NC0000892_Monitoring Report_20160105

/l\rClin
Perfo.mance Applied
Arclin
790 Corinth Road
Moncure, NC 27559
January 5, 2016
Division of Water Quality
Attn: DWQ Central Files
1617 Mail Service Center
Raleigh, North Carolina 27699-1617
Re: Stormwater Sampling Results
Permit: NC0000892
Arclin USA, LLC
Chatham County
Class II
JAN � 6 2016
;,ENTfiR� iION
pVJR SEG
Please find enclosed the original and one copy of the Stormwater Discharge Monitoring Report for Year 3
— Period 12015. This report is for Arclin USA facility located at 790 Corinth Road, Moncure, North
Carolina.
Note: All stormwater during this rain event was contained on -site and sent to our wastewater treatment
ponds.
If you have any questions, please contact Bowman Harvey at 919-545-5753.
Sincerely,
Brian Reddy
Arclin
Plant Manager

STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
Permit Number NCS NC0000892
FACILITY NAME Arclin USA, LLC
PERSON COLLECTING SAMPLE(S) David Lorbacher
CERTIFIED LABORATORY(S) Pace Analytical Lab # 1312L94
Lab #
Part A: Specific Monitoring Requirements
SAMPLES COLLECTED DURING CALENDAR YEAR: 2015
(This monitoring report shall be received by the Division no later than 30 days from
the date the facility receives the sampling results from the laboratory.)
COUNTY Chatham
PHONE NO. [phone]
SIGNATURE OF PERMITTEE OR DESIGNEE
REQUIRED ON PAGE 2.
Outfall
No.
Date
Sample
Collected
00400
00556
00310
00530
00600
00610
00665
00340
71880
pH
Total
Rainfall
Oil &
Grease
BOD 5
Day
TSS
Total
Nitrogen
Ammonia
Total as N
Phosphorus
COD
Formaldehyde
Phenolics, Total
mo/dd/ r
Standard
inches
M /L
M /L
M L
M /L
M
M /L
M /L
M
M /L
002
11/30/15
6.2
.6
ND
120
93
25.4
1.2
.30
870
13
25
003
11/30/15
6.2
.6
ND
120
12.7
13.7
0.72
.082
1240
58
44.3
004
11/30/15
6.4
.6
ND
2.5
4.0
5.6
.37
.074
51
.14
ND
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month? _ yes X no
(if yes, complete Part B)
Part B: Vehicle Maintenance Activitv Monitoring Requirements
Outfall
No.
Date
Sample
Collected
50050
00556
00530
00400
Total Flow
(if applicable)
Total
Rainfall
Oil & Grease
(if appl.)
Non -polar
O&G/TPH
(Method 1664
SGT-HEM), if
appl.
Total
Suspended
Solids
pH
New Motor
Oil Usage
mo/dd/ r
MG
inches
m /I
m /l
unit
al/mo
Form SW U-247, last revised 21212012
Page 1 of 2

STORM EVENT CHARACTERISTICS:
Date 11/30/15
Total Event Precipitation (inches): .6
Event Duration (hours): (only if applicable — see permit.)
(if more than one storm event was sampled)
Date
Total Event Precipitation (inches):
Event Duration (hours): (only if applicable — see permit.)
Mail Original and one copy to:
Division of Water Quality
Attn: Central Files
1617 Mail Service Center
Raleigh, North Carolina 27699-1617
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a
system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person
or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the
best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations."
(Signature of
/ ^ `/r,C
(Date)
Form SW U-247, last revised 21212012
Page 2 of 2

aceAlnalytical
WWW.pm1ab&cam
Pace Analytical Services, Inc.
6701 Conference Drive
Raleigh, NC 27607
[phone]
December 11, 2015
David Lorbacher
Arcl i n-Dy nea/M o n cu re
790 Corinth Road
Chapel Hill, NC 27599
RE: Project: Arclin002
Pace Project No.: 92277937
Dear David Lorbacher:
Enclosed are the analytical results for sample(s) received by the laboratory on December 01, 2015.
The results relate only to the samples included in this report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
Some analyses have been subcontracted outside of the Pace Network. The subcontracted
laboratory report has been attached.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
�� Gti-►.--- �/Y�11-j4j�
Liamm Harrison
[e-mail]
Project Manager
Enclosures
cc: Bowman Harvey, Acrlin-Dynea/Moncure
Chis Lamm, Arclin-Dynea/Moncure
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 1 of 26

aCc. eAna1j6ca /
www.pacelabs.com
Pace Analytical Services, 4nc.
6701 Conference Drive
Raleigh, NC 27607
[phone]
CERTIFICATIONS
Project: Arclin002
Pace Project No.: 92277937
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Florida/NELAP Certification #: E87627
North Carolina Drinking Water Certification #: 37706
Kentucky UST Certification #: 84
North Carolina Field Services Certification #: 5342
West Virginia Certification #: 357
North Carolina Wastewater Certification #: 12
VirginiaNELAP Certification #: 460221
South Carolina Certification #: 99006001
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
North Carolina Wastewater Certification #: 40
Florida/NELAP Certification #: E87648
South Carolina Certification #: 99030001
Massachusetts Certification #: M-NC030
West Virginia Certification #: 356
North Carolina Drinking Water Certification #: 37712
Virginia/VELAP Certification #: 460222
Eden Certification lDs
205 East Meadow Road Suite A, Eden, NC 27288
North Carolina Wastewater Certification #: 633
North Carolina Drinking Water Certification #: 37738
Virginia/VELAP Certification #: 460025
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 2 of 26

acenA17a1Xka!
wmpacel com
Pace Analytical Services, Inc.
6701 Conference Drive
Raleigh, NC 27607
(919)8344984
SAMPLE ANALYTE COUNT
Project: Arclin002
Pace Project No.: 92277937
Lab ID Sample ID Method
Analysts
Analytes
Reported
Laboratory
92277937001 Arcl1n002 HACH 10206
DWJ
1
PASI-E
SM 2540D
CHM
1
PASI-E
SM 4500-NO2 B
DWJ
1
PASI-E
SM 5210B
DWJ
1
PASI-E
EPA 1664E
JMS
1
PASI-C
EPA 9040
MLS
1
PASI-A
EPA 350.1
WRC
1
PASI-A
EPA 351.2
SER
1
PASI A
EPA 365.1
AES2
1
PASI-A
EPA 420.4
DMN
1
PASI-A
SM 5220D
WRC
1
PASI-A
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 3 of 26

aceAnalyftal
www.pacelabs.win
Pace Analytical Services, Inc.
6701 Conference Drive
Raleigh, NC 27607
[phone]
ANALYTICAL RESULTS
Project: Arclin002
Pace Project No.: 92277937
Sample: Arclin002
Lab ID: 92277937001 Collected:
11/30/1510:30
Received: 12/01/15 09:45 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
HACH 10206 Nitrogen, Nitrate
Analytical Method: HACH 10206
Nitrogen, Nitrate
11.0 mg/L
0.60
2
12/02/15 09:35
2540D Total Suspended Solids
Analytical Method: SM 2540D
Total Suspended Solids
93.0 mg/L
5.6
1
12/02/1511:00
D6
450ONO2B Nitrite, unpres
Analytical Method: SM 4500-NO2 B
Nitrogen, Nitrite
0.25 mg/L
0.050
5
12/02/15 10:20
5210E BOD, 5 day EDN
Analytical Method: SM 5210B
BOD, 5 day
120 mg/L
2.0
1
12/02/1510:25 12/07/15 09:30
132
HEM, Oil and Grease
Analytical Method: EPA 1664B
Oil and Grease
ND mg/L
5.0
1
12/03/15 05:29
9040 pH
Analytical Method: EPA 9040
pH
6.2 Std. Units
0.10
1
12/03/15 15:45
H6
350.1 Ammonia, Low Level
Analytical Method: EPA 350.1
Nitrogen, Ammonia
1.2 mg1L
0.010
1
12/09/15 01:00
7664-41-7
351.2 Total Kjeldahl Nitrogen
Analytical Method: EPA 351.2
Nitrogen, Kjeldahl, Total
25.4 mg/L
2.5
5
12/04/15 03:16
7727-37-9
365.1 Phosphorus, Total
Analytical Method: EPA 365.1
Phosphorus
0.30 mg/L
0.050
1
12/04/15 09:33
7723-14-0
420.4 Phenolics, Total
Analytical Method: EPA 420.4
Phenol
25.0 mg/L
3.0
300
12/03/1519:25
108-95-2
5220D COD
Analytical Method: SM 5220D
Chemical Oxygen Demand
870 mg/L
25.0
1
12/08/1515:10
Date: 12/11/2015 10:54 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 4 of 26

aceArla�ytical
www.pacelabs.com
Pace Analytical Services, Inc.
6701 Conference Drive
Raleigh, NC 27607
[phone]
QUALITY CONTROL DATA
Project: Arclin002
Pace Project No.: 92277937
QC Batch: EDEN/20930
Analysis Method: HACH 10206
QC Batch Method: HACH 10206
Analysis Description: 10206 Nitrogen, Nitrate
Associated Lab Samples: 92277937001
METHOD BLANK: 1617791
Matrix: Water
Associated Lab Samples: 92277937001
Blank Reporting
Parameter Units
Result Limit Analyzed Qualifiers
Nitrogen, Nitrate mg/L
ND 0.30 12/02/15 09:35
LABORATORY CONTROL SAMPLE: 1617792
Spike LCS LCS % Rec
Parameter Units
Conc. Result % Rec Limits Qualifiers
Nitrogen, Nitrate mg/L
5 4.8 95 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1617793 1617794
MS MSD
92277933001
Spike Spike MS MSD MS MSD % Rec
Parameter Units Result
Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Nitrate mg/L 9.1
5 5 14.8 14.8 114 114 90-110 0 M1
Results presented on this page are in the units indicated by the "units" column except where an alternate unit is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full.
Date: 12/11 /2015 10:54 AM without the written consent of Pace Analytical Services, Inc..
Page 5 of 26

aC.eAnalyNo/
wmpacelebs.com
Pace Analytical Services,dnc.
6701 Conference Drive
Raleigh, NC 27607
[phone]
QUALITY CONTROL DATA
Project: Arclin002
Pace Project No.: 92277937
QC Batch: EDEN/20933
Analysis Method:
SM 2540D
QC Batch Method: SM 2540D
Analysis Description:
2540D Total Suspended Solids
Associated Lab Samples: 92277937001
METHOD BLANK: 1617895
Matrix: Water
Associated Lab Samples: 92277937001
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Total Suspended Solids
mg/L
ND
2.5 12/02/1510:49
LABORATORY CONTROL SAMPLE: 1617896
Spike LCS
LCS % Rec
Parameter
Units
Conc. Result
% Rec Limits Qualifiers
Total Suspended Solids
mg/L
250 270
108 90-110
SAMPLE DUPLICATE: 1617897
92277785002 Dup
Parameter
Units
Result Result
RPD Qualifiers
Total Suspended Solids
mg/L
ND
H.7
SAMPLE DUPLICATE: 1617898
92277937001 Dup
Parameter
Units
Result Result
RPD Qualifiers
Total Suspended Solids
mg/L
93.0
115 21 D6
Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/11/201510:54 AM without the written consent of Pace Analytical Services, Inc..
Page 6 of 26

ace Analj cal
t e'W-Pacelabs.com
Pace Analytical Services, Inc.
6701 Conference Drive
Raleigh, NC 27607
[phone]
QUALITY CONTROL DATA
Project: Arclin002
Pace Project No.: 92277937
QC Batch: EDEN/20932 Analysis Method: SM 4500-NO2 B
QC Batch Method: SM 4500-NO2 B Analysis Description: 4500NO26, Nitrite, unpres
Associated Lab Samples: 92277937001
METHOD BLANK: 1617812 Matrix: Water
Associated Lab Samples: 92277937001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen, Nitrite mg/L ND 0.010 12/02/15 10:20
LABORATORY CONTROL SAMPLE: 1617813
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Nitrogen, Nitrite mg/L .1 0.11 108 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1617814 1617815
MS MSD
92277851001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Nitrite mg/L ND .1 .1 0.10 0.10 104 104 90-110 0
Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/11/2015 10:54 AM without the written consent of Pace Analytical Services, Inc..
Page 7 of 26

aceAnalX cal
www.pacelabscom
Pace Analytical Services, Inc.
6701 Conference Drive
Raleigh, NC 27607 .
[phone]
QUALITY CONTROL DATA
Project: Arclin002
Pace Project No.: 92277937
QC Batch: EDEN/20928
Analysis Method:
SM 5210B
QC Batch Method: SM 5210B
Analysis Description:
5210E BOD, 5 day EDN
Associated Lab Samples: 92277937001
METHOD BLANK: 1617770
Matrix: Water
Associated Lab Samples: 92277937001
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
BOD, 5 day
mg/L
ND
2.0 12/07/15 09:30
LABORATORY CONTROL SAMPLE: 1617771
Spike LCS
LCS % Rec
Parameter
Units
Conc. Result
% Rec Limits Qualifiers
BOD, 5 day
mg/L
198 172
87 84.6-115.4
SAMPLE DUPLICATE: 1617772
92277933001 Dup
Parameter
Units
Result Result
RPD Qualifiers
BOD, 5 day
mg/L
120
120 0 B2
Results presented on this page are In the units indicated by the "units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/11 /2015 10:54 AM without the written consent of Pace Analytical Services, Inc..
Page 8 of 26

