NC0003417_J15030205report_20150805

DUKE Analytical Laboratory
ENERGY
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone:[phone] Fax:[phone]
Order Summary Report
Order Number: J15030205
Project Name: AB GW ASSESSMENT WATER
Customer Name(s): Tim Hunsucker, Judd Mahan, Kathy Webb, John Toepfer
Customer Address: 1677 Old Smithfield Rd
Goldsboro NC 27530,
Lab Contact: Mary Ann Ogle Phone: [phone]
Mary Ann Ogle
Report Authorized By: i "(Jb 2015.04.01 15:08:22 Date:
(Signature)-04'00'
Mary Ann Ogle
Program Comments:
Please contact the Program Manager (Mary Ann Ogle) with any questions regarding this report.
Data Flags & Calculations:
3/27/2015
Page 1 of 25
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Sample ID's & Descriptions:
Page 2 of 25
Sample ID Plant/Station
2015006539 HF LEE PLANT
2015006542 HF LEE PLANT
2 Total Samples
Collection
Date and Time Collected By
05-Mar-15 12:01 PM
05-Mar-15 12:04 PM
ILLEGIBLE
ILLEGIBLE
Sample Description
AMW-13BC
Filter Blank

Page 3 of 25
Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals Yes No
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits. ❑ Yes No
All laboratory QA/QC requirements are acceptable. (] Yes ❑ No
Report Sections Included:
L� Job Summary Report
❑ Sample Identification
n Technical Validation of Data Package
6 Analytical Laboratory Certificate of Analysis
❑ Analytical Laboratory QC Report
LVI Sub -contracted Laboratory Results
❑ Customer Specific Data Sheets, Reports, & Documentation
❑ Customer Database Entries
6 Chain of Custody
LVI Electronic Data Deliverable (EDD) Sent Separately
Reviewed By: DBA Account Date: 3/27/2015

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15030205
Site: AMW-13BC
Collection Date: 05-Mar-15 12:01 PM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter
Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)
< 0.01
mg-N/L
0.01
INORGANIC IONS BY IC
Chloride
24
mg/L
1
Sulfate
16
mg/L
1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
0.015
mg/L
0.005
Barium (Ba)
0.153
mg/L
0.005
Boron (B)
0.069
mg/L
0.05
Iron (Fe)
0.770
mg/L
0.01
Manganese (Mn)
0.036
mg/L
0.005
Strontium (Sr)
0.151
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
46.3
mg/L
M4 0.1
Magnesium (Mg)
5.18
mg/L
0.005
Potassium (K)
2.48
mg/L
0.1
Sodium (Na)
22.4
mg/L
0.5
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.372
mg/L
0.005
Barium (Ba)
0.163
mg/L
0.005
Boron (B)
0.070
mg/L
0.05
Iron (Fe)
3.62
mg/L
0.01
Manganese (Mn)
0.043
mg/L
0.005
Strontium (Sr)
0.151
mg/L
0.005
Zinc (Zn)
0.008
mg/L
0.005
Sample #: 2015006539
Matrix: GW WW
Page 4 of 25
DF Method Analysis Date/Time Analyst
Vendor Method
V_SHEALY
1
EPA 353.2
03/09/2015 12:08
TLINN
10
EPA 300.0
03/10/2015 17:24
BGN9034
10
EPA 300.0
03/10/2015 17:24
BGN9034
1
EPA 245.1
03/11/2015 13:05
TLINN
1
EPA 245.1
03/16/2015 15:09
ACPAYNE
1
EPA 200.7
03/11/2015 10:09
MHH7131
1
EPA 200.7
03/11/2015 10:09
MHH7131
1
EPA 200.7
03/11/2015 10:09
MHH7131
1
EPA 200.7
03/11/2015 10:09
MHH7131
1
EPA 200.7
03/11/2015 10:09
MHH7131
1
EPA 200.7
03/11/2015 10:09
MHH7131
1
EPA 200.7
03/11/2015 10:09
MHH7131
10
EPA 200.7
03/17/2015 12:46
MHALL3
1
EPA 200.7
03/17/2015 12:46
MHALL3
1
EPA 200.7
03/17/2015 12:46
MHALL3
10
EPA 200.7
03/17/2015 12:46
MHALL3
1
EPA 200.7
03/12/2015 12:49
MHH7131
1
EPA 200.7
03/12/2015 12:49
MHH7131
1
EPA 200.7
03/12/2015 12:49
MHH7131
1
EPA 200.7
03/12/2015 12:49
MHH7131
1
EPA 200.7
03/12/2015 12:49
MHH7131
1
EPA 200.7
03/12/2015 12:49
MHH7131
1
EPA 200.7
03/12/2015 12:49
MHH7131

