NC0088811_Permit Issuance_20150612

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NCDENR
North Carolina Department of Environment and Natural Resources
Pat McCrory
Governor
Mr. Bob Verdinek, Assoc. Director
Facilities & Engineering Services
Pharmaceutical Product Development Inc.
929 North Front Street
Wilmington, NC 28402
Dear Mr. Verdinek:
Donald R. van der Vaart
Secretary
June 12, 2015
Subject: Issuance of NPDES Permit Renewal
Permit No. NC0088811
Pharmaceutical Product Development, Inc
Groundwater Remediation Plant
New Hanover County
Facility Class I
Division personnel have reviewed and approved your application for renewal of the subject permit. Accordingly, we
are forwarding the attached NPDES discharge permit. This permit is issued pursuant to the requirements of North
Carolina General Statute 143-215.1 and the Memorandum of Agreement between North Carolina and the U.S.
Environmental Protection Agency dated October 15, 2007 (or as subsequently amended).
As identified previously, the renewal permit contains the following significant changes from your
current permit:
• The requirement to begin reporting discharge monitoring data electronically using the NC DWR's Electronic
Discharge Monitoring Report (eDMR) internet application has been added to your NPDES permit. [See Special
Condition A. (4.)]
For information on eDMR, registering for eDMR and obtaining an eDMR user account, please visit the following web
page: http://portal.ncdenr.org/web/wg/admin/bog/ipu/edmr.
For information on EPA's proposed NPDES Electronic Reporting Rule, please visit the following website:
http://www2.epa.gov/compliance/proposed-npdes-electronic-reporting-rule.
• . Discharge data, collected as part of Pharmaceutical Product Development's Industrial User Permit (IUP), was
evaluated for the period of Jan. 2011 through October 2014. A Reasonable potential analysis was performed on
the data to determine what toxic parameters should continue to be limited, removed, or added to the NPDES permit
as follows:
o Effluent monitoring for silver was removed from the permit because all IUP samples were less than the
detection level.
o Bi-annual IUP sampling for cyanide showed one hit at 17 ug/L and six at <5 ug/L during the past four years
(2011-2014). Since this is a limited data set (less than 8 samples) and all samples were non -detect except
one, quarterly monitoring for cyanide was added to the permit with no limitation.
1617 Mail Service Center, Raleigh, North Carolina 27699-1617
Phone: [phone] Internet: www.ncdenr.gov
An Equal opportunity 1 Affirmative Action Employer — Made in part by recycled paper

A
Mr. Bob Verdinek, Assoc. Director
June 12, 2015
Page 2 of 2
o Reasonable Potential to violate state Water Quality Standards (WQSs) was shown using IUP discharge data
for arsenic, chromium, molybdenum, and nickel. As a result, arsenic and chromium limitations and monitoring
were maintained in the permit. Limitations and monitoring were added for molybdenum and nickel.
o IUP discharge data for copper showed reasonable potential for the effluent to violate state Water Quality
Standards. IUP discharge data for Zn did not show potential to violate state WQSs; however, the predicted Zn
concentration was greater than 50% of the total allowable concentration. Copper and zinc have action level
standards which apply in conjunction with toxicity test results. Since the facility is not discharging to state
waters at this time, limitations for copper and zinc are not required but quarterly monitoring for both parameters
was maintained in the permit.
Some of the wording has changed in Special Condition A. (2), Acute Toxicity Pass/Fail Limit and the testing
organism was changed to Mysid Shrimp. Per EPA guidance, the most sensitive species should be chosen when
testing only one species (USEPA 1991). Although no species is always the most sensitive to all toxicants,
Mysidopsis bahia has been documented to show a greater sensitivity to ion toxicity than other saltwater test species
(Pillard et al. 2000). Language was inserted at the bottom of this condition that describes a permittee's options for
alternative test species selection.
If any parts, measurement frequencies or sampling requirements contained in this permit are unacceptable to you,
you have the right to an adjudicatory hearing upon written request within thirty (30) days following receipt of this
letter. This request must be in the form of a written petition, conforming to Chapter 150B of the North Carolina
General Statutes, and filed with the Office of Administrative Hearings (6714 Mail Service Center, Raleigh, North
Carolina 27699-6714). Unless such demand is made, this decision shall be final and binding.
Please note that this permit is not transferable except after notice to the Division. The Division may require
modification or revocation and reissuance of the permit. This permit does not affect the legal requirements to
obtain other permits which may be required by the Division of Water Resources or any other Federal, State, or
Local governmental permits that may be required.
If you have any questions concerning this permit, please contact Julie Grcyb by email [e-mail]) or
phone at [phone].
Sinc rely,
Jay Zimmerman
Director, Division of Water Resources
Enclosure: NPDES Permit NC0088811
cc: NPDES Unit
Central Files
Wilmington Regional Office / Water Quality Program
e-copy:
Susan Meadows, Aquatic Toxicity Branch

Permit NCO088811
STATE OF NORTH CAROLINA
DEPARTMENT OF ENVIRONMENT AND NATURAL RESOURCES
DIVISION OF WATER RESOURCES
PERMIT
TO DISCHARGE WASTEWATER UNDER THE
NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM
(NPDES)
In compliance with the provision of North Carolina General Statute 143-215.1, other lawful standards and
regulations promulgated and adopted by the North Carolina Environmental Management Commission, and
the Federal Water Pollution Control Act, as amended, the
Pharmaceutical Product Development, Inc.
is hereby authorized to discharge wastewater from outfalls located at the
Pharmaceutical Product Development, Inc.
Ground Water Remediation Plant
929 North Front Street
Wilmington, NC 28402
New Hanover County
to receiving waters designated as the Northeast Cape Fear River within the Cape Fear River Basin in
accordance with effluent limitations, monitoring requirements, and other applicable conditions set forth in
Parts I, II and III hereof.
. This permit shall become effective ......................August 1, 2015.
This permit and authorization to discharge shall expire at midnight on January 31, 2020.
Signed this day ............... June 12, 2015.
Yt,.Yy Zimmerman
Director, Division of Water Resources
By Authority of the Environmental Management Commission
Page 1 of 7

Permit NCO088811
SUPPLEMENT TO PERMIT COVER SHEET
All previous NPDES Permits issued to this facility, whether for operation or discharge are hereby revoked. As
of this permit issuance, any previously issued permit bearing this number is no longer effective. Therefore, the
exclusive authority to operate and discharge from this facility arises under the permit conditions,
requirements, terms, and provisions included herein.
Pharmaceutical Product Development, Inc.
is hereby authorized to:
1. After the Division receives written notification that a discharge will commence, at least 30 days
prior to discharge, operate a 0.029 MGD groundwater remediation wastewater treatment plant
that includes the following components:
❑ Collection wells and transfer station
❑ Two (2) 20 micron pre -filters
❑ Six (6) ion exchange tanks
❑ Two (2) media tanks
❑ pH adjustment system
❑ Hoses, piping, controls, and fittings
❑ Effluent flow meter
This facility is located at Pharmaceutical Products Development, Inc. Ground Water Remediation
Treatment Plant, on 929 North Front Street, Wilmington, NC 28402 in New Hanover County.
2. Discharge from said treatment facility via outfall 001 at a specified location (see attached map)
into Northeast Cape Fear River, a class SC, Sw stream within the Cape Fear River Basin.
Page 2 of 7

