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WQ0003698_Monitoring - 07-2023_20230808
GW-59A COMPLIANCI�, REPDRT FORM Permit # W l& 0003 61 (Submit one each monitoring period with GIi -59 forms.) 1 Enter date monitoring results were due. ( 23 ) Will this monitoring report (GW-59 and GW-59A) YES NO be submitted after the established due date. x 2 Was any required information missing on the GW-59 report forms? YES NO IF the answer to question 1 or 2 is "YES", list in the space provided below the well identification number(s) and explain the problems encountered in obtaining the required information. 3 Are any of the monitor wells in need of repair or maintenance (damaged casing, unlocked or missing cap, missing YES NO identification plate, area overgrown, etc.)? If the answer is "Yes", contact the Regional Office for guidance. X 4 Are any monitored constituents equal to or above the established standards? E NO If the answer to question 4 is "NO", skip to section 8. If the answer to question 4 is "YES" list the affected wells individually with constituent(s) and concentration(s) exceeding standards in the space provided below: S,e e- At4-�,ckel DJ 5 For the constituents identified in question 4 above, have standards been exceeded previously for the YES NO same constituent(s) in the same well(s) in the last two years? X If the answer to question 5 is "NO", skip to section 8. If the answer to question 5 is "YES", list in the space provided below, each well with constituent(s) exceeding standards, concentration(s) reported, and sample collection date for each occurrence Oipr r-la'aLh"o,y W. See A4tzy--k42JAUG 0 8 2023 Are the monitoring wells listed in section 5 located at or beyond the review boundary? YES NO If the answer is "YES", a groundwater quality problem may be occurring. CONTACT THE REGIONAL OFFICE IMMEDIATELY FOR GUIDANCE. If the answer is "NO", monitoring wells may be improperly located; contact the Regional Office. `i 3 IIDAal 1 0-�43I c e, Co A fac *CL 7 Is the permittee implementing previously approved actions required by the Division involving this YES NO groundwater quality problem? v !� If the answer to question 7 is "YES", describe those actions in the space provided below. If the answer to question 7 is "NO", contact the Reqional Office within 90 days; an evaluation may be required to determine the impact the waste disposal system is having at the review and compliance boundaries surrounding this facility. Failure to do so may subject the permittee to a Notice of Violation fines, and/or penalties. 'Restaflak D-flce Contac.it,� 8 The person completing this portion (G W-59A) of the monitoring report should sign below and submit this form with GW-59 forms for required wells to the address provided at the top of the current GW-59 form. I hereby acknowledge that the above information was evaluated and the information submitted in this report (Compliance Report GW-59A) is true and complete to the best of my knowledge. S2 1120 2� Signa re of Permi ee (or, uth ized Agent) Date Question #4 LAB DATA WHICH EXCEEDS PERMIT DATE MONITORING WELL # PARAMETER REPORTED DATA 7.12.23 1 pH 5.9 2 pH 6.4 Ammonia 5.6 mg/L Iron 42,200 ug/L Manganese 1,530 ug/L 3 pH 5.1 Cobalt 2.8 ug/L Iron 478 ug/L Manganese 85.8 ug/L 4 pH 5.0 Cobalt 3.0 ug/L Manganese 1 124 ug/L F QUESTION #5 LAB DATA WHICH EXCEEDS PERMIT FOR LAST 2 PREVIOUS YEARS 11.30.21 1 pH 5.9 2 Ammonia 6.0 mg/L Iron 28.4mg/L Manganese 1080 ug/L pH 6 3 Nitrate 12.1mg/L Manganese 132 ug/L pH 5 4 Manganese 119 ug/L pH 5.1 5/27-6/9/2022 1 pH 5.7 2 Ammonia 6.4 mg/L Iron 43.9 mg/L Manganese 1,200 ug/L pH 6.3 3 Manganese 107 ug/L 4 pH 5.0 Manganese 172 ug/L pH 5.0 11.3.22 1 pH 5.9 2 Ammonia 5.4 mg/L Iron 27,100ug/L Manganese 1,250 ug/L pH 6.4 3 Cobalt 2.5 ug/L Manganese 98.5 ug/L pH 5.1 4 Manganese 86 ug/L pH 4.9 3.23.23 1 pH 5.9 2 Ammonia 5.9 mg/L Cobalt 1.1 ug/L Iron 50,400 ug/L Manganese 1,310 ug/L 3 pH 5.2 Cobalt 2.2 ug/L Manganese 70.6 ug/L 4 pH 5 Cobalt 3.3 ug/L Manganese 126 ug/L Page 1 7.12.23 1 pH 5.9 2 pH 6.4 Ammonia 5.6 mg/L Iron 42,200 ug/L Manganese 1,530 ug/L 3 pH 5.1 Cobalt 2.8 ug/L Iron 478 ug/L Manganese 85.8 ug/L 4 pH 5 Cobalt 3.0 ug/L Manganese 1 124 ug/L Page 2 SUBMIT FORM ON YELLOW PAPER ONLY • DEPARTMENT OF ENVIRONMENTAL QUALITY - DIV. OF WATER RESOURCES GROUNDWATER QUALITY MONITORING: INFORMATION PROCESSING UNIT COMPLIANCE REPORT FORM 1917 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: 919-807-6306 FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: Facility Name: Corpening Creek WWTP--City of Marion Non -Discharge WC 0003698 UIC NPDES Other Permit Name (if different): Facility Address: Marion NC 28752 TYPE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon ❑ Remediation: Infiltration Gallery Marion NC 28752 County McDowell (State) ❑ Spray Field El Remediation: Contact Person: Tim Horton Telephone#: (828) 652-8843 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Monitoring Well #1 R No. of wells to be sampled: 4 ❑ Water Source Heat Pump ❑ Other: (from Permit) SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): Monitoring Well #1 R Date sample collected: 7/12/2023 FIELD ANALYSES: WAS Well Depth: 62.62 ft. Well Diameter: 2 in. pH 00400: 5.9 units Temp. 000lo: 31.4 °C DRY at Depth to Water Level 82546:26.94 ft. below measuring point Screened Interval: 55 ft. to 65 ft. Spec. Cond. 00094: µMhos time of sampling, Measuring Point is 1.5 ft. above land surface Relative M.P. Elevation: ft. Odor 000a5: None check Volume of water pumped/bailed before sampling: 2.38 gallons Appearance Clear here:❑ Samples for metals were collected unfiltered: ❑ YES ❑ NO and field acidified: N YES ❑ NO LABORATORY INFORMATION Date sample analyzed:7/12-27/2023 Laboratory Name: Pace Analytical Certification No. 40 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N 00615 <0.040 mg/L Pb - Lead o1051 ug/L Coliform: MF Fecal 31616 /100mL Nitrate (NO3) as N 00620 0.062 mg/L Zn - Zinc 01092 mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 mg/L (Note. Use MPN method for highly turbid samples) Orthophosphate 70507 <0.050 mg/L Other (Specify Compounds and Concentration Units): Dissolved Solids:Total 70300 mg/L Al -Aluminum 01105 mg/L Boron: <50 ug/L pH (Lab) 00403 units Ba - Barium 01007 33.4 ug/L Cobalt: <1 ug/L TOC 00680 mg/L Ca - Calcium 00916 mg/L Chloride 00940 mg/L Cd - Cadmium 01027 <0.20 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 288 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? ❑ Yes (1) ❑■ No (0) pecific Conductance 00095 µMhos K - Potassium 00937 mg/L VOC 7873 method # Total Ammonia 00610 <0.10 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen, NH3as N, Ammonia Nitrogen, Total) Mn - Manganese 01055 18.5 ug/L , method # TKN as N 00625 <0.50 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% Tim Horton WWTP Superintendent Permittee (or