NC0003417_J15030356 Report_20150805

DUKE Analytical Laboratory
ENERGY
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone:[phone] Fax:[phone]
Order Summary Report
Order Number: J15030356
Project Name: AB GW ASSESSMENT WATER
Customer Name(s): Tim Hunsucker, Judd Mahan, Kathy Webb, John Toepfer
Customer Address: 1677 Old Smithfield Rd
Goldsboro NC 27530,
Lab Contact: Mary Ann Ogle Mary Ann Ogle Phone: [phone]
B „ �
Report Authorized By: ✓ems 2015.04.06 Date:
(Signature) 15:08:44-04'00'
Mary Ann Ogle
Program Comments:
Please contact the Program Manager (Mary Ann Ogle) with any questions regarding this report.
Data Flags & Calculations:
4/2/2015
Page 1 of 30
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Sample ID's & Descriptions:
Collection
Sample ID Plant/Station Date and Time
Collected By
Sample Description
2015007268
HF LEE PLANT
12-Mar-15 12:00 PM
ILLEGIBLE
AMW-9BC
2015007269
HF LEE PLANT
12-Mar-15 1:16 PM
ILLEGIBLE
Equipment Blank
2015007270
HF LEE PLANT
12-Mar-15 1:16 PM
ILLEGIBLE
Filter Blank
3 Total Samples
Page 2 of 30

Page 3 of 30
Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals Yes No
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits. ❑ Yes No
All laboratory QA/QC requirements are acceptable. (] Yes ❑ No
Report Sections Included:
L� Job Summary Report
❑ Sample Identification
n Technical Validation of Data Package
6 Analytical Laboratory Certificate of Analysis
❑ Analytical Laboratory QC Report
LVI Sub -contracted Laboratory Results
❑ Customer Specific Data Sheets, Reports, & Documentation
❑ Customer Database Entries
6 Chain of Custody
LVI Electronic Data Deliverable (EDD) Sent Separately
Reviewed By: DBA Account Date: 4/2/2015

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15030356
Site: AMW-913C
Collection Date: 12-Mar-15 12:00 PM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter
Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)
< 0.01
mg-N/L
0.01
INORGANIC IONS BY IC
Chloride
3.8
mg/L
0.1
Sulfate
2.2
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
0.008
mg/L
0.005
Barium (Ba)
0.207
mg/L
0.005
Boron (B)
0.064
mg/L
0.05
Iron (Fe)
1.94
mg/L
0.01
Manganese (Mn)
0.262
mg/L
0.005
Strontium (Sr)
0.092
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
40.6
mg/L
M4 0.1
Magnesium (Mg)
8.01
mg/L
0.005
Potassium (K)
1.61
mg/L
0.1
Sodium (Na)
6.06
mg/L
M4 0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.189
mg/L
0.005
Barium (Ba)
0.198
mg/L
0.005
Boron (B)
0.068
mg/L
0.05
Iron (Fe)
3.07
mg/L
0.01
Manganese (Mn)
0.253
mg/L
0.005
Strontium (Sr)
0.084
mg/L
0.005
Zinc (Zn)
0.006
mg/L
0.005
Sample #: 2015007268
Matrix: GW WW
Page 4 of 30
DF Method Analysis Date/Time Analyst
Vendor Method
V_SHEALY
1
EPA 353.2
03/16/2015 12:23
TLINN
1
EPA 300.0
03/18/2015 15:12
BGN9034
1
EPA 300.0
03/18/2015 15:12
BGN9034
1
EPA 245.1
03/17/2015 13:20
ACPAYNE
1
EPA 245.1
03/16/2015 15:42
ACPAYNE
1
EPA 200.7
03/18/2015 10:20
MHALL3
1
EPA 200.7
03/18/2015 10:20
MHALL3
1
EPA 200.7
03/18/2015 10:20
MHALL3
1
EPA 200.7
03/18/2015 10:20
MHALL3
1
EPA 200.7
03/18/2015 10:20
MHALL3
1
EPA 200.7
03/18/2015 10:20
MHALL3
1
EPA 200.7
03/18/2015 10:20
MHALL3
10
EPA 200.7
03/17/2015 14:18
MHALL3
1
EPA 200.7
03/17/2015 14:18
MHALL3
1
EPA 200.7
03/17/2015 14:18
MHALL3
1
EPA 200.7
03/17/2015 14:18
MHALL3
1
EPA 200.7
03/18/2015 11:07
MHH7131
1
EPA 200.7
03/18/2015 11:07
MHH7131
1
EPA 200.7
03/18/2015 11:07
MHH7131
1
EPA 200.7
03/18/2015 11:07
MHH7131
1
EPA 200.7
03/18/2015 11:07
MHH7131
1
EPA 200.7
03/18/2015 11:07
MHH7131
1
EPA 200.7
03/18/2015 11:07
MHH7131

