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HomeMy WebLinkAboutWQ0004972_Monitoring - 07-2023_20230830Monitoring Report Submittal Permit Number#* Name of Facility:* Month:* July Report Information WQ0004972 Forest Lake RV WWTP Type * NDMR, NDAR-1, NDAR-2, NDMLR Confirmation Email Address: * Name of Submitter: * Signature: Date of submittal: Initial Review Year:* 2023 Upload Document* 2023_July_Monthly_Report_WQ0004972 1 AMB complete.pdf PDF Only Please upload one PDF containing all applicable monitoring reports (i.e., NDMR, NDAR-1, NDAR-2, NDMLR, GW-59). agrenier@greenerehssolutions.com Amanda Grenier ol�"a 8/30/2023 This will be filled in automatically Reviewer: Wanda.Gerald Is the project number correct?* WQ0004972 Is the monitoring report accepted?* Yes No Regional Office* Winston-Salem Reviewer: _anonymous Review Date: 9/8/2023 DocuSign Envelope ID: 90A1EB8F-DB1E-4E10-BA1E-CE057359BA3E niON-DISCHARGE APPLICATION REPORT (NDAR-1) Page of r vr�rvi. iv�r�n-i v.�-iu Permit No.: Q1114972 Facility Name: Forest Lake Davie1 irrigation • occur at this facility'? Cover Crop: Grass/Trees ■ NOHourly Rate (in): Hourly Rate (in): Hourly Rate (in): I •: Annual Rate (in): Annual Rate (in): Field Irrigated? Field Irrigated? in in m ��� ®_ 11 1 • 1 1 ---- ---- ---- Monthly ... 12 Month Floating Total (irm ���®���j���j��. j DocuSign Envelope ID: 90A1 EB8F-DB1 E-4E1 0-BA1 E-CE057359BA3E Did the application rates exceed the limits in Attachment B of your permit? O Compliant ❑ Non -Compliant Were adequate measures taken to prevent effluent ponding in or runoff from the sites? O Compliant ❑ Non -Compliant Was a suitable vegetative cover maintained on all sites as specified in your permit? O Compliant ❑ Non -Compliant Were all setbacks listed in your permit maintained for every application to each permitted site? O Compliant ❑ Non -Compliant Were all freeboards maintained in accordance with the specified freeboard heights in your permit? O Compliant ❑ Non -Compliant If the facility is non -compliant, please explain in the space below the reason(s) the facility was not in compliance. Provide in your explanation the date(s) of the non-compliance and describe the corrective action(s) taken. Attach additional sheets if necessary. Operator in Responsible Charge (ORC) Certification Permittee Certification ORC: Amanda Grenier Permittee: MHC TT, LP Certification No.: 1000089 Signing Official: George Gudgeon Grade: SI Phone Number: 919-356-6509 Signing Officials Title: Sr. Vice President Has the ORC changed since the previous NDAR-1? ❑ yes 0 No Phone Number: 312-279-1400 Permit Exp.: 10/31/27 usigned by: "4"t� 448/28/2023 8/30/2023 rizop 80BB4A06FK44C0..- Signature Date Signature Date By this signature, I certify that this report is accurrate and complete to the best of my knowledge. I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that all qualified personnel properly gathered and evaluated the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations. Mail Original and Two Copies to: Division of Water Resources Information Processing Unit 1617 Mail Service Center Raleigh, North Carolina 27699-1617 DocuSign Envelope ID: 90A1EB8F-DB1E-4E10-BA1E-CE057359BA3E Permit No.: WQ0004972 Facility Name: Forest Lake Preserve ELS County: Davie Month: July Year: 2023 PPI: 001 Flow Measuring Point: ElInfluent 0 Effluent ❑ No flow generated parameter Monitoring Point: ❑ Influent ❑ Effluent ❑ Groundwater Lowering ❑ Surface Water Parameter Code 0 50050 00400 50060 70300 00530 00310 31616 00600 00610 00625 00630 00620 00615 00665 00940 U£ O H C 0 N H N o 3E O LL x Q CD S°+ -tea O N t ~ tY U 'O :° ' H N .O C N �a i H G .O N p m m o LL U �o ai .