NC0003417_J15060435report_20150805

DUE Analytical Laboratory
ENERGY
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone:[phone] Fax:[phone]
Order Summary Report
Order Number: J15060435
Project Name: HF LEE PLANT - AB GW ASSESSMENT WATER
Customer Name(s): Tim Hunsucker, Judd Mahan, Kathy Webb, John Toepfer
Customer Address: 1677 Old Smithfield Rd
Goldsboro NC 27530,
Lab Contact: Mary Ann Ogle Mary Ann Ogle Phone: [phone]
Report Authorized By: C/�S 2015.06.27 Date:
(Signature) 11:37:02-04'00'
Mary Ann Ogle
Program Comments:
Please contact the Program Manager (Mary Ann Ogle) with any questions regarding this report.
Data Flags & Calculations:
6/27/2015
Analytical Lab
Page 1 of 99
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Sample ID's & Descriptions:
Analytical Lab
Page 2 of 99
Sample ID Plant/Station
Collection
Date and Time Collected By
Sample Description
2015019018
HF LEE PLANT
11-Jun-15 1:20 PM
ILLEGIBLE
ABMW-1
2015019019
HF LEE PLANT
11-Jun-15 2:27 PM
ILLEGIBLE
ABMW-1S
2015019020
HF LEE PLANT
11-Jun-15 5:15 PM
ILLEGIBLE
AMW-9BC
2015019021
HF LEE PLANT
11-Jun-15 9:18 AM
ILLEGIBLE
AMW-11S
2015019022
HF LEE PLANT
11-Jun-15 9:18 AM
ILLEGIBLE
AMW-11S-Dup
2015019023
HF LEE PLANT
11-Jun-15 10:25 AM
ILLEGIBLE
AMW-11 BC
2015019024
HF LEE PLANT
11-Jun-15 1:24 PM
ILLEGIBLE
AMW-14S
2015019025
HF LEE PLANT
11-Jun-15 12:55 PM
ILLEGIBLE
AMW-14BC
2015019026
HF LEE PLANT
11-Jun-15 10:46 AM
ILLEGIBLE
AMW-15S
2015019027
HF LEE PLANT
11-Jun-15 11:30 AM
ILLEGIBLE
AMW-15BC
2015019028
HF LEE PLANT
11-Jun-15 11:30 AM
ILLEGIBLE
AMW-15BC-Dup
2015019029
HF LEE PLANT
11-Jun-15 5:30 PM
ILLEGIBLE
MW-3
2015019030
HF LEE PLANT
11-Jun-15 8:00 AM
ILLEGIBLE
Filter Blank
2015019031
HF LEE PLANT
11-Jun-15 8:00 AM
ILLEGIBLE
Equipment Blank
14 Total Samples

Analytical Lab
Page 3 of 99
Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals 0 Yes ❑ No
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits. ❑ Yes 0 No
All laboratory QA/QC requirements are acceptable. 0 Yes ❑ No
Report Sections Included:
E%-'] Job Summary Report
❑� Sample Identification
Technical Validation of Data Package
❑� Analytical Laboratory Certificate of Analysis
❑ Analytical Laboratory QC Report
❑d Sub -contracted Laboratory Results
❑ Customer Specific Data Sheets, Reports, & Documentation
❑ Customer Database Entries
❑� Chain of Custody
❑� Electronic Data Deliverable (EDD) Sent Separately
Reviewed By: Mary Ann Ogle Date: 6/27/2015

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060435
Site: ABMW-1
Collection Date: 11-Jun-15 1:20 PM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter
Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)
< 0.01
mg-N/L
B2 0.01
INORGANIC IONS BY IC
Chloride
28
mg/L
1
Sulfate
8.2
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
0.057
mg/L
0.005
Barium (Ba)
0.874
mg/L
0.005
Boron (B)
2.28
mg/L
0.05
Iron (Fe)
24.5
mg/L
0.01
Manganese (Mn)
1.22
mg/L
0.005
Strontium (Sr)
6.14
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
UNDIGESTED METALS BY lCP
Calcium (Ca)
174
mg/L
0.1
Magnesium (Mg)
25.9
mg/L
0.05
Potassium (K)
16.4
mg/L
1
Sodium (Na)
40.0
mg/L
0.5
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.082
mg/L
0.005
Barium (Ba)
0.908
mg/L
0.005
Boron (B)
2.35
mg/L
0.05
Iron (Fe)
25.5
mg/L
0.01
Manganese (Mn)
1.26
mg/L
0.005
Strontium (Sr)
6.34
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Sample #: 2015019018
Matrix: GW WW
Analytical Lab
Page 4 of 99
DF Method Analysis Date/Time Analyst
Vendor Method
V_SHEALY
1
EPA 353.2
06/23/2015 13:17
LSTARLI
10
EPA 300.0
06/16/2015 18:36
BGN9034
1
EPA 300.0
06/16/2015 18:36
BGN9034
1
EPA 245.1
06/16/2015 15:41
ACPAYNE
1
EPA 245.1
06/16/2015 12:24
ACPAYNE
1
EPA 200.7
06/16/2015 12:33
MHALL3
1
EPA 200.7
06/16/2015 12:33
MHALL3
1
EPA 200.7
06/16/2015 12:33
MHALL3
1
EPA 200.7
06/16/2015 12:33
MHALL3
1
EPA 200.7
06/16/2015 12:33
MHALL3
1
EPA 200.7
06/16/2015 12:33
MHALL3
1
EPA 200.7
06/16/2015 12:33
MHALL3
10
EPA 200.7
06/19/2015 10:45
MHALL3
10
EPA 200.7
06/19/2015 10:45
MHALL3
10
EPA 200.7
06/19/2015 10:45
MHALL3
10
EPA 200.7
06/19/2015 10:45
MHALL3
1
EPA 200.7
06/18/2015 14:02
MHALL3
1
EPA 200.7
06/18/2015 14:02
MHALL3
1
EPA 200.7
06/18/2015 14:02
MHALL3
1
EPA 200.7
06/18/2015 14:02
MHALL3
1
EPA 200.7
06/18/2015 14:02
MHALL3
1
EPA 200.7
06/18/2015 14:02
MHALL3
1
EPA 200.7
06/18/2015 14:02
MHALL3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060435
Site: ABMW-1
Collection Date: 11-Jun-15 1:20 PM
Analyte Result Units Qualifiers RDL
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
292
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
7.49
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
3.12
ug/L
0.3
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
299
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
7.43
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
0.254
ug/L
0.2
Vanadium (V) Low Level
3.38
ug/L
0.3
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter
Complete
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS 680 mg/L 25
Total Carbon
TOC 1.0 mg/L 0.1
Sample #: 2015019018
Matrix: GW WW
Analytical Lab
Page 5 of 99
DF
Method
Analysis Date/Time
Analyst
1
EPA 200.8
06/22/2015 08:03
SLS2560
1
EPA 200.8
06/22/2015 08:03
SLS2560
1
EPA 200.8
06/22/2015 08:03
SLS2560
1
EPA 200.8
06/22/2015 08:03
SLS2560
1
EPA 200.8
06/22/2015 08:03
SLS2560
1
EPA 200.8
06/22/2015 08:03
SLS2560
1
EPA 200.8
06/22/2015 08:03
SLS2560
1
EPA 200.8
06/22/2015 08:03
SLS2560
1
EPA 200.8
06/22/2015 08:03
SLS2560
1
EPA 200.8
06/22/2015 08:03
SLS2560
1
EPA 200.8
06/22/2015 08:03
SLS2560
1
EPA 200.8
06/22/2015 08:03
SLS2560
1
EPA 200.8
06/22/2015 08:03
SLS2560
1
EPA 200.8
06/22/2015 02:09
SLS2560
1
EPA 200.8
06/22/2015 02:09
SLS2560
1
EPA 200.8
06/22/2015 02:09
SLS2560
1
EPA 200.8
06/22/2015 02:09
SLS2560
1
EPA 200.8
06/22/2015 02:09
SLS2560
1
EPA 200.8
06/22/2015 02:09
SLS2560
1
EPA 200.8
06/22/2015 02:09
SLS2560
1
EPA 200.8
06/22/2015 02:09
SLS2560
1
EPA 200.8
06/22/2015 02:09
SLS2560
1
EPA 200.8
06/22/2015 02:09
SLS2560
1
EPA 200.8
06/22/2015 02:09
SLS2560
1
EPA 200.8
06/22/2015 02:09
SLS2560
1
EPA 200.8
06/22/2015 02:09
SLS2560
Vendor Method
V_SHEALY
Vendor Method v GEL
Vendor Method V_ELE1
1 SM2540C 06/16/201510:47 AGIBBS5
1 SM5310C/EPA9060A 06/26/201514:43 GHUTCHI

Analytical Lab
Certificate of Laboratory Analysis Page 6 of 99
This report shall not be reproduced, except in full.
Order # J15060435
Site: ABMW-1 Sample #: 2015019018
Collection Date: 11-Jun-15 1:20 PM Matrix: GW WW
Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst
TOTAL SUSPENDED SOLIDS
TSS 55 mg/L 5 1 SM2540D 06/15/201511:50 AGIBBS5

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060435
Site: ABMW-1 S
Collection Date: 11-Jun-15 2:27 PM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter
Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)
< 0.01
mg-N/L
B2 0.01
INORGANIC IONS BY IC
Chloride
39
mg/L
1
Sulfate
29
mg/L
1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
0.041
mg/L
0.005
Barium (Ba)
0.580
mg/L
0.005
Boron (B)
2.49
mg/L
0.05
Iron (Fe)
18.8
mg/L
0.01
Manganese (Mn)
1.14
mg/L
0.005
Strontium (Sr)
4.19
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
UNDIGESTED METALS BY lCP
Calcium (Ca)
132
mg/L
0.1
Magnesium (Mg)
18.5
mg/L
0.05
Potassium (K)
11.2
mg/L
1
Sodium (Na)
34.0
mg/L
0.5
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.048
mg/L
0.005
Barium (Ba)
0.601
mg/L
0.005
Boron (B)
2.55
mg/L
0.05
Iron (Fe)
19.6
mg/L
0.01
Manganese (Mn)
1.17
mg/L
0.005
Strontium (Sr)
4.33
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Sample #: 2015019019
Matrix: GW WW
Analytical Lab
Page 7 of 99
DF Method Analysis Date/Time Analyst
Vendor Method
V_SHEALY
1
EPA 353.2
06/23/2015 13:18
LSTARLI
10
EPA 300.0
06/16/2015 16:55
BGN9034
10
EPA 300.0
06/16/2015 16:55
BGN9034
1
EPA 245.1
06/16/2015 15:44
ACPAYNE
1
EPA 245.1
06/16/2015 12:26
ACPAYNE
1
EPA 200.7
06/16/2015 12:14
MHALL3
1
EPA 200.7
06/16/2015 12:14
MHALL3
1
EPA 200.7
06/16/2015 12:14
MHALL3
1
EPA 200.7
06/16/2015 12:14
MHALL3
1
EPA 200.7
06/16/2015 12:14
MHALL3
1
EPA 200.7
06/16/2015 12:14
MHALL3
1
EPA 200.7
06/16/2015 12:14
MHALL3
10
EPA 200.7
06/19/2015 10:48
MHALL3
10
EPA 200.7
06/19/2015 10:48
MHALL3
10
EPA 200.7
06/19/2015 10:48
MHALL3
10
EPA 200.7
06/19/2015 10:48
MHALL3
1
EPA 200.7
06/18/2015 14:13
MHALL3
1
EPA 200.7
06/18/2015 14:13
MHALL3
1
EPA 200.7
06/18/2015 14:13
MHALL3
1
EPA 200.7
06/18/2015 14:13
MHALL3
1
EPA 200.7
06/18/2015 14:13
MHALL3
1
EPA 200.7
06/18/2015 14:13
MHALL3
1
EPA 200.7
06/18/2015 14:13
MHALL3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060435
Site: ABMW-1 S
Collection Date: 11-Jun-15 2:27 PM
Analyte Result Units Qualifiers RDL
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
783
ug/L
10
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
1.33
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
25.6
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
833
ug/L
10
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
1.43
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
27.5
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
0.303
ug/L
0.3
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter
Complete
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS 530 mg/L 25
Total Carbon
TOC 1.3 mg/L 0.1
Sample #: 2015019019
Matrix: GW WW
Analytical Lab
Page 8 of 99
DF
Method
Analysis Date/Time
Analyst
1
EPA 200.8
06/23/2015 00:02
SLS2560
10
EPA 200.8
06/23/2015 00:02
SLS2560
1
EPA 200.8
06/23/2015 00:02
SLS2560
1
EPA 200.8
06/23/2015 00:02
SLS2560
1
EPA 200.8
06/23/2015 00:02
SLS2560
1
EPA 200.8
06/23/2015 00:02
SLS2560
1
EPA 200.8
06/23/2015 00:02
SLS2560
1
EPA 200.8
06/23/2015 00:02
SLS2560
1
EPA 200.8
06/23/2015 00:02
SLS2560
1
EPA 200.8
06/23/2015 00:02
SLS2560
1
EPA 200.8
06/23/2015 00:02
SLS2560
1
EPA 200.8
06/23/2015 00:02
SLS2560
1
EPA 200.8
06/23/2015 00:02
SLS2560
1
EPA 200.8
06/22/2015 01:47
SLS2560
10
EPA 200.8
06/22/2015 01:47
SLS2560
1
EPA 200.8
06/22/2015 01:47
SLS2560
1
EPA 200.8
06/22/2015 01:47
SLS2560
1
EPA 200.8
06/22/2015 01:47
SLS2560
1
EPA 200.8
06/22/2015 01:47
SLS2560
1
EPA 200.8
06/22/2015 01:47
SLS2560
1
EPA 200.8
06/22/2015 01:47
SLS2560
1
EPA 200.8
06/22/2015 01:47
SLS2560
1
EPA 200.8
06/22/2015 01:47
SLS2560
1
EPA 200.8
06/22/2015 01:47
SLS2560
1
EPA 200.8
06/22/2015 01:47
SLS2560
1
EPA 200.8
06/22/2015 01:47
SLS2560
Vendor Method
V_SHEALY
Vendor Method v GEL
Vendor Method V_ELE1
1 SM2540C 06/16/201510:47 AGIBBS5
1 SM5310C/EPA9060A 06/26/201514:43 GHUTCHI

Analytical Lab
Certificate of Laboratory Analysis Page 9 of 99
This report shall not be reproduced, except in full.
Order # J15060435
Site: ABMW-1 S Sample #: 2015019019
Collection Date: 11-Jun-15 2:27 PM Matrix: GW WW
Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst
TOTAL SUSPENDED SOLIDS
TSS 40 mg/L 5 1 SM2540D 06/15/201511:50 AGIBBS5

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060435
Site: AMW-9BC
Collection Date: 11-Jun-15 5:15 PM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter
Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)
< 0.01
mg-N/L
B2 0.01
INORGANIC IONS BY IC
Chloride
2.9
mg/L
0.1
Sulfate
0.82
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
0.010
mg/L
0.005
Barium (Ba)
0.262
mg/L
0.005
Boron (B)
0.072
mg/L
0.05
Iron (Fe)
2.58
mg/L
0.01
Manganese (Mn)
0.235
mg/L
0.005
Strontium (Sr)
0.091
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
37.0
mg/L
0.01
Magnesium (Mg)
7.77
mg/L
0.005
Potassium (K)
1.62
mg/L
0.1
Sodium (Na)
4.74
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.100
mg/L
0.005
Barium (Ba)
0.275
mg/L
0.005
Boron (B)
0.073
mg/L
0.05
Iron (Fe)
3.65
mg/L
0.01
Manganese (Mn)
0.249
mg/L
0.005
Strontium (Sr)
0.094
mg/L
0.005
Zinc (Zn)
0.006
mg/L
0.005
Sample #: 2015019020
Matrix: GW WW
Analytical Lab
Page 10 of 99
DF Method Analysis Date/Time Analyst
Vendor Method
V_SHEALY
1 EPA 353.2
06/23/2015 13:19
LSTARLI
1 EPA 300.0
06/17/2015 16:29
BGN9034
1 EPA 300.0
06/17/2015 16:29
BGN9034
1 EPA 245.1
06/16/2015 15:46
ACPAYNE
1 EPA 245.1
06/16/2015 12:29
ACPAYNE
1 EPA 200.7
06/16/2015 12:44
MHALL3
1 EPA 200.7
06/16/2015 12:44
MHALL3
1 EPA 200.7
06/16/2015 12:44
MHALL3
1 EPA 200.7
06/16/2015 12:44
MHALL3
1 EPA 200.7
06/16/2015 12:44
MHALL3
1 EPA 200.7
06/16/2015 12:44
MHALL3
1 EPA 200.7
06/16/2015 12:44
MHALL3
1 EPA 200.7
06/19/2015 10:14
MHALL3
1 EPA 200.7
06/19/2015 10:14
MHALL3
1 EPA 200.7
06/19/2015 10:14
MHALL3
1 EPA 200.7
06/19/2015 10:14
MHALL3
1 EPA 200.7
06/18/2015 14:17
MHALL3
1 EPA 200.7
06/18/2015 14:17
MHALL3
1 EPA 200.7
06/18/2015 14:17
MHALL3
1 EPA 200.7
06/18/2015 14:17
MHALL3
1 EPA 200.7
06/18/2015 14:17
MHALL3
1 EPA 200.7
06/18/2015 14:17
MHALL3
1 EPA 200.7
06/18/2015 14:17
MHALL3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060435
Site: AMW-9BC
Collection Date: 11-Jun-15 5:15 PM
Analyte Result Units Qualifiers RDL
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
160
mg/L
25
Total Carbon
TOC
3.3
mg/L
0.1
TOTAL SUSPENDED SOLIDS
TSS
12
mg/L
5
Sample #: 2015019020
Matrix: GW WW
Analytical Lab
Page 11 of 99
DF
Method
Analysis Date/Time
Analyst
1
EPA 200.8
06/23/2015 00:09
SLS2560
1
EPA 200.8
06/23/2015 00:09
SLS2560
1
EPA 200.8
06/23/2015 00:09
SLS2560
1
EPA 200.8
06/23/2015 00:09
SLS2560
1
EPA 200.8
06/23/2015 00:09
SLS2560
1
EPA 200.8
06/23/2015 00:09
SLS2560
1
EPA 200.8
06/23/2015 00:09
SLS2560
1
EPA 200.8
06/23/2015 00:09
SLS2560
1
EPA 200.8
06/23/2015 00:09
SLS2560
1
EPA 200.8
06/23/2015 00:09
SLS2560
1
EPA 200.8
06/23/2015 00:09
SLS2560
1
EPA 200.8
06/23/2015 00:09
SLS2560
1
EPA 200.8
06/23/2015 00:09
SLS2560
1
EPA 200.8
06/22/2015 02:16
SLS2560
1
EPA 200.8
06/22/2015 02:16
SLS2560
1
EPA 200.8
06/22/2015 02:16
SLS2560
1
EPA 200.8
06/22/2015 02:16
SLS2560
1
EPA 200.8
06/22/2015 02:16
SLS2560
1
EPA 200.8
06/22/2015 02:16
SLS2560
1
EPA 200.8
06/22/2015 02:16
SLS2560
1
EPA 200.8
06/22/2015 02:16
SLS2560
1
EPA 200.8
06/22/2015 02:16
SLS2560
1
EPA 200.8
06/22/2015 02:16
SLS2560
1
EPA 200.8
06/22/2015 02:16
SLS2560
1
EPA 200.8
06/22/2015 02:16
SLS2560
1
EPA 200.8
06/22/2015 02:16
SLS2560
Vendor Method
V_SHEALY
Vendor Method V_ELE1
1 SM2540C 06/16/201510:47 AGIBBS5
1 SM5310C/EPA9060A 06/26/201514:43 GHUTCHI
1 SM2540D 06/15/201511:50 AGIBBS5