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15030356
Site: AMW-913C
Collection Date: 12-Mar-15 12:00 PM
Analyte
Result
DISSOLVED METALS BY ICP-MS
Antimony (Sb)
< 1
Arsenic (As)
< 1
Beryllium (Be)
< 1
Cadmium (Cd)
< 1
Chromium (Cr)
< 1
Cobalt (Co)
< 1
Copper (Cu)
< 1
Lead (Pb)
< 1
Molybdenum (Mo)
1.51
Nickel (Ni)
< 1
Selenium (Se)
< 1
Thallium (TI) Low Level
< 0.2
Vanadium (V) Low Level
< 0.3
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
Arsenic (As)
< 1
Beryllium (Be)
< 1
Cadmium (Cd)
< 1
Chromium (Cr)
< 1
Cobalt (Co)
< 1
Copper (Cu)
1.15
Lead (Pb)
< 1
Molybdenum (Mo)
1.10
Nickel (Ni)
< 1
Selenium (Se)
< 1
Thallium (TI) Low Level
< 0.2
Vanadium (V) Low Level
0.553
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
730
Total Carbon
TOC
1.3
TOTAL SUSPENDED SOLIDS
TSS
18
Page 5 of 30
Sample #:
2015007268
Matrix:
GW WW
Units Qualifiers
RDL
DF
Method
Analysis Date/Time
Analyst
ug/L
1
1
EPA 200.8
03/31/2015 12:04
DJSULL1
ug/L
1
1
EPA 200.8
03/31/2015 12:04
DJSULL1
ug/L
1
1
EPA 200.8
03/31/2015 12:04
DJSULL1
ug/L
1
1
EPA 200.8
03/31/2015 12:04
DJSULL1
ug/L
1
1
EPA 200.8
03/31/2015 12:04
DJSULL1
ug/L
1
1
EPA 200.8
03/31/2015 12:04
DJSULL1
ug/L
1
1
EPA 200.8
03/31/2015 12:04
DJSULL1
ug/L
1
1
EPA 200.8
03/31/2015 12:04
DJSULL1
ug/L
1
1
EPA 200.8
03/31/2015 12:04
DJSULL1
ug/L
1
1
EPA 200.8
03/31/2015 12:04
DJSULL1
ug/L
1
1
EPA 200.8
03/31/2015 12:04
DJSULL1
ug/L
0.2
1
EPA 200.8
03/31/2015 12:04
DJSULL1
ug/L
0.3
1
EPA 200.8
03/31/2015 12:04
DJSULL1
ug/L
1
1
EPA 200.8
03/19/2015 14:20
JAHERMA
ug/L
1
1
EPA 200.8
03/19/2015 14:20
JAHERMA
ug/L
1
1
EPA 200.8
03/19/2015 14:20
JAHERMA
ug/L
1
1
EPA 200.8
03/19/2015 14:20
JAHERMA
ug/L
1
1
EPA 200.8
03/19/2015 14:20
JAHERMA
ug/L
1
1
EPA 200.8
03/19/2015 14:20
JAHERMA
ug/L
1
1
EPA 200.8
03/19/2015 14:20
JAHERMA
ug/L
1
1
EPA 200.8
03/19/2015 14:20
JAHERMA
ug/L
1
1
EPA 200.8
03/19/2015 14:20
JAHERMA
ug/L
1
1
EPA 200.8
03/19/2015 14:20
JAHERMA
ug/L
1
1
EPA 200.8
03/19/2015 14:20
JAHERMA
ug/L
0.2
1
EPA 200.8
03/19/2015 14:20
JAHERMA
ug/L
0.3
1
EPA 200.8
03/19/2015 14:20
JAHERMA
Vendor Method
V_SHEALY
Vendor Method
V_ELE1
mg/L
25
1
SM2540C
03/19/201510:33
AGIBBS5
mg/L
0.1
1
SM5310C/EPA9060A
03/23/201514:50
TJA7067
mg/L
5
1
SM2540D
03/16/201510:03
GHUTCHI

