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Home My WebLink AboutNC0003433_J15020654 Report_20150902DUE Analytical Laboratory Page 1of66 ' ENERGY Order Number: Project Name: Customer Name(s): Customer Address: Lab Contact: Report Authorized By: (Signature) Program Comments: 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone:980-875-5245 Fax:980-875-4349 Order Summary Report J15020654 AB GW ASSESSMENT SOIL Tim Hunsucker, Chris Suttell, Kathy Webb, John Toepfer Margaret Galvin -Karr Phone: 980-875-5219 v marge.galvin-karr@duke- i�.. �,� _ u energy.com —OGY, 2015.03.27 14:22:18 -04'00' Date. Margaret Galvin -Karr Please contact the Program Manager (Margaret Galvin -Karr) with any questions regarding this report. Data Flags & Calculations: 3/27/2015 Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Sample ID's & Descriptions: Sample ID Plant/Station Collection Date and Time Collected By Page 2 of 66 Sample Description 2015005344 Cape Fear 24-Feb-15 9:55 AM Synterra MW-12 BRSB (0-2) 2015005345 Cape Fear 24-Feb-15 10:10 AM Synterra MW-12 BRSB (11-12) 2015005346 Cape Fear 24-Feb-15 11:40 AM Synterra MW-12 BRSB (17-18) 2015005347 Cape Fear 23-Feb-15 2:20 PM Synterra Equipment Blank ERB-2(Rotosonic) 4 Total Samples Page 3 of 66 Technical Validation Review Checklist: COC and .pdf report are in agreement with sample totals Yes No and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. ❑ Yes No All laboratory QA/QC requirements are acceptable. (] Yes ❑ No Report Sections Included: L� Job Summary Report ❑ Sample Identification n Technical Validation of Data Package 6 Analytical Laboratory Certificate of Analysis ❑ Analytical Laboratory QC Report LVI Sub -contracted Laboratory Results ❑ Customer Specific Data Sheets, Reports, & Documentation ❑ Customer Database Entries 6 Chain of Custody LVI Electronic Data Deliverable (EDD) Sent Separately Reviewed By: DBA Account Date: 3/27/2015 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15020654 Site: MW-12 BRSB (0-2) Collection Date: 24-Feb-15 9:55 AM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 4 of 66 Sample #: 2015005344 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15020654 Site: MW-12 BRSB (11-12) Collection Date: 24-Feb-15 10:10 AM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 5 of 66 Sample #: 2015005345 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15020654 Site: MW-12 BRSB (17-18) Collection Date: 24-Feb-15 11:40 AM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 6 of 66 Sample #: 2015005346 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15020654 Site: Equipment Blank ERB-2(Rotosonic) Collection Date: 23-Feb-15 2:20 PM Analyte Result Units Qualifiers RDL DF METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Sample #: 2015005347 Matrix: SOIL Page 7 of 66 Method Analysis Date/Time Analyst Vendor Method V_PACE aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9P2Q.�C8,8y&ie. Suite 100 �Huntersville, INC 28078 (704)875-9092 March 18, 2015 Program Manager Duke Energy 13339 Hagers Ferry Road Bldg.7405 MG30A2 Huntersville, NC 28078 RE: Project: J 15020654 Pace Project No.: 92238878 Dear Program Manager: Enclosed are the analytical results for sample(s) received by the laboratory on February 25, 2015. The results relate only to the samples included in this report. Results reported herein conform to the most current TN standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Herring kevin.herring@pacelabs.com HORIZON Database Administrator Enclosures cc: Marge Galvin -Karr, Duke Energy Program Manager, Duke Energy Rodney Wilke, Duke Energy p«FO REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, lqe� �� without the written consent of Pace Analytical Services, Inc.. BRAT, Page 1 of 57 lacmnalyfica( www.pacelabs.com Pace Analytical Services, Inc. G09?I6i§c&&re. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15020654 Pace Project No.: 92238878 Minnesota Certification IDs 1700 Elm Street SE Suite 200, Minneapolis, MN 55414 A21-A Certification #: 2926.01 Alaska Certification #: UST-078 Alaska Certification #MN00064 Alabama Certification #40770 Arizona Certification #: AZ-0014 Arkansas Certification #: 88-0680 California Certification #: 01155CA Colorado Certification #Pace Connecticut Certification #: PH-0256 EPA Region 8 Certification #: 8TMS-L Florida/NELAP Certification #: E87605 Guam Certification #:14-008r Georgia Certification #: 959 Georgia EPD #: Pace Idaho Certification #: MN00064 Hawaii Certification #MN00064 Illinois Certification #: 200011 Indiana Certification#C-MN-01 Iowa Certification #: 368 Kansas Certification #: E-10167 Kentucky Dept of Envi. Protection - DW #90062 Kentucky Dept of Envi. Protection - WW #:90062 Louisiana DEQ Certification #: 3086 Louisiana DHH #: LA140001 Maine Certification #: 2013011 Maryland Certification #: 322 Michigan DEPH Certification #: 9909 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification #: 41320 Arizona Certification #: AZ0735 Connecticut Certification #: PH-0216 Delaware Certification: FL NELAC Reciprocity Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Massachusetts Certification #: M-FL1264 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Green Bay Certification IDs 1241 Bellevue Street, Green Bay, WI 54302 Florida/NELAP Certification #: E87948 Illinois Certification #: 200050 Kentucky Certification #: 82 Louisiana Certification #: 04168 Minnesota Certification #: 055-999-334 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 CERTIFICATIONS Minnesota Certification #: 027-053-137 Mississippi Certification #: Pace Montana Certification #: MT0092 Nevada Certification #: MN_00064 Nebraska Certification #: Pace New Jersey Certification #: MN-002 New York Certification #: 11647 North Carolina Certification #: 530 North Carolina State Public Health #: 27700 North Dakota Certification #: R-036 Ohio EPA#: 4150 Ohio VAP Certification #: CL101 Oklahoma Certification #: 9507 Oregon Certification #: MN200001 Oregon Certification #: MN300001 Pennsylvania Certification #: 68-00563 Puerto Rico Certification Saipan (CNMI) #:MP0003 South Carolina #:74003001 Texas Certification #: T104704192 Tennessee Certification #: 02818 Utah Certification #: MN000642013-4 Virginia DGS Certification #: 251 Virginia/VELAP Certification #: Pace Washington Certification #: C486 West Virginia Certification #: 382 West Virginia DHHR #:9952C Wisconsin Certification #: 999407970 Missouri Certification #: 236 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 Nevada Certification: FL NELAC Reciprocity New Hampshire Certification #: 2958 New Jersey Certification #: FL765 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FLO1264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 Washington Certification #: C955 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity North Dakota Certification #: R-150 South Carolina Certification #: 83006001 Texas Certification #: T104704529-14-1 US Dept of Agriculture #: S-76505 Wisconsin Certification #: 405132750 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 2 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 0g8pli6'8y&e. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15020654 Pace Project No.: 92238878 Asheville Certification IDs North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 CERTIFICATIONS West Virginia Certification #: 356 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 3 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. �Q�ff�in�c&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: J15020654 Pace Project No.: 92238878 Lab ID Sample ID Matrix Date Collected Date Received 92238878001 2015005344 Solid 02/24/15 09:55 02/25/15 16:35 92238878002 2015005346 Solid 02/24/1511:40 02/25/15 16:35 92238878003 2015005345 Solid 02/24/1510:10 02/25/15 16:35 92238878004 2015005345 SPLP Water 02/24/15 10:10 02/25/15 16:35 92238878005 2015005347 Water 02/24/1514:20 02/25/15 16:35 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 4 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. �Q�ffli�c&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: J15020654 92238878 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92238878001 2015005344 EPA 6010 CKJ 15 PASI-0 EPA 6020 CRT, DRS 9 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 GPW 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 9056 CMB 2 PASI-O EPA 9056 CMB 1 PASI-O EPA 9060 TJJ 6 PASI-G 92238878002 2015005346 EPA 6010 CKJ 15 PASI-0 EPA 6020 CRT 9 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 GPW 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 9056 CMB 2 PASI-O EPA 9056 CMB 1 PASI-O EPA 9060 TJJ 6 PASI-G 92238878003 2015005345 EPA 6010 CKJ 15 PASI-0 EPA 6020 CRT 9 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 GPW 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 300.0 AES2 1 PASI-A EPA 353.2 DMN 1 PASI-A SM 4500-CI-E SER 1 PASI-A EPA 9056 CMB 2 PASI-O EPA 9056 CMB 1 PASI-O EPA 9060 TJJ 6 PASI-G 92238878004 2015005345 SPLP EPA 6020A TT3 24 PASI-M EPA 7470 JDD 1 PASI-M 92238878005 2015005347 EPA 6010 IP 14 PASI-M EPA 6020A TT3 10 PASI-M EPA 7470 LMW 1 PASI-M REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 5 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. �Q�ffli�c&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15020654 Pace Project No.: 92238878 Lab Sample ID Client Sample ID Method Parameters SUMMARY OF DETECTION Result Units Report Limit Analyzed 92238878001 2015005344 EPA 6010 Aluminum 