NC0003417_J15060476F_Speciation_20150805

+ DUKE Analytical Laboratory
ENERGY
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone:[phone] Fax:[phone]
Order Summary Report
Order Number: J15060476
Project Name: HF LEE PLANT - AB GW ASSESSMENT SPECIATION
Customer Name(s): Tim Hunsucker, Judd Mahan, Kathy Webb, John Toepfer
Customer Address: 1677 Old Smithfield Rd
Goldsboro NC 27530,
Lab Contact: Peggy Kendall Ph
peggy.kendall@a ne:
Report Authorized B uke-energy.com
a vc Q_ dot, Date:
(Signature) 2015_07_01
Peggy Kendall 12:22:14-04'00'
Program Comments:
Please contact the Program Manager (Peggy Kendall) with any questions regarding this report.
Data Flags & Calculations:
7/1 /2015
Page 1 of 32
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Sample ID's & Descriptions:
Collection
Sample ID Plant/Station Date and Time
Collected By
Sample Description
2015019302
HF LEE PLANT
10-Jun-15 10:25 AM
Synterra
IABMW-3S
2015019303
HF LEE PLANT
10-Jun-15 1:05 PM
Synterra
IABMW-2S
2015019304
HF LEE PLANT
10-Jun-15 3:22 PM
Synterra
AMW-13S
2015019305
HF LEE PLANT
10-Jun-15 4:00 PM
Synterra
AMW-13BC
2015019306
HF LEE PLANT
10-Jun-15 11:05 AM
Synterra
IABMW-15
2015019307
HF LEE PLANT
10-Jun-15 10:30 AM
Synterra
IABMW-1
2015019308
HF LEE PLANT
10-Jun-15 4:53 PM
Synterra
AMW-12S
2015019309
HF LEE PLANT
10-Jun-15 3:41 PM
Synterra
AMW-12BC
8 Total Samples
Page 2 of 32

Page 3 of 32
Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals Yes No
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits. ❑ Yes❑ No
All laboratory QA/QC requirements are acceptable.❑ Yes ❑ No
Report Sections Included:
U Job Summary Report
❑ Sample Identification
n Technical Validation of Data Package
❑ Analytical Laboratory Certificate of Analysis
❑ Analytical Laboratory QC Report
Sub -contracted Laboratory Results
❑ Customer Specific Data Sheets, Reports, & Documentation
❑ Customer Database Entries
66 Chain of Custody
[I/0] Electronic Data Deliverable (EDD) Sent Separately
Reviewed By: Peggy Kendall Date: 7/1/2015

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060476
Site: IABMW-3S
Collection Date: 10-Jun-15 10:25 AM
Analyte Result Units Qualifiers RDL DF
Speciation of an Element - (Analysis Performed by Brooks Rand Labs LLC)
Vendor Parameter Complete
Sample #: 2015019302
Matrix: GW WW
Page 4 of 32
Method Analysis Date/Time Analyst
Vendor Method V_BRAND

Certificate of Laboratory Analysis Page 5 of 32
This report shall not be reproduced, except in full.
Order # J15060476
Site: IABMW-2S
Collection Date: 10-Jun-15 1:05 PM
Analyte Result Units Qualifiers RDL DF
Speciation of an Element - (Analysis Performed by Brooks Rand Labs LLC)
Vendor Parameter Complete
Sample #: 2015019303
Matrix: GW WW
Method Analysis Date/Time Analyst
Vendor Method V_BRAND

Certificate of Laboratory Analysis Page 6 of 32
This report shall not be reproduced, except in full.
Order # J15060476
Site: AMW-13S
Collection Date: 10-Jun-15 3:22 PM
Analyte Result Units Qualifiers RDL DF
Speciation of an Element - (Analysis Performed by Brooks Rand Labs LLC)
Vendor Parameter Complete
Sample #: 2015019304
Matrix: GW WW
Method Analysis Date/Time Analyst
Vendor Method V_BRAND

Certificate of Laboratory Analysis Page 7 of 32
This report shall not be reproduced, except in full.
Order # J15060476
Site: AMW-13BC
Collection Date: 10-Jun-15 4:00 PM
Analyte Result Units Qualifiers RDL DF
Speciation of an Element - (Analysis Performed by Brooks Rand Labs LLC)
Vendor Parameter Complete
Sample #: 2015019305
Matrix: GW WW
Method Analysis Date/Time Analyst
Vendor Method V_BRAND

