NC0003417_J15040277 Report_20150805

DUE Analytical Laboratory
ENERGY
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone:[phone] Fax:[phone]
Order Summary Report
Order Number: J15040277
Project Name: HF LEE PLANT - AB GW ASSESSMENT WATER
Customer Name(s): Tim Hunsucker, Judd Mahan, Kathy Webb, John Toepfer
Customer Address: 1677 Old Smithfield Rd
Goldsboro NC 27530,
Lab Contact: Mary Ann Ogle Phone: [phone]
`p Mary Ann Ogle
Report Authorized By: f 201 5.04.27 Date:
(Signature) 15.5-5 26---04-00
Mary Ann Ogle
Program Comments:
Please contact the Program Manager (Mary Ann Ogle) with any questions regarding this report.
Data Flags & Calculations:
4/27/2015
Analytical Lab
Page 1 of 41
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Sample ID's & Descriptions:
Collection
Sample ID Plant/Station Date and Time
2015010448
2015010449
2015010450
2015010455
2015010456
5 Total Samples
Collected By
Sample Description
HF LEE PLANT
10-Apr-15 2:20 PM
ILLEGIBLE
LLMW-1
HF LEE PLANT
10-Apr-15 1:02 PM
ILLEGIBLE
LLMW-2
HF LEE PLANT
10-Apr-15 9:38 AM
ILLEGIBLE
IABMW-1
HF LEE PLANT
10-Apr-15 8:50 AM
ILLEGIBLE
Filter Blank
HF LEE PLANT
10-Apr-15 8:50 AM
ILLEGIBLE
Equipment Blank
Analytical Lab
Page 2 of 41

Analytical Lab
Page 3 of 41
Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals 0 Yes ❑ No
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits. ❑ Yes 0 No
All laboratory QA/QC requirements are acceptable. 0 Yes ❑ No
Report Sections Included:
E%-'] Job Summary Report
❑� Sample Identification
Technical Validation of Data Package
❑� Analytical Laboratory Certificate of Analysis
❑ Analytical Laboratory QC Report
❑d Sub -contracted Laboratory Results
❑ Customer Specific Data Sheets, Reports, & Documentation
❑ Customer Database Entries
❑� Chain of Custody
❑� Electronic Data Deliverable (EDD) Sent Separately
Reviewed By: Mary Ann Ogle Date: 4/27/2015

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15040277
Site: LLMW-1
Collection Date: 10-Apr-15 2:20 PM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter
Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)
0.014
mg-N/L
0.01
INORGANIC IONS BY IC
Chloride
29
mg/L
1
Sulfate
5.2
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
0.682
mg/L
0.005
Boron (B)
0.100
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
0.123
mg/L
0.005
Strontium (Sr)
1.46
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
UNDIGESTED METALS BY lCP
Calcium (Ca)
50.5
mg/L
0.01
Magnesium (Mg)
7.78
mg/L
0.005
Potassium (K)
5.37
mg/L
0.1
Sodium (Na)
20.1
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.282
mg/L
0.005
Barium (Ba)
0.695
mg/L
0.005
Boron (B)
0.098
mg/L
0.05
Iron (Fe)
0.130
mg/L
0.01
Manganese (Mn)
0.126
mg/L
0.005
Strontium (Sr)
1.49
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Sample #: 2015010448
Matrix: GW_WW
Analytical Lab
Page 4 of 41
DF Method Analysis Date/Time Analyst
Vendor Method
V_SHEALY
1
EPA 353.2
04/15/2015 15:11
LSTARLI
10
EPA 300.0
04/15/2015 21:59
BGN9034
1
EPA 300.0
04/15/2015 21:59
BGN9034
1
EPA 245.1
04/15/2015 12:58
ACPAYNE
1
EPA 245.1
04/15/2015 13:59
ACPAYNE
1
EPA 200.7
04/14/2015 12:59
MHALL3
1
EPA 200.7
04/14/2015 12:59
MHALL3
1
EPA 200.7
04/14/2015 12:59
MHALL3
1
EPA 200.7
04/14/2015 12:59
MHALL3
1
EPA 200.7
04/14/2015 12:59
MHALL3
1
EPA 200.7
04/14/2015 12:59
MHALL3
1
EPA 200.7
04/14/2015 12:59
MHALL3
1
EPA 200.7
04/14/2015 14:57
MHALL3
1
EPA 200.7
04/14/2015 14:57
MHALL3
1
EPA 200.7
04/14/2015 14:57
MHALL3
1
EPA 200.7
04/14/2015 14:57
MHALL3
1
EPA 200.7
04/15/2015 11:26
MHH7131
1
EPA 200.7
04/15/2015 11:26
MHH7131
1
EPA 200.7
04/15/2015 11:26
MHH7131
1
EPA 200.7
04/15/2015 11:26
MHH7131
1
EPA 200.7
04/15/2015 11:26
MHH7131
1
EPA 200.7
04/15/2015 11:26
MHH7131
1
EPA 200.7
04/15/2015 11:26
MHH7131

Analytical Lab
Certificate of Laboratory Analysis Page 5 of 41
This report shall not be reproduced, except in full.
Order # J15040277
Site: LLMW-1
Sample #: 2015010448
Collection Date: 10-Apr-15 2:20
PM
Matrix: GW_WW
Analyte
Result
Units Qualifiers
RDL
DF
Method
Analysis Date/Time
Analyst
DISSOLVED METALS BY ICP-MS
Antimony (Sb)
2.66
ug/L
1
1
EPA 200.8
04/23/2015 11:31
DJSULL1
Arsenic (As)
6.02
ug/L
1
1
EPA 200.8
04/23/2015 11:31
DJSULL1
Beryllium (Be)
< 1
ug/L
1
1
EPA 200.8
04/23/2015 11:31
DJSULL1
Cadmium (Cd)
< 1
ug/L
1
1
EPA 200.8
04/23/2015 11:31
DJSULL1
Chromium (Cr)
< 1
ug/L
1
1
EPA 200.8
04/23/2015 11:31
DJSULL1
Cobalt (Co)
< 1
ug/L
1
1
EPA 200.8
04/23/2015 11:31
DJSULL1
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
04/23/2015 11:31
DJSULL1
Lead (Pb)
< 1
ug/L
1
1
EPA 200.8
04/23/2015 11:31
DJSULL1
Molybdenum (Mo)
1.98
ug/L
1
1
EPA 200.8
04/23/2015 11:31
DJSULL1
Nickel (Ni)
1.28
ug/L
1
1
EPA 200.8
04/23/2015 11:31
DJSULL1
Selenium (Se)
1.76
ug/L
1
1
EPA 200.8
04/23/2015 11:31
DJSULL1
Thallium (TI) Low Level
0.637
ug/L
0.2
1
EPA 200.8
04/23/2015 11:31
DJSULL1
Vanadium (V) Low Level
16.0
ug/L
0.3
1
EPA 200.8
04/23/2015 11:31
DJSULL1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
2.45
ug/L
1
1
EPA 200.8
04/21/2015 13:39
DJSULL1
Arsenic (As)
7.61
ug/L
1
1
EPA 200.8
04/21/2015 13:39
DJSULL1
Beryllium (Be)
< 1
ug/L
1
1
EPA 200.8
04/21/2015 13:39
DJSULL1
Cadmium (Cd)
< 1
ug/L
1
1
EPA 200.8
04/21/2015 13:39
DJSULL1
Chromium (Cr)
< 1
ug/L
1
1
EPA 200.8
04/21/2015 13:39
DJSULL1
Cobalt (Co)
< 1
ug/L
1
1
EPA 200.8
04/21/2015 13:39
DJSULL1
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
04/21/2015 13:39
DJSULL1
Lead (Pb)
< 1
ug/L
1
1
EPA 200.8
04/21/2015 13:39
DJSULL1
Molybdenum (Mo)
2.24
ug/L
1
1
EPA 200.8
04/21/2015 13:39
DJSULL1
Nickel (Ni)
1.57
ug/L
1
1
EPA 200.8
04/21/2015 13:39
DJSULL1
Selenium (Se)
1.69
ug/L
1
1
EPA 200.8
04/21/2015 13:39
DJSULL1
Thallium (TI) Low Level
0.572
ug/L
0.2
1
EPA 200.8
04/21/2015 13:39
DJSULL1
Vanadium (V) Low Level
16.5
ug/L
0.3
1
EPA 200.8
04/21/2015 13:39
DJSULL1
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
Vendor Method
V_SHEALY
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
Vendor Method
V_ELE1
TOTAL DISSOLVED SOLIDS
TDS
270
mg/L
25
1
SM2540C
04/15/201514:30
AGIBBS5
Total Carbon
TOC
1.3
mg/L
0.1
1
SM5310C/EPA9060A
04/16/201511:47
GHUTCHI
TOTAL SUSPENDED SOLIDS
TSS
< 5
mg/L
5
1
SM2540D
04/14/2015 08:09
AGIBBS5