Permit NCO088811
PART I
A. (1.) EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS
[15A NCAC 02B .0400 et seq., 02B .0500 et seq.]
During the period beginning on the effective date of the permit and after the receipt of written notification
that a discharge will commence for a 0.029 MGD remediation treatment facility, and lasting until expiration,
the Permittee is authorized to discharge through outfall 001. Such discharges shall be limited and monitored'
by the Permittee as specified below:
EFFLUENT
CHARACTERISTICS
EFFLUENT LIMITS
MONITORING REQUIREMENTS
Monthly
Average
Weekly
Average
Daily
Maximum
Measurement
Frequency
Sample Type
Sample
Location
Flow
0.029 MGD
Continuous
Recording
Effluent
Total Suspended Solids (TSS)
30.0 mg/L
45.0 mg/L
2/Month
Grab
Effluent
pH
Not greater than 8.5 s.u. nor less than 6.8 s.u.
2/Month
Grab
Effluent
Ammonia as Nitrogen (NH3-N)
(April 1— October 31)
2.0 mg/L
10.0 mg/L
2/Month
Grab
Effluent
Ammonia as Nitrogen (NH3-N)
(November 1— March 31)
4.0 mg/L
20.0 mg/L
2/Month
Grab
Effluent
Arsenic2
10 pg/L
10 pg/L
2/Month
Grab
Effluent
Total Chromium 2
20 pg/L
j
20 pg/L
Monthly
Grab
Effluent
Total Copper 2 , pg/L
Monitor and Report
Quarterly
Grab
Effluent
Total Cyanide, pg/L
Monitor and Report .
Quarterly
Grab
Effluent
Total Molybdenum 2
2 pg/L
2 pg/L
Monthly
Grab
Effluent
Total Nickel 2
8.3 pg/L
75 pg/L
Monthly
Grab
Effluent
Total Zinc 2 , pg/L
Monitor and Report
Quarterly
Grab
Effluent
Acute Toxicity 3
Quarterly
Grab
Effluent
Footnotes:
1. No later than 270 days from the effective date of this permit, begin submitting discharge monitoring
reports electronically using NC DWR's eDMR application system. See Special Condition A (4).
2. Samples shall be taken in conjunction with Acute Toxicity Tests
3. Acute Toxicity Pass/Fail (Mysid Shrimp) at 90%; quarterly during March, June,
September, and December, See Special Condition A. (2.). The collection of the sample
shall coincide with a common sample taken for all the other permit Effluent
Characteristic parameters.
Effluent shall contain no floating solids or foam visible in other than trace amounts.
There shall be no visible sheen or other surface films on the grab sample, or the receiving stream traceable to the
effluent.
Page 3 of 7

Permit NCO088811
A. (2.) ACUTE TOXICITY PASS/FAIL LIMIT (QUARTERLY)
[15A NCAC 02B .0200 et seq.]
The permittee shall conduct acute toxicity tests on a uarterll basis using protocols defined in the North
Carolina Procedure Document entitled "Pass/Fail Methodology For Determining Acute Toxicity In A Single
Effluent Concentration" (Revised December 2010 or subsequent versions). The monitoring shall be performed
as a Mysid Shrimp (Mysidopsis bahia) 24 hour static test. The effluent concentration at which there may be at no
time significant acute mortality is 90% (defined as treatment two in the procedure document). The tests will be
performed during the months of March, June, September, and December. These months signify the first
month of each three month toxicity testing quarter assigned to the facility. Effluent sampling for this testing
must be obtained during representative effluent discharge and shall be performed at the NPDES permitted
final effluent discharge below all treatment processes.
Should any single quarterly monitoring indicate a failure to meet specified limits, then monthly
monitoring will begin immediately until such time that a single test is passed. Upon passing, this monthly
test requirement will revert to quarterly in the months specified above.
All toxicity testing results required as part of this permit condition will be entered on the Effluent Discharge
Monitoring Form (MR-1) for the month in which it was performed, using the parameter code TGOE.
Additionally, DWR Form AT-2 (original) is to be sent to the following address:
Attention: North Carolina Division of Water Resources
Water Sciences Section/ Aquatic Toxicology Branch
1623 Mail Service Center
Raleigh, North Carolina 27699-1623
Completed Aquatic Toxicity Test Forms shall be filed with the Water Sciences Section no later than 30 days
after the end of the reporting period for which the report is made.
Test data shall be complete and accurate and include all supporting chemical/physical measurements
performed in association with the toxicity tests, as well as all dose/response data. Total residual chlorine of
the effluent toxicity sample must be measured and reported if chlorine is employed for disinfection of the
waste stream.
Should there be no discharge of flow from the facility during a month in which toxicity monitoring is
required, the permittee will complete the information located at the top of the aquatic toxicity (AT) test form
indicating the facility name, permit number, pipe number, county, and the month/year of the report with the
notation of "No Flow" in the comment area of the form. The report shall be submitted to the Water Sciences
Section at the address cited above.
Should the permittee fail to monitor during a month in which toxicity monitoring is required, then monthly
monitoring will begin immediately until such time that a single test is passed. Upon passing, this monthly test
requirement will revert to quarterly in the months specified above. Assessment of toxicity compliance is .
based on the toxicity testing quarter, which is the three month time interval that begins on the first day of the
month in which toxicity testing is required by this permit and continues until the final day of the third month
Should any test data from either these monitoring requirements or tests performed by the North Carolina
Division of Water Resources indicate potential impacts to the receiving stream, this permit may be re -opened
and modified to include alternate monitoring requirements or limits.
NOTE: Failure to achieve test conditions as specified in the cited document, such as minimum control
organism survival and appropriate environmental controls, shall constitute an invalid test and will require
immediate follow-up testing to be completed no later than the last day of the month following the month of
the initial monitoring.
Page 4 of 7

Permit NCO088811
USE OF A DIFFERENT TEST ORGANISM
The permittee may request the use of a different test organism upon documentation that the alternate test
organism would provide an equal or greater level of protection and is appropriate based on the characteristics
of the discharge and receiving stream. Such documentation would consist of one of the following:
1. For saltwater classified streams, a fathead minnow may be assigned as the acute testing species if the
salinity of the receiving stream at the point of discharge is <5 ppt throughout the tidally influenced
cycle. This determination may be based on the best professional judgment of DWR staff or data
collection provided by the permittee and approved by DWR staff. This evaluation should include
vertical profiles of salinity/conductivity measurements at both high tide and low tide over several 24
hour cycles.
2. Three consecutive "side -by -side" tests with results indicating that the alternate test organism is as or
more sensitive to the facility's effluent. Each test series would consist of two separate toxicity tests
conducted on the same sample of effluent with the length of exposure specified by the permit, the
only difference between the tests being the organism used.
3. An alternate plan developed by the permittee and approved by the Aquatic Toxicology Unit that
demonstrates an equal level of protection is offered by the test organism.
For items 2 and 3, it must also be demonstrated that viable and standardized culture techniques are available
for that organism and standardized testing methodologies have been developed and validated. This
demonstration should meet guidance provided by EPA in Section 6 of EPA-821-R-02-012, Short Term Methods
for Estimating the Acute Toxicity of Effluents and Receiving Waters to Freshwater Organisms. Fifth Edition,
2002. Requests to use a different test organism and supporting documentation should be sent to NC DWR,
WSS at the address listed above.
A. (3.) ADDITIONAL EFFLUENT TESTING AND REOPENER
[G.S.143-215.1(b)]
The Division of Water Quality may request further effluent characteristic evaluation by means of a written
request stating the type of analysis, a due date, and the reason for the analysis. If the analysis indicates the
applicable Effluent Guidelines or Water Quality Standards were exceeded, then the permit can be reopened
and the appropriate limits added. In the event of a new limit being added, upon request from the permittee a
compliance timetable will be established.
A. (4.) ELECTRONIC REPORTING OF DISCHARGE MONITORING REPORTS
[G.S.143-215.1(B)]
Proposed federal regulations require electronic submittal of all discharge monitoring reports (DMRs) and
specify that, if a state does not establish a system to receive such submittals, then permittees must submit
DMRs electronically to the Environmental Protection Agency (EPA). The Division anticipates that these
regulations will be adopted and is beginning implementation in late 2013.
NOTE: This special condition supplements or supersedes the following sections within Part II of this permit
(Standard Conditions for NPDES Permits):
• Section B. (11.) Signatory Requirements
• Section D. (2.) Reporting
• Section D. (6.) Records Retention
• Section E. (5.) Monitoring Reports
Page 5 of 7

