NC0003417_J15060451report_20150805

DUE Analytical Laboratory
ENERGY
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone:[phone] Fax:[phone]
Order Summary Report
Order Number: J15060451
Project Name: HF LEE PLANT - AB GW ASSESSMENT WATER
Customer Name(s): Tim Hunsucker, Judd Mahan, Kathy Webb, John Toepfer
Customer Address: 1677 Old Smithfield Rd
Goldsboro NC 27530,
Lab Contact: Mary Ann Ogle Phone: [phone]
Mary Ann Ogle
Report Authorized By: % "� 2015.06.27 12:34:2(Date:
(Signature)-04'00'
Mary Ann Ogle
Program Comments:
Please contact the Program Manager (Mary Ann Ogle) with any questions regarding this report.
Data Flags & Calculations:
6/27/2015
Analytical Lab
Page 1 of 49
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Sample ID's & Descriptions:
Collection
Sample ID Plant/Station Date and Time
2015019121
2015019122
2015019123
2015019124
2015019125
2015019126
2015019127
7 Total Samples
Collected By
Sample Description
HF LEE PLANT
12-Jun-15 9:00 AM
ILLEGIBLE
IMW-1S
HF LEE PLANT
12-Jun-15 8:35 AM
ILLEGIBLE
IMW-1BC
HF LEE PLANT
12-Jun-15 12:35 PM
ILLEGIBLE
IMW-2BC
HF LEE PLANT
12-Jun-15 12:49 PM
ILLEGIBLE
SMW-3
HF LEE PLANT
12-Jun-15 10:20 AM
ILLEGIBLE
DMW-3
HF LEE PLANT
12-Jun-15 9:46 AM
ILLEGIBLE
Filter Blank
HF LEE PLANT
12-Jun-15 9:46 AM
ILLEGIBLE
Equipment Blank
Analytical Lab
Page 2 of 49

Analytical Lab
Page 3 of 49
Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals 0 Yes ❑ No
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits. ❑ Yes 0 No
All laboratory QA/QC requirements are acceptable. 0 Yes ❑ No
Report Sections Included:
E%-'] Job Summary Report
❑� Sample Identification
Technical Validation of Data Package
❑� Analytical Laboratory Certificate of Analysis
❑ Analytical Laboratory QC Report
❑d Sub -contracted Laboratory Results
❑ Customer Specific Data Sheets, Reports, & Documentation
❑ Customer Database Entries
❑� Chain of Custody
❑� Electronic Data Deliverable (EDD) Sent Separately
Reviewed By: Mary Ann Ogle Date: 6/27/2015

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060451
Site: IMW-1 S
Collection Date: 12-Jun-15 9:00 AM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter
Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)
3.2
mg-N/L
B2 0.05
INORGANIC IONS BY IC
Chloride
18
mg/L
1
Sulfate
25
mg/L
1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
0.033
mg/L
0.005
Barium (Ba)
0.208
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
2.09
mg/L
0.01
Manganese (Mn)
0.217
mg/L
0.005
Strontium (Sr)
0.122
mg/L
0.005
Zinc (Zn)
0.033
mg/L
0.005
UNDIGESTED METALS BY lCP
Calcium (Ca)
9.73
mg/L
0.01
Magnesium (Mg)
6.55
mg/L
0.005
Potassium (K)
1.72
mg/L
0.1
Sodium (Na)
7.80
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.070
mg/L
0.005
Barium (Ba)
0.206
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
2.23
mg/L
0.01
Manganese (Mn)
0.234
mg/L
0.005
Strontium (Sr)
0.123
mg/L
0.005
Zinc (Zn)
0.077
mg/L
0.005
Sample #: 2015019121
Matrix: GW WW
Analytical Lab
Page 4 of 49
DF Method Analysis Date/Time Analyst
Vendor Method
V_SHEALY
5
EPA 353.2
06/23/2015 14:02
LSTARLI
10
EPA 300.0
06/17/2015 20:19
BGN9034
10
EPA 300.0
06/17/2015 20:19
BGN9034
1
EPA 245.1
06/16/2015 16:26
ACPAYNE
1
EPA 245.1
06/18/2015 13:33
ACPAYNE
1
EPA 200.7
06/18/2015 11:05
MHALL3
1
EPA 200.7
06/18/2015 11:05
MHALL3
1
EPA 200.7
06/18/2015 11:05
MHALL3
1
EPA 200.7
06/18/2015 11:05
MHALL3
1
EPA 200.7
06/18/2015 11:05
MHALL3
1
EPA 200.7
06/18/2015 11:05
MHALL3
1
EPA 200.7
06/18/2015 11:05
MHALL3
1
EPA 200.7
06/19/2015 10:26
MHALL3
1
EPA 200.7
06/19/2015 10:26
MHALL3
1
EPA 200.7
06/19/2015 10:26
MHALL3
1
EPA 200.7
06/19/2015 10:26
MHALL3
1
EPA 200.7
06/17/2015 14:31
MHALL3
1
EPA 200.7
06/17/2015 14:31
MHALL3
1
EPA 200.7
06/17/2015 14:31
MHALL3
1
EPA 200.7
06/17/2015 14:31
MHALL3
1
EPA 200.7
06/17/2015 14:31
MHALL3
1
EPA 200.7
06/17/2015 14:31
MHALL3
1
EPA 200.7
06/17/2015 14:31
MHALL3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060451
Site: IMW-1 S
Collection Date: 12-Jun-15 9:00 AM
Analyte Result Units Qualifiers RDL
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
4.27
ug/L
1
Copper (Cu)
13.0
ug/L
1
Lead (Pb)
1.71
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
3.84
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
4.36
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
3.61
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
110
mg/L
25
Total Carbon
TOC
1.0
mg/L
0.1
TOTAL SUSPENDED SOLIDS
TSS
< 5
mg/L
5
Sample #: 2015019121
Matrix: GW WW
Analytical Lab
Page 5 of 49
DF
Method
Analysis Date/Time
Analyst
1
EPA 200.8
06/23/2015 01:43
SLS2560
1
EPA 200.8
06/23/2015 01:43
SLS2560
1
EPA 200.8
06/23/2015 01:43
SLS2560
1
EPA 200.8
06/23/2015 01:43
SLS2560
1
EPA 200.8
06/23/2015 01:43
SLS2560
1
EPA 200.8
06/23/2015 01:43
SLS2560
1
EPA 200.8
06/23/2015 01:43
SLS2560
1
EPA 200.8
06/23/2015 01:43
SLS2560
1
EPA 200.8
06/23/2015 01:43
SLS2560
1
EPA 200.8
06/23/2015 01:43
SLS2560
1
EPA 200.8
06/23/2015 01:43
SLS2560
1
EPA 200.8
06/23/2015 01:43
SLS2560
1
EPA 200.8
06/23/2015 01:43
SLS2560
1
EPA 200.8
06/22/2015 13:51
SLS2560
1
EPA 200.8
06/22/2015 13:51
SLS2560
1
EPA 200.8
06/22/2015 13:51
SLS2560
1
EPA 200.8
06/22/2015 13:51
SLS2560
1
EPA 200.8
06/22/2015 13:51
SLS2560
1
EPA 200.8
06/22/2015 13:51
SLS2560
1
EPA 200.8
06/22/2015 13:51
SLS2560
1
EPA 200.8
06/22/2015 13:51
SLS2560
1
EPA 200.8
06/22/2015 13:51
SLS2560
1
EPA 200.8
06/22/2015 13:51
SLS2560
1
EPA 200.8
06/22/2015 13:51
SLS2560
1
EPA 200.8
06/22/2015 13:51
SLS2560
1
EPA 200.8
06/22/2015 13:51
SLS2560
Vendor Method
V_SHEALY
Vendor Method V_ELE1
1 SM2540C 06/16/201515:52 AGIBBS5
1 SM5310C/EPA9060A 06/25/201512:17 GHUTCHI
1 SM2540D 06/16/2015 08:20 AGIBBS5