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15040277
Site: LLMW-2
Collection Date: 10-Apr-15 1:02 PM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter
Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)
< 0.01
mg-N/L
0.01
INORGANIC IONS BY IC
Chloride
20
mg/L
1
Sulfate
2.1
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
0.984
mg/L
0.005
Boron (B)
0.087
mg/L
0.05
Iron (Fe)
0.032
mg/L
0.01
Manganese (Mn)
0.371
mg/L
0.005
Strontium (Sr)
1.54
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
UNDIGESTED METALS BY lCP
Calcium (Ca)
28.1
mg/L
0.01
Magnesium (Mg)
9.83
mg/L
0.005
Potassium (K)
8.28
mg/L
0.1
Sodium (Na)
19.6
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.037
mg/L
0.005
Barium (Ba)
0.960
mg/L
0.005
Boron (B)
0.081
mg/L
0.05
Iron (Fe)
0.059
mg/L
0.01
Manganese (Mn)
0.351
mg/L
0.005
Strontium (Sr)
1.53
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Sample #: 2015010449
Matrix: GW_WW
Analytical Lab
Page 6 of 41
DF Method Analysis Date/Time Analyst
Vendor Method
V_SHEALY
1
EPA 353.2
04/15/2015 15:13
LSTARLI
10
EPA 300.0
04/15/2015 22:17
BGN9034
1
EPA 300.0
04/15/2015 22:17
BGN9034
1
EPA 245.1
04/15/2015 13:01
ACPAYNE
1
EPA 245.1
04/15/2015 14:02
ACPAYNE
1
EPA 200.7
04/14/2015 13:10
MHALL3
1
EPA 200.7
04/14/2015 13:10
MHALL3
1
EPA 200.7
04/14/2015 13:10
MHALL3
1
EPA 200.7
04/14/2015 13:10
MHALL3
1
EPA 200.7
04/14/2015 13:10
MHALL3
1
EPA 200.7
04/14/2015 13:10
MHALL3
1
EPA 200.7
04/14/2015 13:10
MHALL3
1
EPA 200.7
04/14/2015 14:54
MHALL3
1
EPA 200.7
04/14/2015 14:54
MHALL3
1
EPA 200.7
04/14/2015 14:54
MHALL3
1
EPA 200.7
04/14/2015 14:54
MHALL3
1
EPA 200.7
04/15/2015 11:38
MHH7131
1
EPA 200.7
04/15/2015 11:38
MHH7131
1
EPA 200.7
04/15/2015 11:38
MHH7131
1
EPA 200.7
04/15/2015 11:38
MHH7131
1
EPA 200.7
04/15/2015 11:38
MHH7131
1
EPA 200.7
04/15/2015 11:38
MHH7131
1
EPA 200.7
04/15/2015 11:38
MHH7131

Analytical Lab
Certificate of Laboratory Analysis Page 7 of 41
This report shall not be reproduced, except in full.
Order # J15040277
Site: LLMW-2
Sample #: 2015010449
Collection Date: 10-Apr-15 1:02
PM
Matrix: GW_WW
Analyte
Result
Units Qualifiers
RDL
DF
Method
Analysis Date/Time
Analyst
DISSOLVED METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
04/23/2015 11:46
DJSULL1
Arsenic (As)
5.29
ug/L
1
1
EPA 200.8
04/23/2015 11:46
DJSULL1
Beryllium (Be)
< 1
ug/L
1
1
EPA 200.8
04/23/2015 11:46
DJSULL1
Cadmium (Cd)
< 1
ug/L
1
1
EPA 200.8
04/23/2015 11:46
DJSULL1
Chromium (Cr)
< 1
ug/L
1
1
EPA 200.8
04/23/2015 11:46
DJSULL1
Cobalt (Co)
1.83
ug/L
1
1
EPA 200.8
04/23/2015 11:46
DJSULL1
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
04/23/2015 11:46
DJSULL1
Lead (Pb)
< 1
ug/L
1
1
EPA 200.8
04/23/2015 11:46
DJSULL1
Molybdenum (Mo)
3.00
ug/L
1
1
EPA 200.8
04/23/2015 11:46
DJSULL1
Nickel (Ni)
4.40
ug/L
1
1
EPA 200.8
04/23/2015 11:46
DJSULL1
Selenium (Se)
< 1
ug/L
1
1
EPA 200.8
04/23/2015 11:46
DJSULL1
Thallium (TI) Low Level
0.972
ug/L
0.2
1
EPA 200.8
04/23/2015 11:46
DJSULL1
Vanadium (V) Low Level
6.02
ug/L
0.3
1
EPA 200.8
04/23/2015 11:46
DJSULL1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
04/21/2015 13:21
DJSULL1
Arsenic (As)
5.73
ug/L
1
1
EPA 200.8
04/21/2015 13:21
DJSULL1
Beryllium (Be)
< 1
ug/L
1
1
EPA 200.8
04/21/2015 13:21
DJSULL1
Cadmium (Cd)
< 1
ug/L
1
1
EPA 200.8
04/21/2015 13:21
DJSULL1
Chromium (Cr)
< 1
ug/L
1
1
EPA 200.8
04/21/2015 13:21
DJSULL1
Cobalt (Co)
1.74
ug/L
1
1
EPA 200.8
04/21/2015 13:21
DJSULL1
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
04/21/2015 13:21
DJSULL1
Lead (Pb)
< 1
ug/L
1
1
EPA 200.8
04/21/2015 13:21
DJSULL1
Molybdenum (Mo)
2.85
ug/L
1
1
EPA 200.8
04/21/2015 13:21
DJSULL1
Nickel (Ni)
4.24
ug/L
1
1
EPA 200.8
04/21/2015 13:21
DJSULL1
Selenium (Se)
< 1
ug/L
1
1
EPA 200.8
04/21/2015 13:21
DJSULL1
Thallium (TI) Low Level
0.997
ug/L
0.2
1
EPA 200.8
04/21/2015 13:21
DJSULL1
Vanadium (V) Low Level
5.33
ug/L
0.3
1
EPA 200.8
04/21/2015 13:21
DJSULL1
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
Vendor Method
V_SHEALY
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
Vendor Method
V_ELE1
TOTAL DISSOLVED SOLIDS
TDS
220
mg/L
25
1
SM2540C
04/15/201514:30
AGIBBS5
Total Carbon
TOC
2.1
mg/L
0.1
1
SM5310C/EPA9060A
04/16/201511:47
GHUTCHI
TOTAL SUSPENDED SOLIDS
TSS
< 5
mg/L
5
1
SM2540D
04/14/2015 08:09
AGIBBS5