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060435
Site: AMW-11 S
Collection Date: 11-Jun-15 9:18 AM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter
Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)
0.025
mg-N/L
0.01
INORGANIC IONS BY IC
Chloride
12
mg/L
1
Sulfate
6.2
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
0.103
mg/L
0.005
Barium (Ba)
0.115
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.036
mg/L
0.01
Manganese (Mn)
0.134
mg/L
0.005
Strontium (Sr)
0.031
mg/L
0.005
Zinc (Zn)
0.007
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
1.79
mg/L
0.01
Magnesium (Mg)
1.87
mg/L
0.005
Potassium (K)
1.26
mg/L
0.1
Sodium (Na)
6.09
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.109
mg/L
0.005
Barium (Ba)
0.119
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.060
mg/L
0.01
Manganese (Mn)
0.139
mg/L
0.005
Strontium (Sr)
0.031
mg/L
0.005
Zinc (Zn)
0.007
mg/L
0.005
Sample #: 2015019021
Matrix: GW WW
Analytical Lab
Page 12 of 99
DF Method Analysis Date/Time Analyst
Vendor Method
V_SHEALY
1
EPA 353.2
06/24/2015 14:50
LSTARLI
10
EPA 300.0
06/17/2015 16:45
BGN9034
1
EPA 300.0
06/17/2015 16:45
BGN9034
1
EPA 245.1
06/16/2015 15:49
ACPAYNE
1
EPA 245.1
06/16/2015 12:31
ACPAYNE
1
EPA 200.7
06/16/2015 12:48
MHALL3
1
EPA 200.7
06/16/2015 12:48
MHALL3
1
EPA 200.7
06/16/2015 12:48
MHALL3
1
EPA 200.7
06/16/2015 12:48
MHALL3
1
EPA 200.7
06/16/2015 12:48
MHALL3
1
EPA 200.7
06/16/2015 12:48
MHALL3
1
EPA 200.7
06/16/2015 12:48
MHALL3
1
EPA 200.7
06/19/2015 09:32
MHALL3
1
EPA 200.7
06/19/2015 09:32
MHALL3
1
EPA 200.7
06/19/2015 09:32
MHALL3
1
EPA 200.7
06/19/2015 09:32
MHALL3
1
EPA 200.7
06/18/2015 15:00
MHALL3
1
EPA 200.7
06/18/2015 15:00
MHALL3
1
EPA 200.7
06/18/2015 15:00
MHALL3
1
EPA 200.7
06/18/2015 15:00
MHALL3
1
EPA 200.7
06/18/2015 15:00
MHALL3
1
EPA 200.7
06/18/2015 15:00
MHALL3
1
EPA 200.7
06/18/2015 15:00
MHALL3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060435
Site: AMW-11 S
Collection Date: 11-Jun-15 9:18 AM
Analyte
Result
Units Qualifiers
RDL
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
8.69
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
3.49
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
9.13
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
3.52
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
48
mg/L
25
Total Carbon
TOC
0.655
mg/L
0.1
TOTAL SUSPENDED SOLIDS
TSS
< 5
mg/L
5
Sample #: 2015019021
Matrix: GW WW
Analytical Lab
Page 13 of 99
DF
Method
Analysis Date/Time
Analyst
1
EPA 200.8
06/23/2015 00:16
SLS2560
1
EPA 200.8
06/23/2015 00:16
SLS2560
1
EPA 200.8
06/23/2015 00:16
SLS2560
1
EPA 200.8
06/23/2015 00:16
SLS2560
1
EPA 200.8
06/23/2015 00:16
SLS2560
1
EPA 200.8
06/23/2015 00:16
SLS2560
1
EPA 200.8
06/23/2015 00:16
SLS2560
1
EPA 200.8
06/23/2015 00:16
SLS2560
1
EPA 200.8
06/23/2015 00:16
SLS2560
1
EPA 200.8
06/23/2015 00:16
SLS2560
1
EPA 200.8
06/23/2015 00:16
SLS2560
1
EPA 200.8
06/23/2015 00:16
SLS2560
1
EPA 200.8
06/23/2015 00:16
SLS2560
1
EPA 200.8
06/22/2015 02:23
SLS2560
1
EPA 200.8
06/22/2015 02:23
SLS2560
1
EPA 200.8
06/22/2015 02:23
SLS2560
1
EPA 200.8
06/22/2015 02:23
SLS2560
1
EPA 200.8
06/22/2015 02:23
SLS2560
1
EPA 200.8
06/22/2015 02:23
SLS2560
1
EPA 200.8
06/22/2015 02:23
SLS2560
1
EPA 200.8
06/22/2015 02:23
SLS2560
1
EPA 200.8
06/22/2015 02:23
SLS2560
1
EPA 200.8
06/22/2015 02:23
SLS2560
1
EPA 200.8
06/22/2015 02:23
SLS2560
1
EPA 200.8
06/22/2015 02:23
SLS2560
1
EPA 200.8
06/22/2015 02:23
SLS2560
Vendor Method
V_SHEALY
Vendor Method V_ELE1
1 SM2540C 06/16/201510:47 AGIBBS5
1 SM5310C/EPA9060A 06/26/201514:43 GHUTCHI
1 SM2540D 06/15/201511:50 AGIBBS5

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060435
Site: AMW-11S-Dup
Collection Date: 11-Jun-15 9:18 AM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter
Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)
0.023
mg-N/L
B2 0.01
INORGANIC IONS BY IC
Chloride
12
mg/L
1
Sulfate
5.8
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
0.103
mg/L
0.005
Barium (Ba)
0.117
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.037
mg/L
0.01
Manganese (Mn)
0.135
mg/L
0.005
Strontium (Sr)
0.032
mg/L
0.005
Zinc (Zn)
0.008
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
1.60
mg/L
0.01
Magnesium (Mg)
1.82
mg/L
0.005
Potassium (K)
1.23
mg/L
0.1
Sodium (Na)
5.98
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.110
mg/L
0.005
Barium (Ba)
0.120
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.057
mg/L
0.01
Manganese (Mn)
0.137
mg/L
0.005
Strontium (Sr)
0.031
mg/L
0.005
Zinc (Zn)
0.006
mg/L
0.005
Sample #: 2015019022
Matrix: GW WW
Analytical Lab
Page 14 of 99
DF Method Analysis Date/Time Analyst
Vendor Method
V_SHEALY
1
EPA 353.2
06/23/2015 13:52
LSTARLI
10
EPA 300.0
06/17/2015 17:02
BGN9034
1
EPA 300.0
06/17/2015 17:02
BGN9034
1
EPA 245.1
06/16/2015 15:51
ACPAYNE
1
EPA 245.1
06/16/2015 12:33
ACPAYNE
1
EPA 200.7
06/16/2015 12:52
MHALL3
1
EPA 200.7
06/16/2015 12:52
MHALL3
1
EPA 200.7
06/16/2015 12:52
MHALL3
1
EPA 200.7
06/16/2015 12:52
MHALL3
1
EPA 200.7
06/16/2015 12:52
MHALL3
1
EPA 200.7
06/16/2015 12:52
MHALL3
1
EPA 200.7
06/16/2015 12:52
MHALL3
1
EPA 200.7
06/19/2015 11:42
MHALL3
1
EPA 200.7
06/19/2015 11:42
MHALL3
1
EPA 200.7
06/19/2015 11:42
MHALL3
1
EPA 200.7
06/19/2015 11:42
MHALL3
1
EPA 200.7
06/18/2015 14:25
MHALL3
1
EPA 200.7
06/18/2015 14:25
MHALL3
1
EPA 200.7
06/18/2015 14:25
MHALL3
1
EPA 200.7
06/18/2015 14:25
MHALL3
1
EPA 200.7
06/18/2015 14:25
MHALL3
1
EPA 200.7
06/18/2015 14:25
MHALL3
1
EPA 200.7
06/18/2015 14:25
MHALL3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060435
Site: AMW-11S-Dup
Collection Date: 11-Jun-15 9:18 AM
Analyte Result Units Qualifiers RDL
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
8.58
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
3.25
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
8.61
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
3.07
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
47
mg/L
25
Total Carbon
TOC
0.687
mg/L
0.1
TOTAL SUSPENDED SOLIDS
TSS
< 5
mg/L
5
Sample #: 2015019022
Matrix: GW WW
Analytical Lab
Page 15 of 99
DF
Method
Analysis Date/Time
Analyst
1
EPA 200.8
06/23/2015 00:23
SLS2560
1
EPA 200.8
06/23/2015 00:23
SLS2560
1
EPA 200.8
06/23/2015 00:23
SLS2560
1
EPA 200.8
06/23/2015 00:23
SLS2560
1
EPA 200.8
06/23/2015 00:23
SLS2560
1
EPA 200.8
06/23/2015 00:23
SLS2560
1
EPA 200.8
06/23/2015 00:23
SLS2560
1
EPA 200.8
06/23/2015 00:23
SLS2560
1
EPA 200.8
06/23/2015 00:23
SLS2560
1
EPA 200.8
06/23/2015 00:23
SLS2560
1
EPA 200.8
06/23/2015 00:23
SLS2560
1
EPA 200.8
06/23/2015 00:23
SLS2560
1
EPA 200.8
06/23/2015 00:23
SLS2560
1
EPA 200.8
06/22/2015 02:30
SLS2560
1
EPA 200.8
06/22/2015 02:30
SLS2560
1
EPA 200.8
06/22/2015 02:30
SLS2560
1
EPA 200.8
06/22/2015 02:30
SLS2560
1
EPA 200.8
06/22/2015 02:30
SLS2560
1
EPA 200.8
06/22/2015 02:30
SLS2560
1
EPA 200.8
06/22/2015 02:30
SLS2560
1
EPA 200.8
06/22/2015 02:30
SLS2560
1
EPA 200.8
06/22/2015 02:30
SLS2560
1
EPA 200.8
06/22/2015 02:30
SLS2560
1
EPA 200.8
06/22/2015 02:30
SLS2560
1
EPA 200.8
06/22/2015 02:30
SLS2560
1
EPA 200.8
06/22/2015 02:30
SLS2560
Vendor Method
V_SHEALY
Vendor Method V_ELE1
1 SM2540C 06/16/201510:47 AGIBBS5
1 SM5310C/EPA9060A 06/26/201514:43 GHUTCHI
1 SM2540D 06/15/201511:50 AGIBBS5

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060435
Site: AMW-11 BC
Collection Date: 11-Jun-15 10:25 AM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter
Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)
< 0.01
mg-N/L
B2 0.01
INORGANIC IONS BY IC
Chloride
4.5
mg/L
0.1
Sulfate
< 0.1
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
0.009
mg/L
0.005
Barium (Ba)
0.007
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
2.37
mg/L
0.01
Manganese (Mn)
0.843
mg/L
0.005
Strontium (Sr)
0.033
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
14.1
mg/L
0.01
Magnesium (Mg)
3.57
mg/L
0.005
Potassium (K)
0.781
mg/L
0.1
Sodium (Na)
6.56
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.019
mg/L
0.005
Barium (Ba)
0.006
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
3.29
mg/L
0.01
Manganese (Mn)
0.983
mg/L
0.005
Strontium (Sr)
0.033
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Sample #: 2015019023
Matrix: GW WW
Analytical Lab
Page 16 of 99
DF Method Analysis Date/Time Analyst
Vendor Method
V_SHEALY
1 EPA 353.2
06/23/2015 13:53
LSTARLI
1 EPA 300.0
06/17/2015 17:18
BGN9034
1 EPA 300.0
06/17/2015 17:18
BGN9034
1 EPA 245.1
06/16/2015 15:53
ACPAYNE
1 EPA 245.1
06/16/2015 12:36
ACPAYNE
1 EPA 200.7
06/16/2015 12:56
MHALL3
1 EPA 200.7
06/16/2015 12:56
MHALL3
1 EPA 200.7
06/16/2015 12:56
MHALL3
1 EPA 200.7
06/16/2015 12:56
MHALL3
1 EPA 200.7
06/16/2015 12:56
MHALL3
1 EPA 200.7
06/16/2015 12:56
MHALL3
1 EPA 200.7
06/16/2015 12:56
MHALL3
1 EPA 200.7
06/19/2015 11:46
MHALL3
1 EPA 200.7
06/19/2015 11:46
MHALL3
1 EPA 200.7
06/19/2015 11:46
MHALL3
1 EPA 200.7
06/19/2015 11:46
MHALL3
1 EPA 200.7
06/18/2015 14:29
MHALL3
1 EPA 200.7
06/18/2015 14:29
MHALL3
1 EPA 200.7
06/18/2015 14:29
MHALL3
1 EPA 200.7
06/18/2015 14:29
MHALL3
1 EPA 200.7
06/18/2015 14:29
MHALL3
1 EPA 200.7
06/18/2015 14:29
MHALL3
1 EPA 200.7
06/18/2015 14:29
MHALL3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060435
Site: AMW-11 BC
Collection Date: 11-Jun-15 10:25 AM
Analyte Result Units Qualifiers RDL
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
1.86
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
1.05
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
1.63
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
86
mg/L
25
Total Carbon
TOC
8.0
mg/L
0.5
TOTAL SUSPENDED SOLIDS
TSS
7.0
mg/L
5
Sample #: 2015019023
Matrix: GW WW
Analytical Lab
Page 17 of 99
DF
Method
Analysis Date/Time
Analyst
1
EPA 200.8
06/23/2015 00:31
SLS2560
1
EPA 200.8
06/23/2015 00:31
SLS2560
1
EPA 200.8
06/23/2015 00:31
SLS2560
1
EPA 200.8
06/23/2015 00:31
SLS2560
1
EPA 200.8
06/23/2015 00:31
SLS2560
1
EPA 200.8
06/23/2015 00:31
SLS2560
1
EPA 200.8
06/23/2015 00:31
SLS2560
1
EPA 200.8
06/23/2015 00:31
SLS2560
1
EPA 200.8
06/23/2015 00:31
SLS2560
1
EPA 200.8
06/23/2015 00:31
SLS2560
1
EPA 200.8
06/23/2015 00:31
SLS2560
1
EPA 200.8
06/23/2015 00:31
SLS2560
1
EPA 200.8
06/23/2015 00:31
SLS2560
1
EPA 200.8
06/22/2015 10:03
SLS2560
1
EPA 200.8
06/22/2015 10:03
SLS2560
1
EPA 200.8
06/22/2015 10:03
SLS2560
1
EPA 200.8
06/22/2015 10:03
SLS2560
1
EPA 200.8
06/22/2015 10:03
SLS2560
1
EPA 200.8
06/22/2015 10:03
SLS2560
1
EPA 200.8
06/22/2015 10:03
SLS2560
1
EPA 200.8
06/22/2015 10:03
SLS2560
1
EPA 200.8
06/22/2015 10:03
SLS2560
1
EPA 200.8
06/22/2015 10:03
SLS2560
1
EPA 200.8
06/22/2015 10:03
SLS2560
1
EPA 200.8
06/22/2015 10:03
SLS2560
1
EPA 200.8
06/22/2015 10:03
SLS2560
Vendor Method
V_SHEALY
Vendor Method V_ELE1
1 SM2540C 06/16/201510:47 AGIBBS5
5 SM5310C/EPA9060A 06/26/201514:43 GHUTCHI
1 SM2540D 06/15/201511:50 AGIBBS5