Certificate of Laboratory Analysis Page 6 of 30
This report shall not be reproduced, except in full.
Order # J15030356
Site: Equipment Blank
Collection Date: 12-Mar-15 1:16 PM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy
Labs)
Vendor Parameter
Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)
0.156
mg-N/L
0.01
INORGANIC IONS BY IC
Chloride
< 0.1
mg/L
0.1
Sulfate
< 0.1
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
UNDIGESTED METALS BY ICP
Calcium (Ca)
0.025
mg/L
M4 0.01
Magnesium (Mg)
< 0.005
mg/L
0.005
Potassium (K)
< 0.1
mg/L
0.1
Sodium (Na)
< 0.05
mg/L
M4 0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
< 0.005
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
< 0.005
mg/L
0.005
Strontium (Sr)
< 0.005
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
Sample #: 2015007269
Matrix: GW WW
DF Method Analysis Date/Time Analyst
Vendor Method
V_SHEALY
1 EPA 353.2
03/16/2015 12:27
TLINN
1 EPA 300.0
03/18/2015 12:31
BGN9034
1 EPA 300.0
03/18/2015 12:31
BGN9034
1 EPA 245.1
03/17/2015 14:12
ACPAYNE
1 EPA 200.7
03/17/2015 14:30
MHALL3
1 EPA 200.7
03/17/2015 14:30
MHALL3
1 EPA 200.7
03/17/2015 14:30
MHALL3
1 EPA 200.7
03/17/2015 14:30
MHALL3
1 EPA 200.7
03/18/2015 11:12
MHH7131
1 EPA 200.7
03/18/2015 11:12
MHH7131
1 EPA 200.7
03/18/2015 11:12
MHH7131
1 EPA 200.7
03/18/2015 11:12
MHH7131
1 EPA 200.7
03/18/2015 11:12
MHH7131
1 EPA 200.7
03/18/2015 11:12
MHH7131
1 EPA 200.7
03/18/2015 11:12
MHH7131
1 EPA 200.8
03/19/2015 14:36
JAHERMA
1 EPA 200.8
03/19/2015 14:36
JAHERMA
1 EPA 200.8
03/19/2015 14:36
JAHERMA
1 EPA 200.8
03/19/2015 14:36
JAHERMA
1 EPA 200.8
03/19/2015 14:36
JAHERMA
1 EPA 200.8
03/19/2015 14:36
JAHERMA
1 EPA 200.8
03/19/2015 14:36
JAHERMA
1 EPA 200.8
03/19/2015 14:36
JAHERMA
1 EPA 200.8
03/19/2015 14:36
JAHERMA
1 EPA 200.8
03/19/2015 14:36
JAHERMA
1 EPA 200.8
03/19/2015 14:36
JAHERMA
1 EPA 200.8
03/19/2015 14:36
JAHERMA
1 EPA 200.8
03/19/2015 14:36
JAHERMA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15030356
Site: Equipment Blank
Collection Date: 12-Mar-15 1:16 PM
Analyte
Result Units Qualifiers RDL DF
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
880 mg/L 25 1
Total Carbon
Page 7 of 30
Sample #: 2015007269
Matrix: GW WW
Method Analysis Date/Time Analyst
Vendor Method V_SHEALY
Vendor Method
V_ELE1
SM2540C 03/19/201510:33 AGIBBS5
TOC 0.259 mg/L 0.1 1 SM5310C/EPA9060A 03/23/201514:50 TJA7067
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L 5 1 SM2540D 03/16/2015 10:03 GHUTCHI