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060476
Site: IABMW-15
Collection Date: 10-Jun-15 11:05 AM
Analyte Result Units Qualifiers RDL DF
Speciation of an Element - (Analysis Performed by Brooks Rand Labs LLC)
Vendor Parameter Complete
Sample #: 2015019306
Matrix: GW WW
Page 8 of 32
Method Analysis Date/Time Analyst
Vendor Method V_BRAND

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060476
Site: IABMW-1
Collection Date: 10-Jun-15 10:30 AM
Analyte Result Units Qualifiers RDL DF
Speciation of an Element - (Analysis Performed by Brooks Rand Labs LLC)
Vendor Parameter Complete
Sample #: 2015019307
Matrix: GW WW
Page 9 of 32
Method Analysis Date/Time Analyst
Vendor Method V_BRAND

Certificate of Laboratory Analysis Page 10 of 32
This report shall not be reproduced, except in full.
Order # J15060476
Site: AMW-12S
Collection Date: 10-Jun-15 4:53 PM
Analyte Result Units Qualifiers RDL DF
Speciation of an Element - (Analysis Performed by Brooks Rand Labs LLC)
Vendor Parameter Complete
Sample #: 2015019308
Matrix: GW WW
Method Analysis Date/Time Analyst
Vendor Method V_BRAND

Certificate of Laboratory Analysis Page 11 of 32
This report shall not be reproduced, except in full.
Order # J15060476
Site: AMW-12BC
Collection Date: 10-Jun-15 3:41 PM
Analyte Result Units Qualifiers RDL DF
Speciation of an Element - (Analysis Performed by Brooks Rand Labs LLC)
Vendor Parameter Complete
Sample #: 2015019309
Matrix: GW WW
Method Analysis Date/Time Analyst
Vendor Method V_BRAND

Page 12 of 32
BRO�©KS
RAND
LABS
MEANINGFUL METALS DATA
June 30, 2015
Jay Perkins
Duke Energy Analytical Laboratory
Mail Code MGO3A2 (Building 7405)
13339 Hagers Ferry Rd.
Huntersville, NC 28078
[phone]
Project: Duke HF Lee Plant (LIMS# J15060476)
Mr. Perkins,
Attached is the report associated with eight (8) aqueous samples submitted for arsenic speciation,
iron speciation, and manganese speciation analyses on June 10, 2015. The samples were
received in a sealed cooler at 1.0°C on June 11, 2015. All samples requesting iron speciation
analysis were analyzed by spectrophotometry. Mn (II) analysis was performed via IC-ICP-CRC-
MS. Mn(IV) analysis were performed via digestion and subsequent analysis by inductively
coupled plasma triple quadrupole mass spectrometry (ICP-QQQ-MS). Any issues associated
with the analyses are addressed in the following report.
If you have any questions, please feel free to contact me at your convenience.
Sincerely,
Russell Gerads
Business Development Director
Brooks Rand Labs, LLC
3958 6th Ave NW • Seattle, WA 98107 • T: 206-632-6206 • F: 206-632-6017 • www.brooksrand.com • [e-mail]

Page 13 of 32
Brooks Rand Labs, LLC
Report prepared for:
Jay Perkins
Duke Energy Analytical Laboratory
Mail Code MGO3A2 (Building 7405)
13339 Hagers Ferry Rd.
Huntersville, NC 28078
Project: Duke HF Lee Plant (LIMS# J15060476)
June 30, 2015
1. Sample Reception
Eight (8) aqueous samples were submitted for arsenic speciation, iron speciation, and
manganese speciation analyses on June 10, 2015. All samples were received in acceptable
condition on June 11, 2015 in a sealed container at 1.0°C.
All samples were received in a laminar flow clean hood, void of trace metals contamination
and ultra -violet radiation, and were designated discrete sample identifiers. An aliquot of
each sample submitted for arsenic speciation analysis was filtered (0.45µm) into a
polypropylene centrifuge tube; all filtrates and original bottles were then stored in a secure,
monitored refrigerator (maintained at a temperature of <6°C) until the analyses could be
performed.
The sample fractions requesting iron speciation analysis were stored in a secure, monitored
refrigerator (maintained at a temperature of <6°C) until the analyses could be performed.
An aliquot of each filtered sample submitted for manganese speciation analysis was decanted
into a polypropylene centrifuge tube for Mn(II) analysis. These fractions were stored in a
secure, monitored refrigerator (maintained at a temperature of <6°C) until the analyses could
be performed. Subsequently, the original bottles (filtered and unfiltered fractions) intended
for Mn speciation were preserved to pH < 2 with concentrated HNO3 and then stored in a
secure polyethylene container, known to be free from trace metals contamination, until the
digestion could be performed.
2. Sample Preparation
All sample preparation is performed in laminar flow clean hoods known to be free from trace
metals contamination. All applied water for dilutions and sample preservatives are
monitored for contamination to account for any biases associated with the sample results.