aceArtalyical
www.pecelabs.com
Pace Analytical Services, Inc.
6701 Conference Drive
Raleigh, NC 27607
(919)8344984
QUALITY CONTROL DATA
Project: Arclin002
Pace Project No.: 92277937
QC Batch: GCSVI23413
Analysis Method:
EPA 1664E
QC Batch Method: EPA 1664E
Analysis Description:
1664 HEM, Oil and Grease
Associated Lab Samples: 92277937001
METHOD BLANK: 1618755
Matrix: Water
Associated Lab Samples: 92277937001
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Oil and Grease
mg/L
ND 5.0 12/03/15 05:22
LABORATORY CONTROL SAMPLE:
1618756
Spike LCS
LCS % Rec
Parameter
Units
Conc. Result
% Rec Limits Qualifiers
Oil and Grease
mg/L
40 34.5
86 78-114
MATRIX SPIKE SAMPLE:
1618757
92277182001 Spike
MS MS % Rec
Parameter
Units
Result Conc.
Result % Rec Limits Qualifiers
Oil and Grease
mg/L
ND 40
37.1 93 78-114
Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/11/2015 10:54 AM without the written consent of Pace Analytical Services, Inc..
Page 9 of 26

aceAnalj cal
www.pacelabs.com
Pace Analytical Services, Inc.
6701 Conference Drive
Raleigh, NC 27607
[phone]
QUALITY CONTROL DATA
Project: Arclin002
Pace Project No.: 92277937
QC Batch: WET/41714 Analysis Method: EPA 9040
QC Batch Method: EPA 9040 Analysis Description: 9040 pH
Associated Lab Samples: 92277937001
SAMPLE DUPLICATE: 1618792
92277933001 Dup
Parameter Units Result Result RPD Qualifiers
pH Std. Units 6.2 6.3 1 D6,H6
Results presented on this page are In the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/11/2015 10:54 AM without the written consent of Pace Analytical Services, Inc..
Page 10 of 26

aceAnafyfca!
www.pacelab&cam
Pace Analytical Services, Inc.
6701 Conference Drive
Raleigh, NC 27607
[phone]
QUALITY CONTROL DATA
Project: Arclin002
Pace Project No.: 92277937
QC Batch: WETA/25661
Analysis Method: EPA 350.1
QC Batch Method: EPA 350.1
Analysis Description: 350.1 Ammonia, Low Level
Associated Lab Samples: 92277937001
METHOD BLANK: 1621670
Matrix: Water
Associated Lab Samples: 92277937001
Blank
Reporting
Parameter Units
Result
Limit
Analyzed Qualifiers
Nitrogen, Ammonia mg/L
ND 0.010
12/09/15 01:00
LABORATORY CONTROL SAMPLE: 1621671
Spike
LCS
LCS % Rec
Parameter Units
Conc.
Result
% Rec Limits Qualifiers
Nitrogen, Ammonia mg/L
1
0.92
92 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1621672
1621673
MS
MSD
92277933001
Spike
Spike MS
MSD MS MSD
% Rec
Parameter Units Result
Conc.
Conc. Result
Result % Rec % Rec
Limits
RPD Qual
Nitrogen, Ammonia mg/L 0.72
1
1 1.1
1.1 36 36
90-110
0 M1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1621674
1621675
MS
MSD
92278045012
Spike
Spike MS
MSD MS MSD
% Rec
Parameter Units Result
Conc.
Conc. Result
Result % Rec % Rec
Limits
RPD Qual
Nitrogen, Ammonia mg/L 0.050
1
1 0.71
0.71 66 66
90-110
1 M1
Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/11/201510:54 AM without the written consent of Pace Analytical Services, Inc..
Page 11 of 26

aceAnalX cal
www.pacerabscom
Pace Analytical Servicesn Inc.
6701 Conference Drive
Raleigh, NC 27607 •
[phone]
QUALITY CONTROL DATA
Project: Arclin002
Pace Project No.: 92277937
QC Batch: WETA/25619
Analysis Method: EPA 351.2
QC Batch Method: EPA 351.2
Analysis Description: 351.2 TKN
Associated Lab Samples: 92277937001
METHOD BLANK: 1619040
Matrix: Water
Associated Lab Samples: 92277937001
Blank Reporting
Parameter Units
Result Limit
Analyzed
Qualifiers
Nitrogen, Kjeldahl, Total mg/L
ND 0.50 12/04/15 02:41
LABORATORY CONTROL SAMPLE: 1619041
Spike LCS
LCS
% Rec
Parameter Units
Conc. Result
% Rec
Limits
Qualifiers
Nitrogen, Kjeldahl, Total mg/L
10 10.4
104
90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1619042 1619043
MS MSD
92276933001
Spike Spike MS
MSD
MS
MSD
% Rec
Parameter Units Result
Conc. Conc. Result
Result
% Rec
% Rec
Limits
RPD Qual
Nitrogen, Kjeldahl, Total m 3.9
10 10 16.0
14.7
121
107
90-110
9 M1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1619044 1619045
MS MSD
92278126001
Spike Spike MS
MSD
MS
MSD
% Rec
Parameter Units Result
Conc. Conc. Result
Result
% Rec
% Rec
Limits
RPD Qual
Nitrogen, Kjeldahl, Total mg/L 1.7
10 10 13.2
11.9
115
103
90-110
10 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12111/201510:54 AM without the written consent of Pace Analytical Services, Inc..
Page 12 of 26

acmnal lcal
�� --�J/
www.Facelabscom
Pace Analytical Services, Inc.
6701 Conference Drive
Raleigh, NC 27607
[phone]
QUALITY CONTROL DATA
Project: Arclin002
Pace Project No.: 92277937
QC Batch: WETA/25621
Analysis Method: EPA 365.1
QC Batch Method: EPA 365.1
Analysis Description: 365.1 Phosphorus, Total
Associated Lab Samples: 92277937001
METHOD BLANK: 1619062
Matrix: Water
Associated Lab Samples: 92277937001
Blank
Reporting
Parameter Units
Result
Limit
Analyzed Qualifiers
Phosphorus mg/L
ND 0.050
12/04/15 09:18
LABORATORY CONTROL SAMPLE: 1619063
Spike
LCS
LCS % Rec
Parameter Units
Conc.
Result
% Rec Limits
Qualifiers
Phosphorus mg/L
2.5
2.7
109 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1619064
1619065
MS
MSD
92277491003
Spike
Spike MS
MSD MS
MSD
% Rec
Parameter Units Result
Conc.
Conc. Result
Result % Rec
% Rec
Limits
RPD Qual
Phosphorus mg/L 139
125
125 269
266 104
102
90-110
1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1619066
1619067
MS
MSD
92277927004
Spike
Spike MS
MSD MS
MSD
% Rec
Parameter Units Result
Conc.
Conc. Result
Result % Rec
% Rec
Limits
RPD Qual
Phosphorus mg/L 124
125
125 252
252 103
103
90-110
0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/11/2015 10:54 AM without the written consent of Pace Analytical Services, Inc..
Page 13 of 26

aceAnalyical®
www.pacelabs ccm
Pace Analytical Services; Inc.
6701 Conference Drive
Raleigh, NC 27607
[phone]
QUALITY CONTROL DATA
Project: Arclin002
Pace Project No.: 92277937
QC Batch: WETA/25614
Analysis Method: EPA 420.4
QC Batch Method: EPA 420.4
Analysis Description: 420.4 Phenolics
Associated Lab Samples: 92277937001
METHOD BLANK: 1618673
Matrix: Water
Associated Lab Samples: 92277937001
Blank Reporting
Parameter Units
Result Limit
Analyzed
Qualifiers
Phenol mg/L
ND 0.010 12/03/1518:30
LABORATORY CONTROL SAMPLE: 1618674
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits
Qualifers
Phenol mg/L
.05 0.049
99 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1618675 1618676
MS MSD
92277023003
Spike Spike MS
MSD MS
MSD
% Rec
Parameter Units Result
Conc. Conc. Result
Result % Rec
% Rec
Limits RPD Qual
Phenol mg/L ND
.05 .05 0.055
0.055 91
91
90-110 1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1618677 1618678
MS MSD
92277023004
Spike Spike MS
MSD MS
MSD
% Rec
Parameter Units Result
Conc. Conc. Result
Result % Rec
% Rec
Limits RPD Qual
Phenol mg/L ND
.05 .05 0.055
0.055 94
93
90-110 1
Results presented on this page are In the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/11/201510:54 AM without the written consent of Pace Analytical Services, Inc..
Page 14 of 26

aceAnalytica!
mmPacelabs.com
Pace Analytical Services, Inc.
6701 Conference Drive
Raleigh, NC 27607
[phone]
QUALITY CONTROL DATA
Project: Arclin002
Pace Project No.: 92277937
QC Batch: WETA/25660
Analysis Method: SM 5220D
QC Batch Method: SM 5220D
Analysis
Description: 5220D COD
Associated Lab Samples: 92277937001
METHOD BLANK: 1621659
Matrix: Water
Associated Lab Samples: 92277937001
Blank
Reporting
Parameter Units
Result
Limit
Analyzed Qualifiers
Chemical Oxygen Demand mg/L
ND 25.0
12/08/1515:10
LABORATORY CONTROL SAMPLE: 1621660
Spike
LCS
LCS
% Rec
Parameter Units
Cone.
Result
% Rec
Limits Qualifiers
Chemical Oxygen Demand mg/L
750
740
99
90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1621661
1621662
MS
MSD
92277826001
Spike
Spike MS
MSD
MS MSD
% Rec
Parameter Units Result
Cone.
Cone. Result
Result
% Rec % Rec
Limits
RPD Qual
Chemical Oxygen Demand mg/L 53.0
750
750 762
762
95 95
90-110
0
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1621663
1621664
MS
MSD
92277927004
Spike
Spike MS
MSD
MS MSD
% Rec
Parameter Units Result
Conc.
Conc. Result
Result
% Rec % Rec
Limits
RPD Qual
Chemical Oxygen Demand mg/L 272
3000
3000 3000
3000
91 91
90-110
0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/11/201510:54 AM without the written consent of Pace Analytical Services, Inc..
Page 15 of 26

aceAna1j&a1
wmpacelabs com
Pace Analytical Services, Inc.
6701 Conference Drive
Raleigh, NC 27607 4
[phone]
QUALIFIERS
Project: Arclin002
Pace Project No.: 92277937
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
LABORATORIES
PASI-A Pace Analytical Services -Asheville
PAST-C Pace Analytical Services - Charlotte
PASI-E Pace Analytical Services - Eden
ANALYTE QUALIFIERS
B2 Oxygen usage is less than 2.0 for all dilutions set. The reported value is an estimated less than value and is calculated
for the dilution using the most amount of sample.
D6 The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits.
H6 Analysis initiated outside of the 15 minute EPA recommended holding time.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/11/2015 10:54 AM without the written consent of Pace Analytical Services, Inc.. Page 16 of 26

4 0
aceAnalXical
Wmpacelebs.com
Pace Analytical Services, Inc.
6701 Conference Drive
Raleigh, NC 27607
(919)8344984
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: Arclin002
Pace Project No.: 92277937
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch Analytical Method Batch
92277937001
Arclin002
HACH 10206
EDEN/20930
92277937001
Arclin002
SM 2540D
EDEN/20933
92277937001
Arclin002
SM 4500-NO2 B
EDEN/20932
92277937001
Arclln002
SM 5210B
EDEN/20928 SM 5210B EDEN/20935
92277937001
Arclin002
EPA 1664B
GCSV/23413
92277937001
Arclin002
EPA 9040
WET/41714
92277937001
Arclin002
EPA 350.1
WETA/25661
92277937001
Arclln002
EPA 351.2
WETA/25619
92277937001
Arclin002
EPA 365.1
WETA/25621
92277937001
Arclin002
EPA 420.4
WETA/25614
92277937001
Arclin002
SM 5220D
WETA/25660
Date: 12/11 /201510:54 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 17 of 26