Certificate of Laboratory Analysis Page 8 of 30
This report shall not be reproduced, except in full.
Order # J15030356
Site: Filter Blank
Collection Date: 12-Mar-15 1:16 PM
Analyte
Result
Units
Qualifiers RDL
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (Al)
< 0.005
mg/L
0.005
Barium (Ba)
< 0.005
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
< 0.005
mg/L
0.005
Strontium (Sr)
< 0.005
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
DISSOLVED METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
Sample #: 2015007270
Matrix: GW WW
DF
Method
Analysis Date/Time
Analyst
1
EPA 245.1
03/16/2015 15:44
ACPAYNE
1
EPA 200.7
03/18/2015 10:51
MHALL3
1
EPA 200.7
03/18/2015 10:51
MHALL3
1
EPA 200.7
03/18/2015 10:51
MHALL3
1
EPA 200.7
03/18/2015 10:51
MHALL3
1
EPA 200.7
03/18/2015 10:51
MHALL3
1
EPA 200.7
03/18/2015 10:51
MHALL3
1
EPA 200.7
03/18/2015 10:51
MHALL3
1
EPA 200.8
03/31/2015 11:18
DJSULL1
1
EPA 200.8
03/31/2015 11:18
DJSULL1
1
EPA 200.8
03/31/2015 11:18
DJSULL1
1
EPA 200.8
03/31/2015 11:18
DJSULL1
1
EPA 200.8
03/31/2015 11:18
DJSULL1
1
EPA 200.8
03/31/2015 11:18
DJSULL1
1
EPA 200.8
03/31/2015 11:18
DJSULL1
1
EPA 200.8
03/31/2015 11:18
DJSULL1
1
EPA 200.8
03/31/2015 11:18
DJSULL1
1
EPA 200.8
03/31/2015 11:18
DJSULL1
1
EPA 200.8
03/31/2015 11:18
DJSULL1
1
EPA 200.8
03/31/2015 11:18
DJSULL1
1
EPA 200.8
03/31/2015 11:18
DJSULL1
Qualifiers:
M4 The spike recovery value was unusable since the analyte concentration in the sample was disproportionate
to the spike level. The associated Laboratory Control Spike recovery was acceptable.

Page 9 of 30
�;- ', " P
'i4w
Eement One Inc.
6319-D Carolina Beach Rd.
Wilmington, NC 28412
Phone: [phone]
Fax: [phone]
[e-mail]
REPORT OF ANALYSES
Duke Energy March 25, 2015
Laboratory Services Client Project Name AB GW Assessment Water
13339 Hagers Ferry Road Bld. MG03A Client Project Number J15030356
Huntersville, NC 28078 PO Number
Sample Matrix GW WW
Date Analyzed 03/18/2015
Delivered by FedEx
eOne ID Duke Energy ID
24284-1 AMW-96C
24284-2 Equipment Blank
Sample Type Grab
Method SM 4500 S2- D
Parameter Result Unit Dil
Sulfide < 0.1 mg/L 1
Date Received
03/17/2015
Time Received
1105
Received by
LLB
DL Date
Time
Sampled
Sampled
0.1 03/12/15 1200
Sulfide < 0.1 mg/L 1 0.1 03/12/15 1316
Ken Smith, Laboratory Director
24284 Duke Report Packet Compiled by
NC Certifications: DW 37788 and DWQ DENR 604

Page 10 of 30
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elernentOne SAMPLE SUBMISSION FORM
TAT 7 BD
Hold Time Expiration 03.19.16 @ 1200 PM
Client: Duke Energy
LIMS No J15030356
Project ID AB GW ssessment Water ----�
Lab Ibge'Ai84
Analysis Due Date 03.18.15
Report Due Date 03.26.15
Date Rec: 03.17.15
Time Rec: 1105
Rec By LLB
H >9 Yes No
<_
Tem 6°C Yes No
Ref. Method:
SM4500 S2 D
If No, Record
If No, Record
Samole Identification & Collection Information
Lab ID
I Client ID
Collection Date
Collection Time
Analysis Requested
1
AMW-9BC
03.12.15
1200 PM
Sulfide
2
Equipment Blank
03.12.15
1316 PM
Sulfide
NOTE for Sulfide
The MS/MSD spike should approximate 2 to 3 times the sample concentration. If no sulfide detected
at 100 pg/L spike the sample to render the final spike concentration at - 500 pg/L
Lab Communications
SS Page 1 4,0,.
Prep By / Date I- tSS by Labeled By / Date 3 • I � . f �
3/17/2015 3:41:43 PM ID Verification By /Date 1 Gam- 3 l8 t S