`, Z lE .o l= Q L A d iii Y O Z ad+ la 'w .`, Z Z iy ._. Z CD !" = Z Vl 7 � s 0 (n ~ s a O U 24-hr hrs GPD su mg/L mg/L mg/L mg/L #/100 mL mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L 1 23,105 2 25,228 3 08:00 5 28,281 6.4 0.1 4 39,522 5 08:00 5 20,765 6.61 0.1 6 08:00 5 34,438 6.7 0.3 7 08:00 5 29,020 7.17 0.4 8 48,644 9 55,505 10 08:00 5 80,147 6.43 0.2 11 08:00 5 36,928 6.5 1.2 12 08:00 5 41,117 6.8 0.3 251 15 5 2 14.7 6.3 9.2 5.4 5.4 <0.2 5.6 57 13 08:00 5 55,786 6.67 0.4 14 08:00 5 50,199 6.28 0.2 15 61,994 16 69,276 17 08:00 5 54,869 6.35 0.2 18 08:15 5 44,982 6.23 0.5 19 08:00 5 65,323 6.24 2 20 09:00 2 61,242 6.04 2.6 21 09:00 1 59,845 6.43 3.7 22 65,787 23 74,707 24 08:00 5 80,493 6.42 0.2 25 08:00 5 60,166 6.52 0.6 26 08:00 5 58,686 6.88 1 27 08:00 5 61,035 6.6 1.2 28 08:00 5 64,126 6.44 1.3 29 63,141 30 77,222 311 08:00 1 5 72,816 6.31 0.2 Average: 53,690 0.84 251.00 15.00 5.00 2.00 14.70 6.30 9.20 5.40 5.40 0.00 5.60 57.00 Daily Maximum: 80,493 7.17 3.70 251.00 15.00 5.00 2.00 14.70 6.30 9.20 5.40 5.40 0.20 5.60 57.00 Daily Minimum: 20,765 6.04 0.10 251.00 15.00 5.00 2.00 14.70 6.30 9.20 5.40 5.40 0.20 5.60 57.00 Sampling Type: Monthly Avg. Limit: Daily Limit: LSample Frequency: Continuous 5x/Week 5X/Week Monthly Monthly Monthly Monthly Monthly Monthly Monthly Monthly Monthly Monthly Monthly 3X/year DocuSign Envelope ID: 90A1 EB8F-DB1 E-4E1 0-BA1 E-CE057359BA3E Sampling Person(s) Certified Laboratories Name: Amanda Grenier Name: Sam Perry Name: Greener EHS Solutions, LLC Name: Pace Analytical Does all monitoring data and sampling frequencies meet the requirements in Attachment A of your permit? 0 Compliant O Non -Compliant If the facility is non -compliant, please explain in the space below the reason(s) the facility was not in compliance. Provide in your explanation the date(s) of the non-compliance and describe the corrective action(s) taken. Attach additional sheets if necessary. The Monthly average flow exceeded the permitted flow of 24,400 gpd. The permitted application rate was not exceeded. The flow meter was calibrated on June 27, 2023 and the meter was reading significantly low before the calibration. This was noted on the June 2023 NDMR. The plant is in the process of an upgrade to increase the capacity as well as investigating extraneous flow for 1/1 and leaking fixtures. Lab Qualifiers, July 12, 2023 - BOD, B2 - Oxygen usage is less than 2.0 for all dilutions set. The reported value is an estimated less than value and is calculated for the dilution using the most amount of sample. Phosphorus and Chloride, M1 - Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. Operator in Responsible Charge (ORC) Certification Permittee Certification ORC: Amanda Grenier Permittee: MHC TT, LP Certification No.: 1000089 Signing Official: George Gudgeon Grade: SI Phone Number: 919-356-6509 Signing Officials Title: Sr. Vice President Has the ORC changed since the previous NDMR? i7 Yes El No Phone Number: 312-279-1400 Permit Expiration: 10/31/2027 DocuSigned by: �J 8/28/2023 ��,� �� Avu 8/30/2023 Ir dAp Signature Date Signature Date By this signature, I certify that this report is accurrate and complete to the best of my knowledge. I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that all qualified personnel properly gathered and evaluated the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations. Mail Original and Two Copies to: Division of Water Resources Information Processing Unit 1617 Mail Service Center Raleigh, North Carolina 27699-1617 DocuSign Envelope ID: 90A1 EB8F-DB1 E-4E1 0-BA1 E-CE057359BA3E ,ace - July 26, 2023 Amanda D. Grenier Greener EHS Solutions 21 Selby Ct. Holly Springs, NC 27540 RE: Project: FOREST LAKE - JULY Pace Project No.: 92676934 Dear Amanda Grenier: Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Enclosed are the analytical results for sample(s) received by the laboratory on July 12, 2023. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services - Asheville • Pace Analytical Services - Charlotte If you have any questions concerning this report, please feel free to contact me. Sincerely, Matthew Brainard matthew.brainard@pacelabs.com (704)875-9092 Project Manager Enclosures REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 18 DocuSign Envelope ID: 90A1 EB8F-DB1 E-4E1 0-BA1 E-CE057359BA3E ,ace - Project: FOREST LAKE - JULY Pace Project No.: 92676934 Pace Analytical Services Charlotte South Carolina Laboratory ID: 99006 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 South Carolina Laboratory ID: 99006 Pace Analytical Services Asheville 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 North Carolina Drinking Water Certification #: 37712 North Carolina Wastewater Certification #: 40 CERTIFICATIONS South Carolina Certification #: 99006001 South Carolina Drinking Water Cert. #: 99006003 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Louisiana DoH Drinking Water #: LA029 VirginiaNELAP Certification #: 460221 South Carolina Laboratory ID: 99030 South Carolina Certification #: 99030001 VirginiaNELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 18 DocuSign Envelope ID: 90A1 EB8F-DB1 E-4E10-BA1 E-CE057359BA3E Pace Analytical Services, LLC �ace- 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: FOREST LAKE - JULY Pace Project No.: 92676934 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92676934001 EFFLUENT GRAB SM 9222D-2015 KDF 1 PASI-C SM 2540C-2015 RVS 1 PASI-A SM 2540D-2015 RVS 1 PASI-A SM 521OB-2016 KO 1 PASI-A TKN+NO3+NO2 Calculation KDF1 1 PASI-A EPA 350.1 Rev 2.0 1993 EGC 1 PASI-A EPA 351.2 Rev 2.0 1993 MFO 1 PASI-A EPA 353.2 Rev 2.0 1993 MFO 1 PASI-A EPA 365.1 Rev 2.0 1993 MDW 1 PASI-A SM 4500-CI-E-2011 MDW 1 PASI-A PASI-A = Pace Analytical Services - Asheville PASI-C = Pace Analytical Services - Charlotte REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 18 DocuSign Envelope ID: 90A1 EB8F-DB1 E-4E1 0-BA1 E-CE057359BA3E ,ace ­ ANALYTICAL RESULTS Project: FOREST LAKE - JULY Pace Project No.: 92676934 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: EFFLUENT GRAB Lab ID: 92676934001 Collected: 07/12/23 09:45 Received: 07/12/23 14:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual MBIO 9222D Fecal Coliform CHT Analytical Method: SM 9222D-2015 Preparation Method: SM 9222D-2015 Pace Analytical Services - Charlotte Fecal Coliforms 2.0 CFU/100 mL 1.0 1 07/12/23 15:09 07/13/23 13:35 2540C Total Dissolved Solids Analytical Method: SM 2540C-2015 Pace Analytical Services -Asheville Total Dissolved Solids 251 mg/L 25.0 1 07/14/23 17:03 2540D Total Suspended Solids Analytical Method: SM 2540D-2015 Pace Analytical Services -Asheville Total Suspended Solids 15.0 mg/L 8.3 1 07/13/23 15:59 5210B BOD, 5 day Analytical Method: SM 521OB-2016 Pace Analytical Services -Asheville BOD, 5 day 5.0 mg/L 2.0 1 07/13/23 17:49 07/18/23 13:43 Total Nitrogen Calculation Analytical Method: TKN+NO3+NO2 Calculation Pace Analytical Services -Asheville Total Nitrogen 