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HomeMy WebLinkAboutNC0048879_Fact Sheet_20231005Fact Sheet NPDES Permit No. NCO048879 Permit Writer/Email Contact Nick Coco, nick.coco@deq.nc.gov: Date: October 2, 2023 Division/Branch: NC Division of Water Resources/NPDES Municipal Permitting Fact Sheet Template: Version 09Jan2017 Permitting Action: ® Renewal ❑ Renewal with Expansion ❑ New Discharge ❑ Modification (Fact Sheet should be tailored to mod request) Note: A complete application should include the following: • For New Dischargers, EPA Form 2A or 2D requirements, Engineering Alternatives Analysis, Fee • For Existing Dischargers (POTW), EPA Form 2A, 3 effluent pollutant scans, 4 2nd species WET tests. • For Existing Dischargers (Non-POTW), EPA Form 2C with correct analytical requirements based on industry category. Complete applicable sections below. If not applicable, enter NA. 1. Basic Facility Information Facility Information Applicant/Facility Name: Town of Cary/North Cary Water Reclamation Facility (WRF) Applicant Address: P.O. Box 8005, Cary, NC 27512-8005 Facility Address: 1900 Old Reedy Creek Road, Cary, NC 27513 Permitted Flow: 12.0 MGD Facility Type/Waste: MAJOR Municipal; 99.88% domestic, 0.12% industrial* Facility Class: Grade IV Biological Water Pollution Control System Treatment Units: Mechanical screening, grit and grease removal, nutrient removal system, secondary clarifiers, sand filters, UV disinfection, cascade aeration, belt thickeners, aerated holding tanks Pretreatment Program (Y/N) Y; LTMP County: Wake Region Raleigh *Based off of permitted flows. Briefly describe the proposed permitting action and facility background: The Town of Cary has applied for an NPDES permit renewal at 12.0 MGD for the North Cary WWTP. This facility serves a population of approximately 89,400 residents in the Towns of Cary and Morrisville and RDU Airport, as well as 1 categorical industrial user (CIUs) via a Division -approved pretreatment program. Treated domestic and industrial wastewater is discharged into Crabtree Creek, a class B; NSW waterbody in the Neuse River Basin. Outfall 001 is approximately 26 miles upstream of waters designated as WS-V. In addition to the NPDES permit, the Town operates facilities for bulk and reclaimed water distribution in accordance with Non -Discharge Permit WQ0017923. Sludge disposal: Sludge is currently hauled to the South Cary WRF biosolids dryer producing Class A biosolids and a beneficial product for reuse as an agricultural fertilizer amendment. Page 1 of 14 Inflow and Infiltration (I/IZ In their application, the Town noted an estimated average daily I/I flow of 183,076 gpd. Large Diameter lining and rehabilitation projects are taking place. Manhole leaks are being sealed and the manholes are being rehabilitated with the application of corrosion -resistant mortar lining. The town has an extensive program focused on cleaning sewer lines and video recording the condition of lines. 2. Receiving Waterbody Information: Receiving Waterbody Information Outfalls/Receiving Stream(s): Outfall 001 - unnamed tributary (UT) to Crabtree Creek' Stream Segment: 27-33-(3.5) Stream Classification: B; NSW Drainage Area (mi2): 52.2 Summer 7Q10 (cfs) 0.3 Winter 7Q10 (cfs): 0.8 30Q2 (cfs): - Average Flow (cfs): Regulated' IWC (% effluent): 98.4 2022 303(d) listed/parameter: Yes, exceeding criteria for Benthos and PCB Fish Tissue Advisory (Advisory, FC, NC)2,3 Subject to TMDL/parameter: Yes- Statewide Mercury TMDL implementation. Basin/HUC: Neuse River/03020201 USGS Topo Quad: D23SE 'On October 28, 2021, the Raleigh Regional Office and EPA conducted a compliance inspection of the North Cary WRF. During the inspection, it was noted that the receiving stream is actually an unnamed tributary to Crabtree Creek (Outfall 001 is approximately 100 feet away from the main channel of Crabtree Creek). Based on this inspection, the receiving stream has been revised. 2Discharge point is located approximately 0.75 miles below the outlet of Lake Crabtree. 32022 Integrated Report notes inconclusive data for DO and turbidity. 3. Effluent Data Summary Effluent data for Outfall 001 is summarized below for the period of January 2019 through May 2023. Table 1. Effluent Data Summary Outfall 001 Permit Parameter Units Average Max Min Limit Flow MGD 6.2 11.65 4.61 MA 12.0 Monitor & Total Monthly Flow MG/month 189 216.85 164.5 Report WA 6.0 CBOD summer mg/1 2.0 4.84 < 2 MA 4.1 WA 12.3 CBOD winter mg/1 2.1 3.77 < 2 MA 8.2 WA 1.5 NH3N summer mg/1 0.12 1.01 0.06 MA 0.5 WA 3.0 NH3N winter mg/1 0.11 1.02 0.1 MA 1.0 Page 2 of 14 TSS mg/l 2.5 4 2.5 WA 45.0 MA 30.0 PH SU 7.4 7.7 6.9 6.0 > pH <9.0 (geometric) Fecal coliform #/100 ml (geomean) 113 < 1 WA 400 1.2 MA 200 DO mg/l 8.4 10 6.9 DA >5.0 Temperature ° C 21.4 27 14 Monitor & Report Monitor & NO2+NO3 mg/l 0.9 3.33 0.31 Report TKN mg/l 1.1 2.62 0.39 Monitor & Report TN mg/l 2 4.73 0.8 Monitor & Report TN Load lb/yr 37,887 43,757 33,920 143,246 TP mg/l 0.3 1.8 0.13 QA 2.0 Total Hardness mg/l 59 65.5 52.2 Monitor & Report MA -Monthly Average, WA -Weekly Average, DM -Daily Maximum, DA=Daily Average 4. Instream Data Summary Instream monitoring may be required in certain situations, for example: 1) to verify model predictions when model results for instream DO are within 1 mg/l of instream standard at full permitted flow; 2) to verify model predictions for outfall diffuser; 3) to provide data for future TMDL; 4) based on other instream concerns. Instream monitoring may be conducted by the Permittee, and there are also Monitoring Coalitions established in several basins that conduct instream sampling for the Permittee (in which case instream monitoring is waived in the permit as long as coalition membership is maintained). Is this facility a member of a Monitoring Coalition with waived instream monitoring (YIN): YES Name of Monitoring Coalition: Lower Neuse River Basin Association If applicable, summarize any instream data and what instream monitoring will be proposed for this permit action: The current permit requires instream monitoring for temperature, dissolved oxygen, pH, CBOD5, and NH3-N upstream at Old Reedy Creek Road and downstream at (D1) Ebenezer Church Road, (D2) between US I and Lassiter Mill Dam and (D3) New Hope Road. As the permittee is a member of the Lower Neuse River Basin Association (LNBA) instream monitoring requirements are provisionally waived. The nearest upstream monitoring station is Ambient Monitoring System (AMS) station J2850000, located just upstream of the outfall. The nearest downstream monitoring station is AMS station J3000000, located approximately 5.3 miles downstream of the outfall. AMS data was also available for fecal coliform, turbidity, conductivity, NO2+NO3, TKN, TP and TSS. Instream data from January 2018 through March 2020 has been summarized below in Table 2. Page 3 of 14 Table 2. Instream Monitoring Data Summary Parameter Units Upstream J2850000 Downstream J3000000 Average Max Min Average Max Min Temperature ° C 17.9 30.8 4.5 16.7 28 5.2 DO mg/1 8.0 13.86 1.6 8.6 13.39 5.31 Conductivity µmhos/cm 122.5 216.4 72.7 218.5 419 95.9 Hardness mg/1 33.25 38 25 42.9 57 29 Ammonia mg/1 - - - 0.06 0.14 0.02 NO2+NO3 mg/1 - - - 0.4 1.1 0.15 TKN mg/1 - - - 0.7 0.86 0.58 TP mg/1 - - - 0.1 0.2 0.06 pH s.u. 7.3 7.7 6.87 7.2 7.7 6.9 TSS mg/1 20 29 9 30.5 36 25 Fecal Coliform #/100ml (geomean) 85.7 850 6 (geomean) 144.4 1400 40 Turbidity NTUs 32.4 70 8.6 17.7 70 2.2 Students t-tests were run at a 95% confidence interval to analyze relationships between instream samples. A statistically significant difference is determined when the t-test p-value result is < 0.05. Downstream temperature was not greater than 32 degrees Celsius [per 15A NCAC 02B .0211 (18)] during the period reviewed. Downstream temperature was not greater than upstream temperature by more than 2.8 degrees Celsius during the period reviewed. It was concluded that no statistically significant difference exists between upstream and downstream temperature. Average downstream DO was above 5 mg/L [per 15A NCAC 02B .0211 (6)] during the period reviewed. Downstream DO was not observed at levels less than 4.0 mg/L during the period reviewed. It was concluded that no statistically significant difference exists between upstream and downstream DO. It was concluded that a statistically significant difference exists between upstream and downstream conductivity, with downstream conductivity generally being observed at levels higher than upstream conductivity. As such, instream conductivity monitoring has been added. Fecal coliform is not currently required in the permit. AMS fecal coliform data was reviewed, and it was concluded that no statistically significant difference exists between upstream and downstream fecal coliform. While downstream fecal coliform was observed at levels greater than 400/100mL on occasion, these observances occurred concurrently with elevated upstream fecal coliform levels greater than 400/100mL. However, as the receiving stream is Class B, in accordance with DWR guidance regarding instream fecal coliform monitoring, instream fecal coliform has been added to the permit. Ambient pH was observed within the range of 6.0 to 9.0 standard units at both monitoring stations during the period reviewed. It was concluded that no statistically significant difference exists between upstream and downstream pH. It was concluded that a statistically significant difference exists between upstream and downstream turbidity, with downstream turbidity generally being observed at levels lower than upstream turbidity. While downstream turbidity was observed at levels greater than 50 NTUs [per 15A NCAC 02B .0211 (21)] during the period reviewed on 1 occasion, this observance occurred concurrently with elevated upstream turbidity levels greater than 50 NTUs. Page 4 of 14 Insufficient downstream data points (2 samples) were available to conduct a statistical analysis for instream TSS. No upstream or downstream monitoring data was provided regarding CBOD5- While downstream monitoring data was provided regarding NH3-N, TKN, NO2+NO3, and TP, no data was provided by the upstream location. It is recommended that NH3-N, TKN, NO2+NO3, and TP be added to the suite of parameters monitored at AMS station J2850000. As the receiving stream is classified NSW and the North Cary WRF effluent is limited for Total Nitrogen and Total Phosphorous, instream monitoring for TKN, NO2+NO3, and TP have been added to the permit. Instream monitoring for NH3-N has been maintained. No instream data were available at either station for CBOD5. It is recommended that CBOD5 be added to AMS stations J2850000 and J3000000. 5. Compliance Summary Summarize the compliance record with permit effluent limits (past 5 years): The facility reported no limit violations from June 2018 through June 2023. Summarize the compliance record with aquatic toxicity test limits and any second species test results (past 5 years): The facility passed 18 of 18 quarterly chronic toxicity tests, as well as all 4 second species chronic toxicity tests from January 2019 to May 2023. Summarize the results from the most recent compliance inspection: The last facility inspection conducted in June 2023 reported that the facility was compliant. 6. Water Quality -Based Effluent Limitations (WQBELs) Dilution and MixingZones ones In accordance with 15A NCAC 2B.0206, the following streamflows are used for dilution considerations for development of WQBELs: 1Q10 streamflow (acute Aquatic Life); 7Q10 streamflow (chronic Aquatic Life; non -carcinogen HH); 30Q2 streamflow (aesthetics); annual average flow (carcinogen, HH). If applicable, describe any other dilution factors considered (e.g., based on CORMLY model results): NA If applicable, describe any mixing zones established in accordance with 15A NCAC 2B.0204(b): NA Oxygen -Consuming Waste Limitations Limitations for oxygen -consuming waste (e.g., BOD) are generally based on water quality modeling to ensure protection of the instream dissolved oxygen (DO) water quality standard. Secondary TBEL limits (e.g., BOD= 30 mg/1 for Municipals) may be appropriate if deemed more stringent based on dilution and model results. Ifpermit limits are more stringent than TBELs, describe how limits were developed: Limitations for summer and winter CBOD5 are based on a 1991 intensive modeling analysis (Qual2E) performed by HDR and reviewed and accepted by the Division with the September 12, 1994 Wasteload Allocation (WLA). No changes are proposed. Ammonia and Total Residual Chlorine Limitations Limitations for ammonia are based on protection of aquatic life utilizing an ammonia chronic criterion of 1.0 mg/1 (summer) and 1.8 mg/1(winter). Acute ammonia limits are derived from chronic criteria, utilizing a multiplication factor of 3 for Municipals and a multiplication factor of 5 for Non -Municipals. Page 5 of 14 Limitations for Total Residual Chlorine (TRC) are based on the NC water quality standard for protection of aquatic life (17 ug/1) and capped at 28 ug/l (acute impacts). Due to analytical issues, all TRC values reported below 50 ug/l are considered compliant with their permit limit. Describe any proposed changes to ammonia and/or TRC limits for this permit renewal: The permit does not currently set limits or monitoring requirements for TRC due to the facility employing UV treatment for disinfection. However, in the event of an emergency where chlorination is required as a backup or temporary means of disinfection at the facility, a TRC limit and monitoring requirement have been added to the permit based on the review in the attached WLA spreadsheet. Please note that TRC monitoring is only required in the event that chlorine is used at the plant and as part of the regular Effluent Pollutant Scans. Limitations for summer and winter ammonia are based on a 1991 intensive modeling analysis (Qual2E) performed by HDR and reviewed and accepted by the Division with the September 12, 1994 WLA and a best professional judgement (BPJ) ammonia agreement with the Town. The ammonia limits have been reviewed in the attached WLA for toxicity and have been found to be protective. No changes are proposed. Reasonable Potential Analysis (RPA) for Toxicants If applicable, conduct RPA analysis and complete information below. The need for toxicant limits is based upon a demonstration of reasonable potential to exceed water quality standards, a statistical evaluation that is conducted during every permit renewal utilizing the most recent effluent data for each outfall. The RPA is conducted in accordance with 40 CFR 122.44 (d) (i). The NC RPA procedure utilizes the following: 1) 95% Confidence Level/95% Probability; 2) assumption of zero background; 3) use of/z detection limit for "less than" values; and 4) streamflows used for dilution consideration based on 15A NCAC 2B.0206. Effective April 6, 2016, NC began implementation of dissolved metals criteria in the RPA process in accordance with guidance titled NPDES Implementation of Instream Dissolved Metals Standards, dated June 10, 2016. A reasonable potential analysis was conducted on effluent toxicant data collected between January 2019 and March 2023. Pollutants of concern included toxicants with positive detections and associated water quality standards/criteria. Based on this analysis, the following permitting actions are proposed for this permit: • Effluent Limit with Monitoring. The following parameters will receive a water quality -based effluent limit (WQBEL) since they demonstrated a reasonable potential to exceed applicable water quality standards/criteria: None • Monitoring. Only. nly. The following parameters will receive a monitor -only requirement since they did not demonstrate reasonable potential to exceed applicable water quality standards/criteria, but the maximum predicted concentration was >50% of the allowable concentration: None • No Limit or Monitoring: The following parameters will not receive a limit or monitoring, since they did not demonstrate reasonable potential to exceed applicable water quality standards/criteria and the maximum predicted concentration was <50% of the allowable concentration: Total Arsenic, Total Cadmium, Total Chromium, Total Copper, Total Cyanide, Total Lead, Total Molybdenum, Total Nickel, Total Selenium, Total Silver, Total Zinc • POTW Effluent Pollutant Scan Review: Three effluent pollutant scans (2020, 2021 and 2022) and additional submitted data were evaluated for additional pollutants of concern. o The following parameter(s) will receive a water quality -based effluent limit (WQBEL) with monitoring, since as part of a limited data set, two samples exceeded the allowable discharge concentration: None Page 6 of 14 o The following parameter(s) will receive a monitor -only requirement, since as part of a limited data set, one sample exceeded the allowable discharge concentration: None o The following parameters will not receive a limit or monitoring, since they did not demonstrate reasonable potential to exceed applicable water quality standards/criteria and the maximum predicted concentration was <50% of the allowable concentration: Total Beryllium, Total Phenolic Compounds, 1,4-dioxane (March 2022 — March 2023) If applicable, attach a spreadsheet of the RPA results as well as a copy of the Dissolved Metals Implementation Fact Sheet for freshwater/saltwater to this Fact Sheet. Include a printout of the RPA Dissolved to Total Metal Calculator sheet if this is a Municipality with a Pretreatment Program. Toxicity Testing Limitations Permit limits and monitoring requirements for Whole Effluent Toxicity (WET) have been established in accordance with Division guidance (per WET Memo, 8/2/1999). Per WET guidance, all NPDES permits issued to Major facilities or any facility discharging "complex" wastewater (contains anything other than domestic waste) will contain appropriate WET limits and monitoring requirements, with several exceptions. The State has received prior EPA approval to use an Alternative WET Test Procedure in NPDES permits, using single concentration screening tests, with multiple dilution follow-up upon a test failure. Describe proposed toxicity test requirement: This is a Major POTW, and a chronic WET limit at 90% effluent will continue on a quarterly frequency. Mercury Statewide TMDL Evaluation There is a statewide TMDL for mercury approved by EPA in 2012. The TMDL target was to comply with EPA's mercury fish tissue criteria (0.3 mg/kg) for human health protection. The TMDL established a wasteload allocation for point sources of 37 kg/year (81 lb/year), and is applicable to municipals and industrial facilities with known mercury discharges. Given the small contribution of mercury from point sources (^ 2% of total load), the TMDL emphasizes mercury minimization plans (MMPs) for point source control. Municipal facilities > 2 MGD and discharging quantifiable levels of mercury (>1 ng/1) will receive an MMP requirement. Industrials are evaluated on a case -by -case basis, depending if mercury is a pollutant of concern. Effluent limits may also be added if annual average effluent concentrations exceed the WQBEL value (based on the NC WQS of 12 ng/1) and/or if any individual value exceeds a TBEL value of 47 ng/l. Table 3. Mercury Effluent Data Summary 2019 2020 2021 2022 2023 # of Samples 4 4 4 4 2 Annual Average Conc. n /L 0.5 0.5 0.5 0.5 0.5 Maximum Conc., n /L 0.5 0.5 0.5 0.5 0.5 TBEL, n /L 47 WQBEL, n L 1 12.2 Describe proposed permit actions based on mercury evaluation: Since no annual average mercury concentration exceeded the WQBEL, and no individual mercury sample exceeded the TBEL, no mercury limit is required. Since the facility did not report quantifiable levels of mercury (> 1 ng/1) during the period reviewed, the mercury minimization plan (MMP) special condition has been removed. Other TMDL/Nutrient Management Strategy Considerations If applicable, describe any other TMDLs/Nutrient Management Strategies and their implementation within this permit: The Environmental Management Commission adopted Nutrient Management Strategy Page 7 of 14 rules in December 1997, classifying the entire Neuse River Basin as Nutrient Sensitive Waters. The point source rule [T15A NCAC 2B .0713 (previously .0234)] sets Total Nitrogen (TN) discharge limits for all point source dischargers larger than 0.5 MGD. The rule also allows dischargers to form a group compliance association and work together to reduce nitrogen; this option allows the association members added flexibility in controlling nitrogen discharges. At the same time, the association is subject to a group NPDES permit ensuring that the association and its individual members are accountable if they exceed the applicable nitrogen limits. Under the rule, there are three types of TN limit in the Neuse: 1. the individual limits in the dischargers' individual permits, 2. the aggregate limit in an association's group NPDES permit, and 3. the individual allocations/limits for each Association member, also in that association permit. A discharger may be subject to the first type of limit, or to the second and third, but never to all three at the same time. The discharger is first subject to the TN limit (if any) in its individual NPDES permit. If becomes a co-permittee to a compliance association's group NPDES permit, it is then governed by the TN limits in that permit. If the association complies with its group TN limit in a given year, all members are deemed to be in compliance with their individual allocations/ limits in the group permit. If the association exceeds its limit, the members then become subject to their individual allocations/ limits as well. Regardless of which permit governs a TN discharge, allocations/ limits will likely change over time as the dischargers purchase, sell, trade, lease, or otherwise transfer nitrogen allocations. The Division will modify the affected permits as necessary to ensure that the limits are kept up to date and reflect any such transactions. Nitrogen: The permit includes nutrient limits consistent with the Nutrient Management Strategy rule. The Permittee receives a TN Load limit of 143,246 lb/yr, a calendar year limit. Table 3: Annual Reported TN Load (Allocation = 143,246 lb/yr) 2019 2020 2021 2022 36,892lb/yr 36,979lb/yr 43,757lb/yr 33,920lb/yr 25.8% of allocation 25.8% of allocation 30.5% of allocation 23.7% of allocation Note: Average reported flow from January 2019 - May 2023 approximately 51.7% of permitted flow. The Permittee is a member of the Neuse River Compliance Association at this time. So long as it remains a co-permittee member, it is deemed to be in compliance with the TN limit in this permit, and its TN discharge is governed instead by the Association's group NPDES permit NCC00000I, first issued December 30, 2002 and most recently renewed on December 12, 2018. Phosphorus: The Permittee's 2.0 mg/L Total Phosphorus limit is carried forward in the new permit. It is a quarterly average limit to conform with the rule requirements. The January 2019 through May 2023 quarterly average reported TP ranged from 0.18 to 0.48 mg/L. Other WQBEL Considerations If applicable, describe any other parameters of concern evaluated for WQBELs: As required by Session Law 2018-5, Senate Bill 99, Section I LI r), every applicant shall submit documentation of any additional pollutants for which there are certified methods with the permit application if their discharge is anticipated via a Chemical Addendum to NPDES Application table. In their application, the Town provided the chemical addendum and informed the Division that additional sampling for 1,4-dioxane, Page 8 of 14 Trichlorofluoromethane and fluoride had been conducted. These parameters were not detected during the sampling events. In addition to the chemical addendum, the Town informed the Division of proactive sampling efforts they have conducted for tracking PFAS compounds. The Town has conducted sampling of the North Cary WRF influent, headworks (influent + recycled flow) and post -filtration. Analysis was conducted using Modified EPA Method 537.1 and Isotope Dilution. The Town found the presence of some PFAS compounds during each of the three sampling events. As the North Cary WRF is a major facility discharging above WS-V waters, monitoring of PFAS chemicals will be added to the permit at a frequency of quarterly. Since an EPA method for sampling and analyzing PFAS in wastewater is not currently available, the HAS sampling requirement in the Permit includes a compliance schedule which delays the effective date of this requirement until the first full calendar quarter beginning 6 months after EPA has a final wastewater method in 40 CFR136 published in the Federal Register to allow time for laboratories to attain certification. This date may be extended upon request and if there are no NC - certified labs. If applicable, describe any special actions (HQW or ORW) this receiving stream and classification shall comply with in order to protect the designated waterbody: NA If applicable, describe any compliance schedules proposed for this permit renewal in accordance with 15A NCAC 2H. 010 7(c) (2) (B), 40CFR 122.47, and EPA May 2007 Memo: NA If applicable, describe any water quality standards variances proposed in accordance with NCGS 143- 215.3(e) and 15A NCAC 2B.0226 for this permit renewal: NA 7. Technology -Based Effluent Limitations (TBELs) Municipals if not applicable, delete and skip to Industrials) Are concentration limits in the permit at least as stringent as secondary treatment requirements (30 mg/l BODS/TSS for Monthly Average, and 45 mg/l for BODS/TSS for Weekly Average). YES If NO, provide a justification for alternative limitations (e.g., waste stabilization pond). NA Are 85% removal requirements for BOD51TSS included in the permit? YES If NO, provide a justification (e.g., waste stabilization pond). NA 8. Antidegradation Review (New/Expanding Discharge): The objective of an antidegradation review is to ensure that a new or increased pollutant loading will not degrade water quality. Permitting actions for new or expanding discharges require an antidegradation review in accordance with 15A NCAC 2B.0201. Each applicant for a new/expanding NPDES permit must document an effort to consider non -discharge alternatives per 15A NCAC 2H.0105( c)(2). In all cases, existing instream water uses and the level of water quality necessary to protect the existing use is maintained and protected. If applicable, describe the results of the antidegradation review, including the Engineering Alternatives Analysis (EAA) and any water quality modeling results: NA 9. Antibacksliding Review: Sections 402(o)(2) and 303(d)(4) of the CWA and federal regulations at 40 CFR 122.44(1) prohibit backsliding of effluent limitations in NPDES permits. These provisions require effluent limitations in a reissued permit to be as stringent as those in the previous permit, with some exceptions where limitations may be relaxed (e.g., based on new information, increases in production may warrant less stringent TBEL limits, or WQBELs may be less stringent based on updated RPA or dilution). Are any effluent limitations less stringent than previous permit (YES/NO): NO If YES, confirm that antibacksliding provisions are not violated: N/A Page 9 of 14 10. Monitoring Requirements Monitoring frequencies for NPDES permitting are established in accordance with the following regulations and guidance: 1) State Regulation for Surface Water Monitoring, 15A NCAC 213.0500; 2) NPDES Guidance, Monitoring Frequency for Toxic Substances (7/15/2010 Memo); 3) NPDES Guidance, Reduced Monitoring Frequencies for Facilities with Superior Compliance (10/22/2012 Memo); 4) Best Professional Judgement (BPJ). Per US EPA (Interim Guidance, 1996), monitoring requirements are not considered effluent limitations under Section 402(o) of the Clean Water Act, and therefore anti - backsliding prohibitions would not be triggered by reductions in monitoring frequencies. For instream monitoring, refer to Section 4. The Town of Cary has requested continuation of 2/week monitoring for CBOD, ammonia, TSS and fecal coliform based on 2012 DWR Guidance Regarding the Reduction of Monitoring Frequencies in NPDES Permits for Exceptionally Performing Facilities. The last three years of the facility's data for these parameters have been reviewed in accordance with the criteria outlined in the guidance. Based on this review, 2/week monitoring frequency has been applied for CBOD, ammonia, fecal coliform, and TSS. The EPA 2012 Recreational Water Quality Criteria for Bacterial Indicators of Fecal Contamination recommends states set bacteriological water quality standards for primary recreation freshwaters using either the Escherichia coli or Enterococcus pathogenic indicators. North Carolina's current recreational surface water quality standards for Class B (primary recreation) waters use the fecal coliform bacteria group pathogenic indicator. The Division sent a letter to the Town of Cary on March 8, 2023 requesting participation in an E. coli Study being conducted across the state. This study is being conducted to evaluate the financial impacts of switching to an E. coli standard for all Class B freshwaters. The data will inform the Regulatory Fiscal Note a required part of the rulemaking package. The study covers the 2023 Swim Season, April through August, and requires instream and effluent monitoring and reporting of fecal coliform, E. coli, turbidity, temperature, DO, conductivity and pH. Additionally, instream sampling events are to be accompanied by a concurrent precipitation recording. The Town has submitted data for April and May, to date. The current permit includes Special Condition A.(5.) Clarification of Compliance When a Permit Limit is Set At or Below ML (Minimum Levels). Special Condition A.(5.) is based on the National Guidance for the Permitting, Monitoring, and Enforcement of Water Quality -Based Effluent Limitations Set Below Analytical Detection/Quantitation Levels: (a.) The following definitions apply to this permit: (i.) The Minimum Level (ML) is defined as the concentration in a sample that is equivalent to the concentration of the lowest calibration standard analyzed by a specific analytical procedure. (ii.) The Method Detection Limit (MDL) is defined as the minimum measured concentration of a substance that can be reported with 99% confidence that the measured concentration is distinguishable from method blank results. (b.) Per 15A NCAC 213.0505 (e)(4)(B), all monitoring required for permit application or to determine compliance with effluent limitations or applicable water quality standards shall be performed using sufficiently sensitive methods. Per 40 CFR 122.2 1 (e)(3)(i), methods are considered sufficiently sensitive when: (i.) the method ML is at or below the level of the applicable water quality criterion for the measured pollutant or pollutant parameter; or Page 10 of 14 (ii.) The method ML is above the applicable water quality criterion, but the amount of the pollutant or pollutant parameter in a facility's discharge is high enough that the method detects and quantifies the level of the pollutant or pollutant parameter in the discharge; or (iii.) The method has the lowest ML of the analytical methods approved under 40 CFR part 136 or required under 40 CFR chapter I, subchapter N or O for the measured pollutant or pollutant parameter. (c.) If no approved methods are capable of achieving a detection level below the permit discharge requirement (or allowable discharge concentration) the method with the lowest ML shall be used. (d.) In cases where the permit limit for a parameter is set at or below the ML for that parameter as defined above using a sufficiently sensitive analytical procedure available and the measurement for that parameter is less than the ML, the permittee shall be considered to be in full compliance with the permit if the value reported (less than ML) on the discharge monitoring report for that parameter is less than the ML (i.e., "< ML"). As Special Condition A.(5.) merely describes the practice of the Division with regard to compliance for parameters whose lowest practical quantitation level is greater than the facility's allowable discharge concentration for said parameter, Special Condition A.(5.) has been removed from the permit. 11. Electronic Reporting Requirements The US EPA NPDES Electronic Reporting Rule was finalized on December 21, 2015. Effective December 21, 2016, NPDES regulated facilities are required to submit Discharge Monitoring Reports (DMRs) electronically. While NPDES regulated facilities would initially be required to submit additional NPDES reports electronically effective December 21, 2020, EPA extended this deadline from December 21, 2020, to December 21, 2025. The current compliance date, effective January 4, 2021, was extended as a final regulation change published in the November 2, 2020 Federal Register. This permit contains the requirements for electronic reporting, consistent with Federal requirements. 12. Summary of Proposed Permitting Actions: Table 4. Current Permit Conditions and Proposed Changes Outfall 001 Parameter Current Permit Proposed Change Basis for Condition/Change Flow MA 12.0 MGD No change 15A NCAC 213.0505 Total Monthly Monitor and Report No change For calculation of TN Load Flow Monthly CBOD5 Summer: No change WQBEL. 1991 QUAL2E Model MA 4.1 mg/1 and 1994 WLA; 2012 DWR WA 6.0 mg/1 Guidance Regarding the Winter: Reduction of Monitoring MA 8.2 mg/1 Frequencies in NPDES Permits WA 12.3 mg/1 for Exceptionally Performing Monitor and report 2/week Facilities NH3-N Summer: No change WQBEL. 1991 QUAL2E Model MA 0.5 mg/1 and 1994 WLA; BPJ agreement WA 1.5 mg/1 with Town; verified with 2023 Winter: WLA; 2012 DWR Guidance MA 1.0 mg/1 Regarding the Reduction of WA 3.0 mg/1 Monitoring Frequencies in Monitor and report 2/week Page 11 of 14 NPDES Permits for Exceptionally Performing Facilities TSS MA 30 mg/1 No change TBEL. Secondary treatment WA 45 mg/l standards/40 CFR 133 / 15A Monitor and report 2/week NCAC 213.0406; 2012 DWR Guidance Regarding the Reduction of Monitoring Frequencies in NPDES Permits for Exceptionally Performing Facilities Fecal coliform MA 200 /100m1 No change WQBEL. State WQ standard, WA 400 /100ml 15A NCAC 2B .0200; Surface Monitor and report 2/week Water Monitoring, 15A NCAC 2B. 0500 Temperature Monitor and Report Daily No change Surface Water Monitoring, 15A NCAC 2B. 0508 DO > 5 mg/1 No change WQBEL. State WQ standard, Monitor and Report Daily 15A NCAC 2B .0200; 15A NCAC 02B .0500 pH 6 — 9 SU No change WQBEL. State WQ standard, Monitor and Report Daily 15A NCAC 2B .0200; 15A NCAC 02B .0500 Total Residual No requirement DM 17 ug/L WQBEL. 2023 WLA. Surface Chlorine Monitor and Report Water Monitoring, 15A NCAC Daily 2B. 0500 — active if chlorination is used TKN Monitor and Report No change For calculation of TN Weekly NO2+NO3 Monitor and Report No change For calculation of TN Weekly Total Nitrogen Monitor and Report No change 15A NCAC 02B .0713; Surface Weekly Water Monitoring, 15A NCAC 2B. 0500 Total Phosphorus QA 2.0 mg/L No change WQBEL. 