NC0003417_J15060613report_20150805

DUE Analytical Laboratory
ENERGY
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone:[phone] Fax:[phone]
Order Summary Report
Order Number: J15060613
Project Name: HF LEE PLANT - AB GW ASSESSMENT WATER
Customer Name(s): Tim Hunsucker, Judd Mahan, Kathy Webb, John Toepfer
Customer Address: 1677 Old Smithfield Rd
Goldsboro NC 27530,
Lab Contact: Mary Ann Ogle Phone: [phone]
n
l ( Mary Ann Ogle
Report Authorized By: Uf 2015.06.30 09:54:06 pate. 6/30/2015
(Signature) /-04'00'
Mary Ann Ogle
Program Comments:
Please contact the Program Manager (Mary Ann Ogle) with any questions regarding this report.
Data Flags & Calculations:
Analytical Lab
Page 1 of 62
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Sample ID's & Descriptions:
Collection
Sample ID Plant/Station Date and Time
Collected By
Sample Description
2015019923
HF LEE PLANT
16-Jun-15 9:53 AM
ILLEGIBLE
SMW-2
2015019924
HF LEE PLANT
16-Jun-15 12:44 PM
ILLEGIBLE
PZ-3
2015019925
HF LEE PLANT
16-Jun-15 9:19 AM
ILLEGIBLE
PZ-4
2015019926
HF LEE PLANT
16-Jun-15 10:25 AM
ILLEGIBLE
PZ-5
2015019927
HF LEE PLANT
16-Jun-15 11:10 AM
ILLEGIBLE
SMW-4
2015019928
HF LEE PLANT
16-Jun-15 8:30 AM
ILLEGIBLE
IMW-3S
2015019929
HF LEE PLANT
16-Jun-15 9:25 AM
ILLEGIBLE
IMW-3BC
2015019945
HF LEE PLANT
16-Jun-15 7:45 AM
ILLEGIBLE
Filter Blank
2015019946
HF LEE PLANT
16-Jun-15 7:45 AM
ILLEGIBLE
Equipment Blank
9 Total Samples
Analytical Lab
Page 2 of 62

Analytical Lab
Page 3 of 62
Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals 0 Yes ❑ No
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits. ❑ Yes 0 No
All laboratory QA/QC requirements are acceptable. 0 Yes ❑ No
Report Sections Included:
E%-'] Job Summary Report
❑� Sample Identification
Technical Validation of Data Package
❑� Analytical Laboratory Certificate of Analysis
❑ Analytical Laboratory QC Report
❑d Sub -contracted Laboratory Results
❑ Customer Specific Data Sheets, Reports, & Documentation
❑ Customer Database Entries
❑� Chain of Custody
❑� Electronic Data Deliverable (EDD) Sent Separately
Reviewed By: Mary Ann Ogle Date: 6/30/2015

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060613
Site: SMW-2
Collection Date: 16-Jun-15 9:53 AM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter
Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)
8.5
mg-N/L
0.05
INORGANIC IONS BY IC
Chloride
16
mg/L
1
Sulfate
4.3
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
0.282
mg/L
0.005
Barium (Ba)
0.339
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
0.062
mg/L
0.005
Strontium (Sr)
0.094
mg/L
0.005
Zinc (Zn)
0.018
mg/L
0.005
UNDIGESTED METALS BY lCP
Calcium (Ca)
10.8
mg/L
0.01
Magnesium (Mg)
5.04
mg/L
0.005
Potassium (K)
3.33
mg/L
0.1
Sodium (Na)
3.95
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.423
mg/L
0.005
Barium (Ba)
0.338
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.100
mg/L
0.01
Manganese (Mn)
0.061
mg/L
0.005
Strontium (Sr)
0.093
mg/L
0.005
Zinc (Zn)
0.016
mg/L
0.005
Sample #: 2015019923
Matrix: GW WW
Analytical Lab
Page 4 of 62
DF Method Analysis Date/Time Analyst
Vendor Method
V_SHEALY
5
EPA 353.2
06/24/2015 15:35
LSTARLI
10
EPA 300.0
06/19/2015 14:29
BGN9034
1
EPA 300.0
06/19/2015 14:29
BGN9034
1
EPA 245.1
06/19/2015 11:48
ACPAYNE
1
EPA 245.1
06/19/2015 13:00
ACPAYNE
1
EPA 200.7
06/18/2015 12:45
MHALL3
1
EPA 200.7
06/18/2015 12:45
MHALL3
1
EPA 200.7
06/18/2015 12:45
MHALL3
1
EPA 200.7
06/18/2015 12:45
MHALL3
1
EPA 200.7
06/18/2015 12:45
MHALL3
1
EPA 200.7
06/18/2015 12:45
MHALL3
1
EPA 200.7
06/18/2015 12:45
MHALL3
1
EPA 200.7
06/19/2015 12:20
MHALL3
1
EPA 200.7
06/19/2015 12:20
MHALL3
1
EPA 200.7
06/19/2015 12:20
MHALL3
1
EPA 200.7
06/19/2015 12:20
MHALL3
1
EPA 200.7
06/19/2015 14:53
MHALL3
1
EPA 200.7
06/19/2015 14:53
MHALL3
1
EPA 200.7
06/19/2015 14:53
MHALL3
1
EPA 200.7
06/19/2015 14:53
MHALL3
1
EPA 200.7
06/19/2015 14:53
MHALL3
1
EPA 200.7
06/19/2015 14:53
MHALL3
1
EPA 200.7
06/19/2015 14:53
MHALL3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060613
Site: SMW-2
Collection Date: 16-Jun-15 9:53 AM
Analyte
Result
Units Qualifiers
RDL
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
1.70
ug/L
1
Copper (Cu)
1.92
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
1.85
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
1.62
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
2.02
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
0.307
ug/L
0.3
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
110
mg/L
25
Total Carbon
TOC
1.0
mg/L
0.1
TOTAL SUSPENDED SOLIDS
TSS
< 5
mg/L
5
Sample #: 2015019923
Matrix: GW WW
Analytical Lab
Page 5 of 62
DF
Method
Analysis Date/Time
Analyst
1
EPA 200.8
06/23/2015 03:31
SLS2560
1
EPA 200.8
06/23/2015 03:31
SLS2560
1
EPA 200.8
06/23/2015 03:31
SLS2560
1
EPA 200.8
06/23/2015 03:31
SLS2560
1
EPA 200.8
06/23/2015 03:31
SLS2560
1
EPA 200.8
06/23/2015 03:31
SLS2560
1
EPA 200.8
06/23/2015 03:31
SLS2560
1
EPA 200.8
06/23/2015 03:31
SLS2560
1
EPA 200.8
06/23/2015 03:31
SLS2560
1
EPA 200.8
06/23/2015 03:31
SLS2560
1
EPA 200.8
06/23/2015 03:31
SLS2560
1
EPA 200.8
06/23/2015 03:31
SLS2560
1
EPA 200.8
06/23/2015 03:31
SLS2560
1
EPA 200.8
06/22/2015 21:51
SLS2560
1
EPA 200.8
06/22/2015 21:51
SLS2560
1
EPA 200.8
06/22/2015 21:51
SLS2560
1
EPA 200.8
06/22/2015 21:51
SLS2560
1
EPA 200.8
06/22/2015 21:51
SLS2560
1
EPA 200.8
06/22/2015 21:51
SLS2560
1
EPA 200.8
06/22/2015 21:51
SLS2560
1
EPA 200.8
06/22/2015 21:51
SLS2560
1
EPA 200.8
06/22/2015 21:51
SLS2560
1
EPA 200.8
06/22/2015 21:51
SLS2560
1
EPA 200.8
06/22/2015 21:51
SLS2560
1
EPA 200.8
06/22/2015 21:51
SLS2560
1
EPA 200.8
06/22/2015 21:51
SLS2560
Vendor Method
V_SHEALY
Vendor Method V_ELE1
1 SM2540C 06/22/201514:30 AGIBBS5
1 SM5310C/EPA9060A 06/27/201511:58 GHUTCHI
1 SM2540D 06/19/2015 07:45 AGIBBS5

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060613
Site: PZ-3
Collection Date: 16-Jun-15 12:44 PM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter
Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)
< 0.01
mg-N/L
0.01
INORGANIC IONS BY IC
Chloride
28
mg/L
1
Sulfate
50
mg/L
1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
0.022
mg/L
0.005
Barium (Ba)
1.49
mg/L
0.005
Boron (B)
1.29
mg/L
0.05
Iron (Fe)
9.30
mg/L
0.01
Manganese (Mn)
0.511
mg/L
0.005
Strontium (Sr)
4.14
mg/L
0.005
Zinc (Zn)
0.008
mg/L
0.005
UNDIGESTED METALS BY lCP
Calcium (Ca)
90.7
mg/L
0.01
Magnesium (Mg)
13.8
mg/L
0.005
Potassium (K)
13.8
mg/L
0.1
Sodium (Na)
35.5
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.104
mg/L
0.005
Barium (Ba)
1.54
mg/L
0.005
Boron (B)
1.27
mg/L
0.05
Iron (Fe)
10.0
mg/L
0.01
Manganese (Mn)
0.521
mg/L
0.005
Strontium (Sr)
4.17
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Sample #: 2015019924
Matrix: GW WW
Analytical Lab
Page 6 of 62
DF Method Analysis Date/Time Analyst
Vendor Method
V_SHEALY
1
EPA 353.2
06/24/2015 15:30
LSTARLI
10
EPA 300.0
06/19/2015 12:34
BGN9034
10
EPA 300.0
06/19/2015 12:34
BGN9034
1
EPA 245.1
06/19/2015 11:51
ACPAYNE
1
EPA 245.1
06/19/2015 13:03
ACPAYNE
1
EPA 200.7
06/18/2015 12:48
MHALL3
1
EPA 200.7
06/18/2015 12:48
MHALL3
1
EPA 200.7
06/18/2015 12:48
MHALL3
1
EPA 200.7
06/18/2015 12:48
MHALL3
1
EPA 200.7
06/18/2015 12:48
MHALL3
1
EPA 200.7
06/18/2015 12:48
MHALL3
1
EPA 200.7
06/18/2015 12:48
MHALL3
1
EPA 200.7
06/19/2015 12:05
MHALL3
1
EPA 200.7
06/19/2015 12:05
MHALL3
1
EPA 200.7
06/19/2015 12:05
MHALL3
1
EPA 200.7
06/19/2015 12:05
MHALL3
1
EPA 200.7
06/19/2015 14:57
MHALL3
1
EPA 200.7
06/19/2015 14:57
MHALL3
1
EPA 200.7
06/19/2015 14:57
MHALL3
1
EPA 200.7
06/19/2015 14:57
MHALL3
1
EPA 200.7
06/19/2015 14:57
MHALL3
1
EPA 200.7
06/19/2015 14:57
MHALL3
1
EPA 200.7
06/19/2015 14:57
MHALL3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060613
Site: PZ-3
Collection Date: 16-Jun-15 12:44 PM
Analyte Result Units Qualifiers RDL
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
215
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
2.40
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
0.876
ug/L
0.3
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
226
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
2.53
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
1.17
ug/L
0.3
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
440
mg/L
25
Total Carbon
TOC
1.3
mg/L
0.1
TOTAL SUSPENDED SOLIDS
TSS
21
mg/L
5
Sample #: 2015019924
Matrix: GW WW
Analytical Lab
Page 7 of 62
DF
Method
Analysis Date/Time
Analyst
1
EPA 200.8
06/23/2015 04:22
SLS2560
1
EPA 200.8
06/23/2015 04:22
SLS2560
1
EPA 200.8
06/23/2015 04:22
SLS2560
1
EPA 200.8
06/23/2015 04:22
SLS2560
1
EPA 200.8
06/23/2015 04:22
SLS2560
1
EPA 200.8
06/23/2015 04:22
SLS2560
1
EPA 200.8
06/23/2015 04:22
SLS2560
1
EPA 200.8
06/23/2015 04:22
SLS2560
1
EPA 200.8
06/23/2015 04:22
SLS2560
1
EPA 200.8
06/23/2015 04:22
SLS2560
1
EPA 200.8
06/23/2015 04:22
SLS2560
1
EPA 200.8
06/23/2015 04:22
SLS2560
1
EPA 200.8
06/23/2015 04:22
SLS2560
1
EPA 200.8
06/22/2015 21:59
SLS2560
1
EPA 200.8
06/22/2015 21:59
SLS2560
1
EPA 200.8
06/22/2015 21:59
SLS2560
1
EPA 200.8
06/22/2015 21:59
SLS2560
1
EPA 200.8
06/22/2015 21:59
SLS2560
1
EPA 200.8
06/22/2015 21:59
SLS2560
1
EPA 200.8
06/22/2015 21:59
SLS2560
1
EPA 200.8
06/22/2015 21:59
SLS2560
1
EPA 200.8
06/22/2015 21:59
SLS2560
1
EPA 200.8
06/22/2015 21:59
SLS2560
1
EPA 200.8
06/22/2015 21:59
SLS2560
1
EPA 200.8
06/22/2015 21:59
SLS2560
1
EPA 200.8
06/22/2015 21:59
SLS2560
Vendor Method
V_SHEALY
Vendor Method V_ELE1
1 SM2540C 06/22/201514:30 AGIBBS5
1 SM5310C/EPA9060A 06/27/201511:58 GHUTCHI
1 SM2540D 06/19/2015 07:45 AGIBBS5

