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Home My WebLink AboutNC0003417_J15050749report_20150805DUKE Analytical Laboratory ENERGY 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone:980-875-5245 Fax:980-875-4349 Order Summary Report Order Number: J15050749 Project Name: HF LEE PLANT - AB GW ASSESSMENT WATER Customer Name(s): Tim Hunsucker, Judd Mahan, Kathy Webb, John Toepfer Customer Address: 1677 Old Smithfield Rd Goldsboro NO 27530, Lab Contact: Mary Ann Oqle Phone: 980-875-5274 Mary Ann Ogle Report Authorized By: 2015.06.17 10:40:51 Date: (Signature) (-04'00' Mary Ann Ogle Program Comments: Please contact the Program Manager (Mary Ann Ogle) with any questions regarding this report. Data Flags & Calculations: 6/16/2015 Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Sample ID's & Descriptions: Collection Sample ID Plant/Station Date and Time Collected By Sample Description 2015016342 HF LEE PLANT 27-May-15 10:16 AM Richard J LLMW-1S 2015016344 HF LEE PLANT 26-May-15 2:40 PM Richard J AMW-6RBC 2015016345 HF LEE PLANT 26-May-15 2:10 PM Richard J IMW-1S 2015016346 HF LEE PLANT 26-May-15 3:45 PM Richard J IMW-2BC 2015016347 HF LEE PLANT 27-May-15 1:34 PM Richard J IMW-3BC 2015016348 HF LEE PLANT 27-May-15 9:45 AM Richard J IMW-1BC 2015016349 HF LEE PLANT 26-May-15 12:45 PM Richard J Equipment Blank 2015016350 HF LEE PLANT 27-May-15 7:45 AM Richard J Equipment Blank 2015016351 HF LEE PLANT 26-May-15 12:45 PM Richard J Filter Blank 2015016352 HF LEE PLANT 27-May-15 7:45 AM Richard J Filter Blank 10 Total Samples Technical Validation Review Checklist: COC and .pdf report are in agreement with sample totals Yes No and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. ❑ Yes No All laboratory QA/QC requirements are acceptable.❑ Yes ❑ No Report Sections Included: U Job Summary Report �/❑ Sample Identification n Technical Validation of Data Package 0 Analytical Laboratory Certificate of Analysis ❑ Analytical Laboratory QC Report l� Sub -contracted Laboratory Results ❑ Customer Specific Data Sheets, Reports, & Documentation ❑ Customer Database Entries d❑ Chain of Custody d❑ Electronic Data Deliverable (EDD) Sent Separately Reviewed By: Peggy Kendall Date: 6/16/2015 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050749 Site: LLMW-1 S Collection Date: 27-May-15 10:16 AM Analyse Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.030 mg-N/L 0.01 INORGANIC IONS BY IC Chloride 29 mg/L 1 Sulfate 0.21 mg/L 0.1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) < 0.005 mg/L 0.005 Barium (Ba) 0.074 mg/L 0.005 Boron (B) 0.053 mg/L 0.05 Iron (Fe) 0.914 mg/L 0.01 Manganese (Mn) 1.36 mg/L 0.005 Strontium (Sr) 0.246 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 11.8 mg/L 0.01 Magnesium (Mg) 4.02 mg/L 0.005 Potassium (K) 3.68 mg/L 0.1 Sodium (Na) 26.4 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.018 mg/L 0.005 Barium (Ba) 0.084 mg/L 0.005 Boron (B) 0.066 mg/L 0.05 Iron (Fe) 0.942 mg/L 0.01 Manganese (Mn) 1.32 mg/L 0.005 Strontium (Sr) 0.250 mg/L 0.005 Zinc (Zn) 0.015 mg/L 0.005 Sample #: 2015016342 Matrix: GW_WW DF Method Analysis Date/Time Analyst Vendor Method V_SHEALY 1 EPA 353.2 06/01/2015 13:59 LSTARL1 10 EPA 300.0 06/01/2015 18:18 BGN9034 1 EPA 300.0 06/01/2015 18:18 BGN9034 1 EPA 245.1 06/01/2015 10:12 ACPAYNE 1 EPA 245.1 06/03/2015 14:49 ACPAYNE 1 EPA 200.7 05/29/2015 12:21 MHALL3 1 EPA 200.7 05/29/2015 12:21 MHALL3 1 EPA 200.7 05/29/2015 12:21 MHALL3 1 EPA 200.7 05/29/2015 12:21 MHALL3 1 EPA 200.7 05/29/2015 12:21 MHALL3 1 EPA 200.7 05/29/2015 12:21 MHALL3 1 EPA 200.7 05/29/2015 12:21 MHALL3 1 EPA 200.7 06/01/2015 12:54 MHALL3 1 EPA 200.7 06/01/2015 12:54 MHALL3 1 EPA 200.7 06/01/2015 12:54 MHALL3 1 EPA 200.7 06/01/2015 12:54 MHALL3 1 EPA 200.7 06/02/2015 10:05 MHALL3 1 EPA 200.7 06/02/2015 10:05 MHALL3 1 EPA 200.7 06/02/2015 10:05 MHALL3 1 EPA 200.7 06/02/2015 10:05 MHALL3 1 EPA 200.7 06/02/2015 10:05 MHALL3 1 EPA 200.7 06/02/2015 10:05 MHALL3 1 EPA 200.7 06/02/2015 10:05 MHALL3 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050749 Site: LLMW-1 S Collection Date: 27-May-15 10:16 AM Analyse Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) 2.34 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) 2.56 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level 0.261 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4) Complete SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 120 mg/L 25 Total Carbon TOC 2.0 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 Sample #: 2015016342 Matrix: GW_WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 06/15/2015 15:35 JAHERMA 1 EPA 200.8 06/15/2015 15:35 JAHERMA 1 EPA 200.8 06/15/2015 15:35 JAHERMA 1 EPA 200.8 06/15/2015 15:35 JAHERMA 1 EPA 200.8 06/15/2015 15:35 JAHERMA 1 EPA 200.8 06/15/2015 15:35 JAHERMA 1 EPA 200.8 06/15/2015 15:35 JAHERMA 1 EPA 200.8 06/15/2015 15:35 JAHERMA 1 EPA 200.8 06/15/2015 15:35 JAHERMA 1 EPA 200.8 06/15/2015 15:35 JAHERMA 1 EPA 200.8 06/15/2015 15:35 JAHERMA 1 EPA 200.8 06/15/2015 15:35 JAHERMA 1 EPA 200.8 06/15/2015 15:35 JAHERMA 1 EPA 200.8 06/07/2015 02:06 SLS2560 1 EPA 200.8 06/07/2015 02:06 SLS2560 1 EPA 200.8 06/07/2015 02:06 SLS2560 1 EPA 200.8 06/07/2015 02:06 SLS2560 1 EPA 200.8 06/07/2015 02:06 SLS2560 1 EPA 200.8 06/07/2015 02:06 SLS2560 1 EPA 200.8 06/07/2015 02:06 SLS2560 1 EPA 200.8 06/07/2015 02:06 SLS2560 1 EPA 200.8 06/07/2015 02:06 SLS2560 1 EPA 200.8 06/07/2015 02:06 SLS2560 1 EPA 200.8 06/07/2015 02:06 SLS2560 1 EPA 200.8 06/07/2015 02:06 SLS2560 1 EPA 200.8 06/07/2015 02:06 SLS2560 Vendor Method V_SHEALY Vendor Method V_ELE1 1 SM2540C 06/01/201511:17 AGIBBS5 1 SM5310C/EPA9060A 06/04/201516:19 GHUTCHI 1 SM2540D 06/01/2015 08:52 AGIBBS5 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050749 Site: AMW-6RBC Collection Date: 26-May-15 2:40 PM Analyse Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.015 mg-N/L M2 0.01 INORGANIC IONS BY IC Chloride 25 mg/L 1 Sulfate 21 mg/L 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) 0.023 mg/L 0.005 Barium (Ba) 0.070 mg/L 0.005 Boron (B) 0.152 mg/L 0.05 Iron (Fe) 2.64 mg/L 0.01 Manganese (Mn) 0.194 mg/L 0.005 Strontium (Sr) 0.112 mg/L 0.005 Zinc (Zn) 0.016 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 18.0 mg/L 0.01 Magnesium (Mg) 6.27 mg/L 0.005 Potassium (K) 5.09 mg/L 0.1 Sodium (Na) 30.3 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.140 mg/L 0.005 Barium (Ba) 0.083 mg/L 0.005 Boron (B) 0.176 mg/L 0.05 Iron (Fe) 3.64 mg/L 0.01 Manganese (Mn) 0.235 mg/L 0.005 Strontium (Sr) 0.127 mg/L 0.005 Zinc (Zn) 0.014 mg/L 0.005 Sample #: 2015016344 Matrix: GW_WW DF Method Analysis Date/Time Analyst Vendor Method V_SHEALY 1 EPA 353.2 06/01/2015 14:12 LSTARL1 10 EPA 300.0 06/01/2015 16:12 BGN9034 10 EPA 300.0 06/01/2015 16:12 BGN9034 1 EPA 245.1 06/01/2015 10:14 ACPAYNE 1 EPA 245.1 06/03/2015 14:51 ACPAYNE 1 EPA 200.7 06/01/2015 11:18 MHALL3 1 EPA 200.7 06/01/2015 11:18 MHALL3 1 EPA 200.7 06/01/2015 11:18 MHALL3 1 EPA 200.7 06/01/2015 11:18 MHALL3 1 EPA 200.7 06/01/2015 11:18 MHALL3 1 EPA 200.7 06/01/2015 11:18 MHALL3 1 EPA 200.7 06/01/2015 11:18 MHALL3 1 EPA 200.7 06/01/2015 13:23 MHALL3 1 EPA 200.7 06/01/2015 13:23 MHALL3 1 EPA 200.7 06/01/2015 13:23 MHALL3 1 EPA 200.7 06/01/2015 13:23 MHALL3 1 EPA 200.7 06/02/2015 10:17 MHALL3 1 EPA 200.7 06/02/2015 10:17 MHALL3 1 EPA 200.7 06/02/2015 10:17 MHALL3 1 EPA 200.7 06/02/2015 10:17 MHALL3 1 EPA 200.7 06/02/2015 10:17 MHALL3 1 EPA 200.7 06/02/2015 10:17 MHALL3 1 EPA 200.7 06/02/2015 10:17 MHALL3 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050749 Site: AMW-6RBC Collection Date: 26-May-15 2:40 PM Analyse Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) 3.68 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) 1.86 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) 2.56 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level 0.488 ug/L 0.3 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4) Complete SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 170 mg/L 25 Total Carbon TOC 0.927 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS 18 mg/L 5 Sample #: 2015016344 Matrix: GW_WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 06/15/2015 16:17 JAHERMA 1 EPA 200.8 06/15/2015 16:17 JAHERMA 1 EPA 200.8 06/15/2015 16:17 JAHERMA 1 EPA 200.8 06/15/2015 16:17 JAHERMA 1 EPA 200.8 06/15/2015 16:17 JAHERMA 1 EPA 200.8 06/15/2015 16:17 JAHERMA 1 EPA 200.8 06/15/2015 16:17 JAHERMA 1 EPA 200.8 06/15/2015 16:17 JAHERMA 1 EPA 200.8 06/15/2015 16:17 JAHERMA 1 EPA 200.8 06/15/2015 16:17 JAHERMA 1 EPA 200.8 06/15/2015 16:17 JAHERMA 1 EPA 200.8 06/15/2015 16:17 JAHERMA 1 EPA 200.8 06/15/2015 16:17 JAHERMA 1 EPA 200.8 06/07/2015 01:39 SLS2560 1 EPA 200.8 06/07/2015 01:39 SLS2560 1 EPA 200.8 06/07/2015 01:39 SLS2560 1 EPA 200.8 06/07/2015 01:39 SLS2560 1 EPA 200.8 06/07/2015 01:39 SLS2560 1 EPA 200.8 06/07/2015 01:39 SLS2560 1 EPA 200.8 06/07/2015 01:39 SLS2560 1 EPA 200.8 06/07/2015 01:39 SLS2560 1 EPA 200.8 06/07/2015 01:39 SLS2560 1 EPA 200.8 06/07/2015 01:39 SLS2560 1 EPA 200.8 06/07/2015 01:39 SLS2560 1 EPA 200.8 06/07/2015 01:39 SLS2560 1 EPA 200.8 06/07/2015 01:39 SLS2560 Vendor Method V_SHEALY Vendor Method V_ELE1 1 SM2540C 06/01/201511:17 AGIBBS5 1 SM5310C/EPA9060A 06/04/201516:19 GHUTCHI 1 SM2540D 05/29/2015 08:53 AGIBBS5 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050749 Site: I1MW-1 S Collection Date: 26-May-15 2:10 PM Analyse Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 2.7 mg-N/L 0.05 INORGANIC IONS BY IC Chloride 19 mg/L 1 Sulfate 24 mg/L 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) 0.018 mg/L 0.005 Barium (Ba) 0.187 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 2.98 mg/L 0.01 Manganese (Mn) 0.272 mg/L 0.005 Strontium (Sr) 0.118 mg/L 0.005 Zinc (Zn) 0.021 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 8.86 mg/L 0.01 Magnesium (Mg) 6.09 mg/L 0.005 Potassium (K) 1.58 mg/L 0.1 Sodium (Na) 7.78 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.171 mg/L 0.005 Barium (Ba) 0.194 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 3.15 mg/L 0.01 Manganese (Mn) 0.258 mg/L 0.005 Strontium (Sr) 0.115 mg/L 0.005 Zinc (Zn) 0.014 mg/L 0.005 Sample #: 2015016345 Matrix: GW_WW DF Method Analysis Date/Time Analyst Vendor Method V_SHEALY 5 EPA 353.2 06/01/2015 14:27 LSTARL1 10 EPA 300.0 06/01/2015 16:30 BGN9034 10 EPA 300.0 06/01/2015 16:30 BGN9034 1 EPA 245.1 06/01/2015 10:16 ACPAYNE 1 EPA 245.1 06/03/2015 14:54 ACPAYNE 1 EPA 200.7 06/01/2015 11:22 MHALL3 1 EPA 200.7 06/01/2015 11:22 MHALL3 1 EPA 200.7 06/01/2015 11:22 MHALL3 1 EPA 200.7 06/01/2015 11:22 MHALL3 1 EPA 200.7 06/01/2015 11:22 MHALL3 1 EPA 200.7 06/01/2015 11:22 MHALL3 1 EPA 200.7 06/01/2015 11:22 MHALL3 1 EPA 200.7 06/01/2015 13:27 MHALL3 1 EPA 200.7 06/01/2015 13:27 MHALL3 1 EPA 200.7 06/01/2015 13:27 MHALL3 1 EPA 200.7 06/01/2015 13:27 MHALL3 1 EPA 200.7 06/02/2015 10:20 MHALL3 1 EPA 200.7 06/02/2015 10:20 MHALL3 1 EPA 200.7 06/02/2015 10:20 MHALL3 1 EPA 200.7 06/02/2015 10:20 MHALL3 1 EPA 200.7 06/02/2015 10:20 MHALL3 1 EPA 200.7 06/02/2015 10:20 MHALL3 1 EPA 200.7 06/02/2015 10:20 MHALL3 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050749 Site: I1MW-1 S Collection Date: 26-May-15 2:10 PM Analyse Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) 6.47 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) 3.64 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) 6.21 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) 3.80 ug/L 1 Selenium (Se) 1.14 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level 0.627 ug/L 0.3 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4) Complete SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 97 mg/L 25 Total Carbon TOC 0.732 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS 5.0 mg/L 5 Sample #: 2015016345 Matrix: GW_WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 06/15/2015 16:38 JAHERMA 1 EPA 200.8 06/15/2015 16:38 JAHERMA 1 EPA 200.8 06/15/2015 16:38 JAHERMA 1 EPA 200.8 06/15/2015 16:38 JAHERMA 1 EPA 200.8 06/15/2015 16:38 JAHERMA 1 EPA 200.8 06/15/2015 16:38 JAHERMA 1 EPA 200.8 06/15/2015 16:38 JAHERMA 1 EPA 200.8 06/15/2015 16:38 JAHERMA 1 EPA 200.8 06/15/2015 16:38 JAHERMA 1 EPA 200.8 06/15/2015 16:38 JAHERMA 1 EPA 200.8 06/15/2015 16:38 JAHERMA 1 EPA 200.8 06/15/2015 16:38 JAHERMA 1 EPA 200.8 06/15/2015 16:38 JAHERMA 1 EPA 200.8 06/07/2015 02:11 SLS2560 1 EPA 200.8 06/07/2015 02:11 SLS2560 1 EPA 200.8 06/07/2015 02:11 SLS2560 1 EPA 200.8 06/07/2015 02:11 SLS2560 1 EPA 200.8 06/07/2015 02:11 SLS2560 1 EPA 200.8 06/07/2015 02:11 SLS2560 1 EPA 200.8 06/07/2015 02:11 SLS2560 1 EPA 200.8 06/07/2015 02:11 SLS2560 1 EPA 200.8 06/07/2015 02:11 SLS2560 1 EPA 200.8 06/07/2015 02:11 SLS2560 1 EPA 200.8 06/07/2015 02:11 SLS2560 1 EPA 200.8 06/07/2015 02:11 SLS2560 1 EPA 200.8 06/07/2015 02:11 SLS2560 Vendor Method V_SHEALY Vendor Method V_ELE1 1 SM2540C 06/01/201511:17 AGIBBS5 1 SM5310C/EPA9060A 06/04/201516:19 GHUTCHI 1 SM2540D 05/29/2015 08:53 AGIBBS5 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050749 Site: IMW-2BC Collection Date: 26-May-15 3:45 PM Analyse Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) < 0.01 mg-N/L 0.01 INORGANIC IONS BY IC Chloride 64 mg/L 1 Sulfate 17 mg/L 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) 0.016 mg/L 0.005 Barium (Ba) 0.039 mg/L 0.005 Boron (B) 0.291 mg/L 0.05 Iron (Fe) 0.110 mg/L 0.01 Manganese (Mn) 0.034 mg/L 0.005 Strontium (Sr) 0.138 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 16.2 mg/L 0.01 Magnesium (Mg) 4.74 mg/L 0.005 Potassium (K) 3.95 mg/L 0.1 Sodium (Na) 81.4 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.078 mg/L 0.005 Barium (Ba) 0.041 mg/L 0.005 Boron (B) 0.293 mg/L 0.05 Iron (Fe) 0.364 mg/L 0.01 Manganese (Mn) 0.038 mg/L 0.005 Strontium (Sr) 0.143 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 Sample #: 2015016346 Matrix: GW_WW DF Method Analysis Date/Time Analyst Vendor Method V_SHEALY 1 EPA 353.2 06/01/2015 14:17 LSTARL1 10 EPA 300.0 06/01/2015 20:05 BGN9034 10 EPA 300.0 06/01/2015 20:05 BGN9034 1 EPA 245.1 06/01/2015 10:19 ACPAYNE 1 EPA 245.1 06/03/2015 14:56 ACPAYNE 1 EPA 200.7 06/01/2015 11:26 MHALL3 1 EPA 200.7 06/01/2015 11:26 MHALL3 1 EPA 200.7 06/01/2015 11:26 MHALL3 1 EPA 200.7 06/01/2015 11:26 MHALL3 1 EPA 200.7 06/01/2015 11:26 MHALL3 1 EPA 200.7 06/01/2015 11:26 MHALL3 1 EPA 200.7 06/01/2015 11:26 MHALL3 1 EPA 200.7 06/01/2015 13:31 MHALL3 1 EPA 200.7 06/01/2015 13:31 MHALL3 1 EPA 200.7 06/01/2015 13:31 MHALL3 1 EPA 200.7 06/01/2015 13:31 MHALL3 1 EPA 200.7 06/02/2015 10:24 MHALL3 1 EPA 200.7 06/02/2015 10:24 MHALL3 1 EPA 200.7 06/02/2015 10:24 MHALL3 1 EPA 200.7 06/02/2015 10:24 MHALL3 1 EPA 200.7 06/02/2015 10:24 MHALL3 1 EPA 200.7 06/02/2015 10:24 MHALL3 1 EPA 200.7 06/02/2015 10:24 MHALL3 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050749 Site: IMW-2BC Collection Date: 26-May-15 3:45 PM Analyse Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) 1.55 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) 10.2 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) 1.61 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) 9.96 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level 0.429 ug/L 0.3 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4) Complete SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 280 mg/L 25 Total Carbon TOC 0.796 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS 9.0 mg/L 5 Sample #: 2015016346 Matrix: GW_WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 06/15/2015 16:45 JAHERMA 1 EPA 200.8 06/15/2015 16:45 JAHERMA 1 EPA 200.8 06/15/2015 16:45 JAHERMA 1 EPA 200.8 06/15/2015 16:45 JAHERMA 1 EPA 200.8 06/15/2015 16:45 JAHERMA 1 EPA 200.8 06/15/2015 16:45 JAHERMA 1 EPA 200.8 06/15/2015 16:45 JAHERMA 1 EPA 200.8 06/15/2015 16:45 JAHERMA 1 EPA 200.8 06/15/2015 16:45 JAHERMA 1 EPA 200.8 06/15/2015 16:45 JAHERMA 1 EPA 200.8 06/15/2015 16:45 JAHERMA 1 EPA 200.8 06/15/2015 16:45 JAHERMA 