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Home My WebLink AboutNC0003417_J15030096report_20150805DUKE Analytical Laboratory ENERGY 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone:980-875-5245 Fax:980-875-4349 Order Summary Report Order Number: J15030096 Project Name: AB GW ASSESSMENT WATER Customer Name(s): Tim Hunsucker, Judd Mahan, Kathy Webb, John Toepfer Customer Address: 1677 Old Smithfield Rd Goldsboro NC 27530, Lab Contact: Mary Ann Ogle Phone: 980-875-5274 Mary Ann Ogle Report Authorized By: �Gy 2015.03.24 15:25:21 Date: (Signature) GGG��CCC 1 04'00' Mary Ann Ogle Program Comments: Please contact the Program Manager (Mary Ann Ogle) with any questions regarding this report. Data Flags & Calculations: 3/24/2015 Page 1 of 62 Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Sample ID's & Descriptions: Collection Sample ID Plant/Station Date and Time Collected By Sample Description 2015006059 HF LEE PLANT 02-Mar-15 12:56 PM ILLEGIBLE AMW-11BC 2015006060 HF LEE PLANT 02-Mar-15 2:15 PM ILLEGIBLE AMW-11S 2015006061 HF LEE PLANT 02-Mar-15 4:33 PM ILLEGIBLE AMW-12S 2015006062 HF LEE PLANT 02-Mar-15 5:15 PM ILLEGIBLE Equipment Blank 2015006063 HF LEE PLANT 02-Mar-15 5:15 PM ILLEGIBLE Filter Blank 2015006070 HF LEE PLANT 03-Mar-15 9:05 AM ILLEGIBLE AMW-12BC 2015006071 HF LEE PLANT 03-Mar-15 11:48 AM ILLEGIBLE AMW-13S 2015006072 HF LEE PLANT 03-Mar-15 12:42 PM ILLEGIBLE Equipment Blank 2015006073 HF LEE PLANT 03-Mar-15 12:42 PM ILLEGIBLE Filter Blank 9 Total Samples Page 2 of 62 Page 3 of 62 Technical Validation Review Checklist: COC and .pdf report are in agreement with sample totals Yes No and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. ❑ Yes No All laboratory QA/QC requirements are acceptable. (] Yes ❑ No Report Sections Included: L� Job Summary Report ❑ Sample Identification n Technical Validation of Data Package 6 Analytical Laboratory Certificate of Analysis ❑ Analytical Laboratory QC Report LVI Sub -contracted Laboratory Results ❑ Customer Specific Data Sheets, Reports, & Documentation ❑ Customer Database Entries 6 Chain of Custody LVI Electronic Data Deliverable (EDD) Sent Separately Reviewed By: DBA Account Date: 3/24/2015 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030096 Site: AMW-11 BC Collection Date: 02-Mar-15 12:56 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.013 mg-N/L 0.01 INORGANIC IONS BY IC Chloride 4.4 mg/L 0.1 Sulfate 1.8 mg/L 0.1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) 0.014 mg/L 0.005 Barium (Ba) 0.006 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 6.08 mg/L 0.01 Manganese (Mn) 1.19 mg/L 0.005 Strontium (Sr) 0.028 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 12.3 mg/L 0.01 Magnesium (Mg) 3.38 mg/L 0.005 Potassium (K) 0.691 mg/L 0.1 Sodium (Na) 6.19 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.079 mg/L 0.005 Barium (Ba) 0.006 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 6.30 mg/L 0.01 Manganese (Mn) 1.22 mg/L 0.005 Strontium (Sr) 0.029 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 Sample #: 2015006059 Matrix: GW WW Page 4 of 62 DF Method Analysis Date/Time Analyst Vendor Method V_SHEALY 1 EPA 353.2 03/09/2015 11:05 TLINN 1 EPA 300.0 03/05/2015 09:42 BGN9034 1 EPA 300.0 03/05/2015 09:42 BGN9034 1 EPA 245.1 03/10/2015 10:47 ACPAYNE 1 EPA 245.1 03/12/2015 14:28 ACPAYNE 1 EPA 200.7 03/05/2015 10:58 MHH7131 1 EPA 200.7 03/05/2015 10:58 MHH7131 1 EPA 200.7 03/05/2015 10:58 MHH7131 1 EPA 200.7 03/05/2015 10:58 MHH7131 1 EPA 200.7 03/05/2015 10:58 MHH7131 1 EPA 200.7 03/05/2015 10:58 MHH7131 1 EPA 200.7 03/05/2015 10:58 MHH7131 1 EPA 200.7 03/13/2015 12:15 MHALL3 1 EPA 200.7 03/13/2015 12:15 MHALL3 1 EPA 200.7 03/13/2015 12:15 MHALL3 1 EPA 200.7 03/13/2015 12:15 MHALL3 1 EPA 200.7 03/12/2015 14:33 MHH7131 1 EPA 200.7 03/12/2015 14:33 MHH7131 1 EPA 200.7 03/12/2015 14:33 MHH7131 1 EPA 200.7 03/12/2015 14:33 MHH7131 1 EPA 200.7 03/12/2015 14:33 MHH7131 1 EPA 200.7 03/12/2015 14:33 MHH7131 1 EPA 200.7 03/12/2015 14:33 MHH7131 Certificate of Laboratory Analysis Page 5 of 62 This report shall not be reproduced, except in full. Order # J15030096 Site: AMW-11 BC Collection Date: 02-Mar-15 12:56 PM Analyte Result DISSOLVED METALS BY ICP-MS Antimony (Sb) < 1 Arsenic (As) < 1 Beryllium (Be) < 1 Cadmium (Cd) < 1 Chromium (Cr) < 1 Cobalt (Co) 2.79 Copper (Cu) < 1 Lead (Pb) < 1 Molybdenum (Mo) 1.25 Nickel (Ni) < 1 Selenium (Se) < 1 Thallium (TI) Low Level < 0.2 Vanadium (V) Low Level < 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 Arsenic (As) < 1 Beryllium (Be) < 1 Cadmium (Cd) < 1 Chromium (Cr) < 1 Cobalt (Co) 2.75 Copper (Cu) <1 Lead (Pb) < 1 Molybdenum (Mo) 1.36 Nickel (Ni) 1.26 Selenium (Se) < 1 Thallium (TI) Low Level < 0.2 Vanadium (V) Low Level < 0.3 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4) Complete SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS < 250 Total Carbon TOC 0.760 TOTAL SUSPENDED SOLIDS TSS < 5 Sample #: 2015006059 Matrix: GW WW Units Qualifiers RDL DF Method Analysis Date/Time Analyst ug/L 1 1 EPA 200.8 03/17/2015 14:04 DJSULL1 ug/L 1 1 EPA 200.8 03/17/2015 14:04 DJSULL1 ug/L 1 1 EPA 200.8 03/17/2015 14:04 DJSULL1 ug/L 1 1 EPA 200.8 03/17/2015 14:04 DJSULL1 ug/L 1 1 EPA 200.8 03/17/2015 14:04 DJSULL1 ug/L 1 1 EPA 200.8 03/17/2015 14:04 DJSULL1 ug/L 1 1 EPA 200.8 03/17/2015 14:04 DJSULL1 ug/L 1 1 EPA 200.8 03/17/2015 14:04 DJSULL1 ug/L 1 1 EPA 200.8 03/17/2015 14:04 DJSULL1 ug/L 1 1 EPA 200.8 03/17/2015 14:04 DJSULL1 ug/L 1 1 EPA 200.8 03/17/2015 14:04 DJSULL1 ug/L 0.2 1 EPA 200.8 03/17/2015 14:04 DJSULL1 ug/L 0.3 1 EPA 200.8 03/17/2015 14:04 DJSULL1 ug/L 1 1 EPA 200.8 03/12/2015 13:11 DJSULL1 ug/L 1 1 EPA 200.8 03/12/2015 13:11 DJSULL1 ug/L 1 1 EPA 200.8 03/12/2015 13:11 DJSULL1 ug/L 1 1 EPA 200.8 03/12/2015 13:11 DJSULL1 ug/L 1 1 EPA 200.8 03/12/2015 13:11 DJSULL1 ug/L 1 1 EPA 200.8 03/12/2015 13:11 DJSULL1 ug/L 1 1 EPA 200.8 03/12/2015 13:11 DJSULL1 ug/L 1 1 EPA 200.8 03/12/2015 13:11 DJSULL1 ug/L 1 1 EPA 200.8 03/12/2015 13:11 DJSULL1 ug/L 1 1 EPA 200.8 03/12/2015 13:11 DJSULL1 ug/L 1 1 EPA 200.8 03/12/2015 13:11 DJSULL1 ug/L 0.2 1 EPA 200.8 03/12/2015 13:11 DJSULL1 ug/L 0.3 1 EPA 200.8 03/12/2015 13:11 DJSULL1 Vendor Method V_SHEALY Vendor Method V_ELE1 mg/L 250 1 SM2540C 03/09/201512:04 GHUTCHI mg/L 0.1 1 SM5310C/EPA9060A 03/05/201516:05 TJA7067 mg/L 5 1 SM2540D 03/06/201511:10 GHUTCHI Certificate of Laboratory Analysis Page 6 of 62 This report shall not be reproduced, except in full. Order # J15030096 Site: AMW-11 S Collection Date: 02-Mar-15 2:15 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.151 mg-N/L 0.01 INORGANIC IONS BY IC Chloride 11 mg/L 1 Sulfate 5.7 mg/L 0.1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) 0.013 mg/L 0.005 Barium (Ba) 0.015 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 0.031 mg/L 0.01 Manganese (Mn) 0.454 mg/L 0.005 Strontium (Sr) 0.032 mg/L 0.005 Zinc (Zn) 0.006 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 4.16 mg/L 0.01 Magnesium (Mg) 1.64 mg/L 0.005 Potassium (K) 1.32 mg/L 0.1 Sodium (Na) 6.30 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.051 mg/L 0.005 Barium (Ba) 0.016 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 0.252 mg/L 0.01 Manganese (Mn) 0.476 mg/L 0.005 Strontium (Sr) 0.032 mg/L 0.005 Zinc (Zn) 0.006 mg/L 0.005 Sample #: 2015006060 Matrix: GW WW DF Method Analysis Date/Time Analyst Vendor Method V_SHEALY 1 EPA 353.2 03/09/2015 11:06 TLINN 10 EPA 300.0 03/05/2015 09:58 BGN9034 1 EPA 300.0 03/05/2015 09:58 BGN9034 1 EPA 245.1 