NC0003433_J15030153 Report_20150902

DUE Analytical Laboratory Page 1 of40
' ENERGY
Order Number:
Project Name:
Customer Name(s):
Customer Address:
Lab Contact:
Report Authorized By:
(Signature)
Program Comments:
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone:[phone] Fax:[phone]
Order Summary Report
J15030153
AB GW ASSESSMENT SOIL
Tim Hunsucker, Chris Suttell, Kathy Webb, John Toepfer
Margaret Galvin -Karr Phone: [phone]
ma -� ' eneryyycomn-karr@duke-
�`G` //���/ Date:
RV I 2015.04.03 12:38:40-04'00'
Margaret Galvin -Karr
Please contact the Program Manager (Margaret Galvin -Karr) with any questions regarding this report.
Data Flags & Calculations:
4/2/2015
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Sample ID's & Descriptions:
Page 2 of 40
Sample ID Plant/Station
2015006311 Cape Fear
2015006312 Cape Fear
2 Total Samples
Collection
Date and Time Collected By
03-Mar-15 11:45 AM
04-Mar-15 3:30 PM
John Chastain
John Chastain
Sample Description
MW-12BRSB (20-21)
ERB-03 Rotosonic

Page 3 of 40
Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals Yes No
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits. ❑ Yes No
All laboratory QA/QC requirements are acceptable. (] Yes ❑ No
Report Sections Included:
L� Job Summary Report
❑ Sample Identification
n Technical Validation of Data Package
6 Analytical Laboratory Certificate of Analysis
❑ Analytical Laboratory QC Report
LVI Sub -contracted Laboratory Results
❑ Customer Specific Data Sheets, Reports, & Documentation
❑ Customer Database Entries
6 Chain of Custody
LVI Electronic Data Deliverable (EDD) Sent Separately
Reviewed By: DBA Account Date: 4/2/2015

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15030153
Site: MW-12BRSB (20-21)
Collection Date: 03-Mar-15 11:45 AM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Page 4 of 40
Sample #: 2015006311
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis Page 5 of 40
This report shall not be reproduced, except in full.
Order # J15030153
Site: ERB-03 Rotosonic
Collection Date: 04-Mar-15 3:30 PM
Analyte Result Units Qualifiers RDL DF
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Sample #: 2015006312
Matrix: OTHER
Method Analysis Date/Time Analyst
Vendor Method V_PACE

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
%Q9'6c&Mde. Suite100
�Huntersville, INC 28078
[phone]
March 13, 2015
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg.7405 MG30A2
Huntersville, NC 28078
RE: Project: J 15030153
Pace Project No.: 92239984
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on March 05, 2015. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TN standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc: Marge Galvin -Karr, Duke Energy
Program Manager, Duke Energy
Rodney Wilke, Duke Energy
p«FO
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
lqe� ��� without the written consent of Pace Analytical Services, Inc..
BRAT,
Page 1 of 33

lacmnalyfica(
www.pacelabs.com
Pace Analytical Services, Inc.
G040cw4de. Suite 100
Huntersville, NC 28078
[phone]
Project: J15030153
Pace Project No.: 92239984
Minnesota Certification IDs
1700 Elm Street SE Suite 200, Minneapolis, MN 55414
A21-A Certification #: 2926.01
Alaska Certification #: UST-078
Alaska Certification #MN00064
Alabama Certification #40770
Arizona Certification #: AZ-0014
Arkansas Certification #: 88-0680
California Certification #: 01155CA
Colorado Certification #Pace
Connecticut Certification #: PH-0256
EPA Region 8 Certification #: 8TMS-L
Florida/NELAP Certification #: E87605
Guam Certification #:14-008r
Georgia Certification #: 959
Georgia EPD #: Pace
Idaho Certification #: MN00064
Hawaii Certification #MN00064
Illinois Certification #: 200011
Indiana Certification#C-MN-01
Iowa Certification #: 368
Kansas Certification #: E-10167
Kentucky Dept of Envi. Protection - DW #90062
Kentucky Dept of Envi. Protection - WW #:90062
Louisiana DEQ Certification #: 3086
Louisiana DHH #: LA140001
Maine Certification #: 2013011
Maryland Certification #: 322
Michigan DEPH Certification #: 9909
Ormond Beach Certification IDs
8 East Tower Circle, Ormond Beach, FL 32174
Alabama Certification #: 41320
Arizona Certification #: AZ0735
Connecticut Certification #: PH-0216
Delaware Certification: FL NELAC Reciprocity
Florida Certification #: E83079
Georgia Certification #: 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification #: 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383
Kentucky Certification #: 90050
Louisiana Certification #: FL NELAC Reciprocity
Louisiana Environmental Certificate #: 05007
Maryland Certification: #346
Massachusetts Certification #: M-FL1264
Michigan Certification #: 9911
Mississippi Certification: FL NELAC Reciprocity
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
CERTIFICATIONS
Minnesota Certification #: 027-053-137
Mississippi Certification #: Pace
Montana Certification #: MT0092
Nevada Certification #: MN_00064
Nebraska Certification #: Pace
New Jersey Certification #: MN-002
New York Certification #: 11647
North Carolina Certification #: 530
North Carolina State Public Health #: 27700
North Dakota Certification #: R-036
Ohio EPA#: 4150
Ohio VAP Certification #: CL101
Oklahoma Certification #: 9507
Oregon Certification #: MN200001
Oregon Certification #: MN300001
Pennsylvania Certification #: 68-00563
Puerto Rico Certification
Saipan (CNMI) #:MP0003
South Carolina #:74003001
Texas Certification #: T104704192
Tennessee Certification #: 02818
Utah Certification #: MN000642013-4
Virginia DGS Certification #: 251
Virginia/VELAP Certification #: Pace
Washington Certification #: C486
West Virginia Certification #: 382
West Virginia DHHR #:9952C
Wisconsin Certification #: 999407970
Missouri Certification #: 236
Montana Certification #: Cert 0074
Nebraska Certification: NE-OS-28-14
Nevada Certification: FL NELAC Reciprocity
New Hampshire Certification #: 2958
New Jersey Certification #: FL765
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FLO1264
South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
Washington Certification #: C955
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
West Virginia Certification #: 356
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 2 of 33