14.7 mg/L 0.040 1 07/25/23 10:58 350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Ammonia 6.3 mg/L 0.10 1 07/25/23 17:32 7664-41-7 351.2 Total Kjeldahl Nitrogen Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Kjeldahl, Total 9.2 mg/L 0.50 1 07/21/23 17:13 07/22/23 05:07 7727-37-9 353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Nitrate 5.4 mg/L 0.20 5 07/14/23 01:11 14797-55-8 365.1 Phosphorus, Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993 Pace Analytical Services -Asheville Phosphorus 5.6 mg/L 0.25 5 07/24/23 18:34 07/24/23 22:08 7723-14-0 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Pace Analytical Services -Asheville Chloride 57.0 mg/L 2.0 2 07/25/2319:59 16887-00-6 Date: 07/26/2023 12:07 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. B2 Page 4 of 18 DocuSign Envelope ID: 90A1 EB8F-DB1 E-4E10-BA1 E-CE057359BA3E Pace Analytical Services, LLC �ace- 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: FOREST LAKE - JULY Pace Project No.: 92676934 QC Batch: 786340 Analysis Method: SM 9222D-2015 QC Batch Method: SM 9222D-2015 Analysis Description: 9222D Fecal Coliform(MF) - CHT Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92676934001 METHOD BLANK: 4076941 Matrix: Water Associated Lab Samples: 92676934001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Fecal Coliforms CFU/100 mL ND 1.0 07/13/23 13:35 SAMPLE DUPLICATE: 4076942 Parameter Fecal Coliforms 92676922006 Dup Units Result Result RPD Qualifiers CFU/100 mL 6.0 ND Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/26/2023 12:07 AM without the written consent of Pace Analytical Services, LLC. Page 5 of 18 DocuSign Envelope ID: 90A1 EB8F-DB1 E-4E10-BA1 E-CE057359BA3E Pace Analytical Services, LLC �ace­ 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: FOREST LAKE - JULY Pace Project No.: 92676934 QC Batch: 786946 Analysis Method: SM 2540C-2015 QC Batch Method: SM 2540C-2015 Analysis Description: 2540C Total Dissolved Solids Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92676934001 METHOD BLANK: 4080028 Associated Lab Samples: 92676934001 Parameter Units Total Dissolved Solids mg/L LABORATORY CONTROL SAMPLE: 4080029 Parameter Units Total Dissolved Solids mg/L SAMPLE DUPLICATE: 4080030 Parameter Units Total Dissolved Solids mg/L Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 25.0 07/14/2317:01 Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 250 248 99 90-110 92676871004 Dup Result Result RPD Qualifiers 553 561 1 SAMPLE DUPLICATE: 4080031 92677008001 Dup Parameter Units Result Result Total Dissolved Solids mg/L 542 544 RPD Qualifiers 0 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/26/2023 12:07 AM without the written consent of Pace Analytical Services, LLC. Page 6 of 18 DocuSign Envelope ID: 90A1 EB8F-DB1 E-4E10-BA1 E-CE057359BA3E Pace Analytical Services, LLC �ace­ 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: FOREST LAKE - JULY Pace Project No.: 92676934 QC Batch: 786534 Analysis Method: SM 2540D-2015 QC Batch Method: SM 2540D-2015 Analysis Description: 2540D Total Suspended Solids Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92676934001 METHOD BLANK: 4077965 Associated Lab Samples: 92676934001 Parameter Units Total Suspended Solids mg/L LABORATORY CONTROL SAMPLE: 4077966 Parameter Units Total Suspended Solids mg/L SAMPLE DUPLICATE: 4078559 Parameter Units Total Suspended Solids mg/L Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 2.5 07/13/2315:55 Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 250 242 97 90-110 92677032001 