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Home My WebLink AboutNC0003417_J15060346 Report_20150805+ DUKE Analytical Laboratory ENERGY 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone:980-875-5245 Fax:980-875-4349 Order Summary Report Order Number: J15060346 Project Name: HF LEE PLANT - AB GW ASSESSMENT SOIL Customer Name(s): Tim Hunsucker, Judd Mahan, Kathy Webb, John Toepfer Customer Address: 1677 Old Smithfield Rd Goldsboro NC 27530, Lab Contact: Margaret Galvin -Karr Phone: 980-875-5219 MXG4644 (101161) Report Authorized By: " 2015.06.24 06:45:01 Date: (Signature)-04'00' Margaret Galvin -Karr Program Comments: Please contact the Program Manager (Margaret Galvin -Karr) with any questions regarding this report. Data Flags & Calculations: 6/20/2015 1 of 60 Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Sample ID's & Descriptions: Collection Sample ID Plant/Station Date and Time 2015018378 2015018379 2015018380 2015018381 4 Total Samples Collected By Sample Description HF LEE PLANT 10-Jun-15 12:10 PM ILLEGIBLE S-10 HF LEE PLANT 10-Jun-15 11:05 AM ILLEGIBLE S-16 HF LEE PLANT 10-Jun-15 12:20 PM ILLEGIBLE S-10 Dup HF LEE PLANT 10-Jun-15 12:50 PM ILLEGIBLE ASW-NR1 2 of 60 3 of 60 Technical Validation Review Checklist: COC and .pdf report are in agreement with sample totals Yes No and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. ❑ Yes❑ No All laboratory QA/QC requirements are acceptable.❑ Yes ❑ No Report Sections Included: U Job Summary Report ❑ Sample Identification n Technical Validation of Data Package ❑ Analytical Laboratory Certificate of Analysis ❑ Analytical Laboratory QC Report Reviewed By: Date: Sub -contracted Laboratory Results ❑ Customer Specific Data Sheets, Reports, & Documentation ❑ Customer Database Entries 0 Chain of Custody [I/0] Electronic Data Deliverable (EDD) Sent Separately Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060346 Site: S-10 Collection Date: 10-Jun-15 12:10 PM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SEDIMENT ANALYSIS - (Analysis Performed by Access Analytical) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 4 of 60 Sample #: 2015018378 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_A.Analytical Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060346 Site: S-16 Collection Date: 10-Jun-15 11:05 AM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SEDIMENT ANALYSIS - (Analysis Performed by Access Analytical) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 5 of 60 Sample #: 2015018379 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_A.Analytical Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060346 Site: S-10 Dup Collection Date: 10-Jun-15 12:20 PM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SEDIMENT ANALYSIS - (Analysis Performed by Access Analytical) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 6 of 60 Sample #: 2015018380 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_A.Analytical Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060346 Site: ASW-NR1 Collection Date: 10-Jun-15 12:50 PM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SEDIMENT ANALYSIS - (Analysis Performed by Access Analytical) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 7 of 60 Sample #: 2015018381 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_A.Analytical Vendor Method V_PACE aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kigc&y&e. Suite 100 Huntersville, INC 28078 (704)875-9092 June 19, 2015 Program Manager Duke Energy 13339 Hagers Ferry Road Bldg.7405 MG30A2 Huntersville, NC 28078 RE: Project: J 15060346 Pace Project No.: 92253898 Dear Program Manager: Enclosed are the analytical results for sample(s) received by the laboratory on June 11, 2015. The results relate only to the samples included in this report. Results reported herein conform to the most current TN standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Herring kevin.herring@pacelabs.com HORIZON Database Administrator Enclosures cc: Marge Galvin -Karr, Duke Energy Program Manager, Duke Energy Mary Ann Ogle, Duke Energy Rodney Wilke, Duke Energy p«FO REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, lqe� �� without the written consent of Pace Analytical Services, Inc.. BRAT, Page 1 of 38 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kig,8y&e. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15060346 Pace Project No.: 92253898 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification #: 41320 Connecticut Certification M PH-0216 Delaware Certification: FL NELAC Reciprocity Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate M 05007 Maryland Certification: #346 Massachusetts Certification #: M-FL1264 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Green Bay Certification IDs 1241 Bellevue Street, Green Bay, WI 54302 Florida/NELAP Certification #: E87948 Illinois Certification #: 200050 Kentucky Certification #: 82 Louisiana Certification #: 04168 Minnesota Certification #: 055-999-334 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification M E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 CERTIFICATIONS Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 Nevada Certification: FL NELAC Reciprocity New Hampshire Certification #: 2958 New Jersey Certification #: FL765 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 Pennsylvania Certification #: 68-00547 Puerto Rico Certification M FLO1264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 Washington Certification #: C955 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity North Dakota Certification #: R-150 South Carolina Certification #: 83006001 Texas Certification #: T104704529-14-1 US Dept of Agriculture #: S-76505 Wisconsin Certification #: 405132750 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 West Virginia Certification M 356 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 2 of 38 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ff�i�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: J15060346 Pace Project No.: 92253898 Lab ID Sample ID Matrix Date Collected Date Received 92253898001 2015018378 Solid 06/10/1512:10 06/11/1510:45 92253898002 2015018379 Solid 06/10/1511:05 06/11/1510:45 92253898003 2015018380 Solid 06/10/1512:20 06/11/1510:45 92253898004 2015018381 Solid 06/10/1512:50 06/11/1510:45 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 3 of 38 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 fflinl c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: J15060346 92253898 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92253898001 2015018378 EPA 6010 CKJ 16 PASI-0 EPA 6020 CRT, DRS 8 PASI-O EPA 7471 TAP 1 PASI-O ASTM D2974-87 MLO 1 PASI-O EPA 9045 TEP 1 PASI-A EPA 9056 KHC 2 PASI-O EPA 9056 KHC 1 PASI-O EPA 9060 TJJ 6 PASI-G 92253898002 2015018379 EPA 6010 CKJ 16 PASI-0 EPA 6020 CRT, DRS 8 PASI-O EPA 7471 TAP 1 PASI-O ASTM D2974-87 MLO 1 PASI-O EPA 9045 TEP 1 PASI-A EPA 9056 KHC 2 PASI-O EPA 9056 KHC 1 PASI-O EPA 9060 TJJ 6 PASI-G 92253898003 2015018380 EPA 6010 CKJ 16 PASI-0 EPA 6020 CRT, DRS 8 PASI-O EPA 7471 TAP 1 PASI-O ASTM D2974-87 MLO 1 PASI-O EPA 9045 TEP 1 PASI-A EPA 9056 KHC 2 PASI-O EPA 9056 KHC 1 PASI-O EPA 9060 TJJ 6 PASI-G 92253898004 2015018381 EPA 6010 CKJ 16 PASI-0 EPA 6020 CRT, DRS 8 PASI-O EPA 7471 TAP 1 PASI-O ASTM D2974-87 MLO 1 PASI-O EPA 9045 TEP 1 PASI-A EPA 9056 KHC 2 PASI-O EPA 9056 KHC 1 PASI-O EPA 9060 TJJ 6 PASI-G REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 4 of 38 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffli�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15060346 Pace Project No.: 92253898 Lab Sample ID Client Sample ID Method Parameters SUMMARY OF DETECTION Result Units Report Limit Analyzed 92253898001 2015018378 EPA 6010 Aluminum 5720 mg/kg 42.1 06/15/15 17:25 D3 EPA 6010 Barium 75.6 mg/kg 4.2 06/15/15 17:25 D3 EPA 6010 Beryllium 0.49 mg/kg 0.42 06/15/15 17:25 D3 EPA 6010 Calcium 901 mg/kg 210 06/15/15 17:25 D3 EPA 6010 Chromium 10.7 mg/kg 2.1 06/15/15 