03/10/2015 10:49 ACPAYNE 1 EPA 245.1 03/12/2015 14:30 ACPAYNE 1 EPA 200.7 03/05/2015 11:02 MHH7131 1 EPA 200.7 03/05/2015 11:02 MHH7131 1 EPA 200.7 03/05/2015 11:02 MHH7131 1 EPA 200.7 03/05/2015 11:02 MHH7131 1 EPA 200.7 03/05/2015 11:02 MHH7131 1 EPA 200.7 03/05/2015 11:02 MHH7131 1 EPA 200.7 03/05/2015 11:02 MHH7131 1 EPA 200.7 03/13/2015 12:19 MHALL3 1 EPA 200.7 03/13/2015 12:19 MHALL3 1 EPA 200.7 03/13/2015 12:19 MHALL3 1 EPA 200.7 03/13/2015 12:19 MHALL3 1 EPA 200.7 03/12/2015 14:37 MHH7131 1 EPA 200.7 03/12/2015 14:37 MHH7131 1 EPA 200.7 03/12/2015 14:37 MHH7131 1 EPA 200.7 03/12/2015 14:37 MHH7131 1 EPA 200.7 03/12/2015 14:37 MHH7131 1 EPA 200.7 03/12/2015 14:37 MHH7131 1 EPA 200.7 03/12/2015 14:37 MHH7131 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030096 Site: AMW-11 S Collection Date: 02-Mar-15 2:15 PM Analyte Result DISSOLVED METALS BY ICP-MS Antimony (Sb) < 1 Arsenic (As) < 1 Beryllium (Be) < 1 Cadmium (Cd) < 1 Chromium (Cr) < 1 Cobalt (Co) 12.1 Copper (Cu) < 1 Lead (Pb) < 1 Molybdenum (Mo) < 1 Nickel (Ni) 4.39 Selenium (Se) < 1 Thallium (TI) Low Level < 0.2 Vanadium (V) Low Level < 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 Arsenic (As) < 1 Beryllium (Be) < 1 Cadmium (Cd) < 1 Chromium (Cr) < 1 Cobalt (Co) 12.5 Copper (Cu) <1 Lead (Pb) < 1 Molybdenum (Mo) < 1 Nickel (Ni) 4.53 Selenium (Se) < 1 Thallium (TI) Low Level < 0.2 Vanadium (V) Low Level < 0.3 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4) Complete SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 55 Total Carbon TOC 0.754 TOTAL SUSPENDED SOLIDS TSS 5.0 Page 7 of 62 Sample #: 2015006060 Matrix: GW WW Units Qualifiers RDL DF Method Analysis Date/Time Analyst ug/L 1 1 EPA 200.8 03/17/2015 14:09 DJSULL1 ug/L 1 1 EPA 200.8 03/17/2015 14:09 DJSULL1 ug/L 1 1 EPA 200.8 03/17/2015 14:09 DJSULL1 ug/L 1 1 EPA 200.8 03/17/2015 14:09 DJSULL1 ug/L 1 1 EPA 200.8 03/17/2015 14:09 DJSULL1 ug/L 1 1 EPA 200.8 03/17/2015 14:09 DJSULL1 ug/L 1 1 EPA 200.8 03/17/2015 14:09 DJSULL1 ug/L 1 1 EPA 200.8 03/17/2015 14:09 DJSULL1 ug/L 1 1 EPA 200.8 03/17/2015 14:09 DJSULL1 ug/L 1 1 EPA 200.8 03/17/2015 14:09 DJSULL1 ug/L 1 1 EPA 200.8 03/17/2015 14:09 DJSULL1 ug/L 0.2 1 EPA 200.8 03/17/2015 14:09 DJSULL1 ug/L 0.3 1 EPA 200.8 03/17/2015 14:09 DJSULL1 ug/L 1 1 EPA 200.8 03/12/2015 13:16 DJSULL1 ug/L 1 1 EPA 200.8 03/12/2015 13:16 DJSULL1 ug/L 1 1 EPA 200.8 03/12/2015 13:16 DJSULL1 ug/L 1 1 EPA 200.8 03/12/2015 13:16 DJSULL1 ug/L 1 1 EPA 200.8 03/12/2015 13:16 DJSULL1 ug/L 1 1 EPA 200.8 03/12/2015 13:16 DJSULL1 ug/L 1 1 EPA 200.8 03/12/2015 13:16 DJSULL1 ug/L 1 1 EPA 200.8 03/12/2015 13:16 DJSULL1 ug/L 1 1 EPA 200.8 03/12/2015 13:16 DJSULL1 ug/L 1 1 EPA 200.8 03/12/2015 13:16 DJSULL1 ug/L 1 1 EPA 200.8 03/12/2015 13:16 DJSULL1 ug/L 0.2 1 EPA 200.8 03/12/2015 13:16 DJSULL1 ug/L 0.3 1 EPA 200.8 03/12/2015 13:16 DJSULL1 Vendor Method V_SHEALY Vendor Method V_ELE1 mg/L 25 1 SM2540C 03/09/201512:04 GHUTCHI mg/L 0.1 1 SM5310C/EPA9060A 03/05/201516:05 TJA7067 mg/L 5 1 SM2540D 03/06/201511:10 GHUTCHI Certificate of Laboratory Analysis Page 8 of 62 This report shall not be reproduced, except in full. Order # J15030096 Site: AMW-12S Collection Date: 02-Mar-15 4:33 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 4.5 mg-N/L 0.04 INORGANIC IONS BY IC Chloride 13 mg/L 1 Sulfate 3.2 mg/L 0.1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) 0.207 mg/L 0.005 Barium (Ba) 0.174 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 0.188 mg/L 0.01 Manganese (Mn) 0.065 mg/L 0.005 Strontium (Sr) 0.059 mg/L 0.005 Zinc (Zn) 0.019 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 4.22 mg/L 0.01 Magnesium (Mg) 3.21 mg/L 0.005 Potassium (K) 2.56 mg/L 0.1 Sodium (Na) 6.60 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.272 mg/L 0.005 Barium (Ba) 0.177 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 0.333 mg/L 0.01 Manganese (Mn) 0.067 mg/L 0.005 Strontium (Sr) 0.059 mg/L 0.005 Zinc (Zn) 0.020 mg/L 0.005 Sample #: 2015006061 Matrix: GW WW DF Method Analysis Date/Time Analyst Vendor Method V_SHEALY 4 EPA 353.2 03/09/2015 11:13 TLINN 10 EPA 300.0 03/05/2015 10:15 BGN9034 1 EPA 300.0 03/05/2015 10:15 BGN9034 1 EPA 245.1 03/10/2015 10:52 ACPAYNE 1 EPA 245.1 03/12/2015 14:33 ACPAYNE 1 EPA 200.7 03/05/2015 11:06 MHH7131 1 EPA 200.7 03/05/2015 11:06 MHH7131 1 EPA 200.7 03/05/2015 11:06 MHH7131 1 EPA 200.7 03/05/2015 11:06 MHH7131 1 EPA 200.7 03/05/2015 11:06 MHH7131 1 EPA 200.7 03/05/2015 11:06 MHH7131 1 EPA 200.7 03/05/2015 11:06 MHH7131 1 EPA 200.7 03/13/2015 12:24 MHALL3 1 EPA 200.7 03/13/2015 12:24 MHALL3 1 EPA 200.7 03/13/2015 12:24 MHALL3 1 EPA 200.7 03/13/2015 12:24 MHALL3 1 EPA 200.7 03/12/2015 14:41 MHH7131 1 EPA 200.7 03/12/2015 14:41 MHH7131 1 EPA 200.7 03/12/2015 14:41 MHH7131 1 EPA 200.7 03/12/2015 14:41 MHH7131 1 EPA 200.7 03/12/2015 14:41 MHH7131 1 EPA 200.7 03/12/2015 14:41 MHH7131 1 EPA 200.7 03/12/2015 14:41 MHH7131 Certificate of Laboratory Analysis Page 9 of 62 This report shall not be reproduced, except in full. Order # J15030096 Site: AMW-12S Sample #: 2015006061 Collection Date: 02-Mar-15 4:33 PM Matrix: GW WW Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst DISSOLVED METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 1 EPA 200.8 03/17/2015 14:15 DJSULL1 Arsenic (As) < 1 ug/L 1 1 EPA 200.8 03/17/2015 14:15 DJSULL1 Beryllium (Be) < 1 ug/L 1 1 EPA 200.8 03/17/2015 14:15 DJSULL1 Cadmium (Cd) < 1 ug/L 1 1 EPA 200.8 03/17/2015 14:15 DJSULL1 Chromium (Cr) < 1 ug/L 1 1 EPA 200.8 03/17/2015 14:15 DJSULL1 Cobalt (Co) 3.85 ug/L 1 1 EPA 200.8 03/17/2015 14:15 DJSULL1 Copper (Cu) 1.25 ug/L 1 1 EPA 200.8 03/17/2015 14:15 DJSULL1 Lead (Pb) < 1 ug/L 1 1 EPA 200.8 03/17/2015 14:15 DJSULL1 Molybdenum (Mo) 1.19 ug/L 1 1 EPA 200.8 03/17/2015 14:15 DJSULL1 Nickel (Ni) 5.56 ug/L 1 1 EPA 200.8 03/17/2015 14:15 DJSULL1 Selenium (Se) < 1 ug/L 1 1 EPA 200.8 03/17/2015 14:15 DJSULL1 Thallium (TI) Low Level < 0.2 ug/L 0.2 1 EPA 200.8 03/17/2015 14:15 DJSULL1 Vanadium (V) Low Level < 0.3 ug/L 0.3 1 EPA 200.8 03/17/2015 14:15 DJSULL1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 1 EPA 200.8 03/12/2015 13:21 DJSULL1 Arsenic (As) < 1 ug/L 1 1 EPA 200.8 03/12/2015 13:21 DJSULL1 Beryllium (Be) < 1 ug/L 1 1 EPA 200.8 03/12/2015 13:21 DJSULL1 Cadmium (Cd) < 1 ug/L 1 1 EPA 200.8 03/12/2015 13:21 DJSULL1 Chromium (Cr) < 1 ug/L 1 1 EPA 200.8 03/12/2015 13:21 DJSULL1 Cobalt (Co) 4.05 ug/L 1 1 EPA 200.8 03/12/2015 13:21 DJSULL1 Copper (Cu) 1.37 ug/L 1 1 EPA 200.8 03/12/2015 13:21 DJSULL1 Lead (Pb) < 1 ug/L 1 1 EPA 200.8 03/12/2015 13:21 DJSULL1 Molybdenum (Mo) 1.34 ug/L 1 1 EPA 200.8 03/12/2015 13:21 DJSULL1 Nickel (Ni) 5.34 ug/L 1 1 EPA 200.8 03/12/2015 13:21 DJSULL1 Selenium (Se) < 1 ug/L 1 1 EPA 200.8 03/12/2015 13:21 DJSULL1 Thallium (TI) Low Level < 0.2 ug/L 0.2 1 EPA 200.8 03/12/2015 13:21 DJSULL1 Vanadium (V) Low Level < 0.3 ug/L 0.3 1 EPA 200.8 03/12/2015 13:21 DJSULL1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4) Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 72 mg/L 25 1 SM2540C 03/09/201512:04 GHUTCHI Total Carbon TOC 0.456 mg/L 0.1 1 SM5310C/EPA9060A 03/05/201516:05 TJA7067 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 1 SM2540D 03/06/2015 11:10 GHUTCHI Certificate of Laboratory Analysis Page 10 of 62 This report shall not be reproduced, except in full. Order # J15030096 Site: Equipment Blank Collection Date: 02-Mar-15 5:15 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) < 0.01 mg-N/L 0.01 INORGANIC IONS BY IC Chloride < 0.1 mg/L 0.1 Sulfate < 0.1 mg/L 