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060613
Site: PZ-4
Collection Date: 16-Jun-15 9:19 AM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter
Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)
< 0.01
mg-N/L
0.01
INORGANIC IONS BY IC
Chloride
13
mg/L
1
Sulfate
48
mg/L
1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
0.098
mg/L
0.005
Barium (Ba)
0.512
mg/L
0.005
Boron (B)
1.89
mg/L
0.05
Iron (Fe)
57.4
mg/L
0.1
Manganese (Mn)
0.477
mg/L
0.005
Strontium (Sr)
7.42
mg/L
0.005
Zinc (Zn)
0.015
mg/L
0.005
UNDIGESTED METALS BY lCP
Calcium (Ca)
217
mg/L
0.1
Magnesium (Mg)
34.1
mg/L
0.05
Potassium (K)
3.25
mg/L
1
Sodium (Na)
15.5
mg/L
0.5
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.280
mg/L
0.005
Barium (Ba)
0.515
mg/L
0.005
Boron (B)
1.87
mg/L
0.05
Iron (Fe)
56.7
mg/L
0.1
Manganese (Mn)
0.473
mg/L
0.005
Strontium (Sr)
7.35
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Sample #: 2015019925
Matrix: GW WW
Analytical Lab
Page 8 of 62
DF Method Analysis Date/Time Analyst
Vendor Method
V_SHEALY
1
EPA 353.2
06/24/2015 15:31
LSTARLI
10
EPA 300.0
06/19/2015 12:51
BGN9034
10
EPA 300.0
06/19/2015 12:51
BGN9034
1
EPA 245.1
06/19/2015 11:53
ACPAYNE
1
EPA 245.1
06/19/2015 13:05
ACPAYNE
1
EPA 200.7
06/18/2015 12:52
MHALL3
1
EPA 200.7
06/18/2015 12:52
MHALL3
1
EPA 200.7
06/18/2015 12:52
MHALL3
10
EPA 200.7
06/18/2015 12:52
MHALL3
1
EPA 200.7
06/18/2015 12:52
MHALL3
1
EPA 200.7
06/18/2015 12:52
MHALL3
1
EPA 200.7
06/18/2015 12:52
MHALL3
10
EPA 200.7
06/19/2015 11:08
MHALL3
10
EPA 200.7
06/19/2015 11:08
MHALL3
10
EPA 200.7
06/19/2015 11:08
MHALL3
10
EPA 200.7
06/19/2015 11:08
MHALL3
1
EPA 200.7
06/19/2015 15:01
MHALL3
1
EPA 200.7
06/19/2015 15:01
MHALL3
1
EPA 200.7
06/19/2015 15:01
MHALL3
10
EPA 200.7
06/19/2015 15:01
MHALL3
1
EPA 200.7
06/19/2015 15:01
MHALL3
1
EPA 200.7
06/19/2015 15:01
MHALL3
1
EPA 200.7
06/19/2015 15:01
MHALL3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060613
Site: PZ-4
Collection Date: 16-Jun-15 9:19 AM
Analyte
Result
Units Qualifiers
RDL
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
4.01
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
1.50
ug/L
1
Copper (Cu)
1.13
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
16.7
ug/L
1
Nickel (Ni)
1.79
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
0.611
ug/L
0.3
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
4.41
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
1.46
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
17.0
ug/L
1
Nickel (Ni)
1.29
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
0.874
ug/L
0.3
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
790
mg/L
25
Total Carbon
TOC
4.8
mg/L
0.1
TOTAL SUSPENDED SOLIDS
TSS
91
mg/L
5
Sample #: 2015019925
Matrix: GW WW
Analytical Lab
Page 9 of 62
DF
Method
Analysis Date/Time
Analyst
1
EPA 200.8
06/23/2015 04:29
SLS2560
1
EPA 200.8
06/23/2015 04:29
SLS2560
1
EPA 200.8
06/23/2015 04:29
SLS2560
1
EPA 200.8
06/23/2015 04:29
SLS2560
1
EPA 200.8
06/23/2015 04:29
SLS2560
1
EPA 200.8
06/23/2015 04:29
SLS2560
1
EPA 200.8
06/23/2015 04:29
SLS2560
1
EPA 200.8
06/23/2015 04:29
SLS2560
1
EPA 200.8
06/23/2015 04:29
SLS2560
1
EPA 200.8
06/23/2015 04:29
SLS2560
1
EPA 200.8
06/23/2015 04:29
SLS2560
1
EPA 200.8
06/23/2015 04:29
SLS2560
1
EPA 200.8
06/23/2015 04:29
SLS2560
1
EPA 200.8
06/22/2015 22:06
SLS2560
1
EPA 200.8
06/22/2015 22:06
SLS2560
1
EPA 200.8
06/22/2015 22:06
SLS2560
1
EPA 200.8
06/22/2015 22:06
SLS2560
1
EPA 200.8
06/22/2015 22:06
SLS2560
1
EPA 200.8
06/22/2015 22:06
SLS2560
1
EPA 200.8
06/22/2015 22:06
SLS2560
1
EPA 200.8
06/22/2015 22:06
SLS2560
1
EPA 200.8
06/22/2015 22:06
SLS2560
1
EPA 200.8
06/22/2015 22:06
SLS2560
1
EPA 200.8
06/22/2015 22:06
SLS2560
1
EPA 200.8
06/22/2015 22:06
SLS2560
1
EPA 200.8
06/22/2015 22:06
SLS2560
Vendor Method
V_SHEALY
Vendor Method V_ELE1
1 SM2540C 06/22/201514:30 AGIBBS5
1 SM5310C/EPA9060A 06/27/201511:58 GHUTCHI
1 SM2540D 06/19/2015 07:45 AGIBBS5

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060613
Site: PZ-5
Collection Date: 16-Jun-15 10:25 AM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter
Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)
4.9
mg-N/L
0.05
INORGANIC IONS BY IC
Chloride
27
mg/L
1
Sulfate
280
mg/L
5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
0.022
mg/L
0.005
Barium (Ba)
0.290
mg/L
0.005
Boron (B)
1.33
mg/L
0.05
Iron (Fe)
8.59
mg/L
0.01
Manganese (Mn)
2.16
mg/L
0.005
Strontium (Sr)
3.54
mg/L
0.005
Zinc (Zn)
0.015
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
215
mg/L
0.1
Magnesium (Mg)
38.2
mg/L
0.05
Potassium (K)
9.41
mg/L
1
Sodium (Na)
34.5
mg/L
0.5
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.040
mg/L
0.005
Barium (Ba)
0.284
mg/L
0.005
Boron (B)
1.29
mg/L
0.05
Iron (Fe)
8.49
mg/L
0.01
Manganese (Mn)
2.07
mg/L
0.005
Strontium (Sr)
3.48
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Sample #: 2015019926
Matrix: GW WW
Analytical Lab
Page 10 of 62
DF Method Analysis Date/Time Analyst
Vendor Method
V_SHEALY
5
EPA 353.2
06/24/2015 15:56
LSTARLI
10
EPA 300.0
06/23/2015 09:04
BGN9034
50
EPA 300.0
06/23/2015 09:04
BGN9034
1
EPA 245.1
06/19/2015 11:56
ACPAYNE
1
EPA 245.1
06/19/2015 13:08
ACPAYNE
1
EPA 200.7
06/18/2015 12:56
MHALL3
1
EPA 200.7
06/18/2015 12:56
MHALL3
1
EPA 200.7
06/18/2015 12:56
MHALL3
1
EPA 200.7
06/18/2015 12:56
MHALL3
1
EPA 200.7
06/18/2015 12:56
MHALL3
1
EPA 200.7
06/18/2015 12:56
MHALL3
1
EPA 200.7
06/18/2015 12:56
MHALL3
10
EPA 200.7
06/19/2015 11:38
MHALL3
10
EPA 200.7
06/19/2015 11:38
MHALL3
10
EPA 200.7
06/19/2015 11:38
MHALL3
10
EPA 200.7
06/19/2015 11:38
MHALL3
1
EPA 200.7
06/19/2015 15:05
MHALL3
1
EPA 200.7
06/19/2015 15:05
MHALL3
1
EPA 200.7
06/19/2015 15:05
MHALL3
1
EPA 200.7
06/19/2015 15:05
MHALL3
1
EPA 200.7
06/19/2015 15:05
MHALL3
1
EPA 200.7
06/19/2015 15:05
MHALL3
1
EPA 200.7
06/19/2015 15:05
MHALL3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060613
Site: PZ-5
Collection Date: 16-Jun-15 10:25 AM
Analyte Result Units Qualifiers RDL
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
29.2
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
30.0
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
43.2
ug/L
1
Nickel (Ni)
17.4
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
0.615
ug/L
0.2
Vanadium (V) Low Level
1.65
ug/L
0.3
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
1.16
ug/L
1
Arsenic (As)
31.2
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
31.1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
47.1
ug/L
1
Nickel (Ni)
17.6
ug/L
1
Selenium (Se)
1.52
ug/L
1
Thallium (TI) Low Level
0.658
ug/L
0.2
Vanadium (V) Low Level
1.84
ug/L
0.3
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
980
mg/L
25
Total Carbon
TOC 7.0 mg/L 1
TOTAL SUSPENDED SOLIDS
TSS 10 mg/L 5
Sample #: 2015019926
Matrix: GW WW
Analytical Lab
Page 11 of 62
DF
Method
Analysis Date/Time
Analyst
1
EPA 200.8
06/23/2015 04:36
SLS2560
1
EPA 200.8
06/23/2015 04:36
SLS2560
1
EPA 200.8
06/23/2015 04:36
SLS2560
1
EPA 200.8
06/23/2015 04:36
SLS2560
1
EPA 200.8
06/23/2015 04:36
SLS2560
1
EPA 200.8
06/23/2015 04:36
SLS2560
1
EPA 200.8
06/23/2015 04:36
SLS2560
1
EPA 200.8
06/23/2015 04:36
SLS2560
1
EPA 200.8
06/23/2015 04:36
SLS2560
1
EPA 200.8
06/23/2015 04:36
SLS2560
1
EPA 200.8
06/23/2015 04:36
SLS2560
1
EPA 200.8
06/23/2015 04:36
SLS2560
1
EPA 200.8
06/23/2015 04:36
SLS2560
1
EPA 200.8
06/22/2015 22:13
SLS2560
1
EPA 200.8
06/22/2015 22:13
SLS2560
1
EPA 200.8
06/22/2015 22:13
SLS2560
1
EPA 200.8
06/22/2015 22:13
SLS2560
1
EPA 200.8
06/22/2015 22:13
SLS2560
1
EPA 200.8
06/22/2015 22:13
SLS2560
1
EPA 200.8
06/22/2015 22:13
SLS2560
1
EPA 200.8
06/22/2015 22:13
SLS2560
1
EPA 200.8
06/22/2015 22:13
SLS2560
1
EPA 200.8
06/22/2015 22:13
SLS2560
1
EPA 200.8
06/22/2015 22:13
SLS2560
1
EPA 200.8
06/22/2015 22:13
SLS2560
1
EPA 200.8
06/22/2015 22:13
SLS2560
Vendor Method
V_SHEALY
Vendor Method V_ELE1
1 SM2540C 06/22/201514:30 AGIBBS5
10 SM5310C/EPA9060A 06/27/201511:58 GHUTCHI
1 SM2540D 06/19/2015 07:45 AGIBBS5