1 EPA 200.8 06/15/2015 16:45 JAHERMA 1 EPA 200.8 06/07/2015 02:15 SLS2560 1 EPA 200.8 06/07/2015 02:15 SLS2560 1 EPA 200.8 06/07/2015 02:15 SLS2560 1 EPA 200.8 06/07/2015 02:15 SLS2560 1 EPA 200.8 06/07/2015 02:15 SLS2560 1 EPA 200.8 06/07/2015 02:15 SLS2560 1 EPA 200.8 06/07/2015 02:15 SLS2560 1 EPA 200.8 06/07/2015 02:15 SLS2560 1 EPA 200.8 06/07/2015 02:15 SLS2560 1 EPA 200.8 06/07/2015 02:15 SLS2560 1 EPA 200.8 06/07/2015 02:15 SLS2560 1 EPA 200.8 06/07/2015 02:15 SLS2560 1 EPA 200.8 06/07/2015 02:15 SLS2560 Vendor Method V_SHEALY Vendor Method V_ELE1 1 SM2540C 06/01/201511:17 AGIBBS5 1 SM5310C/EPA9060A 06/04/201516:19 GHUTCHI 1 SM2540D 05/29/2015 08:53 AGIBBS5 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050749 Site: IMW-3BC Collection Date: 27-May-15 1:34 PM Analyse Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) < 0.01 mg-N/L 0.01 INORGANIC IONS BY IC Chloride 3.1 mg/L 0.1 Sulfate 5.0 mg/L 0.1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) < 0.005 mg/L 0.005 Barium (Ba) 0.262 mg/L 0.005 Boron (B) 0.060 mg/L 0.05 Iron (Fe) 0.939 mg/L 0.01 Manganese (Mn) 0.078 mg/L 0.005 Strontium (Sr) 0.086 mg/L 0.005 Zinc (Zn) 0.008 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 25.9 mg/L 0.01 Magnesium (Mg) 3.52 mg/L 0.005 Potassium (K) 1.08 mg/L 0.1 Sodium (Na) 7.39 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.031 mg/L 0.005 Barium (Ba) 0.267 mg/L 0.005 Boron (B) 0.056 mg/L 0.05 Iron (Fe) 1.51 mg/L 0.01 Manganese (Mn) 0.079 mg/L 0.005 Strontium (Sr) 0.083 mg/L 0.005 Zinc (Zn) 0.006 mg/L 0.005 Sample #: 2015016347 Matrix: GW_WW DF Method Analysis Date/Time Analyst Vendor Method V_SHEALY 1 EPA 353.2 06/01/2015 14:18 LSTARL1 1 EPA 300.0 06/01/2015 23:58 BGN9034 1 EPA 300.0 06/01/2015 23:58 BGN9034 1 EPA 245.1 06/01/2015 10:21 ACPAYNE 1 EPA 245.1 06/03/2015 14:58 ACPAYNE 1 EPA 200.7 06/01/2015 11:30 MHALL3 1 EPA 200.7 06/01/2015 11:30 MHALL3 1 EPA 200.7 06/01/2015 11:30 MHALL3 1 EPA 200.7 06/01/2015 11:30 MHALL3 1 EPA 200.7 06/01/2015 11:30 MHALL3 1 EPA 200.7 06/01/2015 11:30 MHALL3 1 EPA 200.7 06/01/2015 11:30 MHALL3 1 EPA 200.7 06/01/2015 13:35 MHALL3 1 EPA 200.7 06/01/2015 13:35 MHALL3 1 EPA 200.7 06/01/2015 13:35 MHALL3 1 EPA 200.7 06/01/2015 13:35 MHALL3 1 EPA 200.7 06/02/2015 10:28 MHALL3 1 EPA 200.7 06/02/2015 10:28 MHALL3 1 EPA 200.7 06/02/2015 10:28 MHALL3 1 EPA 200.7 06/02/2015 10:28 MHALL3 1 EPA 200.7 06/02/2015 10:28 MHALL3 1 EPA 200.7 06/02/2015 10:28 MHALL3 1 EPA 200.7 06/02/2015 10:28 MHALL3 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050749 Site: IMW-3BC Collection Date: 27-May-15 1:34 PM Analyse Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) 2.11 ug/L 1 Nickel (Ni) 2.40 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) 2.10 ug/L 1 Nickel (Ni) 2.28 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4) Complete SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 110 mg/L 25 Total Carbon TOC 0.541 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS 7.0 mg/L 5 Sample #: 2015016347 Matrix: GW_WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 06/15/2015 16:52 JAHERMA 1 EPA 200.8 06/15/2015 16:52 JAHERMA 1 EPA 200.8 06/15/2015 16:52 JAHERMA 1 EPA 200.8 06/15/2015 16:52 JAHERMA 1 EPA 200.8 06/15/2015 16:52 JAHERMA 1 EPA 200.8 06/15/2015 16:52 JAHERMA 1 EPA 200.8 06/15/2015 16:52 JAHERMA 1 EPA 200.8 06/15/2015 16:52 JAHERMA 1 EPA 200.8 06/15/2015 16:52 JAHERMA 1 EPA 200.8 06/15/2015 16:52 JAHERMA 1 EPA 200.8 06/15/2015 16:52 JAHERMA 1 EPA 200.8 06/15/2015 16:52 JAHERMA 1 EPA 200.8 06/15/2015 16:52 JAHERMA 1 EPA 200.8 06/07/2015 02:20 SLS2560 1 EPA 200.8 06/07/2015 02:20 SLS2560 1 EPA 200.8 06/07/2015 02:20 SLS2560 1 EPA 200.8 06/07/2015 02:20 SLS2560 1 EPA 200.8 06/07/2015 02:20 SLS2560 1 EPA 200.8 06/07/2015 02:20 SLS2560 1 EPA 200.8 06/07/2015 02:20 SLS2560 1 EPA 200.8 06/07/2015 02:20 SLS2560 1 EPA 200.8 06/07/2015 02:20 SLS2560 1 EPA 200.8 06/07/2015 02:20 SLS2560 1 EPA 200.8 06/07/2015 02:20 SLS2560 1 EPA 200.8 06/07/2015 02:20 SLS2560 1 EPA 200.8 06/07/2015 02:20 SLS2560 Vendor Method V_SHEALY Vendor Method V_ELE1 1 SM2540C 06/01/201511:17 AGIBBS5 1 SM5310C/EPA9060A 06/04/201516:19 GHUTCHI 1 SM2540D 06/01/2015 08:52 AGIBBS5 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050749 Site: I1MW-1 BC Collection Date: 27-May-15 9:45 AM Analyse Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.014 mg-N/L 0.01 INORGANIC IONS BY IC Chloride 66 mg/L 1 Sulfate 20 mg/L 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) < 0.005 mg/L 0.005 Barium (Ba) 0.090 mg/L 0.005 Boron (B) 0.151 mg/L 0.05 Iron (Fe) < 0.01 mg/L 0.01 Manganese (Mn) 0.056 mg/L 0.005 Strontium (Sr) 0.101 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 16.5 mg/L 0.01 Magnesium (Mg) 3.29 mg/L 0.005 Potassium (K) 2.22 mg/L 0.1 Sodium (Na) 59.2 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.015 mg/L 0.005 Barium (Ba) 0.095 mg/L 0.005 Boron (B) 0.156 mg/L 0.05 Iron (Fe) 0.147 mg/L 0.01 Manganese (Mn) 0.059 mg/L 0.005 Strontium (Sr) 0.105 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 Sample #: 2015016348 Matrix: GW_WW DF Method Analysis Date/Time Analyst Vendor Method V_SHEALY 1 EPA 353.2 06/01/2015 14:19 LSTARL1 10 EPA 300.0 06/01/2015 21:17 BGN9034 10 EPA 300.0 06/01/2015 21:17 BGN9034 1 EPA 245.1 06/01/2015 10:24 ACPAYNE 1 EPA 245.1 06/03/2015 15:01 ACPAYNE 1 EPA 200.7 06/01/2015 11:33 MHALL3 1 EPA 200.7 06/01/2015 11:33 MHALL3 1 EPA 200.7 06/01/2015 11:33 MHALL3 1 EPA 200.7 06/01/2015 11:33 MHALL3 1 EPA 200.7 06/01/2015 11:33 MHALL3 1 EPA 200.7 06/01/2015 11:33 MHALL3 1 EPA 200.7 06/01/2015 11:33 MHALL3 1 EPA 200.7 06/01/2015 13:39 MHALL3 1 EPA 200.7 06/01/2015 13:39 MHALL3 1 EPA 200.7 06/01/2015 13:39 MHALL3 1 EPA 200.7 06/01/2015 13:39 MHALL3 1 EPA 200.7 06/02/2015 10:32 MHALL3 1 EPA 200.7 06/02/2015 10:32 MHALL3 1 EPA 200.7 06/02/2015 10:32 MHALL3 1 EPA 200.7 06/02/2015 10:32 MHALL3 1 EPA 200.7 06/02/2015 10:32 MHALL3 1 EPA 200.7 06/02/2015 10:32 MHALL3 1 EPA 200.7 06/02/2015 10:32 MHALL3 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050749 Site: I1MW-1 BC Collection Date: 27-May-15 9:45 AM Analyse Result Units Qualifiers RDL TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) 4.00 ug/L 1 Nickel (Ni) 2.05 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) 1.52 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) 4.78 ug/L 1 Nickel (Ni) 2.68 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4) Complete SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 220 mg/L 25 Total Carbon TOC 0.398 mg/L 0.1 TOTAL SUSPENDED SOLIDS TSS 5.0 mg/L 5 Sample #: 2015016348 Matrix: GW_WW DF Method Analysis Date/Time Analyst 1 EPA 200.8 06/15/2015 16:59 JAHERMA 1 EPA 200.8 06/15/2015 16:59 JAHERMA 1 EPA 200.8 06/15/2015 16:59 JAHERMA 1 EPA 200.8 06/15/2015 16:59 JAHERMA 1 EPA 200.8 06/15/2015 16:59 JAHERMA 1 EPA 200.8 06/15/2015 16:59 JAHERMA 1 EPA 200.8 06/15/2015 16:59 JAHERMA 1 EPA 200.8 06/15/2015 16:59 JAHERMA 1 EPA 200.8 06/15/2015 16:59 JAHERMA 1 EPA 200.8 06/15/2015 16:59 JAHERMA 1 EPA 200.8 06/15/2015 16:59 JAHERMA 1 EPA 200.8 06/15/2015 16:59 JAHERMA 1 EPA 200.8 06/15/2015 16:59 JAHERMA 1 EPA 200.8 06/07/2015 02:24 SLS2560 1 EPA 200.8 06/07/2015 02:24 SLS2560 1 EPA 200.8 06/07/2015 02:24 SLS2560 1 EPA 200.8 06/07/2015 02:24 SLS2560 1 EPA 200.8 06/07/2015 02:24 SLS2560 1 EPA 200.8 06/07/2015 02:24 SLS2560 1 EPA 200.8 06/07/2015 02:24 SLS2560 1 EPA 200.8 06/07/2015 02:24 SLS2560 1 EPA 200.8 06/07/2015 02:24 SLS2560 1 EPA 200.8 06/07/2015 02:24 SLS2560 1 EPA 200.8 06/07/2015 02:24 SLS2560 1 EPA 200.8 06/07/2015 02:24 SLS2560 1 EPA 200.8 06/07/2015 02:24 SLS2560 Vendor Method V_SHEALY Vendor Method V_ELE1 1 SM2540C 06/01/201511:17 AGIBBS5 1 SM5310C/EPA9060A 06/04/201516:19 GHUTCHI 1 SM2540D 06/01/2015 08:52 AGIBBS5 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050749 Site: Equipment Blank Collection Date: 26-May-15 12:45 PM Analyse Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.025 mg-N/L 0.01 INORGANIC IONS BY IC