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15030205
Site: AMW-13BC
Collection Date: 05-Mar-15 12:01 PM
Analyte
Result
DISSOLVED METALS BY ICP-MS
Antimony (Sb)
< 1
Arsenic (As)
< 1
Beryllium (Be)
< 1
Cadmium (Cd)
< 1
Chromium (Cr)
< 1
Cobalt (Co)
< 1
Copper (Cu)
< 1
Lead (Pb)
< 1
Molybdenum (Mo)
2.85
Nickel (Ni)
< 1
Selenium (Se)
< 1
Thallium (TI) Low Level
< 0.2
Vanadium (V) Low Level
< 0.3
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
Arsenic (As)
< 1
Beryllium (Be)
< 1
Cadmium (Cd)
< 1
Chromium (Cr)
< 1
Cobalt (Co)
< 1
Copper (Cu)
1.63
Lead (Pb)
< 1
Molybdenum (Mo)
2.28
Nickel (Ni)
2.21
Selenium (Se)
< 1
Thallium (TI) Low Level
< 0.2
Vanadium (V) Low Level
0.962
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
200
Total Carbon
TOC
2.4
TOTAL SUSPENDED SOLIDS
TSS
33
Page 5 of 25
Sample #:
2015006539
Matrix:
GW WW
Units Qualifiers
RDL
DF
Method
Analysis Date/Time
Analyst
ug/L
1
1
EPA 200.8
03/24/2015 13:09
DJSULL1
ug/L
1
1
EPA 200.8
03/24/2015 13:09
DJSULL1
ug/L
1
1
EPA 200.8
03/24/2015 13:09
DJSULL1
ug/L
1
1
EPA 200.8
03/24/2015 13:09
DJSULL1
ug/L
1
1
EPA 200.8
03/24/2015 13:09
DJSULL1
ug/L
1
1
EPA 200.8
03/24/2015 13:09
DJSULL1
ug/L
1
1
EPA 200.8
03/24/2015 13:09
DJSULL1
ug/L
1
1
EPA 200.8
03/24/2015 13:09
DJSULL1
ug/L
1
1
EPA 200.8
03/24/2015 13:09
DJSULL1
ug/L
1
1
EPA 200.8
03/24/2015 13:09
DJSULL1
ug/L
1
1
EPA 200.8
03/24/2015 13:09
DJSULL1
ug/L
0.2
1
EPA 200.8
03/24/2015 13:09
DJSULL1
ug/L
0.3
1
EPA 200.8
03/24/2015 13:09
DJSULL1
ug/L
1
1
EPA 200.8
03/19/2015 13:28
JAHERMA
ug/L
1
1
EPA 200.8
03/19/2015 13:28
JAHERMA
ug/L
1
1
EPA 200.8
03/19/2015 13:28
JAHERMA
ug/L
1
1
EPA 200.8
03/19/2015 13:28
JAHERMA
ug/L
1
1
EPA 200.8
03/19/2015 13:28
JAHERMA
ug/L
1
1
EPA 200.8
03/19/2015 13:28
JAHERMA
ug/L
1
1
EPA 200.8
03/19/2015 13:28
JAHERMA
ug/L
1
1
EPA 200.8
03/19/2015 13:28
JAHERMA
ug/L
1
1
EPA 200.8
03/19/2015 13:28
JAHERMA
ug/L
1
1
EPA 200.8
03/19/2015 13:28
JAHERMA
ug/L
1
1
EPA 200.8
03/19/2015 13:28
JAHERMA
ug/L
0.2
1
EPA 200.8
03/19/2015 13:28
JAHERMA
ug/L
0.3
1
EPA 200.8
03/19/2015 13:28
JAHERMA
Vendor Method
V_SHEALY
Vendor Method
V_ELE1
mg/L
25
1
SM2540C
03/12/201511:21
GHUTCHI
mg/L
0.1
1
SM5310C/EPA9060A
03/11/201516:40
TJA7067
mg/L
5
1
SM2540D
03/10/201510:45
GHUTCHI