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15040277
Site: IABMW-1
Collection Date: 10-Apr-15 9:38 AM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter
Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)
< 0.01
mg-N/L
0.01
INORGANIC IONS BY IC
Chloride
7.2
mg/L
0.1
Sulfate
65
mg/L
1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
0.593
mg/L
0.005
Boron (B)
0.972
mg/L
0.05
Iron (Fe)
0.997
mg/L
0.01
Manganese (Mn)
0.390
mg/L
0.005
Strontium (Sr)
5.55
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
UNDIGESTED METALS BY lCP
Calcium (Ca)
231
mg/L
0.2
Magnesium (Mg)
17.4
mg/L
0.005
Potassium (K)
16.1
mg/L
0.1
Sodium (Na)
27.4
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.019
mg/L
0.005
Barium (Ba)
0.634
mg/L
0.005
Boron (B)
1.05
mg/L
0.05
Iron (Fe)
1.15
mg/L
0.01
Manganese (Mn)
0.423
mg/L
0.005
Strontium (Sr)
5.95
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Sample #: 2015010450
Matrix: GW_WW
Analytical Lab
Page 8 of 41
DF Method Analysis Date/Time Analyst
Vendor Method
V_SHEALY
1
EPA 353.2
04/15/2015 15:18
LSTARLI
1
EPA 300.0
04/16/2015 00:13
BGN9034
10
EPA 300.0
04/16/2015 00:13
BGN9034
1
EPA 245.1
04/15/2015 13:10
ACPAYNE
1
EPA 245.1
04/15/2015 14:04
ACPAYNE
1
EPA 200.7
04/14/2015 13:14
MHALL3
1
EPA 200.7
04/14/2015 13:14
MHALL3
1
EPA 200.7
04/14/2015 13:14
MHALL3
1
EPA 200.7
04/14/2015 13:14
MHALL3
1
EPA 200.7
04/14/2015 13:14
MHALL3
1
EPA 200.7
04/14/2015 13:14
MHALL3
1
EPA 200.7
04/14/2015 13:14
MHALL3
20
EPA 200.7
04/14/2015 14:34
MHALL3
1
EPA 200.7
04/14/2015 14:34
MHALL3
1
EPA 200.7
04/14/2015 14:34
MHALL3
1
EPA 200.7
04/14/2015 14:34
MHALL3
1
EPA 200.7
04/15/2015 11:42
MHH7131
1
EPA 200.7
04/15/2015 11:42
MHH7131
1
EPA 200.7
04/15/2015 11:42
MHH7131
1
EPA 200.7
04/15/2015 11:42
MHH7131
1
EPA 200.7
04/15/2015 11:42
MHH7131
1
EPA 200.7
04/15/2015 11:42
MHH7131
1
EPA 200.7
04/15/2015 11:42
MHH7131

Analytical Lab
Certificate of Laboratory Analysis Page 9 of 41
This report shall not be reproduced, except in full.
Order # J15040277
Site: IABMW-1
Sample #: 2015010450
Collection Date: 10-Apr-15 9:38
AM
Matrix: GW_WW
Analyte
Result
Units Qualifiers
RDL
DF
Method
Analysis Date/Time
Analyst
DISSOLVED METALS BY lCP-MS
Antimony (Sb)
2.22
ug/L
1
1
EPA 200.8
04/23/2015 11:50
DJSULL1
Arsenic (As)
8.30
ug/L
1
1
EPA 200.8
04/23/2015 11:50
DJSULL1
Beryllium (Be)
< 1
ug/L
1
1
EPA 200.8
04/23/2015 11:50
DJSULL1
Cadmium (Cd)
< 1
ug/L
1
1
EPA 200.8
04/23/2015 11:50
DJSULL1
Chromium (Cr)
< 1
ug/L
1
1
EPA 200.8
04/23/2015 11:50
DJSULL1
Cobalt (Co)
4.09
ug/L
1
1
EPA 200.8
04/23/2015 11:50
DJSULL1
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
04/23/2015 11:50
DJSULL1
Lead (Pb)
< 1
ug/L
1
1
EPA 200.8
04/23/2015 11:50
DJSULL1
Molybdenum (Mo)
31.1
ug/L
1
1
EPA 200.8
04/23/2015 11:50
DJSULL1
Nickel (Ni)
8.31
ug/L
1
1
EPA 200.8
04/23/2015 11:50
DJSULL1
Selenium (Se)
< 1
ug/L
1
1
EPA 200.8
04/23/2015 11:50
DJSULL1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
04/23/2015 11:50
DJSULL1
Vanadium (V) Low Level
19.7
ug/L
0.3
1
EPA 200.8
04/23/2015 11:50
DJSULL1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
2.19
ug/L
1
1
EPA 200.8
04/21/2015 13:44
DJSULL1
Arsenic (As)
10.7
ug/L
1
1
EPA 200.8
04/21/2015 13:44
DJSULL1
Beryllium (Be)
< 1
ug/L
1
1
EPA 200.8
04/21/2015 13:44
DJSULL1
Cadmium (Cd)
< 1
ug/L
1
1
EPA 200.8
04/21/2015 13:44
DJSULL1
Chromium (Cr)
< 1
ug/L
1
1
EPA 200.8
04/21/2015 13:44
DJSULL1
Cobalt (Co)
4.68
ug/L
1
1
EPA 200.8
04/21/2015 13:44
DJSULL1
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
04/21/2015 13:44
DJSULL1
Lead (Pb)
< 1
ug/L
1
1
EPA 200.8
04/21/2015 13:44
DJSULL1
Molybdenum (Mo)
34.0
ug/L
1
1
EPA 200.8
04/21/2015 13:44
DJSULL1
Nickel (Ni)
8.72
ug/L
1
1
EPA 200.8
04/21/2015 13:44
DJSULL1
Selenium (Se)
< 1
ug/L
1
1
EPA 200.8
04/21/2015 13:44
DJSULL1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
04/21/2015 13:44
DJSULL1
Vanadium (V) Low Level
18.9
ug/L
0.3
1
EPA 200.8
04/21/2015 13:44
DJSULL1
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
Vendor Method
V_SHEALY
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
Vendor Method
V_ELE1
TOTAL DISSOLVED SOLIDS
TDS
800
mg/L
25
1
SM2540C
04/15/201514:30
AGIBBS5
Total Carbon
TOC
1.4
mg/L
0.1
1
SM5310C/EPA9060A
04/16/201511:47
GHUTCHI
TOTAL SUSPENDED SOLIDS
TSS
< 5
mg/L
5
1
SM2540D
04/14/2015 08:09
AGIBBS5