_ ..:;)C6Aq?1YtiC81
I N1.AV /J �rCr/Jr� Ccr,fr
Document Name: Sample Condition Upon
Document Revised: May 15, 2416
Receipt (SCUR)
Pare 1 of 2'
r
Document No.:
Issuing Authorities:
F-RAL-CS-001-rev.03
face Raleigh Quality of;:e::e
'Page 2 of 2is for Internal Use fJrti:r
Client Name: P�i 61) Y� 1���
Courier (Circle): Fed Ex UPS USPS Client Commercial Pace Other
Custody Seal on Coolor/Box Present: C yes K' no Seals intact: -n yes C no
Packing Material: C Burble Wrap Bubble Bags None Other
Circle Thermometer Used: lR Gun S J22065387�e of ice: V'Jet 8tcte NoneNoneSamplss on ice, cooling process has begun
IR Min flee l �4T�r1�r-479n9r't71
Temp Correction Factor: Add 1 lbtr� C
Date and Initials of person axemining
Corrected Cooler Temp.: `'l C
p„ 1
Biolo ical Tissue is Frozen: yes rio ktr,
g
c tl r s !Prase rat n
clrQck t
Temp shoud be above Wozing to 63C
Comments:
Chain of Custody Present:
Chas ONo
ON/A
1.
Chain of Custody Filled Out:
-,. ONO
ON►A
2.
Chairs of Custody Relinquished:
'es ONO
ONIA
3.
Sampler Name & Signature on COC:
6YO.s CNo
❑N!A
4.
t Sart Alas Arrived within Hold Time:
Yes 014o
OWA
5.
Short Hold Time Analysis <72hr):
4Yes CNo
ONIA
6. G
Rush Turn Around Time Requested:
OYcs RLI
0N1A
7.
Strfficiont Volume:
)'as ONO,
ON/A
8.
Caret( Containers Used:
Yes Otto
ONbi
9.
-Pact: Containers used:
1'os ONO
❑NIA
Containers Intact:
Yes ONO
ONIA
10.
Filtered vclume received for Dissolved tests
OYes C14o
UAIA
11.
Sample Labels match COC:
IY13S ONO,
ONIA
12.
Incluces date/time!10/Anal sis Matrix:
_
All corUiners nea,ing praservadon have boon checked.
Yes 0No
❑NIA
13.
,A'l centain-:rs needing prese.-vation are found to be in
wyas ❑r:o
ONIA
compliance with EPA recommendation.
ex::ep�ions: VOA, colilomi. TOC. O&G. Wl•ORO (waver)
X11jesD&%Io
Srsmplus checked for deci:lorination:
Yes rJrlo
ONiA
14.
hleadspace in VOA Vials ; >6mm):
OYNs Otto
N/A
i6.
'i'rip 3:ank Present:
Oyes Oro
NIA
16.
Trip Blank Custody Seals Present
❑Yes ONO
JNIA
Pace Trip Blank Lot # (if purchased):
Client Nottficationi Resolution:
Person Contacted:
;nu. en'sf Resoiution
Dateliimc:
SCURF /SRF LA_X
Date:
Review::
Note: Whenever there is a discrepancy affecting North Carolina compliance
-mmplas, a copy of this form vAl be sent to the North Carolina DEH14R
Cr:nifcation Oirrco ( i.e out of hold, incorrect preservative, out of tee-np,
incorrect containers)
Field Data Required? Y / N
WO#:92277937
833]]83]
4
Page 18 of 26

ae�,At�lytica!
.-coon A
tequlrrd (,lion: Information -
CHAIN -OF -CUSTODY l Analytical Request Document
r11.�, 4;11a•11 • •r Cu•:t+xtj Ic a LEGAL Ct: +::U:.t� NT. %!i r,-lr- v: int 5-:1a3 must W anrit;:leled a•:eurz:�tY.
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N loncurC, NC 27559
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RE((LINOUI -D BY / AFFILIATION
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A& ANALYTICAL ENVIRONMENTAL SERVICES, INC.
AES
December 11, 2015
Taylor Ezell
Pace Analytical Services, Inc.
9800 Kincev Avenue. Suite 100
HuntersviIle NC 28078
TEL: [phone]
FAX: [phone]
RE: 92277937
Dear Taylor Ezell: Order No: 1512264
Analytical Environmental Services, Inc. received 1 samples on 12/3/2015 10:40:00 AM
for the analyses presented in following report.
No problems were encountered during the analyses. Additionally, all results for the associated
Quality Control samples were within EPA and/or AES established limits. Any discrepancies
associated with the analyses contained herein will be noted and submitted in the form of a
project Case Narrative.
AES' certifications are as follows:
-NELAC/Florida Certification number E87582 for analysis of Environmental Water,
soil/hazardous waste, and Drinking Water Microbiology, effective 07/01/15-06/30/16.
-AIHA-LAP, LLC Laboratory ID: 100671 for Industrial Hygiene samples (Organics,
Inorganics), Environmental Lead (Paint, Soil, Dust Wipes, Air), and Environmental
Microbiology (Fungal) Direct Examination, effective until 09/01/17.
These results relate only to the items tested. This report may only be reproduced in full.
If you have any questions regarding these test results, please feel free to call.
Dorothy deBruvn
Project Manager
3080 Presidential Drive - Atlanta, Georgia 30340 - Tel: [phone] - Fax: [phone] - Toll Free: 800.972.4889
www.aesatlanta.coni Page 1 of 7
Page 20 of 26

•
tbVcrkorder_ 92277937 Worl:crder Name: Arclin002 Result's Requested 121151201E
Repoit I Jnvolce To , .-
; Suticontracx.To„ _
'
RecEcQSt8dinital�rsls
Uamm Har(Lson
L E SAD
Pace Analytical Charlotte
P.O.
9800 Kincey Ave. Suite 100
Hun`wrsville, NC 28078
n�
Phone [phone]
Email: [e-mail]
Preserved Cc.-taisters:: .
�• ...
`
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1 a
l
.
.. .... .. • .. • :.. • .. �
'ColleCE ... .:
•:''.. .. w
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Sal ple lt? _
Datpr itie` ' .
Las lD ,
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1
Arclin002
11130/201510:30
92277837001
hater
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X
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2
3
4
5
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! ='r .Coma
'DateMme
Transfers Released By
Daterrime kocelved By
1 t
iZ c� I t <-s
12
l
3 t
I Cooler Temperature on Receipt
'C Custody Seal
Y or
N Received on lee Y or N Sam
"=fn order to maintain client confidentiality, locadon/name of the samprng site, samplers name and signature may not be provraea an rnrs' k,
This chain of custody is considered complete as is since this information is available in the owner laboratory.
FMT ALL-C-002reu00 24Miarc
Tuesday. Dece-mwwr 01. 2015 5:02:09 K-A

Analytical Environmental Services, Inc
Date: 11-Dec-15
Client: Pace Analytical Services, Inc.
Project: 92277937 Case Narrative
Lab ID: 1512264
Samples arrived after hold time expired. Proceed with analysis per Liamm Harrison via email on 12/3/15.
Formaldehyde Analysis by Method 8315:
Sample 1512264-001 A was received and extracted and/or analyzed outside holding time of 72 hours.
Page 3 of 7
Page 22 of 26

Analytical Environmental Services, Inc
Date: 11-Dec-15
Client:
Pace Analytical Services, Inc.
Client Sample ID:
ARCLIN002
Project Name:
92277937
Collection Date:
11/30/2015 10:30:00 AM
Lab ID:
1512264-001
Matrix:
Aqueous
Analyses reporting Dilution
Y Result Qual Units QatchID Date Analyzed Analyst
Limit
Factor
Carbonyl Compounds by HPLC SW8315A
Formaldehyde
Qualirsers: • Value exceeds maximum contaminant level
BRL Below reporting limit
H Holding times for preparation or analysis exceeded
N Analyte not NELAC certified
B Analyte detected in the associated method blank
> Greater than Result value
13000. 500 H ug/L 216846 1 12/092015 20:19 RF
13 1,4,�
E
Estimated (value above quantitation range)
S
Spike Recovery outside limits due to matrix
Nary
See case narrative
NC
Not confirmed
<
Less than Result value
1
Estimated value detected below Reporting Limit
Page 4 of 7
Page 23 of 26

i
Analytical Environmental Services, Inc.
Sample/Cooler Receipt Checklist
Work Order Number
Checklist completed by
_ �l
Sign re
Date
/UPS
Carrier name: FedEx Courier
_ _• : Client _
US Mail _ Other
Shipping container/cooler in good condition?
Yes k/
.—
No _
Not Present
ent
Custody seals intact on shipping container/cooler?
Yes
No
Not Present
Custody seals intact on sample bottles?
Yes —
No
Not Present ✓
—
Container/Temp Blank temperature in compliance? (0°560Q* Yes ✓
No
Cooler 01 Cooler #2
Cooler #3
Cooler #4
Cooler#5 Cooler #6
Chain of custody present?
Yes ✓
No
Chain of custody signed when relinquished and received?
Yes ✓
No
Chain of custody agrees with sample labels?
Yes -�
No —'
Samples in proper container/bottle?
Yes ✓
No
Sample containers intact?
Yes ✓
No
Sufficient sample volume for indicated test?
Yes —
_
No
All samples received within holding time?
Yes __..
No
Was TAT marked on the •COC?
Yes v
No _
Proceed with Standard TAT as per project history?
Yes ._._
No _
Not Applicable
pp
Water -.VOA vials have zero headspace? No VOA vials submitted
'Yes
—
— No
Water - pH acceptable upon receipt?
•
Y� 1G
No
. Not Applicable
/ Adjusted?
Sample Condition: Good ✓ Other(Explain)
Checked by
J
(For diffusive -samples or AIHA lead) Is a known blank included? Yes
—
No s/
See Case Narrativr'for resolutionpf the Non: -Conformance.
r
r
*Samples do not hay. co ;;Orn :it, NWth the given range for certain parameters.
11Aes serverVlSarnpleReceipt\My DocumentslCOCs and pH Adjustment Sheet\Samplt _Cooler Recipt Checklist Revi.rtf
r
Page 5 of 7
Page 24 of 26

Analytical Environmental Services, Inc
Client: Pace Analytical Services, Inc.
Project Name: 92277937
Lab Order: 1512264
Da
Lab Sample ID Client Sample ID Collection Date Matrix Test Name TCLP Date
1512264-001A ARCLIN002 11/30/2015 10:30:OOAM Aqueous Carbonyl Compounds by HPLC SW8315

Analytical Environmental Services, Inc
Client: Pace Analytical Services, Inc.
ANALYTICA
Project Name: 92277937
NVorkorder: 1512264
l
Sample ID: MB-216846
Client ID:
Units: ug/L
Prep Date:
SampleType: MBLK
TestCode:
Carbonyl Compounds by HPLC SW8315A
BatchID: 216846
Analysis Date
Analyte
Result
RPT Limit SPK value SPK Ref Val
%REC Low Limit
High Limit RPD R
Formaldehyde
BRL
50
Sample ID: LCS-216846
Client ID:
Units: ug/L
Prep Date:
SampleType: LCS
TestCode:
Carbonyl Compounds by HPLC SW8315A
BatchID: 216846
Analysis Date
Analyte
Result
RPT Limit SPK value SPK Ref Val
%REC Low Limit
High Limit RPD R
Formaldehyde
1154
50 1000
115 70
130
Sample ID: 1512687-002BMS
Client ID:
Units: ug/L
Prep Date:
SampleType: MS
TestCode:
Carbonyl Compounds by HPLC SW8315A
BatchID: 216846
Analysis Date
Analyte
Result
RPT Limit SPK value SPK Ref Val
%REC Low Limit
High Limit RPD R,
Formaldehyde
1299
50 1000 56.72
124 42.9
130
Sample ID: 1512687-002BMSD
Client ID:
Units: ug/L
Prep Date:
SampleType: MSD
TestCode:
Carbonyl Compounds by HPLC SW8315A
BatchID: 216846
Analysis Date:
Analyte
Result
RPT Limit SPK value SPK Ref Val
%REC Low Limit
High Limit RPD Rt
Formaldehyde
1151
50 1000 56.72
109 42.9
130 129'
QuaIiriers: > Greater than Result value < Less than Result value B Analyte detecedi
BRL Below reporting limit E Estimated (value above quantization range) H Holding times f
1 Estimated value detected below Reporting Limit N Analyte not NELAC certirred R RPD outside lit
Rpt Lim Reporting Limit S Spike Recovery outside limits due to matrix

aceAnalj4 cal
J
wvw.pacelebs.com
Pace Analytical Services, Inc.
6701 Conference Drive
Raleigh, NC 27607
[phone]
December 11, 2015
David Lorbacher
Arclin-Dynea/Moncure
790 Corinth Road
Chapel Hill, NC 27599
RE: Project: ARCLIN003
Pace Project No.: 92277933
Dear David Lorbacher:
Enclosed are the analytical results for sample(s) received by the laboratory on December 01, 2015.
The results relate only to the samples included in this report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
Some analyses have been subcontracted outside of the Pace Network. The subcontracted
laboratory report has been attached.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Liamm Harrison
[e-mail]
Project Manager
Enclosures
cc: Bowman Harvey, Acrlin-Dynea/Moncure
Chis Lamm, Arclin-Dynea/Moncure
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 1 of 26

aceAnalytical®
www.pacelab&ccm
CERTIFICATIONS
Project: ARCLIN003
Pace Project No.: 92277933
Pace Analytical ServiceS,Jnc.
6701 Conference Drive
Raleigh, NC 27607
(919)8344984
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Florida/NELAP Certification #: E87627
North Carolina Drinking Water Certification #: 37706
Kentucky UST Certification #: 84
North Carolina Field Services Certification #: 5342
West Virginia Certification #: 357
North Carolina Wastewater Certification #: 12
VirginiaNELAP Certification #: 460221
South Carolina Certification #: 99006001
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
North Carolina Wastewater Certification #: 40
Florida/NELAP Certification #: E87648
South Carolina Certification #: 99030001
Massachusetts Certification #: M-NC030
West Virginia Certification #: 356
North Carolina Drinking Water Certification #: 37712
VirginiaNELAP Certification #: 460222
Eden Certification IDs
205 East Meadow Road Suite A, Eden, NC 27288
North Carolina Wastewater Certification #: 633
North Carolina Drinking Water Certification #: 37738
VirginiaNELAP Certification #: 460025
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 2 of 26

aceAnalytical
www.pacelabs.com
om
Pace Analytical Services, Inc.
6701 Conference Drive
Raleigh, NC 27607
[phone]
SAMPLE ANALYTE COUNT
Project: ARCLIN003
Pace Project No.: 92277933
Analytes
Lab ID Sample ID Method
Analysts
Reported
Laboratory
92277933001 ARCLIN003 HACH 10206
DWJ
1
PASI-E
SM 2540D
CHM
1
PASI-E
SM 4500-NO2 B
DWJ
1
PASI-E
SM 5210B
DWJ
1
PASI-E
EPA 1664E
JMS
1
PASI-C
EPA 9040
MLS
1
PASI-A
EPA 350.1
WRC
1
PASI-A
EPA 351.2
SER
1
PASI-A
EPA 365.1
AES2
1
PASI-A
EPA 420.4
DMN
1
PASI A
SM 5220D
WRC
1
PASI-A
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 3 of 26