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15030205
Site: Filter Blank
Collection Date: 05-Mar-15 12:04 PM
Analyte
Result
Units
Qualifiers RDL
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (Al)
0.009
mg/L
0.005
Barium (Ba)
< 0.005
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.016
mg/L
0.01
Manganese (Mn)
< 0.005
mg/L
0.005
Strontium (Sr)
< 0.005
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
DISSOLVED METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
Sample #: 2015006542
Matrix: GW WW
Page 6 of 25
DF
Method
Analysis Date/Time
Analyst
1
EPA 245.1
03/16/2015 15:11
ACPAYNE
1
EPA 200.7
03/11/2015 09:44
MHH7131
1
EPA 200.7
03/11/2015 09:44
MHH7131
1
EPA 200.7
03/11/2015 09:44
MHH7131
1
EPA 200.7
03/11/2015 09:44
MHH7131
1
EPA 200.7
03/11/2015 09:44
MHH7131
1
EPA 200.7
03/11/2015 09:44
MHH7131
1
EPA 200.7
03/11/2015 09:44
MHH7131
1
EPA 200.8
03/24/2015 13:15
DJSULL1
1
EPA 200.8
03/24/2015 13:15
DJSULL1
1
EPA 200.8
03/24/2015 13:15
DJSULL1
1
EPA 200.8
03/24/2015 13:15
DJSULL1
1
EPA 200.8
03/24/2015 13:15
DJSULL1
1
EPA 200.8
03/24/2015 13:15
DJSULL1
1
EPA 200.8
03/24/2015 13:15
DJSULL1
1
EPA 200.8
03/24/2015 13:15
DJSULL1
1
EPA 200.8
03/24/2015 13:15
DJSULL1
1
EPA 200.8
03/24/2015 13:15
DJSULL1
1
EPA 200.8
03/24/2015 13:15
DJSULL1
1
EPA 200.8
03/24/2015 13:15
DJSULL1
1
EPA 200.8
03/24/2015 13:15
DJSULL1
Qualifiers:
M4 The spike recovery value was unusable since the analyte concentration in the sample was disproportionate
to the spike level. The associated Laboratory Control Spike recovery was acceptable.

SHEALY ENVIRONMENTAL SERVICES, INC.
Report of Analysis
Duke Energy
13339 Hagers Ferry Rd
Bldg 7405
Huntersville, NC 28078
Attention: Mary Ann Ogle
Project Name: AB GW Assessment - HF Lee
Project Number:J15030205
Lot Number:QC09046
Date Completed:03/23/2015
Grant Wilton
Project Manager
This report shall not be reproduced, except in its entirety, without the written approval of Shealy Environmental Services, Inc.
The following non -paginated documents are considered part of this report: Chain of Custody Record and Sample Receipt Checklist.
* QC09046*
Shealy Environmental Services, Inc. Page: 1 of 6
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

SHEALY ENVIRONMENTAL SERVICES, INC.
SC DHEC No: 32010 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
Case Narrative
Duke Energy
Lot Number: QC09046
Project Name: AB GW Assessment - HF Lee
Project Number: J15030205
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample
receiving date is documented in the header information associated with each sample.
All results listed in this report relate only to the samples that are contained within this report.
Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the
Shealy Environmental Services, Inc. ("Shealy") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPS), and Shealy
policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below.
If you have any questions regarding this report please contact the Shealy Project Manager listed on the cover page
Shealy Environmental Services, Inc. Page: 2 of 6
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