6230 mg/kg 5.8 03/04/15 19:46 EPA 6010 Barium 77.8 mg/kg 0.58 03/04/15 19:46 EPA 6010 Boron 7.8 mg/kg 2.9 03/04/15 19:46 EPA 6010 Cadmium 0.092 mg/kg 0.058 03/04/15 19:46 EPA 6010 Chromium 9.4 mg/kg 0.29 03/04/15 19:46 EPA 6010 Copper 8.4 mg/kg 0.29 03/04/15 19:46 EPA 6010 Iron 13500 mg/kg 23.1 03/05/15 09:33 D4 EPA 6010 Magnesium 1520 mg/kg 28.9 03/04/15 19:46 EPA 6010 Manganese 1510 mg/kg 2.9 03/05/15 09:33 D4 EPA 6010 Nickel 4.2 mg/kg 0.29 03/04/15 19:46 EPA 6010 Potassium 68.0 mg/kg 57.8 03/04/15 19:46 EPA 6010 Sodium 79.2 mg/kg 57.8 03/04/15 19:46 EPA 6010 Strontium 14.0 mg/kg 0.58 03/04/15 19:46 EPA 6010 Zinc 19.3 mg/kg 1.2 03/04/15 19:46 EPA 6020 Arsenic 0.82J mg/kg 1.2 03/04/15 16:51 D3 EPA 6020 Beryllium 0.47 mg/kg 0.14 03/04/15 16:51 D3 EPA 6020 Cobalt 13.2 mg/kg 1.2 03/05/15 18:33 D3 EPA 6020 Lead 8.7 mg/kg 1.2 03/04/15 16:51 D3 EPA 6020 Selenium 1.1 J mg/kg 1.2 03/04/15 16:51 D3 EPA 6020 Vanadium 30.9 mg/kg 1.2 03/04/15 16:51 D4 EPA 7471 Mercury 0.032 mg/kg 0.0093 03/04/15 13:04 ASTM D2974-87 Percent Moisture 17.3 % 0.10 03/09/15 09:51 EPA 9045 pH at 25 Degrees C 5.7 Std. Units 0.10 03/02/15 12:05 EPA 9060 Total Organic Carbon 2840 mg/kg 732 03/05/15 16:20 EPA 9060 Total Organic Carbon 1970 mg/kg 719 03/05/15 16:25 EPA 9060 Total Organic Carbon 1670 mg/kg 729 03/05/15 16:31 EPA 9060 Total Organic Carbon 2060 mg/kg 726 03/05/15 16:36 EPA 9060 Mean Total Organic Carbon 2140 mg/kg 727 03/05/15 16:20 EPA 9060 RSD% 23.2 % 03/05/15 16:20 92238878002 2015005346 EPA 6010 Aluminum 669 mg/kg 5.8 03/05/15 09:37 EPA 6010 Barium 7.5 mg/kg 0.58 03/05/15 09:37 EPA 6010 Boron 2.1 J mg/kg 2.9 03/05/15 09:37 EPA 6010 Chromium 2.3 mg/kg 0.29 03/05/15 09:37 EPA 6010 Copper 0.92 mg/kg 0.29 03/05/15 09:37 EPA 6010 Iron 2590 mg/kg 2.3 03/05/15 09:37 EPA 6010 Magnesium 150 mg/kg 29.1 03/05/15 09:37 EPA 6010 Manganese 24.0 mg/kg 0.29 03/05/15 09:37 EPA 6010 Nickel 0.83 mg/kg 0.29 03/05/15 09:37 EPA 6010 Potassium 45.2J mg/kg 58.1 03/05/15 09:37 EPA 6010 Sodium 48AJ mg/kg 58.1 03/05/15 09:37 EPA 6010 Strontium 2.1 mg/kg 0.58 03/05/15 09:37 EPA 6010 Zinc 3.3 mg/kg 1.2 03/05/15 09:37 EPA 6020 Arsenic 0.77J mg/kg 1.2 03/04/15 17:05 D3 EPA 6020 Beryllium 0.14J mg/kg 0.14 03/04/15 17:05 D3 EPA 6020 Cobalt 1.4 mg/kg 1.2 03/04/15 17:05 D3 EPA 6020 Lead 1.2 mg/kg 1.2 03/04/15 17:05 D3 REPORT OF LABORATORY ANALYSIS Qualifiers This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 6 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. �Q�fflic&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15020654 Pace Project No.: 92238878 Lab Sample ID Client Sample ID Method Parameters SUMMARY OF DETECTION Result Units Report Limit Analyzed Qualifiers 92238878002 2015005346 EPA 6020 Vanadium 5.7 mg/kg 1.2 03/04/15 17:05 D3 ASTM D2974-87 Percent Moisture 12.3 % 0.10 03/09/15 09:52 EPA 9045 pH at 25 Degrees C 7.3 Std. Units 0.10 03/02/15 12:05 EPA 9060 RSD% 2.5 % 03/05/15 17:38 92238878003 2015005345 EPA 6010 Aluminum 6310 mg/kg 6.3 03/05/15 09:42 EPA 6010 Barium 95.6 mg/kg 0.63 03/05/15 09:42 EPA 6010 Boron 8.8 mg/kg 3.2 03/05/15 09:42 EPA 6010 Cadmium 0.13 mg/kg 0.063 03/04/15 19:54 EPA 6010 Chromium 10.3 mg/kg 0.32 03/05/15 09:42 EPA 6010 Copper 10.4 mg/kg 0.32 03/05/15 09:42 EPA 6010 Iron 13500 mg/kg 2.5 03/05/15 09:42 EPA 6010 Magnesium 2340 mg/kg 31.7 03/05/15 09:42 EPA 6010 Manganese 163 mg/kg 0.32 03/05/15 09:42 EPA 6010 Nickel 6.3 mg/kg 0.32 03/05/15 09:42 EPA 6010 Potassium 255 mg/kg 63.5 03/05/15 09:42 EPA 6010 Sodium 403 mg/kg 63.5 03/05/15 09:42 EPA 6010 Strontium 14.1 mg/kg 0.63 03/05/15 09:42 EPA 6010 Zinc 22.9 mg/kg 1.3 03/05/15 09:42 EPA 6020 Arsenic 1.7 mg/kg 1.3 03/04/15 17:08 D3 EPA 6020 Beryllium 0.43 mg/kg 0.15 03/04/15 17:08 D3 EPA 6020 Cobalt 6.6 mg/kg 1.3 03/04/15 17:08 D3 EPA 6020 Lead 7.6 mg/kg 1.3 03/04/15 17:08 D3 EPA 6020 Selenium 0.87J mg/kg 1.3 03/04/15 17:08 D3 EPA 6020 Vanadium 34.2 mg/kg 1.3 03/04/15 17:08 D4 EPA 7471 Mercury 0.020 mg/kg 0.0095 03/04/15 13:08 ASTM D2974-87 Percent Moisture 19.6 % 0.10 03/09/15 09:52 EPA 9045 pH at 25 Degrees C 7.8 Std. Units 0.10 03/02/15 12:05 EPA 300.0 Sulfate 9.5 mg/L 2.5 03/08/15 03:06 EPA353.2 Nitrogen, Nitrate 0.45 mg/L 0.25 03/11/15 12:59 H1 SM 4500-CI-E Chloride 8.6 mg/L 6.2 03/10/15 03:52 EPA 9060 Total Organic Carbon 624J mg/kg 744 03/05/15 18:01 EPA 9060 Total Organic Carbon 684J mg/kg 740 03/05/15 18:07 EPA 9060 Total Organic Carbon 609J mg/kg 746 03/05/15 18:12 EPA 9060 Total Organic Carbon 700J mg/kg 743 03/05/15 18:18 EPA 9060 Mean Total Organic Carbon 654J mg/kg 743 03/05/15 18:01 EPA 9060 RSD% 6.8 % 03/05/15 18:01 92238878004 2015005345 SPLP EPA 6020A Aluminum 9630 ug/L 10.0 03/12/15 15:19 EPA 6020A Arsenic 3.0 ug/L 0.50 03/12/15 15:19 EPA 6020A Barium 666 ug/L 1.5 03/12/15 16:15 EPA 6020A Beryllium 3.0 ug/L 0.20 03/12/15 15:19 EPA 6020A Boron 11.4 ug/L 5.0 03/12/15 15:19 EPA 6020A Cadmium 0.089 ug/L 0.080 03/12/15 15:19 EPA 6020A Calcium 13300 ug/L 40.0 03/12/15 15:19 EPA 6020A Chromium 8.0 ug/L 0.50 03/12/15 15:19 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 7 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. �Q�ffii�c&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Project: J15020654 Pace Project No.: 92238878 Lab Sample ID Client Sample ID Method Parameters Result 92238878004 2015005345 SPLP EPA 6020A Cobalt 13.5 EPA 6020A Copper 25.5 EPA 6020A Iron 8290 EPA 6020A Lead 27.7 EPA 6020A Magnesium 10800 EPA 6020A Manganese 560 EPA 6020A Nickel 11.7 EPA 6020A Potassium 204 EPA 6020A Selenium 1.2 EPA 6020A Sodium 11000 EPA 6020A Strontium 153 EPA 6020A Vanadium 154 EPA 6020A Zinc 39.3 EPA 7470 Mercury 0.60 92238878005 2015005347 EPA 6010 Calcium 2370 EPA 6010 Iron 2170 EPA 6010 Manganese 74.0 EPA 6010 Sodium 8960 EPA 6020A Lead 0.94 EPA 6020A Strontium 4.8 Units Report Limit Analyzed Qualifiers ug/L 0.50 03/12/1515:19 ug/L 1.0 03/12/1515:19 ug/L 50.0 03/12/1515:19 ug/L 0.10 03/12/1515:19 ug/L 10.0 03/12/1515:19 ug/L 2.5 03/12/1516:15 ug/L 0.50 03/12/1515:19 ug/L 50.0 03/12/1515:19 ug/L 0.50 03/12/1515:19 ug/L 50.0 03/12/1515:19 ug/L 0.50 03/12/1515:19 ug/L 1.0 03/12/1515:19 ug/L 5.0 03/12/1515:19 ug/L 0.60 03/17/1511:10 ug/L 500 03/02/1518:19 ug/L 50.0 03/02/1518:19 ug/L 5.0 03/02/1518:19 ug/L 1000 03/02/1518:19 ug/L 0.10 03/03/1514:27 ug/L 0.50 03/03/1514:27 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 8 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. �Q�ffli�c&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020654 Pace Project No.: 92238878 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: March 18, 2015 General Information: 4 samples were analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3010 with any exceptions noted below. The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/22893 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92238879001 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • MS (Lab ID: 1144537) • Aluminum • Barium • Chromium • Copper • Iron • Magnesium • Manganese • Molybdenum • Potassium • MSD (Lab ID: 1144538) • Aluminum • Barium • Cadmium • Chromium • Copper REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 9 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. �Q�ff�ic&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020654 Pace Project No.: 92238878 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: March 18, 2015 QC Batch: MPRP/22893 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92238879001 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • Iron • Magnesium • Manganese • Molybdenum • Potassium Additional Comments: Analyte Comments: QC Batch: MPRP/22893 D4: Sample was diluted due to the presence of high levels of target analytes. •2015005344 (Lab ID:92238878001) • Iron • Manganese REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 10 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. �Q�ffligc&)e. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020654 Pace Project No.: 92238878 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: March 18, 2015 General Information: 3 samples were analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/22894 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92238666007 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • MS (Lab ID: 1144541) • Antimony • Arsenic • Selenium • MSD (Lab ID: 1144542) • Antimony • Arsenic • Lead • Vanadium Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 11 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. �Q�ffli�c&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020654 Pace Project No.: 92238878 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: March 18, 2015 Analyte Comments: QC Batch: MPRP/22894 DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015005344 (Lab ID:92238878001) • Arsenic • Beryllium • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium •2015005345 (Lab ID:92238878003) • Arsenic • Beryllium • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium •2015005346 (Lab ID:92238878002) • Arsenic • Beryllium • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium • Vanadium • MS (Lab ID: 1144541) • Beryllium • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium • MSD (Lab ID: 1144542) • Beryllium • Cadmium • Cobalt • Lead • Antimony • Selenium REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 12 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g%c8w. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020654 Pace Project No.: 92238878 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: March 18, 2015 Analyte Comments: QC Batch: MPRP/22894 DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. • MSD (Lab ID: 1144542) • Thallium D4: Sample was diluted due to the presence of high levels of target analytes. •2015005344 (Lab ID:92238878001) • Vanadium •2015005345 (Lab ID:92238878003) • Vanadium • MS (Lab ID: 1144541) • Arsenic • Vanadium • MSD (Lab ID: 1144542) • Arsenic • Vanadium N2: The lab does not hold TNI accreditation for this parameter. •2015005344 (Lab ID:92238878001) • Antimony •2015005345 (Lab ID:92238878003) • Antimony •2015005346 (Lab ID:92238878002) • Antimony • BLANK (Lab ID: 1144539) • Antimony • LCS (Lab ID: 1144540) • Antimony • MS (Lab ID: 1144541) • Antimony • MSD (Lab ID: 1144542) • Antimony REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 13 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098gKinic& &e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020654 Pace Project No.: 92238878 Method: EPA 6020A Description: 6020A MET ICPMS Client: Duke Energy Date: March 18, 2015 General Information: 2 samples were analyzed for EPA 6020A. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3020 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/52897 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92239540010 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MSD (Lab ID: 1916666) • Aluminum Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 14 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098gKiny&e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020654 Pace Project No.: 92238878 Method: EPA 7470 Description: 7470 Mercury Client: Duke Energy Date: March 18, 2015 General Information: 2 samples were analyzed for EPA 7470. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7470 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 15 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098gKiny&e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020654 Pace Project No.: 92238878 Method: EPA 7471 Description: 7471 Mercury Client: Duke Energy Date: March 18, 2015 General Information: 3 samples were analyzed for EPA 7471. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7471 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MERP/5420 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 35176987001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1144517) • Mercury R1: RPD value was outside control limits. • MSD (Lab ID: 1144518) • Mercury Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 16 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098gK4-8y&e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020654 Pace Project No.: 92238878 Method: EPA 9045 Description: 9045 pH Soil Client: Duke Energy Date: March 18, 2015 General Information: 3 samples were analyzed for EPA 9045. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Duplicate Sample: All duplicate sample results were within method acceptance criteria with any exceptions noted below. QC Batch: WET/35950 D6: The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits. • DUP (Lab ID: 1400248) • pH at 25 Degrees C Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 17 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g%c& &e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020654 Pace Project No.: 92238878 Method: EPA 300.0 Description: 300.0 IC Anions, SPLP Client: Duke Energy Date: March 18, 2015 General Information: 1 sample was analyzed for EPA 300.0. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 18 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 09Q�K�i�c& &e. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020654 Pace Project No.: 92238878 Method: EPA 353.2 Description: 353.2 Nitrogen, NO2/NO3, SPLP Client: Duke Energy Date: March 18, 2015 General Information: 1 sample was analyzed for EPA 353.2. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 1-11: Analysis conducted outside the EPA method holding time. •2015005345 (Lab ID:92238878003) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 19 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098v�%Y&e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020654 Pace Project No.: 92238878 Method: SM 4500-CI-E Description: 4500 Chloride, SPLP Client: Duke Energy Date: March 18, 2015 General Information: 1 sample was analyzed for SM 4500-CI-E. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 20 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g igc&w. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020654 Pace Project No.: 92238878 Method: EPA 9056 Description: 9056 IC Anions Client: Duke Energy Date: March 18, 2015 General Information: 3 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/44073 DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015005344 (Lab ID:92238878001) • Chloride • Sulfate •2015005345 (Lab ID:92238878003) • Chloride • Sulfate •2015005346 (Lab ID:92238878002) • Chloride • Sulfate REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 21 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 09Qgtr��c&)r�ie. Suite 100 �yJ Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020654 Pace Project No.: 92238878 Method: EPA 9056 Description: 9056 IC Anions 48hr Client: Duke Energy Date: March 18, 2015 General Information: 3 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 113: Sample was received or analysis requested beyond the recognized method holding time. •2015005344 (Lab ID:92238878001) •2015005345 (Lab ID:92238878003) •2015005346 (Lab ID:92238878002) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/44074 DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015005344 (Lab ID:92238878001) • Nitrate as N •2015005345 (Lab ID:92238878003) • Nitrate as N •2015005346 (Lab ID:92238878002) • Nitrate as N REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 22 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098ni�c y&e. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020654 Pace Project No.: 92238878 Method: EPA 9060 Description: Total Organic Carbon Quad Client: Duke Energy Date: March 18, 2015 General Information: 3 samples were analyzed for EPA 9060. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: This data package has been reviewed for quality and completeness and is approved for release. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 23 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098ninic& &e. Suite 100 y Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15020654 Pace Project No.: 92238878 Sample: 2015005344 Lab ID: 92238878001 Collected: 02/24/15 09:55 Received: 02/25/15 16:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 6230 mg/kg 5.8 2.9 1 03/04/15 05:30 03/04/15 19:46 7429-90-5 Barium 77.8 mg/kg 0.58 0.29 1 03/04/15 05:30 03/04/15 19:46 7440-39-3 Boron 7.8 mg/kg 2.9 1.4 1 03/04/15 05:30 03/04/15 19:46 7440-42-8 Cadmium 0.092 mg/kg 0.058 0.029 1 03/04/15 05:30 03/04/15 19:46 7440-43-9 Chromium 9.4 mg/kg 0.29 0.14 1 03/04/15 05:30 03/04/15 19:46 7440-47-3 Copper 8.4 mg/kg 0.29 0.14 1 03/04/15 05:30 03/04/15 19:46 7440-50-8 Iron 13500 mg/kg 23.1 11.6 10 03/04/15 05:30 03/05/15 09:33 7439-89-6 D4 Magnesium 1520 mg/kg 28.9 14.4 1 03/04/15 05:30 03/04/15 19:46 7439-95-4 Manganese 1510 mg/kg 2.9 1.4 10 03/04/15 05:30 03/05/15 09:33 7439-96-5 D4 Molybdenum ND mg/kg 0.58 0.29 1 03/04/15 05:30 03/04/15 19:46 7439-98-7 Nickel 4.2 mg/kg 0.29 0.14 1 03/04/15 05:30 03/04/15 19:46 7440-02-0 Potassium 68.0 mg/kg 57.8 28.9 1 03/04/15 05:30 03/04/15 19:46 7440-09-7 Sodium 79.2 mg/kg 57.8 28.9 1 03/04/15 05:30 03/04/15 19:46 7440-23-5 Strontium 14.0 mg/kg 0.58 0.29 1 03/04/15 05:30 03/04/15 19:46 7440-24-6 Zinc 19.3 mg/kg 1.2 0.58 1 03/04/15 05:30 03/04/15 19:46 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 1.2 0.58 20 03/04/15 05:30 03/04/15 16:51 7440-36-0 D3,N2 Arsenic 0.82J mg/kg 1.2 0.58 20 03/04/15 05:30 03/04/15 16:51 7440-38-2 D3 Beryllium 0.47 mg/kg 0.14 0.069 20 03/04/15 05:30 03/04/15 16:51 7440-41-7 D3 Cadmium ND mg/kg 0.14 0.069 20 03/04/15 05:30 03/04/15 16:51 7440-43-9 D3 Cobalt 13.2 mg/kg 1.2 0.58 20 03/04/15 05:30 03/05/15 18:33 7440-48-4 D3 Lead 8.7 mg/kg 1.2 0.58 20 03/04/15 05:30 03/04/15 16:51 7439-92-1 D3 Selenium 1.1J mg/kg 1.2 0.58 20 03/04/15 05:30 03/04/15 16:51 7782-49-2 D3 Thallium ND mg/kg 1.2 0.58 20 03/04/15 05:30 03/04/15 16:51 7440-28-0 D3 Vanadium 30.9 mg/kg 1.2 0.58 20 03/04/15 05:30 03/04/15 16:51 7440-62-2 D4 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury 0.032 mg/kg 0.0093 0.0047 1 03/04/15 06:40 03/04/15 13:04 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 17.3 % 0.10 0.10 1 03/09/15 09:51 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 5.7 Std. Units 0.10 0.10 1 03/02/15 12:05 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 300 150 5 03/01/15 05:21 16887-00-6 D3 Sulfate ND mg/kg 300 150 5 03/01/15 05:21 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 30.0 15.0 5 03/01/15 05:21 14797-55-8 D3,H3 Date: 03/18/2015 07:22 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 24 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098ni�c y&e. Suite 100 y Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15020654 Pace Project No.: 92238878 Sample: 2015005344 Lab ID: 92238878001 Collected: 02/24/15 09:55 Received: 02/25/15 16:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 2840 mg/kg 732 366 1 03/05/15 16:20 7440-44-0 Total Organic Carbon 1970 mg/kg 719 360 1 03/05/15 16:25 7440-44-0 Total Organic Carbon 1670 mg/kg 729 365 1 03/05/15 16:31 7440-44-0 Total Organic Carbon 