15A NCAC 02B .0713; Monitor and Report Surface Water Monitoring, 15A Weekly NCAC 2B. 0500 TN Load Monitor and Report No change WQBEL. 15A NCAC 02B .0713 monthly (lb/mo) 143,246 lb/yr Monitor and Report yearly (lb/yr) Total Hardness Quarterly monitoring No changes Hardness -dependent dissolved Upstream and in Effluent metals water quality standards approved in 2016 Add quarterly Evaluation of PFAS contribution: PFAS No requirement monitoring with delayed pretreatment facility; implementation Implementation delayed until Page 12 of 14 after EPA certified method becomes available. Toxicity Test Chronic limit, 90% No change WQBEL. No toxics in toxic effluent amounts. 15A NCAC 213.0200 and 15A NCAC 213.0500 Effluent Three times per permit No change; conducted 40 CFR 122 Pollutant Scan cycle in 2025, 2026, 2027 Instream Monitor and Report for Add fecal coliform, Surface Water Monitoring, 15A Monitoring temperature, dissolved TKN, NO2+NO3, and NCAC 2B. 0508; Instream oxygen, pH, CBOD5, and TP; move to Special monitoring review; Division NH3-N 3/week during Condition A.(2.) Guidance Regarding Instream June through September Instream Monitoring Fecal Coliform Monitoring and 1/week during Requirements for remainder of the year; clarity LNBA waiver Mercury MMP Special Condition Remove condition Consistent with 2012 Statewide Minimization Mercury TMDL Implementation Plan (MMP) — no detections during review Calculation of Special Condition A.(2.) Condition maintained; 15A NCAC 02B .0713 TN Load rearranged to Special Condition A.(5.) Annual Limits Special Condition A.(3.) Condition maintained; 15A NCAC 02B .0713 for TN rearranged to Special Condition A.(6.) TN Allocations Special Condition A.(7.) No change 15A NCAC 02B .0713 Compliance for Special Condition A.(5.) Remove condition Condition reiterates Division Non -Detects Clarification of practice; not necessary as a Compliance When a special condition. Permit Limit is Set at or Below ML (Minimum Levels) Stream Sampling Special Condition A.(6.) Condition maintained; Per Permittee request; 15A — Extreme Clarification of rearranged to Special NCAC 2B .0505 (c)(4) Weather Monitoring Requirements Condition A.(8.) Electronic Electronic Reporting No change In accordance with EPA Reporting Special Condition Electronic Reporting Rule 2015. MGD — Million gallons per day, MA - Monthly Average, WA — Weekly Average, DM — Daily Max 13. Public Notice Schedule: Permit to Public Notice: 08/16/2023 Per 15A NCAC 2H .0109 & .0111, The Division will receive comments for a period of 30 days following the publication date of the public notice. Any request for a public hearing shall be submitted to the Director within the 30 days comment period indicating the interest of the party filing such request and the reasons why a hearing is warranted. Page 13 of 14 14. NPDES Division Contact If you have any questions regarding any of the above information or on the attached permit, please contact Nick Coco at (919) 707-3609 or via email at nick.cocogdeq.nc.gov. 15. Fact Sheet Addendum (if applicable): The draft was submitted to the Town of Cary, EPA Region IV, and the Division's Raleigh Regional Office, Aquatic Toxicology Branch, Monitoring Coalition Coordinator and Operator Certification Program for review. Comments were received from the Town of Cary on September 13, 2023. The comments and Division responses are provided in the attached addendum to the fact sheet. No comments were received from any other party. Were there any changes made since the Draft Permit was public noticed (Yes/No): YES If Yes, list changes and their basis below: • Footnote 5 of Section A.(1.) has been revised to include language covering the expectations for TRC monitoring under Special Condition A.(4.) Additional Monitoring Requirements for Permit Renewal. • Language has been added to Special Condition A.(9.) PFAS Monitoring Requirement acknowledging the need for laboratories to become NC -certified in the Final EPA Method 1633 after publication in the Federal Register. • As the Town of Cary does not anticipate a new industrial user with ties to the manufacturing, use, or production of PFAS chemicals, language regarding the increase of monitoring frequency to monthly from quarterly based on the introduction of a new significant industrial user has been removed from Special Condition A.(9.) PFAS Monitoring Requirement. • Typographical errors have been corrected in Special Condition A.(2.) Instream Monitoring Requirements. • Footnote 3 of Section A.(1.) has been corrected to reference CBOD5 instead of BOD5. 16. Fact Sheet Attachments (if applicable): • RPA Spreadsheet Summary • NPDES Implementation of Instream Dissolved Metals Standards — Freshwater Standards • NH3/TRC WLA Calculations • CBOD & TSS Removal Rate Calculations • Mercury TMDL Calculations • Monitoring Frequency Reduction Evaluation • POC Review Form • WET Testing and Self -Monitoring Summary • PFAS Monitoring • Comments received from Town of Cary • Fact Sheet Addendum Page 14 of 14 CARY September 12, 2023 Mr. Nick Coco, P.E. Department of Environmental Quality Division of Water Resources NPDES Municipal Permitting Unit 1617 Mail Service Center Raleigh, NC 27699-1617 Subject: North Cary WRF Draft NPDES Permit (NC0048879) Comments Dear Mr. Coco: On August 16, 2023, Cary received the draft NPDES permit for the North Cary Water Reclamation Facility (NC0048879). We appreciate the opportunity to review the draft permit, fact sheet, and associated reasonable potential analyses (RPA). Cary respectfully submits the following comments and requests for modification of the proposed draft permit. NPDES Permit Cover Letter 1. Total Residual Chlorine (TRC) limits and monitoring requirement (4th bullet point, pg. 1). Request: Remove TRC monitoring as chlorine addition is not listed or permitted for effluent disinfection. Cary will continue to maintain a redundant UV disinfection system, spare parts, service support, and emergency backup generators for our existing and approved method for effluent disinfection. If chlorine addition is required with a future permit modification, chlorine monitoring language can be added. 2. Special condition to monitor effluent PFAS (6th bullet point, pg. 1). Request 1: Cary requests NC Division of Water Resources (NCDWR) acknowledge the role of the State of North Carolina approval processes for laboratory procedures prior to requiring reporting of PFAS sampling results. Request 2: Remove language requiring increased monitoring frequency of PFAS for significant industrial users (SIU). This language is vague and unclear. Increased monitoring for PFAS for SIU should be based on a legitimate concern supported by wastewater monitoring data or categorical industrial user classifications that are found to manufacture or discharge PFAS compounds at levels that warrant increased monitoring. It is anticipated that virtually all industrial and domestic uncontrollable wastewater discharges will contain some level of PFAS detections, therefore with this condition for any new SIU, would trigger increased monitoring requirements with little or no justification or value in monitoring. Part ! A. 1. Effluent Limitations and Monitoring Re uirements (Page 3 of 14 1. Total Residual Chlorine (TRC) limits, monitoring requirement, and Footnote 5. Request: Remove TRC monitoring requirements and footnote 5 as chlorine addition is not listed or permitted for use in the effluent stream. If chlorine addition is required with future permit modification, chlorine monitoring language can be added. 2. Footnote 3: "The monthly average effluent BOD5 and Total Suspended Solids concentrations shall not exceed 15% of the respective influent value (85% removal)." Request: Please correct the footnote to specify carbonaceous biochemical oxygen demand (CBOD5) as permit limits specify CBOD5 not BOD5. 3. Footnote 4: "Twice per week sampling must occur on any two non-consecutive days during the calendar week." Request: Please confirm that week's consisting of holidays will not require two non- consecutive day sampling if holiday prevents it. 4. Effluent Pollutant Scan monitoring requirement. Request: Add a footnote that confirms there is no requirement to monitor for TRC if chlorine disinfection is not used. Part I, AR-) Instream Monitoring Requirements (Page 5 of 14) 1. Table header language: "Beginning on the effective date of this permit and lasting until lasting until permit expiration, the Permittee shall perform instream sampling upstream and downstream of Outfall 001 as specified below:" Request: Remove duplicate language "lasting until." 2. Instream Monitoring Requirements table. Request 1: Please add the Footnote 1 superscript to all monthly measurement frequencies with exception to total hardness. Request 2: Change the sample type for Total Nitrogen to "Calculated". Request 3: Remove the sample location superscript "U10" for hardness — total as CaCO3 (mg/L) 3. Footnote 1 sentence: "Instream sampling requirements €ew are provisionally waived in light of the permittee's participation in the Lower Neuse River Basins Association (LNBA)." Request: Remove the word "for" from the referenced sentence in Footnote 1. Part I A. 4. Additional Monitoring Re uirements for Permit Renewal (Page 7 of 14 1. (a) Effluent Pollutant Scans TRC monitoring requirement. Request: Add language that confirms there is no requirement to monitor for Total Residual Chlorine if Chlorine disinfection is not used. C►AR UTILITIES Part I A. 9. PFAS Monitoring Re uirement (Page 11 of 14 Request 1: Cary requests NCDWR acknowledge the role of the State of North Carolina approval processes for laboratory procedures prior to requiring reporting of PFAS sampling results. Request 2: Please remove language requiring increased monitoring frequency of PFAS for significant industrial users (SIU). This language is vague and unclear. Increased monitoring for PFAS for SIU should be based on a legitimate concern supported by wastewater monitoring data or categorical industrial user classifications that are found to manufacture or discharge PFAS compounds at levels that warrant increased monitoring. It is anticipated that virtually all industrial and domestic uncontrollable wastewater discharges will contain some level of PFAS detections, therefore with this condition for any new SIU, would trigger increased monitoring requirements with little or no justification or value in monitoring. Fact Sheet, 1. Basic Facility Information (Page 1 of 14 Facility Information Table Treatment Units. Request: Please change "aeration holding tanks" to "aerated holding tanks Fact Sheet 6. Water Quality -Based Effluent Limitations WQBELs — Ammonia and Total Residual Chlorine Limitations (Page 6 of 14 Description of any proposed changed to ammonia and/or TRC limits for this permit renewal sentence: "However, in the event of an emergency where chlorination is required as a backup or temporary means of disinfection at the facility, a TRC limit and monitoring requirement have been added to the permit based on the review of the attached WLA spreadsheet. " Comment: The NCWRF is not designed or approved to use chlorine for disinfection. Cary will continue to maintain a dual -fully redundant ultra -violet (UV) disinfection system, spare parts, service support, and emergency backup generators for our existing and approved method for effluent disinfection. If chlorine addition is required with a future permit modification, chlorine monitoring language can be added. Fact Sheet 6. Water Qualit -Based Effluent Limitations WQBELs — Reasonable Potential Analysis (RPA) for Toxicants (Page 6 of 14 1. POTW Effluent Pollutant Scan Review. Request: The fact sheet states, "Four effluent pollutant scans (2020, 2021 and 2022)...". Cary requests that "four" be changed to "three" to match the number of scans performed and cited. Fact Sheet 6. Water Qualit -Based Effluent Limitations WQBELs - Other TMDL/Nutrient Management Strategy Considerations Pa e 8 of 14 1. Other TMDL/Nutrient Management Strategy Considerations. CA nY UTILITIES Request: Please correct all typos to reflect the correct Total Nitrogen allocation of 143,246 Ibs/year. Comment: Cary's North Cary WRF has a permitted total nitrogen load of 143,246 pounds/year and is based on our current 12.0 MGD capacity needs. Both the future hydraulic capacity and nitrogen allocation is very important for Cary's future growth projections. The North Cary WRF total nitrogen allocation is in accordance with the NC Neuse Nutrient Strategy and the Neuse River Compliance Association co-permittee NPDES Permit NC000001. Cary's total nitrogen allocation is finite and even with our WRF currently meeting and exceeding the limits of technology for nitrogen removal, any reduction would be very detrimental. Any proposed reduction in future hydraulic capacity, transportation factor calculation, or nitrogen allocation is extremely important for Cary and likewise any point source discharger in the Neuse River Basin subject to the Neuse Nutrient Strategy. Fact Sheet 12. Summary of Proposed Permitting Actions - Table 4 (Page 13 of 14 1. Stream Sampling — Extreme Weather "Proposed Change" column Request: The proposed change for Stream Sampling— Extreme Weather should be corrected to read "Condition maintained; rearranged to Special Condition A.(8.)." Thank you for the opportunity to review and provide comments on the North NPDES permit renewal. If there are any questions regarding these comments, to contact Mr. Jonathan Bulla, North Cary WRF Plant Manager at (ionathan. b ulla@carync.goy). Sincerely, Jamie Revels, P.E. Utilities Director Cc: Jim Bridges, NCWRF Facilities Operation Supervisor, ORC Donald Smith, Wastewater Collections Program Manager Jonathan Bulla, NCWRF Manager Corrie Bondar, P.E., Assistant Utilities Director Cary WRF draft please feel free 919-677-0850 IA �7 UTILITIES North Cary WRF Fact Sheet Addendum NC0048879 Comments to the draft permit NC0048879, which was public noticed for 30-day comment period on 8/16/2023, were provided by the Town of Cary with several requests. No comments were received from any other party. Individual comments by the Town and Division responses are provided below. 1. Total Residual Chlorine a. Remove TRC monitoring as chlorine addition is not listed or permitted for effluent disinfection. Cary will continue to maintain a redundant UV disinfection system, spare parts, service support, and emergency backup generators for our existing and approved method for effluent disinfection. If chlorine addition is required with a future permit modification, chlorine monitoring language can be added. Response: The inclusion of the requirement for total residual chlorine (TRC) monitoring and limitation is only applicable if, in an emergency situation, the Town finds that the UV system is inoperable and must employ chlorination as a means of disinfection. Opening and modifying a permit to add the requirement to monitor for TRC would take a length of time which is likely longer than the temporary chlorination activity. As such, the Division has applied this requirement to take effect only under such activities where it is necessary. This requirement is consistently applied to facilities in situations similar to the North Cary WRF and has been maintained in the permit. The Division is not requesting chlorine addition, but merely requiring the monitoring and limitation of total residual chlorine in instances where chlorination is used. b. Add language that confirms there is no requirement to monitorforTotal Residual Chlorine if Chlorine disinfection is not used. Response: Footnote 5 of Section A.(1.) has been revised to include language covering the Effluent Pollutant Scan expectations for TRC. 2. PFAS Monitoring a. Cary requests NC Division of Water Resources (NCDWR) acknowledge the role of the State of North Carolina approval processes for laboratory procedures prior to requiring reporting of PFAS sampling results. Response: Language acknowledging the need for laboratories to become NC -certified in the new method has been added to the Special Condition. b. Remove language requiring increased monitoring frequency of PFAS for significant industrial users (SIU). This language is vague and unclear. Increased monitoring for PFAS for SIU should be based on a legitimate concern supported by wastewater monitoring data or categorical industrial user classifications that are found to manufacture or discharge PFAS compounds at levels that warrant increased monitoring. It is anticipated that virtually all industrial and domestic uncontrollable wastewater discharges will contain some level of PFAS detections, therefore with this condition for any new SIU, would trigger increased monitoring requirements with little or no justification or value in monitoring. Response: As the Town of Cary does not anticipate a new industrial user with ties to the manufacturing, use, or production of PFAS chemicals, the Special Condition language has been revised to remove the increase of monitoring frequency to monthly from quarterly based on the introduction of a new significant industrial user. North Cary WRF Fact Sheet Addendum NC0048879 3. Section A.(1.) Footnotes a. Please correct the footnote to specify carbonaceous biochemical oxygen demand (CBODs) as permit limits specify CBODs not BODs. Response: The footnote has been corrected. b. Please confirm that week's consisting of holidays will not require two non-consecutive day sampling if holiday prevents it. Response: The Division requests that the Town make the effort to always conduct the sampling on non-consecutive days. However, if this is not possible due to the timing of holidays (calendar week only has two consecutive days remaining under holiday circumstances), the Town will not be considered out of compliance with the requirement. c. Add a footnote that confirms there is no requirement to monitor for TRC if chlorine disinfection is not used. Response: Footnote 5 now states, "The facility shall monitor TRC only if using chlorination for disinfection." 4. Instream Monitorine Reauirements a. Remove duplicate language "lasting until" from table header. Response: The duplicate language has been removed. b. Please add the Footnote 1 superscript to all monthly measurement frequencies with exception to total hardness. Response: The superscript has been appropriately applied. c. Change the sample type for Total Nitrogen to "Calculated". Response: The sample type has been corrected. d. Remove the sample location superscript "U10" for hardness - total as CaCO3 (mg/Q. Response: The superscript has been removed. e. Remove the word "for" from the referenced sentence in Footnote 1. Response: The word "for" has been removed. 5. Fact Sheet a. Please change "aeration holding tanks" to "aerated holding tanks" in the Facility Information Table Treatment Units. Response: The information has been corrected. b. The fact sheet states, "Four effluent pollutant scans (2020, 2021 and 2022) ... ". Cary requests that "four" be changed to "three" to match the number of scans performed and cited. Response: The number of scans referenced has been corrected in the fact sheet. c. Please correct all typos to reflect the correct Total Nitrogen allocation of 143,246 Ibs/year. Response: The typos have been corrected. d. The proposed change for Stream Sampling- Extreme Weather should be corrected to read "Condition maintained; rearranged to Special Condition A.(8.)." Response: The number of scans referenced has been corrected in the fact sheet. Firefox about:blank AFFIDAVIT OF PUBLICATION Account 4 Order Number Identification Order PO Amount Cols Depth 19489 455962 Print Legal Ad-IPLMS5440 - IPL0135544 $463.04 1 46 L Attention: Wren Thedford DEPARTMENT OF WATER RESOURCES - RALEIGH 1617 MAIL SERVICE CENTER RALEIGH, NC 276991617 meagen.benton@ncdenr.gov --------------------------------------------------------------------------- Public Notice North Carolina Environmental Man- agement CommissiorLfNPDES Unit 1617 Mail Service Center Raleigh, NO 27699-1617 Notice of Intent to Issue NPDES Waste- water Permit NCO048879 North Cary WW The North Carolina Environmen- tal Management Commission propos- es to issue a t•PDFS wastewater dis- charge permit to the person(s) listed below. Written comments regarding the proposed permit will be accepted until 30 days after the publish date of this notice. The Director of the NC Di- vision of Water Resources MR) may hold a public hearing shouki there be a significant degree of public interest. Please mail cumments and/or infor- mation requests to DMR at the atxrve address. Interested persons may visit the DWR at 512 N Salisbury Street, Raleigh, NC 27604 to review the infor- mation on file. Additional information on NPDES permits and this notice may be found on our website: htips://deq. nc.gov/public-notices-hearings, or by calling (919) 707-3601 The Town of Cary )PO Box 8005, Cary, NC 275121 has requested renewal of NPDES permit N00048879 for its North Cary Water Reclamation Facility. located in Wake County. This permitted facil- ity discharges treated municipal and industrial wastewater to an unnamed tributary to Crabtree Creek, a class B.NSW water in the Neuse R ver Ba- sin. Currentty C©O05, ammonia, fecal col*=. DO. pH, total residual chlo- rine, total nitrogen loading, arid total phosphorous are water quality limited. This discharge may affect future al- locations in this segment of Crabtree Creek. IPLO135544 Aug 16 2023 STATE OF NORTH CAROLINA COUNTY OF WAKE, COUNTY OF DURHAM Before the undersigned. a Notary Public of Dallas County, Texas, duly commissioned and authorized to administer oaths. affirmations, etc., personally appeared Tara Pennington, who being duly sworn or affirmed, according to law, cloth depose and say that he or she is Accounts Receivable Specialist of the News & Observer Publishing Company, a corporation organized and doing business under the Laws of the State of North Carolina, and publishing a newspaper known as The News & Observer, Wake and State aforesaid, the said newspaper in which such notice, paper, document, or legal advertisement was published was, at the time of each and every such publication, a newspaper meeting all of the requirements and qualifications of Section 1- 597 of the General Statutes of North Carolina and was a qualified newspaper within the meaning of Section 1-597 of the General Statutes of North Carolina, and that as such he or she makes this affidavit; and is familiar with the books, files and business of said corporation and by reference to the files of said publication the attached advertisement for DEPARTMENT OF WATER RESOURCES RALEIGH was inserted in the aforesaid newspaper on dates as follows: 1 insertion(s) published on: 08.116'23 certify or declare) under penalty of perjury that the foregoing is true and correct. Notary Public in and for the state of Texas, residing in Dallas County STEPHANIE HATCHER • �° My Notary IU # 13353+" ''%•a jr. Expires January 14, 2026 Etttra dtarge for boor duplicate affidavits. Leo dKilintent please do not destroy! I of 1 9/19/2023, 12:36 PM Permit No. NCO048879 NPDES Implementation of Instream Dissolved Metals Standards - Freshwater Standards The NC 2007-2015 Water Quality Standard (WQS) Triennial Review was approved by the NC Environmental Management Commission (EMC) on November 13, 2014. The US EPA subsequently approved the WQS revisions on April 6, 2016, with some exceptions. Therefore, metal limits in draft permits out to public notice after April 6, 2016 must be calculated to protect the new standards - as approved. Table 1. NC Dissolved Metals Water Q ality Standards/A uatic Life Protection Parameter Acute FW, µg/l (Dissolved) Chronic FW, µg/l (Dissolved) Acute SW, µg/1 (Dissolved) Chronic SW, µg/1 (Dissolved) Arsenic 340 150 69 36 Beryllium 65 6.5 --- --- Cadmium Calculation Calculation 40 8.8 Chromium III Calculation Calculation --- --- Chromium VI 16 11 1100 50 Copper Calculation Calculation 4.8 3.1 Lead Calculation Calculation 210 8.1 Nickel Calculation Calculation 74 8.2 Silver Calculation 0.06 1.9 0.1 Zinc Calculation Calculation 90 81 Table 1 Notes: 1. FW= Freshwater, SW= Saltwater 2. Calculation = Hardness dependent standard 3. Only the aquatic life standards listed above are expressed in dissolved form. Aquatic life standards for Mercury and selenium are still expressed as Total Recoverable Metals due to bioaccumulative concerns (as are all human health standards for all metals). It is still necessary to evaluate total recoverable aquatic life and human health standards listed in 15A NCAC 2B.0200 (e.g., arsenic at 10 µg/1 for human health protection; cyanide at 5 µg/L and fluoride at 1.8 mg/L for aquatic life protection). Table 2. Dissolved Freshwater Standards for Hardness -Dependent Metals The Water Effects Ratio (WER) is equal to one unless determined otherwise under 15A NCAC 02B .0211 Subparagraph (11)(d) Metal NC Dissolved Standard, µg/I Cadmium, Acute WER* {1. 136672-[ln hardness](0.041838)} e^10.9151 [ln hardness]-3.1485} Cadmium, Acute Trout waters WER* {1. 136672-[ln hardness](0.041838)} e^{0.9151[In hardness]-3.62361 Cadmium, Chronic WER*{1.101672-[ln hardness](0.041838)} • e^{0.7998[ln hardness] -4.445 11 Chromium III, Acute WER*0.316 e^{0.8190[ln hardness]+3.7256} Chromium III, Chronic WER*0.860 e^{0.8190[ln hardness]+0.6848} Copper, Acute WER*0.960 e^{0.9422[ln hardness]-1.700} Copper, Chronic WER*0.960 e^{0.8545[ln hardness]-1.702} Lead, Acute WER*{1.46203-[ln hardness](0.145712)} • e^{1.273[ln hardness]-1.460} Lead, Chronic WER*{1.46203-[ln hardness](0.145712)} • e^{1.273[ln hardness]-4.705) Nickel, Acute WER*0.998 e^{0.8460[ln hardness]+2.255} Nickel, Chronic WER*0.997 e^{0.8460[ln hardness]+0.0584} Page 1 of 4 Permit No. NCO048879 Silver, Acute WER*0.85 • e"O.72[ln hardness]-6.59} Silver, Chronic Not applicable Zinc, Acute WER*0.978 e^{0.8473[ln hardness]+0.884} Zinc, Chronic WER*0.986 e^{0.8473[ln hardness]+0.884} General Information on the Reasonable Potential Analysis (RPA) The RPA process itself did not change as the result of the new metals standards. However, application of the dissolved and hardness -dependent standards requires additional consideration in order to establish the numeric standard for each metal of concern of each individual discharge. The hardness -based standards require some knowledge of the effluent and instream (upstream) hardness and so must be calculated case -by -case for each discharge. Metals limits must be expressed as `total recoverable' metals in accordance with 40 CFR 122.45(c). The discharge -specific standards must be converted to the equivalent total values for use in the RPA calculations. We will generally rely on default translator values developed for each metal (more on that below), but it is also possible to consider case -specific translators developed in accordance with established methodology. RPA Permitting Guidance/WOBELs for Hardness -Dependent Metals - Freshwater The RPA is designed to predict the maximum likely effluent concentrations for each metal of concern, based on recent effluent data, and calculate the allowable effluent concentrations, based on applicable standards and the critical low -flow values for the receiving stream. If the maximum predicted value is greater than the maximum allowed value (chronic or acute), the discharge has reasonable potential to exceed the standard, which warrants a permit limit in most cases. If monitoring for a particular pollutant indicates that the pollutant is not present (i.e. consistently below detection level), then the Division may remove the monitoring requirement in the reissued permit. To perform a RPA on the Freshwater hardness -dependent metals the Permit Writer compiles the following information: • Critical low flow of the receiving stream, 7Q10 (the spreadsheet automatically calculates the 1 Q 10 using the formula 1 Q 10 = 0.843 (s7Q 10, cfs) 0.993 • Effluent hardness and upstream hardness, site -specific data is preferred • Permitted flow • Receiving stream classification 2. In order to establish the numeric standard for each hardness -dependent metal of concern and for each individual discharge, the Permit Writer must first determine what effluent and instream (upstream) hardness values to use in the equations. The permit writer reviews DMR's, Effluent Pollutant Scans, and Toxicity Test results for any hardness data and contacts the Permittee to see if any additional data is available for instream hardness values, upstream of the discharge. If no hardness data is available, the permit writer may choose to do an initial evaluation using a default hardness of 25 mg/L (CaCO3 or (Ca + Mg)). Minimum and maximum limits on the hardness value used for water quality calculations are 25 mg/L and 400 mg/L, respectively. If the use of a default hardness value results in a hardness -dependent metal showing reasonable potential, the permit writer contacts the Permittee and requests 5 site -specific effluent and upstream hardness samples over a period of one week. The RPA is rerun using the new data. Page 2 of 4 Permit No. NCO048879 The overall hardness value used in the water quality calculations is calculated as follows: Combined Hardness (chronic) _ (Permitted Flow, cfs *Avg. Effluent Hardness, mg/L)+s7Q10, cfs *Avg. Upstream Hardness, mg/L) (Permitted Flow, cfs + s7Q 10, cfs) The Combined Hardness for acute is the same but the calculation uses the IQ 10 flow. 3. The permit writer converts the numeric standard for each metal of concern to a total recoverable metal, using the EPA Default Partition Coefficients (DPCs) or site -specific translators, if any have been developed using federally approved methodology. EPA default partition coefficients or the "Fraction Dissolved" converts the value for dissolved metal at laboratory conditions to total recoverable metal at in -stream ambient conditions. This factor is calculated using the linear partition coefficients found in The Metals Translator: Guidance for Calculating a Total Recoverable Permit Limit from a Dissolved Criterion (EPA 823-B-96-007, June 1996) and the equation: Cdiss = 1 Ctotal I + { [Kp.] [ss('+a)] [10 6] } Where: ss = in -stream suspended solids concentration [mg/1], minimum of 10 mg/L used, and Kpo and a = constants that express the equilibrium relationship between dissolved and adsorbed forms of metals. A list of constants used for each hardness -dependent metal can also be found in the RPA program under a sheet labeled DPCs. 4. The numeric standard for each metal of concern is divided by the default partition coefficient (or site -specific translator) to obtain a Total Recoverable Metal at ambient conditions. In some cases, where an EPA default partition coefficient translator does not exist (ie. silver), the dissolved numeric standard for each metal of concern is divided by the EPA conversion factor to obtain a Total Recoverable Metal at ambient conditions. This method presumes that the metal is dissolved to the same extent as it was during EPA's criteria development for metals. For more information on conversion factors see the June, 1996 EPA Translator Guidance Document. 5. The RPA spreadsheet uses a mass balance equation to determine the total allowable concentration (permit limits) for each pollutant using the following equation: Ca = (s7Q 10 + Qw) (Cwgs) — (s7Q10) (Cb) Qw Where: Ca = allowable effluent concentration (µg/L or mg/L) Cwqs = NC Water Quality Standard or federal criteria (µg/L or mg/L) Cb = background concentration: assume zero for all toxicants except NH3* (µg/L or mg/L) Qw = permitted effluent flow (cfs, match s7Q 10) s7Q 10 = summer low flow used to protect aquatic life from chronic toxicity and human health through the consumption of water, fish, and shellfish from noncarcinogens (cfs) * Discussions are on -going with EPA on how best to address background concentrations Flows other than s7Q 10 may be incorporated as applicable: IQ 10 = used in the equation to protect aquatic life from acute toxicity Page 3 of 4 Permit No. NC0048879 QA = used in the equation to protect human health through the consumption of water, fish, and shellfish from carcinogens 30Q2 = used in the equation to protect aesthetic quality 6. The permit writer enters the most recent 2-3 years of effluent data for each pollutant of concern. Data entered must have been taken within four and one-half years prior to the date of the permit application (40 CFR 122.21). The RPA spreadsheet estimates the 95th percentile upper concentration of each pollutant. The Predicted Max concentrations are compared to the Total allowable concentrations to determine if a permit limit is necessary. If the predicted max exceeds the acute or chronic Total allowable concentrations, the discharge is considered to show reasonable potential to violate the water quality standard, and a permit limit (Total allowable concentration) is included in the permit in accordance with the U.S. EPA Technical Support Document for Water Quality -Based Toxics Control published in 1991. 7. When appropriate, permit writers develop facility specific compliance schedules in accordance with the EPA Headquarters Memo dated May 10, 2007 from James Hanlon to Alexis Strauss on 40 CFR 122.47 Compliance Schedule Requirements. The Total Chromium NC WQS was removed and replaced with trivalent chromium and hexavalent chromium Water Quality Standards. As a cost savings measure, total chromium data results may be used as a conservative surrogate in cases where there are no analytical results based on chromium III or VI. In these cases, the projected maximum concentration (95th %) for total chromium will be compared against water quality standards for chromium III and chromium VI. 9. Effluent hardness sampling and instream hardness sampling, upstream of the discharge, are inserted into all permits with facilities monitoring for hardness -dependent metals to ensure the accuracy of the permit limits and to build a more robust hardness dataset. 