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
%Q9'9c&Mde. Suite100
�Huntersville, NC 28078
[phone]
SAMPLE SUMMARY
Project: J15030153
Pace Project No.: 92239984
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92239984001
92239984002
2015006311
2015006312
Solid
Water
03/03/1511:45
03/04/1515:30
03/05/1515:55
03/05/1515:55
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 3 of 33

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
%Q9'9c&Mde. Suite100
�Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
J15030153
92239984
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92239984001
2015006311
EPA 6010
CKJ
15
PASI-0
EPA 6020
CRT
9
PASI-O
EPA 7471
TAP
1
PASI-O
ASTM D2974-87
GPW
1
PASI-O
EPA 9045
MAB
1
PASI-A
EPA 9056
AIS
2
PASI-O
EPA 9056
AIS
1
PASI-O
92239984002
2015006312
EPA 6020A
TT3
24
PASI-M
EPA 7470
LMW
1
PASI-M
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 4 of 33

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
0980698Mde. Suite100
Huntersville, NC 28078
[phone]
Project: J15030153
Pace Project No.: 92239984
Lab Sample ID
Method
Client Sample ID
Parameters
92239984001
2015006311
EPA 6010
Aluminum
EPA 6010
Barium
EPA 6010
Calcium
EPA 6010
Chromium
EPA 6010
Copper
EPA 6010
Iron
EPA 6010
Magnesium
EPA 6010
Manganese
EPA 6010
Nickel
EPA 6010
Potassium
EPA 6010
Sodium
EPA 6010
Strontium
EPA 6010
Zinc
EPA 6020
Vanadium
ASTM D2974-87
Percent Moisture
EPA 9045
pH at 25 Degrees C
92239984002
2015006312
EPA 6020A
Aluminum
EPA 6020A
Barium
EPA 6020A
Calcium
EPA 6020A
Copper
EPA 6020A
Iron
EPA 6020A
Lead
EPA 6020A
Magnesium
EPA 6020A
Manganese
EPA 6020A
Sodium
SUMMARY OF DETECTION
Result
Units
Report Limit
Analyzed
Qualifiers
569
mg/kg
5.7
03/12/15 23:41
M1
6.0
mg/kg
0.57
03/12/15 23:41
162
mg/kg
28.3
03/12/15 23:41
1.4
mg/kg
0.28
03/12/15 23:41
0.82
mg/kg
0.28
03/12/15 23:41
719
mg/kg
2.3
03/12/15 23:41
M1,R1
122
mg/kg
28.3
03/12/15 23:41
12.3
mg/kg
0.28
03/12/15 23:41
M1,R1
0.56
mg/kg
0.28
03/12/15 23:41
50.9J
mg/kg
56.7
03/12/15 23:41
49.2J
mg/kg
56.7
03/12/15 23:41
1.8
mg/kg
0.57
03/12/15 23:41
1.9
mg/kg
1.1
03/12/15 23:41
5.1
mg/kg
2.8
03/13/1512:25
D3
11.1
%
0.10
03/12/1512:18
7.1
Std. Units
0.10
03/12/15 15:55
10.1
ug/L
10.0
03/10/15 08:26
0.31
ug/L
0.30
03/10/15 08:26
90.0
ug/L
40.0
03/10/15 08:26
1.1
ug/L
1.0
03/10/15 08:26
138
ug/L
50.0
03/10/15 08:26
0.13
ug/L
0.10
03/10/15 08:26
21.2
ug/L
10.0
03/10/15 08:26
4.0
ug/L
0.50
03/10/15 08:26
154
ug/L
50.0
03/10/15 08:26
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 5 of 33

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098Plinic&)r�e. Suite 100
y Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15030153
Pace Project No.: 92239984
Method: EPA 6010
Description: 6010 MET ICP
Client: Duke Energy
Date: March 13, 2015
General Information:
1 sample was analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 3050 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: MPRP/23033
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92239984001
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1153060)
• Aluminum
• Iron
• Manganese
• MSD (Lab ID: 1153061)
• Aluminum
• Iron
R1: RPD value was outside control limits.
• MSD (Lab ID: 1153061)
• Iron
• Manganese
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 6 of 33

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
0980298)de. Suite100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15030153
Pace Project No.: 92239984
Method: EPA 6020
Description: 6020 MET ICPMS
Client: Duke Energy
Date: March 13, 2015
General Information:
1 sample was analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 3050 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: MPRP/23034
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92239985004
M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
• MS (Lab ID: 1153074)
• Antimony
• Beryllium
• Cobalt
• Selenium
• Vanadium
• MSD (Lab ID: 1153075)
• Antimony
• Beryllium
• Selenium
• Vanadium
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 7 of 33

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
09Qy0S98MIde. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15030153
Pace Project No.: 92239984
Method: EPA 6020
Description: 6020 MET ICPMS
Client: Duke Energy
Date: March 13, 2015
Analyte Comments:
QC Batch: MPRP/23034
DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
•2015006311 (Lab ID:92239984001)
• Arsenic
• Beryllium
• Cadmium
• Cobalt
• Lead
• Antimony
• Selenium
• Thallium
• Vanadium
• MS (Lab ID: 1153074)
• Arsenic
• Beryllium
• Cadmium
• Cobalt
• Lead
• Antimony
• Selenium
• Thallium
• MSD (Lab ID: 1153075)
• Arsenic
• Beryllium
• Cadmium
• Cobalt
• Lead
• Antimony
• Selenium
• Thallium
D4: Sample was diluted due to the presence of high levels of target analytes.
• MS (Lab ID: 1153074)
• Vanadium
• MSD (Lab ID: 1153075)
• Vanadium
N2: The lab does not hold TNI accreditation for this parameter.
•2015006311 (Lab ID:92239984001)
• Antimony
• BLANK (Lab ID: 1153072)
• Antimony
• LCS (Lab ID: 1153073)
• Antimony
• MS (Lab ID: 1153074)
• Antimony
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 8 of 33

