00-6
D3
Sulfate
ND
mg/kg
260
130
5
04/03/15 05:39
14808-79-8
D3
9056 IC Anions 48hr
Analytical
Method: EPA 9056
Nitrate as N
ND
mg/kg
26.0
13.0
5
04/03/15 05:39
14797-55-8
H3
Date: 05/11/2015 07:56 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 47 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
98006Jf� pyfy e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15030700
Pace Project No.: 92243096
Sample: 2015008686
Lab ID:
92243096006
Collected:
03/24/15 17:15
Received: 03/27/15 15:45 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample
size and any dilutions.
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared Analyzed
CAS No. Qual
Total Organic Carbon Quad
Analytical
Method: EPA 9060
Total Organic Carbon
ND
mg/kg
636
318
1
04/13/15 09:58
7440-44-0
Total Organic Carbon
ND
mg/kg
636
318
1
04/13/15 10:03
7440-44-0
Total Organic Carbon
ND
mg/kg
636
318
1
04/13/15 10:08
7440-44-0
Total Organic Carbon
ND
mg/kg
628
314
1
04/13/15 10:15
7440-44-0
Mean Total Organic Carbon
ND
mg/kg
634
317
1
04/13/15 09:58
7440-44-0
Surrogates
RSD%
5.0
%
1
04/13/15 09:58
Date: 05/11/2015 07:56 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 48 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980%4srpyf�e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15030700
Pace Project No.: 92243096
Sample: 2015008693
Lab ID:
92243096007 Collected:
03/26/15 13:30
Received: 03/27/15 15:45 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample
size and any dilutions.
Report
Parameters
Results
Units Limit
MDL
DF
Prepared
Analyzed
CAS No.
Qual
6010 MET ICP
Analytical
Method: EPA 6010
Preparation
Method: EPA
3050
Aluminum
3830
mg/kg
5.5
2.7
1
04/03/15 12:24
04/05/15 02:58
7429-90-5
Barium
19.0
mg/kg
0.55
0.27
1
04/03/15 12:24
04/05/15 02:58
7440-39-3
Beryllium
0.79
mg/kg
0.27
0.14
5
04/03/15 12:24
04/09/15 04:33
7440-41-7
D3
Boron
53.2
mg/kg
13.7
6.9
5
04/03/15 12:24
04/09/15 04:33
7440-42-8
D3
Calcium
544
mg/kg
27.4
13.7
1
04/03/15 12:24
04/05/15 02:58
7440-70-2
Chromium
27.3
mg/kg
1.4
0.69
5
04/03/15 12:24
04/09/15 04:33
7440-47-3
D3
Copper
75.1
mg/kg
1.4
0.69
5
04/03/15 12:24
04/09/15 04:33
7440-50-8
D3
Iron
60400
mg/kg
11.0
5.5
5
04/03/15 12:24
04/09/15 04:33
7439-89-6
D4
Magnesium
762
mg/kg
27.4
13.7
1
04/03/15 12:24
04/05/15 02:58
7439-95-4
Manganese
72.6
mg/kg
1.4
0.69
5
04/03/15 12:24
04/09/15 04:33
7439-96-5
Molybdenum
0.62
mg/kg
0.55
0.27
1
04/03/15 12:24
04/05/15 02:58
7439-98-7
Nickel
20.3
mg/kg
0.27
0.14
1
04/03/15 12:24
04/05/15 02:58
7440-02-0
Potassium
262
mg/kg
54.8
27.4
1
04/03/15 12:24
04/05/15 02:58
7440-09-7
Sodium
ND
mg/kg
54.8
27.4
1
04/03/15 12:24
04/05/15 02:58
7440-23-5
Strontium
5.5
mg/kg
0.55
0.27
1
04/03/15 12:24
04/05/15 02:58
7440-24-6
Zinc
56.8
mg/kg
1.1
0.55
1
04/03/15 12:24
04/05/15 02:58
7440-66-6
6020 MET ICPMS
Analytical
Method: EPA 6020
Preparation
Method: EPA
3050
Antimony
ND
mg/kg
2.7
1.4
50
04/03/15 12:24
04/06/1512:24
7440-36-0
M6,N2
Arsenic
7.7
mg/kg
2.7
1.4
50
04/03/15 12:24
04/06/1512:24
7440-38-2
M6
Cadmium
ND
mg/kg
0.33
0.16
50
04/03/15 12:24
04/06/1512:24
7440-43-9
Cobalt
8.4
mg/kg
2.7
1.4
50
04/03/15 12:24
04/06/1512:24
7440-48-4
M6
Lead
15.6
mg/kg
2.7
1.4
50
04/03/15 12:24
04/06/1512:24
7439-92-1
M6,R1
Selenium
ND
mg/kg
2.7
1.4
50
04/03/15 12:24
04/06/1512:24
7782-49-2
M6,R1
Thallium
ND
mg/kg
2.7
1.4
50
04/03/15 12:24
04/06/1512:24
7440-28-0
M6
Vanadium
18.5
mg/kg
2.7
1.4
50
04/03/15 12:24
04/06/1512:24
7440-62-2
M6,R1
7471 Mercury
Analytical
Method: EPA 7471
Preparation
Method: EPA
7471
Mercury
0.058
mg/kg 0.0094
0.0047
1
04/04/15 19:50
04/07/15 09:22
7439-97-6
Percent Moisture
Analytical
Method: ASTM D2974-87
Percent Moisture
11.5
%
0.10
0.10
1
04/04/15 20:06
9045 pH Soil
Analytical
Method: EPA 9045
pH at 25 Degrees C
4.6
Std. Units
0.10
0.10
1
04/08/15 22:00
9056 IC Anions
Analytical
Method: EPA 9056
Chloride
ND
mg/kg
280
140
5
04/03/15 06:01
16887-00-6
D3
Sulfate
ND
mg/kg
280
140
5
04/03/15 06:01
14808-79-8
D3
9056 IC Anions 48hr
Analytical
Method: EPA 9056
Nitrate as N
ND
mg/kg
28.0
14.0
5
04/03/15 06:01
14797-55-8
H3
Date: 05/11/2015 07:56 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 49 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
98006}�irpyf�e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15030700
Pace Project No.: 92243096
Sample: 2015008693
Lab ID:
92243096007
Collected:
03/26/15 13:30
Received: 03/27/15 15:45 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample
size and any dilutions.
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared Analyzed
CAS No. Qual
Total Organic Carbon Quad
Analytical
Method: EPA 9060
Total Organic Carbon
118000
mg/kg
7910
3950
1
04/10/15 18:08
7440-44-0
Total Organic Carbon
91000
mg/kg
8080
4040
1
04/10/15 18:14
7440-44-0
Total Organic Carbon
89500
mg/kg
7600
3800
1
04/10/15 18:21
7440-44-0
Total Organic Carbon
102000
mg/kg
7410
3700
1
04/10/15 18:27
7440-44-0
Mean Total Organic Carbon
100000
mg/kg
7750
3870
1
04/10/15 18:08
7440-44-0
Surrogates
RSD%
13.3
%
1
04/10/15 18:08
Date: 05/11/2015 07:56 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 50 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980%48rpyf�e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15030700
Pace Project No.: 92243096
Sample: 2015008683 SPLP Lab ID: 92243096008 Collected: 03/23/15 15:00 Received: 03/27/15 15:45 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
;T➢Z17c\r�il=11 a � 6?
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Sodium
Strontium
Thallium
Vanadium
Zinc
7470A Mercury
Mercury
Date: 05/11/2015 07:56 AM
Analytical Method: EPA 6020A Preparation Method: EPA 3020
91800
ug/L
50.0
14.9
5
04/27/15 14:23
04/28/15 05:15
7429-90-5
ND
ug/L
0.50
0.15
1
04/27/15 14:23
04/28/15 05:10
7440-36-0
23.6
ug/L
0.50
0.11
1
04/27/15 14:23
04/28/15 05:10
7440-38-2
606
ug/L
1.5
0.40
5
04/27/15 14:23
04/28/15 05:15
7440-39-3
4.1
ug/L
0.20
0.067
1
04/27/15 14:23
04/28/15 05:10
7440-41-7
97.3
ug/L
5.0
1.1
1
04/27/15 14:23
04/28/15 05:10
7440-42-8
0.11
ug/L
0.080
0.024
1
04/27/15 14:23
04/28/15 05:10
7440-43-9
11800
ug/L
40.0
16.0
1
04/27/15 14:23
04/28/15 05:10
7440-70-2
110
ug/L
0.50
0.17
1
04/27/15 14:23
04/28/15 05:10
7440-47-3
34.4
ug/L
0.50
0.13
1
04/27/15 14:23
04/28/15 05:10
7440-48-4
62.5
ug/L
1.0
0.21
1
04/27/15 14:23
04/28/15 05:10
7440-50-8
56500
ug/L
250
68.5
5
04/27/15 14:23
04/28/15 05:15
7439-89-6
36.5
ug/L
0.10
0.046
1
04/27/15 14:23
04/28/15 05:10
7439-92-1
5970
ug/L
10.0
3.2
1
04/27/15 14:23
04/28/15 05:10
7439-95-4
694
ug/L
2.5
1.2
5
04/27/15 14:23
04/28/15 05:15
7439-96-5
64.9
ug/L
0.50
0.094
1
04/27/15 14:23
04/28/15 05:10
7439-98-7
39.6
ug/L
0.50
0.16
1
04/27/15 14:23
04/28/15 05:10
7440-02-0
2060
ug/L
50.0
11.7
1
04/27/15 14:23
04/28/15 05:10
7440-09-7
6.1
ug/L
0.50
0.20
1
04/27/15 14:23
04/28/15 05:10
7782-49-2
1630
ug/L
50.0
16.3
1
04/27/15 14:23
04/28/15 05:10
7440-23-5
276
ug/L
0.50
0.13
1
04/27/15 14:23
04/28/15 05:10
7440-24-6
0.37
ug/L
0.10
0.015
1
04/27/15 14:23
04/28/15 05:10
7440-28-0
313
ug/L
5.0
1.4
5
04/27/15 14:23
04/29/1511:19
7440-62-2
196
ug/L
5.0
2.4
1
04/27/15 14:23
04/28/15 05:10
7440-66-6
Analytical Method: EPA 7470A Preparation Method: EPA 7470A
0.23 ug/L 0.20 0.022 1 04/23/15 11:03 04/23/15 21:18 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 51 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980%48rpyf�e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15030700
Pace Project No.: 92243096
Sample: 2015008685 SPLP Lab ID: 92243096009 Collected: 03/24/15 16:50 Received: 03/27/15 15:45 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
;T➢Z17c\riil=11 a
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Sodium
Strontium
Thallium
Vanadium
Zinc
7470A Mercury
Mercury
Date: 05/11/2015 07:56 AM
Analytical Method: EPA 6020A Preparation Method: EPA 3020
6300
ug/L
10.0
3.0
1
04/29/1514:46
04/30/1511:15
7429-90-5
0.16J
ug/L
0.50
0.15
1
04/29/1514:46
04/30/1511:15
7440-36-0
5.0
ug/L
0.50
0.11
1
04/29/1514:46
04/30/1511:15
7440-38-2
265
ug/L
0.30
0.081
1
04/29/1514:46
04/30/1511:15
7440-39-3
0.24
ug/L
0.20
0.067
1
04/29/1514:46
04/30/1511:15
7440-41-7
47.6
ug/L
5.0
1.1
1
04/29/1514:46
04/30/1511:15
7440-42-8
0.035J
ug/L
0.080
0.024
1
04/29/1514:46
04/30/1511:15
7440-43-9
8710
ug/L
40.0
16.0
1
04/29/1514:46
04/30/1511:15
7440-70-2
4.1
ug/L
0.50
0.17
1
04/29/1514:46
04/30/1511:15
7440-47-3
1.8
ug/L
0.50
0.13
1
04/29/1514:46
04/30/1511:15
7440-48-4
3.3
ug/L
1.0
0.21
1
04/29/1514:46
04/30/1511:15
7440-50-8
6490
ug/L
50.0
13.7
1
04/29/1514:46
04/30/1511:15
7439-89-6
3.5
ug/L
0.10
0.046
1
04/29/1514:46
04/30/1511:15
7439-92-1
2360
ug/L
10.0
3.2
1
04/29/1514:46
04/30/1511:15
7439-95-4
182
ug/L
0.50
0.24
1
04/29/1514:46
04/30/1511:15
7439-96-5
4.6
ug/L
0.50
0.094
1
04/29/1514:46
04/30/1511:15
7439-98-7
2.0
ug/L
0.50
0.16
1
04/29/1514:46
04/30/1511:15
7440-02-0
2640
ug/L
50.0
11.7
1
04/29/1514:46
04/30/1511:15
7440-09-7
0.42J
ug/L
0.50
0.20
1
04/29/1514:46
04/30/1511:15
7782-49-2
3050
ug/L
50.0
16.3
1
04/29/1514:46
04/30/1511:15
7440-23-5
49.9
ug/L
0.50
0.13
1
04/29/1514:46
04/30/1511:15
7440-24-6
0.044J
ug/L
0.10
0.015
1
04/29/1514:46
04/30/1511:15
7440-28-0
25.2
ug/L
1.0
0.28
1
04/29/1514:46
04/30/1511:15
7440-62-2
38.7
ug/L
5.0
2.4
1
04/29/1514:46
04/30/1511:15
7440-66-6
Analytical Method: EPA 7470A Preparation Method: EPA 7470A
0.030J ug/L 0.20 0.022 1 04/23/15 11:03 04/23/15 21:20 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 52 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
98004?rpyf�e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15030700
Pace Project No.: 92243096
Sample: 2015008689 SPLP Lab ID: 92243096010 Collected: 03/25/15 17:00 Received: 03/27/15 15:45 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
;T➢Z17c\r�il=11 a � 6?