2060 mg/kg 726 363 1 03/05/15 16:36 7440-44-0 Mean Total Organic Carbon 2140 mg/kg 727 363 1 03/05/15 16:20 7440-44-0 Surrogates RSD% 23.2 % 1 03/05/15 16:20 Date: 03/18/2015 07:22 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 25 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 09Q�K3i�c& &e. Suite 100 y Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15020654 Pace Project No.: 92238878 Sample: 2015005346 Lab ID: 92238878002 Collected: 02/24/15 11:40 Received: 02/25/15 16:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 669 mg/kg 5.8 2.9 1 03/04/15 05:30 03/05/15 09:37 7429-90-5 Barium 7.5 mg/kg 0.58 0.29 1 03/04/15 05:30 03/05/15 09:37 7440-39-3 Boron 2.1J mg/kg 2.9 1.5 1 03/04/15 05:30 03/05/15 09:37 7440-42-8 Cadmium ND mg/kg 0.058 0.029 1 03/04/15 05:30 03/05/15 09:37 7440-43-9 Chromium 2.3 mg/kg 0.29 0.15 1 03/04/15 05:30 03/05/15 09:37 7440-47-3 Copper 0.92 mg/kg 0.29 0.15 1 03/04/15 05:30 03/05/15 09:37 7440-50-8 Iron 2590 mg/kg 2.3 1.2 1 03/04/15 05:30 03/05/15 09:37 7439-89-6 Magnesium 150 mg/kg 29.1 14.5 1 03/04/15 05:30 03/05/15 09:37 7439-95-4 Manganese 24.0 mg/kg 0.29 0.15 1 03/04/15 05:30 03/05/15 09:37 7439-96-5 Molybdenum ND mg/kg 0.58 0.29 1 03/04/15 05:30 03/05/15 09:37 7439-98-7 Nickel 0.83 mg/kg 0.29 0.15 1 03/04/15 05:30 03/05/15 09:37 7440-02-0 Potassium 45.2J mg/kg 58.1 29.1 1 03/04/15 05:30 03/05/15 09:37 7440-09-7 Sodium 48AJ mg/kg 58.1 29.1 1 03/04/15 05:30 03/05/15 09:37 7440-23-5 Strontium 2.1 mg/kg 0.58 0.29 1 03/04/15 05:30 03/05/15 09:37 7440-24-6 Zinc 3.3 mg/kg 1.2 0.58 1 03/04/15 05:30 03/05/15 09:37 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 1.2 0.58 20 03/04/15 05:30 03/04/15 17:05 7440-36-0 D3,N2 Arsenic 0.77J mg/kg 1.2 0.58 20 03/04/15 05:30 03/04/15 17:05 7440-38-2 D3 Beryllium 0.14J mg/kg 0.14 0.070 20 03/04/15 05:30 03/04/15 17:05 7440-41-7 D3 Cadmium ND mg/kg 0.14 0.070 20 03/04/15 05:30 03/04/15 17:05 7440-43-9 D3 Cobalt 1.4 mg/kg 1.2 0.58 20 03/04/15 05:30 03/04/15 17:05 7440-48-4 D3 Lead 1.2 mg/kg 1.2 0.58 20 03/04/15 05:30 03/04/15 17:05 7439-92-1 D3 Selenium ND mg/kg 1.2 0.58 20 03/04/15 05:30 03/04/15 17:05 7782-49-2 D3 Thallium ND mg/kg 1.2 0.58 20 03/04/15 05:30 03/04/15 17:05 7440-28-0 D3 Vanadium 5.7 mg/kg 1.2 0.58 20 03/04/15 05:30 03/04/15 17:05 7440-62-2 D3 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury ND mg/kg 0.0090 0.0045 1 03/04/15 06:40 03/04/15 13:06 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 12.3 % 0.10 0.10 1 03/09/15 09:52 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 7.3 Std. Units 0.10 0.10 1 03/02/15 12:05 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 283 141 5 03/01/15 06:26 16887-00-6 D3 Sulfate ND mg/kg 283 141 5 03/01/15 06:26 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 28.3 14.1 5 03/01/15 06:26 14797-55-8 D3,H3 Date: 03/18/2015 07:22 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 26 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 09Q�K�i�c& &e. Suite 100 y Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15020654 Pace Project No.: 92238878 Sample: 2015005346 Lab ID: 92238878002 Collected: 02/24/15 11:40 Received: 02/25/15 16:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon ND mg/kg 690 345 1 03/05/15 17:38 7440-44-0 Total Organic Carbon ND mg/kg 681 340 1 03/05/15 17:44 7440-44-0 Total Organic Carbon ND mg/kg 685 343 1 03/05/15 17:50 7440-44-0 Total Organic Carbon ND mg/kg 679 339 1 03/05/15 17:56 7440-44-0 Mean Total Organic Carbon ND mg/kg 684 342 1 03/05/15 17:38 7440-44-0 Surrogates RSD% 2.5 % 1 03/05/15 17:38 Date: 03/18/2015 07:22 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 27 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098ni�c y&e. Suite 100 y Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15020654 Pace Project No.: 92238878 Sample: 2015005345 Lab ID: 92238878003 Collected: 02/24/15 10:10 Received: 02/25/15 16:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 6310 mg/kg 6.3 3.2 1 03/04/15 05:30 03/05/15 09:42 7429-90-5 Barium 95.6 mg/kg 0.63 0.32 1 03/04/15 05:30 03/05/15 09:42 7440-39-3 Boron 8.8 mg/kg 3.2 1.6 1 03/04/15 05:30 03/05/15 09:42 7440-42-8 Cadmium 0.13 mg/kg 0.063 0.032 1 03/04/15 05:30 03/04/15 19:54 7440-43-9 Chromium 10.3 mg/kg 0.32 0.16 1 03/04/15 05:30 03/05/15 09:42 7440-47-3 Copper 10.4 mg/kg 0.32 0.16 1 03/04/15 05:30 03/05/15 09:42 7440-50-8 Iron 13500 mg/kg 2.5 1.3 1 03/04/15 05:30 03/05/15 09:42 7439-89-6 Magnesium 2340 mg/kg 31.7 15.9 1 03/04/15 05:30 03/05/15 09:42 7439-95-4 Manganese 163 mg/kg 0.32 0.16 1 03/04/15 05:30 03/05/15 09:42 7439-96-5 Molybdenum ND mg/kg 0.63 0.32 1 03/04/15 05:30 03/05/15 09:42 7439-98-7 Nickel 6.3 mg/kg 0.32 0.16 1 03/04/15 05:30 03/05/15 09:42 7440-02-0 Potassium 255 mg/kg 63.5 31.7 1 03/04/15 05:30 03/05/15 09:42 7440-09-7 Sodium 403 mg/kg 63.5 31.7 1 03/04/15 05:30 03/05/15 09:42 7440-23-5 Strontium 14.1 mg/kg 0.63 0.32 1 03/04/15 05:30 03/05/15 09:42 7440-24-6 Zinc 22.9 mg/kg 1.3 0.63 1 03/04/15 05:30 03/05/15 09:42 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 1.3 0.63 20 03/04/15 05:30 03/04/15 17:08 7440-36-0 D3,N2 Arsenic 1.7 mg/kg 1.3 0.63 20 03/04/15 05:30 03/04/15 17:08 7440-38-2 D3 Beryllium 0.43 mg/kg 0.15 0.076 20 03/04/15 05:30 03/04/15 17:08 7440-41-7 D3 Cadmium ND mg/kg 0.15 0.076 20 03/04/15 05:30 03/04/15 17:08 7440-43-9 D3 Cobalt 6.6 mg/kg 1.3 0.63 20 03/04/15 05:30 03/04/15 17:08 7440-48-4 D3 Lead 7.6 mg/kg 1.3 0.63 20 03/04/15 05:30 03/04/15 17:08 7439-92-1 D3 Selenium 0.87J mg/kg 1.3 0.63 20 03/04/15 05:30 03/04/15 17:08 7782-49-2 D3 Thallium ND mg/kg 1.3 0.63 20 03/04/15 05:30 03/04/15 17:08 7440-28-0 D3 Vanadium 34.2 mg/kg 1.3 0.63 20 03/04/15 05:30 03/04/15 17:08 7440-62-2 D4 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury 0.020 mg/kg 0.0095 0.0048 1 03/04/15 06:40 03/04/15 13:08 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 19.6 % 0.10 0.10 1 03/09/15 09:52 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 7.8 Std. Units 0.10 0.10 1 03/02/15 12:05 300.0 IC Anions, SPLP Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 03/02/15 17:45 Sulfate 9.5 mg/L 2.5 1.2 1 03/08/15 03:06 14808-79-8 353.2 Nitrogen, NO2/NO3, SPLP Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 03/02/15 17:45 Nitrogen, Nitrate 0.45 mg/L 0.25 0.25 1 03/11/15 12:59 H1 4500 Chloride, SPLP Analytical Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 03/02/15 17:45 Chloride 8.6 mg/L 6.2 3.1 1 03/10/15 03:52 16887-00-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/18/2015 07:22 AM without the written consent of Pace Analytical Services, Inc.. Page 28 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098ni�c y&e. Suite 100 y Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15020654 Pace Project No.: 92238878 Sample: 2015005345 Lab ID: 92238878003 Collected: 02/24/15 10:10 Received: 02/25/15 16:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 309 155 5 03/01/15 06:47 16887-00-6 D3 Sulfate ND mg/kg 309 155 5 03/01/15 06:47 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 30.9 15.5 5 03/01/15 06:47 14797-55-8 D3,1-13 Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 624J mg/kg 744 372 1 03/05/15 18:01 7440-44-0 Total Organic Carbon 684J mg/kg 740 370 1 03/05/15 18:07 7440-44-0 Total Organic Carbon 609J mg/kg 746 373 1 03/05/15 18:12 7440-44-0 Total Organic Carbon 700J mg/kg 743 371 1 03/05/15 18:18 7440-44-0 Mean Total Organic Carbon 654J mg/kg 743 372 1 03/05/15 18:01 7440-44-0 Surrogates RSD% 6.8 % 1 03/05/15 18:01 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/18/2015 07:22 AM without the written consent of Pace Analytical Services, Inc.. Page 29 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098v�%Y&e. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15020654 Pace Project No.: 92238878 Sample: 2015005345 SPLP Lab ID: 92238878004 Collected: 02/24/15 10:10 Received: 02/25/15 16:35 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;T➢Z17c\�iil=11 a Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470 Mercury Mercury Date: 03/18/2015 07:22 AM Analytical Method: EPA 6020A Preparation Method: EPA 3020 9630 ug/L 10.0 1.2 1 03/12/1510:12 03/12/1515:19 7429-90-5 ND ug/L 0.50 0.25 1 03/12/1510:12 03/12/1515:19 7440-36-0 3.0 ug/L 0.50 0.25 1 03/12/1510:12 03/12/1515:19 7440-38-2 666 ug/L 1.5 0.70 5 03/12/1510:12 03/12/1516:15 7440-39-3 3.0 ug/L 0.20 0.066 1 03/12/1510:12 03/12/1515:19 7440-41-7 11.4 ug/L 5.0 1.0 1 03/12/1510:12 03/12/1515:19 7440-42-8 0.089 ug/L 0.080 0.033 1 03/12/1510:12 03/12/1515:19 7440-43-9 13300 ug/L 40.0 8.4 1 03/12/1510:12 03/12/1515:19 7440-70-2 8.0 ug/L 0.50 0.22 1 03/12/1510:12 03/12/1515:19 7440-47-3 13.5 ug/L 0.50 0.25 1 03/12/1510:12 03/12/1515:19 7440-48-4 25.5 ug/L 1.0 0.22 1 03/12/1510:12 03/12/1515:19 7440-50-8 8290 ug/L 50.0 8.0 1 03/12/1510:12 03/12/1515:19 7439-89-6 27.7 ug/L 0.10 0.046 1 03/12/1510:12 03/12/1515:19 7439-92-1 10800 ug/L 10.0 2.8 1 03/12/1510:12 03/12/1515:19 7439-95-4 560 ug/L 2.5 0.68 5 03/12/1510:12 03/12/1516:15 7439-96-5 ND ug/L 0.50 0.24 1 03/12/1510:12 03/12/1515:19 7439-98-7 11.7 ug/L 0.50 0.23 1 03/12/1510:12 03/12/1515:19 7440-02-0 204 ug/L 50.0 8.3 1 03/12/1510:12 03/12/1515:19 7440-09-7 1.2 ug/L 0.50 0.25 1 03/12/1510:12 03/12/1515:19 7782-49-2 11000 ug/L 50.0 18.2 1 03/12/1510:12 03/12/1515:19 7440-23-5 153 ug/L 0.50 0.057 1 03/12/1510:12 03/12/1515:19 7440-24-6 ND ug/L 0.10 0.025 1 03/12/1510:12 03/12/1515:19 7440-28-0 154 ug/L 1.0 0.21 1 03/12/1510:12 03/12/1515:19 7440-62-2 39.3 ug/L 5.0 2.5 1 03/12/1510:12 03/12/1515:19 