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098Pii4c&�r�e. Suite 100
y Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15030153
Pace Project No.: 92239984
Method: EPA 6020
Description: 6020 MET ICPMS
Client: Duke Energy
Date: March 13, 2015
Analyte Comments:
QC Batch: MPRP/23034
N2: The lab does not hold TNI accreditation for this parameter.
• MSD (Lab ID: 1153075)
• Antimony
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 9 of 33

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
0980998)de. Suite100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15030153
Pace Project No.: 92239984
Method: EPA 6020A
Description: 6020A MET ICPMS
Client: Duke Energy
Date: March 13, 2015
General Information:
1 sample was analyzed for EPA 6020A. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 3020 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 10 of 33

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
0980698)de. Suite100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15030153
Pace Project No.: 92239984
Method: EPA 7470
Description: 7470 Mercury
Client: Duke Energy
Date: March 13, 2015
General Information:
1 sample was analyzed for EPA 7470. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 7470 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 11 of 33

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098Pli9c&)r�e. Suite 100
y Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15030153
Pace Project No.: 92239984
Method: EPA 7471
Description: 7471 Mercury
Client: Duke Energy
Date: March 13, 2015
General Information:
1 sample was analyzed for EPA 7471. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 7471 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 12 of 33

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
0980998Mde. Suite100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15030153
Pace Project No.: 92239984
Method: EPA 9045
Description: 9045 pH Soil
Client: Duke Energy
Date: March 13, 2015
General Information:
1 sample was analyzed for EPA 9045. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc.. Page 13 of 33

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
098�ffli9c&)de. Suite100
y Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15030153
Pace Project No.: 92239984
Method: EPA 9056
Description: 9056 IC Anions
Client: Duke Energy
Date: March 13, 2015
General Information:
1 sample was analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc.. Page 14 of 33

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PROJECT NARRATIVE
Project: J15030153
Pace Project No.: 92239984
Method: EPA 9056
Description: 9056 IC Anions 48hr
Client: Duke Energy
Date: March 13, 2015
General Information:
1 sample was analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
1-13: Sample was received or analysis requested beyond the recognized method holding time.
•2015006311 (Lab ID:92239984001)
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 15 of 33