Page 12 of 30
METHOD:
SM 4500 S2- D
ELEMENT ONE
ELEMENT ASSAY:
Sulfide
Spectrophotometer
Wave Length 664
UNITS OF ANSWER
ug/mL
DETECTION LIMIT u
2.500
CLIENT:
Duke
SPK LEVEL u
5
Lab ID#
24284 / 24286
Na2S•9H2OLot#
0000040721
MAX ALIQUOT
25.00
Date:
03/18/15
STANDARD conc(ppm)
X
Time Analysis Begun
16:40
10
Time Analysis Ended
17:48
Analyst:
KAM
STD ABSORPTION
Y
X
Y
0 700
ug STD
SOLUTION
STD
ABS
0 e00
ow
osoo
0.00
1.00
2.50
5.00
7.50
10.00
0.000
0.064
0.175
0.329
0.482
0.646
0400
2
0300
1 0,-
0100
I)6
j
�o°o.w
00„
Zoo 4.00 e.00 eo0 loco 12.0
x
Sloe 0.064248352 Correlation 0.999727523
SAMPLE
I.D.
SAMP
ABS
ug PER
ALIQUOT
ALI in mL
ANALYZED
PREP
VOL in mL
ALI in mL
TAKEN
RESULTS
u /mL
LESS THAN
% SPK REC
SPIKE
LEVEL
LRB
0.00
0.0000
10
10
10
<
0
LRB SPK
0.331
5.0947
10
10
10
0.509
102%
5.0
24284-1
0.019
0.1801
10
10
10
< 01
24284-1 s k
0.338
5.2049
10
10
10
0.520
104%
5.0
24284-2
0.025
0.2746
10
10
10
< 0.1
24284-2 s k
0.371
5.7247
10
10
10
0.572
114%
5.0
24284-1
0.000
0.0000
10
10
2
<
24284-1 s k
0.322
4.9529
10
10
2
2.476
99%
5.0
24284-2
0.001
-0.1034
10
10
2
<
24284-2 s k
0.340
5.2364
10
10
2
2.618
105%
5.0
24284-2
0.001
-0.1034
10
10
1
<
24284-2 s k
0.343
5.2837
10
10
1
5.284
106%
5.0
24284-2
0.002
-0.0876
10
10
0.5
<
24284-2 s k
0.339
5.2207
10
10
0.5
10.441
104%
5.0
24286
0.001
-0.1034
10
10
10
<
24286 s k
0.332
5.1104
10
10
10
0.511
102%
5.0
Blank
0.000
0.0000
10
10
10
<
QC
0.331
5.0947
10
10
0.5
10.189
102%
5.0
Submitted for QA/QC- Date: 03/18/15
By: (Print)
KAM
(sign):

Page 13 of 30
METHOD:
SM 4500 S2- D
ELEMENT ONE
ELEMENT ASSAY:
Sulfide
Spectrophotometer
Wave Length 664
UNITS OF ANSWER
ug/mL
DETECTION LIMIT u
1.000
CLIENT:
Duke
SPK LEVEL u
5
Lab ID#
24284 / 24286 MAX ALI UOT 25.00
03/18/15 Na2S•9H2OLot# STANDARD conc(ppm) X
16:40 0000040721 10
17:48
KAM STD ABSORPTION Y
Y
o iao
Date:
Time Analysis Begun
Time Analysis Ended
Analyst:
X
ug STD
SOLUTION
STD o.eoo
- -
- -
_--_--
em
ABS oboe
0.00
2.50
5.0
7.50
10.00
0.000 04.
0.175
0 200
.1.--
ve
0329
o°°.o0
0.482 2W 400 e.00 e.00 Woo ,zoo
0.646 X
Sloe 0064248352
Correlation 0.999727523
SAMPLE
I.D.
SAMP
ABS
ug PER
ALIQUOT
ALI in mL
ANALYZED
PREP
VOL in mL
ALI in mL
TAKEN
RESULTS
ug/mL
LESS THAN
% SPK REC
SPIKE
LEVEL
LRB
0.00
0.0000
10
10
10
<
0
LRB SPK
0.331
5.0947
10
10
10
0.509
102%
5.0
24284-1
0.019
0.1801
10
10
10
< 0.1
24284-1 s k
0.338
5.2049
10
10
10
0.520
104%
5.0
24284-2
0.025
0.2746
10
10
10
< 0.1 ,
24284-2 s k
0.371
5.7247
10
10
10
0.572
114%
5.0
24284-1
0.000
0.0000
10
10
2
<
24284-1 s k
0.322
4.9529
10
10
2
2.476
99%
5.0
24284-2
0.001
-0.1034
10
10
2
<
24284-2 s k
0.340
5.2364
10
10
2
2.618
105%
5.0
24284-2
0.001
-0.1034
10
10
1
<
24284-2 s k
0.343
5.2837
10
10
1
5.284
106%
5.0
24284-2
0.002
-0.0876
10
10
0.5
<
24284-2 s k
0.339
5.2207
10
10
0.5
10.441
104%
5.0
24286
0.001
-0.1034
10
10
10
< 0.1
24286 s k
0.332
5.1104
10
10
10
0.511
102%
5.0
<
#VALUE!
<
#VALUE!
<
#VALUE!
Blank
0.000
0.0000
10
1
1
QC
0.331
5.0947
10
1
1
0.509
102%1
5.0
Submitted for Q QC- Date: 03/18/15
By: (Print)
KAM
(sign):