aceAnalytieal
wmvpacelabs.com
Pace Analytical Services, tnc.
6701 Conference Drive
Raleigh, NC 27607
(919)834A984
ANALYTICAL RESULTS
Project: ARCLIN003
Pace Project No.: 92277933
Sample: ARCLIN003
Parameters
Lab ID: 92277933001 Collected: 11/3011510:30
Results Units Report Limit DF
Received: 12/01/15 09:45 Matrix: Water
Prepared Analyzed CAS No. Qual
HACH 10206 Nitrogen, Nitrate
Analytical Method: HACH 10206
Nitrogen, Nitrate
9.1 mg/L
0.30
1
12/02/15 09:35
M1
2640D Total Suspended Solids
Analytical Method: SM 2540D
Total Suspended Solids
12.7 mg/L
2.5
1
12/02/1510:56
450ONO2B Nitrite, unpres
Analytical Method: SM 4500-NO2 B
Nitrogen, Nitrite
0.11 mg/L
0.010
1
12/02/1510:20
5210B BOD, 5 day EDN
Analytical Method: SM 5210B
BOD, 5 day
120 mg/L
2.0
1
12/02/1510:25 12/07/15 09:30
B2
HEM, Oil and Grease
Analytical Method: EPA 1664E
Oil and Grease
ND mg/L
5.0
1
12/03/15 05:27
9040 pH
Analytical Method: EPA 9040
pH
6.2 Std. Units
0.10
1
12103/1515:45
D6,H6
350.1 Ammonia, Low Level
Analytical Method: EPA 350.1
Nitrogen, Ammonia
0.72 mg/L
0.010
1
12/09/15 01:00
7664-41-7 M1
351.2 Total Kjeldahl Nitrogen
Analytical Method: EPA 351.2
Nitrogen, Kjeldahl, Total
13.7 mg/L
5.0
10
12/04/15 02:52
7727-37-9
365.1 Phosphorus, Total
Analytical Method: EPA 365.1
Phosphorus
0.082 mg/L
0.050
1
12/04/15 09:32
7723-14-0
420.4 Phenolics, Total
Analytical Method: EPA 420.4
Phenol
44.3 mg/L
5.0
500
12/03/1519:37
108-95-2
5220D COD
Analytical Method: SM 5220D
Chemical Oxygen Demand
1240 mg/L
25.0
1
12/08/1515:10
Date: 12/11/2015 08:00 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 4 of 26

aceArlalytical
www.pacelabscom
Pace Analytical Services, Inc.
6701 Conference Drive
Raleigh, NC 27607
(919)8344984
QUALITY CONTROL DATA
Project: ARCLIN003
Pace Project No.: 92277933
QC Batch: EDEN/20930
Analysis Method: HACH 10206
QC Batch Method: HACH 10206
Analysis Description: 10206 Nitrogen, Nitrate
Associated Lab Samples: 92277933001
METHOD BLANK: 1617791
Matrix: Water
Associated Lab Samples: 92277933001
Blank Reporting
Parameter Units
Result Limit Analyzed Qualifiers
Nitrogen, Nitrate mg/L
ND 0.30 12/02/15 09:35
LABORATORY CONTROL SAMPLE: 1617792
Spike LCS LCS % Rec
Parameter Units
Conc. Result % Rec Limits Qualifiers
Nitrogen, Nitrate mg/L
5 4.8 95 90.110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1617793 1617794
MS MSD
92277933001
Spike Spike MS MSD MS MSD % Rec
Parameter Units Result
Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Nitrate mg/L 9.1
5 5 14.8 14.8 114 114 90-110 0 MI
Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full.
Date: 12/11/2015 08:00 AM without the written consent of Pace Analytical Services, Inc..
Page 5 of 26

aceArralylcal
www.pacelabscom
Pace Analytical Services, Inc.
6701 Conference Drive
Raleigh, NC 27607
[phone]
QUALITY CONTROL DATA
Project: ARCLIN003
Pace Project No.: 92277933
QC Batch: EDEN/20933
Analysis Method:
SM 2540D
QC Batch Method: SM 2540D
Analysis Description:
2540D Total Suspended Solids
Associated Lab Samples: 92277933001
METHOD BLANK: 1617895
Matrix: Water
Associated Lab Samples: 92277933001
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Total Suspended Solids
mg/L
ND
2.5 12/0211510:49
LABORATORY CONTROL SAMPLE: 1617896
Spike LCS
LCS % Rec
Parameter
Units
Conc. Result
% Rec Limits Qualifiers
Total Suspended Solids
mg/L
250 270
108 90-110
SAMPLE DUPLICATE: 1617897
92277785002 Dup
Parameter
Units
Result Result
RPD Qualifiers
Total Suspended Solids
mg/L
ND
3.7
SAMPLE DUPLICATE: 1617898
92277937001 Dup
Parameter
Units
Result Result
RPD Qualifiers
Total Suspended Solids
mg/L
93.0
115 21 D6
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/11/2015 08:00 AM without the written consent of Pace Analytical Services, Inc..
Page 6 of 26

W /
�acieMalxicale
www.pacelabs.cam
Pace Analytical Services, Inc.
6701 Conference Drive
Raleigh, NC 27607
(919)8344984
QUALITY CONTROL DATA
Project: ARCLIN003
Pace Project No.: 92277933
QC Batch: EDEN/20932
Analysis Method: SM 4500-NO2 B
QC Batch Method: SM 4500-NO2 B
Analysis Description: 4500NO2B, Nitrite, unpres
Associated Lab Samples: 92277933001
METHOD BLANK: 1617812
Matrix: Water
Associated Lab Samples: 92277933001
Blank Reporting
Parameter Units
Result Limit Analyzed Qualifiers
Nitrogen, Nitrite mg/L
ND 0.010 12/02/1510:20
LABORATORY CONTROL SAMPLE: 1617813
Spike LCS LCS % Rec
Parameter Units
Conc. Result % Rec Limits Qualifiers
Nitrogen, Nitrite mg/L
.1 0.11 108 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1617814 1617815
MS MSD
92277851001
Spike Spike MS MSD MS MSD % Rec
Parameter Units Result
Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Nitrite mg/L ND
.1 .1 0.10 0.10 104 104 90-110 0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full.
Date: 12/11/2015 08:00 AM without the written consent of Pace Analytical Services, Inc..
Page 7 of 26

aceAnalytical'
wmpaceleWom
Pace Analytical Services, Inc.
6701 Conference Drive
Raleigh, NC 27607
[phone]
QUALITY CONTROL DATA
Project: ARCLIN003
Pace Project No.: 92277933
QC Batch: EDEN/20928
Analysis Method:
SM 5210B
QC Batch Method: SM 5210B
Analysis Description:
5210E BOD, 5 day EDN
Associated Lab Samples: 92277933001
METHOD BLANK: 1617770
Matrix: Water
Associated Lab Samples: 92277933001
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
BOD, 5 day
mg/L
ND
2.0 12/07/15 09:30
LABORATORY CONTROL SAMPLE: 1617771
Spike LCS
LCS % Rec
Parameter
Units
Conc. Result
% Rec Limits Qualifiers
BOD, 5 day
mg/L
198 172
87 84.6-115.4
SAMPLE DUPLICATE: 1617772
92277933001 Dup
Parameter
Units
Result Result
RPD Qualifiers
BOD, 5 day
mg/L
120
120 0 B2
Results presented on this page are In the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/11/2015 08:00 AM without the written consent of Pace Analytical Services, Inc..
Page 8 of 26

aceAnalX cal Is
www.pacelabs.com
Pace Analytical Services, Inc.
6701 Conference Drive
Raleigh, NC 27607
[phone]
QUALITY CONTROL DATA
Project: ARCLIN003
Pace Project No.: 92277933
QC Batch: GCSW23413
Analysis Method:
EPA 1664B
QC Batch Method: EPA 1664B
Analysis Description:
1664 HEM, Oil and Grease
Associated Lab Samples: 92277933001
METHOD BLANK: 1618755
Matrix: Water
Associated Lab Samples: 92277933001
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Oil and Grease
mg/L
ND 5.0 12/03/15 05:22
LABORATORY CONTROL SAMPLE:
1618756
Spike LCS
LCS % Rec
Parameter
Units
Conc. Result
% Rec Limits Qualifiers
Oil and Grease
mg/L
40 34.5
86 78-114
MATRIX SPIKE SAMPLE:
1618757
92277182001 Spike
MS MS % Rec
Parameter
Units
Result Conc.
Result % Rec Limits Qualifiers
Oil and Grease
mg/L
ND 40
37.1 93 78-114
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/11/2015 08:00 AM without the written consent of Pace Analytical Services, Inc..
Page 9 of 26

aceAnalytical
www.pacelabs.com
Pace Analytical Services, Inc.
6701 Conference Drive
Raleigh, NC 27607
[phone]
QUALITY CONTROL DATA
Project: ARCLIN003
Pace Project No.: 92277933
QC Batch: WET/41714 Analysis Method: EPA 9040
QC Batch Method: EPA 9040 Analysis Description: 9040 pH
Associated Lab Samples: 92277933001
SAMPLE DUPLICATE: 1618792
Parameter
pH
92277933001
Units Result
Std. Units 6.2
Dup
Result RPD Qualifiers
6.3 1 D6,H6
Results presented an this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/11/2015 08:00 AM without the written consent of Pace Analytical Services, Inc..
Page 10 of 26

aceAnalylcal
www.pacefabs.com
Pace Analytical Services, Inc.
6701 Conference Drive
Raleigh, NC 27607
[phone]
Project: ARCLIN003
Pace Project No.: 92277933
QC Batch: WETA/25661
QC Batch Method: EPA 350.1
Associated Lab Samples: 92277933001
METHOD BLANK: 1621670
Associated Lab Samples: 92277933001
QUALITY CONTROL DATA
Analysis Method: EPA 350.1
Analysis Description: 350.1 Ammonia, Low Level
Matrix: Water
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen, Ammonia mg/L ND 0.010 12/09/15 01:00
LABORATORY CONTROL SAMPLE: 1621671
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Nitrogen, Ammonia mg/L 1 0.92 92 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1621672 1621673
MS MSD
92277933001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Ammonia mg/L 0.72 1 1 1.1 1.1 36 36 90-110 0 M1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1621674 1621675
MS MSD
92278045012 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Ammonia mg/L 0.050 1 1 0.71 0.71 66 66 90-110 1 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/11/2015 08:00 AM without the written consent of Pace Analytical Services, Inc.. Page 11 of 26

aceAnalytical
www.pacelab&cam
Pace Analytical Services, Inc.
6701 Conference Drive
Raleigh, NC 27607
[phone]
QUALITY CONTROL DATA
Project: ARCLIN003
Pace Project No.: 92277933
QC Batch: WETA/25619
Analysis Method: EPA 351.2
QC Batch Method: EPA 351.2
Analysis Description: 351.2 TKN
Associated Lab Samples: 92277933001
METHOD BLANK: 1619040
Matrix: Water
Associated Lab Samples: 92277933001
Blank Reporting
Parameter Units
Result Limit
Analyzed
Qualifiers
Nitrogen, Kjeldahl, Total mg/L
ND 0.50
12/04/15 02:41
LABORATORY CONTROL SAMPLE: 1619041
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits
Qualifiers
Nitrogen, Kjeldahl, Total mg/L
10 10.4
104 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1619042 1619043
MS MSD
92276933001
Spike Spike MS
MSD MS
MSD
% Rec
Parameter Units Result
Conc. Conc. Result
Result % Rec
% Rec
Limits
RPD Qual
Nitrogen, Kjeldahl, Total mg/L 3.9
10 10 16.0
14.7 121
107
90-110
9 M1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1619044 1619045
MS MSD
92278126001
Spike Spike MS
MSD MS
MSD
% Rec
Parameter Units Result
Conc. Conc. Result
Result % Rec
% Rec
Limits
RPD Qual
Nitrogen, Kjeldahl, Total mg/L 1.7
10 10 13.2
11.9 115
103
90-110
10 M1
Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/11/2015 08:00 AM without the written consent of Pace Analytical Services, Inc..
Page 12 of 26

aceAnalytical
wwwpacelabs.com
Pace Analytical Services, Inc.
6701 Conference Drive
Raleigh, NC 27607
(919)8344984
QUALITY CONTROL DATA
Project: ARCLIN003
Pace Project No.: 92277933
QC Batch: WETA/25621
Analysis Method: EPA 365.1
QC Batch Method: EPA 365.1
Analysis Description: 365.1 Phosphorus, Total
Associated Lab Samples: 92277933001
METHOD BLANK: 1619062
Matrix: Water
Associated Lab Samples: 92277933001
Blank
Reporting
Parameter Units
Result
Limit
Analyzed Qualifiers
Phosphorus mg/L
ND 0.050
12/04/15 09:18
LABORATORY CONTROL SAMPLE: 1619063
Spike
LCS
LCS % Rec
Parameter Units
Conc.
Result
% Rec Limits
Qualifiers
Phosphorus mg/L
2.5
2.7
109 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1619064
1619065
MS
MSD
92277491003
Spike
Spike MS
MSD MS
MSD
% Rec
Parameter Units Result
Conc.
Conc. Result
Result % Rec
% Rec
Limits
RPD Qual
Phosphorus mg/L 139
125
125 269
266 104
102
90-110
1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1619066
1619067
MS
MSD
92277927004
Spike
Spike MS
MSD MS
MSD
% Rec
Parameter Units Result
Conc.
Conc. Result
Result % Rec
% Rec
Limits
RPD Qual
Phosphorus mg/L 124
125
125 252
252 103
103
90-110
0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/11/2015 08:00 AM without the written consent of Pace Analytical Services, Inc..
Page 13 of 26

aceAnalytica!
wmpacefabs.com
Pace Analytical Services, Inc.
6701 Conference Drive
Raleigh, NC 27607
[phone]
QUALITY CONTROL DATA
Project: ARCLIN003
Pace Project No.: 92277933
QC Batch: WETA/25614
Analysis Method: EPA 420.4
QC Batch Method: EPA 420.4
Analysis Description: 420.4 Phenolics
Associated Lab Samples: 92277933001
METHOD BLANK: 1618673
Matrix: Water
Associated Lab Samples: 92277933001
Blank Reporting
Parameter Units
Result Limit
Analyzed
Qualifiers
Phenol mg/L
ND 0.010
12/03/1518:30
LABORATORY CONTROL SAMPLE: 1618674
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits
Qualifiers
Phenol mg/L
.05 0.049
99 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1618675 1618676
MS MSD
92277023003
Spike Spike MS
MSD MS
MSD
% Rec
Parameter Units Result
Conc. Conc. Result
Result % Rec
% Rec
Limits
RPD Qual
Phenol mg/L ND
.05 .05 0.055
0.055 91
91
90-110
1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1618677 1618678
MS MSD
92277023004
Spike Spike MS
MSD MS
MSD
% Rec
Parameter Units Result
Conc. Conc. Result
Result % Rec
% Rec
Limits
RPD Qual
Phenol mg/L ND
.05 .05 0.055
0.055 94
93
90-110
1
Results presented on this page are In the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/11/2015 08:00 AM without the written consent of Pace Analytical Services, Inc..
Page 14 of 26