0.1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 UNDIGESTED METALS BY ICP Calcium (Ca) 0.017 mg/L 0.01 Magnesium (Mg) < 0.005 mg/L 0.005 Potassium (K) < 0.1 mg/L 0.1 Sodium (Na) < 0.05 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) < 0.005 mg/L 0.005 Barium (Ba) < 0.005 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) < 0.01 mg/L 0.01 Manganese (Mn) < 0.005 mg/L 0.005 Strontium (Sr) < 0.005 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 Sample #: 2015006062 Matrix: GW WW DF Method Analysis Date/Time Analyst Vendor Method V_SHEALY 1 EPA 353.2 03/09/2015 11:09 TLINN 1 EPA 300.0 03/04/2015 19:35 BGN9034 1 EPA 300.0 03/04/2015 19:35 BGN9034 1 EPA 245.1 03/10/2015 10:54 ACPAYNE 1 EPA 200.7 03/13/2015 12:44 MHALL3 1 EPA 200.7 03/13/2015 12:44 MHALL3 1 EPA 200.7 03/13/2015 12:44 MHALL3 1 EPA 200.7 03/13/2015 12:44 MHALL3 1 EPA 200.7 03/12/2015 14:45 MHH7131 1 EPA 200.7 03/12/2015 14:45 MHH7131 1 EPA 200.7 03/12/2015 14:45 MHH7131 1 EPA 200.7 03/12/2015 14:45 MHH7131 1 EPA 200.7 03/12/2015 14:45 MHH7131 1 EPA 200.7 03/12/2015 14:45 MHH7131 1 EPA 200.7 03/12/2015 14:45 MHH7131 1 EPA 200.8 03/12/2015 12:55 DJSULL1 1 EPA 200.8 03/12/2015 12:55 DJSULL1 1 EPA 200.8 03/12/2015 12:55 DJSULL1 1 EPA 200.8 03/12/2015 12:55 DJSULL1 1 EPA 200.8 03/12/2015 12:55 DJSULL1 1 EPA 200.8 03/12/2015 12:55 DJSULL1 1 EPA 200.8 03/12/2015 12:55 DJSULL1 1 EPA 200.8 03/12/2015 12:55 DJSULL1 1 EPA 200.8 03/12/2015 12:55 DJSULL1 1 EPA 200.8 03/12/2015 12:55 DJSULL1 1 EPA 200.8 03/12/2015 12:55 DJSULL1 1 EPA 200.8 03/12/2015 12:55 DJSULL1 1 EPA 200.8 03/12/2015 12:55 DJSULL1 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030096 Site: Equipment Blank Collection Date: 02-Mar-15 5:15 PM Analyte Result Units Qualifiers RDL DF METHANE - (Analysis Performed by Shealy Labs) Methane (CH4) Complete SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS < 25 mg/L 25 1 Total Carbon Page 11 of 62 Sample #: 2015006062 Matrix: GW WW Method Analysis Date/Time Analyst Vendor Method V_SHEALY Vendor Method V_ELE1 SM2540C 03/09/201512:04 GHUTCHI TOC 0.164 mg/L 0.1 1 SM5310C/EPA9060A 03/05/201516:05 TJA7067 TOTAL SUSPENDED SOLIDS TSS 13 mg/L 5 1 SM2540D 03/06/201511:10 GHUTCHI Certificate of Laboratory Analysis Page 12 of 62 This report shall not be reproduced, except in full. Order # J15030096 Site: Filter Blank Collection Date: 02-Mar-15 5:15 PM Analyte Result Units Qualifiers RDL Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (Al) < 0.005 mg/L 0.005 Barium (Ba) < 0.005 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) < 0.01 mg/L 0.01 Manganese (Mn) < 0.005 mg/L 0.005 Strontium (Sr) < 0.005 mg/L 0.005 Zinc (Zn) 0.007 mg/L 0.005 DISSOLVED METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 Sample #: 2015006063 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 245.1 03/12/2015 14:35 ACPAYNE 1 EPA 200.7 03/05/2015 10:50 MHH7131 1 EPA 200.7 03/05/2015 10:50 MHH7131 1 EPA 200.7 03/05/2015 10:50 MHH7131 1 EPA 200.7 03/05/2015 10:50 MHH7131 1 EPA 200.7 03/05/2015 10:50 MHH7131 1 EPA 200.7 03/05/2015 10:50 MHH7131 1 EPA 200.7 03/05/2015 10:50 MHH7131 1 EPA 200.8 03/17/2015 13:54 DJSULL1 1 EPA 200.8 03/17/2015 13:54 DJSULL1 1 EPA 200.8 03/17/2015 13:54 DJSULL1 1 EPA 200.8 03/17/2015 13:54 DJSULL1 1 EPA 200.8 03/17/2015 13:54 DJSULL1 1 EPA 200.8 03/17/2015 13:54 DJSULL1 1 EPA 200.8 03/17/2015 13:54 DJSULL1 1 EPA 200.8 03/17/2015 13:54 DJSULL1 1 EPA 200.8 03/17/2015 13:54 DJSULL1 1 EPA 200.8 03/17/2015 13:54 DJSULL1 1 EPA 200.8 03/17/2015 13:54 DJSULL1 1 EPA 200.8 03/17/2015 13:54 DJSULL1 1 EPA 200.8 03/17/2015 13:54 DJSULL1 Certificate of Laboratory Analysis Page 13 of 62 This report shall not be reproduced, except in full. Order # J15030096 Site: AMW-12BC Collection Date: 03-Mar-15 9:05 AM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) < 0.02 mg-N/L 0.02 INORGANIC IONS BY IC Chloride 14 mg/L 1 Sulfate 17 mg/L 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) 0.006 mg/L 0.005 Barium (Ba) 0.010 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 3.10 mg/L 0.01 Manganese (Mn) 0.275 mg/L 0.005 Strontium (Sr) 0.044 mg/L 0.005 Zinc (Zn) 0.006 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 9.27 mg/L M4 0.01 Magnesium (Mg) 2.54 mg/L 0.005 Potassium (K) 2.19 mg/L 0.1 Sodium (Na) 16.5 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.036 mg/L 0.005 Barium (Ba) 0.011 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 3.26 mg/L 0.01 Manganese (Mn) 0.285 mg/L 0.005 Strontium (Sr) 0.046 mg/L 0.005 Zinc (Zn) 0.006 mg/L 0.005 Sample #: 2015006070 Matrix: GW WW DF Method Analysis Date/Time Analyst Vendor Method V_SHEALY 2 EPA 353.2 03/09/2015 11:29 TLINN 10 EPA 300.0 03/04/2015 19:52 BGN9034 10 EPA 300.0 03/04/2015 19:52 BGN9034 1 EPA 245.1 03/10/2015 12:06 ACPAYNE 1 EPA 245.1 03/12/2015 14:37 ACPAYNE 1 EPA 200.7 03/05/2015 11:11 MHH7131 1 EPA 200.7 03/05/2015 11:11 MHH7131 1 EPA 200.7 03/05/2015 11:11 MHH7131 1 EPA 200.7 03/05/2015 11:11 MHH7131 1 EPA 200.7 03/05/2015 11:11 MHH7131 1 EPA 200.7 03/05/2015 11:11 MHH7131 1 EPA 200.7 03/05/2015 11:11 MHH7131 1 EPA 200.7 03/13/2015 12:28 MHALL3 1 EPA 200.7 03/13/2015 12:28 MHALL3 1 EPA 200.7 03/13/2015 12:28 MHALL3 1 EPA 200.7 03/13/2015 12:28 MHALL3 1 EPA 200.7 03/12/2015 14:54 MHH7131 1 EPA 200.7 03/12/2015 14:54 MHH7131 1 EPA 200.7 03/12/2015 14:54 MHH7131 1 EPA 200.7 03/12/2015 14:54 MHH7131 1 EPA 200.7 03/12/2015 14:54 MHH7131 1 EPA 200.7 03/12/2015 14:54 MHH7131 1 EPA 200.7 03/12/2015 14:54 MHH7131 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030096 Site: AMW-12BC Collection Date: 03-Mar-15 9:05 AM Analyte Result DISSOLVED METALS BY ICP-MS Antimony (Sb) < 1 Arsenic (As) < 1 Beryllium (Be) < 1 Cadmium (Cd) < 1 Chromium (Cr) < 1 Cobalt (Co) 1.13 Copper (Cu) < 1 Lead (Pb) < 1 Molybdenum (Mo) < 1 Nickel (Ni) 2.02 Selenium (Se) < 1 Thallium (TI) Low Level < 0.2 Vanadium (V) Low Level < 0.3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 Arsenic (As) < 1 Beryllium (Be) < 1 Cadmium (Cd) < 1 Chromium (Cr) < 1 Cobalt (Co) 1.19 Copper (Cu) <1 Lead (Pb) < 1 Molybdenum (Mo) < 1 Nickel (Ni) 2.20 Selenium (Se) < 1 Thallium (TI) Low Level < 0.2 Vanadium (V) Low Level < 0.3 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4) Complete SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 110 Total Carbon TOC 0.566 TOTAL SUSPENDED SOLIDS TSS < 5 Page 14 of 62 Sample #: 2015006070 Matrix: GW WW Units Qualifiers RDL DF Method Analysis Date/Time Analyst ug/L 1 1 EPA 200.8 03/17/2015 14:20 DJSULL1 ug/L 1 1 EPA 200.8 03/17/2015 14:20 DJSULL1 ug/L 1 1 EPA 200.8 03/17/2015 14:20 DJSULL1 ug/L 1 1 EPA 200.8 03/17/2015 14:20 DJSULL1 ug/L 1 1 EPA 200.8 03/17/2015 14:20 DJSULL1 ug/L 1 1 EPA 200.8 03/17/2015 14:20 DJSULL1 ug/L 1 1 EPA 200.8 03/17/2015 14:20 DJSULL1 ug/L 1 1 EPA 200.8 03/17/2015 14:20 DJSULL1 ug/L 1 1 EPA 200.8 03/17/2015 14:20 DJSULL1 ug/L 1 1 EPA 200.8 03/17/2015 14:20 DJSULL1 ug/L 1 1 EPA 200.8 03/17/2015 14:20 DJSULL1 ug/L 0.2 1 EPA 200.8 03/17/2015 14:20 DJSULL1 ug/L 0.3 1 EPA 200.8 03/17/2015 14:20 DJSULL1 ug/L 1 1 EPA 200.8 03/12/2015 13:26 DJSULL1 ug/L 1 1 EPA 200.8 03/12/2015 13:26 DJSULL1 ug/L 1 1 EPA 200.8 03/12/2015 13:26 DJSULL1 ug/L 1 1 EPA 200.8 03/12/2015 13:26 DJSULL1 ug/L 1 1 EPA 200.8 03/12/2015 13:26 DJSULL1 ug/L 1 1 EPA 200.8 03/12/2015 13:26 DJSULL1 ug/L 1 1 EPA 200.8 03/12/2015 13:26 DJSULL1 ug/L 1 1 EPA 200.8 03/12/2015 13:26 DJSULL1 ug/L 1 1 EPA 200.8 03/12/2015 13:26 DJSULL1 ug/L 1 1 EPA 200.8 03/12/2015 13:26 DJSULL1 ug/L 1 1 EPA 200.8 03/12/2015 13:26 DJSULL1 ug/L 0.2 1 EPA 200.8 