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15040277
Site: Filter Blank
Collection Date: 10-Apr-15 8:50 AM
Analyte
Result
Units
Qualifiers RDL
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
< 0.005
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
< 0.005
mg/L
0.005
Strontium (Sr)
< 0.005
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
DISSOLVED METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
Sample #: 2015010455
Matrix: GW_WW
Analytical Lab
Page 10 of 41
DF
Method
Analysis Date/Time
Analyst
1
EPA 245.1
04/15/2015 14:07
ACPAYNE
1
EPA 200.7
04/14/2015 13:37
MHALL3
1
EPA 200.7
04/14/2015 13:37
MHALL3
1
EPA 200.7
04/14/2015 13:37
MHALL3
1
EPA 200.7
04/14/2015 13:37
MHALL3
1
EPA 200.7
04/14/2015 13:37
MHALL3
1
EPA 200.7
04/14/2015 13:37
MHALL3
1
EPA 200.7
04/14/2015 13:37
MHALL3
1
EPA 200.8
04/23/2015 11:55
DJSULL1
1
EPA 200.8
04/23/2015 11:55
DJSULL1
1
EPA 200.8
04/23/2015 11:55
DJSULL1
1
EPA 200.8
04/23/2015 11:55
DJSULL1
1
EPA 200.8
04/23/2015 11:55
DJSULL1
1
EPA 200.8
04/23/2015 11:55
DJSULL1
1
EPA 200.8
04/23/2015 11:55
DJSULL1
1
EPA 200.8
04/23/2015 11:55
DJSULL1
1
EPA 200.8
04/23/2015 11:55
DJSULL1
1
EPA 200.8
04/23/2015 11:55
DJSULL1
1
EPA 200.8
04/23/2015 11:55
DJSULL1
1
EPA 200.8
04/23/2015 11:55
DJSULL1
1
EPA 200.8
04/23/2015 11:55
DJSULL1

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15040277
Site: Equipment Blank
Collection Date: 10-Apr-15 8:50 AM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy
Labs)
Vendor Parameter
Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)
< 0.01
mg-N/L
0.01
INORGANIC IONS BY IC
Chloride
< 0.1
mg/L
0.1
Sulfate
< 0.1
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
UNDIGESTED METALS BY lCP
Calcium (Ca)
< 0.01
mg/L
0.01
Magnesium (Mg)
< 0.005
mg/L
0.005
Potassium (K)
< 0.1
mg/L
0.1
Sodium (Na)
< 0.05
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
< 0.005
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
< 0.005
mg/L
0.005
Strontium (Sr)
< 0.005
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
Analytical Lab
Page 11 of 41
Sample #: 2015010456
Matrix: GW_WW
DF Method Analysis Date/Time Analyst
Vendor Method V_SHEALY
1 EPA 353.2
04/15/2015 15:21
LSTARLI
1 EPA 300.0
04/15/2015 22:44
BGN9034
1 EPA 300.0
04/15/2015 22:44
BGN9034
1 EPA 245.1
04/15/2015 13:03
ACPAYNE
1 EPA 200.7
04/14/2015 15:01
MHALL3
1 EPA 200.7
04/14/2015 15:01
MHALL3
1 EPA 200.7
04/14/2015 15:01
MHALL3
1 EPA 200.7
04/14/2015 15:01
MHALL3
1 EPA 200.7
04/15/2015 11:47
MHH7131
1 EPA 200.7
04/15/2015 11:47
MHH7131
1 EPA 200.7
04/15/2015 11:47
MHH7131
1 EPA 200.7
04/15/2015 11:47
MHH7131
1 EPA 200.7
04/15/2015 11:47
MHH7131
1 EPA 200.7
04/15/2015 11:47
MHH7131
1 EPA 200.7
04/15/2015 11:47
MHH7131
1 EPA 200.8
04/21/2015 13:35
DJSULL1
1 EPA 200.8
04/21/2015 13:35
DJSULL1
1 EPA 200.8
04/21/2015 13:35
DJSULL1
1 EPA 200.8
04/21/2015 13:35
DJSULL1
1 EPA 200.8
04/21/2015 13:35
DJSULL1
1 EPA 200.8
04/21/2015 13:35
DJSULL1
1 EPA 200.8
04/21/2015 13:35
DJSULL1
1 EPA 200.8
04/21/2015 13:35
DJSULL1
1 EPA 200.8
04/21/2015 13:35
DJSULL1
1 EPA 200.8
04/21/2015 13:35
DJSULL1
1 EPA 200.8
04/21/2015 13:35
DJSULL1
1 EPA 200.8
04/21/2015 13:35
DJSULL1
1 EPA 200.8
04/21/2015 13:35
DJSULL1
METHANE - (Analysis Performed by Shealy Labs)
Methane (CH4) Complete Vendor Method V_SHEALY

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15040277
Site: Equipment Blank
Collection Date: 10-Apr-15 8:50 AM
Analyte Result Units Qualifiers RDL DF
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete
TOTAL DISSOLVED SOLIDS
TDS < 25 mg/L 25 1
Total Carbon
Sample #: 2015010456
Matrix: GW_WW
Analytical Lab
Page 12 of 41
Method Analysis Date/Time Analyst
Vendor Method
V_ELE1
SM2540C 04/15/201514:30 AGIBBS5
TOC 0.247 mg/L 0.1 1 SM5310C/EPA9060A 04/16/201511:47 GHUTCHI
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L 5 1 SM2540D 04/14/2015 08:09 AGIBBS5

Analytical Lab
Page 13 of 41
Element One lnce
6319-D Carolina Beach Rd.
Wilmington, IBC 28412
Phone: [phone]
Fan: 910 792-6853
ellabellnh #-e%m
hnmentOne
REPORT OF ANALYSES
Duke Energy April 22, 2015
Laboratory Services Client Project Name AB GW Assessment
13339 Hagers Ferry Road Bld. MG03A Client Project Number J15040277
Huntersville, NC 28078 PO Number
Sample Matrix
GW WW
Sample Type
Grab
Date Received
04/16/2015
Date Analyzed
04/16/2015
Method
SM 4500 S2- D
Time Received
1040
Delivered by
FedEx
Received by
JRC
eOne ID
Duke Energy ID
Parameter
Result
Unit
Dil
DL Date
Time
Sampled
Sampled
24536-1
LLMW-1
Sulfide
< 0.1
mg/L
1
0.1 04/10/15
1420
24536-2
LLMW-2
Sulfide
< 0.1
mg/L
1
0.1 04/10/15
1302
24536-3
IABMW-1
Sulfide
< 0.1
mg/L
1
0.1 04/10/15
0938
24536-4
Equipment Blank
Sulfide
< 0.1
mg/L
1
0.1 04/10/15
0850
Ken Smith, LaboratoryDirector
24536 Duke Report Packet Compiled by�
NC Certifications: DW 37788 and DWQ DENR 604