SHEALY ENVIRONMENTAL SERVICES, INC.
Report of Analysis
Duke Energy
13339 Hagers Ferry Rd
Bldg 7405
Huntersville, NC 28078
Attention: Mary Ann Ogle
Project Name: AB GW Assessment
Project Number:J15030356
Lot Number:QC17001
Date Completed:03/26/2015
Grant Wilton
Project Manager
This report shall not be reproduced, except in its entirety, without the written approval of Shealy Environmental Services, Inc.
The following non -paginated documents are considered part of this report: Chain of Custody Record and Sample Receipt Checklist.
*QC17001*
Shealy Environmental Services, Inc. Page: 1 of 8
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

SHEALY ENVIRONMENTAL SERVICES, INC.
SC DHEC No: 32010 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
Case Narrative
Duke Energy
Lot Number: QC17001
Project Name: AB GW Assessment
Project Number: J15030356
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample
receiving date is documented in the header information associated with each sample.
All results listed in this report relate only to the samples that are contained within this report.
Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the
Shealy Environmental Services, Inc. ("Shealy") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPS), and Shealy
policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below.
If you have any questions regarding this report please contact the Shealy Project Manager listed on the cover page
Shealy Environmental Services, Inc. Page: 2 of 8
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SHEALY ENVIRONMENTAL SERVICES, INC.
Sample Summary
Duke Energy
Lot Number: QC17001
Project Name: AB GW Assessment
Project Number: J15030356
Sample Number Sample ID Matrix Date Sampled Date Received
001 2015007268 Aqueous 03/12/20151200 03/16/2015
002 2015007269 Aqueous 03/12/20151316 03/16/2015
(2 samples)
Shealy Environmental Services, Inc. Page: 3 of 8
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SHEALY ENVIRONMENTAL SERVICES, INC.
Executive Summary
Duke Energy
Lot Number: QC17001
Project Name: AB GW Assessment
Project Number: J15030356
Sample Sample ID
Matrix Parameter Method Result Q Units Page
001 2015007268
Aqueous Alkalinity SM 2320B- 120 mg/L 5
001 2015007268
Aqueous Bicarbonate Alkalinity SM 2320B- 120 mg/L 5
(2 detections)
Shealy Environmental Services, Inc. Page: 4 of 8
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals
Client: Duke Energy Laboratory ID: QC17001-001
Description: 2015007268 Matrix: Aqueous
Date Sampled:03/12/2015 1200 Project Name: AB GW Assessment
Date Received:03/16/2015 Project Number: J15030356
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 2320B-2011
1 03/23/2015 2052
BWS 70759
1
(Bicarbonate ) SM 2320B-2011
1 03/23/2015 2052
TAF 03/23/2015 2052
1
(Carbonate Al) SM 2320B-2011
1 03/23/2015 2052
TAF 03/23/2015 2052
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
120
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
120
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 5 of 8
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Methane
Client: Duke Energy Laboratory ID: QC17001-001
Description: 2015007268 Matrix: Aqueous
Date Sampled:03/12/2015 1200 Project Name: AB GW Assessment
Date Received:03/16/2015 Project Number: J15030356
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 03/17/2015 1540 DCS 70209
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 6 of 8
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Inorganic non-metals
Client: Duke Energy Laboratory ID: QC17001-002
Description: 2015007269 Matrix: Aqueous
Date Sampled:03/12/2015 1316 Project Name: AB GW Assessment
Date Received:03/16/2015 Project Number: J15030356
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 2320B-2011
1 03/23/2015 2109
BWS 70759
1
(Bicarbonate ) SM 2320B-2011
1 03/23/2015 2109
TAF 03/23/2015 2109
1
(Carbonate Al) SM 2320B-2011
1 03/23/2015 2109
TAF 03/23/2015 2109
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
ND
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 7 of 8
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Methane
Client: Duke Energy Laboratory ID: QC17001-002
Description: 2015007269 Matrix: Aqueous
Date Sampled:03/12/2015 1316 Project Name: AB GW Assessment
Date Received:03/16/2015 Project Number: J15030356
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 03/17/2015 1821 DCS 70209
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 8 of 8
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QC Summary
Shealy Environmental Services, Inc. QC Data for Lot Number: QC17001
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals - Ii
Sample ID: QQ70759-001 Matrix: Aqueous
Batch: 70759
Analytical Method: SM 2320B-2011
Parameter Result Q Dil PQL Units Analysis Date
Alkalinity ND 1 10 mg/L 03/23/20151959
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QC17001
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals - LCS
Sample ID: QQ70759-002 Matrix: Aqueous
Batch: 70759
Analytical Method: SM 2320B-2011
Spike
Amount Result % Rec
Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Alkalinity 100 95 1 95 90-110 03/23/2015 2005
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QC17001
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane - MB
Sample ID: QQ70209-001 Matrix: Aqueous
Batch: 70209
Analytical Method: RSK - 175
Parameter Result Q Dil PQL Units Analysis Date
Methane ND 1 10 ug/L 03/17/20151307
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QC17001
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane - LCS
Sample ID: QQ70209-002 Matrix: Aqueous
Batch: 70209
Analytical Method: RSK - 175
Spike
Amount Result % Rec
Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date
Methane 50 38 1 76 70-130 03/17/20151238
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QC17001
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane - LCSD
Sample ID: QQ70209-003 Matrix: Aqueous
Batch: 70209
Analytical Method: RSK - 175
Spike
Amount Result % Rec % RPD
Parameter (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date
Methane 50 39 1 76 0.78 70-130 30 03/17/20151249
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QC17001
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