03/12/2015 13:26 DJSULL1 ug/L 0.3 1 EPA 200.8 03/12/2015 13:26 DJSULL1 Vendor Method V_SHEALY Vendor Method V_ELE1 mg/L 25 1 SM2540C 03/09/201512:04 GHUTCHI mg/L 0.1 1 SM5310C/EPA9060A 03/05/201516:05 TJA7067 mg/L 5 1 SM2540D 03/06/201511:10 GHUTCHI Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030096 Site: AMW-13S Collection Date: 03-Mar-15 11:48 AM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) < 0.01 mg-N/L 0.01 INORGANIC IONS BY IC Chloride 28 mg/L 1 Sulfate 14 mg/L 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (AI) < 0.005 mg/L 0.005 Barium (Ba) 0.111 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 0.126 mg/L 0.01 Manganese (Mn) 0.607 mg/L 0.005 Strontium (Sr) 0.073 mg/L 0.005 Zinc (Zn) 0.020 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 12.4 mg/L 0.01 Magnesium (Mg) 5.98 mg/L 0.005 Potassium (K) 0.474 mg/L 0.1 Sodium (Na) 22.7 mg/L 0.5 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 3.56 mg/L 0.005 Barium (Ba) 0.136 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 2.38 mg/L 0.01 Manganese (Mn) 0.727 mg/L 0.005 Strontium (Sr) 0.078 mg/L 0.005 Zinc (Zn) 0.022 mg/L 0.005 Sample #: 2015006071 Matrix: GW WW Page 15 of 62 DF Method Analysis Date/Time Analyst Vendor Method V_SHEALY 1 EPA 353.2 03/09/2015 11:18 TLINN 10 EPA 300.0 03/04/2015 20:08 BGN9034 10 EPA 300.0 03/04/2015 20:08 BGN9034 1 EPA 245.1 03/10/2015 12:13 ACPAYNE 1 EPA 245.1 03/12/2015 14:40 ACPAYNE 1 EPA 200.7 03/05/2015 11:15 MHH7131 1 EPA 200.7 03/05/2015 11:15 MHH7131 1 EPA 200.7 03/05/2015 11:15 MHH7131 1 EPA 200.7 03/05/2015 11:15 MHH7131 1 EPA 200.7 03/05/2015 11:15 MHH7131 1 EPA 200.7 03/05/2015 11:15 MHH7131 1 EPA 200.7 03/05/2015 11:15 MHH7131 1 EPA 200.7 03/13/2015 12:32 MHALL3 1 EPA 200.7 03/13/2015 12:32 MHALL3 1 EPA 200.7 03/13/2015 12:32 MHALL3 10 EPA 200.7 03/13/2015 12:32 MHALL3 1 EPA 200.7 03/12/2015 15:02 MHH7131 1 EPA 200.7 03/12/2015 15:02 MHH7131 1 EPA 200.7 03/12/2015 15:02 MHH7131 1 EPA 200.7 03/12/2015 15:02 MHH7131 1 EPA 200.7 03/12/2015 15:02 MHH7131 1 EPA 200.7 03/12/2015 15:02 MHH7131 1 EPA 200.7 03/12/2015 15:02 MHH7131 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030096 Site: AMW-13S Collection Date: 03-Mar-15 11:48 AM Analyte Result DISSOLVED METALS BY ICP-MS Antimony (Sb) < 1 Arsenic (As) < 1 Beryllium (Be) < 1 Cadmium (Cd) < 1 Chromium (Cr) < 1 Cobalt (Co) 30.8 Copper (Cu) < 1 Lead (Pb) < 1 Molybdenum (Mo) < 1 Nickel (Ni) 10.6 Selenium (Se) < 1 Thallium (TI) Low Level < 0.2 Vanadium (V) Low Level 0.487 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 Arsenic (As) < 1 Beryllium (Be) < 1 Cadmium (Cd) < 1 Chromium (Cr) 3.78 Cobalt (Co) 35.7 Copper (Cu) 2.20 Lead (Pb) < 1 Molybdenum (Mo) < 1 Nickel (Ni) 12.5 Selenium (Se) < 1 Thallium (TI) Low Level < 0.2 Vanadium (V) Low Level 6.71 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4) Complete SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS 210 Total Carbon TOC 1.7 TOTAL SUSPENDED SOLIDS TSS 13 Page 16 of 62 Sample #: 2015006071 Matrix: GW WW Units Qualifiers RDL DF Method Analysis Date/Time Analyst ug/L 1 1 EPA 200.8 03/17/2015 14:25 DJSULL1 ug/L 1 1 EPA 200.8 03/17/2015 14:25 DJSULL1 ug/L 1 1 EPA 200.8 03/17/2015 14:25 DJSULL1 ug/L 1 1 EPA 200.8 03/17/2015 14:25 DJSULL1 ug/L 1 1 EPA 200.8 03/17/2015 14:25 DJSULL1 ug/L 1 1 EPA 200.8 03/17/2015 14:25 DJSULL1 ug/L 1 1 EPA 200.8 03/17/2015 14:25 DJSULL1 ug/L 1 1 EPA 200.8 03/17/2015 14:25 DJSULL1 ug/L 1 1 EPA 200.8 03/17/2015 14:25 DJSULL1 ug/L 1 1 EPA 200.8 03/17/2015 14:25 DJSULL1 ug/L 1 1 EPA 200.8 03/17/2015 14:25 DJSULL1 ug/L 0.2 1 EPA 200.8 03/17/2015 14:25 DJSULL1 ug/L 0.3 1 EPA 200.8 03/17/2015 14:25 DJSULL1 ug/L 1 1 EPA 200.8 03/12/2015 13:31 DJSULL1 ug/L 1 1 EPA 200.8 03/12/2015 13:31 DJSULL1 ug/L 1 1 EPA 200.8 03/12/2015 13:31 DJSULL1 ug/L 1 1 EPA 200.8 03/12/2015 13:31 DJSULL1 ug/L 1 1 EPA 200.8 03/12/2015 13:31 DJSULL1 ug/L 1 1 EPA 200.8 03/12/2015 13:31 DJSULL1 ug/L 1 1 EPA 200.8 03/12/2015 13:31 DJSULL1 ug/L 1 1 EPA 200.8 03/12/2015 13:31 DJSULL1 ug/L 1 1 EPA 200.8 03/12/2015 13:31 DJSULL1 ug/L 1 1 EPA 200.8 03/12/2015 13:31 DJSULL1 ug/L 1 1 EPA 200.8 03/12/2015 13:31 DJSULL1 ug/L 0.2 1 EPA 200.8 03/12/2015 13:31 DJSULL1 ug/L 0.3 1 EPA 200.8 03/12/2015 13:31 DJSULL1 Vendor Method V_SHEALY Vendor Method V_ELE1 mg/L 25 1 SM2540C 03/09/201512:04 GHUTCHI mg/L 0.1 1 SM5310C/EPA9060A 03/05/201516:05 TJA7067 mg/L 5 1 SM2540D 03/06/201511:10 GHUTCHI Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030096 Site: Equipment Blank Collection Date: 03-Mar-15 12:42 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.044 mg-N/L 0.01 INORGANIC IONS BY IC Chloride < 0.1 mg/L 0.1 Sulfate < 0.1 mg/L 0.1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 0.05 ug/L 0.05 UNDIGESTED METALS BY ICP Calcium (Ca) < 0.01 mg/L 0.01 Magnesium (Mg) < 0.005 mg/L 0.005 Potassium (K) < 0.1 mg/L 0.1 Sodium (Na) < 0.05 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) < 0.005 mg/L 0.005 Barium (Ba) < 0.005 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) < 0.01 mg/L 0.01 Manganese (Mn) < 0.005 mg/L 0.005 Strontium (Sr) < 0.005 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 Page 17 of 62 Sample #: 2015006072 Matrix: GW WW DF Method Analysis Date/Time Analyst Vendor Method V_SHEALY 1 EPA 353.2 03/09/2015 11:19 TLINN 1 EPA 300.0 03/04/2015 20:24 BGN9034 1 EPA 300.0 03/04/2015 20:24 BGN9034 1 EPA 245.1 03/10/2015 12:15 ACPAYNE 1 EPA 200.7 03/13/2015 13:33 MHALL3 1 EPA 200.7 03/13/2015 13:33 MHALL3 1 EPA 200.7 03/13/2015 13:33 MHALL3 1 EPA 200.7 03/13/2015 13:33 MHALL3 1 EPA 200.7 03/12/2015 15:06 MHH7131 1 EPA 200.7 03/12/2015 15:06 MHH7131 1 EPA 200.7 03/12/2015 15:06 MHH7131 1 EPA 200.7 03/12/2015 15:06 MHH7131 1 EPA 200.7 03/12/2015 15:06 MHH7131 1 EPA 200.7 03/12/2015 15:06 MHH7131 1 EPA 200.7 03/12/2015 15:06 MHH7131 1 EPA 200.8 03/12/2015 13:00 DJSULL1 1 EPA 200.8 03/12/2015 13:00 DJSULL1 1 EPA 200.8 03/12/2015 13:00 DJSULL1 1 EPA 200.8 03/12/2015 13:00 DJSULL1 1 EPA 200.8 03/12/2015 13:00 DJSULL1 1 EPA 200.8 03/12/2015 13:00 DJSULL1 1 EPA 200.8 03/12/2015 13:00 DJSULL1 1 EPA 200.8 03/12/2015 13:00 DJSULL1 1 EPA 200.8 03/12/2015 13:00 DJSULL1 1 EPA 200.8 03/12/2015 13:00 DJSULL1 1 EPA 200.8 03/12/2015 13:00 DJSULL1 1 EPA 200.8 03/12/2015 13:00 DJSULL1 1 EPA 200.8 03/12/2015 13:00 DJSULL1 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030096 Site: Equipment Blank Collection Date: 03-Mar-15 12:42 PM Analyte Result Units Qualifiers RDL DF METHANE - (Analysis Performed by Shealy Labs) Methane (CH4) Complete SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS < 25 mg/L 25 1 Total Carbon Page 18 of 62 Sample #: 2015006072 Matrix: GW WW Method Analysis Date/Time Analyst Vendor Method V_SHEALY Vendor Method V_ELE1 SM2540C 03/09/201512:04 GHUTCHI TOC < 0.1 mg/L 0.1 1 SM5310C/EPA9060A 03/05/2015 16:05 TJA7067 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 1 SM2540D 03/06/2015 11:10 GHUTCHI Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030096 Site: Filter Blank Collection Date: 03-Mar-15 12:42 PM Analyte Result Units Qualifiers RDL Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP Aluminum (Al) < 0.005 mg/L 0.005 Barium (Ba) < 0.005 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) < 0.01 mg/L 0.01 Manganese (Mn) < 0.005 mg/L 0.005 Strontium (Sr) < 0.005 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 DISSOLVED METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 Sample #: 2015006073 Matrix: GW WW Page 19 of 62 DF Method Analysis Date/Time Analyst 1 EPA 245.1 03/12/2015 14:42 