Page 14 of 32
Arsenic Speciation Analysis by IC-ICP-CRC-MS An aliquot of each sample was filtered
directly into a sealed autosampler vial. No further sample preparation was performed as a
buffered EDTA solution was provided by Brooks Rand Labs for field -preservation of the
submitted samples.
Iron Speciation Anal sy is by Spectrophotometry No sample preparation was required as a de -
gassed HCL solution was provided by Brooks Rand Labs for field -preservation of the
submitted samples.
Manganese Mn(II) Analysis by IC-ICP-CRC-MS An aliquot of each sample was filtered
(0.45µm) directly into an autosampler vial for Mn(II) analysis. No additional sample
preparation was performed as any chemical alteration of the samples may shift the
equilibrium of the system resulting in changes in speciation ratios.
Manganese Mn(IV) Analysis by ICP-Q0Q-MS Each filtered and unfiltered sample submitted
for Mn speciation analysis was preserved with 1 % HNO3 (v/v) upon sample receipt. Each
sample fraction was then further digested on a hotblock apparatus with aliquots of 50%
HNO3 (v/v) and 50% HCl (v/v), in accordance with the digestion procedure specified in EPA
Method 200.8. All resulting sample digests were analyzed for total manganese via
inductively coupled plasma triple quadrupole mass spectrometry (ICP-QQQ-MS).
3. Sample Analysis
All sample analysis is preceded by a minimum of a five -point calibration curve spanning the
entire concentration range of interest. Calibration curves are performed at the beginning of
each analytical day. All calibration curves, associated with each species of interest, are
standardized by linear regression resulting in a response factor. All sample results are
instrument blank corrected to account for any operational biases associated with the
analytical platform.
Prior to sample analysis, all calibration curves are verified using second source standards
which are identified as initial calibration verification standards (ICV).
Ongoing instrument performance is identified by the analysis of continuing calibration
verification standards (CCV) and continuing calibration blanks (CCB) at a minimum interval
of every ten analytical runs.
Arsenic Speciation Analysis by IC-ICP-CRC-MS Each sample was analyzed for arsenic
speciation via ion chromatography inductively coupled plasma collision reaction cell mass
spectrometry (IC-ICP-CRC-MS) on June 26, 2015. Aliquots of each sample are injected
onto an anion exchange column and eluted isocratically. The eluting arsenic species are then
introduced into a radio frequency (RF) plasma where energy -transfer processes cause
desolvation, atomization, and ionization. The ions are extracted from the plasma through a
differentially -pumped vacuum interface and travel through a pressurized chamber (CRC)
containing a specific collision gas. Polyatomic interferences, due to their inherently larger
size, collide more frequently with the collision gas and therefore may be separated from the
analyte of interest via kinetic energy discrimination (KED). A solid-state detector detects

Page 15 of 32
ions transmitted through the mass analyzer on the basis of their mass -to -charge ratio (m/z),
and the resulting current is processed by a data handling system.
Retention times for each eluting species are compared to known standards for species
identification.
Iron speciation Analysis by Spectrophotometry All samples submitted for Fe speciation
quantification were analyzed on June 11, 2015, and in accordance with the scientifically
accepted method outlined by:
Stookey, L.L., (1970). "Ferrozine - A new spectrophotometric reagent for iron",
Anal.Chem., 42:779-81.
Manganese Mn(LI) Analysis by IC-ICP-CRC-MS All samples for Mn(II) analysis were
analyzed by ion chromatography inductively coupled plasma collision reaction cell mass
spectrometry (IC-ICP-CRC-MS) on June 17, 2015. Aliquots of each sample are injected
onto an anion exchange column and mobilized by an acidic (pH < 7) gradient. An ion
pairing agent provides a dynamic ion exchange mechanism for the cationic manganese
species on the chromatographic column. The differences in the affinity of manganese species
towards the ion pair agent and the column results in separation. The eluting selenium species
are then introduced into a radio frequency (RF) plasma where energy -transfer processes
cause desolvation, atomization, and ionization. The ions are extracted from the plasma
through a differentially -pumped vacuum interface and travel through a pressurized chamber
(CRC) containing a reaction gas which preferentially reacts with interfering ions of the same
target mass to charge ratios (m/z). A solid-state detector detects ions transmitted through the
mass analyzer and the resulting current is processed by a data handling system.
Retention times for each eluting species are compared to known standards for species
identification.
Manganese Mn(I ' Analysis by ICP-QQQ-MS All samples submitted for Mn speciation
quantitation were analyzed by inductively coupled plasma triple quadrupole mass
spectrometry (ICP-QQQ-MS) on June 23, 2015. Aliquots of each sample digest are
introduced into a radio frequency (RF) plasma where energy -transfer processes cause
desolvation, atomization, and ionization. The ions are extracted from the plasma through a
differentially -pumped vacuum interface and travel through an initial quadrupole (Q1), which
filters the target masses prior to their entrance into a second chamber. The second chamber
contains specific reactive gasses or collision gasses that preferentially react either with
interfering ions of the same target mass to charge ratios (m/z) or with the target analyte,
producing an entirely different mass to charge ratio (m/z) which can then be differentiated
from the initial interferences. The ions then exit the collision/reaction cell into and additional
quadrupole (Q2). A solid-state detector detects ions transmitted through the mass analyzer,
on the basis of their mass -to -charge ratio (m/z), and the resulting current is processed by a
data handling system.