O
1—
wlRu� � Igol a o
a
e
1Wn(0e
,
NNeoI
IA
(MOI•-�N I
sae) elsewNp
l
I
oeNNNN
Ibpe'MeAspws4'J
epUinS
slvuognal9
�O61�aieuI
-MIN
-"Iqm Doi
YOS'19
AsUleo3sIPg
I
NI
`s•
MOWSUVylaw
SOl'SS'LQ
N
wo x At
".
b dWO�
cn
LLn
Analytical Lab
Page 14 of 41
punoisuwnl POPSOP
91volpwatvold iuvvodwl'jouumn3
4

eaementOne SAMPLE SUBMISSION FORM
TAT 7 BD
Hold Time Expiration 04.17.15 @ 0938AM
Client: Duke Energy
LIMS No J15040277
Project ID HF Lee
Analytical Lab
Lab I v age24J36
Analysis Due Date 04.16.15
Report Due Date 04.27.15
Date Rec:
04.16.15
Time Rec:
1040
Rec By
JRC
H >9 es No Tem <_ 6°C a No Ref. Method:
If No, Record If No, Record SM4500 S2 D
a7Q111 IC
Lab ID
IYGIINIIVcluvn a1c vvn�iva•v••
Client ID
Collection Date
Collection Time
Analysis Requested
1
LLMW-1
04.10.15
1420 PM
Sulfide
2
LLMW-2
04.10.15
1302 PM
Sulfide
3
IABMW-1
04.10.15
0938 AM _
Sulfide _
4
Equipment Blank
04.10.15
0850 AM
Sulfide
NOTE
RL is 0.1
Lab Communications
SS Pag 1 of 1 Prep By / Date 0^ L ' i � l K
SS b Labeled By / Dates
4/16 201 1:51:09 PM ID Verification By /Date i +-�• (G

Analytical Lab
Page 16 of 41
METHOD:
SM 4500 S2- D
ELEMENT ONE
ELEMENT ASSAY:
Sulfide
Spectrophotometer
Wave Length 664
UNITS OF ANSWER
DETECTION LIMIT u
1.000
CLIENT:
Duke
SPK LEVEL u
5
Lab ID#
24536 / 24537 MAX ALIQUOT 10.00
4/16/15 Na2S•9H2O Lot # STANDARD conc(ppm) X
14:30 40721 ICal Std Lot: 10
17:50 QC Std Lot:
KAM ISTID ABSORPTION Y
Y o�
Date:
Time Analysis Begun
Time Analysis Ended
Analyst:
X
ug STD
SOLUTION
STD
°7�
o,.
ABS
O'�
0.00
2.50
5.00:,
7.50
10.00
0.000
e<�
0.230
02M
0.413
°,(
0.621
0.759
°°°OM ]W aW ow 8w ,QW 12.W
x
=
Slope 0.076718681'
PREP ALI in mL RESULTS
VOL in mL TAKEN ug/mL
Correlation 0.997430236
SAMPLE
I.D.
SAMP
ABS
ug PER
ALIQUOT
ALI in mL
ANALYZED
LESS THAN
% SPK REC
SPIKE
LEVEL
Std. B. 0.00
0.000
10
10
10
<
0
Std. B. 1.00
0.093
0.8206
10
10
10
<
82%
1
Std. B. 2.50
0.217
2.5002
10
10
10
0.250
100%
2.5
Std. B. 5.00
0.397
4.9384
10
10
10
0.494
99%
5
Std. B. 7.50
0.582
7.4442
10
10
10
0.744
99%
7.5
Std. B. 10.00
0.754
9.7740
10
10
10
0.977
98%
10
LRB
0.000
0.0000
10
10
10
<
#DIV/0!
0
LRB SPK
0.372
4.5997
10
10
10
0.460
92%
5.0
QC
0.390
4.8435
10
10
10
0.484
97%
5.0
24536-1
0.003
-0.3985
10
10
10
1;
0.482
96%
5.0
24536-1 spk
0.388
4.8164
10
10
10
24536-2
0.000
0.0000
10
10
10
<
24536-2 dup
0.007
-0.3443
10
10
10
24536-2 spk
0.372
4.5997
10
10
10
0.460
92%
5.0
24536-3
0.004
-0.3850
10
10
10
0.494
24536-3 spk
0.397
4.9384
10
10
10
99%
5.0
24536-4
0.001
-0.4256
10
10
10
0 .
24536-4 s k
0.417
5.2093
10
10
10
0.521
104%
5.0
24537-1
0.001
-0.4256
10
10
10
<
24537-1 spk
0.119
1.1728
10
10
10
0.117
23%
5.0
24537-2
0.002
-0.4120
10
10
10
Awr-
24537-2 spk
0.351
4.3153
10
10
10
0.432
°f
5.0
24537-3
0.000
0.0000
10
10
10
<
24537-3 s k
0.195
2.2022
10
10
10
0.220
44%
5.0
24537-4
0.000
0.0000
10
10
10
<
24537-4 s k
0.249
2.9337
10
10
10
0.293
59%
5.0
24537-5
0.004
-0.3850
10
10
10
<
24537-5 spk
0.317
3.8547
10
10
10
0.385
77%
5.0
Blank
0.000
0.0000
10
10
10
<
QC
0.384
4.7623
1 10
10
10
1 0.476
95%
5.0
Submitted for QA/QC-
Date: 4/16/15
By: (Print)
KAM
(sign):
p A5& k

Analytical Lab
Page 17 of 41
METHOD:
SM 4500 S2- D
ELEMENT ONE
ELEMENT ASSAY:
Sulfide
Spectrophotometer
Wave Length 664
UNITS OF ANSWER
DETECTION LIMIT u
1.000
CLIENT:
Duke
SPK LEVEL( q)
5
Lab ID#
24536/ 24537
Na2S•91-12O Lot #
40721
1
ISTDABSORPTION
MAX ALIQUOT
10.00
Date:
4/16/15
STANDARD conc(ppm)
X
Time Analysis Begun
14:30 .
Cal Std Lot:
10
Time Analysis Ended
17:50
QC Std Lot:
Analyst:
KAM
Y
X
Y
ug STD
SOLUTION
STD
ABS
07W
0"
0.00
2.50 `
5.00
7.50
10.00
0.000
0,230
0.413
0.621
0.759
0. °
so
01,400
W
,000
02W
0+0
0�0 2.00 400 eW B.00 ,OW 12M
X
ug PER ALI in mL PREP
ALIQUOT ANALYZED VOL in mL
Slope 0.076718681
Correlation 0.997430236'
SAMPLE
I.D.
SAMP
ABS
ALI in mL
TAKEN
RESULTS
ug/mL
LESS THAN
% SPK REC
SPIKE
LEVEL
Std. B. 0.00
0.000
10
10
10
<
0
Std. B. 1.00
0.093
0.8206
10
10
10
<
82%
1
Std. B. 2.50
0.217
2.5002
10
10
10
0.250
100%
2.5
Std. B. 5.00
0.397
4.9384
10
10
10
0.494
99%
5
Std. B. 7.50
0.582
7.4442
10
10
10
0.744
99%
7.5
Std. B. 10.00
0.754
9.7740
10
10
10
0.977
98%
10
LRB
0.000
0.0000
10
10
10
<
#DIV/0!
0
LRB SPK
0.372
4.5997
10
10
10
0.460
92%
5.0
QC
0.390
4.8435
10
10
10
0.484
97%
5.0
24537-6
0.000
0.0000
10
10
10
0.505
101 %
5.0
24537-6 spk
0.405
5.0467
10
10
10
24537-7
0.001
-0.4256
10
10
10
<
24537-7 dup
0.001
1 -0.4256
10
10
10
24537-7 spk
0.400
4.9790
10
10
5
0.996
100%
5.0
24537-1
0.000
0.0000
10
10
5
<
24537-1 spk
0.170
1.8636
10
10
5
0.373
37%
5.0
24537-3
0.001
-0.4256
1 10
10
5
<
24537-3 spk
0.251
2.9607
10
10
5
0.592
59%
5.0
24537-4
0.001
-0.4256
10
10
5
<
24537-4 s k
0.291
3.5026
10
10
5
0.701
70%
5.0
24537-5
0.003
1 -0.3985
10
10
5
<
24537-5 spk
0.33
4.0308
10
10
5
0.806
81 %
5.0
24537-1
0.000
0.0000
10
10
2
<
24537-1 spk
0.276
3.2994
10
10
2
1.650
66%
5.0
24537-3
0.003
-0.3985
10
10
2
<
24537-3 spk
0.322
1 3.9225
10
10
2
1.961
78%
5.0
24537-4
0.001
-0.4256
10
10
2
<
24537-4 spk
0.330
4.0308
10
10
2
2.015
81 %
5.0
24537-5
0.002
-0.4120
10
10
2
0 ;.�
2.178 87%
24537-5 s k
0.354
4.3559
10
10
2
5.0
Blank
0.000
1 0.0000
10
10
10
<
QC
0.383
1 4.7487
10
10
1 10
0.475
1 95%
5.0
Submifted for QA/QC-
Date: 4/16/15
By: (Print)
KAM
(sign)

