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NC0003433_J15020326 - Rev 1_20150902
DUKE ENERGY Revision 1 - April 2, 2015 Analytical Laboratory Page 1 of46 Order Number: Project Name: Customer Name(s): Customer Address: Lab Contact: Report Authorized By: (Signature) Program Comments: 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone:980-875-5245 Fax:980-875-4349 Order Summary Report J15020326 AB GW ASSESSMENT SOIL Tim Hunsucker, Chris Suttell, Kathy Webb, John Toepfer Margaret Galvin -Karr Phone: 980-875-5219 Date: 4/2/2015 Margaret Galvin -Karr Please contact the Program Manager (Margaret Galvin -Karr) with any questions regarding this report. Data Flags & Calculations: Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Revision 1 - April 2, 2015 Sample ID's & Descriptions: Page 2 of 46 Collection Sample ID Plant/Station Date and Time Collected By Sample Description 2015003846 Cape Fear 11-Feb-15 10:30 AM Chris Suttell MW-18SB (0-2) 2015003847 Cape Fear 11-Feb-15 10:45 AM Chris Suttell MW-18SB (25-3) 2015003848 Cape Fear 11-Feb-15 1:55 PM Chris Suttell MW-19SB (0-2) 2015003849 Cape Fear 11-Feb-15 2:10 PM Chris Suttell MW-19SB (4-5) 4 Total Samples Revision 1 - April 2, 2015 Page 3 of 46 Technical Validation Review Checklist: COC and .pdf report are in agreement with sample totals Yes No and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. ❑ Yes No All laboratory QA/QC requirements are acceptable. (] Yes ❑ No Report Sections Included: L� Job Summary Report ❑ Sample Identification n Technical Validation of Data Package 6 Analytical Laboratory Certificate of Analysis ❑ Analytical Laboratory QC Report LVI Sub -contracted Laboratory Results ❑ Customer Specific Data Sheets, Reports, & Documentation ❑ Customer Database Entries 6 Chain of Custody LVI Electronic Data Deliverable (EDD) Sent Separately Reviewed By: DBA Account Date: 3/5/2015 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15020326 Site: MW-18SB (0-2) Collection Date: 11-Feb-15 10:30 AM Analyte Result Units Qualifiers RDL DF DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Revision 1 - April 2, 2015 Page 4 of 46 Sample #: 2015003846 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15020326 Site: MW-18SB (25-3) Collection Date: 11-Feb-15 10:45 AM Analyte Result Units Qualifiers RDL DF DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Revision 1 - April 2, 2015 Page 5 of 46 Sample #: 2015003847 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15020326 Site: MW-19SB (0-2) Collection Date: 11-Feb-15 1:55 PM Analyte Result Units Qualifiers RDL DF DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Revision 1 - April 2, 2015 Page 6 of 46 Sample #: 2015003848 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15020326 Site: MW-19SB (4-5) Collection Date: 11-Feb-15 2:10 PM Analyte Result Units Qualifiers RDL DF DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Revision 1 - April 2, 2015 Page 7 of 46 Sample #: 2015003849 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE aceAnalyical www.pacelabs.com Pac Anr�timll�ervices, Inc. Revision 1 -9PU1 l9ig98M)e. Suite 100 Huntersville, INC 28078 (704)875-9092 March 03, 2015 Program Manager Duke Energy 13339 Hagers Ferry Road Bldg.7405 MG30A2 Huntersville, NC 28078 RE: Project: J 15020326 Pace Project No.: 92237648 Dear Program Manager: Enclosed are the analytical results for sample(s) received by the laboratory on February 12, 2015. The results relate only to the samples included in this report. Results reported herein conform to the most current TN standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Herring kevin.herring@pacelabs.com HORIZON Database Administrator Enclosures cc: Marge Galvin -Karr, Duke Energy Therona James, Duke Energy Program Manager, Duke Energy Rodney Wilke, Duke Energy p«FO REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, lqe� ��� without the written consent of Pace Analytical Services, Inc.. BRAT, Page 1 of 38 aceAnaiXical www.pacelabs.com Pac Anr�timll�ervices, Inc. Revision 1-�pvigc y4lje. Suite 100 Huntersville, NC 28078 (704)875-9092 CERTIFICATIONS Project: J15020326 Pace Project No.: 92237648 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Missouri Certification #: 236 Alabama Certification #: 41320 Montana Certification #: Cert 0074 Arizona Certification #: AZ0735 Nebraska Certification: NE-OS-28-14 Connecticut Certification #: PH-0216 Nevada Certification: FL NELAC Reciprocity Delaware Certification: FL NELAC Reciprocity New Hampshire Certification #: 2958 Florida Certification #: E83079 New Jersey Certification #: FL765 Georgia Certification #: 955 New York Certification #: 11608 Guam Certification: FL NELAC Reciprocity North Carolina Environmental Certificate #: 667 Hawaii Certification: FL NELAC Reciprocity Pennsylvania Certification #: 68-00547 Illinois Certification #: 200068 Puerto Rico Certification #: FLO1264 Indiana Certification: FL NELAC Reciprocity South Carolina Certification: #96042001 Kansas Certification #: E-10383 Tennessee Certification #: TN02974 Kentucky Certification #: 90050 Texas Certification: FL NELAC Reciprocity Louisiana Certification #: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Louisiana Environmental Certificate M 05007 Virginia Environmental Certification #: 460165 Maryland Certification: #346 Washington Certification #: C955 Massachusetts Certification #: M-FL1264 West Virginia Certification #: 9962C Michigan Certification #: 9911 Wisconsin Certification #: 399079670 Mississippi Certification: FL NELAC Reciprocity Wyoming (EPA Region 8): FL NELAC Reciprocity Green Bay Certification IDs 1241 Bellevue Street, Green Bay, WI 54302 New York Certification #: 11888 Florida/NELAP Certification #: E87948 North Dakota Certification #: R-150 Illinois Certification #: 200050 South Carolina Certification #: 83006001 Kentucky Certification #: 82 Texas Certification #: T104704529-14-1 Louisiana Certification #: 04168 US Dept of Agriculture M S-76505 Minnesota Certification #: 055-999-334 Wisconsin Certification #: 405132750 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 2 of 38 aceAnaiXical www.pacelabs.com Pac Anr�timll�ervices, Inc. Revision 1 - A n ORUIPli6c&M �e. Suite 100 y Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: J15020326 Pace Project No.: 92237648 Lab ID Sample ID Matrix Date Collected Date Received 92237648001 2015003846 Solid 02/11/1510:30 02/12/1517:25 92237648002 2015003847 Solid 02/11/1510:45 02/12/1517:25 92237648003 2015003848 Solid 02/11/1513:55 02/12/1517:25 92237648004 2015003849 Solid 02/11/1514:10 02/12/1517:25 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 3 of 38 aceAnalyical www.pacelabs.com Pac Anr�timll�ervices, Inc. Revision 1- A n �Q�fflinlc&fie. Suite100 y Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: J15020326 92237648 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92237648001 2015003846 EPA 6010 CKJ 15 PASI-0 EPA 6020 CRT, DRS 9 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 HEA 1 PASI-O EPA 9045 KAM 1 PASI-O EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92237648002 2015003847 EPA 6010 CKJ 15 PASI-0 EPA 6020 CRT 9 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 HEA 1 PASI-O EPA 9045 KAM 1 PASI-O EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92237648003 2015003848 EPA 6010 CKJ 15 PASI-0 EPA 6020 CRT 9 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 HEA 1 PASI-O EPA 9045 KAM 1 PASI-O EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92237648004 2015003849 EPA 6010 CKJ 15 PASI-0 EPA 6020 CRT 9 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 HEA 1 PASI-O EPA 9045 KAM 1 PASI-O EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 4 of 38 aceAnaiXical www.pacelabs.com Pac Anr�timll�ervices, Inc. Revision 1 - A n ORUIPli2c&M �e. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15020326 Pace Project No.: 92237648 Lab Sample ID Client Sample ID Method Parameters SUMMARY OF DETECTION Result Units Report Limit Analyzed 92237648001 2015003846 EPA 6010 Aluminum 11800 mg/kg 137 02/21/1517:15 D3 EPA 6010 Barium 103 mg/kg 0.69 02/20/15 18:51 EPA 6010 Calcium 664 mg/kg 34.3 02/20/15 18:51 EPA 6010 Chromium 16.4 mg/kg 6.9 02/21/1517:15 D3 EPA 6010 Copper 15.9 mg/kg 6.9 02/21/1517:15 D3 EPA 6010 Iron 17500 mg/kg 2.7 02/20/15 18:51 EPA 6010 Magnesium 1670 mg/kg 34.3 02/20/15 18:51 EPA 6010 Manganese 3520 mg/kg 6.9 02/21/1517:15 D3 EPA 6010 Nickel 6.5J mg/kg 6.9 02/21/1517:15 D3 EPA 6010 Potassium 73.5 mg/kg 68.7 02/20/15 18:51 EPA 6010 Sodium 241 mg/kg 68.7 02/20/15 18:51 EPA 6010 Strontium 10.2 mg/kg 0.69 02/20/15 18:51 EPA 6010 Zinc 29.1 mg/kg 27.5 02/21/1517:15 D3 EPA 6020 Beryllium 0.73 mg/kg 0.41 02/20/15 11:53 D3 EPA 6020 Cobalt 34.7 mg/kg 3.4 02/20/15 11:53 D4 EPA 6020 Lead 12.2 mg/kg 3.4 02/20/15 11:53 D3 EPA 6020 Vanadium 53.9 mg/kg 3.4 02/20/15 11:53 D4 EPA 7471 Mercury 0.050 mg/kg 0.011 02/22/15 10:12 ASTM D2974-87 Percent Moisture 28.3 % 0.10 02/26/15 12:00 EPA 9045 pH at 25 Degrees C 5.2 Std. Units 0.10 02/20/15 13:40 H6 EPA 9056 Sulfate 344J mg/kg 347 02/20/15 23:19 D3 EPA 9060 Total Organic Carbon 4250 mg/kg 598 02/19/15 08:45 EPA 9060 Total Organic Carbon 4230 mg/kg 601 02/19/15 08:50 EPA 9060 Total Organic Carbon 4660 mg/kg 605 02/19/15 08:57 EPA 9060 Total Organic Carbon 3900 mg/kg 596 02/19/15 09:04 EPA 9060 Mean Total Organic Carbon 4260 mg/kg 600 02/19/15 08:45 EPA 9060 RSD% 7.3 % 02/19/15 08:45 92237648002 2015003847 EPA 6010 Aluminum 9950 mg/kg 6.3 02/20/15 18:55 EPA 6010 Barium 43.9 mg/kg 0.63 02/20/15 18:55 EPA 6010 Calcium 444 mg/kg 31.3 02/20/15 18:55 EPA 6010 Chromium 14.8 mg/kg 0.31 02/20/15 18:55 EPA 6010 Copper 11.5 mg/kg 0.31 02/20/15 18:55 EPA 6010 Iron 15500 mg/kg 2.5 02/20/15 18:55 EPA 6010 Magnesium 1820 mg/kg 31.3 02/20/15 18:55 EPA 6010 Manganese 267 mg/kg 0.31 02/20/15 18:55 EPA 6010 Nickel 4.4 mg/kg 0.31 02/20/15 18:55 EPA 6010 Potassium 78.8 mg/kg 62.7 02/20/15 18:55 EPA 6010 Sodium 696 mg/kg 62.7 02/20/15 18:55 EPA 6010 Strontium 6.3 mg/kg 0.63 02/20/15 18:55 EPA 6010 Zinc 17.1 mg/kg 1.3 02/20/15 18:55 EPA 6020 Beryllium 0.27J mg/kg 0.38 02/20/15 11:56 D3 EPA 6020 Cobalt 6.0 mg/kg 3.1 02/20/15 11:56 D3 EPA 6020 Lead 9.6 mg/kg 3.1 02/20/15 11:56 D3 EPA 6020 Vanadium 45.3 mg/kg 3.1 02/20/15 11:56 D4 ASTM D2974-87 Percent Moisture 21.5 % 0.10 02/26/15 12:00 EPA 9045 pH at 25 Degrees C 4.5 Std. Units 0.10 02/20/15 13:40 H6 REPORT OF LABORATORY ANALYSIS Qualifiers This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 5 of 38 aceAnalyical www.pacelabs.com Pac Anr�timll�ervices, Inc. Revision 1 - A n ORUIPli9c&M �e. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15020326 Pace Project No.: 92237648 Lab Sample ID Client Sample ID Method Parameters SUMMARY OF DETECTION Result Units Report Limit Analyzed Qualifiers 92237648002 2015003847 EPA 9060 Total Organic Carbon 1560 mg/kg 601 02/19/15 09:53 EPA 9060 Total Organic Carbon 1520 mg/kg 601 02/19/15 09:59 EPA 9060 Total Organic Carbon 1340 mg/kg 597 02/19/15 10:05 EPA 9060 Total Organic Carbon 1360 mg/kg 601 02/19/15 10:12 EPA 9060 Mean Total Organic Carbon 1450 mg/kg 600 02/19/15 09:53 EPA 9060 RSD% 7.5 % 02/19/15 09:53 92237648003 2015003848 EPA 6010 Aluminum 9130 mg/kg 6.3 02/20/15 18:59 EPA 6010 Barium 58.0 mg/kg 0.63 02/20/15 18:59 EPA 6010 Calcium 215 mg/kg 31.4 02/20/15 18:59 EPA 6010 Chromium 26.5 mg/kg 0.31 02/20/15 18:59 EPA 6010 Copper 7.2 mg/kg 0.31 02/20/15 18:59 EPA 6010 Iron 19400 mg/kg 2.5 02/20/15 18:59 EPA 6010 Magnesium 294 mg/kg 31.4 02/20/15 18:59 EPA 6010 Manganese 2070 mg/kg 6.3 02/21/1517:24 EPA 6010 Nickel 3.9 mg/kg 0.31 02/20/15 18:59 EPA 6010 Potassium 88.6 mg/kg 62.9 02/20/15 18:59 EPA 6010 Strontium 4.4 mg/kg 0.63 02/20/15 18:59 EPA 6010 Zinc 8.2 mg/kg 1.3 02/20/15 18:59 EPA 6020 Arsenic 1.7J mg/kg 3.1 02/20/15 11:59 EPA 6020 Beryllium 0.46 mg/kg 0.38 02/20/15 11:59 EPA 6020 Cobalt 33.7 mg/kg 3.1 02/20/15 11:59 EPA 6020 Lead 23.4 mg/kg 3.1 02/20/15 11:59 EPA 6020 Vanadium 58.8 mg/kg 3.1 02/20/15 11:59 EPA 7471 Mercury 0.052 mg/kg 0.0096 02/22/15 10:21 ASTM D2974-87 Percent Moisture 19.7 % 0.10 02/26/15 12:00 EPA 9045 pH at 25 Degrees C 5.1 Std. Units 0.10 02/20/15 13:40 EPA 9056 Chloride 275J mg/kg 309 02/21/15 00:47 EPA 9056 Sulfate 447 mg/kg 309 02/21/15 00:47 EPA 9060 Total Organic Carbon 1590 mg/kg 603 02/19/15 10:17 EPA 9060 Total Organic Carbon 1610 mg/kg 599 02/19/15 10:24 EPA 9060 Total Organic Carbon 1670 mg/kg 598 02/19/15 10:29 EPA 9060 Total Organic Carbon 1570 mg/kg 604 02/19/15 10:35 EPA 9060 Mean Total Organic Carbon 1610 mg/kg 601 02/19/15 10:17 EPA 9060 RSD% 2.7 % 02/19/15 10:17 92237648004 2015003849 EPA 6010 Aluminum 13300 mg/kg 6.7 02/20/15 19:03 EPA 6010 Barium 41.8 mg/kg 0.67 02/20/15 19:03 EPA 6010 Boron 41.3J mg/kg 66.6 02/21/1517:42 EPA 6010 Calcium 259 mg/kg 33.3 02/20/15 19:03 EPA 6010 Chromium 17.8 mg/kg 0.33 02/20/15 19:03 EPA 6010 Copper 11.2 mg/kg 0.33 02/20/15 19:03 EPA 6010 Iron 38200 mg/kg 53.3 02/21/1517:42 EPA 6010 Magnesium 662 mg/kg 33.3 02/20/15 19:03 EPA 6010 Manganese 52.5 mg/kg 0.33 02/20/15 19:03 EPA 6010 Nickel 2.4 mg/kg 0.33 02/20/15 19:03 REPORT OF LABORATORY ANALYSIS D4 D3 D3 D4 D3 D4 H6 D3 D3 D4 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 6 of 38 aceAnalyical www.pacelabs.com Pac Anr�timll�ervices, Inc. Revision 1 - A n ORUIPli4c&M �e. Suite 100 y Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Project: J15020326 Pace Project No.: 92237648 Lab Sample ID Client Sample ID Method Parameters Result Units 92237648004 2015003849 EPA 6010 Potassium 108 mg/kg EPA 6010 Sodium 46.2J mg/kg EPA 6010 Strontium 7.5 mg/kg EPA 6010 Zinc 6.9 