17:25 D3 EPA 6010 Copper 11.7 mg/kg 2.1 06/15/15 17:25 D3 EPA 6010 Iron 12000 mg/kg 16.8 06/15/15 17:25 D3 EPA 6010 Magnesium 1110 mg/kg 210 06/15/15 17:25 D3 EPA 6010 Manganese 575 mg/kg 2.1 06/15/15 17:25 D3 EPA 6010 Nickel 4.5 mg/kg 2.1 06/15/15 17:25 D3 EPA 6010 Potassium 594 mg/kg 421 06/15/15 17:25 D3 EPA 6010 Strontium 8.3 mg/kg 4.2 06/15/15 17:25 D3 EPA 6010 Zinc 50.8 mg/kg 8.4 06/15/15 17:25 D3 EPA 6020 Arsenic 1.7J mg/kg 1.7 06/15/15 11:43 EPA 6020 Cobalt 7.0 mg/kg 1.7 06/15/15 11:43 EPA 6020 Lead 13.8 mg/kg 1.7 06/15/15 11:43 M6 EPA 6020 Selenium 1 AJ mg/kg 1.7 06/15/15 11:43 EPA 6020 Vanadium 24.1 mg/kg 8.4 06/16/15 11:34 M6 EPA 7471 Mercury 0.030 mg/kg 0.013 06/16/15 11:13 ASTM D2974-87 Percent Moisture 40.3 % 0.10 06/17/15 14:46 EPA 9045 pH at 25 Degrees C 6.3 Std. Units 0.10 06/19/15 11:05 H1 EPA 9060 Total Organic Carbon 10600 mg/kg 2720 06/17/15 15:01 EPA 9060 Total Organic Carbon 9220 mg/kg 2690 06/17/15 15:08 EPA 9060 Total Organic Carbon 8000 mg/kg 2750 06/17/15 15:13 EPA 9060 Total Organic Carbon 11600 mg/kg 2780 06/17/15 15:19 EPA 9060 Mean Total Organic Carbon 9850 mg/kg 2740 06/17/15 15:01 EPA 9060 RSD% 16.0 % 06/17/15 15:01 92253898002 2015018379 EPA 6010 Aluminum 4920 mg/kg 45.3 06/15/15 17:29 D3 EPA 6010 Barium 66.6 mg/kg 4.5 06/15/15 17:29 D3 EPA 6010 Beryllium 0.40J mg/kg 0.45 06/15/15 17:29 D3 EPA 6010 Calcium 856 mg/kg 227 06/15/15 17:29 D3 EPA 6010 Chromium 8.7 mg/kg 2.3 06/15/15 17:29 D3 EPA 6010 Copper 8.4 mg/kg 2.3 06/15/15 17:29 D3 EPA 6010 Iron 10200 mg/kg 18.1 06/15/15 17:29 D3 EPA 6010 Magnesium 874 mg/kg 227 06/15/15 17:29 D3 EPA 6010 Manganese 523 mg/kg 2.3 06/15/15 17:29 D3 EPA 6010 Nickel 3.6 mg/kg 2.3 06/15/15 17:29 D3 EPA 6010 Potassium 490 mg/kg 453 06/15/15 17:29 D3 EPA 6010 Strontium 7.8 mg/kg 4.5 06/15/15 17:29 D3 EPA 6010 Zinc 38.0 mg/kg 9.1 06/15/15 17:29 D3 EPA 6020 Arsenic 1.51 mg/kg 1.8 06/15/15 11:53 EPA 6020 Cobalt 6.1 mg/kg 1.8 06/15/15 11:53 EPA 6020 Lead 10.3 mg/kg 1.8 06/15/15 11:53 EPA 6020 Vanadium 18.5 mg/kg 9.1 06/16/15 11:37 EPA 7471 Mercury 0.033 mg/kg 0.014 06/16/15 11:15 ASTM D2974-87 Percent Moisture 43.9 % 0.10 06/17/15 14:46 REPORT OF LABORATORY ANALYSIS Qualifiers This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 5 of 38 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffli�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15060346 Pace Project No.: 92253898 Lab Sample ID Client Sample ID Method Parameters SUMMARY OF DETECTION Result Units Report Limit Analyzed Qualifiers 92253898002 2015018379 EPA 9045 pH at 25 Degrees C 6.0 Std. Units 0.10 06/19/15 11:05 H1 EPA 9060 Total Organic Carbon 9520 mg/kg 2150 06/17/15 15:25 EPA 9060 Total Organic Carbon 9260 mg/kg 2120 06/17/15 15:31 EPA 9060 Total Organic Carbon 9440 mg/kg 2120 06/17/15 15:36 EPA 9060 Total Organic Carbon 7300 mg/kg 2150 06/17/15 15:42 EPA 9060 Mean Total Organic Carbon 8880 mg/kg 2130 06/17/15 15:25 EPA 9060 RSD% 11.9 % 06/17/15 15:25 92253898003 2015018380 EPA 6010 Aluminum 6240 mg/kg 51.2 06/15/15 17:47 D3 EPA 6010 Barium 83.2 mg/kg 5.1 06/15/15 17:47 D3 EPA 6010 Beryllium 0.51J mg/kg 0.51 06/15/15 17:47 D3 EPA 6010 Calcium 885 mg/kg 256 06/15/15 17:47 D3 EPA 6010 Chromium 11.8 mg/kg 2.6 06/15/15 17:47 D3 EPA 6010 Copper 10.9 mg/kg 2.6 06/15/15 17:47 D3 EPA 6010 Iron 13500 mg/kg 20.5 06/15/15 17:47 D3 EPA 6010 Magnesium 1140 mg/kg 256 06/15/15 17:47 D3 EPA 6010 Manganese 685 mg/kg 2.6 06/15/15 17:47 D3 EPA 6010 Nickel 4.6 mg/kg 2.6 06/15/15 17:47 D3 EPA 6010 Potassium 609 mg/kg 512 06/15/15 17:47 D3 EPA 6010 Strontium 9.0 mg/kg 5.1 06/15/15 17:47 D3 EPA 6010 Zinc 48.1 mg/kg 10.2 06/15/15 17:47 D3 EPA 6020 Arsenic 1.8J mg/kg 2.0 06/15/15 11:56 EPA 6020 Cobalt 7.0 mg/kg 2.0 06/15/15 11:56 EPA 6020 Lead 13.9 mg/kg 2.0 06/15/15 11:56 EPA 6020 Selenium 1 AJ mg/kg 2.0 06/15/15 11:56 EPA 6020 Vanadium 22.9 mg/kg 10.2 06/16/15 11:41 EPA 7471 Mercury 0.038 mg/kg 0.016 06/16/15 11:22 ASTM D2974-87 Percent Moisture 50.8 % 0.10 06/17/15 14:46 EPA 9045 pH at 25 Degrees C 6.7 Std. Units 0.10 06/19/15 11:05 H1 EPA 9060 Total Organic Carbon 10900 mg/kg 2430 06/17/15 15:48 EPA 9060 Total Organic Carbon 10500 mg/kg 2430 06/17/15 15:55 EPA 9060 Total Organic Carbon 17200 mg/kg 2440 06/17/15 16:01 EPA 9060 Total Organic Carbon 15500 mg/kg 2420 06/17/15 16:07 EPA 9060 Mean Total Organic Carbon 13500 mg/kg 2430 06/17/15 15:48 EPA 9060 RSD% 24.8 % 06/17/15 15:48 92253898004 2015018381 EPA 6010 Aluminum 4660 mg/kg 47.7 06/15/15 17:51 D3 EPA 6010 Barium 69.7 mg/kg 4.8 06/15/15 17:51 D3 EPA 6010 Beryllium 0.42J mg/kg 0.48 06/15/15 17:51 D3 EPA 6010 Calcium 786 mg/kg 239 06/15/15 17:51 D3 EPA 6010 Chromium 9.1 mg/kg 2.4 06/15/15 17:51 D3 EPA 6010 Copper 8.8 mg/kg 2.4 06/15/15 17:51 D3 EPA 6010 Iron 11400 mg/kg 19.1 06/15/15 17:51 D3 EPA 6010 Magnesium 937 mg/kg 239 06/15/15 17:51 D3 EPA 6010 Manganese 535 mg/kg 2.4 06/15/15 17:51 D3 EPA 6010 Nickel 4.0 mg/kg 2.4 06/15/15 17:51 D3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 6 of 38 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 fflic&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15060346 Pace Project No.: 92253898 Lab Sample ID Method 92253898004 EPA 6010 EPA 6010 EPA 6010 EPA 6020 EPA 6020 EPA 6020 EPA 6020 EPA 6020 EPA 7471 ASTM D2974-87 EPA 9045 EPA 9060 EPA 9060 EPA 9060 EPA 9060 EPA 9060 EPA 9060 Client Sample ID Parameters 2015018381 Potassium Strontium Zinc Arsenic Cobalt Lead Selenium Vanadium Mercury Percent Moisture pH at 25 Degrees C Total Organic Carbon Total Organic Carbon Total Organic Carbon Total Organic Carbon Mean Total Organic Carbon RSD% SUMMARY OF DETECTION Result Units 537 mg/kg 8.3 mg/kg 39.5 mg/kg 2.8 mg/kg 6.3 mg/kg 10.9 mg/kg 1.2J mg/kg 20.5 mg/kg 0.024 mg/kg 46.1 % 6.8 Std. Units 16000 mg/kg 8470 mg/kg 8940 mg/kg 11200 mg/kg 11200 mg/kg 30.9 % REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Report Limit Analyzed Qualifiers 477 06/15/1517:51 D3 4.8 06/15/1517:51 D3 9.5 06/15/1517:51 D3 1.9 06/15/1511:59 1.9 06/15/1511:59 1.9 06/15/1511:59 1.9 06/15/1511:59 9.5 06/16/1511:44 0.016 06/16/1511:24 0.10 06/17/1514:46 0.10 06/19/1511:05 H1 2210 06/17/1516:25 2230 06/17/1516:30 2200 06/17/1516:36 2230 06/17/1516:41 2220 06/17/1516:25 06/17/15 16:25 Page 7 of 38 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffli�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060346 Pace Project No.: 92253898 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: June 19, 2015 General Information: 4 samples were analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/24704 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 35192778004 M1: Matrix spike recovery exceeded QC limits. • MS (Lab ID: 1242011) • Aluminum • Iron • Magnesium • Manganese • MSD (Lab ID: 1242012) • Aluminum • Iron • Magnesium • Manganese R1: RPD value was outside control limits. • MSD (Lab ID: 1242012) • Iron • Manganese Additional Comments: Batch accepted based on laboratory control sample (LCS) recovery. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 8 of 38 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffli�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060346 Pace Project No.: 92253898 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: June 19, 2015 Analyte Comments: QC Batch: MPRP/24704 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015018378 (Lab ID:92253898001) • Aluminum • Boron • Barium • Beryllium • Calcium • Chromium • Copper • Iron • Potassium • Magnesium • Manganese • Molybdenum • Sodium • Nickel • Strontium • Zinc •2015018379 (Lab ID:92253898002) • Aluminum • Boron • Barium • Beryllium • Calcium • Chromium • Copper • Iron • Potassium • Magnesium • Manganese • Molybdenum • Sodium • Nickel • Strontium • Zinc •2015018380 (Lab ID:92253898003) • Aluminum • Boron • Barium • Beryllium • Calcium • Chromium • Copper • Iron REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 9 of 38 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 fflic&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060346 Pace Project No.: 92253898 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: June 19, 2015 Analyte Comments: QC Batch: MPRP/24704 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015018380 (Lab ID:92253898003) • Potassium • Magnesium • Manganese • Molybdenum • Sodium • Nickel • Strontium • Zinc •2015018381 (Lab ID:92253898004) • Aluminum • Boron • Barium • Beryllium • Calcium • Chromium • Copper • Iron • Potassium • Magnesium • Manganese • Molybdenum • Sodium • Nickel • Strontium • Zinc E: Analyte concentration exceeded the calibration range. The reported result is estimated. • MS (Lab ID: 1242011) • Calcium • Strontium • MSD (Lab ID: 1242012) • Calcium • Strontium REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 10 of 38 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffligc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060346 Pace Project No.: 92253898 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: June 19, 2015 General Information: 4 samples were analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/24705 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92253898001 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • MS (Lab ID: 1242015) • Antimony • Lead • Vanadium • MSD (Lab ID: 1242016) • Antimony • Lead • Vanadium Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 11 of 38 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffli�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060346 Pace Project No.: 92253898 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: June 19, 2015 Batch Comments: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. • QC Batch: ICPM / 10010 Analyte Comments: QC Batch: MPRP/24705 N2: The lab does not hold TNI accreditation for this parameter. •2015018378 (Lab ID:92253898001) • Antimony •2015018379 (Lab ID:92253898002) • Antimony •2015018380 (Lab ID:92253898003) • Antimony •2015018381 (Lab ID:92253898004) • Antimony • BLANK (Lab ID: 1242013) • Antimony • LCS (Lab ID: 1242014) • Antimony • MS (Lab ID: 1242015) • Antimony • MSD (Lab ID: 1242016) • Antimony REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 12 of 38 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KP�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060346 Pace Project No.: 92253898 Method: EPA 7471 Description: 7471 Mercury Client: Duke Energy Date: June 19, 2015 General Information: 4 samples were analyzed for EPA 7471. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7471 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MERP/5856 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 35192778004 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1242035) • Mercury Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 13 of 38 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K�nlc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060346 Pace Project No.: 92253898 Method: EPA 9045 Description: 9045 pH Soil Client: Duke Energy Date: June 19, 2015 General Information: 4 samples were analyzed for EPA 9045. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 111: Analysis conducted outside the EPA method holding time. •2015018378 (Lab ID:92253898001) •2015018379 (Lab ID:92253898002) •2015018380 (Lab ID:92253898003) •2015018381 (Lab ID:92253898004) Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Duplicate Sample: All duplicate sample results were within method acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 14 of 38 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KP�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060346 Pace Project No.: 92253898 Method: EPA 9056 Description: 9056 IC Anions Client: Duke Energy Date: June 19, 2015 General Information: 4 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/47291 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015018378 (Lab ID:92253898001) • Chloride • Sulfate •2015018379 (Lab ID:92253898002) • Chloride • Sulfate •2015018380 (Lab ID:92253898003) • Chloride • Sulfate •2015018381 (Lab ID:92253898004) • Chloride • Sulfate REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 15 of 38 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KP�c&)e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060346 Pace Project No.: 92253898 Method: EPA 9056 Description: 9056 IC Anions 48hr Client: Duke Energy Date: June 19, 2015 General Information: 4 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 111: Analysis conducted outside the EPA method holding time. •2015018378 (Lab ID:92253898001) •2015018380 (Lab ID:92253898003) •2015018381 (Lab ID:92253898004) H3: Sample was received or analysis requested beyond the recognized method holding time. •2015018379 (Lab ID:92253898002) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 16 of 38 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KPc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060346 Pace Project No.: 92253898 Method: EPA 9060 Description: Total Organic Carbon Quad Client: Duke Energy Date: June 19, 2015 General Information: 4 samples were analyzed for EPA 9060. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: This data package has been reviewed for quality and completeness and is approved for release. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 17 of 38 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KP�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15060346 Pace Project No.: 92253898 Sample: 2015018378 Lab ID: 92253898001 Collected: 06/10/15 12:10 Received: 06/11/15 10:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Aluminum Barium Beryllium Boron Calcium Chromium Copper Iron Magnesium Manganese Molybdenum Nickel Potassium Sodium Strontium Zinc 6020 MET ICPMS Antimony Arsenic Cadmium Cobalt Lead Selenium Thallium Vanadium 7471 Mercury Mercury Percent Moisture Percent Moisture 9045 pH Soil pH at 25 Degrees C 9056 IC Anions Chloride Sulfate 9056 IC Anions 48hr Nitrate as N Date: 06/19/2015 12:48 PM Analytical Method: EPA 6010 Preparation Method: EPA 3050 5720 mg/kg 42.1 21.0 5 06/14/1516:30 06/15/1517:25 7429-90-5 75.6 mg/kg 4.2 2.1 5 06/14/1516:30 06/15/1517:25 7440-39-3 0.49 mg/kg 0.42 0.21 5 06/14/1516:30 06/15/1517:25 7440-41-7 ND mg/kg 21.0 10.5 5 06/14/1516:30 06/15/1517:25 7440-42-8 901 mg/kg 210 105 5 06/14/1516:30 06/15/1517:25 7440-70-2 10.7 mg/kg 2.1 1.1 5 06/14/1516:30 06/15/1517:25 7440-47-3 11.7 mg/kg 2.1 1.1 5 06/14/1516:30 06/15/1517:25 7440-50-8 12000 mg/kg 16.8 8.4 5 06/14/1516:30 06/15/1517:25 7439-89-6 1110 mg/kg 210 105 5 06/14/1516:30 06/15/1517:25 7439-95-4 575 mg/kg 2.1 1.1 5 06/14/1516:30 06/15/1517:25 7439-96-5 ND mg/kg 4.2 2.1 5 06/14/1516:30 06/15/1517:25 7439-98-7 4.5 mg/kg 2.1 1.1 5 06/14/1516:30 06/15/1517:25 7440-02-0 594 mg/kg 421 210 5 06/14/1516:30 06/15/1517:25 7440-09-7 ND mg/kg 421 210 5 06/14/1516:30 06/15/1517:25 7440-23-5 8.3 mg/kg 4.2 2.1 5 06/14/1516:30 06/15/1517:25 7440-24-6 50.8 mg/kg 8.4 4.2 5 06/14/1516:30 06/15/1517:25 7440-66-6 Analytical Method: EPA 6020 Preparation Method: EPA 3050 ND mg/kg 1.7 0.84 20 06/14/1516:30 06/15/1511:43 7440-36-0 1.7J mg/kg 1.7 0.84 20 06/14/1516:30 06/15/1511:43 7440-38-2 ND mg/kg 1.0 0.51 100 06/14/1516:30 06/16/1511:34 7440-43-9 7.0 mg/kg 1.7 0.84 20 06/14/1516:30 06/15/1511:43 7440-48-4 13.8 mg/kg 1.7 0.84 20 06/14/1516:30 06/15/1511:43 7439-92-1 1 AJ mg/kg 1.7 0.84 20 06/14/15 16:30 06/15/15 11:43 7782-49-2 ND mg/kg 1.7 0.84 20 06/14/1516:30 06/15/1511:43 7440-28-0 24.1 mg/kg 8.4 4.2 100 06/14/1516:30 06/16/1511:34 7440-62-2 Analytical Method: EPA 7471 Preparation Method: EPA 7471 0.030 mg/kg 0.013 0.0066 1 06/15/15 06:00 06/16/15 11:13 7439-97-6 Analytical Method: ASTM D2974-87 40.3 % 0.10 0.10 1 06/17/1514:46 Analytical Method: EPA 9045 6.3 Std. Units 0.10 0.10 1 Analytical Method: EPA 9056 ND mg/kg 418 209 5 ND mg/kg 418 209 5 Analytical Method: EPA 9056 ND mg/kg 41.8 20.9 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. [�Iyf�1f6'ifilUb7 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 M6, N2 M6 M6 I:fl 06/14/15 21:08 16887-00-6 D3 06/14/15 21:08 14808-79-8 D3 06/14/15 21:08 