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060435
Site: AMW-14S
Collection Date: 11-Jun-15 1:24 PM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter
Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)
< 0.01
mg-N/L
B2 0.01
INORGANIC IONS BY IC
Chloride
15
mg/L
1
Sulfate
31
mg/L
1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
0.056
mg/L
0.005
Barium (Ba)
0.091
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
15.2
mg/L
0.01
Manganese (Mn)
0.157
mg/L
0.005
Strontium (Sr)
0.066
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
6.07
mg/L
0.01
Magnesium (Mg)
3.57
mg/L
0.005
Potassium (K)
8.05
mg/L
0.1
Sodium (Na)
8.73
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.076
mg/L
0.005
Barium (Ba)
0.095
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
15.8
mg/L
0.01
Manganese (Mn)
0.160
mg/L
0.005
Strontium (Sr)
0.069
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Sample #: 2015019024
Matrix: GW WW
Analytical Lab
Page 18 of 99
DF Method Analysis Date/Time Analyst
Vendor Method
V_SHEALY
1
EPA 353.2
06/23/2015 13:54
LSTARLI
10
EPA 300.0
06/17/2015 14:50
BGN9034
10
EPA 300.0
06/17/2015 14:50
BGN9034
1
EPA 245.1
06/16/2015 15:56
ACPAYNE
1
EPA 245.1
06/16/2015 12:38
ACPAYNE
1
EPA 200.7
06/16/2015 12:59
MHALL3
1
EPA 200.7
06/16/2015 12:59
MHALL3
1
EPA 200.7
06/16/2015 12:59
MHALL3
1
EPA 200.7
06/16/2015 12:59
MHALL3
1
EPA 200.7
06/16/2015 12:59
MHALL3
1
EPA 200.7
06/16/2015 12:59
MHALL3
1
EPA 200.7
06/16/2015 12:59
MHALL3
1
EPA 200.7
06/19/2015 11:53
MHALL3
1
EPA 200.7
06/19/2015 11:53
MHALL3
1
EPA 200.7
06/19/2015 11:53
MHALL3
1
EPA 200.7
06/19/2015 11:53
MHALL3
1
EPA 200.7
06/18/2015 14:32
MHALL3
1
EPA 200.7
06/18/2015 14:32
MHALL3
1
EPA 200.7
06/18/2015 14:32
MHALL3
1
EPA 200.7
06/18/2015 14:32
MHALL3
1
EPA 200.7
06/18/2015 14:32
MHALL3
1
EPA 200.7
06/18/2015 14:32
MHALL3
1
EPA 200.7
06/18/2015 14:32
MHALL3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060435
Site: AMW-14S
Collection Date: 11-Jun-15 1:24 PM
Analyte Result Units Qualifiers RDL
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
2.10
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
5.92
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
2.10
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
6.05
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
0.373
ug/L
0.3
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
110
mg/L
25
Total Carbon
TOC
3.0
mg/L
0.1
TOTAL SUSPENDED SOLIDS
TSS
8.0
mg/L
5
Sample #: 2015019024
Matrix: GW WW
Analytical Lab
Page 19 of 99
DF
Method
Analysis Date/Time
Analyst
1
EPA 200.8
06/23/2015 06:04
SLS2560
1
EPA 200.8
06/23/2015 06:04
SLS2560
1
EPA 200.8
06/23/2015 06:04
SLS2560
1
EPA 200.8
06/23/2015 06:04
SLS2560
1
EPA 200.8
06/23/2015 06:04
SLS2560
1
EPA 200.8
06/23/2015 06:04
SLS2560
1
EPA 200.8
06/23/2015 06:04
SLS2560
1
EPA 200.8
06/23/2015 06:04
SLS2560
1
EPA 200.8
06/23/2015 06:04
SLS2560
1
EPA 200.8
06/23/2015 06:04
SLS2560
1
EPA 200.8
06/23/2015 06:04
SLS2560
1
EPA 200.8
06/23/2015 06:04
SLS2560
1
EPA 200.8
06/23/2015 06:04
SLS2560
1
EPA 200.8
06/22/2015 10:14
SLS2560
1
EPA 200.8
06/22/2015 10:14
SLS2560
1
EPA 200.8
06/22/2015 10:14
SLS2560
1
EPA 200.8
06/22/2015 10:14
SLS2560
1
EPA 200.8
06/22/2015 10:14
SLS2560
1
EPA 200.8
06/22/2015 10:14
SLS2560
1
EPA 200.8
06/22/2015 10:14
SLS2560
1
EPA 200.8
06/22/2015 10:14
SLS2560
1
EPA 200.8
06/22/2015 10:14
SLS2560
1
EPA 200.8
06/22/2015 10:14
SLS2560
1
EPA 200.8
06/22/2015 10:14
SLS2560
1
EPA 200.8
06/22/2015 10:14
SLS2560
1
EPA 200.8
06/22/2015 10:14
SLS2560
Vendor Method
V_SHEALY
Vendor Method V_ELE1
1 SM2540C 06/16/201515:52 AGIBBS5
1 SM5310C/EPA9060A 06/26/201514:43 GHUTCHI
1 SM2540D 06/16/2015 08:20 AGIBBS5

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060435
Site: AMW-14BC
Collection Date: 11-Jun-15 12:55 PM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter
Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)
0.020
mg-N/L
0.01
INORGANIC IONS BY IC
Chloride
21
mg/L
1
Sulfate
24
mg/L
1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
0.120
mg/L
0.005
Barium (Ba)
0.054
mg/L
0.005
Boron (B)
0.220
mg/L
0.05
Iron (Fe)
1.84
mg/L
0.01
Manganese (Mn)
0.110
mg/L
0.005
Strontium (Sr)
0.114
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
17.6
mg/L
0.01
Magnesium (Mg)
5.35
mg/L
0.005
Potassium (K)
5.13
mg/L
0.1
Sodium (Na)
38.1
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.080
mg/L
0.005
Barium (Ba)
0.058
mg/L
0.005
Boron (B)
0.225
mg/L
0.05
Iron (Fe)
1.96
mg/L
0.01
Manganese (Mn)
0.115
mg/L
0.005
Strontium (Sr)
0.119
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Sample #: 2015019025
Matrix: GW WW
Analytical Lab
Page 20 of 99
DF Method Analysis Date/Time Analyst
Vendor Method
V_SHEALY
1
EPA 353.2
06/24/2015 14:51
LSTARLI
10
EPA 300.0
06/17/2015 15:07
BGN9034
10
EPA 300.0
06/17/2015 15:07
BGN9034
1
EPA 245.1
06/16/2015 15:58
ACPAYNE
1
EPA 245.1
06/16/2015 12:50
ACPAYNE
1
EPA 200.7
06/16/2015 13:11
MHALL3
1
EPA 200.7
06/16/2015 13:11
MHALL3
1
EPA 200.7
06/16/2015 13:11
MHALL3
1
EPA 200.7
06/16/2015 13:11
MHALL3
1
EPA 200.7
06/16/2015 13:11
MHALL3
1
EPA 200.7
06/16/2015 13:11
MHALL3
1
EPA 200.7
06/16/2015 13:11
MHALL3
1
EPA 200.7
06/19/2015 12:01
MHALL3
1
EPA 200.7
06/19/2015 12:01
MHALL3
1
EPA 200.7
06/19/2015 12:01
MHALL3
1
EPA 200.7
06/19/2015 12:01
MHALL3
1
EPA 200.7
06/18/2015 14:36
MHALL3
1
EPA 200.7
06/18/2015 14:36
MHALL3
1
EPA 200.7
06/18/2015 14:36
MHALL3
1
EPA 200.7
06/18/2015 14:36
MHALL3
1
EPA 200.7
06/18/2015 14:36
MHALL3
1
EPA 200.7
06/18/2015 14:36
MHALL3
1
EPA 200.7
06/18/2015 14:36
MHALL3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060435
Site: AMW-14BC
Collection Date: 11-Jun-15 12:55 PM
Analyte Result Units Qualifiers RDL
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
3.59
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
0.256
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
3.80
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
180
mg/L
25
Total Carbon
TOC
2.0
mg/L
0.1
TOTAL SUSPENDED SOLIDS
TSS
10
mg/L
5
Sample #: 2015019025
Matrix: GW WW
Analytical Lab
Page 21 of 99
DF
Method
Analysis Date/Time
Analyst
1
EPA 200.8
06/23/2015 06:26
SLS2560
1
EPA 200.8
06/23/2015 06:26
SLS2560
1
EPA 200.8
06/23/2015 06:26
SLS2560
1
EPA 200.8
06/23/2015 06:26
SLS2560
1
EPA 200.8
06/23/2015 06:26
SLS2560
1
EPA 200.8
06/23/2015 06:26
SLS2560
1
EPA 200.8
06/23/2015 06:26
SLS2560
1
EPA 200.8
06/23/2015 06:26
SLS2560
1
EPA 200.8
06/23/2015 06:26
SLS2560
1
EPA 200.8
06/23/2015 06:26
SLS2560
1
EPA 200.8
06/23/2015 06:26
SLS2560
1
EPA 200.8
06/23/2015 06:26
SLS2560
1
EPA 200.8
06/23/2015 06:26
SLS2560
1
EPA 200.8
06/22/2015 10:22
SLS2560
1
EPA 200.8
06/22/2015 10:22
SLS2560
1
EPA 200.8
06/22/2015 10:22
SLS2560
1
EPA 200.8
06/22/2015 10:22
SLS2560
1
EPA 200.8
06/22/2015 10:22
SLS2560
1
EPA 200.8
06/22/2015 10:22
SLS2560
1
EPA 200.8
06/22/2015 10:22
SLS2560
1
EPA 200.8
06/22/2015 10:22
SLS2560
1
EPA 200.8
06/22/2015 10:22
SLS2560
1
EPA 200.8
06/22/2015 10:22
SLS2560
1
EPA 200.8
06/22/2015 10:22
SLS2560
1
EPA 200.8
06/22/2015 10:22
SLS2560
1
EPA 200.8
06/22/2015 10:22
SLS2560
Vendor Method
V_SHEALY
Vendor Method V_ELE1
1 SM2540C 06/16/201515:52 AGIBBS5
1 SM5310C/EPA9060A 06/26/201514:43 GHUTCHI
1 SM2540D 06/16/2015 08:20 AGIBBS5

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060435
Site: AMW-15S
Collection Date: 11-Jun-15 10:46 AM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter
Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)
< 0.01
mg-N/L
0.01
INORGANIC IONS BY IC
Chloride
12
mg/L
1
Sulfate
20
mg/L
1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
0.045
mg/L
0.005
Barium (Ba)
0.057
mg/L
0.005
Boron (B)
0.126
mg/L
0.05
Iron (Fe)
3.64
mg/L
0.01
Manganese (Mn)
0.072
mg/L
0.005
Strontium (Sr)
0.074
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
5.90
mg/L
0.01
Magnesium (Mg)
2.48
mg/L
0.005
Potassium (K)
4.02
mg/L
0.1
Sodium (Na)
8.25
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.149
mg/L
0.005
Barium (Ba)
0.062
mg/L
0.005
Boron (B)
0.124
mg/L
0.05
Iron (Fe)
3.95
mg/L
0.01
Manganese (Mn)
0.076
mg/L
0.005
Strontium (Sr)
0.076
mg/L
0.005
Zinc (Zn)
0.005
mg/L
0.005
Sample #: 2015019026
Matrix: GW WW
Analytical Lab
Page 22 of 99
DF Method Analysis Date/Time Analyst
Vendor Method
V_SHEALY
1
EPA 353.2
06/24/2015 14:53
LSTARLI
10
EPA 300.0
06/17/2015 15:23
BGN9034
10
EPA 300.0
06/17/2015 15:23
BGN9034
1
EPA 245.1
06/16/2015 16:10
ACPAYNE
1
EPA 245.1
06/16/2015 12:57
ACPAYNE
1
EPA 200.7
06/16/2015 13:15
MHALL3
1
EPA 200.7
06/16/2015 13:15
MHALL3
1
EPA 200.7
06/16/2015 13:15
MHALL3
1
EPA 200.7
06/16/2015 13:15
MHALL3
1
EPA 200.7
06/16/2015 13:15
MHALL3
1
EPA 200.7
06/16/2015 13:15
MHALL3
1
EPA 200.7
06/16/2015 13:15
MHALL3
1
EPA 200.7
06/19/2015 12:08
MHALL3
1
EPA 200.7
06/19/2015 12:08
MHALL3
1
EPA 200.7
06/19/2015 12:08
MHALL3
1
EPA 200.7
06/19/2015 12:08
MHALL3
1
EPA 200.7
06/18/2015 14:40
MHALL3
1
EPA 200.7
06/18/2015 14:40
MHALL3
1
EPA 200.7
06/18/2015 14:40
MHALL3
1
EPA 200.7
06/18/2015 14:40
MHALL3
1
EPA 200.7
06/18/2015 14:40
MHALL3
1
EPA 200.7
06/18/2015 14:40
MHALL3
1
EPA 200.7
06/18/2015 14:40
MHALL3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060435
Site: AMW-15S
Collection Date: 11-Jun-15 10:46 AM
Analyte Result Units Qualifiers RDL
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
1.71
ug/L
0.3
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
1.15
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
1.92
ug/L
0.3
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
73
mg/L
25
Total Carbon
TOC
3.4
mg/L
0.1
TOTAL SUSPENDED SOLIDS
TSS
< 5
mg/L
5
Sample #: 2015019026
Matrix: GW WW
Analytical Lab
Page 23 of 99
DF
Method
Analysis Date/Time
Analyst
1
EPA 200.8
06/23/2015 06:33
SLS2560
1
EPA 200.8
06/23/2015 06:33
SLS2560
1
EPA 200.8
06/23/2015 06:33
SLS2560
1
EPA 200.8
06/23/2015 06:33
SLS2560
1
EPA 200.8
06/23/2015 06:33
SLS2560
1
EPA 200.8
06/23/2015 06:33
SLS2560
1
EPA 200.8
06/23/2015 06:33
SLS2560
1
EPA 200.8
06/23/2015 06:33
SLS2560
1
EPA 200.8
06/23/2015 06:33
SLS2560
1
EPA 200.8
06/23/2015 06:33
SLS2560
1
EPA 200.8
06/23/2015 06:33
SLS2560
1
EPA 200.8
06/23/2015 06:33
SLS2560
1
EPA 200.8
06/23/2015 06:33
SLS2560
1
EPA 200.8
06/22/2015 10:29
SLS2560
1
EPA 200.8
06/22/2015 10:29
SLS2560
1
EPA 200.8
06/22/2015 10:29
SLS2560
1
EPA 200.8
06/22/2015 10:29
SLS2560
1
EPA 200.8
06/22/2015 10:29
SLS2560
1
EPA 200.8
06/22/2015 10:29
SLS2560
1
EPA 200.8
06/22/2015 10:29
SLS2560
1
EPA 200.8
06/22/2015 10:29
SLS2560
1
EPA 200.8
06/22/2015 10:29
SLS2560
1
EPA 200.8
06/22/2015 10:29
SLS2560
1
EPA 200.8
06/22/2015 10:29
SLS2560
1
EPA 200.8
06/22/2015 10:29
SLS2560
1
EPA 200.8
06/22/2015 10:29
SLS2560
Vendor Method
V_SHEALY
Vendor Method V_ELE1
1 SM2540C 06/16/201515:52 AGIBBS5
1 SM5310C/EPA9060A 06/26/201514:43 GHUTCHI
1 SM2540D 06/16/2015 08:20 AGIBBS5

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060435
Site: AMW-15BC
Collection Date: 11-Jun-15 11:30 AM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter
Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)
< 0.01
mg-N/L
0.01
INORGANIC IONS BY IC
Chloride
11
mg/L
1
Sulfate
14
mg/L
1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
0.081
mg/L
0.005
Barium (Ba)
0.044
mg/L
0.005
Boron (B)
0.170
mg/L
0.05
Iron (Fe)
1.30
mg/L
0.01
Manganese (Mn)
0.087
mg/L
0.005
Strontium (Sr)
0.084
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
12.2
mg/L
0.01
Magnesium (Mg)
5.45
mg/L
0.005
Potassium (K)
5.31
mg/L
0.1
Sodium (Na)
30.2
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.244
mg/L
0.005
Barium (Ba)
0.048
mg/L
0.005
Boron (B)
0.174
mg/L
0.05
Iron (Fe)
1.51
mg/L
0.01
Manganese (Mn)
0.090
mg/L
0.005
Strontium (Sr)
0.088
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Sample #: 2015019027
Matrix: GW WW
Analytical Lab
Page 24 of 99
DF Method Analysis Date/Time Analyst
Vendor Method
V_SHEALY
1
EPA 353.2
06/24/2015 14:54
LSTARLI
10
EPA 300.0
06/17/2015 15:40
BGN9034
10
EPA 300.0
06/17/2015 15:40
BGN9034
1
EPA 245.1
06/16/2015 16:17
ACPAYNE
1
EPA 245.1
06/16/2015 12:59
ACPAYNE
1
EPA 200.7
06/16/2015 14:19
MHALL3
1
EPA 200.7
06/16/2015 14:19
MHALL3
1
EPA 200.7
06/16/2015 14:19
MHALL3
1
EPA 200.7
06/16/2015 14:19
MHALL3
1
EPA 200.7
06/16/2015 14:19
MHALL3
1
EPA 200.7
06/16/2015 14:19
MHALL3
1
EPA 200.7
06/16/2015 14:19
MHALL3
1
EPA 200.7
06/19/2015 12:35
MHALL3
1
EPA 200.7
06/19/2015 12:35
MHALL3
1
EPA 200.7
06/19/2015 12:35
MHALL3
1
EPA 200.7
06/19/2015 12:35
MHALL3
1
EPA 200.7
06/18/2015 14:44
MHALL3
1
EPA 200.7
06/18/2015 14:44
MHALL3
1
EPA 200.7
06/18/2015 14:44
MHALL3
1
EPA 200.7
06/18/2015 14:44
MHALL3
1
EPA 200.7
06/18/2015 14:44
MHALL3
1
EPA 200.7
06/18/2015 14:44
MHALL3
1
EPA 200.7
06/18/2015 14:44
MHALL3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060435
Site: AMW-15BC
Collection Date: 11-Jun-15 11:30 AM
Analyte Result Units Qualifiers RDL
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
1.60
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
1.62
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
140
mg/L
25
Total Carbon
TOC
1.5
mg/L
0.1
TOTAL SUSPENDED SOLIDS
TSS
15
mg/L
5
Sample #: 2015019027
Matrix: GW WW
Analytical Lab
Page 25 of 99
DF
Method
Analysis Date/Time
Analyst
1
EPA 200.8
06/23/2015 06:41
SLS2560
1
EPA 200.8
06/23/2015 06:41
SLS2560
1
EPA 200.8
06/23/2015 06:41
SLS2560
1
EPA 200.8
06/23/2015 06:41
SLS2560
1
EPA 200.8
06/23/2015 06:41
SLS2560
1
EPA 200.8
06/23/2015 06:41
SLS2560
1
EPA 200.8
06/23/2015 06:41
SLS2560
1
EPA 200.8
06/23/2015 06:41
SLS2560
1
EPA 200.8
06/23/2015 06:41
SLS2560
1
EPA 200.8
06/23/2015 06:41
SLS2560
1
EPA 200.8
06/23/2015 06:41
SLS2560
1
EPA 200.8
06/23/2015 06:41
SLS2560
1
EPA 200.8
06/23/2015 06:41
SLS2560
1
EPA 200.8
06/22/2015 10:36
SLS2560
1
EPA 200.8
06/22/2015 10:36
SLS2560
1
EPA 200.8
06/22/2015 10:36
SLS2560
1
EPA 200.8
06/22/2015 10:36
SLS2560
1
EPA 200.8
06/22/2015 10:36
SLS2560
1
EPA 200.8
06/22/2015 10:36
SLS2560
1
EPA 200.8
06/22/2015 10:36
SLS2560
1
EPA 200.8
06/22/2015 10:36
SLS2560
1
EPA 200.8
06/22/2015 10:36
SLS2560
1
EPA 200.8
06/22/2015 10:36
SLS2560
1
EPA 200.8
06/22/2015 10:36
SLS2560
1
EPA 200.8
06/22/2015 10:36
SLS2560
1
EPA 200.8
06/22/2015 10:36
SLS2560
Vendor Method
V_SHEALY
Vendor Method V_ELE1
1 SM2540C 06/16/201515:52 AGIBBS5
1 SM5310C/EPA9060A 06/26/201514:43 GHUTCHI
1 SM2540D 06/16/2015 08:20 AGIBBS5