mg/kg EPA 6020 Beryllium 0.27J mg/kg EPA 6020 Lead 8.6 mg/kg EPA 6020 Vanadium 97.0 mg/kg EPA 7471 Mercury 0.098 mg/kg ASTM D2974-87 Percent Moisture 26.5 % EPA 9045 pH at 25 Degrees C 5.1 Std. Units EPA 9060 Total Organic Carbon 763 mg/kg EPA 9060 Total Organic Carbon 819 mg/kg EPA 9060 Total Organic Carbon 780 mg/kg EPA 9060 Total Organic Carbon 749 mg/kg EPA 9060 Mean Total Organic Carbon 778 mg/kg EPA 9060 RSD% 3.9 % REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Report Limit Analyzed Qualifiers 66.6 02/20/1519:03 66.6 02/20/1519:03 0.67 02/20/1519:03 1.3 02/20/1519:03 0.40 02/20/1512:02 D3 3.3 02/20/1512:02 D3 3.3 02/20/1512:02 D4 0.011 02/22/15 10:23 0.10 02/26/1512:00 0.10 02/20/1513:40 H6 601 02/19/15 10:41 605 02/19/1510:46 597 02/19/1510:53 603 02/19/1510:58 602 02/19/15 10:41 02/19/15 10:41 Page 7 of 38 aceAnaiXical www.pacelabs.com Pac Anr�timll�ervices, Inc. Revision 1 - A n ORU1 l998M)�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020326 Pace Project No.: 92237648 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: March 03, 2015 General Information: 4 samples were analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/22732 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92237739001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1134160) • Aluminum • Iron • Manganese • MSD (Lab ID: 1134161) • Aluminum • Iron • Manganese Additional Comments: Analyte Comments: QC Batch: MPRP/22732 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015003846 (Lab ID:92237648001) • Aluminum • Boron REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 8 of 38 aceAnalyical www.pacelabs.com Pac Anr�timll�ervices, Inc. Revision 1 - A n 09Q�ffi 98M)M e. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020326 Pace Project No.: 92237648 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: March 03, 2015 Analyte Comments: QC Batch: MPRP/22732 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015003846 (Lab ID:92237648001) • Chromium • Copper • Manganese • Molybdenum • Nickel • Zinc •2015003847 (Lab ID:92237648002) • Boron •2015003848 (Lab ID:92237648003) • Boron •2015003849 (Lab ID:92237648004) • Boron D4: Sample was diluted due to the presence of high levels of target analytes. •2015003848 (Lab ID:92237648003) • Manganese •2015003849 (Lab ID:92237648004) • Iron REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 9 of 38 aceAnaiXical www.pacelabs.com Pac Anr�timll�ervices, Inc. Revision 1 - A n ORUIPli9c&) �e. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020326 Pace Project No.: 92237648 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: March 03, 2015 General Information: 4 samples were analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/22733 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92237739001 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • MS (Lab ID: 1134164) • Antimony • Cadmium • Selenium • MSD (Lab ID: 1134165) • Antimony Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 10 of 38 aceAnalyical www.pacelabs.com Pac Anr�timll�ervices, Inc. Revision 1 - A n 09Q�ffl 98M)M e. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020326 Pace Project No.: 92237648 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: March 03, 2015 Analyte Comments: QC Batch: MPRP/22733 DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015003846 (Lab ID:92237648001) • Arsenic • Beryllium • Cadmium • Lead • Antimony • Selenium • Thallium •2015003847 (Lab ID:92237648002) • Arsenic • Beryllium • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium •2015003848 (Lab ID:92237648003) • Arsenic • Beryllium • Cadmium • Lead • Antimony • Selenium • Thallium •2015003849 (Lab ID:92237648004) • Arsenic • Beryllium • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium • MS (Lab ID: 1134164) • Arsenic • Beryllium • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 11 of 38 aceAnalyical www.pacelabs.com Pac Anr�timll�ervices, Inc. Revision 1 - A n 09Q�ffi 98M)M e. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020326 Pace Project No.: 92237648 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: March 03, 2015 Analyte Comments: QC Batch: MPRP/22733 DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. • MS (Lab ID: 1134164) • Vanadium • MSD (Lab ID: 1134165) • Arsenic • Beryllium • Cadmium • Cobalt • Lead • Antimony • Selenium • Thallium • Vanadium D4: Sample was diluted due to the presence of high levels of target analytes. •2015003846 (Lab ID:92237648001) • Cobalt • Vanadium •2015003847 (Lab ID:92237648002) • Vanadium •2015003848 (Lab ID:92237648003) • Cobalt • Vanadium •2015003849 (Lab ID:92237648004) • Vanadium N2: The lab does not hold TNI accreditation for this parameter. •2015003846 (Lab ID:92237648001) • Antimony •2015003847 (Lab ID:92237648002) • Antimony •2015003848 (Lab ID:92237648003) • Antimony •2015003849 (Lab ID:92237648004) • Antimony • BLANK (Lab ID: 1134162) • Antimony • LCS (Lab ID: 1134163) • Antimony • MS (Lab ID: 1134164) • Antimony • MSD (Lab ID: 1134165) • Antimony REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 12 of 38 aceAnaiXical www.pacelabs.com Pac Anr�timll�ervices, Inc. Revision 1 - Apn 09Q�KP 98M)) e. Suite 100 yy Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020326 Pace Project No.: 92237648 Method: EPA 7471 Description: 7471 Mercury Client: Duke Energy Date: March 03, 2015 General Information: 4 samples were analyzed for EPA 7471. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7471 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 13 of 38 aceAnaiXical www.pacelabs.com Pac Anr�timll�ervices, Inc. Revision 1 - Apn 095l9nic&��e. Suite100 yy Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020326 Pace Project No.: 92237648 Method: EPA 9045 Description: 9045 pH Soil Client: Duke Energy Date: March 03, 2015 General Information: 4 samples were analyzed for EPA 9045. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 1-16: Analysis initiated outside of the 15 minute EPA recommended holding time. •2015003846 (Lab ID:92237648001) •2015003847 (Lab ID:92237648002) •2015003848 (Lab ID:92237648003) •2015003849 (Lab ID:92237648004) Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 14 of 38 aceAnaiXical www.pacelabs.com Pac Anr�timll�ervices, Inc. Revision 1 - Apn 095I9298M)�e. Suite 100 yy Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020326 Pace Project No.: 92237648 Method: EPA 9056 Description: 9056 IC Anions Client: Duke Energy Date: March 03, 2015 General Information: 4 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/43844 DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015003846 (Lab ID:92237648001) • Chloride • Sulfate •2015003847 (Lab ID:92237648002) • Chloride • Sulfate •2015003848 (Lab ID:92237648003) • Chloride •2015003849 (Lab ID:92237648004) • Chloride • Sulfate REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 15 of 38 aceAnaiXical www.pacelabs.com Pac Anr�timll�ervices, Inc. Revision 1 - A n 095l9S%Ml) e. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020326 Pace Project No.: 92237648 Method: EPA 9056 Description: 9056 IC Anions 48hr Client: Duke Energy Date: March 03, 2015 General Information: 4 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 1-13: Sample was received or analysis requested beyond the recognized method holding time. •2015003846 (Lab ID:92237648001) •2015003847 (Lab ID:92237648002) •2015003848 (Lab ID:92237648003) •2015003849 (Lab ID:92237648004) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 16 of 38 aceAnaiXical www.pacelabs.com Pac Anr�timll�ervices, Inc. Revision 1 - Apn 09Q�KP 98M)M e. Suite 100 yy Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15020326 Pace Project No.: 92237648 Method: EPA 9060 Description: Total Organic Carbon Quad Client: Duke Energy Date: March 03, 2015 General Information: 4 samples were analyzed for EPA 9060. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: This data package has been reviewed for quality and completeness and is approved for release. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 17 of 38 aceAnalyical www.pacelabs.com Pac Anr�timll�ervices, Inc. Revision 1- Apn 09Q�KP 98MIM e. Suite 100 yy Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15020326 Pace Project No.: 92237648 Sample: 2015003846 Lab ID: 92237648001 Collected: 02/11/15 10:30 Received: 02/12/15 17:25 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 11800 mg/kg 137 68.7 20 02/18/1515:48 02/21/1517:15 7429-90-5 Barium 103 mg/kg 0.69 0.34 1 02/18/1515:48 02/20/1518:51 7440-39-3 Boron ND mg/kg 68.7 34.3 20 02/18/1515:48 02/21/1517:15 7440-42-8 Calcium 664 mg/kg 34.3 17.2 1 02/18/1515:48 02/20/1518:51 7440-70-2 Chromium 16.4 mg/kg 6.9 3.4 20 02/18/1515:48 02/21/1517:15 7440-47-3 Copper 15.9 mg/kg 6.9 3.4 20 02/18/1515:48 02/21/1517:15 7440-50-8 Iron 17500 mg/kg 2.7 1.4 1 02/18/1515:48 02/20/1518:51 7439-89-6 Magnesium 1670 mg/kg 34.3 17.2 1 02/18/1515:48 02/20/1518:51 7439-95-4 Manganese 3520 mg/kg 6.9 3.4 20 02/18/1515:48 02/21/1517:15 7439-96-5 Molybdenum ND mg/kg 13.7 6.9 20 02/18/1515:48 02/21/1517:15 7439-98-7 Nickel 6.5J mg/kg 6.9 3.4 20 02/18/1515:48 02/21/1517:15 7440-02-0 Potassium 73.5 mg/kg 68.7 34.3 1 02/18/1515:48 02/20/1518:51 7440-09-7 Sodium 241 mg/kg 68.7 34.3 1 02/18/1515:48 02/20/1518:51 7440-23-5 Strontium 10.2 mg/kg 0.69 0.34 1 02/18/1515:48 02/20/1518:51 7440-24-6 Zinc 29.1 mg/kg 27.5 13.7 20 02/18/1515:48 02/21/1517:15 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 3.4 1.7 50 02/18/1515:48 02/20/1511:53 7440-36-0 Arsenic ND mg/kg 3.4 1.7 50 02/18/1515:48 02/20/1511:53 7440-38-2 Beryllium 0.73 mg/kg 0.41 0.21 50 02/18/1515:48 02/20/1511:53 7440-41-7 Cadmium ND mg/kg 0.41 0.21 50 02/18/1515:48 02/23/1512:06 7440-43-9 Cobalt 34.7 mg/kg 3.4 1.7 50 02/18/1515:48 02/20/1511:53 7440-48-4 Lead 12.2 mg/kg 3.4 1.7 50 02/18/1515:48 02/20/1511:53 7439-92-1 Selenium ND mg/kg 3.4 1.7 50 02/18/1515:48 02/20/1511:53 7782-49-2 Thallium ND mg/kg 3.4 1.7 50 02/18/1515:48 02/20/1511:53 7440-28-0 Vanadium 53.9 mg/kg 3.4 1.7 50 02/18/1515:48 02/20/1511:53 7440-62-2 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury 0.050 mg/kg 0.011 0.0055 1 02/18/1517:58 02/22/1510:12 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 28.3 % 0.10 0.10 1 02/26/15 12:00 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 5.2 Std. Units 0.10 0.10 1 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 347 173 5 Sulfate 344J mg/kg 347 173 5 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 34.7 17.3 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/03/2015 12:20 PM without the written consent of Pace Analytical Services, Inc.. D3 D3 D3 D3 D3 D3 D3 D3 D3,N2 D3 D3 D3 D4 D3 D3 D3 D4 02/20/15 23:19 16887-00-6 D3,M1 02/20/15 23:19 14808-79-8 D3 02/20/15 23:19 14797-55-8 H3 Page 18 of 38 aceAnalyical www.pacelabs.com Pac Anr�timll�ervices, Inc. Revision 1- Apn 09Q�KP 98M)M e. Suite 100 yy Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15020326 Pace Project No.: 92237648 Sample: 2015003846 Lab ID: 92237648001 Collected: 02/11/15 10:30 Received: 02/12/15 17:25 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 4250 mg/kg 598 299 1 02/19/15 08:45 7440-44-0 Total Organic Carbon 4230 mg/kg 601 300 1 02/19/15 08:50 7440-44-0 Total Organic Carbon 4660 mg/kg 605 302 1 02/19/15 08:57 7440-44-0 Total Organic Carbon 3900 mg/kg 596 298 1 02/19/15 09:04 7440-44-0 Mean Total Organic Carbon 4260 mg/kg 600 300 1 02/19/15 08:45 7440-44-0 Surrogates RSD% 7.3 % 1 02/19/15 08:45 Date: 03/03/2015 12:20 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 19 of 38 aceAnalyical www.pacelabs.com Pac Anr�timll�ervices, Inc. Revision 1- Apn ORQItr� 98MI�e. Suite 100 yy Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15020326 Pace Project No.: 92237648 Sample: 2015003847 Lab ID: 92237648002 Collected: 02/11/15 10:45 Received: 02/12/15 17:25 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 9950 mg/kg 6.3 3.1 1 02/18/1515:48 02/20/1518:55 7429-90-5 Barium 43.9 mg/kg 0.63 0.31 1 02/18/1515:48 02/20/1518:55 7440-39-3 Boron ND mg/kg 62.7 31.3 20 02/18/1515:48 02/21/1517:20 7440-42-8 Calcium 444 mg/kg 31.3 15.7 1 02/18/1515:48 02/20/1518:55 7440-70-2 Chromium 14.8 mg/kg 0.31 0.16 1 02/18/1515:48 02/20/1518:55 7440-47-3 Copper 11.5 mg/kg 0.31 0.16 1 02/18/1515:48 02/20/1518:55 7440-50-8 Iron 15500 mg/kg 2.5 1.3 1 02/18/1515:48 02/20/1518:55 7439-89-6 Magnesium 1820 mg/kg 31.3 15.7 1 02/18/1515:48 02/20/1518:55 7439-95-4 Manganese 267 mg/kg 0.31 0.16 1 02/18/1515:48 02/20/1518:55 7439-96-5 Molybdenum ND mg/kg 0.63 0.31 1 02/18/1515:48 02/20/1518:55 7439-98-7 Nickel 4.4 mg/kg 0.31 0.16 1 02/18/1515:48 02/20/1518:55 7440-02-0 Potassium 78.8 mg/kg 62.7 31.3 1 02/18/1515:48 02/20/1518:55 7440-09-7 Sodium 696 mg/kg 62.7 31.3 1 02/18/1515:48 02/20/1518:55 7440-23-5 Strontium 6.3 mg/kg 0.63 0.31 1 02/18/1515:48 02/20/1518:55 7440-24-6 Zinc 17.1 mg/kg 1.3 0.63 1 02/18/1515:48 02/20/1518:55 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 3.1 1.6 50 02/18/1515:48 02/20/1511:56 7440-36-0 Arsenic ND mg/kg 3.1 1.6 50 02/18/1515:48 02/20/1511:56 7440-38-2 Beryllium 0.27J mg/kg 0.38 0.19 50 02/18/1515:48 02/20/1511:56 7440-41-7 Cadmium ND mg/kg 0.38 0.19 50 02/18/1515:48 02/20/1511:56 7440-43-9 Cobalt 6.0 mg/kg 3.1 1.6 50 02/18/1515:48 02/20/1511:56 7440-48-4 Lead 9.6 mg/kg 3.1 1.6 50 02/18/1515:48 02/20/1511:56 7439-92-1 Selenium ND mg/kg 3.1 1.6 50 02/18/1515:48 02/20/1511:56 7782-49-2 Thallium ND mg/kg 3.1 1.6 50 02/18/1515:48 02/20/1511:56 7440-28-0 Vanadium 45.3 mg/kg 3.1 1.6 50 02/18/1515:48 02/20/1511:56 7440-62-2 