SHEALY ENVIRONMENTAL SERVICES, INC.
Sample Summary
Duke Energy
Lot Number: QC09046
Project Name: AB GW Assessment - HF Lee
Project Number: J15030205
Sample Number Sample ID Matrix Date Sampled Date Received
001 2015006539 Aqueous 03/05/20151201 03/09/2015
(1 sample)
Shealy Environmental Services, Inc. Page: 3 of 6
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SHEALY ENVIRONMENTAL SERVICES, INC.
Executive Summary
Duke Energy
Lot Number: QC09046
Project Name: AB GW Assessment - HF Lee
Project Number: J15030205
Sample Sample ID Matrix Parameter Method Result Q Units Page
001 2015006539 Aqueous Alkalinity SM 2320B- 110 mg/L 5
001 2015006539 Aqueous Bicarbonate Alkalinity SM 2320B- 110 mg/L 5
(2 detections)
Shealy Environmental Services, Inc. Page: 4 of 6
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Inorganic non-metals
Client: Duke Energy Laboratory ID: QC09046-001
Description: 2015006539 Matrix: Aqueous
Date Sampled:03/05/2015 1201 Project Name: AB GW Assessment - HF Lee
Date Received:03/09/2015 Project Number: J15030205
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 2320B-2011
1 03/13/2015 1307
BWS 69742
1
(Bicarbonate ) SM 2320B-2011
1 03/13/2015 1307
BWS 03/13/2015 1307
1
(Carbonate Al) SM 2320B-2011
1 03/13/2015 1307
BWS 03/13/2015 1307
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
110
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
110
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Methane
Client: Duke Energy Laboratory ID: QC09046-001
Description: 2015006539 Matrix: Aqueous
Date Sampled:03/05/2015 1201 Project Name: AB GW Assessment - HF Lee
Date Received:03/09/2015 Project Number: J15030205
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 03/17/2015 1117 DCS 70204
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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QC Summary
Shealy Environmental Services, Inc. QC Data for Lot Number: QC09046
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals - Ii
Sample ID: QQ69742-001 Matrix: Aqueous
Batch: 69742
Analytical Method: SM 2320B-2011
Parameter Result Q Dil PQL Units Analysis Date
Alkalinity ND 1 10 mg/L 03/13/20151229
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QC09046
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals - LCS
Sample ID: QQ69742-002 Matrix: Aqueous
Batch: 69742
Analytical Method: SM 2320B-2011
Spike
Amount Result % Rec
Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Alkalinity 100 93 1 93 90-110 03/13/20151235
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QC09046
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane - MB
Sample ID: QQ70204-001 Matrix: Aqueous
Batch:70204
Analytical Method: RSK - 175
Parameter Result Q Dil PQL Units Analysis Date
Methane ND 1 10 ug/L 03/17/2015 0858
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QC09046
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane - LCS
Sample ID: QQ70204-002 Matrix: Aqueous
Batch:70204
Analytical Method: RSK - 175
Spike
Amount Result % Rec
Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date
Methane 50 41 1 81 70-130 03/17/2015 0826
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QC09046
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane - LCSD
Sample ID: QQ70204-003 Matrix: Aqueous
Batch:70204
Analytical Method: RSK - 175
Spike
Amount Result % Rec % RPD
Parameter (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date
Methane 50 42 1 82 1.8 70-130 30 03/17/2015 0840
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QC09046
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

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106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