Chloride < 0.1 mg/L 0.1 Sulfate 0.12 mg/L 0.1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 UNDIGESTED METALS BY ICP Calcium (Ca) 0.054 mg/L 0.01 Magnesium (Mg) < 0.005 mg/L 0.005 Potassium (K) < 0.1 mg/L 0.1 Sodium (Na) < 0.05 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) < 0.005 mg/L 0.005 Barium (Ba) < 0.005 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) < 0.01 mg/L 0.01 Manganese (Mn) < 0.005 mg/L 0.005 Strontium (Sr) < 0.005 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 Sample #: 2015016349 Matrix: GW_WW DF Method Analysis Date/Time Analyst Vendor Method V_SHEALY 1 EPA 353.2 06/01/2015 14:21 LSTARL1 1 EPA 300.0 06/01/2015 21:35 BGN9034 1 EPA 300.0 06/01/2015 21:35 BGN9034 1 EPA 245.1 06/01/2015 10:26 ACPAYNE 1 EPA 200.7 06/01/2015 14:13 MHALL3 1 EPA 200.7 06/01/2015 14:13 MHALL3 1 EPA 200.7 06/01/2015 14:13 MHALL3 1 EPA 200.7 06/01/2015 14:13 MHALL3 1 EPA 200.7 06/02/2015 10:36 MHALL3 1 EPA 200.7 06/02/2015 10:36 MHALL3 1 EPA 200.7 06/02/2015 10:36 MHALL3 1 EPA 200.7 06/02/2015 10:36 MHALL3 1 EPA 200.7 06/02/2015 10:36 MHALL3 1 EPA 200.7 06/02/2015 10:36 MHALL3 1 EPA 200.7 06/02/2015 10:36 MHALL3 1 EPA 200.8 06/07/2015 02:29 SLS2560 1 EPA 200.8 06/07/2015 02:29 SLS2560 1 EPA 200.8 06/07/2015 02:29 SLS2560 1 EPA 200.8 06/07/2015 02:29 SLS2560 1 EPA 200.8 06/07/2015 02:29 SLS2560 1 EPA 200.8 06/07/2015 02:29 SLS2560 1 EPA 200.8 06/07/2015 02:29 SLS2560 1 EPA 200.8 06/07/2015 02:29 SLS2560 1 EPA 200.8 06/07/2015 02:29 SLS2560 1 EPA 200.8 06/07/2015 02:29 SLS2560 1 EPA 200.8 06/07/2015 02:29 SLS2560 1 EPA 200.8 06/07/2015 02:29 SLS2560 1 EPA 200.8 06/07/2015 02:29 SLS2560 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4) Complete Vendor Method V_SHEALY Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050749 Site: Equipment Blank Collection Date: 26-May-15 12:45 PM Analyse Result Units Qualifiers RDL DF SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS < 25 mg/L 25 1 Total Carbon Sample #: 2015016349 Matrix: GW_WW Method Analysis Date/Time Analyst Vendor Method V_ELE1 SM2540C 06/01/201511:17 AGIBBS5 TOC 1.2 mg/L 0.1 1 SM5310C/EPA9060A 06/04/201516:19 GHUTCHI TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 1 SM2540D 05/29/2015 08:53 AGIBBS5 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050749 Site: Equipment Blank Collection Date: 27-May-15 7:45 AM Analyse Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.044 mg-N/L 0.01 INORGANIC IONS BY IC Chloride < 0.1 mg/L 0.1 Sulfate < 0.1 mg/L 0.1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 UNDIGESTED METALS BY ICP Calcium (Ca) 0.020 mg/L 0.01 Magnesium (Mg) < 0.005 mg/L 0.005 Potassium (K) < 0.1 mg/L 0.1 Sodium (Na) < 0.05 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) < 0.005 mg/L 0.005 Barium (Ba) < 0.005 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) < 0.01 mg/L 0.01 Manganese (Mn) < 0.005 mg/L 0.005 Strontium (Sr) < 0.005 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 Sample #: 2015016350 Matrix: GW_WW DF Method Analysis Date/Time Analyst Vendor Method V_SHEALY 1 EPA 353.2 06/01/2015 14:22 LSTARL1 1 EPA 300.0 06/01/2015 21:52 BGN9034 1 EPA 300.0 06/01/2015 21:52 BGN9034 1 EPA 245.1 06/01/2015 10:28 ACPAYNE 1 EPA 200.7 06/01/2015 14:17 MHALL3 1 EPA 200.7 06/01/2015 14:17 MHALL3 1 EPA 200.7 06/01/2015 14:17 MHALL3 1 EPA 200.7 06/01/2015 14:17 MHALL3 1 EPA 200.7 06/02/2015 10:40 MHALL3 1 EPA 200.7 06/02/2015 10:40 MHALL3 1 EPA 200.7 06/02/2015 10:40 MHALL3 1 EPA 200.7 06/02/2015 10:40 MHALL3 1 EPA 200.7 06/02/2015 10:40 MHALL3 1 EPA 200.7 06/02/2015 10:40 MHALL3 1 EPA 200.7 06/02/2015 10:40 MHALL3 1 EPA 200.8 06/07/2015 02:34 SLS2560 1 EPA 200.8 06/07/2015 02:34 SLS2560 1 EPA 200.8 06/07/2015 02:34 SLS2560 1 EPA 200.8 06/07/2015 02:34 SLS2560 1 EPA 200.8 06/07/2015 02:34 SLS2560 1 EPA 200.8 06/07/2015 02:34 SLS2560 1 EPA 200.8 06/07/2015 02:34 SLS2560 1 EPA 200.8 06/07/2015 02:34 SLS2560 1 EPA 200.8 06/07/2015 02:34 SLS2560 1 EPA 200.8 06/07/2015 02:34 SLS2560 1 EPA 200.8 06/07/2015 02:34 SLS2560 1 EPA 200.8 06/07/2015 02:34 SLS2560 1 EPA 200.8 06/07/2015 02:34 SLS2560 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4) Complete Vendor Method V_SHEALY Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050749 Site: Equipment Blank Collection Date: 27-May-15 7:45 AM Analyse Result Units Qualifiers RDL DF SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS < 25 mg/L 25 1 Total Carbon Sample #: 2015016350 Matrix: GW_WW Method Analysis Date/Time Analyst Vendor Method V_ELE1 SM2540C 06/01/201511:17 AGIBBS5 TOC 0.491 mg/L 0.1 1 SM5310C/EPA9060A 06/04/201516:19 GHUTCHI TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 1 SM2540D 06/01/2015 08:52 AGIBBS5 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050749 Site: Filter Blank Collection Date: 26-May-15 12:45 PM Analyse Result Units Qualifiers RDL Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) < 0.005 mg/L 0.005 Barium (Ba) < 0.005 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) < 0.01 mg/L 0.01 Manganese (Mn) < 0.005 mg/L 0.005 Strontium (Sr) < 0.005 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 Sample #: 2015016351 Matrix: GW_WW DF Method Analysis Date/Time Analyst 1 EPA 245.1 06/03/2015 15:03 ACPAYNE 1 EPA 200.7 06/01/2015 11:37 MHALL3 1 EPA 200.7 06/01/2015 11:37 MHALL3 1 EPA 200.7 06/01/2015 11:37 MHALL3 1 EPA 200.7 06/01/2015 11:37 MHALL3 1 EPA 200.7 06/01/2015 11:37 MHALL3 1 EPA 200.7 06/01/2015 11:37 MHALL3 1 EPA 200.7 06/01/2015 11:37 MHALL3 1 EPA 200.8 06/15/2015 17:06 JAHERMA 1 EPA 200.8 06/15/2015 17:06 JAHERMA 1 EPA 200.8 06/15/2015 17:06 JAHERMA 1 EPA 200.8 06/15/2015 17:06 JAHERMA 1 EPA 200.8 06/15/2015 17:06 JAHERMA 1 EPA 200.8 06/15/2015 17:06 JAHERMA 1 EPA 200.8 06/15/2015 17:06 JAHERMA 1 EPA 200.8 06/15/2015 17:06 JAHERMA 1 EPA 200.8 06/15/2015 17:06 JAHERMA 1 EPA 200.8 06/15/2015 17:06 JAHERMA 1 EPA 200.8 06/15/2015 17:06 JAHERMA 1 EPA 200.8 06/15/2015 17:06 JAHERMA 1 EPA 200.8 06/15/2015 17:06 JAHERMA Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050749 Site: Filter Blank Collection Date: 27-May-15 7:45 AM Analyse Result Units Qualifiers RDL DF Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L DISSOLVED METALS BY ICP Aluminum (AI) < 0.005 mg/L Barium (Ba) < 0.005 mg/L Boron (B) < 0.05 mg/L Iron (Fe) < 0.01 mg/L Manganese (Mn) < 0.005 mg/L Strontium (Sr) < 0.005 mg/L Zinc (Zn) < 0.005 mg/L TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb) < 1 ug/L Arsenic (As) < 1 ug/L Beryllium (Be) < 1 ug/L Cadmium (Cd) < 1 ug/L Chromium (Cr) < 1 ug/L Cobalt (Co) < 1 ug/L Copper (Cu) < 1 ug/L Lead (Pb) < 1 ug/L Molybdenum (Mo) < 1 ug/L Nickel (Ni) < 1 ug/L Selenium (Se) < 1 ug/L Thallium (TI) Low Level < 0.2 ug/L Vanadium (V) Low Level < 0.3 ug/L Sample #: 2015016352 Matrix: GW_WW Method Analysis Date/Time Analyst 0.05 1 EPA 245.1 06/03/2015 15:17 ACPAYNE 0.005 1 EPA 200.7 06/01/2015 11:41 MHALL3 0.005 1 EPA 200.7 06/01/2015 11:41 MHALL3 0.05 1 EPA 200.7 06/01/2015 11:41 MHALL3 0.01 1 EPA 200.7 06/01/2015 11:41 MHALL3 0.005 1 EPA 200.7 06/01/2015 11:41 MHALL3 0.005 1 EPA 200.7 06/01/2015 11:41 MHALL3 0.005 1 EPA 200.7 06/01/2015 11:41 MHALL3 1 1 EPA 200.8 06/15/2015 17:13 JAHERMA 1 1 EPA 200.8 06/15/2015 17:13 JAHERMA 1 1 EPA 200.8 06/15/2015 17:13 JAHERMA 1 1 EPA 200.8 06/15/2015 17:13 JAHERMA 1 1 EPA 200.8 06/15/2015 17:13 JAHERMA 1 1 EPA 200.8 06/15/2015 17:13 JAHERMA 1 1 EPA 200.8 06/15/2015 17:13 JAHERMA 1 1 EPA 200.8 06/15/2015 17:13 JAHERMA 1 1 EPA 200.8 06/15/2015 17:13 JAHERMA 1 1 EPA 200.8 06/15/2015 17:13 JAHERMA 1 1 EPA 200.8 06/15/2015 17:13 JAHERMA 0.2 1 EPA 200.8 06/15/2015 17:13 JAHERMA 0.3 1 EPA 200.8 06/15/2015 17:13 JAHERMA Qualifiers: M2 Matrix spike recovery was Low: the associated Laboratory Control Spike (LCS) was acceptable. -- Additional Information -- M2 - N021NO3 MS/MSD recoveries for sample 2015016344 were below the control limit of 90% (74%, 73%). LCS recoveries were acceptable. Matrix interference is suspected. Mal Element One Inc. 