Authorized Agent) Name and Title - Please print or type SUBMIT FORM ON YELLOW PAPER ONLY DEPARTMENT OF ENVIRONMENTAL QUALITY -DIV. OF WATER RESOURCES GROUNDWATER QUALITY MONITORING: �16117 INFORMATION PROCESSING UNIT COMPLIANCE REPORT FORM MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: 919-807-6306 FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: Facility Name: Corpening Creek WWTP--City of Marion Non -Discharge WQ 0003698 UIC Permit Name (if different): NPDES Other Facility Address: Marion INC 28752 TYPE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon ❑ Remediation: Infiltration Gallery Marion NC 28752 County McDowell ❑ Spray Field ❑ Remediation: Contact Person: Tim Horton Telephone#: (828) 652-8843 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Monitoring Well #2 No. of wells to be sampled: 4 ❑ Water Source Heat Pump ❑ Other: (from Permit) SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): Monitoring Well #2 Date sample collected: 7/12/2023 FIELD ANALYSES: WAS Well Depth: 38.02 ft. Well Diameter: 2 in. pH 00400: 6.4 units Temp. 000lo: 20.6 °C DRY at Depth to Water Level 82546:18.96 ft. below measuring point Screened Interval: 30 ft. to 40 ft. Spec. Cond. 00094: µMhos time of sampling, Measuring Point is 0.22 ft. above land surface Relative M.P. Elevation: ft. Odor 00085: Sulfur check Volume of water pumped/bailed before sampling: 0.40 gallons Appearance Clear here:❑ Samples for metals were collected unfiltered: ❑ YES ❑ NO and field acidified: X YES ❑ NO LABORATORY INFORMATION Date sample analyzed:7/12 - 27/2023 Laboratory Name: Pace Analytical Certification No. 40 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N 00615 <0.040 mg/L Pb - Lead 01051 ug/L Coliform: MF Fecal 31616 /100mL Nitrate (NO3) as N 00620 <0.040 mg/L Zn - Zinc 01092 mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 <0.050 mg/L Other (Specify Compounds and Concentration Units): issolved Solids:Total 70300 mg/L Al -Aluminum 01105 mg/L Boron: <50 ug/L pH (Lab) 00403 units Ba - Barium 01007 55.4 ug/L Cobalt: <1 ug/L TOC 00680 mg/L Ca - Calcium 00916 mg/L Chloride 00940 mg/L Cd - Cadmium 01027 <0.20 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 42,200 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? ❑ Yes (1) ❑■ No (0) Specific Conductance 00095 µMhos K - Potassium 00937 mg/L VOC 7873 method # Total Ammonia oo610 5.6 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen, NH3as N, Ammonia Nitrogen, Total) Mn - Manganese 01055 1,530 ug/L method # TKN as N 00625 5.8 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% SUBMIT FORM ON YELLOW PAPER ONLY 171111111 y GROUNDWATER QUALITY MONITORING: COMPLIANCE REPORT FORM FACILITY INFORMATION Please Print Clearly or Type Facility Name: Corpening Creek WWTP--City of Marion Permit Name (if different): Facility Address: Marion INC 28752 Marion `Street) NC 28752 County McDowell (CI!v) (State) (7io) Contact Person: Tim Horton Telephone#: (828) 652-8843 Well Location/Site Name: Monitoring Well # 3 No. of wells to be sampled: 4 WELL ID NUMBER (from Permit): Monitoring Well #3 Date sample collected: 7/12/2023 Well Depth: 50.02 ft. Well Diameter: 2 in. Depth to Water Level 82546:34.06 ft. below measuring point Screened Interval: 30 ft. Measuring Point is 1.09 ft. above land surface Relative M.P. Elevation: Volume of water pumped/bailed before sampling: 3.04 gallons RESOURCES INFORMATION PROCESSING UNIT 44IL;SERVICE CENTER. RALEIGH. NC 27699.1617 Phone: PERMIT Number: Expiration Date: Non -Discharge WQ 0003698 UIC NPDES Other TYPE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon ❑ Remediation: Infiltration Gallery ❑ Spray Field ❑ Remediation: ❑ Rotary Distributor ❑ Land Application of Sludge ❑ Water Source Heat Pump ❑ Other: to 40 ft ft. Samples for metals were collected unfiltered: ❑ YES ❑ NO and field acidified: K YES ❑ NO FIELD ANALYSES: pH 00400: 5.1 units Spec. Cond. 00094: Odor 00085: None Appearance Clear Temp. 000io: 26.5 °C uMhos Date sample analyzed:7/12 - 27/2023 Laboratory Name: Pace Analytical Certification No. 40 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N 00615 <0.040 mg/L Pb - Lead 01051 ug/L Coliform: MF Fecal 31616 /100mL Nitrate (NO3) as N 00620 7.3 mg/L Zn - Zinc 01092 mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 <0.050 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): issolved Solids:Total 70300 mg/L Al -Aluminum 01105 mg/L Boron: <50 ug/L pH (Lab) 00403 units Ba - Barium 01007 323 ug/L Cobalt: 2.8 ug/L TOC 00680 mg/L Ca - Calcium 00916 mg/L Chloride 00940 mg/L Cd - Cadmium 01027 0.52 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 478 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? ❑ Yes (1) ❑■ No (0) Specific Conductance 00095 µMhos K - Potassium 00937 mg/L VOC 7873 method # Total Ammonia ooseo <0.10 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen, NH3 as N, Ammonia Nitrogen, Total) Mn - Manganese 01055 85.8 ug/L method # TKN as N 00625 <0.50 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs Tim Horton WWTP Superintendent Permittee (or Authorized Agent) Name and Title - Please print or type n%Ar cn n.... nc nn n- mg/L Effluent Total• tnd that the laboratory analytical data ility of fines and imprisonment for kn( ENr� Wrr,'Al mg/L VOC Removal% 23 DRY at time of sampling, check here: 0 (Date) SUBMIT FORM ON YELLOW PAPER ONLY Ir • • DEPARTMENT OF ENVIRONMENTAL QUALITY - DIV. OF WATER RESOURCES GROUNDWATER QUALITY MONITORING: • • INFORMATION PROCESSING UNIT COMPLIANCE REPORT FORM 1617 MAIL SERVICE GENTR, RALEICiH, NC 27689-1817 Ptlone; 919-807.8306 FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: Facility Name: Corpening Creek WWTP--City of Marion Non -Discharge WQ 0003698 UIC Permit Name (if different): NPDES Other Facility Address: Marion NC 28752 TYPE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon ❑ Remediation: Infiltration Gallery Marion 'street) NC 28752 County McDowell (City) (State) (-,P) ❑ Spray Field El Remediation: Contact Person: Tim Horton Telephone#: (828) 652-8843 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Monitoring Well #4 No. of wells to be sampled: 4 ❑ Water Source Heat Pump ❑ Other: (from Permit) SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): Monitoring Well #4 Date sample collected: 7/12/2023 FIELD ANALYSES: WAS Well Depth: 35.37 ft. Well Diameter: 2 in. pH 00400: 5.0 units Temp. 000io: 23.6 °C DRY at Depth to Water Level 82546:20.55 ft. below measuring point Screened Interval: 18.5 ft. to 33 ft. Spec. Cond. 00094: µMhos time of sampling, Measuring Point is 0.51 ft. above land surface Relative M.P. Elevation: ft. Odor 00085: None check Volume of water pumped/bailed before sampling: 0.53 gallons Appearance Clear here: Samples for metals were collected unfiltered: ElYES ❑ NO and field acidified: ❑■ YES ❑ NO LABORATORY INFORMATION Date sample analyze., . _ 