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Shealy Enviamrrh tal Servicim Inc. PW I ul I.
Dnell t Number F AD-016 keprt r;; D4Lc; U7115114
Reoglan Number. 16 Fiird,er D:11v%• I1iR'7f14
Sample Receipt Checklist (SRC)
Client. C:DCo-Jer Inspected byldate:Vyvwq- ,ate Fi Ut
v1eaiv of rewipc ❑ SESI ❑ Client ❑ l_a'PS ❑ FedEx ❑ Airborne Exp Other
Yes Ll
INDEZI1.
Were custad ' Keay[ prewt an the c;onler?
Yes LJ
I No
J
I NA V
1 ?. If custody se:els were present, wvere they intact and unbroken?
Cooler IU Original temperature upon receipt/Dvriwed (corrected) temperaiturc upon romipt:
\ °c I I cc I 1 QC I I 1PC
Method: aTernperattt7jBlank ❑ Against Bottles 1R Gun ID: 04 1R Gun Correction hear; 0 � Clloc
Method of coolant: LJWellce ❑ Sloe Ice ❑ 17ry k e None
ti'ce El
1d1p El`
NAPM
Ef
3, If temperature of any cooler exceeded 6_0"C, was Project Manager notified?
notified by SRC', photme, note (circle one): other.
(For coolers received via commercial courier_ I NIs are to be nokified
ilinmediatel .)
Yts ❑
No
NACX
4, Is the: commercial courier's packiril attikch, J to this form?
Yes
No
5. Were proper custody .Gd=s relm. lshedlreeetwxdd f *,eJ?
Yss ❑
NQ ❑
NA
5a'i'G'ere sqTples relinggished by client to commercial cottrieO
4;4 q . NO ❑
6, Were sample Ws listed on the Cr]C?
Ycs '
Ntr ❑
7. Were Rant le TDs listed cni all sale le containers`?
Yes
No ❑
$. Was colle Ilion date. & tirtie listed on th.c COC?
Yes
IN,) ❑
9. Was enllection date &. time listed on all sam, le caritaiaers?
Yes UILNo
10, Did all container label information UD, d€w, time with the C.00?
Yes
No ❑
11. 1J me 1to be Ccrf4wmed listed on the Ct ?
Yes
+
12. Did all samples arrive in Me proper containers for twit test?
Yes
No ❑
1 13. Laid all containers arrive in good cundition (unbrokeq. lids on, etc.)?
Yes VL
No-7
14. Was adequate sample volurm available?
Yes ❑
No
15. Were all sam&-s received within 14 the IataisliElL, time or 4.9 ltnurs, %vhichcver
comes firSI7
16. Were aay samples qontaiiners missing
ye"s ❑
No
Yes ❑
NQ
17. Were there any excess SaInples not listed an COO
Ym ❑
Nu F
NA
18. Were bubbles prestnt >" -size'irk 'or 6MM in diameter} in any VOA viah?
Yrs ❑
No F]
NA19.
Wm. all trio#s15,1Oa4tGiliFM/nutaiBnt xam ]es receiled at a pHof <27
Yes ❑
No ❑
NA
20, Were all cyanide and/or sulfide.. samplos received at a . f 1 > IT?
Yes ❑
No ❑
NA Zo21.
Were all applicablu NH31TKNfcpnide./pheMl (<fl_'?m&(L) samples free of
residual chlorine'?
Yes ❑
No ❑
NA
22. W'cre collmitan tcrli creatures documntW on the C C for NC saris Im?
Yes ❑
No ❑
NA
23, Were client rernarks/requests (i.e, requested dilutions, MSIMSD drsignabns,
etc...) correctly transcribed from thee C OC inter the comment scciion in HMS?
Yes ❑
No
24. Was the uotc number used taken from the oDntairwr label?
Satmrple=. Preservatlon (Must be von-pleted fur any minple(s) incctrectly preserved or with hcadspace.)
sfimple.(s) were received incorrectly preserved and were adju.;ted
wxoFdingly in sample rccciNzn, with H2,'4ta,},HNU.1-1Cl,Na0H asin SR #
Sartt le(s) were, received with bubbles ram in dia=tcr,
S Ic 3 were received ,nrith IRC .2 rpif #21 is NO
SC Drinking Water project Sarni)]c(s) pH verified to be> 2 by Dale:
Sa ic(a) wc.rc m t received at a pA of <2 and wem adjusted acccurdiri usiri SRk-
SamplelabwsappliEdbyz >.' 'Verified by: l te;
Commtents:
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Page 21 of 25
Duke Energy
Laboratory Services
13339 Hagers Ferry Road Bid. MG03A
Huntersville, NC 28078
Sample Matrix
GW WW
Date Analyzed
03/12/2015
Delivered by
Fed Ex
eOne ID Duke Energy ID
24220-1 AMW-1313C
Element One laic,
63119-0 Carolina Beach Rd.
Wilmington, VAC 28412
Phone: [phone]
Fax: [phone]
el lab a@el lab.com
REPORT OF ANALYSES
March 23, 2015
Client Project Name AB GW Assessment Water
Client Project Number J15030205
PO Number
Sample Type
Grab
Date Received
03/10/2015
Method
SM 4500 S2- D
Time Received
1120
Received by
LLB
Parameter
Result Unit Dil
DL Date
Time
Sampled
Sampled
Sulfide
< 0.1 mg/L 1
0.1 03/05/15
1201
This is the first revision to this report; it was necessary to analyze an additional curve point to meet the requested detection limit
of < 0.1 mg/L.
Ken Smith, Laboratory Director
24220 Duke Report Packet Rev 3.23.15 Compiled byDa-j
NC Certifications: DW 37788 and DWQ DENR 604