10. Hardness and flow values used in the Reasonable Potential Analysis for this permit included: Parameter Value Comments (Data Source) Average Effluent Hardness (mg/L) [Total as, CaCO3 or (Ca+Mg)] 59.21 Average from 112019 to 512023 samples Average Upstream Hardness (mg/L) [Total as, CaCO3 or (Ca+Mg)] 31.89 Average from 112019 to 512023 samples 7Q10 summer (cfs) 0.30 Historical; Previous Fact Sheet IQIO (cfs) 0.26 Calculated in RPA Permitted Flow (MGD) 12.0 NPDES Files Date: 7/24/2023 Permit Writer: Nick Coco Page 4 of 4 North Cary WRF NCO048879 Freshwater RPA - 95% Probability/95% Confidence Using Metal Translators MAXIMUM DATA POINTS = 58 Qw (MGD) = 12.0000 1Q10S (cfs) = 0.26 7Q10S (cfs) = 0.30 7Q10W (cfs) = 0.80 30Q2 (cfs) = 0.30 Avg. Stream Flow, QA (cfs) = 0.30 Receiving Stream: Crabtree Creek HUC 03020201 WWTP/WTP Class: IV IWC% @ 1Q10S = 98.621421 IWC% @ 7Q10S = 98.41269841 IWC% @ 7Q10W = 95.87628866 IWC% @ 30Q2 = 98.41269841 IW%C @ QA = 98.41269841 Stream Class: B;NSW Outfall 001 Qw = 12 MGD COMBINED HARDNESS (mg/L) Acute = 58.83 mg/L Chronic = 5 8.7 8 mg/L PARAMETER NC STANDARDS OR EPA CRITERIA CO)REASONABLE POTENTIAL RESULTS RECOMMENDED ACTION TYPE J CY D Applied Chronic Acute n # Det. Max Pred Cw Allowable Cw Standard Acute (FW): 344.8 Arsenic C 150 FW(7Q10s) 340 ug/L 53 0 2.5 Chronic (FW): 152.4 No RP, Predicted Max < 50% of Allowable Cw - No Max MDL5 Monitoring required Arsenic C 10 HH/WS(Qavg) ug/L NO DETECTS _= Chronic (HH): 10.2 Max MDL 5 Acute: 65.91 Beryllium NC 6.5 FW(7Q10s) 65 ug/L 3 0 1.50 Note: n < 9 C.V. (default) _ Chronic 6.60 No RP, Predicted Max < 50% of Allowable Cw - No Limited data set NO DETECTS Max MDL = 1 Monitoring required Acute: 6.932 Cadmium NC 1.1255 FW(7Q10s) 6.8362 ug/L 53 0 0.505 _ _ Chronic: 1.144 _ No RP, Predicted Max -< 50% of Allowable Cw - No NO DETECTS Max MDL = 1 Monitoring required Acute: NO WQS Total Phenolic Compounds NC 300 A(30Q2) ug/L 3 0 120.0 Note: n < 9 C.V. (default) _ Chronic 304.8 No RP, Predicted Max < 50% of Allowable Cw - No Limited data set NO DETECTS Max MDL 80 Monitoring required Acute: 1,849.8 Chromium III NC 237.11 FW(7Q10s) 1824.29 µg/L 0 0 N/A Chronic: 240.9 Acute: 16.2 Chromium VI NC 11 FW(7Q10s) 16 µg/L 0 0 N/A Chronic: 11.2 a: No monitoring required if all Total Chromium Chromium, Total NC µg/L 53 0 2.5 Max reported value = 2.5 samples are < 5 pg/L or Pred. max for Total Cr is < allowable Cw for Cr VI. NO DETECTS Max MDL = 5 Acute: 23.78 Copper NC 16.3607 FW(7Q10s) 23.4545 ug/L 53 53 6.06 _ Chronic 16.62 No RP, Predicted Max < 50% of Allowable Cw - No No value > Allowable Cw Monitoring required Acute: 22.3 Cyanide NC 5 FW(7Q10s) 22 10 uWL 56 1 5.0 _ ----------------------------- Chronic------ 5.1--- No value > Allowable Cw All values < 10 ug/L - No Monitoring required 48879 RPA, rpa Page 1 of 2 7/24/2023 North Cary WRF NCOO48879 Freshwater RPA - 95% Probability/95% Confidence Using Metal Translators Outfall 001 Qw = 12 MGD Acute: 198.961 Lead NC 7.6382 FW(7Q10s) 196.2184 ug/L 53 0 2.550 Chronic:7.761 No RP, Predicted Max < 50% of Allowable Cw - No NO DETECTS Max MDL = 5 Monitoring required Acute: NO WQS Molybdenum NC 2000 HH(7Q10s) ug/L 53 0 2.5 _ _ _ -< Chronic: 2,032.3 No RP, Predicted Max 50% of Allowable Cw - No NO DETECTS Max MDL = 5 Monitoring required Acute (FW): 701.1 Nickel NC 76.7350 FW(7Q 1 Os) 691.4428 µg/L, 53 0 5.1 Chronic (FW): 78.0 No RP, Predicted Max < 50% of Allowable Cw - No Ma— x MDL_= 10 Monitoring required Nickel NC 25.0000 WS(7Q10s) µg/L NO DETECTS Chronic (WS): 25.4 Max MDL = 10 Acute: 56.8 Selenium NC 5 FW(7Q 10s) 56 ug/L 53 0 2.5 Chronic:5.1 No RP, Predicted Max < 50% of Allowable Cw - No NO DETECTS Max MDL 5 Monitoring required Acute: 1.310 Silver NC 0.06 FW(7Q10s) 1.2917 ug/L 53 0 0.500 Chronic: 0.061 All values non -detect < 1 ug/L ; No monitoring required NO DETECTS Max MDL = 1 Acute: 263.2 No RP, Predicted Max < 50% of Allowable Cw - No Zinc NC 261.4922 FW(7QIOs) 259.5837 ug/L 53 53 71.7 Monitoring required Chronic----- 265.7 - ----------------------------- No value > Allowable Cw Acute: NO WQS 1,4-dioxane C 0.35 HH(Qavg) µg/L 10 0 1.00000 Chronic: 0.356 All values non -detect < 2 ug/L ; No monitoring NO DETECTS Max MDL = 2 required ----------------------------- 48879 RPA, rpa Page 2 of 2 7/24/2023 REASONABLE POTENTIAL ANALYSIS H1 I Effluent Hardness I 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Date Data BDL=1/2DL 1 /8/2019 59.9 59.9 2/5/2019 61.9 61.9 3/5/2019 61.2 61.2 4/2/2019 62.2 62.2 5/7/2019 60.8 60.8 6/4/2019 63 63 7/9/2019 58.1 58.1 8/6/2019 62.5 62.5 9/10/2019 58.7 58.7 10/8/2019 60 60 11 /5/2019 61.6 61.6 12/10/2019 61.9 61.9 1 /7/2020 64.2 64.2 2/4/2020 61.2 61.2 3/3/2020 59.3 59.3 4/7/2020 63.6 63.6 5/5/2020 62 62 6/2/2020 63.6 63.6 7/7/2020 58.6 58.6 8/11 /2020 58.4 58.4 9/1/2020 58.6 58.6 10/6/2020 56.5 56.5 11 /3/2020 57.2 57.2 12/1/2020 54.1 54.1 1 /5/2021 62.1 62.1 2/2/2021 54.8 54.8 3/2/2021 58.2 58.2 4/6/2021 56 56 5/4/2021 54.6 54.6 6/1 /2021 58.1 58.1 7/6/2021 60 60 8/3/2021 57.2 57.2 9/7/2021 56.9 56.9 10/5/2021 52.3 52.3 11 /2/2021 58.2 58.2 12/7/2021 54 54 1 /4/2022 52.2 52.2 2/8/2022 56.9 56.9 3/8/2022 57 57 4/5/2022 65.5 65.5 5/3/2022 60.7 60.7 6/7/2022 58 58 7/12/2022 61.3 61.3 8/2/2022 61.1 61.1 9/13/2022 57.4 57.4 10/4/2022 59.6 59.6 11 /8/2022 54.2 54.2 12/6/2022 60.4 60.4 1/10/2023 59.5 59.5 2/7/2023 61.5 61.5 3/7/2023 60.3 60.3 4/11/2023 62.6 62.6 5/2/2023 58.4 58.4 Results Std Dev. Mean C.V. n 10th Per value Average Value Max. Value Use "PASTE SPECIAL Values" then "COPY" Maximum data points = 58 3.0514 59.2094 0.0515 53 54.64 mg/L 59.21 mg/L 65.50 mg/L H2 Upstream Hardness Date Data BDL=1/2DL 1 1 /8/2019 35.5 35.5 2 2/5/2019 37.5 37.5 3 3/5/2019 32.3 32.3 4 4/2/2019 39.3 39.3 5 5/7/2019 38.3 38.3 6 6/4/2019 37.3 37.3 7 7/9/2019 36.4 36.4 8 8/6/2019 24.5 24.5 9 9/10/2019 28.3 28.3 10 10/8/2019 33.6 33.6 11 11 /5/2019 31.3 31.3 12 12/10/2019 31.3 31.3 13 1 /7/2020 30.9 30.9 14 2/4/2020 35.4 35.4 15 3/3/2020 39.1 39.1 16 4/7/2020 44.5 44.5 17 5/5/2020 38.9 38.9 18 6/2/2020 28 28 19 7/7/2020 31 31 20 8/11/2020 25.1 25.1 21 9/1/2020 21.7 21.7 22 10/6/2020 22.1 22.1 23 11 /3/2020 30 30 24 12/1/2020 27.4 27.4 25 1 /5/2021 25.7 25.7 26 2/2/2021 31.2 31.2 27 3/2/2021 28.5 28.5 28 4/6/2021 37.9 37.9 29 5/4/2021 48 48 30 6/1/2021 50.3 50.3 31 7/6/2021 28.9 28.9 32 8/3/2021 29.2 29.2 33 9/7/2021 27 27 34 10/5/2021 24.4 24.4 35 11 /2/2021 21.6 21.6 36 12/7/2021 25.8 25.8 37 1 /4/2022 20.7 20.7 38 2/8/2022 34.2 34.2 39 3/8/2022 40.6 40.6 40 4/5/2022 42.3 42.3 41 5/3/2022 41.1 41.1 42 6/7/2022 37.1 37.1 43 7/12/2022 31.1 31.1 44 8/2/2022 27.2 27.2 45 9/13/2022 28.4 28.4 46 10/4/2022 21.7 21.7 47 11 /8/2022 26.1 26.1 48 12/6/2022 22.1 22.1 49 1/10/2023 29.6 29.6 50 2/7/2023 34.1 34.1 51 3/7/2023 37 37 52 4/11/2023 30.1 30.1 53 5/2/2023 28.6 28.6 54 55 56 57 58 Results Std Dev. Mean C.V. n 10th Per value Average Value Max. Value Use "PASTE SPECIAL Values" then "COPY" Maximum data points = 58 6.9189 31.8906 0.2170 53 22.56 mg/L 31.89 mg/L 50.30 mg/L 48879 RPA, data - 1 - 7/24/2023 REASONABLE POTENTIAL ANALYSIS Par01 & Par02 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Arsenic Date Data BDL=1/2DL 1 /8/2019 < 5 2.5 2/5/2019 < 5 2.5 3/5/2019 < 5 2.5 4/2/2019 < 5 2.5 5/7/2019 < 5 2.5 6/4/2019 < 5 2.5 7/9/2019 < 5 2.5 8/6/2019 < 5 2.5 9/10/2019 < 5 2.5 10/8/2019 < 5 2.5 11 /5/2019 < 5 2.5 12/10/2019 < 5 2.5 1 /7/2020 < 5 2.5 2/4/2020 < 5 2.5 3/3/2020 < 5 2.5 4/7/2020 < 5 2.5 5/5/2020 < 2 1 6/2/2020 < 5 2.5 7/7/2020 < 5 2.5 8/11 /2020 < 5 2.5 9/1/2020 < 5 2.5 10/6/2020 < 5 2.5 11 /3/2020 < 5 2.5 12/1/2020 < 5 2.5 1 /5/2021 < 5 2.5 2/2/2021 < 5 2.5 3/2/2021 < 5 2.5 4/6/2021 < 5 2.5 5/4/2021 < 5 2.5 6/1/2021 < 5 2.5 7/6/2021 < 5 2.5 8/3/2021 < 5 2.5 9/7/2021 < 5 2.5 10/5/2021 < 5 2.5 11 /2/2021 < 5 2.5 12/7/2021 < 5 2.5 1 /4/2022 < 5 2.5 2/8/2022 < 5 2.5 3/8/2022 < 5 2.5 4/5/2022 < 5 2.5 5/3/2022 < 5 2.5 6/7/2022 < 5 2.5 7/12/2022 < 5 2.5 8/2/2022 < 5 2.5 9/13/2022 < 5 2.5 10/4/2022 < 5 2.5 11 /8/2022 < 5 2.5 12/6/2022 < 5 2.5 1/10/2023 < 5 2.5 2/7/2023 < 5 2.5 3/7/2023 < 5 2.5 4/11/2023 < 5 2.5 5/2/2023 < 5 2.5 Results Std Dev Mean C.V. n Mult Factor = Max. Value Max. Pred Cw Use "PASTE SPECIAL Values" then "COPY" Maximum data points = 58 0.2060 2.4717 0.0834 53 1.00 2.5 ug/L 2.5 ug/L -2- 48879 RPA, data 7/24/2023 REASONABLE POTENTIAL ANALYSIS Par03 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 P a r04 Use "PASTE SPECIAL Beryllium Values" then "COPY" Maximum data points = 58 Date Data BDL=1/2DL Results 5/5/2020 < 1 0.5 Std Dev. 0.0000 8/3/2021 < 1 0.5 Mean 0.5000 2/8/2022 < 1 0.5 C.V. (default) 0.6000 n 3 Mult Factor = 3.00 Max. Value 0.50 ug/L Max. Pred Cw 1.50 ug/L Cadmium Date Data BDL=1/2DL Results 1 1/8/2019 < 1 0.5 Std Dev. 2 2/5/2019 < 1 0.5 Mean 3 3/5/2019 < 1 0.5 C.V. 4 4/2/2019 < 1 0.5 n 5 5/7/2019 < 1 0.5 6 6/4/2019 < 1 0.5 Mult Factor = 7 7/9/2019 < 1 0.5 Max. Value 8 8/6/2019 < 0.5 0.25 Max. Pred Cw 9 9/10/2019 < 0.5 0.25 10 10/8/2019 < 0.5 0.25 11 11 /5/2019 < 0.5 0.25 12 12/10/2019 < 0.5 0.25 13 1 /7/2020 < 0.5 0.25 14 2/4/2020 < 0.5 0.25 15 3/3/2020 < 0.5 0.25 16 4/7/2020 < 0.5 0.25 17 5/5/2020 < 0.5 0.25 18 6/2/2020 < 0.5 0.25 19 7/7/2020 < 0.5 0.25 20 8/11/2020 < 0.5 0.25 21 9/1/2020 < 0.5 0.25 22 10/6/2020 < 0.5 0.25 23 11 /3/2020 < 0.5 0.25 24 12/1/2020 < 0.5 0.25 25 1 /5/2021 < 0.5 0.25 26 2/2/2021 < 0.5 0.25 27 3/2/2021 < 0.5 0.25 28 4/6/2021 < 0.5 0.25 29 5/4/2021 < 0.5 0.25 30 6/1/2021 < 0.5 0.25 31 7/6/2021 < 0.5 0.25 32 8/3/2021 < 0.5 0.25 33 9/7/2021 < 0.5 0.25 34 10/5/2021 < 0.5 0.25 35 11 /2/2021 < 0.5 0.25 36 12/7/2021 < 0.5 0.25 37 1 /4/2022 < 0.5 0.25 38 2/8/2022 < 0.5 0.25 39 3/8/2022 < 0.5 0.25 40 4/5/2022 < 0.5 0.25 41 5/3/2022 < 0.5 0.25 42 6/7/2022 < 0.5 0.25 43 7/12/2022 < 0.5 0.25 44 8/2/2022 < 0.5 0.25 45 9/13/2022 < 0.5 0.25 46 10/4/2022 < 0.5 0.25 47 11 /8/2022 < 0.5 0.25 48 12/6/2022 < 0.5 0.25 49 1/10/2023 < 0.5 0.25 50 2/7/2023 < 0.5 0.25 51 3/7/2023 < 0.5 0.25 52 4/11/2023 < 0.5 0.25 53 5/2/2023 < 0.5 0.25 54 55 56 57 58 Use "PASTE SPECIAL Values" then "COPY" Maximum data points = 58 0.0855 0.2830 0.3019 53 1.01 0.500 ug/L 0.505 ug/L -3- 48879 RPA, data 7/24/2023 REASONABLE POTENTIAL ANALYSIS Par07 Date 1 5/5/2020 2 8/3/2021 3 2/8/2022 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Total Phenolic Compounds Data BDL=1/2DL Results < 10 5 Std Dev. < 20 10 Mean < 80 40 C.V. (default) n Mult Factor = Max. Value Max. Pred Cw Par10 Use "PASTE SPECIAL - Values" then "COPY". Maximum data points = 58 18.9297 18.3333 0.6000 3 3.00 40.0 ug/L 120.0 ug/L Date Data 1 1 /8/2019 < 2 2/5/2019 < 3 3/5/2019 < 4 4/2/2019 < 5 5/7/2019 < 6 6/4/2019 < 7 7/9/2019 < 8 8/6/2019 < 9 9/10/2019 < 10 10/8/2019 < 11 11 /5/2019 < 12 12/10/2019 < 13 1 /7/2020 < 14 2/4/2020 < 15 3/3/2020 < 16 4/7/2020 < 17 5/5/2020 < 18 6/2/2020 < 19 7/7/2020 < 20 8/11 /2020 < 21 9/1/2020 < 22 10/6/2020 < 23 11 /3/2020 < 24 12/1/2020 < 25 1 /5/2021 < 26 2/2/2021 < 27 3/2/2021 < 28 4/6/2021 < 29 5/4/2021 < 30 6/1/2021 < 31 7/6/2021 < 32 8/3/2021 < 33 9/7/2021 < 34 10/5/2021 < 35 11 /2/2021 < 36 12/7/2021 < 37 1 /4/2022 < 38 2/8/2022 < 39 3/8/2022 < 40 4/5/2022 < 41 5/3/2022 < 42 6/7/2022 < 43 7/12/2022 < 44 8/2/2022 < 45 9/13/2022 < 46 10/4/2022 < 47 11 /8/2022 < 48 12/6/2022 < 49 1/10/2023 < 50 2/7/2023 < 51 3/7/2023 < 52 4/11 /2023 < 53 5/2/2023 < 54 55 56 57 58 Chromium, Total BDL=1/2DL Results 5 2.5 Std Dev. 5 2.5 Mean 5 2.5 C.V. 5 2.5 n 5 2.5 5 2.5 Mult Factor = 5 2.5 Max. Value 5 2.5 Max. Pred Cw 5 2.5 5 2.5 5 2.5 5 2.5 5 2.5 5 2.5 5 2.5 5 2.5 5 2.5 5 2.5 5 2.5 5 2.5 5 2.5 5 2.5 5 2.5 5 2.5 5 2.5 5 2.5 5 2.5 5 2.5 5 2.5 5 2.5 5 2.5 5 2.5 5 2.5 5 2.5 5 2.5 5 2.5 5 2.5 5 2.5 5 2.5 5 2.5 5 2.5 5 2.5 5 2.5 5 2.5 5 2.5 5 2.5 5 2.5 5 2.5 5 2.5 5 2.5 5 2.5 5 2.5 5 2.5 Use "PASTE SPECIAL Values" then "COPY" Maximum data points = 58 0.0000 2.5000 0.0000 53 1.00 2.5 pg/L 2.5 pg/L 48879 RPA, data -4- 7/24/2023 REASONABLE POTENTIAL ANALYSIS Pal 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Date 1 /8/2019 2/5/2019 3/5/2019 4/2/2019 5/7/2019 6/4/2019 7/9/2019 8/6/2019 9/10/2019 10/8/2019 11 /5/2019 12/10/2019 1 /7/2020 2/4/2020 3/3/2020 4/7/2020 5/5/2020 6/2/2020 7/7/2020 8/11 /2020 9/1 /2020 10/6/2020 11 /3/2020 12/1 /2020 1 /5/2021 2/2/2021 3/2/2021 4/6/2021 5/4/2021 6/1 /2021 7/6/2021 8/3/2021 9/7/2021 10/5/2021 11 /2/2021 12/7/2021 1 /4/2022 2/8/2022 3/8/2022 4/5/2022 5/3/2022 6/7/2022 7/12/2022 8/2/2022 9/13/2022 10/4/2022 11 /8/2022 12/6/2022 1 /10/2023 2/7/2023 3/7/2023 4/11 /2023 5/2/2023 Data Copper BDL=1/2DL 4 4 4 4 4 4 3 3 4 4 2 2 3 3 2 2 2 2 2 2 3 3 3 3 4 4 2 2 3 3 2 2 3 3 2 2 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 4 4 5 5 4 4 4 4 3 3 5 5 4 4 4 4 4 4 5 5 4 4 5 5 5 5 3 3 4 4 4 4 3 3 4 4 4 4 6 6 4 4 5 5 4 4 4 4 6 6 4 4 3 3 Use "PASTE SPECIAL Values" then "COPY" Maximum data points = 58 Results Std Dev. 0.9891 Mean 3.5849 C.V. 0.2759 n 53 Mult Factor = 1.01 Max. Value 6.00 ug/L Max. Pred Cw 6.06 ug/L Par12 Use "PASTE SPECIAL Cyanide Values" then "COPY" Maximum data points = 58 Date Data BDL=1/2DL Results 1 1/8/2019 < 5 5 Std Dev. 0.0000 2 2/5/2019 < 5 5 Mean 5.00 3 3/5/2019 < 5 5 C.V. 0.0000 4 4/2/2019 < 5 5 n 56 5 5/7/2019 < 5 5 6 6/4/2019 < 5 5 Mult Factor = 1.00 7 7/9/2019 < 5 5 Max. Value 5.0 ug/L 8 8/6/2019 < 5 5 Max. Pred Cw 5.0 ug/L 9 9/10/2019 < 5.0 5 10 10/8/2019 < 5.0 5 11 11 /5/2019 < 5 5 12 12/10/2019 < 5 5 13 1 /7/2020 < 5 5 14 2/4/2020 < 5 5 15 3/3/2020 < 5 5 16 4/7/2020 < 5 5 17 5/5/2020 < 5 5 18 6/2/2020 < 5 5 19 7/7/2020 < 5 5 20 8/11/2020 < 5 5 21 9/1/2020 < 5 5 22 10/6/2020 < 5 5 23 11 /3/2020 < 5 5 24 12/1/2020 < 5 5 25 1 /5/2021 < 5 5 26 2/2/2021 < 5 5 27 3/2/2021 < 5 5 28 4/6/2021 < 5 5 29 5/4/2021 < 5 5 30 6/1/2021 < 5 5 31 7/6/2021 < 5 5 32 8/3/2021 < 5 5 33 9/7/2021 < 5 5 34 10/5/2021 < 5 5 35 11 /2/2021 < 5 5 36 12/7/2021 < 5 5 37 1 /4/2022 < 5 5 38 2/8/2022 < 5 5 39 3/8/2022 < 5 5 40 4/5/2022 6 5 41 5/3/2022 < 5 5 42 5/13/2022 < 5 5 43 5/15/2022 < 5 5 44 5/17/2022 < 5 5 45 6/7/2022 < 5 5 46 7/12/2022 < 5 5 47 8/2/2022 < 5 5 48 9/13/2022 < 5 5 49 10/4/2022 < 5 5 50 11 /8/2022 < 5 5 51 12/6/2022 < 5 5 52 1/10/2023 < 5 5 53 2/7/2023 < 5 5 54 3/7/2023 < 5 5 55 4/11/2023 < 5 5 56 5/2/2023 < 5 5 57 58 -5- 48879 RPA, data 7/24/2023 REASONABLE POTENTIAL ANALYSIS Par14 Use "PASTE SPECIAL Lead Values" then "COPY" Maximum data points = 58 Date BDL=1/2DL Results 1 1 /8/2019 < 5 2.5 Std Dev. 0.5127 2 2/5/2019 < 5 2.5 Mean 1.1981 3 3/5/2019 < 5 2.5 C.V. 0.4279 4 4/2/2019 < 5 2.5 n 53 5 5/7/2019 < 5 2.5 6 6/4/2019 < 5 2.5 Mult Factor = 1.02 7 7/9/2019 < 5 2.5 Max. Value 2.500 ug/L 8 8/6/2019 < 2 1 Max. Pred Cw 2.550 ug/L 9 9/10/2019 < 2 1 10 10/8/2019 < 2 1 11 11 /5/2019 < 2 1 12 12/10/2019 < 2 1 13 1 /7/2020 < 2 1 14 2/4/2020 < 2 1 15 3/3/2020 < 2 1 16 4/7/2020 < 2 1 17 5/5/2020 < 2 1 18 6/2/2020 < 2 1 19 7/7/2020 < 2 1 20 8/11 /2020 < 2 1 21 9/1/2020 < 2 1 22 10/6/2020 < 2 1 23 11 /3/2020 < 2 1 24 12/1/2020 < 2 1 25 1 /5/2021 < 2 1 26 2/2/2021 < 2 1 27 3/2/2021 < 2 1 28 4/6/2021 < 2 1 29 5/4/2021 < 2 1 30 6/1/2021 < 2 1 31 7/6/2021 < 2 1 32 8/3/2021 < 2 1 33 9/7/2021 < 2 1 34 10/5/2021 < 2 1 35 11 /2/2021 < 2 1 36 12/7/2021 < 2 1 37 1 /4/2022 < 2 1 38 2/8/2022 < 2 1 39 3/8/2022 < 2 1 40 4/5/2022 < 2 1 41 5/3/2022 < 2 1 42 6/7/2022 < 2 1 43 7/12/2022 < 2 1 44 8/2/2022 < 2 1 45 9/13/2022 < 2 1 46 10/4/2022 < 2 1 47 11 /8/2022 < 2 1 48 12/6/2022 < 2 1 49 1/10/2023 < 2 1 50 2/7/2023 < 2 1 51 3/7/2023 < 2 1 52 4/11/2023 < 2 1 53 5/2/2023 < 2 1 54 55 56 57 58 Par16 Use "PASTE SPECIAL Molybdenum Values" then "COPY" Maximum data points = 58 Date Data BDL=1/2DL Results 1 1/8/2019 < 5 2.5 Std Dev. 0.0000 2 2/5/2019 < 5 2.5 Mean 2.5000 3 3/5/2019 < 5 2.5 C.V. 0.0000 4 4/2/2019 < 5 2.5 n 53 5 5/7/2019 < 5 2.5 6 6/4/2019 < 5 2.5 Mult Factor = 1.00 7 7/9/2019 < 5 2.5 Max. Value 2.5 ug/L 8 8/6/2019 < 5 2.5 Max. Pred Cw 2.5 ug/L 9 9/10/2019 < 5 2.5 10 10/8/2019 < 5 2.5 11 11 /5/2019 < 5 2.5 12 12/10/2019 < 5 2.5 13 1 /7/2020 < 5 2.5 14 2/4/2020 < 5 2.5 15 3/3/2020 < 5 2.5 16 4/7/2020 < 5 2.5 17 5/5/2020 < 5 2.5 18 6/2/2020 < 5 2.5 19 7/7/2020 < 5 2.5 20 8/11/2020 < 5 2.5 21 9/1/2020 < 5 2.5 22 10/6/2020 < 5 2.5 23 11 /3/2020 < 5 2.5 24 12/1/2020 < 5 2.5 25 1 /5/2021 < 5 2.5 26 2/2/2021 < 5 2.5 27 3/2/2021 < 5 2.5 28 4/6/2021 < 5 2.5 29 5/4/2021 < 5 2.5 30 6/1/2021 < 5 2.5 31 7/6/2021 < 5 2.5 32 8/3/2021 < 5 2.5 33 9/7/2021 < 5 2.5 34 10/5/2021 < 5 2.5 35 11 /2/2021 < 5 2.5 36 12/7/2021 < 5 2.5 37 1 /4/2022 < 5 2.5 38 2/8/2022 < 5 2.5 39 3/8/2022 < 5 2.5 40 4/5/2022 < 5 2.5 41 5/3/2022 < 5 2.5 42 6/7/2022 < 5 2.5 43 7/12/2022 < 5 2.5 44 8/2/2022 < 5 2.5 45 9/13/2022 < 5 2.5 46 10/4/2022 < 5 2.5 47 11 /8/2022 < 5 2.5 48 12/6/2022 < 5 2.5 49 1/10/2023 < 5 2.5 50 2/7/2023 < 5 2.5 51 3/7/2023 < 5 2.5 52 4/11/2023 < 5 2.5 53 5/2/2023 < 5 2.5 54 55 56 57 58 M 48879 RPA, data 7/24/2023 REASONABLE POTENTIAL ANALYSIS Par17 & Par18 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Nickel Date Data BDL=1/2DL 1 /8/2019 < 10 5 2/5/2019 < 10 5 3/5/2019 < 10 5 4/2/2019 < 10 5 5/7/2019 < 10 5 6/4/2019 < 10 5 7/9/2019 < 10 5 8/6/2019 < 10 5 9/10/2019 < 10 5 10/8/2019 < 10 5 11 /5/2019 < 10 5 12/10/2019 < 10 5 1 /7/2020 < 10 5 2/4/2020 < 10 5 3/3/2020 < 10 5 4/7/2020 < 10 5 5/5/2020 < 2 1 6/2/2020 < 10 5 7/7/2020 < 10 5 8/11 /2020 < 10 5 9/1/2020 < 10 5 10/6/2020 < 10 5 11 /3/2020 < 10 5 12/1/2020 < 10 5 1 /5/2021 < 10 5 2/2/2021 < 10 5 3/2/2021 < 10 5 4/6/2021 < 10 5 5/4/2021 < 10 5 6/1/2021 < 10 5 7/6/2021 < 10 5 8/3/2021 < 10 5 9/7/2021 < 10 5 10/5/2021 < 10 5 11 /2/2021 < 10 5 12/7/2021 < 10 5 1 /4/2022 < 10 5 2/8/2022 < 10 5 3/8/2022 < 10 5 4/5/2022 < 10 5 5/3/2022 < 10 5 6/7/2022 < 10 5 7/12/2022 < 10 5 8/2/2022 < 10 5 9/13/2022 < 10 5 10/4/2022 < 10 5 11 /8/2022 < 10 5 12/6/2022 < 10 5 1/10/2023 < 10 5 2/7/2023 < 10 5 3/7/2023 < 10 5 4/11/2023 < 10 5 5/2/2023 < 10 5 Use"PASTE SPECIAL - Values" then "COPY". Maximum data Results points = 58 Std Dev. 0.5494 Mean 4.9245 C.V. 0.1116 n 53 Mult Factor = 1.01 Max. Value 5.0 pg/L Max. Pred Cw 5.1 dig/L Par19 Use "PASTE SPECIAL - Selenium Values" then "COPY". Maximum data points = 58 Date Data BDL=1/2DL Results 1 1 /8/2019 < 5 2.5 Std Dev. 0.2747 2 2/5/2019 < 5 2.5 Mean 2.4623 3 3/5/2019 < 5 2.5 C.V. 0.1116 4 4/2/2019 < 5 2.5 n 53 5 5/7/2019 < 5 2.5 6 6/4/2019 < 5 2.5 Mult Factor = 1.01 7 7/9/2019 < 5 2.5 Max. Value 2.5 ug/L 8 8/6/2019 < 5 2.5 Max. Pred Cw 2.5 ug/L 9 9/10/2019 < 5 2.5 10 10/8/2019 < 5 2.5 11 11 /5/2019 < 5 2.5 12 12/10/2019 < 5 2.5 13 1 /7/2020 < 5 2.5 14 2/4/2020 < 5 2.5 15 3/3/2020 < 5 2.5 16 4/7/2020 < 5 2.5 17 5/5/2020 < 1 0.5 18 6/2/2020 < 5 2.5 19 7/7/2020 < 5 2.5 20 8/11 /2020 < 5 2.5 21 9/1/2020 < 5 2.5 22 10/6/2020 < 5 2.5 23 11 /3/2020 < 5 2.5 24 12/1/2020 < 5 2.5 25 1 /5/2021 < 5 2.5 26 2/2/2021 < 5 2.5 27 3/2/2021 < 5 2.5 28 4/6/2021 < 5 2.5 29 5/4/2021 < 5 2.5 30 6/1/2021 < 5 2.5 31 7/6/2021 < 5 2.5 32 8/3/2021 < 5 2.5 33 9/7/2021 < 5 2.5 34 10/5/2021 < 5 2.5 35 11 /2/2021 < 5 2.5 36 12/7/2021 < 5 2.5 37 1 /4/2022 < 5 2.5 38 2/8/2022 < 5 2.5 39 3/8/2022 < 5 2.5 40 4/5/2022 < 5 2.5 41 5/3/2022 < 5 2.5 42 6/7/2022 < 5 2.5 43 7/12/2022 < 5 2.5 44 8/2/2022 < 5 2.5 45 9/13/2022 < 5 2.5 46 10/4/2022 < 5 2.5 47 11 /8/2022 < 5 2.5 48 12/6/2022 < 5 2.5 49 1/10/2023 < 5 2.5 50 2/7/2023 < 5 2.5 51 3/7/2023 < 5 2.5 52 4/11 /2023 < 5 2.5 53 5/2/2023 < 5 2.5 54 55 56 57 58 -7- 48879 RPA, data 7/24/2023 REASONABLE POTENTIAL ANALYSIS Par20 Use "PASTE SPECIAL Silver Values" then "COPY" Maximum data points = 58 Date Data BDL=1/2DL Results 1 1 /8/2019 < 1 0.5 Std Dev. 0.0000 2 2/5/2019 < 1 0.5 Mean 0.5000 3 3/5/2019 < 1 0.5 C.V. 0.0000 4 4/2/2019 < 1 0.5 n 53 5 5/7/2019 < 1 0.5 6 6/4/2019 < 1 0.5 Mult Factor = 1.00 7 7/9/2019 < 1 0.5 Max. Value 0.500 ug/L 8 8/6/2019 < 1 0.5 Max. Pred Cw 0.500 ug/L 9 9/10/2019 < 1 0.5 10 10/8/2019 < 1 0.5 11 11 /5/2019 < 1 0.5 12 12/10/2019 < 1 0.5 13 1 /7/2020 < 1 0.5 14 2/4/2020 < 1 0.5 15 3/3/2020 < 1 0.5 16 4/7/2020 < 1 0.5 17 5/5/2020 < 1 0.5 18 6/2/2020 < 1 0.5 19 7/7/2020 < 1 0.5 20 8/11 /2020 < 1 0.5 21 9/1/2020 < 1 0.5 22 10/6/2020 < 1 0.5 23 11 /3/2020 < 1 0.5 24 12/1/2020 < 1 0.5 25 1 /5/2021 < 1 0.5 26 2/2/2021 < 1 0.5 27 3/2/2021 < 1 0.5 28 4/6/2021 < 1 0.5 29 5/4/2021 < 1 0.5 30 6/1/2021 < 1 0.5 31 7/6/2021 < 1 0.5 32 8/3/2021 < 1 0.5 33 9/7/2021 < 1 0.5 34 10/5/2021 < 1 0.5 35 11 /2/2021 < 1 0.5 36 12/7/2021 < 1 0.5 37 1 /4/2022 < 1 0.5 38 2/8/2022 < 1 0.5 39 3/8/2022 < 1 0.5 40 4/5/2022 < 1 0.5 41 5/3/2022 < 1 0.5 42 6/7/2022 < 1 0.5 43 7/12/2022 < 1 0.5 44 8/2/2022 < 1 0.5 45 9/13/2022 < 1 0.5 46 10/4/2022 < 1 0.5 47 11 /8/2022 < 1 0.5 48 12/6/2022 < 1 0.5 49 1/10/2023 < 1 0.5 50 2/7/2023 < 1 0.5 51 3/7/2023 < 1 0.5 52 4/11/2023 < 1 0.5 53 5/2/2023 < 1 0.5 54 55 56 57 58 Par21 Use "PASTE SPECIAL Zinc Values" then "COPY" Maximum data points = 58 Date Data BDL=1/2DL Results 1 1/8/2019 53 53 Std Dev. 9.5212 2 2/5/2019 59 59 Mean 49.0377 3 3/5/2019 47 47 C.V. 0.1942 4 4/2/2019 52 52 n 53 5 5/7/2019 46 46 6 6/4/2019 26 26 Mult Factor = 1.01 7 7/9/2019 40 40 Max. Value 71.0 ug/L 8 8/6/2019 43 43 Max. Pred Cw 71.7 ug/L 9 9/10/2019 39 39 10 10/8/2019 46 46 11 11 /5/2019 43 43 12 12/10/2019 57 57 13 1 /7/2020 50 50 14 2/4/2020 41 41 15 3/3/2020 54 54 16 4/7/2020 46 46 17 5/5/2020 50 50 18 6/2/2020 30 30 19 7/7/2020 37 37 20 8/11/2020 41 41 21 9/1/2020 60 60 22 10/6/2020 62 62 23 11 /3/2020 71 71 24 12/1/2020 56 56 25 1 /5/2021 52 52 26 2/2/2021 59 59 27 3/2/2021 56 56 28 4/6/2021 53 53 29 5/4/2021 53 53 30 6/1/2021 44 44 31 7/6/2021 45 45 32 8/3/2021 48 48 33 9/7/2021 51 51 34 10/5/2021 50 50 35 11 /2/2021 57 57 36 12/7/2021 65 65 37 1 /4/2022 53 53 38 2/8/2022 62 62 39 3/8/2022 69 69 40 4/5/2022 57 57 41 5/3/2022 58 58 42 6/7/2022 51 51 43 7/12/2022 52 52 44 8/2/2022 35 35 45 9/13/2022 34 34 46 10/4/2022 42 42 47 11 /8/2022 50 50 48 12/6/2022 47 47 49 1/10/2023 45 45 50 2/7/2023 47 47 51 3/7/2023 46 46 52 4/11/2023 36 36 53 5/2/2023 33 33 54 55 56 57 58 48879 RPA, data 7/24/2023 REASONABLE POTENTIAL ANALYSIS Par22 Use"PASTE SPECIAL -Values" 1,4-dioxane then "COPY". Maximum data points = 58 Date Data BDL=1/2DL Results 1 3/8/2022 < 2 1 Std Dev. 0.0000 2 4/5/2022 < 2 1 Mean 1.0000 3 5/3/2022 < 2 1 C.V. 0.0000 4 6/14/2022 < 2 1 n 10 5 6/17/2022 < 2 1 6 9/13/2022 < 2 1 Mult Factor = 1.00 7 9/16/2022 < 2 1 Max. Value 1.0 pg/L 8 11/15/2022 < 2 1 Max. Pred Cw 1.0 pg/L 9 11/18/2022 < 2 1 10 3/14/2023 < 2 1 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 48879 RPA, data - 9 - 7/24/2023 Freshwater RPA - 95% Probability/95% Confidence Using Metal Translators MAXIMUM DATA POINTS = 58 Table 1. Project Information ❑ CHECK IF HQW OR ORW WQS Facility Name North Cary WRF WWTP/WTP Class IV NPDES Permit NCO048879 Outfall 001 Flow, Qw (MGD) 12.000 Receiving Stream Crabtree Creek HUC Number 03020201 Stream Class ElApply WS Hardness WQC B;NSW 7Q10s (cfs) 0.300 7Q10w (cfs) 0.80 30Q2 (cfs) 0.30 QA (cfs) 0.30 1 Q10s (cfs) 0.26 Effluent Hardness 59.21 mg/L (Avg) Upstream Hardness ------------- 31.89 mg/L (Avg) ------------------ Combined Hardness Chronic 58.7878 m gL Combined Hardness Acute 58.83 mg/L _,_-dioxane W__TVuse_dforconsideration of downstream WS waters. WS-V waters 26 miles Data Source(s) ❑ CHECK TO APPLY MODEL downstream. 7Q10s used as conservative estimate of 30Q2 and QA. REQUIRED DATA ENTRY Par01 Par02 Par03 Par04 Par05 Par061111111111 Par07 Par08 Par09 Par10 Par11 Par12 Par13 Par14 Par15 Par16 Par17 Par18 Par19 Par20 Par21 Par22 Par23 Par24 Table 2. Parameters of Concern Name WQs Type Chronic Modifier Acute PQL Units Arsenic Aquactic Life C 150 FW 340 ug/L Arsenic Human Health Water Supply C 10 HH/WS N/A ug/L Beryllium Aquatic Life NC 6.5 FW 65 ug/L Cadmium Aquatic Life NC 1.1255 FW 6.8362 ug/L Chlorides Aquatic Life NC 230 FW mg/L Chlorinated Phenolic Compounds Water Supply NC 1 A ug/L Total Phenolic Compounds Aquatic Life NC 300 A ug/L Chromium III Aquatic Life NC 237.1140 FW 1824.2883 ug/L Chromium VI Aquatic Life NC 11 FW 16 pg/L Chromium, Total Aquatic Life NC N/A FW N/A pg/L Copper Aquatic Life NC 16.3607 FW 23.4545 ug/L Cyanide Aquatic Life NC 5 FW 22 10 ug/L Fluoride Aquatic Life NC 1,800 FW ug/L Lead Aquatic Life NC 7.6382 FW 196.2184 ug/L Mercury Aquatic Life NC 12 FW 0.5 -,^" Molybdenum Human Health NC 2000 HH ug/L Nickel Aquatic Life NC 76.7350 FW 691.4428 pg/L Nickel Water Supply NC 25.0000 WS N/A pg/L Selenium Aquatic Life NC 5 FW 56 ug/L Silver Aquatic Life NC 0.06 FW 1.2917 ug/L Zinc Aquatic Life NC 261.4922 FW 259.5837 ug/L 1 ,4-dioxane Human Health C 0.35 HH pg/L 48879 RPA, input 7/24/2023 48879 RPA, input 7/24/2023 NCO048879 North Cary WRF CBOD monthly removal rate Month January-19 February-19 March-19 April-19 May-19 June-19 July-19 August-19 September-19 October-19 November-19 December-19 January-20 February-20 March-20 April-20 May-20 June-20 July-20 August-20 September-20 October-20 November-20 December-20 January-21 February-21 March-21 April-21 May-21 June-21 RR (%) 98.96 98.73 99.06 99.01 99.24 99.29 99.18 99.18 99.00 99.29 99.28 99.19 99.18 99.12 99.13 99.11 99.16 99.19 99.13 99.16 99.12 99.14 99.19 99.09 99.12 99.05 99.19 99.23 99.24 99.23 Month July-21 August-21 September-21 October-21 November-21 December-21 January-22 February-22 March-22 April-22 May-22 June-22 July-22 August-22 September-22 October-22 November-22 December-22 January-23 February-23 March-23 April-23 May-23 June-23 July-23 August-23 September-23 October-23 November-23 December-23 Overall CBOD removal rate RR (%) 99.15 99.19 99.23 99.27 99.27 99.30 99.10 99.25 99.22 99.20 99.22 99.22 99.21 99.16 99.19 99.22 99.21 99.22 99.11 99.19 99.22 99.19 99.04 99.16 7/6/2023 TSS monthly removal rate Month January-19 February-19 March-19 April-19 May-19 June-19 July-19 August-19 September-19 October-19 November-19 December-19 January-20 February-20 March-20 Apri I-20 May-20 June-20 July-20 August-20 September-20 October-20 November-20 December-20 January-21 February-21 March-21 April-21 May-21 June-21 RR (%) 99.14 99.13 99.25 99.15 99.16 99.25 99.22 99.16 99.08 99.29 99.24 99.07 99.25 99.25 99.19 99.02 99.13 99.19 99.04 99.08 99.12 99.12 99.25 99.10 99.03 99.08 99.21 99.23 99.27 99.26 Month July-21 August-21 September-21 October-21 November-21 December-21 January-22 February-22 March-22 April-22 May-22 June-22 July-22 August-22 September-22 October-22 November-22 December-22 January-23 February-23 March-23 April-23 May-23 June-23 July-23 August-23 September-23 October-23 November-23 December-23 Overall TSS removal rate RR (%) 99.22 99.26 99.28 99.32 99.24 99.30 99.06 99.25 99.20 99.18 99.24 99.23 99.32 99.22 99.25 99.17 99.24 99.20 99.11 99.22 99.18 99.19 99.08 99.19 I • ■ PO Box 7565 Asheville, NC 28802 Phone: (828) 350-9364 Fax: (828)350-9368 IN ,� Environmental Testing Solutions, Inc. August 23, 2019 Mr. Jason Parker North Cary WWTP 1900 Old Reedy Creek Road Cary, NC 27512 RE: ETS PROJECT NUMBER: 14399 Dear Mr. Parker: Enclosed are toxicity test results for samples from the North Cary WWTP received by Environmental Testing Solutions, Inc. August 06 through August 10, 2019. Parameter Test Procedure EPA Method Final Result Code Number Fathead Minnow (Pimephales promelas) Larval THP6C Survival and Growth, Test Method 1000.0 EPA-821-R-02-013 ChV >100% Note: ChV = Chronic Value. A numeric value representing the geometric mean of the highest concentration having no detectable impairment of survival or growth and the lowest concentration that does have a detectable impairment of survival or growth. If this test was performed as an NPDES requirement or by Administrative Letter, please enter the ChV value >100% on the Effluent Discharge Monitoring Form (MR-1) for the collection date August 05, 2018 using the parameter code THP6C. Additionally, please sign and submit the original DWQ Aquatic Toxicity Form (AT-5) by September 30, 2019. If you have any questions concerning these results, please feel free to contact me. Sincerely, .iln� urtlt�e:' Laboratory Director This report should not be reproduced, except in its entirety, without the written consent of Environmental Testing Solutions, Inc. The results in this report relate only to the samples submitted for analysis, North Carolina Certificate Numbers: Biological Analyses: 37, Drinking Water: 37786, Wastewater: 600 South Carolina Certificate Number: Clean Water Act: 99053-001 DIVISION OF WATER QUALITY April 22, 2002 To: Dave Goodrich, Supervisor NPDES Unit From: Susan A. Wilson, Environmental Engineer NPDES Unit Subject: Guidance Regarding Conductivity and Fecal Coliform Monitoring INSTREAM CONDUCTIVITY AND FECAL COLIFORM MONITORING GUIDANCE Fecal coliformn monitoring: Instream monitoring for fecal coliform may be removed from municipal or domestic wastewater permits (major or minor), unless the water body is impaired due to coliform or is a Class B waterbody. Conductivity monitoring: Instream monitoring for conductivity may be removed from all 100% domestic wastewater permits. Instream conductivity monitoring must remain for industrial discharges and domestic discharges that have a pretreatment program. https://ncconnect- my. sharepoint.com/personal/nick_coco_deq_nc_gov/Documents/Documents/Permits/Issued/2020- 21/NC0039594 Maiden WWTP/fecal and conductivity monitoring.doc 7/5/23 WQ5 = 12 ng/L Facility Name North Cary WRF/NC0048879 /Permit No. Total Mercury 1631E PQL = 0.5 ng/L Date Modifier Data Entry Value MERCURY WQBEL/TBEL EVALUATION V:2013-6 No Limit Required No MMP Required 7Q10s = 0.300 cfs WQBEL = 12.19 ng/L Permitted Flow = 12.000 47 ng/L 2/4/19 < 1 0.5 5/6/19 < 1 0.5 8/5/19 < 1 0.5 11/4/19 < 1 0.5 0.5 ng/L - Annual Average for 2019 2/3/20 < 1 0.5 5/4/20 < 1 0.5 8/10/20 < 1 0.5 11/2/20 < 1 0.5 0.5 ng/L - Annual Average for 2020 2/12/21 < 1 0.5 5/3/21 < 1 0.5 8/2/21 < 1 0.5 11/1/21 < 1 0.5 0.5 ng/L - Annual Average for 2021 2/7/22 < 1 0.5 5/2/22 < 1 0.5 8/1/22 < 1 0.5 11/7/22 < 1 0.5 0.5 ng/L - Annual Average for 2022 2/6/23 < 1 0.5 5/1/23 < 1 0.5 0.5 ng/L - Annual Average for 2023 North Cary WRF/NC0048879 Mercury Data Statistics (Method 1631E) 2019 2020 2021 2022 # of Samples 4 4 4 4 Annual Average, ng/L 0.5 0.5 0.5 0.50 Maximum Value, ng/L 0.50 0.50 0.50 0.5 TBEL, ng/L 47 WQBEL, ng/L 12.2 2023 0.5 0.5 Reduction in Frequency Evalaution Facility: North Cary WRF Permit No. NC0048879 Review period (use 3 5/2020 - 5/2023 yrs) Approval Criteria: Y/N? 1. Not currently under SOC Y 2. Not on EPA Quarterly noncompliance report Y 3. Facility or employees convicted of CWA violations N # of non monthly Monthly 3-yr mean # daily # daily Reduce Data Review Units average SOo/ (geo mean < 50%? 200% samples <15? 200% samples < 207 monthly > 2? #civil penalty > 1? Frequency? average limit limit MA for FC) MA >200% WA >200% limit asessment (Yes/No ) violations CBOD (Weighted) mg/L 8.625 5.80833 2.9 0 Y 11.6 0 Y 0 N 0 N Y TSS mg/L 45 30 15 0.5305519 Y 60 0 Y 0 N 0 N Y Ammonia (weighted) mg/L 2.125 0.70833 0.4 0.0469231 Y 1.42 0 Y 0 N 0 N Y Fecal Coliform #/100 400 200 100 0.871374 Y M 1800 0 1 Y 0 N 0 N Y United States Environmental Protection Agency Form Approved. EPA Washington, D.C. 20460 OMB No. 2040-0057 Water Compliance Inspection Report Approval expires 8-31-98 Section A: National Data System Coding (i.e., PCS) Transaction Code NPDES yr/mo/day Inspection Type Inspector Fac Type 1 IN 1 2 u 3 I NCO048879 111 121 23/06/16 I17 18 LC] I 19 I s I 20L] 21111I I I I I I I II I I I I I I I I I I I I I I I I I I I I I I I II I I I I I r6 Inspection Work Days Facility Self -Monitoring Evaluation Rating B1 QA ---------------------- Reserved ------------------- 67 1.0 701d I 711„ I 72 I r., I 71 I 74 79 I I I I I I I80 L—I ty L-1 I I Section B: Facility Data Name and Location of Facility Inspected (For Industrial Users discharging to POTW, also include Entry Time/Date Permit Effective Date POTW name and NPDES permit Number) 09:30AM 23/06/16 19/01/01 North Cary WRF 1900 Old Reedy Creek Rd Exit Time/Date Permit Expiration Date Cary NC 27513 01:OOPM 23/06/16 23/02/28 Name(s) of Onsite Representative(s)/Titles(s)/Phone and Fax Number(s) Other Facility Data Jonathan Andrew Bulla/ORC/919-677-0850/ Name, Address of Responsible Official/Title/Phone and Fax Number Contacted Donald Bradley Smith,PO Box 8005 Cary NC 275128005//919-469-4095/9194694304 No Section C: Areas Evaluated During Inspection (Check only those areas evaluated) Permit 0 Flow Measurement Operations & Maintenar Records/Reports Self -Monitoring Progran 0 Sludge Handling Dispo: Facility Site Review Effluent/Receiving Wate Laboratory Section D: Summary of Finding/Comments (Attach additional sheets of narrative and checklists as necessary) (See attachment summary) Name(s) and Signature(s) of Inspector(s) Agency/Office/Phone and Fax Numbers Date OriATuvia DWR/NPDES WW Permitting Unit/704-663-1699/ Kevin Fowler DWR/RRO WQ/919-791-4200/ Signature of Management Q A Reviewer Agency/Office/Phone and Fax Numbers Date Vanessa E Manuel DWR/RRO WQ/919-791-4200/ EPA Form 3560-3 (Rev 9-94) Previous editions are obsolete. Page# NPDES yr/mo/day Inspection Type NCO048879 I11 12I 23/06/16 117 18 i c i (Cont.) Section D: Summary of Finding/Comments (Attach additional sheets of narrative and checklists as necessary) On June 16, 2023, the DWR as conducted a compliance training inspection at the subject facility attended by: Ori Tuvia, Octovis Henriquez, Douglas Dowden, Min Xiao, Anjali Orlando, Nick coco, Fenton Brown and Kevin Fowler. The assistance of Jim Bridges and Jonathan Bulla was greatly appreciated during the inspection. Observations during the inspection are summarized below, as well as an inspection checklist is attached for your records. • The current permit expired February 28, 2023, the facility has submitted a permit renewal application in a timely manner and operates under the expired permit. The facility is permitted to discharge at a rate of 12.0 MGO and consists of: mechanical screening; influent pump station; grit and grease removal system; Nutrient removal system consisting of anaerobic selectors, oxidation ditches, anoxic zones and reaeration zones; secondary clarifiers; deep -bed sand filters; UV disinfection; cascade aeration; gravity belt thickeners; aerated sludge holding tanks. During the inspection one of the three reactor basins, one of two UV channels, and one of the three circular clarifiers were offline due to low flow. All online treatment units appeared to be operating satisfactorily. • The facility is a WW-4 Wastewater Treatment Plant and is staffed 24 hours/day 7 days a week. • Records Review: Discharge Monitoring Report records for February 2022 and February 2023 were reviewed with lab bench sheets and no transcription errors were noted. Chain of Custody forms are completed and kept on site. A daily operation log book is maintained and kept on site. Records are maintained for at least three years.- The laboratory on site is certified to analyze most permit parameters (lab cert. no. 107). Toxicity and Mercury are sent to private labs for analysis. A cursory review of the laboratory was conducted and the laboratory appeared to be properly operated. Field meter calibration records were reviewed.- Biosolids are thickened and temporarily stored on site in aerated tanks. The sludge is hauled to the South Cary WRF or Western Wake Regional WRF for aerobic digestion and thermal drying into Class A residuals.- The facility discharges to Crabtree creek, Class B, Nutrient Sensitive Waters, in the Neuse River basin. The right of way to the discharged point is maintained. The effluent was clear, trace amount of foam was observed, which dissipated within 100 feet of the outfall. No visible impacts were noted immediately downstream of the discharge point. It was noted that the receiving stream is actually an unnamed tributary to Crabtree Creek (Outfall 001 is about 100 yards away from the main channel of Crabtree Creek), the receiving stream of the facility will be revised when the permit is up for renewal. Page# Permit: NCO048879 Owner -Facility: North CaryWRF Inspection Date: 06/16/2023 Inspection Type: Compliance Evaluation Permit Yes No NA NE (If the present permit expires in 6 months or less). Has the permittee submitted a new 0 ❑ ❑ ❑ application? Is the facility as described in the permit? ❑ 0 ❑ ❑ # Are there any special conditions for the permit? M ❑ ❑ ❑ Is access to the plant site restricted to the general public? 