'9
aceAnalytical
www.pacelabs.com
Pace Analytical Services, Inc.
6701 Conference Drive
Raleigh, NC 27607
(919)8344984
QUALITY CONTROL DATA
Project: ARCLIN003
Pace Project No.: 92277933
QC Batch: WETA/25660
Analysis Method: SM 5220D
QC Batch Method: SM 5220D
Analysis Description: 5220D COD
Associated Lab Samples: 92277933001
METHOD BLANK: 1621659
Matrix: Water
Associated Lab Samples: 92277933001
Blank
Reporting
Parameter Units
Result
Limit
Analyzed Qualifiers
Chemical Oxygen Demand mg/L
ND 25.0
12/08/1515:10
LABORATORY CONTROL SAMPLE: 1621660
Spike
LCS
LCS
% Rec
Parameter Units
Cone.
Result
% Rec
Limits Qualifiers
Chemical Oxygen Demand mg/L
750
740
99
90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1621661
1621662
MS
MSD
92277826001
Spike
Spike MS
MSD
MS MSD
% Rec
Parameter Units Result
Cone.
Cone. Result
Result
% Rec % Rec
Limits
RPD Qual
Chemical Oxygen Demand mg/L 53.0
750
750 762
762
95 95
90-110
0
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1621663
1621664
MS
MSD
92277927004
Spike
Spike MS
MSD
MS MSD
% Rec
Parameter Units Result
Cone.
Cone. Result
Result
% Rec % Rec
Limits
RPD Qual
Chemical Oxygen Demand mg/L 272
3000
3000 3000
3000
91 91
90-110
0
Results presented on this page are In the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in Rill,
Date: 12/11 /2015 08:00 AM without the written consent of Pace Analytical Services, Inc..
Page 15 of 26

aceAnaljftal
www.pacelabscom
Pace Analytical Services, Inc.
6701 Conference Drive
Raleigh, NC 27607
[phone]
QUALIFIERS
Project: ARCLIN003
Pace Project No.: 92277933
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
LABORATORIES
PASI-A Pace Analytical Services - Asheville
PASI-C Pace Analytical Services - Charlotte
PASI-E Pace Analytical Services - Eden
ANALYTE QUALIFIERS
B2 Oxygen usage is less than 2.0 for all dilutions set. The reported value is an estimated less than value and is calculated
for the dilution using the most amount of sample.
D6 The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits.
H6 Analysis initiated outside of the 15 minute EPA recommended holding time.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/11/2015 08:00 AM without the written consent of Pace Analytical Services, Inc.. Page 16 of 26

aceArtalytical
www.pacelabs.com
Pace Analytical Services, Inc.
6701 Conference Drive
Raleigh, NC 27607
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: ARCLIN003
Pace Project No.: 92277933
Analytical
Lab 1D
Sample ID
QC Batch Method
QC Batch Analytical Method Batch
92277933001
ARCLIN003
HACH 10206
EDEN/20930
92277933001
ARCLIN003
SM 2540D
EDEN/20933
92277933001
ARCLIN003
SM 4500-NO2 B
EDEN/20932
92277933001
ARCLIN003
SM 5210B
EDEN/20928 SM 5210B EDEN/20935
92277933001
ARCLIN003
EPA 1664B
GCSV/23413
92277933001
ARCLIN003
EPA 9040
WET/41714
92277933001
ARCLIN003
EPA 350.1
WETA/25661
92277933001
ARCLIND03
EPA 351.2
WETA/25619
92277933001
ARCLIN003
EPA 365.1
WETA/25621
92277933001
ARCLIN003
EPA 420.4
WETA/25614
92277933001
ARCLIN003
SM 5220D
WETA/25660
Date: 12/11 /2015 08:00 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 17 of 26

1..AceLapical6
wwwp1
Document Kevlseb: May it), zu 10
-Page-1 of 2*
Issuing Authodtles:
Pace Relel h Quality Office
*Page 2 of 2 is for Internal USe Only
Client Name:\�V _61" U&\A
uocument Hume: sample Condition Upon
Document No.:
F-RAL-CS-001-rev.03
Courier (Circle): Fed Ex UPS USPS Client Commercial Pace Other_!__,__
Custody Seal on Cooler/Box Present: yes J� no Seals intact: ,n yes o no
Packing Material: 1:1 Bubble Wrap Bubble Bags None rj Other
Circle Thermometer Used: IR Gun 206538 a of Ice: Wet Blue None Q Samples on ice, cooling process has began
IS /�..� lf..�L 1 llAtZa9•s/
Temp Correction Factor: Add ! btract
C
Date and Initials of person examining
Corrected Cooler Temp.: *0 C
Biological Tissue Is Frozen: Yes No NIA
chf Prey t t
eck
Temp should be above freezing to 68C
Comments:
Chain of Custody Present:
14w ONO
ONIA
1.
2.
Chain of Custody Filled Out' es ONo
❑N!A
Chain of Custody Relinquished:
4e. ❑NO
OWA
3.
Sampler Home & Si nature on COC:
Yas ONo
CIwA
4.
Samples Arrived within Hold Time:
Yes ONo
OwA
5.
Short Hold Time Anal is <72hr :
AYes ONO
❑NIA
6. s
Rush Turn Around Time Requested:
OYes Q4w
OWA
7.
Sufficient Volume:
VfYes ONo
DIVA
8.
Correct Containers Used:
Yes ONo
i7WA
9.
-Pace Containers Used:
.
Yea ONo
ONrA
Containers Intact:
es ONo
ONIA
10..
Filtered volume received for Dissolved tests
OYes ONo
IA
i i .
Sample Labels match COC:
Ye ONo
(3wA
12.
-includes datePomeAD/Anal sis Matrix:
All containers needing preservation have been checked.
es ONo
?�
❑WA
13. .
All containers needing preservation are found to be In
ONo
OWA
compliance with EPA recommendatlon.
exceens: VOA. colfform. TOC, 090. WWRO (water)
/yes ONO
Samples checked for dechlodnation:
Yes CINo
❑N!A
14.
Headspace In VOA Vials >6mm :
Oyes DNo
YiWA
15.
Trip Blank Present:
Oyes 17No
WA
16.
Trip Blank Custody Seals Present
Oyes ONo
JWA
Pace Trip Blank Lot # if purchased
Client NotHicationt Resolution:
Person Contacted:
Comments/ Resolution:
DateTme:
SCURF ISRF ' `"
Date:
Review:: (� l LO •Z1�
Note: Whenever there is a dlscrepaney affecting North Carolina compliance
samples, a oopy of this farm will be sent to the North Carolina DEHNR
Certification Oglee ( I.e out of hold, Incorrect preservative, out of temp.
Incorrect containers)
Field Date Required? Y 1 N
WO#:92277933
1111111111111111111111I
„ azz
Page 18 of 26

to
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ADDITIONAL COMMENTS
REUNCIIISHED BY f AFFIUATION
DATE
TWE
A*C PFEDftY rAFFIL T N
DATE
TIME
SAMPLE CONDITIONS
SAMPLER NAME AND SIGNATURE
P'�INT Nx?w trt SAMPLF=a
V i�.i _ �..t �t _
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ANALYTICAL ENVIRONMENTAL SERVICES, INC.
ABS
December 10, 2015
Taylor Ezell
Pace Analytical Services, Inc.
9800 Kincev Avenue. Suite 100
Huntersville NC 28078
TEL: [phone]
FAX: [phone]
RE: 92277933
Dear Taylor Ezell: Order No: 1512265
Analytical Environmental Services, Inc. received 1 samples on 12/3/2015 10:40:00 AM
for the analyses presented in following report.
No problems were encountered during the analyses. Additionally, all results for the associated
Quality Control samples were within EPA and/or AES established limits. Any discrepancies
associated with the analyses contained herein will be noted and submitted in the form of a
project Case Narrative.
AES' certifications are as follows:
-NELAC/Florida Certification number E87582 for analysis of Environmental Water,
soil/hazardous waste, and Drinking Water Microbiology, effective 07/01/15-06/30/16.
-AIHA-LAP, LLC Laboratory ID: 100671 for Industrial Hygiene samples (Organics,
Inorganics), Environmental Lead (Paint, Soil, Dust Wipes, Air), and Environmental
Microbiology (Fungal) Direct Examination, effective until 09/01/17.
These results relate only to the items tested. This report may only be reproduced in full.
If you have any questions regarding these test results, please feel free to call.
Dorothy deBruvn
Project Manager
a080 Presidential Drive - Atlanta, Georgia 30340 - Tel: [phone] - Fax: 770.457.818S - Toll Free: 800.972.4889
www.aesatlanta.com Page 1 of 7
Page 20 of 26

Workorder: 92277933 Workorder Name: ARCLIN003 Results Requested 12/15/2015
iRepon1-,Invcice •io . • ' . s Tn .. - _ • • • • _ ...t • t`e.r,.sc�e.t A fthjela .
f_iamm Ha�son
Pace Anat cal Charlotte
- -
P.O.
9800 tGncey Ave. Suite 100
Huntersville. hC 28078
Phone [phone]
A6
Email: [e-mail]
: •.Fresenred.Coritainersr:;
W.
r. •
'Collect
u
ttecn
Sample ia;; ,•;
..
-Di te/Trnie , -• _ '�
i. li l ' ' _'
i�►atrut
t
1
ARCLIN003
111301201510:30
192277933001
Water
l
X
2
3
d
t
t
5
;
Transfers Released By Date/Time Received By Datelrme
s
2 l
3
Cooler Temperature on Receipt - -C Custodv Seal Y or N Received on fee Y or N Same
'**In order to maintain client confidenfiality, location/name of the sampling site, sampler's name and signature may not be provided on this COC
This chain of custody is considered complete as is since this information is available in the ownerlaboratory.
Tuesday, December 01.015:09:40 Piq
FMT-,ALL-C-002rev.00 NMarW
t

Analytical Environmental Services, Inc
Date: 10-Dec-15
Client: Pace Analytical Services, Inc.
Project: 92277933 Case Narrative
Lab ID: 1512265
Samples arrived after hold time expired. Proceed with analysis per Liamm Harrison via email on 12/3/15.
Formaldehyde Analysis by Method 8315:
Sample 1512265-001 A was received and extracted and/or analyzed outside holding time of 72 hours.
Page 3 of 7
Page 22 of 26

Analytical Environmental Services, Inc Date: l0-Dec-15
Client:
Pace Analytical Services, Inc.
Client Sample ID:
ARCLIN003
Project Name:
92277933
Collection Date:
11/30/2015 10:30:00 AM
Lab ID:
1512265-001
Matrix:
Aqueous
Reporting Dilution
Analyses Result Qual Units BatchID Date Analyzed Analyst
Limit Factor
Carbonyl Compounds by HPLC SW8315A
Formaldehyde
Qualifiers: • Value exceeds maximum contaminant level
BRL Below reporting limit
H Holding times for preparation or analysis exceeded
N Analyte not NELAC certified
B Analytc detected in the associated method blank
> Greater than Result value
58000 5000 H ug/L 216703 10 12/042015 23:21 RF
E
Estimated (value above quantitation range)
S
Spike Recovery outside limits due to matrix
Han
See cast narrative
NC
Nat confirmed
<
Less than Result value
J
Estimated value detected below Reporting Limit
Page 4 of 7
Page 23 of 26