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060435
Site: AMW-15BC-Dup
Collection Date: 11-Jun-15 11:30 AM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter
Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)
< 0.01
mg-N/L
0.01
INORGANIC IONS BY IC
Chloride
11
mg/L
1
Sulfate
15
mg/L
1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
0.085
mg/L
0.005
Barium (Ba)
0.045
mg/L
0.005
Boron (B)
0.172
mg/L
0.05
Iron (Fe)
1.27
mg/L
0.01
Manganese (Mn)
0.087
mg/L
0.005
Strontium (Sr)
0.084
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
12.1
mg/L
0.01
Magnesium (Mg)
5.40
mg/L
0.005
Potassium (K)
5.25
mg/L
0.1
Sodium (Na)
30.3
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.260
mg/L
0.005
Barium (Ba)
0.047
mg/L
0.005
Boron (B)
0.173
mg/L
0.05
Iron (Fe)
1.49
mg/L
0.01
Manganese (Mn)
0.089
mg/L
0.005
Strontium (Sr)
0.086
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Sample #: 2015019028
Matrix: GW WW
Analytical Lab
Page 26 of 99
DF Method Analysis Date/Time Analyst
Vendor Method
V_SHEALY
1
EPA 353.2
06/24/2015 15:00
LSTARLI
10
EPA 300.0
06/17/2015 15:56
BGN9034
10
EPA 300.0
06/17/2015 15:56
BGN9034
1
EPA 245.1
06/16/2015 16:19
ACPAYNE
1
EPA 245.1
06/16/2015 13:02
ACPAYNE
1
EPA 200.7
06/16/2015 13:22
MHALL3
1
EPA 200.7
06/16/2015 13:22
MHALL3
1
EPA 200.7
06/16/2015 13:22
MHALL3
1
EPA 200.7
06/16/2015 13:22
MHALL3
1
EPA 200.7
06/16/2015 13:22
MHALL3
1
EPA 200.7
06/16/2015 13:22
MHALL3
1
EPA 200.7
06/16/2015 13:22
MHALL3
1
EPA 200.7
06/19/2015 12:31
MHALL3
1
EPA 200.7
06/19/2015 12:31
MHALL3
1
EPA 200.7
06/19/2015 12:31
MHALL3
1
EPA 200.7
06/19/2015 12:31
MHALL3
1
EPA 200.7
06/16/2015 15:37
MHALL3
1
EPA 200.7
06/16/2015 15:37
MHALL3
1
EPA 200.7
06/16/2015 15:37
MHALL3
1
EPA 200.7
06/16/2015 15:37
MHALL3
1
EPA 200.7
06/16/2015 15:37
MHALL3
1
EPA 200.7
06/16/2015 15:37
MHALL3
1
EPA 200.7
06/16/2015 15:37
MHALL3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060435
Site: AMW-15BC-Dup
Collection Date: 11-Jun-15 11:30 AM
Analyte Result Units Qualifiers RDL
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
1.70
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
1.79
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
0.363
ug/L
0.3
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
150
mg/L
25
Total Carbon
TOC
0.439
mg/L
0.1
TOTAL SUSPENDED SOLIDS
TSS
16
mg/L
5
Sample #: 2015019028
Matrix: GW WW
Analytical Lab
Page 27 of 99
DF
Method
Analysis Date/Time
Analyst
1
EPA 200.8
06/23/2015 06:48
SLS2560
1
EPA 200.8
06/23/2015 06:48
SLS2560
1
EPA 200.8
06/23/2015 06:48
SLS2560
1
EPA 200.8
06/23/2015 06:48
SLS2560
1
EPA 200.8
06/23/2015 06:48
SLS2560
1
EPA 200.8
06/23/2015 06:48
SLS2560
1
EPA 200.8
06/23/2015 06:48
SLS2560
1
EPA 200.8
06/23/2015 06:48
SLS2560
1
EPA 200.8
06/23/2015 06:48
SLS2560
1
EPA 200.8
06/23/2015 06:48
SLS2560
1
EPA 200.8
06/23/2015 06:48
SLS2560
1
EPA 200.8
06/23/2015 06:48
SLS2560
1
EPA 200.8
06/23/2015 06:48
SLS2560
1
EPA 200.8
06/22/2015 12:24
SLS2560
1
EPA 200.8
06/22/2015 12:24
SLS2560
1
EPA 200.8
06/22/2015 12:24
SLS2560
1
EPA 200.8
06/22/2015 12:24
SLS2560
1
EPA 200.8
06/22/2015 12:24
SLS2560
1
EPA 200.8
06/22/2015 12:24
SLS2560
1
EPA 200.8
06/22/2015 12:24
SLS2560
1
EPA 200.8
06/22/2015 12:24
SLS2560
1
EPA 200.8
06/22/2015 12:24
SLS2560
1
EPA 200.8
06/22/2015 12:24
SLS2560
1
EPA 200.8
06/22/2015 12:24
SLS2560
1
EPA 200.8
06/22/2015 12:24
SLS2560
1
EPA 200.8
06/22/2015 12:24
SLS2560
Vendor Method
V_SHEALY
Vendor Method V_ELE1
1 SM2540C 06/16/201515:52 AGIBBS5
1 SM5310C/EPA9060A 06/26/201514:43 GHUTCHI
1 SM2540D 06/16/2015 08:20 AGIBBS5

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060435
Site: MW-3
Collection Date: 11-Jun-15 5:30 PM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter
Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)
< 0.01
mg-N/L
M2, B2 0.01
INORGANIC IONS BY IC
Chloride
26
mg/L
1
Sulfate
58
mg/L
1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
0.066
mg/L
0.005
Barium (Ba)
0.344
mg/L
0.005
Boron (B)
2.23
mg/L
0.05
Iron (Fe)
27.1
mg/L
0.01
Manganese (Mn)
1.98
mg/L
0.005
Strontium (Sr)
4.06
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
127
mg/L
0.1
Magnesium (Mg)
19.2
mg/L
0.05
Potassium (K)
12.3
mg/L
1
Sodium (Na)
32.8
mg/L
0.5
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.226
mg/L
0.005
Barium (Ba)
0.355
mg/L
0.005
Boron (B)
2.24
mg/L
0.05
Iron (Fe)
28.2
mg/L
0.01
Manganese (Mn)
2.00
mg/L
0.005
Strontium (Sr)
4.16
mg/L
0.005
Zinc (Zn)
0.009
mg/L
0.005
Sample #: 2015019029
Matrix: GW WW
Analytical Lab
Page 28 of 99
DF Method Analysis Date/Time Analyst
Vendor Method
V_SHEALY
1
EPA 353.2
06/23/2015 13:47
LSTARLI
10
EPA 300.0
06/17/2015 16:12
BGN9034
10
EPA 300.0
06/17/2015 16:12
BGN9034
1
EPA 245.1
06/16/2015 16:22
ACPAYNE
1
EPA 245.1
06/16/2015 13:04
ACPAYNE
1
EPA 200.7
06/16/2015 13:26
MHALL3
1
EPA 200.7
06/16/2015 13:26
MHALL3
1
EPA 200.7
06/16/2015 13:26
MHALL3
1
EPA 200.7
06/16/2015 13:26
MHALL3
1
EPA 200.7
06/16/2015 13:26
MHALL3
1
EPA 200.7
06/16/2015 13:26
MHALL3
1
EPA 200.7
06/16/2015 13:26
MHALL3
10
EPA 200.7
06/19/2015 10:52
MHALL3
10
EPA 200.7
06/19/2015 10:52
MHALL3
10
EPA 200.7
06/19/2015 10:52
MHALL3
10
EPA 200.7
06/19/2015 10:52
MHALL3
1
EPA 200.7
06/16/2015 15:41
MHALL3
1
EPA 200.7
06/16/2015 15:41
MHALL3
1
EPA 200.7
06/16/2015 15:41
MHALL3
1
EPA 200.7
06/16/2015 15:41
MHALL3
1
EPA 200.7
06/16/2015 15:41
MHALL3
1
EPA 200.7
06/16/2015 15:41
MHALL3
1
EPA 200.7
06/16/2015 15:41
MHALL3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060435
Site: MW-3
Collection Date: 11-Jun-15 5:30 PM
Analyte Result Units Qualifiers RDL
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
444
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
5.76
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
22.2
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
445
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
5.61
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
21.1
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
0.305
ug/L
0.3
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
510
mg/L
25
Total Carbon
TOC
1.3
mg/L
0.1
TOTAL SUSPENDED SOLIDS
TSS
61
mg/L
5
Sample #: 2015019029
Matrix: GW WW
Analytical Lab
Page 29 of 99
DF
Method
Analysis Date/Time
Analyst
1
EPA 200.8
06/23/2015 07:17
SLS2560
1
EPA 200.8
06/23/2015 07:17
SLS2560
1
EPA 200.8
06/23/2015 07:17
SLS2560
1
EPA 200.8
06/23/2015 07:17
SLS2560
1
EPA 200.8
06/23/2015 07:17
SLS2560
1
EPA 200.8
06/23/2015 07:17
SLS2560
1
EPA 200.8
06/23/2015 07:17
SLS2560
1
EPA 200.8
06/23/2015 07:17
SLS2560
1
EPA 200.8
06/23/2015 07:17
SLS2560
1
EPA 200.8
06/23/2015 07:17
SLS2560
1
EPA 200.8
06/23/2015 07:17
SLS2560
1
EPA 200.8
06/23/2015 07:17
SLS2560
1
EPA 200.8
06/23/2015 07:17
SLS2560
1
EPA 200.8
06/22/2015 12:32
SLS2560
1
EPA 200.8
06/22/2015 12:32
SLS2560
1
EPA 200.8
06/22/2015 12:32
SLS2560
1
EPA 200.8
06/22/2015 12:32
SLS2560
1
EPA 200.8
06/22/2015 12:32
SLS2560
1
EPA 200.8
06/22/2015 12:32
SLS2560
1
EPA 200.8
06/22/2015 12:32
SLS2560
1
EPA 200.8
06/22/2015 12:32
SLS2560
1
EPA 200.8
06/22/2015 12:32
SLS2560
1
EPA 200.8
06/22/2015 12:32
SLS2560
1
EPA 200.8
06/22/2015 12:32
SLS2560
1
EPA 200.8
06/22/2015 12:32
SLS2560
1
EPA 200.8
06/22/2015 12:32
SLS2560
Vendor Method
V_SHEALY
Vendor Method V_ELE1
1 SM2540C 06/16/201515:52 AGIBBS5
1 SM5310C/EPA9060A 06/26/201514:43 GHUTCHI
1 SM2540D 06/16/2015 08:20 AGIBBS5

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060435
Site: Filter Blank
Collection Date: 11-Jun-15 8:00 AM
Analyte
Result
Units
Qualifiers RDL
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
< 0.005
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
< 0.005
mg/L
0.005
Strontium (Sr)
< 0.005
mg/L
0.005
Zinc (Zn)
0.007
mg/L
0.005
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
Sample #: 2015019030
Matrix: GW WW
Analytical Lab
Page 30 of 99
DF
Method
Analysis Date/Time
Analyst
1
EPA 245.1
06/16/2015 13:07
ACPAYNE
1
EPA 200.7
06/16/2015 14:02
MHALL3
1
EPA 200.7
06/16/2015 14:02
MHALL3
1
EPA 200.7
06/16/2015 14:02
MHALL3
1
EPA 200.7
06/16/2015 14:02
MHALL3
1
EPA 200.7
06/16/2015 14:02
MHALL3
1
EPA 200.7
06/16/2015 14:02
MHALL3
1
EPA 200.7
06/16/2015 14:02
MHALL3
1
EPA 200.8
06/23/2015 07:24
SLS2560
1
EPA 200.8
06/23/2015 07:24
SLS2560
1
EPA 200.8
06/23/2015 07:24
SLS2560
1
EPA 200.8
06/23/2015 07:24
SLS2560
1
EPA 200.8
06/23/2015 07:24
SLS2560
1
EPA 200.8
06/23/2015 07:24
SLS2560
1
EPA 200.8
06/23/2015 07:24
SLS2560
1
EPA 200.8
06/23/2015 07:24
SLS2560
1
EPA 200.8
06/23/2015 07:24
SLS2560
1
EPA 200.8
06/23/2015 07:24
SLS2560
1
EPA 200.8
06/23/2015 07:24
SLS2560
1
EPA 200.8
06/23/2015 07:24
SLS2560
1
EPA 200.8
06/23/2015 07:24
SLS2560

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060435
Site: Equipment Blank
Collection Date: 11-Jun-15 8:00 AM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy
Labs)
Vendor Parameter
Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)
< 0.01
mg-N/L
B2 0.01
INORGANIC IONS BY IC
Chloride
< 0.1
mg/L
0.1
Sulfate
< 0.1
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
UNDIGESTED METALS BY lCP
Calcium (Ca)
0.015
mg/L
0.01
Magnesium (Mg)
< 0.005
mg/L
0.005
Potassium (K)
< 0.1
mg/L
0.1
Sodium (Na)
< 0.05
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
< 0.005
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
< 0.005
mg/L
0.005
Strontium (Sr)
< 0.005
mg/L
0.005
Zinc (Zn)
0.006
mg/L
0.005
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
Analytical Lab
Page 31 of 99
Sample #: 2015019031
Matrix: GW WW
DF Method Analysis Date/Time Analyst
Vendor Method V_SHEALY
1 EPA 353.2
06/23/2015 13:21
LSTARLI
1 EPA 300.0
06/17/2015 20:02
BGN9034
1 EPA 300.0
06/17/2015 20:02
BGN9034
1 EPA 245.1
06/16/2015 16:24
ACPAYNE
1 EPA 200.7
06/19/2015 09:44
MHALL3
1 EPA 200.7
06/19/2015 09:44
MHALL3
1 EPA 200.7
06/19/2015 09:44
MHALL3
1 EPA 200.7
06/19/2015 09:44
MHALL3
1 EPA 200.7
06/16/2015 15:53
MHALL3
1 EPA 200.7
06/16/2015 15:53
MHALL3
1 EPA 200.7
06/16/2015 15:53
MHALL3
1 EPA 200.7
06/16/2015 15:53
MHALL3
1 EPA 200.7
06/16/2015 15:53
MHALL3
1 EPA 200.7
06/16/2015 15:53
MHALL3
1 EPA 200.7
06/16/2015 15:53
MHALL3
1 EPA 200.8
06/22/2015 12:39
SLS2560
1 EPA 200.8
06/22/2015 12:39
SLS2560
1 EPA 200.8
06/22/2015 12:39
SLS2560
1 EPA 200.8
06/22/2015 12:39
SLS2560
1 EPA 200.8
06/22/2015 12:39
SLS2560
1 EPA 200.8
06/22/2015 12:39
SLS2560
1 EPA 200.8
06/22/2015 12:39
SLS2560
1 EPA 200.8
06/22/2015 12:39
SLS2560
1 EPA 200.8
06/22/2015 12:39
SLS2560
1 EPA 200.8
06/22/2015 12:39
SLS2560
1 EPA 200.8
06/22/2015 12:39
SLS2560
1 EPA 200.8
06/22/2015 12:39
SLS2560
1 EPA 200.8
06/22/2015 12:39
SLS2560
METHANE - (Analysis Performed by Shealy Labs)
Methane (CH4) Complete Vendor Method V_SHEALY

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060435
Site: Equipment Blank
Collection Date: 11-Jun-15 8:00 AM
Analyte Result Units Qualifiers RDL DF
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete
TOTAL DISSOLVED SOLIDS
TDS < 25 mg/L 25 1
Total Carbon
Sample #: 2015019031
Matrix: GW WW
Analytical Lab
Page 32 of 99
Method Analysis Date/Time Analyst
Vendor Method
V_ELE1
SM2540C 06/16/201515:52 AGIBBS5
TOC 0.249 mg/L 0.1 1 SM5310C/EPA9060A 06/26/201514:43 GHUTCHI
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L 5 1 SM2540D 06/16/2015 08:20 AGIBBS5
Qualifiers:
132 Target analyte was detected in blank(s) at a concentration greater than the reporting limit but less than the
reporting limit. Analyte concentration in sample is valid and may be used for compliance purposes.