Permit NC0088811
1. Reporting f Supersedes Section D. (2.) and Section E. (5.) (aa)]
BeginxZdng no later than 270 days from the effective date of this permit, the permittee shall begin reporting
discharge monitoring data electronically using the NC DWR's Electronic Discharge Monitoring Report
(eDMR) internet application.
Monitoring results obtained during the previous month(s) shall be summarized for each month and
submitted electronically using eDMR. The eDMR system allows permitted facilities to enter monitoring
data and submit DMRs electronically using the internet. Until such time that the state's eDMR application
is compliant with EPA's Cross -Media Electronic Reporting Regulation (CROMERR), permittees will be
required to submit all discharge monitoring data to the state electronically using eDMR and will be
required to complete the eDMR submission by printing, signing, and submitting one signed original and a
copy of the computer printed eDMR to the following address:
NC DENR / DWR / Information Processing Unit
ATTENTION: Central Files / eDMR
1617 Mail Service Center
Raleigh, North Carolina 27699-1617
If a permittee is unable to use the eDMR system due to a demonstrated hardship or due to the facility
being physically located in an area where less than 10 percent of the households have broadband access,
then a temporary waiver from'the NPDES electronic reporting requirements may be granted and
discharge monitoring data may be submitted on paper DMR forms (MR 1,1.1, 2,3) or alternative forms
approved by the Director. Duplicate signed copies shall be submitted to the mailing address above.
Requests for temporary waivers from the NPDES electronic reporting requirements must be submitted in
writing to the Division for written approval at least sixty (60) days, prior to the date the facility would be
required under this permit to begin using eDMR. Temporary waivers shall be valid for twelve (12)
months and shall thereupon expire. At such time, DMRs shall be submitted electronically to the Division
unless the permittee re -applies for and is granted a new'temporary waiver by the Division.
Information on eDMR and application for a temporary waiver from the NPDES electronic reporting
requirements is found on the following web page:
hft://portal.ncdenr.org/webZwq/admin/­bogZil2u/­edmr
Regardless of the submission method, the first DMR is due on the last day of the month following the
issuance of the permit or in the case of a new facility, on the last day of the month following the
commencement of discharge.
2. Signatory Requirements [Supplements Section B. (11.) (b) and supersedes Section B (11.) (d)1
All eDMRs submitted to the permit issuing authority shall be signed by a person described in Part II,
Section B. (11.) (a) or by a duly authorized representative of that person as described in Part II, Section B.
(11.)(b). A person, and not a position, must be delegated signatory authority for eDMR reporting
purposes.
For eDMR submissions, the person signing and submitting the DMR must obtain an eDMR user account
and login credentials to access the eDMR system. For more information on North Carolina's eDMR
system, registering for eDMR and obtaining an eDMR user account, please visit the following web page:
http:/ /portal.ncdenr.org/web/wci/admin/bog/ipu/edmr
Page 6 of 7

Permit NCO088811
Certification. Any person submitting an electronic DMR using the state's eDMR system shall make the
following certification [40 CFR 122.22]. NO OTHER STATEMENTS OF CERTIFICATION WILL BE
ACCEPTED:
"I certifij, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the
information submitted. Based on my inquiry of the person or persons who manage the system, or those persons
directly responsible forgathering the information, the information submitted is, to the best of my knowledge and
belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations."
3. Records Retention [Supplements Section D. (6.)l
The permittee shall retain records of all Discharge Monitoring Reports, including eDMR submissions.
These records or copies shall be maintained for a period of at least 3 years from the date of the report. This
period may be extended by request of the Director at any time [40 CFR 122.41]:
Page 7 of 7

i O }
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0

AFFIDAVIT OF PUBLICATION
STATE OF NORTH CAROLINA
COUNTY OF NEW HANOVER
Before the undersigned, a Notary Public of Said County and State,
Notice oflntent to Issue a NPDES
Wastewater Permit Jarimy Springer
he North Carolina Environmental
Who, being duly sworn or affirmed, according to the law, says that he/she is
until 30 days after the
Accounting Specialist
to of this notice. The Di -
he INC Division of Water
( uld may hold a public
could there be a si publicgnifi.
of THE STAR -NEWS, a corporation organized and doing business under the Laws of the State of
rP g g
'ee of public interest.
North Carolina, and publishing a newspaper known as STAR -NEWS in the City of Wilmington
iil comments and/or m-
requests to DWft at the
ress. Interested persons
Public Notice North Carolina Environmental Management Commission/NPDES Unit, 1617
t eRa Raleigh, atWR NCto re512 N. view
Mail Service Center Raleigh, NC 27699-1617Notice oflntent to Issue a NPDES Wastewater
I on file. Additional in-
on NPDES permits and
Permit The North Carolina Environmental Management Commission proposes to issue a NP
g P
may be found on our
ground- was inserted in the aforesaid newspaper in space, and on dates as follows:
in New
ted dis-
,ater to
River. 3113Ix
And at the time of such publication Star -News was a newspaper meeting all the requirements and
qualifications prescribed by Sec. No. 1-597 G.S. of N.C.
� Title: Accountin Specialist
Sworn or affirmed to, and subscribed before me this _ day of
wrt-b A.D., 2 oT s tyW�
In Testimony Whereof, I have hereunto set my hand and affixed my offic' oo
year aforesaid. gR
kr" TAR
N
O
My commission expires fft�- day of TAU.&—, 201,(0
0Ot,1360
Upon reading the aforegoing affidavit with the advertisement thereto annexed it is adjudged by the Court that the
publication was duly and properly made and that the summons has been duly and legally served on the defendant(s).
This day of
Clerk of Superior Court
MAIL TO:

iVo ���if, W4 Im 4-ofb7-Wj
I A<e of h 6MAJ RP 6 0 e ate
Permit No. NCO088811
DENR/DWR
FACT SHEET FOR NPDES PERMIT DEVELOPMENT
NPDES No. NCO088811
Facility Information
Applicant/Facility
Name:
Pharmaceutical Product Development, Inc.
Applicant Address:
929 North Front Street; Wilmington, North Carolina 28402
Facility Address:
929 North Front Street; Wilmington, North Carolina 28402
Permitted Flow
0.029 MGD
Type of Waste:
Ground water remediation
Facility/Permit Status:
Class I / New
County:
New Hanover
Miscellaneous
Receiving Stream:
NE Cape Fear
River
Stream
Classification:
SC, Sw
Subbasin:
03-06-23
Index No.
18-74-(61)
Drainage Area (mi):
NA
8-Digit HUC:
03030007
Summer 7Q10 (cfs)
Tidal
303(d) Listed?
Yes, 2014 303(d) list for
copper
Winter 7Q10 (cfs :
Tidal
Regional Office:
Wilmington
30Q2, (cfs)
Tidal
State Grid / USGS
Quad:
K27NW Wilmington, NC
Average Flow (cfs):
Tidal
Permit Writer:
Julie Grzyb
IWC (%):
NA
Date:
2/10/15 Final
BACKGROUND
Pharmaceutical Products Development, Inc. (PPD) constructed an office building located on a
7.48 acre tract formerly used as a chemical terminal by Almont Shipping. Following
construction, groundwater was observed seeping into the lower parking deck and the adjacent
courtyard. To receive a final Certificate of Occupancy, PPD was required to recover the seepage
and discharge the wastewaters to the City's sanitary sewer, under an approved Industrial User
Permit (IUP). The IUP was issued with the condition that PPD investigate an alternative disposal
method for the groundwater. PPD performed an Engineering Alternatives Analysis and
concluded that a direct discharge to the Cape Fear River was the most economically feasible
disposal alternative, other than a continued discharge to the sanitary sewer via the IUP.
This discharge is currently permitted as an Industrial User Permit by the City of Wilmington
POTW. The IUP permit was issued with the understanding that this option was short term and at
some point in the future this discharge would not be accepted. The Division agrees that the
recommended method would be to continue to utilize the POTW and that in the absence of the
POTW accepting the discharge, the surface discharge of treated wastewaters would be allowable.
PPD would have to install adequate treatment to meet NPDES permit limitations prior to a direct
discharge to surface waters. To date, there has been no discharge of wastewaters via the NPDES
permit.
PROPOSED WASTEWATER TREATMENT
Depending on rain events 8,000 gpd to 10,500 gpd of recovered groundwater is discharged to the
POTW. The initial analysis of the ground water yielded high levels of ammonia and arsenic.

Permit No. NCO088811
PPD's original application included an ion exchange system proposed to reduce ammonia and
arsenic levels in the extracted groundwater prior to discharge. A treatability study was conducted
to determine the optimum treatment system configuration to achieve the target treatment goals of
an arsenic human health standard of 10 ug/L and an ammonia limitation of 2 mg/L. PPD reported
that the results of the study determined that the proposed treatment system would be able to treat
the recovered groundwater for ammonia and arsenic and achieve effluent concentrations of <3
mg/L for ammonia and < 10 ug/L for arsenic. The proposed system would consist of disposable
cartridge pre -filters to remove suspended materials, a series of ion exchange tanks to remove
arsenic and ammonia, and a pH adjustment system. In addition, as the ion system becomes spent,
a contract service would be hired to install new units and remove the spent units. The contract
service would be responsible for disposal of the spent units.
The design flow used for the system was 2 gpm to 20 gpm with 10 gpm being optimum. For
permitting purposes 20 gpm or 0.029 MGD was used to define the permitted flow. The discharge
would flow to a local storm drain which discharges to the Northeast Cape Fear River
approximately 1,000 feet from the site.
The Northeast Cape Fear is a class SC, swamp stream within the Cape Fear River Basin. This
segment of the NE Cape Fear is listed on the 2014 303(d) list, impaired for copper.
PERMITTING STRATEGY
Wastewaters discharged to the POTW are analyzed for the following parameters as part of PPD's
IUP: As, Cd, Cr, Cu, Zn, Ammonia, Chloride, TKN, TS, pH, Conductivity, Temperature,
Barium, Aluminum, Ni, and Mo. Twice a year the facility tests its discharge for additional
pollutants such as Ag, CN, Pb, Phosphorus, and Oil & Grease. Since limited data was submitted
on the effluent with the initial application, IUP data collected from Jan. 2013 through October
2014 was evaluated to help determine what parameters should continue to be limited or removed
from the permit. The following data summarizes the IUP data. All the data can be found in a
spreadsheet titled Industrial User Permit Discharge Data attached to the fact sheet.
Table I. Industrial User Permit data collected Jan. 2013 — Oct. 2014 (discharge to POTW)
Parameter
As
Cd
Cr
Cu
Zn
Ammonia
Chloride
ugAL
u /L
u /L
u /L
u /L
mg/L
mg/L
Average
21.3
0.49
4.73
5.49
16.3
37.72
172.7
Maximum
93.9
1
18.81
16.61
45.11
177
318
Permit Limit
10
120
1
1
12S/4W
Parameter
TKN
pH
Cond
Temp
Barium
Aluminum
Ni
Mo
m
s.u.
m /cm
C
u /L
u
u /L
u /L
Average
34.7
7.43
1.16
19.8
53.7
79.8
4.1
9.2
Maximum
1 1681
8.61
2.51
25.11
59.7
1 131
1 5.51
13.5
Permit Limit
1
1 6.8-8.5
Parameter
Ag
O & G
TP
u /L
mg/L
mg/L
Average
<5
<5
0.35
Maximum
I <10
1 8.71
1.0
Permit Limit
2

Permit No. NCO088811
COMPLIANCE REVIEW
This facility has not had a NPDES discharge.
No toxicity tests or inspections were performed.
REASONABLE POTENTIAL ANALYSIS
Since IUP wastewater data was available, a reasonable potential analysis was performed on the
following parameters: As, Cd, Cr, Cu, Mo, Ni, and Zn.
Reasonable Potential to violate state Water Quality Standards (WQSs) was shown for As, Cr,
Mo, and Ni. As and Cr limitations and monitoring were maintained in the permit. The As
limitation is based on the state's human health standard of 10 ug/L to protect for fish
consumption. Limitations and monitoring were added for Mo and Ni. Metal limitations for Cr,
Mo, and Ni are based on aquatic life saltwater standards.
Reasonable potential to violate state WQSs for copper was shown. Since copper has an action
level standard and is implemented based on toxicity testing, monitoring will remain in the permit.
A copper permit limitation will not be established until toxicity testing is performed and can be
evaluated in conjunction with copper sampling results.
Industrial User Permit Discharge data for Zn did not show potential to violate state WQSs,
however, the predicted Zn concentration was greater than 50% of the total allowable
concentration. As a result, Zn monitoring will be maintained in the permit.
Bi-annual sampling for Ag showed eight samples <5 or <10 ug/L during the past four years
(2011-2014). Ag is not considered to be a pollutant of concern and the monitoring requirement
was removed from the permit.
Bi-annual sampling for CN showed one hit at 17 ug/L and six at <5 ug/L during the past four
years (2011-2014). Since this is a limited data set (less than 8 samples) and all samples were
non -detect except one, quarterly monitoring for CN was added to the permit with no limitation at
this time.
PERMIT LIMITATION BASIS FOR OTHER PARAMETERS
Ammonia as nitrogen- Ammonia limits were established based on a permitting strategy to meet
summer and winter limitations of 2 mg/L and 4 mg/L, respectively. These limits will be
maintained in the permit.
Whole Effluent Toxicity Test - The quarterly Acute Pass/Fail Toxicity Limit test (WET test) will
be maintained in the permit and is required of all complex wastewaters containing metals.
Oil and grease are addressed as a narrative standard.
A list of parameters and the regulatory basis for each limit or monitoring requirement can be
found at the end of the Fact Sheet under Table II.
SUMMARY OF PROPOSED CHANGES
The following permit changes are proposed for this permit renewal/expansion:
1. Addition of electronic DNM requirement.
2. Removed effluent monitoring for silver.
3. Added effluent monitoring and limitations for molybdenum and nickel.
4. Added effluent monitoring for cyanide.
3