2 -, '7 O;LS Laboratory Name: Pace Analytical Certification No. 40 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N 00615 <0.040 mg/L Pb - Lead 01051 ug/L Coliform: MF Fecal 31616 /100mL Nitrate (NO3) as N 00620 3.3 mg/L Zn - Zinc 01092 mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 mg/L (Note. Use MPN method for highly turbid samples) Orthophosphate 70507 <0.050 mg/L Other (Specify Compounds and Concentration Units): issolved Solids:Total 70300 mg/L Al -Aluminum 01105 mg/L Boron: <50 ug/L pH (Lab) 00403 units Ba - Barium 01007 115 ug/L Cobalt: 3.Oug/L TOC oomo mg/L Ca - Calcium 00916 mg/L Chloride 00940 mg/L Cd - Cadmium 01027 <0.20 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 <50 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? ❑ Yes (1) 0 No (0) pecific Conductance 00095 µMhos K - Potassium 00937 mg/L VOC 7873 method # Total Ammonia 00610 <0.10 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen, NH3as N; Ammonia Nitrogen, Total) Mn - Manganese 01055 124 ug/L method # TKN as N 00625 <0.50 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal%a n,n, cn n-.. nc - 1 Yi ce L Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 July 27, 2023 Mr. Tim Horton City of Marion 3982 NC Hwy 226 South Marion, NC 28752 RE: Project: MONITORING WELLS Pace Project No.: 92677108 Dear Mr. Horton: Enclosed are the analytical results for sample(s) received by the laboratory on July 12, 2023. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services -Asheville • Pace Analytical Services - Charlotte If you have any questions concerning this report, please feel free to contact me. Sincerely, Jonathan W Biddix jonathan.biddix@pacelabs.com (704)875-9092 Project Manager Enclosures REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 26 Pace Analytical Services, LLC ' /''� /� /'� 2225 Riverside Dr. Q / G" A Asheville, NC 28804 YV (828)254-7176 Project: MONITORING WELLS Pace Project No.: 92677108 Pace Analytical Services Charlotte South Carolina Laboratory ID: 99006 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 South Carolina Laboratory ID: 99006 Pace Analytical Services Asheville 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 North Carolina Drinking Water Certification #: 37712 North Carolina Wastewater Certification #: 40 CERTIFICATIONS South Carolina Certification #: 99006001 South Carolina Drinking Water Cert. #: 99006003 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Louisiana DoH Drinking Water* LA029 VirginiaNELAP Certification #: 460221 South Carolina Laboratory ID: 99030 South Carolina Certification #: 99030001 VirginiaNELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 26 Pace Analytical Services, LLC 2225 Riverside Dr. ce( Asheville, NC 28804 yj 4 (828)254_7176 SAMPLE SUMMARY Project: MONITORING WELLS Pace Project No.: 92677108 Lab ID Sample ID Matrix Date Collected Date Received 92677108001 MW-3 Water 07/12/2311:20 07/12/2317:40 92677108002 MW-2 Water 07/12/2312:10 07/12/2317:40 92677108003 MW-4 Water 07/12/2313:10 07/12/2317:40 92677108004 MW-1R Water 07/12/2315:20 07/12/2317:40 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 26 rice SAMPLE ANALYTE COUNT Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: MONITORING WELLS Pace Project No.: 92677108 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92677108001 MW-3 EPA 200.8 Rev 5.4 1994 KRL 6 PASI-A SM 4500-H+B-2011 SMS 1 PASI-A EPA 300.0 Rev 2.1 1993 CDC 4 PASI-A EPA 350.1 Rev 2.0 1993 EGC 1 PASI-A EPA 351.2 Rev 2.0 1993 MFO 1 PASI-A EPA 353.2 Rev 2.0 1993 MFO 2 PASI-A SM 4500-P E-2011 JP1 1 PASI-A 92677108002 MW-2 EPA 200.8 Rev 5.4 1994 KRL 6 PASI-A SM 4500-H+B-2011 SMS 1 PASI-A EPA 300.0 Rev 2.1 1993 CDC 4 PASI-A EPA 350.1 Rev 2.0 1993 EGC 1 PASI-A EPA 351.2 Rev 2.0 1993 MFO 1 PASI-A EPA 353.2 Rev 2.0 1993 MFO 2 PASI-A SM 4500-P E-2011 JP1 1 PASI-A 92677108003 MW-4 EPA 200.8 Rev 5.4 1994 KRL 6 PASI-A SM 4500-1-1+13-2011 SMS 1 PASI-A EPA 300.0 Rev 2.1 1993 CDC 4 PASI-A EPA 350.1 Rev 2.0 1993 EGC 1 PASI-A EPA 351.2 Rev 2.0 1993 MFO 1 PASI-A EPA 353.2 Rev 2.0 1993 MFO 2 PASI-A SM 4500-P E-2011 JP1 1 PASI-A 92677108004 MW-1R EPA 200.8 Rev 5.4 1994 KRL 6 PASI-A SM 4500-H+B-2011 SMS 1 PASI-A EPA 300.0 Rev 2.1 1993 CDC 4 PASI-A EPA 350.1 Rev 2.0 1993 EGC 1 PASI-A EPA 351.2 Rev 2.0 1993 MFO 1 PASI-A EPA 353.2 Rev 2.0 1993 MFO 2 PASI-A SM 4500-P E-2011 JP1 1 PASI-A PASI-A = Pace Analytical Services - Asheville PASI-C = Pace Analytical Services - Charlotte REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 26 Pace Analytical Services, LLC yj /'� 2225 Riverside Dr. / e Asheville, NC 28804 4 (828)254-7176 ANALYTICAL RESULTS Project: MONITORING WELLS Pace Project No.: 92677108 Sample: MW-3 Lab ID: 92677108001 Collected: 07/12/23 11:20 Received: 07/12/23 17:40 Matrix: Water Parameters Results Units PQL Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by Pace Collected By Ryan Byas Collected Date 7/12/23 Collected Time 11:20 pH 5.1 Std. Units Temperature 26.5 deg C Static Water Level 34.06 feet Specific Conductance 114.2 umhos/cm Oxygen, Dissolved 3.3 mg/L Total Well Depth 50.02 feet Turbidity 9.6 NTU Odor None Appearance Clear MDL DF Prepared 1 1 1 1 1 1 1 1 1 1 1 Analyzed CAS No. Qual 07/27/23 15:18 07/27/23 15:18 07/27/23 15:18 07/27/23 15:18 07/27/23 15:18 07/27/23 15:18 07/27/23 15:18 07/27/23 15:18 07/27/23 15:18 7782-44-7 07/27/23 15:18 07/27/23 15:18 07/27/23 15:18 07/27/23 15:18 200.8 MET ICPMS Analytical Method: EPA 200.8 Rev 5.4 1994 Preparation Method: EPA 200.8 Rev 5.4 1994 Pace Analytical Services -Asheville Barium Boron Cadmium Cobalt Iron Manganese 4500H+ pH, Electrometric pH at 25 Degrees C 300.0 IC Anions 28 Days Bromide Chloride Fluoride Sulfate 323 ug/L 3.0 0.64 3 07/22/23 11:38 07/25/23 23:47 7440-39-3 ND ug/L 50.0 8.5 1 07/22/23 11:38 07/25/23 04:59 7440A2-8 0.52 ug/L 0.20 0.060 1 07/22/23 11:38 07/25/23 04:59 7440A3-9 2.8 ug/L 1.0 0.050 1 07/22/23 11:38 07/25/23 04:59 7440A8A 478 ug/L 50.0 20.9 1 07/22/23 11:38 07/25/23 04:59 7439-89-6 85.8 ug/L 2.0 1.0 1 07/22/23 11:38 07/25/23 04:59 7439-96-5 Analytical Method: SM 4500-H+B-2011 Pace Analytical Services -Asheville 5.3 Std. Units 0.10 0.10 1 Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services -Asheville 0.11 mg/L 0.10 0.060 1 7.9 mg/L 1.0 0.60 1 ND mg/L 0.10 0.050 1 ND mg/L 1.0 0.50 1 07/20/23 13:55 07/14/23 23:19 24959-67-9 07/14/23 23:19 16887-00-6 07/14/23 23:19 16984-48-8 07/14/23 23:19 14808-79-8 350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Ammonia ND mg/L 0.10 0.031 1 07/26/23 09:19 7664-41-7 351.2 Total Kjeldahl Nitrogen Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Kjeldahl, Total ND mg/L 0.50 0.25 1 07/25/23 17:22 07/26/23 03:18 7727-37-9 Date: 07/27/2023 03:56 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. H3 Page 5 of 26 Pace Analytical Services, LLC yj ///'''��� 2225 Riverside Dr. / e, " � Asheville, NC 