14797-55-8 H1 Page 18 of 38 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K��c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15060346 Pace Project No.: 92253898 Sample: 2015018378 Lab ID: 92253898001 Collected: 06/10/15 12:10 Received: 06/11/15 10:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 10600 mg/kg 2720 1360 1 06/17/15 15:01 7440-44-0 Total Organic Carbon 9220 mg/kg 2690 1350 1 06/17/15 15:08 7440-44-0 Total Organic Carbon 8000 mg/kg 2750 1370 1 06/17/15 15:13 7440-44-0 Total Organic Carbon 11600 mg/kg 2780 1390 1 06/17/15 15:19 7440-44-0 Mean Total Organic Carbon 9850 mg/kg 2740 1370 1 06/17/15 15:01 7440-44-0 Surrogates RSD% 16.0 % 1 06/17/15 15:01 Date: 06/19/2015 12:48 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 19 of 38 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15060346 Pace Project No.: 92253898 Sample: 2015018379 Lab ID: 92253898002 Collected: 06/10/15 11:05 Received: 06/11/15 10:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Aluminum Barium Beryllium Boron Calcium Chromium Copper Iron Magnesium Manganese Molybdenum Nickel Potassium Sodium Strontium Zinc 6020 MET ICPMS Antimony Arsenic Cadmium Cobalt Lead Selenium Thallium Vanadium 7471 Mercury Mercury Percent Moisture Percent Moisture 9045 pH Soil pH at 25 Degrees C 9056 IC Anions Chloride Sulfate 9056 IC Anions 48hr Nitrate as N Date: 06/19/2015 12:48 PM Analytical Method: EPA 6010 Preparation Method: EPA 3050 4920 mg/kg 45.3 22.7 5 06/14/1516:30 06/15/1517:29 7429-90-5 66.6 mg/kg 4.5 2.3 5 06/14/1516:30 06/15/1517:29 7440-39-3 0.40J mg/kg 0.45 0.23 5 06/14/1516:30 06/15/1517:29 7440-41-7 ND mg/kg 22.7 11.3 5 06/14/1516:30 06/15/1517:29 7440-42-8 856 mg/kg 227 113 5 06/14/1516:30 06/15/1517:29 7440-70-2 8.7 mg/kg 2.3 1.1 5 06/14/1516:30 06/15/1517:29 7440-47-3 8.4 mg/kg 2.3 1.1 5 06/14/1516:30 06/15/1517:29 7440-50-8 10200 mg/kg 18.1 9.1 5 06/14/1516:30 06/15/1517:29 7439-89-6 874 mg/kg 227 113 5 06/14/1516:30 06/15/1517:29 7439-95-4 523 mg/kg 2.3 1.1 5 06/14/1516:30 06/15/1517:29 7439-96-5 ND mg/kg 4.5 2.3 5 06/14/1516:30 06/15/1517:29 7439-98-7 3.6 mg/kg 2.3 1.1 5 06/14/1516:30 06/15/1517:29 7440-02-0 490 mg/kg 453 227 5 06/14/1516:30 06/15/1517:29 7440-09-7 ND mg/kg 453 227 5 06/14/1516:30 06/15/1517:29 7440-23-5 7.8 mg/kg 4.5 2.3 5 06/14/1516:30 06/15/1517:29 7440-24-6 38.0 mg/kg 9.1 4.5 5 06/14/1516:30 06/15/1517:29 7440-66-6 Analytical Method: EPA 6020 Preparation Method: EPA 3050 ND mg/kg 1.8 0.91 20 06/14/1516:30 06/15/1511:53 7440-36-0 1.5J mg/kg 1.8 0.91 20 06/14/1516:30 06/15/1511:53 7440-38-2 ND mg/kg 1.1 0.54 100 06/14/1516:30 06/16/1511:37 7440-43-9 6.1 mg/kg 1.8 0.91 20 06/14/1516:30 06/15/1511:53 7440-48-4 10.3 mg/kg 1.8 0.91 20 06/14/1516:30 06/15/1511:53 7439-92-1 ND mg/kg 1.8 0.91 20 06/14/1516:30 06/15/1511:53 7782-49-2 ND mg/kg 1.8 0.91 20 06/14/1516:30 06/15/1511:53 7440-28-0 18.5 mg/kg 9.1 4.5 100 06/14/1516:30 06/16/1511:37 7440-62-2 Analytical Method: EPA 7471 Preparation Method: EPA 7471 0.033 mg/kg 0.014 0.0072 1 06/15/15 06:00 06/16/15 11:15 7439-97-6 Analytical Method: ASTM D2974-87 43.9 % 0.10 0.10 1 06/17/1514:46 Analytical Method: EPA 9045 6.0 Std. Units 0.10 0.10 1 Analytical Method: EPA 9056 ND mg/kg 440 220 5 ND mg/kg 440 220 5 Analytical Method: EPA 9056 ND mg/kg 44.0 22.0 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. [�Iyf�1f6'ifilUb7 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 N2 I:fl 06/14/15 21:29 16887-00-6 D3 06/14/15 21:29 14808-79-8 D3 06/14/15 21:29 14797-55-8 H3 Page 20 of 38 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KPgc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15060346 Pace Project No.: 92253898 Sample: 2015018379 Lab ID: 92253898002 Collected: 06/10/15 11:05 Received: 06/11/15 10:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 9520 mg/kg 2150 1080 1 06/17/15 15:25 7440-44-0 Total Organic Carbon 9260 mg/kg 2120 1060 1 06/17/15 15:31 7440-44-0 Total Organic Carbon 9440 mg/kg 2120 1060 1 06/17/15 15:36 7440-44-0 Total Organic Carbon 7300 mg/kg 2150 1070 1 06/17/15 15:42 7440-44-0 Mean Total Organic Carbon 8880 mg/kg 2130 1070 1 06/17/15 15:25 7440-44-0 Surrogates RSD% 11.9 % 1 06/17/15 15:25 Date: 06/19/2015 12:48 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 21 of 38 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K��c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15060346 Pace Project No.: 92253898 Sample: 2015018380 Lab ID: 92253898003 Collected: 06/10/15 12:20 Received: 06/11/15 10:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Aluminum Barium Beryllium Boron Calcium Chromium Copper Iron Magnesium Manganese Molybdenum Nickel Potassium Sodium Strontium Zinc 6020 MET ICPMS Antimony Arsenic Cadmium Cobalt Lead Selenium Thallium Vanadium 7471 Mercury Mercury Percent Moisture Percent Moisture 9045 pH Soil pH at 25 Degrees C 9056 IC Anions Chloride Sulfate 9056 IC Anions 48hr Nitrate as N Date: 06/19/2015 12:48 PM Analytical Method: EPA 6010 Preparation Method: EPA 3050 6240 mg/kg 51.2 25.6 5 06/14/1516:30 06/15/1517:47 7429-90-5 83.2 mg/kg 5.1 2.6 5 06/14/1516:30 06/15/1517:47 7440-39-3 0.511 mg/kg 0.51 0.26 5 06/14/1516:30 06/15/1517:47 7440-41-7 ND mg/kg 25.6 12.8 5 06/14/1516:30 06/15/1517:47 7440-42-8 885 mg/kg 256 128 5 06/14/1516:30 06/15/1517:47 7440-70-2 11.8 mg/kg 2.6 1.3 5 06/14/1516:30 06/15/1517:47 7440-47-3 10.9 mg/kg 2.6 1.3 5 06/14/1516:30 06/15/1517:47 7440-50-8 13500 mg/kg 20.5 10.2 5 06/14/1516:30 06/15/1517:47 7439-89-6 1140 mg/kg 256 128 5 06/14/1516:30 06/15/1517:47 7439-95-4 685 mg/kg 2.6 1.3 5 06/14/1516:30 06/15/1517:47 7439-96-5 ND mg/kg 5.1 2.6 5 06/14/1516:30 06/15/1517:47 7439-98-7 4.6 mg/kg 2.6 1.3 5 06/14/1516:30 06/15/1517:47 7440-02-0 609 mg/kg 512 256 5 06/14/1516:30 06/15/1517:47 7440-09-7 ND mg/kg 512 256 5 06/14/1516:30 06/15/1517:47 7440-23-5 9.0 mg/kg 5.1 2.6 5 06/14/1516:30 06/15/1517:47 7440-24-6 48.1 mg/kg 10.2 5.1 5 06/14/1516:30 06/15/1517:47 7440-66-6 Analytical Method: EPA 6020 Preparation Method: EPA 3050 ND mg/kg 2.0 1.0 20 06/14/1516:30 06/15/1511:56 7440-36-0 1.8J mg/kg 2.0 1.0 20 06/14/1516:30 06/15/1511:56 7440-38-2 ND mg/kg 1.2 0.61 100 06/14/1516:30 06/16/1511:41 7440-43-9 7.0 mg/kg 2.0 1.0 20 06/14/1516:30 06/15/1511:56 7440-48-4 13.9 mg/kg 2.0 1.0 20 06/14/1516:30 06/15/1511:56 7439-92-1 1 AJ mg/kg 2.0 1.0 20 06/14/15 16:30 06/15/15 11:56 7782-49-2 ND mg/kg 2.0 1.0 20 06/14/1516:30 06/15/1511:56 7440-28-0 22.9 mg/kg 10.2 5.1 100 06/14/1516:30 06/16/1511:41 7440-62-2 Analytical Method: EPA 7471 Preparation Method: EPA 7471 0.038 mg/kg 0.016 0.0078 1 06/15/15 06:00 06/16/15 11:22 7439-97-6 Analytical Method: ASTM D2974-87 50.8 % 0.10 0.10 1 06/17/1514:46 Analytical Method: EPA 9045 6.7 Std. Units 0.10 0.10 1 Analytical Method: EPA 9056 ND mg/kg 508 254 5 ND mg/kg 508 254 5 Analytical Method: EPA 9056 ND mg/kg 50.8 25.4 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. [�Iyf�1f6'ifilUb7 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 N2 I:fl 06/14/15 21:51 16887-00-6 D3 06/14/15 21:51 14808-79-8 D3 06/14/15 21:51 14797-55-8 H1 Page 22 of 38 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K��c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15060346 Pace Project No.: 92253898 Sample: 2015018380 Lab ID: 92253898003 Collected: 06/10/15 12:20 Received: 06/11/15 10:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 10900 mg/kg 2430 1210 1 06/17/15 15:48 7440-44-0 Total Organic Carbon 10500 mg/kg 2430 1210 1 06/17/15 15:55 7440-44-0 Total Organic Carbon 17200 mg/kg 2440 1220 1 06/17/15 16:01 7440-44-0 Total Organic Carbon 15500 mg/kg 2420 1210 1 06/17/15 16:07 7440-44-0 Mean Total Organic Carbon 13500 mg/kg 2430 1210 1 06/17/15 15:48 7440-44-0 Surrogates RSD% 24.8 % 1 06/17/15 15:48 Date: 06/19/2015 12:48 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 23 of 38 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K3nic&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15060346 Pace Project No.: 92253898 Sample: 2015018381 Lab ID: 92253898004 Collected: 06/10/15 12:50 