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Sodium
Strontium
Thallium
Vanadium
Zinc
7470A Mercury
Mercury
Date: 05/11/2015 07:56 AM
Analytical Method: EPA 6020A Preparation Method: EPA 3020
16.2
ug/L
10.0
3.0
1
04/29/1514:46
04/30/1510:42
7429-90-5
4.3
ug/L
0.50
0.15
1
04/29/1514:46
04/30/1510:42
7440-36-0
3.9
ug/L
0.50
0.11
1
04/29/1514:46
04/30/1510:42
7440-38-2
292
ug/L
0.30
0.081
1
04/29/1514:46
04/30/1510:42
7440-39-3
ND
ug/L
0.20
0.067
1
04/29/1514:46
04/30/1510:42
7440-41-7
81.5
ug/L
5.0
1.1
1
04/29/1514:46
04/30/1510:42
7440-42-8
0.18
ug/L
0.080
0.024
1
04/29/1514:46
04/30/1510:42
7440-43-9
3450
ug/L
40.0
16.0
1
04/29/1514:46
04/30/1510:42
7440-70-2
0.46J
ug/L
0.50
0.17
1
04/29/1514:46
04/30/1510:42
7440-47-3
4.7
ug/L
0.50
0.13
1
04/29/1514:46
04/30/1510:42
7440-48-4
0.801
ug/L
1.0
0.21
1
04/29/1514:46
04/30/1510:42
7440-50-8
ND
ug/L
50.0
13.7
1
04/29/1514:46
04/30/1510:42
7439-89-6
ND
ug/L
0.10
0.046
1
04/29/1514:46
04/30/1510:42
7439-92-1
593
ug/L
10.0
3.2
1
04/29/1514:46
04/30/1510:42
7439-95-4
26.6
ug/L
0.50
0.24
1
04/29/1514:46
04/30/1510:42
7439-96-5
14.3
ug/L
0.50
0.094
1
04/29/1514:46
04/30/1510:42
7439-98-7
13.5
ug/L
0.50
0.16
1
04/29/1514:46
04/30/1510:42
7440-02-0
450
ug/L
50.0
11.7
1
04/29/1514:46
04/30/1510:42
7440-09-7
14.8
ug/L
0.50
0.20
1
04/29/1514:46
04/30/1510:42
7782-49-2
2400
ug/L
50.0
16.3
1
04/29/1514:46
04/30/1510:42
7440-23-5
267
ug/L
0.50
0.13
1
04/29/1514:46
04/30/1510:42
7440-24-6
ND
ug/L
0.10
0.015
1
04/29/1514:46
04/30/1510:42
7440-28-0
9.9
ug/L
1.0
0.28
1
04/29/1514:46
04/30/1510:42
7440-62-2
66.6
ug/L
5.0
2.4
1
04/29/1514:46
04/30/1510:42
7440-66-6
Analytical Method: EPA 7470A Preparation Method: EPA 7470A
ND ug/L 0.20 0.022 1 04/23/15 11:03 04/23/15 21:22 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 53 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980%4grpyf�e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15030700
Pace Project No.: 92243096
Sample: 2015008691 SPLP Lab ID: 92243096011 Collected: 03/26/15 11:30 Received: 03/27/15 15:45 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
;T➢Z17c\riil=11 a
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Sodium
Strontium
Thallium
Vanadium
Zinc
7470A Mercury
Mercury
Date: 05/11/2015 07:56 AM
Analytical Method: EPA 6020A Preparation Method: EPA 3020
7.7J
ug/L
10.0
3.0
1
04/29/1514:46
04/30/1510:51
7429-90-5
ND
ug/L
0.50
0.15
1
04/29/1514:46
04/30/1510:51
7440-36-0
ND
ug/L
0.50
0.11
1
04/29/1514:46
04/30/1510:51
7440-38-2
182
ug/L
0.30
0.081
1
04/29/1514:46
04/30/1510:51
7440-39-3
ND
ug/L
0.20
0.067
1
04/29/1514:46
04/30/1510:51
7440-41-7
97.0
ug/L
5.0
1.1
1
04/29/1514:46
04/30/1510:51
7440-42-8
0.031J
ug/L
0.080
0.024
1
04/29/1514:46
04/30/1510:51
7440-43-9
598
ug/L
40.0
16.0
1
04/29/1514:46
04/30/1510:51
7440-70-2
0.84
ug/L
0.50
0.17
1
04/29/1514:46
04/30/1510:51
7440-47-3
5.6
ug/L
0.50
0.13
1
04/29/1514:46
04/30/1510:51
7440-48-4
0.79J
ug/L
1.0
0.21
1
04/29/1514:46
04/30/1510:51
7440-50-8
ND
ug/L
50.0
13.7
1
04/29/1514:46
04/30/1510:51
7439-89-6
0.11
ug/L
0.10
0.046
1
04/29/1514:46
04/30/1510:51
7439-92-1
383
ug/L
10.0
3.2
1
04/29/1514:46
04/30/1510:51
7439-95-4
152
ug/L
0.50
0.24
1
04/29/1514:46
04/30/1510:51
7439-96-5
ND
ug/L
0.50
0.094
1
04/29/1514:46
04/30/1510:51
7439-98-7
1.9
ug/L
0.50
0.16
1
04/29/1514:46
04/30/1510:51
7440-02-0
326
ug/L
50.0
11.7
1
04/29/1514:46
04/30/1510:51
7440-09-7
ND
ug/L
0.50
0.20
1
04/29/1514:46
04/30/1510:51
7782-49-2
2030
ug/L
50.0
16.3
1
04/29/1514:46
04/30/1510:51
7440-23-5
10.4
ug/L
0.50
0.13
1
04/29/1514:46
04/30/1510:51
7440-24-6
ND
ug/L
0.10
0.015
1
04/29/1514:46
04/30/1510:51
7440-28-0
ND
ug/L
1.0
0.28
1
04/29/1514:46
04/30/1510:51
7440-62-2
128
ug/L
5.0
2.4
1
04/29/1514:46
04/30/1510:51
7440-66-6
Analytical Method: EPA 7470A Preparation Method: EPA 7470A
0.030J ug/L 0.20 0.022 1 04/23/15 11:03 04/23/15 21:33 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 54 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800&pyfy e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15030700
Pace Project No.: 92243096
Sample: 2015008692 SPLP Lab ID: 92243096012 Collected: 03/26/15 08:45 Received: 03/27/15 15:45 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
;T➢Z17c\�iil=11 a
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Sodium
Strontium
Thallium
Vanadium
Zinc
7470A Mercury
Mercury
Date: 05/11/2015 07:56 AM
Analytical Method: EPA 6020A Preparation Method: EPA 3020
145
ug/L
10.0
3.0
1
04/29/1514:46
04/30/1511:10
7429-90-5
ND
ug/L
0.50
0.15
1
04/29/1514:46
04/30/1511:10
7440-36-0
ND
ug/L
0.50
0.11
1
04/29/1514:46
04/30/1511:10
7440-38-2
168
ug/L
0.30
0.081
1
04/29/1514:46
04/30/1511:10
7440-39-3
ND
ug/L
0.20
0.067
1
04/29/1514:46
04/30/1511:10
7440-41-7
95.5
ug/L
5.0
1.1
1
04/29/1514:46
04/30/1511:10
7440-42-8
0.063J
ug/L
0.080
0.024
1
04/29/1514:46
04/30/1511:10
7440-43-9
1350
ug/L
40.0
16.0
1
04/29/1514:46
04/30/1511:10
7440-70-2
0.40J
ug/L
0.50
0.17
1
04/29/1514:46
04/30/1511:10
7440-47-3
1.8
ug/L
0.50
0.13
1
04/29/1514:46
04/30/1511:10
7440-48-4
1.3
ug/L
1.0
0.21
1
04/29/1514:46
04/30/1511:10
7440-50-8
1560
ug/L
50.0
13.7
1
04/29/1514:46
04/30/1511:10
7439-89-6
0.21
ug/L
0.10
0.046
1
04/29/1514:46
04/30/1511:10
7439-92-1
823
ug/L
10.0
3.2
1
04/29/1514:46
04/30/1511:10
7439-95-4
150
ug/L
0.50
0.24
1
04/29/1514:46
04/30/1511:10
7439-96-5
ND
ug/L
0.50
0.094
1
04/29/1514:46
04/30/1511:10
7439-98-7
1.8
ug/L
0.50
0.16
1
04/29/1514:46
04/30/1511:10
7440-02-0
696
ug/L
50.0
11.7
1
04/29/1514:46
04/30/1511:10
7440-09-7
ND
ug/L
0.50
0.20
1
04/29/1514:46
04/30/1511:10
7782-49-2
2570
ug/L
50.0
16.3
1
04/29/1514:46
04/30/1511:10
7440-23-5
22.7
ug/L
0.50
0.13
1
04/29/1514:46
04/30/1511:10
7440-24-6
ND
ug/L
0.10
0.015
1
04/29/1514:46
04/30/1511:10
7440-28-0
ND
ug/L
1.0
0.28
1
04/29/1514:46
04/30/1511:10
7440-62-2
160
ug/L
5.0
2.4
1
04/29/1514:46
04/30/1511:10
7440-66-6
Analytical Method: EPA 7470A Preparation Method: EPA 7470A
ND ug/L 0.20 0.022 1 04/23/15 11:03 04/23/15 21:39 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 55 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
98007tbirpyf�e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15030700
Pace Project No.: 92243096
Sample: 2015008684 Lab ID: 92243096013 Collected: 03/23/15 10:45 Received: 03/27/15 15:45 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
;I➢ZI7c\�i,I=11 l[99�r 6?
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Sodium
Strontium
Thallium
Vanadium
Zinc
7470 Mercury
Mercury
Date: 05/11/2015 07:56 AM
Analytical Method: EPA 6020A Preparation Method: EPA 3020
123
ug/L
10.0
3.0
1
04/02/15 07:30
04/02/15 19:08
7429-90-5
ND
ug/L
0.50
0.15
1
04/02/15 07:30
04/02/15 19:08
7440-36-0
ND
ug/L
0.50
0.11
1
04/02/15 07:30
04/02/15 19:08
7440-38-2
2.6
ug/L
0.30
0.081
1
04/02/15 07:30
04/02/15 19:08
7440-39-3
ND
ug/L
0.20
0.067
1
04/02/15 07:30
04/02/15 19:08
7440-41-7
ND
ug/L
5.0
1.1
1
04/02/15 07:30
04/02/15 19:08
7440-42-8
ND
ug/L
0.080
0.024
1
04/02/15 07:30
04/02/15 19:08
7440-43-9
373
ug/L
40.0
16.0
1
04/02/15 07:30
04/02/15 19:08
7440-70-2
0.50
ug/L
0.50
0.17
1
04/02/15 07:30
04/02/15 19:08
7440-47-3
ND
ug/L
0.50
0.13
1
04/02/15 07:30
04/02/15 19:08
7440-48-4
ND
ug/L
1.0
0.21
1
04/02/15 07:30
04/02/15 19:08
7440-50-8
1030
ug/L
50.0
13.7
1
04/02/15 07:30
04/02/15 19:08
7439-89-6
0.27
ug/L
0.10
0.046
1
04/02/15 07:30
04/02/15 19:08
7439-92-1
79.0
ug/L
10.0
3.2
1
04/02/15 07:30
04/02/15 19:08
7439-95-4
19.8
ug/L
0.50
0.24
1
04/02/15 07:30
04/02/15 19:08
7439-96-5
0.73
ug/L
0.50
0.094
1
04/02/15 07:30
04/02/15 19:08
7439-98-7
0.78
ug/L
0.50
0.16
1
04/02/15 07:30
04/02/15 19:08
7440-02-0
129
ug/L
50.0
11.7
1
04/02/15 07:30
04/02/15 19:08
7440-09-7
ND
ug/L
0.50
0.20
1
04/02/15 07:30
04/02/15 19:08
7782-49-2
259
ug/L
50.0
16.3
1
04/02/15 07:30
04/02/15 19:08
7440-23-5
2.5
ug/L
0.50
0.13
1
04/02/15 07:30
04/02/15 19:08
7440-24-6
ND
ug/L
0.10
0.015
1
04/02/15 07:30
04/02/15 19:08
7440-28-0
ND
ug/L
1.0
0.28
1
04/02/15 07:30
04/02/15 19:08
7440-62-2
ND
ug/L
5.0
2.4
1
04/02/15 07:30
04/02/15 19:08
7440-66-6
Analytical Method: EPA 7470 Preparation Method: EPA 7470
ND ug/L 0.20 0.022 1 04/01/15 09:20 04/01/15 13:38 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 56 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800Airpyf�e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15030700
Pace Project No.: 92243096
Sample: 2015008687 Lab ID: 92243096014 Collected: 03/24/15 08:30 Received: 03/27/15 15:45 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
;I➢ZI7c\ri,I=11 l[99�r 6?