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060613
Site: SMW-4
Collection Date: 16-Jun-15 11:10 AM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter
Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)
< 0.01
mg-N/L
0.01
INORGANIC IONS BY IC
Chloride
4.5
mg/L
1
Sulfate
14
mg/L
1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
0.061
mg/L
0.005
Barium (Ba)
0.111
mg/L
0.005
Boron (B)
0.321
mg/L
0.05
Iron (Fe)
14.7
mg/L
0.01
Manganese (Mn)
0.220
mg/L
0.005
Strontium (Sr)
0.410
mg/L
0.005
Zinc (Zn)
0.025
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
14.6
mg/L
0.01
Magnesium (Mg)
4.71
mg/L
0.005
Potassium (K)
2.81
mg/L
0.1
Sodium (Na)
6.17
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.336
mg/L
0.005
Barium (Ba)
0.114
mg/L
0.005
Boron (B)
0.318
mg/L
0.05
Iron (Fe)
14.9
mg/L
0.01
Manganese (Mn)
0.219
mg/L
0.005
Strontium (Sr)
0.408
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Sample #: 2015019927
Matrix: GW WW
Analytical Lab
Page 12 of 62
DF Method Analysis Date/Time Analyst
Vendor Method
V_SHEALY
1
EPA 353.2
06/24/2015 15:49
LSTARLI
10
EPA 300.0
06/19/2015 13:23
BGN9034
10
EPA 300.0
06/19/2015 13:23
BGN9034
1
EPA 245.1
06/19/2015 12:10
ACPAYNE
1
EPA 245.1
06/19/2015 13:10
ACPAYNE
1
EPA 200.7
06/18/2015 13:00
MHALL3
1
EPA 200.7
06/18/2015 13:00
MHALL3
1
EPA 200.7
06/18/2015 13:00
MHALL3
1
EPA 200.7
06/18/2015 13:00
MHALL3
1
EPA 200.7
06/18/2015 13:00
MHALL3
1
EPA 200.7
06/18/2015 13:00
MHALL3
1
EPA 200.7
06/18/2015 13:00
MHALL3
1
EPA 200.7
06/19/2015 10:11
MHALL3
1
EPA 200.7
06/19/2015 10:11
MHALL3
1
EPA 200.7
06/19/2015 10:11
MHALL3
1
EPA 200.7
06/19/2015 10:11
MHALL3
1
EPA 200.7
06/19/2015 15:10
MHALL3
1
EPA 200.7
06/19/2015 15:10
MHALL3
1
EPA 200.7
06/19/2015 15:10
MHALL3
1
EPA 200.7
06/19/2015 15:10
MHALL3
1
EPA 200.7
06/19/2015 15:10
MHALL3
1
EPA 200.7
06/19/2015 15:10
MHALL3
1
EPA 200.7
06/19/2015 15:10
MHALL3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060613
Site: SMW-4
Collection Date: 16-Jun-15 11:10 AM
Analyte Result Units Qualifiers RDL
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
6.24
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
3.21
ug/L
0.3
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
6.02
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
3.59
ug/L
0.3
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
130
mg/L
25
Total Carbon
TOC 8.3 mg/L 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L 5
Sample #: 2015019927
Matrix: GW WW
Analytical Lab
Page 13 of 62
DF
Method
Analysis Date/Time
Analyst
1
EPA 200.8
06/23/2015 04:44
SLS2560
1
EPA 200.8
06/23/2015 04:44
SLS2560
1
EPA 200.8
06/23/2015 04:44
SLS2560
1
EPA 200.8
06/23/2015 04:44
SLS2560
1
EPA 200.8
06/23/2015 04:44
SLS2560
1
EPA 200.8
06/23/2015 04:44
SLS2560
1
EPA 200.8
06/23/2015 04:44
SLS2560
1
EPA 200.8
06/23/2015 04:44
SLS2560
1
EPA 200.8
06/23/2015 04:44
SLS2560
1
EPA 200.8
06/23/2015 04:44
SLS2560
1
EPA 200.8
06/23/2015 04:44
SLS2560
1
EPA 200.8
06/23/2015 04:44
SLS2560
1
EPA 200.8
06/23/2015 04:44
SLS2560
1
EPA 200.8
06/22/2015 22:20
SLS2560
1
EPA 200.8
06/22/2015 22:20
SLS2560
1
EPA 200.8
06/22/2015 22:20
SLS2560
1
EPA 200.8
06/22/2015 22:20
SLS2560
1
EPA 200.8
06/22/2015 22:20
SLS2560
1
EPA 200.8
06/22/2015 22:20
SLS2560
1
EPA 200.8
06/22/2015 22:20
SLS2560
1
EPA 200.8
06/22/2015 22:20
SLS2560
1
EPA 200.8
06/22/2015 22:20
SLS2560
1
EPA 200.8
06/22/2015 22:20
SLS2560
1
EPA 200.8
06/22/2015 22:20
SLS2560
1
EPA 200.8
06/22/2015 22:20
SLS2560
1
EPA 200.8
06/22/2015 22:20
SLS2560
Vendor Method
V_SHEALY
Vendor Method V_ELE1
1 SM2540C 06/22/201514:30 AGIBBS5
10 SM5310C/EPA9060A 06/27/201511:58 GHUTCHI
1 SM2540D 06/19/2015 07:45 AGIBBS5

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060613
Site: IMW-3S
Collection Date: 16-Jun-15 8:30 AM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter
Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)
< 0.01
mg-N/L
0.01
INORGANIC IONS BY IC
Chloride
4.5
mg/L
0.1
Sulfate
1.4
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
0.020
mg/L
0.005
Barium (Ba)
0.148
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
5.69
mg/L
0.01
Manganese (Mn)
0.693
mg/L
0.005
Strontium (Sr)
0.070
mg/L
0.005
Zinc (Zn)
0.048
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
10.1
mg/L
0.01
Magnesium (Mg)
4.56
mg/L
0.005
Potassium (K)
1.50
mg/L
0.1
Sodium (Na)
8.05
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.022
mg/L
0.005
Barium (Ba)
0.142
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
6.32
mg/L
0.01
Manganese (Mn)
0.722
mg/L
0.005
Strontium (Sr)
0.067
mg/L
0.005
Zinc (Zn)
0.016
mg/L
0.005
Sample #: 2015019928
Matrix: GW WW
Analytical Lab
Page 14 of 62
DF Method Analysis Date/Time Analyst
Vendor Method
V_SHEALY
1 EPA 353.2
06/24/2015 15:50
LSTARLI
1 EPA 300.0
06/19/2015 15:51
BGN9034
1 EPA 300.0
06/19/2015 15:51
BGN9034
1 EPA 245.1
06/19/2015 12:03
ACPAYNE
1 EPA 245.1
06/19/2015 13:12
ACPAYNE
1 EPA 200.7
06/18/2015 13:04
MHALL3
1 EPA 200.7
06/18/2015 13:04
MHALL3
1 EPA 200.7
06/18/2015 13:04
MHALL3
1 EPA 200.7
06/18/2015 13:04
MHALL3
1 EPA 200.7
06/18/2015 13:04
MHALL3
1 EPA 200.7
06/18/2015 13:04
MHALL3
1 EPA 200.7
06/18/2015 13:04
MHALL3
1 EPA 200.7
06/19/2015 13:21
MHALL3
1 EPA 200.7
06/19/2015 13:21
MHALL3
1 EPA 200.7
06/19/2015 13:21
MHALL3
1 EPA 200.7
06/19/2015 13:21
MHALL3
1 EPA 200.7
06/23/2015 09:56
MHH7131
1 EPA 200.7
06/23/2015 09:56
MHH7131
1 EPA 200.7
06/23/2015 09:56
MHH7131
1 EPA 200.7
06/23/2015 09:56
MHH7131
1 EPA 200.7
06/23/2015 09:56
MHH7131
1 EPA 200.7
06/23/2015 09:56
MHH7131
1 EPA 200.7
06/23/2015 09:56
MHH7131