ACPAYNE 1 EPA 200.7 03/05/2015 10:54 MHH7131 1 EPA 200.7 03/05/2015 10:54 MHH7131 1 EPA 200.7 03/05/2015 10:54 MHH7131 1 EPA 200.7 03/05/2015 10:54 MHH7131 1 EPA 200.7 03/05/2015 10:54 MHH7131 1 EPA 200.7 03/05/2015 10:54 MHH7131 1 EPA 200.7 03/05/2015 10:54 MHH7131 1 EPA 200.8 03/17/2015 13:59 DJSULL1 1 EPA 200.8 03/17/2015 13:59 DJSULL1 1 EPA 200.8 03/17/2015 13:59 DJSULL1 1 EPA 200.8 03/17/2015 13:59 DJSULL1 1 EPA 200.8 03/17/2015 13:59 DJSULL1 1 EPA 200.8 03/17/2015 13:59 DJSULL1 1 EPA 200.8 03/17/2015 13:59 DJSULL1 1 EPA 200.8 03/17/2015 13:59 DJSULL1 1 EPA 200.8 03/17/2015 13:59 DJSULL1 1 EPA 200.8 03/17/2015 13:59 DJSULL1 1 EPA 200.8 03/17/2015 13:59 DJSULL1 1 EPA 200.8 03/17/2015 13:59 DJSULL1 1 EPA 200.8 03/17/2015 13:59 DJSULL1 Qualifiers: M4 The spike recovery value was unusable since the analyte concentration in the sample was disproportionate to the spike level. The associated Laboratory Control Spike recovery was acceptable. Page 20 of 62 Duke Energy Laboratory Services 13339 Hagers Ferry Road Bld. MG03A Huntersville, NC 28078 Mernent One Inc. 6319-D Carolina (Beach Rd. Wilmington, NC 28412 Phone: 910 793-0128 Fax: 910 792-6853 e1 lab a@e1 lab.com REPORT OF ANALYSES March 23, 2015 Client Project Name HF Lee Client Project Number J15030096 PO Number Sample Matrix GW WW Sample Type Grab Date Received 03/10/2015 Date Analyzed 03/12/2015 Method SM 4500 S2- D Time Received 1120 Delivered by Fed Ex Received by LLB eOne ID Duke Energy ID Parameter Result Unit Dil DL Date Time Sampled Sampled 24229-1 AMW-11 BC Sulfide < 0.1 mg/L 1 0.1 03/02/15 1256 24229-2* AMW-11 S Sulfide < 0.5 mg/L 5 0.1 03/02/15 1415 24229-3* AMW-12S Sulfide < 0.5 mg/L 5 0.1 03/02/15 1633 24229-4 Equipment Blank Sulfide < 0.1 mg/L 1 0.1 03/02/15 1715 24229-5* AMW-12BC Sulfide < 0.5 mg/L 5 0.1 03/03/15 0905 24229-6 AMW-13S Sulfide < 0.1 mg/L 1 0.1 03/03/15 1148 24229-7* Equipment Blank Sulfide < 0.5 mg/L 5 0.1 03/03/15 1242 Samples were received and analyzed outside of hold time. *Sample spike recovery outside of QA limits of 85-115%; dilution necessary to meet laboratory QA limits. This is the first revision to this report; it was necessary to analyze an additional curve point to meet the requested detection limit of < 0.1 mg/L. Ken Rmith, Laboratory Director 24229 Duke Report Packet Rev 3.23.15 Compiled by-M.I-) NC Certifications: DW 37788 and DWQ DENR 604 Page 21 of 62 W N •= sle;aw •- 00. penlosslp F O w 'k Molaq �( b any 0 o - tU I I �I�I of d (Ltuewal A) OpulnS i i aVi C IQ84S A — � I 0 U.�� uJ 3 � a s 'Rllulinlltl Al 001 -� cf S ' CON'VOS'lo -- 141 _ E " mews A le[►Ounnew J, g SOl'SSl Z�- E b J a 9ar0 x Q^1ww .�: 5 1Nn fa E r 'dwoo qua 01 0 M m E V 1 O m 15 - � o ! F N O a O je o_F� sjr„ c�i;i� W J. ^i -- Tp O I I; I�;o I � i G10 � i C7 i Q i 0 7 i y o E Y i cwg�i�! C U i i 1�'; 1 �M �rlf^iM ch c� Mt'f' M � G O O �Xq O J Q ofin fi `� 2 V► N CL V) 3 3 aA ; 0 h 0 o m 0 v e A 'Q' IQ o. �3 a� O m = m9 r D r, Q J punojeuwnt poilsep eleolpuleseeld :1ueylodwl'j8wolsn3 N r� _ N M X > a e 1z • eZ U Y GI F �U i y >, � m d 10 d C u t�y d M d M �OIft:a Y O 1 ry LL m C C .y c 'C Q m � g m � a W o9 � � L a a aT W W 3 q Im W W elementOne SAMPLE SUBMISSION FORM Lab IOpge 14`119 TAT 7 BD Hold Time Expiration 03.09.15 @ 1256 PM Client: Duke Energy LIMS No J15030096 Project ID HF Lee Analysis Due Date 03.11.15 Report Due Date 03.18.15 Date Rec: 03.10.15 Time Rec: 1120 Rec By LLB H >9 es No Tem <_ 60C es No Ref. Method: SM4500 S2 D If No, Record If No, Record I Samnle Identification & Cnller_tinn Infnrmatinn Lab ID Client ID Collection Date Collection Time Analysis Requested 1 AMW-11 BC 03.02.15 1256 PM Sulfide 2 AMW-11 S 03.02.15 1415 PM Sulfide 3 AMW-12S _ � 03.02.15 1633 PM Sulfide 4 Equipment Blank_ _ _ 03.02.15 � 1715 PM Sulfide 5 AMW-12BC 03.03.15 0905 AM Sulfide 6 AMW-13S _ 03.03.15 1148 AM Sulfide 7 Equipment Blank 03.03.15 _ 1242 PM __ Sulfide NOTE for Sulfide The MS/MSD spike should approximate 2 to 3 times the sample concentration. If no sulfide detected at 100 pg/L spike the sample to render the final spike concentration at - 500 pg/L Lab Communications 1. Per Jay via a mail, analyze samples out of hold time and document on report---03.10.15 LLB SS Page 1 of Prep By / Date A SS by Labeled By / Date .3 , /o . / 3/11/2015 1 :02 AM ID Verification By /Date Page 23 of 62 METHOD: SM 4500 S2- D ELEMENT ONE ELEMENT ASSAY: Sulfide Spectrophotometer Wave Length 664 UNITS OF ANSWER DETECTIONS LIMEjug) u mL CLIENT: Duke SPK LEVEL u 5 Lab ID# 24229, 24230, 24231 3/11/15 12:45 17:00 KAM _ Y Na2S•9H2O Lot 5010904 WC2-62-1 WC2-62-2 - MAX ALI UOT STANDARD conc(ppm) - STD ABSORPTION - --- -- - - 10.00 X 10 Y - - Date: Time Analysis Begun Time Analysis Ended Analyst: X ug STD STD Moo SOLUTION ABS 06M 0.00 0.000 °.00 1.00 0.064 ( o- 2.50 0.170 0200 5.00 0.341 010° 7 50 0 482 ° - --C �„ - - - I o00 200 400 800 000 i0.0o 1200. 10.00 0.626 x �I Sloe 0.062980221. Correlation 0.999000062 SAMPLE SAMP ug PER ALI in mL PREP ALI in mL RESULTS LESS THAN SPIKE I.D. ABS ALIQUOT ANALYZED VOL in mL TAKEN ug/mL % SPK REC LEVEL LRB 0.000 0.0000 10 10 10 <0.1 0 LRB SPK 0.341 5.3348 10 10 10 0.533 107% 5.0 24229-1 0.003 -0.2600 10 10 10 <011 24229-1 s k 0,297 4.6065 10 10 10 0.461 92% 5.0 24229-2 0.003 -0.2600 10 10 10 <0.1 24229-2 s k 0.217 3.2822 10 10 10 0.328 66% 5.0 24229-3 0.001 -0.2931 10 10 10 <0.1 24229-3 s k 0.234 3.5636 10 10 10 0.356 71 % 5.0 242294 0.001 -0.2931 10 10' 40 <01 24229-4 s k 0.305 4.7389 10 10 10 0.474 . 95% 5.0 24229-5 0.003 -0.2600 10 10 10 <0A 24229-5 dup 0.002 -0.2766 10 10 10 <0.1 -6% 24229-5 s k 0.228 3.4643 10 10 10 0.346 69% 5.0 24229-6 0.004 -0.2436 , 10 10 10 . <00 24229-6 s k 0.288 4.4575 10 I0 10 0,446 89% 5.0 24229-7 0.003 -0.2600 10 10 10 <0.1 24229-7 s k 1 0.263 4.0437 10 10 10 0.404 81 % 5.0 5.0 24230-2 0.003 -0.2600 10 101, 10 <0.1 24230-2 du 0.000 010000 10 10. 10' <0.1 24230-2spk 0.291 4.5071 10 10 10 0.01 90%0 5.0 24231 0.003 _0.2600 10 - 10 10 <0.1 24231 s k - 0.301 4.6727 10 10. 10 0.467 93% 5.0 Blank 0.000 0.0000 10 10 10 <0.1 QC 0.335 5.2355 10 10 10 0.524 5.0 Submitted OrQ - Date:�%��/� Bv:(Print) '1`-)Mn �- Sulfide 4 Page 24 of 62 METHOD: SM 4500 S2- D ELEMENT ONE ELEMENT ASS": Sulfide Spectrophotometer Wave Length 664 UNITS OF ANSWER u mL DETECTION LIMIT u CLIENT: Duke SPK LEVEL u 5 Lab ID# 24224 228, 229, 230 231 3/12/15 15:00 17:00 KAM DMR Y Na2S•9H2O Lot 5010904 WC2-62-1 WC2-62-2 - - MAX ALIQUOT STANDARD conc(ppm) STD ABSORPTION --- -- - --- - - 10.00 X 10 Y Date: Time Analysis Begun Time Analysis Ended Analyst: X ug STD STD 0 700 SOLUTION ABS 0000 0.00 0.000 0400 1.00 0.064 I ^ 3" 2.50 0.170 5.00 750 0.341 0 482 ° - 911 00z0 000 2a0 4.. an0 000 10.00 +.0. 10.00 0.626 x L' F Sio a 0.06298022 Correlation 0.999000862 SAMPLE I.D. SAMP ABS ug PER ALIQUOT ALI in mL ANALYZED PREP VOL in mL ALI in mL TAKEN RESULTS ug/mL LESS THAN % SPK REC SPIKE LEVEL LRB 0.000 10 10 10 <0.1 0 LRB SPK 0.341 5.3348 10 10 10 0.533 107% 5.0 24224-5 0.003 -0.2600 10 10 2 <0.5 24224-5 spk 0.318 4,9541 10 10 2 2.477 99% ` 5.0 24224-6 0.003 -0.2600 10 To 2 <0.5 24224-6spk 0.358 6.6162 10 10 112°% 5.0 24224-7 0.001 -0.2931 10 10 2 <0.5 24224-7 s k 0.353 5.5334 10 10 2 2.767 5.0 24228-2 0,002 -0.276E 10 10 2; <0.5 2422E-2 gpk 0.358 5.6162 10 10 2 2.808 112% 5.0 24228.4 0.003 -02600 10 10 2 <0.5. 242284 s k 0.337 5.2686 10 1.0 2 ` 2.6.34 105°b, , ` 5.0 24229-1 0.001 -0.2931 10 10 2 <0.5 24229-1 s k 0.338 5.2851 10 10 2 2.643 106°k 5.0 24229-2 0.0001 10 10 2: <0.5. 24229-2 splk 0.354 5.5500 1 10 -to 2 . 