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Sodium
Strontium
Thallium
Vanadium
Zinc
7470 Mercury
Mercury
Date: 05/11/2015 07:56 AM
Analytical Method: EPA 6020A Preparation Method: EPA 3020
59.9
ug/L
10.0
3.0
1
04/02/15 07:30
04/02/15 19:11
7429-90-5
ND
ug/L
0.50
0.15
1
04/02/15 07:30
04/02/15 19:11
7440-36-0
ND
ug/L
0.50
0.11
1
04/02/15 07:30
04/02/15 19:11
7440-38-2
1.0
ug/L
0.30
0.081
1
04/02/15 07:30
04/02/15 19:11
7440-39-3
ND
ug/L
0.20
0.067
1
04/02/15 07:30
04/02/15 19:11
7440-41-7
ND
ug/L
5.0
1.1
1
04/02/15 07:30
04/02/15 19:11
7440-42-8
ND
ug/L
0.080
0.024
1
04/02/15 07:30
04/02/15 19:11
7440-43-9
141
ug/L
40.0
16.0
1
04/02/15 07:30
04/02/15 19:11
7440-70-2
1.1
ug/L
0.50
0.17
1
04/02/15 07:30
04/02/15 19:11
7440-47-3
ND
ug/L
0.50
0.13
1
04/02/15 07:30
04/02/15 19:11
7440-48-4
ND
ug/L
1.0
0.21
1
04/02/15 07:30
04/02/15 19:11
7440-50-8
814
ug/L
50.0
13.7
1
04/02/15 07:30
04/02/15 19:11
7439-89-6
0.11
ug/L
0.10
0.046
1
04/02/15 07:30
04/02/15 19:11
7439-92-1
35.7
ug/L
10.0
3.2
1
04/02/15 07:30
04/02/15 19:11
7439-95-4
10.3
ug/L
0.50
0.24
1
04/02/15 07:30
04/02/15 19:11
7439-96-5
0.74
ug/L
0.50
0.094
1
04/02/15 07:30
04/02/15 19:11
7439-98-7
ND
ug/L
0.50
0.16
1
04/02/15 07:30
04/02/15 19:11
7440-02-0
67.1
ug/L
50.0
11.7
1
04/02/15 07:30
04/02/15 19:11
7440-09-7
ND
ug/L
0.50
0.20
1
04/02/15 07:30
04/02/15 19:11
7782-49-2
135
ug/L
50.0
16.3
1
04/02/15 07:30
04/02/15 19:11
7440-23-5
1.1
ug/L
0.50
0.13
1
04/02/15 07:30
04/02/15 19:11
7440-24-6
ND
ug/L
0.10
0.015
1
04/02/15 07:30
04/02/15 19:11
7440-28-0
ND
ug/L
1.0
0.28
1
04/02/15 07:30
04/02/15 19:11
7440-62-2
7.3
ug/L
5.0
2.4
1
04/02/15 07:30
04/02/15 19:11
7440-66-6
Analytical Method: EPA 7470 Preparation Method: EPA 7470
ND ug/L 0.20 0.022 1 04/01/15 09:20 04/01/15 13:40 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 57 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800hirpyf�e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15030700
Pace Project No.: 92243096
Sample: 2015008688 Lab ID: 92243096015 Collected: 03/25/15 16:26 Received: 03/27/15 15:45 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
;I➢ZI7c\ri,I=11a 99�r6?
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Sodium
Strontium
Thallium
Vanadium
Zinc
7470 Mercury
Mercury
Date: 05/11/2015 07:56 AM
Analytical Method: EPA 6020A Preparation Method: EPA 3020
567
ug/L
10.0
3.0
1
04/02/15 07:30
04/02/15 19:14
7429-90-5
ND
ug/L
0.50
0.15
1
04/02/15 07:30
04/02/15 19:14
7440-36-0
ND
ug/L
0.50
0.11
1
04/02/15 07:30
04/02/15 19:14
7440-38-2
6.6
ug/L
0.30
0.081
1
04/02/15 07:30
04/02/15 19:14
7440-39-3
ND
ug/L
0.20
0.067
1
04/02/15 07:30
04/02/15 19:14
7440-41-7
ND
ug/L
5.0
1.1
1
04/02/15 07:30
04/02/15 19:14
7440-42-8
ND
ug/L
0.080
0.024
1
04/02/15 07:30
04/02/15 19:14
7440-43-9
155
ug/L
40.0
16.0
1
04/02/15 07:30
04/02/15 19:14
7440-70-2
3.1
ug/L
0.50
0.17
1
04/02/15 07:30
04/02/15 19:14
7440-47-3
0.66
ug/L
0.50
0.13
1
04/02/15 07:30
04/02/15 19:14
7440-48-4
ND
ug/L
1.0
0.21
1
04/02/15 07:30
04/02/15 19:14
7440-50-8
1570
ug/L
50.0
13.7
1
04/02/15 07:30
04/02/15 19:14
7439-89-6
0.35
ug/L
0.10
0.046
1
04/02/15 07:30
04/02/15 19:14
7439-92-1
201
ug/L
10.0
3.2
1
04/02/15 07:30
04/02/15 19:14
7439-95-4
22.0
ug/L
0.50
0.24
1
04/02/15 07:30
04/02/15 19:14
7439-96-5
1.3
ug/L
0.50
0.094
1
04/02/15 07:30
04/02/15 19:14
7439-98-7
1.1
ug/L
0.50
0.16
1
04/02/15 07:30
04/02/15 19:14
7440-02-0
201
ug/L
50.0
11.7
1
04/02/15 07:30
04/02/15 19:14
7440-09-7
ND
ug/L
0.50
0.20
1
04/02/15 07:30
04/02/15 19:14
7782-49-2
442
ug/L
50.0
16.3
1
04/02/15 07:30
04/02/15 19:14
7440-23-5
1.3
ug/L
0.50
0.13
1
04/02/15 07:30
04/02/15 19:14
7440-24-6
ND
ug/L
0.10
0.015
1
04/02/15 07:30
04/02/15 19:14
7440-28-0
1.3
ug/L
1.0
0.28
1
04/02/15 07:30
04/02/15 19:14
7440-62-2
10
ug/L
5.0
2.4
1
04/02/15 07:30
04/02/15 19:14
7440-66-6
Analytical Method: EPA 7470 Preparation Method: EPA 7470
ND ug/L 0.20 0.022 1 04/01/15 09:20 04/01/15 13:43 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 58 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800hrpyf�e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J15030700
Pace Project No.: 92243096
Sample: 2015008690 Lab ID: 92243096016 Collected: 03/26/15 08:30 Received: 03/27/15 15:45 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
;I➢ZI7c\�i,I=11 l[99�r 6?
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Sodium
Strontium
Thallium
Vanadium
Zinc
7470 Mercury
Mercury
Date: 05/11/2015 07:56 AM
Analytical Method: EPA 6020A Preparation Method: EPA 3020
236
ug/L
10.0
3.0
1
04/02/15 07:30
04/02/15 19:17
7429-90-5
ND
ug/L
0.50
0.15
1
04/02/15 07:30
04/02/15 19:17
7440-36-0
ND
ug/L
0.50
0.11
1
04/02/15 07:30
04/02/15 19:17
7440-38-2
2.8
ug/L
0.30
0.081
1
04/02/15 07:30
04/02/15 19:17
7440-39-3
ND
ug/L
0.20
0.067
1
04/02/15 07:30
04/02/15 19:17
7440-41-7
ND
ug/L
5.0
1.1
1
04/02/15 07:30
04/02/15 19:17
7440-42-8
ND
ug/L
0.080
0.024
1
04/02/15 07:30
04/02/15 19:17
7440-43-9
505
ug/L
40.0
16.0
1
04/02/15 07:30
04/02/15 19:17
7440-70-2
2.7
ug/L
0.50
0.17
1
04/02/15 07:30
04/02/15 19:17
7440-47-3
3.5
ug/L
0.50
0.13
1
04/02/15 07:30
04/02/15 19:17
7440-48-4
2.8
ug/L
1.0
0.21
1
04/02/15 07:30
04/02/15 19:17
7440-50-8
479
ug/L
50.0
13.7
1
04/02/15 07:30
04/02/15 19:17
7439-89-6
0.44
ug/L
0.10
0.046
1
04/02/15 07:30
04/02/15 19:17
7439-92-1
55.7
ug/L
10.0
3.2
1
04/02/15 07:30
04/02/15 19:17
7439-95-4
7.1
ug/L
0.50
0.24
1
04/02/15 07:30
04/02/15 19:17
7439-96-5
ND
ug/L
0.50
0.094
1
04/02/15 07:30
04/02/15 19:17
7439-98-7
0.57
ug/L
0.50
0.16
1
04/02/15 07:30
04/02/15 19:17
7440-02-0
125
ug/L
50.0
11.7
1
04/02/15 07:30
04/02/15 19:17
7440-09-7
ND
ug/L
0.50
0.20
1
04/02/15 07:30
04/02/15 19:17
7782-49-2
67.7
ug/L
50.0
16.3
1
04/02/15 07:30
04/02/15 19:17
7440-23-5
2.5
ug/L
0.50
0.13
1
04/02/15 07:30
04/02/15 19:17
7440-24-6
ND
ug/L
0.10
0.015
1
04/02/15 07:30
04/02/15 19:17
7440-28-0
ND
ug/L
1.0
0.28
1
04/02/15 07:30
04/02/15 19:17
7440-62-2
5.4
ug/L
5.0
2.4
1
04/02/15 07:30
04/02/15 19:17
7440-66-6
Analytical Method: EPA 7470 Preparation Method: EPA 7470
ND ug/L 0.20 0.022 1 04/01/15 09:20 04/01/15 13:45 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 59 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
98007VW �e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15030700
Pace Project No.: 92243096
QC Batch: MERP/13104
Analysis Method: EPA 7470
QC Batch Method: EPA 7470
Analysis Description: 7470 Mercury
Associated Lab Samples: 92243096013, 92243096014,
92243096015, 92243096016
METHOD BLANK: 1929182
Matrix: Water
Associated Lab Samples: 92243096013, 92243096014,
92243096015, 92243096016
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Mercury ug/L
ND 0.20
04/01/1513:03
LABORATORY CONTROL SAMPLE: 1929183
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Mercury ug/L
5 5.4
108 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1929376 1929377
MS MSD
92242976005
Spike Spike MS
MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec Limits RPD RPD Qual
Mercury ug/L ND
5 5 5.3
5.5 106 110 75-125 4 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/11/2015 07:56 AM without the written consent of Pace Analytical Services, Inc..
Page 60 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
98008rpyf�e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15030700
Pace Project No.: 92243096
QC Batch: MERP/13319
Analysis Method: EPA 7470A
QC Batch Method: EPA 7470A
Analysis Description: 7470A Mercury Water
Associated Lab Samples: 92243096008, 92243096009,
92243096010, 92243096011, 92243096012
METHOD BLANK: 1946188
Matrix: Water
Associated Lab Samples: 92243096008, 92243096009,
92243096010, 92243096011, 92243096012
Blank Reporting
Parameter Units
Result Limit Analyzed Qualifiers
Mercury ug/L
ND 0.20 04/23/15 21:14
LABORATORY CONTROL SAMPLE: 1946189
Spike LCS LCS % Rec
Parameter Units
Conc. Result % Rec Limits Qualifiers
Mercury ug/L
5 4.9 98 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1946230 1946231
MS MSD
92243096011
Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Mercury ug/L 0.030J
5 5 4.7 4.7 94 93 80-120 0 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/11/2015 07:56 AM without the written consent of Pace Analytical Services, Inc..