63119-D Carolina Beach Rd. Wilmington, NC 28412 Phone: 910 793-0128 Fax: 910 792-6853 ellab@ellab.com e�n One REPORT OF ANALYSES Duke Energy June 9, 2015 Laboratory Services Client Project Name AB GW Assessment Groundwater HF Lee 13339 Hagers Ferry Road Bld. MG03A Client Project Number J15050749 Huntersville, NC 28078 PO Number Sample Matrix GW WW Sample Type Grab Date Received 05/29/2015 Date Analyzed 06/01/2015 Method SM 4500 S2- D Time Received 1645 Delivered by FedEx Received by LLB eOne ID Duke Energy ID Parameter Result Unit Dil DL Date Sampled Time Sampled 24895-1 LLMW-1 S Sulfide < 0.1 mg/L 1 0.1 05/27/15 1016 24895-2 AMW-GRBC Sulfide 0.110 mg/L 1 0.1 05/26/15 1440 24895-3 IMW-1 S Sulfide < 0.1 mg/L 1 0.1 05/26/15 1410 24895-4* IMW-2 BC Sulfide < 0.2 mg/L 2 0.1 05/26/15 1545 24895-5 IMW-3 BC Sulfide < 0.1 mg/L 1 0.1 05/27/15 1334 24895-6 IMW-1 BC Sulfide < 0.1 mg/L 1 0.1 05/27/15 0945 24895-7* Equipment Blank Sulfide < 0.2 mg/L 2 0.1 05/26/15 1245 24895-8 Equipment Blank Sulfide < 0.1 mg/L 1 0.1 05/27/15 0745 *Sample spike recovery outside of QA limits of 85-115%; dilution necessary to meet laboratory QA limits. Ken Smith, Laboratory Director 24895 Duke Report Packet Compiled by NC Certifications: DW 37788 and DWQ DENR 604 9 T 1 05 ig w Li i t _ THE i W JUi a m Ft I C T E 7 4 Io U � OO K i r punoieuini peilsep alvolpu2 aseoµi :wumdun'sawoasn3 V J _ J ? Of tq y c E � e U N O �A v G � U � S E I9 k � �ta v O. F a �} N UU E C vIn ma z%� p 2z W W wwia E g C elementOne SAMPLE SUBMISSION FORM Lab ID 24895 TAT 7 BD Hold Time Expiration 06.02.15 @ 1410 Client: Duke Energy LIMS No J15050749 Project ID HF Lee Analysis Due Date 06.01.15 Report Due Date 06.09.15 Date Rec: 05.29.15 Time Rec: 0445 Rec By LLB >9 a No �lj Tem <_ 6°C No Ref. Method: SM4500 S2 D No, Record If No, Record Sample Identification & Collection Information Lab ID Client ID Collection Date Collection Time Analysis Requested 1 LLMW-1 S 05/27/15 1016 u i 2 AMW-GRBC 05/26/15 1440 3 IMW-1 S 05/26/15 1410 ulf d 4 IMW-2 BC 05/26/15 1545 u fid 5 IMW-3 BC 05/27/15 1334 1 - 6 IMW-1 BC 05/27/15 0945 Sulf 7 Equipment Blank 05/26/15 1245 ulfi 8 Equipment Blank 05/27/15 0745 ulfid NOTE for Sulfide The MS/MSD spike should approximate 2 to 3 times the sample concentration. If no sulfide detected at 100 pg/L spike the sample to render the final spike concentration at - 500 pg/L Lab Communications All AB Groundwater Assessment jobs need a RL of 0.1 SS Page 1 of 1 Prep By / Date 6 - 1, IS SS by(::)N _ Labeled By / Date .� (a : I • k 5 6/9/2015 11:57:11 AM ID Verification By /Date 4.� 6 + tS METHOD: SM 4500 S2- D ELEMENT ASSAY: Sulfide CLIENT: Duke Lab ID# 24894 / 895 / 896 / 897 / 898` Date: 6/1 /15 Time Analysis Begun 10:00 Time AnaIvsIS Ended 12:50 X Y ug STD STD SOLUTION ABS 0.00 0.000 1.00 0.098 2.50 0.233 5.00 0.442 7.50 0.654 10.00 0.835 ELEMENT ONE Wave Length 664 SPK LEVELL& 5 MAX ALIQUOT 10.00 Na2S•9H2O Lot # STANDARD conc(ppm) X 40721 Cal Std Lot: WC2-85-1 10 QC Std Lot: W62-85-2 10 STD ABSORPTION Y U.300 0700 0,600 - osoo 0 0 4ao 447 .733 0.2 0.1w o.0 160 �000 0.00 200 4.00 800 800 10.00 12M x " f „ t la,SAMPLE Sloe 0.08365054.9 orrelation 0.999269608 I.D. SAMP ABS ug PER ALIQUOT ALI in mL ANALYZED PREP VOL in mL ALI in mL TAKEN RESULTS ug/mL LESS THAN % SPK REC SPIKE LEVEL Sid. B. 0.00 0.000 0.0000 10 10 10 < 0.0 Std. B. 1.00 0.100 0.9268 10 10 10 < 92.68% 1.0 Std. B. 2.50 0.230 2.5255 10 10 10 0.253 101.02% 2.5 Std. B. 5.00 0.435 5.0466 10 10 10 0.505 100.93% 5.0 Std, B. 7.50 0.623 7.3586 10 10 10 0.736 98.11 % 7.5 Std. B. 10.00 0.817 9.7444 10 10 10 0.974 97.44% 10.0 LRB 0.000 0.0000 10 10 10 < 0 LRB SPK 0.460 5.3541 10 10 10 0.535 107% 5.0 QC 0.454 5.2803 10 10 10 0.528 106% 5.0 24894-1 0.011 -0.1677 10 10 10 ' <0.1, 24894-1 s k 0.411 4.7515 10 10 10 0.475 95% 5.0 24894-2 0.000 0.0000 10 10 10 -<r01 24894-2 dup 0.004 -0.2538 10 10 10 < 0.1 24894-2 s k 0.452 5.2557 10 10 10 0.526 105% 5.0 24894-3 0.012 -0.1554 10 10 10 < p,1, 24894-3 s k 0.409 4.7269 10 10 10 0.473 95% 5.0 24894-4 0.003 -0.2661 10 10 10 = < 0,1' `_ r 24894-4 s k 0.453 5.2680 10 10 10 0.527 105% 5.0 24894-5 0.002 -0.2784 10 10 10 24894-5 s k 0.449 5.2188 10 10 10 0.522 104% 5.0 24895-1 0.003 -0.2661 10 10 100.1' 24895-1 s k 0.422 4.8867 10 10 10 0.489 98% 5.0 24895-2 0.114 1.0990 10 10 10 0111.0 24895-2 s k 0.493 5.7599 10 10 10 0.576 93% 5.0 24895-3 0.002 -0.2784 10 10 10 24895-3 s k 0.400 4.6162 10 10 10 0.462 92% 5.0 24895-4 0.080 1 0.6809 10 10 10 < 24895-4 s k 0.497 5.8091 10 10 10 0.581 116% 5.0 Blank 0.000 0.0000 10 10 10 < QC 0.456 5.3049 10 10 10 0.530 106% 0 Submitted fOr QA/QC- Date: 06/01/15 By: (Print) KAM (sign): 1/- Page 1 of 5 METHOD: SM 4500 S2- D ELEMENT ASSAY: Sulfide CLIENT: Duke Lab ID# 24894 / 895 / 896 / 897 / 898 Date: 6/1/15 Time Analysis Begun 10:00 Time Analysis Ended 12:50 X Y ug STD STD SOLUTION ABS 0.00 0.000 1.00 0.098 2.50 0.233 5.00 0.442 7.50 0.654 10.00 0.835 ELEMENT ONE Wave Length 664 SPK LEVEL (uc MAX ALIQUOT Na2S•9H2O Lot # STANDARD co 40721 Cal Std Lot: QC Std Lot: r STD ABSORPI 5 10.05 X 10 10 u Sloe 0.083650549 orrelation 0.999269608 SAMPLE I.D. SAMP ABS ug PER ALIQUOT ALI in mL ANALYZED PREP VOL in mL ALI in mL TAKEN RESULTS u /mL LESS THAN % SPK REC SPIKE LEVEL Std. B. 0.00 0.000 0.0000 10 10 10 < 0.0 Std. B. 1.00 0.100 0.9268 10 10 10 < 92.68% 1.0 Std, B. 2.50 0.230 2.5255 10 10 10 0.253 10101.02% 2.5 Std. B. 5.00 0.435 5.0466 10 10 10 0.505 100.93% 5.0 Std. B. 7.50 0.623 7.3586 10 10 10 0.736 98.11 % 7.5 Std. B. 10.00 0.817 9.7444 10 10 10 0.974 97.44% 10.0 LRB 0.000 0.0000 10 10 10 < 0 LRB SPK 0.460 5.3541 10 10 10 0.535 107% 5.0 QC 0.454 5.2803 10 10 10 0.528 106% 5.0 24895-5 0.003 -0.2661 10 10 10 24895-5 s k 0.435 5.0466 10 10 10 0.505 101 % 5.0 24895-6 0.005 -0.2415 10 10 10 0:1; 24895-6 dup 0.002 -0.2784 10 10 10 < 0.1 24895-6 s k 0.431 4.9974 10 10 10 0.500 100% 5.0 24895-7 0.000 1 0.0000 10 10 10 < 24895-7 s k 0.347 3.9644 10 10 10 0.396 79% 5.0 24895-8 0.000 0.0000 10 10 10 24895-8 s k 0.446 5.1819 10 10 10 0.518 104% 5.0 24896-1 0.006 -0.2292 10 10 10 24896-1 s k 0.413 4.7761 10 10 10 0.478 96% 5.0 24896-2 0.000 0.0000 10 10 10 { © T� 24896-2 s k, 0.435 5.0466 10 10 10 0.505 101% 5.0 24896-3 0.019 -0.0693 10 10 10 C?:1 24896-3 s k 0.417 4.8252 10 10 10 0.483 97% 5.0 24896-4 • 0.003 -0.2661 10 10 10.01 24896-4 s k 0.448 5.2065 10 10 10 0.521 104% 5.0 24896-5 0.004 -0.2538 10 10 10� (} 1 24896-5 s k 0.421 4.8744 10 10 10 0.487 97% 5.0 Blank 0.000 0.0000 10 10 10 < QC 0.456 5.3049 10 10 10 0.530 106% 5.0 Submitted for QA/QC- Date: 06/01/15 By: (Print) KAM (s r Page 2 of 5 METHOD: SM 4500 S2- D ELEMENT ONE ELEMENT ASSAY: Sulfide Spectrophotometer UNITS OF ANSWE u /mL Date: 6/1/15 Time Analysis Begun 10:00 Time Analysis Ended 12:50 Analyst: KAM X Y ug STD STD SOLUTION ABS 0.00 0.000 1.00 0.098 2.50 0.233 5.00 0.442 7.50 0.654 10.00 0.835 Wave Length 664 "" `� I IVIY LIIVII 1 SPK LEVEL (ug) MAX ALIQUOT Na2S•9H2O Lot # STANDARD conc(ppm) 40721 Cal Std Lot: Wr,2. QC Std Lot: W 2 STD ABSORPTION x Sloe 0.083650549 orrelation 0.999259508 SAMPLE I.D. SAMP ABS ug PER ALIQUOT ALI in mL ANALYZED PREP VOL in mL ALI in mL TAKEN RESULTS u 1mL LESS THAN % SPK REC SPIKE LEVEL Std. B. 0.00 0.000 0.0000 10 10 10 < 0.0 Std. B. 1.00 0.100 0.9268 10 10 10 < 92.68% 1.0 Std. B. 2.50 0.230 2.5255 10 10 10 0.253 101.02% 2.5 Std. B. 5.00 0.435 5.0466 10 10 10 0.505 100.93% 5.0 Std. B. 7.50 0.623 7.3586 10 10 10 0.736 98.11 % 7.5 Std. B. 10.00 0.817 9.7444 10 10 10 0.974 97.44% 10.0 LRB 0.000 0.0000 10 10 10 < 0 LRB SPK 0.460 5.3541 10 10 10 0.535 107% 5.0 QC 0.454 5.2803 10 10 10 0.528 106% 5.0 24896-6 0.014 -0.1308 10 10 10 < 24896-6 s k 0.297 3.3495 10 10 10 0.335 67% 5.0 24897-1 0.030 0.0660 10 10 10 24897-1 spk 0.388 4.4686 10 10 10 0.447 89% 5.0 24897-2 0.007 -0.2169 10 10 10 24897-2 dup 0.001 -0.2907 10 10 10 < 0.1 24897-2 s k 0.385 1 4.4317 10 10 10 0.443 89% 5.0 24897-3 0.017 1 -0.0939 10 10 10 24897-3 s k 0.417 4.8252 10 10 10 0.483 97% 5.0 24897-4 0.005 -0.2415 10 10 10 24897-4 s k 0.452 5.2557 10 10 10 0.526 105% 5.0 24898-1 0.005 -0.2415 10 10 10 24898-1 s k 0.403 4.6531 10 10 10 0.465 ' 93% 5.0 24898-2 0.006 -0.2292 10 10 10 24898-2 s k 0.431 4.9974 10 10 10 0.500 100% 5.0 24898-3 0.002 -0.2784 10 10 10 24898-3 s k 0.428 4.9605 10 10 10 0.496 99% 5.0 24898-4 0.006 -0.2292 10 10 10"'111 ' 24898-4 s k 0.396 4.5670 10 10 10 0.457 91 % 5.0 Blank 0.000 0.0000 10 10 10 < QC 1 0.456 5.3049 10 10 10 0.530 106% Submitted for QA/QC- Date: 06/01/15 By: (Print) KAM _,.5,0 (s Page 3 of 5 METHOD: SM 4500 S2- D ELEMENT ONE ELEMENT ASSAY: Sulfide Spectrophotometer Wave Length 664 UNITS OF ANSWER, ug/mL 1.000 5 DETECTION LIMIT CLIENT: Duke SPK LEVEL u Lab ID# 24894 / 895 / 896 / 897 / 898 / 899 6/1/15 10 00 12:50 KAM Y MAX ALIQUOT Na2S•9H2O Lot # STANDARD conc(ppm) 40721 Cal Std Lot: W 1 QC Std Lot: W JSTD ABSORPTION 10.00 Date: X Time Analysis Begun . 