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060613
Site: IMW-3S
Collection Date: 16-Jun-15 8:30 AM
Analyte Result Units Qualifiers RDL
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
12.9
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
5.32
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
12.2
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
6.22
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
94
mg/L
25
Total Carbon
TOC
1.5
mg/L
0.1
TOTAL SUSPENDED SOLIDS
TSS
< 5
mg/L
5
Sample #: 2015019928
Matrix: GW WW
Analytical Lab
Page 15 of 62
DF
Method
Analysis Date/Time
Analyst
1
EPA 200.8
06/23/2015 04:51
SLS2560
1
EPA 200.8
06/23/2015 04:51
SLS2560
1
EPA 200.8
06/23/2015 04:51
SLS2560
1
EPA 200.8
06/23/2015 04:51
SLS2560
1
EPA 200.8
06/23/2015 04:51
SLS2560
1
EPA 200.8
06/23/2015 04:51
SLS2560
1
EPA 200.8
06/23/2015 04:51
SLS2560
1
EPA 200.8
06/23/2015 04:51
SLS2560
1
EPA 200.8
06/23/2015 04:51
SLS2560
1
EPA 200.8
06/23/2015 04:51
SLS2560
1
EPA 200.8
06/23/2015 04:51
SLS2560
1
EPA 200.8
06/23/2015 04:51
SLS2560
1
EPA 200.8
06/23/2015 04:51
SLS2560
1
EPA 200.8
06/23/2015 08:51
SLS2560
1
EPA 200.8
06/23/2015 08:51
SLS2560
1
EPA 200.8
06/23/2015 08:51
SLS2560
1
EPA 200.8
06/23/2015 08:51
SLS2560
1
EPA 200.8
06/23/2015 08:51
SLS2560
1
EPA 200.8
06/23/2015 08:51
SLS2560
1
EPA 200.8
06/23/2015 08:51
SLS2560
1
EPA 200.8
06/23/2015 08:51
SLS2560
1
EPA 200.8
06/23/2015 08:51
SLS2560
1
EPA 200.8
06/23/2015 08:51
SLS2560
1
EPA 200.8
06/23/2015 08:51
SLS2560
1
EPA 200.8
06/23/2015 08:51
SLS2560
1
EPA 200.8
06/23/2015 08:51
SLS2560
Vendor Method
V_SHEALY
Vendor Method V_ELE1
1 SM2540C 06/22/201514:30 AGIBBS5
1 SM5310C/EPA9060A 06/27/201511:58 GHUTCHI
1 SM2540D 06/19/2015 07:45 AGIBBS5

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060613
Site: IMW-3BC
Collection Date: 16-Jun-15 9:25 AM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter
Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)
< 0.01
mg-N/L
0.01
INORGANIC IONS BY IC
Chloride
3.0
mg/L
0.1
Sulfate
4.6
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
0.263
mg/L
0.005
Boron (B)
0.059
mg/L
0.05
Iron (Fe)
0.647
mg/L
0.01
Manganese (Mn)
0.088
mg/L
0.005
Strontium (Sr)
0.082
mg/L
0.005
Zinc (Zn)
0.008
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
24.6
mg/L
0.01
Magnesium (Mg)
3.70
mg/L
0.005
Potassium (K)
1.13
mg/L
0.1
Sodium (Na)
7.46
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.011
mg/L
0.005
Barium (Ba)
0.258
mg/L
0.005
Boron (B)
0.052
mg/L
0.05
Iron (Fe)
0.994
mg/L
0.01
Manganese (Mn)
0.086
mg/L
0.005
Strontium (Sr)
0.076
mg/L
0.005
Zinc (Zn)
0.007
mg/L
0.005
Sample #: 2015019929
Matrix: GW WW
Analytical Lab
Page 16 of 62
DF Method Analysis Date/Time Analyst
Vendor Method
V_SHEALY
1 EPA 353.2
06/24/2015 15:57
LSTARLI
1 EPA 300.0
06/19/2015 16:08
BGN9034
1 EPA 300.0
06/19/2015 16:08
BGN9034
1 EPA 245.1
06/19/2015 12:12
ACPAYNE
1 EPA 245.1
06/19/2015 13:22
ACPAYNE
1 EPA 200.7
06/18/2015 13:15
MHALL3
1 EPA 200.7
06/18/2015 13:15
MHALL3
1 EPA 200.7
06/18/2015 13:15
MHALL3
1 EPA 200.7
06/18/2015 13:15
MHALL3
1 EPA 200.7
06/18/2015 13:15
MHALL3
1 EPA 200.7
06/18/2015 13:15
MHALL3
1 EPA 200.7
06/18/2015 13:15
MHALL3
1 EPA 200.7
06/19/2015 12:39
MHALL3
1 EPA 200.7
06/19/2015 12:39
MHALL3
1 EPA 200.7
06/19/2015 12:39
MHALL3
1 EPA 200.7
06/19/2015 12:39
MHALL3
1 EPA 200.7
06/23/2015 10:56
MHH7131
1 EPA 200.7
06/23/2015 10:56
MHH7131
1 EPA 200.7
06/23/2015 10:56
MHH7131
1 EPA 200.7
06/23/2015 10:56
MHH7131
1 EPA 200.7
06/23/2015 10:56
MHH7131
1 EPA 200.7
06/23/2015 10:56
MHH7131
1 EPA 200.7
06/23/2015 10:56
MHH7131

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060613
Site: IMW-3BC
Collection Date: 16-Jun-15 9:25 AM
Analyte Result Units Qualifiers RDL
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
1.11
ug/L
1
Nickel (Ni)
2.52
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
1.21
ug/L
1
Nickel (Ni)
2.25
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
150
mg/L
25
Total Carbon
TOC
0.675
mg/L
0.1
TOTAL SUSPENDED SOLIDS
TSS
< 5
mg/L
5
Sample #: 2015019929
Matrix: GW WW
Analytical Lab
Page 17 of 62
DF
Method
Analysis Date/Time
Analyst
1
EPA 200.8
06/23/2015 04:58
SLS2560
1
EPA 200.8
06/23/2015 04:58
SLS2560
1
EPA 200.8
06/23/2015 04:58
SLS2560
1
EPA 200.8
06/23/2015 04:58
SLS2560
1
EPA 200.8
06/23/2015 04:58
SLS2560
1
EPA 200.8
06/23/2015 04:58
SLS2560
1
EPA 200.8
06/23/2015 04:58
SLS2560
1
EPA 200.8
06/23/2015 04:58
SLS2560
1
EPA 200.8
06/23/2015 04:58
SLS2560
1
EPA 200.8
06/23/2015 04:58
SLS2560
1
EPA 200.8
06/23/2015 04:58
SLS2560
1
EPA 200.8
06/23/2015 04:58
SLS2560
1
EPA 200.8
06/23/2015 04:58
SLS2560
1
EPA 200.8
06/23/2015 08:08
SLS2560
1
EPA 200.8
06/23/2015 08:08
SLS2560
1
EPA 200.8
06/23/2015 08:08
SLS2560
1
EPA 200.8
06/23/2015 08:08
SLS2560
1
EPA 200.8
06/23/2015 08:08
SLS2560
1
EPA 200.8
06/23/2015 08:08
SLS2560
1
EPA 200.8
06/23/2015 08:08
SLS2560
1
EPA 200.8
06/23/2015 08:08
SLS2560
1
EPA 200.8
06/23/2015 08:08
SLS2560
1
EPA 200.8
06/23/2015 08:08
SLS2560
1
EPA 200.8
06/23/2015 08:08
SLS2560
1
EPA 200.8
06/23/2015 08:08
SLS2560
1
EPA 200.8
06/23/2015 08:08
SLS2560
Vendor Method
V_SHEALY
Vendor Method V_ELE1
1 SM2540C 06/22/201514:30 AGIBBS5
1 SM5310C/EPA9060A 06/27/201511:58 GHUTCHI
1 SM2540D 06/19/2015 07:45 AGIBBS5

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060613
Site: Filter Blank
Collection Date: 16-Jun-15 7:45 AM
Analyte
Result
Units
Qualifiers RDL
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
< 0.005
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
< 0.005
mg/L
0.005
Strontium (Sr)
< 0.005
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
Sample #: 2015019945
Matrix: GW WW
Analytical Lab
Page 18 of 62
DF
Method
Analysis Date/Time
Analyst
1
EPA 245.1
06/19/2015 13:14
ACPAYNE
1
EPA 200.7
06/18/2015 13:26
MHALL3
1
EPA 200.7
06/18/2015 13:26
MHALL3
1
EPA 200.7
06/18/2015 13:26
MHALL3
1
EPA 200.7
06/18/2015 13:26
MHALL3
1
EPA 200.7
06/18/2015 13:26
MHALL3
1
EPA 200.7
06/18/2015 13:26
MHALL3
1
EPA 200.7
06/18/2015 13:26
MHALL3
1
EPA 200.8
06/23/2015 05:05
SLS2560
1
EPA 200.8
06/23/2015 05:05
SLS2560
1
EPA 200.8
06/23/2015 05:05
SLS2560
1
EPA 200.8
06/23/2015 05:05
SLS2560
1
EPA 200.8
06/23/2015 05:05
SLS2560
1
EPA 200.8
06/23/2015 05:05
SLS2560
1
EPA 200.8
06/23/2015 05:05
SLS2560
1
EPA 200.8
06/23/2015 05:05
SLS2560
1
EPA 200.8
06/23/2015 05:05
SLS2560
1
EPA 200.8
06/23/2015 05:05
SLS2560
1
EPA 200.8
06/23/2015 05:05
SLS2560
1
EPA 200.8
06/23/2015 05:05
SLS2560
1
EPA 200.8
06/23/2015 05:05
SLS2560

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060613
Site: Equipment Blank
Collection Date: 16-Jun-15 7:45 AM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy
Labs)
Vendor Parameter
Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)
0.021
mg-N/L
0.01
INORGANIC IONS BY IC
Chloride
< 0.1
mg/L
0.1
Sulfate
< 0.1
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
UNDIGESTED METALS BY lCP
Calcium (Ca)
0.048
mg/L
0.01
Magnesium (Mg)
< 0.005
mg/L
0.005
Potassium (K)
< 0.1
mg/L
0.1
Sodium (Na)
< 0.05
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.009
mg/L
0.005
Barium (Ba)
< 0.005
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
< 0.005
mg/L
0.005
Strontium (Sr)
< 0.005
mg/L
0.005
Zinc (Zn)
0.010
mg/L
0.005
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
Analytical Lab
Page 19 of 62
Sample #: 2015019946
Matrix: GW WW
DF Method Analysis Date/Time Analyst
Vendor Method V_SHEALY
1 EPA 353.2
06/24/2015 15:59
LSTARLI
1 EPA 300.0
06/19/2015 14:13
BGN9034
1 EPA 300.0
06/19/2015 14:13
BGN9034
1 EPA 245.1
06/19/2015 12:14
ACPAYNE
1 EPA 200.7
06/19/2015 12:43
MHALL3
1 EPA 200.7
06/19/2015 12:43
MHALL3
1 EPA 200.7
06/19/2015 12:43
MHALL3
1 EPA 200.7
06/19/2015 12:43
MHALL3
1 EPA 200.7
06/23/2015 10:12
MHH7131
1 EPA 200.7
06/23/2015 10:12
MHH7131
1 EPA 200.7
06/23/2015 10:12
MHH7131
1 EPA 200.7
06/23/2015 10:12
MHH7131
1 EPA 200.7
06/23/2015 10:12
MHH7131
1 EPA 200.7
06/23/2015 10:12
MHH7131
1 EPA 200.7
06/23/2015 10:12
MHH7131
1 EPA 200.8
06/23/2015 08:58
SLS2560
1 EPA 200.8
06/23/2015 08:58
SLS2560
1 EPA 200.8
06/23/2015 08:58
SLS2560
1 EPA 200.8
06/23/2015 08:58
SLS2560
1 EPA 200.8
06/23/2015 08:58
SLS2560
1 EPA 200.8
06/23/2015 08:58
SLS2560
1 EPA 200.8
06/23/2015 08:58
SLS2560
1 EPA 200.8
06/23/2015 08:58
SLS2560
1 EPA 200.8
06/23/2015 08:58
SLS2560
1 EPA 200.8
06/23/2015 08:58
SLS2560
1 EPA 200.8
06/23/2015 08:58
SLS2560
1 EPA 200.8
06/23/2015 08:58
SLS2560
1 EPA 200.8
06/23/2015 08:58
SLS2560
METHANE - (Analysis Performed by Shealy Labs)
Methane (CH4) Complete Vendor Method V_SHEALY