Analytical Lab
Page 18 of 41
METHOD:
SM 4500 S2- D
ELEMENT ONE
ELEMENT ASSAY:
Sulfide
Spectrophotometer
Wave Length 564
UNITS OF ANSWER
u' /mL
DETECTION LIMIT u
1.000
CLIENT:
Duke
SPK LEVEL (um
5
Lab ID#
24536 / 24537
Na2S•9H2O Lot #
40721
IQC
__
MAX ALIQUOT
10.00
Date:
4/16/15
STANDARD conc(ppm)
X
Time Analysis Begun
14:30
Cal Std Lot:
10
Time Analysis Ended
17:50
Std Lot:
Analyst:
KAM
STD ABSORPTION
_
Y
X
Y
---
D.800
0,759
ug STD
SOLUTION
STD
ABS
o.rou
D�
0.00
1.00
2,50
5.00.
7.50
10.00
0.000
0.091
0.230
0.413
0.621
0.759
osoo
a.ao0
03M
zoo
0,200
0 to
o0°0&
zoo 4W 600 800 low 12.00
X
._ � ,. , � „,
,� . �_
, _ ., �, , �
Slope 0.076718681
Correlation 0.987430236
SAMPLE
I.D.
SAMP
ABS
ug PER
ALIQUOT
ALI in mL
ANALYZED
PREP
VOL in mL
ALI in mL
TAKEN
RESULTS
u /mL
LESS THAN
% SPK REC
SPIKE
LEVEL
Std. B. 0.00
0
10
10
10
<
0
Std. B. 1.00
0.093
0.8206
10
10
10
<
82%
1
Std. B. 2.50
0.217
2.5002
10
10
10
0.250
100%
2.5
Std. B. 5.00
0.397
4.9384
10
10
10
0.494
99%
5
Std. B. 7.50
0.582
7.4442
10
10
10
0.744
99%
7.5
Std. B. 10.00
0.754
9.7740
10
10
10
0.977
98%
10
LRB
0.000
0.0000
10
10
10
<
0
LRB SPK
0.372
4.5997
10
10
10
0.460
92%
5.0
QC
0.390
4.8435
10
10
10
0.484
97%
5.0
24537-1
-0.001
0.0000
10
10
1
<
24537-1 dup
0.001
-0.4256
10
10
1
<
24537-1 s k
0.297
3.5838
10
10
1
3.584
72%
5.0
24537-3
0.001
-0.4256
10
10
1
<
24537-3 s k
0.326
3.9766
10
10
1
3.977
80%
5.0
24537-4
0.005
-0.3714
10
10
1
<
24537-4 s k
0.334
4.0850
10
10
1
4.085
82%
5.0
24537-1
-0.001
0.0000
10
10
0.5
2 0
8.901
24537-1 s k
0.361
4.4507
10
10
0.5
89%
5.0
24537-3
-0.001
0.0000
10
10
0.5
9.010
24537-3 s k
0.365
4.5049
10
10
0.5
90%
5.0
24537-4
0.002
-0.4120
10
10
0.5
11411,1=�
9.145
24537-4 s k
0.370
4.5726
10
10
0.5
91 %
5.0
Blank
0.000
0.0000
10
10
10
<
QC
0.380
4.7081
10
10
10
0.471
94%
5.0
Submitted for QA/QC- Date: 4/16/15
By: (Print)
KAM
(sign):
PG9e 3

SHEALY ENVIRONMENTAL SERVICES, INC.
Report of Analysis
Duke Energy
13339 Hagers Ferry Rd
Bldg 7405
Huntersville, NC 28078
Attention: Mary Ann Ogle
Project Name: AB GW Assessment Water
Project Number:J15040277
Lot Number:QD16018
Date Completed:04/24/2015
Grant Wilton
Project Manager
This report shall not be reproduced, except in its entirety, without the written approval of Shealy Environmental Services, Inc.
The following non -paginated documents are considered part of this report: Chain of Custody Record and Sample Receipt Checklist.
* QD1 601 8*
Shealy Environmental Services, Inc. Page: 1 of 12
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

SHEALY ENVIRONMENTAL SERVICES, INC.
SC DHEC No: 32010 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
Case Narrative
Duke Energy
Lot Number: QD16018
Project Name: AB GW Assessment Water
Project Number: J15040277
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample
receiving date is documented in the header information associated with each sample.
All results listed in this report relate only to the samples that are contained within this report.
Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the
Shealy Environmental Services, Inc. ("Shealy") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPS), and Shealy
policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below.
If you have any questions regarding this report please contact the Shealy Project Manager listed on the cover page
Shealy Environmental Services, Inc. Page: 2 of 12
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

SHEALY ENVIRONMENTAL SERVICES, INC.
Sample Summary
Duke Energy
Lot Number: QD16018
Project Name: AB GW Assessment Water
Project Number: J15040277
Sample Number
Sample ID
Matrix
Date Sampled
Date Received
001
2015010448
Aqueous
04/10/20151420
04/16/2015
002
2015010449
Aqueous
04/10/20151302
04/16/2015
003
2015010450
Aqueous
04/10/2015 0938
04/16/2015
004
2015010456
Aqueous
04/10/2015 0850
04/16/2015
(4 samples)
Shealy Environmental Services, Inc. Page: 3 of 12
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