Analytical Lab
Page 33 of 99
Element One lInc.
6319-D Carolina Beach Rd.
Wilmington, NC 28412
Phone: [phone]
Fax: [phone]
[e-mail]
eke entOne
REPORT OF ANALYSES
Duke Energy
June 22, 2015
Laboratory Services
Client Project Name AB GW Assessment
water (wells) HF Lee
13339 Hagers Ferry Road Bld. MG03A
Client Project Number
J15060435
Huntersville, NC 28078
PO Number
Sample Matrix GW WW
Sample Type Grab
Date
Received
06/15/2015
Date Analyzed 06/17/2015
Method SM 4500 Sz- D
Time
Received
1535
Delivered by FedEx
Received by
LLB
eOne ID Duke Energy ID
Parameter Result
Unit
Dil
DL
Date
Time
Sampled
Sampled
25078-1 ABMW-1
Sulfide < 0.1
mg/L
1
0.1
06/11/15
1320
25078-2 ABMW-1S
Sulfide <0.1
mg/L
1
0.1
06/11/15
1427
25078-3 ABMW-913C
Sulfide < 0.1
mg/L
1
0.1
06/11/15
1715
25078-4 ABMW-11S
Sulfide <0.1
mg/L
1
0.1
06/11/15
0918
25078-5 ABMW-11S Dup
Sulfide <0.1
mg/L
1
0.1
06/11/15
0918
25078-6 ABMW-11 BC
Sulfide < 0.1
mg/L
1
0.1
06/11/15
1025
25078-7 ABMW-14S
Sulfide 0.186
mg/L
1
0.1
06/11/15
1324
25078-8 ABMW-14BC
Sulfide < 0.1
mg/L
1
0.1
06/11/15
1255
— l( �Za
Ken Smith, Laboratory Director
25078 Duke Report Packet Compiled byAL-5
NC Certifications: DW 37788 and DWQ DENR 604

Analytical Lab
Page 34 of 99
Elerrneint One lnc.
6319-D Carolina Beach Rd.
Wilmington, IBC 28412
Phone: [phone]
Fax: [phone]
[e-mail]
REPORT OF ANALYSES
Duke Energy
June 22, 2015
Laboratory Services
Client Project Name AB GW Assessment water (wells) HF Lee
13339 Hagers Ferry Road Bld. MG03A Client Project Number J15060435
Huntersville, NC 28078
PO Number
Sample Matrix GW WW
Sample Type Grab Date Received
06/15/2015
Date Analyzed 06/17/2015
Method SM 4500 S2- D Time Received
1535
Delivered by FedEx
Received by
LLB
eOne ID Duke Energy ID
Parameter Result Unit Dil DL Date
Sampled
Time
Sampled
25078-9
ABMW-15S
Sulfide
0.552
mg/L
1
0.1
06/11/15
1046
25078-10*
ABMW-15BC
Sulfide
< 0.5
mg/L
5
0.1
06/11/15
1130
25078-11 *
ABMW-15BC Dup
Sulfide
< 0.5
mg/L
5
0.1
06/11/15
1130
25078-12*
MW-3
Sulfide
< 0.2
mg/L
2
0.1
06/11/15
1730
25078-13
Equipment Blank
Sulfide
< 0.1
mg/L
1
0.1
06/11/15
0800
*Sample spike recovery outside of QA limits of 85-115%; dilution necessary to meet laboratory QA limits.
Ken Smith, Laboratory Director
25078 Duke Report Packet Compiled bym
NC Certifications: DW 37788 and DWQ DENR 604

Analytical Lab
Page 35 of 99
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elementOne SAMPLE SUBMISSION FORM
TAT 7 BD
Hold Time Expiration 06.18.15 @ 0800
Client: Duke Energy
LIMS No J15060435
Project ID HF Lee
Analytical Lab
Lab I bage 2608
Analysis Due Date 06.17.15
Report Due Date 06.24.15
Date Rec: 06.15.15
Time Rec: 1535
Rec By LLB
/Ye5,' No
Tern p :5 6°C Yes No
Ref. Method:
SM4500 S2 D
�J�H'
f No, Record
If No, Record I
odmijiv munuiliuduun ag %,vilieution inivrinnation
Lab ID
Client ID
Collection Date
Collection Time
Analysis Requested
1
ABMW-1
06.11.15
1320
Sulfide-
2
ABMW-11S
06.11.15
1427
u
3
AMW-9BC
06.11.15
1715
Sulfid-9
4
AMW-1 1 S
06.11.15
0918
5
AMW-1 1 S Dup
06.11.15
0918 ("Sul...
6
AMW-11 1 BC
06.11.15
1025
ulfide
7
AMW-14S
06.11.15
1324
8
AMW-'1 4 B'C-
06.-1-1.15
1255
9
AMW-1 5S
06,11.15
1046
Sulfide
10
AMW-15BC
06.11.15
1130
lull E,
11
AMW-'1 5BC Dup'
0 11 6 - . - 1 1 1.15
11 - 30 1 <�
�Ulf
1-2
-MW-3
0 1 6 . - 1 - 1 - 1 1 5
1730 1 .1
Sulfi
—1,3
Equipment Blank
06AT1 5
0800
NOTE for
Sulfide The MS/MSD spike should
I
approximate 2 to 3
times the sample concentration.
If no sulfide detected
at 100 pg/L spike the sample
to render the final
spike concentration at
— 500 pg/L
SS Page 1 1
SS by
6/16/2015 11:24:41 AM
Prep By Date e/5,
Labeled By / Date
ID Verification By /Date �

Analytical Lab
Page 37 of 99
IMETHOD: SM 4500 S2- D ELEMENT ONE I
ELEMENT ASSAY:
Sulfide
Spectrophotometer
Wave Length 664
CLIENT:
Duke
Lab ID#
25070/ 0741075/ 076/
018/067aL709-0
Na2S-9H2O Lot#
40721
Date:
06/17/15
Time Analysis Begun
8:00
Time Analysis Ended
16:00
Analyst:
KAM
x
Y
ug STD
STD
SOLUTION
ABS
0.00
(TO -00
1.00
0.092
2.50
0.210
5.00
0.407
7.50
0.591
10.00
0.779
ANDARD conc(ppm)
I Std Lot: SD-O'
' Std Lot: SD-O'
'D ABSORPTION
0.600
01M
I'M
.500
y
0,400
0'"
0.200
A07-
- - ---------
01M
2.. AM nm A-
x
ALI in mL PREP
ANALYZED VOL in mL
e O�077597802Correlation
0.99967031
SAMPLE
I.D.
SAMP
ABS
ug PE
ALIQUQT
ALI in mL
TAKEN
RESULTS
ug/mL
LESS THAN
% SPK REC
SPIKE
LEVEL
Std. B. 0.00
0.000
0.0000
10
10
10
<
0.0
Std. B. 1.00
0.100
1.0651
10
10
10
0.107
106.51%
1.0
Std. B. 2.50
0.229
2.768$
10
10
10
0.277
110.74%
2.5
Std. B. 5.00
0.431
5.436
10
10
10
0.544
108.72%
5.0
Std. B. 7.50
0.610
7,799
10
10
10
0.780
104.00%
7.5
Std. B. 10.00
0.762
9.8061
10
10
10
0.981
98.07%
16.0
LRB
0.000
0.0000
10
10
10
At
0.0
LRB SPK
0.437
5.515g
10
10
10
0.552
111%
5.0
QC
0.446
5.6340
10
10
10
0.563
113%
5.0
25070-1
0.005
-0.1894
10
10
10
25070-1 splk
0.426
5.369T
10
10
10
0.537
107%
5.0
25070-2
0.007
-0.1630
10
10
10
25070-2 du p
0.011
-0.1102
10
10
10
< 0.1
25070-2 spk
0.407
1 5.1190
10
10
10
0.512
102%
5.0
25070-3
0.011
-0. 11 OF
10
10
10
<
25070-3 spk
0.295
3.6401
10
10
10
0.364
73%
5.0
25070-4
0.002
-0.229h
10
10
10
.0
25070-4 splk
0.440
5.554$
10
10
10
0.555
111%
5.0
25074-1
0.024
1 0.061$
10
10
10
<
25074-1spk
0.325
4.0362
10
10
10
0.404
81%
5.0
25074-2
0.014
-0.070
10
1 10
10
25074-2 spk
0.418
5.264
10
10
10
0.526
105%
5.0
25074-3
0.002
-0.229h
10
10
10
25074-3 spk
0.435
5.488$
10
10
10
0.549
110%
5.0
25075-1
0.009
-0.1366
10
10
10
<
25075-1spk
0.329
4.0890
10
10
10
0.409
82%
5.0
25075-2
0.007
-0.163
10
10
10
25075-2 sek
0.384
4.815$
10
10
10
0.482
96%
5.0
Blank
-0.001
0.0000
1 10
10
10
At
QC
1 0.438
5.528
10
10
10
0.553
111%
5.0
Submitted for QAIQC
- Date:06/
7/15
By: (Print)
KAM
a
(sign): 7-777,77
Page 1 of 6

Analytical Lab
Page 38 of 99
METHOD:
SM 45CIO
S2- D
ELEMENT ONE
ELEMENT ASSAY:
Sulfide
Spectrophotometer
Wave Length 664
UNITS OF ANSWER
ug/mL:
DETECTION LIMIT u
1.000
CLIENT:
Duke
SPK LEVEL u
5
Lab ID#
25070/074/075/ri6/
06/17/15
8:00
16:00
KAM
Y °
07$/ 089/ 090MAX ALIQUOT
Na2S•9H2O Lot # STANDARD conc(ppm)
40721 Cal Std Lot: SD-07-3
1 QC Std Lot: SD-07-4
STD ABSORPTION
10.00
Date:
X
Time Analysis Begun
10
Time Analysis Ended
10
Analyst:
Y
X
ug STD
SOLUTION
STD 0.800
-
-- --
ABS °'°°
------
--- --
-----
°�°°
wow
0.00
1.00
2.50
7.50
10.00
0.000
°.SW
-
0.092
0.4W
----
-
- x -
--
-
-,�
0.210
0.597
0.779
5D z.W <.OD 6. D °.� ,°�
X -
Sloe 0.077597802
Correlation 0:999670315
SAMPLE
I.D.
SAMP
ABS
ug PE
ALI QU
T
ALI in mL
ANALYZED
PREP
VOL in mL
ALI in mL
TAKEN
RESULTS
ug/mL
LESS THAN
% SPK REC
SPIKE
LEVEL
Std. B. 0.00
0.000
0.0000
10
10
10
<
0.0
Std. B. 1.00
0.100
1.06511
10
10
10
0.107
106.51 %
1.0
Std. B. 2.50
0.229
2.768
10
10
10
0.277
110.74%
2.5
Std. B. 5.00
0.431
5.4360
10
10
10
0.544
108.72%
5.0
Std. B. 7.50
0.610
7.799
10
10
10
0.780
104.00%
7.5
Std. B. 10.00
0.762
9.806
10
10
10
0.981
98.07%
10.0
LRB
0.000
0.0000
10
10
10
<
0.0
LRBSPK
0.437
5.515g
10
10
10
0.552
111%
5.0
QC
0.446
5.6340
10
10
10
0.563
113%
5.0
25075-3
0.017
-0.031g
10
10
10
<
25075-3 s k
0.334
4.1551
10
10
10
0.416
83%
5.0
25076-1
0.010
-0.1231
10
10
25076-1 du
0.007
-0.163
10
10
10
< 0.1
25076-1 s k
0.409
5.145
10
10
10
0.515
103%
5.0
25076-2
0.012
-0.0970
10
10
10
25076-2 s k
0,422
5.31711
10
10
10
0.532
106%
5.0
25076-3
0.006
-0,1762
10
10
10
<
25076-3 s k
0.287
3.5341
10
10
10
0.353
71 %
5.0
25076-4
0.004
-0.2026
10
10
10
77,
0&&
25076-4 s k
0.383
4.80211
10
10
10
0.480
96%
5.0
25077-1
0.012
-0.0970
10
10
10
25077-1 s k
0.385
4.828§
10
10
10
0.483
97%
5.0
25077-2
0.010
-0.1234
10
10
10
71 ;
25077-2 s k
0.400
5.0260
10
10
10
0.503
101 %
5.0
25077-3
0.009
-0.1366
10
10
10L
•gyp �``
25077-3 s k
0.374
4.683
10
10
10
0.468
94%
5.0
25077-4
0.002
-0.2291
10
10
10.
.0.1
25077-4 s k
0.423
5.3303
10
10
10
0.533
107%
5.0
Blank
0.000
0.0000
10
10
10
<
QC
0.435
5.4888
10 1
10
10
0.549
110%
5.0
Submitted fOr QA/QC- Date: 06/V/15
By: (Print)
KAM (sign):
Page 2 of 6

Analytical Lab
Page 39 of 99
METHOD:
SM 45 S
0 S2- D -
ELEMENT ONE
ELEMENT ASSAY:
Sulfide
Spectrophotometer
Wave Length 664
UNITS OF ANSWER
u /mL
DETECTION LIMELug)
1.000
CLIENT:
puke
SPK LEVEL u
5
Lab ID#
25070/ 074/ 075/ 0
6/ 078/ 089/ 090
Na2S•9H2O Lot#
40721
1
MAX ALIQUOT
10.00
Date:
06/17/15
STANDARD conc(ppm)
X
Time Analysis Begun
8:00
Cal Std Lot: SD-07-3
10
Time Analysis Ended
16:00
QC Std Lot: SD-07-4
10
Analyst:
KAM'
STD ABSORPTION
Y
X
Y
----- ---
ug STD
SOLUTION
STD �
ABS
°�
E00
000
2.50
7.50
10.00
0.000
0.210
0.597
0.779
0
0.5°0
-- ----
------
----
-
-.-x6x
r-`-------
-----------
�,000
°
.w 2W ,.W e.W a.w 10.w 12,W
x
Slope 0.077597802
Correlation 0.999670315
SAMPLE
I.D.
SAMP
ABS
ug PE
Al T
ALI in mL
ANALYZED
PREP
VOL in mL
ALI in mL
TAKEN
RESULTS
u /mL
LESS THAN
% SPK REC
SPIKE
LEVEL
Std. B. 0.00
0.000
0.000
10
10
10
<
0.0
Std. B. 1.00
0.100
1.0651
10
10
10
0.107
106.51 %
1.0
Std. B. 2.50
0.229
2.768
10
10
10
0.277
110.74%
2.5
Std. B. 5.00
0.431
5.4360
10
10
10
0.544
108.72%
5.0
Std. B. 7.50
0.610
7.7991
10
10
10
0.780
104.00%
7.5
Std. B. 10.00
0.762
9.806'
10
10
10
0.981
98.07%
10.0
LRB
0.000
O.00OQ
10
10
10
<
0.0
LRB SPK
0.437
5.5152
10
10
10
0.552
111%
5.0
QC
0.446
5.6340
10
10
10
0.563
113%
5.0
25078-1
0.057
0.4972
10
10
10
01
25078-1 s k
0.395
4.960
10
10
10
0.496
99%
5.0
25078-2
0.075
0.7349
10
10
10.0;1
, xw
25078-2 s k
0.424
5.3435
10
10
10
0.534
107%
5.0
25078-3
0.032
0.1671
10
10
10�fla1
25078-3 dup
0.034
0.193$
10
10
10
< 0.1
25078-3 spk
0.432
5.449
10
10
10
0.545
109%
5.0
25078-4
0.002
-0.2291
10
10
10
Q O;, ,
25078-4 s k
0.419
5.2775
10
10
10
0.528
106%
5.0
25078-5
0.006
-0.1762
10
10
10
25078-5 s k
0.417
5.2511
10
10
10
0.525
105%
5.0
25078-6
0.019
-0.0046
10
10
10
25078-6 s k
0.410
5.1587
10
10
10
0.516
103%
5.0
25078-7
0.160
1.8574
10
10
10
25078-7 s k
0.553
7.0470
10
10
10
0.705
104%
5.0
25078-8
0.055
0.4708
10
10
10
25078-8 s k
0.441
5.5689
10
10
10
0.557
111 %
5.0
25078-9
0.437
5.5152
10
10
10
0,52
25078-9 s k
0.770
9.9128
10
10
10
0.991
88%
5.0
Blank
-0.001
0.0000
10
10
10
<
QC
0.437
1 5.5152
10
10
10
0.552
110%
5.0
Submitted for QA/QC-
Date: 06/17/15
By: (Print)
KAM
(sign):
/
Page 3 of 6