7440-66-6 Analytical Method: EPA 7470 Preparation Method: EPA 7470 0.60 ug/L 0.60 0.078 1 03/16/1511:15 03/17/1511:10 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 30 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098nigc y&e. Suite 100 y Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15020654 Pace Project No.: 92238878 Sample: 2015005347 Lab ID: 92238878005 Collected: 02/24/15 14:20 Received: 02/25/15 16:35 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3010 Aluminum ND ug/L 200 18.4 1 03/02/1510:26 03/02/1518:19 7429-90-5 Barium ND ug/L 10.0 5.0 1 03/02/1510:26 03/02/1518:19 7440-39-3 Boron ND ug/L 150 75.0 1 03/02/15 10:26 03/03/15 09:03 7440-42-8 Calcium 2370 ug/L 500 250 1 03/02/1510:26 03/02/1518:19 7440-70-2 Chromium ND ug/L 10.0 5.0 1 03/02/1510:26 03/02/1518:19 7440-47-3 Copper ND ug/L 10.0 1.2 1 03/02/1510:26 03/02/1518:19 7440-50-8 Iron 2170 ug/L 50.0 4.8 1 03/02/1510:26 03/02/1518:19 7439-89-6 Magnesium ND ug/L 500 250 1 03/02/1510:26 03/02/1518:19 7439-95-4 Manganese 74.0 ug/L 5.0 2.5 1 03/02/1510:26 03/02/1518:19 7439-96-5 Molybdenum ND ug/L 15.0 2.3 1 03/02/1510:26 03/02/1518:19 7439-98-7 Nickel ND ug/L 20.0 10.0 1 03/02/1510:26 03/02/1518:19 7440-02-0 Potassium ND ug/L 2500 1250 1 03/02/1510:26 03/02/1518:19 7440-09-7 Sodium 8960 ug/L 1000 500 1 03/02/1510:26 03/02/1518:19 7440-23-5 Zinc ND ug/L 20.0 4.6 1 03/02/1510:26 03/02/1518:19 7440-66-6 6020A MET ICPMS Analytical Method: EPA 6020A Preparation Method: EPA 3020 Antimony ND ug/L 0.50 0.25 1 03/03/1512:17 03/03/1514:27 7440-36-0 Arsenic ND ug/L 0.50 0.25 1 03/03/1512:17 03/03/1514:27 7440-38-2 Beryllium ND ug/L 0.20 0.066 1 03/03/1512:17 03/03/1514:27 7440-41-7 Cadmium ND ug/L 0.080 0.033 1 03/03/1512:17 03/03/1514:27 7440-43-9 Cobalt ND ug/L 0.50 0.25 1 03/03/1512:17 03/03/1514:27 7440-48-4 Lead 0.94 ug/L 0.10 0.046 1 03/03/1512:17 03/03/1514:27 7439-92-1 Selenium ND ug/L 0.50 0.25 1 03/03/1512:17 03/03/1514:27 7782-49-2 Strontium 4.8 ug/L 0.50 0.057 1 03/03/1512:17 03/03/1514:27 7440-24-6 Thallium ND ug/L 0.10 0.025 1 03/03/1512:17 03/03/1514:27 7440-28-0 Vanadium ND ug/L 1.0 0.21 1 03/03/1512:17 03/03/1514:27 7440-62-2 7470 Mercury Analytical Method: EPA 7470 Preparation Method: EPA 7470 Mercury ND ug/L 0.20 0.026 1 03/02/1510:50 03/04/1512:52 7439-97-6 Date: 03/18/2015 07:22 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 31 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098ni�c y&e. Suite 100 y Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15020654 Pace Project No.: 92238878 QC Batch: MERP/12854 Analysis Method: EPA 7470 QC Batch Method: EPA 7470 Analysis Description: 7470 Mercury Associated Lab Samples: 92238878005 METHOD BLANK: 1908523 Matrix: Water Associated Lab Samples: 92238878005 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury ug/L ND 0.20 03/04/1512:35 LABORATORY CONTROL SAMPLE: 1908524 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 5 5.1 101 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1909276 1909277 MS MSD 92238878005 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 5 5 5.3 5.1 106 101 75-125 4 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/18/2015 07:22 AM without the written consent of Pace Analytical Services, Inc.. Page 32 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098gwiny&e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15020654 Pace Project No.: 92238878 QC Batch: MERP/12947 Analysis Method: EPA 7470 QC Batch Method: EPA 7470 Analysis Description: 7470 Mercury Associated Lab Samples: 92238878004 METHOD BLANK: 1916161 Matrix: Water Associated Lab Samples: 92238878004 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury ug/L ND 0.20 03/17/1510:53 LABORATORY CONTROL SAMPLE: 1916162 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 5 5.0 100 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1916612 1916613 MS MSD 92240170035 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 5 5 4.9 4.8 97 97 75-125 0 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/18/2015 07:22 AM without the written consent of Pace Analytical Services, Inc.. Page 33 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098gwinlc& &e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15020654 Pace Project No.: 92238878 QC Batch: MERP/5420 Analysis Method: EPA 7471 QC Batch Method: EPA 7471 Analysis Description: 7471 Mercury Associated Lab Samples: 92238878001, 92238878002, 92238878003 METHOD BLANK: 1144515 Matrix: Solid Associated Lab Samples: 92238878001, 92238878002, 92238878003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury mg/kg ND 0.0082 03/04/1512:19 LABORATORY CONTROL SAMPLE: 1144516 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury mg/kg .083 0.083 100 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1144517 1144518 MS MSD 35176987001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury mg/kg 1.1 1.02 .875 1.6 2.1 43 106 80-120 27 20 M1,R1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/18/2015 07:22 AM without the written consent of Pace Analytical Services, Inc.. Page 34 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098gWi2c8w. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15020654 Pace Project No.: 92238878 QC Batch: MPRP/22893 Analysis Method: EPA 6010 QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid Associated Lab Samples: 92238878001, 92238878002, 92238878003 METHOD BLANK: 1144535 Matrix: Associated Lab Samples: 92238878001, 92238878002, 92238878003 Blank Parameter Units Result Solid Reporting Limit Analyzed Aluminum mg/kg ND 5.1 03/04/1516:22 Barium mg/kg ND 0.51 03/04/1516:22 Boron mg/kg ND 2.5 03/04/1516:22 Cadmium mg/kg ND 0.051 03/04/1516:22 Chromium mg/kg ND 0.25 03/04/1516:22 Copper mg/kg ND 0.25 03/04/1516:22 Iron mg/kg ND 2.0 03/04/1516:22 Magnesium mg/kg ND 25.3 03/04/1516:22 Manganese mg/kg ND 0.25 03/04/1516:22 Molybdenum mg/kg ND 0.51 03/04/1516:22 Nickel mg/kg ND 0.25 03/04/1516:22 Potassium mg/kg ND 50.6 03/04/1516:22 Sodium mg/kg ND 50.6 03/04/1516:22 Strontium mg/kg ND 0.51 03/04/1516:22 Zinc mg/kg ND 1.0 03/04/1516:22 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 1144536 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Aluminum mg/kg 127 123 97 80-120 Barium mg/kg 12.7 13.0 102 80-120 Boron mg/kg 127 125 98 80-120 Cadmium mg/kg 1.3 1.3 101 80-120 Chromium mg/kg 12.7 12.5 98 80-120 Copper mg/kg 12.7 12.3 97 80-120 Iron mg/kg 127 113 89 80-120 Magnesium mg/kg 637 595 93 80-120 Manganese mg/kg 12.7 12.6 99 80-120 Molybdenum mg/kg 12.7 12.4 97 80-120 Nickel mg/kg 12.7 12.7 99 80-120 Potassium mg/kg 637 632 99 80-120 Sodium mg/kg 637 665 104 80-120 Strontium mg/kg 12.7 12.6 99 80-120 Zinc mg/kg 63.7 63.9 100 80-120 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/18/2015 07:22 AM without the written consent of Pace Analytical Services, Inc.. Page 35 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098mc8w. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15020654 Pace Project No.: 92238878 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1144537 1144538 MS MSD 92238879001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum mg/kg 18700 135 137 20800 21400 1510 1950 75-125 3 20 M6 Barium mg/kg 479 13.5 13.7 280 245 -1470 -1700 75-125 13 20 M6 Boron mg/kg 26AJ 135 137 155 151 95 91 75-125 2 20 Cadmium mg/kg ND 1.4 1.4 1.2 1.0 86 73 75-125 14 20 M6 Chromium mg/kg 68.3 13.5 13.7 90.6 93.6 165 184 75-125 3 20 M6 Copper mg/kg 18.9 13.5 13.7 27.9 26.4 67 54 75-125 6 20 M6 Iron mg/kg 35500 135 137 34600 35800 -644 233 75-125 3 20 M6 Magnesium mg/kg 17000 675 687 20000 20800 439 555 75-125 4 20 M6 Manganese mg/kg 3200 13.5 13.7 2340 2070 -6390 -8250 75-125 12 20 M6 Molybdenum mg/kg ND 13.5 13.7 7.9 8.1 53 54 75-125 3 20 M6 Nickel mg/kg 50.0 13.5 13.7 61.5 66.8 85 122 75-125 8 20 Potassium mg/kg 14300 675 687 17400 17600 468 492 75-125 1 20 M6 Sodium mg/kg 416J 675 687 1110 1130 103 104 75-125 2 20 Strontium mg/kg 28.4 13.5 13.7 39.9 39.2 85 79 75-125 2 20 Zinc mg/kg 226 67.5 68.7 300 304 110 114 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/18/2015 07:22 AM without the written consent of Pace Analytical Services, Inc.. Page 36 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g%c& &e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15020654 Pace Project No.: 92238878 QC Batch: MPRP/52678 Analysis Method: EPA 6010 QC Batch Method: EPA 3010 Analysis Description: 6010 MET Associated Lab Samples: 92238878005 METHOD BLANK: 1908505 Associated Lab Samples: 92238878005 Parameter Units Matrix: Blank Result Water Reporting Limit Analyzed Aluminum ug/L ND 200 03/02/1517:24 Barium ug/L ND 10.0 03/02/1517:24 Boron ug/L ND 150 03/03/15 08:05 Calcium ug/L ND 500 03/02/1517:24 Chromium ug/L ND 10.0 03/02/1517:24 Copper ug/L ND 10.0 03/02/1517:24 Iron ug/L ND 50.0 03/02/1517:24 Magnesium ug/L ND 500 03/02/1517:24 Manganese ug/L ND 5.0 03/02/1517:24 Molybdenum ug/L ND 15.0 03/02/1517:24 Nickel ug/L ND 20.0 03/02/1517:24 Potassium ug/L ND 2500 03/02/1517:24 Sodium ug/L ND 1000 03/02/1517:24 Zinc ug/L ND 20.0 03/02/1517:24 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 1908506 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Aluminum ug/L 10000 9190 92 80-120 Barium ug/L 1000 957 96 80-120 Boron ug/L 1000 909 91 80-120 Calcium ug/L 10000 10000 100 80-120 Chromium ug/L 1000 945 95 80-120 Copper ug/L 1000 956 96 80-120 Iron ug/L 10000 9550 95 80-120 Magnesium ug/L 10000 8990 90 80-120 Manganese ug/L 1000 974 97 80-120 Molybdenum ug/L 1000 911 91 80-120 Nickel ug/L 1000 940 94 80-120 Potassium ug/L 10000 9650 96 80-120 Sodium ug/L 10000 9520 95 80-120 Zinc ug/L 1000 920 92 80-120 Qualifiers MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1908507 1908508 MS MSD 92238666013 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum ug/L ND 10000 10000 9540 9530 95 95 75-125 0 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/18/2015 07:22 AM without the written consent of Pace Analytical Services, Inc.. Page 37 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098mc8w. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15020654 Pace Project No.: 92238878 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1908507 1908508 MS MSD 92238666013 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Barium ug/L ND 1000 1000 996 942 100 94 75-125 6 20 Boron ug/L ND 1000 1000 923 933 91 92 75-125 1 20 Calcium ug/L ND 10000 10000 10700 10500 106 103 75-125 3 20 Chromium ug/L ND 1000 1000 985 932 98 93 75-125 6 20 Copper ug/L 15.5 1000 1000 984 936 97 92 75-125 5 20 Iron ug/L 72.0 10000 10000 10100 9690 101 96 75-125 5 20 Magnesium ug/L ND 10000 10000 9590 9010 96 90 75-125 6 20 Manganese ug/L ND 1000 1000 1020 960 101 96 75-125 6 20 Molybdenum ug/L ND 1000 1000 952 914 95 91 75-125 4 20 Nickel ug/L ND 1000 1000 985 926 98 93 75-125 6 20 Potassium ug/L ND 10000 10000 10000 9620 97 93 75-125 4 20 Sodium ug/L ND 10000 10000 9950 9650 99 96 75-125 3 20 Zinc ug/L ND 1000 1000 980 912 98 91 75-125 7 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/18/2015 07:22 AM without the written consent of Pace Analytical Services, Inc.. Page 38 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098mc8w. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15020654 Pace Project No.: 92238878 QC Batch: MPRP/22894 Analysis Method: EPA 6020 QC Batch Method: EPA 3050 Analysis Description: 6020 MET SOLID Associated Lab Samples: 92238878001, 92238878002, 92238878003 METHOD BLANK: 1144539 Matrix: Solid Associated Lab Samples: 92238878001, 92238878002, 92238878003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Antimony mg/kg ND 0.050 03/04/1516:14 N2 Arsenic mg/kg ND 0.050 03/04/1516:14 Beryllium mg/kg ND 0.0061 03/04/1516:14 Cadmium mg/kg ND 0.0061 03/04/1516:14 Cobalt mg/kg ND 0.050 03/04/1516:14 Lead mg/kg ND 0.050 03/04/1516:14 Selenium mg/kg ND 0.050 03/04/1516:14 Thallium mg/kg ND 0.050 03/04/1516:14 Vanadium mg/kg ND 0.050 03/04/1516:14 LABORATORY CONTROL SAMPLE: Parameter 1144540 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Antimony mg/kg 2.5 2.6 102 80-120 N2 Arsenic mg/kg 2.5 2.7 107 80-120 Beryllium mg/kg .25 0.28 109 80-120 Cadmium mg/kg .25 0.27 104 80-120 Cobalt mg/kg 2.5 2.7 105 80-120 Lead mg/kg 2.5 2.6 103 80-120 Selenium mg/kg 2.5 2.9 113 80-120 Thallium mg/kg 2.5 2.6 101 80-120 Vanadium mg/kg 2.5 2.7 104 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1144541 92238666007 Parameter Units Result MS Spike Conc. MSD Spike Conc. 1144542 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits Max RPD RPD Qual Antimony mg/kg ND 4.21 4.38 3.2 3.6 55 61 75-125 12 20 D3,M6, N2 Arsenic mg/kg 76.9 4.21 4.38 79.0 73.3 51 -79 75-125 7 20 D4,M6 Beryllium mg/kg 2.4 .421 .438 3.0 2.8 123 88 75-125 4 20 D3 Cadmium mg/kg 0.24 .421 .438 0.68 0.65 105 93 75-125 4 20 D3 Cobalt mg/kg 6.4 4.21 4.38 10.4 10.5 97 94 75-125 1 20 D3 Lead mg/kg 13.7 4.21 4.38 17.9 16.0 102 52 75-125 11 20 D3,M6 Selenium mg/kg 11.1 4.21 4.38 13.9 14.7 66 81 75-125 6 20 D3,M6 Thallium mg/kg 1.5J 4.21 4.38 4.8 5.0 80 80 75-125 3 20 D3 Vanadium mg/kg 50.5 4.21 4.38 54.5 50.4 95 -3 75-125 8 20 D4,M6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/18/2015 07:22 AM without the written consent of Pace Analytical Services, Inc.. Page 39 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098mc& &e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15020654 Pace Project No.: 92238878 QC Batch: MPRP/52715 Analysis Method: EPA 6020A QC Batch Method: EPA 3020 Analysis Description: 6020A Water UPD4 Associated Lab Samples: 92238878005 METHOD BLANK: 1909910 Associated Lab Samples: 92238878005 Parameter Units Matrix: Blank Result Water Reporting Limit Analyzed Antimony ug/L ND 0.50 03/03/1514:24 Arsenic ug/L ND 0.50 03/03/1514:24 Beryllium ug/L ND 0.20 03/03/1514:24 Cadmium ug/L ND 0.080 03/03/1514:24 Cobalt ug/L ND 0.50 03/03/1514:24 Lead ug/L ND 0.10 03/03/1514:24 Selenium ug/L ND 0.50 03/03/1514:24 Strontium ug/L ND 0.50 03/03/1514:24 Thallium ug/L ND 0.10 03/03/1514:24 Vanadium ug/L ND 1.0 03/03/1514:24 LABORATORY CONTROL SAMPLE: 1909911 Parameter Units Antimony ug/L Arsenic ug/L Beryllium ug/L Cadmium ug/L Cobalt ug/L Lead ug/L Selenium ug/L Strontium ug/L Thallium ug/L Vanadium ug/L Qualifiers Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 80 86.6 108 80-120 80 87.2 109 80-120 80 85.1 106 80-120 80 87.4 109 80-120 80 86.3 108 80-120 80 88.0 110 80-120 80 86.0 107 80-120 80 85.6 107 80-120 80 89.0 111 80-120 80 87.8 110 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1909912 1909913 MS MSD 92238878005 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 80 80 89.2 89.3 111 111 75-125 0 20 Arsenic ug/L ND 80 80 89.8 89.3 112 111 75-125 1 20 Beryllium ug/L ND 80 80 95.9 85.1 120 106 75-125 12 20 Cadmium ug/L ND 80 80 93.6 92.0 117 115 75-125 2 20 Cobalt ug/L ND 80 80 92.5 91.9 115 114 75-125 1 20 Lead ug/L 0.94 80 80 93.8 92.7 116 115 75-125 1 20 Selenium ug/L ND 80 80 96.8 85.1 121 106 75-125 13 20 Strontium ug/L 4.8 80 80 95.0 94.1 113 112 75-125 1 20 Thallium ug/L ND 80 80 91.9 90.6 115 113 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/18/2015 07:22 AM without the written consent of Pace Analytical Services, Inc.. Page 40 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098mc8w. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15020654 Pace Project No.: 92238878 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1909912 1909913 MS MSD 92238878005 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qua] Vanadium ug/L ND 80 80 92.8 91.2 115 113 75-125 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/18/2015 07:22 AM without the written consent of Pace Analytical Services, Inc.. Page 41 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098mc8w. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15020654 Pace Project No.: 92238878 QC Batch: MPRP/52897 Analysis Method: EPA 6020A QC Batch Method: EPA 3020 Analysis Description: 6020A Water UPD4 Associated Lab Samples: 92238878004 METHOD BLANK: 1916229 Associated Lab Samples: 92238878004 Parameter Units Aluminum ug/L Antimony ug/L Arsenic ug/L Barium ug/L Beryllium ug/L Boron ug/L Cadmium ug/L Calcium ug/L Chromium ug/L Cobalt ug/L Copper ug/L Iron ug/L Lead ug/L Magnesium ug/L Manganese ug/L Molybdenum ug/L Nickel ug/L Potassium ug/L Selenium ug/L Sodium ug/L Strontium ug/L Thallium ug/L Vanadium ug/L Zinc ug/L Matrix: Water Blank Result Reporting Limit Analyzed ND 10.0 03/12/1515:35 ND 0.50 03/12/1515:35 ND 0.50 03/12/1515:35 ND 0.30 03/12/1515:35 ND 0.20 03/12/1515:35 ND 5.0 03/12/1515:35 ND 0.080 03/12/1515:35 ND 40.0 03/12/1515:35 ND 0.50 03/12/1515:35 ND 0.50 03/12/1515:35 ND 1.0 03/12/1515:35 ND 50.0 03/12/1515:35 ND 0.10 03/12/1515:35 ND 10.0 03/12/1515:35 ND 0.50 03/12/1515:35 ND 0.50 03/12/1515:35 ND 0.50 03/12/1515:35 ND 50.0 03/12/1515:35 ND 0.50 03/12/1515:35 ND 50.0 03/12/1515:35 ND 0.50 03/12/1515:35 ND 0.10 03/12/1515:35 ND 1.0 03/12/1515:35 ND 5.0 03/12/1515:35 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 1916230 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Aluminum ug/L 80 79.2 99 80-120 Antimony ug/L 80 82.0 103 80-120 Arsenic ug/L 80 82.2 103 80-120 Barium ug/L 80 83.3 104 80-120 Beryllium ug/L 80 79.7 100 80-120 Boron ug/L 80 82.0 102 80-120 Cadmium ug/L 80 84.3 105 80-120 Calcium ug/L 1000 1070 107 80-120 Chromium ug/L 80 84.2 105 80-120 Cobalt ug/L 80 87.8 110 80-120 Copper ug/L 80 84.1 105 80-120 Iron ug/L 1000 1060 106 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/18/2015 07:22 AM without the written consent of Pace Analytical Services, Inc.. Page 42 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098ony&e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15020654 Pace Project No.: 92238878 LABORATORY CONTROL SAMPLE: 1916230 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Lead ug/L 80 85.1 106 80-120 Magnesium ug/L 1000 1020 102 80-120 Manganese ug/L 80 88.5 111 80-120 Molybdenum ug/L 80 88.3 110 80-120 Nickel ug/L 80 88.3 110 80-120 Potassium ug/L 1000 1040 104 80-120 Selenium ug/L 80 84.6 106 80-120 Sodium ug/L 1000 1040 104 80-120 Strontium ug/L 80 82.6 103 80-120 Thallium ug/L 80 91.4 114 80-120 Vanadium ug/L 80 87.4 109 80-120 Zinc ug/L 80 80.3 100 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1916665 1916666 MS MSD 92239540010 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum ug/L 44.7 80 80 142 147 121 128 75-125 4 20 M1 Antimony ug/L ND 80 80 83.1 82.4 104 103 75-125 1 20 Arsenic ug/L ND 80 80 81.0 81.8 101 102 75-125 1 20 Barium ug/L 3.8 80 80 84.2 85.7 100 102 75-125 2 20 Beryllium ug/L ND 80 80 81.0 78.8 101 98 75-125 3 20 Boron ug/L ND 80 80 93.8 87.2 112 103 75-125 7 20 Cadmium ug/L ND 80 80 84.8 85.2 106 107 75-125 0 20 Calcium ug/L 3900 1000 1000 5040 5150 114 125 75-125 2 20 Chromium ug/L 4.2 80 80 87.0 87.7 103 104 75-125 1 20 Cobalt ug/L ND 80 80 84.3 85.0 105 106 75-125 1 20 Copper ug/L 2.0 80 80 84.9 86.0 104 105 75-125 1 20 Iron ug/L 404 1000 1000 1470 1500 107 110 75-125 2 20 Lead ug/L 0.47 80 80 85.4 85.8 106 107 75-125 