Permit No. NCO088811
5. Addition of revised Toxicity testing language and change testing organism to Mysid Shrimp.
PROPOSED SCHEDULE FOR PERMIT ISSUANCE
Draft Permit to Public Notice: March 11, 2015 (estimate)
Permit Scheduled to Issue: May 4, 2015 (estimate)
NPDES DIVISION CONTACT
If you have questions regarding any of the above information or on the attached permit, please contact
Julie Grzyb at [phone] or email [e-mail].
NAME: DATE:
TABLE II. RATIONALE FOR LIMITATIONS AND METALS MONITORING
EFFLUENT LIMITS
RATIONALE FOR LIMITATION
EFFLUENT
Monthly
Weekly
Daily
CHARACTERISTICS
Average
Average
Maximum
Flow
0.029 MGD
15A NCAC 02B .0400 et seq., 02B .0500 et seq
Used similar BAT for Municipal Wastewaters -
Total Suspended Solids (fSS)
30.0 mg/L
45.0 mg/L
Administrative Code 15A NCAC 02B .0406 for
pH
Not greater than 8.5 s.u. nor less than 6.8 s.u.
Administrative Code 15A NCAC 02B .0211
2-5-90 Agreement between Division and EPA
Ammonia as Nitrogen (NH3-N)
2.0 mg/L
10.0 mg/L
Region IV to use summer NH3-N criteria of
(April 1—October 31)
2 mg/L for minors to protect against toxicity
2-5-90 Agreement between Division and EPA
Ammonia as Nitrogen (NH3-N)
4.0 mg/L
20.0 mg/L
Region IV to use winter NH3-N criteria of
(November 1—March 31)
4 mg/L for minors to protect against toxicity
Arsenic
10 pg/L
10 pg/L
Reasonable potential analysis determination
based on standards from Administrative Code
Total Chromium
20 pg/L
20 pg/L
Total Molybdenum
2 p9/L
2 pg/L
15A NCAC 02B .0211 and Appendix A.
Total Nickel
8•3 p9/L
75 pg/L
Total Copper
Monitor and Report
Reasonable potential analysis determination
based on standards from Administrative Code
Total Cyanide
Monitor and Report
15A NCAC 02B .0211.
Total Zinc
Monitor and Report
Acute Toxicity
15A NCAC 02B .0200 et seq.
REGIONAL OFFICE COMMENTS
NAME:
4
DATE:

PPD - discharge to POTW
Outfall discharge to POTW
NCO088811 2014 Saltwater RPA 95% Probablity/96% Confidence
MAXIMUM DATA POINTS = 58
Qw (MGD) = 0.03
W WTP/WTP Class: Class
I QIOS(efs)= Acute IWC =100%
IWC @1Q10S = 100.00%
7Q10S(cfs)= Tidal, IWC=100%
IWC @7QIOS= 100.00%
7Q IOW(cfs)= Tidal, IWC=100%
IWC@7QIOW= 100.00%
30Q2 (cfs)= Tidal, IWC = 100 %
IWC @ 30Q2 = 100.00%
Avg. Stream Flow, QA (cfs) = Tidal, IWC = 100%
IWC @ QA = 100.00%
Receiving Stream: NE Cape Fear
Stream Class: SC, Sw
Qw = 0.029 MGD
PARAMETER
STANDARDS R CRITERIA (2)
N
REASONABLE POTENTIAL RESULTS
TYPE
I
a
RECOMMENDED ACTION
NC WQS / Applied �/¢ FAV /
Max Pred
n # Det. Allowable Cw
Chronic Standard Acute
Cw
Acute: NO WQS
RPA for non -AL- apply Monthly Monitoring
Arsenic
C
10 HH
ug/L
23 18
151.2
with Limit
______________________
17 value(s) > Allowable Cw
Acute: 42.0
No RPA, Predicted Max< 50%of Allowable Cw
Cadmium
NC
5 SW J]
ug/L
23 1
1.5
No Monitoring required
Chronic:_____5.0
No value > Allowable Cw
Acute: NO WQS
RPA for non -AL - apply Monthly Monitoring
Chromium
NC
20 SW
ugA.
23 1
303
with Limit
_
__Chronic:—____20
No value > Allowable Cw
Acute: 5.8
RPA for A CuZnA L(,,g,Fe,CI) -apply Quarterly
Copper (AL)
NC
3 SW 5.8
ug/L
23 9
25.2
Monitoring in conjunction with TOX Test
--Chronic—____3.0------------------------------
5 values > Allowable Cw
Acute: 1.0
RPA for Limited Dataset (n<8 samples) - apply
Cyanide
NC
I SW 1
10.0
ug/L
7 1 34.2
_ _ _ ____
QuarterlyMonitoring
6samples < 5(PQL) and one sample> allowable
Note: n < 9 Default C.V.
_____
Chronic: LO
Limited data set
Cw
Acute: NO WQS
RPA for Limited Dataset (n<8) but 2 values>
Allowable Cw- apply Monthly Monitoring with
Molybdenum
NC
'_.0 Fill
mg/L
4 3
35.0
Limit
Notc:n<9
Default C.V.
------------------------------
Chronic: 2.0
Limited data set
4 value(s) > Allowable Cw
Acute: 75.0
RPA for Limited Dataset (n<8) but 2 values>
Allowable Cw- apply Monthly Monitoring with
Nickel
NC
s.; S\\75
ug/L
4 2
14.2
Limit
Note: n < 9
Default C.V.
------------------------------
Chronic: 8.3
Limited Jata set
No value > Allowable Cw
Acute: 95
No RPA, Predicted Max >_50%of Allowable
Zmn (AL)
NC
86 SW 95
ug/L
23 IS
59.53
Cw_-_apply Quarterly M_onit_orin_g
_ _ _ _ _ ___
Chronic: 86
....... _
No value> Allowable Cw
9595 SALTWATER RPA20141.xlsm,rpa
Page 1 of 1 3/2/2015