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060451
Site: IMW-1 BC
Collection Date: 12-Jun-15 8:35 AM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter
Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)
0.064
mg-N/L
B2 0.01
INORGANIC IONS BY IC
Chloride
70
mg/L
1
Sulfate
20
mg/L
1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
0.096
mg/L
0.005
Boron (B)
0.166
mg/L
0.05
Iron (Fe)
0.016
mg/L
0.01
Manganese (Mn)
0.066
mg/L
0.005
Strontium (Sr)
0.110
mg/L
0.005
Zinc (Zn)
0.021
mg/L
0.005
UNDIGESTED METALS BY lCP
Calcium (Ca)
17.3
mg/L
0.01
Magnesium (Mg)
3.52
mg/L
0.005
Potassium (K)
2.44
mg/L
0.1
Sodium (Na)
62.5
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.014
mg/L
0.005
Barium (Ba)
0.101
mg/L
0.005
Boron (B)
0.171
mg/L
0.05
Iron (Fe)
0.098
mg/L
0.01
Manganese (Mn)
0.066
mg/L
0.005
Strontium (Sr)
0.113
mg/L
0.005
Zinc (Zn)
0.007
mg/L
0.005
Sample #: 2015019122
Matrix: GW WW
Analytical Lab
Page 6 of 49
DF Method Analysis Date/Time Analyst
Vendor Method
V_SHEALY
1
EPA 353.2
06/23/2015 13:56
LSTARLI
10
EPA 300.0
06/17/2015 21:08
BGN9034
10
EPA 300.0
06/17/2015 21:08
BGN9034
1
EPA 245.1
06/16/2015 16:29
ACPAYNE
1
EPA 245.1
06/18/2015 13:40
ACPAYNE
1
EPA 200.7
06/18/2015 11:16
MHALL3
1
EPA 200.7
06/18/2015 11:16
MHALL3
1
EPA 200.7
06/18/2015 11:16
MHALL3
1
EPA 200.7
06/18/2015 11:16
MHALL3
1
EPA 200.7
06/18/2015 11:16
MHALL3
1
EPA 200.7
06/18/2015 11:16
MHALL3
1
EPA 200.7
06/18/2015 11:16
MHALL3
1
EPA 200.7
06/19/2015 11:49
MHALL3
1
EPA 200.7
06/19/2015 11:49
MHALL3
1
EPA 200.7
06/19/2015 11:49
MHALL3
1
EPA 200.7
06/19/2015 11:49
MHALL3
1
EPA 200.7
06/17/2015 14:43
MHALL3
1
EPA 200.7
06/17/2015 14:43
MHALL3
1
EPA 200.7
06/17/2015 14:43
MHALL3
1
EPA 200.7
06/17/2015 14:43
MHALL3
1
EPA 200.7
06/17/2015 14:43
MHALL3
1
EPA 200.7
06/17/2015 14:43
MHALL3
1
EPA 200.7
06/17/2015 14:43
MHALL3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060451
Site: IMW-1 BC
Collection Date: 12-Jun-15 8:35 AM
Analyte
Result
Units Qualifiers
RDL
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
12.9
ug/L
1
Lead (Pb)
1.62
ug/L
1
Molybdenum (Mo)
3.71
ug/L
1
Nickel (Ni)
2.62
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
3.74
ug/L
1
Nickel (Ni)
2.25
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
230
mg/L
25
Total Carbon
TOC
0.508
mg/L
0.1
TOTAL SUSPENDED SOLIDS
TSS
< 5
mg/L
5
Sample #: 2015019122
Matrix: GW WW
Analytical Lab
Page 7 of 49
DF
Method
Analysis Date/Time
Analyst
1
EPA 200.8
06/23/2015 01:50
SLS2560
1
EPA 200.8
06/23/2015 01:50
SLS2560
1
EPA 200.8
06/23/2015 01:50
SLS2560
1
EPA 200.8
06/23/2015 01:50
SLS2560
1
EPA 200.8
06/23/2015 01:50
SLS2560
1
EPA 200.8
06/23/2015 01:50
SLS2560
1
EPA 200.8
06/23/2015 01:50
SLS2560
1
EPA 200.8
06/23/2015 01:50
SLS2560
1
EPA 200.8
06/23/2015 01:50
SLS2560
1
EPA 200.8
06/23/2015 01:50
SLS2560
1
EPA 200.8
06/23/2015 01:50
SLS2560
1
EPA 200.8
06/23/2015 01:50
SLS2560
1
EPA 200.8
06/23/2015 01:50
SLS2560
1
EPA 200.8
06/22/2015 13:30
SLS2560
1
EPA 200.8
06/22/2015 13:30
SLS2560
1
EPA 200.8
06/22/2015 13:30
SLS2560
1
EPA 200.8
06/22/2015 13:30
SLS2560
1
EPA 200.8
06/22/2015 13:30
SLS2560
1
EPA 200.8
06/22/2015 13:30
SLS2560
1
EPA 200.8
06/22/2015 13:30
SLS2560
1
EPA 200.8
06/22/2015 13:30
SLS2560
1
EPA 200.8
06/22/2015 13:30
SLS2560
1
EPA 200.8
06/22/2015 13:30
SLS2560
1
EPA 200.8
06/22/2015 13:30
SLS2560
1
EPA 200.8
06/22/2015 13:30
SLS2560
1
EPA 200.8
06/22/2015 13:30
SLS2560
Vendor Method
V_SHEALY
Vendor Method V_ELE1
1 SM2540C 06/16/201515:52 AGIBBS5
1 SM5310C/EPA9060A 06/25/201512:17 GHUTCHI
1 SM2540D 06/16/2015 08:20 AGIBBS5

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060451
Site: IMW-2BC
Collection Date: 12-Jun-15 12:35 PM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter
Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)
0.023
mg-N/L
B2 0.01
INORGANIC IONS BY IC
Chloride
69
mg/L
1
Sulfate
8.6
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
0.018
mg/L
0.005
Barium (Ba)
0.037
mg/L
0.005
Boron (B)
0.337
mg/L
0.05
Iron (Fe)
0.080
mg/L
0.01
Manganese (Mn)
0.047
mg/L
0.005
Strontium (Sr)
0.126
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
UNDIGESTED METALS BY lCP
Calcium (Ca)
16.0
mg/L
0.1
Magnesium (Mg)
4.86
mg/L
0.05
Potassium (K)
3.85
mg/L
1
Sodium (Na)
101
mg/L
0.5
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.410
mg/L
0.005
Barium (Ba)
0.039
mg/L
0.005
Boron (B)
0.331
mg/L
0.05
Iron (Fe)
0.771
mg/L
0.01
Manganese (Mn)
0.050
mg/L
0.005
Strontium (Sr)
0.129
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Sample #: 2015019123
Matrix: GW WW
Analytical Lab
Page 8 of 49
DF Method Analysis Date/Time Analyst
Vendor Method
V_SHEALY
1
EPA 353.2
06/23/2015 13:58
LSTARLI
10
EPA 300.0
06/17/2015 23:52
BGN9034
1
EPA 300.0
06/17/2015 23:52
BGN9034
1
EPA 245.1
06/16/2015 16:31
ACPAYNE
1
EPA 245.1
06/18/2015 13:42
ACPAYNE
1
EPA 200.7
06/18/2015 11:28
MHALL3
1
EPA 200.7
06/18/2015 11:28
MHALL3
1
EPA 200.7
06/18/2015 11:28
MHALL3
1
EPA 200.7
06/18/2015 11:28
MHALL3
1
EPA 200.7
06/18/2015 11:28
MHALL3
1
EPA 200.7
06/18/2015 11:28
MHALL3
1
EPA 200.7
06/18/2015 11:28
MHALL3
10
EPA 200.7
06/19/2015 10:56
MHALL3
10
EPA 200.7
06/19/2015 10:56
MHALL3
10
EPA 200.7
06/19/2015 10:56
MHALL3
10
EPA 200.7
06/19/2015 10:56
MHALL3
1
EPA 200.7
06/17/2015 14:46
MHALL3
1
EPA 200.7
06/17/2015 14:46
MHALL3
1
EPA 200.7
06/17/2015 14:46
MHALL3
1
EPA 200.7
06/17/2015 14:46
MHALL3
1
EPA 200.7
06/17/2015 14:46
MHALL3
1
EPA 200.7
06/17/2015 14:46
MHALL3
1
EPA 200.7
06/17/2015 14:46
MHALL3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060451
Site: IMW-2BC
Collection Date: 12-Jun-15 12:35 PM
Analyte Result Units Qualifiers RDL
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
1.81
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
29.3
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
2.21
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
30.3
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
0.629
ug/L
0.3
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
350
mg/L
25
Total Carbon
TOC
3.1
mg/L
0.1
TOTAL SUSPENDED SOLIDS
TSS
11
mg/L
5
Sample #: 2015019123
Matrix: GW WW
Analytical Lab
Page 9 of 49
DF
Method
Analysis Date/Time
Analyst
1
EPA 200.8
06/23/2015 01:21
SLS2560
1
EPA 200.8
06/23/2015 01:21
SLS2560
1
EPA 200.8
06/23/2015 01:21
SLS2560
1
EPA 200.8
06/23/2015 01:21
SLS2560
1
EPA 200.8
06/23/2015 01:21
SLS2560
1
EPA 200.8
06/23/2015 01:21
SLS2560
1
EPA 200.8
06/23/2015 01:21
SLS2560
1
EPA 200.8
06/23/2015 01:21
SLS2560
1
EPA 200.8
06/23/2015 01:21
SLS2560
1
EPA 200.8
06/23/2015 01:21
SLS2560
1
EPA 200.8
06/23/2015 01:21
SLS2560
1
EPA 200.8
06/23/2015 01:21
SLS2560
1
EPA 200.8
06/23/2015 01:21
SLS2560
1
EPA 200.8
06/22/2015 13:59
SLS2560
1
EPA 200.8
06/22/2015 13:59
SLS2560
1
EPA 200.8
06/22/2015 13:59
SLS2560
1
EPA 200.8
06/22/2015 13:59
SLS2560
1
EPA 200.8
06/22/2015 13:59
SLS2560
1
EPA 200.8
06/22/2015 13:59
SLS2560
1
EPA 200.8
06/22/2015 13:59
SLS2560
1
EPA 200.8
06/22/2015 13:59
SLS2560
1
EPA 200.8
06/22/2015 13:59
SLS2560
1
EPA 200.8
06/22/2015 13:59
SLS2560
1
EPA 200.8
06/22/2015 13:59
SLS2560
1
EPA 200.8
06/22/2015 13:59
SLS2560
1
EPA 200.8
06/22/2015 13:59
SLS2560
Vendor Method
V_SHEALY
Vendor Method V_ELE1
1 SM2540C 06/16/201515:52 AGIBBS5
1 SM5310C/EPA9060A 06/25/201512:17 GHUTCHI
1 SM2540D 06/16/2015 08:20 AGIBBS5