2.775 111% 5.0 24229-3 0.002 -0.2766 10 10 2 <0.5 ea -a 0.003 1 -0.2600 10 10 2 <0;5 !9-5 s k !9-6 0.356 0.002 5.5831 -0.2766 10 <' 10 -10 10 2 2 2.792 <0.5 L 112% 5.0 M-6 s k !9-7 0.337 0.001 5.2686 -0.2931 10 10 : 10 10 2 2 2.634 <0.6 105%'' 5.0 !9.7 splk 10-1 0.340 0.002 5.3182 -0.2766 10 10 10 10 2 2 2.659 <0.5 106% 5.0 10.1 spk 10-2 0.335 0.000 5.2355 0.0000 10 10 10 10 2: 2 2.618 <0.5 105°k 5.0 10-2 dup 0.001 -0.2931 10 10 2 <0.5 10-2 s k 0.351 5.5003 10 10 2 2.750 110% 5.0 11 0.002 -0.2766 10 10 2 <0.5 1 s k 0.345 5.4010 10 10 2 2.700 108% 5.0 Blank 0.000 0.0000 10 10 10 <0.1 QC 0.335 5.2355 10 10 10 0.524 105% imitte thr Q QC- Date: By: (Print) 5.0 (sign): 7 Sulfide 8 Paqe 25 of 62 METHOD: SM 4500 S2- D ELEMENT ONE ELEMENT ASSAY: Sulfide Spectrophotometer UNITS OF ANSWER DETECTION L Wave Length 664 IMIT u Duke SPK LEVEL u 24218, 229, 221, 223 MAX ALIQUOT 3/12/15 Na2S-9H2O Lot 5010904 STANDARD conc(ppm) 17:00 WC2-62-1 19:00 WC2-62-2 KAM DMR KMS STD ABSORPTION Y- u /mL 2.500 5 10.00 X CLIENT: Lab ID# Date: Time Analysis Begun 10 Time Analysis Ended Analyst: y X ug STD SOLUTION STD ABS- 0.000 0.n00 0.064 1 Y 0.170 0.341 0,0,004 0.482 01705.00 _ 041 o.�a_ . i 0.00 1.00 2.50 7.50 10.00 4.00 000 200 0.626 X i SAMPLE SAMP ug PER ALI in mL PREP I.D. ABS ALIQUOT ANALYZED VOL in mL Sloe 0.06298022 ALI in mL RESULTS TAKEN u /mL Correlation 0.999000i362 LESS THAN SPIKE % SPK REC LEVEL LRB 0.000 10 10 10 <0.1 0 LRB SPK 0.341 5.3348 10 10 10 0.533 107% 5.0 24218-1 0,011 -0.1276 10 10 2, <0.5. 24218-1 s k 0.332 5.1858 10 10 2 2.593 104% 5.0 24218-6 0.019 0.0048 10. 10 ' 2 <0.5 24218-6 s k 24229-3 0.335 ' 0.014 5.2355 -0.0780 10 10 10 10 2 2 2.618 <U.5 105% 5.0 24229-3 s k 24229-4 0.335 0.008 5.2355 -0.1773 10 10 10 10 2 2 2.618 <0.5 105°l0 5.0 24229-4 s k 24218-2 0.326 0.027 5.0865 0.1372 10 10 10 10 2 2 2.543 <0.5 : 102% 5.0 24218-2 s k 24218.5 0.317 0.020 4.9375 0.0214 10 10 10 10 2 0:5 2.469 <2 99% 5.0 2421.8-5 s k 0.259 3.9775 10 10 0:5 7.955 80% 5.0 24221-2 24221-2 spk 0.007 0.315 -0.1938 4.9044 10 10 16 10 2 2 <0 5 2.452 98°h 100%' 5.0 5.0 24223-2 0.016 -0.0449 10 10 2 <0.5 24223-2 s k 0.322 5.0203 10 10 2 2.510 <0.5 24223-4 0.054 0.5841 10 10 2 24223-4 s k 24223-4 0.177 2.6201 10 10 2 1.310 <2 52% 5.0 24223-4 0.018 -0.0117 10 10 05 s k 0.230 3,4974 10 10 0,5 6.995 70% 5.0 <0.1 Blank .0.000 0.0000 1 10 10 10 QC ubmitt for Q 0.335 5.2355 10 Date: 10 By: (Print) 10 0.524 105% 5.0 (sign): Sulfide 9 SHEALY ENVIRONMENTAL SERVICES, INC. Report of Analysis Duke Energy 13339 Hagers Ferry Rd Bldg 7405 Huntersville, NC 28078 Attention: Mary Ann Ogle Project Name: Groundwater Assessment - HF Lee Project Number:J15030096 Lot Number:QC05039 Date Completed:03/16/2015 Grant Wilton Project Manager This report shall not be reproduced, except in its entirety, without the written approval of Shealy Environmental Services, Inc. The following non -paginated documents are considered part of this report: Chain of Custody Record and Sample Receipt Checklist. *QC05039* Shealy Environmental Services, Inc. Page: 1 of 18 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. SC DHEC No: 32010 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative Duke Energy Lot Number: QC05039 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the Shealy Environmental Services, Inc. ("Shealy") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPs), and Shealy policies. Any exceptions to the NELAC standards, the QAMP, SOPS or policies are qualified on the results page or discussed below. If you have any questions regarding this report please contact the Shealy Project Manager listed on the cover page Shealy Environmental Services, Inc. Page: 2 of 18 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. Sample Summary Duke Energy Lot Number: QC05039 Sample Number Sample ID Matrix Date Sampled Date Received 001 20152006059 Aqueous 03/02/20151256 03/05/2015 002 20152006060 Aqueous 03/02/20151415 03/05/2015 003 20152006061 Aqueous 03/02/20151633 03/05/2015 004 20152006062 Aqueous 03/02/20151715 03/05/2015 005 20152006063 Aqueous 03/02/20151715 006 20152006070 Aqueous 03/03/2015 0905 03/05/2015 007 20152006071 Aqueous 03/03/20151148 03/05/2015 008 20152006072 Aqueous 03/03/20151242 03/05/2015 009 20152006073 Aqueous 03/03/20151242 (9 samples) Shealy Environmental Services, Inc. Page: 3 of 18 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. Executive Summary Duke Energy Lot Number: QC05039 Sample Sample ID Matrix Parameter Method Result Q Units Page 001 20152006059 Aqueous Alkalinity SM 2320B- 51 mg/L 5 001 20152006059 Aqueous Bicarbonate Alkalinity SM 2320B- 51 mg/L 5 001 20152006059 Aqueous Methane RSK - 175 19 ug/L 6 002 20152006060 Aqueous Alkalinity SM 2320B- 11 mg/L 7 002 20152006060 Aqueous Bicarbonate Alkalinity SM 2320B- 11 mg/L 7 006 20152006070 Aqueous Alkalinity SM 2320B- 36 mg/L 13 006 20152006070 Aqueous Bicarbonate Alkalinity SM 2320B- 36 mg/L 13 006 20152006070 Aqueous Methane RSK - 175 24 ug/L 14 007 20152006071 Aqueous Alkalinity SM 2320B- 43 mg/L 15 007 20152006071 Aqueous Bicarbonate Alkalinity SM 2320B- 43 mg/L 15 (10 detections) Shealy Environmental Services, Inc. Page: 4 of 18 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals Client: Duke Energy Laboratory ID: QC05039-001 Description: 20152006059 Matrix: Aqueous Date Sampled:03/02/2015 1256 Date Received:03/05/2015 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 03/06/2015 1709 BWS 69383 1 (Bicarbonate ) SM 2320B-2011 1 03/06/2015 1709 BWS 03/06/2015 1709 1 (Carbonate Al) SM 2320B-2011 1 03/06/2015 1709 BWS 03/06/2015 1709 CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 51 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 51 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 5 of 18 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane Client: Duke Energy Laboratory ID: QC05039-001 Description: 20152006059 Matrix: Aqueous Date Sampled:03/02/2015 1256 Date Received:03/05/2015 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 03/12/2015 2354 JJG 69885 CAS Analytical Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 19 10 ug/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 6 of 18 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals Client: Duke Energy Laboratory ID: QC05039-002 Description: 20152006060 Matrix: Aqueous Date Sampled:03/02/2015 1415 Date Received:03/05/2015 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 03/06/2015 1713 BWS 69383 1 (Bicarbonate ) SM 2320B-2011 1 03/06/2015 1713 BWS 03/06/2015 1713 1 (Carbonate Al) SM 2320B-2011 1 03/06/2015 1713 BWS 03/06/2015 1713 CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 11 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 11 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 7 of 18 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane Client: Duke Energy Laboratory ID: QC05039-002 Description: 20152006060 Matrix: Aqueous Date Sampled:03/02/2015 1415 Date Received:03/05/2015 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 03/13/2015 0005 JJG 69885 CAS Analytical Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 10 ug/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 8 of 18 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals Client: Duke Energy Laboratory ID: QC05039-003 Description: 20152006061 Matrix: Aqueous Date Sampled:03/02/2015 1633 Date Received:03/05/2015 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 03/06/2015 1730 BWS 69383 1 (Bicarbonate ) SM 2320B-2011 1 03/06/2015 1730 BWS 