Dup Result Result RPD Qualifiers 40.5 43.0 6 SAMPLE DUPLICATE: 4078560 92676938001 Dup Parameter Units Result Result Total Suspended Solids mg/L 2260 2080 RPD Qualifiers 8 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/26/2023 12:07 AM without the written consent of Pace Analytical Services, LLC. Page 7 of 18 DocuSign Envelope ID: 90A1 EB8F-DB1 E-4E10-BA1 E-CE057359BA3E Pace Analytical Services, LLC �ace­ 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: FOREST LAKE - JULY Pace Project No.: 92676934 QC Batch: 786578 Analysis Method: SM 521 OB-2016 QC Batch Method: SM 521OB-2016 Analysis Description: 5210E BOD, 5 day Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92676934001 METHOD BLANK: 4078166 Associated Lab Samples: 92676934001 Parameter Units BOD, 5 day mg/L LABORATORY CONTROL SAMPLE: 4078168 Parameter Units BOD, 5 day mg/L Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 2.0 07/18/2312:50 Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 198 199 101 84.6-115 SAMPLE DUPLICATE: 4078169 92677055002 Dup Parameter Units Result Result BOD, 5 day mg/L 688 776 RPD Qualifiers 12 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/26/2023 12:07 AM without the written consent of Pace Analytical Services, LLC. Page 8 of 18 DocuSign Envelope ID: 90A1 EB8F-DB1 E-4E10-BA1 E-CE057359BA3E Pace Analytical Services, LLC �ace­ 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: FOREST LAKE - JULY Pace Project No.: 92676934 QC Batch: 788581 Analysis Method: EPA 350.1 Rev 2.0 1993 QC Batch Method: EPA 350.1 Rev 2.0 1993 Analysis Description: 350.1 Ammonia Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92676934001 METHOD BLANK: 4087722 Associated Lab Samples: 92676934001 Parameter Units Nitrogen, Ammonia mg/L LABORATORY CONTROL SAMPLE: 4087723 Parameter Units Nitrogen, Ammonia mg/L Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 0.10 07/25/23 15:57 Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 5 5.1 102 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4087724 4087725 MS MSD 92677689005 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Ammonia mg/L <0.10 5 5 5.2 5.1 103 103 90-110 0 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4087726 4087727 MS MSD 92677689006 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Ammonia mg/L <0.10 5 5 4.9 4.9 98 98 90-110 0 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/26/2023 12:07 AM without the written consent of Pace Analytical Services, LLC. Page 9 of 18 DocuSign Envelope ID: 90A1 EB8F-DB1 E-4E10-BA1 E-CE057359BA3E Pace Analytical Services, LLC �ace­ 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: FOREST LAKE - JULY Pace Project No.: 92676934 QC Batch: 788347 Analysis Method: EPA 351.2 Rev 2.0 1993 QC Batch Method: EPA 351.2 Rev 2.0 1993 Analysis Description: 351.2 TKN Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92676934001 METHOD BLANK: 4086786 Associated Lab Samples: 92676934001 Parameter Units Nitrogen, Kjeldahl, Total mg/L LABORATORY CONTROL SAMPLE: 4086787 Parameter Units Nitrogen, Kjeldahl, Total mg/L Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 0.50 07/22/23 05:06 Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 10 10 100 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4086788 4086789 MS MSD 92677138004 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Kjeldahl, Total mg/L 0.60 10 10 11.1 11.1 105 105 90-110 0 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4086790 4086791 MS MSD 92677138005 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Kjeldahl, Total mg/L 0.59 10 10 11.2 11.2 106 106 90-110 0 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/26/2023 12:07 AM without the written consent of Pace Analytical Services, LLC. Page 10 of 18 DocuSign Envelope ID: 90A1 EB8F-DB1 E-4E10-BA1 E-CE057359BA3E Pace Analytical Services, LLC �ace­ 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: FOREST LAKE - JULY Pace Project No.: 92676934 QC Batch: 786706 Analysis Method: EPA 353.2 Rev 2.0 1993 QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite, Unpres. Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92676934001 METHOD BLANK: 4078943 Associated Lab Samples: 92676934001 Parameter Units Nitrogen, Nitrate mg/L LABORATORY CONTROL SAMPLE: 4078944 Parameter Units Nitrogen, Nitrate mg/L Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 0.040 07/14/23 00:42 Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 1.5 1.5 99 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4078945 4078946 MS MSD 92677079001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Nitrate mg/L 0.064 1.5 1.5 1.5 1.5 94 98 90-110 3 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4078947 4078948 MS MSD 92677108002 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Nitrate mg/L 0.027J 1.5 1.5 1.2 1.2 78 80 90-110 2 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/26/2023 12:07 AM without the written consent of Pace Analytical Services, LLC. Page 11 of 18 DocuSign Envelope ID: 90A1 EB8F-DB1 E-4E10-BA1 E-CE057359BA3E Pace Analytical Services, LLC �ace­ 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: FOREST LAKE - JULY Pace Project No.: 92676934 QC Batch: 788796 Analysis Method: EPA 365.1 Rev 2.0 1993 QC Batch Method: EPA 365.1 Rev 2.0 1993 Analysis Description: 365.1 Phosphorus, Total Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92676934001 METHOD BLANK: 4088548 Associated Lab Samples: 92676934001 Parameter Units Phosphorus mg/L LABORATORY CONTROL SAMPLE: 4088549 Parameter Units Phosphorus mg/L Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 0.050 07/24/23 22:00 Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 2.5 2.5 101 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4088550 4088551 MS MSD 92676938001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Phosphorus mg/L 19.9 2.5 2.5 22.7 21.9 114 80 90-110 4 M1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4088552 4088553 MS MSD 92676938002 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Phosphorus mg/L 4.1 2.5 2.5 6.7 6.5 104 97 90-110 3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/26/2023 12:07 AM without the written consent of Pace Analytical Services, LLC. Page 12 of 18 DocuSign Envelope ID: 90A1 EB8F-DB1 E-4E10-BA1 E-CE057359BA3E Pace Analytical Services, LLC �ace­ 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: FOREST LAKE - JULY Pace Project No.: 92676934 QC Batch: 788857 Analysis Method: SM 4500-CI-E-2011 QC Batch Method: SM 4500-CI-E-2011 Analysis Description: 4500 Chloride Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92676934001 METHOD BLANK: 4089097 Associated Lab Samples: 92676934001 Parameter Units Chloride mg/L LABORATORY CONTROL SAMPLE: 4089098 Parameter Units Chloride mg/L Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 1.0 07/25/23 19:41 Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 20 19.4 97 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4089099 4089100 MS MSD 92676930001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Chloride mg/L 47.4 10 10 55.7 55.7 82 83 90-110 0 