28804 �J �J (828)254-7176 ANALYTICAL RESULTS Project: MONITORING WELLS Pace Project No.: 92677108 Sample: MW3 Lab ID: 92677108001 Collected: 07/12/23 11:20 Received: 07/12/23 17:40 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Nitrate 7.3 mg/L 0.20 0.050 5 07/14/23 01:14 14797-55-8 Nitrogen, Nitrite ND mg/L 0.040 0.031 1 07/14/23 00:58 14797-65-0 SM4500P-E, Phosphate, Ortho Analytical Method: SM 4500-P E-2011 Pace Analytical Services -Asheville Orthophosphate as P ND mg/L 0.050 0.012 1 07/14/23 04:12 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/27/2023 03:56 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 26 Vace", Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: MONITORING WELLS Pace Project No.: 92677108 Sample: MW-2 Lab ID: 92677108002 Collected: 07/12/23 12:10 Received: 07/12/23 17:40 Matrix: Water Parameters Monitoring Well Data Performed by Collected By Collected Date Collected Time pH Temperature Static Water Level Specific Conductance Oxygen, Dissolved Total Well Depth Turbidity Odor Appearance 200.8 MET ICPMS Barium Boron Cadmium Cobalt Iron Manganese 4500H+ pH, Electrometric pH at 25 Degrees C 300.0 IC Anions 28 Days Bromide Chloride Fluoride Sulfate 350.1 Ammonia Nitrogen, Ammonia 351.2 Total Kjeldahl Nitrogen Nitrogen, Kjeldahl, Total Date: 07/27/2023 03:56 PM Results Units PQL MDL DF Prepared Analyzed CAS No. Qual Analytical Method: Pace Analytical Services - Charlotte Pace 1 07/27/23 15:31 Ryan 1 07/27/23 15:31 Byas 7/12/23 1 07/27/23 15:31 12:10 1 07/27/23 15:31 6.4 Std. Units 1 07/27/23 15:31 20.6 deg C 1 07/27/23 15:31 18.96 feet 1 07/27/23 15:31 330.2 umhos/cm 1 07/27/23 15:31 .80 mg/L 1 07/27/23 15:31 7782-44-7 38.02 feet 1 07/27/23 15:31 2.4 NTU 1 07/27/23 15:31 Sulfur 1 07/27/23 15:31 Clear 1 07/27/23 15:31 Analytical Method: EPA 200.8 Rev 5.4 1994 Preparation Method: EPA 200.8 Rev 5.4 1994 Pace Analytical Services -Asheville 55.4 ug/L 1.0 0.21 1 07/22/23 11:38 07/25/23 05:04 7440-39-3 40.1J ug/L 50.0 8.5 1 07/22/23 11:38 07/25/23 05:04 7440-42-8 ND ug/L 0.20 0.060 1 07/22/23 11:38 07/25/23 05:04 7440-43-9 0.96.1 ug/L 1.0 0.050 1 07/22/23 11:38 07/25/23 05:04 7440-48-4 42200 ug/L 500 209 10 07/22/23 11:38 07/25/23 23:52 7439-89-6 1530 ug/L 20.0 10.2 10 07/22/23 11:38 07/25/23 23:52 7439-96-5 Analytical Method: SM 4500-H+B-2011 Pace Analytical Services -Asheville 6.3 Std. Units 0.10 0.10 1 07/20/23 13:59 Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services -Asheville 0.071J mg/L 0.10 0.060 1 07/14/23 23:34 24959-67-9 1.2 mg/L 1.0 0.60 1 07/14/23 23:34 16887-00-6 ND mg/L 0.10 0.050 1 07/14/23 23:34 16984-48-8 0.71J mg/L 1.0 0.50 1 07/14/23 23:34 14808-79-8 Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services -Asheville 5.6 mg/L 0.10 0.031 1 07/26/2311:54 7664-41-7 Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993 Pace Analytical Services - Asheville 5.8 mg/L 0.50 0.25 1 07/25/23 17:22 07/26/23 03:19 7727-37-9 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. H3 Page 7 of 26 Pace Analytical Services, LLC 2225 Riverside Dr. Yace, 1 Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: MONITORING WELLS Pace Project No.: 92677108 Sample: MW-4 Lab ID: 92677108003 Collected: 07/12/23 13:10 Received: 07/12/23 17:40 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by Pace 1 07/27/23 15:40 Collected By Ryan 1 07/27/23 15:40 Byas Collected Date 7/12123 1 07/27/23 15:40 Collected Time 13:10 1 07/27/23 15:40 pH 5.0 Std. Units 1 07/27/23 15:40 Temperature 23.6 deg C 1 07/27/23 15:40 Static Water Level 20.55 feet 1 07/27/23 15:40 Specific Conductance 63.7 umhos/cm 1 07/27/23 15:40 Oxygen, Dissolved .5 mg/L 1 07/27/23 15:40 7782-44-7 Total Well Depth 35.37 feet 1 07/27/23 15:40 Turbidity .1 NTU 1 07/27/23 15:40 Odor None 1 07/27/23 15:40 Appearance Clear 1 07/27/23 15:40 200.8 MET ICPMS Analytical Method: EPA 200.8 Rev 5.4 1994 Preparation Method: EPA 200.8 Rev 5.4 1994 Pace Analytical Services -Asheville Barium Boron Cadmium Cobalt Iron Manganese 4500H+ pH, Electrometric pH at 25 Degrees C 300.0 IC Anions 28 Days Bromide Chloride Fluoride Sulfate 350.1 Ammonia Nitrogen, Ammonia 351.2 Total Kjeldahl Nitrogen Nitrogen, Kjeldahl, Total Date: 07/27/2023 03:56 PM 115 ug/L 1.0 0.21 1 07/22/23 11:38 07/25/23 05:09 7440-39-3 ND ug/L 50.0 8.5 1 07/22/23 11:38 07/25/23 05:09 744042-8 0.181 ug/L 0.20 0.060 1 07/22/23 11:38 07/25/23 05:09 744043-9 3.0 ug/L 1.0 0.050 1 07/22/23 11:38 07/25/23 05:09 7440484 31.3J ug/L 50.0 20.9 1 07/22/23 11:38 07/25/23 05:09 7439-89-6 124 ug/L 2.0 1.0 1 07/22/23 11:38 07/25/23 05:09 7439-96-5 Analytical Method: SM 4500-H+B-2011 Pace Analytical Services -Asheville 5.4 Std. Units 0.10 0.10 1 Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services -Asheville 0.20 mg/L 0.10 0.060 1 2.2 mg/L 1.0 0.60 1 ND mg/L 0.10 0.050 1 ND mg/L 1.0 0.50 1 Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services -Asheville ND mg/L 0.10 0.031 1 07/20/23 14:03 07/15/23 00:36 24959-67-9 07/15/23 00:36 16887-00-6 07/15/23 00:36 16984-48-8 07/15/23 00:36 14808-79-8 07/26/2311:58 7664-41-7 Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993 Pace Analytical Services -Asheville ND mg/L 0.50 0.25 1 07/25/23 17:22 07/26/23 03:23 7727-37-9 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. H3 Page 9 of 26 Pace Analytical Services, LLC 2225 Riverside Dr. yj ce, ' Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: MONITORING WELLS Pace Project No.: 92677108 Sample: MW-4 Lab ID: 92677108003 Collected: 07/12/23 13:10 Received: 07/12/23 17:40 Matrix: Water Parameters 353.2 Nitrogen, NO2/NO3 unpres Nitrogen, Nitrate Nitrogen, Nitrite SM4500P-E, Phosphate, Ortho Orthophosphate as P Date: 07/27/2023 03:56 PM Results Units PQL MDL DF Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services -Asheville 3.3 mg/L 0.040 0.010 1 ND mg/L 0.040 0.031 1 Analytical Method: SM 4500-P E-2011 Pace Analytical Services -Asheville ND mg/L 0.050 0.012 1 Prepared Analyzed CAS No. Qual REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 07/14/23 01:05 14797-55-8 07/14/23 01:05 14797-65-0 07/14/23 04:15 Page 10 of 26 Pace Analytical Services, LLC 2225 Riverside Dr. aces w Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: MONITORING WELLS Pace Project No.: 92677108 Sample: MW-1R Lab ID: 92677108004 Collected: 07/12/23 15:20 Received: 07/12/23 17:40 Matrix: Water Parameters Monitoring Well Data Performed by Collected By Collected Date Collected Time pH Temperature Static Water Level Specific Conductance Oxygen, Dissolved Total Well Depth Turbidity Odor Appearance 200.8 MET ICPMS Barium Boron Cadmium Cobalt Iron Manganese 4500H+ pH, Electrometric pH at 25 Degrees C 300.0 IC Anions 28 Days Bromide Chloride Fluoride Sulfate 350.1 Ammonia Nitrogen, Ammonia 351.2 Total Kjeldahl Nitrogen Nitrogen, Kjeldahl, Total Date: 07/27/2023 03:56 PM Results Units PQL MDL DF Prepared Analytical