Received: 06/11/15 10:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Aluminum Barium Beryllium Boron Calcium Chromium Copper Iron Magnesium Manganese Molybdenum Nickel Potassium Sodium Strontium Zinc 6020 MET ICPMS Antimony Arsenic Cadmium Cobalt Lead Selenium Thallium Vanadium 7471 Mercury Mercury Percent Moisture Percent Moisture 9045 pH Soil pH at 25 Degrees C 9056 IC Anions Chloride Sulfate 9056 IC Anions 48hr Nitrate as N Date: 06/19/2015 12:48 PM Analytical Method: EPA 6010 Preparation Method: EPA 3050 4660 mg/kg 47.7 23.9 5 06/14/1516:30 06/15/1517:51 7429-90-5 69.7 mg/kg 4.8 2.4 5 06/14/1516:30 06/15/1517:51 7440-39-3 0.42J mg/kg 0.48 0.24 5 06/14/1516:30 06/15/1517:51 7440-41-7 ND mg/kg 23.9 11.9 5 06/14/1516:30 06/15/1517:51 7440-42-8 786 mg/kg 239 119 5 06/14/1516:30 06/15/1517:51 7440-70-2 9.1 mg/kg 2.4 1.2 5 06/14/1516:30 06/15/1517:51 7440-47-3 8.8 mg/kg 2.4 1.2 5 06/14/1516:30 06/15/1517:51 7440-50-8 11400 mg/kg 19.1 9.5 5 06/14/1516:30 06/15/1517:51 7439-89-6 937 mg/kg 239 119 5 06/14/1516:30 06/15/1517:51 7439-95-4 535 mg/kg 2.4 1.2 5 06/14/1516:30 06/15/1517:51 7439-96-5 ND mg/kg 4.8 2.4 5 06/14/1516:30 06/15/1517:51 7439-98-7 4.0 mg/kg 2.4 1.2 5 06/14/1516:30 06/15/1517:51 7440-02-0 537 mg/kg 477 239 5 06/14/1516:30 06/15/1517:51 7440-09-7 ND mg/kg 477 239 5 06/14/1516:30 06/15/1517:51 7440-23-5 8.3 mg/kg 4.8 2.4 5 06/14/1516:30 06/15/1517:51 7440-24-6 39.5 mg/kg 9.5 4.8 5 06/14/1516:30 06/15/1517:51 7440-66-6 Analytical Method: EPA 6020 Preparation Method: EPA 3050 ND mg/kg 1.9 0.95 20 06/14/1516:30 06/15/1511:59 7440-36-0 2.8 mg/kg 1.9 0.95 20 06/14/1516:30 06/15/1511:59 7440-38-2 ND mg/kg 1.1 0.57 100 06/14/1516:30 06/16/1511:44 7440-43-9 6.3 mg/kg 1.9 0.95 20 06/14/1516:30 06/15/1511:59 7440-48-4 10.9 mg/kg 1.9 0.95 20 06/14/1516:30 06/15/1511:59 7439-92-1 1.2J mg/kg 1.9 0.95 20 06/14/1516:30 06/15/1511:59 7782-49-2 ND mg/kg 1.9 0.95 20 06/14/1516:30 06/15/1511:59 7440-28-0 20.5 mg/kg 9.5 4.8 100 06/14/1516:30 06/16/1511:44 7440-62-2 Analytical Method: EPA 7471 Preparation Method: EPA 7471 0.024 mg/kg 0.016 0.0078 1 06/15/15 06:00 06/16/15 11:24 7439-97-6 Analytical Method: ASTM D2974-87 46.1 % 0.10 0.10 1 06/17/1514:46 Analytical Method: EPA 9045 6.8 Std. Units 0.10 0.10 1 Analytical Method: EPA 9056 ND mg/kg 458 229 5 ND mg/kg 458 229 5 Analytical Method: EPA 9056 ND mg/kg 45.8 22.9 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. [�Iyf�1f6'ifilNb7 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 N2 I:fl 06/14/15 22:12 16887-00-6 D3 06/14/15 22:12 14808-79-8 D3 06/14/15 22:12 14797-55-8 H1 Page 24 of 38 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K��c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15060346 Pace Project No.: 92253898 Sample: 2015018381 Lab ID: 92253898004 Collected: 06/10/15 12:50 Received: 06/11/15 10:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 16000 mg/kg 2210 1100 1 06/17/15 16:25 7440-44-0 Total Organic Carbon 8470 mg/kg 2230 1120 1 06/17/15 16:30 7440-44-0 Total Organic Carbon 8940 mg/kg 2200 1100 1 06/17/15 16:36 7440-44-0 Total Organic Carbon 11200 mg/kg 2230 1120 1 06/17/15 16:41 7440-44-0 Mean Total Organic Carbon 11200 mg/kg 2220 1110 1 06/17/15 16:25 7440-44-0 Surrogates RSD% 30.9 % 1 06/17/15 16:25 Date: 06/19/2015 12:48 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 25 of 38 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060346 Pace Project No.: 92253898 QC Batch: MERP/5856 Analysis Method: EPA 7471 QC Batch Method: EPA 7471 Analysis Description: 7471 Mercury Associated Lab Samples: 92253898001, 92253898002, 92253898003, 92253898004 METHOD BLANK: 1242033 Matrix: Solid Associated Lab Samples: 92253898001, 92253898002, 92253898003, 92253898004 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury mg/kg ND 0.0080 06/16/1510:52 LABORATORY CONTROL SAMPLE: 1242034 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury mg/kg .08 0.082 102 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1242035 1242036 MS MSD 35192778004 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury mg/kg 0.11 0.14 20 20 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/19/2015 12:48 PM without the written consent of Pace Analytical Services, Inc.. Page 26 of 38 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060346 Pace Project No.: 92253898 QC Batch: MPRP/24704 Analysis Method: EPA 6010 QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid Associated Lab Samples: 92253898001, 92253898002, 92253898003, 92253898004 METHOD BLANK: 1242009 Matrix: Solid Associated Lab Samples: 92253898001, 92253898002, 92253898003, 92253898004 Blank Reporting Parameter Units Result Limit Analyzed Aluminum mg/kg ND 5.1 06/15/1516:24 Barium mg/kg ND 0.51 06/15/1516:24 Beryllium mg/kg ND 0.051 06/15/1516:24 Boron mg/kg ND 2.5 06/15/1516:24 Calcium mg/kg ND 25.4 06/15/1516:24 Chromium mg/kg ND 0.25 06/15/1516:24 Copper mg/kg ND 0.25 06/15/1516:24 Iron mg/kg ND 2.0 06/15/1516:24 Magnesium mg/kg ND 25.4 06/15/1516:24 Manganese mg/kg ND 0.25 06/15/1516:24 Molybdenum mg/kg ND 0.51 06/15/1516:24 Nickel mg/kg ND 0.25 06/15/1516:24 Potassium mg/kg ND 50.8 06/15/1516:24 Sodium mg/kg ND 50.8 06/15/1516:24 Strontium mg/kg ND 0.51 06/15/1516:24 Zinc mg/kg ND 1.0 06/15/1516:24 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 1242010 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Aluminum mg/kg 127 126 99 80-120 Barium mg/kg 12.7 12.9 101 80-120 Beryllium mg/kg 1.3 1.3 101 80-120 Boron mg/kg 127 123 97 80-120 Calcium mg/kg 635 642 101 80-120 Chromium mg/kg 12.7 12.7 100 80-120 Copper mg/kg 12.7 12.3 96 80-120 Iron mg/kg 127 128 101 80-120 Magnesium mg/kg 635 633 100 80-120 Manganese mg/kg 12.7 12.5 98 80-120 Molybdenum mg/kg 12.7 12.4 97 80-120 Nickel mg/kg 12.7 12.9 101 80-120 Potassium mg/kg 635 615 97 80-120 Sodium mg/kg 635 625 98 80-120 Strontium mg/kg 12.7 12.6 99 80-120 Zinc mg/kg 63.5 64.1 101 80-120 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/19/2015 12:48 PM without the written consent of Pace Analytical Services, Inc.. Page 27 of 38 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K��c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060346 Pace Project No.: 92253898 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1242011 35192778004 Parameter Units Result MS Spike Conc. MSD Spike Conc. 1242012 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits Max RPD RPD Qual Aluminum mg/kg 137 137 1360 1450 401 465 75-125 6 20 M1 Barium mg/kg 13.7 13.7 24.0 23.4 104 99 75-125 3 20 Beryllium mg/kg 1.37 1.37 1.3 1.3 93 93 75-125 0 20 Boron mg/kg 137 137 144 141 99 97 75-125 2 20 Calcium mg/kg 682 686 171000 170000 -4280 -4490 75-125 1 20 E Chromium mg/kg 6.7 13.7 13.7 19.6 19.7 95 95 75-125 1 20 Copper mg/kg 13.7 13.7 19.6 22.3 106 125 75-125 13 20 Iron mg/kg 137 137 1720 5140 -39 2460 75-125 100 20 M1,R1 Magnesium mg/kg 682 686 2000 2120 45 62 75-125 6 20 M1 Manganese mg/kg 13.7 13.7 25.9 37.0 73 153 75-125 35 20 M1,R1 Molybdenum mg/kg 13.7 13.7 13.8 14.4 93 97 75-125 4 20 Nickel mg/kg 13.7 13.7 14.2 14.4 94 95 75-125 1 20 Potassium mg/kg 682 686 870 861 115 113 75-125 1 20 Sodium mg/kg 682 686 1370 1300 89 77 75-125 6 20 Strontium mg/kg 13.7 13.7 1500 1310 -2610 -3950 75-125 13 20 E Zinc mg/kg 68.2 68.6 97.0 96.3 108 106 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/19/2015 12:48 PM without the written consent of Pace Analytical Services, Inc.. Page 28 of 38 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K��c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060346 Pace Project No.: 92253898 QC Batch: MPRP/24705 Analysis Method: EPA 6020 QC Batch Method: EPA 3050 Analysis Description: 6020 MET SOLID Associated Lab Samples: 92253898001, 92253898002, 92253898003, 92253898004 METHOD BLANK: 1242013 Matrix: Solid Associated Lab Samples: 92253898001, 92253898002, 92253898003, 92253898004 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Antimony mg/kg ND 0.053 06/16/1511:10 N2 Arsenic mg/kg ND 0.053 06/16/1511:10 Cadmium mg/kg ND 0.0063 06/16/1511:10 Cobalt