0 ❑ ❑ ❑ Is the inspector granted access to all areas for inspection? 0 ❑ ❑ ❑ Comment: The current permit expired February 28, 2023, the facility has submitted a permit renewal application in a timely manner and operates under the expired permit. The receiving stream is actually an unnamed tributary to Crabtree Creek (Outfall 001 is about 100 yards away from the main channel of Crabtree Creek), receiving stream will be revised when the permit is up for renewal. Operations & Maintenance Yes No NA NE Is the plant generally clean with acceptable housekeeping? 0 ❑ ❑ ❑ Does the facility analyze process control parameters, for ex: MLSS, MCRT, Settleable 0 ❑ ❑ ❑ Solids, pH, DO, Sludge Judge, and other that are applicable? Comment: Facility analyzes the following parameters for process control: mixed liquor settleometer, suspended solids, pH, phosphax (PO4-P), nitratax (NOx), temperature; UV dose and flow; returned activated sludge flow; wasted sludge volume; alkalinity; and clarifier sludge blanket. Laboratory Yes No NA NE Are field parameters performed by certified personnel or laboratory? 0 ❑ ❑ ❑ Are all other parameters(excluding field parameters) performed by a certified lab? 0 ❑ ❑ ❑ # Is the facility using a contract lab? 0 ❑ ❑ ❑ # Is proper temperature set for sample storage (kept at less than or equal to 6.0 ■ ❑ ❑ ❑ degrees Celsius)? Incubator (Fecal Coliform) set to 44.5 degrees Celsius+/- 0.2 degrees? ■ ❑ ❑ ❑ Incubator (BOD) set to 20.0 degrees Celsius +/- 1.0 degrees? 0 ❑ ❑ ❑ Comment: The laboratory on site is certified to analyze most permit parameters (lab cert. no 107). Toxicity and Mercury are sent to private labs for analysis. A cursory review of the laboratory was conducted and the laboratory appeared to be properly operated. Field meter calibration records were reviewed Record Keeping Yes No NA NE Are records kept and maintained as required by the permit? 0 ❑ ❑ ❑ Is all required information readily available, complete and current? 0 ❑ ❑ ❑ Are all records maintained for 3 years (lab. reg. required 5 years)? 0 ❑ ❑ ❑ Page# 3 Permit: NCO048879 Owner -Facility: North Cary WRF Inspection Date: 06/16/2023 Inspection Type: Compliance Evaluation Record Keeping Yes No NA NE Are analytical results consistent with data reported on DMRs? 0 ❑ ❑ ❑ Is the chain -of -custody complete? 0 ❑ ❑ ❑ Dates, times and location of sampling Name of individual performing the sampling Results of analysis and calibration Dates of analysis Name of person performing analyses Transported COCs Are DMRs complete: do they include all permit parameters? 0 ❑ ❑ ❑ Has the facility submitted its annual compliance report to users and DWQ? ❑ ❑ ❑ (If the facility is = or > 5 MGD permitted flow) Do they operate 24/7 with a certified ❑ ❑ ❑ operator on each shift? Is the ORC visitation log available and current? 0 ❑ ❑ ❑ Is the ORC certified at grade equal to or higher than the facility classification? 0 ❑ ❑ ❑ Is the backup operator certified at one grade less or greater than the facility ❑ ❑ ❑ classification? Is a copy of the current NPDES permit available on site? 0 ❑ ❑ ❑ Facility has copy of previous year's Annual Report on file for review? ❑ ❑ ❑ Comment: Discharge Monitoring Report records for February 2022 and February 2023 were reviewed with lab bench sheets and no transcription errors were noted. Chain of Custody forms are completed and kept on site. A daily operation log book is maintained and kept on site. Records are maintained for at least three years Flow Measurement - Influent Yes No NA NE # Is flow meter used for reporting? ❑ 0 ❑ ❑ Is flow meter calibrated annually? 0 ❑ ❑ ❑ Is the flow meter operational? 0 ❑ ❑ ❑ (If units are separated) Does the chart recorder match the flow meter? ❑ ❑ 0 ❑ Comment: Influent and effluent flow meters are calibrated twice per year. Bar Screens Yes No NA NE Type of bar screen a.Manual b.Mechanical Are the bars adequately screening debris? 0 ❑ ❑ ❑ Page# 4 Permit: NC0048879 Inspection Date: 06/16/2023 Bar Screens Is the screen free of excessive debris? Is disposal of screening in compliance? Is the unit in good condition? Owner -Facility: North CaryWRF Inspection Type: Compliance Evaluation Yes No NA NE ■ ❑ ❑ ❑ ■ ❑ ❑ ❑ ■ ❑ ❑ ❑ Comment: Two coarse screens ( 1/ 2 inch) and two fine screens ( 1/ 4 inch). Manual bar screen serves as backup. Pump Station - Influent Yes No NA NE Is the pump wet well free of bypass lines or structures? 0 ❑ ❑ ❑ Is the wet well free of excessive grease? 0 ❑ ❑ ❑ Are all pumps present? 0 ❑ ❑ ❑ Are all pumps operable? ■ ❑ ❑ ❑ Are float controls operable? 0 ❑ ❑ ❑ Is SCADA telemetry available and operational? 0 ❑ ❑ ❑ Is audible and visual alarm available and operational? ❑ ❑ ❑ Comment: Influent pump station # land # 2, each with four pumps. Grit Removal Yes No NA NE Type of grit removal a.Manual ❑ b.Mechanical Is the grit free of excessive organic matter? 0 ❑ ❑ ❑ Is the grit free of excessive odor? 0 ❑ ❑ ❑ # Is disposal of grit in compliance? 0 ❑ ❑ ❑ Comment: Grease Removal Yes No NA NE # Is automatic grease removal present? ■ ❑ ❑ ❑ Is grease removal operating properly? ■ ❑ ❑ ❑ Comment: Influent Sampling Yes No NA NE # Is composite sampling flow proportional? 0 ❑ ❑ ❑ Is sample collected above side streams? 0 ❑ ❑ ❑ Is proper volume collected? M ❑ ❑ ❑ Page# 5 Permit: NCO048879 Owner -Facility: North CaryWRF Inspection Date: 06/16/2023 Inspection Type: Compliance Evaluation Influent Sampling Yes No NA NE Is the tubing clean? 0 ❑ ❑ ❑ # Is proper temperature set for sample storage (kept at less than or equal to 6.0 ■ ❑ ❑ ❑ degrees Celsius)? Is sampling performed according to the permit? ■ ❑ ❑ ❑ Comment: Comment: Flow proportional composite sample Aeration Basins Yes No NA NE Mode of operation Ext. Air Type of aeration system Diffused Is the basin free of dead spots? 0 ❑ ❑ ❑ Are surface aerators and mixers operational? 0 ❑ ❑ ❑ Are the diffusers operational? ■ ❑ ❑ ❑ Is the foam the proper color for the treatment process? 0 ❑ ❑ ❑ Does the foam cover less than 25% of the basin's surface? 0 ❑ ❑ ❑ Is the DO level acceptable? 0 ❑ ❑ ❑ Is the DO level acceptable?(1.0 to 3.0 mg/1) 0❑ ❑ ❑ Comment: Three trains of biological nutrient removal basins all trains have had a new diffuser system installed. Train A and B were on line, Train C was down due to low flow. Equalization Basins Is the basin aerated? Is the basin free of bypass lines or structures to the natural environment? Is the basin free of excessive grease? Are all pumps present? Are all pumps operable? Are float controls operable? Are audible and visual alarms operable? # Is basin size/volume adequate? Yes No NA NE • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ ❑ ❑ ❑ ■ ❑ ❑ ❑ ■ ❑ ❑ ❑ ■ ❑ ❑ ■ ❑ Comment: EQ basins used from the old WWTP, converted from two existing clarifiers, one with aeration, an EQ pump station. Nutrient Removal # Is total nitrogen removal required? # Is total phosphorous removal required? Yes No NA NE • ❑ ❑ ❑ • ❑ ❑ ❑ Page# 6 Permit: NC0048879 Inspection Date: 06/16/2023 Owner -Facility: North CaryWRF Inspection Type: Compliance Evaluation Nutrient Removal Yes No NA NE Type Biological # Is chemical feed required to sustain process? ❑ ■ ❑ ❑ Is nutrient removal process operating properly? ■ ❑ ❑ ❑ Comment: Being converted from two existing clarifiers, one with aeration, an EQ pump station was under construction at the time of inspection Secondary Clarifier Is the clarifier free of black and odorous wastewater? Is the site free of excessive buildup of solids in center well of circular clarifier? Are weirs level? Is the site free of weir blockage? Is the site free of evidence of short-circuiting? Is scum removal adequate? Is the site free of excessive floating sludge? Is the drive unit operational? Is the return rate acceptable (low turbulence)? Is the overflow clear of excessive solids/pin floc? Is the sludge blanket level acceptable? (Approximately'/4 of the sidewall depth) Comment: Two ( A and B) of three secondary clarifiers were on line. Yes No NA NE ■ ❑ ❑ ❑ ■ ❑ ❑ ❑ ■ ❑ ❑ ❑ ■ ❑ ❑ ❑ ■ ❑ ❑ ❑ ■ ❑ ❑ ❑ ■ ❑ ❑ ❑ ■ ❑ ❑ ❑ ■ ❑ ❑ ❑ ■ ❑ ❑ ❑ ■ ❑ ❑ ❑ Pumps-RAS-WAS Yes No NA NE Are pumps in place? ■ ❑ ❑ ❑ Are pumps operational? ■ ❑ ❑ ❑ Are there adequate spare parts and supplies on site? ■ ❑ ❑ ❑ Comment: Each clarifier has a RAS- WAS pump station, with two RAS pumps and one WAS pump. Filtration (High Rate Tertiary) Yes No NA NE Type of operation: Up flow Is the filter media present? ■ ❑ ❑ ❑ Is the filter surface free of clogging? ■ ❑ ❑ ❑ Is the filter free of growth? ■ ❑ ❑ ❑ Is the air scour operational? ■ ❑ ❑ ❑ Is the scouring acceptable? ■ ❑ ❑ ❑ Is the clear well free of excessive solids and filter media? ■ ❑ ❑ ❑ Page# 7 Permit: NCO048879 Owner -Facility: North CaryWRF Inspection Date: 06/16/2023 Inspection Type: Compliance Evaluation Filtration (High Rate Tertiary) Yes No NA NE Comment: Deep - bed sand filters with 12 cells are backwshed constantly. Disinfection - UV Yes No NA NE Are extra UV bulbs available on site? 0 ❑ ❑ ❑ Are UV bulbs clean? 0 ❑ ❑ ❑ Is UV intensity adequate? ■ ❑ ❑ ❑ Is transmittance at or above designed level? ■ ❑ ❑ ❑ Is there a backup system on site? ❑ ❑ 0 ❑ Is effluent clear and free of solids? 0 ❑ ❑ ❑ Comment: One of two UV channels were in use. Each channel has capacity of 21 MGD. Flow Measurement - Effluent Yes No NA NE # Is flow meter used for reporting? 0 ❑ ❑ ❑ Is flow meter calibrated annually? 0 ❑ ❑ ❑ Is the flow meter operational? 0 ❑ ❑ ❑ (If units are separated) Does the chart recorder match the flow meter? ❑ ❑ 0 ❑ Comment: Influent and effluent flow meters are calibrated twice per year. Effluent Sampling Yes No NA NE Is composite sampling flow proportional? 0 ❑ ❑ ❑ Is sample collected below all treatment units? 0 ❑ ❑ ❑ Is proper volume collected? 0 ❑ ❑ ❑ Is the tubing clean? ■ ❑ ❑ ❑ # Is proper temperature set for sample storage (kept at less than or equal to 6.0 0 ❑ ❑ ❑ degrees Celsius)? Is the facility sampling performed as required by the permit (frequency, sampling type ❑ ❑ ❑ representative)? Comment: The subject permit requires both grab and composite samples. Effluent Pipe Yes No NA NE Is right of way to the outfall properly maintained? 0 ❑ ❑ ❑ Are the receiving water free of foam other than trace amounts and other debris? 0 ❑ ❑ ❑ If effluent (diffuser pipes are required) are they operating properly? ❑ ❑ ■ ❑ Page# 8 Permit: NC0048879 Inspection Date: 06/16/2023 Effluent Pipe Comment: Upstream / Downstream Sampling Owner -Facility: North CaryWRF Inspection Type: Compliance Evaluation Is the facility sampling performed as required by the permit (frequency, sampling type, and sampling location)? Comment: Standby Power Is automatically activated standby power available? Is the generator tested by interrupting primary power source? Is the generator tested under load? Was generator tested & operational during the inspection? Do the generator(s) have adequate capacity to operate the entire wastewater site? Is there an emergency agreement with a fuel vendor for extended run on back-up power? Is the generator fuel level monitored? Comment: Chemical Feed Is containment adequate? Is storage adequate? Are backup pumps available? Is the site free of excessive leaking? Comment: Solids Handling Equipment Is the equipment operational? Is the chemical feed equipment operational? Is storage adequate? Is the site free of high level of solids in filtrate from filter presses or vacuum filters? Is the site free of sludge buildup on belts and/or rollers of filter press? Is the site free of excessive moisture in belt filter press sludge cake? The facility has an approved sludge management plan? Yes No NA NE Yes No NA NE ■ ❑ ❑ ❑ Yes No NA NE • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ ❑ ❑ ❑ ■ ❑ ❑ ❑ ❑ ❑ ❑ ■ ■ ❑ ❑ ❑ Yes No NA NE • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ Yes No NA NE • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ Page# 9 Permit: NCO048879 Inspection Date: 06/16/2023 Owner -Facility: North CaryWRF Inspection Type: Compliance Evaluation Solids Handling Equipment Yes No NA NE Comment: Two gravity belt thickeners dewater wasted sludge. Not in operation at the time of inspetion ( facility usually wastes sludge at night). Dewatered sludge is stored in two sludge holding tanks, and then taken to South Cary WRF or Western Wake Regional WRF for further treatment. Aerobic Digester Is the capacity adequate? Is the mixing adequate? Is the site free of excessive foaming in the tank? # Is the odor acceptable? # Is tankage available for properly waste sludge? Comment: Two 0. 75 million gallon aerated sludge holding tanks. Only one was in use. Yes No NA NE ❑ ❑ ❑ ❑ ❑ ❑ ❑ ❑ ❑ ❑ ❑ ❑ ❑ ❑ ❑ Page# 10 Whole Effluent Toxicity Testing and Self Monitoring Summary Newport WWTP NCO021555/001 County: Carteret Region: WIRO Basin: WOK03 Jan Apr Jul Oct Ceri7dPF Begin: 4/1/2013 Chr Lim: 82% T NonComp: 7Q10: 0.4 PF: 1.2 IWC: 66.0 Freq: Q J F M A M J J A S O 2019 Pass - - Pass - - Pass - - Pass 2020 Pass - - Pass - - Pass - - Pass 2021 Pass - - Pass - - Pass - - Pass 2022 Fail INVALID >100(P)>100 >100 Pass - - Pass - - Pass 2023 Pass - - Pass - - - - - - Newton - Clark Creek WWTP NCO036196/001 County: Catawba Region: MRO Basin: CTB35 Mar Jun Sep Dec Ceri7dPF Begin: 8/1/2021 chr lim: 56%@5MGD NonComp: Single 7Q10: 6.0 PF: 5.0 IWC: 56.32 Freq: Q J F M A M J J A S O 2019 - - Pass(s) - - Pass(s)>100(P) - - Pass >100 - 2020 - - Pass(s) - >100(P) Pass - - Pass >100(P) - 2021 - - Pass (S) Pass (S) - - Pass (s) Pass (s) >100 IF - - Pass (S) Pass (5) - 2022 - - Pass (S) Pass (S) - - Pass (5) Pass (S) - - Pass Pass - 2023 - - Pass Pass - - - - - - - Norfolk Southern Railway Co. -Linwood NCO029246/011 County: Davidson Region: WSRO Basin: YAD04 Mar Jun Sep Dec Ceri24PF Begin: 6/1/2014 Acu lim: 90% NonComp: Single 7Q10: 1.2 PF: 0.317 IWC: 29.0 Freq: Q J F M A M I J A S O 2019 Pass - H - - Pass - - H - 2020 - - H - - - - - Pass - 2021 Pass - Pass - - H - - H - 2022 - - Pass - - H - - H - 2023 - - H - - - - - - - North Cary WRF NCO048879/001 County: Wake Region: RRO Basin: NEU02 Feb May Aug Nov Ceri7dPF Begin: 1/1/2019 chr lim: 90% NonComp: Single 7Q10: 0.30 PF: 12.0 IWC: 90 Freq: Q J F M A M J J A S O 2019 - Pass - - Pass - - Pass - - 2020 - Pass - - >100(P) Pass - - Pass - - 2021 - Pass 97.5(P) - - Pass - - Pass - - 2022 - Pass - - >100(P)Pass - - Pass - - 2023 - Pass - - Pass - - - - - North Durham WRF NCO023841/001 County: Durham Region: RRO Basin: NEU01 Jan Apr Jul Oct Ceri7dPF Begin: 1/1/2020 chr lim: 90% NonComp: Single 7Q10: 0.075 PF: 20.0 IWC: 99.5 Freq: Q J F M A M J I A S O 2019 Pass - - Pass - - Pass - - Pass 2020 Pass - - Pass - - Pass - - Pass 2021 Pass - - Pass - - Pass - - Pass 2022 Pass - - Pass - - Pass - - Pass 2023 Pass>100 - - Pass 31.8 - - - - - - SOC JOC: N D SOC JOC: N D Pass(s) >100(P) Pass Pass (S) Pass (S) >100 Pass Pass SOC JOC: N D H INVALID H Pass SOC JOC: N D Pass Pass Pass Pass SOC JOC: N D Leeend: P= Fathead minnow (Pimohales oromelas). H=No Flow (facility is active). s = Split test between Certified Labs Page 77 of 115 AlB I C I D I E I F I G I H I I I J I K I L I M N 1 O 1 P Pollutants of Concern (POC) Review Form Version:2022.09.28 1 2 1. Facility's General Information Date of (draft) Review 7/24/2023 c. POC review due to: e. Contact Information 3 Date of (final) Review Municipal NPDES renewal ❑J Regional Office (RO) Raleigh 4 NPDES Permit Writer (pw) Nick Coco HWA-AT/LTMP Review ❑ RO PT Staff Cheng Zhang RO NPDES Staff Kevin Fowler 5 Perm ittee- Facility Name North Cary WRF New Industries ❑ Facility PT Staff, email Donald Johnson, don. lohnson(a)townofcary.org 6 7 NPDES Permit Number NCO048879 WWTP expansion ❑ f. Receiving Stream 8 NPDES Permit Effective Date Stream reclass./adjustment ❑ Outfall Chemical Addendum Submittal Outfall relocation/adjustment ❑ Receiving Stream: Crabtree Creek QA, cfs: Regulated; below Lake Crabtree 9 Date 10 NPDES Permit Public Notice Date 7Q10 update ❑ Stream Class B;NSW 7Q10 (S), cfs: 0.3 11 eDMR data evaluated from: 1/1/2019 to 5/31/2023 Other POC review trigger, explain: Oufall Lat. 35.50.16 Outfall Long. 78.46.50 12 a. WWTP Capacity Summary Outfall II 13 Current Permitted Flow, mgd Designed Flow, 12 n Receiving Stream: QA, cfs: 9 IF 14 Permitted SIU Flow, mgd 0.0140 d. IU Summary Stream Class 7Q10, cfs: 15 b. PT Docs. Summary # IUs Oufall Lat. Outfall Long. 16 IWS approval date 4/5/2019 # SIUs Is there a PWS intake downstream of the Facility's Outfall(s)? 0 YES ❑ NO 17 L L/STMP approval date: 11/19/2019 # CIUs Comments: 18 a) HWA-AT approval date 6/24/2019 # NSCIUs The nearest downstream water supply (WS-V) boundary is located approximately 26 miles downstream of the outfall # IUs w/Local E Permits or Other 19 L d ITypes 20 cn w 2. Industrial Users' Information. 21 d # Industrial User (IU) Name IU Activity IU Non Conventional Pollutans & Toxic Pollutant IUP Effective Date Z 1 Catalent Pharma Solutions, LLC 40 CFR 439 flow, temperature, pH, TSS, CBOD, ammonia, TKN, TN, TP, arsenic, cadmium, chromium, copper, cyanide, fluoride, lead, mercury, 1/1/2019 molybdenum, nickel, selenium, silver, zinc, acetone, n-Amyl acetate, ethyl acetate, isopropyl acetate, methylene chloride, ethanol, VOCs 22 23 24 25 26 27 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 2 3 4 5 6 Comment:1 3. Status of Pretreatment Program (check all that apply) Status of Pretreatment Program (check all that apply) ❑ 1) facility has no SIU's, does have Division approved Pretreatment Program that is INACTIVE ❑ 2) facility has no SIU's, does not have Division approved Pretreatment Program ❑ 3) facility has SIUs and DWQ approved Pretreatment Program 3a) Full Program with LTMP ❑ 3b) Modified Program with STMP ❑ 4) additional conditions regarding Pretreatment attached or listed below 0 5) facility's sludge is being land applied or composted 6) facility's sludge is incinerated (add Beryllium and Mercury sampling according to § 503.43) p 7) facility's sludge is taken to a landfill, if yes which landfill: 8) other Sludge Disposal Plan: ISludge is currently hauled to the South Cary WRF biosolids dryer producing Class A biosolids and a beneficial product for reuse as an agricultural fertilizer amendment. Sludge Permit No: Page 1 POC Review Form AlB I C I D I E I F I G I H I I I J I K I L I M I N 1 O 1 P 49 4. LTMP/STMP and HWA Review 50 PW: Find USTMP document, HWA spreadsheet, DMR, previous and new NPDES permit for next section. 51 Cn Cn c U a- Parameter of Concern (POC) Check List New NPDES POC Previous NPDES POC Required by EPA PT(1) POC due to Sludge (2) POC due to SIU (3) POTW POC (4) % Removal Rate L/STMF Effluent Freq. NPDEI Effluent Freq. PQLs review Comment 52 PQL from USTMP, ug/I Required PQL per NPDES permit Recomm. PQL, ug/I 0 Flow El El ❑ El53 54 0 ICBOD Li0 ❑ ❑ 55 0 TSS ❑ p ❑ ❑ ❑ 56 0 NH3 ❑ El ❑ ❑ ❑ 57 ❑ Arsenic ❑ ❑ 0 ❑ ❑ 2.0 58 ❑ Barium ❑ ❑ ❑ ❑ ❑ 59 ❑ Beryllium(5) ❑ ❑ ❑ ❑ ❑ 60 p Cadmium(1) ❑ ❑ p 0 ❑ ❑ 0.5 61 p Chromium(l) ❑ ❑ 0 p ❑ ❑ 5.0 62 0 Copper(1) ❑ ❑ 0 p ❑ ❑ 2.0 63 0 Cyanide ❑ ❑ p ❑ ❑ 64 p Lead(1) ❑ p p p ❑ ❑ 2.0 65 ❑ Mercury(5) ❑ ❑ p p ❑ 0.001 66 ❑ Molybdenum ❑ ❑ p ❑ ❑ 10.0 67 p Nickel(l) ❑ ❑ p p ❑ ❑ 68 0 Selenium ❑ p p ❑ ❑ 1.0 69 0 Silver ❑ ❑ p ❑ ❑ 1.0 70 0 Zinc(1) ❑ ❑ 0 ❑ ❑ 10.0 71 p Sludge Flow to Disposal p ❑ ❑ 72 p % Solids to Disposal p ❑ ❑ 73 ❑ Oil & Grease ❑ ❑ 74 0 TN ❑ 0 ❑ ❑ ❑ 75 0 TP ❑ 0 ❑ ❑ ❑ 76 0 TKN ❑ p ❑ ❑ ❑ 77 0 NO2+NO3 ❑ p ❑ ❑ ❑ 78 0 ❑ ❑ ❑ ❑ ❑ 80 [A ❑ ❑ ❑ ❑ ❑ 81 ❑ ❑ ❑ ❑ ❑ 82 ❑ ❑ ❑ ❑ ❑ 83 Footnotes: 84 (1) Always in the LTMP/STMP due to EPA -PT requirement 85 (2) Only in LTMP/STMP if listed in sludge permit 86 (3) Only in LTMP/STMP while SIU still discharges to POTW 87 (4) Only in LTMP/STMP when pollutant is of concern to POTW 88 (5) In LTMP/STMP, if sewage sludge is incinerated 89 Please use blue font for the info updated by pw 90 Please use red font for POC that need to be added/modified in USTMP sampling plan 91 Please font for POC that be from LISTIMIP POC listisampling 5. Comments use orange and strikethrough may removed plan- 92 Blue shaded cell (D60: H81): Parameters usually included under that POC list W 93 94 Facility Summary/background information/NPDES-PT regulatory action: POC to be added/modified in USTMP: 95 ORC's comments on IU/POC: 96 POC submitted through Chemical Addendum or Supplemental Chemical Datasheet: 97 Additional pollutants added to USTMP due to POTW s concerns: 98 NPDES pw's comments on IU/POC: 99 6. Pretreatment updates in response to NPDES permit renewal 100 NPDES Permit Effective Date 180 days after effective (date): Permit writer, please add list of required/recommended PT updates in NPDES permit cover letter. Page 2 POC Review Form NH3/TRC WLA Calculations Facility: North Cary W RF PermitNo. NC0048879 Prepared By: Nick Coco Enter Design Flow (MGD): 12 Enter s7Q10 (cfs): 0.3 Enter w7Q10 (cfs): 0.8 Total Residual Chlorine (TRC) Daily Maximum Limit (ug/1) Ammonia (Summer) Monthly Average Limit (mg NH3-N/1) s7Q10 (CFS) 0.3 s7Q10 (CFS) 0.3 DESIGN FLOW (MGD) 12 DESIGN FLOW (MGD) 12 DESIGN FLOW (CFS) 18.6 DESIGN FLOW (CFS) 18.6 STREAM STD (UG/L) 17.0 STREAM STD (MG/L) 1.0 Upstream Bkgd (ug/1) 0 Upstream Bkgd (mg/1) 0.22 IWC (%) 98.41 IWC (%) 98.41 Allowable Conc. (ug/1) 17 Allowable Conc. (mg/1) 1.0 Less stringent than current limit. Maintain limit. Ammonia (Winter) Monthly Average Limit (mg NH3-N/1) Fecal Coliform w7Q10 (CFS) 0.8 Monthly Average Limit: 200/100mI DESIGN FLOW (MGD) 12 (If DF >331; Monitor) DESIGN FLOW (CFS) 18.6 (If DF<331; Limit) STREAM STD (MG/L) 1.8 Dilution Factor (DF) 1.02 Upstream Bkgd (mg/1) 0.22 IWC (%) 95.88 Allowable Conc. (mg/1) 1.9 Less stringent than current limit. Maintain limit. Total Residual Chlorine 1. Cap Daily Max limit at 28 ug/I to protect for acute toxicity Ammonia (as NH3-N) 1. If Allowable Conc > 35 mg/I, Monitor Only 2. Monthly Avg limit x 3 = Weekly Avg limit (Municipals) 3. Monthly Avg limit x 5 = Daily Max limit (Non-Munis) If the allowable ammonia concentration is > 35 mg/L, no limit shall be imposed Fecal Coliform 1. Monthly Avg limit x 2 = 400/100 ml = Weekly Avg limit (Municipals) = Daily Max limit (Non -Muni) CA.RY LIVE INSPIRED" - July 7, 2023 Nick Coco Fngineer III NPDES Municipal Permitting Unit NC DEQ/ DWR/ Water Quality Permitting 1617 Mail Service Center Raleigh, NC. 27699-1617 Subject: NPDES Permit NO. NCO048879 monitoring frequency reduction request Dear Mr. Coco, The Town of Cary would like to submit, for your further review, a request to continue reduced monitoring frequency for C130D5, TSS, Ammonia, and Fecal Coliform. The facility has no more than one civil penalty assessment for the permit limit violations for each target parameter during the previous three years. The North Cary Water Reclamation Facility (WRF) does not have any civil penalty assessments for permit violations for any target parameters in the previous three-year period. Neither the permittee nor any of its employees have been convicted of criminal violations of the Clean Water Act within the previous five years. Neither the permittee nor any of the employees at the North Cary WRF have been convicted in the last five years of criminal violations of the Clean Water Act. 3. The facility is not currently under an SOC for target parameter effluent limit noncompliance. The North Cary WRF is not under a special order by consent (SOC) for target parameter effluent limit noncompliance. 4. The facility is not on the EPA's Quarterly Noncompliance Report for target parameter limit violations. The North Cary WRF is not on the EPA's Quarterly Noncompliance Report for target parameter limit violations. 5. For BODs, C130D5, NH3-N and TSS, the three-year arithmetic mean of effluent data must be less than fifty percent of the monthly average permit limit. For fecal coliform or enterococci, the three-year geometric mean must be less than 50 percent of the 919.677.0850 1 carync.gov PO Box 8005 Cary, NC 27512 monthly average permit limit. For parameters with summer and winter limits, an annual arithmetic mean of the season limits may be used in the calculation. The North Cary WRF effluent three-year arithmetic mean for CBODS, NH3-N, and TSS is less than 50% of the monthly seasonally adjusted permit limit. The fecal coliform three-year geometric mean is less than 50% of the monthly average permit limit. North Cary WRF (NC0048879) Effluent Data CB011S I Fecal Coliform TSS NH3-N m /L cfu/100m1 m /L m /L 3 Year (Avg.) 0.038 < 2.5 0.022 3 year Geometric mean 1.177 Permit Limit - Monthly Avg. 5.81 200 30 0.71 (Seasonally adjusted — CBOD & NH3 % 3 Yr. Avg./Permit Limit 0.7% 0.6% 0.0% 3.1% 6. With the exception of fecal coliform or enterococci, no more than 15 daily sampling results over the 3-year review period can be over 200% of the monthly average limit for BOD5, CBOD5, TSS, or NH3-N. Values associated with the documented impacts of extreme weather or events beyond the control of the permittee will not be included. There are no sampling results for CBOD5, TSS, or NH3-N in excess of 200% recorded in the past three years at the North Cary WRF. North Cary WRF (NC0048879) Effluent Data CBOD5 TSS NH3-N m /L 5.81 m /L 30 m /L 0.71 Permit Limit - Monthly Avg. Seasonal) adjusted — CBOD & NH3 3 Year (Max. Value) 2.77 0.0 0.93 % 3 Yr. Max Day/Permit 1 Limit 47.7% 0.0% 131% 7. For Fecal coliform or enterococci, no more than 20 daily sampling results may be over 200% of the weekly average limit. Values associated with the documented impacts of extreme weather or events beyond the control of the permittee will not be included. There are no sample results for Fecal coliform in excess of 200% of the weekly average limit recorded during the past three years at the North Cary WRF. North Cary WRF C0048879 Effluent Data Fecal Coliform cfu/ 1 OOmI Permit Limit - Weekly Avg. 400 3 Year (Max. Value) 113 % 3 Yr. Max Day/Permit Limit 28.3% CARY 2 uve iNyrusv- 8. For the four target parameters, sampling results shall not show more than two non - monthly (weekly) average limit violations during the previous year. The North Cary Water Reclamation facility had no (weekly) average limit violations during the previous year. North Cary WRF (NC0048879) Effluent Data CB0115 Fecal Uollform 11'S5 NH3-N mg/L cfu/100ml m /L m /L Permit Limit Weekly summer/winter 6.0/12.3 400 45 1.5/3.0 Max recorded value in the 2.21 113 0.0 0.19 past 12 months 9. Reduced effluent monitoring must not impair assessment of sensitive downstream uses, such as endangered species. The Town of Cary is not aware of any downstream use or assessment that would prohibit the reduction in effluent monitoring for CBODS, TSS, NH3-N and Fecal Coliform from a daily monitoring requirement. In meeting the criteria in the NC DWQ Guidance Regarding the Reduction of Monitoring Frequencies in NPDES Permits for Exceptionally Performing Facilities, the Town of Cary hereby requests a continuation of reduced effluent monitoring frequency for CBODS, TSS, NH3-N, and Fecal Coliform at the North Cary WRF. If you have any additional questions, or desire any additional information, please contact me at 919-677-0830 or e-mail me at ionathan.Buila@carync.gov. Respectfully Submitted, 1 athan Bulla NCWRF Manager CC: Jamie Revels, P.E., Utilities Director Jim Bridges, ORC, NCWRF Facility Operations Supervisor Jason Parker, NCWRF Laboratory Supervisor CARY /E INS Y I RED" Hayes, Mitch From: Jim Bridges Jim.bridges@carync.gov> Sent: Friday, May 19. 2023 3:10 PM To: Hayes, Mitch Cc: Jonathan Bulla Subject: [External] NCWRF Influent Composite Sampler Location CAUTION: External email. Do not click links or open attachments unless verified. Report suspicious emails with the Report Message button located on your Outlook menu bar on the Home tab. Mr. Hayes, This is a follow up email to our conversation this afternoon. We will be relocating our influent composite sampler from our regional pump station to our headworks while we do maintenance work at our pump station. This work will take approximately one week to complete and then the sampler will return to it's original location. We will note this change as a comment in our May el)MR. Thank you for talking with me this afternoon and if anything changes with this plan I will reach back out to you. Jim Bridges, ORC Facility Operations Supervisor North Cary Water Reclamation Facility CARYI,., IT!f^l- PO Box 8005 / Cary, NC 27512-8005 1900 Old Reedy Creek Rd. J Cary, NC 27513 Phone: 919-677-0850 1 Mobile:919-621-2019 Email: iim.bridses@caryncgo@caryncgo In keeping with the NC Public Records Law, e-malts, and attachments, may be released to others upon request for inspection and copying. CA ■■ -LIVE INSPIRED" - Date: June 2, 2023 Mr. Nick Coco Environmental Specialist III NCDEQ/Division of Water Resources 1617 Mail Service Center Raleigh, NC 27699-1617 ELECTRONIC SUBMITTAL Subject: Cary — North Cary WRF (NC0048879) PFAS Wastewater Testing Dear Mr. Coco, The Town of Cary — North Cary Water Reclamation Facility (NCWRF) would like to provide the NC Department of Environmental Quality information pertaining to per-polyfluoroalkyl substances (PFAS) sampled for and analyzed using non -certified analytical methods. The enclosed PFAS data represents wastewater treatment process monitoring that occurred during the period of calendar year 2020 to present. We performed this additional monitoring to better understand the presence and occurrence of PFAS at our water reclamation facility. Information provided in the enclosed summary spreadsheet include the following sampling locations and the sample identification abbreviations: Influent — influent wastewater without any plant recycle. Headworks (Inf + Rec) — influent wastewater combined with plant recycle streams such as filter backwash and GBT filtrate. Post Filter — sample taken upstream of ultraviolet light disinfection and cascade aeration. We hope that this submittal is found to be useful as we all continue to evaluate the emerging PFAS contaminants in NC. Please contact Jason Parker, NCWRF Laboratory Supervisor, by phone at 919-677- 0850 or by email at jason.parker@carync.gov if there are any specific questions regarding this submittal. Sincerely, Jonathan Bulla NCWRF Manager 919 677 0850 Jonathan.BuIla@carync.gov Enclosed: 2020 — 2023 NCWRF PFAS Supplemental Data Spreadsheet 919.469.4000 1 carync.gov PO Box 8005 Cary, NC 27512 Enter a date to enable droodowns for other columns Do NOT use a formula for these cells Qualifier Analyte Name Analyte Acronym Date Result ng/1 Qualifier Type Value Method Location Grab/Composite DWR / Permittee Regional Office Permit Type Permit Number Permit Name River Basin 10:2 Fluorotelomersulfonic Acid 10:2-FTS 2/25/2020 N.D. EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 4:2 Fluorotelomersulfonic Acid 4:2-FTS 2/25/2020 N.D. EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 6:2 Fluorotelomersulfonic Acid 6:2-FTS 2/25/2020 N.D. EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 8:2 Fluorotelomersulfonic Acid 8:2-FTS 2/25/2020 N.D. EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-ethyl perfluorooctanesulfonamidoacetic acid NEtFOSAA 2/25/2020 N.D. EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-ethylperfluoro-l-octanesulfonamide NEtPFOSA 2/25/2020 N.D. EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 2-(N ethyl perfluoro--octanesulfonamido)-ethanol NEtPFOSAE 2/25/2020 N.D. EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-methyl perfluorooctanesulfonamidoacetic acid NMeFOSAA 2/25/2020 N.D. EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-methylperfluoro-l-octanesulfonamide NMePFOSA 2/25/2020 N.D. EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 2-(N-methylperfluoro-l-octanesulfonamiso)-ethanol NMePFOSAE 2/25/2020 N.D. EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorobutanesulfonic Acid PFBS 2/25/2020 5.2 J EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorobutanoic Acid PFBA 2/25/2020 N.D. EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorodecanesulfonic Acid PFDS 2/25/2020 N.D. EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorodecanoic Acid PFDA 2/25/2020 N.D. EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorododecanesulfonic Acid PFDoS 2/25/2020 N.D. EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorododecanoic Acid PFDoDA 2/25/2020 N.D. EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroheptanesulfonic Acid PFHpS 2/25/2020 N.D. EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroheptanoic Acid PFHpA 2/25/2020 4.8 J EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexadecanoic Acid PFHxDA 2/25/2020 N.D. EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexanesulfonic Acid PFHxS 2/25/2020 N.D. EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexanoic Acid PFHxA 2/25/2020 15 J EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorononanesulfonic Acid PFNS 2/25/2020 N.D. EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorononanoic Acid PFNA 2/25/2020 N.D. EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctadecanoic Acid PFODA 2/25/2020 N.D. EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanesulfonamide PFOSA 2/25/2020 N.D. EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanesulfonic Acid PFOS 2/25/2020 N.D. EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanoic Acid PFOA 2/25/2020 5.4 J EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoropentanesulfonate PFPeS 2/25/2020 N.D. EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoropentanoic Acid PFPeA 2/25/2020 15 J EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorotetradecanoic Acid PFTeDA 2/25/2020 N.D. EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorotridecanoic Acid PFTrDA 2/25/2020 N.D. EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroundecanoic Acid PFUnDA 2/25/2020 N.D. EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 10:2 Fluorotelomersulfonic Acid 10:2-FTS 2/25/2020 N.D. EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 4:2 Fluorotelomersulfonic Acid 4:2-FTS 2/25/2020 N.D. EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 6:2 Fluorotelomersulfonic Acid 6:2-FTS 2/25/2020 N.D. EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 8:2 Fluorotelomersulfonic Acid 8:2-FTS 2/25/2020 N.D. EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-ethyl perfluorooctanesulfonamidoacetic acid NEtFOSAA 2/25/2020 N.D. EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-ethylperfluoro-l-octanesulfonamide NEtPFOSA 2/25/2020 N.D. EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 2-(N ethyl perfluoro--octanesulfonamido)-ethanol NEtPFOSAE 2/25/2020 N.D. EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-methyl perfluorooctanesulfonamidoacetic acid NMeFOSAA 2/25/2020 N.D. EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-methylperfluoro-l-octanesulfonamide NMePFOSA 2/25/2020 N.D. EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 2-(N-methylperfluoro-l-octanesulfonamiso)-ethanol NMePFOSAE 2/25/2020 N.D. EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorobutanesulfonic Acid PFBS 2/25/2020 5.7 J EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorobutanoic Acid PFBA 2/25/2020 29 J EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorodecanesulfonic Acid PFDS 2/25/2020 