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060451
Site: SMW-3
Collection Date: 12-Jun-15 12:49 PM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter
Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)
< 0.01
mg-N/L
B2 0.01
INORGANIC IONS BY IC
Chloride
18
mg/L
1
Sulfate
18
mg/L
1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
0.031
mg/L
0.005
Barium (Ba)
0.048
mg/L
0.005
Boron (B)
0.082
mg/L
0.05
Iron (Fe)
13.4
mg/L
0.01
Manganese (Mn)
3.00
mg/L
0.005
Strontium (Sr)
0.092
mg/L
0.005
Zinc (Zn)
0.020
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
11.5
mg/L
0.01
Magnesium (Mg)
8.85
mg/L
0.005
Potassium (K)
0.585
mg/L
0.1
Sodium (Na)
14.9
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.078
mg/L
0.005
Barium (Ba)
0.050
mg/L
0.005
Boron (B)
0.090
mg/L
0.05
Iron (Fe)
13.7
mg/L
0.01
Manganese (Mn)
2.76
mg/L
0.005
Strontium (Sr)
0.090
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Sample #: 2015019124
Matrix: GW WW
Analytical Lab
Page 10 of 49
DF Method Analysis Date/Time Analyst
Vendor Method
V_SHEALY
1
EPA 353.2
06/23/2015 13:59
LSTARLI
10
EPA 300.0
06/17/2015 21:41
BGN9034
10
EPA 300.0
06/17/2015 21:41
BGN9034
1
EPA 245.1
06/16/2015 16:33
ACPAYNE
1
EPA 245.1
06/18/2015 13:44
ACPAYNE
1
EPA 200.7
06/18/2015 13:36
MHALL3
1
EPA 200.7
06/18/2015 13:36
MHALL3
1
EPA 200.7
06/18/2015 13:36
MHALL3
1
EPA 200.7
06/18/2015 13:36
MHALL3
1
EPA 200.7
06/18/2015 13:36
MHALL3
1
EPA 200.7
06/18/2015 13:36
MHALL3
1
EPA 200.7
06/18/2015 13:36
MHALL3
1
EPA 200.7
06/19/2015 11:57
MHALL3
1
EPA 200.7
06/19/2015 11:57
MHALL3
1
EPA 200.7
06/19/2015 11:57
MHALL3
1
EPA 200.7
06/19/2015 11:57
MHALL3
1
EPA 200.7
06/17/2015 14:50
MHALL3
1
EPA 200.7
06/17/2015 14:50
MHALL3
1
EPA 200.7
06/17/2015 14:50
MHALL3
1
EPA 200.7
06/17/2015 14:50
MHALL3
1
EPA 200.7
06/17/2015 14:50
MHALL3
1
EPA 200.7
06/17/2015 14:50
MHALL3
1
EPA 200.7
06/17/2015 14:50
MHALL3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060451
Site: SMW-3
Collection Date: 12-Jun-15 12:49 PM
Analyte Result Units Qualifiers RDL
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
55.2
ug/L
1
Copper (Cu)
1.14
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
8.11
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
0.350
ug/L
0.3
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
56.4
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
8.99
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
0.323
ug/L
0.3
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
150
mg/L
25
Total Carbon
TOC
1.4
mg/L
0.1
TOTAL SUSPENDED SOLIDS
TSS
< 5
mg/L
5
Sample #: 2015019124
Matrix: GW WW
Analytical Lab
Page 11 of 49
DF
Method
Analysis Date/Time
Analyst
1
EPA 200.8
06/23/2015 01:57
SLS2560
1
EPA 200.8
06/23/2015 01:57
SLS2560
1
EPA 200.8
06/23/2015 01:57
SLS2560
1
EPA 200.8
06/23/2015 01:57
SLS2560
1
EPA 200.8
06/23/2015 01:57
SLS2560
1
EPA 200.8
06/23/2015 01:57
SLS2560
1
EPA 200.8
06/23/2015 01:57
SLS2560
1
EPA 200.8
06/23/2015 01:57
SLS2560
1
EPA 200.8
06/23/2015 01:57
SLS2560
1
EPA 200.8
06/23/2015 01:57
SLS2560
1
EPA 200.8
06/23/2015 01:57
SLS2560
1
EPA 200.8
06/23/2015 01:57
SLS2560
1
EPA 200.8
06/23/2015 01:57
SLS2560
1
EPA 200.8
06/22/2015 14:06
SLS2560
1
EPA 200.8
06/22/2015 14:06
SLS2560
1
EPA 200.8
06/22/2015 14:06
SLS2560
1
EPA 200.8
06/22/2015 14:06
SLS2560
1
EPA 200.8
06/22/2015 14:06
SLS2560
1
EPA 200.8
06/22/2015 14:06
SLS2560
1
EPA 200.8
06/22/2015 14:06
SLS2560
1
EPA 200.8
06/22/2015 14:06
SLS2560
1
EPA 200.8
06/22/2015 14:06
SLS2560
1
EPA 200.8
06/22/2015 14:06
SLS2560
1
EPA 200.8
06/22/2015 14:06
SLS2560
1
EPA 200.8
06/22/2015 14:06
SLS2560
1
EPA 200.8
06/22/2015 14:06
SLS2560
Vendor Method
V_SHEALY
Vendor Method V_ELE1
1 SM2540C 06/16/201515:52 AGIBBS5
1 SM5310C/EPA9060A 06/25/201512:17 GHUTCHI
1 SM2540D 06/16/2015 08:20 AGIBBS5

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060451
Site: DMW-3
Collection Date: 12-Jun-15 10:20 AM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter
Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)
< 0.01
mg-N/L
B2 0.01
INORGANIC IONS BY IC
Chloride
6.8
mg/L
0.1
Sulfate
46
mg/L
1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
0.091
mg/L
0.005
Barium (Ba)
0.066
mg/L
0.005
Boron (B)
0.154
mg/L
0.05
Iron (Fe)
48.2
mg/L
0.01
Manganese (Mn)
3.67
mg/L
0.005
Strontium (Sr)
0.052
mg/L
0.005
Zinc (Zn)
0.029
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
9.07
mg/L
0.01
Magnesium (Mg)
5.91
mg/L
0.005
Potassium (K)
0.627
mg/L
0.1
Sodium (Na)
10.5
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.113
mg/L
0.005
Barium (Ba)
0.069
mg/L
0.005
Boron (B)
0.148
mg/L
0.05
Iron (Fe)
49.1
mg/L
0.01
Manganese (Mn)
3.65
mg/L
0.005
Strontium (Sr)
0.052
mg/L
0.005
Zinc (Zn)
0.027
mg/L
0.005
Sample #: 2015019125
Matrix: GW WW
Analytical Lab
Page 12 of 49
DF Method Analysis Date/Time Analyst
Vendor Method
V_SHEALY
1
EPA 353.2
06/23/2015 14:03
LSTARLI
1
EPA 300.0
06/18/2015 00:25
BGN9034
10
EPA 300.0
06/18/2015 00:25
BGN9034
1
EPA 245.1
06/16/2015 15:07
ACPAYNE
1
EPA 245.1
06/18/2015 13:47
ACPAYNE
1
EPA 200.7
06/18/2015 11:35
MHALL3
1
EPA 200.7
06/18/2015 11:35
MHALL3
1
EPA 200.7
06/18/2015 11:35
MHALL3
1
EPA 200.7
06/18/2015 11:35
MHALL3
1
EPA 200.7
06/18/2015 11:35
MHALL3
1
EPA 200.7
06/18/2015 11:35
MHALL3
1
EPA 200.7
06/18/2015 11:35
MHALL3
1
EPA 200.7
06/19/2015 11:27
MHALL3
1
EPA 200.7
06/19/2015 11:27
MHALL3
1
EPA 200.7
06/19/2015 11:27
MHALL3
1
EPA 200.7
06/19/2015 11:27
MHALL3
1
EPA 200.7
06/17/2015 14:54
MHALL3
1
EPA 200.7
06/17/2015 14:54
MHALL3
1
EPA 200.7
06/17/2015 14:54
MHALL3
1
EPA 200.7
06/17/2015 14:54
MHALL3
1
EPA 200.7
06/17/2015 14:54
MHALL3
1
EPA 200.7
06/17/2015 14:54
MHALL3
1
EPA 200.7
06/17/2015 14:54
MHALL3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060451
Site: DMW-3
Collection Date: 12-Jun-15 10:20 AM
Analyte
Result
Units Qualifiers
RDL
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
40.0
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
17.7
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
41.8
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
18.4
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
190
mg/L
25
Total Carbon
TOC
0.873
mg/L
0.1
TOTAL SUSPENDED SOLIDS
TSS
7.0
mg/L
5
Sample #: 2015019125
Matrix: GW WW
Analytical Lab
Page 13 of 49
DF
Method
Analysis Date/Time
Analyst
1
EPA 200.8
06/23/2015 02:05
SLS2560
1
EPA 200.8
06/23/2015 02:05
SLS2560
1
EPA 200.8
06/23/2015 02:05
SLS2560
1
EPA 200.8
06/23/2015 02:05
SLS2560
1
EPA 200.8
06/23/2015 02:05
SLS2560
1
EPA 200.8
06/23/2015 02:05
SLS2560
1
EPA 200.8
06/23/2015 02:05
SLS2560
1
EPA 200.8
06/23/2015 02:05
SLS2560
1
EPA 200.8
06/23/2015 02:05
SLS2560
1
EPA 200.8
06/23/2015 02:05
SLS2560
1
EPA 200.8
06/23/2015 02:05
SLS2560
1
EPA 200.8
06/23/2015 02:05
SLS2560
1
EPA 200.8
06/23/2015 02:05
SLS2560
1
EPA 200.8
06/22/2015 14:13
SLS2560
1
EPA 200.8
06/22/2015 14:13
SLS2560
1
EPA 200.8
06/22/2015 14:13
SLS2560
1
EPA 200.8
06/22/2015 14:13
SLS2560
1
EPA 200.8
06/22/2015 14:13
SLS2560
1
EPA 200.8
06/22/2015 14:13
SLS2560
1
EPA 200.8
06/22/2015 14:13
SLS2560
1
EPA 200.8
06/22/2015 14:13
SLS2560
1
EPA 200.8
06/22/2015 14:13
SLS2560
1
EPA 200.8
06/22/2015 14:13
SLS2560
1
EPA 200.8
06/22/2015 14:13
SLS2560
1
EPA 200.8
06/22/2015 14:13
SLS2560
1
EPA 200.8
06/22/2015 14:13
SLS2560
Vendor Method
V_SHEALY
Vendor Method V_ELE1
1 SM2540C 06/16/201515:52 AGIBBS5
1 SM5310C/EPA9060A 06/25/201512:17 GHUTCHI
1 SM2540D 06/16/2015 08:20 AGIBBS5