1 20 Magnesium ug/L 229 1000 1000 1240 1280 101 105 75-125 3 20 Manganese ug/L 8.0 80 80 96.7 98.5 111 113 75-125 2 20 Molybdenum ug/L 1.5 80 80 87.8 88.9 108 109 75-125 1 20 Nickel ug/L ND 80 80 88.0 89.1 109 111 75-125 1 20 Potassium ug/L 1290 1000 1000 2370 2400 108 111 75-125 1 20 Selenium ug/L ND 80 80 85.3 83.7 106 104 75-125 2 20 Sodium ug/L 3180 1000 1000 4250 4390 108 121 75-125 3 20 Strontium ug/L 21.4 80 80 103 104 102 104 75-125 2 20 Thallium ug/L ND 80 80 87.8 87.5 110 109 75-125 0 20 Vanadium ug/L 1.8 80 80 88.9 90.1 109 110 75-125 1 20 Zinc ug/L 5.1 80 80 84.9 85.8 100 101 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/18/2015 07:22 AM without the written consent of Pace Analytical Services, Inc.. Page 43 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 09Q�Ijinlc& &e. Suite 100 y Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15020654 Pace Project No.: 92238878 QC Batch: PMST/3315 Analysis Method: ASTM D2974-87 QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture Associated Lab Samples: 92238878001, 92238878002, 92238878003 SAMPLE DUPLICATE: 1150025 92238879001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 7.5 7.3 2 10 SAMPLE DUPLICATE: 1150026 35178367003 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 4.1 4.2 4 10 SAMPLE DUPLICATE: 1150027 35178367013 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 7.2 8.4 15 10 D6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/18/2015 07:22 AM without the written consent of Pace Analytical Services, Inc.. Page 44 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098ony&e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15020654 Pace Project No.: 92238878 QC Batch: WET/35950 Analysis Method: EPA 9045 QC Batch Method: EPA 9045 Analysis Description: 9045 pH Associated Lab Samples: 92238878001, 92238878002, 92238878003 SAMPLE DUPLICATE: 1400247 92238666008 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 7.5 7.5 1 10 SAMPLE DUPLICATE: 1400248 92239113005 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 4.6 4.4 4 10 D6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/18/2015 07:22 AM without the written consent of Pace Analytical Services, Inc.. Page 45 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098nny&e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15020654 Pace Project No.: 92238878 QC Batch: WETA/22152 Analysis Method: EPA 300.0 QC Batch Method: EPA 300.0 Analysis Description: 300.0 IC Anions Associated Lab Samples: 92238878003 METHOD BLANK: 1405632 Matrix: Water Associated Lab Samples: 92238878003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Sulfate mg/L ND 2.0 03/08/15 00:17 LABORATORY CONTROL SAMPLE: 1405633 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfate mg/L 20 20.0 100 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1405634 1405635 MS MSD 92238666005 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfate mg/L 12.8 36.1 36.1 49.4 49.3 101 101 0 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/18/2015 07:22 AM without the written consent of Pace Analytical Services, Inc.. Page 46 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098mc& &e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15020654 Pace Project No.: 92238878 QC Batch: WETA/22179 Analysis Method: EPA 353.2 QC Batch Method: EPA 353.2 Analysis Description: 353.2 Nitrate + Nitrite, Unpres. Associated Lab Samples: 92238878003 METHOD BLANK: 1407887 Matrix: Water Associated Lab Samples: 92238878003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, Nitrate mg/L 0.23 0.020 03/11/15 12:43 B LABORATORY CONTROL SAMPLE: 1407888 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Nitrate mg/L 2.5 2.4 98 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1407896 1407897 MS MSD 92238666006 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Nitrate mg/L 0.32 3.1 3.1 3.1 3.1 92 91 90-110 0 10 H1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/18/2015 07:22 AM without the written consent of Pace Analytical Services, Inc.. Page 47 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098nny&e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15020654 Pace Project No.: 92238878 QC Batch: WETA/22158 Analysis Method: SM 4500-CI-E QC Batch Method: SM 4500-CI-E Analysis Description: 4500 Chloride Associated Lab Samples: 92238878003 METHOD BLANK: 1406049 Matrix: Water Associated Lab Samples: 92238878003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/L ND 1.0 03/10/15 03:45 LABORATORY CONTROL SAMPLE: 1406050 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloride mg/L 20 21.2 106 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1406051 1406052 MS MSD 92238666005 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride mg/L ND 36.1 36.1 41.2 40.8 108 107 90-110 1 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/18/2015 07:22 AM without the written consent of Pace Analytical Services, Inc.. Page 48 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098ony&e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15020654 Pace Project No.: 92238878 QC Batch: WETA/44073 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92238878001, 92238878002, 92238878003 METHOD BLANK: 1143165 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/kg ND 49.7 03/01/15 00:43 Sulfate mg/kg ND 49.7 03/01/15 00:43 LABORATORY CONTROL SAMPLE: 1143166 Parameter Units Chloride mg/kg Sulfate mg/kg MATRIX SPIKE SAMPLE: 1143168 Parameter Units Chloride mg/kg Sulfate mg/kg SAMPLE DUPLICATE: 1143167 Parameter Chloride Sulfate Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 499 497 100 80-120 499 501 100 80-120 92238666001 Spike MS MS % Rec Result Conc. Result % Rec Limits Qualifiers ND 574 553 96 80-120 ND 574 586 91 80-120 92238666001 Dup Units Result Result mg/kg ND ND mg/kg ND ND Max RPD RPD Qualifiers 20 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/18/2015 07:22 AM without the written consent of Pace Analytical Services, Inc.. Page 49 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098g"c8w. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15020654 Pace Project No.: 92238878 QC Batch: WETA/44074 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92238878001, 92238878002, 92238878003 METHOD BLANK: 1143169 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrate as N mg/kg ND 5.0 03/01/15 00:43 LABORATORY CONTROL SAMPLE: 1143170 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg 49.9 52.0 104 80-120 MATRIX SPIKE SAMPLE: 1143172 92238666001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg ND 57.4 57.8 101 80-120 H3 SAMPLE DUPLICATE: 1143171 92238666001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Nitrate as N mg/kg ND ND 20 H3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/18/2015 07:22 AM without the written consent of Pace Analytical Services, Inc.. Page 50 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098ogc y&e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15020654 Pace Project No.: 92238878 QC Batch: WETA/27440 Analysis Method: EPA 9060 QC Batch Method: EPA 9060 Analysis Description: 9060 TOC Average Associated Lab Samples: 92238878001, 92238878002, 92238878003 METHOD BLANK: 1123387 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mean Total Organic Carbon mg/kg ND 600 03/05/15 09:09 LABORATORY CONTROL SAMPLE: 1123388 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mean Total Organic Carbon mg/kg 120000 110000 92 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1123389 1123390 MS MSD 92238666003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg 2210 13100 13100 12700 11900 80 73 50-150 7 30 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1123391 1123392 MS MSD 92238878001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg 2140 7280 7230 8010 8250 81 84 50-150 3 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/18/2015 07:22 AM without the written consent of Pace Analytical Services, Inc.. Page 51 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098ony&e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: J15020654 Pace Project No.: 92238878 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-G Pace Analytical Services - Green Bay PASI-M Pace Analytical Services - Minneapolis PASI-O Pace Analytical Services - Ormond Beach ANALYTE QUALIFIERS B Analyte was detected in the associated method blank. D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. D4 Sample was diluted due to the presence of high levels of target analytes. D6 The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits. H1 Analysis conducted outside the EPA method holding time. H3 Sample was received or analysis requested beyond the recognized method holding time. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. N2 The lab does not hold TNI accreditation for this parameter. R1 RPD value was outside control limits. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/18/2015 07:22 AM without the written consent of Pace Analytical Services, Inc.. Page 52 of 57 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098oi�c y&e. Suite 100 y Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: J15020654 Pace Project No.: 92238878 Lab ID Sample ID QC Batch Method QC Batch Analytical Method 92238878001 2015005344 EPA 3050 MPRP/22893 EPA 6010 92238878002 2015005346 EPA 3050 MPRP/22893 EPA 6010 92238878003 2015005345 EPA 3050 MPRP/22893 EPA 6010 92238878005 2015005347 EPA 3010 MPRP/52678 EPA 6010 92238878001 2015005344 EPA 3050 MPRP/22894 EPA 6020 92238878002 2015005346 EPA 3050 MPRP/22894 EPA 6020 92238878003 2015005345 EPA 3050 MPRP/22894 EPA 6020 92238878004 2015005345 SPLP EPA 3020 MPRP/52897 EPA 6020A 92238878005 2015005347 EPA 3020 MPRP/52715 EPA 6020A 92238878004 2015005345 SPLP EPA 7470 MERP/12947 EPA 7470 92238878005 2015005347 EPA 7470 MERP/12854 EPA 7470 92238878001 2015005344 EPA 7471 MERP/5420 EPA 7471 92238878002 2015005346 EPA 7471 MERP/5420 EPA 7471 92238878003 2015005345 EPA 7471 MERP/5420 EPA 7471 92238878001 2015005344 ASTM D2974-87 PMST/3315 92238878002 2015005346 ASTM D2974-87 PMST/3315 92238878003 2015005345 ASTM D2974-87 PMST/3315 92238878001 2015005344 EPA 9045 WET/35950 92238878002 2015005346 EPA 9045 WET/35950 92238878003 2015005345 EPA 9045 WET/35950 92238878003 2015005345 EPA 300.0 WETA/22152 92238878003 2015005345 EPA 353.2 WETA/22179 92238878003 2015005345 SM 4500-CI-E WETA/22158 92238878001 2015005344 EPA 9056 WETA/44073 92238878002 2015005346 EPA 9056 WETA/44073 92238878003 2015005345 EPA 9056 WETA/44073 92238878001 2015005344 EPA 9056 WETA/44074 92238878002 2015005346 EPA 9056 WETA/44074 92238878003 2015005345 EPA 9056 WETA/44074 92238878001 2015005344 EPA 9060 WETA/27440 92238878001 2015005344 EPA 9060 WETA/27441 92238878002 2015005346 EPA 9060 WETA/27440 92238878002 2015005346 EPA 9060 WETA/27441 92238878003 2015005345 EPA 9060 WETA/27440 92238878003 2015005345 EPA 9060 WETA/27441 Date: 03/18/2015 07:22 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Analytical Batch ICP/14009 ICP/14009 ICP/14009 ICP/22903 ICPM/9338 ICPM/9338 ICPM/9338 ICPM/23451 ICPM/23379 MERC/15061 MERC/14935 MERC/5413 MERC/5413 MERC/5413 Page 53 of 57 ,.l�aceArlalytrcal' Sample Condition Upon Receipt (SCUR) Page 1 of 2 Document Number: issuing Auth$rit F-CHR-CS-003-rev.15 Pace Huntersville Qua y ice Client Name: Courier: ❑ Fed Ex UPS❑ USPS❑ Client❑ Commercial❑ C-Pacd Other Custody Seal on Cooler/Box Present: ❑ yes ❑ nog Seals intact: ❑ yes ❑ no Packing Material: [] Bubble 1❑p ❑ Bubble Bogs ❑ None ❑ Other Thermometer Used: IR Gun CT*1 Type of Ice: Wet Blue Wong ❑ Samples -on ice; cooling process has begun 'rnrnn 1 nrrnr4inn Panfnr T1AA1 Hn r..nrrPrtinn Corrected Cooler Tom p . N jl �C Biological Tissue is Frozen: Yes No f Date and Initials of poison exartpining contents: �S Z Y r Temp should be above freezing to 6°C Comments: Chain of Custody Present: ©Yes, Y'es []No El N/A 1. Chain of Custody Filled Out: ❑Yep ❑No ❑NIA 2. Chain of Custody Relinquished: Yes ❑No ❑NIA 3. Sampler Name & Signature on COC: ❑Y s IZNo ❑NIA 4. Samples Arrived within Hold Time: Yes ❑No ❑NIA 5. Short Hold Time Analysis (<72hr): ❑Yes❑,�moo ❑NrA 6. Rush Turn Around Time Requested: ❑Yes ON ❑NIA 7. Sufficient Volume: V es ❑No ❑NIA 8. Correct Containers Used: CYes ❑No ❑NIA 9. -Pace Containers Used: Dyes, L No ❑NIA Containers Intact: Des ❑No ❑INNIA 10, Filtered volume received for Dissolved tests ❑Yes ❑No �'JNIA 11. Sample Labels match COC: Pes ❑No ❑NIA 12. -Includes dateltime/1D/Analysis Matrix: All containers needing preservation have been checked. F)Yes ❑No ONIA 13. All containers needing preservation are found to be in ❑Yes ❑No IJNIA compliance with EPA recommendation. exceptions: VOA, coliform, TOO, O&G, WI-DRO (water) ❑Yes �INo Samples checked for dechlorination: ❑Yes ❑No ZNIA 14. Headspace in VOA Vials >6mm): ❑Yes ❑No Q 15. Trip Blank Present: El ❑No ,CIA QN/A 16. Trip Blank Custody Seals Present ❑Yes DNo 941A Pace Trip Blank Lot # (if purchased): Client Notification/ Resolution: Person Contacted: Comments/ Resolution: DateFrime: SCURF Review: Date: 2 2/� SRF Review: 1 9 Date, I & LI Note: Whenever there i a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (Le out of hold, incorrect preservative, out of temp, Incorrect containers) Field Data Required? Y / N W0#:92238878 1111111111111111111111IIIN Page 54 of 57 Page 62 of 66 M w i ro u Customer must Complele us 75 \ - - U f OIL a m I m 11 " cN w o o m rn customar to complclo appropriato columns to rlgYlt M n q _ n w t� V.If � 0 r-i r ym C) D N I� a ro 4 43�'�� CD n n 0 CP Im g I IQ O -!a oo looms �I® ciz vroi t G - N b i `n m m 5 Z R Q� NO `n i .y �' j l7 CT V -O' 'RO�4 tle LT Cl Q d d� wir Ngx� 8 �i(-j�? �,A j comp. is R 3 3L 1 ra ;, A ly—V) r i 1 ieGrab Req Ire o i;U I ,I X X Total Metals (PACE 5 o i! t'?r Anions (PACE) 5 c I rn rn �o �,. l X X PH (PACE) 5 O i --I SPLP - Total Metals and Anions (PACE) 5 1� Sediment specific tests ! (Access Analytical) i Organic Carbon` i I i a i • A _. J n A b 00rn 1" ca 7 Z ® Y a �otal JJ of Cio�tainofs 0 Cf A (I 7-� .1 y� v� Page 55 of 57 �.>��ceAnalyticaltl Sample Condition Upon Receipt SCUR Page I of 2 Document Number: Issuing Author F-CHR-CS-003-rev.15 Pace Huntersville Clui Client Name: 1 c lu Courier: ❑ Fed Ex ❑ UPS❑ USPS❑ Client❑ Commercial❑ (jF6cej Other, 10 , '� M Custody Seat on Cooler/Box Present: El Yes , -no Seals intact C] yes ❑ na Packing Material: ❑Bubble VDp ❑Bubble Bags ❑ (�lon4:❑ Other L %-2-5 � % / .. Thermometer Used: IR Gun T114 Type of Ice: W t Blue orl9, ❑ Samples on ice, cooling process has begun Tamn rnrrm- inn Fnnfrir T'IA(11 Nn C orrpntinn Corrected Cooler Temp.: i .0 Biological Tissue is Frozen: Yes No g date and Initials of person examining S ' 1's contents: ' Temp should be above freezing to 6°C Comments: Chain of Custody Present © s ❑No El N/A 1. Chain of Custody Filled Out Yes 0110 ❑NIA 2. Chain of Custody Relinquished: D<es ❑No. ❑NIA g, Sampler Name & Signature on COC: Dyes dNo ❑NIA 4. Samples Arrived within Hold Time: [As ❑No ❑NIA 5. Short Hold Time Analysis (<72hr), ❑Yes No ❑NIA 6. Rush Turn Around Time Requested: ❑Yes No ❑NIA 7. Sufficient Volume: ' Yes ONO ❑NIA 8, Correct Containers Used: fl7Yes ONO ❑NIA g, -Pace Containers Used: Dyes ❑nto ❑N/A Containers Intact: ❑ es El No ❑lTA 10. Filtered volume received for Dissolved tests ❑Yes ONo 1 NIA 11. Sample Labels match COC: Yes ONO ❑NIA 12. -Includes date/time/ID/Analysis Matrix: All containers needing preservation have been checked. Des ❑No ❑NIA 13. All containers needing preservation are found to be in CllDyes ONO ❑NIA compliance with EPA recommendation. exceptions: VOA, couferm, TOC, O&G, WI-DRO (water) ❑Yes DNO Samples checked for dechlorination: ❑Yes ❑No NIA 14. Headspace in VOA Vials (>6mm): ❑Yes ONO ONIA 15. Trip Blank Present: Dyes ❑No % A 16. Trip Blank Custody Seals Present Dyes ❑No ©NIA Pace Trip Blank Lot # (if purchased): Client Notification/ Resolution: Person Contacted, Comments/ Resolution: Date/Time: SCURF Review: 1 Date: z z5 S SRF Review: Date: i6� 1S Note: Whenever the is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office ( Le out of hold, incorrect preservative, out of temp, incorrect containers) Field Data Required? Y 1 N Place label here 9 �z3 OR Handwrite project number (if no label available) Page 56 of 57 r r gmm rn 0 o m m 2 rr sa cr u nn �m> CD 3 � n n I L N n c � n m n c -0 (n 3 Sy \\\ N u) Q m '! l� C� dV P C s VI Z -. Qi Customer, important: please indicate desired turnaround ly y 0 a �I 11 � 0 E �G 11II[111IIIII[[II�[ S7 o � a O Pr p Page 64 of 66 b v � Q O n l • M � .p II r O ` 000 C I 4rab � 13^ � 3 io �lN TSS.TOS i Methane (RSS( n 175j V-Shealy 2E Cl, SO4, I�1 -1 O S � S ! 1 10 �Y TOC, Nitrate- m ! i n R Nitrite Il ! �I Alkalk ity, o BloarlWMte, Carbonate -r g C V Shealy) Sulfide e 6 c (V_Element 1 ) i metals 1 s • r 3F TOUI Y Cordalnere tS N VI Page 57 of 57 Page 65 of 66 BA o W m a 3 C S G c S C m _ C 2M .C� C IN m D CAI f�+ N Cal n a 0 d N � n C S T W T C ,\ ro 3 (� L� 3 n � n All 9 ➢ 9 D Z e N 0 z -d n zy d� A- y N 03 � 1 � � N ? a 1. /C D a r N N N fl. A -- 7 _ 7 G Customer to complete appropri columns to �v Customer must ro y i m O. i7 0 I n <�,0 m � 2. C »= . 0 " 3 m m n n 3 : o O O x ro0 7 ➢ ry j n m C n ? o m _ C ` Gt0 N n � M m a v �o = a CD= Z n O CL w n (7 3 m w C O o n (n d o o ,ro u p 'm' » rt Z N M Z C rn,l;z Drn sddo 0 y K S G y 3 c n ; o. tD Q N H 1 1 >> w O O I 3 7 O M= rt l m y 1^ y n ! x 0 � r l o d Z !O N t—CZ D O Za N �' ii OI Z c 0 ii IN v aUD CD I I N ,C,AA I Y+ A Z 1 wio i i v •---•—•-----•� < — ° nQ jn D ^-�` 3 10 m` C) F� m o � v' 1D O 'LA 00 iZ I-� w�� 'D 1 I Z A=9 0 � d!r- o. • z � � lys S Z O I,� , O � l y' V^k r 01' "Grab Req ire �, ° r 3 ' Z) p IS I �: O ; 01 M Total Metals (PACE 5 s;A Anions (PACE) 5 N ➢ 0' 3 3 u y a' rn CDI N O i pH (PACE) 5 M m I o d I 0 SPLP - Total Metals and Anions (PACE) 5 A 0 C.) v_ ' Sediment specific tests (Access Analytical) 5 �x o 8 a Z to („ =I I ; Organic Carbon (Assess,Ax►al�rtlsal , IL 5 I � -.-•-•- 1 U SLI Oo U (7 y b z m �r��s iu r o p, '.—. r - D 20Total # of Containers \ 4 a X_ Page 66 of 66 v\�p - ----- ---- ---- ---- c om ustomer Must Cfete n 3 n CL n n V^. _ m I c W mm C - I -- C mLc c 33 S r c D 1 0 zz rw w o S- Jt dim C 1 n &n in 3 to j h h i f t G CrG O m 1 A W i on n: M ICD g w I D 3 c A a m W t; m D m m m E 0 3 m 3 m 3 W 3 m (n 0 m� 7 3 g o m i N r O 5.' 3 G x C O I Q n ae o ' I= g o r O D 3 f N� N _"OR.. n I$ m cQ o n D to o ii NlIzz CD ¢ A M P r � r O D 0 3 m r• c C) zC N io 3 D A Comp. r I M n41 �• TSS,TDS y 4 0 N c, Methane (RSK pIXI ' 175) V_Shealy m i �. �'s Cl, 504, m o i o C ym V TOC, Nitrate- Nitrite I o ! DI i m n Alkalinity, Bicarbonate, •o o, ! A O Customer, important: please indicate Carbonate m oo 3 i V Shealy) _ Z desired turnaround - a Sulfide $ N °m v o (V_Element1) c i i - I '--0- O �1 M . O a O a a a ? y d m 0 m ly o ID z m m D C _D C Oi' a _U a n D Metals (see o m o M below) Dissolved o N metals m N N z N F.T-_ o 0 0 0 0 0 0 0 0 0 0 0 0 0 Total # Containers 4