SHEALY ENVIRONMENTAL SERVICES, INC.
Executive Summary
Duke Energy
Lot Number: QD16018
Project Name: AB GW Assessment Water
Project Number: J15040277
Sample Sample ID
Matrix Parameter Method
Result Q
Units
Page
001
2015010448
Aqueous Alkalinity SM 2320B-
110
mg/L
5
001
2015010448
Aqueous Bicarbonate Alkalinity SM 2320B-
110
mg/L
5
001
2015010448
Aqueous Methane RSK - 175
64
ug/L
6
002
2015010449
Aqueous Alkalinity SM 2320B-
120
mg/L
7
002
2015010449
Aqueous Bicarbonate Alkalinity SM 2320B-
120
mg/L
7
002
2015010449
Aqueous Methane RSK - 175
45
ug/L
8
003
2015010450
Aqueous Alkalinity SM 2320B-
640
mg/L
9
003
2015010450
Aqueous Bicarbonate Alkalinity SM 2320B-
640
mg/L
9
003
2015010450
Aqueous Methane RSK - 175
90
ug/L
10
(9 detections)
Shealy Environmental Services, Inc. Page: 4 of 12
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals
Client: Duke Energy Laboratory ID: QD16018-001
Description: 2015010448 Matrix: Aqueous
Date Sampled:04/10/2015 1420 Project Name: AB GW Assessment Water
Date Received:04/16/2015 Project Number: J15040277
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 2320B-2011
1 04/22/2015 1627
HMA 72555
1
(Bicarbonate ) SM 2320B-2011
1 04/22/2015 1815
HMA
1
(Carbonate Al) SM 2320B-2011
1 04/22/2015 1815
HMA
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
110
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
110
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 5 of 12
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane
Client: Duke Energy Laboratory ID: QD16018-001
Description: 2015010448 Matrix: Aqueous
Date Sampled:04/10/2015 1420 Project Name: AB GW Assessment Water
Date Received:04/16/2015 Project Number: J15040277
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 04/17/2015 2210 JJG 72833
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 64 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 6 of 12
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals
Client: Duke Energy Laboratory ID: QD16018-002
Description: 2015010449 Matrix: Aqueous
Date Sampled:04/10/2015 1302 Project Name: AB GW Assessment Water
Date Received:04/16/2015 Project Number: J15040277
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 2320B-2011
1 04/22/2015 1627
HMA 72555
1
(Bicarbonate ) SM 2320B-2011
1 04/22/2015 1827
HMA
1
(Carbonate Al) SM 2320B-2011
1 04/22/2015 1827
HMA
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
120
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
120
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 7 of 12
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane
Client: Duke Energy Laboratory ID: QD16018-002
Description: 2015010449 Matrix: Aqueous
Date Sampled:04/10/2015 1302 Project Name: AB GW Assessment Water
Date Received:04/16/2015 Project Number: J15040277
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 04/17/2015 2221 JJG 72833
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 45 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 8 of 12
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals
Client: Duke Energy Laboratory ID: QD16018-003
Description: 2015010450 Matrix: Aqueous
Date Sampled:04/10/2015 0938 Project Name: AB GW Assessment Water
Date Received:04/16/2015 Project Number: J15040277
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 2320B-2011
1 04/22/2015 1627
HMA 72555
1
(Bicarbonate ) SM 2320B-2011
1 04/22/2015 1832
HMA
1
(Carbonate Al) SM 2320B-2011
1 04/22/2015 1832
HMA
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
640
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
640
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 9 of 12
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane
Client: Duke Energy Laboratory ID: QD16018-003
Description: 2015010450 Matrix: Aqueous
Date Sampled:04/10/2015 0938 Project Name: AB GW Assessment Water
Date Received:04/16/2015 Project Number: J15040277
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 04/17/2015 2237 JJG 72833
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 90 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 10 of 12
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals
Client: Duke Energy Laboratory ID: QD16018-004
Description: 2015010456 Matrix: Aqueous
Date Sampled:04/10/2015 0850 Project Name: AB GW Assessment Water
Date Received:04/16/2015 Project Number: J15040277
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 2320B-2011
1 04/22/2015 1627
HMA 72555
1
(Bicarbonate ) SM 2320B-2011
1 04/22/2015 1839
HMA
1
(Carbonate Al) SM 2320B-2011
1 04/22/2015 1839
HMA
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
ND
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 11 of 12
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane
Client: Duke Energy Laboratory ID: QD16018-004
Description: 2015010456 Matrix: Aqueous
Date Sampled:04/10/2015 0850 Project Name: AB GW Assessment Water
Date Received:04/16/2015 Project Number: J15040277
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 04/17/2015 2030 JJG 72833
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 12 of 12
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

QC Summary
Shealy Environmental Services, Inc. QC Data for Lot Number: QD16018
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals - Ii
Sample ID: QQ72555-001 Matrix: Aqueous
Batch: 72555
Analytical Method: SM 2320B-2011
Parameter Result Q Dil PQL Units Analysis Date
Alkalinity ND 1 10 mg/L 04/22/20151627
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QD16018
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals - LCS
Sample ID: QQ72555-002 Matrix: Aqueous
Batch: 72555
Analytical Method: SM 2320B-2011
Spike
Amount Result % Rec
Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Alkalinity 100 110 1 109 90-110 04/22/20151627
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QD16018
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals - MS
Sample ID: QD16018-001MS Matrix: Aqueous
Batch: 72555
Analytical Method: SM 2320B-2011
Sample Spike
Amount Amount Result % Rec
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Alkalinity 110 100 260 N 1 155 70-130 04/22/20151627
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QD16018
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals - MSD
Sample ID: QD16018-001MID Matrix: Aqueous
Batch: 72555
Analytical Method: SM 2320B-2011
Sample Spike
Amount Amount Result % Rec % RPD
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date
Alkalinity 110 100 280 N 1 168 5.1 70-130 20 04/22/20151627
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QD16018
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane - MB
Sample ID: QQ72833-001 Matrix: Aqueous
Batch:72833
Analytical Method: RSK - 175
Parameter Result Q Dil PQL Units Analysis Date
Methane ND 1 10 ug/L 04/17/2015 2008
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QD16018
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane - LCS
Sample ID: QQ72833-002 Matrix: Aqueous
Batch:72833
Analytical Method: RSK - 175
Spike
Amount Result % Rec
Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date
Methane 150 150 1 99 70-130 04/17/20151748
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QD16018
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane - LCSD
Sample ID: QQ72833-003 Matrix: Aqueous
Batch:72833
Analytical Method: RSK - 175
Spike
Amount Result % Rec % RPD
Parameter (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date
Methane 150 140 1 95 4.3 70-130 30 04/17/20151738
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QD16018
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

SHEALY ENVIRONMENTAL SERVICES, INC.
w�lun14F.
P+dI�l3
i I{p1•
`
j
� Y
+ H*4
60
'�I�II.�i14�
■
;N�N
wall
Yi
JU
#
g
jl
�
� Bpi'S61
cu4
K
A
A
1
Z'
Q6
_
6 C
C
�
I
4
CJ
01
o
41
O
(j
SJ*1 LL
Tt
LU
IL
-
.�.�__..�:.�.�
I
�
'
7I$
r
$g
z
1 * R
Al
I
I
1 9 Ia 1 I I I II
I3 a I KPT
. .,� .
Hi 4h
x
1
"�..inb a mw- isawd.5
t
pwom m kupm[+
,,,,Wwiafo-la :VJT:PBdtl1'J9W61IRD
lil
F
Oi
LF
i
�ij®
C 3
2E r
%
Mal
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