Analytical Lab
Page 40 of 99
METHOD:
SM 4500 S2- D
ELEMENT ONE
ELEMENT ASSAY:
Sulfide
Spectrophotometer
Wave Length 664
UNITS OF ANSWER
ug/mL
DETECTI2U,6MEjqM
1.000
CLIENT:
Duke
SPK LEVEL u
5
Lab ID#
25070/ 0,74/ 075/ 076/ 078/,089/ 090,
06/17/15
8:00
16:00
KAM
y
MAX ALLO-UOT
Na2S-9H2O Lot# STANDARD conc(ppm)
40721 Cal Std Lot: SD-07-3
1 QC Std Lot: SD-07-4
ISTD ABSORPTION
10.00
x
10
10
Date:
Time Analysis Begun
Time Analysis Ended
Analyst:
x
1
ug STD STD
SOLUTION ABS
0.00 0.000
1.00 0.092
2.50 0.210
5.00 0.407
750 n 597
0.800
01mo
0.600
0.wo
o.30D
02M
0.100
0.00 200 4.W 800 8.00 low 12M
10.00 1 0.779 x
-;15
N� Slope 0.077697802 Correlation 0.0996703
SAMPLE SAMP ug PER ALI in ml- PREP ALI in mL RESULTS LESS THAN SPIKE
I.D. ABS ALIQUOT ANALYZED VOL in ml- TAKEN ug/mL % SPK REC LEVEL
Std. B. 0.00 0.000 0.0000 10 10 10 < 0.0
Std. B. 1.00 0.100 1.0651 10 10 10 0.107 106.51% 1.0
Std. B. 2.50 0.229 2.7685 10 10 10 0.277 110.74% 2.5
Std. B. 5.00 0.431 5.4360 10 10 10 0.544 108.72% 5.0
Std. B. 7.50 0.610 7.7997 10 10 10 0.780 104.00% 7.5
Std. B. 10.00 0.762 9.8069 10 10 10 0.981 98.07% 10.0
LRB 0.000 0.0000 10 10 10 < 0.0
LRB SPK 0.437 5.5152 10 10 10 0.552 111% 5.0
QC 0.446 5.6340 10 10 10 0.563 113% 5.0
25078-10 0.059 0.5236 10 10 10 <
25078-10 spk 0.178 2.0951 10 10 10 0.210 42% 5.0
25078-11 0.047 0.3652 10 10 10 <
25078-11 spk 0.180 2.1215 10 10 10 0.212 42% 5.0
25078-12 0.026 0.0879 10 10 10 <
25078-12 splk 0.338 4.2079 10 10 10 0.421 84% 5.0
25078-13 0.010 -0.1234 10 10 10
25078-13 du p 0.005 -0.1894 10 10 10 < 0.1
25078-13 splk 0.404 5.0794 10 10 10 0.508 102% 5.0
25089-1 0.019 -0.0046 10 10 10 <
25089-1spk 0.221 2.6629 10 10 10 0.266 53% 5.0
25089-2 0.027 0.1011 10 10 10 <
25089-2 spk 0.216 2.5969 10 10 10 0.260 52% 5.0
25089-3 0.006 -0.1762 10 10 10 <
25089-3 splk 0.329 4.0890 10 10 10 0.409 82% 5.0
25089-4 0.009 -0.1366 10 10 10
25089-4 spk 0.424 5.3435 10 10 10 0.534 107% 5.0
71
25090-1 0.145 1.6593 10 10 10 .0,966
25090-1spk 0.519 6.5980 10 10 10 0.660 99% 5.0
Blank -0.001 0.0000 10 10 10 <
QC 0.435 5,4888 10 10 10 0.549 110% 5.0
Submiffed for QAIQC - Date:06/17/15 By: (Print) -T- KAM
1(sign): 7 =777 7771
Page 4 of 6
0.00 200 4.W 800 8.00 low 12M
10.00 1 0.779 x
-;15
N� Slope 0.077697802 Correlation 0.0996703
SAMPLE SAMP ug PER ALI in ml- PREP ALI in mL RESULTS LESS THAN SPIKE
I.D. ABS ALIQUOT ANALYZED VOL in ml- TAKEN ug/mL % SPK REC LEVEL
Std. B. 0.00 0.000 0.0000 10 10 10 < 0.0
Std. B. 1.00 0.100 1.0651 10 10 10 0.107 106.51% 1.0
Std. B. 2.50 0.229 2.7685 10 10 10 0.277 110.74% 2.5
Std. B. 5.00 0.431 5.4360 10 10 10 0.544 108.72% 5.0
Std. B. 7.50 0.610 7.7997 10 10 10 0.780 104.00% 7.5
Std. B. 10.00 0.762 9.8069 10 10 10 0.981 98.07% 10.0
LRB 0.000 0.0000 10 10 10 < 0.0
LRB SPK 0.437 5.5152 10 10 10 0.552 111% 5.0
QC 0.446 5.6340 10 10 10 0.563 113% 5.0
25078-10 0.059 0.5236 10 10 10 <
25078-10 spk 0.178 2.0951 10 10 10 0.210 42% 5.0
25078-11 0.047 0.3652 10 10 10 <
25078-11 spk 0.180 2.1215 10 10 10 0.212 42% 5.0
25078-12 0.026 0.0879 10 10 10 <
25078-12 splk 0.338 4.2079 10 10 10 0.421 84% 5.0
25078-13 0.010 -0.1234 10 10 10
25078-13 du p 0.005 -0.1894 10 10 10 < 0.1
25078-13 splk 0.404 5.0794 10 10 10 0.508 102% 5.0
25089-1 0.019 -0.0046 10 10 10 <
25089-1spk 0.221 2.6629 10 10 10 0.266 53% 5.0
25089-2 0.027 0.1011 10 10 10 <
25089-2 spk 0.216 2.5969 10 10 10 0.260 52% 5.0
25089-3 0.006 -0.1762 10 10 10 <
25089-3 splk 0.329 4.0890 10 10 10 0.409 82% 5.0
25089-4 0.009 -0.1366 10 10 10
25089-4 spk 0.424 5.3435 10 10 10 0.534 107% 5.0
71
25090-1 0.145 1.6593 10 10 10 .0,966
25090-1spk 0.519 6.5980 10 10 10 0.660 99% 5.0
Blank -0.001 0.0000 10 10 10 <
QC 0.435 5,4888 10 10 10 0.549 110% 5.0
Submiffed for QAIQC - Date:06/17/15 By: (Print) -T- KAM
1(sign): 7 =777 7771
Page 4 of 6
Page 4 of 6

Analytical Lab
Page 41 of 99
METHOD:
SM 4500 S2- D
ELEMENT ONE
ELEMENT ASSAY:
Sulfide
Spectrophotometer
Wave Length 664
UNITS OF ANSWER
ug/mL
DETECTION LIMIT u
SPK LEVEL u
1.000
5
CLIENT:
Duke
Lab ID#
25070/ 074/ 075/ 076/ 078/ 089/ 090
Na2S•9H2O Lot #
40721
MAX ALIQUOT
10.00
Date:
06/17/15
STANDARD conc(ppm)
X
Time Analysis Begun
8:00
Cal Std Lot: SD-07-3
10
Time Analysis Ended
16:00
QC Std Lot: SD-0 7-4
10
Analyst:
KAM
STD ABSORPTION
Y
X
Y
ug STD
STD
SOLUTION
ABS
0.00
0.000
1.00
0.092
2.50
0.210
5.00
0.407
7.50
0.597
10.00
0.779
o.�
0.]00
0.B0D
o.
- ------
y
o40D
- ---- -
------ --
--
0.300
.-
0.
-
-----.-----
-
- -
------
O,ao
- --
- -
--
- ---
-----
-
--
-- -
0000
_sue
2.00 4.00 6.00 am 10.00 12.00
X
_..
,
PREP
VOL in mL
Sloe 0.077597802
Correlation 0.999670315
SAMPLE
I.D.
SAMP
ABS
ug PER
ALIQUOT
ALI in mL
ANALYZED
ALI in mL
TAKEN
RESULTS
ug/mL
LESS THAN
% SPK REC
SPIKE
LEVEL
Std. B. 0.00
0.000
0.0000
10
10
10
<
0.0
Std. B. 1.00
0.100
1.0651
10
10
10
0.107
106.51 %
1.0
Std. B. 2.50
0.229
2.7685
10
10
1 10
0.277
110.74%
2.5
Std. B. 5.00
0.431
5.4360
10
10
10
0.544
108.72%
5.0
Std. B. 7.50
0.610
1 7.7997
10
10
10
0.780
104.00%
7.5
Std. B. 10.00
0.762
1 9.8069
10
10
10
0.981
98.07%
10.0
LRB
0.000
0.0000
10
10
10
<
0.0
LRB SPK
0.437
5.5152
10
10
10
0.552
111%
5.0
QC
0.446
5.6340
10
10
10
0.563
113%
5.0
25090-2
0.026
0.0879
10
10
10
<
25090-2 spk
0.430
5.4228
10
10
10
0.542
108%
5.0
25090-3
0.008
-0.1498
10
10
10
<
25090-3 spk
0.427
5.3831
10
10
10
0.538
108%
5.0
24186-19.2 QC
0.258
3.1515
10
10
1
3.151
TV = 4.23
25070-3
0.007
-0.1630
10
10
5�_
25070-3 spk
0.362
4.5248
10
10
5
0.905
90%
5.0
25074-1
0.005
-0.1894
10
10
5`''
25074-1 s k
0.381
4.7757
10
10
5
0.955
96%
5.0
25075-1
0.002
-0.2291
10
10
5�
25075-1 s k
0.364
4.5512
10
10
5
0.910
91 %
5.0
25075-3
0.012
-0.0970
10
10
5
25075-3 spk
0.372
4.6569
10
10
5
0.931
93%
5.0
25076-3
0.002
-0.2291
10
10
5
17
25076-3 spk
0.357
4.4588
10
10
5
0.892
89%
5.0
25078-10
0.025
0.0747
10
10
5
<
25078-10 spk
0.279
3.4288
10
10
5
0.686
69%
5.0
25078-11
0.026
0.0879
10
10
5
<
25078-11 spk
0.259
3.1647
10
10
5
0.633
63%
5.0
Blank
0.000
0.0000
10
10
10
<
QC 0.435 5.4888 10
Submitted for QA/QC- Date: 06/17/15 1
10
By: (Print)
10 0.549
KAM
110% 5.0
(sign):
Page 5 of 6

Analytical Lab
Page 42 of 99
METHOD:
SM 4500 S2- D
ELEMENT ONE
ELEMENT ASSAY:
Sulfide
Spectrophotometer
Wave Length 664
UNITS OF ANSWER
u /ml.
DETECTION LIMIT u
1.000
CLIENT:
Duke
SPK LEVu
EL
5
Lab ID#
25070/ 074/ 075/ 076 078/ 089/ 090
Na2S•9H2O Lot #
40721
MAX ALIQUOT
10.00
Date:
06/17/1.5
STANDARD conc(ppm)
X
Time Analysis Begun
8:00
lCal Std Lot: SD-07-3
10
Time Analysis Ended
16:00
1 QC Std Lot: SD-07-4
10
Analyst:
KAM
STD ABSORPTION
Y
X
Y
a�
u.ea0
ug STD
SOLUTION
STD
ABS
0mo
0.00
1.00
500
7.50
10.00
0.000
0.092
0.407
0.597
0.779
0=
-,
Yam°
0.,00
- --
-- - ---
��--
--, -
---- -
- -- --
-sue
0.200
0.100-
L
-
- - --- --- - -
°°°°
000 200 4.00 &00 0.00 /0.00 11.00
i
s
..:'
Sloe 0.077597,802
Correlation 0:9996703151
SAMPLE
I.D.
SAMP
ABS
ug PER
ALIQUOT
ALI in mL
ANALYZED
PREP
VOL in mL
ALI in mL
TAKEN
RESULTS
ug/mL
LESS THAN
% SPK REC
SPIKE
LEVEL
Std. B. 0.00
0.000
0.0000
10
10
10
<
0.0
Std. B. 1.00
0.100
1.0651
10
10
10
0.107
106.51 %
1.0
Std. B. 2.50
0.229
2.7685
10
10
10
0.277
110.74%
2.5
Std. B. 5.00
0.431
5.4360
10
10
10
0.544
108.72%
5.0
Std. B. 7.50
0.610
7.7997
10
10
10
0.780
104.00%
7.5
Std. B. 10.00
0.762
9.8069
10
10
10
0.981
98.07%
10.0
LRB
0.000
0.0000
10
10
10
<
0.0
LRB SPK
0.437
5.5152
10
10
10
0.552
111 %
5.0
QC
0.446
5.6340
10
10
10
0.563
113%
5.0
25078-12
0.012
-0.0970
10
10
5
25078-12 s k
0.366
4.5776
10
10
5
0.916
92%
5.0
25089-1
0.014
-0.0706
10
10
5
<
25089-1 s k
0.321
3.9834
10
10
5
0.797
80%
5.0
25089-2
0.016
-0.0442
10
10
5
<
25089-2 spk
0.311
3.8513
10
10
5
0.770
77%
5.0
25089-3
0.002
-0.2291
10
10
5
25089-3 s k
0.364
4.5512
10
10
5
0.910
91 %
5.0
25078-10
0.017
-0.0310
10
10
2
25078-10 s k
0.383
4.8021
10
10
2
2.401
96%
5.0
25078-11
0.010
-0.1234
10
10
2
25078-11 s k
0.390
4.8946
10
10
2
2.447
98%
5.0
25089-1
0.013
-0.0838
10
10
2
25089-1 s k
0.399
5.0134
10
10
2
2.507
100%
5.0
25089-2
0.011
-0.1102
10
10
2
<
25089-2 s k
0.403
5.0662
10
10
2
2.533
101 %
5.0
Blank
0.000
0.0000
10
10
10
<
QC
0.439
5.5416
10
10
10
0.554
111 %
5.0
Submiffed for QA/QC- Date: 06/17/15
By: (Print)
KAM (sign):
Page 6 of 6

® Laboratories LLc
nalytical Lab
Crwge 43 of 99
a member of The GEL Group IN'.
P4 Box 30712 Charleston. SC 29417
2040 Sange Road Chad eston.SC29407
P 843556.8171
F 843.76Gi.1178
gel.com
June 26, 2015
Mary Ann Ogle
Duke Energy Analytical Laboratory
13339 Hagers Ferry Road
Mail Code: MGO3A2
Huntersville, North Carolina 28078
Re: AB GW Assessment Water
Work Order: 375273
SDG: J15060435
Dear Mary:
GEL Laboratories, LLC (GEL) appreciates the opportunity to provide the enclosed analytical results for the
sample(s) we received on June 17, 2015. This original data report has been prepared and reviewed in accordance
with GEL's standard operating procedures.
Our policy is to provide high quality, personalized analytical services to enable you to meet your analytical needs
on time every time. We trust that you will find everything in order and to your satisfaction. If you have any
questions, please do not hesitate to call me at [phone], ext. 4443.
Sincerely,
'Le
En�Trrent for
Lindsay Fabra
Project Manager
Purchase Order: 1142110
Enclosures
Pa

Analytical Lab
Page 44 of 99
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis Report
for
DUP0002 Duke Energy
Client SDG: J15060435 GEL Work Order: 375273
The Qualifiers in this report are defined as follows:
* A quality control analyte recovery is outside of specified acceptance criteria
** Analyte is a Tracer compound
** Analyte is a surrogate compound
U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless qualified on the Certificate of Analysis.
The designation ND, if present, appears in the result column when the analyte concentration is not detected above
the limit as defined in the 'U' qualifier above.
This data report has been prepared and reviewed in accordance with GEL Laboratories LLC
standard operating procedures. Please direct any questions to your Project Manager, Lindsay Fabra.
Reviewed by
Page 2 of 11

Analytical Lab
GEL LABORATORIES LLC Page 45 of 99
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company:
Duke Energy Analytical Laboratory
Address :
13339 Hagers Ferry Road
Mail Code: MG03A2
Huntersville, North Carolina 28078
Contact:
Mary Ann Ogle
Project:
AB GW Assessment Water
Client Sample ID:
Sample ID:
Matrix:
Collect Date:
Receive Date:
Collector:
2015014018
375273001
Ground Water
11-JUN-15 13 :20
17-JUN-15
Client
Report Date: June 26, 2015
Project: DUKE00225
Client ID: DUP0002
Parameter Qualifier Result DL RL Units DF Analyst Date Time Batch Method
Metals Analysis-ICP-MS
SW846 3010A/6020A Liquid "As Received"
Uranium-233 U 0.00
0.00001
0.00005
ug/mL
1
SKJ 06/25/15
1607 1486745 1
Uranium-234 U 0.00
0.00001
0.00005
ug/mL
1
Uranium-236 U 2.00E-06
0.00001
0.00005
ug/mL
1
Uranium-238 0.00187
0.000067
0.0002
ug/mL
1
SKJ 06/26/15
1206 1488565 2
Rad Gas Flow Proportional Counting
GFPC, Ra228, Liquid "As Received"
Radium-228 U 2.28
2.30
3.00
pCi/L
AXM6 06/25/15
1102 1486781 3
Rad Radium-226
Lucas Cell, Ra226, liquid "As Received"
Radium-226 0.812
0.656
1.00
pCi/L
CXP3 06/25/15
0720 1486765 4
The following Prep Methods were performed:
Method Description
Analyst
Date
Time Prep Batch
SW846 3010A SW 846 3010 Acid Digestion
JP1
06/25/15
1630
1488564
SW846 3010A SW 846 3010 Acid Digestion
JXM5
06/18/15
0700
1486744
The following Analytical Methods were performed:
Method Description
Analyst Comments
1 SW846 3010A/6020A
2 SW846 3010A/6020A
3 EPA 904.0/SW846 9320 Modified
4 EPA 903.1 Modified
Surrogate/Tracer Recovery Test
Result
Nominal
Recovery%
Acceptable Limits
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"
84.2
(15%-125%)
Notes:
Page 3 of 11

Analytical Lab
GEL LABORATORIES LLC Page 46 of 99
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis
Company:
Duke Energy Analytical Laboratory
Address :
13339 Hagers Ferry Road
Mail Code: MG03A2
Huntersville, North Carolina 28078
Contact:
Mary Ann Ogle
Project:
AB GW Assessment Water
Client Sample ID:
Sample ID:
Matrix:
Collect Date:
Receive Date:
Collector:
2015014019
375273002
Ground Water
11-JUN-15 14:27
17-JUN-15
Client
Report Date: June 26, 2015
Project: DUKE00225
Client ID: DUP0002
Parameter Qualifier Result DL RL Units DF Analyst Date Time Batch Method
Metals Analysis-ICP-MS
SW846 3010A/6020A Liquid "As Received"
Uranium-233 U 0.00
0.00001
0.00005
ug/mL
1
SKJ 06/25/15
1612 1486745 1
Uranium-234 U 0.00
0.00001
0.00005
ug/mL
1
Uranium-236 U 1.00E-06
0.00001
0.00005
ug/mL
1
Uranium-238 0.00172
0.000067
0.0002
ug/mL
1
SKJ 06/26/15
1211 1488565 2
Rad Gas Flow Proportional Counting
GFPC, Ra228, Liquid "As Received"
Radium-228 1.70
1.38
3.00
pCi/L
AXM6 06/25/15
1102 1486781 3
Rad Radium-226
Lucas Cell, Ra226, liquid "As Received"
Radium-226 U 0.456
0.670
1.00
pCi/L
CXP3 06/25/15
0720 1486765 4
The following Prep Methods were performed:
Method Description
Analyst
Date
Time Prep Batch
SW846 3010A SW 846 3010 Acid Digestion
JP1
06/25/15
1630
1488564
SW846 3010A SW 846 3010 Acid Digestion
JXM5
06/18/15
0700
1486744
The following Analytical Methods were performed:
Method Description
Analyst Comments
1 SW846 3010A/6020A
2 SW846 3010A/6020A
3 EPA 904.0/SW846 9320 Modified
4 EPA 903.1 Modified
Surrogate/Tracer Recovery Test
Result
Nominal
Recovery%
Acceptable Limits
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"
87.6
(15%-125%)
Notes:
Page 4 of 11