SHEALY ENVIRONMENTAL SERVICES, INC.
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Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

SHEALY ENVIRONMENTAL SERVICES, INC.
51re�1} Envi ffinrnaual ssmv-,us, Inc_ Nge I of 1
DacumcnGNurober F-AD4I6 Riplacm mare`117115.114
Revislon Number 16 Effactive fUE2: 11.10?e 14
Sample Receipt Checklist (SRC 1
Client: l r c E o er c> A Fouler Inspected by)date: 4C1! q -7- j 5 Lot #; O i'10Ol
Means ofreoript' ❑ SESI ❑ Client ❑ UP ❑ FWEx ❑ Ai1'bnrnc f.xp . C}ther
F1 INokfl1. lvcre custody,Seals rCSLR1 On t11e o_ 1�_ `? -
-Yes
Yes Ll
I No Lj I NA Z 11 it-otigtody seals were Msent, wm r11e inset and unbroken?
r Cox ler TDIOriginal ternpemiure upon receiprlDerived (corrected) temperatum upon receipt:
Method: ❑ Temperature Ukmk ZAZainst i#ortlea IR Arun ID: 94 TR hurl Corr€rtion Factor; Q °C
Methw of coolant- el Icy >llue ke Ll Dry Iee ❑ None �
Yes El
No El
NA
_
3. If tlmperat re of any cooler cxc dod 6.0°O, was Pros lm Manager notliied?
Plvf notified by SRC, phoule, rlotc (circle ono), odtcr. _
(For cocilem reed 4ed via commcrciat courier. FMs ere to be notified
immediately.)
Yes
No ❑
NA 0
.I4_ is the catnmercial courier's packin,2Shp attached to this firm?
'ca
No ❑
5. Were propu mstody proccclures (rc ' uished icocivcd) fulluwod?
Ye<s ❑
o Z
NA
5a Were sHmples relinquished Opu clielit to commercial couri,elI
Y
o ❑
6. Were sample 113s listed the (X)C?
Yes
No ❑
?. crc sample IN lisled on all Barn ple containers?
"ye-s
o
S. Was collection date & time .listed -on the CDC?
Yes
o ❑
9. Was 1llogdon date &. timc listed on all sam lc r cmlauacrs?
Yes
o ❑
10. Did all container label information II}, date time) agree with the 000?
yw
No 0
11. Wem tests to be pciforined listed on the MC9
Yes KNQ
❑
NQ❑
12. Did all samples arrive is the Mper container for each tcs['.x
YM 0
1�-17id all containers arrive in Socd oandition (unbroken, lids or. etc.)'
yeg
No ❑
14_ Was ade uale sainple volume available?
Yes ❑
N.LS_
WEm all samplesreceived. wirls'in %x the bolding time or 49 hours, xvhi::hc� vr
comes first?
16_ Were any samples ecmiainm 1ni$sing?
Ym ❑
No
Yes ❑
No
17. Were there any excess sam Ics > tat listed an i)QQ"
Yes
No
-MA. ❑
16_ Were bubhlcs cnt � _sire„ !G „or 6inm in diame.:er in any 'VCIA vials?
Yes ❑
No ❑
MA
19- Wcrc all nx4aLV0&G4MMrLu1rierj1 samples rrocivcd ii t as pH of ="2?
Yes ❑
No ❑
NA C;r
20 Wifeall cyanide author sulfide sun tub rued cl at a PH >12'?
' r'r;s El
No D
NA RK
21 _ Wm all applicable, NH3T1'KNr'cyaAi6e,'phen01 (<O.2rogjl.) samples fiw of
residual clllarine`
Y(.% ❑
No
NA
21 Were collection tern ratures documeaW c the O C for NC sarn 1c3F
Y:s ❑
No []
23 Were rJient remarleshcqucsts {i.. requested dilutions, M 'ivlSD desig�ti�ns
etc__) corral!y transcribed frnm the COC intu thec0mment smtiali in LIMS?
Yin [:]I
No EY
24. Was the c uole ourni-per used taken from the contsnier label?
s8lmple F'leservatten (Mt1%t he cmnpluLiNI for any sgtnple(s) inGun=#ly prescr iod ur with healdspooe.)
SaMPlc(s) were rcccived iiworrectly proved and were adjustocl
in santi le receiving with :S0,,I3NO3,H aCl . w i ng SR#
_aocordkigly
s unple s were received will'« bubbles. 6 mm in diameter.
Sa I s were rracei wA with TRC >O.2 UkL if #21 is NO)
C Drinking Water PrajaA Samples) pH vcritied to be �- 2 by Date,-
sample(s) were not received at a pH of <2 amld-wtrene adjusted aaoordingly usin SR#
Sample labels applied bye r4jAQ Verified by; Thu �
coriml nls:
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