Page 61 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800Mrpyf�e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15030700
Pace Project No.: 92243096
QC Batch: MERP/5551
Analysis Method: EPA 7471
QC Batch Method: EPA 7471
Analysis Description: 7471 Mercury
Associated Lab Samples: 92243096001, 92243096002,
92243096003, 92243096004, 92243096005
METHOD BLANK: 1174890
Matrix: Solid
Associated Lab Samples: 92243096001, 92243096002,
92243096003, 92243096004, 92243096005
Blank Reporting
Parameter Units
Result Limit Analyzed Qualifiers
Mercury mg/kg
ND 0.0081 04/04/15 20:07
LABORATORY CONTROL SAMPLE: 1174891
Spike LCS LCS % Rec
Parameter Units
Conc. Result % Rec Limits Qualifiers
Mercury mg/kg
.081 0.077 94 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1174892 1174893
MS MSD
92242976001
Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Mercury mg/kg 0.25
.083 .083 0.33 0.32 101 88 80-120 3 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/11/2015 07:56 AM without the written consent of Pace Analytical Services, Inc..
Page 62 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800firpyf�e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15030700
Pace Project No.: 92243096
QC Batch: MERP/5552
Analysis Method: EPA 7471
QC Batch Method: EPA 7471
Analysis Description: 7471 Mercury
Associated Lab Samples: 92243096006, 92243096007
METHOD BLANK: 1175000
Matrix: Solid
Associated Lab Samples: 92243096006, 92243096007
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Mercury mg/kg
ND 0.0083
04/07/15 08:19
LABORATORY CONTROL SAMPLE: 1175001
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Mercury mg/kg
.083 0.078
95 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1175002 1175003
MS MSD
92243090001
Spike Spike MS
MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec Limits RPD RPD Qual
Mercury mg/kg ND
.0898 .0909 0.093
0.093 100 99 80-120 0 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/11/2015 07:56 AM without the written consent of Pace Analytical Services, Inc..
Page 63 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800mrpyf�e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15030700
Pace Project No.: 92243096
QC Batch: MPRP/23407 Analysis Method: EPA 6010
QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid
Associated Lab Samples: 92243096001, 92243096002, 92243096003, 92243096004, 92243096005
METHOD BLANK: 1173242 Matrix: Solid
Associated Lab Samples: 92243096001, 92243096002, 92243096003, 92243096004, 92243096005
Blank Reporting
Parameter Units Result Limit Analyzed
Aluminum
mg/kg
ND
5.1
04/07/15 07:49
Barium
mg/kg
ND
0.51
04/07/15 07:49
Beryllium
mg/kg
ND
0.051
04/07/15 07:49
Boron
mg/kg
ND
2.5
04/07/15 07:49
Calcium
mg/kg
ND
25.3
04/07/15 07:49
Chromium
mg/kg
ND
0.25
04/07/15 07:49
Copper
mg/kg
ND
0.25
04/07/15 07:49
Iron
mg/kg
ND
2.0
04/07/15 07:49
Magnesium
mg/kg
ND
25.3
04/07/15 07:49
Manganese
mg/kg
ND
0.25
04/07/15 07:49
Molybdenum
mg/kg
ND
0.51
04/07/15 07:49
Nickel
mg/kg
ND
0.25
04/07/15 07:49
Potassium
mg/kg
ND
50.5
04/07/15 07:49
Sodium
mg/kg
ND
50.5
04/07/15 07:49
Strontium
mg/kg
ND
0.51
04/07/15 07:49
Zinc
mg/kg
0.56J
1.0
04/07/15 07:49
Qualifiers
LABORATORY CONTROL SAMPLE:
Parameter
1173243
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
Aluminum
mg/kg
126
136
108
80-120
Barium
mg/kg
12.6
13.5
107
80-120
Beryllium
mg/kg
1.3
1.4
112
80-120
Boron
mg/kg
126
137
109
80-120
Calcium
mg/kg
628
687
109
80-120
Chromium
mg/kg
12.6
13.3
106
80-120
Copper
mg/kg
12.6
13.5
108
80-120
Iron
mg/kg
126
136
108
80-120
Magnesium
mg/kg
628
658
105
80-120
Manganese
mg/kg
12.6
13.8
110
80-120
Molybdenum
mg/kg
12.6
13.2
105
80-120
Nickel
mg/kg
12.6
13.4
107
80-120
Potassium
mg/kg
628
659
105
80-120
Sodium
mg/kg
628
692
110
80-120
Strontium
mg/kg
12.6
13.5
108
80-120
Zinc
mg/kg
62.8
67.9
108
80-120
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/11/2015 07:56 AM without the written consent of Pace Analytical Services, Inc.. Page 64 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980079,6fyf�e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15030700
Pace Project No.: 92243096
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
1173244
1173245
MS
MSD
92242976001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Aluminum
mg/kg
12700
124
127
13000
12900
226
209
75-125
0
20 M1
Barium
mg/kg
218
12.4
12.7
231
236
106
145
75-125
2
20 M1
Beryllium
mg/kg
5.0
1.2
1.3
5.9
5.8
79
70
75-125
2
20 M1
Boron
mg/kg
60.9
124
127
169
170
88
86
75-125
0
20
Calcium
mg/kg
3250
620
635
3720
3550
75
47
75-125
4
20 M1
Chromium
mg/kg
20.3
12.4
12.7
29.9
30.6
77
81
75-125
2
20
Copper
mg/kg
55.1
12.4
12.7
62.4
62.6
58
59
75-125
0
20 M1
Iron
mg/kg
6240
124
127
5540
5650
-562
-462
75-125
2
20 M1
Magnesium
mg/kg
793
620
635
1360
1380
92
92
75-125
1
20
Manganese
mg/kg
46.8
12.4
12.7
56.2
56.6
76
77
75-125
1
20
Molybdenum
mg/kg
2.2J
12.4
12.7
13.2
13.7
88
90
75-125
4
20
Nickel
mg/kg
30.4
12.4
12.7
41.6
42.8
90
97
75-125
3
20
Potassium
mg/kg
1530
620
635
2230
2260
113
115
75-125
1
20
Sodium
mg/kg
333
620
635
938
963
98
99
75-125
3
20
Strontium
mg/kg
222
12.4
12.7
206
201
-128
-165
75-125
3
20 M1
Zinc
mg/kg
42.7
62
63.5
100
104
93
96
75-125
3
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/11/2015 07:56 AM without the written consent of Pace Analytical Services, Inc..
Page 65 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980vrpyf�e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15030700
Pace Project No.: 92243096
QC Batch: MPRP/23414 Analysis Method: EPA 6010
QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid
Associated Lab Samples: 92243096006, 92243096007
METHOD BLANK: 1173679
Associated Lab Samples: 92243096006, 92243096007
Parameter
Units
Aluminum
mg/kg
Barium
mg/kg
Beryllium
mg/kg
Boron
mg/kg
Calcium
mg/kg
Chromium
mg/kg
Copper
mg/kg
Iron
mg/kg
Magnesium
mg/kg
Manganese
mg/kg
Molybdenum
mg/kg
Nickel
mg/kg
Potassium
mg/kg
Sodium
mg/kg
Strontium
mg/kg
Zinc
mg/kg
Matrix: Solid
Blank
Result
Reporting
Limit
Analyzed
ND
5.1
04/05/15 02:37
ND
0.51
04/05/15 02:37
ND
0.051
04/05/15 02:37
ND
2.6
04/05/15 02:37
ND
25.7
04/05/15 02:37
ND
0.26
04/05/15 02:37
ND
0.26
04/05/15 02:37
ND
2.1
04/05/15 02:37
ND
25.7
04/05/15 02:37
ND
0.26
04/05/15 02:37
ND
0.51
04/05/15 02:37
ND
0.26
04/05/15 02:37
ND
51.4
04/05/15 02:37
ND
51.4
04/05/15 02:37
ND
0.51
04/05/15 02:37
ND
1.0
04/05/15 02:37
Qualifiers
LABORATORY CONTROL SAMPLE:
Parameter
1173680
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
Aluminum
mg/kg
128
128
100
80-120
Barium
mg/kg
12.8
13.3
104
80-120
Beryllium
mg/kg
1.3
1.3
99
80-120
Boron
mg/kg
128
126
98
80-120
Calcium
mg/kg
641
636
99
80-120
Chromium
mg/kg
12.8
12.8
99
80-120
Copper
mg/kg
12.8
12.5
98
80-120
Iron
mg/kg
128
125
97
80-120
Magnesium
mg/kg
641
632
99
80-120
Manganese
mg/kg
12.8
12.6
99
80-120
Molybdenum
mg/kg
12.8
12.3
96
80-120
Nickel
mg/kg
12.8
12.7
99
80-120
Potassium
mg/kg
641
686
107
80-120
Sodium
mg/kg
641
693
108
80-120
Strontium
mg/kg
12.8
12.7
99
80-120
Zinc
mg/kg
64.1
63.6
99
80-120
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/11/2015 07:56 AM without the written consent of Pace Analytical Services, Inc..
Page 66 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980mirpyf�e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15030700
Pace Project No.: 92243096
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
1173681
1173682
MS
MSD
92243096006
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Aluminum
mg/kg
6810
124
136
9360
8720
2070
1410
75-125
7
20 M1
Barium
mg/kg
81.6
12.4
13.6
89.6
91.6
65
74
75-125
2
20 M1
Beryllium
mg/kg
0.42
1.26
1.37
1.6
1.7
96
91
75-125
4
20 D3
Boron
mg/kg
14.7
124
136
113
121
79
78
75-125
7
20 D3
Calcium
mg/kg
2750
618
680
3180
3380
69
93
75-125
6
20 M1
Chromium
mg/kg
8.9
12.4
13.6
22.4
22.6
109
101
75-125
1
20 D3
Copper
mg/kg
9.0
12.4
13.6
21.8
21.7
104
93
75-125
1
20 D3
Iron
mg/kg
10200
124
136
14200
12200
3190
1440
75-125
15
20 M1
Magnesium
mg/kg
4940
618
680
6980
6480
330
227
75-125
7
20 M1
Manganese
mg/kg
386
12.4
13.6
456
405
564
137
75-125
12
20 D3,M1
Molybdenum
mg/kg
ND
12.4
13.6
7.8
9.2
63
68
75-125
16
20 M1
Nickel
mg/kg
6.3
12.4
13.6
17.1
18.1
87
87
75-125
6
20
Potassium
mg/kg
1180
618
680
1870
1860
112
100
75-125
1
20
Sodium
mg/kg
95.7
618
680
645
736
89
94
75-125
13
20
Strontium
mg/kg
21.9
12.4
13.6
32.1
35.0
82
96
75-125
9
20
Zinc
mg/kg
50.7
61.8
68
111
112
98
90
75-125
0
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/11/2015 07:56 AM without the written consent of Pace Analytical Services, Inc..
Page 67 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980%ypyf�e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15030700
Pace Project No.: 92243096
QC Batch: MPRP/23408 Analysis Method: EPA 6020
QC Batch Method: EPA 3050 Analysis Description: 6020 MET SOLID
Associated Lab Samples: 92243096001, 92243096002, 92243096003, 92243096004, 92243096005
METHOD BLANK: 1173246
Matrix:
Solid
Associated Lab Samples:
92243096001, 92243096002,
92243096003, 92243096004, 92243096005
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Antimony
mg/kg
0.026J
0.050
04/06/1510:43 N2
Arsenic
mg/kg
ND
0.050
04/06/1510:43
Cadmium
mg/kg
ND
0.0060
04/06/1510:43
Cobalt
mg/kg
ND
0.050
04/06/1510:43
Lead
mg/kg
ND
0.050
04/06/1510:43
Selenium
mg/kg
ND
0.050
04/06/1510:43
Thallium
mg/kg
ND
0.050
04/06/1510:43
Vanadium
mg/kg
ND
0.050
04/06/1510:43
LABORATORY CONTROL SAMPLE:
Parameter
1173247
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
Antimony
mg/kg
2.5
2.6
103
80-120 N2
Arsenic
mg/kg
2.5
2.6
105
80-120
Cadmium
mg/kg
.25
0.25
100
80-120
Cobalt
mg/kg
2.5
2.6
103
80-120
Lead
mg/kg
2.5
2.5
101
80-120
Selenium
mg/kg
2.5
2.6
104
80-120
Thallium
mg/kg
2.5
2.6
103
80-120
Vanadium
mg/kg
2.5
2.5
101
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
1173248
1173249
MS
MSD
92242976002
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Antimony
mg/kg
1 AJ
2.6
2.4
2.9
2.5
56
43
75-125
15
20 M6, N2
Arsenic
mg/kg
17.1
2.6
2.4
24.2
21.5
272
178
75-125
12
20 M6
Cadmium
mg/kg
ND
.26
.24
0.36
0.31
109
99
75-125
12
20
Cobalt
mg/kg
5.0
2.6
2.4
8.9
8.7
153
152
75-125
3
20 M6
Lead
mg/kg
7.3
2.6
2.4
12.6
11.9
203
191
75-125
5
20 M6
Selenium
mg/kg
12.6
2.6
2.4
18.9
15.9
243
137
75-125
17
20 M6
Thallium
mg/kg
ND
2.6
2.4
2.2J
2.OJ
66
62
75-125
20 M6
Vanadium
mg/kg
30.9
2.6
2.4
38.5
37.5
293
270
75-125
3
20 M6
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/11/2015 07:56 AM without the written consent of Pace Analytical Services, Inc..