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060613
Site: Equipment Blank
Collection Date: 16-Jun-15 7:45 AM
Analyte Result Units Qualifiers RDL DF
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete
TOTAL DISSOLVED SOLIDS
TDS < 25 mg/L 25 1
Total Carbon
Sample #: 2015019946
Matrix: GW WW
Analytical Lab
Page 20 of 62
Method Analysis Date/Time Analyst
Vendor Method
V_ELE1
SM2540C 06/22/201514:30 AGIBBS5
TOC 0.350 mg/L 0.1 1 SM5310C/EPA9060A 06/27/201511:58 GHUTCHI
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L 5 1 SM2540D 06/19/2015 07:45 AGIBBS5

Analytical Lab
Page 21 of 62
Element One lnc.
6319-D Carolina Beach Rd.
Wilmington, NC 28412
Phone: [phone]
Fau: 910 792-6853
el lab@e18ab
.Iom
eke;,c untOne
REPORT OF ANALYSES
Duke Energy
June 23, 2015
Laboratory Services
Client Project Name AB GW Assessment waters (wells) HF Lee
13339 Hagers Ferry Road Bid.
MG03A Client Project Number J15060613
Huntersville, NC 28078
PO Number
Sample Matrix GW WW
Sample Type Grab
Date Received
06/19/2015
Date Analyzed 06/22/2015
Method SM 4500 S2- D
Time Received
1645
Delivered by Fed Ex
Received by
LLB
eOne ID Duke Energy ID
Parameter Result Unit
Dil
DL Date
Time
Sampled
Sampled
25138-1 SMW-2
Sulfide < 0.1 mg/L
1
0.1 06/16/15
0953
25138-2 PZ-3
Sulfide < 0.1 mg/L
1
0.1 06/16/15
1249
25138-3* PZ-4
Sulfide < 0.2 mg/L
2
0.1 06/16/15
0919
25138-4 PZ-5
Sulfide < 0.1 mg/L
1
0.1 06/16/15
1025
25138-5" SMW-4
Sulfide < 0.5 mg/L
5
0.1 06/16/15
1110
25138-6 IMW-3S
Sulfide < 0.1 mg/L
1
0.1 06/16/15
0830
25138-7 IMW-3BC
Sulfide < 0.1 mg/L
1
0.1 06/16/15
0925
25138-8 Equipment Blank
Sulfide < 0.1 mg/L
1
0.1 06/16/15
0745
"Sample spike recovery outside of QA limits of 85-115%; dilution necessary to meet laboratory QA limits.
Ken Smith, Laboratory Director
25138 Duke Report Packet Compiled by—R�-
NC Certifications: DW 37788 and DWQ DENR 604

!y u 1 �aa — _�� _ Analytical Lab
S-C a _ _
auuF CSS Page 22 of
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y u
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elementOne SAMPLE SUBMISSION FORM
TAT 56D
Hold Time Expiration 06.23.15 @ 0745
Client: Duke Energy
LIMS No J15060613
Project ID HF Lee
Analytical Lab
Lab V 23 29138
Analysis Due Date 06.22.15
Report Due Date 06.23.15
Date Rec: 06.19.15
Time Rec: 1645
Rec By LLB
H >9 a No Tem <_ 60C No Ref. Method:
If No, Record If No, Record SM4500 S2 D
Sample Identification & Cnllpc+inn Infnrmnfinn
Lab ID
I Client ID
Collection Date
Collection Time
Analysis Requested
1
SMW-2 _
06.16.15
0953
2
PZ-3
06.16.15
1249
3
PZ-4
06.16.15
0919
ulfi
4
PZ-5
06.16.15
1025
5
SMW_-4
06.16.15
1110
6
IMW-3S _
06.16.15
0830
e
_7
IMW-3BC
_
06.16.15
0925
e
8
Equipment Blank
06.16.15
0745
NOTE for Sulfide
The MS/MSD spike should approximate 2 to 3 times the sample concentration. If no sulfide detected
at 100 pg/L spike the sample to render the final spike concentration at — 500 pg/L
Lab Communications
All AB Groundwater Assessment jobs need a RL of 0.1
Per Email 5 Day TAT
SS Page 1 of 1 Prep By / Date A M 6 a a t s
SS by Labeled By / Date . ZZ .
6/22/20 1:16:34 PM ID Verification By /Date r.

Analytical Lab
Page 24 of 62
METHOD:
SM 4500 S2--D
ELEMENT ONE
ELEMENT ASSAY:
Sulfide
Spectrophotometer
Wave Length 664
UNITS OF ANSWER
u /mL
DETECTIONLIMIT u
1.000
CLIENT:
Duke
SPK LEVEL (u4)
5
Lab ID#
25138/ 139/ 140/ 141/ 142/ 143
Na2S•9H2O Lot #
40721
MAX ALIQUOT
10.00
Date:
06/22/15
STANDARD conc(ppm)
X
Time Analysis Begun
12:00
ICal Std Lot: SD-10-3 1
10
Time Analysis Ended
16:00
JQC Std Lot: SD-10-4
10
Analyst:
KAM
ISTID ABSORPTION
Y
X
Y
ugSTD
SOLUTION
STD
ABS
1701
0,00
1.00
2.50
5.00
7.50
10.00
0.000
0.098
0.218
0.417
0.605
0.776
0600
�
0°
°'°°
o.aao a :oo aoo eao eao low tiW
x
SAMPLE
I.D.
d ...
SAMP
ABS
M
ug PER
ALIQUOT
MINIM- -
ALI in mL
ANALYZED
PREP
VOL in mL
Sloe 0.077338462
Correlation 0.99911033
ALI in mL
TAKEN
RESULTS
u /mL
LESS THAN
% SPK REC
SPIKE
LEVEL
Std. B. 0.00
0.000
0.0000
10
10
10
<
0.0
Std. B. 1.00
0.090
0.8053
10
10
10
<
80.53%
1.0
Std. B. 2.50
0.223
1 2.5940
10
10
10
0.259
103.76%
2.5
Std. B. 5.00
0.425
5.3106
10
10
10
0.531
106.21 %
5.0
Std. B. 7.50
0.616
7.8793
10
10
10
0.788
105.06%
7.5
Std. B. 10.00
0.800
10.3538
10
10
10
1.035
103.54%
10.0
LRB
0.000
0.0000
10
10
10
<
0.0
LRB SPK
0.427
5.3375
10
10
10
0.534
107%
5.0
QC
0.420
5.2434
10
10
10
0.524
105%
5.0
25138-1
0.001
-0.3916
10
10
10.
25138-1 s k
0.421
5.2568
10
10
10
0.526
105%
5.0
25138-2
0.030
-0.0016
10
10
10
25138-2 dup
0.028
-0.0285
10
10
10
< 0.1
25138-2 s k
0.431
1 5.3913
10
10
10
0.539
108%
5.0
25138-3
0.021
-0.1226
10
10
10
< 0.1
25138-3 s k
0.488
6.1579
10
10
10
0.616
123%
5.0
25138-4
0.028
-0.0285
10
10
10�k�
25138-4 s k
0.414
5.1627
10
10
10
0.516
103%
5.0
25138-5
0.085
0.7381
10
10
10
<
25138-5 spk
0.520
6.5882
10
10
10
0.659
132%
5.0
25138-6
0.000
0.0000
10
10
10
25138-6 s k
0.410
5.1089
10
10
10
0.511
102%
5.0
25138-7
0.000
0.0000
10
10
10�
`
25138-7 s k
0.438
5.4854
10
10
10
0.549
110%
5.0
25138-8
-0.001
0.0000
10
10
10
25138-8 spk
0.429
5.3644
10
10
10
0.536
107%
5.0
25139-1
0.000
0.0000
10
10
10
25139-1 s k
0.345
4.2347
10
10
10
0.423
85%
5.0
Blank
0.000
0.0000
10
10
10
<
QC
0.422
5.2703
10
10
10
0.527
105%
5.0
Submitted for QA/QC-
Date: 06/22/15
By: (Print)
KAM
(sign):
NMI
Page 1 of 5