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060451
Site: Filter Blank
Collection Date: 12-Jun-15 9:46 AM
Analyte
Result
Units
Qualifiers RDL
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
< 0.005
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
< 0.005
mg/L
0.005
Strontium (Sr)
< 0.005
mg/L
0.005
Zinc (Zn)
0.005
mg/L
0.005
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
Sample #: 2015019126
Matrix: GW WW
Analytical Lab
Page 14 of 49
DF
Method
Analysis Date/Time
Analyst
1
EPA 245.1
06/18/2015 13:49
ACPAYNE
1
EPA 200.7
06/18/2015 11:39
MHALL3
1
EPA 200.7
06/18/2015 11:39
MHALL3
1
EPA 200.7
06/18/2015 11:39
MHALL3
1
EPA 200.7
06/18/2015 11:39
MHALL3
1
EPA 200.7
06/18/2015 11:39
MHALL3
1
EPA 200.7
06/18/2015 11:39
MHALL3
1
EPA 200.7
06/18/2015 11:39
MHALL3
1
EPA 200.8
06/23/2015 07:31
SLS2560
1
EPA 200.8
06/23/2015 07:31
SLS2560
1
EPA 200.8
06/23/2015 07:31
SLS2560
1
EPA 200.8
06/23/2015 07:31
SLS2560
1
EPA 200.8
06/23/2015 07:31
SLS2560
1
EPA 200.8
06/23/2015 07:31
SLS2560
1
EPA 200.8
06/23/2015 07:31
SLS2560
1
EPA 200.8
06/23/2015 07:31
SLS2560
1
EPA 200.8
06/23/2015 07:31
SLS2560
1
EPA 200.8
06/23/2015 07:31
SLS2560
1
EPA 200.8
06/23/2015 07:31
SLS2560
1
EPA 200.8
06/23/2015 07:31
SLS2560
1
EPA 200.8
06/23/2015 07:31
SLS2560

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060451
Site: Equipment Blank
Collection Date: 12-Jun-15 9:46 AM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy
Labs)
Vendor Parameter
Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)
< 0.01
mg-N/L
B2 0.01
INORGANIC IONS BY IC
Chloride
< 0.1
mg/L
0.1
Sulfate
0.29
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
UNDIGESTED METALS BY lCP
Calcium (Ca)
0.034
mg/L
0.01
Magnesium (Mg)
< 0.005
mg/L
0.005
Potassium (K)
< 0.1
mg/L
0.1
Sodium (Na)
< 0.05
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.006
mg/L
0.005
Barium (Ba)
< 0.005
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
< 0.005
mg/L
0.005
Strontium (Sr)
< 0.005
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
Analytical Lab
Page 15 of 49
Sample #: 2015019127
Matrix: GW WW
DF Method Analysis Date/Time Analyst
Vendor Method V_SHEALY
1 EPA 353.2
06/23/2015 14:05
LSTARLI
1 EPA 300.0
06/17/2015 22:13
BGN9034
1 EPA 300.0
06/17/2015 22:13
BGN9034
1 EPA 245.1
06/16/2015 16:36
ACPAYNE
1 EPA 200.7
06/19/2015 09:51
MHALL3
1 EPA 200.7
06/19/2015 09:51
MHALL3
1 EPA 200.7
06/19/2015 09:51
MHALL3
1 EPA 200.7
06/19/2015 09:51
MHALL3
1 EPA 200.7
06/17/2015 14:58
MHALL3
1 EPA 200.7
06/17/2015 14:58
MHALL3
1 EPA 200.7
06/17/2015 14:58
MHALL3
1 EPA 200.7
06/17/2015 14:58
MHALL3
1 EPA 200.7
06/17/2015 14:58
MHALL3
1 EPA 200.7
06/17/2015 14:58
MHALL3
1 EPA 200.7
06/17/2015 14:58
MHALL3
1 EPA 200.8
06/22/2015 14:42
SLS2560
1 EPA 200.8
06/22/2015 14:42
SLS2560
1 EPA 200.8
06/22/2015 14:42
SLS2560
1 EPA 200.8
06/22/2015 14:42
SLS2560
1 EPA 200.8
06/22/2015 14:42
SLS2560
1 EPA 200.8
06/22/2015 14:42
SLS2560
1 EPA 200.8
06/22/2015 14:42
SLS2560
1 EPA 200.8
06/22/2015 14:42
SLS2560
1 EPA 200.8
06/22/2015 14:42
SLS2560
1 EPA 200.8
06/22/2015 14:42
SLS2560
1 EPA 200.8
06/22/2015 14:42
SLS2560
1 EPA 200.8
06/22/2015 14:42
SLS2560
1 EPA 200.8
06/22/2015 14:42
SLS2560
METHANE - (Analysis Performed by Shealy Labs)
Methane (CH4) Complete Vendor Method V_SHEALY

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060451
Site: Equipment Blank
Collection Date: 12-Jun-15 9:46 AM
Analyte Result Units Qualifiers RDL DF
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete
TOTAL DISSOLVED SOLIDS
TDS < 25 mg/L 25 1
Total Carbon
Sample #: 2015019127
Matrix: GW WW
Analytical Lab
Page 16 of 49
Method Analysis Date/Time Analyst
Vendor Method
V_ELE1
SM2540C 06/16/201515:52 AGIBBS5
TOC 0.274 mg/L 0.1 1 SM5310C/EPA9060A 06/25/201512:17 GHUTCHI
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L 5 1 SM2540D 06/16/2015 08:20 AGIBBS5
Qualifiers:
B2 Target analyte was detected in blank(s) at a concentration greater than the reporting limit but less than the
reporting limit. Analyte concentration in sample is valid and may be used for compliance purposes.