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ANALYTICAL RESULTS
Project: J15030153
Pace Project No.: 92239984
Sample: 2015006311
Lab ID:
92239984001 Collected:
03/03/15 11:45
Received: 03/05/15 15:55 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample
size and any dilutions.
Report
Parameters
Results
Units Limit
MDL
DF
Prepared
Analyzed
CAS No.
Qual
6010 MET ICP
Analytical
Method: EPA 6010
Preparation
Method: EPA 3050
Aluminum
569
mg/kg
5.7
2.8
1
03/11/15 18:24
03/12/15 23:41
7429-90-5
M1
Barium
6.0
mg/kg
0.57
0.28
1
03/11/15 18:24
03/12/15 23:41
7440-39-3
Boron
ND
mg/kg
2.8
1.4
1
03/11/15 18:24
03/12/15 23:41
7440-42-8
Calcium
162
mg/kg
28.3
14.2
1
03/11/15 18:24
03/12/15 23:41
7440-70-2
Chromium
1.4
mg/kg
0.28
0.14
1
03/11/15 18:24
03/12/15 23:41
7440-47-3
Copper
0.82
mg/kg
0.28
0.14
1
03/11/15 18:24
03/12/15 23:41
7440-50-8
Iron
719
mg/kg
2.3
1.1
1
03/11/15 18:24
03/12/15 23:41
7439-89-6
M1,R1
Magnesium
122
mg/kg
28.3
14.2
1
03/11/15 18:24
03/12/15 23:41
7439-95-4
Manganese
12.3
mg/kg
0.28
0.14
1
03/11/15 18:24
03/12/15 23:41
7439-96-5
M1,R1
Molybdenum
ND
mg/kg
0.57
0.28
1
03/11/15 18:24
03/12/15 23:41
7439-98-7
Nickel
0.56
mg/kg
0.28
0.14
1
03/11/15 18:24
03/12/15 23:41
7440-02-0
Potassium
50.9J
mg/kg
56.7
28.3
1
03/11/15 18:24
03/12/15 23:41
7440-09-7
Sodium
49.2J
mg/kg
56.7
28.3
1
03/11/15 18:24
03/12/15 23:41
7440-23-5
Strontium
1.8
mg/kg
0.57
0.28
1
03/11/15 18:24
03/12/15 23:41
7440-24-6
Zinc
1.9
mg/kg
1.1
0.57
1
03/11/15 18:24
03/12/15 23:41
7440-66-6
6020 MET ICPMS
Analytical
Method: EPA 6020
Preparation
Method: EPA 3050
Antimony
ND
mg/kg
2.8
1.4
50
03/11/15 18:24
03/13/1512:25
7440-36-0
D3,N2
Arsenic
ND
mg/kg
2.8
1.4
50
03/11/15 18:24
03/13/1512:25
7440-38-2
D3
Beryllium
ND
mg/kg
0.34
0.17
50
03/11/15 18:24
03/13/1512:25
7440-41-7
D3
Cadmium
ND
mg/kg
0.34
0.17
50
03/11/15 18:24
03/13/1512:25
7440-43-9
D3
Cobalt
ND
mg/kg
2.8
1.4
50
03/11/15 18:24
03/13/1512:25
7440-48-4
D3
Lead
ND
mg/kg
2.8
1.4
50
03/11/15 18:24
03/13/1512:25
7439-92-1
D3
Selenium
ND
mg/kg
2.8
1.4
50
03/11/15 18:24
03/13/1512:25
7782-49-2
D3
Thallium
ND
mg/kg
2.8
1.4
50
03/11/15 18:24
03/13/1512:25
7440-28-0
D3
Vanadium
5.1
mg/kg
2.8
1.4
50
03/11/15 18:24
03/13/1512:25
7440-62-2
D3
7471 Mercury
Analytical
Method: EPA 7471
Preparation
Method: EPA 7471
Mercury
ND
mg/kg 0.0087
0.0044
1
03/11/1514:40
03/12/1513:57
7439-97-6
Percent Moisture
Analytical
Method: ASTM D2974-87
Percent Moisture
11.1
%
0.10
0.10
1
03/12/15 12:18
9045 pH Soil
Analytical
Method: EPA 9045
pH at 25 Degrees C
7.1
Std. Units
0.10
0.10
1
03/12/15 15:55
9056 IC Anions
Analytical
Method: EPA 9056
Chloride
ND
mg/kg
286
143
5
03/10/15 08:35
16887-00-6
Sulfate
ND
mg/kg
286
143
5
03/10/15 08:35
14808-79-8
9056 IC Anions 48hr
Analytical
Method: EPA 9056
Nitrate as N
ND
mg/kg
28.6
14.3
5
03/10/15 08:35
14797-55-8
H3
Date: 03/13/2015 04:31 PM
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: J15030153
Pace Project No.: 92239984
Sample: 2015006312 Lab ID: 92239984002 Collected: 03/04/15 15:30 Received: 03/05/15 15:55 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
;I➢ZI7c\��,I=11a
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Sodium
Strontium
Thallium
Vanadium
Zinc
7470 Mercury
Mercury
Date: 03/13/2015 04:31 PM
Analytical Method: EPA 6020A Preparation Method: EPA 3020
10.1
ug/L
10.0
1.2
1
03/09/15 15:03
03/10/15 08:26
7429-90-5
ND
ug/L
0.50
0.25
1
03/09/15 15:03
03/10/15 08:26
7440-36-0
ND
ug/L
0.50
0.25
1
03/09/15 15:03
03/10/15 08:26
7440-38-2
0.31
ug/L
0.30
0.14
1
03/09/15 15:03
03/10/15 08:26
7440-39-3
ND
ug/L
0.20
0.066
1
03/09/15 15:03
03/10/15 08:26
7440-41-7
ND
ug/L
5.0
1.0
1
03/09/15 15:03
03/10/15 08:26
7440-42-8
ND
ug/L
0.080
0.033
1
03/09/15 15:03
03/10/15 08:26
7440-43-9
90.0
ug/L
40.0
8.4
1
03/09/15 15:03
03/10/15 08:26
7440-70-2
ND
ug/L
0.50
0.22
1
03/09/15 15:03
03/10/15 08:26
7440-47-3
ND
ug/L
0.50
0.25
1
03/09/15 15:03
03/10/15 08:26
7440-48-4
1.1
ug/L
1.0
0.22
1
03/09/15 15:03
03/10/15 08:26
7440-50-8
138
ug/L
50.0
8.0
1
03/09/15 15:03
03/10/15 08:26
7439-89-6
0.13
ug/L
0.10
0.046
1
03/09/15 15:03
03/10/15 08:26
7439-92-1
21.2
ug/L
10.0
2.8
1
03/09/15 15:03
03/10/15 08:26
7439-95-4
4.0
ug/L
0.50
0.14
1
03/09/15 15:03
03/10/15 08:26
7439-96-5
ND
ug/L
0.50
0.24
1
03/09/15 15:03
03/10/15 08:26
7439-98-7
ND
ug/L
0.50
0.23
1
03/09/15 15:03
03/10/15 08:26
7440-02-0
ND
ug/L
50.0
8.3
1
03/09/15 15:03
03/10/15 08:26
7440-09-7
ND
ug/L
0.50
0.25
1
03/09/15 15:03
03/10/15 08:26
7782-49-2
154
ug/L
50.0
18.2
1
03/09/15 15:03
03/10/15 08:26
7440-23-5
ND
ug/L
0.50
0.057
1
03/09/15 15:03
03/10/15 08:26
7440-24-6
ND
ug/L
0.10
0.025
1
03/09/15 15:03
03/10/15 08:26
7440-28-0
ND
ug/L
1.0
0.21
1
03/09/15 15:03
03/10/15 08:26
7440-62-2
ND
ug/L
5.0
2.5
1
03/09/15 15:03
03/10/15 08:26
7440-66-6
Analytical Method: EPA 7470 Preparation Method: EPA 7470
ND ug/L 0.20 0.026 1 03/09/1517:05 03/10/1516:16 7439-97-6
REPORT OF LABORATORY ANALYSIS
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Page 17 of 33

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QUALITY CONTROL DATA
Project: J15030153
Pace Project No.: 92239984
QC Batch: MERP/12928 Analysis Method: EPA 7470
QC Batch Method: EPA 7470 Analysis Description: 7470 Mercury
Associated Lab Samples: 92239984002
METHOD BLANK: 1914231 Matrix: Water
Associated Lab Samples: 92239984002
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Mercury ug/L ND 0.20 03/10/1515:55
LABORATORY CONTROL SAMPLE: 1914232
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Mercury ug/L 5 4.6 91 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1914233 1914234
MS MSD
92239543001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Mercury ug/L ND 5 5 4.7 4.7 94 94 75-125 1 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 03/13/2015 04:31 PM without the written consent of Pace Analytical Services, Inc..
Page 18 of 33

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QUALITY CONTROL DATA
Project: J15030153
Pace Project No.: 92239984
QC Batch: MERP/5460
Analysis Method: EPA 7471
QC Batch Method: EPA 7471
Analysis Description: 7471 Mercury
Associated Lab Samples: 92239984001
METHOD BLANK: 1152887
Matrix: Solid
Associated Lab Samples: 92239984001
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Mercury
mg/kg
ND 0.0080
03/12/1513:27
LABORATORY CONTROL SAMPLE: 1152888
Spike LCS
LCS % Rec
Parameter
Units
Conc. Result
% Rec Limits Qualifiers
Mercury
mg/kg
.08 0.075
94 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1152889 1152890
MS MSD
35177233002
Spike Spike MS
MSD MS MSD % Rec Max
Parameter Units
Result
Conc. Conc. Result
Result % Rec % Rec Limits RPD RPD Qual
Mercury mg/kg
0.0048U
.0994 .0982 0.097
0.085 94 84 80-120 13 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 03/13/2015 04:31 PM without the written consent of Pace Analytical Services, Inc..
Page 19 of 33