N.D. EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorodecanoic Acid PFDA 2/25/2020 N.D. EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorododecanesulfonic Acid PFDoS 2/25/2020 N.D. EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorododecanoic Acid PFDoDA 2/25/2020 N.D. EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroheptanesulfonic Acid PFHpS 2/25/2020 N.D. EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroheptanoic Acid PFHpA 2/25/2020 5.6 J EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexadecanoic Acid PFHxDA 2/25/2020 N.D. EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexanesulfonic Acid PFHxS 2/25/2020 N.D. EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexanoic Acid PFHxA 2/25/2020 15 J EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorononanesulfonic Acid PFNS 2/25/2020 N.D. EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorononanoic Acid PFNA 2/25/2020 N.D. EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctadecanoic Acid PFODA 2/25/2020 N.D. EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanesulfonamide PFOSA 2/25/2020 N.D. EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanesulfonic Acid PFOS 2/25/2020 N.D. EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanoic Acid PFOA 2/25/2020 5.9 J EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoropentanesulfonate PFPeS 2/25/2020 N.D. EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoropentanoic Acid PFPeA 2/25/2020 16 J EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorotetradecanoic Acid PFTeDA 2/25/2020 N.D. EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorotridecanoic Acid PFTrDA 2/25/2020 N.D. EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroundecanoic Acid PFUnDA 2/25/2020 N.D. EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 10:2 Fluorotelomersulfonic Acid 10:2-FTS 2/25/2020 N.D. EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 4:2 Fluorotelomersulfonic Acid 4:2-FTS 2/25/2020 N.D. EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 6:2 Fluorotelomersulfonic Acid 6:2-FTS 2/25/2020 N.D. EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 8:2 Fluorotelomersulfonic Acid 8:2-FTS 2/25/2020 N.D. EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-ethyl perfluorooctanesulfonamidoacetic acid NEtFOSAA 2/25/2020 N.D. EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-ethylperfluoro-l-octanesulfonamide NEtPFOSA 2/25/2020 N.D. EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 2-(N ethyl perfluoro--octanesulfonamido)-ethanol NEtPFOSAE 2/25/2020 N.D. EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-methyl perfluorooctanesulfonamidoacetic acid NMeFOSAA 2/25/2020 0.79 J EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-methylperfluoro-l-octanesulfonamide NMePFOSA 2/25/2020 N.D. EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 2-(N-methylperfluoro-l-octanesulfonamiso)-ethanol NMePFOSAE 2/25/2020 N.D. EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorobutanesulfonic Acid PFBS 2/25/2020 5.1 EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorobutanoic Acid PFBA 2/25/2020 11 EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorodecanesulfonic Acid PFDS 2/25/2020 N.D. EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorodecanoic Acid PFDA 2/25/2020 0.84 J EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorododecanesulfonic Acid jPFDoS 1 2/25/2020 1 N.D. I I I EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorododecanoic Acid jPFDoDA 1 2/25/2020 1 N.D. I I I EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroheptanesulfonic Acid PFHpS 2/25/2020 N.D. EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroheptanoic Acid PFHpA 2/25/2020 5.3 EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexadecanoic Acid PFHxDA 2/25/2020 N.D. EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexanesulfonic Acid PFHxS 2/25/2020 1.4 J EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexanoic Acid PFHxA 2/25/2020 19 EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorononanesulfonic Acid PFNS 2/25/2020 N.D. EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorononanoic Acid PFNA 2/25/2020 0.65 J EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctadecanoic Acid PFODA 2/25/2020 N.D. EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanesulfonamide PFOSA 2/25/2020 0.53 J EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanesulfonic Acid PFOS 2/25/2020 4.1 EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanoic Acid PFOA 2/25/2020 6.6 EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoropentanesulfonate PFPeS 2/25/2020 N.D. EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoropentanoic Acid PFPeA 2/25/2020 16 EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorotetradecanoic Acid PFTeDA 2/25/2020 N.D. EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorotridecanoic Acid PFTrDA 2/25/2020 N.D. EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroundecanoic Acid PFUnDA 2/25/2020 N.D. EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 10:2 Fluorotelomersulfonic Acid 10:2-FTS 6/9/2020 N.D. U EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 4:2 Fluorotelomersulfonic Acid 4:2-FTS 6/9/2020 N.D. U EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 6:2 Fluorotelomersulfonic Acid 6:2-FTS 6/9/2020 N.D. U EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 8:2 Fluorotelomersulfonic Acid 8:2-FTS 6/9/2020 N.D. U EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-ethyl perfluorooctanesulfonamidoacetic acid NEtFOSAA 6/9/2020 0.55 J EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-ethylperfluoro-l-octanesulfonamide NEtPFOSA 6/9/2020 N.D. U EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 2-(N ethyl perfluoro--octanesulfonamido)-ethanol NEtPFOSAE 6/9/2020 N.D. U EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-methyl perfluorooctanesulfonamidoacetic acid NMeFOSAA 6/9/2020 0.86 J EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-methylperfluoro-l-octanesulfonamide NMePFOSA 6/9/2020 N.D. U EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 2-(N-methylperfluoro-l-octanesulfonamiso)-ethanol NMePFOSAE 6/9/2020 5.5 EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorobutanesulfonic Acid PFBS 6/9/2020 4.1 EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorobutanoic Acid PFBA 6/9/2020 8.5 EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorodecanesulfonic Acid PFDS 6/9/2020 2.7 EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorodecanoic Acid PFDA 6/9/2020 N.D. U EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorododecanesulfonic Acid PFDoS 6/9/2020 N.D. U EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorododecanoic Acid PFDoDA 6/9/2020 N.D. U EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroheptanesulfonic Acid PFHpS 6/9/2020 N.D. U EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroheptanoic Acid PFHpA 6/9/2020 4.4 EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexadecanoic Acid PFHxDA 6/9/2020 N.D. U EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexanesulfonic Acid PFHxS 6/9/2020 2.5 EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexanoic Acid PFHxA 6/9/2020 14 EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorononanesulfonic Acid PFNS 6/9/2020 N.D. U EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorononanoic Acid PFNA 6/9/2020 0.79 J EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctadecanoic Acid PFODA 6/9/2020 N.D. U*1 EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanesulfonamide PFOSA 6/9/2020 N.D. U EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanesulfonic Acid PFOS 6/9/2020 5.1 EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanoic Acid PFOA 6/9/2020 4.9 EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoropentanesulfonate PFPeS 6/9/2020 N.D. U EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoropentanoic Acid PFPeA 6/9/2020 11 EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorotetradecanoic Acid PFTeDA 6/9/2020 N.D. U EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorotridecanoic Acid PFTrDA 6/9/2020 N.D. U EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroundecanoic Acid PFUnDA 6/9/2020 N.D. U EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 10:2 Fluorotelomersulfonic Acid 10:2-FTS 6/9/2020 N.D. U EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 4:2 Fluorotelomersulfonic Acid 4:2-FTS 6/9/2020 ND U EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 6:2 Fluorotelomersulfonic Acid 6:2-FTS 6/9/2020 ND U EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 8:2 Fluorotelomersulfonic Acid 8:2-FTS 6/9/2020 ND U EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-ethyl perfluorooctanesulfonamidoacetic acid NEtFOSAA 6/9/2020 0.52 J EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-ethylperfluoro-l-octanesulfonamide NEtPFOSA 6/9/2020 ND U EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 2-(N ethyl perfluoro--octanesulfonamido)-ethanol NEtPFOSAE 6/9/2020 ND U EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-methyl perfluorooctanesulfonamidoacetic acid NMeFOSAA 6/9/2020 1.2 J EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-methylperfluoro-l-octanesulfonamide NMePFOSA 6/9/2020 ND U EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 2-(N-methylperfluoro-l-octanesulfonamiso)-ethanol NMePFOSAE 6/9/2020 3.1 EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorobutanesulfonic Acid PFBS 6/9/2020 6.4 EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorobutanoic Acid PFBA 6/9/2020 9.2 EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorodecanesulfonic Acid PFDS 6/9/2020 0.59 J EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorodecanoic Acid PFDA 6/9/2020 1.0 J EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorododecanesulfonic Acid PFDoS 6/9/2020 ND U EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorododecanoic Acid PFDoDA 6/9/2020 ND U EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroheptanesulfonic Acid PFHpS 6/9/2020 ND U EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroheptanoic Acid PFHpA 6/9/2020 4.7 EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexadecanoic Acid PFHxDA 6/9/2020 ND U EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexanesulfonic Acid PFHxS 6/9/2020 2.2 EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexanoic Acid PFHxA 6/9/2020 20 EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorononanesulfonic Acid PFNS 6/9/2020 ND U EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorononanoic Acid PFNA 6/9/2020 0.74 J EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctadecanoic Acid PFODA 6/9/2020 ND U EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanesulfonamide PFOSA 6/9/2020 ND U EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanesulfonic Acid PFOS 6/9/2020 3.0 EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanoic Acid PFOA 6/9/2020 6.4 EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoropentanesulfonate PFPeS 6/9/2020 1.2 J EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoropentanoic Acid PFPeA 6/9/2020 14 EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorotetradecanoic Acid PFTeDA 6/9/2020 ND U EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorotridecanoic Acid PFTrDA 6/9/2020 ND U EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroundecanoic Acid PFUnDA 6/9/2020 ND U EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 10:2 Fluorotelomersulfonic Acid 10:2-FTS 6/9/2020 ND U EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 4:2 Fluorotelomersulfonic Acid 4:2-FTS 1 6/9/2020 1 ND I U EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 6:2 Fluorotelomersulfonic Acid 6:2-FTS 1 6/9/2020 1 ND I U EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 8:2 Fluorotelomersulfonic Acid 8:2-FTS 6/9/2020 ND U EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-ethyl perfluorooctanesulfonamidoacetic acid NEtFOSAA 6/9/2020 ND U EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-ethylperfluoro-l-octanesulfonamide NEtPFOSA 6/9/2020 ND U EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 2-(N ethyl perfluoro--octanesulfonamido)-ethanol NEtPFOSAE 6/9/2020 ND U EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-methyl perfluorooctanesulfonamidoacetic acid NMeFOSAA 6/9/2020 1.7 J EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-methylperfluoro-l-octanesulfonamide NMePFOSA 6/9/2020 ND U EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 2-(N-methylperfluoro-l-octanesulfonamiso)-ethanol NMePFOSAE 6/9/2020 ND U EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorobutanesulfonic Acid PFBS 6/9/2020 10 EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorobutanoic Acid PFBA 6/9/2020 ND U EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorodecanesulfonic Acid PFDS 6/9/2020 ND U EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorodecanoic Acid PFDA 6/9/2020 1.5 J EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorododecanesulfonic Acid PFDoS 6/9/2020 ND U EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorododecanoic Acid PFDoDA 6/9/2020 ND U EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroheptanesulfonic Acid PFHpS 6/9/2020 ND U EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroheptanoic Acid PFHpA 6/9/2020 5.3 EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexadecanoic Acid PFHxDA 6/9/2020 ND U EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexanesulfonic Acid PFHxS 6/9/2020 1.5 J EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexanoic Acid PFHxA 6/9/2020 39 EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorononanesulfonic Acid PFNS 6/9/2020 ND U EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorononanoic Acid PFNA 6/9/2020 0.99 J EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctadecanoic Acid PFODA 6/9/2020 ND U EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanesulfonamide PFOSA 6/9/2020 0.52 J EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanesulfonic Acid PFOS 6/9/2020 5.5 EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanoic Acid PFOA 6/9/2020 ND U EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoropentanesulfonate PFPeS 6/9/2020 ND U EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoropentanoic Acid PFPeA 6/9/2020 25 EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorotetradecanoic Acid PFTeDA 6/9/2020 ND U EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorotridecanoic Acid PFTrDA 6/9/2020 ND U EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroundecanoic Acid PFUnDA 6/9/2020 ND U EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 10:2 Fluorotelomersulfonic Acid 10:2-FTS 9/15/2020 N.D. U EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 4:2 Fluorotelomersulfonic Acid 4:2-FTS 9/15/2020 N.D. U EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 6:2 Fluorotelomersulfonic Acid 6:2-FTS 9/15/2020 N.D. U EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 8:2 Fluorotelomersulfonic Acid 8:2-FTS 9/15/2020 N.D. U EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-ethyl perfluorooctanesulfonamidoacetic acid NEtFOSAA 9/15/2020 N.D. U EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-ethylperfluoro-l-octanesulfonamide NEtPFOSA 9/15/2020 N.D. U EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 2-(N ethyl perfluoro--octanesulfonamido)-ethanol NEtPFOSAE 9/15/2020 N.D. U EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-methyl perfluorooctanesulfonamidoacetic acid NMeFOSAA 9/15/2020 N.D. U EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-methylperfluoro-l-octanesulfonamide NMePFOSA 9/15/2020 N.D. U EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 2-(N-methylperfluoro-l-octanesulfonamiso)-ethanol NMePFOSAE 9/15/2020 N.D. U EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorobutanesulfonic Acid PFBS 9/15/2020 N.D. U EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorobutanoic Acid PFBA 9/15/2020 N.D. U EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorodecanesulfonic Acid PFDS 9/15/2020 N.D. U EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorodecanoic Acid PFDA 9/15/2020 N.D. U EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorododecanesulfonic Acid PFDoS 9/15/2020 N.D. U EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorododecanoic Acid PFDoDA 9/15/2020 N.D. U EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroheptanesulfonic Acid PFHpS 9/15/2020 N.D. U EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroheptanoic Acid PFHpA 9/15/2020 N.D. U EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexadecanoic Acid PFHxDA 9/15/2020 N.D. U EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexanesulfonic Acid PFHxS 9/15/2020 N.D. U EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexanoic Acid PFHxA 9/15/2020 8.6 J EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorononanesulfonic Acid PFNS 9/15/2020 N.D. U EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorononanoic Acid PFNA 9/15/2020 N.D. U EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctadecanoic Acid PFODA 9/15/2020 N.D. U EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanesulfonamide PFOSA 9/15/2020 N.D. U EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanesulfonic Acid PFOS 9/15/2020 8.5 A EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanoic Acid PFOA 9/15/2020 N.D. U EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoropentanesulfonate PFPeS 9/15/2020 N.D. U EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoropentanoic Acid PFPeA 9/15/2020 13 J EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorotetradecanoic Acid PFTeDA 9/15/2020 N.D. U EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorotridecanoic Acid PFTrDA 9/15/2020 N.D. U EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroundecanoic Acid PFUnDA 9/15/2020 N.D. U EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse HFPODA GenX 9/15/2020 N.D. U EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse DONA ADONA 9/15/2020 N.D. U EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 9CI-PF3ONS F53B 9/15/2020 N.D. U EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 11C1-PF3OUdS F53B 9/15/2020 N.D. U EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 10:2 Fluorotelomersulfonic Acid 10:2-FTS 9/15/2020 N.D. U EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 4:2 Fluorotelomersulfonic Acid 4:2-FTS 9/15/2020 N.D. U EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 6:2 Fluorotelomersulfonic Acid 6:2-FTS 9/15/2020 N.D. U EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 8:2 Fluorotelomersulfonic Acid 8:2-FTS 9/15/2020 N.D. U EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-ethyl perfluorooctanesulfonamidoacetic acid NEtFOSAA 9/15/2020 N.D. U EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-ethylperfluoro-l-octanesulfonamide NEtPFOSA 9/15/2020 N.D. U EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 2-(N ethyl perfluoro--octanesulfonamido)-ethanol NEtPFOSAE 9/15/2020 N.D. U EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-methyl perfluorooctanesulfonamidoacetic acid NMeFOSAA 9/15/2020 N.D. U EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-methylperfluoro-l-octanesulfonamide NMePFOSA 9/15/2020 N.D. U EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 2-(N-methylperfluoro-l-octanesulfonamiso)-ethanol NMePFOSAE 9/15/2020 N.D. U EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorobutanesulfonic Acid PFBS 9/15/2020 5.2 A EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorobutanoic Acid PFBA 9/15/2020 N.D. U EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorodecanesulfonic Acid PFDS 9/15/2020 N.D. U EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorodecanoic Acid PFDA 9/15/2020 N.D. U EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorododecanesulfonic Acid PFDoS 9/15/2020 N.D. U EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorododecanoic Acid PFDoDA 9/15/2020 N.D. U EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroheptanesulfonic Acid jPFHpS 1 9/15/2020 1 N.D. I U I EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroheptanoic Acid jPFHpA 1 9/15/2020 1 N.D. I U I EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexadecanoic Acid PFHxDA 9/15/2020 N.D. U EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexanesulfonic Acid PFHxS 9/15/2020 N.D. U EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexanoic Acid PFHxA 9/15/2020 9.5 J EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorononanesulfonic Acid PFNS 9/15/2020 N.D. U EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorononanoic Acid PFNA 9/15/2020 N.D. U EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctadecanoic Acid PFODA 9/15/2020 N.D. U EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanesulfonamide PFOSA 9/15/2020 N.D. U EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanesulfonic Acid PFOS 9/15/2020 6.1 J EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanoic Acid PFOA 9/15/2020 5.3 J EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoropentanesulfonate PFPeS 9/15/2020 N.D. U EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoropentanoic Acid PFPeA 9/15/2020 14 J EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorotetradecanoic Acid PFTeDA 9/15/2020 N.D. U EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorotridecanoic Acid PFTrDA 9/15/2020 N.D. U EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroundecanoic Acid PFUnDA 9/15/2020 N.D. U EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse HFPODA GenX 9/15/2020 N.D. U EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse DONA ADONA 9/15/2020 N.D. U EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 9CI-PF3ONS F53B 9/15/2020 N.D. U EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 11C1-PF3OUdS F53B 9/15/2020 N.D. U EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 10:2 Fluorotelomersulfonic Acid 10:2-FTS 9/15/2020 N.D. U EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 4:2 Fluorotelomersulfonic Acid 4:2-FTS 9/15/2020 N.D. U EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 6:2 Fluorotelomersulfonic Acid 6:2-FTS 9/15/2020 2.2 J EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 8:2 Fluorotelomersulfonic Acid 8:2-FTS 9/15/2020 N.D. U EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-ethyl perfluorooctanesulfonamidoacetic acid NEtFOSAA 9/15/2020 N.D. U EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-ethylperfluoro-l-octanesulfonamide NEtPFOSA 9/15/2020 N.D. U EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 2-(N ethyl perfluoro--octanesulfonamido)-ethanol NEtPFOSAE 9/15/2020 N.D. U EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-methyl perfluorooctanesulfonamidoacetic acid NMeFOSAA 9/15/2020 1.4 J EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-methylperfluoro-l-octanesulfonamide NMePFOSA 9/15/2020 N.D. U EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 2-(N-methylperfluoro-l-octanesulfonamiso)-ethanol NMePFOSAE 9/15/2020 N.D. U EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorobutanesulfonic Acid PFBS 9/15/2020 5.0 EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorobutanoic Acid PFBA 9/15/2020 10 EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorodecanesulfonic Acid PFDS 9/15/2020 N.D. U EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorodecanoic Acid PFDA 9/15/2020 1.7 J EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorododecanesulfonic Acid PFDoS 9/15/2020 N.D. U EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorododecanoic Acid PFDoDA 9/15/2020 N.D. U EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroheptanesulfonic Acid PFHpS 9/15/2020 N.D. U EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroheptanoic Acid PFHpA 9/15/2020 2.4 EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexadecanoic Acid PFHxDA 9/15/2020 N.D. U EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexanesulfonic Acid PFHxS 9/15/2020 1.1 J EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexanoic Acid PFHxA 9/15/2020 22 EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorononanesulfonic Acid PFNS 9/15/2020 N.D. U EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorononanoic Acid PFNA 9/15/2020 0.64 J EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctadecanoic Acid PFODA 9/15/2020 N.D. U EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanesulfonamide PFOSA 9/15/2020 N.D. U EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanesulfonic Acid PFOS 9/15/2020 5.0 EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanoic Acid PFOA 9/15/2020 14 EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoropentanesulfonate PFPeS 9/15/2020 N.D. U EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoropentanoic Acid PFPeA 9/15/2020 38 EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorotetradecanoic Acid PFTeDA 9/15/2020 N.D. U EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorotridecanoic Acid PFTrDA 9/15/2020 N.D. U EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroundecanoic Acid PFUnDA 9/15/2020 N.D. U EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse HFPODA GenX 9/15/2020 N.D. U EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse DONA ADONA 9/15/2020 N.D. U EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 9CI-PF3ONS F53B 9/15/2020 N.D. U EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 11C1-PF3OUdS F53B 9/15/2020 N.D. U EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 10:2 Fluorotelomersulfonic Acid 10:2-FTS 11/17/2020 ND U EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 4:2 Fluorotelomersulfonic Acid 4:2-FTS 11/17/2020 ND U EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 6:2 Fluorotelomersulfonic Acid 6:2-FTS 11/17/2020 ND U EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 8:2 Fluorotelomersulfonic Acid 8:2-FTS 11/17/2020 ND U EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-ethyl perfluorooctanesulfonamidoacetic acid NEtFOSAA 11/17/2020 ND U EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-ethylperfluoro-l-octanesulfonamide NEtPFOSA 11/17/2020 ND U EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 2-(N ethyl perfluoro--octanesulfonamido)-ethanol NEtPFOSAE 11/17/2020 ND U EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-methyl perfluorooctanesulfonamidoacetic acid NMeFOSAA 11/17/2020 ND U EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-methylperfluoro-l-octanesulfonamide NMePFOSA 11/17/2020 ND U EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 2-(N-methylperfluoro-l-octanesulfonamiso)-ethanol NMePFOSAE 11/17/2020 ND U EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorobutanesulfonic Acid PFBS 11/17/2020 6.4 J EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorobutanoic Acid PFBA 11/17/2020 ND U EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorodecanesulfonic Acid PFDS 11/17/2020 ND U EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorodecanoic Acid PFDA 11/17/2020 ND U EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorododecanesulfonic Acid PFDoS 11/17/2020 ND U EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorododecanoic Acid PFDoDA 11/17/2020 ND U EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroheptanesulfonic Acid PFHpS 11/17/2020 ND U EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroheptanoic Acid PFHpA 11/17/2020 ND U EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexadecanoic Acid PFHxDA 11/17/2020 ND U EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexanesulfonic Acid PFHxS 11/17/2020 ND U EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexanoic Acid PFHxA 11/17/2020 16 J EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorononanesulfonic Acid PFNS 11/17/2020 ND U EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorononanoic Acid PFNA 11/17/2020 ND U EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctadecanoic Acid PFODA 11/17/2020 ND U EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanesulfonamide PFOSA 11/17/2020 ND U EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanesulfonic Acid PFOS 11/17/2020 11 JI EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanoic Acid PFOA 11/17/2020 7.5 J EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoropentanesulfonate jPFPeS 1 11/17/2020 1 ND I U I EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoropentanoic Acid PFPeA 11/17/2020 12 J EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorotetradecanoic Acid PFTeDA 11/17/2020 ND U EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorotridecanoic Acid PFTrDA 11/17/2020 ND U EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroundecanoic Acid PFUnDA 11/17/2020 ND U EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse HFPODA GenX 11/17/2020 ND U EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse DONA ADONA 11/17/2020 ND U EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 9CI-PF3ONS F53B 11/17/2020 ND U EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 11C1-PF3OUdS F53B 11/17/2020 ND U EPA 537 v 1.1 Modified Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 10:2 Fluorotelomersulfonic Acid 10:2-FTS 11/17/2020 ND U EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 4:2 Fluorotelomersulfonic Acid 4:2-FTS 11/17/2020 ND U EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 6:2 Fluorotelomersulfonic Acid 6:2-FTS 11/17/2020 ND U EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 8:2 Fluorotelomersulfonic Acid 8:2-FTS 11/17/2020 ND U EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-ethyl perfluorooctanesulfonamidoacetic acid NEtFOSAA 11/17/2020 ND U EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-ethylperfluoro-l-octanesulfonamide NEtPFOSA 11/17/2020 ND U EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 2-(N ethyl perfluoro--octanesulfonamido)-ethanol NEtPFOSAE 11/17/2020 ND U EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-methyl perfluorooctanesulfonamidoacetic acid NMeFOSAA 11/17/2020 ND U EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-methylperfluoro-l-octanesulfonamide NMePFOSA 11/17/2020 ND U EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 2-(N-methylperfluoro-l-octanesulfonamiso)-ethanol NMePFOSAE 11/17/2020 ND U EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorobutanesulfonic Acid PFBS 11/17/2020 6.7 J EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorobutanoic Acid PFBA 11/17/2020 ND U EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorodecanesulfonic Acid PFDS 11/17/2020 ND U EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorodecanoic Acid PFDA 11/17/2020 ND U EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorododecanesulfonic Acid PFDoS 11/17/2020 ND U EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorododecanoic Acid PFDoDA 11/17/2020 ND U EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroheptanesulfonic Acid PFHpS 11/17/2020 ND U EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroheptanoic Acid PFHpA 11/17/2020 ND U EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexadecanoic Acid PFHxDA 11/17/2020 ND U EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexanesulfonic Acid PFHxS 11/17/2020 ND U EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexanoic Acid PFHxA 11/17/2020 15 J EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorononanesulfonic Acid PFNS 11/17/2020 ND U EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorononanoic Acid PFNA 11/17/2020 ND U EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctadecanoic Acid PFODA 11/17/2020 ND U EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanesulfonamide PFOSA 11/17/2020 ND U EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanesulfonic Acid PFOS 11/17/2020 18 A EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanoic Acid PFOA 11/17/2020 9.4 J EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoropentanesulfonate PFPeS 11/17/2020 ND U EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoropentanoic Acid PFPeA 11/17/2020 14 J EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorotetradecanoic Acid PFTeDA 11/17/2020 ND U EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorotridecanoic Acid PFTrDA 11/17/2020 ND U EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroundecanoic Acid PFUnDA 11/17/2020 ND U EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse HFPODA GenX 11/17/2020 ND U EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse DONA ADONA 11/17/2020 ND U EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 9CI-PF3ONS F53B 11/17/2020 ND U EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 11C1-PF3OUdS F53B 11/17/2020 ND U EPA 537 v 1.1 Modified Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 10:2 Fluorotelomersulfonic Acid 10:2-FTS 11/17/2020 ND U EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 4:2 Fluorotelomersulfonic Acid 4:2-FTS 11/17/2020 ND U EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 6:2 Fluorotelomersulfonic Acid 6:2-FTS 11/17/2020 ND U EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 8:2 Fluorotelomersulfonic Acid 8:2-FTS 11/17/2020 ND U EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-ethyl perfluorooctanesulfonamidoacetic acid NEtFOSAA 11/17/2020 ND U EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-ethylperfluoro-l-octanesulfonamide NEtPFOSA 11/17/2020 ND U EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 2-(N ethyl perfluoro--octanesulfonamido)-ethanol NEtPFOSAE 11/17/2020 ND U EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-methyl perfluorooctanesulfonamidoacetic acid NMeFOSAA 11/17/2020 1.1 J EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-methylperfluoro-l-octanesulfonamide NMePFOSA 11/17/2020 ND U EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 2-(N-methylperfluoro-l-octanesulfonamiso)-ethanol NMePFOSAE 11/17/2020 ND U EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorobutanesulfonic Acid PFBS 11/17/2020 7.5 EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorobutanoic Acid PFBA 11/17/2020 12 EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorodecanesulfonic Acid PFDS 11/17/2020 ND U EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorodecanoic Acid PFDA 11/17/2020 ND U EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorododecanesulfonic Acid PFDoS 11/17/2020 ND U EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorododecanoic Acid PFDoDA 11/17/2020 ND U EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroheptanesulfonic Acid PFHpS 11/17/2020 ND U EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroheptanoic Acid PFHpA 11/17/2020 4.5 EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexadecanoic Acid PFHxDA 11/17/2020 ND U EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexanesulfonic Acid PFHxS 11/17/2020 1.8 EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexanoic Acid PFHxA 11/17/2020 24 EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorononanesulfonic Acid PFNS 11/17/2020 ND U EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorononanoic Acid PFNA 11/17/2020 