Analytical Lab
Page 17 of 49
[Element One lnc.
6319-D Carolina Beach Rd.
Wilmington, SIC 28412
Phone: [phone]
Fax: [phone]
e11ab%aiellah corn
e� nsntOne
REPORT OF ANALYSES
Duke Energy
June 25, 2015
Laboratory Services
Client Project Name AB GW Assessment water (wells) HF Lee
13339 Hagers Ferry Road Bld.
MG03A Client Project Number J15060451
Huntersville, NC 28078
PO Number
Sample Matrix GW WW
Sample Type Grab Date Received
06/16/2015
Date Analyzed 06/18/2015
Method SM 4500 S2- D Time Received
1312
Delivered by FedEx
Received by
LLB
eOne ID Duke Energy ID
Parameter Result Unit Dil DL Date
Time
Sampled
Sampled
25088-1 IMWAS
Sulfide < 0.1 mg/L 1 0.1 06/12/15
0900
25088-2 IMW-1 BC
25088-3
IMW-2BC
25088-4
SMW-3
25088-5
DMW-3
25088-6
Equipment Blank
Sulfide
Sulfide
< 0.1
1.47
mg/L 1
mg/L 2
Sulfide
< 0.1
mg/L
Sulfide
< 0.1
mg/L
Sulfide
< 0.1
mg/L
0.1
06/12/15
0.1
06/12/15
0.1
06/12/15
1 0.1 06/12/15
1 0.1 06/12/15
Rev. 06.25.15 to correct the sample ID for 25088-1.
LNG
Ken mith, Laboratory Director
25088 Duke Report Packet Rev. 06.25.15 Compiled by -)(AS
NC Certifications: DW 37788 and DWQ DENR 604
0835
1235
1244
1020
0946

Analytical Lab
Page 18 of 49
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Analytical Lab
elementOne SAMPLE SUBMISSION FORM Lab (Ije 1929688
TAT 7 BD Analysis Due Date 06.18.15
Hold Time Expiration 06.19.15 @ 0835 Report Due Date 06.24.15
Client: Duke Energy Date Rec: 06.16.15
LIMS No J15060451 Time Rec: 1312
Project ID HF Lee Rec By LLB
H >9 XEep No Temps 6°C Yes Ref. Method:
If No, Record If No, Record �?G G SM4500 S2 D
ocumilG ivannmcation at 1.,oillecillon inrormation
Lab ID
Client ID
Collection Date
Collection Time
Analysis Requested
1
IMW-1S
06.12.15
0900
2
IMW-1BC
� 6.12.15
0835
ulfid
3
IMW-26C
06 12 15
1235
ulfid
4
SMW-3
06.12.15
1249
u i
5
DMW 3
06 12.15
1020
i e
6
Equipment Blank
06.12.15
0946
u I
NOTE for Sulfide The MS/MSD spike should approximate 2 to 3 times the sample concentration. If no sulfide detected
at 100 pg/L spike the sample to render the final spike concentration at — 500 pg/L
SS Page .j,'9f 1 Prep By / Date 1 A'-\ 6 ' %, ( S
SS by Labeled By / Date '`',�a G 0-15-
6/17/2015 9:33:29 AM ID Verification By /Date, ! I S

Analytical Lab
Page 20 of 49
METHOD:
SM 4500 S2- D
ELEMENT ONE
ELEMENT ASSAY:
Sulfide
Spectrophotometer
Wave Length 664
Na2S•9H2O Lot #
40721
UNITS OF ANSWER
ug/mL
DETECTION LIMIT u
1.000
CLIENT:
Lab ID#
Duke
25088/ 091/ 092/ 096/ 097/ 098/ 099
SPK LEVEL u
MAX ALIQUOT
5
10.00
Date:
06/18/15
STANDARD conc(ppm)
X
Time Analysis Begun
8:00
Cal Std Lot: SD-08-1
10
Time Analysis Ended
12:20
QC Std Lot: SD-08-2
10
Analyst:
KAM
STD ABSORPTION
Y
X
Y
o.�
om
ug STD
SOLUTION
STD
ABS
°'°°
0.00
1.00
2.50
5.00
7.50
10.00 '
0.000
0.093
0.226
0.425
0c600
0.782
0.o�
Y
a.aoo
.azs
0 00
.zzs
a,w
0� :.� 40 e� an o.� 2.�
X
Ew
SAMPLE
I.D.
Std. B. 0.00
Std. B. 1.00
Std. B. 2.50
Std. B. 5.00
Std. B. 7.50
Std. B. 10.00
SAMP
ABS
0.000
0.098
0.223
0.421
0.610
0.771
ug PER
ALIQUOT
0.0000
0.8727
1 2.5603
5.2334
7.7849
9.9585
ALI in mL
ANALYZED
10
10
10
10
10
10
PREP
VOL in mL
10
10
10
10
10
10
Slope 0,077674725
ALI in mL RESULTS
TAKEN ug/mL
10 <
10 <
10 0.256
10 0.523
10 0.778
10 0.996
Correlation 0.99887486E
LESS THAN SPIKE
% SPK REC LEVEL
0.0
87.27% 1.0
102.41 % 2.5
104.67% 5.0
103.80% 7.5
99.58% 10.0
LRB
0.000
0.0000
10
10
10
<
0.0
LRB SPK
0.425
5.2874
10
10
10
0.529
106%
5.0
QC
0.430
5.3549
10
10
10
0.535
107%
5.0
5088-1
0.014
-0.2613
10
10
10
25088-1 s k
0.407
1 5.0444
10
10
10
0.504..
101 %
5.0
25088-2
0.003
-0.4098
10
10
10
1
< 0.1
25088-2 dup
0.003
-0.4098
10
10
10
N /fit
25088-2 spk
0.428
5.3279
10
10
10
0.533
107%
5.0
25088-3
1 Q}2
13.0771
10
10
10
1.308
25088 3 s k
...�
17.1137
10 1
10
10
1.711
81 %
5.0
25088-4
0.036
0.0357
10
10
10.
0.561
25088-4 spk
0.449
5.6114
10
10
10
112%
5.0
25088-5
0.003
-0.4098
10
10
10
p.1.
25088-5 spk
0.396
4.8958
10
10
10
0.490
98%
5.0
25088-6
0.002
-0.4233
10
10
10
0 x
0.531
25088-6 spk
0.427
5.3144
10
10
10
106%
5.0
25091
0.011
-0.3018
10
10
10
�
0.491
25091 s k
0.397
4.9093
10
10
10
98%
5.0
25092-1
0.024
-0.1263
10
10
10
�{}
0.542
25092-1 s k
0.435
5.4224
10
10
10
108%
5.0
25092-2
0.066
0.4407
10
10
10
< 0.1
25092-2 s k
0.194
2.1688
10
10
10
0.217
43%
5.0
Blank
-0.001 1
0.0000
10
10
10 1
<
QC
0.428 1
5.3279
10
10
10 1
0.533
107°/a
5.
Submitted for QA/QC- Date: 06/18/15
By: (Print)
KAM
(sign):
Page 1 of 5

Analytical Lab
Page 21 of 49
METHOD:
SM 4500 S2- D
ELEMENT ONE
ELEMENT ASSAY:
Sulfide
Spectrophotometer
Wave Length 664
>
Na2S•9H2O Lot #
40721
UNITS OF ANSWER
ug/mL
DETECTION LIMIT u
1.000
CLIENT:
Lab ID#
Duke
25088/ 091/ 092/ 096/ 097/ 098/ 099
SPK LEVEL u
MAX ALIQUOT
5
10.00
Date:
06/18/15
STANDARD conc(ppm)
X
Time Analysis Begun
8:00
Cal Std Lot: SD-08-1
10
Time Analysis Ended
12:20
QC Std Lot: SD-08-2
10
Analyst:
KAM
STD ABSORPTION
Y
X
y
- _
o�
ug STD
SOLUTION
STD
ABS
0700
-ate
0.00
100
2.50
5,00
7.50
10.00
0.000
0.093
0.226
0.425
0.600
0.782
o.aao
azs
�sm
0.200
a,00
i
oo zoo aoo aoo aoo 10 to zoo
x
I
SAMPLE
I.D.
SAMP
ABS
mom
ug PER
ALIQUOT
MINE W.
ALI in mL
ANALYZED
PREP
VOL in mL
Sloe 0.077674725
Correlation 0.998874861
ALI in mL
TAKEN
RESULTS
u /mL
LESS THAN
% SPK REC
SPIKE
LEVEL
Std. B. 0.00
0.000
0.0000
10
10
10
<
0.0
Std. B. 1.00
0.098
0.8727
10
10
10
<
87.27%
1.0
Std. B. 2.50
0.223
1 2.5603
10
10
10
0.256
102.41 %
2.5
Std. B. 5.00
0.421
5.2334
10
10
10
0.523
104.67%
5.0
Std. B. 7.50
0.610
7.7849
10
10
10
0.778
103.80%
7.5
Std. B. 10.00
0.771
9.9585
10
10
10
0.996
99.58%
10.0
LRB
0.000
0.0000
10
10
10
<
0.0
LRB SPK
0.425
5.2874
10
10
10
0.529
106%
5.0
QC
0.430
5.3549
10
10
10
0.535
107%
5.0
25092-3
0.001
-0.4368
10
10
10
5,
0.531
25092-3 spk
0.427
5.3144
10
10
10
106%
5.0
25092-4
0.013
-0.2748
10
10
10
25092-4 dup
0.014
-0.2613
10
10
10
< 0.1
25092-4 spk
0.362
4.4368
10
10
10
0.444
89%
5.0
25092-5
0.001
-0.4368
10
10
10
25092-5 spk
0.418
5.1929
10
10
10
0.519
104%
5.0
25096-1
0.002
-0.4233
10
10
10-�,
<,
0.483
25096-1 spk
0.391
4.8283
10
10
10
97%
5.0
25096-2
0.003
-0.4098
10
10
10
<
25096-2 spk
0.325
3.9373
10
10
10
0.394
79%
5.0
6-3
0.020
-0.1803
10
10
10
0.514 _
25096-3 spk
0.414
5.1389
10
10
10
103%
5.0
25096-4
0.096
0.8457
10
10
10
<
25096-4 spk
0.483
6.0704
10
10
10
0.607
121 %
5.0
25096-5
0.747
9.6345
10
10
10_
1.394
25096-5 spk
1.066
13.9411
10
10
10
86%
5.0
25096-6
0.004
-0.3963
10
10
10e;
.
25096-6 spk
0.415
5.1524
10
10
10
0.515
103%
5.0
Blank
-0.001
0.0000
10
10
10
<
QC
0.427
5.3144
10
10
10
0.531
106%
5.0
Submitted for QA/QC-
Date: 06/18/15
By: (Print)
KAM (sign):
Page 2 of 5