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[phone]
QUALITY CONTROL DATA
Project: J15030153
Pace Project No.: 92239984
QC Batch: MPRP/23033 Analysis Method: EPA 6010
QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid
Associated Lab Samples: 92239984001
METHOD BLANK: 1153058
Associated Lab Samples: 92239984001
Parameter
Units
Matrix:
Blank
Result
Solid
Reporting
Limit
Analyzed
Aluminum
mg/kg
ND
5.0
03/12/15 23:28
Barium
mg/kg
ND
0.50
03/12/15 23:28
Boron
mg/kg
ND
2.5
03/12/15 23:28
Calcium
mg/kg
ND
25.2
03/12/15 23:28
Chromium
mg/kg
ND
0.25
03/12/15 23:28
Copper
mg/kg
ND
0.25
03/12/15 23:28
Iron
mg/kg
ND
2.0
03/12/15 23:28
Magnesium
mg/kg
ND
25.2
03/12/15 23:28
Manganese
mg/kg
ND
0.25
03/12/15 23:28
Molybdenum
mg/kg
ND
0.50
03/12/15 23:28
Nickel
mg/kg
ND
0.25
03/12/15 23:28
Potassium
mg/kg
ND
50.4
03/12/15 23:28
Sodium
mg/kg
ND
50.4
03/12/15 23:28
Strontium
mg/kg
ND
0.50
03/12/15 23:28
Zinc
mg/kg
ND
1.0
03/12/15 23:28
Qualifiers
LABORATORY CONTROL SAMPLE:
Parameter
1153059
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
Aluminum
mg/kg
127
128
101
80-120
Barium
mg/kg
12.7
13.3
105
80-120
Boron
mg/kg
127
127
100
80-120
Calcium
mg/kg
633
643
102
80-120
Chromium
mg/kg
12.7
13.1
103
80-120
Copper
mg/kg
12.7
12.7
100
80-120
Iron
mg/kg
127
124
98
80-120
Magnesium
mg/kg
633
641
101
80-120
Manganese
mg/kg
12.7
12.7
100
80-120
Molybdenum
mg/kg
12.7
12.9
102
80-120
Nickel
mg/kg
12.7
13.3
105
80-120
Potassium
mg/kg
633
645
102
80-120
Sodium
mg/kg
633
658
104
80-120
Strontium
mg/kg
12.7
12.4
98
80-120
Zinc
mg/kg
63.3
65.9
104
80-120
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/13/2015 04:31 PM without the written consent of Pace Analytical Services, Inc..
Page 20 of 33

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QUALITY CONTROL DATA
Project: J15030153
Pace Project No.: 92239984
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
1153060
1153061
MS
MSD
92239984001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Aluminum
mg/kg
569
138
139
1430
1270
627
505
75-125
12
20 M1
Barium
mg/kg
6.0
13.8
13.9
22.1
20.7
116
105
75-125
6
20
Boron
mg/kg
ND
138
139
139
135
100
95
75-125
3
20
Calcium
mg/kg
162
690
699
950
937
114
111
75-125
1
20
Chromium
mg/kg
1.4
13.8
13.9
15.6
15.3
103
99
75-125
2
20
Copper
mg/kg
0.82
13.8
13.9
14.4
14.1
99
95
75-125
2
20
Iron
mg/kg
719
138
139
1140
913
308
138
75-125
23
20 M1,R1
Magnesium
mg/kg
122
690
699
934
830
118
101
75-125
12
20
Manganese
mg/kg
12.3
13.8
13.9
32.6
26.2
147
100
75-125
22
20 M1,R1
Molybdenum
mg/kg
ND
13.8
13.9
12.8
13.1
93
93
75-125
2
20
Nickel
mg/kg
0.56
13.8
13.9
14.7
14.8
103
102
75-125
0
20
Potassium
mg/kg
50.9J
690
699
772
741
104
99
75-125
4
20
Sodium
mg/kg
49.2J
690
699
773
745
105
100
75-125
4
20
Strontium
mg/kg
1.8
13.8
13.9
17.3
16.5
112
105
75-125
5
20
Zinc
mg/kg
1.9
69
69.9
72.2
71.3
102
99
75-125
1
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/13/2015 04:31 PM without the written consent of Pace Analytical Services, Inc..
Page 21 of 33

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Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15030153
Pace Project No.: 92239984
QC Batch: MPRP/23034 Analysis Method: EPA 6020
QC Batch Method: EPA 3050 Analysis Description: 6020 MET SOLID
Associated Lab Samples: 92239984001
METHOD BLANK: 1153072
Matrix:
Solid
Associated Lab Samples: 92239984001
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Antimony
mg/kg
ND
0.050
03/13/1512:18 N2
Arsenic
mg/kg
ND
0.050
03/13/1512:18
Beryllium
mg/kg
ND
0.0060
03/13/1512:18
Cadmium
mg/kg
ND
0.0060
03/13/1512:18
Cobalt
mg/kg
ND
0.050
03/13/1512:18
Lead
mg/kg
ND
0.050
03/13/1512:18
Selenium
mg/kg
ND
0.050
03/13/1512:18
Thallium
mg/kg
ND
0.050
03/13/1512:18
Vanadium
mg/kg
ND
0.050
03/13/1512:18
LABORATORY CONTROL SAMPLE:
Parameter
1153073
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
Antimony
mg/kg
2.6
2.6
100
80-120 N2
Arsenic
mg/kg
2.6
2.6
102
80-120
Beryllium
mg/kg
.26
0.28
110
80-120
Cadmium
mg/kg
.26
0.25
99
80-120
Cobalt
mg/kg
2.6
2.7
104
80-120
Lead
mg/kg
2.6
2.6
102
80-120
Selenium
mg/kg
2.6
2.7
106
80-120
Thallium
mg/kg
2.6
2.6
101
80-120
Vanadium
mg/kg
2.6
2.6
99
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1153074
MS
92239985004 Spike
Parameter Units Result Conc.
MSD
Spike
Conc.
1153075
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
Max
RPD RPD Qual
Antimony
mg/kg
ND
2.99
2.99
1.5J
1.51
24
24
75-125
20 D3,M6,
N2
Arsenic
mg/kg
ND
2.99
2.99
4.1
3.9
94
87
75-125
7
20 D3
Beryllium
mg/kg
0.26J
.299
.299
0.67
0.67
137
141
75-125
1
20 D3,M6
Cadmium
mg/kg
ND
.299
.299
0.41
0.36
122
108
75-125
13
20 D3
Cobalt
mg/kg
8.8
2.99
2.99
13.8
11.8
163
101
75-125
15
20 D3,M6
Lead
mg/kg
2.6J
2.99
2.99
5.7
5.5
102
98
75-125
4
20 D3
Selenium
mg/kg
ND
2.99
2.99
3.4
3.4
73
72
75-125
2
20 D3,M6
Thallium
mg/kg
ND
2.99
2.99
3.3
3.1
99
96
75-125
5
20 D3
Vanadium
mg/kg
45.9
2.99
2.99
54.8
52.2
296
213
75-125
5
20 D4,M6
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/13/2015 04:31 PM without the written consent of Pace Analytical Services, Inc..
Page 22 of 33