2-85-1 10 Time Analysis Ended 2-85-2 10 Analyst: Y t -- - -o- T X ug STD SOLUTION STD I ABS !, °,m _ -- -1 -- - - - -- 0.00 1.00 2.50 5.00 7.50 10.00 0.000 °" °°°° 0.098 0.233 0.442 0.654 0.835 0.+00 °°°° x Sloe 0.083650649 orrelation 0.999259608 SAMPLE I.D. SAMP ABS ug PER ALIQUOT ALI in mL ANALYZED PREP VOL in mL ALI in mL TAKEN RESULTS ug/mL LESS °° THAN SPK REC SPIKE LEVEL Std. B. 0.00 0.000 0.0000 10 10 10 < 0.0 Std. B. 1.00 0.100 0.9268 10 10 10 < 92.68% 1.0 Std. B. 2.50 0.230 2.5255 10 10 10 0.253 101.02% 2.5 Std. B. 5.00 0.435 5.0466 10 10 10 0.505 1100.93% 5.0 Std. B. 7.50 0.623 7.3586 10 10 10 0.736 98.11 % 7.5 Std. B. 10.00 0.817 9.7444 10 10 10 0.974 97.44% 10.0 LRB 0.000 0.0000 10 10 10 < 0 LRB SPK 0.460 5.3541 10 10 10 0.535 107% 5.0 QC 0.454 5.2803 10 10 10 0.528 106% 5.0 24898-5 0.011 -0.1677 10 10 10 < 24898-5 s k 0.290 3.2634 10 10 10 0.326 65% 5.0 24898-6 0.268 2.9929 10 10 10 24898-6 s k 0.702 8.3301 10 1 10 10 0.833 107% 5.0 24898-7 0.003 -0.2661 10 10 10 24898-7 s k 0.413 4.7761 10 10 10 0.478 96% 5.0 24898-8 0.201 2.1689 10 10 10 fl.17 24898-8 dup 0.187 1.9967 10 10 10 0.200 24898-8 s k 0.572 6.7314 10 10 10 0.673 95% 5.0 24898-9 0.000 0.0000 10 10 10' `"01 24898-9 s k 0.447 5.1942 10 10 10 0.519 104% 5.0 24899-1 0.013 -0.1431 10 10 10 < 24899-1 s k 0.307 1 3.4725 10 10 10 0.347 69% 5.0 24899-2 0.005 -0.2415 10 10 10 <<0°1; A 24899-2 s k 0.417 4.8252 10 10 10 0.483 97% 5.0 24899-3 0.013 -0.1431 10 10 10 0! 1 24899-3 s k 0.437 5.0712 10 10 10 0.507 101 % 5.0 24899-4 0.001 -0.2907 10 10 10 01. 24899-4 s k 0.447 5.1942 10 10 10 0.519 104% 5.0 Blank 0.000 0.0000 10 10 10 < QC 0.454 1 5.2803 10 10 1 10 0.528 106% 5 Submitted for QA/QC- Date: 06/01/15 By: (Print) KAM (s gn): Page 4 of 5 P HOD : SM 4500 S2- DENT ASSAY: Sulfide CLIENT: Duke Lab ID# 24894 / 8951896 / 897 189E Date: 6111 1'S x I YJ o. ug STD STD I oaW )LUTION ABS "00 0.6w 0.00 0.000 y 1.00 0.098 °`W 0,310 2.50 0.233 0100 5.00 0.442 0100 7.50 0,654 0.=( 10.00 0.835 SAMPLE I.D. SAMP I ug Ntrc ABS ALIQUOT Std. B. 0.00 0.000 0.0000 Std. B. 1.00 0.100 0.9268 Std. B. 2.50 0.230 2.5255 Std. B. 5.00 0.435 5.0466 Std. B. 7.50 0.623 7.3586 Std. B. 10.00 0.817 9.7444 LRB 0.000 0.0000 LRB SPK 0.460 5.3541 QC 0.454 5.2803 24895-4 0.045 0.2504 24895-4 s k 0.475 5.5385 24895-7 24895-7 s k 0.000 0.458 0.0000 5.3295 24896-6 0.014 -0.1308 24896-6 s k 0.392 4.5178 24898-5 0.005 -0.2415 24898-5 s k 0.37. 4.3087 24899-1 -0.001 0.0000 24899-1 s k 0.366 4.1981 24899-1 0.001 -0.2907 24899-1 spk 0.414 4.7884 Blank 0.000 1 0.0000 QC 1 0.455 5.2926 Fed -for QA/QC - Date: 06/0 ELEMENT ONE pectrophotometer Length 664 MOFSWIMWave TNa,S•9HZ0 Lot# corn40721 200 4,W 6.00 x III n mL ANALYZED 10 10 10 10 10 10 PREP VOL in mL 10 10 10 10 10 10 ALI in mL TAKEN 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 5 10 10 5 10 10 5 10 10 5 10 10 5 10 10 5 10 10 5 10 10 5 10 10 5 10 10 5 10 10 2 10 10 2 10 10 10 10 10 10 By: (Print) Page 5 of 5 8.00 ug/mL < < 0.253 0.505 0.736 0.974 % SPK REC 92.68% 101.02% 100.93% 98.11 % 97.44% LEVEL 0.0 1.0 2.5 5.0 7.5 10.0 < 0 0.535 107% 5.0 0.528 106% 5.0 r02 _11108 _ 111% 5.0 1.066 107% 5.0 02. _ _ 0.904 90% 5.0 0.862 86% 5.0 0.840 84% 5.0 2.394 96% 5.0 < 0.529 106% SHEALY ENVIRONMENTAL SERVICES, INC. Report of Analysis Duke Energy 13339 Hagers Ferry Rd Bldg 7405 Huntersville, NC 28078 Attention: Mary Ann Ogle Project Name: AB GW Assessment Water - HF Lee Project Number:J15050749 Lot Number:QF01020 Date Completed:06/05/2015 Grant Wilton Project Manager This report shall not be reproduced, except in its entirety, without the written approval of Shealy Environmental Services, Inc. The following non -paginated documents are considered part of this report: Chain of Custody Record and Sample Receipt Checklist. * QF01 0 2 0 * Shealy Environmental Services, Inc. Page: 1 of 20 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. SC DHEC No: 32010 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative Duke Energy Lot Number: QF01020 Project Name: AB GW Assessment Water - HF Lee Project Number: J15050749 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the Shealy Environmental Services, Inc. ("Shealy") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPS), and Shealy policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below. If you have any questions regarding this report please contact the Shealy Project Manager listed on the cover page Shealy Environmental Services, Inc. Page: 2 of 20 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. Sample Summary Duke Energy Lot Number: QF01020 Project Name: AB GW Assessment Water - HF Lee Project Number: J15050749 Sample Number Sample ID Matrix Date Sampled Date Received 001 2015016342 Aqueous 05/27/20151016 05/29/2015 002 2015016344 Aqueous 05/26/20151440 05/29/2015 003 2015016345 Aqueous 05/26/20151410 05/29/2015 004 2015016346 Aqueous 05/26/20151545 05/29/2015 005 2015016347 Aqueous 05/27/20151334 05/29/2015 006 2015016348 Aqueous 05/27/2015 0945 05/29/2015 007 2015016349 Aqueous 05/27/20151245 05/29/2015 008 2015016350 Aqueous 05/27/2015 0745 05/29/2015 (8 samples) Shealy Environmental Services, Inc. Page: 3 of 20 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. Executive Summary Duke Energy Lot Number: QF01020 Project Name: AB GW Assessment Water - HF Lee Project Number: J15050749 Sample Sample ID Matrix Parameter Method Result Q Units Page 001 2015016342 Aqueous Alkalinity SM 2320B- 71 mg/L 5 001 2015016342 Aqueous Bicarbonate Alkalinity SM 2320B- 71 mg/L 5 001 2015016342 Aqueous Methane RSK - 175 29 ug/L 6 002 2015016344 Aqueous Alkalinity SM 2320B- 83 mg/L 7 002 2015016344 Aqueous Bicarbonate Alkalinity SM 2320B- 83 mg/L 7 003 2015016345 Aqueous Alkalinity SM 2320B- 12 mg/L 9 003 2015016345 Aqueous Bicarbonate Alkalinity SM 2320B- 12 mg/L 9 004 2015016346 Aqueous Alkalinity SM 2320B- 130 mg/L 11 004 2015016346 Aqueous Bicarbonate Alkalinity SM 2320B- 130 mg/L 11 005 2015016347 Aqueous Alkalinity SM 2320B- 82 mg/L 13 005 2015016347 Aqueous Bicarbonate Alkalinity SM 2320B- 82 mg/L 13 006 2015016348 Aqueous Alkalinity SM 2320B- 70 mg/L 15 006 2015016348 Aqueous Bicarbonate Alkalinity SM 2320B- 70 mg/L 15 (13 detections) Shealy Environmental Services, Inc. Page: 4 of 20 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals Client: Duke Energy Laboratory ID: QF01020-001 Description: 2015016342 Matrix: Aqueous Date Sampled:05/27/2015 1016 Project Name: AB GW Assessment Water - Date Received:05/29/2015 Project Number: J15050749 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 06/02/2015 1714 HMA 76308 1 (Bicarbonate ) SM 2320B-2011 1 06/02/2015 1714 HMA 06/02/2015 1714 1 (Carbonate Al) SM 2320B-2011 1 06/02/2015 1714 HMA 06/02/2015 1714 CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 71 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 71 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 5 of 20 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane Client: Duke Energy Laboratory ID: QF01020-001 Description: 2015016342 Matrix: Aqueous Date Sampled:05/27/2015 1016 Project Name: AB GW Assessment Water - Date Received:05/29/2015 Project Number: J15050749 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 06/03/2015 1854 JJG 76496 CAS Analytical Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 29 10 ug/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 6 of 20 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals Client: Duke Energy Laboratory ID: QF01020-002 Description: 2015016344 Matrix: Aqueous Date Sampled:05/26/2015 1440 Project Name: AB GW Assessment Water - Date Received:05/29/2015 Project Number: J15050749 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 06/02/2015 1721 HMA 76308 1 (Bicarbonate ) SM 2320B-2011 1 06/02/2015 1721 HMA 06/02/2015 1721 1 (Carbonate Al) SM 2320B-2011 1 06/02/2015 1721 HMA 06/02/2015 1721 CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 83 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 83 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 7 of 20 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane Client: Duke Energy Laboratory ID: QF01020-002 Description: 2015016344 Matrix: Aqueous Date Sampled:05/26/2015 1440 Project Name: AB GW Assessment Water - Date Received:05/29/2015 Project Number: J15050749 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 06/03/2015 2148 JJG 76497 CAS Analytical Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 10 ug/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 8 of 20 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals Client: Duke Energy Laboratory ID: QF01020-003 Description: 2015016345 Matrix: Aqueous Date Sampled:05/26/2015 1410 Project Name: AB GW Assessment Water - Date Received:05/29/2015 Project Number: J15050749 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 06/02/2015 1737 HMA 76308 1 (Bicarbonate ) SM 2320B-2011 1 06/02/2015 1737 HMA 06/02/2015 1737 1 (Carbonate Al) SM 2320B-2011 1 06/02/2015 1737 HMA 06/02/2015 1737 CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 12 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 12 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 9 of 20 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane Client: Duke Energy Laboratory ID: QF01020-003 Description: 2015016345 Matrix: Aqueous Date Sampled:05/26/2015 1410 Project Name: AB GW Assessment Water - Date Received:05/29/2015 Project Number: J15050749 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 06/03/2015 2159 JJG 76497 CAS Analytical Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 10 ug/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 10 of 20 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals Client: Duke Energy Laboratory ID: QF01020-004 Description: 2015016346 Matrix: Aqueous Date Sampled:05/26/2015 1545 Project Name: AB GW Assessment Water - Date Received:05/29/2015 Project Number: J15050749 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 06/02/2015 1744 HMA 76308 1 (Bicarbonate ) SM 2320B-2011 1 06/02/2015 1744 HMA 06/02/2015 1744 1 (Carbonate Al) SM 2320B-2011 1 06/02/2015 1737 HMA 06/02/2015 1744 CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 130 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 130 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 11 of 20 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane Client: Duke Energy Laboratory ID: QF01020-004 Description: 2015016346 Matrix: Aqueous Date Sampled:05/26/2015 1545 Project Name: AB GW Assessment Water - Date Received:05/29/2015 Project Number: J15050749 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 06/03/2015 2222 JJG 76497 CAS Analytical Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 10 ug/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 12 of 20 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals Client: Duke Energy Laboratory ID: QF01020-005 Description: 2015016347 Matrix: Aqueous Date Sampled:05/27/2015 1334 Project Name: AB GW Assessment Water - Date Received:05/29/2015 Project Number: J15050749 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 06/02/2015 1749 HMA 76308 1 (Bicarbonate ) SM 2320B-2011 1 06/02/2015 1749 HMA 06/02/2015 1749 1 (Carbonate Al) SM 2320B-2011 1 06/02/2015 1749 HMA 06/02/2015 1749 CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 82 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 82 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 13 of 20 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane Client: Duke Energy Laboratory ID: QF01020-005 Description: 2015016347 Matrix: Aqueous Date Sampled:05/27/2015 1334 Project Name: AB GW Assessment Water - Date Received:05/29/2015 Project Number: J15050749 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 06/03/2015 2232 JJG 76497 CAS Analytical Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 10 ug/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 14 of 20 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals Client: Duke Energy Laboratory ID: QF01020-006 Description: 2015016348 Matrix: Aqueous Date Sampled:05/27/2015 0945 Project Name: AB GW Assessment Water - Date Received:05/29/2015 Project Number: J15050749 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 06/02/2015 1755 HMA 76308 1 (Bicarbonate ) SM 2320B-2011 1 06/02/2015 1755 HMA 06/02/2015 1755 1 (Carbonate Al) SM 2320B-2011 1 06/02/2015 1755 HMA 06/02/2015 1755 CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 70 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 70 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 15 of 20 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane Client: Duke Energy Laboratory ID: QF01020-006 Description: 2015016348 Matrix: Aqueous Date Sampled:05/27/2015 0945 Project Name: AB GW Assessment Water - Date Received:05/29/2015 Project Number: J15050749 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 06/03/2015 2253 JJG 76497 CAS Analytical Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 10 ug/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 16 of 20 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals Client: Duke Energy Laboratory ID: QF01020-007 Description: 2015016349 Matrix: Aqueous Date Sampled:05/27/2015 1245 Project Name: AB GW Assessment Water - Date Received:05/29/2015 Project Number: J15050749 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 06/02/2015 1845 HMA 76309 1 (Bicarbonate ) SM 2320B-2011 1 06/02/2015 1845 HMA 06/02/2015 1845 1 (Carbonate Al) SM 2320B-2011 1 06/02/2015 1845 HMA 06/02/2015 1845 CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 ND 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 17 of 20 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane Client: Duke Energy Laboratory ID: QF01020-007 Description: 2015016349 Matrix: Aqueous Date Sampled:05/27/2015 1245 Project Name: AB GW Assessment Water - Date Received:05/29/2015 Project Number: J15050749 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 06/03/2015 2306 JJG 76497 CAS Analytical Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 10 ug/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 18 of 20 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals Client: Duke Energy Laboratory ID: QF01020-008 Description: 2015016350 Matrix: Aqueous Date Sampled:05/27/2015 0745 Project Name: AB GW Assessment Water - Date Received:05/29/2015 Project Number: J15050749 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 06/02/2015 1851 HMA 76309 1 (Bicarbonate ) SM 2320B-2011 1 06/02/2015 1851 HMA 06/02/2015 1851 1 (Carbonate Al) SM 2320B-2011 1 06/02/2015 1851 HMA 06/02/2015 1851 CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 ND 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 19 of 20 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane Client: Duke Energy Laboratory ID: QF01020-008 Description: 2015016350 Matrix: Aqueous Date Sampled:05/27/2015 0745 Project Name: AB GW Assessment Water - Date