M1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4089101 4089102 MS MSD 92676930002 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Chloride mg/L 2.6 10 10 11.9 12.2 93 97 90-110 3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/26/2023 12:07 AM without the written consent of Pace Analytical Services, LLC. Page 13 of 18 DocuSign Envelope ID: 90A1 EB8F-DB1 E-4E10-BA1 E-CE057359BA3E Pace Analytical Services, LLC �ace­ 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: FOREST LAKE - JULY Pace Project No.: 92676934 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as "Total" may vary slightly from the sum of the reported component parameters. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TN -The NELAC Institute. ANALYTE QUALIFIERS B2 Oxygen usage is less than 2.0 for all dilutions set. The reported value is an estimated less than value and is calculated for the dilution using the most amount of sample. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/26/2023 12:07 AM without the written consent of Pace Analytical Services, LLC. Page 14 of 18 DocuSign Envelope ID: 90A1 EB8F-DB1 E-4E1 0-BA1 E-CE057359BA3E ,ace - QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Pace Project No.: FOREST LAKE - JULY 92676934 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92676934001 EFFLUENT GRAB SM 9222D-2015 786340 SM 9222D-2015 786341 92676934001 EFFLUENT GRAB SM 254OC-2015 786946 92676934001 EFFLUENT GRAB SM 2540D-2015 786534 92676934001 EFFLUENT GRAB SM 521 OB-2016 786578 SM 521 OB-2016 786683 92676934001 EFFLUENT GRAB TKN+NO3+NO2 789026 Calculation 92676934001 EFFLUENT GRAB EPA 350.1 Rev 2.0 1993 788581 92676934001 EFFLUENT GRAB EPA 351.2 Rev 2.0 1993 788347 EPA 351.2 Rev 2.0 1993 788555 92676934001 EFFLUENT GRAB EPA 353.2 Rev 2.0 1993 786706 92676934001 EFFLUENT GRAB EPA 365.1 Rev 2.0 1993 788796 EPA 365.1 Rev 2.0 1993 788880 92676934001 EFFLUENT GRAB SM 4500-CI-E-2011 788857 Date: 07/26/2023 12:07 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 15 of 18 / fJnnn I yL�— 1— a�•vr-r rNnr-rrvr� r-VvvJ vVL_Ja1fIt./1C VVIIUIUVII VLrVII RCGCIPL DocuSign Envelope ID: 90A1 EB8F-DB1 E-4E1 0-BA1 E-CE057359BA3E Effective Date: 11/14/2022 Laboratory receiving samples: Asheville ❑ Eden❑ Greenwood ❑ Huntersville E� Raleigh❑ Mechanicsville❑ Atlanta[:] Kernersville❑ ConditionSample Client Name: WO# : 92676934 Upon Project � r I I � ( q Courier: ❑ ❑F d ExCUPS ❑Client Commercial ]Pace ❑OtPer: IIIII' I IIII I I II I III III 92676934 Custody Seal Present? ❑Yes E No Seals Intact? []Yes [�No Packing Material: ❑Bubble Wrap ❑Bubble Bags t2(m-Ine ❑ Other Thermometer: ❑ IR Gun 10: , [—� )o Type of Ice: wet ❑Blue ?_ Correction Factor: \ Cooler Temp: Add/Subtract ('C) lJ L Cooler Temp Corrected (°C • L - USDA Regulated Soil ( N/A, water sample) Did samples originate in a quarantine zone within the United States: CA, NY, or SC Date/Initials Person Examining Contents: Biological Tissue cozen? ❑Yes ❑No U /A ❑None Temp should be above freezing to ST ❑Samples out of temp criteria. Samples on ice, cooling process has begun Did samples oriainatr' from a Fnraion <nurrn (intornalinnallo jcheck maps)? LJYes LJNo including Hawaii and Puerto Rico)? [:]Yes [:]No Comments/Discrepancy: Chain of Custody Present? s ❑No ❑N/A 1. Samples Arrived within Hold Time? gYes []No ❑N/A 2. Short Hold Time Analysis (02 hr.)