aceAnaiXical
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Pace Analytical Services, Inc.
09899898Mde. Suite100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15030153
Pace Project No.: 92239984
QC Batch: MPRP/52837 Analysis Method: EPA 6020A
QC Batch Method: EPA 3020 Analysis Description: 6020A Water UPD4
Associated Lab Samples: 92239984002
METHOD BLANK: 1914175
Associated Lab Samples: 92239984002
Parameter
Units
Aluminum
ug/L
Antimony
ug/L
Arsenic
ug/L
Barium
ug/L
Beryllium
ug/L
Boron
ug/L
Cadmium
ug/L
Calcium
ug/L
Chromium
ug/L
Cobalt
ug/L
Copper
ug/L
Iron
ug/L
Lead
ug/L
Magnesium
ug/L
Manganese
ug/L
Molybdenum
ug/L
Nickel
ug/L
Potassium
ug/L
Selenium
ug/L
Sodium
ug/L
Strontium
ug/L
Thallium
ug/L
Vanadium
ug/L
Zinc
ug/L
Matrix: Water
Blank
Result
Reporting
Limit
Analyzed
ND
10.0
03/10/15 07:50
ND
0.50
03/10/15 07:50
ND
0.50
03/10/15 07:50
ND
0.30
03/10/15 07:50
ND
0.20
03/10/15 07:50
ND
5.0
03/10/15 07:50
ND
0.080
03/10/15 07:50
ND
40.0
03/10/15 07:50
ND
0.50
03/10/15 07:50
ND
0.50
03/10/15 07:50
ND
1.0
03/10/15 07:50
ND
50.0
03/10/15 07:50
ND
0.10
03/10/15 07:50
ND
10.0
03/10/15 07:50
ND
0.50
03/10/15 07:50
ND
0.50
03/10/15 07:50
ND
0.50
03/10/15 07:50
ND
50.0
03/10/15 07:50
ND
0.50
03/10/15 07:50
ND
50.0
03/10/15 07:50
ND
0.50
03/10/15 07:50
ND
0.10
03/10/15 07:50
ND
1.0
03/10/15 07:50
ND
5.0
03/10/15 07:50
Qualifiers
LABORATORY CONTROL SAMPLE:
Parameter
1914176
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
Aluminum
ug/L
80
86.3
108
80-120
Antimony
ug/L
80
85.1
106
80-120
Arsenic
ug/L
80
84.9
106
80-120
Barium
ug/L
80
83.6
104
80-120
Beryllium
ug/L
80
85.6
107
80-120
Boron
ug/L
80
86.0
107
80-120
Cadmium
ug/L
80
87.1
109
80-120
Calcium
ug/L
1000
1070
107
80-120
Chromium
ug/L
80
87.8
110
80-120
Cobalt
ug/L
80
87.9
110
80-120
Copper
ug/L
80
90.4
113
80-120
Iron
ug/L
1000
1100
110
80-120
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/13/2015 04:31 PM without the written consent of Pace Analytical Services, Inc..
Page 23 of 33

aceAnaiXical
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Pace Analytical Services, Inc.
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�J Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15030153
Pace Project No.: 92239984
LABORATORY CONTROL SAMPLE:
1914176
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits
Qualifiers
Lead
ug/L
80
87.6
110
80-120
Magnesium
ug/L
1000
1090
109
80-120
Manganese
ug/L
80
87.1
109
80-120
Molybdenum
ug/L
80
85.2
107
80-120
Nickel
ug/L
80
88.7
111
80-120
Potassium
ug/L
1000
1050
105
80-120
Selenium
ug/L
80
84.3
105
80-120
Sodium
ug/L
1000
1090
109
80-120
Strontium
ug/L
80
84.1
105
80-120
Thallium
ug/L
80
88.8
111
80-120
Vanadium
ug/L
80
85.9
107
80-120
Zinc
ug/L
80
87.3
109
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
1914177
1914178
MS
MSD
92239543001
Spike
Spike
MS
MSD
MS MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec % Rec
Limits
RPD
RPD Qual
Aluminum
ug/L
37.6
80
80
126
126
111
111
75-125
0
20
Antimony
ug/L
ND
80
80
84.5
80.8
105
101
75-125
4
20
Arsenic
ug/L
ND
80
80
85.0
82.7
106
103
75-125
3
20
Barium
ug/L
1.0
80
80
83.2
81.7
103
101
75-125
2
20
Beryllium
ug/L
ND
80
80
84.4
84.1
106
105
75-125
0
20
Boron
ug/L
ND
80
80
87.1
88.9
108
110
75-125
2
20
Cadmium
ug/L
ND
80
80
87.3
85.3
109
107
75-125
2
20
Calcium
ug/L
529
1000
1000
1580
1590
105
106
75-125
1
20
Chromium
ug/L
0.50
80
80
87.8
86.0
109
107
75-125
2
20
Cobalt
ug/L
ND
80
80
84.8
82.9
106
104
75-125
2
20
Copper
ug/L
ND
80
80
90.9
89.3
112
110
75-125
2
20
Iron
ug/L
117
1000
1000
1220
1190
110
108
75-125
2
20
Lead
ug/L
0.20
80
80
86.9
84.0
108
105
75-125
3
20
Magnesium
ug/L
25.0
1000
1000
1120
1100
110
107
75-125
2
20
Manganese
ug/L
3.0
80
80
89.8
88.4
109
107
75-125
2
20
Molybdenum
ug/L
2.0
80
80
85.7
83.9
105
102
75-125
2
20
Nickel
ug/L
0.61
80
80
88.9
87.5
110
109
75-125
2
20
Potassium
ug/L
79.1
1000
1000
1110
1090
103
101
75-125
2
20
Selenium
ug/L
ND
80
80
83.9
83.6
105
104
75-125
0
20
Sodium
ug/L
ND
1000
1000
1110
1080
107
104
75-125
3
20
Strontium
ug/L
0.90
80
80
84.5
82.9
105
103
75-125
2
20
Thallium
ug/L
ND
80
80
86.5
83.3
108
104
75-125
4
20
Vanadium
ug/L
ND
80
80
84.5
83.1
105
104
75-125
2
20
Zinc
ug/L
ND
80
80
87.9
90.4
105
108
75-125
3
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 03/13/2015 04:31 PM without the written consent of Pace Analytical Services, Inc..
Page 24 of 33