ND U EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctadecanoic Acid PFODA 11/17/2020 ND U EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanesulfonamide PFOSA 11/17/2020 0.47 J EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanesulfonic Acid PFOS 11/17/2020 6.0 EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanoic Acid PFOA 11/17/2020 16 EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoropentanesulfonate PFPeS 11/17/2020 ND U EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoropentanoic Acid PFPeA 11/17/2020 25 EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorotetradecanoic Acid PFTeDA 11/17/2020 ND U EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorotridecanoic Acid PFTrDA 11/17/2020 ND U EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroundecanoic Acid PFUnDA 11/17/2020 ND U EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse HFPODA GenX 11/17/2020 ND U EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse DONA ADONA 11/17/2020 ND U EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 9CI-PF3ONS F53B 11/17/2020 ND U EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 11C1-PF3OUdS F53B 11/17/2020 ND U EPA 537 v 1.1 Modified Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorobutanoic Acid PFBA 3/10/2021 <LOD (0.146) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoropentanoic Acid PFPeA 3/10/2021 <LOD (0.162) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexanoic Acid jPFHxA 1 3/10/2021 1 9.51 1 1 Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroheptanoic Acid jPFHpA 1 3/10/2021 1 2.37 1 1 Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanoic Acid PFOA 3/10/2021 4.53 Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorononanoic Acid PFNA 3/10/2021 0.462 Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorodecanoic Acid PFDA 3/10/2021 0.204 J Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroundecanoic Acid PFUnDA 3/10/2021 <LOD (0.176) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorododecanoic Acid PFDoDA 3/10/2021 <LOD (0.192) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorotridecanoic Acid PFTrDA 3/10/2021 <LOD (0.144) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorotetradecanoic Acid PFTeDA 3/10/2021 <LOD (0.208) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorobutanesulfonic Acid PFBS 3/10/2021 <LOD (0.338) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoropentanesulfonate PFPeS 3/10/2021 <LOD (0.196) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexanesulfonic Acid PFHxS 3/10/2021 <LOD (0.182) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroheptanesulfonic Acid PFHpS 3/10/2021 <LOD (0.129) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanesulfonic Acid PFOS 3/10/2021 4.85 Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorononanesulfonic Acid PFNS 3/10/2021 <LOD (0.0823) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorodecanesulfonic Acid PFDS 3/10/2021 <LOD (0.183) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 4:2 Fluorotelomersulfonic Acid 4:2-FTS 3/10/2021 <LOD (0.112) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 6:2 Fluorotelomersulfonic Acid 6:2-FTS 3/10/2021 0.367 Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 8:2 Fluorotelomersulfonic Acid 8:2-FTS 3/10/2021 0.589 Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanesulfonamide PFOSA 3/10/2021 <LOD (0.124) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-methyl perfluorooctanesulfonamidoacetic acid NMeFOSAA 3/10/2021 <LOD (0.137) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-ethyl perfluorooctanesulfonamidoacetic acid NEtFOSAA 3/10/2021 <LOD (0.104) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse HFPODA HFPODA 3/10/2021 <LOD (0.217) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 4,8-dioxa 31-1-perfluorononanoic acid DONA 3/10/2021 0.122 J Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 9CI-PF3ONS 9CI-PF3ONS 3/10/2021 <LOD (0.114) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 11 CI-PF3OUdS 11 CI-PF3OUdS 3/10/2021 <LOD (0.114) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 10:2 Fluorotelomersulfonic Acid 10:2-FTS 3/10/2021 <LOD (0.228) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-ethylperfluoro-l-octanesulfonamide N-EtPFOSA 3/10/2021 <LOD (0.228) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 2-(N ethyl perfluoro--octanesulfonamido)-ethanol N-EtPFOSAE 3/10/2021 <LOD (6.85) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-methylperfluoro-l-octanesulfonamide N-McPFOSA 3/10/2021 <LOD (0.228) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 2-(N-methylperfluoro-l-octanesulfonamiso)-ethanol N-McPFOSAE 3/10/2021 <LOD (6.85) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorododecanesulfonic Acid PFDoS 3/10/2021 <LOD (2.13) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexadecanoic Acid PFHxDA 3/10/2021 <LOD (1.41) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctadecanoic Acid PFODA 3/10/2021 <LOD (1.41) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorobutanoic Acid PFBA 3/10/2021 <LOD (0.143) U Isotope Dilution Headworks (Inf+ Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoropentanoic Acid PFPeA 3/10/2021 <LOD (0.159) U Isotope Dilution Headworks (Inf+ Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexanoic Acid PFHxA 3/10/2021 11.3 Isotope Dilution Headworks (Inf+ Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroheptanoic Acid PFHpA 3/10/2021 2.71 Isotope Dilution Headworks (Inf+ Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanoic Acid PFOA 3/10/2021 4.84 Isotope Dilution Headworks (Inf+ Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorononanoic Acid PFNA 3/10/2021 0.513 Isotope Dilution Headworks (Inf+ Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorodecanoic Acid PFDA 3/10/2021 0.241 J Isotope Dilution Headworks (Inf+ Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroundecanoic Acid PFUnDA 3/10/2021 <LOD (0.173) U Isotope Dilution Headworks (Inf+ Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorododecanoic Acid PFDoDA 3/10/2021 <LOD (0.189) U Isotope Dilution Headworks (Inf+ Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorotridecanoic Acid PFTrDA 3/10/2021 <LOD (0.141) U Isotope Dilution Headworks (Inf+ Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorotetradecanoic Acid PFTeDA 3/10/2021 <LOD (0.204) U Isotope Dilution Headworks (Inf+ Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorobutanesulfonic Acid PFBS 3/10/2021 <LOD (0.332) U Isotope Dilution Headworks (Inf+ Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoropentanesulfonate PFPeS 3/10/2021 <LOD (0.192) U Isotope Dilution Headworks (Inf+ Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexanesulfonic Acid PFHxS 3/10/2021 <LOD (0.178) U Isotope Dilution Headworks (Inf+ Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroheptanesulfonic Acid PFHpS 3/10/2021 <LOD (0.126) U Isotope Dilution Headworks (Inf+ Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanesulfonic Acid PFOS 3/10/2021 5.66 Isotope Dilution Headworks (Inf+ Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorononanesulfonic Acid PFNS 3/10/2021 <LOD (0.0807) U Isotope Dilution Headworks (Inf+ Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorodecanesulfonic Acid PFDS 3/10/2021 <LOD (0.179) U Isotope Dilution Headworks (Inf+ Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 4:2 Fluorotelomersulfonic Acid 4:2-FTS 3/10/2021 <LOD (0.110) U Isotope Dilution Headworks (Inf+ Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 6:2 Fluorotelomersulfonic Acid 6:2-FTS 3/10/2021 0.403 Isotope Dilution Headworks (Inf+ Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 8:2 Fluorotelomersulfonic Acid 8:2-FTS 3/10/2021 0.327 Isotope Dilution Headworks (Inf+ Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanesulfonamide PFOSA 3/10/2021 <LOD (0.121) U Isotope Dilution Headworks (Inf+ Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-methyl perfluorooctanesulfonamidoacetic acid NMeFOSAA 3/10/2021 <LOD (0.135) U Isotope Dilution Headworks (Inf+ Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-ethyl perfluorooctanesulfonamidoacetic acid NEtFOSAA 3/10/2021 <LOD (0.102) U Isotope Dilution Headworks (Inf+ Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse HFPODA HFPODA 3/10/2021 <LOD (0.213) U Isotope Dilution Headworks (Inf+ Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 4,8-dioxa 31-1-perfluorononanoic acid DONA 3/10/2021 0.130 J Isotope Dilution Headworks (Inf+ Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 9CI-PF3ONS 9CI-PF3ONS 3/10/2021 <LOD (0.112) U Isotope Dilution Headworks (Inf+ Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 11 CI-PF3OUdS 11 CI-PF3OUdS 3/10/2021 <LOD (0.112) U Isotope Dilution Headworks (Inf+ Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 10:2 Fluorotelomersulfonic Acid 10:2-FTS 3/10/2021 <LOD (0.224) U Isotope Dilution Headworks (Inf+ Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-ethylperfluoro-l-octanesulfonamide N-EtPFOSA 3/10/2021 <LOD (0.224) U Isotope Dilution Headworks (Inf+ Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 2-(N ethyl perfluoro--octanesulfonamido)-ethanol N-EtPFOSAE 3/10/2021 <LOD (6.73) U Isotope Dilution Headworks (Inf+ Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-methylperfluoro-l-octanesulfonamide N-McPFOSA 3/10/2021 <LOD (0.224) U Isotope Dilution Headworks (Inf+ Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 2-(N-methyl perfluoro-l-octanesulfonamiso)-ethanol N-McPFOSAE 3/10/2021 <LOD (6.73) U Isotope Dilution Headworks (Inf+ Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorododecanesulfonic Acid PFDoS 3/10/2021 <LOD (2.09) U Isotope Dilution Headworks (Inf+ Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexadecanoic Acid PFHxDA 3/10/2021 <LOD (1.38) U Isotope Dilution Headworks (Inf+ Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctadecanoic Acid PFODA 3/10/2021 <LOD (1.38) U Isotope Dilution Headworks (Inf+ Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorobutanoic Acid PFBA 3/10/2021 1.03 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoropentanoic Acid PFPeA 3/10/2021 <LOD (0.157) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexanoic Acid PFHxA 3/10/2021 17.1 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroheptanoic Acid PFHpA 3/10/2021 2.47 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanoic Acid PFOA 3/10/2021 8.26 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorononanoic Acid PFNA 3/10/2021 0.687 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorodecanoic Acid PFDA 3/10/2021 0.790 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroundecanoic Acid PFUnDA 3/10/2021 <LOD (0.171) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorododecanoic Acid PFDoDA 3/10/2021 <LOD (0.187) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorotridecanoic Acid PFTrDA 3/10/2021 <LOD (0.140) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorotetradecanoic Acid PFTeDA 3/10/2021 <LOD (0.202) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorobutanesulfonic Acid PFBS 3/10/2021 <LOD (0.328) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoropentanesulfonate PFPeS 3/10/2021 <LOD (0.190) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexanesulfonic Acid PFHxS 3/10/2021 1.99 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroheptanesulfonic Acid PFHpS 3/10/2021 <LOD (0.125) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanesulfonic Acid PFOS 3/10/2021 4.31 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorononanesulfonic Acid PFNS 3/10/2021 <LOD (0.0799) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorodecanesulfonic Acid PFDS 3/10/2021 <LOD (0.178) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 4:2 Fluorotelomersulfonic Acid 4:2-FTS 3/10/2021 <LOD (0.109) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 6:2 Fluorotelomersulfonic Acid 6:2-FTS 3/10/2021 0.274 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 8:2 Fluorotelomersulfonic Acid 8:2-FTS 3/10/2021 0.259 J Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanesulfonamide PFOSA 3/10/2021 <LOD (0.120) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-methyl perfluorooctanesulfonamidoacetic acid NMeFOSAA 3/10/2021 0.921 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-ethyl perfluorooctanesulfonamidoacetic acid NEtFOSAA 3/10/2021 <LOD (0.101) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse HFPODA HFPODA 3/10/2021 <LOD (0.211) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 4,8-dioxa 31-1-perfluorononanoic acid DONA 3/10/2021 <LOD (0.111) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 9CI-PF3ONS 9CI-PF3ONS 3/10/2021 <LOD (0.111) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 11 CI-PF3OUdS 11 CI-PF3OUdS 3/10/2021 <LOD (0.111) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 10:2 Fluorotelomersulfonic Acid 10:2-FTS 3/10/2021 <LOD (0.222) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-ethylperfluoro-l-octanesulfonamide N-EtPFOSA 3/10/2021 <LOD (0.222) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 2-(N ethyl perfluoro--octanesulfonamido)-ethanol N-EtPFOSAE 3/10/2021 <LOD (6.66) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-methylperfluoro-l-octanesulfonamide N-McPFOSA 3/10/2021 <LOD (0.222) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 2-(N-methylperfluoro-l-octanesulfonamiso)-ethanol N-McPFOSAE 3/10/2021 <LOD (6.66) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorododecanesulfonic Acid PFDoS 3/10/2021 <LOD (2.07) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexadecanoic Acid PFHxDA 3/10/2021 <LOD (1.37) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctadecanoic Acid PFODA 3/10/2021 <LOD (1.37) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorobutanoic Acid PFBA 6/7/2021 <LOD (0.144) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoropentanoic Acid PFPeA 6/7/2021 8.95 Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexanoic Acid PFHxA 6/7/2021 6.14 Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroheptanoic Acid PFHpA 6/7/2021 1.47 Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanoic Acid PFOA 6/7/2021 2.98 Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorononanoic Acid PFNA 6/7/2021 0.422 Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorodecanoic Acid PFDA 6/7/2021 0.231 J Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroundecanoic Acid PFUnDA 6/7/2021 <LOD (0.174) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorododecanoic Acid PFDoDA 6/7/2021 <LOD (0.190) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorotridecanoic Acid PFTrDA 6/7/2021 <LOD (0.142) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorotetradecanoic Acid PFTeDA 6/7/2021 <LOD (0.205) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorobutanesulfonic Acid PFBS 6/7/2021 <LOD (0.334) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoropentanesulfonate PFPeS 6/7/2021 <LOD (0.194) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexanesulfonic Acid PFHxS 6/7/2021 <LOD (0.180) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroheptanesulfonic Acid PFHpS 6/7/2021 <LOD (0.127) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanesulfonic Acid PFOS 6/7/2021 3.78 Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorononanesulfonic Acid PFNS 6/7/2021 <LOD (0.0814) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorodecanesulfonic Acid PFDS 6/7/2021 <LOD (0.181) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 4:2 Fluorotelomersulfonic Acid 4:2-FTS 6/7/2021 <LOD (0.111) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 6:2 Fluorotelomersulfonic Acid 6:2-FTS 6/7/2021 1.16 Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 8:2 Fluorotelomersulfonic Acid 8:2-FTS 6/7/2021 0.232 J Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanesulfonamide PFOSA 6/7/2021 <LOD (0.122) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-methyl perfluorooctanesulfonamidoacetic acid NMeFOSAA 6/7/2021 <LOD (0.136) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-ethyl perfluorooctanesulfonamidoacetic acid NEtFOSAA 6/7/2021 <LOD (0.103) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse HFPODA HFPODA 6/7/2021 <LOD (0.215) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 4,8-dioxa 31-1-perfluorononanoic acid DONA 6/7/2021 0.370 Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 9CI-PF3ONS 9CI-PF3ONS 6/7/2021 <LOD (0.113) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 11 CI-PF3OUdS 11 CI-PF3OUdS 6/7/2021 <LOD (0.113) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 10:2 Fluorotelomersulfonic Acid 10:2-FTS 6/7/2021 <LOD (0.226) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-ethylperfluoro-l-octanesulfonamide N-EtPFOSA 6/7/2021 <LOD (0.226) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 2-(N ethyl perfluoro--octanesulfonamido)-ethanol N-EtPFOSAE 6/7/2021 <LOD (6.78) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-methylperfluoro-l-octanesulfonamide N-McPFOSA 6/7/2021 <LOD (0.226) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 2-(N-methylperfluoro-l-octanesulfonamiso)-ethanol N-McPFOSAE 6/7/2021 <LOD (6.78) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorododecanesulfonic Acid PFDoS 6/7/2021 <LOD (2.11) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexadecanoic Acid PFHxDA 6/7/2021 <LOD (1.36) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctadecanoic Acid PFODA 6/7/2021 <LOD (1.36) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorobutanoic Acid PFBA 6/7/2021 <LOD (0.140) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoropentanoic Acid PFPeA 6/7/2021 11.0 Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexanoic Acid PFHxA 6/7/2021 9.49 Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroheptanoic Acid PFHpA 6/7/2021 1.62 Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanoic Acid PFOA 6/7/2021 4.66 Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorononanoic Acid PFNA 6/7/2021 0.480 Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorodecanoic Acid PFDA 6/7/2021 0.655 Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroundecanoic Acid PFUnDA 6/7/2021 <LOD (0.169) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorododecanoic Acid PFDoDA 6/7/2021 <LOD (0.185) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorotridecanoic Acid PFTrDA 6/7/2021 <LOD (0.138) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorotetradecanoic Acid PFTeDA 6/7/2021 <LOD (0.200) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorobutanesulfonic Acid PFBS 6/7/2021 <LOD (0.325) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoropentanesulfonate PFPeS 6/7/2021 <LOD (0.189) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexanesulfonic Acid PFHxS 6/7/2021 <LOD (0.175) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroheptanesulfonic Acid PFHpS 6/7/2021 <LOD (0.124) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanesulfonic Acid PFOS 6/7/2021 3.27 Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorononanesulfonic Acid PFNS 6/7/2021 <LOD (0.0791) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorodecanesulfonic Acid PFDS 6/7/2021 <LOD (0.176) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 4:2 Fluorotelomersulfonic Acid 4:2-FTS 6/7/2021 <LOD (0.108) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 6:2 Fluorotelomersulfonic Acid 6:2-FTS 6/7/2021 1.68 Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 8:2 Fluorotelomersulfonic Acid 8:2-FTS 6/7/2021 0.674 Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanesulfonamide PFOSA 6/7/2021 <LOD (0.119) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-methyl perfluorooctanesulfonamidoacetic acid NMeFOSAA 6/7/2021 0.719 Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-ethyl perfluorooctanesulfonamidoacetic acid NEtFOSAA 6/7/2021 <LOD (0.0998) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse HFPODA jHFPODA 6/7/2021 1 <LOD (0.209) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 4,8-dioxa 31-1-perfluorononanoic acid IDONA 6/7/2021 1 0.288 Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 9CI-PF3ONS 9CI-PF3ONS 6/7/2021 <LOD (0.110) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 11 CI-PF3OUdS 11 CI-PF3OUdS 6/7/2021 <LOD (0.110) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 10:2 Fluorotelomersulfonic Acid 10:2-FTS 6/7/2021 <LOD (0.220) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-ethylperfluoro-l-octanesulfonamide N-EtPFOSA 6/7/2021 <LOD (0.220) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 2-(N ethyl perfluoro--octanesulfonamido)-ethanol N-EtPFOSAE 6/7/2021 <LOD (6.59) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-methylperfluoro-l-octanesulfonamide N-McPFOSA 6/7/2021 <LOD (0.220) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 2-(N-methylperfluoro-l-octanesulfonamiso)-ethanol N-McPFOSAE 6/7/2021 <LOD (6.59) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorododecanesulfonic Acid PFDoS 6/7/2021 <LOD (2.05) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexadecanoic Acid PFHxDA 6/7/2021 <LOD (1.32) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctadecanoic Acid PFODA 6/7/2021 <LOD (1.32) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorobutanoic Acid PFBA 6/7/2021 <LOD (0.141) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoropentanoic Acid PFPeA 6/7/2021 20.6 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexanoic Acid PFHxA 6/7/2021 21.2 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroheptanoic Acid PFHpA 6/7/2021 2.59 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanoic Acid PFOA 6/7/2021 12.5 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorononanoic Acid PFNA 6/7/2021 0.747 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorodecanoic Acid PFDA 6/7/2021 1.19 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroundecanoic Acid PFUnDA 6/7/2021 <LOD (0.170) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorododecanoic Acid PFDoDA 6/7/2021 <LOD (0.186) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorotridecanoic Acid PFTrDA 6/7/2021 <LOD (0.139) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorotetradecanoic Acid PFTeDA 6/7/2021 <LOD (0.200) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorobutanesulfonic Acid PFBS 6/7/2021 <LOD (0.326) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoropentanesulfonate PFPeS 6/7/2021 <LOD (0.189) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexanesulfonic Acid PFHxS 6/7/2021 1.30 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroheptanesulfonic Acid PFHpS 6/7/2021 <LOD (0.124) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanesulfonic Acid PFOS 6/7/2021 4.30 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorononanesulfonic Acid PFNS 6/7/2021 <LOD (0.0794) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorodecanesulfonic Acid PFDS 6/7/2021 <LOD (0.176) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 4:2 Fluorotelomersulfonic Acid 4:2-FTS 6/7/2021 <LOD (0.108) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 6:2 Fluorotelomersulfonic Acid 6:2-FTS 6/7/2021 2.09 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 8:2 Fluorotelomersulfonic Acid 8:2-FTS 6/7/2021 0.546 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanesulfonamide PFOSA 6/7/2021 <LOD (0.119) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-methyl perfluorooctanesulfonamidoacetic acid NMeFOSAA 6/7/2021 1.12 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-ethyl perfluorooctanesulfonamidoacetic acid NEtFOSAA 6/7/2021 0.121 J Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse HFPODA HFPODA 6/7/2021 <LOD (0.210) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 4,8-dioxa 31-1-perfluorononanoic acid DON A 6/7/2021 <LOD (0.110) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 9CI-PF3ONS 9CI-PF3ONS 6/7/2021 <LOD (0.110) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 11 CI-PF3OUdS 11 CI-PF3OUdS 6/7/2021 <LOD (0.110) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 10:2 Fluorotelomersulfonic Acid 10:2-FTS 6/7/2021 <LOD (0.221) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-ethylperfluoro-l-octanesulfonamide N-EtPFOSA 6/7/2021 <LOD (0.221) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 2-(N ethyl perfluoro--octanesulfonamido)-ethanol N-EtPFOSAE 6/7/2021 <LOD (6.62) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-methylperfluoro-l-octanesulfonamide N-McPFOSA 6/7/2021 <LOD (0.221) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 2-(N-methylperfluoro-l-octanesulfonamiso)-ethanol N-McPFOSAE 6/7/2021 <LOD (6.62) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorododecanesulfonic Acid PFDoS 6/7/2021 <LOD (2.06) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexadecanoic Acid PFHxDA 6/7/2021 <LOD (1.32) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctadecanoic Acid PFODA 6/7/2021 <LOD (1.32) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorobutanoic Acid PFBA 9/14/2021 <LOD (0.147) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoropentanoic Acid PFPeA 9/14/2021 <LOD (0.163) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexanoic Acid PFHxA 9/14/2021 5.28 Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroheptanoic Acid PFHpA 9/14/2021 0.926 Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanoic Acid PFOA 9/14/2021 1.74 Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorononanoic Acid PFNA 9/14/2021 0.295 Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorodecanoic Acid PFDA 9/14/2021 0.343 Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroundecanoic Acid PFUnDA 9/14/2021 <LOD (0.178) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorododecanoic Acid PFDoDA 9/14/2021 <LOD (0.194) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorotridecanoic Acid PFTrDA 9/14/2021 <LOD (0.145) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorotetradecanoic Acid PFTeDA 9/14/2021 <LOD (0.209) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorobutanesulfonic Acid PFBS 9/14/2021 <LOD (0.341) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoropentanesulfonate PFPeS 9/14/2021 <LOD (0.198) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexanesulfonic Acid PFHxS 9/14/2021 <LOD (0.183) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroheptanesulfonic Acid PFHpS 9/14/2021 <LOD (0.130) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanesulfonic Acid PFOS 9/14/2021 <LOD (0.154) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorononanesulfonic Acid PFNS 9/14/2021 <LOD (0.0830) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorodecanesulfonic Acid PFDS 9/14/2021 <LOD (0.184) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 4:2 Fluorotelomersulfonic Acid 4:2-FTS 9/14/2021 0.198 J Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 6:2 Fluorotelomersulfonic Acid 6:2-FTS 9/14/2021 0.695 Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 8:2 Fluorotelomersulfonic Acid 8:2-FTS 9/14/2021 <LOD (0.164) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanesulfonamide PFOSA 9/14/2021 <LOD (0.125) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-methyl perfluorooctanesulfonamidoacetic acid NMeFOSAA 9/14/2021 <LOD (0.138) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-ethyl perfluorooctanesulfonamidoacetic acid NEtFOSAA 9/14/2021 <LOD (0.105) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse HFPODA HFPODA 9/14/2021 <LOD (0.219) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 4,8-dioxa 31-1-perfluorononanoic acid DONA 9/14/2021 <LOD (0.115) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 9CI-PF3ONS 9CI-PF3ONS 9/14/2021 <LOD (0.115) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 11 CI-PF3OUdS 11 CI-PF3OUdS 9/14/2021 <LOD (0.115) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 10:2 Fluorotelomersulfonic Acid 10:2-FTS 9/14/2021 <LOD (0.231) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-ethylperfluoro-l-octanesulfonamide N-EtPFOSA 9/14/2021 <LOD (0.231) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 2-(N ethyl perfluoro--octanesulfonamido)-ethanol N-EtPFOSAE 9/14/2021 <LOD (6.92) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-methylperfluoro-l-octanesulfonamide N-McPFOSA 9/14/2021 <LOD (0.231) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 2-(N-methylperfluoro-l-octanesulfonamiso)-ethanol N-McPFOSAE 9/14/2021 <LOD (6.92) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorododecanesulfonic Acid PFDoS 9/14/2021 <LOD (2.15) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexadecanoic Acid PFHxDA 9/14/2021 <LOD (1.38) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctadecanoic Acid JPFODA 1 9/14/2021 1 29.6 1 1 Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorobutanoic Acid JPFBA 1 9/14/2021 1 <LOD (0.149) 1 U I Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoropentanoic Acid PFPeA 9/14/2021 14.3 Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexanoic Acid PFHxA 9/14/2021 8.29 Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroheptanoic Acid PFHpA 9/14/2021 1.63 Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanoic Acid PFOA 9/14/2021 4.56 Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorononanoic Acid PFNA 9/14/2021 0.358 Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorodecanoic Acid PFDA 9/14/2021 0.412 Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroundecanoic Acid PFUnDA 9/14/2021 <LOD (0.180) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorododecanoic Acid PFDoDA 9/14/2021 <LOD (0.197) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorotridecanoic Acid PFTrDA 9/14/2021 <LOD (0.147) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorotetradecanoic Acid PFTeDA 9/14/2021 <LOD (0.212) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorobutanesulfonic Acid PFBS 9/14/2021 <LOD (0.346) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoropentanesulfonate PFPeS 9/14/2021 <LOD (0.201) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexanesulfonic Acid PFHxS 9/14/2021 <LOD (0.186) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroheptanesulfonic Acid PFHpS 9/14/2021 <LOD (0.132) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanesulfonic Acid PFOS 9/14/2021 9.83 Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorononanesulfonic Acid PFNS 9/14/2021 <LOD (0.0842) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorodecanesulfonic Acid PFDS 9/14/2021 <LOD (0.187) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 4:2 Fluorotelomersulfonic Acid 4:2-FTS 9/14/2021 <LOD (0.115) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 6:2 Fluorotelomersulfonic Acid 6:2-FTS 9/14/2021 1.16 Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 8:2 Fluorotelomersulfonic Acid 8:2-FTS 9/14/2021 0.234 J Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanesulfonamide PFOSA 9/14/2021 0.166 J Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-methyl perfluorooctanesulfonamidoacetic acid NMeFOSAA 9/14/2021 <LOD 0.140) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-ethyl perfluorooctanesulfonamidoacetic acid NEtFOSAA 9/14/2021 <LOD (0.106) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse HFPODA HFPODA 9/14/2021 <LOD (0.222) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 4,8-dioxa 31-1-perfluorononanoic acid DONA 9/14/2021 <LOD (0.117) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 9CI-PF3ONS 9CI-PF3ONS 9/14/2021 <LOD (0.117) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 11 CI-PF3OUdS 11 CI-PF3OUdS 9/14/2021 <LOD (0.117) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 10:2 Fluorotelomersulfonic Acid 10:2-FTS 9/14/2021 <LOD (0.234) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-ethylperfluoro-l-octanesulfonamide N-EtPFOSA 9/14/2021 <LOD (0.234) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 2-(N ethyl perfluoro--octanesulfonamido)-ethanol N-EtPFOSAE 9/14/2021 <LOD (7.02) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-methylperfluoro-l-octanesulfonamide N-McPFOSA 9/14/2021 <LOD (0.234) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 2-(N-methylperfluoro-l-octanesulfonamiso)-ethanol N-McPFOSAE 9/14/2021 <LOD (7.02) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorododecanesulfonic Acid PFDoS 9/14/2021 <LOD (2.18) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexadecanoic Acid PFHxDA 9/14/2021 <LOD (1.40) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctadecanoic Acid PFODA 9/14/2021 <LOD (1.40) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorobutanoic Acid PFBA 9/14/2021 12.6 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoropentanoic Acid PFPeA 9/14/2021 23.3 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexanoic Acid PFHxA 9/14/2021 14.0 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroheptanoic Acid PFHpA 9/14/2021 1.67 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanoic Acid PFOA 9/14/2021 7.13 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorononanoic Acid PFNA 9/14/2021 0.494 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorodecanoic Acid PFDA 9/14/2021 0.812 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroundecanoic Acid PFUnDA 9/14/2021 <LOD (0.175) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorododecanoic Acid PFDoDA 9/14/2021 <LOD (0.191) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorotridecanoic Acid PFTrDA 9/14/2021 <LOD (0.143) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorotetradecanoic Acid PFTeDA 9/14/2021 <LOD (0.207) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorobutanesulfonic Acid PFBS 9/14/2021 <LOD (0.337) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoropentanesulfonate PFPeS 9/14/2021 <LOD (0.195) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexanesulfonic Acid PFHxS 9/14/2021 1.57 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroheptanesulfonic Acid PFHpS 9/14/2021 <LOD (0.128) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanesulfonic Acid PFOS 9/14/2021 14.6 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorononanesulfonic Acid PFNS 9/14/2021 <LOD (0.0819) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorodecanesulfonic Acid PFDS 9/14/2021 <LOD (0.182) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 4:2 Fluorotelomersulfonic Acid 4:2-FTS 9/14/2021 <LOD (0.112) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 6:2 Fluorotelomersulfonic Acid 6:2-FTS 9/14/2021 1.97 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 8:2 Fluorotelomersulfonic Acid 8:2-FTS 9/14/2021 <LOD (0.162) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanesulfonamide PFOSA 9/14/2021 <LOD (0.123) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-methyl perfluorooctanesulfonamidoacetic acid NMeFOSAA 9/14/2021 0.551 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-ethyl perfluorooctanesulfonamidoacetic acid NEtFOSAA 9/14/2021 <LOD (0.103) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse HFPODA HFPODA 9/14/2021 <LOD (0.216) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 4,8-dioxa 31-1-perfluorononanoic acid DONA 9/14/2021 <LOD (0.114) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 