Analytical Lab
Page 25 of 62
METHOD:
SM 4500 S2- D
ELEMENT ONE
ELEMENT ASSAY:
Sulfide
Spectrophotometer
Wave Length 664
UNITS OF ANSWER
ug/mL
DETECTION LIMIT u
1.000
CLIENT:
Duke
SPK LEYELLuM
5
Lab ID#
25138/ 139/ 140/ 141/ 142/ 143
Na2S•9H2O Lot #
40721
MAX ALIQUOT
10.00
Date:
06/22/15
STANDARD conc(ppm)
X
Time Analysis Begun
12:00
Cal Std Lot: SD-10-3
10
Time Analysis Ended
16:00
QC Std Lot: SD-10-4
10
Analyst:
KAM
ISTID ABSORPTION I
Y
o
ug STD
SOLUTION
STD
ABS
°'°°
0.00
1.00
2.50
5.00
7.50
10.00
0.000
0.098
0.218
0.417
0.605
0.776
0600
0500
°'°°
Yz�
-
03M
O2M
0+0,
°°°o0 :00 4.00 600 a00 ,OW 120
X
SAMPLE
I.D.
SAMP ug PER
ABS ALIQUOT
ALI in mL
ANALYZED
PREP
VOL in mL
Sloe 0.077338462
Correlation 0.99911033
ALI in mL
TAKEN
RESULTS
ug/mL
LESS THAN
% SPK REC
SPIKE
LEVEL
Std. B. 0.00
0.000
0.0000
10
10
10
<
0.0
Std. B. 1.00
0.090
0.8053
10
10
10
<
80.53%
1.0
Std. B. 2.50
0.223
2.5940
10
10
10
0.259
103.76%
2.5
Std. B. 5.00
0.425
5.3106
10
10
10
0.531
106.21 %
5.0
Std. B. 7.50
0.616
7.8793
10
10
10
0.788
105.06%
7.5
Std. B. 10.00
0.800
10.3538
10
10
10
1.035
103.54%
10.0
LRB
0.000
0.0000
10
10
10
<
0.0
LRB SPK
0.427
5.3375
10
10
10
0.534
107%
5.0
QC
0.420
5.2434
10
10
10
0.524
105%
5.0
25139-2
0.003
-0.3647
10
10
10�
rr
25139-2 s k
0.431
5.3913
10
10
10
0.539
108%
5.0
25139-3
0.025
-0.0688
10
10
10
25139-3 dup
0.025
-0.0688
10
10
10
< 0.1
25139-3 spk
0.450
5.6468
10
10
10
0.565
113%
5.0
25140-1
0.000
0.0000
10
10
10
25140-1 s k
0.412
5.1358
10
10
10
0.514
103%
5.0
25140-2
0.006
-0.3244
10
10
10
25140-2 s k
0.401
4.9878
10
10
10
0.499
100%
5.0
25140-3
0.010
-0.2706
10
10
10
a
25140-3 spk
0.379
4.6920
10
10
10
0.469
94%
5.0
25140-4
0.000
0.0000
10
10
10
;
25140-4 s k
0.402
5.0013
10
10
10
0.500
100%
5.0
25140-5
0.002
-0.3781
10
10
10
25140-5 s k
0.414
5.1627
10
10
10
0.516
103%
5.0
25140-6
0.002
-0.3781
10
10
10
25140-6 s k
0.379
4.6920
10
10
10
0.469
94%
5.0
25140-7
0.277
3.3202
10
10
10
0.332
25140-7 s k
0.293
3.5354
10
10
10
0.354
4%
5.0
Blank
0.000
0.0000 j
10
10
10
<
QC
0.421
5.2568
1 10
10
10
0.526
105%
5.0
Submitted for QA/QC-
Date: 06/22/15
By: (Print)
KAM
(sign):
Page 2 of 5

Analytical Lab
Page 26 of 62
METHOD: SM 4500 S2- D ELEMENT ONE
ELEMENT ASSAY: Sulfide Spectrophotometer UNITS OF ANSWER ug/mL
Wave Length 664 DETECTION 1.000
CLIENT: Duke LIMITuSPK LEVEL u 5
Lab ID# 25138/ 139/ 140/ 1411 142/ 143^ MAX ALIQUOT _ 10.00
Date: 06/22/15 Na2S•9H2O Lot # STANDARD conc(ppm) X
Time Analysis Begun 12:00 40721 ICal Std Lot: SD-10-3 10
Time Analysis Ended 16:00 1 QC Std Lot: SD-10-4 10
Analyst: KAM JSTD ABSORPTION Y
X Y
ug STD STD OBW
SOLUTION ABS 07M
0.00 0.000 Y�
1.00 0.098 04M
2.50 0.218 0300
0200
5.00 0.417 0100
7.50 0.605 0000
000 200 000 6.00 8.00 10.00 1200.
10.00 0.776 x
,�� 1 Sloe 0.077338462 Correlation 0.99911033
SAMPLE SAMP ug PER ALI in mL PREP ALI in mL RESULTS LESS THAN SPIKE
I.D. ABS ALIQUOT ANALYZED VOL in mL TAKEN ug/mL % SPK REC LEVEL
Std. B. 0.00 0.000 0.0000 10 10 10 < 0.0
Std. B. 1.00 0.090 0.8053 10 10 10 < 80.53% 1.0
Std. B. 2.50 0.223 1 2.5940 10 1 10 10 0.259 103.76% 2.5
Std. B. 5.00 0.425 1 5.3106 10 10 10 0.531 106.21 % 5.0
Std. B. 7.50 0.616 7.8793 10 10 10 0.788 105.06% 7.5
Std. B. 10.00 0.800 10.3538 10 10 10 1.035 103.54% 10.0
LRB 0.000 0.0000 10 10 10 < 0.0
LRB SPK 0.427 5.3375 10 10 10 0.534 107% 5.0
QC 0.420 5.2434 10 10 10 0.524 105% 5.0
25140-8 0.009-0.2840 10 10 10 <
25140-8 s k 0.301 3.6430 10 10 10 0.364 73% 5.0
o
25140-9 -0.001 0.0000 10 10 10 E g ,
25140-9 s k 0.429 5.3644 10 10 10 0.536 107% 5.0
25141-1 0.0201 -0.1361 10 10 10 <
25141-1 dup 0.019-0.1495 10 10 10 <
25141-1 s k 0.129 1.3298 10 10 10 0.133 27% 5.0
25141-2 0.006-0.3244 10 10 10
25141-2 s k 0.361 4.4499 10 10 10 0.445 89% 5.0
25141-3 0.0041 -0.3513 10 10 10j "
25141-3 s k 0.349 4.2885 10 10 10 0.429 86% 5.0
25141-4 -0.001 0.0000 10 10 10e�.:,``�„,;��
25141-4 s k 0.432 5.4047 10 10 10 0.540 108% 5.0
7: 7 r
25142-1 0.178 1.9888 10 10 10 09J
25142-1 spk 0.564 7.1799 10 10 10 0.718 104% 5.0
25142-2 0.002-0.3781 10 10 1010
�94�
25142-2 s k 0.345 4.2347 10 10 10 0.423 85% 5.0
25142-3 0.001-0.3916 10 10 10-pe
25142-3 s k 0.368 4.5440 10 10 10 0.454 91% 5.0
Blank 0.000 0.0000 10 10 10 1 <
QC 0.421 5.2568 10 10 1 10 1 0.526 105% 5.0
Submitted for QA/QC- Date: 06/22/15 By: (Print) I KAM (sign):
Page 3 of 5

Analytical Lab
Page 27 of 62
METHOD:
SM 4500 S2- D
ELEMENT ONE
ELEMENT ASSAY:
Sulfide
Spectrophotometer
Wave Length 664
UNITS OF ANSWER
ug/mL
DETECTION LIMIT u
1.000
CLIENT:
Duke
SPK LEVEL u
5
Lab ID#
25138/ 139/ 140/ 141/ 142/ 143
Na2S•9H2O Lot #
40721
MAX ALIQUOT
10.00
Date:
06/22/15
STANDARD conc(ppm)
X
Time Analysis Begun
12:00
Cal Std Lot: SD-10-3
10
Time Analysis Ended
16:00
QC Std Lot: SD-10-4
10
Analyst:
KAM
STD ABSORPTION
Y
X
Y
omo
ug STD
SOLUTION
STD
ABS
0eoo
0700
0.00
1.00
2.50
5.00
7.50
10.00
0.000
0.098
0.218
0.417
0.605
0.776
0=
Ob00
°°
0300
-°°
0.200
- i000
0100
0.00000 200 .M eoo 800 1000 1200
i
SAMPLE
I.D.
SAMP ug PER
ABS ALIQUOT
TALI in mL
ANALYZED
PREP
VOL in mL
Slope 0.077338462
ALI in mL RESULTS
TAKEN ug/mL
Correlation 0.99911033
LESS THAN SPIKE
% SPK REC LEVEL
Std. B. 0.00
0.000
0.0000
10
10
10
<
0.0
Std. B. 1.00
0.090
0.8053
10
10
10
<
80.53%
1.0
Std. B. 2.50
0.223
2.5940
10
10
10
0.259
103.76%
2.5
Std. B. 5.00
0.425
5.3106
10
10
10
0.531
106.21 %
5.0
Std. B. 7.50
0.616
7.8793
10
10
10
0.788
105.06%
7.5
Std. B. 10.00
0.800
10.3538
10
10
10
1.035
103.54%
10.0
LRB
0.000
0.0000
10
10
10
<
0.0
LRB SPK
0.427
5.3375
10
10
10
0.534
107%
5.0
QC
0.420
5.2434
10
10
10
0.524
105%
5.0
25143-1
0.007
-0.3109
10
10
10
25143-1 s k
0.381
4.7189
10
10
10
0.472
94%
5.0
25143-2
0.064
0.4557
10
1 10
10
<
25143-2 spk
0.467
5.8754
10
10
10
0.588
118%
5.0
25143-3
0.023
-0.0957
10
10
10.:
<�
25143-3 s k
0.351
4.3154
10
10
10
0.432
86%
5.0
25143-4
O.OD2
-0.3781
10
10
10
25143-4 dup
0.002
-0.3781
10
10
10
< 0.1
25143-4 s k
0.380
4.7054
10
10
10
0.471
94%
5.0
25143-5
0.000
0.0000
10
10
10
25143-5 s k
0.440
5.5123
10
10
10
0.551
110%
5.0
25140-7
0.012
-0.2437
10
10
10�0�`1
25140-7 s k
0.388
4.8130
10
10
10
0.481
96%
5.0
25138-3
0.014
-0.2168
10
10
5�,,,'-
25138-3 spk
0.450
5.6468
10
10
5
1.129
113%
5.0
25138-5
0.040
0.1329
10
10
5
<
25138-5 s k
0.460
5.7813
10
10
5
1.156
116%
5.0
25140-8
0.009
-0.2840
10
10
5
b n 3
25140-8 s k
0.355
4.3692
10
10
5
0.874
87%
5.0
Blank
0.000
0.0000
10
10
10
<
QC
0.419
5.2299
10
10
10
0.523
105%
5.0
Submitted for QA/QC-
Date: 06/22/15
By: (Print)
KAM
(sign): "
/,011
Page 4 of 5