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury ND mg/kg 0.0098 0.0049 1 02/18/1517:58 02/22/1510:18 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 21.5 % 0.10 0.10 1 02/26/15 12:00 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 4.5 Std. Units 0.10 0.10 1 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 322 161 5 Sulfate ND mg/kg 322 161 5 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 32.2 16.1 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/03/2015 12:20 PM without the written consent of Pace Analytical Services, Inc.. D3 D3,N2 D3 D3 D3 D3 D3 D3 D3 D4 02/21/15 00:25 16887-00-6 D3 02/21/15 00:25 14808-79-8 D3 02/21/15 00:25 14797-55-8 H3 Page 20 of 38 aceAnalyical www.pacelabs.com Pac Anr�timll�ervices, Inc. Revision 1- Apn 09Q�tf�%c&M�e. Suite100 yy Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15020326 Pace Project No.: 92237648 Sample: 2015003847 Lab ID: 92237648002 Collected: 02/11/15 10:45 Received: 02/12/15 17:25 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 1560 mg/kg 601 300 1 02/19/15 09:53 7440-44-0 Total Organic Carbon 1520 mg/kg 601 301 1 02/19/15 09:59 7440-44-0 Total Organic Carbon 1340 mg/kg 597 298 1 02/19/15 10:05 7440-44-0 Total Organic Carbon 1360 mg/kg 601 300 1 02/19/15 10:12 7440-44-0 Mean Total Organic Carbon 1450 mg/kg 600 300 1 02/19/15 09:53 7440-44-0 Surrogates RSD% 7.5 % 1 02/19/15 09:53 Date: 03/03/2015 12:20 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 21 of 38 aceAnalyical www.pacelabs.com Pac Anr�timll�ervices, Inc. Revision 1- Apntr 09Q�98MIM e. Suite 100 yy Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15020326 Pace Project No.: 92237648 Sample: 2015003848 Lab ID: 92237648003 Collected: 02/11/15 13:55 Received: 02/12/15 17:25 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 9130 mg/kg 6.3 3.1 1 02/18/1515:48 02/20/1518:59 7429-90-5 Barium 58.0 mg/kg 0.63 0.31 1 02/18/1515:48 02/20/1518:59 7440-39-3 Boron ND mg/kg 62.9 31.4 20 02/18/1515:48 02/21/1517:24 7440-42-8 Calcium 215 mg/kg 31.4 15.7 1 02/18/1515:48 02/20/1518:59 7440-70-2 Chromium 26.5 mg/kg 0.31 0.16 1 02/18/1515:48 02/20/1518:59 7440-47-3 Copper 7.2 mg/kg 0.31 0.16 1 02/18/1515:48 02/20/1518:59 7440-50-8 Iron 19400 mg/kg 2.5 1.3 1 02/18/1515:48 02/20/1518:59 7439-89-6 Magnesium 294 mg/kg 31.4 15.7 1 02/18/1515:48 02/20/1518:59 7439-95-4 Manganese 2070 mg/kg 6.3 3.1 20 02/18/1515:48 02/21/1517:24 7439-96-5 Molybdenum ND mg/kg 0.63 0.31 1 02/18/1515:48 02/20/1518:59 7439-98-7 Nickel 3.9 mg/kg 0.31 0.16 1 02/18/1515:48 02/20/1518:59 7440-02-0 Potassium 88.6 mg/kg 62.9 31.4 1 02/18/1515:48 02/20/1518:59 7440-09-7 Sodium ND mg/kg 62.9 31.4 1 02/18/1515:48 02/20/1518:59 7440-23-5 Strontium 4.4 mg/kg 0.63 0.31 1 02/18/1515:48 02/20/1518:59 7440-24-6 Zinc 8.2 mg/kg 1.3 0.63 1 02/18/1515:48 02/20/1518:59 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 3.1 1.6 50 02/18/1515:48 02/20/1511:59 7440-36-0 Arsenic 1.7J mg/kg 3.1 1.6 50 02/18/1515:48 02/20/1511:59 7440-38-2 Beryllium 0.46 mg/kg 0.38 0.19 50 02/18/1515:48 02/20/1511:59 7440-41-7 Cadmium ND mg/kg 0.38 0.19 50 02/18/1515:48 02/20/1511:59 7440-43-9 Cobalt 33.7 mg/kg 3.1 1.6 50 02/18/1515:48 02/20/1511:59 7440-48-4 Lead 23.4 mg/kg 3.1 1.6 50 02/18/1515:48 02/20/1511:59 7439-92-1 Selenium ND mg/kg 3.1 1.6 50 02/18/1515:48 02/20/1511:59 7782-49-2 Thallium ND mg/kg 3.1 1.6 50 02/18/1515:48 02/20/1511:59 7440-28-0 Vanadium 58.8 mg/kg 3.1 1.6 50 02/18/1515:48 02/20/1511:59 7440-62-2 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury 0.052 mg/kg 0.0096 0.0048 1 02/18/1517:58 02/22/1510:21 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 19.7 % 0.10 0.10 1 02/26/15 12:00 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 5.1 Std. Units 0.10 0.10 1 9056 IC Anions Analytical Method: EPA 9056 Chloride 275J mg/kg 309 155 5 Sulfate 447 mg/kg 309 155 5 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 30.9 15.5 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/03/2015 12:20 PM without the written consent of Pace Analytical Services, Inc.. D3 D4 D3,N2 D3 D3 D3 D4 D3 D3 D3 D4 02/21/15 00:47 16887-00-6 D3 02/21/15 00:47 14808-79-8 02/21/15 00:47 14797-55-8 H3 Page 22 of 38 aceAnalyical www.pacelabs.com Pac Anr�timll�ervices, Inc. Revision 1- A n ORU10698M)�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15020326 Pace Project No.: 92237648 Sample: 2015003848 Lab ID: 92237648003 Collected: 02/11/15 13:55 Received: 02/12/15 17:25 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 1590 mg/kg 603 302 1 02/19/15 10:17 7440-44-0 Total Organic Carbon 1610 mg/kg 599 299 1 02/19/15 10:24 7440-44-0 Total Organic Carbon 1670 mg/kg 598 299 1 02/19/15 10:29 7440-44-0 Total Organic Carbon 1570 mg/kg 604 302 1 02/19/15 10:35 7440-44-0 Mean Total Organic Carbon 1610 mg/kg 601 301 1 02/19/15 10:17 7440-44-0 Surrogates RSD% 2.7 % 1 02/19/15 10:17 Date: 03/03/2015 12:20 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 23 of 38 aceAnalyical www.pacelabs.com Pac Anr�timll�ervices, Inc. Revision 1- A n ORUIOinic&��e. Suite100 y Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15020326 Pace Project No.: 92237648 Sample: 2015003849 Lab ID: 92237648004 Collected: 02/11/15 14:10 Received: 02/12/15 17:25 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 13300 mg/kg 6.7 3.3 1 02/18/1515:48 02/20/1519:03 7429-90-5 Barium 41.8 mg/kg 0.67 0.33 1 02/18/1515:48 02/20/1519:03 7440-39-3 Boron 41.3J mg/kg 66.6 33.3 20 02/18/1515:48 02/21/1517:42 7440-42-8 Calcium 259 mg/kg 33.3 16.6 1 02/18/1515:48 02/20/1519:03 7440-70-2 Chromium 17.8 mg/kg 0.33 0.17 1 02/18/1515:48 02/20/1519:03 7440-47-3 Copper 11.2 mg/kg 0.33 0.17 1 02/18/1515:48 02/20/1519:03 7440-50-8 Iron 38200 mg/kg 53.3 26.6 20 02/18/1515:48 02/21/1517:42 7439-89-6 Magnesium 662 mg/kg 33.3 16.6 1 02/18/1515:48 02/20/1519:03 7439-95-4 Manganese 52.5 mg/kg 0.33 0.17 1 02/18/1515:48 02/20/1519:03 7439-96-5 Molybdenum ND mg/kg 0.67 0.33 1 02/18/1515:48 02/20/1519:03 7439-98-7 Nickel 2.4 mg/kg 0.33 0.17 1 02/18/1515:48 02/20/1519:03 7440-02-0 Potassium 108 mg/kg 66.6 33.3 1 02/18/1515:48 02/20/1519:03 7440-09-7 Sodium 46.2J mg/kg 66.6 33.3 1 02/18/1515:48 02/20/1519:03 7440-23-5 Strontium 7.5 mg/kg 0.67 0.33 1 02/18/1515:48 02/20/1519:03 7440-24-6 Zinc 6.9 mg/kg 1.3 0.67 1 02/18/1515:48 02/20/1519:03 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 3.3 1.7 50 02/18/1515:48 02/20/1512:02 7440-36-0 Arsenic ND mg/kg 3.3 1.7 50 02/18/1515:48 02/20/1512:02 7440-38-2 Beryllium 0.27J mg/kg 0.40 0.20 50 02/18/1515:48 02/20/1512:02 7440-41-7 Cadmium ND mg/kg 0.40 0.20 50 02/18/1515:48 02/20/1512:02 7440-43-9 Cobalt ND mg/kg 3.3 1.7 50 02/18/1515:48 02/20/1512:02 7440-48-4 Lead 8.6 mg/kg 3.3 1.7 50 02/18/1515:48 02/20/1512:02 7439-92-1 Selenium ND mg/kg 3.3 1.7 50 02/18/1515:48 02/20/1512:02 7782-49-2 Thallium ND mg/kg 