03/06/2015 1730 1 (Carbonate Al) SM 2320B-2011 1 03/06/2015 1730 BWS 03/06/2015 1730 CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 ND 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 9 of 18 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane Client: Duke Energy Laboratory ID: QC05039-003 Description: 20152006061 Matrix: Aqueous Date Sampled:03/02/2015 1633 Date Received:03/05/2015 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 03/13/2015 0017 JJG 69885 CAS Analytical Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 10 ug/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 10 of 18 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals Client: Duke Energy Laboratory ID: QC05039-004 Description: 20152006062 Matrix: Aqueous Date Sampled:03/02/2015 1715 Date Received:03/05/2015 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 03/06/2015 1734 BWS 69383 1 (Bicarbonate ) SM 2320B-2011 1 03/06/2015 1734 BWS 03/06/2015 1734 1 (Carbonate Al) SM 2320B-2011 1 03/06/2015 1734 BWS 03/06/2015 1734 CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 ND 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 11 of 18 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane Client: Duke Energy Laboratory ID: QC05039-004 Description: 20152006062 Matrix: Aqueous Date Sampled:03/02/2015 1715 Date Received:03/05/2015 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 03/12/2015 2245 JJG 69885 CAS Analytical Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 10 ug/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 12 of 18 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals Client: Duke Energy Laboratory ID: QC05039-006 Description: 20152006070 Matrix: Aqueous Date Sampled:03/03/2015 0905 Date Received:03/05/2015 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 03/06/2015 1752 BWS 69383 1 (Bicarbonate ) SM 2320B-2011 1 03/06/2015 1752 BWS 03/06/2015 1752 1 (Carbonate Al) SM 2320B-2011 1 03/06/2015 1752 BWS 03/06/2015 1752 CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 36 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 36 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 13 of 18 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane Client: Duke Energy Laboratory ID: QC05039-006 Description: 20152006070 Matrix: Aqueous Date Sampled:03/03/2015 0905 Date Received:03/05/2015 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 03/13/2015 2034 DCS 69938 CAS Analytical Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 24 10 ug/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 14 of 18 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals Client: Duke Energy Laboratory ID: QC05039-007 Description: 20152006071 Matrix: Aqueous Date Sampled:03/03/2015 1148 Date Received:03/05/2015 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 03/06/2015 1827 BWS 69407 1 (Bicarbonate ) SM 2320B-2011 1 03/06/2015 1827 BWS 03/06/2015 1827 1 (Carbonate Al) SM 2320B-2011 1 03/06/2015 1827 BWS 03/06/2015 1827 CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 43 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 43 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 15 of 18 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane Client: Duke Energy Laboratory ID: QC05039-007 Description: 20152006071 Matrix: Aqueous Date Sampled:03/03/2015 1148 Date Received:03/05/2015 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 03/15/2015 1345 JJG 70039 CAS Analytical Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 10 ug/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 16 of 18 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals Client: Duke Energy Laboratory ID: QC05039-008 Description: 20152006072 Matrix: Aqueous Date Sampled:03/03/2015 1242 Date Received:03/05/2015 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 03/06/2015 1832 BWS 69407 1 (Bicarbonate ) SM 2320B-2011 1 03/06/2015 1832 BWS 03/06/2015 1832 1 (Carbonate Al) SM 2320B-2011 1 03/06/2015 1832 BWS 03/06/2015 1832 CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 ND 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 17 of 18 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane Client: Duke Energy Laboratory ID: QC05039-008 Description: 20152006072 Matrix: Aqueous Date Sampled:03/03/2015 1242 Date Received:03/05/2015 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 03/15/2015 1513 JJG 70039 CAS Analytical Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 10 ug/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 18 of 18 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 QC Summary Shealy Environmental Services, Inc. QC Data for Lot Number: QC05039 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals - Ii Sample ID: QQ69383-001 Matrix: Aqueous Batch: 69383 Analytical Method: SM 2320B-2011 Parameter Result Q Dil PQL Units Analysis Date Alkalinity ND 1 10 mg/L 03/06/20151507 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QC05039 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals - LCS Sample ID: QQ69383-002 Matrix: Aqueous Batch: 69383 Analytical Method: SM 2320B-2011 Spike Amount Result % Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Alkalinity 100 100 1 104 90-110 03/06/20151514 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QC05039 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals - MS Sample ID: QC05039-004MS Matrix: Aqueous Batch: 69383 Analytical Method: SM 2320B-2011 Sample Spike Amount Amount Result % Rec Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Alkalinity ND 100 90 1 90 70-130 03/06/20151741 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QC05039 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals - MSD Sample ID: QC05039-004MD Matrix: Aqueous Batch: 69383 Analytical Method: SM 2320B-2011 Sample Spike Amount Amount Result % Rec % RPD Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date Alkalinity ND 100 89 1 89 0.99 70-130 20 03/06/20151747 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QC05039 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals - Ii Sample ID: QQ69407-001 Matrix: Aqueous Batch: 69407 Analytical Method: SM 2320B-2011 Parameter Result Q Dil PQL Units Analysis Date Alkalinity ND 1 10 mg/L 03/06/20151816 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QC05039 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals - LCS Sample ID: QQ69407-002 Matrix: Aqueous Batch: 69407 Analytical Method: SM 2320B-2011 Spike Amount Result % Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Alkalinity 100 100 1 100 90-110 03/06/20151822 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QC05039 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane - MB Sample ID: QQ69885-001 Matrix: Aqueous Batch: 69885 Analytical Method: RSK - 175 Parameter Result Q Dil PQL Units Analysis Date Methane ND 1 10 ug/L 03/12/2015 2230 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QC05039 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane - LCS Sample ID: QQ69885-002 Matrix: Aqueous Batch: 69885 Analytical Method: RSK - 175 Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Methane 50 45 1 90 70-130 03/12/2015 2210 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QC05039 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane - LCSD Sample ID: QQ69885-003 Matrix: Aqueous Batch: 69885 Analytical Method: RSK - 175 Spike Amount Result % Rec % RPD Parameter (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date Methane 50 51 1 101 