Analytical Lab
Page 22 of 49
METHOD:
SM 4500 S2- D
ELEMENT ONE
ELEMENT ASSAY:
Sulfide
Spectrophotometer
Wave Length 664
Na2S•9H2O Lot #
40721
UNITS OF ANSWER
u /mL_.
DETECTION LIMIT u
1.000
CLIENT:
Lab ID#
Duke
25088/ 091/ 092/ 096/ 097/ 0981099
SPK LEVEL u
MAX ALIQUOT
5
10.00
Date:
06/18/15
STANDARD conc(ppm)
X
Time Analysis Begun
8:00
Cal Std Lot: SD-08-1
10
Time Analysis Ended
12:20
jQC-Std Lot: SD-08-2
10
Analyst:
KAM
STD ABSORPTION
Y
X
y
- -
ug STD
SOLUTION
STD
ABS
owo
0700
0.00
1.00
2.50
5.00
0.0.0
100
0.000
0.093
0.226
0.425'
0.6001
0.782
11
a.�
1.200
1
-
00°u.m 2.00 4.60 em s.ao °oo zro
x
SAMPLE
I.D.
Std. B. 0.00
Std. B. 1.00
Std. B. 2.50
Std. B. 5.00
Std. B. 7.50
Std. B. 10.00
SAMP
ABS
0.000
0.098
0.223
0.421
0.610
0.771
ug PER
ALIQUOT
0.0000
0.8727
2.5603
5.2334
7.7849
9.9585
ALI in mL
ANALYZED
10
10
10
10
10
10
PREP
VOL in mL
10
10
10
10
10
10
Sloe 0.077674725
ALI in mL RESULTS
TAKEN u /mL
10 <
10 <
10 0.256
10 0.523
10 0.778
10 0.996
Correlation 0.998874861+
LESS THAN SPIKE
% SPK REC LEVEL
0.0
87.27% 1.0
102.41 % 2.5
104.67% 5.0
103.80% 7.5
99.53% 10.0
LRB
0.000
0.0000
10
10
10
<
0.0
LRB SPK
0.425
5.2874
10
10
10
0.529
106%
5.0
QC
0.430
5.3549
10
10
10
0.535
107%
5.0
25097-1
0.009
-0.3288
10
10
10
0.495
25097-1 s k
0.400
4.9498
10
10
10
99%
5.0
25097-2
0.003
-0.4098
10
10
10
<
25097-2 spk
0.338
4.1128
10
10
10
0.411
82%
5.0
25097-3
0.007
-0.3558
10
10
10
<
25097-3 dup
0.004
-0.3963
10
10
10
<
25097-3 spk
0.180
1.9798
10
10
10
0.198
40%
5.0
25097-4
0.004
-0.3963
10
10
10
<
25097-4 spk
0.338
4.1128
10
10
10
0.411
82%
5.0
25097-5
0.001
-0.4368
10
10
10
0.535
25097-5 spk
0.430
5.3549
10
10
10
107%
5.0
25097-6
0.004
-0.3963
10
10
10
25097-6 spk
0.372
4.5718
10
10
10
0.457
91 %
5.0
25098-1
0.003
-0.4098
10
10
10
2A��
0.529
25098-1 spk
0.425
5.2874
10
10
10
106%
5.0
25098-2
0.025
-0.1128
10
10
10
25098-2 spk
0.423
5.2604
10
10
10
0.526
105%
5.0
25098-3
0.009
-0.3288
10
10
10
25098-3 spk
0.427
5.3144
10
10
10
0.531
106%
5.0
Blank
-0.001
0.0000
10
10
10
<
QC
0.428
5.3279
10
10
10
0.533
107%
5.0
Submitted for QA/QC- Date: 06/18/15
By. (Print)
KAM
(sign): ti G
Page 3 of 5

Analytical Lab
Page 23 of 49
METHOD:
SM 4500 S2- D
ELEMENT ONE
ELEMENT ASSAY:
Sulfide
Spectrophotometer
Wave Length 664
UNITS OF ANSWER
ug/mL
DETECTION LIMIT u
1.000
CLIENT:
Duke
SPK LEYELLuca
5
Lab ID#
25088/ 091/ 092/ 096/ 097/ 098/ 099
Na2S•9H2O Lot #
40721
MAX ALIQUOT
10.00
Date:
06/18/15
STANDARD conc(ppm)
_
X
Time Analysis Begun
8:00
Cal Std Lot: SD-08-1
10
Time Analysis Ended
12:20
QC Std Lot: SD-08-2
10
Analyst:
KAM
ISTID ABSORPTION0900
Y
X
Y
ug STD
SOLUTION
STD
ABS
o.=
°'°°
0.00
1.00
2.50
5.00
7.50
10.00
0.000 `
0.093
0.226:
0.425
0,600,
0.782
sw
r
aaao
ers
-
0.200
a+�
°
o� 2.00 aao sa em 10.00 1200
x
nwimm
SAMPLE
I.D.
SAMP
ABS
ug PER ALI in mL
ALIQUOT ANALYZED
PREP
VOL in mL
Sloe 0.077674725
Correlation 0.998874861
ALI in mL
TAKEN
RESULTS
ug/mL
LESS THAN
% SPK REC
SPIKE
LEVEL
Std. B. 0.00
0.000
0.0000
10
10
10
<
0.0
Std. B. 1.00
0.098
0.8727
10
10
10
<
87.27%
1.0
Std. B. 2.50
0.223
1 2.5603
10
10
10
0.256
102.41 %
2.5
Std. B. 5.00
0.421
5.2334
10
10
10
0.523
104.67%
5.0
Std. B. 7.50
0.610
7.7849
10
10
10
0.778
103.80%
7.5
Std. B. 10.00
0.771
9.9585
10
10
10
0.996
99.58%
10.0
LRB
0.000
0.0000
10
10
10
<
0.0
LRB SPK
0.425
5.2874
10
10
10
0.529
106%
5.0
QC
0.430
5.3549
10
10
10
0.535
107%
5.0
25098-4
0.007
-0.3558
10
10
10
0 t
25098-4 s k
0.376
4.6258
10
10
10
0.463
93%
5.0
25098-5
0.003
-0.4098
10
10
10
9 ,c p;7
25098-5 spk
0.415
5.1524
10
10
10
0.515
103%
5.0
25098-6
0.002
-0.4233
10
10
10
'
25098-6 s k
0.428
5.3279
10
10
10
0.533
107%
5.0
25099
0.021
-0.1668
10
10
10
t
25099 dup
0.019
-0.1938
10
10
10
< 0.1
25099 spk
0.390
4.8148
10
10
10
0.481
96%
5.0
24186-19.2 QC
0.485
6.0974
10
10
2
3.049
TV=4.23
25088-3
0.578
7.3529
10
10
5
25088-3 s k
0.918
11.9430
10
10
5
2.389
92%
5.0
25092-2
0.038
0.0627
10
10
5
<
25092-2 spk
0.308
3.7078
10
10
5
0.742
74%
5.0
25096-2
0.002
-0.4233
10
10
5
. ,
25096-2 s k
0.389
4.8013
10
10
5
0.960
96%
5.0
25096-4
0.048
0.1977
10
10
5
25096-4 s k
0.455
5.6924
10
10
5
1.138
114%
5.0
25097-2
0.001
-0.4368
10
10
5
25097-2 spk
0.379
4.6663
10
10
5
0.933
93%
5.0
Blank
-0.001
0.0000
10
10
10
<
QC
0.425
5.2874
10
10
10
0.529
106%
5.0
Submitted for QA/QC-
Date: 06/18/15
By: (Print)
KAM (sign):
Page 4 of 5