Analytical Lab
Page 28 of 62
METHOD:
SM 4500 S2- D
ELEMENT ONE
ELEMENT ASSAY:
Sulfide
Spectrophotometer
Wave Length 664
UNITS OF ANSWER
ug/mL
DETECTION LIMIT u
1.000
CLIENT:
Duke
SPK LEVELLuM
5
Lab ID#
25138/ 139/ 140/ 141/ 142/ 143
Na2S•9H20 Lot #
40721
MAX ALIQUOT
10.00
Date:
06/22/15
STANDARD conc(ppm)
X
Time Analysis Begun
12:00
Cal Std Lot: SD-10-3
10
Time Analysis Ended
16:00
QC Std Lot: SD-10-4
10
Analyst:
KAM
STD ABSORPTION
Y
X
Y
o.�
ug STD
SOLUTION
STD
ABS
0"
0700
0.00
1.00
2.50
5.00
7.50
10.00
0.000
0,098
0.218
0.417
0.605
0.776
0.�
z�
0. °
°'°°
o.2DO
0+m
°° ow _w 4.00 ew 8.00 10.00 12M
SAMPLE
I.D.
SAMP
ABS
ug PER
ALIQUOT
ALI in mL
ANALYZED
PREP
VOL in mL
Sloe 0.077338462
ALI in mL RESULTS
TAKEN ug/mL
Correlation 0.9991`1033
LESS THAN SPIKE
% SPK REC LEVEL
Std. B. 0.00
0.000
0.0000
10
10
10
<
0.0
Std. B. 1.00
0.090
0.8053
10
10
10
<
80.53%
1.0
Std. B. 2.50
0.223
2.5940
10
10
10
0.259
103.76%
2.5
Std. B. 5.00
0.425
5.3106
10
10
10
0.531
106.21 %
5.0
Std. B. 7.50
0.616
7.8793
10
10
10
0.788
105.06%
7.5
Std. B. 10.00
0.800
10.3538
10
10
10
1.035
103.54%
10.0
LRB
0.000
0.0000
10
10
10
<
0.0
LRB SPK
0.427
5,3375
10
10
10
0.534
107%
5.0
QC
0.420
5.2434
10
10
10
0.524
105%
5.0
25141-1
0.066
0.4826
10
10
5
<
25141-1 dup
0.012
-0.2437
10
10
5
<
25141-1 s k
0.151
1.6257
10
10
5
0.325
33%
5.0
25143-2
0.037
0.0926
10
10
5
'Am . w;
25143-2 spk
0.440
5.5123
10
10
5
1.102
110%
5.0
25138-5
0.030
-0.0016
10
10
2
, . , 0.,a _ _ -
25138-5 s k
0.452
5.6737
10
10
2
2.837
113%
5.0
25141-1
0.009
-0.2840
10
10
2
<
25141-1 dup
0.024
-0.0823
10
10
2
<
25141-1 spk
0.295
3.5623
10
10
2
1.781
71%
6.0
25141-1
0.005
-0.3378
10
10
1
,: "R
25141-1 dup
0.003
-0.3647
10
10
1
< 1.0
25141-1 s k
0.357
4.3961
10
10
1
4.396
88%
5.0
Blank
0.000
0.0000
10
10
10
<
QC
0,419
5.2299
10
10
10
0.523
105%
5.0
Submitted for QA/QC-
Date: 06/22/15
By: (Print)
KAM (sign):
Page 5 of 5

SHEALY ENVIRONMENTAL SERVICES, INC.
Report of Analysis
Duke Energy
13339 Hagers Ferry Rd
Bldg 7405
Huntersville, NC 28078
Attention: Mary Ann Ogle
Project Name: AB GW Assessment Water - H F Lee
Project Number:J15060613
Lot Number:QF19030
Date Completed:06/28/2015
Grant Wilton
Project Manager
This report shall not be reproduced, except in its entirety, without the written approval of Shealy Environmental Services, Inc.
The following non -paginated documents are considered part of this report: Chain of Custody Record and Sample Receipt Checklist.
* QF1 9030*
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SHEALY ENVIRONMENTAL SERVICES, INC.
SC DHEC No: 32010 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
Case Narrative
Duke Energy
Lot Number: QF19030
Project Name: AB GW Assessment Water - H F Lee
Project Number: J15060613
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample
receiving date is documented in the header information associated with each sample.
All results listed in this report relate only to the samples that are contained within this report.
Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the
Shealy Environmental Services, Inc. ("Shealy") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPS), and Shealy
policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below.
If you have any questions regarding this report please contact the Shealy Project Manager listed on the cover page
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SHEALY ENVIRONMENTAL SERVICES, INC.
Sample Summary
Duke Energy
Lot Number: QF19030
Project Name: AB GW Assessment Water - H F Lee
Project Number: J15060613
Sample Number
Sample ID
Matrix
Date Sampled
Date Received
001
2015019923
Aqueous
06/16/2015 0953
06/19/2015
002
2015019924
Aqueous
06/16/20151244
06/19/2015
003
2015019925
Aqueous
06/16/2015 0919
06/19/2015
004
2015019926
Aqueous
06/16/20151025
06/19/2015
005
2015019927
Aqueous
06/16/20151110
06/19/2015
006
2015019928
Aqueous
06/16/2015 0830
06/19/2015
007
2015019929
Aqueous
06/16/2015 0925
06/19/2015
008
2015019946
Aqueous
06/16/2015 0745
06/19/2015
(8 samples)
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SHEALY ENVIRONMENTAL SERVICES, INC.
Executive Summary
Duke Energy
Lot Number: QF19030
Project Name: AB GW Assessment Water - H F Lee
Project Number: J15060613
Sample Sample ID
Matrix Parameter Method
Result Q
Units
Page
002
2015019924
Aqueous Methane RSK - 175
2800
ug/L
8
003
2015019925
Aqueous Alkalinity SM 2320B-
580
mg/L
9
003
2015019925
Aqueous Bicarbonate Alkalinity SM 2320B-
580
mg/L
9
003
2015019925
Aqueous Methane RSK - 175
560
ug/L
10
004
2015019926
Aqueous Alkalinity SM 2320B-
420
mg/L
11
004
2015019926
Aqueous Bicarbonate Alkalinity SM 2320B-
420
mg/L
11
004
2015019926
Aqueous Methane RSK - 175
210
ug/L
12
005
2015019927
Aqueous Alkalinity SM 2320B-
56
mg/L
13
005
2015019927
Aqueous Bicarbonate Alkalinity SM 2320B-
56
mg/L
13
005
2015019927
Aqueous Methane RSK - 175
280
ug/L
14
006
2015019928
Aqueous Alkalinity SM 2320B-
56
mg/L
15
006
2015019928
Aqueous Bicarbonate Alkalinity SM 2320B-
56
mg/L
15
007
2015019929
Aqueous Alkalinity SM 2320B-
84
mg/L
17
007
2015019929
Aqueous Bicarbonate Alkalinity SM 2320B-
84
mg/L
17
(14 detections)
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Inorganic non-metals
Client: Duke Energy Laboratory ID: QF19030-001
Description: 2015019923 Matrix: Aqueous
Date Sampled:06/16/2015 0953 Project Name: AB GW Assessment Water -
Date Received:06/19/2015 Project Number: J15060613
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 2320B-2011
1 06/24/2015 2234
HMA 77998
1
(Bicarbonate ) SM 2320B-2011
1 06/24/2015 2234
HMA
1
(Carbonate Al) SM 2320B-2011
1 06/24/2015 2234
HMA
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
ND
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Methane
Client: Duke Energy Laboratory ID: QF19030-001
Description: 2015019923 Matrix: Aqueous
Date Sampled:06/16/2015 0953 Project Name: AB GW Assessment Water -
Date Received:06/19/2015 Project Number: J15060613
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 06/25/2015 1902 JJG 78171
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Inorganic non-metals
Client: Duke Energy Laboratory ID: QF19030-002
Description: 2015019924 Matrix: Aqueous
Date Sampled:06/16/2015 1244 Project Name: AB GW Assessment Water -
Date Received:06/19/2015 Project Number: J15060613
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 2320B-2011
1 06/24/2015 2237
HMA 77998
1
(Bicarbonate ) SM 2320B-2011
1 06/24/2015 2237
HMA
1
(Carbonate Al) SM 2320B-2011
1 06/24/2015 2237
HMA
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
ND
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Methane
Client: Duke Energy Laboratory ID: QF19030-002
Description: 2015019924 Matrix: Aqueous
Date Sampled:06/16/2015 1244 Project Name: AB GW Assessment Water -
Date Received:06/19/2015 Project Number: J15060613
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
2 RSK - 175 20 06/26/2015 1210 DCS 78230
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 2800 200 ug/L 2
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Inorganic non-metals
Client: Duke Energy Laboratory ID: QF19030-003
Description: 2015019925 Matrix: Aqueous
Date Sampled:06/16/2015 0919 Project Name: AB GW Assessment Water -
Date Received:06/19/2015 Project Number: J15060613
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 2320B-2011
1 06/24/2015 2249
HMA 77998
1
(Bicarbonate ) SM 2320B-2011
1 06/24/2015 2249
HMA
1
(Carbonate Al) SM 2320B-2011
1 06/24/2015 2249
HMA
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
580
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
580
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Methane
Client: Duke Energy Laboratory ID: QF19030-003
Description: 2015019925 Matrix: Aqueous
Date Sampled:06/16/2015 0919 Project Name: AB GW Assessment Water -
Date Received:06/19/2015 Project Number: J15060613
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 06/25/2015 2105 JJG 78171
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 560 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Inorganic non-metals
Client: Duke Energy Laboratory ID: QF19030-004
Description: 2015019926 Matrix: Aqueous
Date Sampled:06/16/2015 1025 Project Name: AB GW Assessment Water -
Date Received:06/19/2015 Project Number: J15060613
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 2320B-2011
1 06/24/2015 2311
HMA 77998
1
(Bicarbonate ) SM 2320B-2011
1 06/24/2015 2311
HMA
1
(Carbonate Al) SM 2320B-2011
1 06/24/2015 2311
HMA
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
420
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
420
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Methane
Client: Duke Energy Laboratory ID: QF19030-004
Description: 2015019926 Matrix: Aqueous
Date Sampled:06/16/2015 1025 Project Name: AB GW Assessment Water -
Date Received:06/19/2015 Project Number: J15060613
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 06/25/2015 2117 JJG 78171
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 210 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Inorganic non-metals
Client: Duke Energy Laboratory ID: QF19030-005
Description: 2015019927 Matrix: Aqueous
Date Sampled:06/16/2015 1110 Project Name: AB GW Assessment Water -
Date Received:06/19/2015 Project Number: J15060613
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 2320B-2011
1 06/24/2015 2317
HMA 77998
1
(Bicarbonate ) SM 2320B-2011
1 06/24/2015 2317
HMA
1
(Carbonate Al) SM 2320B-2011
1 06/24/2015 2317
HMA
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
56
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
56
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Methane
Client: Duke Energy Laboratory ID: QF19030-005
Description: 2015019927 Matrix: Aqueous
Date Sampled:06/16/2015 1110 Project Name: AB GW Assessment Water -
Date Received:06/19/2015 Project Number: J15060613
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 06/25/2015 2129 JJG 78171
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 280 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Inorganic non-metals
Client: Duke Energy Laboratory ID: QF19030-006
Description: 2015019928 Matrix: Aqueous
Date Sampled:06/16/2015 0830 Project Name: AB GW Assessment Water -
Date Received:06/19/2015 Project Number: J15060613
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 2320B-2011
1 06/24/2015 2322
HMA 77998
1
(Bicarbonate ) SM 2320B-2011
1 06/24/2015 2322
HMA
1
(Carbonate Al) SM 2320B-2011
1 06/24/2015 2322
HMA
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
56
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
56
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Methane
Client: Duke Energy Laboratory ID: QF19030-006
Description: 2015019928 Matrix: Aqueous
Date Sampled:06/16/2015 0830 Project Name: AB GW Assessment Water -
Date Received:06/19/2015 Project Number: J15060613
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 06/25/2015 2148 JJG 78171
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 16 of 20
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Inorganic non-metals
Client: Duke Energy Laboratory ID: QF19030-007
Description: 2015019929 Matrix: Aqueous
Date Sampled:06/16/2015 0925 Project Name: AB GW Assessment Water -
Date Received:06/19/2015 Project Number: J15060613
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 2320B-2011
1 06/24/2015 2329
HMA 77998
1
(Bicarbonate ) SM 2320B-2011
1 06/24/2015 2329
HMA
1
(Carbonate Al) SM 2320B-2011
1 06/24/2015 2329
HMA
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
84
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
84
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Methane
Client: Duke Energy Laboratory ID: QF19030-007
Description: 2015019929 Matrix: Aqueous
Date Sampled:06/16/2015 0925 Project Name: AB GW Assessment Water -
Date Received:06/19/2015 Project Number: J15060613
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 06/25/2015 2159 JJG 78171
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 18 of 20
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Inorganic non-metals
Client: Duke Energy Laboratory ID: QF19030-008
Description: 2015019946 Matrix: Aqueous
Date Sampled:06/16/2015 0745 Project Name: AB GW Assessment Water -
Date Received:06/19/2015 Project Number: J15060613
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 2320B-2011
1 06/24/2015 2336
HMA 77998
1
(Bicarbonate ) SM 2320B-2011
1 06/24/2015 2336
HMA
1
(Carbonate Al) SM 2320B-2011
1 06/24/2015 2336
HMA
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
ND
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Methane
Client: Duke Energy Laboratory ID: QF19030-008
Description: 2015019946 Matrix: Aqueous
Date Sampled:06/16/2015 0745 Project Name: AB GW Assessment Water -
Date Received:06/19/2015 Project Number: J15060613
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 06/25/2015 2210 JJG 78171
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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QC Summary
Shealy Environmental Services, Inc. QC Data for Lot Number: QF19030
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals - MB
Sample ID: QQ77998-001 Matrix: Aqueous
Batch:77998
Analytical Method: SM 2320B-2011
Parameter Result Q Dil PQL Units Analysis Date
Alkalinity ND 1 10 mg/L 06/24/2015 2151
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QF19030
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals - LCS
Sample ID: QQ77998-002 Matrix: Aqueous
Batch:77998
Analytical Method: SM 2320B-2011
Spike
Amount Result % Rec
Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Alkalinity 100 100 1 100 90-110 06/24/2015 2157
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QF19030
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals - MS
Sample ID: QF19030-008MS Matrix: Aqueous
Batch:77998
Analytical Method: SM 2320B-2011
Sample Spike
Amount Amount Result % Rec
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Alkalinity ND 100 95 1 95 70-130 06/24/2015 2341
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QF19030
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals - MSD
Sample ID: QF19030-008MD Matrix: Aqueous
Batch:77998
Analytical Method: SM 2320B-2011
Sample Spike
Amount Amount Result % Rec % RPD
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date
Alkalinity ND 100 94 1 94 0.49 70-130 20 06/24/2015 2347
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QF19030
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane - MB
Sample ID: QQ78171-001 Matrix: Aqueous
Batch:78171
Analytical Method: RSK - 175
Parameter Result Q Dil PQL Units Analysis Date
Methane ND 1 10 ug/L 06/25/20151606
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QF19030
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane - LCS
Sample ID: QQ78171-002 Matrix: Aqueous
Batch:78171
Analytical Method: RSK - 175
Spike
Amount Result % Rec
Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date
Methane 150 110 1 73 70-130 06/25/20151504
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QF19030
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane - LCSD
Sample ID: QQ78171-003 Matrix: Aqueous
Batch:78171
Analytical Method: RSK - 175
Spike
Amount Result % Rec % RPD
Parameter (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date
Methane 150 120 1 76 3.9 70-130 30 06/25/20151516
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QF19030
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane - MB
Sample ID: QQ78230-001 Matrix: Aqueous
Batch:78230
Analytical Method: RSK - 175
Parameter Result Q Dil PQL Units Analysis Date
Methane ND 1 10 ug/L 06/26/2015 0927
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QF19030
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane - LCS
Sample ID: QQ78230-002 Matrix: Aqueous
Batch:78230
Analytical Method: RSK - 175
Spike
Amount Result % Rec
Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date
Methane 150 110 1 73 70-130 06/26/2015 0858
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QF19030
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane - LCSD
Sample ID: QQ78230-003 Matrix: Aqueous
Batch:78230
Analytical Method: RSK - 175
Spike
Amount Result % Rec % RPD
Parameter (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date
Methane 150 110 1 73 0.13 70-130 30 06/26/2015 0912
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QF19030
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