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elernentOne SAMPLE SUBMISSION FORM
TAT 7 BD
Hold Time Expiration 03.12.15 @ 1201 PM
Client: Duke Energy
LIMS No J15030205
Project ID AB GW Assessment Water
Lab I&ge
2�422 0
Analysis Due Date
03.11.15
Report Due Date
03.19.15
Date Rec:
03.10.15
Time Rec:
1120
Rec By
LLB
H >9 a No
Tem <_ 6°C es No
Ref. Method:
SM4500 S2 D
If No, Record
If No, Record d
Samnle Identification & Collection Information
Lab ID
I Client ID
Collection Date
Collection Time
Analysis Requested
1
AMW-13BC
03.05.15
1201 PM
Sulfide
NOTE for Sulfide The MS/MSD spike should approximate 2 to 3 times the sample concentration. If no sulfide detected
at 100 pg/L spike the sample to render the final spike concentration at - 500 pg/L
Lab Communications
.............
SS Page 1 0 Prep By / Date � 2?A (A{ )
SS by Labeled By / Date 3 . , f
3/10/2015 3:28:49 PM ID Verification By /Date

Page 24 of 25
Sulfide 1

C_ H_ A_IN OF CUSTODY RECORD AN_D A_N_A_L_Y_S_IS_R_ E_ Q_U_EST FORM
- ------ -_ - 1 Duke Enernv Analvtical Lahnratnry --_.-.-----------------------------------------------------------------------------------------
--.---.--_._-.----.-.- Analvtical Laboratory Use Only -.-.-.-.-.- -.-.-.-'-.-.-._.- -.-- i Pape 25 of 25
i Llunw Clow" yy ! Page _1_ of _1
Mail Code 9 Hag (Building 7405) Order # _ atrix GW_WW sam orlg-t From NC l 9 _1-
Analytical Laboratory 3339HagersFerryRd ! ! 1 pes sc DISTRIBUTION
TI5 �3c. �j
i l —
Chain of Custody & Huntersville, N. C. 28079
i l iLogged By Date & Time _ i ORIGINAL to LAB, COPY to CLIENT
i Sample Log (706) e75-5245 l i z �,J SAMPLE PROGRAM l
! I
Fa_x_: j7o4) 875-503_8 _ _ _ _ ✓ Ground Water_ NPDES
J
,Project
_ c1
Name AB GW Assessment water Phone No ;Vendor I �`J Drinking Water UST_
• COC REV DATE 1/22I2015
RCRAWaste_ i
l�Ilempnt 1 Cooler TemQJC�.__-._._
Client Fax No:
980-875-5032 ilteredPO1142133 Filtration 0.45
um
( )
UnfilteredBusiness
Unit' Process: Rasp. Center To: Ice/.✓.• Preservative Ice Ice Ice
Ice
H2304 „ s,u„su
Project ID: y If Mafl
lume (mL) 2000 40 ml 300 125 500 500 500 1 250
MG03A3
Waterbody: station: SHEALY 41ner T e yp PET glass PET PET PET PET HDPE HOPE
PO 1142089
Sample Description or ID Cn d a, m Co
K —
nun-snaaea areas. ondui v Z T c_ IDE — ar c3
F j O 'c N O N u
du.1
..-----._.._.--.._..- _ ,,d, o
Collection Information n «- N U� m m a y Won d 1O
GIPS Location o to 4 n 0" '> 0
A a o E
Date Time Si nature o t7 H U f- Z¢ m L)> to
1li154'
�3 $�
3 S j5
j;%t7i
X
1
2
1
1
t
1
1
1
9
0
0
i
0
I
0
o
0
o
0
i
0
0
--'
o
i
o
5y Z
Filter Blank
S j
t�
�,(o—�
t
1
i Relitiguish"ed By; 4
o
o
Date/Time: J,
Received By:
1
Date/Time:
TOTAL
t
z
t
t
1
e
i ;
Customer to sign & date beloW
Relinquished By DatelTime
Accepted Date/Time �.,
�,F}� �
a;
Requested Turnaround
Total 11
> / 5-
S-1, S �✓ s7
y
14 Days
Relinquished By D e/Time
Accepted By: DatelTime
d=
ne
Accepted DatelTime
Relinq ed By Date/Time
y:
\
7 Days
\ ' -
E
o
Seal/Locked By DatelTime
Sealed/Lock Opened By DatelTime
5
E N
48 Hr
9
N
Comments
ELEMENTS by ICP MIS (TRM): As, Be, Cd, Co, Cr, Cu, Mo, Ni, Pb, Sb, Se, TI (LL), V (LL)
o
`Other
ELEMENTS by ICP (TRM): At, Ba, B, Fe, Mn, Sr, Zn ICP Undigested Ca, Mg, K, Na Hg by 245.1
_ASAP
Add. Cost Will Apply
Dissolved metals : all metals ICP, IMS,Hg
c