Analytical Environmental Services, Inc.
Sample/Cooler Receipt Checklist
Client 0a, � t
Work Order Number a
Checklist completed by
Sign re
Date
Carrier PedEx '�! UPS
name: _ Courier _ Client—
I
US Mail — Other
E Shipping container/cooler in good condition?
Yes
No
Not Present
Custody seals intact on shipping container/cooler?
Yes —
No _.
Not Present —
Custody seals intact on sample bottles?
Yes _
No —
Not Present
Container/Temp Blank temperature in compliance? (0°_<6°C)* Yes ✓
No
Cooler
#1 Cooler #2 Cooler #3
Cooler #4
•Cooler#5 Cooler #6
Chain of custody present?
Yes ✓
No —
Chain of custody signed when relinquished and received?
Yes
No —
Chain of custody agrees with sample labels?
Yes '�
No._
Samples in proper container/bottle?
Yes ✓
No —
Sample containers intact?
Yes
No
—
Sufficient sample volume for indicated test?
Yes
No
A11 samples received within holding time?
Yes _
No
Was TAT marked on the-COC?
Yes
No
Proceed with Standard TAT as per project history?
Yes _
No
Not Applicable
Water - VOA vials have zero headspace? No VOA vials submitted f
Yes
No „w
Water - pH acceptable upon receipt?
Yes
No —
Not Applicable _
Adjusted?
Checked by
Sample Condition: Good ✓ Other(Explain)
(For diffusive -samples or AIHA lead) Is a known blank included? Yes
No V"
See Case Narraf-;ve for resolution of the Non -Conformance.
9
r
Samples do not; a:A*. to c reply with the given range for certain parameters.
11Aes serverll\Sample ReceiptlMy Document
slCOCs and pH Adjustment Sheet\Sampli; Cooler Recipt Checklist Revl.rtf
Page 5 of 7
Page 24 of 26

Analytical Environmental Services, Inc
Client: Pace Analytical Services, Inc.
Project Name: 92277933
Lab Order: 1512265
Da
Lab Sample ID Client Sample ID Collection Date Matrix Test Name TCLP Date
1512265-001A ARCLIN003 11/30/2015 10:30:00AM Aqueous Carbonyl Compounds by HPLC SW8315

Analytical Environmental Services, Inc
Client: Pace Analytical Services, Inc.
ANALYTICA
Project Name: 92277933
Workorder: 1512265
l
Sample ID: MB-216703
Client ID:
Units: ug/L
Prep Date:
SampleType: MBLK
TestCode:
Carbonyl Compounds by HPLC SW8315A
BatchID: 216703
Analysis Date
Analyte
Result
RPT Limit SPK value SPK Ref Val
%REC Low Limit
High Limit RPD R
Formaldehyde
BRL
50
Sample ID: LCS-216703
Client ID:
Units: ug/L
Prep Date:
SampleType: LCS
TestCode:
Carbonyl Compounds by HPLC SW8315A
BatchID: 216703
Analysis Date
Analyte
Result
RPT Limit SPK value SPK Ref Val
%REC Low Limit
High Limit RPD R
Formaldehyde
1186
50 1000
119 70
130
Sample ID: 1512263-OOIAMS
Client ID:
Units: ug/L
Prep Date:
SampleType: MS
TestCode:
Carbonyl Compounds by HPLC SW8315A
BatchID: 216703
Analysis Date
Analyte
Result
RPT Limit SPK value SPK Ref Val
%REC Low Limit
High Limit RPD R,
Formaldehyde
1281
50 1000 138.9
114 42.9
130
Sample ID: 1512263-001AMSD
Client ID:
Units: ug/L
Prep Date:
SampleType: MSD
TestCode:
Carbonyl Compounds by HPLC SW8315A
BatchID: 216703
Analysis Date
Analyte
Result
RPT Limit SPK value SPK Ref Val
%REC Low Limit
High Limit RPD Ri
Formaldehyde
1279
50 1000 138.9
114 42.9
130 128
Qualifiers: > Greater than Result value < Less than Result value B Analyte detecte
• BRL Below reporting limit E Estimated (value above quantization range) H Holding times f
J Estimated value detected below Reporting Limit N Analyte not NELAC certified R RPD outside lii
Rpt Lim Reporting Limit S Spike Recovery outside limits due to matrix

aceAnaljica!
www.pacelabscom
Pace Analytical Services, Inc.
6701 Conference Drive
Raleigh, NC 27607
(919)8344984
December 11, 2015
David Lorbacher
Arclin-Dynea/Moncure
790 Corinth Road
Chapel Hill, NC 27599
RE: Project: ARCLIN004
Pace Project No.: 92277936
Dear David Lorbacher:
Enclosed are the analytical results for sample(s) received by the laboratory on December 01, 2015.
The results relate only to the samples included in this report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
Some analyses have been subcontracted outside of the Pace Network. The subcontracted
laboratory report has been attached.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
\,�% cz.� C-P"f
Liamm Harrison
[e-mail]
Project Manager
Enclosures
cc: Bowman Harvey, Acrlin-Dynea/Moncure
Chis Lamm, Arclin-Dynea/Moncure
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 1 of 26

aceAnalyical
www.pacelsftcom
Pace Analytical Services, ;pc.
6701 Conference D*e
Raleigh, NC 27607 t
[phone]
CERTIFICATIONS
Project: ARCLIN004
Pace Project No.: 92277936
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Flodda/NELAP Certification #: E87627
North Carolina Drinking Water Certification #: 37706
Kentucky UST Certification #: 84
North Carolina Field Services Certification #: 5342
West Virginia Certification #: 357
North Carolina Wastewater Certification #: 12
VirginiaNELAP Certification #: 460221
South Carolina Certification #: 99006001
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
North Carolina Wastewater Certification #: 40
Flonda/NELAP Certification #: E87648
South Carolina Certification #: 99030001
Massachusetts Certification #: M-NC030
West Virginia Certification #: 356
North Carolina Drinking Water Certification #: 37712
VirginiaNELAP Certification #: 460222
Eden Certification IDs
205 East Meadow Road Suite A, Eden, NC 27288
North Carolina Wastewater Certification #: 633
North Carolina Drinking Water Certification #: 37738
VirginiaNELAP Certification #: 460025
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 2 of 26

aceAnalj cal
WWW-pacelab&com
Pace Analytical Services, Inc.
6701 Conference Drive
Raleigh, NC 27607
(919)8344984
SAMPLE ANALYTE COUNT
Project: ARCLIN004
Pace Project No.: 92277936
Analytes
Lab 1D Sample ID Method
Analysts
Reported
Laboratory
92277936001 ARCLIN004 HACH 10206
DWJ
1
PASI-E
SM 2540D
CHM
1
PASI-E
SM 4500-NO2 B
DWJ
1
PASI-E
SM 5210B
DWJ
1
PASI-E
EPA 1664E
JMS
1
PASI-C
EPA 9040
MLS
1
PASI-A
EPA 350.1
WRC
1
PASI-A
EPA 351.2
SER
1
PASI-A
EPA 365.1
AES2
1
PASI A
EPA 420.4
DMN
1
PASI-A
SM 5220D
WRC
1
PASI-A
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 3 of 26

aceAnalytical
www.pacelabs.com
Pace Analytical Services, Inc.
6701 Conference Drive
Raleigh, NC 27607
[phone]
ANALYTICAL RESULTS
Project: ARCLIN004
Pace Project No.: 92277936
Sample: ARCLIN004
Lab ID: 92277936001 Collected:
11/30/15 10:30
Received: 12/01/15 09:43 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
HACH 10206 Nitrogen, Nitrate
Analytical Method: HACH 10206
Nitrogen, Nitrate
17.6 mg/L
0.60
2
12/02/15 09:35
2540D Total Suspended Solids
Analytical Method: SM 2540D
Total Suspended Solids
4.0 mg/L
2.5
1
12/02/15 10:58
4500NO2B Nitrite, unpres
Analytical Method: SM 4500-NO2 B
Nitrogen, Nitrite
0.086 mg/L
0.010
1
12/02/15 10:20
6210B BOD, 5 day EDN
Analytical Method: SM 5210B
BOD, 5 day
. 2.5 mg/L
2.0
1
12/0211510:25 12/07/15 09:30
HEM, Oil and Grease
Analytical Method: EPA 1664E
Oil and Grease
ND mg/L
5.0
1
12/03/15 05:28
9040 pH
Analytical Method: EPA 9040
pH
6.4 Std. Units
0.10
1
12/03/15 15:45
H6
350.1 Ammonia, Low Level
Analytical Method: EPA 350.1
Nitrogen, Ammonia
0.37 mg/L
0.010
1
12/09/15 01:00
7664-41-7
351.2 Total Kjeldahl Nitrogen
Analytical Method: EPA 351.2
Nitrogen, Kjeldahl, Total
5.6 mg/L
0.50
1
12/04/15 02:53
7727-37-9
365.1 Phosphorus, Total
Analytical Method: EPA 365.1
Phosphorus
0.074 mg/L
0.050
1
12/04/15 09:33
7723-14-0
420.4 Phenolics, Total
Analytical Method: EPA 420.4
Phenol
ND mg/L
0.010
1
12/03/1519:11
108-95-2
5220D COD
Analytical Method: SM 5220D
Chemical Oxygen Demand
61.0 mg/L
25.0
1
12/08/1515:10
Date: 12/11/2015 08:22 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 4 of 26

acaftiX cal
wmpacelabs.com
Pace Analytical Services, Inc.
6701 Conference Drive
Raleigh, NC 27607
[phone]
QUALITY CONTROL DATA
Project: ARCLIN004
Pace Project No.: 92277936
QC Batch: EDEN/20930 Analysis Method: HACH 10206
QC Batch Method: HACH 10206 Analysis Description: 10206 Nitrogen, Nitrate
Associated Lab Samples: 92277936001
METHOD BLANK: 1617791 Matrix: Water
Associated Lab Samples: 92277936001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen, Nitrate mg/L ND 0.30 12/02/15 09:35
LABORATORY CONTROL SAMPLE: 1617792
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Nitrogen, Nitrate mg/L 5 4.8 95 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1617793 1617794
MS MSD
92277933001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Nitrate mg/L 9.1 5 5 14.8 14.8 114 114 90-110 0 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except In full,
Date: 12/11 /2015 08:22 AM without the written consent of Pace Analytical Services, Inc..
Page 5 of 26

aceAna1j ca!®
wmpacelaftcom
Pace Analytical Services, Inc.
6701 Conference Drive
Raleigh, NC 27607
[phone]
QUALITY CONTROL DATA
Project: ARCLIN004
Pace Project No.: 92277936
QC Batch: EDEN/20933
Analysis Method:
SM 2540D
QC Batch Method: SM 2540D
Analysis Description:
2540D Total Suspended Solids
Associated Lab Samples: 92277936001
METHOD BLANK: 1617895
Matrix: Water
Associated Lab Samples: 92277936001
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Total Suspended Solids
mg/L
ND
2.5 12/02/1510:49
LABORATORY CONTROL SAMPLE: 1617896
Spike LCS
LCS % Rec
Parameter
Units
Conc. Result
% Rec Limits Qualifiers
Total Suspended Solids
mg/L
250 270
108 90-110
SAMPLE DUPLICATE: 1617897
92277785002 Dup
Parameter
Units
Result Result
RPD Qualifiers
Total Suspended Solids
mg/L
ND
3.7
SAMPLE DUPLICATE: 1617898
92277937001 Dup
Parameter
Units
Result Result
RPD Qualifiers
Total Suspended Solids
mg/L
93.0
115 21 D6
Results presented on this page are In the units indicated by the "Units" column except where an alternate unit is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/11 /2015 08:22 AM without the written consent of Pace Analytical Services, Inc..
Page 6 of 26

ace ArraIj 6ca ®
www.pacelabs.com
Pace Analytical Services, Inc.
6701 Conference Drive
Raleigh, NC 27607
(919)8344984
QUALITY CONTROL DATA
Project: ARCLIN004
Pace Project No.: 92277936
QC Batch: EDEN/20932 Analysis Method: SM 4500-NO2 B
QC Batch Method: SM 4500-NO2 B Analysis Description: 4500NO213, Nitrite, unpres
Associated Lab Samples: 92277936001
METHOD BLANK: 1617812 Matrix: Water
Associated Lab Samples: 92277936001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen, Nitrite mg/L ND 0.010 12/02/15 10:20
LABORATORY CONTROL SAMPLE: 1617813
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Nitrogen, Nitrite mg/L .1 0.11 108 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1617814 1617815
MS MSD
92277851001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Nitrite mg/L ND .1 .1 0.10 0.10 104 104 90-110 0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/11 /2015 08:22 AM without the written consent of Pace Analytical Services, Inc..
Page 7 of 26

aceAnalylcal
wmpecelabs.com
Pace Analytical Services, Inc.
6701 Conference Drive
Raleigh, NC 27607
[phone]
QUALITY CONTROL DATA
Project: ARCLIN004
Pace Project No.: 92277936
QC Batch: EDEN/20928
Analysis Method:
SM 5210B
QC Batch Method: SM 5210B
Analysis Description:
5210E BOD, 5 day EDN
Associated Lab Samples: 92277936001
METHOD BLANK: 1617770
Matrix: Water
Associated Lab Samples: 92277936001
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
BOD, 5 day
mg/L
ND
2.0 12/07/15 09:30
LABORATORY CONTROL SAMPLE: 1617771
Spike LCS
LCS % Rec
Parameter
Units
Conc. Result
% Rec Limits Qualifiers
BOD, 5 day
mg/L
198 172
87 84.6-115.4
SAMPLE DUPLICATE: 1617772
92277933001 Dup
Parameter
Units
Result Result
RPD Qualifiers
BOD, 5 day
mg/L
120
120 0 B2
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/11/2015 08:22 AM without the written consent of Pace Analytical Services, Inc..
Page 8 of 26