Page 68 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800&6fy f�e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15030700
Pace Project No.: 92243096
QC Batch: MPRP/23415 Analysis Method: EPA 6020
QC Batch Method: EPA 3050 Analysis Description: 6020 MET SOLID
Associated Lab Samples: 92243096006, 92243096007
METHOD BLANK: 1173683
Matrix:
Solid
Associated Lab Samples:
92243096006, 92243096007
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Antimony
mg/kg
ND
0.051
04/06/1512:03 N2
Arsenic
mg/kg
ND
0.051
04/06/1512:03
Cadmium
mg/kg
ND
0.0061
04/06/1512:03
Cobalt
mg/kg
ND
0.051
04/06/1512:03
Lead
mg/kg
ND
0.051
04/06/1512:03
Selenium
mg/kg
ND
0.051
04/06/1512:03
Thallium
mg/kg
ND
0.051
04/06/1512:03
Vanadium
mg/kg
ND
0.051
04/06/1512:03
LABORATORY CONTROL SAMPLE: 1173684
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
Antimony
mg/kg
2.4
2.3
96
80-120 N2
Arsenic
mg/kg
2.4
2.4
101
80-120
Cadmium
mg/kg
.24
0.22
92
80-120
Cobalt
mg/kg
2.4
2.4
100
80-120
Lead
mg/kg
2.4
2.3
96
80-120
Selenium
mg/kg
2.4
2.4
99
80-120
Thallium
mg/kg
2.4
2.4
98
80-120
Vanadium
mg/kg
2.4
2.3
97
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1173685
1173686
MS
MSD
92243096007
Spike
Spike
MS
MSD
MS MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec % Rec
Limits
RPD
RPD Qual
Antimony
mg/kg
ND
2.94
2.71
2.1J
1.51
65 50
75-125
20 M6, N2
Arsenic
mg/kg
7.7
2.94
2.71
55.9
54.0
1640 1720
75-125
3
20 M6
Cadmium
mg/kg
ND
.294
.271
0.28J
0.29J
90 102
75-125
20
Cobalt
mg/kg
8.4
2.94
2.71
26.9
24.3
630 594
75-125
10
20 M6
Lead
mg/kg
15.6
2.94
2.71
40.1
32.0
835 610
75-125
23
20 M6, R1
Selenium
mg/kg
ND
2.94
2.71
4.3
3.1
104 69
75-125
32
20 M6,R1
Thallium
mg/kg
ND
2.94
2.71
ND
ND
16 8
75-125
20 M6
Vanadium
mg/kg
18.5
2.94
2.71
19.0
29.2
16 398
75-125
42
20 M6, RI
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/11/2015 07:56 AM without the written consent of Pace Analytical Services, Inc..
Page 69 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800A,irpyf�e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15030700
Pace Project No.: 92243096
QC Batch: MPRP/53294 Analysis Method: EPA 6020A
QC Batch Method: EPA 3020 Analysis Description: 6020A Water UPD4
Associated Lab Samples: 92243096013, 92243096014, 92243096015, 92243096016
METHOD BLANK: 1929140 Matrix: Water
Associated Lab Samples: 92243096013, 92243096014, 92243096015, 92243096016
Blank Reporting
Parameter Units Result Limit
Analyzed
Aluminum
ug/L
ND
10.0
04/02/1515:57
Antimony
ug/L
ND
0.50
04/02/1515:57
Arsenic
ug/L
ND
0.50
04/02/1515:57
Barium
ug/L
ND
0.30
04/02/1515:57
Beryllium
ug/L
ND
0.20
04/02/1515:57
Boron
ug/L
ND
5.0
04/02/1515:57
Cadmium
ug/L
ND
0.080
04/02/1515:57
Calcium
ug/L
ND
40.0
04/02/1515:57
Chromium
ug/L
ND
0.50
04/02/1515:57
Cobalt
ug/L
ND
0.50
04/02/1515:57
Copper
ug/L
ND
1.0
04/02/1515:57
Iron
ug/L
ND
50.0
04/02/1515:57
Lead
ug/L
ND
0.10
04/02/1515:57
Magnesium
ug/L
ND
10.0
04/02/1515:57
Manganese
ug/L
ND
0.50
04/02/1515:57
Molybdenum
ug/L
ND
0.50
04/02/1515:57
Nickel
ug/L
ND
0.50
04/02/1515:57
Potassium
ug/L
ND
50.0
04/02/1515:57
Selenium
ug/L
ND
0.50
04/02/1515:57
Sodium
ug/L
ND
50.0
04/02/1515:57
Strontium
ug/L
ND
0.50
04/02/1515:57
Thallium
ug/L
ND
0.10
04/02/1515:57
Vanadium
ug/L
ND
1.0
04/02/1515:57
Zinc
ug/L
ND
5.0
04/02/1515:57
Qualifiers
LABORATORY CONTROL SAMPLE:
Parameter
1929141
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
Aluminum
ug/L
80
84.1
105
80-120
Antimony
ug/L
80
83.2
104
80-120
Arsenic
ug/L
80
84.5
106
80-120
Barium
ug/L
80
81.8
102
80-120
Beryllium
ug/L
80
84.6
106
80-120
Boron
ug/L
80
83.9
105
80-120
Cadmium
ug/L
80
81.8
102
80-120
Calcium
ug/L
1000
981
98
80-120
Chromium
ug/L
80
83.4
104
80-120
Cobalt
ug/L
80
81.8
102
80-120
Copper
ug/L
80
77.6
97
80-120
Iron
ug/L
1000
1060
106
80-120
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/11/2015 07:56 AM without the written consent of Pace Analytical Services, Inc.. Page 70 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980%�'pyf�e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15030700
Pace Project No.: 92243096
LABORATORY CONTROL SAMPLE:
1929141
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits
Qualifiers
Lead
ug/L
80
86.5
108
80-120
Magnesium
ug/L
1000
1020
102
80-120
Manganese
ug/L
80
86.1
108
80-120
Molybdenum
ug/L
80
79.2
99
80-120
Nickel
ug/L
80
81.2
101
80-120
Potassium
ug/L
1000
1060
106
80-120
Selenium
ug/L
80
83.2
104
80-120
Sodium
ug/L
1000
1030
103
80-120
Strontium
ug/L
80
83.1
104
80-120
Thallium
ug/L
80
85.4
107
80-120
Vanadium
ug/L
80
83.2
104
80-120
Zinc
ug/L
80
84.9
106
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
1929142
1929143
MS
MSD
92242959001
Spike
Spike
MS
MSD
MS MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec % Rec
Limits
RPD
RPD Qual
Aluminum
ug/L
11.6
80
80
102
97.4
113
107
75-125
5
20
Antimony
ug/L
ND
80
80
83.7
83.2
105
104
75-125
1
20
Arsenic
ug/L
ND
80
80
85.5
85.6
107
107
75-125
0
20
Barium
ug/L
ND
80
80
83.5
83.1
104
103
75-125
0
20
Beryllium
ug/L
ND
80
80
85.8
85.2
107
107
75-125
1
20
Boron
ug/L
ND
80
80
86.4
85.8
107
106
75-125
1
20
Cadmium
ug/L
ND
80
80
82.2
82.9
103
104
75-125
1
20
Calcium
ug/L
ND
1000
1000
1050
1000
102
96
75-125
5
20
Chromium
ug/L
ND
80
80
85.2
85.3
106
106
75-125
0
20
Cobalt
ug/L
ND
80
80
83.6
82.9
105
104
75-125
1
20
Copper
ug/L
1.5
80
80
80.3
79.9
99
98
75-125
1
20
Iron
ug/L
ND
1000
1000
1090
1080
107
106
75-125
1
20
Lead
ug/L
0.24
80
80
87.0
87.8
108
109
75-125
1
20
Magnesium
ug/L
12.9
1000
1000
1070
1050
105
104
75-125
1
20
Manganese
ug/L
1.1
80
80
87.9
87.9
109
109
75-125
0
20
Molybdenum
ug/L
ND
80
80
79.8
80.1
100
100
75-125
0
20
Nickel
ug/L
ND
80
80
83.3
82.5
104
103
75-125
1
20
Potassium
ug/L
ND
1000
1000
1120
1130
110
110
75-125
1
20
Selenium
ug/L
ND
80
80
84.0
84.0
105
105
75-125
0
20
Sodium
ug/L
ND
1000
1000
1090
1090
105
105
75-125
0
20
Strontium
ug/L
ND
80
80
83.8
84.3
105
105
75-125
1
20
Thallium
ug/L
ND
80
80
83.7
84.3
105
105
75-125
1
20
Vanadium
ug/L
ND
80
80
83.4
83.7
104
105
75-125
0
20
Zinc
ug/L
ND
80
80
87.3
86.6
106
105
75-125
1
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/11/2015 07:56 AM without the written consent of Pace Analytical Services, Inc..