Page 16 of 32
4. Analytical Issues
No significant analytical issues were encountered. All quality control parameters associated
with the samples were within acceptance limits.
Unknown arsenic species were present in various samples associated with the arsenic
speciation analysis resulting in late elution into following sample injections. The late eluting
peaks did not affect the target arsenic species; however, differentiation between late eluting
peaks and other unknown arsenic species for a given sample could not be accomplished.
Mn(IV) is quantified by analyzing the water samples for total Mn and dissolved Mn. Mn(IV)
is operationally defined as the difference between the filtered and unfiltered total Mn
concentrations, since it is thermodynamically favored to be in the form of a precipitate.
The eMDL values for arsenite, arsenate, and dimethylarsinic acid are generated using the
standard deviation of replicate analyses of the lowest standard in the calibration curve. The
eMDL for monomethylarsonic acid is calculated from the average eMDL of the three arsenic
species contained in the calibration (i.e., arsenite, arsenate, and dimethylarsinic acid); the
calibration and CCVs do not contain monomethylarsonic acid due to impurities in this
standard which would bias the results for other arsenic species.
The eMDL value for Fe(II) has been generated from replicate analyses of the lowest standard
in the calibration curve. The eMDL value for total recoverable Fe was set at 1/3 the value of
the associated reporting limit since the standard deviation associated with the replicate
analyses of the lowest standard in the calibration curve was zero.
The eMDL for Mn(II) has been generated from replicate analyses of the lowest standard in
the calibration curve.
The eMDL values for Mn(IV) been calculated using the standard deviation of the method
blanks prepared and analyzed concurrently with the submitted samples.
If you have any questions or concerns regarding this report, please feel free to contact me.
Sincerely,
Russell Gerads
Business Development Director
Brooks Rand Labs, LLC

Page 17 of 32
Speciation Results for Duke Energy
Project Name: Duke HF Lee Plant
Contact: Jay Perkins
LIMS# J15060476
Date: June 30, 2015
Report Generated by: Russell Gerads
Brooks Rand Labs, LLC
Sample Results (2)
Unknown As
Sample ID
As(III)
As(V)
MMAs
DMAs
Species
IABMW-3S
2.10
1.30
ND (<0.053)
ND (<0.083)
NA
IABMW-2S
3.54
0.970
ND (<0.053)
ND (<0.083)
NA
AMW-13S
ND (<0.049)
ND (<0.028)
ND (<0.053)
ND (<0.083)
NA
AMW-13SBC
0.544
ND (<0.028)
ND (<0.053)
ND (<0.083)
NA
IABMW-15
1.03
0.486
ND (<0.053)
ND (<0.083)
NA
IABMW-1
20.5
2.66
ND (<0.053)
ND (<0.083)
NA
AMW-12S
ND (<0.049)
ND (<0.028)
ND (<0.053)
ND (<0.083)
NA
AMW-12BC
0.352
0.116
ND (<0.053)
ND (<0.083)
NA
All results reflect the applied dilution and are reported in pg/L
ND = Not detected at the applied dilution
MMAs = monomethylarsonic acid
DMAs = dimethylarsinic acid
Unknown As Species = Total concentration of all unknown As species observed by IC-ICP-MS
NA = Not available. Please see narrative.