Analytical Lab
Page 24 of 49
METHOD:
SM 4500 S2- D
ELEMENT ONE
ELEMENT ASSAY:
Sulfide Spectrophotometer UNITS OF ANSWER
Wave Length 664 DETECTION LIMIT u
puke SPK LEVEL (ug)
25088/ 091/ 092/ 096/ 097/ 098/ 099 MAX ALIQUOT
06/18/15 Na2S•9H2O Lot # STANDARD conc(ppm)
8:00 40721 Cal Std Lot: SD-08-1
12:20 QC Std Lot: SD-08-2
KAM STD ABSORPTION
y -
u /mL
1.000
CLIENT:
Lab ID#
5
10.00
Date:
X
Time Analysis Begun
10
Time Analysis Ended
10
Analyst:
X
Y
- -
ug STD
SOLUTION
STD
0
ABS
0'00
0.00
1.00
2.50
5.00
7.50
10.00
0800
-o�
0.000 -
0.500
0.093
0,
0.400
.425
0.300
0.226
0.200
.226
0.425
0.100
-,00
0.600
0.782
0000.00 200 400 000 1000 12.00
X
i
SAMPLE
I.D.
Std. B. 0.00
Std. B. 1.00
Std. B. 2.50
Std. B. 5.00
Std. B. 7.50
Std. B. 10.00
SAMP
ABS
0.000
0.098
0.223
0.421
0.610
0.771
ug PER
ALIQUOT
0.0000
0.8727
2.5603
5.2334
7.7849
9.9585
Sloe 0.077674725
Correlation 0.998874861
ALI in mL
ANALYZED
10
10
10
10
10
10
PREP
VOL in mL
10
10
10
10
10
10
ALI in mL
TAKEN
10
10
10
10
10
10
RESULTS
u /mL
<
<
0.256
0.523
0.778
0.996
LESS THAN
% SPK REC
87.27%
102.41 %
104.67%
103.80%
99.58%
SPIKE
LEVEL
0.0
1.0
2.5
5.0
7.5
10.0
LRB
0.000
0.0000
10
10
10
<
0.0
LRB SPK
0.425
5.2874
10
10
10
0.529
106%
5.0
QC
0.430
5.3549
10
10
10
0.535
107%
5.0
25097-3
0.000
0.0000
10
10
5
<
25097-3 dup
0.003
-0.4098
10
10
5
<
25097-3 spk
0.299
3.5863
10
10
5
0.717
72%
5.0
25097-4
0.003
-0.4098
10
10
5
�09•`
0.976
25097-4 s k
0.395
4.8823
10
10
5
98%
5.0
25092-2
0.018
-0.2073
10
10
2
2.488
25092-2 s k
0.402
4.9769
10
10
2
100%
5.0
25097-3
0.002
-0.4233
10
10
2
7775
< 0.5
25097-3 du
-0.001
0.0000
10
10
2
25097-3 s k
0.391
4.8283
10
10
2
2.414
97%
5.0
Blank
-0.001
0.0000
10
10
10
<
QC 0.425 5.2874 10
Submitted for QA/QC- Date: 06/18/15
10
By: (Print)
10 0.529
KAM
106% 5.0
(sign):
Page 5 of 5

SHEALY ENVIRONMENTAL SERVICES, INC.
Report of Analysis
Duke Energy
13339 Hagers Ferry Rd
Bldg 7405
Huntersville, NC 28078
Attention: Mary Ann Ogle
Project Name: AB GW Assessment Water - HF Lee
Project Number:J15060451
Lot Number:QF16020
Date Completed:06/23/2015
Grant Wilton
Project Manager
This report shall not be reproduced, except in its entirety, without the written approval of Shealy Environmental Services, Inc.
The following non -paginated documents are considered part of this report: Chain of Custody Record and Sample Receipt Checklist.
* QF1 6020*
Shealy Environmental Services, Inc. Page: 1 of 16
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SHEALY ENVIRONMENTAL SERVICES, INC.
SC DHEC No: 32010 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
Case Narrative
Duke Energy
Lot Number: QF16020
Project Name: AB GW Assessment Water - HF Lee
Project Number: J15060451
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample
receiving date is documented in the header information associated with each sample.
All results listed in this report relate only to the samples that are contained within this report.
Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the
Shealy Environmental Services, Inc. ("Shealy") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPS), and Shealy
policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below.
If you have any questions regarding this report please contact the Shealy Project Manager listed on the cover page
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SHEALY ENVIRONMENTAL SERVICES, INC.
Sample Summary
Duke Energy
Lot Number: QF16020
Project Name: AB GW Assessment Water - HF Lee
Project Number: J15060451
Sample Number
Sample ID
Matrix
Date Sampled
Date Received
001
2015019121
Aqueous
06/12/2015 0900
06/16/2015
002
2015019122
Aqueous
06/12/2015 0835
06/16/2015
003
2015019123
Aqueous
06/12/20151235
06/16/2015
004
2015019124
Aqueous
06/12/20151249
06/16/2015
005
2015019125
Aqueous
06/12/20151020
06/16/2015
006
2015019127
Aqueous
06/12/2015 0946
06/16/2015
(6 samples)
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SHEALY ENVIRONMENTAL SERVICES, INC.
Executive Summary
Duke Energy
Lot Number: QF16020
Project Name: AB GW Assessment Water - HF Lee
Project Number: J15060451
Sample Sample ID
Matrix
Parameter Method
Result Q
Units
Page
001
2015019121
Aqueous
Alkalinity SM 2320B-
11
mg/L
5
001
2015019121
Aqueous
Bicarbonate Alkalinity SM 2320B-
11
mg/L
5
002
2015019122
Aqueous
Alkalinity SM 2320B-
74
mg/L
7
002
2015019122
Aqueous
Bicarbonate Alkalinity SM 2320B-
74
mg/L
7
003
2015019123
Aqueous
Alkalinity SM 2320B-
180
mg/L
9
003
2015019123
Aqueous
Bicarbonate Alkalinity SM 2320B-
170
mg/L
9
004
2015019124
Aqueous
Alkalinity SM 2320B-
84
mg/L
11
004
2015019124
Aqueous
Bicarbonate Alkalinity SM 2320B-
84
mg/L
11
004
2015019124
Aqueous
Methane RSK - 175
620
ug/L
12
005
2015019125
Aqueous
Alkalinity SM 2320B-
68
mg/L
13
005
2015019125
Aqueous
Bicarbonate Alkalinity SM 2320B-
68
mg/L
13
005
2015019125
Aqueous
Methane RSK - 175
17
ug/L
14
(12 detections)
Shealy Environmental Services, Inc. Page: 4 of 16
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Inorganic non-metals
Client: Duke Energy Laboratory ID: QF16020-001
Description: 2015019121 Matrix: Aqueous
Date Sampled:06/12/2015 0900 Project Name: AB GW Assessment Water -
Date Received:06/16/2015 Project Number: J15060451
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 2320B-2011
1 06/19/2015 2344
HMA 77675
1
(Bicarbonate ) SM 2320B-2011
1 06/19/2015 2344
HMA
1
(Carbonate Al) SM 2320B-2011
1 06/19/2015 2344
HMA
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
11
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
11
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Methane
Client: Duke Energy Laboratory ID: QF16020-001
Description: 2015019121 Matrix: Aqueous
Date Sampled:06/12/2015 0900 Project Name: AB GW Assessment Water -
Date Received:06/16/2015 Project Number: J15060451
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 06/22/2015 1517 DCS 77844
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Inorganic non-metals
Client: Duke Energy Laboratory ID: QF16020-002
Description: 2015019122 Matrix: Aqueous
Date Sampled:06/12/2015 0835 Project Name: AB GW Assessment Water -
Date Received:06/16/2015 Project Number: J15060451
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 2320B-2011
1 06/19/2015 2350
HMA 77675
1
(Bicarbonate ) SM 2320B-2011
1 06/19/2015 2350
HMA
1
(Carbonate Al) SM 2320B-2011
1 06/19/2015 2350
HMA
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
74
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
74
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Methane
Client: Duke Energy Laboratory ID: QF16020-002
Description: 2015019122 Matrix: Aqueous
Date Sampled:06/12/2015 0835 Project Name: AB GW Assessment Water -
Date Received:06/16/2015 Project Number: J15060451
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 06/22/2015 1530 DCS 77844
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Inorganic non-metals
Client: Duke Energy Laboratory ID: QF16020-003
Description: 2015019123 Matrix: Aqueous
Date Sampled:06/12/2015 1235 Project Name: AB GW Assessment Water -
Date Received:06/16/2015 Project Number: J15060451
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 2320B-2011
1 06/19/2015 2357
HMA 77675
1
(Bicarbonate ) SM 2320B-2011
1 06/19/2015 2357
HMA
1
(Carbonate Al) SM 2320B-2011
1 06/19/2015 2357
HMA
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
180
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
170
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Methane
Client: Duke Energy Laboratory ID: QF16020-003
Description: 2015019123 Matrix: Aqueous
Date Sampled:06/12/2015 1235 Project Name: AB GW Assessment Water -
Date Received:06/16/2015 Project Number: J15060451
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 06/22/2015 1540 DCS 77844
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Inorganic non-metals
Client: Duke Energy Laboratory ID: QF16020-004
Description: 2015019124 Matrix: Aqueous
Date Sampled:06/12/2015 1249 Project Name: AB GW Assessment Water -
Date Received:06/16/2015 Project Number: J15060451
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 2320B-2011
1 06/20/2015 0003
HMA 77675
1
(Bicarbonate ) SM 2320B-2011
1 06/20/2015 0003
HMA
1
(Carbonate Al) SM 2320B-2011
1 06/20/2015 0003
HMA
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
84
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
84
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Methane
Client: Duke Energy Laboratory ID: QF16020-004
Description: 2015019124 Matrix: Aqueous
Date Sampled:06/12/2015 1249 Project Name: AB GW Assessment Water -
Date Received:06/16/2015 Project Number: J15060451
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 06/22/2015 1550 DCS 77844
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 620 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Inorganic non-metals
Client: Duke Energy Laboratory ID: QF16020-005
Description: 2015019125 Matrix: Aqueous
Date Sampled:06/12/2015 1020 Project Name: AB GW Assessment Water -
Date Received:06/16/2015 Project Number: J15060451
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 2320B-2011
1 06/20/2015 0022
HMA 77675
1
(Bicarbonate ) SM 2320B-2011
1 06/20/2015 0022
HMA
1
(Carbonate Al) SM 2320B-2011
1 06/20/2015 0022
HMA
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
68
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
68
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 13 of 16
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane
Client: Duke Energy Laboratory ID: QF16020-005
Description: 2015019125 Matrix: Aqueous
Date Sampled:06/12/2015 1020 Project Name: AB GW Assessment Water -
Date Received:06/16/2015 Project Number: J15060451
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 06/22/2015 1600 DCS 77844
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 17 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 14 of 16
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals
Client: Duke Energy Laboratory ID: QF16020-006
Description: 2015019127 Matrix: Aqueous
Date Sampled:06/12/2015 0946 Project Name: AB GW Assessment Water -
Date Received:06/16/2015 Project Number: J15060451
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 2320B-2011
1 06/20/2015 0029
HMA 77675
1
(Bicarbonate ) SM 2320B-2011
1 06/20/2015 0029
HMA
1
(Carbonate Al) SM 2320B-2011
1 06/20/2015 0029
HMA
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
ND
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 15 of 16
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane
Client: Duke Energy Laboratory ID: QF16020-006
Description: 2015019127 Matrix: Aqueous
Date Sampled:06/12/2015 0946 Project Name: AB GW Assessment Water -
Date Received:06/16/2015 Project Number: J15060451
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 06/22/2015 1610 DCS 77844
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 16 of 16
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