3.3 1.7 50 02/18/1515:48 02/20/1512:02 7440-28-0 Vanadium 97.0 mg/kg 3.3 1.7 50 02/18/1515:48 02/20/1512:02 7440-62-2 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury 0.098 mg/kg 0.011 0.0053 1 02/18/1517:58 02/22/1510:23 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 26.5 % 0.10 0.10 1 02/26/15 12:00 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 5.1 Std. Units 0.10 0.10 1 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 338 169 5 Sulfate ND mg/kg 338 169 5 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 33.8 16.9 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/03/2015 12:20 PM without the written consent of Pace Analytical Services, Inc.. D3 D4 D3,N2 D3 D3 D3 D3 D3 D3 D3 D4 02/21/15 01:09 16887-00-6 D3 02/21/15 01:09 14808-79-8 D3 02/21/15 01:09 14797-55-8 H3 Page 24 of 38 aceAnalyical www.pacelabs.com Pac Anr�timll�ervices, Inc. Revision 1- A n ORU10298M)�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15020326 Pace Project No.: 92237648 Sample: 2015003849 Lab ID: 92237648004 Collected: 02/11/15 14:10 Received: 02/12/15 17:25 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 763 mg/kg 601 301 1 02/19/15 10:41 7440-44-0 Total Organic Carbon 819 mg/kg 605 303 1 02/19/15 10:46 7440-44-0 Total Organic Carbon 780 mg/kg 597 299 1 02/19/15 10:53 7440-44-0 Total Organic Carbon 749 mg/kg 603 302 1 02/19/15 10:58 7440-44-0 Mean Total Organic Carbon 778 mg/kg 602 301 1 02/19/15 10:41 7440-44-0 Surrogates RSD% 3.9 % 1 02/19/15 10:41 Date: 03/03/2015 12:20 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 25 of 38 aceAnaiXical www.pacelabs.com Pac Anr�timll�ervices, Inc. Revision 1 - A n ORUIOSCW'I�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15020326 Pace Project No.: 92237648 QC Batch: MERP/5386 Analysis Method: EPA 7471 QC Batch Method: EPA 7471 Analysis Description: 7471 Mercury Associated Lab Samples: 92237648001, 92237648002, 92237648003, 92237648004 METHOD BLANK: 1134154 Matrix: Solid Associated Lab Samples: 92237648001, 92237648002, 92237648003, 92237648004 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury mg/kg ND 0.0082 02/22/15 09:33 LABORATORY CONTROL SAMPLE: 1134155 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury mg/kg .08 0.082 102 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1134156 1134157 MS MSD 92237650015 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury mg/kg 0.022 .077 .081 0.098 0.097 98 92 80-120 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/03/2015 12:20 PM without the written consent of Pace Analytical Services, Inc.. Page 26 of 38 aceAnaiXical www.pacelabs.com Pac Anr�timll�ervices, Inc. Revision 1 - A n ORU10498MI�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15020326 Pace Project No.: 92237648 QC Batch: MPRP/22732 Analysis Method: EPA 6010 QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid Associated Lab Samples: 92237648001, 92237648002, 92237648003, 92237648004 METHOD BLANK: 1134158 Matrix: Solid Associated Lab Samples: 92237648001, 92237648002, 92237648003, 92237648004 Blank Reporting Parameter Units Result Limit Analyzed Aluminum mg/kg ND 5.0 02/21/1515:20 Barium mg/kg ND 0.50 02/21/1515:20 Boron mg/kg ND 2.5 02/21/1515:20 Calcium mg/kg ND 25.2 02/21/1515:20 Chromium mg/kg ND 0.25 02/21/1515:20 Copper mg/kg ND 0.25 02/21/1515:20 Iron mg/kg ND 2.0 02/21/1515:20 Magnesium mg/kg ND 25.2 02/21/1515:20 Manganese mg/kg ND 0.25 02/21/1515:20 Molybdenum mg/kg ND 0.50 02/21/1515:20 Nickel mg/kg ND 0.25 02/21/1515:20 Potassium mg/kg ND 50.4 02/21/1515:20 Sodium mg/kg ND 50.4 02/21/1515:20 Strontium mg/kg ND 0.50 02/21/1515:20 Zinc mg/kg ND 1.0 02/21/1515:20 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 1134159 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Aluminum mg/kg 124 124 100 80-120 Barium mg/kg 12.4 12.5 101 80-120 Boron mg/kg 124 126 102 80-120 Calcium mg/kg 619 612 99 80-120 Chromium mg/kg 12.4 12.2 98 80-120 Copper mg/kg 12.4 12.2 99 80-120 Iron mg/kg 124 118 96 80-120 Magnesium mg/kg 619 623 101 80-120 Manganese mg/kg 12.4 12.5 101 80-120 Molybdenum mg/kg 12.4 12.6 102 80-120 Nickel mg/kg 12.4 12.6 102 80-120 Potassium mg/kg 619 608 98 80-120 Sodium mg/kg 619 612 99 80-120 Strontium mg/kg 12.4 12.7 103 80-120 Zinc mg/kg 61.9 63.3 102 80-120 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/03/2015 12:20 PM without the written consent of Pace Analytical Services, Inc.. Page 27 of 38 aceAnaiXical www.pacelabs.com Pac Anr�timll�ervices, Inc. Revision 1- A n 09Q�K3 98M)M e. Suite 100 y Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15020326 Pace Project No.: 92237648 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1134160 1134161 MS MSD 92237739001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum mg/kg 2590 121 127 4990 5000 1990 1900 75-125 0 20 M1 Barium mg/kg 5.6 12.1 12.7 19.8 19.8 117 112 75-125 0 20 Boron mg/kg 3.3 121 127 113 112 91 86 75-125 1 20 Calcium mg/kg ND 604 633 624 612 100 94 75-125 2 20 Chromium mg/kg 3.2 12.1 12.7 14.9 15.2 97 95 75-125 2 20 Copper mg/kg 1.8 12.1 12.7 14.0 14.0 101 97 75-125 0 20 Iron mg/kg 3270 121 127 3800 3850 440 464 75-125 1 20 M1 Magnesium mg/kg 99.9 604 633 774 761 112 104 75-125 2 20 Manganese mg/kg 21.4 12.1 12.7 29.7 29.0 69 60 75-125 3 20 M1 Molybdenum mg/kg ND 12.1 12.7 10.2 10.8 84 85 75-125 6 20 Nickel mg/kg 0.94 12.1 12.7 13.4 14.1 103 104 75-125 5 20 Potassium mg/kg 58.6 604 633 660 682 100 99 75-125 3 20 Sodium mg/kg ND 604 633 608 608 100 95 75-125 0 20 Strontium mg/kg 0.49 12.1 12.7 12.6 13.4 100 102 75-125 6 20 Zinc mg/kg 2.6 60.4 63.3 63.6 65.6 101 100 75-125 3 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/03/2015 12:20 PM without the written consent of Pace Analytical Services, Inc.. Page 28 of 38 aceAnaiXical www.pacelabs.com Pac Anr�timll�ervices, Inc. Revision 1 - A n 09Q�K3 98MIM e. Suite 100 y Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15020326 Pace Project No.: 92237648 QC Batch: MPRP/22733 Analysis Method: EPA 6020 QC Batch Method: EPA 3050 Analysis Description: 6020 MET Associated Lab Samples: 92237648001, 92237648002, 92237648003, 92237648004 METHOD BLANK: 1134162 Matrix: Solid Associated Lab Samples: 92237648001, 92237648002, 92237648003, 92237648004 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Antimony mg/kg ND 0.051 02/20/1510:43 N2 Arsenic mg/kg ND 0.051 02/20/1510:43 Beryllium mg/kg ND 0.0061 02/20/1510:43 Cadmium mg/kg ND 0.0061 02/20/1510:43 Cobalt mg/kg ND 0.051 02/20/1510:43 Lead mg/kg ND 0.051 02/20/1510:43 Selenium mg/kg ND 0.051 02/20/1510:43 Thallium mg/kg ND 0.051 02/20/1510:43 Vanadium mg/kg ND 0.051 02/20/1510:43 LABORATORY CONTROL SAMPLE: Parameter 1134163 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Antimony mg/kg 2.5 2.4 94 80-120 N2 Arsenic mg/kg 2.5 2.5 100 80-120 Beryllium mg/kg .25 0.25 100 80-120 Cadmium mg/kg .25 0.25 98 80-120 Cobalt mg/kg 2.5 2.6 103 80-120 Lead mg/kg 2.5 2.6 102 80-120 Selenium mg/kg 2.5 2.5 98 80-120 Thallium mg/kg 2.5 2.5 100 80-120 Vanadium mg/kg 2.5 2.5 98 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1134164 MS 92237739001 Spike Parameter Units Result Conc. MSD Spike Conc. 1134165 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits Max RPD RPD Qual Antimony mg/kg ND 2.5 2.5 1AJ 1.6J 56 64 75-125 20 D3,M6, N2 Arsenic mg/kg ND 2.5 2.5 3.0 2.9 92 89 75-125 4 20 D3 Beryllium mg/kg ND .25 .25 0.38 0.41 87 100 75-125 7 20 D3 Cadmium mg/kg ND .25 .25 0.32 0.22J 127 89 75-125 20 D3,M6 Cobalt mg/kg ND 2.5 2.5 3.9 3.7 103 99 75-125 5 20 D3 Lead mg/kg 3.2 2.5 2.5 5.9 5.7 109 104 75-125 3 20 D3 Selenium mg/kg ND 2.5 2.5 2.3J 2.6 68 79 75-125 20 D3,M6 Thallium mg/kg ND 2.5 2.5 2.6 2AJ 87 81 75-125 20 D3 Vanadium mg/kg 7.9 2.5 2.5 10.9 10.5 117 102 75-125 4 20 D3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/03/2015 12:20 PM without the written consent of Pace Analytical Services, Inc.. Page 29 of 38 aceAnaiXical www.pacelabs.com Pac Anr�timll�ervices, Inc. Revision 1 - A n 095'S�c&M �e. Suite 100 y Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15020326 Pace Project No.: 92237648 QC Batch: PMST/3288 Analysis Method: ASTM D2974-87 QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture Associated Lab Samples: 92237648001, 92237648002, 92237648003, 92237648004 SAMPLE DUPLICATE: 1140613 35175323001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 99.0 99.0 0 10 SAMPLE DUPLICATE: 1140614 35176352001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 12.0 13.0 8 10 SAMPLE DUPLICATE: 1140615 35176352010 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 11.2 11.7 5 10 SAMPLE DUPLICATE: 1140616 35176478008 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 4.5 4.6 4 10 SAMPLE DUPLICATE: 1140617 35176618001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 9.2 9.6 5 10 SAMPLE DUPLICATE: 1140618 35176830001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 6.3 8.3 26 10 D6 SAMPLE DUPLICATE: 1140619 35176427006 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 14.0 16.0 13 10 D6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/03/2015 12:20 PM without the written consent of Pace Analytical Services, Inc.. Page 30 of 38 aceAnaiXical www.pacelabs.com Pac Anr�timll�ervices, Inc. Revision 1 - A n 09Q�K3 98M)M e. Suite 100 y Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15020326 Pace Project No.: 92237648 QC Batch: WET/29355 Analysis Method: EPA 9045 QC Batch Method: EPA 9045 Analysis Description: 9045 pH Associated Lab Samples: 92237648001, 92237648002, 92237648003, 92237648004 SAMPLE DUPLICATE: 1136238 92237903003 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 5.6 5.6 0 20 H6 SAMPLE DUPLICATE: 1136794 92237904003 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 7.0 7.0 0 20 H6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/03/2015 12:20 PM without the written consent of Pace Analytical Services, Inc.. Page 31 of 38 aceAnaiXical www.pacelabs.com Pac Anr�timll�ervices, Inc. Revision 1 - A n 09Q�K3 98MIM e. Suite 100 y Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15020326 Pace Project No.: 92237648 QC Batch: WETA/43844 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92237648001, 92237648002, 92237648003, 92237648004 METHOD BLANK: 1136814 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/kg ND 49.9 02/20/15 22:34 Sulfate mg/kg ND 49.9 02/20/15 22:34 LABORATORY CONTROL SAMPLE: 1136815 Parameter Units Chloride mg/kg Sulfate mg/kg MATRIX SPIKE SAMPLE: 1136817 Parameter Units Chloride mg/kg Sulfate mg/kg SAMPLE DUPLICATE: 1136816 Parameter Chloride Sulfate Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 499 528 106 80-120 499 524 105 80-120 92237648001 Spike MS MS % Rec Result Conc. Result % Rec Limits Qualifiers ND 711 666 72 80-120 M 1 344J 711 966 87 80-120 92237648001 Dup Units Result Result mg/kg ND ND mg/kg 344J 358 Max RPD RPD Qualifiers 20 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/03/2015 12:20 PM without the written consent of Pace Analytical Services, Inc.. Page 32 of 38 aceAnaiXical www.pacelabs.com Pac Anr�timll�ervices, Inc. Revision 1 - A n 09Q�I� 98MIM e. Suite 100 y Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15020326 Pace Project No.: 92237648 QC Batch: WETA/43843 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92237648001, 92237648002, 92237648003, 92237648004 METHOD BLANK: 1136806 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrate as N mg/kg ND 5.0 02/20/15 22:34 LABORATORY CONTROL SAMPLE: 1136807 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg 49.9 53.9 108 80-120 MATRIX SPIKE SAMPLE: 1136809 92237648001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg ND 71.1 65.5 92 80-120 H3 SAMPLE DUPLICATE: 1136808 92237648001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Nitrate as N mg/kg ND ND 20 H3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/03/2015 12:20 PM without the written consent of Pace Analytical Services, Inc.. Page 33 of 38 aceAnaiXical www.pacelabs.com Pac Anr�timll�ervices, Inc. Revision 1 - A n 095Winlc&��e. Suite100 y Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15020326 Pace Project No.: 92237648 QC Batch: WETA/27294 Analysis Method: EPA 9060 QC Batch Method: EPA 9060 Analysis Description: 9060 TOC Average Associated Lab Samples: 92237648001, 92237648002, 92237648003, 92237648004 METHOD BLANK: 1118961 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mean Total Organic Carbon mg/kg ND 600 02/19/15 07:57 LABORATORY CONTROL SAMPLE: 1118962 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mean Total Organic Carbon mg/kg 120000 117000 98 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1118963 1118964 MS MSD 92237648001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg 4260 5980 6000 11300 11400 117 119 50-150 1 30 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1118965 1118966 MS MSD 92237650001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg 1380 5990 6000 7480 7300 102 99 50-150 3 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/03/2015 12:20 PM without the written consent of Pace Analytical Services, Inc.. Page 34 of 38 Pac Anr�timll�ervices, Inc. Revision 1 - A �in aceAnalyical �2c&fie. Suite100 Huntersville, NC 28078 www.pacelabs.com (704)875-9092 QUALIFIERS Project: J15020326 Pace Project No.: 92237648 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TN -The NELAC Institute. LABORATORIES PASI-G Pace Analytical Services - Green Bay PASI-O Pace Analytical Services - Ormond Beach ANALYTE QUALIFIERS D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. D4 Sample was diluted due to the presence of high levels of target analytes. D6 The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits. H3 Sample was received or analysis requested beyond the recognized method holding time. H6 Analysis initiated outside of the 15 minute EPA recommended holding time. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. N2 The lab does not hold TN accreditation for this parameter. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/03/2015 12:20 PM without the written consent of Pace Analytical Services, Inc.. Page 35 of 38 acmnalytical www.pacelabs.com Pac Anp�ti5all�ervices, Inc. Revision 1 -PA ri 0g6g I� g8f4-6ve. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: J15020326 Pace Project No.: 92237648 Lab ID Sample ID QC Batch Method QC Batch Analytical Method 92237648001 2015003846 EPA 3050 MPRP/22732 EPA 6010 92237648002 2015003847 EPA 3050 MPRP/22732 EPA 6010 92237648003 2015003848 EPA 3050 MPRP/22732 EPA 6010 92237648004 2015003849 EPA 3050 MPRP/22732 EPA 6010 92237648001 2015003846 EPA 3050 MPRP/22733 EPA 6020 92237648002 2015003847 EPA 3050 MPRP/22733 EPA 6020 92237648003 2015003848 EPA 3050 MPRP/22733 EPA 6020 92237648004 2015003849 EPA 3050 MPRP/22733 EPA 6020 92237648001 2015003846 EPA 7471 MERP/5386 EPA 7471 92237648002 2015003847 EPA 7471 MERP/5386 EPA 7471 92237648003 2015003848 EPA 7471 MERP/5386 EPA 7471 92237648004 2015003849 EPA 7471 MERP/5386 EPA 7471 92237648001 2015003846 ASTM D2974-87 PMST/3288 92237648002 2015003847 ASTM D2974-87 PMST/3288 92237648003 2015003848 ASTM D2974-87 PMST/3288 92237648004 2015003849 ASTM D2974-87 PMST/3288 92237648001 2015003846 EPA 9045 WET/29355 92237648002 2015003847 EPA 9045 WET/29355 92237648003 2015003848 EPA 9045 WET/29355 92237648004 2015003849 EPA 9045 WET/29355 92237648001 2015003846 EPA 9056 WETA/43844 92237648002 2015003847 EPA 9056 WETA/43844 92237648003 2015003848 EPA 9056 WETA/43844 92237648004 2015003849 EPA 9056 WETA/43844 92237648001 2015003846 EPA 9056 WETA/43843 92237648002 2015003847 EPA 9056 WETA/43843 92237648003 2015003848 EPA 9056 WETA/43843 92237648004 2015003849 EPA 9056 WETA/43843 92237648001 2015003846 EPA 9060 WETA/27294 92237648001 2015003846 EPA 9060 WETA/27300 92237648002 2015003847 EPA 9060 WETA/27294 92237648002 2015003847 EPA 9060 WETA/27300 92237648003 2015003848 EPA 9060 WETA/27294 92237648003 2015003848 EPA 9060 WETA/27300 92237648004 2015003849 EPA 9060 WETA/27294 92237648004 2015003849 EPA 9060 WETA/27300 Date: 03/03/2015 12:20 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Analytical Batch ICP/13910 ICP/13910 ICP/13910 ICP/13910 ICPM/9278 ICPM/9278 ICPM/9278 ICPM/9278 MERC/5380 MERC/5380 MERC/5380 MERC/5380 Page 36 of 38 ("p"Ce Ar�MICal. Sample Condition Upon Receipt SCUR Page 1 of 2 tg Document Number: IsstflsAuthotl*il 2, 2015 F-CHR-CS-003-rev.15 Pace Huntersville QQW61Yi`dW Client Name: 0 A `lk- /�,ne�/'� Courier: ❑ Fed Ex ❑ UPS❑ USPS❑ Client❑ Co mercial❑ ac Other Q ti6nal Custody Seal on CooterlBox Present: ❑ s no Seals intact: ❑ yes ❑ no Oroi. I�UC Dat7LLA Proj: Name: Packing Material: ❑ Bubble %ap Bubble Bags ❑ None ❑ Other Thermometer Used: IR Gun 6T,t Type of Ice: et Blue None Samples on ice, cooling process has begun Tmmn Cnerpe— inn Fnnfnr T14nl No Crlrmcfian Corrected Cooler Tem I - p•� C Temp should be above freezing to 6°C Biological Tissue is Frozen: Yes No NI Comments: Date and Initials g(5o x ni ng contents: Chain of Custody Present: es ❑No ❑NIA 1. Chain of Custody Filled Out: Yes No ❑NIA 2. Chain of Custody Relinquished: es 0No ❑ IA 3. Sampler Name & Signature on COC: Dyes �❑NIA 4. Samples Arrived within Hold Time: ❑Yes EINo ❑NIA 5. Short Hold Time Analysis (<72hr): Dyes C IN6 NIA 6. Rush Turn Around Time Requested: ❑Yes o ❑NIA 7. Sufficient Volume: e_Jallo ❑NIA 8. Correct Containers Used: -'Pace Containers Used: s o s ❑ o De ❑NIA ❑NIA 9, Containers Intact: s ❑No ❑NIA 46. Filtered volume received for Dissolved tests ❑Yes ❑ e "' NIA 11. Sample Labels match COC: -Includes date/time/ID/Analysis Matrix: es ❑No ONIA 12. 1-14 All containers needing preservation have been checked. All containers needing preservation are found to be in compliance with EPA recommendation. exceptions: VOA, coliform, TOC, O&G, WI-DRO (water) ❑Yes ❑No ❑Yes ❑No Dyes o iA /L11A 1 , �' Samples checked for dechlorination: Dyes ❑No E16A 14. Headspace in VOA Vials (>6mm): ❑Yes ©No Q IA 16. Trip Blank Present: Trip Blank Custody Seals Present Pace Trip Blank Lot # (if purchased): ❑Yes ONO ❑Yes ❑No m-A IA Client Notification/ Resolution: Person Contacted: Comments/ Resolution: Date/Time: SCURF Review: IC49- 1 Date: I 2 13 SRF Review: Date: !3 Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (i.e out of hold, incorrect preservative, out of temp, incorrect containers) Field Data Required? Place label here Y / N n�OR unii►i�Nim648 Page 37 of 38 Revision 1 - April 2, 2015 Page 45 of 46 f' C 0 a c � 0 m S C Z ' O Y 5553 Customer to cornpfete appropriate columns to rtpht a 4 L Z 0 y �-yq { , J n m n a� �y VY 0, W G� rf $* a s to -1 D 4 I CCD, ID O T N AY a� R D kill p k C fl A I � 7 I n w uj 7 4 r �i 1 N I C is t ` a 00 w rt m d �' 0 Q. r w el 1u w u m W a = 0)Q H o o 0 N .� (0y I�yza IL n° C n G Lj)Q ® ' L". 0 3 Z R n ri..t 4 I� LL 6 j � + o $ S W a Rm I L-_._-_._._... C' m cry f 0 7 i 000 w . I JV It' o �C - t6A lye a z FI ;, Req Ire 3 Q r 5 n QQ u r L t c 'Cornp. �C t�Grab �. Total Metals (PACE) Anions (PACE) 5 N Cu pH (PACE) 5 � SPLP -Total Metals and Anions (PACE) 5 Sediment specific tests (Access Analytical) 5 .. Organic Carbon (Ac°°no 5 s 0 I- O y g S 7°Total # of Containers ¢fi QL> V% W .I I Page 38 of 38 Revision 1 - April 2, 2015 Page 46 of 46 _CHAIN OF C_USTO_D_Y_R_E__C_O_R_D_ _A_N__D_ _A__N_ALYSIS REQUEST FORM_ _ _ _ DUKE Analytical Laboratory Services i i Analytical Laboratory Use OnlyPage of 1 i 1 Work Order NC_x_ to,Iii,Mail Code MG03A2 (Building 7405) i I a a 3 ac. Matrix: SOIL Samples Originating SC_ OH_ DISTRIBUTION Z10ENERGY Inter Hl e, N. Ferry 80 i i From ORIGINAL L LAB, Huntersville, N. C. 28078 j i—Logged By DeaiTims 1 COPY to CLIENT (980) 875-5245 i i (, c z j Q� SAMPLE PROGRAM Ground Water -... -•� .•.e - r ��•- � • I )-' I S /J -% V - NPDES Other_ 1►Project Netts AB GW Assessment a Soil 2)Phone No: Cape He-ar 3)CIIeMi pi Mark McDade, Synterra Kathy Webb, Synterra io)Process ID S)OPerating A�Unft: CPOO i♦: When s we need the tollowin 2 Provide correct aCcounting for U r..-.--..-..----i LAB USE ONLY II "Lab� 13 �' 3g 1 I' Plant _ RCRA x nAf-r I i REV DATE 112312015 Chris - - • operatingcollection . • .�■ rr ��»c>r�il►1��J� -,_t�t�llf4 ----�1�------- -!��%ii+�z ��ita'��)♦� 7i1♦�i����-������ ��t�L'tt•1L►Sl�'r—:iaiC���J ■■■ ■■ ■■■■■■■■■■■■■■■■■ �■ ■■ No FINEFINE �MMII NNE �■ ■■ ■■■■■■i ■ME ■■■■ -_•� - - I■ ■■■■■■■■■i■■■■■■■ ■� _ ■MIS■■■■ ■■■■■■ V1ot ovl ru- Pic. z-l;L-/5 CT5 /31fz a �s V-C U4 U