Page 18 of 32
Speciation Results for Duke Energy
Project Name: Duke HF Lee Plant
Contact: Jay Perkins
LIMS# J15060476
Date: June 30, 2015
Report Generated by: Russell Gerads
Brooks Rand Labs, LLC
Sample Results (3
Sample ID
Fe(II)
Fe(III)*
Mn (II)
Mn(IV)**
IABMW-3S
54500
1450
1280
8.82
IABMW-2S
25000
ND (<500)
1560
ND (<0.16)
AMW-13S
11
7
25.5
ND (<0.16)
AMW-13BC
10000
527
102
1.49
IABMW-15
46400
2910
5500
259
IABMW-1
6090
517
534
ND (<0.16)
AMW-12S
9
ND (<5)
20.6
1.82
AMW-12BC
11600
270
278
10.7
All results reflect the applied dilution and are reported in pg/L
ND = Not detected at the applied dilution
NR = Analysis not requested
*Fe(III) operationally defined as the difference between total recoverable Fe and Fe(II)
*Mn(IV) operationally defined as the difference between total and dissolved Mn

Page 19 of 32
Speciation Results for Duke Energy
Project Name: Duke HF Lee Plant
Contact: Jay Perkins
LIMS# J15060476
Date: June 30, 2015
Report Generated by: Russell Gerads
Brooks Rand Labs, LLC
Qualitv Control Summary - Preparation Blank Summary (2
Analyte (Ng/L)
PBW1
PBW2
PBW3
PBW4
Mean
StdDev
eMDL*
eMDL 10x
RL 10x
As(III)
0.000
0.000
0.000
0.000
0.000
0.000
0.005
0.049
0.20
As(V)
0.000
0.000
0.000
0.000
0.000
0.000
0.003
0.028
0.20
MMAs
0.000
0.000
0.000
0.000
0.000
0.000
0.005
0.053
0.20
DMAs
0.000
0.000
0.000
0.000
0.000
0.000
0.008
0.083
0.21
eMDL = Estimated Method Detection Limit; RL = Reporting Limit
*Please see narrative regarding eMDL calculations

Page 20 of 32
Speciation Results for Duke Energy
Project Name: Duke HF Lee Plant
Contact: Jay Perkins
LIMS# J15060476
Date: June 30, 2015
Report Generated by: Russell Gerads
Brooks Rand Labs, LLC
Quality Control Summary - Preparation Blank Summary (3
Analyte (Ng/L) PBW1 PBW2 PBW3 PBW4
Mean
StdDev
eMDL**
eMDL 1x
RL 1x
eMDL 2x
RL 2x
Fe(II) 0.0 -2.3 -2.3 -2.3
-1.7
1.1
3.6
3.6
20
10
40
Total Fe -2.2 -2.2 -2.2 -2.2
-2.2
0.0
6.7
6.7
20
10
40
eMDL = Estimated Method Detection Limit; RL = Reporting Limit
**Please see narrative regarding eMDL calculations
Quality Control Summary - Preparation Blank Summary
(3)
Analyte (pg/L) PBW1 PBW2 PBW3 PBW4
Mean
StdDev
eMDL*
eMDL 10x
RL 10x
eMDL 25x
RL 25x
Mn (ll) -0.21 0.08 -0.13 -0.15
-0.09
0.12
0.091
0.91
5.0
-
-
Total Mn 0.068 0.030 -0.047 0.063
0.017
0.053
0.006
-
-
0.16
1.0
Diss Mn -0.144 -0.115 -0.051 -0.064
-0.103
0.044
0.005
-
-
0.13
1.0
eMDL = Estimated Method Detection Limit; RL = Reporting Limit
*Please see narrative regarding eMDL calculations
***Preparation blank is a statistical outlier according to the Grubb's Test. Please see narrative.

Page 21 of 32
Speciation Results for Duke Energy
Project Name: Duke HF Lee Plant
Contact: Jay Perkins
LIMS# J15060476
Date: June 30, 2015
Report Generated by: Russell Gerads
Brooks Rand Labs, LLC
Quality Control Summary - Certified Reference Materials (2
Analyte (Ng/L)
CRM
True Value
Result
Recovery
As(III)
LCS
5.00
5.043
100.9
As(V)
LCS
5.00
4.581
91.6
MMAs
LCS
5.07
5.732
113.0
DMAs
LCS
3.63
3.509
96.8
Quality Control Summary
- Certified Reference Materials (3)
Analyte (pg/L)
CRM
True Value
Result
Recovery
Fe(II)
ICV
500.0
509.1
101.8
Total Fe
LCS
500.0
497.2
99.4
Mn (II)
LCS
10.00
10.85
108.5
Total Mn
TMDA-70.2
312
276.9
88.8
Diss Mn
TMDA-70.2
312
325.8
104.4