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
0989%98Mde. Suite100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15030153
Pace Project No.: 92239984
QC Batch: PMST/3334
Analysis Method:
ASTM D2974-87
QC Batch Method: ASTM D2974-87
Analysis Description:
Dry Weight/Percent Moisture
Associated Lab Samples: 92239984001
SAMPLE DUPLICATE: 1154364
35178521001
Dup
Max
Parameter
Units
Result
Result RPD
RPD Qualifiers
Percent Moisture
%
19.6
19.7 1
10
SAMPLE DUPLICATE: 1154365
35178455003
Dup
Max
Parameter
Units
Result
Result RPD
RPD Qualifiers
Percent Moisture
%
26.0
27.9 7
10
SAMPLE DUPLICATE: 1154366
35178455013
Dup
Max
Parameter
Units
Result
Result RPD
RPD Qualifiers
Percent Moisture
%
11.8
11.3 4
10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
0989K3inl98f46e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15030153
Pace Project No.: 92239984
QC Batch: WET/36142 Analysis Method: EPA 9045
QC Batch Method: EPA 9045 Analysis Description: 9045 pH
Associated Lab Samples: 92239984001
SAMPLE DUPLICATE: 1407673
Parameter
pH at 25 Degrees C
SAMPLE DUPLICATE: 1407674
Parameter
pH at 25 Degrees C
92240170008 Dup Max
Units Result Result RPD RPD Qualifiers
Std. Units 5.9 5.7 3 10
92240158003 Dup Max
Units Result Result RPD RPD Qualifiers
Std. Units 6.0 6.1 1 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 03/13/2015 04:31 PM without the written consent of Pace Analytical Services, Inc.. Page 26 of 33

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
0989ISQ-Wde. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15030153
Pace Project No.: 92239984
QC Batch: WETA/44361 Analysis Method: EPA 9056
QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions
Associated Lab Samples: 92239984001
METHOD BLANK: 1150712 Matrix: Solid
Associated Lab Samples:
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Chloride mg/kg ND 49.4 03/09/15 22:58
Sulfate mg/kg ND 49.4 03/09/15 22:58
LABORATORY CONTROL SAMPLE:
1150713
Parameter
Units
Chloride
mg/kg
Sulfate
mg/kg
MATRIX SPIKE SAMPLE:
1150715
Parameter
Units
Chloride
mg/kg
Sulfate
mg/kg
SAMPLE DUPLICATE: 1150714
Parameter
Chloride
Sulfate
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
495 509 103 80-120
495 502 101 80-120
92239543005 Spike MS MS % Rec
Result Conc. Result % Rec Limits Qualifiers
ND 662 563 68 80-120 M 1
ND 662 741 96 80-120
92239543005 Dup
Units Result Result
mg/kg ND ND
mg/kg ND ND
Max
RPD RPD Qualifiers
20
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 03/13/2015 04:31 PM without the written consent of Pace Analytical Services, Inc.. Page 27 of 33

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
0989ISS-Wde. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J15030153
Pace Project No.: 92239984
QC Batch: WETA/44360
Analysis Method:
EPA 9056
QC Batch Method: EPA 9056
Analysis Description:
9056 IC Anions
Associated Lab Samples: 92239984001
METHOD BLANK: 1150708
Matrix: Solid
Associated Lab Samples:
Blank Reporting
Parameter
Units
Result Limit
Analyzed
Qualifiers
Nitrate as N
mg/kg
ND 4.9
03/09/15 22:58
LABORATORY CONTROL SAMPLE:
1150709
Spike LCS
LCS
% Rec
Parameter
Units
Conc. Result
% Rec
Limits
Qualifiers
Nitrate as N
mg/kg
49.5 51.1
103
80-120
MATRIX SPIKE SAMPLE:
1150711
92239543005 Spike
MS
MS
% Rec
Parameter
Units
Result Conc.
Result
% Rec
Limits Qualifiers
Nitrate as N
mg/kg
ND 66.2
58.8
84 80-120 H3
SAMPLE DUPLICATE: 1150710
92239543005 Dup
Max
Parameter
Units
Result Result
RPD
RPD
Qualifiers
Nitrate as N
mg/kg
ND ND
20 H3
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 03/13/2015 04:31 PM without the written consent of Pace Analytical Services, Inc.. Page 28 of 33