mg/kg ND 0.053 06/16/1511:10 Lead mg/kg ND 0.053 06/16/1511:10 Selenium mg/kg ND 0.053 06/16/1511:10 Thallium mg/kg ND 0.053 06/16/1511:10 Vanadium mg/kg ND 0.053 06/16/1511:10 LABORATORY CONTROL SAMPLE: 1242014 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Antimony mg/kg 2.5 2.4 98 80-120 N2 Arsenic mg/kg 2.5 2.5 102 80-120 Cadmium mg/kg .25 0.24 97 80-120 Cobalt mg/kg 2.5 2.6 104 80-120 Lead mg/kg 2.5 2.5 102 80-120 Selenium mg/kg 2.5 2.4 97 80-120 Thallium mg/kg 2.5 2.5 102 80-120 Vanadium mg/kg 2.5 2.5 103 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1242015 1242016 MS MSD 92253898001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony mg/kg ND 4.02 4.19 2.8 2.7 64 60 75-125 3 20 M6, N2 Arsenic mg/kg 1.7J 4.02 4.19 5.3 5.7 90 95 75-125 7 20 Cadmium mg/kg ND .402 .419 0.57J 0.52J 113 98 75-125 20 Cobalt mg/kg 7.0 4.02 4.19 10.7 10.5 90 83 75-125 1 20 Lead mg/kg 13.8 4.02 4.19 16.5 16.5 67 62 75-125 1 20 M6 Selenium mg/kg 1 AJ 4.02 4.19 4.6 4.7 78 78 75-125 3 20 Thallium mg/kg ND 4.02 4.19 4.4 4.5 104 104 75-125 3 20 Vanadium mg/kg 24.1 4.02 4.19 24.3 24.4 6 7 75-125 0 20 M6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/19/2015 12:48 PM without the written consent of Pace Analytical Services, Inc.. Page 29 of 38 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060346 Pace Project No.: 92253898 QC Batch: PMST/3655 Analysis Method: ASTM D2974-87 QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture Associated Lab Samples: 92253898001, 92253898002, 92253898003, 92253898004 SAMPLE DUPLICATE: 1244637 92253352001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 25.0 23.4 6 10 SAMPLE DUPLICATE: 1244638 92253898001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 40.3 43.9 9 10 SAMPLE DUPLICATE: 1244639 35192643006 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 16.8 16.4 2 10 SAMPLE DUPLICATE: 1244640 35192841001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 16.6 18.1 9 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/19/2015 12:48 PM without the written consent of Pace Analytical Services, Inc.. Page 30 of 38 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K�gc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060346 Pace Project No.: 92253898 QC Batch: WET/38242 Analysis Method: EPA 9045 QC Batch Method: EPA 9045 Analysis Description: 9045 pH Associated Lab Samples: 92253898001, 92253898002, 92253898003, 92253898004 SAMPLE DUPLICATE: 1489496 92253898001 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 6.3 6.3 0 10 H1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/19/2015 12:48 PM without the written consent of Pace Analytical Services, Inc.. Page 31 of 38 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K��c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060346 Pace Project No.: 92253898 QC Batch: WETA/47291 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92253898001, 92253898002, 92253898003, 92253898004 METHOD BLANK: 1242091 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/kg ND 50.1 06/14/1513:38 Sulfate mg/kg ND 50.1 06/14/1513:38 LABORATORY CONTROL SAMPLE: 1242092 Parameter Units Chloride mg/kg Sulfate mg/kg MATRIX SPIKE SAMPLE: 1242094 Parameter Units Chloride mg/kg Sulfate mg/kg SAMPLE DUPLICATE: 1242093 Parameter Chloride Sulfate Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 492 453 92 80-120 492 449 91 80-120 92253899001 Spike MS MS % Rec Result Conc. Result % Rec Limits Qualifiers ND 541 489 72 80-120 H3,M1 ND 541 516 82 80-120 H3 92253899001 Dup Units Result Result mg/kg ND ND mg/kg ND ND Max RPD RPD Qualifiers 20 H3 20 H3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/19/2015 12:48 PM without the written consent of Pace Analytical Services, Inc.. Page 32 of 38 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060346 Pace Project No.: 92253898 QC Batch: WETA/47290 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92253898001, 92253898002, 92253898003, 92253898004 METHOD BLANK: 1242087 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrate as N mg/kg ND 5.0 06/14/15 13:38 LABORATORY CONTROL SAMPLE: 1242088 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg 49.2 46.6 95 80-120 MATRIX SPIKE SAMPLE: 1242090 92253899001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg ND 54.1 50.4 92 80-120 H3 SAMPLE DUPLICATE: 1242089 92253899001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Nitrate as N mg/kg ND ND 20 H3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/19/2015 12:48 PM without the written consent of Pace Analytical Services, Inc.. Page 33 of 38 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 1inlc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060346 Pace Project No.: 92253898 QC Batch: WETA/29034 Analysis Method: EPA 9060 QC Batch Method: EPA 9060 Analysis Description: 9060 TOC Average Associated Lab Samples: 92253898001, 92253898002, 92253898003, 92253898004 METHOD BLANK: 1176055 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mean Total Organic Carbon mg/kg ND 600 06/17/15 07:46 LABORATORY CONTROL SAMPLE: 1176056 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mean Total Organic Carbon mg/kg 120000 111000 93 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1176057 1176058 MS MSD 92252908004 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg 482J 7180 7140 6380 6040 82 78 50-150 5 30 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1176059 1176060 MS MSD 92252908005 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg 574J 8340 8320 6910 6400 76 70 50-150 8 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/19/2015 12:48 PM without the written consent of Pace Analytical Services, Inc.. Page 34 of 38 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: J15060346 Pace Project No.: 92253898 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TN -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-G Pace Analytical Services - Green Bay PASI-O Pace Analytical Services - Ormond Beach BATCH QUALIFIERS Batch: ICPM/10010 Ill Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. ANALYTE QUALIFIERS D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. E Analyte concentration exceeded the calibration range. The reported result is estimated. H1 Analysis conducted outside the EPA method holding time. H3 Sample was received or analysis requested beyond the recognized method holding time. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. N2 The lab does not hold TN accreditation for this parameter. R1 RPD value was outside control limits. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/19/2015 12:48 PM without the written consent of Pace Analytical Services, Inc.. Page 35 of 38 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 I� %fir&e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: J15060346 Pace Project No.: 92253898 Lab ID Sample ID QC Batch Method QC Batch Analytical Method 92253898001 2015018378 EPA 3050 MPRP/24704 EPA 6010 92253898002 2015018379 EPA 3050 MPRP/24704 EPA 6010 92253898003 2015018380 EPA 3050 MPRP/24704 EPA 6010 92253898004 2015018381 EPA 3050 MPRP/24704 EPA 6010 92253898001 2015018378 EPA 3050 MPRP/24705 EPA 6020 92253898002 2015018379 EPA 3050 MPRP/24705 EPA 6020 92253898003 2015018380 EPA 3050 MPRP/24705 EPA 6020 92253898004 2015018381 EPA 3050 MPRP/24705 EPA 6020 92253898001 2015018378 EPA 7471 MERP/5856 EPA 7471 92253898002 2015018379 EPA 7471 MERP/5856 EPA 7471 92253898003 2015018380 EPA 7471 MERP/5856 EPA 7471 92253898004 2015018381 EPA 7471 MERP/5856 EPA 7471 92253898001 2015018378 ASTM D2974-87 PMST/3655 92253898002 2015018379 ASTM D2974-87 PMST/3655 92253898003 2015018380 ASTM D2974-87 PMST/3655 92253898004 2015018381 ASTM D2974-87 PMST/3655 92253898001 2015018378 EPA 9045 WET/38242 92253898002 2015018379 EPA 9045 WET/38242 92253898003 2015018380 EPA 9045 WET/38242 92253898004 2015018381 EPA 9045 WET/38242 92253898001 2015018378 EPA 9056 WETA/47291 92253898002 2015018379 EPA 9056 WETA/47291 92253898003 2015018380 EPA 9056 WETA/47291 92253898004 