Page 22 of 32
Speciation Results for Duke Energy
Project Name: Duke HF Lee Plant
Contact: Jay Perkins
LIMS# J15060476
Date: June 30, 2015
Report Generated by: Russell Gerads
Brooks Rand Labs, LLC
Quality Control Summary - Matrix Duplicates (2)
Analyte (pg/L)
Sample ID
Rep 1
Rep 2
Mean
RPD
As(III)
AMW-12BC
0.352
0.411
0.382
15.6
As(V)
AMW-12BC
0.116
0.123
0.120
6.0
MMAs
AMW-12BC
ND (<0.053)
ND (<0.053)
NC
NC
DMAs
AMW-12BC
ND (<0.083)
ND (<0.083)
NC
NC
ND = Not detected at the applied dilution
NC = Value was not calculated due to one or more concentrations below the eMDL

Page 23 of 32
Speciation Results for Duke Energy
Project Name: Duke HF Lee Plant
Contact: Jay Perkins
LIMS# J15060476
Date: June 30, 2015
Report Generated by: Russell Gerads
Brooks Rand Labs, LLC
Qualitv Control Summary - Matrix Duplicates (3
Analyte (pg/L)
Sample ID
Rep 1
Rep 2
Mean
RPD
Fe(II)
Batch QC
24890
24550
24720
1.4
Total Fe
Batch QC
56000
58230
57115
3.9
Mn (II)
AMW-13S
25.50
25.19
25.35
1.2
Total Mn
Batch QC
34.68
33.43
34.05
3.7
Diss Mn
Batch QC
15.91
16.43
16.17
3.2

Page 24 of 32
Speciation Results for Duke Energy
Project Name: Duke HF Lee Plant
Contact: Jay Perkins
LIMS# J15060476
Date: June 30, 2015
Report Generated by: Russell Gerads
Brooks Rand Labs, LLC
Quality Control Summary - Matrix Spike/Matrix Spike Duplicate (2)
Analyte (lag/L)
Sample ID
Spike Conc
MS Result
Recovery
Spike Conc
MSD Result
Recovery
RPD
As(III)
AMW-12BC
20.00
19.31
96.5
20.00
19.69
98.5
2.0
As(V)
AMW-12BC
20.00
18.97
94.9
20.00
19.37
96.8
2.1
DMAs
AMW-12BC
20.98
19.33
92.1
20.98
19.40
92.4
0.4
Qualitv Control Summary - Matrix Spike/Matrix Spike Duplicate (3
Analyte (lag/L)
Sample ID
Spike Conc
MS Result
Recovery
Spike Conc
MSD Result
Recovery
RPD
Fe(II)
Batch QC
25000
50230
102.0
25000
49210
98.0
2.1
Total Fe
Batch QC
100000
150100
93.0
100000
148700
91.6
0.9
Mn (II)
AMW-13S
50.00
80.07
109.5
50.00
80.26
109.8
0.8
Total Mn
Batch QC
1000
875.1
84.1
1000
1063
102.9
19.4
Diss Mn
Batch QC
1000
1003
98.7
1000
1026
101.0
2.3

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18804 \onhcreek I'arkwav Phpiiiq (4�"�.'i�f4�3'3-33CN1
Bothell, WA 98011 Fax [phone]
(:,m �amTcn�a
'tiaa mct Svti
BRL Project Am 1ana er: erev itlaute
(,Owat i Person:
h6chard )atobs
By subruttingof samples the client agrees to all terns and conditons ser forth
in the quotation provided by the BRL project manager. If you are not familiar
with the term and conditions associated with your project, please contact tour
BRL representative as soon as ossible [phone].
lsh<;ss148 Rixrr tit. 22H
6 cc„vilk•, �(; 21N)OI
P11(wic Numher: 864 .431) 1 45;
I ;ix \umber:
Requested Turn .bound Time:
Ftreui Address:
Method of Sample Deliverv:
Prujrct Name:
I 1 i.ce
Courier Tracking Dumber:
Pr,, cct \u nbm
Confirmation of Sample Reception: � Yes ® NO
P( ) Nunnhci: 12I-608
s nipic 11)
Bottle 11)
Date and me
Matrix+
Volume
Presenative
Initials
Requested Analytes and Methods
Comments
4L _ 3
♦
r z
_ �; •} I
';_�g
EDTA - 1
As Spec
field filtered
_
NH4OH/NH4SO4
De assed HCI
None
_...__r�
None
—_—Cr�VI)_ —
field filtered
field filtered
�v Fe Spec— _
;
Mn Spec -- _ --
Mn Spec _— --
field filtered
unfiltered
None
Se Spec —
field filtered
7 _
•
-1 w; <
6
-WE
,2-fT
EDTA - i
NH4OH/NH4SO4
Degassed HCI
None
None
_ T %
_
---- As Spec-- -
Cr(VI)
field filtered
field filtered
field filtered
field filtered
•
rrA
3 6`"17I
3!2 J
Fe Spec
_ Mn Spec_—_
__— _Mn Spec - -
unfiltered
field filtered
None
Se Spec
Relinquished by: (sign)
Received by (signj�
-
a�',._
>�
(print)
(print) ) c
lc -
'r
r
DatelTime: 0
Date/Time:�j (.� �1
Comments:
Temp:
shed by: (sign)
ERece,edby: (sign)
(print)_
(print)
Date/Time:Dateffime:Temp.
Comments:
P1ra�c ackwlnt for each sample bowie as a sepcniic line Item for verification purl)oscs.
\1.1+:1\ Air, i-rr>ltscatcr l \\'�, >ca�r.ttcr ,SA I cnw:11,JXk'1tr1 J AXj, sr,tstcwatcr AV'\\;...nil"I `. �cdtm nt (SD), tissue (l"S), hrodtta !P;, Wlict IO)
Re, I (April 2005)