Received:05/29/2015 Project Number: J15050749 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 06/03/2015 2320 JJG 76497 CAS Analytical Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 10 ug/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 20 of 20 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 QC Summary Shealy Environmental Services, Inc. QC Data for Lot Number: QF01020 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals - Ii Sample ID: QQ76308-001 Matrix: Aqueous Batch: 76308 Analytical Method: SM 2320B-2011 Parameter Result Q Dil PQL Units Analysis Date Alkalinity ND 1 10 mg/L 06/02/20151515 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QF01020 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals - LCS Sample ID: QQ76308-002 Matrix: Aqueous Batch: 76308 Analytical Method: SM 2320B-2011 Spike Amount Result % Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Alkalinity 100 94 1 94 90-110 06/02/20151521 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QF01020 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals - MS Sample ID: QF01020-006MS Matrix: Aqueous Batch: 76308 Analytical Method: SM 2320B-2011 Sample Spike Amount Amount Result % Rec Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Alkalinity 70 100 160 1 85 70-130 06/02/20151802 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QF01020 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals - MSD Sample ID: QF01020-006MD Matrix: Aqueous Batch: 76308 Analytical Method: SM 2320B-2011 Sample Spike Amount Amount Result % Rec % RPD Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date Alkalinity 70 100 160 1 90 3.3 70-130 20 06/02/20151808 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QF01020 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals - Ii Sample ID: QQ76309-001 Matrix: Aqueous Batch: 76309 Analytical Method: SM 2320B-2011 Parameter Result Q Dil PQL Units Analysis Date Alkalinity ND 1 10 mg/L 06/02/20151821 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QF01020 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals - LCS Sample ID: QQ76309-002 Matrix: Aqueous Batch: 76309 Analytical Method: SM 2320B-2011 Spike Amount Result % Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Alkalinity 100 92 1 92 90-110 06/02/20151827 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QF01020 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane - MB Sample ID: QQ76496-001 Matrix: Aqueous Batch: 76496 Analytical Method: RSK - 175 Parameter Result Q Dil PQL Units Analysis Date Methane ND 1 10 ug/L 06/03/20151449 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QF01020 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane - LCS Sample ID: QQ76496-002 Matrix: Aqueous Batch: 76496 Analytical Method: RSK - 175 Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Methane 150 160 1 106 70-130 06/03/20151328 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QF01020 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane - LCSD Sample ID: QQ76496-003 Matrix: Aqueous Batch: 76496 Analytical Method: RSK - 175 Spike Amount Result % Rec % RPD Parameter (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date Methane 150 150 1 101 4.8 70-130 30 06/03/20151340 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QF01020 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane - MB Sample ID: QQ76497-001 Matrix: Aqueous Batch: 76497 Analytical Method: RSK - 175 Parameter Result Q Dil PQL Units Analysis Date Methane ND 1 10 ug/L 06/03/2015 2116 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QF01020 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane - LCS Sample ID: QQ76497-002 Matrix: Aqueous Batch: 76497 Analytical Method: RSK - 175 Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Methane 150 150 1 101 70-130 06/03/2015 2030 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QF01020 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane - LCSD Sample ID: QQ76497-003 Matrix: Aqueous Batch: 76497 Analytical Method: RSK - 175 Spike Amount Result % Rec % RPD Parameter (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date Methane 150 130 1 89 13 70-130 30 06/03/2015 2053 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QF01020 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. Shealy EnvFn rorncncai Scry�ices, Inc Docurnam NUn* r: IF AU C-16 RapP�p� D... ]TPle]ff��+14 Yisi f�'u mbfr. 1' Ef&cc; vc Dane: Oa/ ReI3 Sample Receipt Checklist RQ �F �'� �� ' I CClient.aolcrInspr✓cted by/tlate: �•„ tilIt # Means of reccipr- ❑ .SIESI ❑ client Elups I[I FcdEx � Airbornc Ex P �'thCl 'Yes Na 1. V4'ere Yes No NA 2_ l€ custatd scale �ve[o rtsC.nt, were the intact and unbroken? cooler iI}1Qriginfll tcmpera[ure upon rtt�iipLr'Derivec] (c�rre>`t[.�) ternp�erafure upon reecipt: I'+rie.thvrt: � Terrpr.faturc lank A,�ainst Bnttia`,S Il;i Glair LDS 5- [R Gun Correction Facta�ar: � 4 etltod of eoalarit: Wet I Blue Ioe crL�sfvd X seals present oil the cooler? �C Dry lcr- ElNone. 3. If re-01peralure of any cooler exs e.adcd 6,Clatr:, WaS Project Manager notified? Yes � No ❑ Phil notified by SRC, NA � onc, note (circles one), other: _ (For coolers reccived via commercial courier, k"AU arc to be notified immediatel - Yes ❑ No ❑ NA 4. is the csamrn6rcial courier's ckiq sli attached to this form? Y No 5_ Werc proper custoid oc redijreS relin uishr-keruceiveci folfollowed?_Y� ❑ No NA 5a Were sarsilets Tlin uished by client U) u ammercial c uurier' Yes No ❑ & Were 5a II~ IDs listed Ou the EtJC? YCs 1400 7. Werr. sample IDS Iistcd on ali sample conC-aincls? Yes No ❑ 8- Was oolluc ion date firnc listed r3rr the COr—? _y4a5 No a__! 9• Was cC►ilectiyon date: & tirne listed on all sa le contairicrs? Yes ['do El10, Did all container la be] infornt121#io❑ ID, date Cim15 ee with the COC? yCS No El1L_ Were tests. to be erformcd listed on the COC? yes No ❑ 1.2, Did all sam les arr.iVa in the ro r containers for each test? Yes No-0 13_ Did all containers arri-ve ingood cnnditian unbroken Lids can, ate.)? Yes ND ❑ 14. Was adequate sa le volurrie available? Yes El NO 13. Were all sampleR re ivied within'A the holding time. or 48 houis, whichever comes firs#? 4 s o 1 , Wcrc any samples conlainers mi ing9 Yes Q No IT Were there an exce55 samples. not listed on C{)C7 'yaks ❑ No NA El18. V40crc bubbles present ," ea -size" (Y."or 6mm in d]ai eTer in a VIDA veats? ypes No NA 19_ V4'ere all txtetatls/O&G]HEM)nutriicat samples rtceive4 at S Hof �C2? 'YES El 7' o C N ��}_ 4�lre• all C at7lii� and/or suI ide sS]Si ltS received at a H >22? Yes d Nu ❑ 21 . Were all appljr bles NII3fI'KN/cyajii&!/phenol (<0_2mg}L) samples frcc of ,BL �, residual a: 4orinc? Yes [—j No ❑ NA y 22_ Were, collection tern ratures docurrie.ne�droTi the COC; N far C sat let? Yes C] 1,10 ❑ NA [�' 23. erE c lienr remarks/requests (Le- lequesecd 61uriom, MiS, SD designations, ric.., correctlytranscribed from the COO into the comment section in L.rms? I Ye.s ❑ Ala �24_ Was the quote number used taken from the container label? SamMin Sample PrIeS rVAEi0FI (t b, completed for any Sample($) incorfe l reserved err with heads(7tace. Samples) ---we re received incorrectly preserved and were. aadjusted accardin 1 in earn le rec vin R with H2S0,aH1+� ,H1Cl,Na0H usin SR # Sa lc s wGre received with bubbles;*6 MM in diarneter, Sample(s)were rccvived with TRC:'st1,2 +L Ile 421 is NO SC Drinking Waluy Project Smple(s) pH verified to he > 2 by Date - le s' Were were not recciv°crf tit a PH of <2 arA were. adjusted aCWTdin ly usin SR# Sant le labels applicd by; ~^, Verified try-_ Data: Comn mets: Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. � CY i I F � dj ae' f Ch C3 U1. t1`g� ! re IN N;11 iq Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 000- -lCX mangy oom om®IMM CUMm am MISSION ==an oam om�o m amm.m�em�o�Co iBC�miiCeie��ne�iio Cr io�iini�onio C C�MECiiii��iiio Nam IN ummosoC Illm soomoAom�nomo =Ron nn�m _Man Si%�C CirCoeaoo�o�oo©