Pace Analytical Services, Inc
aceAnalXical ® � ��tr�4c&rr�e. Suite100
Huntersville, NC 28078078
www.pacelabs.com [phone]
QUALIFIERS
Project: J15030153
Pace Project No.: 92239984
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
LABORATORIES
PASI-A Pace Analytical Services - Asheville
PASI-M Pace Analytical Services - Minneapolis
PASI-O Pace Analytical Services - Ormond Beach
ANALYTE QUALIFIERS
D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
D4 Sample was diluted due to the presence of high levels of target analytes.
H3 Sample was received or analysis requested beyond the recognized method holding time.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
N2 The lab does not hold TN accreditation for this parameter.
R1 RPD value was outside control limits.
REPORT OF LABORATORY ANALYSIS
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Date: 03/13/2015 04:31 PM without the written consent of Pace Analytical Services, Inc.. Page 29 of 33

aceAnaiXical
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Pace Analytical Services, Inc.
0989%98Mde. Suite100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: J15030153
Pace Project No.: 92239984
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
92239984001
2015006311
EPA 3050
MPRP/23033
EPA 6010
92239984001
2015006311
EPA 3050
MPRP/23034
EPA 6020
92239984002
2015006312
EPA 3020
MPRP/52837
EPA 6020A
92239984002
2015006312
EPA 7470
MERP/12928
EPA 7470
92239984001
2015006311
EPA 7471
MERP/5460
EPA 7471
92239984001
2015006311
ASTM D2974-87
PMST/3334
92239984001
2015006311
EPA 9045
WET/36142
92239984001
2015006311
EPA 9056
WETA/44361
92239984001
2015006311
EPA 9056
WETA/44360
Date: 03/13/2015 04:31 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Analytical
Batch
ICP/14087
ICPM/9393
ICPM/23421
MERC/15006
MERC/5450
Page 30 of 33

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Page 33 of 33

_ _ _ CHAIN OF CUSTOD_Y_RECORD AND _ _ANALYSIS REQUEST F_O__R_M Page 39 of 40
DUKE e4nalytical Laboratory Services i i Anal ical Laborato Use Onl j
j i work Order 1 Page 1 of Mail Code MG03A2 (Building 7405) NC x
1333
I i Matdz: SOIL Samples Originating sc_ OH_ ! DISTRIBUTION
9 Hagers Ferry Rd s�
ENERGY., N Huntersville, N.C. 28078 i iLoggedBy Debi From ORIGINAL to LAB,
[phone] i i ,(\f./�_ �2 �/ /.� J SAMPLE PROGRAM Ground Water_ j COPY to CLIENT
Fax: [phone] w/ �J J / NPDES Other j
............ _ _�_.Z._._. _._._._. _._._.J �%
PACE ���. — —
x REV DATE 1/23/2015
Cooler Tem C
PO 1142081
1)Project Name AB GW Assessment -Soil 2)Phone No: Plant
Cape Fear RCRA
7)client
John Toepfer, Duke
4)Fax No:
Mark McDade, Synterra
Kathy Webb, Synterra
Chris Suttel, Synterra
5)Business Unit:
s)Project ID: ACLCP1402
)Mail Code:
e) Operating Unit-
9)ActivRy 10:
10)Prmess ID
CP00
G
NCCPSPM
i�Q>?)�)u: When specific accounting has been established and
is not indicated abo•
e need the folio,: ng:
1) Enter correct accounting in all 5 accounting
fields above, Or
2+ Provide correct accounttn for Operating Unit and Process ID.
F.._.._.._.._..-1
j LAB USE ONLY j
! !
Lab
' ID
t
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Matrix
(s°il,sedimem,Ash)
13Sam le Description or
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21)Relinquishetl Daternme
2015-o3 -,0'
(Relinquished By _ Date?ime
12
Metals: Al, Sb, As, Ba, Be, B, Cd, Ca, Cr, Co, Cu, Fe, Pb, Mg, Mn,
I 4=Ice
"proonate areas.
Preservatives when used must be
added within 15 minutes of sample
collection
14CT011ection Information
I
Date Time - Sldnature
By:
Na,
C I,
5=None
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DateMme
22Requested Turnaround
pate ime
14 Days _ _x
Days _.
ae Hr
ime
Qj1drime
5 /<t;V z

CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM _
Duke Energy
Duke Energy Analytical Laboratory
Analytical Laboratory
Mail Cone 9 7405)
I Chain of Custody &
He" Ferry(Build
aggro Ferry Rd
Huldersville, N. C. 2a07a
Sample Log
(7041 e75,5245
__
_ _ ......
_ _ _ _ _ Fax: 704 e75S03B I
Project Name AB GW Assessment water
Phone No:
Client o%eHt! 7b6PPelzL KAiW,- ALzW
Fax No:
980-875-503�
109Aek ^,PADd CHIC/$ 5W07725L
Business Unit:
Process:
Reap. Center To:
Project 10:
Activity ID:
Mau Code:
MG03A3
Waterbody:
Stauon: —d
Py
By
Analytical Laborato Use Only
I !Order Matrix GW_WW NC i
I I /�• �'� /� Samples Orlpirutirp Fran SC_ 1
!L
ogged
SAMPLE PROGRAMGround WaterNPDESDrinking Water UST
RCRA WasteCooler Tam _ C p-'-- -'--'-._L . -.. .._ _..............................- ' - - - -
PO 1142081 :iltration (0.45 um) Unfiltered
Preservative Ice Ice Ice '° .
H2Ical Ice 304 "°e"'"°°"i
Container Volume (mL) 2000 40 rill 300 125 500 Soo
Container Type PET glass PET PET PET PET
(a
CCt
as
Sample Description or ID
P P
Customer to complete all appropriate
non -shaded areas.
to
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Collection Information
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GPS Location
Date
Time
Signature
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3 —03 NO
/- Soo,„!
Filter Blank
1 I 2 I 1 I 1
Date/Time
RDiS• 03-oif 17,00
Date/Time lAccepted By�1
ELEMENTS by ICP_MS (TRM): As, Be, Cd, Co, Cr, CuTMo, Ni, Pb, Sb, SGVTI (I o (LL)
ELEMENTS by ICP (TRM): At, Be, B, Fe, Mn, Sr, Zn ICP Undigested Ca, Mg, K, Na Hg by 245.1
Dissolved metals: all metals ICP, IMS,Hg
ap
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Page 40 of 40
Page � of
DISTRIBUTION
ORIGINAL to LAB, COPY to CLIENT
)lraA a
d filtered
M
I I I 1
Requested Turnaround
*14 Days
7 Days
•48Hr
`Other _ASAP
Add. Cost Will Apply
250
HOPE
a
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0
0
0
0
0
0
0
0
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1
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0
1
6
Total if1 I
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