Analytical Lab
Page 47 of 99
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
QC Summary
Duke Energy Analytical Laboratory
13339 Hagers Ferry Road
Mail Code: MG03A2
Huntersville, North Carolina
Contact: Mary Ann Ogle
Workorder: 375273
Report Date: June 26, 2015
Page 1 of 3
Parmname
NOM
Sample
Qual
QC
Units
RPD%o
REC%
Range Anlst
Date Time
Metals Analysis - ICPMS
Batch 1486745
QC1203339548 375273001 DUP
Uranium-233
U
ND
U
ND
ug/mL
N/A
SKJ
06/25/1516:08
Uranium-234
U
ND
U
ND
ug/mL
N/A
Uranium-236
U
ND
U
ND
ug/mL
N/A
QC1203339553 LCS
Uranium-233
0.0005
0.000523
ug/mL
105
(80%-120%)
06/25/1516:05
Uranium-234
0.00055
0.000558
ug/mL
101
(80%-120%)
Uranium-236
0.005
0.00594
ug/mL
119
(80%-120%)
QC1203339546 MB
Uranium-233
U
ND
ug/mL
06/25/1516:04
Uranium-234
U
ND
ug/mL
Uranium-236
U
ND
ug/mL
QC1203339554 375273001 MS
Uranium-233
0.0005
U
ND
0.000515
ug/mL
103
(75%-125%)
06/25/1516:10
Uranium-234
0.00055
U
ND
0.00055
ug/mL
100
(75%-125%)
Uranium-236
0.005
U
ND
0.00584
ug/mL
117
(75%-125%)
QC1203339550 375273001 SDILT
Uranium-233
U
ND
U
ND
ug/L
N/A
06/25/1516:11
Uranium-234
U
ND
U
ND
ug/L
N/A
Uranium-236
U
ND
U
ND
ug/L
N/A
(0%-10%)
Batch 1488565
QC1203344264 375273001 DUP
Uranium-238
0.00187
0.00189
ug/mL
0.892
(0%-20%) SKJ
06/26/1512:07
QC1203344263 LCS
Uranium-238
0.0496
0.0552
ug/mL
111
(80%-120%)
06/26/1512:02
Page 5 of 11

Analytical Lab
Page 48 of 99
Workorder: 375273
Parmname
Metals Analysis - ICPMS
Batch 1488565
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
QC Summary
Page 2 of 3
NOM Sample Qual QC Units RPD% REC'%o Range Anlst Date Time
QC1203344262 MB
Uranium-238 U
ND
ug/mL
QC1203344265 375273001 MS
Uranium-238 0.0496 0.00187
0.0561
ug/mL
QC1203344266 375273001 SDILT
Uranium-238 1.87
0.401
ug/L 7.07
Rad Gas Flow
Batch 1486781
QC1203339632 375273001 DUP
Radium-228 U 2.28
2.17
pCi/L 5.26
QC1203339633 LCS
Radium-228 30.7
31.0
pCi/L
QC1203339631 MB
Radium-228
2.80
pCi/L
Rad Ra-226
Batch 1486765
QC1203339590 375273001 DUP
Radium-226 0.812
1.07
pCi/L 27.6
QC1203339592 LCS
Radium-226 24.7
24.8
pCi/L
QC1203339589 MB
Radium-226
0.718
pCi/L
QC1203339591 375273001 MS
Radium-226 124 0.812
123
pCi/L
Notes:
The Qualifiers in this report are defined as follows:
** Analyte is a Tracer compound
< Result is less than value reported
> Result is greater than value reported
BD Results are either below the MDC or tracer recovery is low
E %difference of sample and SD is >10%. Sample concentration must
meet flagging criteria
109 (75%-125%)
(0%-10%)
SKJ 06/26/1512:01
06/26/15 12:09
06/26/15 12:10
(0% - 100%) AXM6 06/25/15 11:03
101 (75%-125%) 06/25/1511:05
06/25/15 11:03
(0% - 100%) CXP3 06/25/15 07:20
100 (75%-125%) 06/25/15 07:55
06/25/15 07:20
99.1 (75%-125%) 06/25/15 07:55
Page 6of11

Analytical Lab
Page 49 of 99
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
QC Summary
Workorder: 375273 Page 3 of 3
Parmname NOM Sample Qual QC Units RPD% REC% Range Anlst Date Time
FA Failed analysis.
FB Mercury was found present at quantifiable concentrations in field blanks received with these samples. Data associated with the blank are deemed
invalid for reporting to regulatory agencies
H Analytical holding time was exceeded
J Value is estimated
K Analyte present. Reported value may be biased high. Actual value is expected to be lower.
L Analyte present. Reported value may be biased low. Actual value is expected to be higher.
M M if above MDC and less than LLD
M REMP Result > MDC/CL and < RDL
N Metals --The Matrix spike sample recovery is not within specified control limits
N/A RPD or %Recovery limits do not apply.
N1 See case narrative
ND Analyte concentration is not detected above the detection limit
NJ Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
Q One or more quality control criteria have not been met. Refer to the applicable narrative or DER.
R Sample results are rejected
U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
UI Gamma Spectroscopy --Uncertain identification
UJ Gamma Spectroscopy --Uncertain identification
UL Not considered detected. The associated number is the reported concentration, which may be inaccurate due to a low bias.
X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
Y Other specific qualifiers were required to properly define the results. Consult case narrative.
RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL. Qualifier Not Applicable for Radiochemistry.
h Preparation or preservation holding time was exceeded
N/A indicates that spike recovery limits do not apply when sample concentration exceeds spike cone. by a factor of 4 or more or %oRPD not applicable.
^ The Relative Percent Difference (RPD) obtained from the sample duplicate (DUP) is evaluated against the acceptance criteria when the sample is greater than
five times (5X) the contract required detection limit (RL). In cases where either the sample or duplicate value is less than 5X the RL, a control limit of +/- the
RL is used to evaluate the DUP result.
* Indicates that a Quality Control parameter was not within specifications.
For PS, PSD, and SDILT results, the values listed are the measured amounts, not final concentrations.
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless qualified on the QC Summary.
Page 7 of 11

I4
Analytical Lab
Page 50 of 99
C ... a
O I�
a ¢` o
punOjewnl peaisop
®1Pc-Ipul 88pkld jewolznO
J ar
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1
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Page 8 of 11

Analytical Lab
Page 51 of 99
Laboratories rc
SAMPLE RECEIPT & REVIEW FORM
i
Client:
SDG/AR/COC/Work Order:
Received By: UQ
Date Received:?
e *If Net Counts > 100cpm on samples not marked "radioactive", contact the Radiation Safety Group for further
Suspected Hazard Information
>"
investigation.
COC/Samples marked as radioactive?
Maximum Net Counts Observed* (Observed Counts - Area Background Counts):
Classified Radioactive tI or III by RSO?
if yes, Were swipes taken of sample containers < action levels?
COC/Samples marked containing PCBs?
Package, COC, and/or Samples marked as
beryllium or asbestos containing?
If yes, samples ate to be segregated its Safety Controlled Samples, and opened by the GEL Safety Group.
Shipped as a DOT hazardous?
azard Class Shipped: ITN#:
Samples identified as Foreign Soil?
Sample Receipt Criteria
Z z
CommenWQualifiers (Required for Non -Conforming Items)
Shipping containers received intact
Circle Applicable:
I
and sealed?
Seals broken Damaged container Liking container Other (describe)
Samples requiring cold preservation
r' Pmservatron Method* Ice bags Blue ice Dry ice None Otter (describe)
2
within (0 < 6 deg, C)?*
all temperatures are recorded in a 'ms
2a
Daily check perforated and passed on
Temperature Device Serial #:
Secondary Temperature Device Serial # (If Applicable): r rj r p
?
IR temperature gun.
Chain of custody documents included
3
with shipment?
Circle Applicable:
4
Sample containers intact and sealed?
Seals broken Damaged container Leaking container Other (describe)
Samples requiring chemical
Sample ID's, containers affected and observed pit:
5
preservation at proper pH?
If Preservation added Lot#:
Do Low Level Perchlorate samples
Sample ID's and containers affected:
6
(EPA 6850) have headspace as
required?
VOA vials free of headspace (defined
Sample to's and containers affected:
7
as < 6mm bubble)?
(If yes, immediately deliver to Volatiles laboratory)
8
Are Encore containers present?
Samples received within holding
ID's and tests affected:
9
time?
Sample ID's on COC match ID's on
Sample ID's and containers affected:
10
bottles?
Date & time on COC match date &
Sample In's affected:
it
time on bottles?
Number of containers received match
Sample ID's affected:
12
number indicated on COC?
Are sample containers identifiable as
13
GEL provided?
COC form is property signed in
14
relinquished/received sections?
Circle Applicable:
ti -
FedEx Air FedEx Ground UPS Field Services Courier Iher
15
Carrier and tracking number.
C
Comments (Use Continuation Form if needed):
PM(or PMA)review: Initials _f Date �1 Pageofk_ GL-OHL-SR-001 Rev 1
Page 9 of 11

Analytical Lab
Page 52 of 99
List of current GEL Certifications as of 26 June 2015
State
Certification
Alaska
UST-110
Arkansas
88-0651
CLIA
42DO904046
California
2940 Interim
Colorado
SC00012
Connecticut
PH-0169
Delaware
SC000122013-10
DoD ELAP/ ISO17025 A2LA
2567.01
Florida NELAP
E87156
Foreign Soils Permit
P330-12-00283, P330-12-00284
Georgia
SC00012
Georgia SDWA
967
Hawaii
SC000122013-10
Idaho Chemistry
SC00012
Idaho Radiochemistry
SC00012
Illinois NELAP
200029
Indiana
C—SC-01
Kansas NELAP
E-10332
Kentucky SDWA
90129
Kentucky Wastewater
90129
Louisiana NELAP
03046 (A133904)
Louisiana SDWA
LA150001
Maryland
270
Massachusetts
M—SCO 12
Michigan
9976
Mississippi
SC000122013-10
Nebraska
NE—OS-26-13
Nevada
SC000122014-1
New Hampshire NELAP
2054
New Jersey NELAP
SCO02
New Mexico
SC00012
New York NELAP
11501
North Carolina
233
North Carolina SDWA
45709
Oklahoma
9904
Pennsylvania NELAP
68-00485
Plant Material Permit
PDEP-12-00260
S.Carolina Radchem
10120002
South Carolina Chemistry
10120001
Tennessee
TN 02934
Texas NELAP
T104704235-15-10
Utah NELAP
SC000122015-17
Vermont
VT87156
Virginia NELAP
460202
Washington
C780
West Virginia
997404
Page 10 of 11

Analytical Lab
There are no "Data Exception Reports" associated with this analytical rel.53 of 99
Page 11 of 11