I < 1! 1" n '43-1 "
18804 Northcreek Parkway
Bothell, WA 98011
PRage �"323-3300
Fax [phone]
Conn run' Nainci S%,n'I*crr;i
BRL Project Nana era Jereniv haute
Richard lacohs
--
By submitting of samples the client agrees to all terms and conditions set forth
in the quotation provided by the BRI, project manager. If you are not familiar
with the icrni and conditions associated with your project, please contact your
BRI., representative as soon as possible [phone].
1-18 River t. S'I'f-. 22(1
Greenville, SC 29601
Phone NUITIbM 864 430-14-96
Fax Nwnbcr:
Recju"tedTurn Around Tirric.
FAnall Adklrc>!"
Method of Sam pIc Deliver)-:
Project N.1111C.
I I F Lee
Courier Tracking Dumber:
Proicct Number
Confirmation of Sample Reception: F9 We
W 1—
U No
N ) N'linhen 1217608
Sample 11)
Bottle 11)
I)aic and 1-wic
L, t r LX
Volume
Preservative
lrutials
Requested Asialytes and Methods
Comments
A finn)
3 G-7 9 -3,
EDTA - 1
NH40H/NH4SO4
Degassed HO
As Spec
field filtered
field filtered
'70 3
Fe Sp
Spec
Mn Spec
-
Se Spec
field filtered
field filtered
unfiltered
field filtered
None
-
None
MLI-J- -31 Jsc
EDTA - 1
As Spec
field filtered
field filtered
field filtered
field filtered
unfiltered
field filtered
)3 SQXo v
t
NH40H/NH4SO4
None
None
Fe Spec
Mn Spec
Mn Spec
None
Se Spec
Relinquished by (sign)
Received by (sign):{print)Date/Time:
(print)
DaterTime:/6-/6-)-f5Z I'3o
Comments:
Temp C--
Relinquished by (sign)
Received by (sign)
(print)
(print)
Date/Time:
Date/Time:
Comments:
Temp:
Pease account 6)r cacti sample Nittle as a sepciate I ine ,tern for verification purposes -
%11- I I I �XAXi, —il (SLI, sudmictil 'Sl)), n,��uc (I'S, product t'?), other (( Yj
-w'hNk.fl"T JAY �S\\*�'Ypmlidw'lwt t;\\' ;AV';,, i
RcA 1 1 (April 21N)S,