SHEALY ENVIRONMENTAL SERVICES, INC
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Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

SHEALY ENVIRONMENTAL SERVICES, INC.
Shz*EnrlrocnKnmil S icex: PU& 1 Ur t
Documul. Npmtwi F-AL416 kglaczi Bare! I IM 14
Rrui3iuo sludib'LL= 17 Effxlive No: O 30/1.5
Sample-eeeipt Cbcckfist (3RC)
C1imt; - Cooler Inspeettd Lot #,
Jh'letuta of receipt, Q SES] ❑ Clirnt ❑ UPS ❑ Fedl x [ ,AirhorneExp 0thcr
Ycs ❑ I Nc
1. Were GUSWY seals Present on the cooler'?
Yes No
LJ
I NA
2, If custody sells wum gent, were they intact and unbroken?
Clouler 1D?Qrig,iaaJ to aperature upon receiptT)erivecl (correc'ted) temperature upon receipt: op+
k.n rz.I,, 1V cif I _ I _ __"C f 11 4
,N] ethod= ❑ Te niperattuc Plmk a Again:att Bottles IR Gun ID: IR Gun Corrmotiem Factor: D .b £"C
lftraod of coolad. ct Iee ❑ Blue ice ❑ Dry Ioe ❑ None
Vic. ❑
NL3 ❑
N
I if tamperature of ozy choler exceeded &01C, was Project Manager natiified?
PM notified by SRC, phone, note (circle one), other,
(For oaolers roc d ved via commercial ccorier, FMr, are to he nntified
immediately.)
Yes
NU ❑
N-&
4" is the commercial courier's packing dip attached to this fordo?
Yes
Nn ❑
5" Wcac proper custudy procedures ref' isboVreceived followed?"
'des
NO
NAZ
5A V4'ere $a m lea reltn niched clicat to cDmmerctal CUL'',F4 r?
Yea
Z
No ❑
6, Wize r4mo le ]D% listed on the COC?
Yes
NU
7. Were le X)s listed on all sa ]c ct+nlain tz_?
Y+
Nei ❑
8" Was collrxtion date & time listed on the CUC?
Yes
No ❑
9" Way collection date & time listed on all earn lc contairv-Ts?
Yes
i
No ❑
10. Dirt all container label information (1p date timmC a with the C QC7
Yes
No ❑
11, Were teM to be perforined listed on tier. COO!:'
3fes
No ❑
12. Did all sample-; arr;ve in the prDper cL)nluincrs 1br ea& test?
yer,
7
NO ❑
13, Nd all containers arrive in g2od cmdiiion unbro.iren, lids on, etc,
Yes
2r
No ❑
14, Was ad iat+c sample volkimc available?
Yes ❑
No
155. 'Were all samples rcccivcd within 1/1 the holding time or 46 hours, whicbever
Gomm first's
16. W= any same Ies containers a►isain ?
Yes M
0
Yes ❑
Nn
17. Were there any excess Sam es not listed an ccxG'!
Yes ❑
No
i�_ ❑
18. = bubble1c seikt " -size' (!4 or fimm in dlaffiGter)in aily VaA viaals'f?
Yes Ll
No J
NAU
19. Were all MetaW0&t1I133;14i,`nuthMt samples Maiverl at a P11 of-1?
..
Yes ❑
No ❑
NA
20. Were all cyanidc andior sulfide samples r eived at a H > 12?
Yee ❑
No C]
NA
21. Were all applicable NH3aKN/eyanide.+p o1(0,2mg/L) samples free of
residual chlorine?
Y77
77
PEA El
22. Wem collection temperaNres documented on the 00C± for tiC writ lea?
❑
No ❑
N,%L.
1
23. Were clieslt rcnmrk%'rcelucsts (i.a. rcqueste�d dilutions, MSl14ISD designEtions,
eta,„)oorrectl transcribed from the bC" into the ocrrment section inL1-iS'
�es
es
No 2r
1 24. Was the quotc numbier used taken ftom the comer late]'?
Sample Preservatiiox (Must be couVlete'd fbrany sample(s) into redly Mserved or with he•adspacc,)
sample($Jl were received micorre ly preserved and were 4usled
accordingly in sam 1e, roccivim wi III (H2S0* 03 HCl Na0H) using SR #
Samplc s were received with bubb] es >6 mm in dialindex.
S 0 WP lets) w= received with TRC >0,2 m "L 1# #21 is No
9C: D inking Wader Prefect Samples) pi! verified to bo> 2 by Date:
Sample & Were not mvvcd at a EH of <2 w d were adjusted acrardiUly using SRC
Sam le labels a lkd by; Verified b .; Datc. q
Comments;
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

_ _ _ CHAIN OF CUSTODY RECORD CAMP +DNA. '�5Pq R!'Qi_IEST FORM
_..duke ErT ee f'gy--'-'- UxMF€ rYY MiIS ii t> •�rahory -~I �. .._�_._.—-------- . _ _..Amlpucal Ubcrablre U5* 00, _......... — ........ _—.'--'_
r.`sr®uy4p IStAaNq neat , ...- Martrlx G'W�YfW a.a .a+r ar. tiC!
4e Wn e L'
i Ladtioralory Otabta W+, p — afl
hiIM1�- Hv�r R. „9��{ � ItC. mum
S"i*4 PTWIW w ,1�nd�Iil 0:4 Tk�reF.. axr,rl,IF ataa�AJUA1
FaAw dit W81r _— ......... _.l �'f f 'J t-.:�r�:i M.xi.r rs•iil
AD GVV Aaaoa ward WOW ft: � � Ian rhr w.rt: � Wr. r _
[sxol[sA_ aura- _. ^_. fq
CIIirMI . _.+
900�6735=I ._
1 { � Shealy FII1asGrfn 10,44 ulrtj' lk Unflttored
m�aatlrir. "`�."' a"s P01142089 proser5.t
MG03A3 ° Ge+rtajw Vohenn ImL) 20W 40 ml 70 - in wo NO
rnrcv- amp: ,3uS1 t.n C mminor Type PET glass PET FLT POT m
FletTiLail't
a�aap]C [ oscriplian taT ID P01142133
•Irrr.aprlyea nan �
�aPS Lp��liam Gaifcetian IMerrcrtran gpry} '}jC � i � � c , a l
% 1 $ 1 1 1 1
Pa 7!3
r ,I
Filter Blank
Euipmont Blank
_ L—Twn I._'1 1 z 4 1 2 1 2
r to jjW do bolo,
IJ} {,��,/p tirlblgrF "
11aMir3nr
L_, frr
--coftnmw Am"
-- o k U d py i Dabajrim
ELEMENT$ by 1CP_M6 (TRW: AS. @o. Gad, Co, Cf. . CU, W, K Pb, St• se,. ri JLLI, V.[LL1
ELEMENTS ar 10P ITRM): Al. Do, W Fe. MrL Sr, 2m NL'R UndWe6tsd Ca, lip, K. Me Hq pY 2A&I
tftsalMsd mdals : a41 rnkt,N IC,P, JM5,Hg
ME
Analytical Lab
Page 62 of 62
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