SHEALY ENVIRONMENTAL SERVICES, INC.
Slimy Environmental Srr%*.�, Inc. Pme Id I
Mrm=i Number: F-AD016 Rq,lacet rate; 07e1544
Rive un Tumber. 16 RiThtdve De e: 1:1A17,14
Sample Receipt Checklist (SRC)
Client, , C'ac�ler Inspected b}�'dat:;+ry C +. i 'S,Lat 0: MIZZNve
Means crfreceilrt: ❑ SES1 ❑Client ❑ UPS PfFcdEx ❑ AirhomeFxp ❑ f? er
Ycs Ll
I Nr� LeT
I
I l _ Were custody GIs Msent on the cooler'
Yes ❑
I No El
I NA pr
12- If custody seals were prewnt, were they intacct and unbroken?
Cooler I] Original temperature upon mceipVDaived (Cormcted) temporature upon roccipt:
:44clhod: 2rTeimperature Blank ❑ Against Battles 1R Gun ID: IR Oun Con&, cca Factor 4vCk T '
Mclhod of coolant- 2' wet lire ❑ Blue Ice 0 Py Ice ZI None
Yes 14
tdar ❑
IdA
3. If =p mmnzo of atly cooler cxceeded 6.fl"C"., was beet Ni;�navrr inn-.4ificO
PM notified by SRC, phone, note (circle one), other: _.
(For coolem received via commercial courier, P34s are to be n,otifiM
immediatel . j
Yes
No ❑
NA ❑
4. I9 the comtr�ncial courier's kin -lip attnched to this JCinal?
l Ycs
No ❑
5, Were proptr eustody procedures relLmpiishedliereived followed'?
Yes
No ❑
INA ❑
5a Were samples relinquished by client to ccumemid councr`7
Y1�s
xo ❑
d, Were sale le IDs listed nn the C:?
Yes C&
Na ❑
7, V4'Eta< san7 le IDs listed on all sample containers?
Y+cs L61
No
R. war, collection dote & time listed on the C-QC?
Yen
Na ❑
9. Ww collection dl to & time listed on all saes lc cimtainers?
Yes
No ❑
10- Did all container label information ID date, time agree with the C ?
YES
No
1 1 . Were tests to be performed Kited oti the COC?
YES
No ❑
12. Did all satin pies arrive in the proper i owainerrs fur each I=?
Yes
No ❑
13. Did all crmtaincrs arrive in good condition unbrokita lids on, etc_)?
Ycs
No ❑
14. Was adtquate sani le volume available?
Yaps ❑
No �`
15- Were all 9arrlples rmrived within LA- the holding t"e or 48 bours, whiche-vcr
come, first?
Ycs
No
lb, W= ally samples containm massin .
Yen ❑ I
No
-
17. V4= there any emccss Sam lcs not listed nn C Cf?
YES I
No
NA ❑
18, Were bubbles present >" a -$tea+ !+"Or 6mrn in di-m-nerer) ill any VOA vlall;?
Yes ❑
No ❑
I4lA,B'
19. W= all mctslsl{] + Irnutrieslt samples recei�,td at a pH of <2?
Ycs
No
NA
20. Were all cyanide andlvr sulfade sale lea rec vcxi al a pH >12?
Yes ❑
No
NA
21, ilh = all applicable NH'3f['f�N1cyanideVphenool (<:0 2u EVL) san}p1e.� fret of
residual chlurine?
Yes ❑
No ❑
NA
22_ Were collectien Ignparatures documented on the C OC: for NC sam leO
Yes
NA
23_ Wm client remx wks�mquests (t,t_ requested dllutlow, I4 &N SD dc°sipations,
etc—) correctly trarlscribed born the C OC` into the rrinlinmt section in LIMS?
Ya s ❑ INo
Z
24, Was the quote number used taken from the oontainer 13M?
_
Sample Preservation (Must ba completed for ai y sample(s) incerrinutly pruserved or with headspace_)
ample(s) _ were received incorrectly pre -served and were ahjastc�ll
a0C,0 din l in sample receivingwith (H Sc]a1,H1wQ3JIC1 Na0H) using SR
Salrl le(s) were received witll bubblas ?6 rem in +diar ,
am le s were received with "TRC A.2 mg1L if #21 is No
SC DrUimg Waltz Pruj cut Sample(s) pH verified to be > 2 by Datce
Saul le(s) wcrc not received at a pH of <2 Ind wcrr adjusled acoord]tI y using SR#
SI1m le Labels apig i ed by: _ Verified b T7a[e:
Cow
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

CHAIN OF CUSTODY RECORD AND ANALYSIS_ REQUE_ _S_T F_OR_ _M -----
"---•-------- ---- —�' Duke Energy Analytical Laboratory -; '----•-•---•-•----._...........
_—._._._.-.-.q------t Lattorato Use Onl NC
Duke Energy I .0CadaMGOW IBuading7A31 Order �^ IMatrix GW_WW s.,w.o,gw,wcra, sC
Analytical Laboratory 13339 Hagars Ferry Rd "'�
Chain of Custody 8 Hunhrsvik, N.t. 2s9]e I i� gyn pap6Time SAMPLE PROGRAM
Sam le Lo ()0413)332a5 ` (.1 �0-6Ground Water �_ NPDES
P 9 ._.�._._._._._._.Faze-QW) 673deM ._._ _ _ _ _ _ ` v— -._._._._._._._._._._._._._._._._._ ODrinking Wand t13Tftmo,a AS GW Assessment water ,POoiM k°' RCRA Waceew_.._._.._.._.._.._.._._.._.._.._.._--_---------.._.._.._.
raea Element One —
3nt -- — 1990-876-6032 15 um) b Unfiltered
:Irl@SS Unit: rewas: �RNp CaMNar Ta vative Ice ke Ica Hx�oa
,e110, _ _ � � PO# 731367 a (mL) 2000 40 ml 300 us Soo 60o
ecT OFT PET
nalytical Lab
Page _1_of—t_ age41 of41
DISTRIBUTION
ORIGINAI. to LAB COPY to CLIENT SYNTERRA FDD
COC REV DATE 1/22/2015
naarea
HOPEItmPE
Dllccllj
PO# 1115153
H
Sample Description or ID
GPS Location
on
ME
unin
no
M1
M
Noon
SEMEN
ON
M101
M1
n
ON
M1
ON
M101
Z
IN
moM
m
Date/Time p, , 1Acc d ByDateTime
:
r
a,
Requested Turnaround
Total 18
i /f
Y
�nle
'pttp(T'mle eepted By: -
S
� a
94 Days
tirnllN
9 � Accepted v
�
a
°n, m
7 Days
• 48 Hr
- -- — SooleNLock Opened I3Y Daldlinte
5: 'a
o
u
ELEMENTS by ICP(TRM): As, Be, Cd, Co, Cr. Cu, Mo, Ni, Pb, Sb, Se, TI (1-4 V (LL)
E
•Other ---ASAP—
_MS
ELEMENTS ELEMENTS by ICP (TRM): Al. Ba, B, Fe. Mn, Sr, Zn ICP_Undigested Ca. Mg, K, No Hg by 245A
3
Add Cost Will Apply
Dissolved metals: all metals ICP, IMS.Hg
0
_