c
E
c
CHAINO_F_C_ US_T_O__D_Y__ RECORD _ AND ANALYSIS_REQU_E__S_T_ FORM--
_M
Duke Energy Duke Energy Analytical Laboratory i i Anal ical Laborato Use Onlyi Page 30 of 30
Analytical Laboratory Mail CodeMG03A2 (euilding7405) !Order# Matrix GW WW SamplecOnginatingFrom NC_ Page _1_of_1_
7 ` ry 13339 Hagers Ferry Rd ! 1S0 3 (� 3� sc_ DISTRIBUTION
Chain of Custody 8 Huntersville, N. C. 28078 i {Logged By Date &Time _ _ i ORIGINAL to LAB, COPY to CLIENT
Sample Log [phone] �` SAMPLE PROGRAM
Fax. [phone]
P 9 1._)_-_-_-_-_._-_-_-_- J I �--c_ 3 I I' I I J.S Ground Water NPDES
Project Name
AB GW Assessment water
Phone No:
Client
Fax No:
980-875-5032
Business Unit:
Pro<eca:
Reap. Center To:
Project to:
Activity to:
Mail Code:
MG03A3
Waterbody:
Station:
i ve'd
lement 1
a
Dnnking Water_ UST_ I COC REV DATE 1/22/2015.
RCRA Waste _ i
I
- - �oolerTeme(P,.......................................
- --.._.._.._.._-.;
PO 1142133 Filtration (0.45 um)
Unfiltered
filtered
i Preservative
Ice
Ice
Ice
ICet
H2SO4
Ice
°r"'OXI
rcxu.a
SH EALY tolume (mL)
2000
40 ml
300
125
500
500
500
250
PET
glass
PET
PET
PET
I PET
I
HDPE
HDPE
nn 'I 'I A -)nOn Rainer Type
Sample Description or ID ...t..orr: o oFrPr vt.rr
non -shaded areas.
Collection Information
GPS Location
Date Time Signature
N
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F
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U
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X
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1
1
1
9
D
0
0
0
0
0
0
0
0
0
0
0
0
Filter Blank
0
0
1
TOTAL
A
8
Reli '�(shed By
Date/Time
Accepted By:
Da a/Time
Y
/����"�"/A
`
�(�
u
Requested Turnaround
Relinquishe/d� By Date/Time
Aftepted By: DatelTime
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m �
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14 Days
Relinquished B Date/Time
Accepted By: Date/Time
c
7 Days
c E
m
o
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Sealed/Lock Opened By Date/TIme
CL
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" 48 Hr
Co ents
ELEME S y _ S (TRM): As, Be, Cd, Co, Cr, Cu, Mo, Ni, Pb, Sb, Se, TI (LL), V (LL)
ELEMENTS by ICP
(TRM): Al, Ba, B, Fe, Mn, Sr, Zn
ICP_Undigested
Ca, Mg, K, Na Hg by 245.1
o
Other _ASAP
Dissolved metals :
all metals ICP, IMS,Hg
0
Add. Cost Will Apply
U
Total A,