SHEALY ENVIRONMENTAL SERVICES, INC.
Report of Analysis
Duke Energy
13339 Hagers Ferry Rd
Bldg 7405
Huntersville, NC 28078
Attention: Mary Ann Ogle
Project Name: AB GW Assessment Water - HF Lee
Project Number:J15060435
Lot Number:QF15010
Date Completed:06/23/2015
Grant Wilton
Project Manager
This report shall not be reproduced, except in its entirety, without the written approval of Shealy Environmental Services, Inc.
The following non -paginated documents are considered part of this report: Chain of Custody Record and Sample Receipt Checklist.
* QF1 501 0*
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SHEALY ENVIRONMENTAL SERVICES, INC.
SC DHEC No: 32010 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
Case Narrative
Duke Energy
Lot Number: QF15010
Project Name: AB GW Assessment Water - HF Lee
Project Number: J15060435
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample
receiving date is documented in the header information associated with each sample.
All results listed in this report relate only to the samples that are contained within this report.
Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the
Shealy Environmental Services, Inc. ("Shealy") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPS), and Shealy
policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below.
If you have any questions regarding this report please contact the Shealy Project Manager listed on the cover page
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SHEALY ENVIRONMENTAL SERVICES, INC.
Sample Summary
Duke Energy
Lot Number: QF15010
Project Name: AB GW Assessment Water - HF Lee
Project Number: J15060435
Sample Number
Sample ID
Matrix
Date Sampled
Date Received
001
2015019018
Aqueous
06/11/20151320
06/15/2015
002
2015019019
Aqueous
06/11/20151427
06/15/2015
003
2015019020
Aqueous
06/11/20151715
06/15/2015
004
2015019021
Aqueous
06/11/2015 0918
06/15/2015
005
2015019022
Aqueous
06/11/2015 0918
06/15/2015
006
2015019023
Aqueous
06/11/20151025
06/15/2015
007
2015019024
Aqueous
06/11/20151324
06/15/2015
008
2015019025
Aqueous
06/11/20151255
06/15/2015
009
2015019026
Aqueous
06/11/20151046
06/15/2015
010
2015019027
Aqueous
06/11/20151130
06/15/2015
011
2015019028
Aqueous
06/11/20151130
06/15/2015
012
2015019029
Aqueous
06/11/20151730
06/15/2015
013
2015019031
Aqueous
06/11/2015 0800
06/15/2015
3 samples
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SHEALY ENVIRONMENTAL SERVICES, INC.
Executive Summary
Duke Energy
Lot Number: QF15010
Project Name: AB GW Assessment Water - HF Lee
Project Number: J15060435
Sample Sample ID
Matrix
Parameter Method
Result Q
Units
Page
001
2015019018
Aqueous
Alkalinity SM 2320B-
550
mg/L
5
001
2015019018
Aqueous
Bicarbonate Alkalinity SM 2320B-
550
mg/L
5
001
2015019018
Aqueous
Methane RSK - 175
580
ug/L
6
002
2015019019
Aqueous
Alkalinity SM 2320B-
380
mg/L
7
002
2015019019
Aqueous
Bicarbonate Alkalinity SM 2320B-
380
mg/L
7
002
2015019019
Aqueous
Methane RSK - 175
1000
ug/L
8
003
2015019020
Aqueous
Alkalinity SM 2320B-
130
mg/L
9
003
2015019020
Aqueous
Bicarbonate Alkalinity SM 2320B-
120
mg/L
9
003
2015019020
Aqueous
Methane RSK - 175
160
ug/L
10
006
2015019023
Aqueous
Alkalinity SM 2320B-
51
mg/L
15
006
2015019023
Aqueous
Bicarbonate Alkalinity SM 2320B-
51
mg/L
15
006
2015019023
Aqueous
Methane RSK - 175
21
ug/L
16
007
2015019024
Aqueous
Alkalinity SM 2320B-
23
mg/L
17
007
2015019024
Aqueous
Bicarbonate Alkalinity SM 2320B-
23
mg/L
17
007
2015019024
Aqueous
Methane RSK - 175
16
ug/L
18
008
2015019025
Aqueous
Alkalinity SM 2320B-
97
mg/L
19
008
2015019025
Aqueous
Bicarbonate Alkalinity SM 2320B-
96
mg/L
19
009
2015019026
Aqueous
Alkalinity SM 2320B-
18
mg/L
21
009
2015019026
Aqueous
Bicarbonate Alkalinity SM 2320B-
18
mg/L
21
009
2015019026
Aqueous
Methane RSK - 175
15
ug/L
22
010
2015019027
Aqueous
Alkalinity SM 2320B-
93
mg/L
23
010
2015019027
Aqueous
Bicarbonate Alkalinity SM 2320B-
92
mg/L
23
011
2015019028
Aqueous
Alkalinity SM 2320B-
92
mg/L
25
011
2015019028
Aqueous
Bicarbonate Alkalinity SM 2320B-
91
mg/L
25
011
2015019028
Aqueous
Methane RSK - 175
12
ug/L
26
012
2015019029
Aqueous
Alkalinity SM 2320B-
350
mg/L
27
012
2015019029
Aqueous
Bicarbonate Alkalinity SM 2320B-
350
mg/L
27
012
2015019029
Aqueous
Methane RSK - 175
290
ug/L
28
(28 detections)
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Inorganic non-metals
Client: Duke Energy Laboratory ID: QF15010-001
Description: 2015019018 Matrix: Aqueous
Date Sampled:06/11/2015 1320 Project Name: AB GW Assessment Water -
Date Received:06/15/2015 Project Number: J15060435
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 2320B-2011
1 06/17/2015 1907
HMA 77512
1
(Bicarbonate ) SM 2320B-2011
1 06/17/2015 1907
HKB
1
(Carbonate Al) SM 2320B-2011
1 06/17/2015 1907
HMA
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
550
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
550
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Methane
Client: Duke Energy Laboratory ID: QF15010-001
Description: 2015019018 Matrix: Aqueous
Date Sampled:06/11/2015 1320 Project Name: AB GW Assessment Water -
Date Received:06/15/2015 Project Number: J15060435
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 06/19/2015 1124 DCS 77688
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 580 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Inorganic non-metals
Client: Duke Energy Laboratory ID: QF15010-002
Description: 2015019019 Matrix: Aqueous
Date Sampled:06/11/2015 1427 Project Name: AB GW Assessment Water -
Date Received:06/15/2015 Project Number: J15060435
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 2320B-2011
1 06/17/2015 1916
HMA 77512
1
(Bicarbonate ) SM 2320B-2011
1 06/17/2015 1916
HKB
1
(Carbonate Al) SM 2320B-2011
1 06/17/2015 1916
HMA
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
380
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
380
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Methane
Client: Duke Energy Laboratory ID: QF15010-002
Description: 2015019019 Matrix: Aqueous
Date Sampled:06/11/2015 1427 Project Name: AB GW Assessment Water -
Date Received:06/15/2015 Project Number: J15060435
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
2 RSK - 175 5 06/19/2015 2015 JJG 77732
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 1000 50 ug/L 2
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Inorganic non-metals
Client: Duke Energy Laboratory ID: QF15010-003
Description: 2015019020 Matrix: Aqueous
Date Sampled:06/11/2015 1715 Project Name: AB GW Assessment Water -
Date Received:06/15/2015 Project Number: J15060435
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 2320B-2011
1 06/19/2015 1842
HMA 77674
1
(Bicarbonate ) SM 2320B-2011
1 06/19/2015 1842
HMA
1
(Carbonate Al) SM 2320B-2011
1 06/19/2015 1842
HMA
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
130
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
120
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Methane
Client: Duke Energy Laboratory ID: QF15010-003
Description: 2015019020 Matrix: Aqueous
Date Sampled:06/11/2015 1715 Project Name: AB GW Assessment Water -
Date Received:06/15/2015 Project Number: J15060435
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 06/19/2015 1257 DCS 77688
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 160 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Inorganic non-metals
Client: Duke Energy Laboratory ID: QF15010-004
Description: 2015019021 Matrix: Aqueous
Date Sampled:06/11/2015 0918 Project Name: AB GW Assessment Water -
Date Received:06/15/2015 Project Number: J15060435
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 2320B-2011
1 06/19/2015 1900
HMA 77674
1
(Bicarbonate ) SM 2320B-2011
1 06/19/2015 1900
HMA
1
(Carbonate Al) SM 2320B-2011
1 06/19/2015 1900
HMA
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
ND
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Methane
Client: Duke Energy Laboratory ID: QF15010-004
Description: 2015019021 Matrix: Aqueous
Date Sampled:06/11/2015 0918 Project Name: AB GW Assessment Water -
Date Received:06/15/2015 Project Number: J15060435
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 06/19/2015 1307 DCS 77688
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Inorganic non-metals
Client: Duke Energy Laboratory ID: QF15010-005
Description: 2015019022 Matrix: Aqueous
Date Sampled:06/11/2015 0918 Project Name: AB GW Assessment Water -
Date Received:06/15/2015 Project Number: J15060435
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 2320B-2011
1 06/19/2015 1905
HMA 77674
1
(Bicarbonate ) SM 2320B-2011
1 06/19/2015 1905
HMA
1
(Carbonate Al) SM 2320B-2011
1 06/19/2015 1905
HMA
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
ND
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Methane
Client: Duke Energy Laboratory ID: QF15010-005
Description: 2015019022 Matrix: Aqueous
Date Sampled:06/11/2015 0918 Project Name: AB GW Assessment Water -
Date Received:06/15/2015 Project Number: J15060435
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 06/19/2015 1334 DCS 77688
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Inorganic non-metals
Client: Duke Energy Laboratory ID: QF15010-006
Description: 2015019023 Matrix: Aqueous
Date Sampled:06/11/2015 1025 Project Name: AB GW Assessment Water -
Date Received:06/15/2015 Project Number: J15060435
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 2320B-2011
1 06/19/2015 1911
HMA 77674
1
(Bicarbonate ) SM 2320B-2011
1 06/19/2015 1911
HMA
1
(Carbonate Al) SM 2320B-2011
1 06/19/2015 1911
HMA
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
51
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
51
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Methane
Client: Duke Energy Laboratory ID: QF15010-006
Description: 2015019023 Matrix: Aqueous
Date Sampled:06/11/2015 1025 Project Name: AB GW Assessment Water -
Date Received:06/15/2015 Project Number: J15060435
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 06/19/2015 1344 DCS 77688
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 21 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Inorganic non-metals
Client: Duke Energy Laboratory ID: QF15010-007
Description: 2015019024 Matrix: Aqueous
Date Sampled:06/11/2015 1324 Project Name: AB GW Assessment Water -
Date Received:06/15/2015 Project Number: J15060435
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 2320B-2011
1 06/19/2015 1916
HMA 77674
1
(Bicarbonate ) SM 2320B-2011
1 06/19/2015 1916
HMA
1
(Carbonate Al) SM 2320B-2011
1 06/19/2015 1916
HMA
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
23
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
23
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Methane
Client: Duke Energy Laboratory ID: QF15010-007
Description: 2015019024 Matrix: Aqueous
Date Sampled:06/11/2015 1324 Project Name: AB GW Assessment Water -
Date Received:06/15/2015 Project Number: J15060435
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 06/19/2015 1354 DCS 77688
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 16 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Inorganic non-metals
Client: Duke Energy Laboratory ID: QF15010-008
Description: 2015019025 Matrix: Aqueous
Date Sampled:06/11/2015 1255 Project Name: AB GW Assessment Water -
Date Received:06/15/2015 Project Number: J15060435
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 2320B-2011
1 06/19/2015 1922
HMA 77674
1
(Bicarbonate ) SM 2320B-2011
1 06/19/2015 1922
HMA
1
(Carbonate Al) SM 2320B-2011
1 06/19/2015 1922
HMA
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
97
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
96
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Methane
Client: Duke Energy Laboratory ID: QF15010-008
Description: 2015019025 Matrix: Aqueous
Date Sampled:06/11/2015 1255 Project Name: AB GW Assessment Water -
Date Received:06/15/2015 Project Number: J15060435
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 06/19/2015 1405 DCS 77688
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 20 of 30
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals
Client: Duke Energy Laboratory ID: QF15010-009
Description: 2015019026 Matrix: Aqueous
Date Sampled:06/11/2015 1046 Project Name: AB GW Assessment Water -
Date Received:06/15/2015 Project Number: J15060435
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 2320B-2011
1 06/19/2015 1927
HMA 77674
1
(Bicarbonate ) SM 2320B-2011
1 06/19/2015 1927
HMA
1
(Carbonate Al) SM 2320B-2011
1 06/19/2015 1927
HMA
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
18
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
18
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 21 of 30
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane
Client: Duke Energy Laboratory ID: QF15010-009
Description: 2015019026 Matrix: Aqueous
Date Sampled:06/11/2015 1046 Project Name: AB GW Assessment Water -
Date Received:06/15/2015 Project Number: J15060435
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 06/19/2015 1415 DCS 77688
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 15 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 22 of 30
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals
Client: Duke Energy Laboratory ID: QF15010-010
Description: 2015019027 Matrix: Aqueous
Date Sampled:06/11/2015 1130 Project Name: AB GW Assessment Water -
Date Received:06/15/2015 Project Number: J15060435
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 2320B-2011
1 06/19/2015 1948
HMA 77674
1
(Bicarbonate ) SM 2320B-2011
1 06/19/2015 1948
HMA
1
(Carbonate Al) SM 2320B-2011
1 06/19/2015 1948
HMA
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
93
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
92
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 23 of 30
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane
Client: Duke Energy Laboratory ID: QF15010-010
Description: 2015019027 Matrix: Aqueous
Date Sampled:06/11/2015 1130 Project Name: AB GW Assessment Water -
Date Received:06/15/2015 Project Number: J15060435
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 06/19/2015 1426 DCS 77688
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 24 of 30
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals
Client: Duke Energy Laboratory ID: QF15010-011
Description: 2015019028 Matrix: Aqueous
Date Sampled:06/11/2015 1130 Project Name: AB GW Assessment Water -
Date Received:06/15/2015 Project Number: J15060435
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 2320B-2011
1 06/19/2015 1955
HMA 77674
1
(Bicarbonate ) SM 2320B-2011
1 06/19/2015 1955
HMA
1
(Carbonate Al) SM 2320B-2011
1 06/19/2015 1955
HMA
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
92
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
91
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 25 of 30
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane
Client: Duke Energy Laboratory ID: QF15010-011
Description: 2015019028 Matrix: Aqueous
Date Sampled:06/11/2015 1130 Project Name: AB GW Assessment Water -
Date Received:06/15/2015 Project Number: J15060435
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 06/19/2015 1436 DCS 77688
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 12 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 26 of 30
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals
Client: Duke Energy Laboratory ID: QF15010-012
Description: 2015019029 Matrix: Aqueous
Date Sampled:06/11/2015 1730 Project Name: AB GW Assessment Water -
Date Received:06/15/2015 Project Number: J15060435
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 2320B-2011
1 06/19/2015 2004
HMA 77674
1
(Bicarbonate ) SM 2320B-2011
1 06/19/2015 2004
HMA
1
(Carbonate Al) SM 2320B-2011
1 06/19/2015 2004
HMA
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
350
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
350
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 27 of 30
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane
Client: Duke Energy Laboratory ID: QF15010-012
Description: 2015019029 Matrix: Aqueous
Date Sampled:06/11/2015 1730 Project Name: AB GW Assessment Water -
Date Received:06/15/2015 Project Number: J15060435
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 06/19/2015 1450 DCS 77688
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 290 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 28 of 30
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals
Client: Duke Energy Laboratory ID: QF15010-013
Description: 2015019031 Matrix: Aqueous
Date Sampled:06/11/2015 0800 Project Name: AB GW Assessment Water -
Date Received:06/15/2015 Project Number: J15060435
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 2320B-2011
1 06/19/2015 2010
HMA 77674
1
(Bicarbonate ) SM 2320B-2011
1 06/19/2015 2010
HMA
1
(Carbonate Al) SM 2320B-2011
1 06/19/2015 2010
HMA
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
ND
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 29 of 30
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane
Client: Duke Energy Laboratory ID: QF15010-013
Description: 2015019031 Matrix: Aqueous
Date Sampled:06/11/2015 0800 Project Name: AB GW Assessment Water -
Date Received:06/15/2015 Project Number: J15060435
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 06/19/2015 2101 JJG 77732
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 30 of 30
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

QC Summary
Shealy Environmental Services, Inc. QC Data for Lot Number: QF15010
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals - MB
Sample ID: QQ77512-001 Matrix: Aqueous
Batch:77512
Analytical Method: SM 2320B-2011
Parameter Result Q Dil PQL Units Analysis Date
Alkalinity ND 1 10 mg/L 06/17/20151803
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QF15010
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals - LCS
Sample ID: QQ77512-002 Matrix: Aqueous
Batch:77512
Analytical Method: SM 2320B-2011
Spike
Amount Result % Rec
Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Alkalinity 100 94 1 94 90-110 06/17/20151809
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QF15010
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals - MB
Sample ID: QQ77674-001 Matrix: Aqueous
Batch:77674
Analytical Method: SM 2320B-2011
Parameter Result Q Dil PQL Units Analysis Date
Alkalinity ND 1 10 mg/L 06/19/20151829
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QF15010
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals - LCS
Sample ID: QQ77674-002 Matrix: Aqueous
Batch:77674
Analytical Method: SM 2320B-2011
Spike
Amount Result % Rec
Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Alkalinity 100 97 1 97 90-110 06/19/20151835
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QF15010
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals - MS
Sample ID: QF15010-003MS Matrix: Aqueous
Batch:77674
Analytical Method: SM 2320B-2011
Sample Spike
Amount Amount Result % Rec
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Alkalinity 130 100 200 1 77 70-130 06/19/20151848
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QF15010
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals - MSD
Sample ID: QF15010-003MD Matrix: Aqueous
Batch:77674
Analytical Method: SM 2320B-2011
Sample Spike
Amount Amount Result % Rec % RPD
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date
Alkalinity 130 100 200 1 79 1.4 70-130 20 06/19/20151855
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QF15010
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane - MB
Sample ID: QQ77688-001 Matrix: Aqueous
Batch:77688
Analytical Method: RSK - 175
Parameter Result Q Dil PQL Units Analysis Date
Methane ND 1 10 ug/L 06/19/2015 0931
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QF15010
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane - LCS
Sample ID: QQ77688-002 Matrix: Aqueous
Batch:77688
Analytical Method: RSK - 175
Spike
Amount Result % Rec
Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date
Methane 50 47 1 94 70-130 06/19/2015 0906
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QF15010
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane - LCSD
Sample ID: QQ77688-003 Matrix: Aqueous
Batch:77688
Analytical Method: RSK - 175
Spike
Amount Result % Rec % RPD
Parameter (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date
Methane 50 46 1 91 2.9 70-130 30 06/19/2015 0918
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QF15010
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane - MB
Sample ID: QQ77732-001 Matrix: Aqueous
Batch:77732
Analytical Method: RSK - 175
Parameter Result Q Dil PQL Units Analysis Date
Methane ND 1 10 ug/L 06/19/20151718
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QF15010
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane - LCS
Sample ID: QQ77732-002 Matrix: Aqueous
Batch:77732
Analytical Method: RSK - 175
Spike
Amount Result % Rec
Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date
Methane 50 43 1 86 70-130 06/19/20151638
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QF15010
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane - LCSD
Sample ID: QQ77732-003 Matrix: Aqueous
Batch:77732
Analytical Method: RSK - 175
Spike
Amount Result % Rec % RPD
Parameter (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date
Methane 50 47 1 93 8.4 70-130 30 06/19/20151651
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QF15010
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

SHEALY ENVIRONMENTAL SERVICES, INC.
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Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

SHEALY ENVIRONMENTAL SERVICES, INC.
S, a jy EnWironmtnial Service, 1ne. $� 1 41 1
Dno..ournuf hl (ember F-AD-036 E ffe a ivc Dme.Dale! 1 Ll3kB
FRvWon N7emher: 17 YC6rr�o3�e Tkaic:!`Jd, '1
Sample Receipt Checkfi5t (SRC.)
Client, �P. t l Cuolci lnsp�cted by;dale; Ici .r�p-1 —I� Ems[ �° 3 P1 0\0_.
Mcans of rercipt; SESI ❑ Client ❑ UPS ❑ 1'rdFA ©Airborm pxp - 0Lhcr
'des Pro 1. Were custcrd seals present on the c.uole.T?
Y°es No NA IIf custady seals weTe prese lit, were they intact and unbroken?
Coo1cI i.i3l igim Ierx peratura upon receipVDcrived (cotfected) temperarure upon receipt;
Meth[& ❑ Temperature, Agalinst got*ales 1R Gun ID: ER Velum srection Factor; °C
Method of lant: et roc Blue Ice Dr ien None _
3 temperature of any cooler exceeded 6.IrC, was project Manager notified?
yes LJ No
0 r4A PM nuiifed by SRC, phone, note. (circle onc), other:
(Fors lers received via catt'rraercial c aurier, P-1is are to be notified
Yes ❑
1r5,
yes, ❑
©
I.Lo ©
1 +
NA
4. Is the commercial 00urigr's aclrin Nli attatched W this form?
were KgEcr custody roedurtS (relin lShed{rCL'CIYf-d followed?
5a Were sampIcsMliTiquished by cifent ro commercial wurier?
'Yes
❑
b_ Were saMple. lid listed on the MC?
Yes
7.Grtre sa de il3s listed an all sa Ile containers?
8. Wffi wllwinn date & time 1%ted can the, CQC?
i
9. Was collection (late & tine listed on all sam lr �nontainers'a
10. Did all a tEt er label irdraTmatinn D date (lime a -c with the CGIC?
1I. Were tests to be rormaed listed ail the COO
12, Did all sam 1es arrive in the rb r eonta%r�ers far each tent?
13. Did all containers ariivc in good condition twbrokrn lids an, etc ?
14, Was adequatc sane le volume ava<_ilahle?
15, Were ail sArnples received +whin rhet holding time nor 4811ou.rs, whichevcr
comes first?
1-*iyesj�;e
Yes 0
Yes ❑
Na
No
Yes ❑
No
16. Were liny Samples cunbliuers m;cQin ?
rt
iWEr«`rr
17_ Were there any excess samples not listed on Ct7M
8, Were hvb6les present " er1 9bze" `Va"or 6mrn in-iiaimter in "y aVOAviala?
9. Wcrc all mt3t.;lsj0&Cj HEM/nutricr►t s 11 les received at a PH of C2?
Were all cyanide andior sufflde samples received at a pH >12?
21. Were all applicable I`]TUaKN}oyaniderphenol (<Vmg/Q samples freB of
residual chlurin�e `a
Y+Ps
Yes ❑
y
Iqo
No
No 0
NA
I'rA
:CIA
N A
❑
o
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NA
22 W-erie collection temperatures documented on the COC for NC samples?
�LN, 23_ Were client tamarlsjrtquests (i.e. requested dilutions, MSji+.'SD designations,
Y{�s N ` etC.., WTrecxl transcri"d from the COC into the c�bnimentSecti6n In L S?
yes 0 24. Was the qUGjr+ FILIrn aer ased tLkcn from the oontaineT label?
Sample Pregerv2doln (Mill be cornplettd for any Snmplt�s) 7nc� real reserved or with headspacc.)
Sarnplc(s} ware received incorrectly preserved and were adjusted
accordingjv in Sample receivirl.9 with H2S0"I'HN0;110,t'laC using SIB
Sam werc received with bubbles ->4 iron in; diameter.
Sam l s) were recaeiyed with't RC >I1.2 rng L if #21 is No
SC Drinking Water Project Sarnple(s) pH verified to he > 2 by Date:
1 sware ntat rccei 'eci at a H of <2 aTrd were ad°ustsed ac€ordin unin SR#
�Samle labels $ ii+vd h 'Verified b,: Date:
—
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Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM
Analytical Lab
Page 99 of 99
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Duke Energy Duke Energy Analytical Laboratory
Analytical LaMbofat use vn
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DISTRIBUTION
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ELEMENTS by ICP MS (TRM): As, Be, Cd, Co, Cr, Cu, Mo, Ni, Pb, SID, Se, TI (ILL), V (LL)
ELEMENTS by ICP (TRM): All, Be, 8, Fe, Mn, Sr, Zn
ICP_Undigested Ca, Mg, K, Na Hg by 245.1
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Dissolved metals: all metals ICP, IMS,Hg
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