? es ❑No []N/A 3. Rush Turn Around Time Requested? ❑Yes No ❑N/A 4. Sufficient Volume? [J'Yes ❑No []N/A S. Correct Containers Used? -Pace Containers Used? Q J� ❑No []No ❑NIA ❑N/A 6. Containers Intact? [2 es ❑No El NIA 7. Dissolved analysis: Samples Field Filtered? ❑Yes [-]No N/A R. Sample Labels Match COC? -Includes Oate/Time/ID/Analysis Matrix: 21yes "/T ❑No ❑N/A 9. Headspace in VOA Vials (>S-Gmm)? [-]Yes C]PJo J]N/A 10. Trip Blank Present? Trip Blank Custody Seals Present? ❑Yes ❑Ye5 7N. ❑N/A ❑N/A 11. COMMENTS/SAMPLE DISCREPANCY CLIENT NOTIFICATION/RESOLUTION Person contacted: Project Manager SCURF Review: Project Manager SRF Review: Lot ID of split containers: Date/Time: Date: Date: Field Data Required? ❑Yes ❑NO Qualtrax ID: 69614 Page 1 of 2 Page 16 of 18 vwrNrc vvrrwuain vNvn nca.crN� Ana I— — DocuSign Envelope ID: 9OA1EB8F-DB1E-4E10-BA1E-CE057359BA3E Effective Date: 11/14/2022 *Check mark top half of box if pH and/or dechlorination is verified and Project 0 within the acceptance range for preservation samples. Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC. Wig "Bottom half of box is to list number of bottles ***Check all unpreserved Nitrates for chlorine WO## : 92676934 PM: MWB Due Date: 07/26/23 CLIENT: 92-Greener z N z d z d .-. V v M Z °� ry A a z v z N V rry V ¢ Z ¢ z _ I I rir 01 z d f0 27 ar v n c v a a c Z v a a c N 2 vd, Q. S n n O N v S n M O z _ y «v a " Q z y = a S O u :"n m v a c D N v = c v 2 2. y n c O y n v O S = a o O N z Q v a Z ¢ Z U z ^� ON N V v Z r �, a C ` 2 -r O d m d ar �' o c Y o l7 n > Q V u n a Q Z u ,� m a. R O ry ry = z � m d a c D Z A c O/ 2 d a o _ `� a - E v, .Ni a J E a fV �• a J E o N u m (1 ;, '-1 N ° G E Ln ry ... a J E o N Ln N E N ti .. a E N N i C� C 0/ a W E Q a`, _ ,-� d E Q v _ rl G J E o It d Q v N E J of N a Q J E R O > E C Q O J E q ¢ O J E p ¢ Q E Q t4 C - E O m a N m VI J E N `m V7 J E _a a E In C Q of O c lA J E D Q J E O iC E ry if > a. a m M m a m > e. a m > 0. a m H O a m Z a CL d IV v a m -t A. A. m t'i 3 .ti t7 a i l9 to a M to C7 a " t7 0 a M rn O a R Q1 l� o i Ol O o F 01 > ] 0 U > > Or o o D r, a x .m.. ]C � > ,-i lit a Ln N F- N a tA N cc M a co O W a LA > 01 to o 1 — — \ — 2 3 \\ \ 4 I — 5 \ \ \ 6 i IEN — 7 8 N I I 9 I I 10 11-\ i 12 I — pH Adjustment Log for Preserved Samples Sample ID Type of Preservative pH upon receipt Date preservation adjusted Time preservation adjusted Amount of Preservative added Lot ff r+ure. vvnenever there Is a discrepancy arrecung North Carolina compliance samples, a copy of this form will be sent to the North Carolina DENR Certification Office (i.e. Out of hold, incorrect preservative, out of temp, incorrect containers. Dualtrax ID: 69614 Page 2 of 2 Page 17 of 18 Dow! I 'ign Envelope I ID: I 90AlEB8F-DB1E-4E10-BA1E-CE057359BA3E I I I I ITEM # 1 o 3 d a r, o- a �n m a D � f) O � N � O 7 N d O 3 o i 0D �� 3 D EL m 0 3 o n n D = omr o r m N O 0 o �� - o oN m X a x o = 1 m 3 r O D 1 0 $ z 0 O o d O C 3 0 \ �Y V m Ii Z Z N O m � 3 O mO MATRIX CODE (see valid codes to left) fD D 3 SAMPLE TYPE (G=GRAB C=COf.1P) \ m o - m D C 1 T m COO iD nri O D ~ om v A v r m S r m O C Z Z Q /7 ,� 1 77 m D ; m m m 0 o D o m z o > D -a v L7 m m SAMPLE MAP AT COLLECTION p A 1 C n J 1 mS D Q I ` 4 OF CONTAINERS G Q 3 111 Unpreserved \ S m J 1 0 0. o N'❑ V1n H2SO4 m n o �`J J HNO3 a Z: m m 3 HCI i. Z m a t NaOH lv 1° �- D ° �- n r' 0 m Na2S203 N 3 mMethanol m o � _ < other v n > a a Analyses Test Y!N BOD 5-day 1 m z A ��-, 1` Fecal Coli(orm MF, M-FC N c c Q o Ammonia/ T. Phos a, = a Total Nitrogen & TKN x �\ Nitrate 1 a o ' TSS u N TDS n T N m -_ Chloride s z /^ C m 'D m r TEMP in C A m Residual Chlorine (Y/N) n Z C c G o Received on Ice (YIN) m 0 m D usto y Sealed Z 0 Cooler : © O Y/N z In Samples Intact - (YIN) t- Page 18 of 18