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Home My WebLink AboutNC0003417_J15050429 Report_20150805+ DUKE Analytical Laboratory ENERGY 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone:980-875-5245 Fax:980-875-4349 Order Summary Report Order Number: J15050429 Project Name: HF LEE PLANT - AB GW ASSESSMENT SOIL Customer Name(s): Tim Hunsucker, Judd Mahan, Kathy Webb, John Toepfer Customer Address: 1677 Old Smithfield Rd Goldsboro NC 27530, Lab Contact: Margaret Galvin -Karr Phone: 980-875-5219 MXG4644 (101161) Report Authorized By: 2015.06.13 11:52:22 (Signature) 0400 Date: �"`N RGY Margaret Galvin -Karr Program Comments: Please contact the Program Manager (Margaret Galvin -Karr) with any questions regarding this report. Data Flags & Calculations: 6/13/2015 1 of 70 Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Sample ID's & Descriptions: 2ot70 Collection Sample ID Plant/Station Date and Time Collected By Sample Description 2015014795 HF LEE PLANT 11-May-15 10:45 AM Judd Mahan IMW-3(0.5-2) 2015014796 HF LEE PLANT 11-May-15 10:58 AM Judd Mahan IMW-3(4-5) 2015014797 HF LEE PLANT 11-May-15 1:22 PM Judd Mahan IMW-3(8-9) 2015014798 HF LEE PLANT 13-May-15 8:56 AM Judd Mahan LLMW-3(2-3) 2015014799 HF LEE PLANT 11-May-15 10:00 AM Judd Mahan Equipment Blank 2015014800 HF LEE PLANT 13-May-15 8:30 AM Judd Mahan Equipment Blank 6 Total Samples 3 of 70 Technical Validation Review Checklist: COC and .pdf report are in agreement with sample totals Yes No and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. ❑ Yes❑ No All laboratory QA/QC requirements are acceptable.❑ Yes ❑ No Report Sections Included: U Job Summary Report ❑ Sample Identification n Technical Validation of Data Package ❑ Analytical Laboratory Certificate of Analysis ❑ Analytical Laboratory QC Report Reviewed By: Date: Sub -contracted Laboratory Results ❑ Customer Specific Data Sheets, Reports, & Documentation ❑ Customer Database Entries 0 Chain of Custody [I/0] Electronic Data Deliverable (EDD) Sent Separately Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050429 Site: IMW-3(0.5-2) Collection Date: 11-Mav-15 10:45 AM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 4 of 70 Sample #: 2015014795 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050429 Site: IMW-3(4-5) Collection Date: 11-Mav-15 10:58 AM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 5 of 70 Sample #: 2015014796 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050429 Site: IMW-3(8-9) Collection Date: 11-May-15 1:22 PM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 6 of 70 Sample #: 2015014797 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050429 Site: LLMW-3(2-3) Collection Date: 13-Mav-15 8:56 AM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 7 of 70 Sample #: 2015014798 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050429 Site: Equipment Blank Collection Date: 11-May-15 10:00 AM Analyte Result Units Qualifiers RDL DF METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Sample #: 2015014799 Matrix: SOIL 8 of 70 Method Analysis Date/Time Analyst Vendor Method V_PACE Certificate of Laboratory Analysis 9 of 70 This report shall not be reproduced, except in full. Order # J15050429 Site: Equipment Blank Collection Date: 13-May-15 8:30 AM Analyte Result Units Qualifiers RDL DF METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Sample #: 2015014800 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 )i6,8y fde. Suite 100 Huntersville, INC 28078 (704)875-9092 June 09, 2015 Program Manager Duke Energy 13339 Hagers Ferry Road Bldg.7405 MG30A2 Huntersville, NC 28078 RE: Project: J 15050429 Pace Project No.: 92250342 Dear Program Manager: Enclosed are the analytical results for sample(s) received by the laboratory on May 18, 2015. The results relate only to the samples included in this report. Results reported herein conform to the most current TN standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Herring kevin.herring@pacelabs.com HORIZON Database Administrator Enclosures cc: Marge Galvin -Karr, Duke Energy Program Manager, Duke Energy Mary Ann Ogle, Duke Energy Rodney Wilke, Duke Energy p«FO REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, lqe� �� without the written consent of Pace Analytical Services, Inc.. BRAT, Page 1 of 60 lacmnalyfica( www.pacelabs.com Pace Analytical Services, Inc. 9800 FSiinfflde. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15050429 Pace Project No.: 92250342 Minnesota Certification IDs 1700 Elm Street SE Suite 200, Minneapolis, MN 55414 A21-A Certification #: 2926.01 Alaska Certification #: UST-078 Alaska Certification #MN00064 Alabama Certification #40770 Arizona Certification #: AZ-0014 Arkansas Certification #: 88-0680 California Certification #: 01155CA Colorado Certification #Pace Connecticut Certification #: PH-0256 EPA Region 8 Certification #: 8TMS-L Florida/NELAP Certification #: E87605 Guam Certification #:14-008r Georgia Certification #: 959 Georgia EPD #: Pace Idaho Certification #: MN00064 Hawaii Certification #MN00064 Illinois Certification #: 200011 Indiana Certification#C-MN-01 Iowa Certification #: 368 Kansas Certification #: E-10167 Kentucky Dept of Envi. Protection - DW #90062 Kentucky Dept of Envi. Protection - WW #:90062 Louisiana DEQ Certification #: 3086 Louisiana DHH #: LA140001 Maine Certification #: 2013011 Maryland Certification #: 322 Michigan DEPH Certification #: 9909 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification #: 41320 Connecticut Certification #: PH-0216 Delaware Certification: FL NELAC Reciprocity Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Massachusetts Certification #: M-FL1264 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Green Bay Certification IDs 1241 Bellevue Street, Green Bay, WI 54302 Florida/NELAP Certification #: E87948 Illinois Certification #: 200050 Kentucky Certification #: 82 Louisiana Certification #: 04168 Minnesota Certification #: 055-999-334 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 CERTIFICATIONS Minnesota Certification #: 027-053-137 Mississippi Certification #: Pace Montana Certification #: MT0092 Nevada Certification #: MN_00064 Nebraska Certification #: Pace New Jersey Certification #: MN-002 New York Certification #: 11647 North Carolina Certification #: 530 North Carolina State Public Health #: 27700 North Dakota Certification #: R-036 Ohio EPA#: 4150 Ohio VAP Certification #: CL101 Oklahoma Certification #: 9507 Oregon Certification #: MN200001 Oregon Certification #: MN300001 Pennsylvania Certification #: 68-00563 Puerto Rico Certification Saipan (CNMI) #:MP0003 South Carolina #:74003001 Texas Certification #: T104704192 Tennessee Certification #: 02818 Utah Certification #: MN000642013-4 Virginia DGS Certification #: 251 Virginia/VELAP Certification #: Pace Washington Certification #: C486 West Virginia Certification #: 382 West Virginia DHHR #:9952C Wisconsin Certification #: 999407970 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 Nevada Certification: FL NELAC Reciprocity New Hampshire Certification #: 2958 New Jersey Certification #: FL765 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FLO1264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 Washington Certification #: C955 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity North Dakota Certification #: R-150 South Carolina Certification #: 83006001 Texas Certification #: T104704529-14-1 US Dept of Agriculture #: S-76505 Wisconsin Certification #: 405132750 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 2 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 f iQ'8y fde. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15050429 Pace Project No.: 92250342 Asheville Certification IDs North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 CERTIFICATIONS West Virginia Certification #: 356 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 3 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 f ig'8y fde. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: J15050429 Pace Project No.: 92250342 Lab ID Sample ID Matrix Date Collected Date Received 92250342001 2015014795 Solid 05/11/1510:45 05/18/15 14:35 92250342002 2015014796 Solid 05/11/1510:58 05/18/15 14:35 92250342003 2015014797 Solid 05/11/1513:22 05/18/15 14:35 92250342004 2015014798 Solid 05/13/15 08:56 05/18/15 14:35 92250342005 2015014799 Water 05/11/1510:00 05/18/15 14:35 92250342006 2015014800 Water 05/13/15 08:30 05/18/15 14:35 92250342007 2015014798 SPLP Water 05/13/15 08:56 05/18/15 14:35 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 4 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffli '8yfde. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: J15050429 92250342 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92250342001 2015014795 EPA 6010 TAP 16 PASI-0 EPA 6020 DRS 8 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 MLO 1 PASI-O EPA 9045 MAB 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92250342002 2015014796 EPA 6010 TAP 16 PASI-0 EPA 6020 DRS 8 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 MLO 1 PASI-O EPA 9045 MAB 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92250342003 2015014797 EPA 6010 TAP 16 PASI-0 EPA 6020 DRS 8 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 MLO 1 PASI-O EPA 9045 MAB 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92250342004 2015014798 EPA 6010 TAP 16 PASI-0 EPA 6020 DRS 8 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 MLO 1 PASI-O EPA 9045 MAB 1 PASI-A EPA 300.0 AES2 1 PASI-A EPA 353.2 DMN 1 PASI-A SM 4500-CI-E SER 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92250342005 2015014799 EPA 6020A RJS 24 PASI-M EPA 7470A JDD 1 PASI-M REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 5 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 f ig'8y fde. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: J15050429 92250342 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92250342006 2015014800 EPA 6020A RJS 24 PASI-M EPA 7470A JDD 1 PASI-M 92250342007 2015014798 SPLP EPA 6020A TT3 24 PASI-M EPA 7470A JDD 1 PASI-M REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 6 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffli '8yfde. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15050429 Pace Project No.: 92250342 Lab Sample ID Client Sample ID Method Parameters SUMMARY OF DETECTION Result Units Report Limit Analyzed 92250342001 2015014795 EPA 6010 Aluminum 2340 mg/kg 27.7 05/30/15 21:41 EPA 6010 Barium 14.0 mg/kg 2.8 05/30/15 21:41 EPA 6010 Chromium 2.5 mg/kg 1.4 05/30/15 21:41 EPA 6010 Copper 1.7 mg/kg 1.4 05/30/15 21:41 EPA 6010 Iron 2600 mg/kg 11.1 05/30/15 21:41 EPA 6010 Manganese 4.5 mg/kg 1.4 05/30/15 21:41 EPA 6010 Zinc 8.3 mg/kg 5.5 05/30/15 21:41 EPA 6020 Lead 43.1 mg/kg 5.5 05/29/15 12:38 EPA 6020 Vanadium 6.7 mg/kg 5.5 05/29/15 12:38 EPA 7471 Mercury 0.024 mg/kg 0.0090 05/30/15 14:05 ASTM D2974-87 Percent Moisture 8.4 % 0.10 06/03/15 10:21 EPA 9045 pH at 25 Degrees C 4.6 Std. Units 0.10 05/28/15 15:25 EPA 9060 Total Organic Carbon 4110 mg/kg 653 06/03/15 21:21 EPA 9060 Total Organic Carbon 3780 mg/kg 649 06/03/15 21:27 EPA 9060 Total Organic Carbon 4530 mg/kg 650 06/03/15 21:34 EPA 9060 Total Organic Carbon 4390 mg/kg 654 06/03/15 21:40 EPA 9060 Mean Total Organic Carbon 4200 mg/kg 652 06/03/15 21:21 EPA 9060 RSD% 7.8 % 06/03/15 21:21 92250342002 2015014796 EPA 6010 Aluminum 5670 mg/kg 32.2 05/30/15 21:45 EPA 6010 Barium 44.7 mg/kg 3.2 05/30/15 21:45 EPA 6010 Beryllium 0.30J mg/kg 0.32 05/30/15 21:45 EPA 6010 Calcium 111J mg/kg 161 05/30/15 21:45 EPA 6010 Chromium 6.3 mg/kg 1.6 05/30/15 21:45 EPA 6010 Copper 1 AJ mg/kg 1.6 05/30/15 21:45 EPA 6010 Iron 24200 mg/kg 12.9 05/30/15 21:45 EPA 6010 Magnesium 186 mg/kg 161 05/30/15 21:45 EPA 6010 Manganese 6.3 mg/kg 1.6 05/30/15 21:45 EPA 6010 Strontium 3.OJ mg/kg 3.2 05/30/15 21:45 EPA 6020 Lead 8.9 mg/kg 6.4 05/29/15 12:41 EPA 6020 Vanadium 22.4 mg/kg 6.4 05/29/15 12:41 ASTM D2974-87 Percent Moisture 21.5 % 0.10 06/03/15 10:21 EPA 9045 pH at 25 Degrees C 4.7 Std. Units 0.10 05/28/15 15:25 EPA 9060 Total Organic Carbon 1080 mg/kg 765 06/03/15 21:46 EPA 9060 Total Organic Carbon 1130 mg/kg 761 06/03/15 21:53 EPA 9060 Total Organic Carbon 1020 mg/kg 769 06/03/15 21:59 EPA 9060 Total Organic Carbon 1240 mg/kg 758 06/03/15 22:05 EPA 9060 Mean Total Organic Carbon 1120 mg/kg 763 06/03/15 21:46 EPA 9060 RSD% 8.2 % 06/03/15 21:46 92250342003 2015014797 EPA 6010 Aluminum 2910 mg/kg 27.5 05/30/15 21:49 EPA 6010 Barium 92.0 mg/kg 2.7 05/30/15 21:49 EPA 6010 Beryllium 0.53 mg/kg 0.27 05/30/15 21:49 EPA 6010 Calcium 444 mg/kg 137 05/30/15 21:49 EPA 6010 Chromium 4.6 mg/kg 1.4 05/30/15 21:49 EPA 6010 Copper 2.6 mg/kg 1.4 05/30/15 21:49 REPORT OF LABORATORY ANALYSIS Qualifiers This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 7 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffli .8yfde. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15050429 Pace Project No.: 92250342 Lab Sample ID Client Sample ID Method Parameters SUMMARY OF DETECTION Result Units Report Limit Analyzed Qualifiers 92250342003 2015014797 EPA 6010 Iron 2250 mg/kg 11.0 05/30/15 21:49 EPA 6010 Magnesium 284 mg/kg 137 05/30/15 21:49 EPA 6010 Manganese 21.7 mg/kg 1.4 05/30/15 21:49 EPA 6010 Nickel 1.4 mg/kg 1.4 05/30/15 21:49 EPA 6010 Strontium 6.2 mg/kg 2.7 05/30/15 21:49 EPA 6020 Lead 3AJ mg/kg 5.5 05/29/15 12:44 EPA 6020 Vanadium 10.3 mg/kg 5.5 05/29/15 12:44 EPA 7471 Mercury 0.0070J mg/kg 0.0088 05/30/15 14:10 ASTM D2974-87 Percent Moisture 8.0 % 0.10 06/03/15 10:21 EPA 9045 pH at 25 Degrees C 4.9 Std. Units 0.10 05/28/15 15:25 EPA 9060 Total Organic Carbon 374J mg/kg 654 06/03/15 22:12 EPA 9060 Total Organic Carbon 466J mg/kg 654 06/03/15 22:18 EPA 9060 Total Organic Carbon 414J mg/kg 653 06/03/15 22:25 EPA 9060 Total Organic Carbon 441J mg/kg 657 06/03/15 22:31 EPA 9060 Mean Total Organic Carbon 424J mg/kg 654 06/03/15 22:12 EPA 9060 RSD% 9.3 % 06/03/15 22:12 92250342004 2015014798 EPA 6010 Aluminum 8610 mg/kg 49.9 05/30/15 21:53 EPA 6010 Barium 495 mg/kg 5.0 05/30/15 21:53 EPA 6010 Beryllium 3.2 mg/kg 0.50 05/30/15 21:53 EPA 6010 Calcium 10200 mg/kg 250 05/30/15 21:53 EPA 6010 Chromium 14.9 mg/kg 2.5 05/30/15 21:53 EPA 6010 Copper 23.9 mg/kg 2.5 05/30/15 21:53 EPA 6010 Iron 22500 mg/kg 20.0 05/30/15 21:53 EPA 6010 Magnesium 1080 mg/kg 250 05/30/15 21:53 EPA 6010 Manganese 245 mg/kg 2.5 05/30/15 21:53 EPA 6010 Nickel 12.1 mg/kg 2.5 05/30/15 21:53 EPA 6010 Potassium 616 mg/kg 499 05/30/15 21:53 EPA 6010 Strontium 166 mg/kg 5.0 05/30/15 21:53 EPA 6010 Zinc 7.9J mg/kg 10 05/30/15 21:53 EPA 6020 Arsenic 55.2 mg/kg 10 05/29/15 12:46 EPA 6020 Cobalt 6.OJ mg/kg 10 05/29/15 12:46 EPA 6020 Lead 5AJ mg/kg 10 05/29/15 12:46 EPA 6020 Selenium 5.7J mg/kg 10 05/29/15 12:46 EPA 6020 Vanadium 31.0 mg/kg 10 05/29/15 12:46 EPA 7471 Mercury 0.095 mg/kg 0.015 05/30/15 14:12 ASTM D2974-87 Percent Moisture 47.3 % 0.10 06/03/15 10:21 EPA 9045 pH at 25 Degrees C 7.0 Std. Units 0.10 05/28/15 15:25 EPA 300.0 Sulfate 6.0 mg/L 3.8 05/31/15 05:16 B EPA 9060 Total Organic Carbon 56900 mg/kg 4530 06/03/15 22:37 EPA 9060 Total Organic Carbon 74100 mg/kg 4550 06/03/15 22:50 EPA 9060 Total Organic Carbon 84900 mg/kg 4460 06/03/15 23:00 EPA 9060 Total Organic Carbon 129000 mg/kg 4440 06/03/15 23:09 EPA 9060 Mean Total Organic Carbon 86300 mg/kg 4490 06/03/15 22:37 EPA 9060 RSD% 35.8 % 06/03/15 22:37 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 8 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffli '8yfde. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15050429 Pace Project No.: 92250342 Lab Sample ID Client Sample ID Method Parameters SUMMARY OF DETECTION Result Units Report Limit Analyzed 92250342005 2015014799 EPA 6020A Aluminum 7.OJ ug/L 10.0 05/27/15 13:56 EPA 6020A Antimony 0.22J ug/L 0.50 05/27/15 13:56 EPA 6020A Barium 0.17J ug/L 0.30 05/27/15 13:56 EPA 6020A Calcium 57.1 ug/L 40.0 05/27/15 13:56 EPA 6020A Magnesium 14.3 ug/L 10.0 05/27/15 13:56 EPA 6020A Manganese 0.31J ug/L 0.50 05/27/15 13:56 EPA 6020A Potassium 14.7J ug/L 50.0 05/27/15 13:56 EPA 6020A Sodium 80.4 ug/L 50.0 05/27/15 13:56 EPA 6020A Strontium 0.30J ug/L 0.50 05/27/15 13:56 92250342006 2015014800 EPA 6020A Aluminum 6.5J ug/L 10.0 05/27/15 14:00 EPA 6020A Calcium 21.1J ug/L 40.0 05/27/15 14:00 EPA 6020A Magnesium 5AJ ug/L 10.0 05/27/15 14:00 EPA 6020A Potassium 13AJ ug/L 50.0 05/27/15 14:00 EPA 6020A Sodium 20.7J ug/L 50.0 05/27/15 14:00 92250342007 2015014798 SPLP EPA 6020A Aluminum 157 ug/L 10.0 06/02/15 10:21 EPA 6020A Antimony 2.8 ug/L 0.50 06/01/1518:04 EPA 6020A Arsenic 25.9 ug/L 0.50 06/01/1518:04 EPA 6020A Barium 243 ug/L 0.30 06/01/1518:04 EPA 6020A Boron 133 ug/L 5.0 06/01/1518:04 EPA 6020A Cadmium 0.026J ug/L 0.080 06/01/1518:04 EPA 6020A Calcium 16800 ug/L 40.0 06/01/1518:04 EPA 6020A Chromium 0.84 ug/L 0.50 06/01/1518:04 EPA 6020A Cobalt 0.21J ug/L 0.50 06/01/1518:04 EPA 6020A Copper 4.1 ug/L 1.0 06/01/1518:04 EPA 6020A Iron 130 ug/L 50.0 06/01/1518:04 EPA 6020A Lead 0.32 ug/L 0.10 06/01/1518:04 EPA 6020A Magnesium 343 ug/L 10.0 06/01/1518:04 EPA 6020A Manganese 104 ug/L 0.50 06/01/1518:04 EPA 6020A Molybdenum 1.4 ug/L 0.50 06/01/1518:04 EPA 6020A Nickel 1.5 ug/L 0.50 06/01/1518:04 EPA 6020A Potassium 725 ug/L 50.0 06/01/1518:04 EPA 6020A Selenium 10.5 ug/L 0.50 06/01/1518:04 EPA 6020A Sodium 1460 ug/L 50.0 06/01/1518:04 EPA 6020A Strontium 166 ug/L 0.50 06/01/1518:04 EPA 6020A Thallium 0.026J ug/L 0.10 06/01/1518:04 EPA 6020A Vanadium 22.9 ug/L 1.0 06/01/1518:04 EPA 6020A Zinc 90.5 ug/L 5.0 06/01/1518:04 REPORT OF LABORATORY ANALYSIS Qualifiers This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 9 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffli ,8yfde. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15050429 Pace Project No.: 92250342 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: June 09, 2015 General Information: 4 samples were analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/24366 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92245394022 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1226123) • Aluminum • Barium • Boron • Copper • Iron • Molybdenum • MSD (Lab ID: 1226124) • Aluminum • Barium • Boron • Chromium • Copper • Iron • Manganese R1: RPD value was outside control limits. • MSD (Lab ID: 1226124) REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 10 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KPi '8yfde. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15050429 Pace Project No.: 92250342 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: June 09, 2015 QC Batch: MPRP/24366 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92245394022 R1: RPD value was outside control limits. • Iron Additional Comments: Batch Comments: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. • QC Batch: ICP / 14887 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 11 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 tf�nic&)rfde. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15050429 Pace Project No.: 92250342 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: June 09, 2015 General Information: 4 samples were analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/24367 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92245394022 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • MS (Lab ID: 1226127) • Antimony • Arsenic • Selenium • Thallium • Vanadium • MSD (Lab ID: 1226128) • Antimony • Cadmium • Lead • Selenium • Thallium • Vanadium REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 12 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K2'8y fd.. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15050429 Pace Project No.: 92250342 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: June 09, 2015 Additional Comments: Batch Comments: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. • QC Batch: ICPM / 9867 Analyte Comments: QC Batch: MPRP/24367 N2: The lab does not hold TNI accreditation for this parameter. •2015014795 (Lab ID:92250342001) • Antimony •2015014796 (Lab ID:92250342002) • Antimony •2015014797 (Lab ID:92250342003) • Antimony •2015014798 (Lab ID:92250342004) • Antimony • BLANK (Lab ID: 1226125) • Antimony • LCS (Lab ID: 1226126) • Antimony • MS (Lab ID: 1226127) • Antimony • MSD (Lab ID: 1226128) • Antimony REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 13 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KS'8y fd.. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15050429 Pace Project No.: 92250342 Method: EPA 6020A Description: 6020A MET ICPMS Client: Duke Energy Date: June 09, 2015 General Information: 3 samples were analyzed for EPA 6020A. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3020 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/54605 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92250183001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1973803) • Aluminum • Calcium • MSD (Lab ID: 1973804) • Aluminum • Calcium QC Batch: MPRP/54772 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 10308223006 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1980685) • Boron • Calcium • Magnesium REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 14 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K4'8y fd.. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15050429 Pace Project No.: 92250342 Method: EPA 6020A Description: 6020A MET ICPMS Client: Duke Energy Date: June 09, 2015 QC Batch: MPRP/54772 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 10308223006 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • Potassium • Sodium • Strontium • MSD (Lab ID: 1980686) • Aluminum • Calcium • Magnesium • Potassium • Sodium • Strontium Additional Comments: Analyte Comments: QC Batch: MPRP/54772 E: Analyte concentration exceeded the calibration range. The reported result is estimated. • MS (Lab ID: 1980685) • Calcium • Sodium • MSD (Lab ID: 1980686) • Calcium • Sodium REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 15 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KPi '8yfde. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15050429 Pace Project No.: 92250342 Method: EPA 7470A Description: 7470A Mercury Client: Duke Energy Date: June 09, 2015 General Information: 3 samples were analyzed for EPA 7470A. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7470A with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 16 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 tf� '8yfde. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15050429 Pace Project No.: 92250342 Method: EPA 7471 Description: 7471 Mercury Client: Duke Energy Date: June 09, 2015 General Information: 4 samples were analyzed for EPA 7471. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7471 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 17 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 l�'8 r fde. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15050429 Pace Project No.: 92250342 Method: EPA 9045 Description: 9045 pH Soil Client: Duke Energy Date: June 09, 2015 General Information: 4 samples were analyzed for EPA 9045. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Duplicate Sample: All duplicate sample results were within method acceptance criteria with any exceptions noted below. QC Batch: WET/37692 D6: The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits. • DUP (Lab ID: 1468313) • pH at 25 Degrees C Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 18 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KPi '8yfde. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15050429 Pace Project No.: 92250342 Method: EPA 300.0 Description: 300.0 IC Anions, SPLP Client: Duke Energy Date: June 09, 2015 General Information: 1 sample was analyzed for EPA 300.0. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. QC Batch: WETA/23110 B: Analyte was detected in the associated method blank. • BLANK for HBN 265986 [WETA/231 (Lab ID: 1471529) • Sulfate Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 19 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 tf� '8yfde. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15050429 Pace Project No.: 92250342 Method: EPA 353.2 Description: 353.2 Nitrogen, NO2/NO3, SPLP Client: Duke Energy Date: June 09, 2015 General Information: 1 sample was analyzed for EPA 353.2. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 1-11: Analysis conducted outside the EPA method holding time. •2015014798 (Lab ID:92250342004) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: WETA/23177 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92249487002,92250202006 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1476702) • Nitrogen, Nitrate • MSD (Lab ID: 1476703) • Nitrogen, Nitrate Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 20 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 %'8yfde. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15050429 Pace Project No.: 92250342 Method: SM 4500-CI-E Description: 4500 Chloride, SPLP Client: Duke Energy Date: June 09, 2015 General Information: 1 sample was analyzed for SM 4500-CI-E. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: WETA/23132 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92249061003,92249703005 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1472685) • Chloride • MSD (Lab ID: 1472686) • Chloride Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 21 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 �nlc&)rfde. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15050429 Pace Project No.: 92250342 Method: EPA 9056 Description: 9056 IC Anions Client: Duke Energy Date: June 09, 2015 General Information: 4 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/46609 DI Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015014795 (Lab ID:92250342001) • Chloride • Sulfate •2015014796 (Lab ID:92250342002) • Chloride • Sulfate •2015014797 (Lab ID:92250342003) • Chloride • Sulfate •2015014798 (Lab ID:92250342004) • Chloride • Sulfate REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 22 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 �2c8y fd.. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15050429 Pace Project No.: 92250342 Method: EPA 9056 Description: 9056 IC Anions 48hr Client: Duke Energy Date: June 09, 2015 General Information: 4 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 1-13: Sample was received or analysis requested beyond the recognized method holding time. •2015014795 (Lab ID:92250342001) •2015014796 (Lab ID:92250342002) •2015014797 (Lab ID:92250342003) •2015014798 (Lab ID:92250342004) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 23 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 t S'8y fd.. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15050429 Pace Project No.: 92250342 Method: EPA 9060 Description: Total Organic Carbon Quad Client: Duke Energy Date: June 09, 2015 General Information: 4 samples were analyzed for EPA 9060. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: This data package has been reviewed for quality and completeness and is approved for release. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 24 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 t 4,8y fd.. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15050429 Pace Project No.: 92250342 Sample: 2015014795 Lab ID: 92250342001 Collected: 05/11/15 10:45 Received: 05/18/15 14:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 2340 mg/kg 27.7 13.9 5 05/28/15 20:10 05/30/15 21:41 7429-90-5 Barium 14.0 mg/kg 2.8 1.4 5 05/28/15 20:10 05/30/15 21:41 7440-39-3 Beryllium ND mg/kg 0.28 0.14 5 05/28/15 20:10 05/30/15 21:41 7440-41-7 Boron ND mg/kg 13.9 6.9 5 05/28/15 20:10 05/30/15 21:41 7440-42-8 Calcium ND mg/kg 139 69.3 5 05/28/15 20:10 05/30/15 21:41 7440-70-2 Chromium 2.5 mg/kg 1.4 0.69 5 05/28/15 20:10 05/30/15 21:41 7440-47-3 Copper 1.7 mg/kg 1.4 0.69 5 05/28/15 20:10 05/30/15 21:41 7440-50-8 Iron 2600 mg/kg 11.1 5.5 5 05/28/15 20:10 05/30/15 21:41 7439-89-6 Magnesium ND mg/kg 139 69.3 5 05/28/15 20:10 05/30/15 21:41 7439-95-4 Manganese 4.5 mg/kg 1.4 0.69 5 05/28/15 20:10 05/30/15 21:41 7439-96-5 Molybdenum ND mg/kg 2.8 1.4 5 05/28/15 20:10 05/30/15 21:41 7439-98-7 Nickel ND mg/kg 1.4 0.69 5 05/28/15 20:10 05/30/15 21:41 7440-02-0 Potassium ND mg/kg 277 139 5 05/28/15 20:10 05/30/15 21:41 7440-09-7 Sodium ND mg/kg 277 139 5 05/28/15 20:10 05/30/15 21:41 7440-23-5 Strontium ND mg/kg 2.8 1.4 5 05/28/15 20:10 05/30/15 21:41 7440-24-6 Zinc 8.3 mg/kg 5.5 2.8 5 05/28/15 20:10 05/30/15 21:41 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 5.5 2.8 100 05/28/15 20:10 05/29/15 12:38 7440-36-0 N2 Arsenic ND mg/kg 5.5 2.8 100 05/28/15 20:10 05/29/15 12:38 7440-38-2 Cadmium ND mg/kg 0.67 0.33 100 05/28/15 20:10 05/29/15 12:38 7440-43-9 Cobalt ND mg/kg 5.5 2.8 100 05/28/15 20:10 05/29/15 12:38 7440-48-4 Lead 43.1 mg/kg 5.5 2.8 100 05/28/15 20:10 05/29/15 12:38 7439-92-1 Selenium ND mg/kg 5.5 2.8 100 05/28/15 20:10 05/29/15 12:38 7782-49-2 Thallium ND mg/kg 5.5 2.8 100 05/28/15 20:10 05/29/15 12:38 7440-28-0 Vanadium 6.7 mg/kg 5.5 2.8 100 05/28/15 20:10 05/29/15 12:38 7440-62-2 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury 0.024 mg/kg 0.0090 0.0045 1 05/28/15 21:30 05/30/15 14:05 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 8.4 % 0.10 0.10 1 06/03/15 10:21 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 4.6 Std. Units 0.10 0.10 1 05/28/15 15:25 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 277 138 5 05/21/15 23:37 16887-00-6 D3 Sulfate ND mg/kg 277 138 5 05/21/15 23:37 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 27.7 13.8 5 05/21/15 23:37 14797-55-8 H3 Date: 06/09/2015 05:14 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 25 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 %,8yfde. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15050429 Pace Project No.: 92250342 Sample: 2015014795 Lab ID: 92250342001 Collected: 05/11/15 10:45 Received: 05/18/15 14:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 4110 mg/kg 653 326 1 06/03/15 21:21 7440-44-0 Total Organic Carbon 3780 mg/kg 649 325 1 06/03/15 21:27 7440-44-0 Total Organic Carbon 4530 mg/kg 650 325 1 06/03/15 21:34 7440-44-0 Total Organic Carbon 4390 mg/kg 654 327 1 06/03/15 21:40 7440-44-0 Mean Total Organic Carbon 4200 mg/kg 652 326 1 06/03/15 21:21 7440-44-0 Surrogates RSD% 7.8 % 1 06/03/15 21:21 Date: 06/09/2015 05:14 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 26 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 %,8yfde. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15050429 Pace Project No.: 92250342 Sample: 2015014796 Lab ID: 92250342002 Collected: 05/11/15 10:58 Received: 05/18/15 14:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 5670 mg/kg 32.2 16.1 5 05/28/15 20:10 05/30/15 21:45 7429-90-5 Barium 44.7 mg/kg 3.2 1.6 5 05/28/15 20:10 05/30/15 21:45 7440-39-3 Beryllium 0.30J mg/kg 0.32 0.16 5 05/28/15 20:10 05/30/15 21:45 7440-41-7 Boron ND mg/kg 16.1 8.0 5 05/28/15 20:10 05/30/15 21:45 7440-42-8 Calcium 111J mg/kg 161 80.4 5 05/28/15 20:10 05/30/15 21:45 7440-70-2 Chromium 6.3 mg/kg 1.6 0.80 5 05/28/15 20:10 05/30/15 21:45 7440-47-3 Copper 1.4J mg/kg 1.6 0.80 5 05/28/15 20:10 05/30/15 21:45 7440-50-8 Iron 24200 mg/kg 12.9 6.4 5 05/28/15 20:10 05/30/15 21:45 7439-89-6 Magnesium 186 mg/kg 161 80.4 5 05/28/15 20:10 05/30/15 21:45 7439-95-4 Manganese 6.3 mg/kg 1.6 0.80 5 05/28/15 20:10 05/30/15 21:45 7439-96-5 Molybdenum ND mg/kg 3.2 1.6 5 05/28/15 20:10 05/30/15 21:45 7439-98-7 Nickel ND mg/kg 1.6 0.80 5 05/28/15 20:10 05/30/15 21:45 7440-02-0 Potassium ND mg/kg 322 161 5 05/28/15 20:10 05/30/15 21:45 7440-09-7 Sodium ND mg/kg 322 161 5 05/28/15 20:10 05/30/15 21:45 7440-23-5 Strontium 3.OJ mg/kg 3.2 1.6 5 05/28/15 20:10 05/30/15 21:45 7440-24-6 Zinc ND mg/kg 6.4 3.2 5 05/28/15 20:10 05/30/15 21:45 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 6.4 3.2 100 05/28/15 20:10 05/29/15 12:41 7440-36-0 N2 Arsenic ND mg/kg 6.4 3.2 100 05/28/15 20:10 05/29/15 12:41 7440-38-2 Cadmium ND mg/kg 0.77 0.39 100 05/28/15 20:10 05/29/15 12:41 7440-43-9 Cobalt ND mg/kg 6.4 3.2 100 05/28/15 20:10 05/29/15 12:41 7440-48-4 Lead 8.9 mg/kg 6.4 3.2 100 05/28/15 20:10 05/29/15 12:41 7439-92-1 Selenium ND mg/kg 6.4 3.2 100 05/28/15 20:10 05/29/15 12:41 7782-49-2 Thallium ND mg/kg 6.4 3.2 100 05/28/15 20:10 05/29/15 12:41 7440-28-0 Vanadium 22.4 mg/kg 6.4 3.2 100 05/28/15 20:10 05/29/15 12:41 7440-62-2 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury ND mg/kg 0.010 0.0052 1 05/28/15 21:30 05/30/15 14:07 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 21.5 % 0.10 0.10 1 06/03/15 10:21 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 4.7 Std. Units 0.10 0.10 1 05/28/15 15:25 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 313 156 5 05/21/15 23:58 16887-00-6 D3 Sulfate ND mg/kg 313 156 5 05/21/15 23:58 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 31.3 15.6 5 05/21/15 23:58 14797-55-8 H3 Date: 06/09/2015 05:14 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 27 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 l� ,8y fd.. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15050429 Pace Project No.: 92250342 Sample: 2015014796 Lab ID: 92250342002 Collected: 05/11/15 10:58 Received: 05/18/15 14:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 1080 mg/kg 765 382 1 06/03/15 21:46 7440-44-0 Total Organic Carbon 1130 mg/kg 761 381 1 06/03/15 21:53 7440-44-0 Total Organic Carbon 1020 mg/kg 769 385 1 06/03/15 21:59 7440-44-0 Total Organic Carbon 1240 mg/kg 758 379 1 06/03/15 22:05 7440-44-0 Mean Total Organic Carbon 1120 mg/kg 763 382 1 06/03/15 21:46 7440-44-0 Surrogates RSD% 8.2 % 1 06/03/15 21:46 Date: 06/09/2015 05:14 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 28 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 %c&yfde. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15050429 Pace Project No.: 92250342 Sample: 2015014797 Lab ID: 92250342003 Collected: 05/11/15 13:22 Received: 05/18/15 14:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 2910 mg/kg 27.5 13.7 5 05/28/15 20:10 05/30/15 21:49 7429-90-5 Barium 92.0 mg/kg 2.7 1.4 5 05/28/15 20:10 05/30/15 21:49 7440-39-3 Beryllium 0.53 mg/kg 0.27 0.14 5 05/28/15 20:10 05/30/15 21:49 7440-41-7 Boron ND mg/kg 13.7 6.9 5 05/28/15 20:10 05/30/15 21:49 7440-42-8 Calcium 444 mg/kg 137 68.7 5 05/28/15 20:10 05/30/15 21:49 7440-70-2 Chromium 4.6 mg/kg 1.4 0.69 5 05/28/15 20:10 05/30/15 21:49 7440-47-3 Copper 2.6 mg/kg 1.4 0.69 5 05/28/15 20:10 05/30/15 21:49 7440-50-8 Iron 2250 mg/kg 11.0 5.5 5 05/28/15 20:10 05/30/15 21:49 7439-89-6 Magnesium 284 mg/kg 137 68.7 5 05/28/15 20:10 05/30/15 21:49 7439-95-4 Manganese 21.7 mg/kg 1.4 0.69 5 05/28/15 20:10 05/30/15 21:49 7439-96-5 Molybdenum ND mg/kg 2.7 1.4 5 05/28/15 20:10 05/30/15 21:49 7439-98-7 Nickel 1.4 mg/kg 1.4 0.69 5 05/28/15 20:10 05/30/15 21:49 7440-02-0 Potassium ND mg/kg 275 137 5 05/28/15 20:10 05/30/15 21:49 7440-09-7 Sodium ND mg/kg 275 137 5 05/28/15 20:10 05/30/15 21:49 7440-23-5 Strontium 6.2 mg/kg 2.7 1.4 5 05/28/15 20:10 05/30/15 21:49 7440-24-6 Zinc ND mg/kg 5.5 2.7 5 05/28/15 20:10 05/30/15 21:49 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 5.5 2.7 100 05/28/15 20:10 05/29/15 12:44 7440-36-0 N2 Arsenic ND mg/kg 5.5 2.7 100 05/28/15 20:10 05/29/15 12:44 7440-38-2 Cadmium ND mg/kg 0.66 0.33 100 05/28/15 20:10 05/29/15 12:44 7440-43-9 Cobalt ND mg/kg 5.5 2.7 100 05/28/15 20:10 05/29/15 12:44 7440-48-4 Lead 3AJ mg/kg 5.5 2.7 100 05/28/15 20:10 05/29/15 12:44 7439-92-1 Selenium ND mg/kg 5.5 2.7 100 05/28/15 20:10 05/29/15 12:44 7782-49-2 Thallium ND mg/kg 5.5 2.7 100 05/28/15 20:10 05/29/15 12:44 7440-28-0 Vanadium 10.3 mg/kg 5.5 2.7 100 05/28/15 20:10 05/29/15 12:44 7440-62-2 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury 0.0070J mg/kg 0.0088 0.0044 1 05/28/15 21:30 05/30/15 14:10 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 8.0 % 0.10 0.10 1 06/03/15 10:21 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 4.9 Std. Units 0.10 0.10 1 05/28/15 15:25 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 269 134 5 05/22/15 00:19 16887-00-6 D3 Sulfate ND mg/kg 269 134 5 05/22/15 00:19 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 26.9 13.4 5 05/22/15 00:19 14797-55-8 H3 Date: 06/09/2015 05:14 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 29 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 %,8yfde. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15050429 Pace Project No.: 92250342 Sample: 2015014797 Lab ID: 92250342003 Collected: 05/11/15 13:22 Received: 05/18/15 14:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 374J mg/kg 654 327 1 06/03/15 22:12 7440-44-0 Total Organic Carbon 466J mg/kg 654 327 1 06/03/15 22:18 7440-44-0 Total Organic Carbon 414J mg/kg 653 326 1 06/03/15 22:25 7440-44-0 Total Organic Carbon 441J mg/kg 657 328 1 06/03/15 22:31 7440-44-0 Mean Total Organic Carbon 424J mg/kg 654 327 1 06/03/15 22:12 7440-44-0 Surrogates RSD% 9.3 % 1 06/03/15 22:12 Date: 06/09/2015 05:14 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 30 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 %,8yfde. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15050429 Pace Project No.: 92250342 Sample: 2015014798 Lab ID: 92250342004 Collected: 05/13/15 08:56 Received: 05/18/15 14:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Aluminum Barium Beryllium Boron Calcium Chromium Copper Iron Magnesium Manganese Molybdenum Nickel Potassium Sodium Strontium Zinc 6020 MET ICPMS Antimony Arsenic Cadmium Cobalt Lead Selenium Thallium Vanadium 7471 Mercury Mercury Percent Moisture Percent Moisture 9045 pH Soil pH at 25 Degrees C 300.0 IC Anions, SPLP Sulfate 353.2 Nitrogen, NO2/NO3, SPLP Nitrogen, Nitrate 4500 Chloride, SPLP Chloride Date: 06/09/2015 05:14 PM Analytical Method: EPA 6010 Preparation Method: EPA 3050 8610 mg/kg 49.9 25.0 5 05/28/15 20:10 05/30/15 21:53 7429-90-5 495 mg/kg 5.0 2.5 5 05/28/15 20:10 05/30/15 21:53 7440-39-3 3.2 mg/kg 0.50 0.25 5 05/28/15 20:10 05/30/15 21:53 7440-41-7 ND mg/kg 25.0 12.5 5 05/28/15 20:10 05/30/15 21:53 7440-42-8 10200 mg/kg 250 125 5 05/28/15 20:10 05/30/15 21:53 7440-70-2 14.9 mg/kg 2.5 1.2 5 05/28/15 20:10 05/30/15 21:53 7440-47-3 23.9 mg/kg 2.5 1.2 5 05/28/15 20:10 05/30/15 21:53 7440-50-8 22500 mg/kg 20.0 10 5 05/28/15 20:10 05/30/15 21:53 7439-89-6 1080 mg/kg 250 125 5 05/28/15 20:10 05/30/15 21:53 7439-95-4 245 mg/kg 2.5 1.2 5 05/28/15 20:10 05/30/15 21:53 7439-96-5 ND mg/kg 5.0 2.5 5 05/28/15 20:10 05/30/15 21:53 7439-98-7 12.1 mg/kg 2.5 1.2 5 05/28/15 20:10 05/30/15 21:53 7440-02-0 616 mg/kg 499 250 5 05/28/15 20:10 05/30/15 21:53 7440-09-7 ND mg/kg 499 250 5 05/28/15 20:10 05/30/15 21:53 7440-23-5 166 mg/kg 5.0 2.5 5 05/28/15 20:10 05/30/15 21:53 7440-24-6 7.9J mg/kg 10 5.0 5 05/28/15 20:10 05/30/15 21:53 7440-66-6 Analytical Method: EPA 6020 Preparation Method: EPA 3050 ND mg/kg 10 5.0 100 05/28/15 20:10 05/29/15 12:46 7440-36-0 55.2 mg/kg 10 5.0 100 05/28/15 20:10 05/29/15 12:46 7440-38-2 ND mg/kg 1.2 0.60 100 05/28/15 20:10 05/29/15 12:46 7440-43-9 6.01 mg/kg 10 5.0 100 05/28/15 20:10 05/29/15 12:46 7440-48-4 5AJ mg/kg 10 5.0 100 05/28/15 20:10 05/29/15 12:46 7439-92-1 5.7J mg/kg 10 5.0 100 05/28/15 20:10 05/29/15 12:46 7782-49-2 ND mg/kg 10 5.0 100 05/28/15 20:10 05/29/15 12:46 7440-28-0 31.0 mg/kg 10 5.0 100 05/28/15 20:10 05/29/15 12:46 7440-62-2 Analytical Method: EPA 7471 Preparation Method: EPA 7471 0.095 mg/kg 0.015 0.0077 1 05/28/15 21:30 05/30/15 14:12 7439-97-6 Analytical Method: ASTM D2974-87 47.3 % 0.10 0.10 1 06/03/1510:21 Analytical Method: EPA 9045 7.0 Std. Units 0.10 0.10 1 05/28/15 15:25 N2 Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 05/20/15 05:25 6.0 mg/L 3.8 1.9 1 05/31 /15 05:16 14808-79-8 B Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 05/20/15 05:25 ND mg/L 0.38 0.38 1 06/09/1511:28 H1 Analytical Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 05/20/15 05:25 ND mg/L 9.5 4.7 1 06/04/15 07:03 16887-00-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 31 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 t�iTc8y fd.. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15050429 Pace Project No.: 92250342 Sample: 2015014798 Lab ID: 92250342004 Collected: 05/13/15 08:56 Received: 05/18/15 14:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 465 233 5 05/22/15 00:41 16887-00-6 D3 Sulfate ND mg/kg 465 233 5 05/22/15 00:41 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 46.5 23.3 5 05/22/15 00:41 14797-55-8 H3 Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 56900 mg/kg 4530 2260 1 06/03/15 22:37 7440-44-0 Total Organic Carbon 74100 mg/kg 4550 2280 1 06/03/15 22:50 7440-44-0 Total Organic Carbon 84900 mg/kg 4460 2230 1 06/03/15 23:00 7440-44-0 Total Organic Carbon 129000 mg/kg 4440 2220 1 06/03/15 23:09 7440-44-0 Mean Total Organic Carbon 86300 mg/kg 4490 2250 1 06/03/15 22:37 7440-44-0 Surrogates RSD% 35.8 % 1 06/03/15 22:37 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/09/2015 05:14 PM without the written consent of Pace Analytical Services, Inc.. Page 32 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 t'Q'8y fd.. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15050429 Pace Project No.: 92250342 Sample: 2015014799 Lab ID: 92250342005 Collected: 05/11/15 10:00 Received: 05/18/15 14:35 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;I➢ZI7c\�i,I=11a Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470A Mercury Mercury Date: 06/09/2015 05:14 PM Analytical Method: EPA 6020A Preparation Method: EPA 3020 7.OJ ug/L 10.0 3.0 1 05/26/1510:19 05/27/1513:56 7429-90-5 0.22J ug/L 0.50 0.15 1 05/26/1510:19 05/27/1513:56 7440-36-0 ND ug/L 0.50 0.11 1 05/26/1510:19 05/27/1513:56 7440-38-2 0.17J ug/L 0.30 0.081 1 05/26/1510:19 05/27/1513:56 7440-39-3 ND ug/L 0.20 0.067 1 05/26/1510:19 05/27/1513:56 7440-41-7 ND ug/L 5.0 1.1 1 05/26/1510:19 05/27/1513:56 7440-42-8 ND ug/L 0.080 0.024 1 05/26/1510:19 05/27/1513:56 7440-43-9 57.1 ug/L 40.0 16.0 1 05/26/1510:19 05/27/1513:56 7440-70-2 ND ug/L 0.50 0.17 1 05/26/1510:19 05/27/1513:56 7440-47-3 ND ug/L 0.50 0.13 1 05/26/1510:19 05/27/1513:56 7440-48-4 ND ug/L 1.0 0.21 1 05/26/1510:19 05/27/1513:56 7440-50-8 ND ug/L 50.0 13.7 1 05/26/1510:19 05/27/1513:56 7439-89-6 ND ug/L 0.10 0.046 1 05/26/1510:19 05/27/1513:56 7439-92-1 14.3 ug/L 10.0 3.2 1 05/26/1510:19 05/27/1513:56 7439-95-4 0.31J ug/L 0.50 0.24 1 05/26/1510:19 05/27/1513:56 7439-96-5 ND ug/L 0.50 0.094 1 05/26/1510:19 05/27/1513:56 7439-98-7 ND ug/L 0.50 0.16 1 05/26/1510:19 05/27/1513:56 7440-02-0 14.7J ug/L 50.0 11.7 1 05/26/1510:19 05/27/1513:56 7440-09-7 ND ug/L 0.50 0.20 1 05/26/1510:19 05/27/1513:56 7782-49-2 80.4 ug/L 50.0 16.3 1 05/26/1510:19 05/27/1513:56 7440-23-5 0.30J ug/L 0.50 0.13 1 05/26/1510:19 05/27/1513:56 7440-24-6 ND ug/L 0.10 0.015 1 05/26/1510:19 05/27/1513:56 7440-28-0 ND ug/L 1.0 0.28 1 05/26/1510:19 05/27/1513:56 7440-62-2 ND ug/L 5.0 2.4 1 05/26/1510:19 05/27/1513:56 7440-66-6 Analytical Method: EPA 7470A Preparation Method: EPA 7470A ND ug/L 0.20 0.022 1 05/20/1518:25 05/21/1514:45 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 33 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 %'8yfde. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15050429 Pace Project No.: 92250342 Sample: 2015014800 Lab ID: 92250342006 Collected: 05/13/15 08:30 Received: 05/18/15 14:35 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;I➢ZI7c\�i,I=11 l[99�� 6? Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470A Mercury Mercury Date: 06/09/2015 05:14 PM Analytical Method: EPA 6020A Preparation Method: EPA 3020 6.5J ug/L 10.0 3.0 1 05/26/1510:19 05/27/1514:00 7429-90-5 ND ug/L 0.50 0.15 1 05/26/1510:19 05/27/1514:00 7440-36-0 ND ug/L 0.50 0.11 1 05/26/1510:19 05/27/1514:00 7440-38-2 ND ug/L 0.30 0.081 1 05/26/1510:19 05/27/1514:00 7440-39-3 ND ug/L 0.20 0.067 1 05/26/1510:19 05/27/1514:00 7440-41-7 ND ug/L 5.0 1.1 1 05/26/1510:19 05/27/1514:00 7440-42-8 ND ug/L 0.080 0.024 1 05/26/1510:19 05/27/1514:00 7440-43-9 21.1J ug/L 40.0 16.0 1 05/26/1510:19 05/27/1514:00 7440-70-2 ND ug/L 0.50 0.17 1 05/26/1510:19 05/27/1514:00 7440-47-3 ND ug/L 0.50 0.13 1 05/26/1510:19 05/27/1514:00 7440-48-4 ND ug/L 1.0 0.21 1 05/26/1510:19 05/27/1514:00 7440-50-8 ND ug/L 50.0 13.7 1 05/26/1510:19 05/27/1514:00 7439-89-6 ND ug/L 0.10 0.046 1 05/26/1510:19 05/27/1514:00 7439-92-1 5AJ ug/L 10.0 3.2 1 05/26/1510:19 05/27/1514:00 7439-95-4 ND ug/L 0.50 0.24 1 05/26/1510:19 05/27/1514:00 7439-96-5 ND ug/L 0.50 0.094 1 05/26/1510:19 05/27/1514:00 7439-98-7 ND ug/L 0.50 0.16 1 05/26/1510:19 05/27/1514:00 7440-02-0 13AJ ug/L 50.0 11.7 1 05/26/1510:19 05/27/1514:00 7440-09-7 ND ug/L 0.50 0.20 1 05/26/1510:19 05/27/1514:00 7782-49-2 20.7J ug/L 50.0 16.3 1 05/26/1510:19 05/27/1514:00 7440-23-5 ND ug/L 0.50 0.13 1 05/26/1510:19 05/27/1514:00 7440-24-6 ND ug/L 0.10 0.015 1 05/26/1510:19 05/27/1514:00 7440-28-0 ND ug/L 1.0 0.28 1 05/26/1510:19 05/27/1514:00 7440-62-2 ND ug/L 5.0 2.4 1 05/26/1510:19 05/27/1514:00 7440-66-6 Analytical Method: EPA 7470A Preparation Method: EPA 7470A ND ug/L 0.20 0.022 1 05/20/1518:25 05/21/1514:47 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 34 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 %'8yfde. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15050429 Pace Project No.: 92250342 Sample: 2015014798 SPLP Lab ID: 92250342007 Collected: 05/13/15 08:56 Received: 05/18/15 14:35 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;T➢Z17c\�iil=11 a Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470A Mercury Mercury Date: 06/09/2015 05:14 PM Analytical Method: EPA 6020A Preparation Method: EPA 3020 157 ug/L 10.0 3.0 1 05/31/15 05:35 06/02/15 10:21 7429-90-5 2.8 ug/L 0.50 0.15 1 05/31/15 05:35 06/01/15 18:04 7440-36-0 25.9 ug/L 0.50 0.11 1 05/31/15 05:35 06/01/15 18:04 7440-38-2 243 ug/L 0.30 0.081 1 05/31/15 05:35 06/01/15 18:04 7440-39-3 ND ug/L 0.20 0.067 1 05/31/15 05:35 06/01/15 18:04 7440-41-7 133 ug/L 5.0 1.1 1 05/31/15 05:35 06/01/15 18:04 7440-42-8 0.026J ug/L 0.080 0.024 1 05/31/15 05:35 06/01/15 18:04 7440-43-9 16800 ug/L 40.0 16.0 1 05/31/15 05:35 06/01/15 18:04 7440-70-2 0.84 ug/L 0.50 0.17 1 05/31/15 05:35 06/01/15 18:04 7440-47-3 0.21 J ug/L 0.50 0.13 1 05/31/15 05:35 06/01/15 18:04 7440-48-4 4.1 ug/L 1.0 0.21 1 05/31/15 05:35 06/01/15 18:04 7440-50-8 130 ug/L 50.0 13.7 1 05/31/15 05:35 06/01/15 18:04 7439-89-6 0.32 ug/L 0.10 0.046 1 05/31/15 05:35 06/01/15 18:04 7439-92-1 343 ug/L 10.0 3.2 1 05/31/15 05:35 06/01/15 18:04 7439-95-4 104 ug/L 0.50 0.24 1 05/31/15 05:35 06/01/15 18:04 7439-96-5 1.4 ug/L 0.50 0.094 1 05/31/15 05:35 06/01/15 18:04 7439-98-7 1.5 ug/L 0.50 0.16 1 05/31/15 05:35 06/01/15 18:04 7440-02-0 725 ug/L 50.0 11.7 1 05/31/15 05:35 06/01/15 18:04 7440-09-7 10.5 ug/L 0.50 0.20 1 05/31/15 05:35 06/01/15 18:04 7782-49-2 1460 ug/L 50.0 16.3 1 05/31/15 05:35 06/01/15 18:04 7440-23-5 166 ug/L 0.50 0.13 1 05/31/15 05:35 06/01/15 18:04 7440-24-6 0.026J ug/L 0.10 0.015 1 05/31/15 05:35 06/01/15 18:04 7440-28-0 22.9 ug/L 1.0 0.28 1 05/31/15 05:35 06/01/15 18:04 7440-62-2 90.5 ug/L 5.0 2.4 1 05/31/15 05:35 06/01/15 18:04 7440-66-6 Analytical Method: EPA 7470A Preparation Method: EPA 7470A ND ug/L 0.20 0.022 1 06/01/1514:25 06/01/1519:29 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 35 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 %,8ftde. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050429 Pace Project No.: 92250342 QC Batch: MERP/13618 Analysis Method: EPA 7470A QC Batch Method: EPA 7470A Analysis Description: 7470A Mercury Water Associated Lab Samples: 92250342005, 92250342006 METHOD BLANK: 1971548 Matrix: Water Associated Lab Samples: 92250342005, 92250342006 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury ug/L ND 0.20 05/21/1514:00 LABORATORY CONTROL SAMPLE: 1971549 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 5 5.2 104 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1971550 1971551 MS MSD 92249681008 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 5 5 5.1 5.1 102 102 80-120 0 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/09/2015 05:14 PM without the written consent of Pace Analytical Services, Inc.. Page 36 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 %,8ftde. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050429 Pace Project No.: 92250342 QC Batch: MERP/13722 Analysis Method: EPA 7470A QC Batch Method: EPA 7470A Analysis Description: 7470A Mercury Water Associated Lab Samples: 92250342007 METHOD BLANK: 1981066 Matrix: Water Associated Lab Samples: 92250342007 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury ug/L ND 0.20 06/01/1519:17 LABORATORY CONTROL SAMPLE: 1981067 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 5 4.9 98 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1981068 1981069 MS MSD 10308264001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 5 5 5.0 4.9 99 99 80-120 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/09/2015 05:14 PM without the written consent of Pace Analytical Services, Inc.. Page 37 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Iic&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050429 Pace Project No.: 92250342 QC Batch: MERP/5780 Analysis Method: EPA 7471 QC Batch Method: EPA 7471 Analysis Description: 7471 Mercury Associated Lab Samples: 92250342001, 92250342002, 92250342003, 92250342004 METHOD BLANK: 1226134 Matrix: Solid Associated Lab Samples: 92250342001, 92250342002, 92250342003, 92250342004 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury mg/kg ND 0.0080 05/30/1513:26 LABORATORY CONTROL SAMPLE: 1226135 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury mg/kg .081 0.074 91 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1226136 1226137 MS MSD 92245394022 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury mg/kg 0.015 .11 .102 0.10 0.10 81 86 80-120 1 20 H3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/09/2015 05:14 PM without the written consent of Pace Analytical Services, Inc.. Page 38 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 %c&ftde. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050429 Pace Project No.: 92250342 QC Batch: MPRP/24366 Analysis Method: EPA 6010 QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid Associated Lab Samples: 92250342001, 92250342002, 92250342003, 92250342004 METHOD BLANK: 1226121 Matrix: Solid Associated Lab Samples: 92250342001, 92250342002, 92250342003, 92250342004 Blank Reporting Parameter Units Result Limit Analyzed Aluminum mg/kg ND 5.1 05/30/15 20:03 Barium mg/kg ND 0.51 05/30/15 20:03 Beryllium mg/kg ND 0.051 05/30/15 20:03 Boron mg/kg ND 2.6 05/30/15 20:03 Calcium mg/kg ND 25.6 05/30/15 20:03 Chromium mg/kg ND 0.26 05/30/15 20:03 Copper mg/kg ND 0.26 05/30/15 20:03 Iron mg/kg ND 2.0 05/30/15 20:03 Magnesium mg/kg ND 25.6 05/30/15 20:03 Manganese mg/kg ND 0.26 05/30/15 20:03 Molybdenum mg/kg ND 0.51 05/30/15 20:03 Nickel mg/kg ND 0.26 05/30/15 20:03 Potassium mg/kg ND 51.2 05/30/15 20:03 Sodium mg/kg ND 51.2 05/30/15 20:03 Strontium mg/kg ND 0.51 05/30/15 20:03 Zinc mg/kg ND 1.0 05/30/15 20:03 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 1226122 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Aluminum mg/kg 128 131 102 80-120 Barium mg/kg 12.8 13.0 102 80-120 Beryllium mg/kg 1.3 1.3 101 80-120 Boron mg/kg 128 125 98 80-120 Calcium mg/kg 641 652 102 80-120 Chromium mg/kg 12.8 12.3 96 80-120 Copper mg/kg 12.8 12.5 97 80-120 Iron mg/kg 128 128 100 80-120 Magnesium mg/kg 641 626 98 80-120 Manganese mg/kg 12.8 12.7 99 80-120 Molybdenum mg/kg 12.8 12.6 98 80-120 Nickel mg/kg 12.8 12.9 101 80-120 Potassium mg/kg 641 592 92 80-120 Sodium mg/kg 641 634 99 80-120 Strontium mg/kg 12.8 12.9 101 80-120 Zinc mg/kg 64.1 63.7 99 80-120 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/09/2015 05:14 PM without the written consent of Pace Analytical Services, Inc.. Page 39 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 %,8ftde. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050429 Pace Project No.: 92250342 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1226123 1226124 MS MSD 92245394022 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum mg/kg 11300 162 161 17500 18600 3820 4540 75-125 6 20 M1 Barium mg/kg 40.0 16.2 16.1 64.0 69.6 148 184 75-125 8 20 M1 Beryllium mg/kg 0.60 1.57 1.57 2.1 2.2 91 100 75-125 6 20 Boron mg/kg ND 162 161 75.1 81.3 45 50 75-125 8 20 M1 Calcium mg/kg ND 812 804 707 766 87 95 75-125 8 20 Chromium mg/kg 11.7 16.2 16.1 30.4 34.2 115 140 75-125 12 20 M1 Copper mg/kg 15.5 16.2 16.1 37.2 39.1 133 146 75-125 5 20 M1 Iron mg/kg 24000 162 161 30100 37500 3760 8380 75-125 22 20 M1,R1 Magnesium mg/kg 302 812 804 1110 1210 100 113 75-125 8 20 Manganese mg/kg 32.5 16.2 16.1 46.7 56.2 88 148 75-125 18 20 M1 Molybdenum mg/kg ND 16.2 16.1 12.0 13.1 67 75 75-125 9 20 M1 Nickel mg/kg 1.8 16.2 16.1 17.2 18.3 94 102 75-125 6 20 Potassium mg/kg 227J 812 804 925 997 86 96 75-125 8 20 Sodium mg/kg ND 812 804 699 755 86 94 75-125 8 20 Strontium mg/kg ND 16.2 16.1 16.5 18.2 97 108 75-125 9 20 Zinc mg/kg 15.5 81.2 80.4 93.3 101 96 107 75-125 8 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/09/2015 05:14 PM without the written consent of Pace Analytical Services, Inc.. Page 40 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Iji ,8ftde. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050429 Pace Project No.: 92250342 QC Batch: MPRP/24367 Analysis Method: EPA 6020 QC Batch Method: EPA 3050 Analysis Description: 6020 MET SOLID Associated Lab Samples: 92250342001, 92250342002, 92250342003, 92250342004 METHOD BLANK: 1226125 Matrix: Solid Associated Lab Samples: 92250342001, 92250342002, 92250342003, 92250342004 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Antimony mg/kg ND 0.051 05/29/1511:41 N2 Arsenic mg/kg ND 0.051 05/29/1511:41 Cadmium mg/kg ND 0.0061 05/29/1511:41 Cobalt mg/kg ND 0.051 05/29/1511:41 Lead mg/kg ND 0.051 05/29/1511:41 Selenium mg/kg ND 0.051 05/29/1511:41 Thallium mg/kg ND 0.051 05/29/1511:41 Vanadium mg/kg ND 0.051 05/29/1511:41 LABORATORY CONTROL SAMPLE: Parameter 1226126 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Antimony mg/kg 2.6 2.4 92 80-120 N2 Arsenic mg/kg 2.6 2.4 95 80-120 Cadmium mg/kg .26 0.25 100 80-120 Cobalt mg/kg 2.6 2.4 95 80-120 Lead mg/kg 2.6 2.3 92 80-120 Selenium mg/kg 2.6 2.4 94 80-120 Thallium mg/kg 2.6 2.4 96 80-120 Vanadium mg/kg 2.6 2.4 95 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1226127 1226128 MS MSD 92245394022 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony mg/kg ND 3.14 3.27 ND ND 16 22 75-125 20 M6, N2 Arsenic mg/kg 3.5J 3.14 3.27 5.7J 6.7 70 97 75-125 20 M6 Cadmium mg/kg ND .314 .327 ND ND 84 70 75-125 20 M6 Cobalt mg/kg ND 3.14 3.27 4.6J 5.01 89 102 75-125 20 Lead mg/kg 12.8 3.14 3.27 15.9 17.7 96 151 75-125 11 20 M6 Selenium mg/kg 3.5J 3.14 3.27 4.5J 4.1J 31 19 75-125 20 M6 Thallium mg/kg ND 3.14 3.27 ND ND 65 71 75-125 20 M6 Vanadium mg/kg 28.7 3.14 3.27 33.7 39.0 157 318 75-125 15 20 M6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/09/2015 05:14 PM without the written consent of Pace Analytical Services, Inc.. Page 41 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 1jiT igy fde. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050429 Pace Project No.: 92250342 QC Batch: MPRP/54605 Analysis Method: EPA 6020A QC Batch Method: EPA 3020 Analysis Description: 6020A Water UPD4 Associated Lab Samples: 92250342005, 92250342006 METHOD BLANK: 1973801 Associated Lab Samples: 92250342005, 92250342006 Parameter Units Aluminum ug/L Antimony ug/L Arsenic ug/L Barium ug/L Beryllium ug/L Boron ug/L Cadmium ug/L Calcium ug/L Chromium ug/L Cobalt ug/L Copper ug/L Iron ug/L Lead ug/L Magnesium ug/L Manganese ug/L Molybdenum ug/L Nickel ug/L Potassium ug/L Selenium ug/L Sodium ug/L Strontium ug/L Thallium ug/L Vanadium ug/L Zinc ug/L Matrix: Water Blank Result Reporting Limit Analyzed ND 10.0 05/28/15 09:29 ND 0.50 05/28/15 09:29 ND 0.50 05/28/15 09:29 ND 0.30 05/28/15 09:29 ND 0.20 05/28/15 09:29 ND 5.0 05/28/15 09:29 ND 0.080 05/28/15 09:29 ND 40.0 05/28/15 09:29 ND 0.50 05/28/15 09:29 ND 0.50 05/28/15 09:29 ND 1.0 05/28/15 09:29 ND 50.0 05/28/15 09:29 ND 0.10 05/28/15 09:29 ND 10.0 05/28/15 09:29 ND 0.50 05/28/15 09:29 ND 0.50 05/28/15 09:29 ND 0.50 05/28/15 09:29 ND 50.0 05/28/15 09:29 ND 0.50 05/28/15 09:29 ND 50.0 05/28/15 09:29 ND 0.50 05/28/15 09:29 ND 0.10 05/28/15 09:29 ND 1.0 05/28/15 09:29 ND 5.0 05/28/15 09:29 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 1973802 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Aluminum ug/L 80 79.9 100 80-120 Antimony ug/L 80 75.9 95 80-120 Arsenic ug/L 80 75.4 94 80-120 Barium ug/L 80 76.7 96 80-120 Beryllium ug/L 80 77.9 97 80-120 Boron ug/L 80 75.2 94 80-120 Cadmium ug/L 80 77.6 97 80-120 Calcium ug/L 1000 994 99 80-120 Chromium ug/L 80 78.4 98 80-120 Cobalt ug/L 80 78.1 98 80-120 Copper ug/L 80 77.9 97 80-120 Iron ug/L 1000 973 97 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/09/2015 05:14 PM without the written consent of Pace Analytical Services, Inc.. Page 42 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 I Q igy fd.. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050429 Pace Project No.: 92250342 LABORATORY CONTROL SAMPLE: 1973802 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Lead ug/L 80 79.0 99 80-120 Magnesium ug/L 1000 972 97 80-120 Manganese ug/L 80 77.9 97 80-120 Molybdenum ug/L 80 77.2 96 80-120 Nickel ug/L 80 79.0 99 80-120 Potassium ug/L 1000 968 97 80-120 Selenium ug/L 80 77.8 97 80-120 Sodium ug/L 1000 974 97 80-120 Strontium ug/L 80 77.9 97 80-120 Thallium ug/L 80 78.2 98 80-120 Vanadium ug/L 80 79.0 99 80-120 Zinc ug/L 80 79.3 99 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1973803 1973804 MS MSD 92250183001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum ug/L 203 80 80 516 523 391 400 75-125 1 20 M1 Antimony ug/L ND 80 80 76.6 75.6 96 94 75-125 1 20 Arsenic ug/L 0.39J 80 80 76.6 75.9 95 94 75-125 1 20 Barium ug/L 3.7 80 80 82.7 81.5 99 97 75-125 1 20 Beryllium ug/L 0.0801 80 80 80.6 79.0 101 99 75-125 2 20 Boron ug/L 7.5 80 80 80.5 83.0 91 94 75-125 3 20 Cadmium ug/L ND 80 80 77.6 78.0 97 97 75-125 1 20 Calcium ug/L 527 1000 1000 1830 1830 130 130 75-125 0 20 M1 Chromium ug/L 1.7 80 80 80.8 79.6 99 97 75-125 1 20 Cobalt ug/L 0.20J 80 80 78.5 78.0 98 97 75-125 1 20 Copper ug/L 1.0 80 80 81.1 79.3 100 98 75-125 2 20 Iron ug/L 324 1000 1000 1450 1440 113 112 75-125 1 20 Lead ug/L 0.24 80 80 80.4 78.8 100 98 75-125 2 20 Magnesium ug/L 107 1000 1000 1170 1160 107 105 75-125 1 20 Manganese ug/L 9.0 80 80 92.0 90.5 104 102 75-125 2 20 Molybdenum ug/L 1.0 80 80 79.5 77.8 98 96 75-125 2 20 Nickel ug/L 2.1 80 80 82.8 82.7 101 101 75-125 0 20 Potassium ug/L 79.9 1000 1000 1130 1130 105 105 75-125 0 20 Selenium ug/L ND 80 80 78.5 76.4 98 95 75-125 3 20 Sodium ug/L 267 1000 1000 1410 1400 115 113 75-125 1 20 Strontium ug/L 2.8 80 80 82.4 82.4 99 99 75-125 0 20 Thallium ug/L 0.016J 80 80 81.8 80.0 102 100 75-125 2 20 Vanadium ug/L 0.81J 80 80 81.1 80.0 100 99 75-125 1 20 Zinc ug/L 4.2J 80 80 83.4 83.2 99 99 75-125 0 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/09/2015 05:14 PM without the written consent of Pace Analytical Services, Inc.. Page 43 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 I S igy fd.. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050429 Pace Project No.: 92250342 QC Batch: MPRP/54772 Analysis Method: EPA 6020A QC Batch Method: EPA 3020 Analysis Description: 6020A Water UPD4 Associated Lab Samples: 92250342007 METHOD BLANK: 1980141 Associated Lab Samples: 92250342007 Parameter Units Aluminum ug/L Antimony ug/L Arsenic ug/L Barium ug/L Beryllium ug/L Boron ug/L Cadmium ug/L Calcium ug/L Chromium ug/L Cobalt ug/L Copper ug/L Iron ug/L Lead ug/L Magnesium ug/L Manganese ug/L Molybdenum ug/L Nickel ug/L Potassium ug/L Selenium ug/L Sodium ug/L Strontium ug/L Thallium ug/L Vanadium ug/L Zinc ug/L Matrix: Water Blank Result Reporting Limit Analyzed ND 10.0 06/01/1517:29 ND 0.50 06/01/1517:29 ND 0.50 06/01/1517:29 ND 0.30 06/01/1517:29 ND 0.20 06/01/1517:29 ND 5.0 06/01/1517:29 ND 0.080 06/01 /15 17:29 ND 40.0 06/01/1517:29 ND 0.50 06/01/1517:29 ND 0.50 06/01/1517:29 ND 1.0 06/01/1517:29 ND 50.0 06/01/1517:29 ND 0.10 06/01/1517:29 ND 10.0 06/01/1517:29 ND 0.50 06/01/1517:29 ND 0.50 06/01/1517:29 ND 0.50 06/01/1517:29 ND 50.0 06/01/1517:29 ND 0.50 06/01/1517:29 ND 50.0 06/01/1517:29 ND 0.50 06/01/1517:29 ND 0.10 06/01/1517:29 ND 1.0 06/01/1517:29 ND 5.0 06/01/1517:29 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 1980142 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Aluminum ug/L 80 86.2 108 80-120 Antimony ug/L 80 84.8 106 80-120 Arsenic ug/L 80 85.4 107 80-120 Barium ug/L 80 84.3 105 80-120 Beryllium ug/L 80 88.0 110 80-120 Boron ug/L 80 80.9 101 80-120 Cadmium ug/L 80 85.7 107 80-120 Calcium ug/L 1000 999 100 80-120 Chromium ug/L 80 88.9 111 80-120 Cobalt ug/L 80 85.1 106 80-120 Copper ug/L 80 85.5 107 80-120 Iron ug/L 1000 1100 110 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/09/2015 05:14 PM without the written consent of Pace Analytical Services, Inc.. Page 44 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 14,8y fd.. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050429 Pace Project No.: 92250342 LABORATORY CONTROL SAMPLE: 1980142 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Lead ug/L 80 84.1 105 80-120 Magnesium ug/L 1000 1090 109 80-120 Manganese ug/L 80 89.5 112 80-120 Molybdenum ug/L 80 86.4 108 80-120 Nickel ug/L 80 84.9 106 80-120 Potassium ug/L 1000 1080 108 80-120 Selenium ug/L 80 83.4 104 80-120 Sodium ug/L 1000 1070 107 80-120 Strontium ug/L 80 86.9 109 80-120 Thallium ug/L 80 90.0 113 80-120 Vanadium ug/L 80 87.3 109 80-120 Zinc ug/L 80 86.3 108 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1980685 1980686 MS MSD 10308223006 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum ug/L 203 80 80 279 258 94 69 75-125 8 20 M1 Antimony ug/L <2.5 80 80 86.6 84.9 107 105 75-125 2 20 Arsenic ug/L 9.1 80 80 94.9 93.6 107 106 75-125 1 20 Barium ug/L 369 80 80 448 443 98 92 75-125 1 20 Beryllium ug/L <1.0 80 80 81.6 81.5 102 102 75-125 0 20 Boron ug/L 1010 80 80 1070 1070 74 75 75-125 0 20 M1 Cadmium ug/L <0.40 80 80 85.2 84.1 106 105 75-125 1 20 Calcium ug/L 148000 1000 1000 146000 144000 -157 -410 75-125 2 20 E,M1 Chromium ug/L <2.5 80 80 86.4 85.8 107 106 75-125 1 20 Cobalt ug/L 3.3 80 80 86.7 85.3 104 102 75-125 2 20 Copper ug/L <5.0 80 80 82.2 81.1 102 101 75-125 1 20 Iron ug/L <250 1000 1000 1200 1180 106 103 75-125 2 20 Lead ug/L <0.50 80 80 79.0 78.5 98 98 75-125 1 20 Magnesium ug/L 51800 1000 1000 52000 51300 21 -45 75-125 1 20 M1 Manganese ug/L 30.9 80 80 113 111 103 100 75-125 2 20 Molybdenum ug/L 153 80 80 239 234 107 102 75-125 2 20 Nickel ug/L 5.7 80 80 86.2 85.4 101 100 75-125 1 20 Potassium ug/L 14800 1000 1000 15500 15300 70 51 75-125 1 20 M1 Selenium ug/L 348 80 80 421 415 92 84 75-125 1 20 Sodium ug/L 372000 1000 1000 368000 362000 -396 -960 75-125 2 20 E,M1 Strontium ug/L 1430 80 80 1480 1460 62 37 75-125 1 20 M1 Thallium ug/L <0.50 80 80 83.9 82.9 105 104 75-125 1 20 Vanadium ug/L <5.0 80 80 94.0 92.7 112 111 75-125 1 20 Zinc ug/L 55.0 80 80 140 139 106 105 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/09/2015 05:14 PM without the written consent of Pace Analytical Services, Inc.. Page 45 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Ijigc&y fd.. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050429 Pace Project No.: 92250342 QC Batch: PMST/3611 Analysis Method: ASTM D2974-87 QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture Associated Lab Samples: 92250342001, 92250342002, 92250342003, 92250342004 SAMPLE DUPLICATE: 1230675 92249703001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 30.3 29.7 2 10 SAMPLE DUPLICATE: 1230676 92250342001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 8.4 7.6 10 10 SAMPLE DUPLICATE: 1230677 92250337006 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 23.9 18.4 26 10 D6 SAMPLE DUPLICATE: 1230678 35189955001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 26.3 24.7 6 10 SAMPLE DUPLICATE: 1230679 35190037003 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 5.2 4.8 9 10 SAMPLE DUPLICATE: 1230680 35190542006 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 1.6 1.3 19 10 D6 SAMPLE DUPLICATE: 1230681 35190534005 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 9.3 9.1 3 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/09/2015 05:14 PM without the written consent of Pace Analytical Services, Inc.. Page 46 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 16,8y fd.. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050429 Pace Project No.: 92250342 SAMPLE DUPLICATE: 1230682 35190535009 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 8.6 8.7 1 10 SAMPLE DUPLICATE: 1230683 35190628001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 4.9 4.9 1 10 SAMPLE DUPLICATE: 1230684 35190846005 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 7.1 6.9 3 10 SAMPLE DUPLICATE: 1230685 35190910008 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 2.4 2.3 6 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/09/2015 05:14 PM without the written consent of Pace Analytical Services, Inc.. Page 47 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ",igy fd.. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050429 Pace Project No.: 92250342 QC Batch: WET/37692 Analysis Method: EPA 9045 QC Batch Method: EPA 9045 Analysis Description: 9045 pH Associated Lab Samples: 92250342001, 92250342002, 92250342003, 92250342004 SAMPLE DUPLICATE: 1468313 92250515012 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 6.8 6.7 1 10 D6 SAMPLE DUPLICATE: 1468314 Parameter pH at 25 Degrees C 92250515011 Dup Units Result Result Std. Units 8.4 8.4 Max RPD RPD Qualifiers 0 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/09/2015 05:14 PM without the written consent of Pace Analytical Services, Inc.. Page 48 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 %,8ftde. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050429 Pace Project No.: 92250342 QC Batch: WETA/23110 Analysis Method: EPA 300.0 QC Batch Method: EPA 300.0 Analysis Description: 300.0 IC Anions Associated Lab Samples: 92250342004 METHOD BLANK: 1471529 Matrix: Water Associated Lab Samples: 92250342004 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Sulfate mg/L 3.1 2.0 05/30/15 23:22 LABORATORY CONTROL SAMPLE: 1471530 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfate mg/L 20 19.8 99 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1471531 1471532 MS MSD 92249101017 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfate mg/L 3.0 29.3 29.3 30.9 30.7 95 94 1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1471533 1471534 MS MSD 92250183011 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfate mg/L 8.3 37.2 37.2 44.0 43.9 96 96 0 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/09/2015 05:14 PM without the written consent of Pace Analytical Services, Inc.. Page 49 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Iji ,8ftde. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050429 Pace Project No.: 92250342 QC Batch: WETA/23177 Analysis Method: EPA 353.2 QC Batch Method: EPA 353.2 Analysis Description: 353.2 Nitrate + Nitrite, Unpres. Associated Lab Samples: 92250342004 METHOD BLANK: 1476700 Matrix: Water Associated Lab Samples: 92250342004 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, Nitrate mg/L 0.15 0.020 06/09/15 10:56 Z2 LABORATORY CONTROL SAMPLE: 1476701 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Nitrate mg/L 2.5 2.4 95 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1476702 1476703 MS MSD 92249487002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Nitrate mg/L ND 2.6 2.6 2.4 2.4 89 89 90-110 1 10 H1,M1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1476704 1476705 MS MSD 92250202006 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Nitrate mg/L ND 3.1 3.1 3.1 3.2 93 94 90-110 2 10 H1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/09/2015 05:14 PM without the written consent of Pace Analytical Services, Inc.. Page 50 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 t 6,8y fd.. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050429 Pace Project No.: 92250342 QC Batch: WETA/23132 Analysis Method: SM 4500-CI-E QC Batch Method: SM 4500-CI-E Analysis Description: 4500 Chloride Associated Lab Samples: 92250342004 METHOD BLANK: 1472681 Matrix: Water Associated Lab Samples: 92250342004 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/L ND 1.0 06/04/15 06:39 LABORATORY CONTROL SAMPLE: 1472682 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloride mg/L 20 21.0 105 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1472683 1472684 MS MSD 92249061003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride mg/L ND 24.2 24.2 27.1 27.1 109 110 90-110 0 10 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1472685 1472686 MS MSD 92249703005 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride mg/L ND 20 20 23.1 23.3 114 115 90-110 1 10 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/09/2015 05:14 PM without the written consent of Pace Analytical Services, Inc.. Page 51 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 �T igy fde. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050429 Pace Project No.: 92250342 QC Batch: WETA/46609 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92250342001, 92250342002, 92250342003, 92250342004 METHOD BLANK: 1220363 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/kg ND 50.2 05/21/1516:50 Sulfate mg/kg ND 50.2 05/21/1516:50 LABORATORY CONTROL SAMPLE: 1220364 Parameter Units Chloride mg/kg Sulfate mg/kg MATRIX SPIKE SAMPLE: 1220366 Parameter Units Chloride mg/kg Sulfate mg/kg SAMPLE DUPLICATE: 1220365 Parameter Chloride Sulfate Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 499 521 104 80-120 499 512 103 80-120 92250329001 Spike MS MS % Rec Result Conc. Result % Rec Limits Qualifiers ND 790 695 71 80-120 M 1 ND 790 687 73 80-120 M 1 92250329001 Dup Units Result Result mg/kg ND ND mg/kg ND ND Max RPD RPD Qualifiers 20 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/09/2015 05:14 PM without the written consent of Pace Analytical Services, Inc.. Page 52 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 t Q igy fd.. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050429 Pace Project No.: 92250342 QC Batch: WETA/46608 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92250342001, 92250342002, 92250342003, 92250342004 METHOD BLANK: 1220359 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrate as N mg/kg ND 5.0 05/21/15 16:50 LABORATORY CONTROL SAMPLE: 1220360 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg 49.9 51.0 102 80-120 MATRIX SPIKE SAMPLE: 1220362 92250329001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg ND 79 69.1 87 80-120 H3 SAMPLE DUPLICATE: 1220361 92250329001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Nitrate as N mg/kg ND ND 20 H3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/09/2015 05:14 PM without the written consent of Pace Analytical Services, Inc.. Page 53 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 t S igy fd.. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15050429 Pace Project No.: 92250342 QC Batch: WETA/28805 Analysis Method: EPA 9060 QC Batch Method: EPA 9060 Analysis Description: 9060 TOC Average Associated Lab Samples: 92250342001, 92250342002, 92250342003, 92250342004 METHOD BLANK: 1167968 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mean Total Organic Carbon mg/kg ND 600 06/03/15 06:27 LABORATORY CONTROL SAMPLE: 1167969 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mean Total Organic Carbon mg/kg 120000 105000 87 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1167970 1167971 MS MSD 92249681006 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg 1260 6500 6490 7600 7510 98 96 50-150 1 30 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1167972 1167973 MS MSD 92250058005 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg 18400 17400 17400 37500 37300 110 109 50-150 1 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/09/2015 05:14 PM without the written consent of Pace Analytical Services, Inc.. Page 54 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 t 4'8y fd.. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: J15050429 Pace Project No.: 92250342 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TN -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-G Pace Analytical Services - Green Bay PASI-M Pace Analytical Services - Minneapolis PASI-O Pace Analytical Services - Ormond Beach BATCH QUALIFIERS Batch: ICP/14887 Ill Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. Batch: ICPM/9867 III Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. ANALYTE QUALIFIERS B Analyte was detected in the associated method blank. D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. D6 The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits. E Analyte concentration exceeded the calibration range. The reported result is estimated. H1 Analysis conducted outside the EPA method holding time. H3 Sample was received or analysis requested beyond the recognized method holding time. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/09/2015 05:14 PM without the written consent of Pace Analytical Services, Inc.. Page 55 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 �gc&y fd.. Suite 100 Huntersville, INC 28078 (704)875-9092 QUALIFIERS Project: J15050429 Pace Project No.: 92250342 ANALYTE QUALIFIERS M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. N2 The lab does not hold TIN accreditation for this parameter. R1 RPD value was outside control limits. Z2 Analyte present in the associated method blank above the detection limit. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/09/2015 05:14 PM without the written consent of Pace Analytical Services, Inc.. Page 56 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 t 6'8y fd.. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: J15050429 Pace Project No.: 92250342 Lab ID Sample ID QC Batch Method QC Batch Analytical Method 92250342001 2015014795 EPA 3050 MPRP/24366 EPA 6010 92250342002 2015014796 EPA 3050 MPRP/24366 EPA 6010 92250342003 2015014797 EPA 3050 MPRP/24366 EPA 6010 92250342004 2015014798 EPA 3050 MPRP/24366 EPA 6010 92250342001 2015014795 EPA 3050 MPRP/24367 EPA 6020 92250342002 2015014796 EPA 3050 MPRP/24367 EPA 6020 92250342003 2015014797 EPA 3050 MPRP/24367 EPA 6020 92250342004 2015014798 EPA 3050 MPRP/24367 EPA 6020 92250342005 2015014799 EPA 3020 MPRP/54605 EPA 6020A 92250342006 2015014800 EPA 3020 MPRP/54605 EPA 6020A 92250342007 2015014798 SPLP EPA 3020 MPRP/54772 EPA 6020A 92250342005 2015014799 EPA 7470A MERP/13618 EPA 7470A 92250342006 2015014800 EPA 7470A MERP/13618 EPA 7470A 92250342007 2015014798 SPLP EPA 7470A MERP/13722 EPA 7470A 92250342001 2015014795 EPA 7471 MERP/5780 EPA 7471 92250342002 2015014796 EPA 7471 MERP/5780 EPA 7471 92250342003 2015014797 EPA 7471 MERP/5780 EPA 7471 92250342004 2015014798 EPA 7471 MERP/5780 EPA 7471 92250342001 2015014795 ASTM D2974-87 PMST/3611 92250342002 2015014796 ASTM D2974-87 PMST/3611 92250342003 2015014797 ASTM D2974-87 PMST/3611 92250342004 2015014798 ASTM D2974-87 PMST/3611 92250342001 2015014795 EPA 9045 WET/37692 92250342002 2015014796 EPA 9045 WET/37692 92250342003 2015014797 EPA 9045 WET/37692 92250342004 2015014798 EPA 9045 WET/37692 92250342004 2015014798 EPA 300.0 WETA/23110 92250342004 2015014798 EPA 353.2 WETA/23177 92250342004 2015014798 SM 4500-CI-E WETA/23132 92250342001 2015014795 EPA 9056 WETA/46609 92250342002 2015014796 EPA 9056 WETA/46609 92250342003 2015014797 EPA 9056 WETA/46609 92250342004 2015014798 EPA 9056 WETA/46609 92250342001 2015014795 EPA 9056 WETA/46608 92250342002 2015014796 EPA 9056 WETA/46608 92250342003 2015014797 EPA 9056 WETA/46608 92250342004 2015014798 EPA 9056 WETA/46608 92250342001 2015014795 EPA 9060 WETA/28805 92250342001 2015014795 EPA 9060 WETA/28808 92250342002 2015014796 EPA 9060 WETA/28805 Date: 06/09/2015 05:14 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Analytical Batch ICP/14887 ICP/14887 ICP/14887 ICP/14887 ICPM/9867 ICPM/9867 ICPM/9867 ICPM/9867 ICPM/24447 ICPM/24447 ICPM/24559 MERC/15810 MERC/15810 MERC/15958 MERC/5770 MERC/5770 MERC/5770 MERC/5770 Page 57 of 60 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 "'8yfde. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: J15050429 Pace Project No.: 92250342 Lab ID Sample ID QC Batch Method QC Batch 92250342002 2015014796 EPA 9060 WETA/28808 92250342003 2015014797 EPA 9060 WETA/28805 92250342003 2015014797 EPA 9060 WETA/28808 92250342004 2015014798 EPA 9060 WETA/28805 92250342004 2015014798 EPA 9060 WETA/28808 Date: 06/09/2015 05:14 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Analytical Method Analytical Batch Page 58 of 60 I IVVGUIfIVn[ IVarfte: le Condition Upon Receil Document Number: F-CHR-CS-003-rev.16 Client Name: 110- uocument Revised: May 18, 2015 Page 1 of 2" Issuing Authority:68 of 70 Pace Huntersville Qualitv Office * Page 2 of 2 is for Internal Use Only Courier: ❑ Fed Ex ❑ UPS❑ tJSPS❑ Client❑ Commercial❑ a Other Custody Seal on Cooler/Box Present: El no Seats intact: ❑ yes ❑ no Packing Material: [] Bubble VDp ❑ Bubble Bags ❑ None Other Thermometer Used: IR Gun T1401 Type of Ice: Wet Blue None ❑ Samples on ice, cooling process has begun Temp Correction Factor T1401 No Correction Corrected Cooler Temp.: ` -C Biological Tissue is Frozen: Yes No NIA pate and Initials of erson examining Temp should be above freezing to 6°C contents: Comments: Chain of Custody Present: a ONO ❑NIA 1. Chain of Custody Filled Out: 2YW El No El NIA 2, Chairs of Custody Relinquished: Yes ❑No ❑NIA 3, Sampler Name & Signature on COC: ❑Yes ❑No &NIA 4, Samples Arrived within Hold Time: Yes ONO ❑NIA 5. Short Hold Time Analysis (<72hr): ❑Yes NNo ❑NIA 6. Rush Turn Around Time Requested: ❑Yes &o ❑NIA 7. Sufficient Volume: es ONO ❑NIA 8, Correct Containers Used: W4, L7ZooMIA 9, -Pace Containers Used: ❑YeZN/A Containers Intact: As ❑No ❑NIA 10. Filtered volume received for Dissolved tests ❑Yes ❑No NIA 11. Sample Labels match COC: 114 ONO ❑NIA 12. -Includes date/time/tD/Analysis Matrix: 601 aO All containers needing preservation have been checked Yes No ❑NIA 13, All containers needing preservation are found to be in Yes ❑No ®N!A compliance with EPA recommendation. exceptions: VOA, coliform, TOC, O&G, W-DRO (water) ❑Y ❑No Samples checked for dechlorination: Yes ❑No ❑NIA 14. Headspace in VOA Vials (>6mm): Dyes ONO NIA 15. Trip Blank Present: ❑Yes ©No IONIA 16. Trip Blank Custody Seals Present ❑Yes ONO ANIA Pace Trip Blank Lot # (if purchased): Client Notification/ Resolution: Field Data Required? Y 1 N Person Contacted: Date/Time: Comments/ Resolution: SCURF Review: Date: `�Pffrf5P WO# : 92250342 SRF Review: juk Date: 1 �br Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR I Certification Office (Le out of hold, incorrect preservative, out of temp, 92250342 incorrect containers) Page 59 of 60 D U7 0 0 O z N Customer mull Complete 69 of 70 � .._ ._. _.. .._ ._. _„ „_ ,_, _•. ,._.•_. _„ _ a Q Er d m. L a -� a 0' ' r, o �+ '^ CJz� c ,�1 ,z. q a ' m :� � pay i Ctlalemer to Complete appropriate columns to rfg - Z �+ ^ v I - n ic 4 3a d n C ° ' n K r ? Q st m m '° m A xCD I 1 > Irl s �+ �" ❑ o o I i 7 1 C CCL " 3 d. fl1 I C° m -zI ri a 'V -C� pQ oIt CD. p p Y=uO j0 n n w cr , m f) f!! n v Cni N ` Lo o L �Ia ronnm oI> DQ iR W of m p g o ' I� a y cD N j 0 V• V ry or N ' " D L ._._,_.._._._- VI M1A, O I -.._._ - _.� ✓Vi ' CL d IImo' i '1 N .� f ► V1 1D 'w L� N ^7 i m A p w o 1 0 ' i Q> �� NJgCv ' i itJ 0o �� ' i Ulxs i y _ CO C1 T r Y 0 to Zi fyfnn ; •t�.�, 0 Iz "Comp. sap aty5 s e i o "Grab Req ire o x I m i Total Metals, Anions, 3' O R'Cn P 1 r - 8 oz jar (PACE) 6 h v i �p �� G �+ ii 110 TaC 7- 4 oz jar 4 3 c i rn a [' (PACE) I m s 0{ a a 0. b SPLP - Total Metals S and Anions ; 2 - 8 oz jars (PACE) a i �] 5 0� 3 j Sediment specific tests 2 - 8 oz jar ' (ACCESS I i i ANALYTICAL) 5 i i �=lnln i z i a i mTff +� _._.C'._._ _._.- 3 r! m� n0d C 0 - -- 'S p z07 01 M ®co z0- ' 1mZ 2°Total # of Containers Page 60 of 60 CHAIN OF_ CUSTODY RECORD AND ANALYSIS REQUEST___ FORM i �, �- - - Analytical Laboratory S�rvic+�ls_. _I F Analytical La T I Only - - - � . � g _.e._._,_._. '1�1' 1 wtth �nser NC_ Ms1I M6 3Jli CE33elei 7i I ['�, SOIL _ 13330 Hager s Ferry Rd , .}U M■lrt■: 1 ! ;!>fmpks r}„gInnr,ngL_rs"w ilunlereYUle. N. [;.. 3ho7�1' i {Laq�` anyNERGYe [5■tla T>iw - Lam? 875 6245 1 I r l3aa-------.--_._i L., + antra,[ i ie{it;u+lM C!�O"IM I@f� t wror t Name AB GTOUndwator Assessment - Sall I2"-.& W. IiF Let -II aS1<!I„rw i ��IFaK Na: .lI AB GVV �;: u. g yal■tese um i 6j[ nn9ttt In: TjMY Co-tls_ F 2 ruling U� 3 _ 'alit-11V 0 i DlPlae�les l4 YUhett i+Y4cifilc ac�bLattlnq Ilan Limon o- IabI4140 ! and Is nnl Inducated above ;.r,..d the I:Ibl 1ng: 1� Enlef r4w'rrrrl dccoun7iny hl all 5 accounting rietds above, Df 2 PrctuiUn {� FaC@ accauritin IOrt - er,tUt IJlnit and PFccnsx !Cl j• LAIR UstOWY Matrix I•, ( M. sedl n nt' ktifl 13�_ SOrn IS [t�ri tlarl rar ID f, 1 :LY"w�' - r ■ r'7T�e�� ' r— b Z ' ! n a I : u 6 t I 1 !� r--7 - j I 1 j lh J 1 1 1_ + � WATER £ IPMNENT BLANK 1 PER DAY +Ik T70 i S L : 2 4D RlN1i�Ptl■—FLatl LiY G+�1ui'[I"�;a PACE, Cool■r T3nno PCB 1142081 1"�nbser .:i i 2�FIa5C}, 3i ---------- L.00K... elarlrelarlaL al�riaa_ . Praaarwatlues when used must be added within 15 minutes of sample Collection "C611el:ti0ini Inforlrtatlon Date Tintoy-� _5,+�I)at, fe 1I- i :31f F- �tV��S 13-r5� �30 - t5■telTl - - - - - Metals: A]. Sb, As, Ba, Be, S, Cd. Ca. Cr, Cc, Cu, Fe, i'h, Mg. Mn, Mo, NI, Anions: CO. Nitrate-N. SGrtirnent$per.iLicPara meters: %solid! AM 'L� le Size Caw_ I"Wit to v i --- ,:-, in C7 W W L) -�` QV cm G N I� � } -V&- P3 ran -r _A- -/ Fr ,�../ Redox Potential xynterra EDIT DISTRIE1U710M ! ORIGINAL to LA8, I COPY o3 CI, I FNT I RE1 �7P1 G w r U 2.2RequasW Turnaroullct 14 Da" p 7 hays ' 4a H,