9CI-PF3ONS 9CI-PF3ONS 9/14/2021 <LOD (0.114) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 11 CI-PF3OUdS 11 CI-PF3OUdS 9/14/2021 <LOD (0.114) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 10:2 Fluorotelomersulfonic Acid 10:2-FTS 9/14/2021 <LOD (0.227) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-ethylperfluoro-l-octanesulfonamide N-EtPFOSA 9/14/2021 <LOD (0.227) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 2-(N ethyl perfluoro--octanesulfonamido)-ethanol N-EtPFOSAE 9/14/2021 <LOD (6.82) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-methylperfluoro-l-octanesulfonamide N-McPFOSA 9/14/2021 <LOD (0.227) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 2-(N-methylperfluoro-l-octanesulfonamiso)-ethanol N-McPFOSAE 9/14/2021 <LOD (6.82) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorododecanesulfonic Acid PFDoS 9/14/2021 <LOD (2.12) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexadecanoic Acid PFHxDA 9/14/2021 <LOD (1.36) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctadecanoic Acid PFODA 9/14/2021 <LOD (1.36) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorobutanoic Acid PFBA 11/9/2021 <LOD (1.28) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoropentanoic Acid PFPeA 11/9/2021 17.7 Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexanoic Acid PFHxA 11/9/2021 8.75 Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroheptanoic Acid PFHpA 11/9/2021 1.66 J Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanoic Acid PFOA 11/9/2021 <LOD (1.48) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorononanoic Acid PFNA 11/9/2021 <LOD (0.634) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorodecanoic Acid PFDA 11/9/2021 <LOD (0.704) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroundecanoic Acid PFUnDA 11/9/2021 <LOD (1.54) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorododecanoic Acid PFDoDA 11/9/2021 <LOD (1.68) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorotridecanoic Acid PFTrDA 11/9/2021 <LOD (1.26) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorotetradecanoic Acid jPFTeDA 1 11/9/2021 1 <LOD (1.82) 1 U I Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorobutanesulfonic Acid JPFBS 1 11/9/2021 1 <LOD (2.96) 1 U I Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoropentanesulfonate PFPeS 11/9/2021 <LOD (1.72) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexanesulfonic Acid PFHxS 11/9/2021 <LOD (1.59) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroheptanesulfonic Acid PFHpS 11/9/2021 <LOD (1.13) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanesulfonic Acid PFOS 11/9/2021 2.14 J Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorononanesulfonic Acid PFNS 11/9/2021 <LOD (0.720) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorodecanesulfonic Acid PFDS 11/9/2021 <LOD (1.60) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 4:2 Fluorotelomersulfonic Acid 4:2-FTS 11/9/2021 <LOD (0.983) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 6:2 Fluorotelomersulfonic Acid 6:2-FTS 11/9/2021 <LOD (0.967) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 8:2 Fluorotelomersulfonic Acid 8:2-FTS 11/9/2021 <LOD (1.43) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanesulfonamide PFOSA 11/9/2021 <LOD (1.08) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-methyl perfluorooctanesulfonamidoacetic acid NMeFOSAA 11/9/2021 <LOD (1.20) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-ethyl perfluorooctanesulfonamidoacetic acid NEtFOSAA 11/9/2021 <LOD (0.908) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse HFPODA HFPODA 11/9/2021 <LOD (1.90) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 4,8-dioxa 31-1-perfluorononanoic acid DONA 11/9/2021 <LOD (1.00) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 9CI-PF3ONS 9CI-PF3ONS 11/9/2021 <LOD (1.00) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 11 CI-PF3OUdS 11 CI-PF3OUdS 11/9/2021 <LOD (1.00) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 10:2 Fluorotelomersulfonic Acid 10:2-FTS 11/9/2021 <LOD (2.00) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-ethylperfluoro-l-octanesulfonamide N-EtPFOSA 11/9/2021 <LOD (2.00) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 2-(N ethyl perfluoro--octanesulfonamido)-ethanol N-EtPFOSAE 11/9/2021 <LOD (60.0) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-methylperfluoro-l-octanesulfonamide N-McPFOSA 11/9/2021 <LOD (2.00) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 2-(N-methyl perfluoro-l-octanesulfonamiso)-ethanol N-McPFOSAE 11/9/2021 <LOD (60.0) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorododecanesulfonic Acid PFDoS 11/9/2021 <LOD (18.7) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexadecanoic Acid PFHxDA 11/9/2021 <LOD (12.0) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctadecanoic Acid PFODA 11/9/2021 <LOD (12.0) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorobutanoic Acid PFBA 11/9/2021 <LOD (1.28) U Isotope Dilution Headworks (Inf+ Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoropentanoic Acid PFPeA 11/9/2021 21.4 Isotope Dilution Headworks (Inf+ Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexanoic Acid PFHxA 11/9/2021 11.9 Isotope Dilution Headworks (Inf+ Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroheptanoic Acid PFHpA 11/9/2021 1.37 J Isotope Dilution Headworks (Inf+ Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanoic Acid PFOA 11/9/2021 2.81 Isotope Dilution Headworks (Inf+ Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorononanoic Acid PFNA 11/9/2021 <LOD (0.634) U Isotope Dilution Headworks (Inf+ Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorodecanoic Acid PFDA 11/9/2021 1.85 J Isotope Dilution Headworks (Inf+ Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroundecanoic Acid PFUnDA 11/9/2021 <LOD (1.54) U Isotope Dilution Headworks (Inf+ Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorododecanoic Acid PFDoDA 11/9/2021 <LOD (1.68) U Isotope Dilution Headworks (Inf+ Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorotridecanoic Acid PFTrDA 11/9/2021 <LOD (1.26) U Isotope Dilution Headworks (Inf+ Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorotetradecanoic Acid PFTeDA 11/9/2021 <LOD (1.82) U Isotope Dilution Headworks (Inf+ Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorobutanesulfonic Acid PFBS 11/9/2021 <LOD (2.96) U Isotope Dilution Headworks (Inf+ Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoropentanesulfonate PFPeS 11/9/2021 <LOD (1.72) U Isotope Dilution Headworks (Inf+ Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexanesulfonic Acid PFHxS 11/9/2021 <LOD (1.59) U Isotope Dilution Headworks (Inf+ Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroheptanesulfonic Acid PFHpS 11/9/2021 1.45 J Isotope Dilution Headworks (Inf+ Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanesulfonic Acid PFOS 11/9/2021 12.7 Isotope Dilution Headworks (Inf+ Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorononanesulfonic Acid PFNS 11/9/2021 <LOD (0.720) U Isotope Dilution Headworks (Inf+ Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorodecanesulfonic Acid PFDS 11/9/2021 <LOD (1.60) U Isotope Dilution Headworks (Inf+ Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 4:2 Fluorotelomersulfonic Acid 4:2-FTS 11/9/2021 <LOD (0.983) U Isotope Dilution Headworks (Inf+ Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 6:2 Fluorotelomersulfonic Acid 6:2-FTS 11/9/2021 <LOD (0.967) U Isotope Dilution Headworks (Inf+ Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 8:2 Fluorotelomersulfonic Acid 8:2-FTS 11/9/2021 <LOD (1.43) U Isotope Dilution Headworks (Inf+ Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanesulfonamide PFOSA 11/9/2021 <LOD (1.08) U Isotope Dilution Headworks (Inf+ Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-methyl perfluorooctanesulfonamidoacetic acid NMeFOSAA 11/9/2021 5.23 Isotope Dilution Headworks (Inf+ Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-ethyl perfluorooctanesulfonamidoacetic acid NEtFOSAA 11/9/2021 <LOD (0.908) U Isotope Dilution Headworks (Inf+ Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse HFPODA HFPODA 11/9/2021 <LOD (1.90) U Isotope Dilution Headworks (Inf+ Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 4,8-dioxa 31-1-perfluorononanoic acid DONA 11/9/2021 <LOD (1.00) U Isotope Dilution Headworks (Inf+ Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 9CI-PF3ONS 9CI-PF3ONS 11/9/2021 <LOD (1.00) U Isotope Dilution Headworks (Inf+ Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 11 CI-PF3OUdS 11 CI-PF3OUdS 11/9/2021 <LOD (1.00) U Isotope Dilution Headworks (Inf+ Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 10:2 Fluorotelomersulfonic Acid 10:2-FTS 11/9/2021 <LOD (2.00) U Isotope Dilution Headworks (Inf+ Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-ethylperfluoro-l-octanesulfonamide N-EtPFOSA 11/9/2021 <LOD (2.00) U Isotope Dilution Headworks (Inf+ Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 2-(N ethyl perfluoro--octanesulfonamido)-ethanol N-EtPFOSAE 11/9/2021 <LOD (60.0) U Isotope Dilution Headworks (Inf+ Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-methylperfluoro-l-octanesulfonamide N-McPFOSA 11/9/2021 <LOD (2.00) U Isotope Dilution Headworks (Inf+ Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 2-(N-methyl perfluoro-l-octanesulfonamiso)-ethanol N-McPFOSAE 11/9/2021 <LOD (60.0) U Isotope Dilution Headworks (Inf+ Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorododecanesulfonic Acid PFDoS 11/9/2021 <LOD (18.7) U Isotope Dilution Headworks (Inf+ Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexadecanoic Acid PFHxDA 11/9/2021 <LOD (12.0) U Isotope Dilution Headworks (Inf+ Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctadecanoic Acid PFODA 11/9/2021 <LOD (12.0) U Isotope Dilution Headworks (Inf+ Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorobutanoic Acid PFBA 11/9/2021 12.5 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoropentanoic Acid PFPeA 11/9/2021 22.6 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexanoic Acid PFHxA 11/9/2021 21.1 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroheptanoic Acid PFHpA 11/9/2021 1.33 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanoic Acid PFOA 11/9/2021 7.39 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorononanoic Acid PFNA 11/9/2021 0.466 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorodecanoic Acid PFDA 11/9/2021 0.713 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroundecanoic Acid PFUnDA 11/9/2021 <LOD (0.188) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorododecanoic Acid PFDoDA 11/9/2021 <LOD (0.205) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorotridecanoic Acid PFTrDA 11/9/2021 <LOD (0.153) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorotetradecanoic Acid PFTeDA 11/9/2021 <LOD (0.221) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorobutanesulfonic Acid PFBS 11/9/2021 <LOD (0.360) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoropentanesulfonate PFPeS 11/9/2021 <LOD (0.209) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexanesulfonic Acid PFHxS 11/9/2021 1.83 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroheptanesulfonic Acid PFHpS 11/9/2021 <LOD (0.137) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanesulfonic Acid PFOS 11/9/2021 5.55 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorononanesulfonic Acid PFNS 11/9/2021 <LOD (0.0877) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorodecanesulfonic Acid PFDS 11/9/2021 <LOD (0.195) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 4:2 Fluorotelomersulfonic Acid 4:2-FTS 11/9/2021 <LOD (0.120) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 6:2 Fluorotelomersulfonic Acid 6:2-FTS 11/9/2021 0.451 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 8:2 Fluorotelomersulfonic Acid 8:2-FTS 11/9/2021 0.261 J Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanesulfonamide PFOSA 11/9/2021 <LOD (0.132) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-methyl perfluorooctanesulfonamidoacetic acid NMeFOSAA 11/9/2021 <LOD (0.146) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-ethyl perfluorooctanesulfonamidoacetic acid NEtFOSAA 11/9/2021 <LOD (0.111) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse HFPODA HFPODA 11/9/2021 <LOD (0.231) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 4,8-dioxa 31-1-perfluorononanoic acid DONA 11/9/2021 <LOD (0.122) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 9CI-PF3ONS 9CI-PF3ONS 11/9/2021 <LOD (0.122) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 11 CI-PF3OUdS 11 CI-PF3OUdS 11/9/2021 <LOD (0.122) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 10:2 Fluorotelomersulfonic Acid 10:2-FTS 11/9/2021 <LOD (0.244) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-ethylperfluoro-l-octanesulfonamide N-EtPFOSA 11/9/2021 <LOD (0.244) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 2-(N ethyl perfluoro--octanesulfonamido)-ethanol N-EtPFOSAE 11/9/2021 <LOD (7.31) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-methylperfluoro-l-octanesulfonamide N-McPFOSA 11/9/2021 <LOD (0.244) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 2-(N-methylperfluoro-l-octanesulfonamiso)-ethanol N-McPFOSAE 11/9/2021 <LOD (7.31) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorododecanesulfonic Acid PFDoS 11/9/2021 <LOD (2.27) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexadecanoic Acid PFHxDA 11/9/2021 <LOD (1.46) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctadecanoic Acid PFODA 11/9/2021 <LOD (1.46) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorobutanoic Acid PFBA 3/8/2022 11.7 Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoropentanoic Acid PFPeA 3/8/2022 10.9 Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexanoic Acid PFHxA 3/8/2022 12.6 Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroheptanoic Acid PFHpA 3/8/2022 2.36 Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanoic Acid PFOA 3/8/2022 6.05 Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorononanoic Acid PFNA 3/8/2022 0.404 Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorodecanoic Acid PFDA 3/8/2022 0.333 Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroundecanoic Acid PFUnDA 3/8/2022 <LOD (0.166) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorododecanoic Acid PFDoDA 3/8/2022 <LOD (0.181) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorotridecanoic Acid PFTrDA 3/8/2022 <LOD (0.135) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorotetradecanoic Acid PFTeDA 3/8/2022 <LOD (0.195) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorobutanesulfonic Acid PFBS 3/8/2022 4.42 Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoropentanesulfonate PFPeS 3/8/2022 <LOD (0.184) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexanesulfonic Acid PFHxS 3/8/2022 2.28 Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroheptanesulfonic Acid PFHpS 3/8/2022 <LOD (0.121) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanesulfonic Acid PFOS 3/8/2022 3.69 Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorononanesulfonic Acid PFNS 3/8/2022 <LOD (0.0774) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorodecanesulfonic Acid PFDS 3/8/2022 <LOD (0.172) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 4:2 Fluorotelomersulfonic Acid 4:2-FTS 3/8/2022 <LOD (0.106) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 6:2 Fluorotelomersulfonic Acid 6:2-FTS 3/8/2022 0.219 J Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 8:2 Fluorotelomersulfonic Acid 8:2-FTS 3/8/2022 0.376 Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanesulfonamide PFOSA 3/8/2022 <LOD (0.116) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-methyl perfluorooctanesulfonamidoacetic acid NMeFOSAA 3/8/2022 0.302 Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-ethyl perfluorooctanesulfonamidoacetic acid NEtFOSAA 3/8/2022 0.186 J Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse HFPODA HFPODA 3/8/2022 <LOD (0.204) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 4,8-dioxa 31-1-perfluorononanoic acid DONA 3/8/2022 <LOD (0.107) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 9CI-PF3ONS 9CI-PF3ONS 3/8/2022 <LOD (0.107) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 11 CI-PF3OUdS 11 CI-PF3OUdS 3/8/2022 <LOD (0.107) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 10:2 Fluorotelomersulfonic Acid 10:2-FTS 3/8/2022 <LOD (0.215) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-ethylperfluoro-l-octanesulfonamide N-EtPFOSA 3/8/2022 <LOD (0.215) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 2-(N ethyl perfluoro--octanesulfonamido)-ethanol N-EtPFOSAE 3/8/2022 <LOD (6.45) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-methylperfluoro-l-octanesulfonamide N-McPFOSA 3/8/2022 <LOD (0.215) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 2-(N-methylperfluoro-l-octanesulfonamiso)-ethanol N-McPFOSAE 3/8/2022 <LOD (6.45) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorododecanesulfonic Acid PFDoS 3/8/2022 <LOD (2.01) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexadecanoic Acid PFHxDA 3/8/2022 <LOD (1.29) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctadecanoic Acid PFODA 3/8/2022 3.79 Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorobutanoic Acid PFBA 3/8/2022 9.97 Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoropentanoic Acid PFPeA 3/8/2022 12.9 Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexanoic Acid PFHxA 3/8/2022 13.7 Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroheptanoic Acid PFHpA 3/8/2022 2.65 Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanoic Acid PFOA 3/8/2022 4.71 Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorononanoic Acid PFNA 3/8/2022 0.418 Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorodecanoic Acid PFDA 3/8/2022 0.628 Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroundecanoic Acid PFUnDA 3/8/2022 <LOD (0.231) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorododecanoic Acid PFDoDA 3/8/2022 <LOD (0.252) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorotridecanoic Acid PFTrDA 3/8/2022 <LOD (0.189) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorotetradecanoic Acid PFTeDA 3/8/2022 <LOD (0.272) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorobutanesulfonic Acid PFBS 3/8/2022 <LOD (0.444) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoropentanesulfonate PFPeS 3/8/2022 <LOD (0.258) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexanesulfonic Acid PFHxS 3/8/2022 2.61 Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroheptanesulfonic Acid PFHpS 3/8/2022 <LOD (0.169) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanesulfonic Acid PFOS 3/8/2022 3.94 Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorononanesulfonic Acid PFNS 3/8/2022 <LOD (0.108) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorodecanesulfonic Acid PFDS 3/8/2022 <LOD (0.240) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 4:2 Fluorotelomersulfonic Acid 4:2-FTS 3/8/2022 <LOD (0.148) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 6:2 Fluorotelomersulfonic Acid 6:2-FTS 3/8/2022 0.428 Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 8:2 Fluorotelomersulfonic Acid 8:2-FTS 3/8/2022 0.235 J Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanesulfonamide PFOSA 3/8/2022 <LOD (0.162) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-methyl perfluorooctanesulfonamidoacetic acid NMeFOSAA 3/8/2022 0.737 Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-ethyl perfluorooctanesulfonamidoacetic acid NEtFOSAA 3/8/2022 <LOD (0.136) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse HFPODA HFPODA 3/8/2022 <LOD (0.285) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 4,8-dioxa 31-1-perfluorononanoic acid DONA 3/8/2022 <LOD (0.150) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 9CI-PF3ONS 9CI-PF3ONS 3/8/2022 <LOD (0.150) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 11 CI-PF3OUdS 11 CI-PF3OUdS 3/8/2022 <LOD (0.150) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 10:2 Fluorotelomersulfonic Acid 10:2-FTS 3/8/2022 <LOD (0.300) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-ethylperfluoro-l-octanesulfonamide N-EtPFOSA 3/8/2022 <LOD (0.300) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 2-(N ethyl perfluoro--octanesulfonamido)-ethanol N-EtPFOSAE 3/8/2022 <LOD (9.00) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-methylperfluoro-l-octanesulfonamide N-McPFOSA 3/8/2022 <LOD (0.300) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 2-(N-methylperfluoro-l-octanesulfonamiso)-ethanol N-McPFOSAE 1 3/8/2022 1 <LOD (9.00) 1 U I Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorododecanesulfonic Acid jPFDoS 1 3/8/2022 1 <LOD (2.80) 1 U I Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexadecanoic Acid PFHxDA 3/8/2022 <LOD 1.80) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctadecanoic Acid PFODA 3/8/2022 <LOD (1.80) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorobutanoic Acid PFBA 3/8/2022 11.4 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoropentanoic Acid PFPeA 3/8/2022 14.0 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexanoic Acid PFHxA 3/8/2022 24.1 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroheptanoic Acid PFHpA 3/8/2022 2.55 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanoic Acid PFOA 3/8/2022 8.23 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorononanoic Acid PFNA 3/8/2022 0.456 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorodecanoic Acid PFDA 3/8/2022 0.872 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroundecanoic Acid PFUnDA 3/8/2022 <LOD (0.175) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorododecanoic Acid PFDoDA 3/8/2022 <LOD (0.191) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorotridecanoic Acid PFTrDA 3/8/2022 <LOD (0.143) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorotetradecanoic Acid PFTeDA 3/8/2022 <LOD (0.206) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorobutanesulfonic Acid PFBS 3/8/2022 4.15 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoropentanesulfonate PFPeS 3/8/2022 0.241 J Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexanesulfonic Acid PFHxS 3/8/2022 1.67 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroheptanesulfonic Acid PFHpS 3/8/2022 <LOD (0.128) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanesulfonic Acid PFOS 3/8/2022 4.01 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorononanesulfonic Acid PFNS 3/8/2022 <LOD (0.0818) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorodecanesulfonic Acid PFDS 3/8/2022 <LOD (0.182) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 4:2 Fluorotelomersulfonic Acid 4:2-FTS 3/8/2022 <LOD (0.112) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 6:2 Fluorotelomersulfonic Acid 6:2-FTS 3/8/2022 0.148 J Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 8:2 Fluorotelomersulfonic Acid 8:2-FTS 3/8/2022 0.185 J Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanesulfonamide PFOSA 3/8/2022 <LOD (0.123) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-methyl perfluorooctanesulfonamidoacetic acid NMeFOSAA 3/8/2022 0.966 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-ethyl perfluorooctanesulfonamidoacetic acid NEtFOSAA 3/8/2022 0.125 J Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse HFPODA HFPODA 3/8/2022 <LOD (0.216) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 4,8-dioxa 31-1-perfluorononanoic acid DONA 3/8/2022 <LOD (0.114) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 9CI-PF3ONS 9CI-PF3ONS 3/8/2022 <LOD (0.114) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 11 CI-PF3OUdS 11 CI-PF3OUdS 3/8/2022 <LOD (0.114) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 10:2 Fluorotelomersulfonic Acid 10:2-FTS 3/8/2022 <LOD (0.227) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-ethylperfluoro-l-octanesulfonamide N-EtPFOSA 3/8/2022 <LOD (0.227) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 2-(N ethyl perfluoro--octanesulfonamido)-ethanol N-EtPFOSAE 3/8/2022 <LOD (6.82) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-methylperfluoro-l-octanesulfonamide N-McPFOSA 3/8/2022 <LOD (0.227) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 2-(N-methylperfluoro-l-octanesulfonamiso)-ethanol N-McPFOSAE 3/8/2022 <LOD (6.82) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorododecanesulfonic Acid PFDoS 3/8/2022 <LOD (2.12) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexadecanoic Acid PFHxDA 3/8/2022 <LOD (1.36) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctadecanoic Acid PFODA 3/8/2022 <LOD (1.36) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorobutanoic Acid PFBA 6/14/2022 8.81 Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoropentanoic Acid PFPeA 6/14/2022 12.4 Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexanoic Acid PFHxA 6/14/2022 9.45 Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroheptanoic Acid PFHpA 6/14/2022 1.87 Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanoic Acid PFOA 6/14/2022 3.04 Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorononanoic Acid PFNA 6/14/2022 0.330 J Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorodecanoic Acid PFDA 6/14/2022 0.524 J Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroundecanoic Acid PFUnDA 6/14/2022 <LOD (0.179) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorododecanoic Acid PFDoDA 6/14/2022 <LOD (0.196) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorotridecanoic Acid PFTrDA 6/14/2022 <LOD (0.146) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorotetradecanoic Acid PFTeDA 6/14/2022 <LOD (0.211) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorobutanesulfonic Acid PFBS 6/14/2022 2.49 Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoropentanesulfonate PFPeS 6/14/2022 <LOD (0.199) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexanesulfonic Acid PFHxS 6/14/2022 <LOD (0.185) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroheptanesulfonic Acid PFHpS 6/14/2022 <LOD (0.131) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanesulfonic Acid PFOS 6/14/2022 3.54 Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorononanesulfonic Acid PFNS 6/14/2022 <LOD (0.0836) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorodecanesulfonic Acid PFDS 6/14/2022 <LOD (0.186) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 4:2 Fluorotelomersulfonic Acid 4:2-FTS 6/14/2022 <LOD (0.114) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 6:2 Fluorotelomersulfonic Acid 6:2-FTS 6/14/2022 0.380 J Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 8:2 Fluorotelomersulfonic Acid 8:2-FTS 6/14/2022 0.470 J Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanesulfonamide PFOSA 6/14/2022 <LOD (0.126) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-methyl perfluorooctanesulfonamidoacetic acid NMeFOSAA 6/14/2022 1.08 Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-ethyl perfluorooctanesulfonamidoacetic acid NEtFOSAA 6/14/2022 <LOD (0.106) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse HFPODA HFPODA 6/14/2022 <LOD (0.221) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 4,8-dioxa 31-1-perfluorononanoic acid DONA 6/14/2022 <LOD (0.116) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 9CI-PF3ONS 9CI-PF3ONS 6/14/2022 <LOD (0.116) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 11 CI-PF3OUdS 11 CI-PF3OUdS 6/14/2022 <LOD (0.116) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 10:2 Fluorotelomersulfonic Acid 10:2-FTS 6/14/2022 <LOD (0.232) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-ethylperfluoro-l-octanesulfonamide N-EtPFOSA 6/14/2022 <LOD (0.232) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 2-(N ethyl perfluoro--octanesulfonamido)-ethanol N-EtPFOSAE 6/14/2022 <LOD (6.97) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-methylperfluoro-l-octanesulfonamide N-McPFOSA 6/14/2022 <LOD (0.232) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 2-(N-methylperfluoro-l-octanesulfonamiso)-ethanol N-McPFOSAE 6/14/2022 <LOD (6.97) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorododecanesulfonic Acid PFDoS 6/14/2022 <LOD (2.17) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexadecanoic Acid PFHxDA 6/14/2022 <LOD (1.39) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctadecanoic Acid PFODA 6/14/2022 <LOD (1.39) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorobutanoic Acid PFBA 6/14/2022 10.5 Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoropentanoic Acid PFPeA 6/14/2022 31.8 Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexanoic Acid PFHxA 6/14/2022 12.8 Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroheptanoic Acid PFHpA 6/14/2022 2.10 Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanoic Acid PFOA 6/14/2022 4.19 Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorononanoic Acid PFNA 6/14/2022 0.403 J Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorodecanoic Acid PFDA 6/14/2022 0.409 J Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroundecanoic Acid JPFUnDA 1 6/14/2022 1 <LOD (0.176) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorododecanoic Acid jPFDoDA 1 6/14/2022 1 <LOD (0.193) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorotridecanoic Acid PFTrDA 6/14/2022 <LOD (0.144) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorotetradecanoic Acid PFTeDA 6/14/2022 <LOD (0.208) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorobutanesulfonic Acid PFBS 6/14/2022 3.07 Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoropentanesulfonate PFPeS 6/14/2022 <LOD (0.196) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexanesulfonic Acid PFHxS 6/14/2022 <LOD (0.182) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroheptanesulfonic Acid PFHpS 6/14/2022 <LOD (0.129) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanesulfonic Acid PFOS 6/14/2022 3.81 Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorononanesulfonic Acid PFNS 6/14/2022 <LOD (0.824) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorodecanesulfonic Acid PFDS 6/14/2022 <LOD (0.183) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 4:2 Fluorotelomersulfonic Acid 4:2-FTS 6/14/2022 <LOD (0.112) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 6:2 Fluorotelomersulfonic Acid 6:2-FTS 6/14/2022 0.732 Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 8:2 Fluorotelomersulfonic Acid 8:2-FTS 6/14/2022 <LOD (0.163) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanesulfonamide PFOSA 6/14/2022 <LOD (0.124) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-methyl perfluorooctanesulfonamidoacetic acid NMeFOSAA 6/14/2022 <LOD (0.137) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-ethyl perfluorooctanesulfonamidoacetic acid NEtFOSAA 6/14/2022 <LOD (0.104) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse HFPODA HFPODA 6/14/2022 0.225 J Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 4,8-dioxa 31-1-perfluorononanoic acid DONA 6/14/2022 <LOD (0.114) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 9CI-PF3ONS 9CI-PF3ONS 6/14/2022 <LOD (0.114) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 11 CI-PF3OUdS 11 CI-PF3OUdS 6/14/2022 <LOD (0.114) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 10:2 Fluorotelomersulfonic Acid 10:2-FTS 6/14/2022 <LOD (0.229) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-ethylperfluoro-l-octanesulfonamide N-EtPFOSA 6/14/2022 <LOD (0.229) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 2-(N ethyl perfluoro--octanesulfonamido)-ethanol N-EtPFOSAE 6/14/2022 <LOD (6.86) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-methylperfluoro-l-octanesulfonamide N-McPFOSA 6/14/2022 <LOD (0.229) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 2-(N-methylperfluoro-l-octanesulfonamiso)-ethanol N-McPFOSAE 6/14/2022 <LOD (6.86) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorododecanesulfonic Acid PFDoS 6/14/2022 <LOD (2.14) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexadecanoic Acid PFHxDA 6/14/2022 <LOD (1.37) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctadecanoic Acid PFODA 6/14/2022 <LOD (1.37) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorobutanoic Acid PFBA 6/14/2022 14.1 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoropentanoic Acid PFPeA 6/14/2022 18.8 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexanoic Acid PFHxA 6/14/2022 17.8 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroheptanoic Acid PFHpA 6/14/2022 2.28 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanoic Acid PFOA 6/14/2022 9.12 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorononanoic Acid PFNA 6/14/2022 0.470 J Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorodecanoic Acid PFDA 6/14/2022 0.863 J Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroundecanoic Acid PFUnDA 6/14/2022 <LOD (0.178) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorododecanoic Acid PFDoDA 6/14/2022 <LOD (0.194) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorotridecanoic Acid PFTrDA 6/14/2022 <LOD (0.145) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorotetradecanoic Acid PFTeDA 6/14/2022 <LOD 0.210) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorobutanesulfonic Acid PFBS 6/14/2022 3.35 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoropentanesulfonate PFPeS 6/14/2022 0.252 J Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexanesulfonic Acid PFHxS 6/14/2022 0.641 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroheptanesulfonic Acid PFHpS 6/14/2022 <LOD (0.130) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanesulfonic Acid PFOS 6/14/2022 4.78 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorononanesulfonic Acid PFNS 6/14/2022 <LOD (0.0832) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorodecanesulfonic Acid PFDS 6/14/2022 <LOD (0.185) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 4:2 Fluorotelomersulfonic Acid 4:2-FTS 6/14/2022 <LOD (0.114) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 6:2 Fluorotelomersulfonic Acid 6:2-FTS 6/14/2022 0.356 J Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 8:2 Fluorotelomersulfonic Acid 8:2-FTS 6/14/2022 0.274 J Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanesulfonamide PFOSA 6/14/2022 1.48 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-methyl perfluorooctanesulfonamidoacetic acid NMeFOSAA 6/14/2022 0.807 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-ethyl perfluorooctanesulfonamidoacetic acid NEtFOSAA 6/14/2022 <LOD (0.105) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse HFPODA HFPODA 6/14/2022 <LOD (0.219) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 4,8-dioxa 31-1-perfluorononanoic acid DONA 6/14/2022 <LOD (0.116) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 9CI-PF3ONS 9CI-PF3ONS 6/14/2022 <LOD (0.116) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 11 CI-PF3OUdS 11 CI-PF3OUdS 6/14/2022 <LOD (0.116) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 10:2 