aceAnalgical
www.pacelabscom
Pace Analytical Services, Inc.
6701 Conference Drive
Raleigh, NC 27607
(919)8344984
QUALITY CONTROL DATA
Project: ARCLIN004
Pace Project No.: 92277936
QC Batch: GCSV/23413
Analysis Method:
EPA 1664E
QC Batch Method: EPA 1664E
Analysis Description:
1664 HEM, Oil and Grease
Associated Lab Samples: 92277936001
METHOD BLANK: 1618755
Matrix: Water
Associated Lab Samples: 92277936001
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Oil and Grease
mg/L
ND 5.0 12/03/15 05:22
LABORATORY CONTROL SAMPLE: 1618756
Spike LCS
LCS % Rec
Parameter
Units
Conc. Result
% Rec Limits Qualifiers
Oil and Grease
mg/L
40 34.5
86 78-114
MATRIX SPIKE SAMPLE: 1618757
92277182001 Spike
MS MS % Rec
Parameter
Units
Result Conc.
Result % Rec Limits Qualifiers
Oil and Grease
mg/L
ND 40
37.1 93 78-114
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/11/2015 08:22 AM without the written consent of Pace Analytical Services, Inc..
Page 9 of 26

aceAnalytical
www.pscelaftcam
Pace Analytical Services, Inc.
6701 Conference Drive
Raleigh, NC 27607 4
[phone]
QUALITY CONTROL DATA
Project: ARCLIN004
Pace Project No.: 92277936
QC Batch: WET/41714 Analysis Method: EPA 9040
QC Batch Method: EPA 9040 Analysis Description: 9040 pH
Associated Lab Samples: 92277936001
SAMPLE DUPLICATE: 1618792
Parameter Units
pH Std. Units
92277933001 Dup
Result Result
6.2 6.3
RPD Qualifiers
1 D6,H6
Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/11 /2015 08:22 AM without the written consent of Pace Analytical Services, Inc..
Page 10 of 26

aceAr�alytical
aw►upacdabs com
Pace Analytical Services, Inc.
6701 Conference Drive
Raleigh, NC 27607
(919)8344984
QUALITY CONTROL DATA
Project: ARCLIN004
Pace Project No.: 92277936
QC Batch: WETA/25661
Analysis Method: EPA 350.1
QC Batch Method: EPA 350.1
Analysis Description: 350.1 Ammonia, Low Level
Associated Lab Samples: 92277936001
METHOD BLANK: 1621670
Matrix: Water
Associated Lab Samples: 92277936001
Blank
Reporting
Parameter Units
Result
Limit
Analyzed Qualifiers
Nitrogen, Ammonia mg/L
ND 0.010
12/09/15 01:00
LABORATORY CONTROL SAMPLE: 1621671
Spike
LCS
LCS % Rec
Parameter Units
Conc.
Result
% Rec Limits Qualifiers
Nitrogen, Ammonia mg/L
1
0.92
92 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1621672
1621673
MS
MSD
92277933001
Spike
Spike MS
MSD MS MSD
% Rec
Parameter Units Result
Conc.
Conc. Result
Result % Rec % Rec
Limits
RPD Qual
Nitrogen, Ammonia mg/L 0.72
1
1 1.1
1.1 36 36
90-110
0 M1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1621674
1621675
MS
MSD
92278045012
Spike
Spike MS
MSD MS MSD
% Rec
Parameter Units Result
Conc.
Conc. Result
Result % Rec % Rec
Limits
RPD Qual
Nitrogen, Ammonia mg/L 0.050
1
1 0.71
0.71 66 66
90-110
1 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/11 /2015 08:22 AM without the written consent of Pace Analytical Services, Inc..
Page 11 of 26

aceh7alyflcal
www.pacelabs.com
Pace Analytical Services, lac.
6701 Conference Drive
Raleigh, NC 27607
(919)8344984
QUALITY CONTROL DATA
Project: ARCLIN004
Pace Project No.: 92277936
QC Batch: WETA/25619
Analysis Method: EPA 351.2
QC Batch Method: EPA 351.2
Analysis Description: 351.2
TKN
Associated Lab Samples: 92277936001
METHOD BLANK: 1619040
Matrix: Water
Associated Lab Samples: 92277936001
Blank Reporting
Parameter Units
Result Limit
Analyzed
Qualifiers
Nitrogen, Kjeldahl, Total mg/L
ND 0.50
12/04/15 02:41
LABORATORY CONTROL SAMPLE: 1619041
Spike LCS
LCS % Rec
Parameter Units
Cone. Result
% Rec Limits
Qualifiers
Nitrogen, Kjeldahl, Total mg/L
10 10.4
104 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1619042 1619043
MS MSD
92276933001
Spike Spike MS
MSD MS
MSD
% Rec
Parameter Units Result
Cone. Cone. Result
Result % Rec
% Rec
Limits
RPD Qual
Nitrogen, Kjeldahl, Total mg/L 3.9
10 10 16.0
14.7 121
107
90-110
9 M1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1619044 1619045
MS MSD
92278126001
Spike Spike MS
MSD MS
MSD
% Rec
Parameter Units Result
Cane. Cone. Result
Result % Rec
% Rec
Limits
RPD Qual
Nitrogen, Kjeldahl, Total mg/L 1.7
10 10 13.2
11.9 115
103
90-110
10 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full.
Date: 12/11/2015 08:22 AM without the written consent of Pace Analytical Services, Inc..
Page 12 of 26

aceAnalytical
www.pacelabscom
Pace Analytical Services, Inc.
6701 Conference Drive
Raleigh, NC 27607
[phone]
QUALITY CONTROL DATA
Project: ARCLIN004
Pace Project No.: 92277936
QC Batch: WETA/25621
Analysis Method: EPA 365.1
QC Batch Method: EPA 365.1
Analysis Description: 365.1 Phosphorus, Total
Associated Lab Samples: 92277936001
METHOD BLANK: 1619062
Matrix: Water
Associated Lab Samples: 92277936001
Blank
Reporting
Parameter Units
Result
Limit
Analyzed Qualifiers
Phosphorus mg/L
ND 0.050
12/04/15 09:18
LABORATORY CONTROL SAMPLE: 1619063
Spike
LCS
LCS % Rec
Parameter Units
Conc.
Result
% Rec Limits
Qualifiers
Phosphorus mg/L
2.5
2.7
109 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1619064
1619065
MS
MSD
92277491003
Spike
Spike MS
MSD MS
MSD
% Rec
Parameter Units Result
Conc.
Conc. Result
Result % Rec
% Rec
Limits
RPD Qual
Phosphorus mg/L 139
125
125 269
266 104
102
90-110
1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1619066
1619067
MS
MSD
92277927004
Spike
Spike MS
MSD MS
MSD
% Rec
Parameter Units Result
Conc.
Conc. Result
Result % Rec
% Rec
Limits
RPD Qual
Phosphorus mg/L 124
125
125 252
252 103
103
M110
0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except In full,
Date: 12/11/2015 08:22 AM without the written consent of Pace Analytical Services, Inc..
Page 13 of 26

aceAnalytical
w m..Facelabs.ccm
Pace Analytical Services, Inc.
6701 Conference Drive
Raleigh, NC 27607
(919)8344984
QUALITY CONTROL DATA
Project: ARCLIN004
Pace Project No.: 92277936
QC Batch: WETA/25614
Analysis Method: EPA 420.4
QC Batch Method: EPA 420.4
Analysis Description: 420.4 Phenolics
Associated Lab Samples: 92277936001
METHOD BLANK: 1618673
Matrix: Water
Associated Lab Samples: 92277936001
Blank
Reporting
Parameter Units
Result
Limit
Analyzed
Qualifiers
Phenol mg/L
ND 0.010
12/03/1518:30
LABORATORY CONTROL SAMPLE: 1618674
Spike
LCS
LCS % Rec
Parameter Units
Conc.
Result
% Rec Limits
Qualifiers
Phenol mg/L
.05
0.049
99 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1618675
1618676
MS
MSD
92277023003
Spike
Spike MS
MSD MS
MSD
% Rec
Parameter Units Result
Conc.
Conc. Result
Result % Rec
% Rec
Limits
RPD Qual
Phenol mg/L ND
.05
.05 0.055
0.055 91
91
90-110
1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1618677
1618678
MS
MSD
92277023004
Spike
Spike MS
MSD MS
MSD
% Rec
Parameter Units Result
Conc.
Conc. Result
Result % Rec
% Rec
Limits
RPD Qual
Phenol mg/L ND
.05
.05 0.055
0.055 94
93
90-110
1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/11/2015 08:22 AM without the written consent of Pace Analytical Services, Inc..
Page 14 of 26

aceAnaljftal
www.pacelabs cam
Pace Analytical Services, Inc.
6701 Conference Drive
Raleigh, NC 27607
[phone]
QUALITY CONTROL DATA
Project: ARCLIN004
Pace Project No.: 92277936
QC Batch: WETA/25660
Analysis Method: SM 5220D
QC Batch Method: SM 5220D
Analysis Description: 5220D COD
Associated Lab Samples: 92277936001
METHOD BLANK: 1621659
Matrix: Water
Associated Lab Samples: 92277936001
Blank
Reporting
Parameter Units
Result
Limit
Analyzed
Qualifiers
Chemical Oxygen Demand mg/L
ND 25.0
12/08/15 15:10
LABORATORY CONTROL SAMPLE: 1621660
Spike
LCS
LCS
% Rec
Parameter Units
Conc.
Result
% Rec
Limits
Qualifiers
Chemical Oxygen Demand mg/L
750
740
99
90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1621661
1621662
MS
MSD
92277826001
Spike
Spike MS
MSD
MS
MSD
% Rec
Parameter Units Result
Conc.
Conc. Result
Result
% Rec
% Rec
Limits
RPD Qual
Chemical Oxygen Demand mg/L 53.0
750
750 762
762
95
95
90-110
0
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1621663
1621664
MS
MSD
92277927004
Spike
Spike MS
MSD
MS
MSD
% Rec
Parameter Units Result
Conc.
Conc. Result
Result
% Rec
% Rec
Limits
RPD Qual
Chemical Oxygen Demand mg/L 272
3000
3000 3000
3000
91
91
90-110
0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full.
Date: 12/11/2015 08:22 AM without the written consent of Pace Analytical Services, Inc..
Page 15 of 26

aceAnalyflcal
wmpacelabs cam
Pace Analytical Services, Inc.
6701 Conference Drive
Raleigh, NC 27607
[phone]
QUALIFIERS
Project: ARCLIN004
Pace Project No.: 92277936
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
LABORATORIES
PAST -A Pace Analytical Services -Asheville
PASI-C Pace Analytical Services - Charlotte
PASI-E Pace Analytical Services - Eden
ANALYTE QUALIFIERS
B2 Oxygen usage is less than 2.0 for all dilutions set. The reported value is an estimated less than value and is calculated
for the dilution using the most amount of sample.
D6 The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits.
H6 Analysis initiated outside of the 15 minute EPA recommended holding time.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/11/2015 08:22 AM without the written consent of Pace Analytical Services, Inc.. Page 16 of 26

�alceAnalXkafv
www.patelabs com
Pace Analytical Services, Inc.
6701 Conference Drive
Raleigh, NC 27607
(919)8344984
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: ARCLIN004
Pace Project No.: 92277936
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch Analytical Method Batch
92277936001
ARCLIN004
HACH 10206
EDEN/20930
92277936001
ARCLIN004
SM 2540D
EDEN/20933
92277936001
ARCLIN004
SM 4500-NO2 B
EDEN/20932
92277936001
ARCLIN004
SM 5210B
EDEN/20928 SM 5210B EDEN/20935
92277936001
ARCLIN004
EPA 1664B
GCSV/23413
92277936001
ARCLIN004
EPA 9040
WET/41714
92277936001
ARCLIN004
EPA 350.1
WETA/25661
92277936001
ARCLIN004
EPA 351.2
WETA/25619
92277936001
ARCLIN004
EPA 365.1
WETA/25621
92277936001
ARCLIN004
EPA 420.4
WETA/25614
92277936001
ARCLIN004
SM 5220D
WETA/25660
Date: 12/11/2015 08:22 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 17 of 26

1""
Document Name: Sample Condition Upon
I)oct,rnent Revis,:d: i?Vlay 1a, 2015 i
' Ann fIG?1'.-
Receipt (SCUR
Paco 1 of 2
Document No.:
Issuing Authorities:
..Yc1C
Y�<,.,.
F-RAL-CS-00,;-rev.03
Pace Raleigh QualitY O:fic3
'Page 2 of 2 is for Internal Use only
Client Narne:
Courier ;Circle): Fed Ex UPS USPS Client Commercial Pace 0:ncr_
Custody Soaf on Cooler/Box Present: iyes no Seals Intact: yes --c
Pa. -king t4aterlal: 0 Bubble Wrap f-1 Bubble Bags Z None - Other
Circlo Thermometer used: IR Gun S ''22l}65 8 pe of Ice: Jet Slue None Samples on ace, conlinz process has N'T"I
,K C;un csa p.;si�i.ccuoa��
—.---.�•.
l):�te and Initials of person examining
Temp Correction Factor' Add / ibtract _ �
L
c t i s�1 Prose ati n
t
`g1��f
Con•ectod Cooler Tontp.: �� C
13ioloc/ical Tissue
is Frozen: Nees ;.o ,�r►.�
, cltieck Z. 1
srZ:ail bra above freezing !o WC
Coniments:
-rhaii: of Custody Present:
cis Ct•to
DNA
1.
i_,I rain of Custody Filled Out:
es O;,o
Ot•t,A
2•
Chain of Custody Relinquished:
cs Otto
OwA
3.
;Sampler Na,ne & Signature on COC:
Ycs ❑;:a
G:��k
:.
Samoles Arrived within Hold lime:
iynr. Or-;o
OruA
5.
Short Hold Time Analysis (<72hr):
yas ❑m;
Ort,%
6. ��t✓
Rush Turn Around Time Requested:
Oyes ao
i:::s:.,
7.
Sufti•.;ieut plume:
0yes 0!,10
Grtl;,
8.
C onact Containers Used:
ees Otto
`Yes
0 t,I v,
9.
41aze Containers Used:
Oa:o
Ct*%
<:�',f�:ai:lE-r, intact:
014a
C.-HA
10.
'Xiawed tacit:=ne received for Dissolved tests
Oyes MID
Sa mole _at:els watch COC:
Yes Otto
t_ lnv%
12.
-111CILI fes, date.►'time/lDlAnah sis Matrix:
k-
lAl! containrs neear, eding Fresatiun have b"n cneamd.
E
�es CND
GNW.A
13.
(1AL c:..ital:ter needing preservation are found to t:e in
VY05 Otla
Ei`rA
EFA reccrenlendatiol.
: C-w. Qutl.0 n. T%)C, C .C. �`11• RO (' aler)
40C. ❑.•!�i
-
!s.-virsles ;hiic;kee for dech'.crination:
ONA
14.
- ea:3space in VCA Via!s >6min):
O'eas 11140
'JN!A
15.
TrIL E!wk Present:
0-{es One
XtJ1A
16.
IT:ip 6iank Custody Seals Present
Oyes Otto
/MIA
r......+rrf'.
Client ltiovicationl Rasolution: Field Data Required? Y ! ti
Person Contacted:
CNi-trients/ Resolu:ion.
SCURF 1SRF
Review::
Data:
DatelTime:
V-. f.ene er there is a discrepancy affect -jig tlonh Catolira compilancO
s3ir:ples. a copy of t ,is furor V611 be sent to :he North Carolina DEIWR
Gsr:iC.cation Ufriro (i.e out of hold, incorrect preservative, out of temp,
incorrect contalners)
WO#:92277936
1111111111111111111 ill
92277936
Page 18 of 26