Page 71 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980vrpyf�e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15030700
Pace Project No.: 92243096
QC Batch: MPRP/53956 Analysis Method: EPA 6020A
QC Batch Method: EPA 3020 Analysis Description: 6020A Water UPD4
Associated Lab Samples: 92243096008
METHOD BLANK: 1949352
Associated Lab Samples: 92243096008
Parameter
Units
Matrix:
Blank
Result
Water
Reporting
Limit
Analyzed Qualifiers
Aluminum
ug/L
6.9J
10.0
04/28/15 04:56
Antimony
ug/L
ND
0.50
04/28/15 04:56
Arsenic
ug/L
0.14J
0.50
04/28/15 04:56
Barium
ug/L
0.32
0.30
04/28/15 04:56 P8
Beryllium
ug/L
ND
0.20
04/28/15 04:56
Boron
ug/L
ND
5.0
04/28/15 04:56
Cadmium
ug/L
ND
0.080
04/28/15 04:56
Calcium
ug/L
16.OJ
40.0
04/28/15 04:56
Chromium
ug/L
0.64
0.50
04/28/15 04:56 P8
Cobalt
ug/L
ND
0.50
04/28/15 04:56
Copper
ug/L
0.29J
1.0
04/28/15 04:56
Iron
ug/L
31.3J
50.0
04/28/15 04:56
Lead
ug/L
0.056J
0.10
04/28/15 04:56
Magnesium
ug/L
3.6J
10.0
04/28/15 04:56
Manganese
ug/L
0.31 J
0.50
04/28/15 04:56
Molybdenum
ug/L
0.14J
0.50
04/28/15 04:56
Nickel
ug/L
0.23J
0.50
04/28/15 04:56
Potassium
ug/L
ND
50.0
04/28/15 04:56
Selenium
ug/L
ND
0.50
04/28/15 04:56
Sodium
ug/L
ND
50.0
04/28/15 04:56
Strontium
ug/L
ND
0.50
04/28/15 04:56
Thallium
ug/L
0.0191
0.10
04/28/15 04:56
Vanadium
ug/L
ND
1.0
04/29/1511:06
Zinc
ug/L
ND
5.0
04/28/15 04:56
LABORATORY CONTROL SAMPLE:
Parameter
1949353
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
Aluminum
ug/L
80
77.2
96
80-120
Antimony
ug/L
80
76.4
95
80-120
Arsenic
ug/L
80
76.1
95
80-120
Barium
ug/L
80
77.0
96
80-120
Beryllium
ug/L
80
79.0
99
80-120
Boron
ug/L
80
78.8
99
80-120
Cadmium
ug/L
80
78.2
98
80-120
Calcium
ug/L
1000
1000
100
80-120
Chromium
ug/L
80
78.9
99
80-120
Cobalt
ug/L
80
77.1
96
80-120
Copper
ug/L
80
77.4
97
80-120
Iron
ug/L
1000
960
96
80-120
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/11/2015 07:56 AM without the written consent of Pace Analytical Services, Inc.. Page 72 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980V,pyf�e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15030700
Pace Project No.: 92243096
LABORATORY CONTROL SAMPLE:
1949353
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits
Qualifiers
Lead
ug/L
80
78.1
98
80-120
Magnesium
ug/L
1000
971
97
80-120
Manganese
ug/L
80
76.6
96
80-120
Molybdenum
ug/L
80
77.8
97
80-120
Nickel
ug/L
80
78.2
98
80-120
Potassium
ug/L
1000
950
95
80-120
Selenium
ug/L
80
76.2
95
80-120
Sodium
ug/L
1000
952
95
80-120
Strontium
ug/L
80
76.7
96
80-120
Thallium
ug/L
80
76.7
96
80-120
Vanadium
ug/L
80
79.4
99
80-120
Zinc
ug/L
80
77.4
97
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
1949383
1949384
MS
MSD
10304468001
Spike
Spike
MS
MSD
MS MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec % Rec
Limits
RPD
RPD Qual
Aluminum
ug/L
139
80
80
240
217
126
98
75-125
10
20 M1
Antimony
ug/L
ND
80
80
77.4
73.7
97
92
75-125
5
20
Arsenic
ug/L
ND
80
80
77.1
73.5
96
92
75-125
5
20
Barium
ug/L
154
80
80
243
230
111
96
75-125
5
20
Beryllium
ug/L
ND
80
80
78.0
74.8
97
93
75-125
4
20
Boron
ug/L
91.8
80
80
181
170
112
98
75-125
6
20
Cadmium
ug/L
ND
80
80
78.7
74.6
98
93
75-125
5
20
Calcium
ug/L
1280
1000
1000
2430
2270
115
99
75-125
7
20
Chromium
ug/L
0.96
80
80
79.4
75.9
98
94
75-125
4
20
Cobalt
ug/L
1.7
80
80
79.6
76.8
97
94
75-125
4
20
Copper
ug/L
1.1
80
80
79.6
76.0
98
94
75-125
5
20
Iron
ug/L
1450
1000
1000
2500
2360
104
91
75-125
5
20
Lead
ug/L
0.19
80
80
79.0
75.7
98
94
75-125
4
20
Magnesium
ug/L
771
1000
1000
1780
1680
101
91
75-125
6
20
Manganese
ug/L
138
80
80
221
210
104
91
75-125
5
20
Molybdenum
ug/L
ND
80
80
78.4
75.2
98
94
75-125
4
20
Nickel
ug/L
1.8
80
80
80.1
77.4
98
95
75-125
3
20
Potassium
ug/L
627
1000
1000
1590
1530
97
90
75-125
4
20
Selenium
ug/L
ND
80
80
78.6
73.8
98
92
75-125
6
20
Sodium
ug/L
2340
1000
1000
3370
3230
103
89
75-125
4
20
Strontium
ug/L
20.6
80
80
98.3
93.7
97
91
75-125
5
20
Thallium
ug/L
ND
80
80
77.9
73.4
97
92
75-125
6
20
Vanadium
ug/L
ND
80
80
76.0
75.4
95
94
75-125
1
20
Zinc
ug/L
149
80
80
237
223
110
93
75-125
6
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/11/2015 07:56 AM without the written consent of Pace Analytical Services, Inc..
Page 73 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980%�rpyf�e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15030700
Pace Project No.: 92243096
QC Batch: MPRP/54015 Analysis Method: EPA 6020A
QC Batch Method: EPA 3020 Analysis Description: 6020A Water UPD4
Associated Lab Samples: 92243096009, 92243096010, 92243096011, 92243096012
METHOD BLANK: 1951182 Matrix: Water
Associated Lab Samples: 92243096009, 92243096010, 92243096011, 92243096012
Blank Reporting
Parameter Units Result Limit
Analyzed
Aluminum
ug/L
ND
10.0
04/30/1510:23
Antimony
ug/L
ND
0.50
04/30/1510:23
Arsenic
ug/L
ND
0.50
04/30/1510:23
Barium
ug/L
0.12J
0.30
04/30/1510:23
Beryllium
ug/L
ND
0.20
04/30/1510:23
Boron
ug/L
ND
5.0
04/30/1510:23
Cadmium
ug/L
ND
0.080
04/30/1510:23
Calcium
ug/L
ND
40.0
04/30/1510:23
Chromium
ug/L
ND
0.50
04/30/1510:23
Cobalt
ug/L
ND
0.50
04/30/1510:23
Copper
ug/L
ND
1.0
04/30/1510:23
Iron
ug/L
ND
50.0
04/30/1510:23
Lead
ug/L
0.049J
0.10
04/30/1510:23
Magnesium
ug/L
5.9J
10.0
04/30/1510:23
Manganese
ug/L
0.31 J
0.50
04/30/15 10:23
Molybdenum
ug/L
ND
0.50
04/30/1510:23
Nickel
ug/L
ND
0.50
04/30/1510:23
Potassium
ug/L
ND
50.0
04/30/1510:23
Selenium
ug/L
ND
0.50
04/30/1510:23
Sodium
ug/L
ND
50.0
04/30/1510:23
Strontium
ug/L
ND
0.50
04/30/1510:23
Thallium
ug/L
ND
0.10
04/30/1510:23
Vanadium
ug/L
ND
1.0
04/30/1510:23
Zinc
ug/L
ND
5.0
04/30/1510:23
Qualifiers
LABORATORY CONTROL SAMPLE:
Parameter
1951183
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
Aluminum
ug/L
80
84.0
105
80-120
Antimony
ug/L
80
77.4
97
80-120
Arsenic
ug/L
80
78.8
99
80-120
Barium
ug/L
80
78.0
97
80-120
Beryllium
ug/L
80
75.8
95
80-120
Boron
ug/L
80
76.4
96
80-120
Cadmium
ug/L
80
78.5
98
80-120
Calcium
ug/L
1000
1000
100
80-120
Chromium
ug/L
80
77.8
97
80-120
Cobalt
ug/L
80
79.0
99
80-120
Copper
ug/L
80
81.2
101
80-120
Iron
ug/L
1000
970
97
80-120
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/11/2015 07:56 AM without the written consent of Pace Analytical Services, Inc.. Page 74 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980089r6fyf�e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15030700
Pace Project No.: 92243096
LABORATORY CONTROL SAMPLE:
1951183
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits
Qualifiers
Lead
ug/L
80
77.0
96
80-120
Magnesium
ug/L
1000
979
98
80-120
Manganese
ug/L
80
78.1
98
80-120
Molybdenum
ug/L
80
78.2
98
80-120
Nickel
ug/L
80
80.6
101
80-120
Potassium
ug/L
1000
971
97
80-120
Selenium
ug/L
80
80.2
100
80-120
Sodium
ug/L
1000
982
98
80-120
Strontium
ug/L
80
78.6
98
80-120
Thallium
ug/L
80
74.0
93
80-120
Vanadium
ug/L
80
78.0
98
80-120
Zinc
ug/L
80
78.5
98
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
1951297
1951298
MS
MSD
92243096009
Spike
Spike
MS
MSD
MS MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec % Rec
Limits
RPD
RPD Qual
Aluminum
ug/L
6300
80
80
9620
11000
4150
5880
75-125
13
20 M1
Antimony
ug/L
0.16J
80
80
70.7
73.4
88
92
75-125
4
20
Arsenic
ug/L
5.0
80
80
79.0
82.8
92
97
75-125
5
20
Barium
ug/L
265
80
80
360
379
119
142
75-125
5
20 M1
Beryllium
ug/L
0.24
80
80
78.8
82.4
98
103
75-125
4
20
Boron
ug/L
47.6
80
80
134
141
108
116
75-125
5
20
Cadmium
ug/L
0.035J
80
80
77.2
79.2
97
99
75-125
3
20
Calcium
ug/L
8710
1000
1000
9760
9960
105
125
75-125
2
20
Chromium
ug/L
4.1
80
80
82.2
85.4
98
102
75-125
4
20
Cobalt
ug/L
1.8
80
80
79.6
82.4
97
101
75-125
3
20
Copper
ug/L
3.3
80
80
83.0
85.7
100
103
75-125
3
20
Iron
ug/L
6490
1000
1000
7280
9350
79
286
75-125
25
20 M1,R1
Lead
ug/L
3.5
80
80
79.2
82.0
95
98
75-125
3
20
Magnesium
ug/L
2360
1000
1000
3750
3930
139
157
75-125
5
20 M1
Manganese
ug/L
182
80
80
265
276
104
117
75-125
4
20
Molybdenum
ug/L
4.6
80
80
78.6
81.4
93
96
75-125
3
20
Nickel
ug/L
2.0
80
80
81.6
84.2
99
103
75-125
3
20
Potassium
ug/L
2640
1000
1000
4260
4870
162
223
75-125
13
20 M1
Selenium
ug/L
0.42J
80
80
72.5
73.3
90
91
75-125
1
20
Sodium
ug/L
3050
1000
1000
4070
4260
102
121
75-125
5
20
Strontium
ug/L
49.9
80
80
127
132
97
102
75-125
3
20
Thallium
ug/L
0.044J
80
80
75.0
77.3
94
97
75-125
3
20
Vanadium
ug/L
25.2
80
80
104
109
99
104
75-125
4
20
Zinc
ug/L
38.7
80
80
128
125
112
108
75-125
3
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/11/2015 07:56 AM without the written consent of Pace Analytical Services, Inc..
Page 75 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980vrpyf�e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15030700
Pace Project No.: 92243096
QC Batch: PMST/3411
Analysis Method:
ASTM D2974-87
QC Batch Method: ASTM
D2974-87
Analysis Description:
Dry Weight/Percent Moisture
Associated Lab Samples:
92243096001,92243096002,92243096003,92243096004,92243096005,92243096006,92243096007
SAMPLE DUPLICATE:
1174882
35181405002
Dup
Max
Parameter
Units
Result
Result RPD
RPD
Qualifiers
Percent Moisture
%
15.7
15.5 1
10
SAMPLE DUPLICATE:
1174883
92243188001
Dup
Max
Parameter
Units
Result
Result RPD
RPD
Qualifiers
Percent Moisture
%
18.7 1
10
SAMPLE DUPLICATE:
1174884
92243093008
Dup
Max
Parameter
Units
Result
Result RPD
RPD
Qualifiers
Percent Moisture
%
6.6
4.6 35
10 D6
SAMPLE DUPLICATE:
1174885
92243093018
Dup
Max
Parameter
Units
Result
Result RPD
RPD
Qualifiers
Percent Moisture
%
22.8
23.9 5
10
SAMPLE DUPLICATE:
1174886
92242955005
Dup
Max
Parameter
Units
Result
Result RPD
RPD
Qualifiers
Percent Moisture
%
4.1
4.2 3
10
SAMPLE DUPLICATE:
1174887
92243087002
Dup
Max
Parameter
Units
Result
Result RPD
RPD
Qualifiers
Percent Moisture
%
19.2
18.8 2
10
SAMPLE DUPLICATE:
1174888
92242920003
Dup
Max
Parameter
Units
Result
Result RPD
RPD
Qualifiers
Percent Moisture
%
25.3
25.9 2
10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/11/2015 07:56 AM without the written consent of Pace Analytical Services, Inc.. Page 76 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980mirpyf�e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15030700
Pace Project No.: 92243096
SAMPLE DUPLICATE: 1174889
92242920016 Dup Max
Parameter Units Result Result RPD RPD
Percent Moisture % 19.3 20.3 5 10
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/11/2015 07:56 AM without the written consent of Pace Analytical Services, Inc..