12 70-130 30 03/12/2015 2156 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QC05039 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane - MB Sample ID: QQ69938-001 Matrix: Aqueous Batch:69938 Analytical Method: RSK - 175 Parameter Result Q Dil PQL Units Analysis Date Methane ND 1 10 ug/L 03/13/20151111 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QC05039 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane - LCS Sample ID: QQ69938-002 Matrix: Aqueous Batch:69938 Analytical Method: RSK - 175 Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Methane 50 57 1 112 70-130 03/13/20151049 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QC05039 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane - LCSD Sample ID: QQ69938-003 Matrix: Aqueous Batch:69938 Analytical Method: RSK - 175 Spike Amount Result % Rec % RPD Parameter (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date Methane 50 60 1 118 5.3 70-130 30 03/13/20151059 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QC05039 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane - MB Sample ID: QQ70039-001 Matrix: Aqueous Batch: 70039 Analytical Method: RSK - 175 Parameter Result Q Dil PQL Units Analysis Date Methane ND 1 10 ug/L 03/15/20151129 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QC05039 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane - LCS Sample ID: QQ70039-002 Matrix: Aqueous Batch: 70039 Analytical Method: RSK - 175 Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Methane 50 48 1 96 70-130 03/15/20151034 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QC05039 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane - LCSD Sample ID: QQ70039-003 Matrix: Aqueous Batch: 70039 Analytical Method: RSK - 175 Spike Amount Result % Rec % RPD Parameter (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date Methane 50 46 1 90 6.0 70-130 30 03/15/20151052 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QC05039 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. CY TF� IW�8 -0004�010 l�llm� one IMIN ON memo 103. Now Emmons 01��111111G� man MCI �o�ooi� ��iiiiiii�' OCCC�O��IIMEN II��G� EMINMEME MEN k 11 Q Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. Shealy Envirac.monta[Scrvio s:Inc. Doeumenl Numhei F-AD-016 Rerisioil Number. 16 Sample Receipt Cheuklis# (SRQ page i 4,i1'1 Rep aces Dazt. 0TA 5V31 i:tF �tr c Dale' 11+�1114 Client: _ Cooler Inspected try/date �,r��- �Ir� �� Lot #: Means of ruacipl SESI ❑ Client ❑ Ll1Y5 El FedEx (I Airborne Exls ❑ Other Yes No 1- Were custody seals present on the cooler? Yes ❑ No U I NA a 1 2- If custudy seals were presAml, ware they intact and unbroken? Cooler ID 0riginall temperature upon receipt/Derived (corremed) temperature Upon rtctipt: -- f %.'�rf 1.-31-oC f f _ 4 11 + VC I f � Method- L '-lremperntare F3I0r1k ❑ Against Bottles 1R C">ran TU 44 IR Gun �:grrcotkon Factor. 12, .C!&°C Nfuthod rlfcoolant: 2:) et Ice 0 Blue Icy LJ Dry I-ce None 'des ❑ No ❑ NAZ 3. If tetnperaturr of any coolcr cxcccdcd 6,0'C, was Project Manager notified? PM notified by 5RC, phone, nQtc (circle one), other. (For coolers received via cornmeraial Couricr, PMs are to he notified Vrs ❑ No ❑ NA 4. is The commercial courier's packing slip attached to th.IS term? Yes No ❑ IIA;crc prupur cwdudy procedures (relin uishe&received) followed? Yes No ❑ NA 5a L"Verre samples relinquished by client to commercial courier? — Ycs No ❑ 6. Were sarn le IDS lasted Oil the COC7 Yes No ❑ 7� Wera sarnp le, IDs 1istud on a]I saWle containers? Yes :vu ® a. Was collection date &time listed on the COC? Yes No ] u. 9. Was collcuicrn Bata & tirm lick d can all sEmn& �Epntainers? Yes No ❑ 10. Did all container label informaliion 11) datetime a ee with the COC'? Yes No Ell 1 - Were tests to be performed listed on the coc,? Yes No ❑ 12. Did a]I sm les arrive iTt the proper containers for each test`.' Yes Z No ❑ 13. Did a]I containers ar 5ve in.good condition [unbra cn, lids on, etc,)? Yes Nis ❑ 14, Was adequate sate le volume available? Ycs No 15, Were all sample-. received within 1/z the holding lima or .48 }yours: �.w�h clie�.e- cremes first? 16. Were any samples containers missing? Yes ❑ No Cri yes No 17. Were there any excess sale legs not listed on COO Yes ❑ I No NA ❑ 1 R- Were bubbles present >" ea -size" lW'or 6trnm in diamctur in an VOA viaW Yes ❑ No ❑ NA Fer 19. Wcm all rnvtals./0&G1FffiNVipu6unt samples received at a pH of <7 Yes ❑ No ❑ NA 20. Were all cq anide andior sulfide samples received at a pH >12? Yts ❑ Nu ❑ NA 21. Wert, all applicable N 3ITKN/cyanidelphennl (<0.2m,9fL) sampleg free of � residual. chlorine? I Ycs No ❑ NA 22.4dcrc collation tcrriperaturcs documented on the COC for LAIC earn lee? Yes ❑ No ❑ NA 23. Were clienTremarks/regaeslts (i.e. requested dilutions, %eMSD designations, l etc..,) con=tly transcribed. from The COC into the coinmeut section in LIMS? Yes ❑ I Na Z 24, Was the quotp, number used taken from the container label? Sample Preservation (Must be completed for any samples) ittcot'rectly prescrvcd or with hea&PS c,) Sample(s) were received inuarrecIly pre9erved and were adjusted accordingly in sample receiving with (Fiz54r,tiN ,HCrIY'�Ia+ N) using SR # :Saar le s ,wcm rweived with bubbles �16 mm in diatrtetter. Sam le s were received wiIh TRC: >0-� mz!L ([f#2l is No SC [Drinking Waler P°rJ ct Sarnple(s) pH verified tQ be> 2 by Date: _ Sant le(s) were not received at pH of<2 and were adjusted ar-cordinEly Ai SR# SB�it lc labels applied b; : `-,_ Verified by. ' — Date, Ccurnmcnts: Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Alt 0` 0 OG I 0('7 00 0?o \(- 0710 073, CHAIN OF CUSTODY RECORD AND A Duke Energy Duke Energy Analytical Laboratory Analyst Mall CW. MG03A2 (euaaing 7405) , .jOrder SO � � MatrlX Analytical Laboratory 13339 Hag— FerryRd it Chain of Custody & Huntersvllle, N. C. 2w7a I'-°ae'd By Dab & Time 9 R3b1 oa) b755 Sample Log Faa: L70a) e7sso�s __ �s rt Nr^• Groundwater Assessment Phg1f fd ' 'Vww V Shealy Faa No: int �// / 980-875 032 j7t` Lr PO# 1115153 n(0'4s' prowsa: R••P•csmsr To: mess Unit: reserva It ID: acapay ID: xus CaN: Element 1 olume (I MG03A3 Wily: slate— Pll 114?133 tainerT LYSIS_ REQUEST FORM a—..... Use On.--._._.-'-'-'-'_'-'-'_'_'_'_'_'------- borato ly NO aanpisr Onpins0np F— — g`,— ZL SAMPLE PROGRAM Ground Water NPDES _ Drinklne Water_ UST_ RCRA Waste _ :�_.._.._. .............. .._.._........................... ..-.._.._.._.. b Unfiltered Ice lea lead lee 2000 40 ml 300 125 Soo SW PET p18s3 PET I PET PET I PET Page _1_of_1_ Page 62 of 62 DISTRIBUTION ORIGINAL to LAB, COPY to CLIENT COC REV DATE 1/22/2015 .a rltered HDPEIHDPE r a• a s r e law ■■0©e�i■o/A■ ■oa 0 r � ©■■n© e ■■m■■i■om o ■■■ilool IN ■■i■M■■i■n o IN IMMIN n �al ■■o©oa■io ■ M o 0■■�■ r� ■■ ■■■i■■n o �■ ■■■■■■■■■■■■■■■0 �■ ■■■■■■ ■■■0 - �■ ■■■■■■ IN �■ ■■■■■■■■■■■ OEM ■■0 .�■ 101001■■■■■■ ■■■M0 ■� .�■■■■■■■■■■■■_■■■■�■iI' ■o ■■ gym■■■ ■■■ MEM ■�■■■■■own ■■■■r�A ■■■i ■■■■EMININ si■■i■■own ■■� .: ■■ ■■ iMEMMMONN-01 low no ME 1 Aatemme art rem r 3/`1 /� ZL Relinquished By Y, at M. ADtm B ' Daternme ELEMENTS by ICP MS (Digested-TRM): As, Be, Cd, Co, Cr, Cu, IAo, Ni, Pb, Sb, Se (CRC Method) TI (low level)V (low level) ELEMENTS by ICP (Digested Til Al, Ba, B, Fe, Mn, Sr, Zn ICP_Undigested Ca, Mg, K, Na Dissolved metals: Speciation: Relinguished BY Date/Time: Re Receivived By: FF CSC. Date/Time: Requested Turnaround Total 14 E m v '14 Days m C 3 CL E 7 Days c Q a 48 Hr E 'n - m �v m E 0 "Other _ASAP �+ 3 "Add. Cost Will Apply U