18804 Northcreek parkway PlFGW(41Vt 93-3300
Bothell, AY'A 98011 Fax [phone]
C ,mpany ..role: '�en1 erra
BRI. Project \fana er: leremv laute
(corn a�a pctse�n:
hichard lscobs
By subnvtting of samples the client agrees to all terms and conditions set lorth
in the quotation provided be the BRL project manager. If you are not familiar
with the term and conditions associated with your project, please contact vour
BRL representative as soon as possible 425 483-3300.
lcicires>: 1.18 R!vcr St. �,TE 22o
Grccmille, 19601
Phone Number: 864-430 145.5
fax Number:
Requested Turn .bound Time:
1_.MAII address:
Method of Sample Delivery:
Pro cct ,lame:
l l F Lee
Courier Tracking Number:
prviect Number:
Confirmation of Sample Reception: Y.. N�
N) Number: 121-608
S;tntple 11�
Battle III
Date and Tune
Matrix
Volume
Preservative
Initials
Requested Analytes and Methods
Comments
,C31 ; vJ f
3 3 �'/ 7
6- ^ I
._._ �= :
_ __
_ _
s
—_. EDTA - I
_
_ As Spec
field filtered
field filtered
_ .
_,._._._..._
NH4OH/NH4SO4
_ gNassed HCI,
None - _
_ _._._ None __.
None
'
—
_. _ _
Cr�VI�
•
`� ;
- �` 0
Fe Spec
Mn Spec T _-
Mn Spec --
field filtered
1
43 S1
field filtered
unfiltered
field filtered
•
ty
Se Spec _
_ __...- _ _
—__
EDTA -_1 _ -__
NH4OH/NH4SO4
HCI
�_. None----..--,--
None __..---_-
None
.1> _
- -
_-_ ._ .
_._ As Spec.--
Cr(VI)
field filtered
field filtered
field filtered
36i `.Degassed
_ -- Fe Spec
276 19
Mn Spec-.__.�.._._
field filtered — -- -
unfiltered
field filtered
6
_ Mn Spec --
Se Spec
Relinquished by: (sign)
Received by (sign)
J
(print)
(print) !
I �... } ::_I
Dateffime: %hi %
Dateffime�� t t l u• c i.;
Comments:
Temp: / (,, ' r--
Relinquished by: (sign)
Received by (sign)
(print)
(print)
Dateffime:
Dateffime:
Comments.
Temp:
please :ircdyunt for each sample bottle as a seperate line item for verification purposes.
\t:urt� Atr, %�resh�eatrr '11� ;, scaW.itcr ;��C`j, };r„t.rnl�ratcr t(;�kj, wastewater (\V\Xj, soil ;Jl„scciiment (tiI�), a<sue (I-S}; pmdutt (P;, other jOj
Rc\- 1.1 (April 2(H)S)

1 1 C16It,r)14W- '
> �
i
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V f .-"' , -
Page 32 of 32
18804 Northcreek Parkway Phone [phone]
Bothell, VIA 98011 Fax [phone]
C n-, rangy Nance Svri Terra
BRL I'ro ect \lana ger: jereniv Maute
t tit t Yrrs�nz
Richard 1 cobs
B}- submitting of samples the client agrees to all terms and conditions set forth
in the quotation provided by the BRL project manager. If you are not familiar
with the term and conditions associated with your project, please contact your
BRL re resentative as soon as possible [phone].
Addrvv': 1,18 Rivet tit. tiTF 221 t
Grccri ilk% tit. 29w I
Phone Numhcr- 864-430 1455
F:t\ Niimhcr:
Re nested "I'tnn .Around Time:
Email address
;Method of Sample Delivery:
Project Name
H F, Ixe
Courier Trackin Number:
Project Number:
Confirmation of Sample Reception:
M Vpe No
m
PO Number: 1217608
Sample 11)
Bottle 119
Date and T ne
Nfatrix
Volume
Preservative
Initials
Requested Analytes and Methods
Comments
"R 72-
0 5
, -
j __.
EDTA_1
As Spec
field filtered
field filtered
field filtered
•
3 ��
_
NH4OH/NH4SO4
Degassed HCI
_
Cr(VI)
Fe Spec
Mn Spec
None
field filtered
None
None
Mn Spec _
Se Spec
unfiltered -
field filtered
EDTA - 1
As Spec
field filtered
field filtered
field filtered_
NH4OH/NH4SO4
— --
�'
Degassed HCI
Fe Spec
17 i
None
Mn Spec_____ ' _
_---pec_____
Mn Spec
Se Spec _ .
field filtered
_--filter
unfiltered
field filtered
•
"r '
__----
None
---
None
Relinquished by {sign)
Received by. (sign) L24-
�> .,(print) r'�_,
(print) • , c
; _ L_ k -` ..;,. % _
DatefTime. c— J 730
DatefTime: t, I Ci '-1 �"
Comments:
Temp: ( �c
Relinquished by (sign)
Received by (sign)
(print)
(print)
DatefTime:
DatefTime
Comments:
Temp:
cA1C ACCOe,,,l 10e uAcri satnp,c uoutc as a scperaie tine neat for verification purposes.
�t:uns An, I tc�hu.rn s (I 1C , :eauatcr isWi, AV°i, w:utcwatrt (Sl.}, scdnnrnt (Sl)), tisue (1'S), product (P), other (())
Rc� 1.1 (April 2(1415)