Page 77 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800jypy f�e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15030700
Pace Project No.: 92243096
QC Batch: WET/36525 Analysis Method: EPA 9045
QC Batch Method: EPA 9045 Analysis Description: 9045 pH
Associated Lab Samples: 92243096001
SAMPLE DUPLICATE: 1422956
Parameter
pH at 25 Degrees C
SAMPLE DUPLICATE: 1422957
Parameter
pH at 25 Degrees C
92242920012 Dup Max
Units Result Result RPD RPD Qualifiers
Std. Units 6.6 6.6 0 10
92242920014 Dup Max
Units Result Result RPD RPD Qualifiers
Std. Units 8.0 8.0 0 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/11/2015 07:56 AM without the written consent of Pace Analytical Services, Inc.. Page 78 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
98006rpyf�e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15030700
Pace Project No.: 92243096
QC Batch: WET/36550 Analysis Method: EPA 9045
QC Batch Method: EPA 9045 Analysis Description: 9045 pH
Associated Lab Samples: 92243096002, 92243096006
SAMPLE DUPLICATE: 1423905
92243388001 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
pH at 25 Degrees C Std. Units 7.1 7.2 1 10
SAMPLE DUPLICATE: 1423906
92243093007 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
pH at 25 Degrees C Std. Units 6.3 6.3 0 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/11/2015 07:56 AM without the written consent of Pace Analytical Services, Inc.. Page 79 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800g4,6fy f�e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15030700
Pace Project No.: 92243096
QC Batch: WET/36581 Analysis Method: EPA 9045
QC Batch Method: EPA 9045 Analysis Description: 9045 pH
Associated Lab Samples: 92243096003
SAMPLE DUPLICATE: 1424937
Parameter
pH at 25 Degrees C
SAMPLE DUPLICATE: 1424938
Parameter
pH at 25 Degrees C
92242396001 Dup Max
Units Result Result RPD RPD Qualifiers
Std. Units 5.1 5.1 1 10
92243093010 Dup Max
Units Result Result RPD RPD Qualifiers
Std. Units 6.4 6.3 0 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/11/2015 07:56 AM without the written consent of Pace Analytical Services, Inc.. Page 80 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
98004rpyf�e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15030700
Pace Project No.: 92243096
QC Batch: WET/36660 Analysis Method: EPA 9045
QC Batch Method: EPA 9045 Analysis Description: 9045 pH
Associated Lab Samples: 92243096004, 92243096005, 92243096007
SAMPLE DUPLICATE: 1427812
92243088009 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
pH at 25 Degrees C Std. Units 6.9 7.0 1 10
SAMPLE DUPLICATE: 1427813
92243096004 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
pH at 25 Degrees C Std. Units 4.8 4.8 0 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/11/2015 07:56 AM without the written consent of Pace Analytical Services, Inc.. Page 81 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800Airpyf�e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15030700
Pace Project No.: 92243096
QC Batch: WETA/22469 Analysis Method: EPA 300.0
QC Batch Method: EPA 300.0 Analysis Description: 300.0 IC Anions
Associated Lab Samples: 92243096001
METHOD BLANK: 1428206 Matrix: Water
Associated Lab Samples: 92243096001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Sulfate mg/L 2.OJ 2.0 04/07/1514:55
LABORATORY CONTROL SAMPLE: 1428207
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Sulfate mg/L 20 19.6 98 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1428208 1428209
MS MSD
92240170029 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfate mg/L 2.OJ 24.8 24.8 25.3 25.4 94 94 0 H1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1428210 1428211
MS MSD
92242976002 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfate mg/L 12.7 41 41 53.8 53.7 100 100 0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/11/2015 07:56 AM without the written consent of Pace Analytical Services, Inc.. Page 82 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800*rpyf�e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15030700
Pace Project No.: 92243096
QC Batch: WETA/22495
Analysis Method: EPA 300.0
QC Batch Method: EPA 300.0
Analysis Description: 300.0 IC Anions
Associated Lab Samples: 92243096002, 92243096003,
92243096004, 92243096005
METHOD BLANK: 1430392
Matrix: Water
Associated Lab Samples: 92243096002, 92243096003,
92243096004, 92243096005
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Sulfate mg/L
3.4 2.0
04/09/1516:42
LABORATORY CONTROL SAMPLE: 1430393
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Sulfate mg/L
20 19.3
96 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1430394 1430395
MS MSD
92243096002
Spike Spike MS
MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec Limits RPD RPD Qual
Sulfate mg/L 3.9
20.6 20.6 22.4
22.3 90 89 1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1430396 1430397
MS MSD
92243393001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfate mg/L 11.3 37.9 37.9 46.4 46.7 93 94 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/11/2015 07:56 AM without the written consent of Pace Analytical Services, Inc..
Page 83 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800Iirpyf�e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15030700
Pace Project No.: 92243096
QC Batch: WETA/22500
Analysis Method: EPA 353.2
QC Batch Method: EPA 353.2
Analysis Description: 353.2 Nitrate + Nitrite, Unpres.
Associated Lab Samples: 92243096001, 92243096002,
92243096003, 92243096004
METHOD BLANK: 1431018
Matrix: Water
Associated Lab Samples: 92243096001, 92243096002,
92243096003, 92243096004
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Nitrogen, Nitrate mg/L
0.11 0.020
04/09/15 19:03 Z2
LABORATORY CONTROL SAMPLE: 1431019
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Nitrogen, Nitrate mg/L
2.5 2.4
97 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1431020 1431021
MS MSD
92242504018
Spike Spike MS
MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec Limits RPD RPD Qual
Nitrogen, Nitrate mg/L ND
4 4 4.1
4.1 99 99 90-110 0 10 H1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1431022 1431023
MS MSD
92242504019 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Nitrogen, Nitrate mg/L ND 2.5 2.5 2.4 2.4 92 92 90-110 0 10 H1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/11/2015 07:56 AM without the written consent of Pace Analytical Services, Inc..
Page 84 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800girpyf�e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15030700
Pace Project No.: 92243096
QC Batch: WETA/22501
Analysis Method: EPA 353.2
QC Batch Method: EPA 353.2
Analysis Description: 353.2 Nitrate + Nitrite, Unpres.
Associated Lab Samples: 92243096005
METHOD BLANK: 1431026
Matrix: Water
Associated Lab Samples: 92243096005
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Nitrogen, Nitrate mg/L
0.16 0.020
04/09/15 19:46 Z2
LABORATORY CONTROL SAMPLE: 1431027
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Nitrogen, Nitrate mg/L
2.5 2.4
97 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1431028 1431029
MS MSD
92243245004
Spike Spike MS
MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec Limits RPD RPD Qual
Nitrogen, Nitrate mg/L ND
2.5 2.5 2.7
2.7 102 102 90-110 0 10 H1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1431030 1431031
MS MSD
92243245005 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Nitrogen, Nitrate mg/L ND 2.5 2.5 2.5 2.5 92 92 90-110 0 10 H1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/11/2015 07:56 AM without the written consent of Pace Analytical Services, Inc..
Page 85 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980M,pyf�e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15030700
Pace Project No.: 92243096
QC Batch: WETA/22478
Analysis Method: SM 4500-CI-E
QC Batch Method: SM 4500-CI-E
Analysis Description: 4500 Chloride
Associated Lab Samples: 92243096001
METHOD BLANK: 1428876
Matrix: Water
Associated Lab Samples: 92243096001
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Chloride mg/L
ND 1.0
04/08/15 02:24
LABORATORY CONTROL SAMPLE: 1428877
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Chloride mg/L
20 20.2
101 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1428878 1428879
MS MSD
92242504017
Spike Spike MS
MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec Limits RPD RPD Qual
Chloride mg/L ND
26.3 26.3 28.3
28.1 103 102 90-110 1 10
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1428880 1428881
MS MSD
92243093009 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Chloride mg/L ND 31.8 31.8 32.7 32.0 100 98 90-110 2 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/11/2015 07:56 AM without the written consent of Pace Analytical Services, Inc..
Page 86 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
98Qmirpyf�e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15030700
Pace Project No.: 92243096
QC Batch: WETA/22491
Analysis Method: SM 4500-CI-E
QC Batch Method: SM 4500-CI-E
Analysis Description: 4500 Chloride
Associated Lab Samples: 92243096002, 92243096003,
92243096004, 92243096005
METHOD BLANK: 1430197
Matrix: Water
Associated Lab Samples: 92243096002, 92243096003,
92243096004, 92243096005
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Chloride mg/L
ND 1.0
04/09/15 04:54
LABORATORY CONTROL SAMPLE: 1430198
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Chloride mg/L
20 21.2
106 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1430199 1430200
MS MSD
92243096002
Spike Spike MS
MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec Limits RPD RPD Qual
Chloride mg/L 3.9J
20.6 20.6 26.6
26.7 110 111 90-110 1 10 M1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1430201 1430202
MS MSD
92243393001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Chloride mg/L ND 37.9 37.9 40.2 39.6 102 101 90-110 1 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/11/2015 07:56 AM without the written consent of Pace Analytical Services, Inc..
Page 87 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
98"rpyf�e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15030700
Pace Project No.: 92243096
QC Batch: WETA/45049 Analysis Method: EPA 9056
QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions
Associated Lab Samples: 92243096001,92243096002,92243096003,92243096004,92243096005,92243096006,92243096007
METHOD BLANK: 1172374 Matrix: Solid
Associated Lab Samples:
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Chloride mg/kg ND 49.5 04/03/15 00:40
Sulfate mg/kg ND 49.5 04/03/15 00:40
LABORATORY CONTROL SAMPLE:
1172376
Parameter
Units
Chloride
mg/kg
Sulfate
mg/kg
MATRIX SPIKE SAMPLE:
1172378
Parameter
Units
Chloride
mg/kg
Sulfate
mg/kg
SAMPLE DUPLICATE: 1172377
Parameter
Chloride
Sulfate
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
497 524 105 80-120
497 513 103 80-120
92243245003 Spike MS MS % Rec
Result Conc. Result % Rec Limits Qualifiers
ND 1190 1010 77 80-120 MO
ND 1190 1040 88 80-120
92243245003 Dup
Units Result Result
mg/kg ND ND
mg/kg ND ND
Max
RPD RPD Qualifiers
20
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 05/11/2015 07:56 AM without the written consent of Pace Analytical Services, Inc.. Page 88 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980mrpyf�e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15030700
Pace Project No.: 92243096
QC Batch: WETA/45063
Analysis Method: EPA 9056
QC Batch Method: EPA 9056
Analysis Description: 9056 IC Anions
Associated Lab Samples: 92243096001,92243096002,92243096003,92243096004,92243096005,92243096006,92243096007
METHOD BLANK: 1172585
Matrix: Solid
Associated Lab Samples:
Blank Reporting
Parameter
Units
Result Limit Analyzed
Qualifiers
Nitrate as N
mg/kg
ND 5.0 04/03/15 00:40
LABORATORY CONTROL SAMPLE:
1172586
Spike LCS LCS
% Rec
Parameter
Units
Conc. Result % Rec
Limits Qualifiers
Nitrate as N
mg/kg
49.7 52.6 106
80-120
MATRIX SPIKE SAMPLE:
1172588
92243245003 Spike MS
MS % Rec
Parameter
Units
Result Conc. Result
% Rec Limits Qualifiers
Nitrate as N
mg/kg
ND 119 107
91 80-120 H3
SAMPLE DUPLICATE: 1172587
92243245003 Dup
Max
Parameter
Units
Result Result RPD
RPD Qualifiers
Nitrate as N
mg/kg
ND ND
20 H3
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/11/2015 07:56 AM without the written consent of Pace Analytical Services, Inc.. Page 89 of 97

aceAnaiXical
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Pace Analytical Services, Inc.
980�irpyf�e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15030700
Pace Project No.: 92243096
QC Batch: WETA/27952
Analysis Method: EPA 9060
QC Batch Method: EPA 9060
Analysis Description: 9060 TOC Average
Associated Lab Samples: 92243096001,92243096002,92243096003,92243096004,92243096005,92243096006,92243096007
METHOD BLANK: 1138851
Matrix: Solid
Associated Lab Samples:
Blank Reporting
Parameter Units
Result Limit Analyzed Qualifiers
Mean Total Organic Carbon mg/kg
ND 600 04/10/15 08:33
LABORATORY CONTROL SAMPLE: 1138852
Spike LCS LCS % Rec
Parameter Units
Conc. Result % Rec Limits Qualifiers
Mean Total Organic Carbon mg/kg
120000 123000 103 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1138853 1138854
MS MSD
92243088004
Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Mean Total Organic Carbon mg/kg 99900
88300 88000 192000 192000 104 104 50-150 0 30
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1138855 1138856
MS MSD
92243088005 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Mean Total Organic Carbon mg/kg 52500 88200 87200 135000 133000 93 92 50-150 1 30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/11/2015 07:56 AM without the written consent of Pace Analytical Services, Inc..
Page 90 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980mirpyf�e. Suite 100
Huntersville, NC 28078
[phone]
QUALIFIERS
Project: J15030700
Pace Project No.: 92243096
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
LABORATORIES
PASI-A
Pace Analytical Services - Asheville
PASI-G
Pace Analytical Services - Green Bay
PASI-M
Pace Analytical Services - Minneapolis
PASI-O
Pace Analytical Services - Ormond Beach
ANALYTE QUALIFIERS
B Analyte was detected in the associated method blank.
D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
D4 Sample was diluted due to the presence of high levels of target analytes.