Industrial User Permit
(IUP) Discharge
Data
I
1,
Pharmaceutic
I Prod NC0088811
Date
As
Cd
Cr
"Cu
Zn
Ammonia
Chloride
TKN
TS
pH Cord
Temp
Barium Alumi Ni Mo Ag CN
O & G TP
ug/L
ug/L
ug/L.
ug/L
ug/L
mg/L
mg/L
mg/L
mg/L
s.u. _m5/cm
C
ug/L ug/L ug/L ug/l ug/L ug/L
mg/L mg_/L
_ _
10/11/2014
< 10
<
1 <
5,<
5
< 10
13.5
140
13.5
582
7.4
1.07
23
_ 1_7
<5 1
9/15/2014
13.9
<
1 <
51
13.2
30.1
14.5
152
1.7
600
7.4
1.13
24
<5
<5 0.29
8/5/2014
5.2
<
1I<
5
8.8
25.6
69.9
174
70.6
577
_ 7.7
_
47.8 131 5.5 13_.5 <5 <5
<5 0.23
1 <
51<
6/19/2014 < 10 <
5
22.6
11.9
142
11.2
539
7.1
0.89
_24.1
<5
<5 0.24
5/16/2014
11.3
<
_ _
1 <
.5
<
5.
16.2
24.1
111
25.2
466
7.86
0.98
22.3
<5
<5 0.23
4/15/2014
10.9
<
1 <
5
<
5
12.9
12.4
142
13
522
7.2
1.01
19.7
47.9 <100 <5 <5 <5 <5
<5 0.24
3/18/2014
13.3
<
0.1 <
1
1.1
15.1
13.3
169
12.4
538
7.09
0.98
14.6
<5
<5 0.44
2/17/2014
10.5
<
1
18.8
_
<
5-:
17.7
13.1
24
_ 12.4.
548
7.51
1
_ 13
8.7 0.13
1/16/2014
< 10
<
1 <
5
< _
5
45.1
12.1
146
13.7
568
7.15
1.04
15.1
_
12/12/2013
< 10
<
1 <
5
<
5
27.3
_ 13.3
150
17.4
581
7.48
1.07_
16.2
_
11/14/2013
83.2
<
0.1 <
1
11.6
12
167
277
137
540
8.6
2.51
17.1
10/17/2013
18.5
<
0.1 <
1
_
< _
0.5
13.2
13.8
186
14
614
7.2
1.12
22.2-'-
9/17/2013
18.5
<
0.1 <
1
<
0.5
13.2
13.9
186
14
614
7.2
1.12
22.2
8/6/2013
12.1
<
1 <.
5
<
5
18.3
12.7
144
13.5
595
7.29
0.98
25.1
59.3 <10.0 <5 5.9 <5
_
7/14/2013
11.6
<
0.1 <
5
_
1.9
8.7
13.3
171
14
611
7.94
0.98
24.7
6/20/2013
11.8
<
_
0.1 <
5
_
1.6
10.9
12.9
166
15.4
606
8.36
1.94
23.9
5/20/2013
93.9
<
0.1 <
5
1 16.6
12.4
177
318
144
1000
7.45
0.99
21.3
4/17/2013
82
<
0.1 <
5
9.4
< 10
172
252
168
866
7.12
1.01
18._9
3/18/2013
15.7
<
0.1 <
5
_
<
5
< 10
_ 15.4
163
16.2
600
7.2
1.05
16.4
q
2/4/2013
15.7
<
0.1 <
1
_
1.1
11.6
25.3
176
24.1
328
7.46
1.085
14.6.
_ _
59.7 28.6 2.7 8.1 <16'
1/17/2013
< 1
<
0.1 <
5
< _
5
11.9
14.1
209
17.1
632
6.7
1.08
20.1
12/13/2012
10.8
_
<
_
0.1 <
5
<
5
< 10
15.6
185
17.2
663
7.14
1.14
18.5,(
_
11/19/2012
10.8
<
0.1 <
5
<
5
< 10
16.5
188
11.4;�.:
642
7.35
1.24
18.4
average
21.31
0.491
4.73
5.49
16.3
37.72
172.7�
34.7
601.39
7.43,
1.16'
19.8'.
_
53.7 79.8 4.1� 9.2
0.35
maximum
I 93.9
1
18.8
16.6
45.1
177
318
168
1000
8.6
2.51I
25.1
59.7
1311
5.5
13.51 1
1 1

2014 AU Number: I JAU Name:
AU Description:
Cape Fear River Basin
Length Area: AU Units: Classification:
Subbasin Northeast Cape Fear River
18-74-39b Burgaw Creek 9.5 FW Miles C;Sw
From Osgood Branch to Northeast Cape Fear River
IRCategory: ACS: Parameter Of Interest: Collection Year: 303(d) yr:
5 EC Copper (7 µg/l, AL, FW) 2008 2008
18-74-63-2 Burnt Mill Creek 4.6 FW Miles C;Sw
From source to Smith Creek
IRCategory:
5
5
ACS: Parameter Of Interest:
EC Benthos Poor (Nar, AL, FW)
EC Chlorophyll a (40 µg/I, AL, NC)
Collection Year: 303(d) yr:
1998 1998
2012 2014
18-74-19a Goshen Swamp 16.6 FW Miles C;Sw
From source to Bear Swamp
IRCategory: ACS: Parameter Of Interest: Collection Year: 303(d) yr:
5 EC Benthos Severe (Nar, AL, FW) 2009 2006
18-74-42 Lillington Creek 5.0 FW Miles C;Sw
From source to Northeast Cape Fear River
IRCategory: ACS: Parameter Of Interest: Collection Year: 303(d) yr:
S EC pH (4.3 su, AL, Sw) 2012 2010
18-74-55a Long Creek 7.7 FW Miles C;Sw
From source to Cypress Creek
IRCategory: ACS: Parameter Of Interest: Collection Year: 303(d) yr:
5 EC Benthos Severe (Nar, AL, FW) 2003 2006
18-74-33-5 Mill Pond 2.4 FW Miles C;Sw
From source to Holly Shelter Creek
IRCategory: ACS: Parameter Of Interest:
Collection Year: 303(d) yr:
1 5 EC pH (4.3 su, AL, Sw)
2012 2012
18-74-25 Muddy Creek
14.0 FW Miles C;Sw
From source to Mortheast Cape Fear River
IRCategory: ACS: Parameter Of Interest:
Collection Year: 303(d) yr:
5 EC Benthos Fair (Nar, AL, FW)
2003 2000
18-74-(61) Northeast Cape Fear River
1.0 S Acres SC;Sw
From mouth of Ness Creek to Cape Fear River
IRCategory: ACS: Parameter Of Interest:
Collection Year: 303(d) yr:
5e EC Copper (3 µg/I, AL, SW)
2008
2014 NC 303(d) List -Category 5 Final December 19, 2014 Page 18 of 149

NCDENR
North Carolina Department of Environment and Natural Resources
Division of Water Quality
Beverly Eaves Perdue Coleen H. Sullins Dee Freeman
Governor Director Secretary
August 10, 2011
NPDES Permit Renewal Staff Report
To: Julie Grzyb, NPDES Complex Permitting Unit
From: Dean Hunkele, Senior Environmental Specialist —Wilmington
Facility: PPD (NC0088811)
Specific Permit Comments:
1. The permit should be corrected to reflect the appropriate surface water classification of PNA
HQW. The permit needs to impose TSS limitations of 10 mg/L (daily maximum) instead of the
current limits.
2. The quarterly parameter monitoring months need to specified so "phantom" violations do not
occur in BIMS if system is ever built & used. For ease on everyone, it is recommended that the
same months as the toxicity monitoring are selected.
Wilmington Regional Office
127 Cardinal Drive Extension Wilmington, NC 28405
Phone: [phone] / FAX: [phone]
Internet: www.ncwaterguality.org
None Carolina
�tura!iff
An Equal Opportunity/Affirmative Action Employer
50% Recycled/10Y Post Consumer Paper
Customer Service 1-877-623-6748