Method: Pace Analytical Services - Charlotte Pace 1 Ryan 1 Byas 7/12/23 1 15:20 1 5.9 Std. Units 1 31.4 deg C 1 26.94 feet 1 62.62 umhos/cm 1 5.3 mg/L 1 62.62 feet 1 8.9 NTU 1 None 1 Clear 1 Analyzed CAS No. Qual 07/27/23 15:51 07/27/23 15:51 07/27/23 15:51 07/27/23 15:51 07/27/23 15:51 07/27/23 15:51 07/27/23 15:51 07/27/23 15:51 07/27/23 15:51 7782-44-7 07/27/23 15:51 07/27/23 15:51 07/27/23 15:51 07/27/23 15:51 Analytical Method: EPA 200.8 Rev 5.4 1994 Preparation Method: EPA 200.8 Rev 5.4 1994 Pace Analytical Services -Asheville 33.4 ug/L 1.0 0.21 1 07/22/23 11:38 07/25/23 05:14 7440-39-3 ND ug/L 50.0 8.5 1 07/22/23 11:38 07/25/23 05:14 7440-42-8 ND ug/L 0.20 0.060 1 07/22/23 11:38 07/25/23 05:14 7440-43-9 0.141 ug/L 1.0 0.050 1 07/22/23 11:38 07/25/23 05:14 7440-48-4 288 ug/L 50.0 20.9 1 07/22/23 11:38 07/25/23 05:14 7439-89-6 18.5 ug/L 2.0 1.0 1 07/22/23 11:38 07/25/23 05:14 7439-96-5 Analytical Method: SM 4500-H+B-2011 Pace Analytical Services -Asheville 6.2 Std. Units 0.10 0.10 1 Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services -Asheville ND mg/L 0.10 0.060 1 ND mg/L 1.0 0.60 1 ND mg/L 0.10 0.050 1 ND mg/L 1.0 0.50 1 Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services -Asheville ND mg/L 0.10 0.031 1 07/20/23 14:07 07/15/23 00:52 24959-67-9 07/15/23 00:52 16887-00-6 07/15/23 00:52 16984-48-8 07/15/23 00:52 14808-79-8 07/26/2312:03 7664-41-7 Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993 Pace Analytical Services -Asheville ND mg/L 0.50 0.25 1 07/25/23 17:22 07/26/23 03:26 7727-37-9 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. H3 Page 11 of 26 �ace Project: MONITORING WELLS Pace Project No.: 92677108 0 ANALYTICAL RESULTS Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Sample: MWAR Lab ID: 92677108004 Collected: 07/12/23 15:20 Received: 07/12/23 17:40 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services - Asheville Nitrogen, Nitrate 0.062 mg/L 0.040 0.010 1 07/14/23 01:08 14797-55-8 Nitrogen, Nitrite ND mg/L 0.040 0.031 1 07/14/23 01:08 14797-65-0 SM4500P-E, Phosphate, Ortho Analytical Method: SM 4500-P E-2011 Pace Analytical Services -Asheville Orthophosphate as P 0.018.11 mg/L 0.050 0.012 1 07/14/23 04:17 Date: 07/27/2023 03:56 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 12 of 26 Pace Analytical Services, LLC 2225 Riverside Dr. ' Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: MONITORING WELLS Pace Project No.: 92677108 QC Batch: 788276 Analysis Method: EPA 200.8 Rev 5.4 1994 QC Batch Method: EPA 200.8 Rev 5.4 1994 Analysis Description: 200.8 MET Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92677108001, 92677108002, 92677108003, 92677108004 METHOD BLANK: 4086502 Matrix: Water Associated Lab Samples: 92677108001, 92677108002, 92677108003, 92677108004 Blank Reporting Parameter Units Result Limit MDL Analyzed Barium ug/L ND 1.0 0.21 07/25/23 03:54 Boron ug/L ND 50.0 8.5 07/25/23 03:54 Cadmium ug/L ND 0.20 0.060 07/25/23 03:54 Cobalt ug/L ND 1.0 0.050 07/25/23 03:54 Iron ug/L ND 50.0 20.9 07/25/23 03:54 Manganese ug/L ND 2.0 1.0 07/25/23 03:54 LABORATORY CONTROL SAMPLE: 4086503 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Barium ug/L 50 51.8 104 85-115 Boron ug/L 50 50.6 101 85-115 Cadmium ug/L 50 52.3 105 85-115 Cobalt ug/L 50 53.5 107 85-115 Iron ug/L 1250 1350 108 85-115 Manganese ug/L 50 53.3 107 85-115 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4086504 MS 92676993002 Spike Parameter Units Result Conc. Barium ug/L 10.5 50 Boron ug/L 66.8 50 Cadmium ug/L ND 50 Cobalt ug/L ND 50 Iron ug/L 2700 1250 Manganese ug/L 197 50 Qualifiers Qualifiers 4086505 MSD Spike MS MSD MS MSD % Rec Max Conc. Result Result % Rec % Rec Limits RPD RPD Qual 50 62.0 63.0 103 105 70-130 2 20 50 116 113 97 92 70-130 3 20 50 50.7 51.2 101 102 70-130 1 20 50 52.5 52.7 104 104 70-130 0 20 1250 3940 3950 99 100 70-130 0 20 50 249 249 105 105 70-130 0 20 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4086506 4086507 MS MSD 92677318002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Barium ug/L 1.4 50 50 53.1 52.7 103 102 70-130 1 20 Boron ug/L ND 50 50 53.7 53.2 100 99 70-130 1 20 Cadmium ug/L ND 50 50 50.7 50.8 101 102 70-130 0 20 Cobalt ug/L ND 50 50 52.9 52.6 106 105 70-130 1 20 Results presented on this page are In the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/27/2023 03:56 PM without the written consent of Pace Analytical Services, LLC. Page 13 of 26 QUALITY CONTROL DATA Project: MONITORING WELLS Pace Project No.: 92677108 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4086506 4086507 MS MSD 92677318002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qua[ Iron ug/L ND 1250 1250 1400 1390 108 107 70-130 1 20 Manganese ug/L 5.4 50 50 58.4 57.7 106 105 70-130 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/27/2023 03:56 PM without the written consent of Pace Analytical Services, LLC. Page 14 of 26 4 V QUALITY CONTROL DATA Project: MONITORING WELLS Pace Project No.: 92677108 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QC Batch: 786751 Analysis Method: EPA 300.0 Rev 2.1 1993 QC Batch Method: EPA 300.0 Rev 2.1 1993 Analysis Description: 300.0 IC Anions Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92677108001, 92677108002, 92677108003, 92677108004 METHOD BLANK: 4079032 Matrix: Water Associated Lab Samples: 92677108001, 92677108002, 92677108003, 92677108004 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Bromide mg/L ND 0.10 0.060 07/14/2316:37 Chloride mg/L ND 1.0 0.60 07/14/2316:37 Fluoride mg/L ND 0.10 0.050 07/14/2316:37 Sulfate mg/L ND 1.0 0.50 07/14/2316:37 LABORATORY CONTROL SAMPLE: 4079033 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Bromide mg/L 2.5 2.5 100 90-110 Chloride mg/L 50 50.7 101 90-110 Fluoride mg/L 2.5 2.5 100 90-110 Sulfate mg/L 50 49.9 100 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4079034 4079035 MS MSD 92677218001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Bromide mg/L ND 2.5 2.5 2.5 2.6 102 103 90-110 1 10 Chloride mg/L 5.0 50 50 56.3 56.9 103 104 90-110 1 10 Fluoride mg/L 0.11 2.5 2.5 2.6 2.6 98 100 90-110 2 10 Sulfate mg/L ND 50 50 51.0 51.7 100 102 90-110 1 10 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4079036 4079037 MS MSD 92676944002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Bromide mg/L 0.53 2.5 2.5 3.2 3.2 108 106 90-110 2 10 Chloride mg/L 162 50 50 216 215 108 106 90-110 0 10 Fluoride mg/L ND 2.5 2.5 ND ND 0 0 90-110 10 M1 Sulfate mg/L 35.1 50 50 79.7 79.6 89 89 90-110 0 10 M1 Results presented on this page are In the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 07/27/2023 03:56 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 16 of 26 �� cem Pace Analytical Services, LLC 2225 Riverside Dr. ' r Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: MONITORING WELLS Pace Project No.: 92677108 QC Batch: 788937 Analysis Method: EPA 350.1 Rev 2.0 1993 QC Batch Method: EPA 350.1 Rev 2.0 1993 Analysis Description: 350.1 Ammonia Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92677108001 METHOD BLANK: 4089440 Matrix: Water Associated Lab Samples: 92677108001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Nitrogen, Ammonia mg/L ND 0.10 0.031 07/26/23 08:36 LABORATORY CONTROL SAMPLE: 4089441 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Ammonia mg/L 5 5.2 104 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4089442 4089443 MS MSD 92677977001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Ammonia mg/L 1.2 5 5 6.3 6.3 102 102 90-110 0 10 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4089444 4089445 MS MSD 92677978001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qua[ Nitrogen, Ammonia mg/L 14.9 5 5 19.9 20.1 101 105 90-110 1 10 Results presented on this page are In the units indicated by the "Units" column except where an attemate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/27/2023 03:56 PM without the written consent of Pace Analytical Services, LLC. Page 17 of 26 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: MONITORING WELLS Pace Project No.: 92677108 QC Batch: 789259 Analysis Method: EPA 350.1 Rev 2.0 1993 QC Batch Method: EPA 350.1 Rev 2.0 1993 Analysis Description: 350.1 Ammonia Laboratory: Pace Analytical Services - Asheville Associated Lab Samples: 92677108002, 92677108003, 92677108004 METHOD BLANK: 4090787 Matrix: Water Associated Lab Samples: 92677108002, 92677108003, 92677108004 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Nitrogen, Ammonia mg/L ND 0.10 0.031 07/26/23 11:51 LABORATORY CONTROL SAMPLE: 4090788 Spike LCS LCS % Rec Parameter Units Cone. Result % Rec Limits Qualifiers Nitrogen, Ammonia mg/L 5 5.1 102 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4090789 4090790 MS MSD 92677108002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Ammonia mg/L 5.6 5 5 10.4 10.4 96 96 90-110 0 10 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4090791 4090792 MS MSD 92677108003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Ammonia mg/L ND 5 5 5.2 5.1 103 102 90-110 1 10 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/27/2023 03:56 PM without the written consent of Pace Analytical Services, LLC. Page 18 of 26 Pace Analytical Services, LLC Yace" 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: MONITORING WELLS Pace Project No.: 92677108 QC Batch: 789051 Analysis Method: EPA 351.2 Rev 2.0 1993 QC Batch Method: EPA 351.2 Rev 2.0 1993 Analysis Description: 351.2 TKN Laboratory: Pace Analytical Services - Asheville Associated Lab Samples: 92677108001, 92677108002, 92677108003, 92677108004 METHOD BLANK: 4089877 Matrix: Water Associated Lab Samples: 92677108001, 92677108002, 92677108003, 92677108004 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Nitrogen, Kjeldahl, Total mg/L ND 0.50 0.25 07/26/23 03:16 LABORATORY CONTROL SAMPLE: 4089878 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Kjeldahl, Total mg/L 10 9.9 99 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4089879 4089880 MS MSD 92677108003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Kjeldahl, Total mg/L ND 10 10 10.2 10 100 98 90-110 3 10 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4089881 4089882 MS MSD 92677108004 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qua] Nitrogen, Kjeldahl, Total mg/L ND 10 10 9.8 10.0 98 100 90-110 2 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/27/2023 03:56 PM without the written consent of Pace Analytical Services, LLC. Page 19 of 26 Pace Analytical Services, LLC ace( � 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: MONITORING WELLS Pace Project No.: 92677108 QC Batch: 786706 Analysis Method: EPA 353.2 Rev 2.0 1993 QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite, Unpres. Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92677108001, 92677108002, 92677108003, 92677108004 METHOD BLANK: 4078943 Matrix: Water Associated Lab Samples: 92677108001, 92677108002, 92677108003, 92677108004 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Nitrogen, Nitrate mg/L ND 0.040 0.010 07/14/23 00:42 Nitrogen, Nitrite mg/L ND 0.040 0.031 07/14/23 00:42 LABORATORY CONTROL SAMPLE: 4078944 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Nitrate mg/L 1.5 1.5 99 90-110 Nitrogen, Nitrite mg/L 1 0.97 97 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4078945 4078946 MS MSD 92677079001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Nitrate mg/L 0.064 1.5 1.5 1.5 1.5 94 98 90-110 3 10 Nitrogen, Nitrite mg/L 0.055 1 1 1.0 1.0 97 99 90-110 2 10 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4078947 4078948 MS MSD 92677108002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Nitrate mg/L 0.027J 1.5 1.5 1.2 1.2 78 80 90-110 2 10 Nitrogen, Nitrite mg/L ND 1 1 0.87 0.89 84 86 90-110 2 10 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/27/2023 03:56 PM without the written consent of Pace Analytical Services, LLC. Page 20 of 26 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 2880404 (828)254-7176 QUALITY CONTROL DATA Project: MONITORING WELLS Pace Project No.: 92677108 QC Batch: 786714 Analysis Method: SM 4500-P E-2011 QC Batch Method: SM 4500-P E-2011 Analysis Description: SM450OP-E Phosphorus, Ortho Laboratory: Pace Analytical Services - Asheville Associated Lab Samples: 92677108001, 92677108002, 92677108003, 92677108004 METHOD BLANK: 4078963 Matrix: Water Associated Lab Samples: 92677108001, 92677108002, 92677108003, 92677108004 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Orthophosphate as P mg/L ND 0.050 0.012 07/14/23 04:10 LABORATORY CONTROL SAMPLE: 4078964 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Orthophosphate as P mg/L 0.25 0.25 99 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4078965 4078966 MS MSD 92677148001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Orthophosphate as P mg/L ND 0.25 0.25 0.27 0.29 98 102 90-110 4 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/27/2023 03:56 PM without the written consent of Pace Analytical Services, LLC. Page 21 of 26 Pace Analytical Services, LLC 2225 Riverside Dr. ace Asheville, NC 28804 (828)254-7176 QUALIFIERS Project: MONITORING WELLS Pace Project No.: 92677108 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as 'Total' may vary slightly from the sum of the reported component parameters. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. ANALYTE QUALIFIERS E Analyte concentration exceeded the calibration range. The reported result is estimated. H3 Sample was received or analysis requested beyond the recognized method holding time. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/27/2023 03:56 PM without the written consent of Pace Analytical Services, LLC. Page 22 of 26 Pace Analytical Services, LLC Yace , r 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: MONITORING WELLS 92677108 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92677108001 MW-3 92677108002 MW-2 92677108003 MW-4 92677108004 MW-1R 92677108001 MW-3 EPA 200.8 Rev 5.4 1994 788276 EPA 200.8 Rev 5.4 1994 788606 92677108002 MW-2 EPA 200.8 Rev 5.4 1994 788276 EPA 200.8 Rev 5.4 1994 788606 92677108003 MW-4 EPA 200.8 Rev 5.4 1994 788276 EPA 200.8 Rev 5.4 1994 788606 92677108004 MW-1 R EPA 200.8 Rev 5.4 1994 788276 EPA 200.8 Rev 5.4 1994 788606 92677108001 MW-3 SM 4500-H+B-2011 788076 92677108002 MW-2 SM 4500-H+B-2011 788076 92677108003 MW-4 SM 4500-H+B-2011 788076 92677108004 MW-1R SM4500-H+B-2011 788076 92677108001 MW-3 EPA 300.0 Rev 2.1 1993 786751 92677108002 MW-2 EPA 300.0 Rev 2.1 1993 786751 92677108003 MW-4 EPA 300.0 Rev 2.1 1993 786751 92677108004 MWAR EPA 300.0 Rev 2.1 1993 786751 92677108001 MW-3 EPA 350.1 Rev 2.0 1993 788937 92677108002 MW-2 EPA 350.1 Rev 2.0 1993 789259 92677108003 MW-4 EPA 350.1 Rev 2.0 1993 789259 92677108004 MW-1R EPA 350.1 Rev 2.0 1993 789259 92677108001 MW-3 EPA 351.2 Rev 2.0 1993 789051 EPA 351.2 Rev 2.0 1993 789226 92677108002 MW-2 EPA 351.2 Rev 2.0 1993 789051 EPA 351.2 Rev 2.0 1993 789226 92677108003 MW-4 EPA 351.2 Rev 2.0 1993 789051 EPA 351.2 Rev 2.0 1993 789226 92677108004 MWAR EPA 351.2 Rev 2.0 1993 789051 EPA 351.2 Rev 2.0 1993 789226 92677108001 MW-3 EPA 353.2 Rev 2.0 1993 786706 92677108002 MW-2 EPA 353.2 Rev 2.0 1993 786706 92677108003 MW-4 EPA 353.2 Rev 2.0 1993 786706 92677108004 MW-1 R EPA 353.2 Rev 2.0 1993 786706 92677108001 MW-3 SM 4500-P E-2011 786714 92677108002 MW-2 SM 4500-P E-2011 786714 92677108003 MW-4 SM 4500-P E-2011 786714 92677108004 MW-1 R SM 4500-P E-2011 786714 Date: 07/27/2023 03:56 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full; without the written consent of Pace Analytical Services, LLC. Page 23 of 26 -I UOU Effective Date: 11/14/2022 Laboratory receiving samples: Asheville ❑ Eden[-] Greenwood ❑ Huntersville❑ Raleigh[] Mechanicsville❑ Atlanta[] Kernersville❑ Sample Client Name: I ConditionUpon Receipt WO#:92677108 / � , f=��l' ; � Project q: Courier: ❑�dCeHIM Ex❑UP5 Other: ❑ClientCommercial 1111111111111111 ❑ 92677108 Custody Seal Present? ❑Yes ❑JNo Seals intact? Dyes [ No Packing Material: ❑Bubble Wrap ❑Bubble Bags lone ❑ Other Thermometer: ❑ IR Gun 10: Type of Ice: Gwet ❑Blue ^ Correction Factor: r Cooler Temp: Add/Subtract ('C) L r-� Cooler Temp Corrected ('CK �— USDA Regulated Soil ( ffN/A, water sample) Did samples originate in a quarantine zone within the United States: CA. NY. or SC Date/Initials Person Examining Contents: Biological Tissue ozen? []Yes(:]No[/A ❑Pone Temp should be above freezing to 6'C []Samples out of temp criteria. Samples on ice, cooling process has begun Did umnlne nrioimro rrnm a F—ion ...,,.re ❑..r...,.er..... emu.. [check maps)? ❑Yes ❑No including Hawaii and Puerto Rico)') [:]Yes.. ❑No Comments/Discrepancy: Chain of CustodyPresent? (�Ycs. ❑No ❑N/A 1. Samples Arrived within Hold Time? es ❑No ❑N/A 2. Short Hold Time Analysis (<72 hr.)? Dyes QNq ❑N/A 3. Rush Turn Around Time Requested? Dyes No []N/A 4. Sufficient Volume? dyes ❑No ❑N/A 5. Correct Containers Used? Pace Containers Used? fes OYks ❑No ❑No ❑N/A ❑N/A 6. Containers Intact? dyes ❑No ❑N A 7. Dissolved analysis: Samples Field Filtered? ❑Y_es ❑No [ 4/A 8. Sample Labels Match COC? Includes Date/Time/ID/Analysis Matrix: dyes ❑No ❑N/A 9. Headspace in VOA Vials (>5.6mm)? Des ❑No N/A 10. Trip Blank Present? Trip Blank Custody Seals Present? ❑Yes Dyes EINo [�No ❑N/A ❑N/A 11. COMMENTS/SAMPLE DISCREPANCY CLIENT NOTIFICATION/RESOLUTION Person contacted: Lot ID of split containers: Date/Time. Project Manager SCURF Review: Date: Project Manager SRF Review: Date: Field Data Required? Dyes (-]No Qualtrax ID: 69614 Page 1 of 2 Page 24 of 26 -f auc; Effective Date: 11/14/2022 `Check mark top half of box if pH and/or dechlorjnation is verified and project I wO# ' 92677108 within the acceptance range for preservation samples. FM: JWB Due Dale: 07/27/23 Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/80LS (water) DOC, LLHS ••Bottom half of box is to list number of bottles CLIENT: 93—MARION 'Check all unpreserved Nitrates for chlorine M 'O N W a Z L v N V _ N! V ff O A Z as tj ti n v, a C •� ? V �_ Q Y N N V = V a a Q Z ? Z x X q a 7 a ;zz m u ? '4 d c lJ d C V a Q. V ai n ON N S z = = Q 2 N u O ra Z l3 a Z N a ] S n = C O v O r = y ON 2 a Zz V z w = O Vr z y C t ? O rL m Q C A d > z 2 a d z 2Z a ,n = C C G Ct C M it ca J vEi ry a J o ,, rV J E o m d = a J E e4 J E tn E �' a E ,n e4 E o 3 'c Q y '+ E Q m = .•! ¢ J E o Ln E Q _ — < J E o !n E Q J E O O > E O ap > J E O O > O O > J E O o 1 J E p m O. '^ m V7 J E 'n d Vl J E O _n a J E O E a C C O c 4A J E E Q J E — > m > m > ca m > d ra N 0. m Z 0. m N a m Ch 0. am LL 3 (7 a S l9 a M 0 a H a N M W a O in b o S l7 o J: CM 69 > in l9 > > M O o d a. > `n 0. N IL m a'o O a t9 > of o 1 i — 71 3 t„ 4 V� V — S 6 NF- 7 8 i 9 10 11 12 pH Adjustment Log for Preserved Samples Sample ID Type of Preservative pH upon receipt Date preservation adjusted Time preservation Amount of Preservative adjusted added Note: WhPnovar thorn .c - c-- .. .., Ott ..._ Lot R -• -------o ---• ..,.,,o a .... y.o, a wpy u, trns roan Will oe sent to the north Carolina DENR Certification Office (,.e- Out of hold, incorrect preservative, out of temp, incorrect containers. Quallrax ID: 69614 Page 2 of 2 Page 25 of 26 CHAIN-OF-CUSTODY / Analytical Request Document • •+� I ne I,,nam-or-uustoay is a LtUAL ucx;uMtN 1. All relevant fields must be completed accurately. I Submitting a sample via this chain of custody constitutes acknowledgment and acceptance of the Pace Terms and Conditions found at https:/Iinfb.pacelabs.com/hubfs/pas-star)dard-terms.pdf. Section A Section B Section C Required Client Information: Required Project Information: Invoice information: Page1 t Company: City of Manion Report To: Tim Horton Attention: Address: 3982 NC 226 South Copy To: Company Name: Manon, NC 28752 Address: Email: thorton@manonne-or Purchase Order* Pace Quote: Phone: (828)803-5736 Fax Project Name: Monitoring Wells Pace Project Manager: onalhan.biddix acelabs.com, Requested Due Date: Project #: Pace Profile #: 13150-1 NC MATRIX cope ° COLLECTED z Preservatives or nwino Wafer DW o U O Water WT [r� Ws4r Ylatsr Ww Prco�f P J Z SoivsofW SL SAMPLE ID m ++ a oa oL v �_ START END m m One Character per box. wfpe WP M fu a z '¢ m Z F + o tA•Z, 0-91, -) M p a w m n o I Sample Ids must be uniqueTsX w o ro v O U v tr < Q O C N Z U 0R W N L O E O N DATE TIME DATE TIME w_ _ = Z Z 2 O cv cn Y'1 M O 2 a to w-� T ✓'r rnur3 I(Z7 X X X K I 'A M w- Z Iva c yIx Ix I X x Mom- 1R ►Sto b LA F i i I 7 7 t i PRINT Narlle d SAMPLER: R c � b A Ai SIGNATURE of SAMPLER: Q DATE Si ned: / / 9 7!2 Z IL o z met', o� " A >�,�� n y,� as u ... . �'eartnfytlCal � 1o�eo130i :.1d dii+eE . t7bcuiaieril Nttmtb�m t• ►R-Ft I� QQE v 03. _ S.Authwi r Pace fismtef$Vi. j 1(KY Ottiee Bg: PUMP S A.. ;rujy:la*q Purge Infortnaatlon. Date Purged:,, ��l . r�Z ..:_ �'i katt : I 1 JA PurgingMetfkG.4; M�eov tee,, oon Totial: of me Purged-, 1�SoO: (gallons niis/ Sampl9:ng,Lgfo6H Rape Collec6edi 7 f 1 Z Time Couddid i iZ0 PM-). Sampling F.cltxlpmetlt Used:1d+.. j%aA con Instrument ID:_ Bottle Type Preservation nalysis ti .. yNZit'1 'R+8 Y2SoMl 1'b1#:G RKQ3 1 Z0007.. 