QC Summary
Shealy Environmental Services, Inc. QC Data for Lot Number: QF16020
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals - MB
Sample ID: QQ77675-001 Matrix: Aqueous
Batch:77675
Analytical Method: SM 2320B-2011
Parameter Result Q Dil PQL Units Analysis Date
Alkalinity ND 1 10 mg/L 06/19/2015 2147
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QF16020
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals - LCS
Sample ID: QQ77675-002 Matrix: Aqueous
Batch:77675
Analytical Method: SM 2320B-2011
Spike
Amount Result % Rec
Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Alkalinity 100 99 1 99 90-110 06/19/2015 2154
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QF16020
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane - MB
Sample ID: QQ77844-001 Matrix: Aqueous
Batch:77844
Analytical Method: RSK - 175
Parameter Result Q Dil PQL Units Analysis Date
Methane ND 1 10 ug/L 06/22/20151159
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QF16020
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane - LCS
Sample ID: QQ77844-002 Matrix: Aqueous
Batch:77844
Analytical Method: RSK - 175
Spike
Amount Result % Rec
Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date
Methane 50 49 1 97 70-130 06/22/20151130
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QF16020
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane - LCSD
Sample ID: QQ77844-003 Matrix: Aqueous
Batch:77844
Analytical Method: RSK - 175
Spike
Amount Result % Rec % RPD
Parameter (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date
Methane 50 48 1 96 1.7 70-130 30 06/22/20151141
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QF16020
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

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Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

SHEALY ENVIRONMENTAL SERVICES, INC.
Shealy EnviTork coral Senjiu% the
Document Number, F•AD4345
Redi.oe Numbu, 17
P14P1of1
Rbplarias Mile: 14
Effective Dale:
Sample Receipt ChwUst (SRC)
Client- DO KLL C-Li Yy(° N Ceoicr Inspected by/date:
WCans Of recelpt! SESI ❑ Client ❑ UPS ❑ FedEx ❑ Airborne E-tlp Othcr
Yes El
lliool­
_Wcrzcustody seals present on the cooler?
Yes
No 0. J, �TA
2- It wstogy steals were prosent, were they intact and unbroken: —
Cooler lll'``],A)rig�rnall lemperatuto upon zeciptoDerived �corrc cwd) ternperaiure upon receipt.
Mcthud. ❑ Temperslure Blpnk Against l3ttltles fly Gun Ul 5' IR Gun C orrrction Factrin T
Method of coolant; FJf ct lam: ❑ Blue Ice ❑ Dr • [ee El None -
3. If tempernrure.of any; weler exceeded 6.0°C, was Project Manager notified!
y. Q No ❑ A PM notified by SRC:, phone, note (circle one), other`.
Ebr coolers received via fiommcrcial courier, PM.-, are to kN-� nulificd
irnmc+iatol .
Ye' s ❑ PWEJ NA 4. is Ilic commercial urierds packing &Hp atta , ed to this form?
Yes No ❑ 1 - C.re proper cusiody prwEdures Tel ing pisbecVreoeived followed?
Yes ❑No
D
I NA -ET-
Sa Were sanlpl&s relinquisbod by client to cornmercia] courier?
Yes
6, Wert Sample II)s listed on the —00 ?
T Were sample 1D9 listed on all sample tmtainets?
Yes
❑
Yes
❑
S. Was collection date & d Me listed on the COC?
Yes
N ❑
9, WW =11ection date & time listed on all sam lc containers?
1f1. Did all corltaiuerr label informallion Ili dale, Chile)a ee Witlt the +�C C
Yes
41
Q
Yes
❑
_
11. 'Were, tests to be performed lisled on theCOC?
11 Chid all sarn1p Ies arrive in the r containters for each test?
Yes
o ❑
Yes
El13.
Did all containers arrive in goad coodition (wibrolcen, lids on, etc..,)?
141 Was adc€luale sample volurne avaiIab[0
15, Were all satitples reicivedwithin�V-2 the holding time. nr -0 hours, WbieheVet
coat'--s first?
16- Wcrc any sam les acrneainers missin
Yes
No ❑
Yes ❑
No
Yes ❑
Na
Yea ❑
.No
17, Were thete any excess sarap4si not listed on COC?
Yes
No2r
t o ❑
18. Wurc bubbles resc-nt ;, ` a -size" 'M'or 6mm in diameter in any VOA vials?
Yes ❑
No ❑
I'TA.
9. Were all teaJr,,+C9{' (J[f1.C�tlnrtrrirtnk s21m cs received at a Hof ¢27
Yes
No ❑
NA
20e Were all cyanide and/or sulfide samples received at a pH >12?
Yes ❑
Nc, ❑
NA
21, W re all applicable JKKecyanideJphetlel ( 1-2mgJE) samples free of
rye ual chlorine?
Yes LJ
Nu[] I-NAIZ
22. Were coll+oction ternperatures documented on the COC far NTC. Ram les?
'lees ❑
No ❑
LO
3Were client remar"?requests (i.e. requested dilutions, MSIMSD designations,
etc.,.ct+rrectl .. transcribed from the COC into the comment section in I..IMS?
Y77
NID
24. Wa6 Ific q uulr� number used taken from the nunlainer label?
�rrrpla
Preservation
(Must be completed for any satr>lale(s) rre�,rreetly presetyed or with headspalce.)
Samples) were reeei%,ed irEwrra-Aly prreserveA and were adjZ ted
accordinglyacoordingly in slim le. receiving W10 H2S0,t HN%J-1C'1,Na(? using SR #
Sam i s
were received with bubbles >6 meta in diameter,
samples) _ werc rr-ccivcd wilb TRC A.2 If 021 is No
s Drinking Water Pruject nmple(F;) pT l verified to be > 2 by Date:
sam 1 s) were not received at a H of <2 and were adjusted aOcaordin ly using SRN
Sample labels applied b
Vc.-rificd by- Late.
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM
Fnorev AnahRical 1_abemtnry
1 ahemf. U— rfnly
Analytical Lab
vuAe r-nergy uy i ce:, —y"I
Mall Cod° MG03A2 (Building 7405) 1 Order # Matrix GW WW NC— Page _1_ of _t_
Analytical Laboratory, 13339 Hagen Ferry Rd i i _ 5amplaa o,iginaunq From be 1 DISTRIBUTION
HUMersvllle, N. C. 28078 ��`10-IC.khS-
Chain of Custody & I Loyggd By pang I ORIGINAL to LAB, COPY to CLIF
Sample Log [phone] 1 i < 9 SAMPLE PROGRAM r
i I �S it e��
Faz: 704 8765038
r.._._._._._._._._._._._._._._._._._._._._. ._,_._._._._._. _._.S._.L._._._._._._._._._._._.: ! Ground Water_ NPDES
IN "°' (VaadN Drinking Water_ UST_ i
"a^° AB GW Assessment water (1a<. A- RCRA Waste_ COC REV DATE 1/22/2015
(wellslCooler TemPSCl.._.._..
Client Fax Ho.
980-876 Shealy iltration (0.45 um) b Unfiltered bnered
Business Unit: ' R.w•c«rr Pd1142089 Preservative Ice ke I— "I..'
10: Mae Coda:
7-7MG03A3 -1 ainer Volume (ml-) 2000 40 ml 300 its Soo Soo 2L 500 250
.arbody: HF Lee Elementl Container Type PET glass PET PET PET PET HOPE HOPE HDPE
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Other
ELEMENTS by ICP_MS (TRM): As, Be, Cd, Co, Cr, Cu, Mo, Ni, Pb, Sb, Se, TI (LL), V (ILL)
ELEMENTS by ICP (TRM): AI, Be, B, Fe, Mn, Sr, Zn ICP Undigested Ca, Mg, K, Na Hg by 245.1
h
_ASAP
Add. Cost Will Apply
Dissolved metals: all metals ICP, IMS,Hg
U
Total E
terra EDD