ECS CAROLINAS, LLP "Setting the Standard for Service"
Geotechnical • Construction Materials • Environmental • Facilities NC Registered Engineerin9 Finn F-107e
July 29, 2011
North Carolina Department of Environment and Natural Resources
Division of Water Quality / NPDES Unit
1617 Mail Service Center
Raleigh, North Carolina 27699-1617
Reference: Permit Renewal Application
PPD
929 North Front Street
Wilmington, North Carolina
Permit No. NCO088811
ECS Carolinas, LLP (ECS) is providing the attached permit renewal application at the request of
PPD for their groundwater seepage discharge. The original permit was obtained on November
1, 2009.
The groundwater seepage is currently being discharged to the Cape Fear Public Utility Authority
(CFPUA) through CFPUA discharge permit N123. The groundwater is currently collecting in
sumps and is then pumped into a nearby CFPUA sewer manhole. A flow meter and sample
collection port are located between the collection sumps and CFPUA discharge manhole. Per
the CFPUA discharge permit, the discharge water is sampled monthly and the results from
2009 through June 2011 are summarized in the attached table.
As part of the CFPUA permit requirements, an alternative discharge option is required to be
addressed. To meet the CFPUA requirement, PPD obtained a NPDES discharge permit as an
alternative. However, the CFPUA discharge permit is more economically feasible. Therefore,
PPD has not used the NPDES discharge permit, which would require the construction of a
treatment system to reduce the ammonia and arsenic concentrations. PPD would like to renew
the NPDES discharge permit as a second alternative in the event the CFPUA discharge permit
is no longer an option. At that time, PPD would construct the required treatment system
necessary to meet the NPDES permit effluent limits.
Please contact either ECS at [phone] or Bob Verdinek with PPD at [phone] with
questions or comments.
Sincerely,
ECS Carolinas, LLP
0-6 c-cam
Amy C. Conchas, REM
Principal Scientist
Attachments: Permit Application
Rudy Smithick, P.G.
Environmental Department Manager
7211 Ogden Business Park, Suite 201, Wilmington, NC 28411 • T: 910-686-9114 • F: 910-686-9666 , www.ecslimited.com
ECS Capitol Services, PLLC • ECS Carolinas, LLP • ECS Florida, LLC • EGS Midwest, LLC • ECS Mid -Atlantic, LLC • ECS Southeast, LLC • ECS Texas, LLP

NPDES PERMIT APPLICATION - SHORTIORM C - GW
For discharges associated with groundwater treatment facilities.
Mail the complete application to:
N. C. Department of Environment and Natural Resources
Division of Water Quality / NPDES Unit
1617 Mail Service Center, Raleigh, NC 27699-1617
NPDES Permit Number INCO088811
If you are completing this form in computer use the TAB key or the up - doom arrows to move from. one
,field to the next. To check the boxes, click your mouse on top of the box. Otherwise, please print or type.
1. Contact Information:
Owner Name
Facility Name
Mailing Address
City
State / Zip Code
Telephone Number
Fax Number
e-mail Address
Pharmaceutical Product Devlopment, Inc.
Pharmaceutical Product Devlopment, Inc.
929 North Front Street
Wilmington
North Carolina 28402
[phone]
[phone]
[e-mail]
2. Location of facility producing discharge:
Check here if same as above
Street Address or State Road
City
State / Zip Code
County
3. Operator Information:
Name of the firm, consultant or other entity that operates the facility. (Note that this is not referring to the
Operator in Responsible Charge or ORQ
Name Pharmaceutical Product Devlopment, Inc.
Mailing Address 929 North Front Street
City Wilmington
State / Zip Code North Carolina 28402
Telephone Number [phone]
Fax Number [phone]
4. Ownership Status:
Federal ❑ State ❑ Private Z Public ❑

NPDES PERMIT APPLICATION - SHORf FORM C - GW
For discharges associated with groundwater treatment facilities.
S. Products recovered:
Gasoline ❑ Diesel fuel ❑ Solvents ❑ Other Ammonia
6. Number of separate discharge points: 1
OutfaU Identification number(s) 1
7. Frequency of discharge: Continuous ® Intermittent ❑
If intermittent:
Days per week discharge occurs: Duration:
S. Treatment System Design flow 0.288 MGD
9. Name of receiving stream(s) (Provide a map showing the exact location of each outfall, including
latitude and longitude
Northeast Cape Fear River Outfali Latitude 34° 14135"N Outfall Longitude 77°5714"W
10. Please list all additives to the treatment system, including chemicals or nutrients, that have
the potential to be discharged.
No additives
11. Is this facility located on Indian country? (check one)
Yes ❑ No
12. Additional Information
All applicants (including renewals):
A USGS topographical map (or copy of the relevant portion) which shows all outfalls
A summary of the most recent analytical results (effluent data, if available) containing the
maximum values for each chemical detected
NEW Applicants only:
Engineering Alternative Analysis
Description of remediation treatment system components, capacities, and removal efficiency
for detected compounds.
If the treatment system will discharge to a storm sewer, written approval from the
municipality responsible for the sewer.
A list of any chemicals found in detectable amounts at the site, with the maximum observed
concentration reported for each chemical (the most recent sample must be collected less
than one year prior to the date of this application)
For petroleum -contaminated sites - Analyses for Volatile Organic Compounds (VOC) should
be performed. Analyses for any fuel additives likely to be present at the site and for phenol
and lead should also be performed.
For sites contaminated with solvents or other contaminants - EPA Method 624/625
analysis should be performed.

NPDES PERMIT APPLICATION - SHORT ''FORM C - GW
For discharges associated with groundwater treatment facilities.
13. Applicant Certification
I certify that I am familiar with the information contained in the application and that to the
best of my knowledge and belief such information is true, complete, and accurate.
r
�� �Ri�.�.I�JC �%S.SoG .72tCrvR. �CK/ T/ES � �nl�...tE�'x•.� SdcS.
Printed name of Person Signing Title
Jo- `e,/ 7 - z49 -//
Signature of Applicant Date
North Carolina General Statute 143-215.6 (b)(2) provides that: Any person who knowingly makes any false
statement representation, or certification in any application, record, report, plan, or other document files or
required to be maintained under Article 21 or regulations of the Environmental Management Commission
implementing that Article, or who falsifies, tampers with, or knowingly renders inaccurate any recording or
monitoring device or method required to be operated or maintained under Article 21 or regulations of the
Environmental Management Commission implementing that Article, shall be guilty of a misdemeanor punishable
by a fine not to exceed $25,000, or by imprisonment not to exceed six months, or by both. (18 U.S.C. Section
1001 provides a punishment by a fine of not more than $25,000 or imprisonment not more than 5 years, or both,
for a similar offense.)

COA
YADKIN 4�iLM� '7y,�L�N�
-� M
PtLTRA TIO
I'Af
13
s
WI h.
a 1�syy LI
&
"TO
'
uAl I
Approximate Scale 1 inch =2,000 feet.
Contour Interval = 5 feet
Outfall Latitude 34°14'35"N
Outfall Longitude 77°57'4"W
FIGURE 1: OUTFALL MAP
Source: 115GS, Wilmington, North Carolina Quadrangle 1979.
Facility Latitude 34°14'45.2"N
Facility Longitude 77°57'56.3"W
TOWER
I N
PPD
929 North Front Street
Wilmington, North Carolina
ECS Project No. 22-11228C1