Fluorotelomersulfonic Acid 10:2-FTS 6/14/2022 <LOD (0.231) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-ethylperfluoro-l-octanesulfonamide N-EtPFOSA 6/14/2022 <LOD (0.231) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 2-(N ethyl perfluoro--octanesulfonamido)-ethanol N-EtPFOSAE 6/14/2022 <LOD (6.93) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-methylperfluoro-l-octanesulfonamide N-McPFOSA 6/14/2022 <LOD (0.231) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 2-(N-methylperfluoro-l-octanesulfonamiso)-ethanol N-McPFOSAE 6/14/2022 <LOD (6.93) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorododecanesulfonic Acid PFDoS 6/14/2022 <LOD (2.16) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexadecanoic Acid PFHxDA 6/14/2022 <LOD (1.39) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctadecanoic Acid PFODA 6/14/2022 <LOD (1.39) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorobutanoic Acid PFBA 9/13/2022 6.81 J Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoropentanoic Acid PFPeA 9/13/2022 5.24 J Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexanoic Acid PFHxA 9/13/2022 7.09 J Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroheptanoic Acid PFHpA 9/13/2022 <LOD (3.05) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanoic Acid PFOA 9/13/2022 <LOD (4.43) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorononanoic Acid PFNA 9/13/2022 <LOD (1.90) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorodecanoic Acid PFDA 9/13/2022 <LOD (2.11) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroundecanoic Acid PFUnDA 9/13/2022 <LOD (4.63) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorododecanoic Acid PFDoDA 9/13/2022 <LOD (5.05) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorotridecanoic Acid PFTrDA 9/13/2022 <LOD (3.78) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorotetradecanoic Acid PFTeDA 9/13/2022 <LOD (5.45) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorobutanesulfonic Acid PFBS 9/13/2022 <LOD (8.88) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoropentanesulfonate PFPeS 9/13/2022 <LOD (5.15) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexanesulfonic Acid PFHxS 9/13/2022 <LOD (4.78) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroheptanesulfonic Acid PFHpS 9/13/2022 <LOD (3.38) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanesulfonic Acid PFOS 9/13/2022 <LOD (4.00) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorononanesulfonic Acid PFNS 9/13/2022 <LOD (2.16) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorodecanesulfonic Acid PFDS 9/13/2022 <LOD (4.80) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 4:2 Fluorotelomersulfonic Acid 4:2-FTS 1 9/13/2022 1 <LOD (2.95) 1 U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 6:2 Fluorotelomersulfonic Acid 6:2-FTS 1 9/13/2022 1 <LOD (2.90) 1 U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 8:2 Fluorotelomersulfonic Acid 8:2-FTS 9/13/2022 <LOD (4.28) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanesulfonamide PFOSA 9/13/2022 <LOD (3.25) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-methyl perfluorooctanesulfonamidoacetic acid NMeFOSAA 9/13/2022 <LOD (3.60) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-ethyl perfluorooctanesulfonamidoacetic acid NEtFOSAA 9/13/2022 <LOD (2.73) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse HFPODA HFPODA 9/13/2022 <LOD (5.70) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 4,8-dioxa 31-1-perfluorononanoic acid DONA 9/13/2022 <LOD (3.00) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 9CI-PF3ONS 9CI-PF3ONS 9/13/2022 <LOD (3.00) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 11 CI-PF3OUdS 11 CI-PF3OUdS 9/13/2022 <LOD (3.00) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 10:2 Fluorotelomersulfonic Acid 10:2-FTS 9/13/2022 <LOD (6.00) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-ethylperfluoro-l-octanesulfonamide N-EtPFOSA 9/13/2022 <LOD (6.00) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 2-(N ethyl perfluoro--octanesulfonamido)-ethanol N-EtPFOSAE 9/13/2022 <LOD (180) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-methylperfluoro-l-octanesulfonamide N-McPFOSA 9/13/2022 <LOD (6.00) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 2-(N-methylperfluoro-l-octanesulfonamiso)-ethanol N-McPFOSAE 9/13/2022 <LOD (180) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorododecanesulfonic Acid PFDoS 9/13/2022 <LOD (56.0) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexadecanoic Acid PFHxDA 9/13/2022 <LOD (36.0) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctadecanoic Acid PFODA 9/13/2022 <LOD (36.0) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorobutanoic Acid PFBA 9/13/2022 9.79 J Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoropentanoic Acid PFPeA 9/13/2022 10.3 J Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexanoic Acid PFHxA 9/13/2022 8.85 J Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroheptanoic Acid PFHpA 9/13/2022 <LOD (3.05) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanoic Acid PFOA 9/13/2022 <LOD (4.43) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorononanoic Acid PFNA 9/13/2022 <LOD (1.90) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorodecanoic Acid PFDA 9/13/2022 <LOD (2.11) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroundecanoic Acid PFUnDA 9/13/2022 <LOD (4.63) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorododecanoic Acid PFDoDA 9/13/2022 <LOD (5.05) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorotridecanoic Acid PFTrDA 9/13/2022 <LOD (3.78) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorotetradecanoic Acid PFTeDA 9/13/2022 <LOD (5.45) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorobutanesulfonic Acid PFBS 9/13/2022 <LOD (8.88) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoropentanesulfonate PFPeS 9/13/2022 <LOD (5.15) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexanesulfonic Acid PFHxS 9/13/2022 <LOD (4.78) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroheptanesulfonic Acid PFHpS 9/13/2022 <LOD (3.38) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanesulfonic Acid PFOS 9/13/2022 <LOD (4.00) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorononanesulfonic Acid PFNS 9/13/2022 <LOD (2.16) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorodecanesulfonic Acid PFDS 9/13/2022 <LOD (4.80) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 4:2 Fluorotelomersulfonic Acid 4:2-FTS 9/13/2022 <LOD (2.95) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 6:2 Fluorotelomersulfonic Acid 6:2-FTS 9/13/2022 <LOD (2.90) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 8:2 Fluorotelomersulfonic Acid 8:2-FTS 9/13/2022 <LOD (4.28) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanesulfonamide PFOSA 9/13/2022 <LOD (3.25) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-methyl perfluorooctanesulfonamidoacetic acid NMeFOSAA 9/13/2022 <LOD (3.60) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-ethyl perfluorooctanesulfonamidoacetic acid NEtFOSAA 9/13/2022 <LOD (2.73) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse HFPODA HFPODA 9/13/2022 <LOD (5.70) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 4,8-dioxa 31-1-perfluorononanoic acid DONA 9/13/2022 <LOD (3.00) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 9CI-PF3ONS 9CI-PF3ONS 9/13/2022 <LOD (3.00) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 11 CI-PF3OUdS 11 CI-PF3OUdS 9/13/2022 <LOD (3.00) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 10:2 Fluorotelomersulfonic Acid 10:2-FTS 9/13/2022 <LOD (6.00) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-ethylperfluoro-l-octanesulfonamide N-EtPFOSA 9/13/2022 <LOD (6.00) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 2-(N ethyl perfluoro--octanesulfonamido)-ethanol N-EtPFOSAE 9/13/2022 <LOD (180) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-methylperfluoro-l-octanesulfonamide N-McPFOSA 9/13/2022 <LOD (6.00) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 2-(N-methylperfluoro-l-octanesulfonamiso)-ethanol N-McPFOSAE 9/13/2022 <LOD (180) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorododecanesulfonic Acid PFDoS 9/13/2022 <LOD (56.0) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexadecanoic Acid PFHxDA 9/13/2022 <LOD (36.0) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctadecanoic Acid PFODA 9/13/2022 <LOD (36.0) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorobutanoic Acid PFBA 9/13/2022 10.4 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoropentanoic Acid PFPeA 9/13/2022 21.1 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexanoic Acid PFHxA 9/13/2022 22.1 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroheptanoic Acid PFHpA 9/13/2022 1.48 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanoic Acid PFOA 9/13/2022 7.77 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorononanoic Acid PFNA 9/13/2022 0.387 J Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorodecanoic Acid PFDA 9/13/2022 0.931 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroundecanoic Acid PFUnDA 9/13/2022 <LOD (0.178) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorododecanoic Acid PFDoDA 9/13/2022 <LOD (0.195) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorotridecanoic Acid PFTrDA 9/13/2022 <LOD (0.146) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorotetradecanoic Acid PFTeDA 9/13/2022 <LOD (0.210) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorobutanesulfonic Acid PFBS 9/13/2022 3.05 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoropentanesulfonate PFPeS 9/13/2022 <LOD (0.199) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexanesulfonic Acid PFHxS 9/13/2022 0.702 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroheptanesulfonic Acid PFHpS 9/13/2022 <LOD (0.130) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanesulfonic Acid PFOS 9/13/2022 3.34 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorononanesulfonic Acid PFNS 9/13/2022 <LOD (0.0833) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorodecanesulfonic Acid PFDS 9/13/2022 <LOD (0.185) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 4:2 Fluorotelomersulfonic Acid 4:2-FTS 9/13/2022 <LOD (0.114) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 6:2 Fluorotelomersulfonic Acid 6:2-FTS 9/13/2022 0.473 J Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 8:2 Fluorotelomersulfonic Acid 8:2-FTS 9/13/2022 <LOD (0.165) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanesulfonamide PFOSA 9/13/2022 <LOD (0.125) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-methyl perfluorooctanesulfonamidoacetic acid NMeFOSAA 9/13/2022 0.723 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-ethyl perfluorooctanesulfonamidoacetic acid NEtFOSAA 9/13/2022 0.241 J Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse HFPODA HFPODA 9/13/2022 <LOD (0.220) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 4,8-dioxa 31-1-perfluorononanoic acid DONA 9/13/2022 <LOD (0.116) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 9CI-PF3ONS 9CI-PF3ONS 9/13/2022 <LOD (0.116) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 11 CI-PF3OUdS 11 CI-PF3OUdS 9/13/2022 <LOD (0.116) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 10:2 Fluorotelomersulfonic Acid 10:2-FTS 9/13/2022 <LOD (0.231) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-ethylperfluoro-l-octanesulfonamide N-EtPFOSA 9/13/2022 1 <LOD (0.231) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 2-(N ethyl perfluoro--octanesulfonamido)-ethanol N-EtPFOSAE 9/13/2022 1 <LOD (6.94) 1 U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-methyl perfluoro-l-octanesulfonamide N-McPFOSA 9/13/2022 <LOD (0.231) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 2-(N-methylperfluoro-l-octanesulfonamiso)-ethanol N-McPFOSAE 9/13/2022 <LOD (6.94) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorododecanesulfonic Acid PFDoS 9/13/2022 <LOD (2.16) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexadecanoic Acid PFHxDA 9/13/2022 <LOD (1.39) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctadecanoic Acid PFODA 9/13/2022 <LOD (1.39) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorobutanoic Acid PFBA 11/15/2022 19.7 Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoropentanoic Acid PFPeA 11/15/2022 11.5 Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexanoic Acid PFHxA 11/15/2022 8.58 Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroheptanoic Acid PFHpA 11/15/2022 1.13 J Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanoic Acid PFOA 11/15/2022 2.23 J Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorononanoic Acid PFNA 11/15/2022 <LOD (0.634) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorodecanoic Acid PFDA 11/15/2022 <LOD (0.704) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroundecanoic Acid PFUnDA 11/15/2022 <LOD (1.54) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorododecanoic Acid PFDoDA 11/15/2022 <LOD (1.68) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorotridecanoic Acid PFTrDA 11/15/2022 <LOD (1.26) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorotetradecanoic Acid PFTeDA 11/15/2022 <LOD (1.82) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorobutanesulfonic Acid PFBS 11/15/2022 <LOD (2.96) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoropentanesulfonate PFPeS 11/15/2022 <LOD (1.72) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexanesulfonic Acid PFHxS 11/15/2022 <LOD (1.59) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroheptanesulfonic Acid PFHpS 11/15/2022 <LOD (1.13) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanesulfonic Acid PFOS 11/15/2022 <LOD (1.33) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorononanesulfonic Acid PFNS 11/15/2022 <LOD (0.720) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorodecanesulfonic Acid PFDS 11/15/2022 <LOD (1.60) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 4:2 Fluorotelomersulfonic Acid 4:2-FTS 11/15/2022 <LOD (0.983) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 6:2 Fluorotelomersulfonic Acid 6:2-FTS 11/15/2022 2.52 J Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 8:2 Fluorotelomersulfonic Acid 8:2-FTS 11/15/2022 <LOD (1.43) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanesulfonamide PFOSA 11/15/2022 <LOD (1.08) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-methyl perfluorooctanesulfonamidoacetic acid NMeFOSAA 11/15/2022 <LOD (1.20) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-ethyl perfluorooctanesulfonamidoacetic acid NEtFOSAA 11/15/2022 <LOD (0.908) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse HFPODA HFPODA 11/15/2022 <LOD (1.90) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 4,8-dioxa 31-1-perfluorononanoic acid DONA 11/15/2022 <LOD (1.00) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 9CI-PF3ONS 9CI-PF3ONS 11/15/2022 <LOD (1.00) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 11 CI-PF3OUdS 11 CI-PF3OUdS 11/15/2022 <LOD (1.00) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 10:2 Fluorotelomersulfonic Acid 10:2-FTS 11/15/2022 <LOD (2.00) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-ethylperfluoro-l-octanesulfonamide N-EtPFOSA 11/15/2022 <LOD (2.00) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 2-(N ethyl perfluoro--octanesulfonamido)-ethanol N-EtPFOSAE 11/15/2022 <LOD (60.0) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-methylperfluoro-l-octanesulfonamide N-McPFOSA 11/15/2022 <LOD (2.00) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 2-(N-methylperfluoro-l-octanesulfonamiso)-ethanol N-McPFOSAE 11/15/2022 <LOD (60.0) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorododecanesulfonic Acid PFDoS 11/15/2022 <LOD (18.7) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexadecanoic Acid PFHxDA 11/15/2022 <LOD (12.0) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctadecanoic Acid PFODA 11/15/2022 <LOD (12.0) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorobutanoic Acid PFBA 11/15/2022 15.5 Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoropentanoic Acid PFPeA 11/15/2022 13.0 Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexanoic Acid PFHxA 11/15/2022 10.6 Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroheptanoic Acid PFHpA 11/15/2022 <LOD (1.02) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanoic Acid PFOA 11/15/2022 3.24 J Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorononanoic Acid PFNA 11/15/2022 <LOD (0.634) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorodecanoic Acid PFDA 11/15/2022 <LOD (0.704) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroundecanoic Acid PFUnDA 11/15/2022 <LOD (1.54) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorododecanoic Acid PFDoDA 11/15/2022 <LOD (1.68) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorotridecanoic Acid PFTrDA 11/15/2022 <LOD (1.26) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorotetradecanoic Acid PFTeDA 11/15/2022 <LOD (1.82) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorobutanesulfonic Acid PFBS 11/15/2022 <LOD (2.96) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoropentanesulfonate PFPeS 11/15/2022 <LOD (1.72) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexanesulfonic Acid PFHxS 11/15/2022 <LOD (1.59) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroheptanesulfonic Acid PFHpS 11/15/2022 <LOD (1.13) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanesulfonic Acid PFOS 11/15/2022 <LOD (1.33) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorononanesulfonic Acid PFNS 11/15/2022 <LOD (0.720) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorodecanesulfonic Acid PFDS 11/15/2022 <LOD (1.60) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 4:2 Fluorotelomersulfonic Acid 4:2-FTS 11/15/2022 <LOD (0.983) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 6:2 Fluorotelomersulfonic Acid 6:2-FTS 11/15/2022 1.27 J Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 8:2 Fluorotelomersulfonic Acid 8:2-FTS 11/15/2022 <LOD (1.43) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanesulfonamide PFOSA 11/15/2022 <LOD (1.08) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-methyl perfluorooctanesulfonamidoacetic acid NMeFOSAA 11/15/2022 <LOD (1.20) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-ethyl perfluorooctanesulfonamidoacetic acid NEtFOSAA 11/15/2022 <LOD (0.908) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse HFPODA HFPODA 11/15/2022 <LOD (1.90) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 4,8-dioxa 31-1-perfluorononanoic acid DONA 11/15/2022 <LOD (1.00) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 9CI-PF3ONS 9CI-PF3ONS 11/15/2022 <LOD (1.00) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 11 CI-PF3OUdS 11 CI-PF3OUdS 11/15/2022 <LOD (1.00) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 10:2 Fluorotelomersulfonic Acid 10:2-FTS 11/15/2022 <LOD (2.00) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-ethylperfluoro-l-octanesulfonamide N-EtPFOSA 11/15/2022 <LOD (2.00) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 2-(N ethyl perfluoro--octanesulfonamido)-ethanol N-EtPFOSAE 11/15/2022 <LOD (60.0) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-methylperfluoro-l-octanesulfonamide N-McPFOSA 11/15/2022 <LOD (2.00) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 2-(N-methylperfluoro-l-octanesulfonamiso)-ethanol N-McPFOSAE 11/15/2022 <LOD (60.0) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorododecanesulfonic Acid PFDoS 11/15/2022 <LOD (18.7) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexadecanoic Acid PFHxDA 11/15/2022 <LOD (12.0) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctadecanoic Acid PFODA 11/15/2022 <LOD (12.0) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorobutanoic Acid PFBA 11/15/2022 10.8 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoropentanoic Acid PFPeA 11/15/2022 25.4 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexanoic Acid PFHxA 11/15/2022 24.0 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroheptanoic Acid PFHpA 11/15/2022 2.78 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanoic Acid JPFOA 1 11/15/2022 1 11.0 1 1 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorononanoic Acid JPFNA 1 11/15/2022 1 0.433 1 1 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorodecanoic Acid PFDA 11/15/2022 0.945 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroundecanoic Acid PFUnDA 11/15/2022 <LOD (0.181) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorododecanoic Acid PFDoDA 11/15/2022 <LOD (0.197) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorotridecanoic Acid PFTrDA 11/15/2022 <LOD (0.148) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorotetradecanoic Acid PFTeDA 11/15/2022 <LOD (0.213) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorobutanesulfonic Acid PFBS 11/15/2022 4.82 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoropentanesulfonate PFPeS 11/15/2022 <LOD (0.201) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexanesulfonic Acid PFHxS 11/15/2022 0.777 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroheptanesulfonic Acid PFHpS 11/15/2022 <LOD (0.132) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanesulfonic Acid PFOS 11/15/2022 2.87 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorononanesulfonic Acid PFNS 11/15/2022 <LOD (0.0844) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorodecanesulfonic Acid PFDS 11/15/2022 <LOD (0.188) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 4:2 Fluorotelomersulfonic Acid 4:2-FTS 11/15/2022 <LOD (0.115) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 6:2 Fluorotelomersulfonic Acid 6:2-FTS 11/15/2022 0.149 J Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 8:2 Fluorotelomersulfonic Acid 8:2-FTS 11/15/2022 <LOD (0.167) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanesulfonamide PFOSA 11/15/2022 0.167 J Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-methyl perfluorooctanesulfonamidoacetic acid NMeFOSAA 11/15/2022 <LOD (0.141) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-ethyl perfluorooctanesulfonamidoacetic acid NEtFOSAA 11/15/2022 <LOD (0.106) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse HFPODA HFPODA 11/15/2022 <LOD (0.223) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 4,8-dioxa 31-1-perfluorononanoic acid DONA 11/15/2022 <LOD (0.117) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 9CI-PF3ONS 9CI-PF3ONS 11/15/2022 <LOD (0.117) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 11 CI-PF3OUdS 11 CI-PF3OUdS 11/15/2022 <LOD (0.117) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 10:2 Fluorotelomersulfonic Acid 10:2-FTS 11/15/2022 <LOD (0.234) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-ethylperfluoro-l-octanesulfonamide N-EtPFOSA 11/15/2022 <LOD (0.234) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 2-(N ethyl perfluoro--octanesulfonamido)-ethanol N-EtPFOSAE 11/15/2022 <LOD (7.03) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-methylperfluoro-l-octanesulfonamide N-McPFOSA 11/15/2022 <LOD (0.234) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 2-(N-methylperfluoro-l-octanesulfonamiso)-ethanol N-McPFOSAE 11/15/2022 <LOD (7.03) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorododecanesulfonic Acid PFDoS 11/15/2022 <LOD (2.19) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexadecanoic Acid PFHxDA 11/15/2022 <LOD (1.41) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctadecanoic Acid PFODA 11/15/2022 <LOD (1.41) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorobutanoic Acid PFBA 3/14/2023 <LOD (2.12) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoropentanoic Acid PFPeA 3/14/2023 9.80 Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexanoic Acid PFHxA 3/14/2023 8.62 Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroheptanoic Acid PFHpA 3/14/2023 <LOD (1.87) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanoic Acid PFOA 3/14/2023 2.96 J Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorononanoic Acid PFNA 3/14/2023 <LOD (0.1.20) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorodecanoic Acid PFDA 3/14/2023 <LOD (1.52) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroundecanoic Acid PFUnDA 3/14/2023 <LOD (1.20) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorododecanoic Acid PFDoDA 3/14/2023 <LOD (2.17) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorotridecanoic Acid PFTrDA 3/14/2023 <LOD (1.77) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorotetradecanoic Acid PFTeDA 3/14/2023 <LOD (2.03) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorobutanesulfonic Acid PFBS 3/14/2023 3.32 J Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoropentanesulfonate PFPeS 3/14/2023 <LOD (1.10) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexanesulfonic Acid PFHxS 3/14/2023 <LOD (4.12) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroheptanesulfonic Acid PFHpS 3/14/2023 <LOD (2.58) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanesulfonic Acid PFOS 3/14/2023 2.91 J Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorononanesulfonic Acid PFNS 3/14/2023 <LOD (1.66) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorodecanesulfonic Acid PFDS 3/14/2023 <LOD (2.80) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 4:2 Fluorotelomersulfonic Acid 4:2-FTS 3/14/2023 <LOD (0.692) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 6:2 Fluorotelomersulfonic Acid 6:2-FTS 3/14/2023 <LOD (2.52) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 8:2 Fluorotelomersulfonic Acid 8:2-FTS 3/14/2023 <LOD (1.20) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanesulfonamide PFOSA 3/14/2023 <LOD (0.748) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-methyl perfluorooctanesulfonamidoacetic acid NMeFOSAA 3/14/2023 <LOD (1.50) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-ethyl perfluorooctanesulfonamidoacetic acid NEtFOSAA 3/14/2023 <LOD (2.17) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse HFPODA HFPODA 3/14/2023 <LOD (0.565) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 4,8-dioxa 31-1-perfluorononanoic acid DONA 3/14/2023 <LOD (1.44) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 9CI-PF3ONS 9CI-PF3ONS 3/14/2023 <LOD (3.42) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 11 CI-PF3OUdS 11 CI-PF3OUdS 3/14/2023 <LOD (2.52) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 10:2 Fluorotelomersulfonic Acid 10:2-FTS 3/14/2023 <LOD (4.08) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-ethylperfluoro-l-octanesulfonamide N-EtPFOSA 3/14/2023 <LOD (3.30) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 2-(N ethyl perfluoro--octanesulfonamido)-ethanol N-EtPFOSAE 3/14/2023 <LOD (8.17) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-methylperfluoro-l-octanesulfonamide N-McPFOSA 3/14/2023 <LOD (2.20) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 2-(N-methylperfluoro-l-octanesulfonamiso)-ethanol N-McPFOSAE 3/14/2023 <LOD (5.07) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorododecanesulfonic Acid PFDoS 3/14/2023 <LOD (2.68) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexadecanoic Acid PFHxDA 3/14/2023 <LOD (2.83) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctadecanoic Acid PFODA 3/14/2023 <LOD (6.70) U Isotope Dilution Influent Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorobutanoic Acid PFBA 3/14/2023 <LOD (2.12) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoropentanoic Acid PFPeA 3/14/2023 8.31 Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexanoic Acid PFHxA 3/14/2023 8.52 Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroheptanoic Acid PFHpA 3/14/2023 <LOD (1.87) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanoic Acid PFOA 3/14/2023 3.57 J Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorononanoic Acid PFNA 3/14/2023 <LOD (0.1.20) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorodecanoic Acid PFDA 3/14/2023 <LOD (1.52) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroundecanoic Acid PFUnDA 3/14/2023 <LOD (1.20) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorododecanoic Acid PFDoDA 3/14/2023 <LOD (2.17) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorotridecanoic Acid PFTrDA 3/14/2023 <LOD (1.77) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorotetradecanoic Acid PFTeDA 3/14/2023 <LOD (2.03) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorobutanesulfonic Acid PFBS 3/14/2023 <LOD (2.83) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoropentanesulfonate PFPeS 3/14/2023 <LOD (1.10) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexanesulfonic Acid PFHxS 3/14/2023 <LOD (4.12) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroheptanesulfonic Acid PFHpS 3/14/2023 <LOD (2.58) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanesulfonic Acid JPFOS 1 3/14/2023 1 <LOD (2.82) 1 U I Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorononanesulfonic Acid JPFNS 1 3/14/2023 1 <LOD (1.66) 1 U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorodecanesulfonic Acid PFDS 3/14/2023 <LOD (2.80) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 4:2 Fluorotelomersulfonic Acid 4:2-FTS 3/14/2023 <LOD (0.692) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 6:2 Fluorotelomersulfonic Acid 6:2-FTS 3/14/2023 <LOD (2.52) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 8:2 Fluorotelomersulfonic Acid 8:2-FTS 3/14/2023 <LOD (1.20) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanesulfonamide PFOSA 3/14/2023 <LOD (0.748) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-methyl perfluorooctanesulfonamidoacetic acid NMeFOSAA 3/14/2023 <LOD (1.50) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-ethyl perfluorooctanesulfonamidoacetic acid NEtFOSAA 3/14/2023 <LOD (2.17) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse HFPODA HFPODA 3/14/2023 <LOD (0.565) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 4,8-dioxa 31-1-perfluorononanoic acid DONA 3/14/2023 <LOD (1.44) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 9CI-PF3ONS 9CI-PF3ONS 3/14/2023 <LOD (3.42) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 11 CI-PF3OUdS 11 CI-PF3OUdS 3/14/2023 <LOD (2.52) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 10:2 Fluorotelomersulfonic Acid 10:2-FTS 3/14/2023 <LOD (4.08) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-ethylperfluoro-l-octanesulfonamide N-EtPFOSA 3/14/2023 <LOD (3.30) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 2-(N ethyl perfluoro--octanesulfonamido)-ethanol N-EtPFOSAE 3/14/2023 <LOD (8.17) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-methylperfluoro-l-octanesulfonamide N-McPFOSA 3/14/2023 <LOD (2.20) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 2-(N-methylperfluoro-l-octanesulfonamiso)-ethanol N-McPFOSAE 3/14/2023 <LOD (5.07) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorododecanesulfonic Acid PFDoS 3/14/2023 <LOD (2.68) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexadecanoic Acid PFHxDA 3/14/2023 <LOD (2.83) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctadecanoic Acid PFODA 3/14/2023 <LOD (6.70) U Isotope Dilution Headworks (Inf + Rec) Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorobutanoic Acid PFBA 3/14/2023 <LOD (2.12) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoropentanoic Acid PFPeA 3/14/2023 11.7 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexanoic Acid PFHxA 3/14/2023 15.5 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroheptanoic Acid PFHpA 3/14/2023 <LOD (1.87) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanoic Acid PFOA 3/14/2023 6.50 Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorononanoic Acid PFNA 3/14/2023 <LOD (1.20) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorodecanoic Acid PFDA 3/14/2023 <LOD (1.52) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroundecanoic Acid PFUnDA 3/14/2023 <LOD (1.20) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorododecanoic Acid PFDoDA 3/14/2023 <LOD (2.17) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorotridecanoic Acid PFTrDA 3/14/2023 <LOD (1.77) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorotetradecanoic Acid PFTeDA 3/14/2023 <LOD (2.03) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorobutanesulfonic Acid PFBS 3/14/2023 <LOD (2.83) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoropentanesulfonate PFPeS 3/14/2023 <LOD (1.10) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexanesulfonic Acid PFHxS 3/14/2023 <LOD (4.12) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluoroheptanesulfonic Acid PFHpS 3/14/2023 <LOD (2.58) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanesulfonic Acid PFOS 3/14/2023 2.85 J Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorononanesulfonic Acid PFNS 3/14/2023 <LOD (1.66) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorodecanesulfonic Acid PFDS 3/14/2023 <LOD (2.80) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 4:2 Fluorotelomersulfonic Acid 4:2-FTS 3/14/2023 <LOD (0.692) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 6:2 Fluorotelomersulfonic Acid 6:2-FTS 3/14/2023 <LOD (2.52) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 8:2 Fluorotelomersulfonic Acid 8:2-FTS 3/14/2023 <LOD (1.20) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctanesulfonamide PFOSA 3/14/2023 <LOD (0.748) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-methyl perfluorooctanesulfonamidoacetic acid NMeFOSAA 3/14/2023 <LOD (1.50) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-ethyl perfluorooctanesulfonamidoacetic acid NEtFOSAA 3/14/2023 <LOD (2.17) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse HFPODA HFPODA 3/14/2023 <LOD (0.565) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 4,8-dioxa 31-1-perfluorononanoic acid DONA 3/14/2023 <LOD (1.44) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 9CI-PF3ONS 9CI-PF3ONS 3/14/2023 <LOD (3.42) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 11 CI-PF3OUdS 11 CI-PF3OUdS 3/14/2023 <LOD (2.52) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 10:2 Fluorotelomersulfonic Acid 10:2-FTS 3/14/2023 <LOD (4.08) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-ethylperfluoro-l-octanesulfonamide N-EtPFOSA 3/14/2023 <LOD (3.30) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 2-(N ethyl perfluoro--octanesulfonamido)-ethanol N-EtPFOSAE 3/14/2023 <LOD (8.17) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse N-methylperfluoro-l-octanesulfonamide N-McPFOSA 3/14/2023 <LOD (2.20) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse 2-(N-methylperfluoro-l-octanesulfonamiso)-ethanol N-McPFOSAE 3/14/2023 <LOD (5.07) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorododecanesulfonic Acid PFDoS 3/14/2023 <LOD (2.68) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorohexadecanoic Acid PFHxDA 3/14/2023 <LOD (2.83) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse Perfluorooctadecanoic Acid PFODA 3/14/2023 <LOD (6.70) U Isotope Dilution Post Filter Composite Permittee Raleigh NPDES NC0004879 North Cary WRF Neuse