50-1 f t.L.. +/T i Ifs .rI&S t;c 1.12 504 k N KA Pe25 ;oo.o,353.Z. f d Field 14leasurementaXObservations Sam .le Tem .. ; :.. 2 (v. Tlmc 1 ! 2 ...... Turbitii.. tub:: r1, Time: 117. DiS& oxy oxig/ ..) . 3 `T Qie: i?e.2+ mg/L: — Time: Specific .Cond. ("uS):. t i y A Time:. Res. d:(bi8/L)/(µ9/i ): 7 Tirtte: ✓ Sample H B,u. S•� Time: P P ?� Odor: N a N Q c - Time: . ReDax (MVO '— 'l hr Appearance; Tiirie: ReDox (EH value),YSI ProPlus-+200 V `— Other. -- / (sunng/eloudy/rainy) Temp, $ L_(`T). Wind o, S (mph) Sampler Signature: cyan Q-;h Date:__ 7/r2/23 Stabilization Test Time Temp. i�isa Oxy Spee. Cond. pH (&tL)-. ReDox. Turbidity, Volume removed Water Other .Purged' (Oq (mg/L) fug (mV) ON. (Pilo. m16 level (ft) . OvLi. 10.3 V7 63 Soo ; t! 5-0 lid 059 5 ZIA 3.4 126& s.c --. S. o 0 ("45 1Z1. b 51.5 2 SO O 905 zi�o 3, 114 .1 — 144.5 1 35OZ acm 2D19. eAn#y..b Da Meld' ta9heet , par In�dient IVuoobeS; : Issueinj... . F- �1R..FLD.O©1.[eud3: Pace HijntersMe Office IVell DismQte. r. Multi lfaation Factor* Clioi►t: _ C; 4Y of MAC; o n 1.0.0408 00tion: _�n aF; o n ,nt C 1.2 1.65 Project, j, , d y O F s ,% z O 13 z Q.F7 3 0.3670 4 0.6530 �teviewed: Date-ar44 By: off-11314 %3: &-z 8 1.46$0 $4�,bilixatian test° . ,. tme. Purged TOMp. o : E c) QissOxy; n/�-) s� �..:: aranid, :' ;. : pW.:). :.ReDo) 41nV.: Turbidity .. voltmeRemoved (gail'oi :.....: .} W terleueP �t,tu� A'rclE o e It L - S�� SS,464. i0 00 i� Up .o : 3.:. 113.7 ............. Sao ................. ►o5 z7o It t _.._ 8 Soo... S qQ x ov eataEyrtaa� tt rroo+teki dtntn lac Date saucde.gi.2b 1 .: ; . - wF.rwi becumeat Numbul IK. M Ft.�Upl�av 06.. . 1 Ah Ay�it�eiol�:I'aceHunte�w4de' A.:.'. Beni:, [�;'F7 iaP /ti+.:a., Loeadan:►•.r����NC >?©jet*t.#::Cty.oF�.•:rn. sA saty 2az3 3ampiut�on ......... . Dake-��i�lec�� � .C.>�.�-� �eCo,�erted: ,� �:1 � a�►�� . { Sampling,8quipmentUsed: .f 144 f Affi Imtrument11be t Bottle Type 1' eservation AnalYais Re aired QB 714/ 3 LL .. 2150^1 tip4t.[., HNC Mc+*.14 zoo Pq I I6mye tK/.F; r+!! S o 2.Sn1 .4b�tt'( HSAO� . I4rnrwnio... Tku 3.2S.o�►t g�•-SF.�C: Uln4�[5 3O•0, 353- .,gN itSOONt .Field MeasurementsfObservar�ns: . Santplt Temp..(Pc): 7-4. b Timer T4rbMi:W (Mtu); 2 1"i Time: 21 J DWc0xy:(M&/I .): 0-8 TTime: Fe 2+ ma Time: Specii`ic Cbad. (:uS): 3 So. 2 Time+, Sample �3 (s.u4� b • .N Thne: , Odo'r: 5utcu,f "rime: 121� ReDox (OV)t r— Time, T�' pearance: G Z 1 Acp - to r one RODOX (EH value):YSI FroPlus.+200mV � Othec �^ Tim GeneraVWeather Observation's•: { / oudy/rainy} �'emp. (°l W ind: S-1 � m Bunn ( ph) Sampler Signature Ry . A lkY ae�i Pate: -7f il-1 Z3 Stabilization Test Time Purged 'hemp. {° Dw Oxy. {ml Spec. Cond. (uS) pH (s.c�.): ReDox (m Tuzbidily (nfu� q ume removed (gaU:o nls L Water level (fit):. . Other . 1 t S 5 'L `J • o y S 04 • eA►wly/l/Cal ' LNxuvftnt'Nxn*: Field data Sheet Date Issued: Ivlamh 6, 2D19: page: I of i i Document Number FEAR-CARD 00t-rev:Q3 Issuing Authority: race Hunteraville Quatity Office Field Data. Sheet' G� Name and Affiliation (Sampler(s): ILA 8 Q- t e- ]name and Affiliation (Inspector): b hk Well Information Well. TD: Well Diameter - Total Well Depth: 353 7 ft Static Water Level: 20 S 5 ft Height of Water Column: ty ft WeII Locked: Construction:. I ld Data Sheet Review: Date. 0--1l3) 7-3 By: Steel) Multi Factor*: � � 63 [*(Radius/ 12)2 x 3.14 x 7.481 Casing Volume: gallons Cal. 3 Volumes: 7. 2 i gallons Pump Intake: - 3 ?)---it Purge Information Date Purged: 7 W/ L Z / Z3 Start: t �- Pictish. 3� 0 5 T'u rge Rate: S A To ly Xcl ) Purging Method 40r,S fi-tf C g 41 M f Total Volume Purged: Z000 (gallons/IQL) Sampling Information l Date Collected:_ 7 /1 Z / Z3 Time Collected: 131 O (am/ m) Sampling Equipment Used: ru-? instrumentlD:_YSZ Bottle Type Preservation Analysis Required LSo•�4 9ie-St+'t 7V A�. A�ati�it. U✓��;.I�t! (t5 r laS f't HNO3 N nt.tS �ZSoy KNereC MGf^41 206j __ Or'li.o pftiesDt.�C 300.4, 53.L; Pal yraoAt Field Measurements/Observations Sample Temp (°C): Z3. b Time: 13 I?_.^Turbidity (ntu): � � Time: l 7 N Diss Oxy (mg/L): . 5 Ti., Fe 2+ mg/L: Time Specific Cond. (uuS): Timer Res. a (mg/LY(µg/L):.- Time: Sample pH. (s.u.): 0 ---Time: Odor:._.. N 9,c a Tithe: 13 10 ReDox (mV)c Time: Appearance: G lea / Time: �- ReDox (EH value):YSl. ProPlus.+200m.V r Other: Time: --�� General/Weather Observations: wo,$ P! i n it: L k N e cod; n ci sunny loudy/rainy) Temp.14-_(M- Wind -10 (mph) Sampler Signature: Date:-_ 7/ 1 Z/2 _ Stabilization Test Time Purged Temp. o (C) Diss Oxy. (n g/L) Song` Cond. (US) pH (s.u.) ReDox (mV) Turbidity (ntu) Volume removed (gallons mis L Water level (ft) Other ►2Sa 2.3. 3 0-6 3 5.0 1 . 0 Soo ?A. - —0-0.1 - t2U u 5.0 ----- 0,6 tabu vZ, 2 S 1300 o.2 O's bj. S.p O 1 Soo Z2.a i o 2, 5 0.7 5.0 Zoo o 111.00 ~„ Ii�a►,��ra�J' r po�urAlitnti�teit�Piet� data Sheet Document tVwptaer: t?-��-0R2�riO3 Jasutng ALtfitorfw.PeceHLmteravllre�uality .axcaLa_ rratvr a evv ^es Height of titer Cglrimri> �S �Q� �aUill#� xulumC:: • - —. _.. �t1LUI16 CAI; � lfoltnsiesi %7_4 � ,FE , I'urs+e Iu#oraiatiaa . . - Date.Pu. rged: t :fit Z "� ..Start.• 1; Iri l oo ru S/x; % .. ... , .. 4: 5 ::._.iastF; (�5 Fu�Fpe_)Iatie: '1 purging Method:: f 4. 1 4�. L fit( Af Total Volume Purged: 1000 : fga�lons i') ocmatiQn. Date Collectedi. 7 '2 'S Time Colleeteii _ j,�•p dam Sampling Equipment Used: Instrument-)D. K I Lo 3 W / I f - boa LI Bottle Type Pteservation Analysis Required 50 2 f. �t� " 'H.1lO� Mf3t,oTt� LOo.7 SO At- ?rob f:cw/I*Ner 111n4�1•i. Or-flo oL.cSp►ot2 1Zy�nL' rtt.( r2304 Aeunow;o.� TKN 3:w �_12 PH %60 N+ .Field MeasurementatObservations Sample Tem p p (°C);. 3 l , � . Time;. 13 L� Turbidity (ntu}; -. Time: Diss Oxx (ing/L) y . 3Tim. Fe 2+ mgjL: -' 'Time; ` Specif Iccond. { us): �S' S Time. Res.-Cl (ehg I;)(g/L):: "' Tinne; Sample OR ReDox m :: • -- ...-- �. E ;• ....'Tlione` Appearanee;G � l Ti�►e:.......--..-�-....... . Rebox (19H value)-.YST ProPlu9.*200mV -� -- Other: General/Weather ObservaHona• �yudy/rafny) Temp,-j (M. Wind -1,0 (mph) Sampler Signature: Ryo- 8-4eAS Date: Stabilization Test Spey. Volume . Time Purged Temp. u (C) Dins Oxy: (mg/ L). Cond. pH (s.u.) Repox Turbidity (htu.) removed (gallo / Water . level (ft). Other ((US)(inY} . L : 3 S 4 103.0 5.5 W. q 5.1 17 - a- 2 27.7 i. 8 loon t o9 t,� 2i. dl � 1.2 SAa 1405 31, Z `�. — VIA loot/ plpctw. t;Nanlg; a ... f _ !ui�ett�t N'ttitii�er:: F 24R F[:b-0Ql teu:11 POL* HuntdnMI a QMHIY`Of ct . TiM o •