2009 - 2011 Analytical Results Summary
PPD - 929 North Front Street
Historical Effluent Monitoring Data
ECS Pro'ect 22-11228C1
Contaminant of Concern
E
¢
T
EEF
d
o
t2
m
m
a
U
o
`
E?o
n
om
'°
tJ
£
Z.
a
i
_
i
m
O
2
n
s
r
G
v°
?
°
E
y"
a
o
_
m
Sample ID
Date
Collected
POTW124G
Dt/12/09
NA
NA
NA
NA
NA
NA
268
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
7.91
10886
POTW125G
01116109
NA
50.8
SOL
NA
NA
NA
272
NA
NA
BDL NA
NA
NA
NA
NA
NA
NA
NA
47.1
928
15.0
NA
NA
NA
NA
8.04
10886
POTW126C
02/03,09
0.552
56.3
0.0163
BDL
9
BDL
243
BDL
70
0.012
BDL
0.119
BDL
BDL
BDL
SOL
0.320
BDL
48.8
972
24.0
SOL
0.3
BDL
BDL
8.33
10,061
POTWI27G
03/11/09
NA
1 50.5
10.0144
NA
NA
I NA
1 256
NA
NA
SOL
NA
NA
I NA
NA
NA
NA
NA
NA
51.2
881
1 7.0
1 NA
NA
NA
NA
7.62
11,425
POTW72BG
04/09/09
NA
54.1
0.03
NA
NA
NA
300
NA
NA
0.328
NA
NA
NA
NA
NA
NA
NA
NA
652
980
26.0
NA
NA
NA
NA
7.85
8.8%
POTW129G
05M 1109
0.177
43.8
BDL
NA
NA
NA
247
NA
NA
BDL
NA
NA
NA
NA
NA
NA
NA
NA
534
881
9.0
NA
NA
NA
NA
8.41
6,453
POTW130G
06/12/09
2.84
63.0
0.0178
NA
NA
NA
284
NA
NA
a264
NA
NA
NA
NA
NA
NA
NA
NA
67.9
936
BDL
NA
NA
NA
NA
8.43
11,279
POTW131G
07/15/09
0.173
41.8
0.0113
NA
NA
NA
261
NA
NA
0.0159
NA
NA
NA
NA
NA
NA
NA
NA
62.0
894
1A
NA
NA
NA
NA
7.94
14,956
POTW132C
08104111
2.73
47.9
0.0167
BDL
33
BDL
263
BDL
36.5
0.0166
BDL
0.779
SOL
BDL
BDL
SOL
0.289
BDL
48.3
884
BDL
0.0210
BDL
SOL
BDL
7.90
17.551
POTW133G
09/17/09
2.11
49.8
SOL
NA
NA
NA
268
NA
NA
SOL
NA
NA
NA
NA
NA
NA
NA
NA
55.9
920
4.0
NA
NA
NA
NA
7.60
16.021
POTW134G
10/19/09
1.87
50.6
BDL
NA
NA
NA
264
NA
NA
0.0105
NA
NA
NA
NA
NA
NA
NA
NA
48.1
946
BDL
NA
NA
NA
NA
8.45
12,917
POTW135G
11/19/09
0.809
47.6
0.0145
NA
NA
NA
247
NA
NA
10.02671
NA
NA
NA
NA
NA
NA
NA
NA
34.0
850
4.0
NA
NA
NA
NA
7.97
IZ537
POTW136G
12/17Po9
1.17
48.6
0.0108
NA
NA
NA
233
NA
I'IA
BDL
NA
NA
NA
NA
NA
NA
NA
NA
28.0
795
4.0
NA
NA
NA
NA
8.10
13,014
POTW137G
01/18/10
0.811
35.3
SOL
NA
NA
NA
227
NA
NA
BDL
NA
NA
NA
NA
NA
NA
NA
NA
40.5
752
3.6
NA
NA
NA
NA
8.37
13,757
POTWI39C
0209/10
1.06
46.1
0.0148
BDL
7.0
BDL
263
BDL
41.8
0.0159
BDL
0.590
SOL
BDL
SOL
BDL
0.302
BDL
52.6
769
6.5
BDL
SOL
BDL
SOL
8.64
12.939
POTW140G
03/17/10
0.955
33.5
0.0142
NA
NA
NA
325
NA
NA
0.0438
NA
NA
NA
NA
NA
NA
NA
NA
38.3
846
20.0
NA
NA
NA
NA
8.26
12.170
POTW141G
04/19/10
0.705
35
0.019
NA
NA
NA
237
NA
NA
0.348
NA
NA
NA
NA
NA
NA
NA
NA
3DA
865
71.0
NA
NA
SOL
NA8.06
10,453
POTWI42G
05/17/10
0.506
25.6
0.0179
NA
NA
NA
194
NA
NA
0.499
NA
NA
NA
NA
NA
NA
NA
NA
27.6
694
20.0
NA
NA
BDL
NA
7.89
10.780
POTW143G
06/18/10
W.100
34.5
0.0106
NA
NA
NA
210
NA
NA
0.012
NA
NA
NA
NA
NA
NA
NA
NA
35.7
765
BDL
NA
NA
SOL
NA
8.02
11.462
POTW144G
07/19/10
0.188
1 44.8
10.0152
NA
NA
NA
217
NA
NA1
0.1441
NA
NA
NA
NA
NA
NA
NA
NA 1
37.2
770
9.0
NA
NA
BDL
NA
7.89
10,538
POTW145C
08/03/10
0.275
40.4
0.0130
BDL
52
BDL
227
BDL
16.2
0.164
BDL
2.23
0.0240
BDL
0.0154
BDL
0.10
BDL
39.9
807
3.0
0.347
0.12
BDL
BDL
7.80
11.008
POTW146G
09/20/10
2.74
62.7
0.1560
NA
NA
NA
me
14t
NA
0.511
NA
NA
NA
NA
NA
NA
NA
NA
64.0
$55
4.0
NA
NA
SOL
NA
8.63
15788
POTW147G
10/14/11
1.09
39.0
0.0110
PIA
NA
NA
223
NA
NA
BDL
NA
NA
NA
NA
NA
NA
NA
NA
35.0
779
25.0
NA
NA
SOL
I NA 1
7.39 113.494
POTW148G
11/22/10
BDL
25.0
0.100
NA
NA
NA
210
NA
NA
0.0187
NA
NA
NA
NA
NA
NA
NA
NA
28.0
734
4.0
NA
NA
BDL I
NA 1
7.47
10669
POTW149G
12/20/10
024
71.9
0.0603
NA
NA
NA
281
NA
NA
SOL
NA
NA
NA
NA
NA
NA
NA
NA
74.1
775
54.0
NA I
NA
BDL
NA
7.62
10426
POTW750G
0119/11
0.27
25.5
SOL
NA
NA
NA
212
NA
NA
BDL
NA
NA
NA
NA
NA
NA
NA
NA
29.9
803
BDL
NA
NA
SOL
NA
8.50
10089
POTW151C
02/01/11
BDL
23.8
SOL
BDL
96
BDL
187
32.9
30.5
0.0135
0.0170
0.63
BDL
BDL
BDL
8.7
0.13
SOL
32.9
788
4.0
0.0278
0.13
BDL
SOL
8.30
10742
POTW152G
03/18/11
SOL
23.4I
L
NA
NA
PIA
178
NA
NA
0.01151
NA
NA
NA
NA
NA
NA
NA
NA
23.8
641
12.0
NA
NA
SOL
NA
7.88
9809
POTWI53G
04120/11
BDL
24.7
1 BDL
NA
NA
NA
194
NA
NA
BDL
NA
NA
NA
NA
NA
NA
NA
NA
25.5
671
7.0
NA
NA
SOL
NA
7.76
9215
POTW754G
05/18/11
0.523
25.7
0.0119
NA
NA
NA
P12
NA
NA
0. 104
NA
NA
NA
NA
NA
NA
NA
NA
23.9
1000
11.0
NA
NA
BDL
NA
7.T7
8969
PO:G
06/28/11
BDL
22.6
0.0108
NA
NA
NA
227
NA
NA
BDL
NA
NA
NA
NA
NA
NA
NA
NA
62.8
698
BDL
NA
NA
BDL
NA
7.55
8078
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