2015018381 EPA 9056 WETA/47291 92253898001 2015018378 EPA 9056 WETA/47290 92253898002 2015018379 EPA 9056 WETA/47290 92253898003 2015018380 EPA 9056 WETA/47290 92253898004 2015018381 EPA 9056 WETA/47290 92253898001 2015018378 EPA 9060 WETA/29034 92253898001 2015018378 EPA 9060 WETA/29035 92253898002 2015018379 EPA 9060 WETA/29034 92253898002 2015018379 EPA 9060 WETA/29035 92253898003 2015018380 EPA 9060 WETA/29034 92253898003 2015018380 EPA 9060 WETA/29035 92253898004 2015018381 EPA 9060 WETA/29034 92253898004 2015018381 EPA 9060 WETA/29035 Date: 06/19/2015 12:48 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Analytical Batch ICP/15077 ICP/15077 ICP/15077 ICP/15077 ICPM/10010 ICPM/10010 ICPM/10010 ICPM/10010 MERC/5836 MERC/5836 MERC/5836 MERC/5836 Page 36 of 38 ��17170M,qYlcaf' —V%Iul 1101Il IVdl11U. Sample Condition Upon Receil Document Number: F-CHR-CS-003-rev.16 uocumenE meviseu: may 10, Gv I:) SCUR Page 1 of 2* Issuing Authority: 44 of 60 Pace Huntersville Qualitv Office Client Name: '_ ,l Lne * Page 2 of 2 is for Internal Use Only Courier: ❑ Fed Ex ❑ UPS❑ LISP Client❑ emmercial❑ Pace Other Custody Seal on Cooler/Box Present: ❑ yes no Seals intact: ❑ yes X no Packing Material: ❑ Bubble 10 ❑ Bubble Bags ❑ None Other r _ Thermometer Used: IR Gun 1401 Type of Wet Blue None Samples on Ice, cooling process has begun Temp Correction Factor T No Correction i Corrected Cooler Temp.: + 'C Temp should be above freezing to 6°C Biological Tissue is Frozen: Yes No NI� g Comments: Date and In t#i i grson examining contents: 6 rl Chain of Custody Present: Ye []No ❑N/A 1, Chain of Custody Filled Out; Yes ONO ❑NIA 2. Chain of Custody Relinquished: s ❑No ❑NIA 3. Sampler Name &Signature on COC: Ye.,s ❑No ❑N/A 4. Samples Arrived within Hold Time: Yes ❑No ❑NIA 5. Short Hold Time Analysis (<72hr): Dyes PIN9, ON/A 6. Rush Turn Around Time Requested: ❑Y No ❑NrA 7. Sufficient Volume: Y s ❑No ❑NIA 8. Correct Containers Used: -Pace Containers Used: s❑No ZYOQNo ❑wA ❑NIA 9. Containers Intact: es ❑No ❑NIA 10, Filtered volume received for Dissolved tests Dyes ONO FrNIA 11. Sample Labels match COC: -Includes date/time/ID/Analysis Matrix: Yes ONO ❑NIA 12. All containers needing preservation have been checked. All containers needing preservation are found to be in compliance with EPA recommendation, exceptions: VOA, coliform, TOC, O&G, W-DRO (water) Dyes ONO ❑Yes ❑No [-]Yes o NIA NIA 13. Samples checked for dechlorination: Dyes ONO NIA 14. Headspace in VOA Vials ( >6mm): Dyes ONO to Trip Blank Present: Trip Blank Custody Seals Present Pace Trip Blank Lot # (if purchased): - Dyes ONO Dyes ❑No XIA' ❑r r' 1 . Client Notification/ Resolution: Field Data Required? Y / N Person Contacted: Comments/ Resolution: Date/Time: SCURF Review: Dale: SRF Review: Date: Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office ( i.e out of hold, incorrect preservative, out of temp, incorrect containers) WOp:92253896 92253898II IIIIIINIII Page 37 of 38 0 Q ' ua UO Y LD Sit m E U . 0 ©0 p0U-_ G Q I. I 1 1 ICI ,u�Fl c N n I ZNO I 6 I I b i i ; D i i ffi Ey UD Ly I u a tc" i ID o siauiaiu00 io # Ieaoioz 5 oov) Jul zo g - Z s;sa; al;laads;uawlpaS 8-Z 0l pue s laaol - aet zo t' ` E OOi ,0�5 (3OVd) aef zo Hd Qe °SsCli1u] ao a �udayt ` SQrS"�'ar�C IIcosRnn?°;Gc�reC ku eUaa,�u w;�u 1 •1dnluxdooi � geo�et«O A ro- It `�oLNiN wl� baiO C od 1CE a N . ..... •-'- U .-.-.-._.--- Q OCu qjAa a v C-I zo c c 7 , pytI $ -2M1Oi u 02CI! C i'l y oI O I ` y jdLLdOCLl[uaoo oa iawalsnDJ-g Q a G 140P OI SUUMI07 L- - - Tf w E G O I •�- i r 1 - a�^RhUGj lFnw inwasnp .\ IN oCl of 60 a E x o T Q ; t MOSI: 14 m �0 C O a Page 38 of 38 46 of 60 June 23, 2015 Access Analytical 7478 Carlisle Street Irmo, South Carolina 29063 Attn: Mr. Ashley Amick Re: Summary of Laboratory Testing AB Groundwater Assessment Terracon Project No. 73075016 (WOJ15060346) Dear Mr. Amick: Irerracon Terracon has performed the requested laboratory testing program indicated by your Chain of Custody Record, dated 06/15/15. The correspondence indicated hydrometer testing for Samples S-10, S-16, S-10DUP, and ASW-NR1. The results have been electronically forwarded to you in PDF format at aamick@accessanalyticalinc.com, as instructed. If there are any questions regarding the results or if we can be of additional service, please contact us. Sincerely, Terracon Consultants, Inc. Rebecca Simms, CET Laboratory Manager Attachments Copies: 1xc: Above (PDF via email) 1xc: File RS/PM Phillit iso P.E. Geo artment Manager Terracon Consultants, Inc. 521 Clemson Road Columbia, South Carolina 29229 P [803] 741 9000 F [803] 741 9900 terracon.com GRAIN SIZE DISTRIBUTION 47 of 60 ASTM D422 100 95 90 85 80 75 70 65 w 60 >- 55 m w Z 50 LL I— 45 z w 40 w d 35 30 25 20 15 10 5 0 U.S. SIEVE OPENING IN INCHES U.S. SIEVE NUMBERS HYDROMETER n I z a 1n is Qn cn Inn inn 1■■1■IIIIIINN ■1111111■Ilmiiillki gml 1111■■111111■■� 100 10 1 0.1 GRAIN SIZE IN MILLIMETERS 0.01 0.001 I COBBLES GRAVEL I SAND SILT OR CLAY coarse fine coarse I medium I fine Boring ID Depthl AASHTO Classification LL PL PI Cc Cu I• ASW-NR1 0 2.33 15.75I Boring ID Depthl D1o0 Dso D, D10 %Gravel %Sand %Silt f %Clay 0 ASW-NR1 0 2 0.112 0.043 0.007 0.0 54.6 37.0 8.4 PROJECT: AB GW Assessment - Asheville Sediment PROJECT NUMBER: 73075011 SITE: Asheville, North Carolina Irerracon CLIENT: Access Analytical 521 Clemson Road Columbia, South Carolina GRAIN SIZE DISTRIBUTION 48 of 60 ASTM D422 U.S. SIEVE OPENING IN INCHES U.S. SIEVE NUMBERS I HYDROMETER 6 4 3 2 1.5 1 3/4 1123/8 3 4 6 810 1416 20 30 40 50 60 100 140 200 100 95 90 85 80 75 70 65 w 60 >- 55 m z 50 I— 45 z LU 40 w d 35 30 25 20 15 10 5 0 100 10 1 0.1 0.01 0.001 GRAIN SIZE IN MILLIMETERS COBBLES GRAVEL SAND SILT OR CLAY coarse fine coarse medium fine GRAIN SIZE DISTRIBUTION 49 of 60 ASTM D422 U.S. SIEVE OPENING IN INCHES U.S. SIEVE NUMBERS I HYDROMETER 6 4 3 2 1.5 1 3/4 1123/8 3 4 6 810 1416 20 30 40 50 60 100 140 200 100 95 90 85 80 75 70 65 w 60 >- 55 m z 50 I— 45 z LU 40 w d 35 30 25 20 15 10 5 0 100 10 1 0.1 0.01 0.001 GRAIN SIZE IN MILLIMETERS COBBLES GRAVEL SAND SILT OR CLAY coarse fine coarse medium fine GRAIN SIZE DISTRIBUTION 50 of 60 ASTM D422 U.S. SIEVE OPENING IN INCHES U.S. SIEVE NUMBERS I HYDROMETER 6 4 3 2 1.5 1 3/4 1123/8 3 4 6 810 1416 20 30 40 50 60 100 140 200 100 95 90 85 80 75 70 65 w 60 >- 55 co Z 50 LL I- 45 z LU 40 w d 35 30 25 20 15 10 Ilk 0 L: 100 10 1 0.1 0.01 0.001 GRAIN SIZE IN MILLIMETERS COBBLES GRAVEL SAND SILT OR CLAY coarse fine coarse medium fine ¢ of* ¢ a © ° Q$ z z z z 7 cc JC?W DC CT. �� ar�U �O G �1 O -0Zp .o � [CrJ" N U LL W N 5 y O Y—' -. 73 L w i O c i o ii m w 0 WJ r c 'm 2 o it "S oC u © c2si Euo 4U)r u U3 o L cnv~ c$ m N w ? t z z c 3 �'t �. m n�+ ��`� V �m w -� v •fie - 'rqm.D-. Q a C7 Ua fL O } t moS h3oc ?'e r r r ?- _ cu SM amn 4]roy Q U ?nN ma¢6 t� !C U n v o� rn$ a C -J- co g �cLo x ov�c�_ '1 11 of y C N L V Q% m� �a © E o � � c cn a 0 ro _r aCD U s � —* ` O a �sa!r neeleup e1r ns6�zurs T I'llue s�sl:la'n nsWca'e eaA)eaa k'°eAleue GJ �.. r�tt�r=�rf.�rr�tr�:r�rtrrt v HT s t 'StSx'iVKV ff`d I Q� t 4' (1C'�321 ?P.Mflm Pvqm Fes- ?A-i- x ✓, J L 4mlgsUw 41aLLigU!» 9iZUleitOo StdUl�lltl] 84lUlgUIX] SZ Ii�C7Un� �'W4g1Y» bn ' WiU5631Y» 'C7 r W L rn U !' Do 4 f E� z ef, z--4 qel G] O fA � 7 'O ` Q Cf) 0 O O r W 52 of 60 Acass ANALYTICAL, INC. ANALYTICAL REPORT CLIENT Duke Energy 13339 Hagers Ferry Rd. Huntersville NC 28078 ATTENTION Marge Galvin -Karr PROJECT ID J15060346 LABORATORY REPORT NUMBER 15061777 DATE June 22, 2015 Primary Data Review By Secondary Data Review By Ashley Amick Chantelle Kanhai Project Manager, Access Analytical Project Manager, AES aamick@axs-inc.com PLEASE NOTE: - Unless otherwise noted, all analysis on this report performed at Analytical Environmental Services Inc. (AES Inc), 3080 Presidential Drive, Atlanta, GA 30340. - AES is SCDHEC certified laboratory # 98016, NCDENR certified lab # 562, GA certified lab # FL-E87582, NELAP certified laboratory # E87582 - Local support services for this project are provided by Access Analytical, Inc. Access Analytical is a representative of AES serving client in the SC/NC/GA areas. All questions regarding this report should be directed to your local Access Analytical representative at 803.781.4243 or toll fee at 883.315.4243 Page 1 of 8 - - --%SQl71 Synterra EDD -•- --- - ---- ------•----------- -------- - - 53 of 60 ...................... - - - --- -------- .......