CHAIN -OF -CUSTODY / Analytical Request Document
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ANALYTICAL ENVIRONMENTAL SERVICES, INC.
AES
December 10, 2015
Taylor Ezell
Pace Analytical Services, Inc.
9800 Kincev Avenue. Suite 100
Huntersville NC 28078
TEL: [phone]
FAX: [phone]
RE: 92277936
Dear Taylor Ezell: Order No: 1512263
Analytical Environmental Services, Inc. received 1 samples on 12/3/2015 10:40:00 AM
for the analyses presented in following report.
No problems were encountered during the analyses. Additionally, all results for the associated
Quality Control samples were within EPA and/or AES established limits. Any discrepancies
associated with the analyses contained herein will be noted and submitted in the form of a
project Case Narrative.
AES' certifications are as follows:
-NELAC/Florida Certification number E87582 for analysis of Environmental Water,
soil/hazardous waste, and Drinking Water Microbiology, effective 07/01/15-06/30/16.
-AIHA-LAP, LLC Laboratory ID: 100671 for Industrial Hygiene samples (Organics,
Inorganics), Environmental Lead (Paint, Soil, Dust Wipes, Air), and Environmental
Microbiology (Fungal) Direct Examination, effective until 09/01/17.
These results relate only to the items tested. This report may only be reproduced in full.
If you have any questions regarding these test results, please feel free to call.
Dorothy deBruvn
Project Manager
3080 Presidential Drive - Atlanta, Georgia 30340 - Tel: [phone] - Fax: [phone] - Toll Free: 800.972.4889
w w.aesatlanta.com Page 1 of 7
Page 20 of 26

Chain of Custody
Workorder: 92277936
Workorder Name:
ARCLIN004
Results Requested 12/15/21
Uvojer I ern fdf4i13fC V11 F%ca.a+ Wr
I d t i t client confidentiality locatiOn/name of the sampling site, sampler's name and signature may not be provided on i
n or er o ma n a�n
This chain of custody is considered complete as is since this information is available in the owner laboratory.
Tuesday, December 01, 2016 4:53:40 PM
FAT-ALL-G002rev.00 2•

Analytical Environmental Services, Inc
Date: 10-Dec-15
Client: Pace Analytical Services, Inc.
Project: 92277936 Case Narrative
Lab ID: 1512263
Samples arrived after hold time expired. Proceed with analysis per Liamm Harrison via email on 12/3/15.
Formaldehyde Analysis by Method 8315:
Sample 1512263-001 A was received and extracted and/or analyzed outside holding time of 72 hours.
Page 3 of 7
Page 22 of 26

Analytical Environmental Services, Inc Date: 10-Dec-15
Client:
Pace Analytical Services, Inc.
Client Sample ID:
ARCLIN004
Project Name:
92277936
Collection Date:
11/30/2015 10:30:00 AM
Lab ID:
1512263-001
Matrix:
Aqueous
Analyses reporting Dilution
Y Result Limit Qual Units BatchID Date Analyzed Analyst
Factor
Carbonyl Compounds by HPLC SW8315A
Formaldehyde 140 50 H ug/L 216703 1 12/04/20I519:25 RF
x 114 WO -
Qualifiers: • Value exceeds maximum contaminant level
BRL Below reporting limit
H Holding times for preparation or analysis exceeded
N Analyte not NELAC certified
B Analyte detected in the associated method blank
> Greater than Result value
E Estimated (value above quantitation range)
S Spike Recovery outside limits due to matrix
Narr See case narrative
NC Not confirmed
< Less than Result value
J Estimated value detected below Reporting Limit
Page 4 of 7
Page 23 of 26

IL
Analytical Environmental Services, Inc.
Sample/Cooler Receipt Checklist
Client Pon,444k-r-A
Work Order Number S 1 �R 2
Checklist completed by
Sign re
Date
/UPS
Mail Other
Carrier name: FedEx — Courier — Client
^ US ^
Shipping container/cooler in goad condition?Yes
No —
Not Present —
Custody seals intact on shipping container/cooler?
Yes _
No !
Not Present v/'
Custody seals intact on sample bottles.
Yes
No
Not Present ✓
—
- Container/Temp Blank temperature in compliance? (0°_<6*Q* Yes ✓
No —
Cooler #1 Cooler #2 Cooler #3
Cooler #4
Cooler#5 Cooler #6
Chain of custody present?
Yes ✓
No —
Chain of custody signed when relinquished and received? Yes `�
No —
Chain of custody agrees with sample labels?
Yes '�
No —
Samples in proper container/bottle?
Yes ✓
No —
Sample containers intact?
Yes `�
No —
J
Sufficient sample volume for indicated test?
p
Yes —
No
—/
All samples received within holding time?
Yes
No
Was TAT marked on the COC?
Yes V/
No
Proceed with Standard TAT as per project history?
Yes —
No —
Not Applicable
Water- VOA vials have zero headspace? Nd VOA vials submitted ,f
Yes
— No —
Water - pH acceptable upon receipt?
Yes
No —
Not Applicable —
Adjusted?
Checked by
�•' '
Sample Condition: Good ,/ Other(Explain)
(For diffusive -samples or AIHA lead) Is a known blank
included? Yes
—
No ✓
See Case Narrative for resolution of the Non:6Conformance.
* Samples do not have to comply with the given range for certain parameters.
AAes serveAl\Sample ReceiptlMy DocumentslCOCs and pH Adjustment SheetlSample Cooler Reeipt Checklist Revl.rtf
Page 5 of 7
Page 24 of 26

Permit Number: NC ,-NCO 8377
FACILITY NAME Mayo Steam Electric Plant
PERSON COLLECTING SAMPLE(S) Herbert M. Lea, Jr.
CERTIFIED LABORATORY(S)
PartA: Specific Monitoring Requirements
STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT-mD
Mayo Plant Lab Lab #
PACE Analytical Lab it
AP, A j PJES,�Q,I.LECTED DURING CALENDAR YEAR: 2014
This moniituuor�linng report shall be received by the Division no later than 30 days from
E I'J i ti Ahatel�tgliity receives the sampling results from the laboratory.)
N( ISOG County Person
5064
40/503/530
Phone No. 336-597-73 9 Rot i'e" . A ,
(SIGNATURE OF PERMITEre6R DESIGNEE)
By this signature, I certify that this report is accurate
and complete to the best of my knowledge.
Outfall
Date
00530
00556
01002
01042
80103
71900
01147
00400
01097
01022
01105
00945
No.
Sample
Collected
Total
Suspended
Solids
Oil and
Grease
Arsenic
Total'
Copper
Total
COD
Mercury
Selenium
pH
Antimony
Boron
Aluminum
Sulfate
mo/dd/yr
mg/I
mg/I
ug/I
ug/I
mg/I
ug/I
ug/I
std. units
ug/I.
ug/I
ug/I
mg/I
Outfall010
3 3 2014
56.7
2.3
0.74
5.10
36.0
0.016*
1.0
5.87
<0.50
<25.0
3320
13.3
*Above 0.012 ug
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month? No
( if yes complete Part B )
Part B: NA
Mail Original and one copy to:
STORM EVENT CHARACTERISTICS ( if more than one storm event was sampled) Division of Water Quality
Date 3/3/2014 Date Attn: Central Files
Total Event Precipitation inches) 0.4 Total Event Precipitation (inches) 1617 Mail Services Center
event duration (hours): 12 event duration (hours): Raleigh, North Carolina 27699-1617
" I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified
personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering
the Information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalities for submitting false
information, Including the possibility of fines and imprioonment for knowing violations."
William J. Thacker
Permittee
( Sig at e o ermittee)
Date

Analytical Environmental Services, Inc
Client:
Pace Analytical Services, Inc.
Project Name:
92277936
Lab Order:
1512263
Lab Sample ID Client Sample ID Collection Date
1512263-001A ARCLIN004 11/30/2015 10:30:OOAM
Da
Matrix Test Name TCLP Date
Aqueous Carbonyl Compounds by HPLC SW8315

Analytical Environmental Services, Inc
Client: Pace Analytical Services, Inc.
ANALYTICA
Project Name: 92277936
Workorder: 1512263
1
Sample ID: MB-216703
CIient ID:
Units: ug/L
Prep Date:
SampleType: MBLK
TestCode:
Carbonyl Compounds by HPLC SW8315A
BatchID: 216703
Analysis Date
Analyte
Result
RPT Limit SPK value SPK Ref Val
%REC Low Limit
High Limit RPD R.
Formaldehyde
BRL
50
Sample ID: LCS-216703
Client ID:
Units: ug/L
Prep Date:
SampleType: LCS
TestCode:
Carbonyl Compounds by HPLC SW8315A
BatchID: 216703
Analysis Date
Analyte
Result
RPT Limit SPK value SPK Ref Val
%REC Low Limit
High Limit RPD Ri
Formaldehyde
1186
50 1000
119 70
130
Sample ID: 1512263-OOIAMS
Client ID:
ARCLIN004
Units: ug/L
Prep Date:
SampleType: MS
TestCode:
Carbonyl Compounds by HPLC MOM
BatchID: 216703
Analysis Date:
Analyte
Result
RPT Limit SPK value SPK Ref Val
%REC Low Limit
High Limit RPD R(
Formaldehyde
1281
50 1000 138.9
114 42.9
130
Sample ID: 1512263-OOIAMSD
Client ID:
ARCLIN004
Units: ug/L
Prep Date:
SampleType: MSD
TestCode:
Carbonyl Compounds by HPLC SW8315A
BatchID: 216703
Analysis Date:
Analyte
Result
RPT Limit SPK value SPK Ref Val
%REC Low Limit
High Limit RPD Rc
Formaldehyde
1279
50 1000 138.9
114 42.9
130 128:
Qualifiers: > Greater than Result value < Less than Result value B Analyte detected
BRL Below reporting limit E Estimated (value above quantitation range) H Holding times fc
J Estimated value detected below Reporting Limit N Analyte not NELAC certified R RPD outside lin
Rpt Lim Reporting Limit S Spike Recovery outside limits due to matrix

STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
Permit Number: NC NCO038377 SAMPLES COLLECTED DURING CALENDAR YEAR: 2014
(This monitoring report shall be received by the Division no later than 30 days from
the date the facility receives the sampling results from the laboratory.)
FACILITY NAME Mayo Steam Electric Plant County Person
PERSON COLLECTING SAMPLE(S) Herbert M. Lea, Jr. P one No. 336-597-7 9
CERTIFIED LABORATORY(S) Mayo Plant Lab Lab # 5064
PACE Analytical Lab # 40/503/530 (SIGNATURE OF PERMITEE OR D 'IGNEE)
By this signature, I certify that this report is accvmte
and complete to the best of my knowledge.
Part A: Specific Monitoring Requirements
Outfall
Date.
01012
01027
01034
01051
01067
01077
01059
01092
00916
No.
Sample
Collected
Beryllium
Cadmium
Chromium
Lead
Nickel
Silver
Thallium
Zinc
Calcium
mo/dd/yr
ug/I
ug/I
ug/1
ug/I
ug/1
ug/I
ug/1
ug/1
ug/1
Ou a11010
3 3 2014
0.11
<0.050
6.7
2.9
3.8
<0.050
<0.50
24.7
34000
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month? No
( if yes complete Part B )
Part B: NA
Mail Original and one copy to:
STORM EVENT CHARACTERISTICS (if more than one storm event was sampled) Division of Water Quality
Date 3/3/2014 Date Attn: Central Files
Total Event Precipitation (inches) 0.4 Total Event Precipitation (inches) 1617 Mail Services Center
event duration (hours): 12 event duration (hours): Raleigh, North Carolina 27699-1617
I maity, under Penalty of law, that this doeument and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified
personnel propedy gather and evaluate the Information submitted. Eased on my Inquiry of the person or persons who manage the system, or those persons directly responsible for gathering
the information, the Information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalities for submitting false
Information, including the possibility of fines and impriconment for knowing violations.'
&/,
William J. Thacker Date / / G
Permittee ( Sig6olfure of Permittee)