D6 The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits.
H1 Analysis conducted outside the EPA method holding time.
H3 Sample was received or analysis requested beyond the recognized method holding time.
MO Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
N2 The lab does not hold TN accreditation for this parameter.
P8 Analyte was detected in the method blank. All associated samples had concentrations of at least ten times greater than
the blank or were below the reporting limit.
R1 RPD value was outside control limits.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
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aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980mirpyf�e. Suite 100
Huntersville, INC 28078
[phone]
QUALIFIERS
Project: J15030700
Pace Project No.: 92243096
ANALYTE QUALIFIERS
Z2 Analyte present in the associated method blank above the detection limit.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/11/2015 07:56 AM without the written consent of Pace Analytical Services, Inc.. Page 92 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
98"rpyf�e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
Pace Project No.:
J15030700
92243096
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92243096001
2015008683
EPA 3050
MPRP/23407
EPA 6010
ICP/14331
92243096002
2015008685
EPA 3050
MPRP/23407
EPA 6010
ICP/14331
92243096003
2015008689
EPA 3050
MPRP/23407
EPA 6010
ICP/14331
92243096004
2015008691
EPA 3050
MPRP/23407
EPA 6010
ICP/14331
92243096005
2015008692
EPA 3050
MPRP/23407
EPA 6010
ICP/14331
92243096006
2015008686
EPA 3050
MPRP/23414
EPA6010
ICP/14326
92243096007
2015008693
EPA 3050
MPRP/23414
EPA 6010
ICP/14326
92243096001
2015008683
EPA 3050
MPRP/23408
EPA 6020
ICPM/9542
92243096002
2015008685
EPA 3050
MPRP/23408
EPA 6020
ICPM/9542
92243096003
2015008689
EPA 3050
MPRP/23408
EPA 6020
ICPM/9542
92243096004
2015008691
EPA 3050
MPRP/23408
EPA 6020
ICPM/9542
92243096005
2015008692
EPA 3050
MPRP/23408
EPA 6020
ICPM/9542
92243096006
2015008686
EPA 3050
MPRP/23415
EPA 6020
ICPM/9535
92243096007
2015008693
EPA 3050
MPRP/23415
EPA 6020
ICPM/9535
92243096008
2015008683 SPLP
EPA 3020
MPRP/53956
EPA 6020A
ICPM/23977
92243096009
2015008685 SPLP
EPA 3020
MPRP/54015
EPA 6020A
ICPM/24021
92243096010
2015008689 SPLP
EPA 3020
MPRP/54015
EPA 6020A
ICPM/24021
92243096011
2015008691 SPLP
EPA 3020
MPRP/54015
EPA 6020A
ICPM/24021
92243096012
2015008692SPLP
EPA 3020
MPRP/54015
EPA 6020A
ICPM/24021
92243096013
2015008684
EPA 3020
MPRP/53294
EPA 6020A
ICPM/23639
92243096014
2015008687
EPA 3020
MPRP/53294
EPA 6020A
ICPM/23639
92243096015
2015008688
EPA 3020
MPRP/53294
EPA 6020A
ICPM/23639
92243096016
2015008690
EPA 3020
MPRP/53294
EPA 6020A
ICPM/23639
92243096013
2015008684
EPA 7470
MERP/13104
EPA 7470
MERC/15220
92243096014
2015008687
EPA 7470
MERP/13104
EPA 7470
MERC/15220
92243096015
2015008688
EPA 7470
MERP/13104
EPA 7470
MERC/15220
92243096016
2015008690
EPA 7470
MERP/13104
EPA 7470
MERC/15220
92243096008
2015008683 SPLP
EPA 7470A
MERP/13319
EPA 7470A
MERC/15488
92243096009
2015008685 SPLP
EPA 7470A
MERP/13319
EPA 7470A
MERC/15488
92243096010
2015008689 SPLP
EPA 7470A
MERP/13319
EPA 7470A
MERC/15488
92243096011
2015008691 SPLP
EPA 7470A
MERP/13319
EPA 7470A
MERC/15488
92243096012
2015008692 SPLP
EPA 7470A
MERP/13319
EPA 7470A
MERC/15488
92243096001
2015008683
EPA 7471
MERP/5551
EPA 7471
MERC/5539
92243096002
2015008685
EPA 7471
MERP/5551
EPA 7471
MERC/5539
92243096003
2015008689
EPA 7471
MERP/5551
EPA 7471
MERC/5539
92243096004
2015008691
EPA 7471
MERP/5551
EPA 7471
MERC/5539
92243096005
2015008692
EPA 7471
MERP/5551
EPA 7471
MERC/5539
92243096006
2015008686
EPA 7471
MERP/5552
EPA 7471
MERC/5540
92243096007
2015008693
EPA 7471
MERP/5552
EPA 7471
MERC/5540
92243096001
2015008683
ASTM D2974-87
PMST/3411
92243096002
2015008685
ASTM D2974-87
PMST/3411
92243096003
2015008689
ASTM D2974-87
PMST/3411
92243096004
2015008691
ASTM D2974-87
PMST/3411
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/11/2015 07:56 AM without the written consent of Pace Analytical Services, Inc.. Page 93 of 97

acmnalytical
www.pacelabs.com
Pace Analytical Services, Inc.
98"reybe. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: J15030700
Pace Project No.: 92243096
Lab ID Sample ID QC Batch Method QC Batch
92243096005
2015008692
ASTM D2974-87
PMST/3411
92243096006
2015008686
ASTM D2974-87
PMST/3411
92243096007
2015008693
ASTM D2974-87
PMST/3411
92243096001
2015008683
EPA 9045
WET/36525
92243096002
2015008685
EPA 9045
WET/36550
92243096003
2015008689
EPA 9045
WET/36581
92243096004
2015008691
EPA 9045
WET/36660
92243096005
2015008692
EPA 9045
WET/36660
92243096006
2015008686
EPA 9045
WET/36550
92243096007
2015008693
EPA 9045
WET/36660
92243096001
2015008683
EPA 300.0
WETA/22469
92243096002
2015008685
EPA 300.0
WETA/22495
92243096003
2015008689
EPA 300.0
WETA/22495
92243096004
2015008691
EPA 300.0
WETA/22495
92243096005
2015008692
EPA 300.0
WETA/22495
92243096001
2015008683
EPA 353.2
WETA/22500
92243096002
2015008685
EPA 353.2
WETA/22500
92243096003
2015008689
EPA 353.2
WETA/22500
92243096004
2015008691
EPA 353.2
WETA/22500
92243096005
2015008692
EPA 353.2
WETA/22501
92243096001
2015008683
SM 4500-CI-E
WETA/22478
92243096002
2015008685
SM 4500-CI-E
WETA/22491
92243096003
2015008689
SM 4500-CI-E
WETA/22491
92243096004
2015008691
SM 4500-CI-E
WETA/22491
92243096005
2015008692
SM 4500-CI-E
WETA/22491
92243096001
2015008683
EPA 9056
WETA/45049
92243096002
2015008685
EPA 9056
WETA/45049
92243096003
2015008689
EPA 9056
WETA/45049
92243096004
2015008691
EPA 9056
WETA/45049
92243096005
2015008692
EPA 9056
WETA/45049
92243096006
2015008686
EPA 9056
WETA/45049
92243096007
2015008693
EPA 9056
WETA/45049
92243096001
2015008683
EPA 9056
WETA/45063
92243096002
2015008685
EPA 9056
WETA/45063
92243096003
2015008689
EPA 9056
WETA/45063
92243096004
2015008691
EPA 9056
WETA/45063
92243096005
2015008692
EPA 9056
WETA/45063
92243096006
2015008686
EPA 9056
WETA/45063
92243096007
2015008693
EPA 9056
WETA/45063
92243096001
2015008683
EPA 9060
WETA/27952
92243096001
2015008683
EPA 9060
WETA/27953
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/11/2015 07:56 AM without the written consent of Pace Analytical Services, Inc..
Analytical
Analytical Method Batch
Page 94 of 97

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
98"rpyf�e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: J15030700
Pace Project No.: 92243096
Lab ID
Sample ID
QC Batch Method
QC Batch
92243096002
2015008685
EPA
9060
WETA/27952
92243096002
2015008685
EPA
9060
WETA/27953
92243096003
2015008689
EPA
9060
WETA/27952
92243096003
2015008689
EPA
9060
WETA/27953
92243096004
2015008691
EPA
9060
WETA/27952
92243096004
2015008691
EPA
9060
WETA/27953
92243096005
2015008692
EPA
9060
WETA/27952
92243096005
2015008692
EPA
9060
WETA/27953
92243096006
2015008686
EPA
9060
WETA/27952
92243096006
2015008686
EPA
9060
WETA/27953
92243096007
2015008693
EPA
9060
WETA/27952
92243096007
2015008693
EPA
9060
WETA/27953
Date: 05/11/2015 07:56 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Analytical Method
Analytical
Batch
Page 95 of 97

s.PlaceAnalytical° Sam le Condition Upon Recef t SCUR Pane 1 of 2
Document Number: Issuing Authority:
I F-CHR-CS-003-rev.15 Pace Huntersville Qualit i V
Client dame: /Vt
Courier: ❑ Fed Ex ❑ UPS❑ LISPS❑ Client❑ Co erciai❑ caccAther_I w
Custody Seal on CoolerlBox Present: ❑ es ❑ no Seals intact: ❑ yes El no
Packing Material: ❑ Bubble V❑Ip Bubble Bags ❑ None ❑ Other
Thermometer Used: IR Gun T1 Type of Ice: et ue None Samples on ice, cooling process has begun
Temp Correction Factor T1401 No Correction
on
Corrected Cooler Temp.: •C Biological Tissue is Frozen: Yes ri'"NI� contents: Date and InitialsPArson exmini
�m "
Temp should be above freezing to 6°C Comments:
Chain of Custody Present: es o ❑NIA 1.
Chain of Custody Filled Out: Yes o ❑NIA 2.
Chain of Custody Relinquished: es o ❑NIA 3.
Sampler Name & Signature on COC:
es ON -
❑NIA 4.
Samples Arrived within Hold Time:
❑ ❑No
IA 5.
Short Mold Time Analysis (a72hr):
Dyes 6No
PNIA 16.
Rush Turn Around Time Requested:
❑Yes o
❑NIA 7.
Sufficient Volume:
es
❑NIA $.
Correct Containers Used:
Wd's*"ONoNIA
9,
-Pace Containers Used:
❑Yes o
❑NIA
Containers Intact:
Yes ONO
❑N/A 1
Filtered volume received for Dissolved tests
❑Yes ❑
❑ IA 11.
Sample labels match COC:
❑ s ❑No
❑NIA 12.
-Includes dateltime/lD/Analysis Matrix:
All containers needing preservation have been checked.
No
❑NIA 13.
All containers needing preservation are found to be in
Zes IelNo
❑NIA
compliance with EPA recommendation.
exceptions: VOA, colirorm, TOC, 0&G, VJI-DRO (water) ❑Yes o
Samples checked for dechlorination: Dyes ❑No Nl 4.
11
Headspace in VOA Vials (?6mm): Dyes ONO 0 Nrk 15.
Trip Blank Present: Dyes ONO 'yfA 16.
Trip Blank Custody Seals Present Dyes ❑No El NIA
Pace Trip Blank Lot # (if purchased):
Client Notification/ Resolution: Field Data Required? Y ! N
Person Contacted: Date/Time:
Comments/ Resolution:
SCURF Review: ,Lt-t Date: I�{
SRF Review: I loate: 3 tax
Note: Whenever there is a discrepancy affecting North Carolina compliance
samples, a copy of this form will be sent to the North Carolina DEHNR
Certification Office (Le out of hold, incorrect preservative, out of temp,
incorrect containers)
WO#:92243096
1111111111111111111111
l�lll
Page 96 of 97

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Page 97 of 97

CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM
I fAnal Analyti"I Laborsto Use Only
Wad, Ord" roit, DU�KE 61.1k Code 41G03A2 jliluiiidlng 7413110 MAHN: 301L. S—p4.. nriU—king sc; a v H -
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NIM 420ba Or DW.. 6 1 1�
Vr ENERGY, (Noj �Zrr- `AMPLE FR03RAN cm,.�d W4".
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RCRA
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8MIek MC[BdR, $yfltftrF8 PO 114201
Kathy Webb, SYntenl -Fr,�7. 3-]RNCa
Chris Sutbal, Synterra --4v A-1cm A=nFle 6") LO L0 Lh
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41 Oparaing Unit:
Cno G NCCPSPM
M"r, "Wrific opelcounjing hm been eFLIablinhed dLVA ho " Indket4ad IMOVS
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