- Anal ical Laboratory Use Onl Pas DUKE Analytical Laboratory Services Nc—x- i wo a order SOIL sc= i DISTRIBUTION I I—: - /' matrix: OH Mail Code MG03A2 (Building 7405) I i , / i 117 s inatin From --� ORIGINAL to LAB, 13339 Hagen Ferry Rd I ! COPY to CLIENT 'ENERGY Huntersville, N. C. 26078 jLogOed 6y Date S Time i c , ,A M (980) 876-6246 i i /i/_l) rc�/ /� l SAMPLE PROGRAM Ground Water _ 1 ......... Fax_LSOi876:4349----_-_--, t NPDES_ Other_ Plant_ 2)Phons No: ACCeSS Arla�ytlCa� �3 �. 1 }Pro)ect Name AB Groundwater Assessment - Soil PO Number 1142057 cooler Tam c 4}Faz No: "Pr Serv.:1z 7)CIIeM AB GW L� - 2=H Oa 3 � �N 1 J 4- In 6)PreN iect IO: 7)Mall Code: JI Pace c P )Business Unit: m YA e PC 1142081 teletc all r = o a w 9)Activity ID: 1a)Process ID . 3) Operating Unit: IredS. C iW.: - -- QCL Q Q J specific accounting Preservatives when used must be W n v, 0 )r added within 16 minutes of sample C Q ++ U co a r "! o i,,��, �� u -0 . collection N V- IL E 'C J -••-••- - 74Collection Information d a a Q o R -a 00 Q -LAB USE ONLY ! Matrix • Z c j j 0 a�� F- rnQ Nt�IQ j "Lob ID (sell, sedpn.M. Ash) 13Sam (e Description or ID Date nme SI nature Sediment 1/ iL b l 210 I I Z T<D / 21 I t Z I {� i I � l - I I 1 I j I I 1 I 1 " 1 1 _ j 1 �-1 ; I j I . I I L 22Requested TurnarOul 14 Days x4 •7 Days •48 Hr Metals: AI, Sb, As, Ba, Be, B, Cd, Ca, Cr, Co, Cu, Fe, Pb, Mg, Mn, Mo, Ni, K, Se, Na, Sr, Ti, V, Zn, Mercury, pH Anions: Cl, Nitrate-N, SO4 Sediment Specific Parameters: CEC, Particle Size Distribution, Redox Potential Analytical Environmental Services, Inc Date: 22-Jun-1554 of 60 Client: Duke Energy Project: J15060346 Case Narrative Lab ID: 1506F77 REDOX POTENTIAL 1506F77-001 310.4 mV 274.7 mV 245.0 mV 1506F77-002 238.2 mV 191.3 mV 38.7 mV 1506F77-003 4.2 mV 9.9 mV 1.7 mV 1506F77-004 6.9 mV 14.9 mV 8.5 mV Page 3 of 8 55 of 60 Analytical Environmental Services, Inc Date: 22-Jun-15 Client: Duke Energy Client Sample ID: 5-10 Project Name: J15060346 Collection Date: 6/10/2015 12:10:00 PM Lab ID: 15061777-001 Matrix: Sediment Reporting Dilution Analyses Result Qual Units BatchID Date Analyzed Analyst Limit Factor CEC of Soils (Na Saturation) SW9081 Cation Exchange Capacity Qualifiers: r Value exceeds maximum contaminant level BRL Below reporting limit H Holding times for preparation or analysis exceeded N Analyte not NELAC certified B Analyte detected in the associated method blank > Greater than Result value (SW9081) 3.1 1.0 meq/100g 208876 1 06/18/2015 00:00 IO E Estimated (value above quantitation range) S Spike Recovery outside limits due to matrix Nan See case narrative NC Not confirmed < Less than Result value J Estimated value detected below Reporting Limit Page 4 of 8 56 of 60 Analytical Environmental Services, Inc Date: 22-Jun-15 Client: Duke Energy Client Sample ID: S-16 Project Name: J15060346 Collection Date: 6/10/2015 11:05:00 AM Lab ID: 15061777-002 Matrix: Sediment Reporting Dilution Analyses Result Qual Units BatcbID Date Analyzed Analyst Limit Factor CEC of Soils (Na Saturation) SW9081 Cation Exchange Capacity Qualifiers: r Value exceeds maximum contaminant level BRL Below reporting limit H Holding times for preparation or analysis exceeded N Analyte not NELAC certified B Analyte detected in the associated method blank > Greater than Result value (SW9081) 3.5 1.0 meq/100g 208876 1 06/18/2015 00:00 IO E Estimated (value above quantitation range) S Spike Recovery outside limits due to matrix Nan See case narrative NC Not confirmed < Less than Result value J Estimated value detected below Reporting Limit Page 5 of 8 57 of 60 Analytical Environmental Services, Inc Date: 22-Jun-15 Client: Duke Energy Client Sample ID: S-10 DUP Project Name: J15060346 Collection Date: 6/10/2015 12:20:00 PM Lab ID: 15061777-003 Matrix: Sediment Reporting Dilution Analyses Result Qual Units BatcbID Date Analyzed Analyst Limit Factor CEC of Soils (Na Saturation) SW9081 Cation Exchange Capacity Qualifiers: r Value exceeds maximum contaminant level BRL Below reporting limit H Holding times for preparation or analysis exceeded N Analyte not NELAC certified B Analyte detected in the associated method blank > Greater than Result value (SW9081) 4.8 1.0 meq/100g 208876 1 06/18/2015 00:00 IO E Estimated (value above quantitation range) S Spike Recovery outside limits due to matrix Nan See case narrative NC Not confirmed < Less than Result value J Estimated value detected below Reporting Limit Page 6 of 8 Analytical Environmental Services, Inc Date: 22-Jun-15 Client: Duke Energy Client Sample ID: ASW-NR1 Project Name: J15060346 Collection Date: 6/10/2015 12:50:00 PM Lab ID: 15061777-004 Matrix: Sediment Reporting Dilution Analyses Result Qual Units BatcbID Date Analyzed Analyst Limit Factor CEC of Soils (Na Saturation) SW9081 Cation Exchange Capacity Qualifiers: r Value exceeds maximum contaminant level BRL Below reporting limit H Holding times for preparation or analysis exceeded N Analyte not NELAC certified B Analyte detected in the associated method blank > Greater than Result value (SW9081) 4.3 1.0 meq/100g 208876 1 06/18/2015 00:00 IO E Estimated (value above quantitation range) S Spike Recovery outside limits due to matrix Nan See case narrative NC Not confirmed < Less than Result value J Estimated value detected below Reporting Limit Page 7 of 8 59 of 60 Analytical E»vironniental Services, Inc. Sample/Cooler Receipt Checklist Client _ 461-155 Checklist completed by 6 eg lI S ! T Signat re Date Carrier name: FedEY ZUPS _ Courier— Client— US Mail Other Stripping container/cooler in good condition? Custody seals intact on shipping container/cooler? Custody seals intact on sample bottles? Work Order Number /50aF'77 Yes I No Yes No Yes No Container/Temp /Blank temperature in compliance? (0°<_G°C)* Yes Cooler #1 3. -[ Cooler #2 Cooler #3 Cooler #4 Chain of custody present? Yes Chain of custody signed when relinquished and received? Yes Chain of custody agrees with sample labels? Yes Samples in proper container/bottle? Yes Sample containers intact? Yes Sufficient sample voitu-ne for indicated test? Yes All samples received within holding time? Yes Was TAT marked on the COC? Yes Proceed with Standard TAT as per project history? Yes Water - VOA vials have zero headspace? No VOA vials submitted Water - pH acceptable upon receipt? Yes Adjusted? Sample Condition: Good Other(Explain) (For diffusive samples or AIHA lead) Is a known blank included? See Case Narrative for resolution of the Non-Cortfornrance. No Not Present Not Present Not Present Cooler#5 No No No No No No No No No _ Yes No Checked by Cooler #G Not Applicable No / Not Applicable Yes No Z * Samples do not have to comply with the given range for certain parameters. 11Aes_scrver111Samp1e ReceiptVMy Documents\COCs and pH Adjustment Shect\Sanrple Cooler Recipt Checklist_Revl.rtf Page 8 of 8 x�J 60 of 60 �� v�stoma: r: csi Con±pl�r.e - N 9 m! m s w! moil _ 21 o tl o 1� Z 3 3 M - W m Customer to complete appropriate columns to right n £ i D rn 3 _ V f1w rC ry i � m L C ✓T L O .n {� V m (0 CO y ^ = N W p7 w 9� 4 (D i ya Q rt jT 3Wm >y ar ® Z C. N _. to o c Z c c Z I o� Q a' fl G 0 � a• V� \ X D -0 D ----- r, . rD G `� COL T T 0 3 D (D nS 'z CD o i a roof °�- v » S LA= Q P . ID Ln i • 7 i V N I a N ' 3 it 3 C O A Ow 2 m = It ° ', ` ''Grab Req ire H to Total Meials ,Anions, a PH 1 - 8 oz jar (PACE) 5 Io TOC 1 - 4 oz jar 4 a — — — — (PACE) m w I o � S -Total Viand Anlo 2-8 D 3 a s jars (PAC 0 5 Sediment specific tests 2 - 8 oz jar (ACCESS I a° N N ANALYTICAL) a 5 � a Z m � I^ 00 w s � C Z A o D W \ 0 0:: _ o Ci r O v ZOz 0 ;= 2'Total # of Containers 0 VA im u •1: N1—/ Al"